TRNG THPT CHUYN NGUYN HU

THI TH I HC LN I NM HC MN HA HC

Thi gian lm bi: 90 pht; (60 cu trc nghim)

M thi 132

H, tn th sinh:.......................................................................... S bo danh:...............................................................................

I. Phn chung cho tt c cc th sinh( 40 cu, t cu {<1>} n cu {<40>}) Cu 1: X l mt ancol c cng thc phn t C3H8On, X c kh nng ha tan Cu(OH)2 nhit thng. S cht c th c ca X l: A. 3 B. 4 C. 2 D. 1 Cu 2: t chy hon ton 1 anhit X c nCO2 - nH2O = nX. Cho 11,52 gam X phn ng vi lng d AgNO3 trong NH3 c 69,12 gam Ag. Cng thc ca X l: A. CH2(CHO)2 . B. CH2=CH-CHO. C. CH3CHO. D. HCHO. Cu 3: T m kg khoai c cha 25% tinh bt, bng phng php ln men ngi ta iu ch c 100 lt ru 0 60 .Gi tr ca m l: (bit khi lng ring ca C2H5OH l 0,8g/ml hiu sut chung ca c qu trnh l 90%) A. 375,65kg B. 338,09kg C. 676,2kg. D. 93,91kg Cu 4: Cht hu c X c cng thc phn t l C5H8O2. Cho X tc dng vi dung dch Br2 thu c cht hu c Y c cng thc l C5H8O2Br2. un nng Y trong NaOH d thu c glixerol, NaBr v mui cacboxylat ca axit Z. Vy cng thc cu to ca X l : A. HCOOCH(CH3)-CH=CH2 B. CH3-COOCH=CH-CH3 C. CH2=CH-COOCH2CH3 D. CH3COOCH2-CH=CH2 Cu 5: Ha tan hon ton 31,25 gam hn hp X gm Mg, Al v Zn trong dung dch HNO3, sau phn ng hon ton thu c dung dch Y v hn hp gm 0,1 mol N2O v 0,1 mol NO. C cn dung dch sau phn ng thu c 157,05 gam hn hp mui. Vy s mol HNO3 b kh trong phn ng trn l: A. 0,45 mol B. 0,5 mol C. 0,30 mol D. 0,40 mol Cu 6: Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin, vinyl clorua. S cht trong dy khi thy phn trong dung dch NaOH long(d), un nng sinh ra ancol l: A. 4 B. 3 C. 5 D. 6 Cu 7: Mt - aminoaxit c cng thc phn t l C2H5NO2, khi t chy 0,1 mol oligopeptit X to nn t aminoaxit th thu c 12,6 gam nc.Vy X l: A. tetrapeptit B. ipeptit C. tripeptit D. pentapeptit Cu 8: Kh CO2 tc dng c vi: (1) nc Gia-ven; (2) dung dch K2CO3; (3) nc Brom; (4) dung dch NaHSO3; (5) dung dch KOH, (6) dung dch NaHCO3, (7) Mg nung nng. A. 1, 2, 5, 6 B. 2, 4, 5, 7 C. 1, 2, 5, 7 D. 2, 3, 4, 5 Cu 9: t chy hon ton 29,16 gam hn hp X gm RCOOH, C2H3COOH, v (COOH)2 thu c m gam

H2O v 21,952 lt CO2 (ktc). Mt khc, 29,16 gam hn hp X phn ng hon ton vi NaHCO3 d thu c 11,2 lt (ktc) kh CO2.Gi tr ca m l A. 10,8 gam B. 9 gam C. 8,1gam D. 12,6 gam Cu 10: Gi s gang cng nh thp ch l hp kim ca St vi Cacbon v St ph liu ch gm St, Cacbon t0 v Fe2O3. Coi phn ng xy ra trong l luyn thp Martanh Fe2O3 + 3C 2 Fe + 3CO l: Khi lng St ph liu (cha 40% Fe2O3, 1%C) cn dng khi luyn vi 6 tn gang 5%C trong l luyn thp Martanh, nhm thu c loi thp 1%C, l: A. 1,82 tn B. 2,73 tn C. 1,98 tn D. 2,93 tn Cu 11: t chy hon ton m gam cht bo X (cha triglixerit ca axit stearic,axit panmitic v cc axit bo t do ). Sau phn ng thu c 13,44 lt CO2 (ktc) v 10,44 gam nc. X phng ho m gam X (H=90%) th thu c khi lng glixerol l: A. 2,484 gam B. 0,828 gam C. 1,656 gam D. 0,92 gam Cu 12: Cho t t 300ml dung dch NaHCO3 0,1M, K2CO3 0,2M vo 100ml dung dch HCl 0,2M; NaHSO4 0,6M thu c V lt CO2 thot ra ktc v dung dch X. Thm vo dung dch X 100ml dung dch KOH 0,6M; BaCl2 1,5M thu c m gam kt ta. Gi tr ca V v m l: Trang 1/5 - M thi 132

A. 0,448 lt v 11,82g B. 0,448 lt v 25,8g C. 1,0752 lt v 23,436g D. 1,0752 lt v 24,224g Cu 13: Sc 13,44 lt CO2 ( ktc) vo 200 ml dung dch X gm Ba(OH)2 1,5M v NaOH 1M . Sau phn ng thu c m1 gam kt ta v dung dch X. Cho dung dch X tc dng vi 200ml dung dch BaCl2 1,2M; KOH 1,5M thu c m2 gam kt ta. Gi tr ca m2 l: A. 39,4 gam B. 47,28 gam C. 59,1 gam D. 66,98 gam Cu 14: Ho tan hon ton hn hp X (gm x mol Fe, y mol Cu, z mol Fe2O3 v t mol Fe3O4) trong dung dch HCl khng thy kh c kh bay ra khi khi bnh, dung dch thu c ch cha 2 mui. Mi quan h gia s mol cc cht c trong hn hp X l. A. x+ y = 2z +2t B. x +y = z +t C. x+y =2z +3t D. x+y =2z +2t Cu 15: Ha tan hon ton m gam hn hp gm Na, Na2O, NaOH v Na2CO3 trong dung dch axt H2SO4 40% (va ) thu c 8,96 lt hn hp kh c t khi i vi H2 bng 16,75 v dung dch Y c nng 51,449%. C cn Y thu c 170,4 gam mui. Gi tr ca m l: A. 37,2 gam B. 50,4 gam C. 50,6 gam D. 23,8 gam Cu 16: Hn hp X gm hai aminoaxit mch h no c 1 nhm COOH v 1 nhm NH2 ng ng k tip c phn trm khi lng oxi l 37,427%. Cho m gam X tc dng vi 800ml dung dch KOH 1M (d) sau khi phn ng kt thc c cn dung dch thu c 90,7gam cht rn khan. m c gi tr l : A. 67,8 gam B. 68,4 gam C. 58,14 gam D. 58,85 gam Cu 17: Cho s phn ng
O OH ,t, x, txt NaOH du ,t CuO , t CH C6H5 CH3 +Cl ( a. s+) A B C D E .Tn gi ca E l: A. phenyl axetat B. metyl benzoat C. axit benzoic D. phenl metyl ete Cu 18: Ha tan 32,52 gam photpho halogenua vo nc c dung dch X. trung ha hon ton dung dch X cn 300 ml dung dch KOH 2M. Cng thc ca photpho halogenua l: A. PCl5 B. PBr5 C. PBr3 D. PCl3. Cu 19: Hp cht hu c mch h X c cng thc phn t C5H10O. Cht X khng phn ng vi Na, tho
2 0 0 3
2

mn s chuyn ho sau: X Y Este c mi chui chn. Tn ca X l A. 2-metylbutanal. B. pentanal. C. 3-metylbutanal. D. 2,2-imetylpropanal Cu 20: Cho dy cc cht: C r O 3 , C r 2 O 3 , SiO2, Cr(OH)3, CrO, Zn(OH)2, NaHCO3, Al2O3. S cht trong dy tc dng c vi dung dch NaOH (c, nng) l A. 4. B. 7. C. 6. D. 5. Cu 21: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,1 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng dung dch thay i: A. gim 10,4 gam. B. tng 7,8 gam. C. gim 7,8 gam. D. tng 14,6 gam. Cu 22: Cho C7H16 dng vi clo c chiu sng theo t l mol 1: 1 thu c hn hp gm 3 dn xut monoclo. S cng thc cu to ca C7H16 c th c l A. 4 B. 5 C. 2 D. 3 Cu 23: Ho tan Fe3O4 trong lng d dung dch H2SO4 long thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al, H2S? A. 5 B. 8 C. 6 D. 7 Cu 24: Xt phn ng thun nghch sau: SO2(k) + NO2(k) SO3(k) +

+ H 2 ,Ni,t

+ CH 3COOH,Xt H 2 SO 4

NO(k). Cho 0,11(mol) SO2, 0,1(mol) NO2, 0,07(mol) SO3 vo bnh kn 1 lt. Khi t cn bng ha hc th cn li 0,02(mol) NO2. Vy hng s cn bng KC l A. 20 B. 18 C. 23 D. 0,05 Cu 25: Cht no sau y tn ti dng mng tinh th phn t? A. P trng, than ch B. kim cng, pht pho C. kim cng, P trng D. I2, nc Cu 26: C cc nhn nh sau: Trang 2/5 - M thi 132

1)Cu hnh electron ca ion X l 1s 2s 2p 3s 3p 3d . Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc chu k 4, nhm VIIIB. + 2)Cc ion v nguyn t: Ne , Na , F c im chung l c cng s electron. 2+ + 3) Bn knh ca cc vi ht sau c sp xp theo th t gim dn: Mg , Na , F , Na, K. 4)Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l K, Mg, Si, 5)Tnh baz ca dy cc hiroxit: NaOH, Al(OH)3 , Mg(OH)2 gim dn. Cho: N (Z = 7), F (Z=9), Ne (Z=10), Na (Z=11), Mg (Z=12), Al (Z=13), K (Z = 19), Si (Z = 14). S nhn nh ng: A. 5. B. 4. C. 3. D. 2. Cu 27: un nng fomandehit vi phenol (d) c axit lm xc tc thu c polime c cu trc: A. Mch phn nhnh B. Mch khng phn nhnh C. Khng xc nh c D. Mng li khng gian Cu 28: Cho Cacbon (C) ln lt tc dng vi H2, Al, H2 O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 5 B. 6 C. 7 D. 4 Cu 29: Cho cc dung dch sau cng nng mol/l : NH2CH2COOH (1), CH3COOH (2), CH3CH2NH2 (3), NH3 (4). Th t pH tng dn ng l : A. (2), (1), (4), (3) B. (1), (2), (3), (4) C. (1), (2), (4), (3) D. (2), (1), (3), (4) Cu 30: Mt mui X c cng thc C3H10O3N2. Ly 17,08g X cho phn ng ht vi 200ml dung dch KOH 2M. C cn dung dch sau phn ng thu c phn hi v cht rn. Trong phn hi c mt cht hu c Y (bc 1), trong phn rn ch l hn hp cc cht v c. Khi lng ca phn rn l: A. 16,16g B. 28,7g C. 16,6g D. 11,8g Cu 31: Cho cc cht: BaCl2; NaHSO3; NaHCO3; KHS; NH4Cl; AlCl3; CH3COONH4, Al2 O3, Zn, ZnO. S cht lng tnh l: A. 8 B. 7 C. 6 D. 5 Cu 32: Nhn nh no sau y khng ng? A. Phn t mantoz do 2 gc glucoz lin kt vi nhau qua nguyn t oxi, gc th nht C1, gc th hai C4(C1OC4) B. Phn t saccaroz do 2 gc glucoz v fructoz lin kt vi nhau qua nguyn t oxi, gc glucoz C1, gc fructoz C4(C1OC4) C. Tinh bt c 2 loi lin kt [1,4]glicozit v [1,6]glicozit D. Xenluloz c cc lin kt [1,4]glicozit Cu 33: in phn vi in cc tr dung dch cha 0,3 mol AgNO3 vi cng dng in 2,68 A, trong thi gian t (gi) thu c dung dch X (hiu sut qu trnh in phn l 100%). Cho 22,4 gam bt Fe vo X thy thot ra kh NO (sn phm kh duy nht) v sau cc phn ng hon ton thu c 34,28 gam cht rn. Gi tr ca t l A. 0,60. B. 1,00. C. 0,25. D. 1,20. o Cu 34: Sc 1,56g C2H2 vo dung dch cha HgSO4, H2SO4 trong nc 80 C thu c hn hp gm 2 cht kh (bit hiu sut phn ng t 80%). Tip tc cho hn hp kh thu c qua dung dch AgNO3/NH3 d thu c m gam kt ta. Gi tr ca m l: A. 13,248g B. 2,88g C. 12,96g D. 28,8g Cu 35: Cho cc phn ng: (a) Zn + HCl (long) (b) Fe3O4 + H2SO4 (long) (c) KClO3 + HCl (c) (d) Cu + H2SO4 (c) (e) Al + H2SO4 (long) (g) FeSO4 + KMnO4 + H2SO4

2+

S phn ng m H ca axit ng vai tr cht oxi ho l A. 5. B. 3. C. 6. D. 2. Cu 36: Cho t t 450 ml dd HCl 1M vo 500 ml dung dch X gm Na2CO3 v NaHCO3 th thu c 5,6 lt kh (ktc) v dung dch Y. Cho dung dch Y tc dng vi dung dch Ba(OH)2 d th thu c 19,7 gam kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dung dch X ln lt l: A. 0,2M v 0,15M B. 0,2M v 0,3M C. 0,3M v 0,4M D. 0,4M v 0,3M Trang 3/5 - M thi 132

Cu 37: Cho cc polime sau: PE (1), PVC (2), cao su buna (3), poli isopren (4), amiloz (5), amilopectin (6), xenluloz (7), cao su lu ho (8), nha rezit (9). Cc polime c cu trc khng phn nhnh l A. 1,2,3,4,6,7. B. 1,3,4,5,8. C. 1,2,4,6,8. D. 1,2,3,4,5,7. Cu 38: Thc hin cc th nghim sau: (a) Nung NH4NO3 rn. (b) un nng NaCl tinh th vi dung dch H2SO4 (c). (c) Cho CaOCl2 vo dung dch HCl c. (d) Sc kh CO2 vo dung dch Ca(OH)2 (d). (e) Sc kh SO2 vo dung dch KMnO4. (g) Cho dung dch KHSO4 vo dung dch NaHCO3. h) Cho ZnS vo dung dch HCl (long). (i) Cho Na2CO3 vo dung dch Fe2(SO4)3. S th nghim sinh ra cht kh l A. 4. B. 5. C. 2. D. 6. Cu 39: Cho cc kim loi: Cr, W , Fe , Cu , Cs . Sp xp theo chiu tng dn cng t tri sang phi l A. Cu < Cs < Fe < Cr < W B. Cu < Cs < Fe < W < Cr C. Cs < Cu < Fe < Cr < W D. Cs < Cu < Fe < W < Cr Cu 40: Khi nhit phn hon ton m gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 nhiu nht l A. KNO3 B. AgNO3 C. KMnO4 D. KClO3 II. Phn ring( 10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II ) Phn I: Theo chng trnh Chun ( t cu {<41>} n cu {<50>}) Cu 41: Oxi ho khng hon ton 0,16 mol hn hp gm ancol etylic v mt ancol n chc X bng CuO nung nng(H=100%), thu c hn hp cht hu c Y. Cho hn hp Y phn ng vi AgNO3 trong dung dch NH3 d thu c 51,84 gam bc. Tn gi ca X l A. propan-2-ol B. 2-metylpropan-2-ol C. propan-1-ol D. Metanol Cu 42: Dy gm cc cht c th iu ch trc tip c axit axetic l: A. C2H2, CH3CHO, HCOOCH3 B. C2H5OH, HCHO, CH3COOCH3 C. C2H5OH, CH3CHO, CH3COOCH3 D. C2H5OH, CH3CHO, HCOOCH3 Cu 43: Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, K2O, MgO nung nhit cao. Sau phn ng hn hp rn cn li l: A. Cu, Fe, K2O, MgO. B. Cu, Fe, K2O, Mg. C. Cu, FeO, KOH, MgO. D. Cu, Fe, KOH, MgO. Cu 44: Cho cc phn ng: (1) Ca(OH)2 + Cl2 (4) H2S + SO2 (2) NO2 + NaOH (5) KClO3 + S t o (3) PbS + O3 (6) Fe3O4 + HCl S phn ng oxi ho kh l A. 2. B. 4 C. 5. D. 3 Cu 45: Ho tan hon ton m gam Fe trong dung dch HNO3 thy c 0,3 mol kh NO2 sn phm kh duy nht thot ra, nh tip dung dch HCl va vo li thy c 0,02 mol kh NO duy nht bay ra. C cn dung dch sau phn ng thu c cht rn c khi lng l: A. 24,27 g B. 26,92 g C. 19,5 g D. 29,64 g Cu 46: Trong cc cht : propen (I) ; 2-metylbut-2-en(II) ; 3,4-imetylhex-3-en(III) ; 3-cloprop-1-en(IV) ; 1,2-icloeten (V), cht no c ng phn hnh hc : A. I, V B. III, V C. II, IV D. I, II, III, IV Cu 47: C cc dung dch sau (dung mi nc) : CH3NH2 (1); anilin (2); amoniac (3); HOOC-CH(NH2)COOH (4); H2N-CH(COOH)-NH2(5), lysin (6), axit glutamic (7). Cc cht lm qu tm chuyn thnh mu xanh l:

A. (1), (2), (3) B. (1), (3), (5), (6) C. (1), (2), (3), (5) D. (1), (2), (3), (4), (5) Cu 48: X l mt -Aminoaxit no, cha 1 nhm -COOH v 1 nhm -NH2. T m gam X iu ch c m1 gam ipeptit. T 2m gam X iu ch c m2 gam tripeptit. t chy m1 gam ipeptit thu c 0,3 mol nc. t chy m2 gam tripeptit thu c 0,55 mol H2O. Gi tr ca m l: A. 11,25 gam B. 13,35 gam C. 22,50 gam D. 26,70 gam Cu 49: Tch ring Ag ra khi hn hp Ag, Cu, Ni, Fe dng bt. Dung dch cn dng l (vn gi nguyn khi lng ca Ag ban u) A. Dung dch FeCl3 B. Dung dch HNO3 c ngui Trang 4/5 - M thi 132

C. Dung dch H2SO4 long D. Dung dch HCl Cu 50: Cc kh thi cng nghip v ca cc ng c t, xe my... l nguyn nhn ch yu gy ra ma axit. Thnh phn ha hc ch yu trong cc kh thi trc tip gy ra ma axit l: A. NO2, CO2, CO. B. SO2, CO, NO2. C. SO2, CO, NO. D. NO, NO2, SO2. Phn II: Theo chng trnh nng cao Cu 51: Thu phn hon ton 150 gam hn hp cc ipeptit thu c 159 gam cc aminoaxit. Bit rng cc ipeptit c to bi cc aminoaxit ch cha mt nguyn t N trong phn t. Nu ly 1/10 khi lng aminoaxit thu c tc dng vi HCl d th lng mui thu c l: A. 19,55 gam B. 20,735 gam C. 20,375 gam D. 23,2 gam Cu 52: Hn hp X gm: HCHO, CH3COOH, HCOOCH3 v CH3CH(OH)COOH. t chy hon ton hn hp X cn V lt O2 (ktc) sau phn ng thu c CO2 v H2O. Hp th ht sn phm chy vo nc vi trong d thu c 50 gam kt ta. Vy gi tr ca V tng ng l: A. 7,84 lt B. 8,40 lt C. 11,2 lt D. 16,8 lt Cu 53: Tnh pH ca dd A gm HF 0,1M v NaF 0,1M.Bit hng s axit ca HF l Ka = 6,8.10-4. A. 2,18 B. 1,18 C. 3,17 D. 1,37 Cu 54: A l mt hp cht mu lc thc t khng tan trong dung dch long axit v kim. Khi nu chy vi K2CO3 c mt khng kh th chuyn thnh cht B c mu vng (d tan trong nc). Cho cht B tc dng vi H2SO4 long to thnh cht C c mu da cam. Cht C tc dng vi HCl c thy to thnh cht kh mu vng lc. A, B, C ln lt l A. Cr2O3, K2CrO4, K2Cr2O7. B. CrO3, K2CrO4, K2Cr2O7. C. CrO, K2Cr2O7, K2CrO4. D. Cr2O3, K2Cr2O7, K2CrO4. Cu 55: C dung dch X gm (KNO3 v H2SO4). Cho ln lt tng cht sau: Fe2O3, FeCl2, Cu, FeCl3, Fe3O4, CuO, FeO tc dng vi dung dch X. S phn ng oxi ha kh xy ra l A. 5 B. 4 C. 3 D. 2 Cu 56: Khng th dng cht no sau y phn bit CO2 v SO2? A. Dung dch KMnO4 B. Kh H2S C. dung dch Br2. D. Ba(OH)2. Cu 57: Cho 7,52g hn hp hi gm C2H2 v CH3CHO tc dng vi dung dch AgNO3/NH3 d thu c 50,4g kt ta. Ha tan kt ta vo dung dch HCl d cn li m gam khng tan. Gi tr ca m l: A. 34,44 gam B. 38,82gam C. 56,04gam D. 13,44gam 0 Cu 58: T 180 lt ancol etylic 40 (khi lng ring ca ancol etylic nguyn cht l d = 0,8g/ml) iu ch c bao nhiu kg cao su buna (hiu sut qu trnh l 75%) A. 25,357 kg B. 18,783 kg C. 28,174 kg D. 18,087 kg Cu 59: Pht biu no sau y l ng: A. Trong n mn in ho trn cc m xy ra qu trnh oxi ho. B. Trong in phn dung dch NaCl trn catot xy ra qu trnh oxi ho nc. C. Than cc l nguyn liu cho qu trnh sn xut thp. D. Criolit c tc dng h nhit nng chy ca Al. Cu 60: Pht biu no sau y l ng? A. Trng hp stiren thu c poli(phenol-fomanehit). B. T nilon-6,6 c iu ch bng phn ng trng hp hexametylen iamin vi axit aipic. C. Trng hp buta-1,3-ien vi stiren c xc tc Na c cao su buna-S. D. T visco l t tng hp.

S GIO DC V O TO TN TRNG THPT TRI CAU

7 THI TH I HC Mn: Ho (Thi gian lm bi 90 pht)

H, tn th sinh:......................................................................SBD:..............................

Cho bit:H=,7, C=,72, N=,74, O=,76, Mg=24, Al=27, P=3,7, S=32, Cl=35,5, K=39, Ca=40, Cr=52, Fe=56, Cu=64, Zn=65, Br=80, Ag=108, Ba=137
Cu 1: Mt cht bt mu lc thm X thc t khng tan trong dung dch long ca axit v kim. Khi nu chy vi dd NaOH c v c mt kh clo n chuyn thnh cht Y d tan trong nc, cht Y tc dng vi dd axit sunfuric long chuyn thnh cht Z . Cht Z b S kh thnh cht X v cht Z oxi ha c axit clohidric thnh kh clo. Tn ca cc cht X,Y,Z v s phn ng oxihoa - kh ln lt l: A. crom(III) hiroxit; natriicromat; natricromat ; 2 B. crom(III) oxit; natricromat; natriicromat ; 3 C. crom(III) oxit; natriicromat ; natricromat ; 2 D. crom(III) oxit; natricromat; natriicromat ; 2 Cu 2: Cho 2,58 gam hn hp gm Al va Mg phn ng va vi 20 ml dung dch hn hp 2 axt HNO3 4M v H2SO4 7M (m c). Thu c 0,02 mol mi kh SO2, NO, N2O. Tnh s khi lng mui thu c sau phn ng A. 16,60 gam B. 15,34 gam C. 12,10 gam D. 18,58 gam Cu 3: Mt hn hp X gm ankan A v anken B c chia thnh 2 phn: - Phn 1: c th tch l 11,2 lt, em trn vi 6,72 lt H2, un nng (c xc tc Ni) n khi phn ng hon ton ri a v nhit v p sut ban u th thy hn hp kh sau phn ng c th tch gim 25% so vi ban u. - Phn 2: nng 80 gam, em t chy hon ton thu c 242 gam CO2. Cng thc phn t ca A v B ln lt l: A. C4H10 v C3H6 B. C3H8 v C2H4 C. C2H6 v C3H6 D. CH4 v C4H8 Cu 4: Hp th hon ton V lt CO2 (ktc) vo 400ml dung dch NaOH a M th thu c dng dch X. Cho t t va khuy u 300ml dung dch HCl 1M vo X thu c dung dch Y v 4,48 lt kh (ktc). Cho Y tc dng vi Ca(OH)2 d xut hin 30 gam kt ta. Xac inh a? A. 0,75M. B. 2M. C. 1,5M. D. 1M. Cu 5: E l este mch khng nhnh ch cha C, H, O, khng cha nhm chc no khc. un nng mt lng E vi 150 ml dung dch NaOH 1M n kt thc phn ng. trung ho dung dch thu c cn 60ml dung dch HCl 0,5M. C cn dung dch sau khi trung ho c 11,475 gam hn hp hai mui khan v 5,52 gam hn hp 2 ancol n chc. Cng thc cu to ca este l A. CH3CH2CH2-OOC-CH2CH2COOCH3 B. HCOOCH3 v CH3COOC2H5 C. C2H5-COO-C2H5 D. CH3-CH2-OOC-CH2COOCH3 Cu 6: phn bit 4 cc ng ring bit 4 loi nc sau b mt nhn: nc ct, nc cng tm thi, nc cng vnh cu, nc cng ton phn: A. un nng, dng dd NaOH B. dng dd Na2CO3 , un nng C. un nng, dng dd Na2CO3 D. Dng dd Ca(OH)2 , un nng Cu 7: Cho hi nc i qua than nng c hn hp kh A gm CO2,CO, H2. Ton b lng kh A va kh ht 72 gam CuO thnh Cu v thu c m gam H2O. Lng nc ny hp th vo 8,8 gam dd H2SO4 98% th dd axit H2SO4 gim xung cn 44%. Phn trm th tch CO2 trong hn hp kh A l A. 28,57. B. 16,14. C. 14,29. D. 13,24. Cu 8: Ho tan mt loi qung st vo dd HNO3 long, d thu c hn hp X gm 2 cht kh khng mu trong c mt kh l oxit ca nit. Tn gi ca qung b ho tan l: A. Hematit nu. B. Manhetit. C. Xiderit. D. Pirit. Cu 9: Mt trong cc tc dng ca mui it l c tc dng phng bnh bu c. Thnh phn ca mui it l: A. NaCl c trn thm mt lng nh KI B. NaCl c trn thm mt lng nh AgI C. NaCl c trn thm mt lng nh I2 D. NaCl c trn thm mt lng nh HI Cu 10: C 5 hn hp kh c nh s: 1. CO2, SO2, N2, HCl. 2. Cl2, CO, H2S, O2. 3. HCl, CO, N2, Cl2. 4. H2, HBr, CO2, SO2. 5. O2, CO, N2, H2, NO. 6. F2 , O2 ; N2 ; HF C bao nhiu hn hp kh khng tn ti c iu kin thng : A. 2 B. 5 C. 4 D. 3

Cu 11: Ta tin hnh cc th nghim: MnO2 tc dng vi dung dch HCl (1). t qung sunfua (2); Nhit phn mui Zn(NO3)2 (3) Nung hn hp: CH3COONa + NaOH/CaO (4). Nhit phn KNO3(5). Cc bao nhiiu th nghim to ra sn phm kh gy nhim mi trng l: A. 5 B. 3 C. 4 D. 2 Cu 12: C 3 dung dch sau ng trong 3 l mt nhn: dung dch natriphenolat, natri cacbonat, natrialuminat, natri fomat. phn bit 3 dung dch ny bng mt thuc th ta dng: A. Dung dch HCl B. Qu tm C. Dung dch CaCl2 D. Dung dch NaOH Cu 13: Nhit phn 17,54 gam hn hp X gm KClO3 v KMnO4, thu c O2 v m gam cht rn gm K2MnO4, MnO2 v KCl . Ton b lng O2 tc dng ht vi cacbon nng , thu c 3,584 lt hn hp kh Y (ktc) c t khi so vi O2 l 1. Thnh phn % theo khi lng ca KClO3 trong X l: A. 62,76% B. 74,92% C. 72,06% D. 27,94% Cu 14: Cho 80 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 83,02 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l: A. 12,58 gam B. 12,4 gam C. 12,0 gam D. 12,944 gam Cu 15: Chn cu sai trong s cc cu sau y A. Ngm thanh thp trong du ha ri ngoi khng kh m thanh thp s b n mn chm hn B. Trn b mt ca cc h nc vi hay cc thng nc vi ngoi khng kh thng c mt lp vng mng. Lp vng ny ch yu l canxi cacbonat. C. Nhit nng chy ca hp kim thng cao hn nhit nng chy ca cc kim loi ban u D. Phng php in phn c th iu ch c hu ht cc kim loi t Li, Na, Fe, Cu, Ag. Cu 16: Dy cc cht no sau y tt c cc cht u d b nhit phn A. NaHCO3, MgCO3, BaSO4, (NH4)2CO3. B. NaHCO3, NH4HCO3, H2SiO3, NH4Cl. C. K2CO3, Ca(HCO3)2, MgCO3, (NH4 )2CO3, D. NaHCO3, Na2CO3, CaCO3, NH4NO3. Cu 17: Cho tng dung dch: NH4Cl, HNO3, Na2CO3, Ba(HCO3)2, MgSO4, Al(OH)3 ln lt tc dng vi dung dch Ba(OH)2. S phn ng thuc loi axit baz l: A. 4 B. 2 C. 5 D. 3 Cu 18: Cho cc t sau: t axetat, t capron, t nitron, t visco, t nilon-6,6; t enang hay t nilon-7, t lapsan hay poli (etylen terephtalat). C bao nhiu t thuc loi t poliamit? A. 2 B. 4 C. 3 D. 1 Cu 19: T khi hn hp X gm: C2H6; C2H2; C2H4 so vi H2 l 14,25. t chy hon ton 11,4 gam X, cho sn phm vo bnh ng dung dch Ca(OH)2 d thy khi lng bnh tng m gam v c a gam kt ta. Gi tr ca m v a ln lt l A. 62,4 v 80. B. 68,50 v 40. C. 73,12 v 70. D. 51,4 v 80. Cu 20: Cho hn hp cha Na, Ba ly d vo 180g dung dch H2SO4 49% th th tch kh H2 thot ra iu kin tiu chun l: A. 20,16 lit B. 77,28 lit C. 134,4 lit D. 67,2 lit Cu 21: Cho 5,6g bt Fe vo 300ml dung dch HCl 1M sau phn ng thu c dung dch A . Cho A tc dng vi 800ml dung dch AgNO3 1M n phn ng hon ton to m gam kt ta. Gi tr ca m l: A. 43,05g B. 10,8g C. 21,6g D. 53,85g Cu 22: Cho cc cht: etilenglicol, anlyl bromua, metylbenzoat, valin, brombenzen, axit propenoic, axeton, tripanmitin, lng trng trng, .Trong cc cht ny, s cht tc dng vi dd NaOH l: A. 5 B. 6 C. 4 D. 7 Cu 23: Cho m gam Fe vo dung dch AgNO3 c hn hp X gm 2 kim loi. Chia X lm 2 phn. - Phn 1: c khi lng m1 gam, cho tc dng vi dung dch HCl d, c 0,1 mol kh H2. - Phn 2: c khi lng m2 gam, cho tc dng ht vi dung dch HNO3 long d, c 0,4 mol kh NO. Bit m2 m1 = 32,8. Gi tr ca m bng: A. 1,74 gam hoc 6,33 gam B. 33,6 gam hoc 47,1 gam C. 3,36 gam hoc 4,71 gam D. 17,4 gam hoc 63,3 gam m gam Cu 24: Ho tan hon ton hn hp X gm FeS2 v Cu2S vo axit HNO3 (va ), thu c dung dch X (ch cha hai mui sunfat) v 8,96 lt (ktc) kh duy nht NO. Nu cng cho lng X trn tan vo trong dd H2SO4 c nng thu c V lit (ktc) kh SO2 . Gi tr ca V l A. 8,96. B. 13,44. C. 6,72. D. 5,6. Cu 25: Cho dy cc cht: isopentan , lysin, glucoz, isobutilen, propanal, isopren, axit metacrylic, phenyl amin, m-crezol, cumen, stiren, xiclo propan. S cht trong dy phn ng c vi nc brom l: A. 9 B. 6 C. 8 D. 7

Cu 26: Trong cc dy cht sau, dy gm tt c cc cht u khng tham gia phn ng trng bc l: A. Vinyl axetilen, etilen, benzen, axit fomic B. Metyl axetat, but-2-in, mantoz, fructoz C. Vinyl fomat, but-1-in, vinyl axetilen, anehit propionic D. Axetilen, propin, saccaroz, axit oxalic Cu 27: Cho cc pht biu sau v cacbohirat: (a) fructoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit, khi un vi dd H2SO4 long th sn phm thu c u c phn ng trng gng (c) Trong dung dch, glucoz v saccaroz u ha tan Cu(OH)2, to phc mu xanh lam m. (d) Khi thy phn hon ton hn hp gm xeluloz v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng fructoz vi Cu(OH)2 / NaOH u thu c Cu2O (g) Glucoz v glucoz u tc dng vi H2 (xc tc Ni, un nng) to sobitol. S pht biu ng l: A. 3 B. 5 C. 4 D. 6 Cu 28: Cho cn bng ha hc: a A(k) + b B(k) cC(k) + d D(k). (A, B, C, D l k hiu cc cht, a, b, c, d l h s nguyn dng ca phng trnh phn ng). 1050C, s mol cht D l x mol; 180oC, s mol cht D l y mol. Bit x > y, (a + b) > (c + d). Kt lun no sau y ng: A. Phn ng thun ta nhit v tng hiu sut cn gim p sut B. Phn ng thun ta nhit v tng hiu sut cn tng p sut C. Phn ng thun thu nhit v tng hiu sut cn tng p sut D. Phn ng thun thu nhit v tng hiu sut cn gim p sut. Cu 29: 17,7 gam hn hp X gm 2 anehit n chc phn ng hon ton vi dung dch AgNO3 trong NH3 (dng d) c 1,95 mol Ag v dung dch Y. Ton b Y tc dng vi dung dch HCl d c 0,45 mol CO2. Cc cht trong hn hp X gm: A. C2H3CHO v HCHO B. C2H5CHO v CH3CHO C. CH3CHO v HCHO D. C2H5CHO v HCHO Cu 30: Cho s sau: X Z CH3COOH Y T Vi mi mi tn l mt phn ng th X,Y,Z,T l: A. etanol, natri axetat, anehit axetic, glucoz B. etylaxetat ,natri etylat, etanol, C. anehit axetic, vinylaxetat, etylclorua, butan D. metanol, butan, etanol ,natri axetat Cu 31: in phn 1lit dd hn hp gm HCl 0,01M ;CuSO4 0,01M v NaCl 0,02M vi in cc tr ,mng ngn xp . Khi anot thu c 0,336lit kh (ktc) th dng in phn. Dung dch sau in phn c pH bng: A. pH =8 B. pH =6 C. pH =7 D. pH =5 Cu 32: Trong cc phn ng sau: 1, dung dch BaS + dd H2SO4 2, dung dch Na2CO3 +dd FeCl3 3, dung dch Na2CO3 + dd CaCl2 4, dung dch Mg(HCO3)2 + dd HCl 5, dung dch(NH4)2SO4 + dd KOH 6, dung dch NH4HCO3 + dd Ba(OH)2 Cc phn ng sn phm to ra c ng thi c kt ta v kh bay ra l: A. 1,2,6 B. 1,4,6 C. 3,4,5 D. 1,5,6 Cu 33: Cho cc pht biu sau: (a) Khi t chy hon ton mt cht hu c X bt k cha C, H, O, nu thu c s mol CO2 nh hn s mol H2O th X l ankan hoc ancol no, mch h (b) Trong thnh phn hp cht hu c nht thit phi c H (c) Lin kt ha hc ch yu trong hp cht hu c l lin kt cng ha tr. (d) Nhng hp cht hu c c thnh phn nguyn t ging nhau, thnh phn phn t hn km nhau 1 hay nhiu nhm CH2 - l ng ng ca nhau (e) Phn ng hu c thng xy ra chm v khng theo mt hng nht nh (g) Hp cht C7H8BrCl c vng benzen trong phn t S pht biu ng l A. 4 B. 3 C. 2 D. 5

Cu 34: Pht biu no sau y l ng? A. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ha hc, ch cn dng thuc th l dd KMnO4. B. Dung dch phenol v dung dch anilin khng lm i mu qu tm nhng dung dch mui ca chng th lm i mu qu tm C. Phn ng gia glixerol vi axit HNO3 c ( iu kin thch hp), to thnh thuc sng khng khi D. Trong phn ng este ha gia cc axit hu c, n chc RCOOH vi ancol no, n chc ROH, sn phm H2O to nn t -H trong nhm -COOH ca axit v nhm -OH ca ancol. Cu 35: Cho s sau: 0 KOH /e tan ol ( t0 ) NaOH ,HCl H ( t ) 2 (CH3)2CH-CH2CH2Cl ABCDE O E c cng thc cu to l A. (CH3)2CH-CH2CH2OH. B. (CH3)2CH-CH(OH)CH3. C. (CH3)2C=CHCH3. D. (CH3)2C(OH)-CH2CH3. Cu 36: Cho cc nguyn t 19K, 11Na, 20Ca, 9F, 8O, 17Cl. C bao nhiu phn t hp cht ion to thnh t 2 nguyn t trong cc nguyn t trn c cu hnh electron ca cation khc cu hnh electron ca anion ? A. 4 B. 6 C. 3 D. 5 Cu 37: Cht X c CTPT C8H14O4 tho mn s sau: X + 2NaOH ( X1 + X2 + H2O X1 + H2SO4 ( X3 + Na2SO4 nX3 + nX4 ( nilon 6,6 + nH2O 2X2 + X3 ( X5 + 2H2O ; Cng thc cu to ca X l: A. HCOO(CH2)6OOCH B. CH3OOC(CH2)4COOCH3 C. CH3OOC(CH2)5COOH D. CH3CH2OOC(CH2)4COOH Cu 38: Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 46 B. 68 C. 45 D. 85 Cu 39: Cho cc cht sau: ancol etylic(1),imetyl ete (2), axit axetic (3), metyl axetat(5), etyl clorua(6). Sp xp theo chiu gim nhit si l: A. 3 > 1 > 5 > 2 > 6 B. 3 > 1 > 5 > 6 > 2 C. 3 > 1 > 6 > 5 > 2 D. 3 > 1 > 6 > 2 > 5 Cu 40: Hn hp kh A gm SO2 v khng kh c t l th tch l 1 : 5. Nung hn hp A vi xc tc V2O5 trong mt bnh kn c dung tch khng i thu c hn hp kh B. T khi ca A so vi B l 0,93. Khng kh c 20% th tch l O2 v 80% th tch l N2. Tnh hiu sut ca phn ng oxihoa SO2 : A. 75% B. 86% C. 84% D. 80% Cu 41: So snh linh ng ca nguyn t H trong nhm chc ca cc cht hu c sau: C6H5OH, HOCH2-CH2OH ; C6H13OH , C6H5COOH A. HOCH2-CH2OH < C6H13OH < C6H5OH < C6H5COOH B. HOCH2-CH2OH < C6H13OH < C6H5COOH < C6H5OH C. C6H13OH < HOCH2-CH2OH < C6H5OH < C6H5COOH D. C6H5OH < HOCH2-CH2OH < C6H13OH < C6H5COOH Cu 42: Hai cc ng dung dch HCl t trn hai a cn A,B . Cn trng thi cn bng . Cho 5gam CaCO3 vo cc A v 4,784gam M2CO3 ( M : Kim loi kim ) vo cc B . Sau khi hai mui tan hon ton , cn tr li v tr thng bng . Xc nh Kim loi M? A. K B. Cs C. Li D. Na Cu 43: un nng hn hp A gm: 0,1 mol axeton; 0,08 mol anehit acrylic (propenal); 0,06 mol isopren v 0,32mol hiro c Ni lm xc tc thu c hn hp kh v hi B. T khi ca B so vi khng kh l 375/203. Hiu sut hiro tham gia phn ng cng l: A. 87,5% B. 93,75% C. 80% D. 75,6% Cu 44: Kh no tha mn tt c cc tnh cht: to kt ta vi dung dch AgNO3, lm mt mu dung dch KMnO4, khng tn ti trong mt hn hp vi SO2, tc dng c vi nc clo. A. C2H2 B. H2S C. NH3 D. HCl Cu 45: Y l hexapeptit c to thnh t glyxin. Cho 0,15 mol Y tc dng hon ton vi dd NaOH (ly d 20% so vi lng cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn? A. 87,3 gam B. 9,99 gam C. 107,1 gam D. 94,5 gam Cu 46: Mt hn hp gm hai axit cacboxylic no, n chc k tip nhau trong dy ng ng. Ly m gam hn hp ri thm vo 75ml dung dch NaOH 0,2M, sau phi dng ht 25ml dung dch HCl 0,2M trung ha kim d thu c dung dch X. C cn dung dch X n khi lng khng i thu c 1,0425gam mui khan. Phn trm khi lng ca axit c khi lng phn t b hn trong hn hp trn l: A. 50% B. 43,39% C. 40% D. 46,61

Cu 47: t chy hon ton mt lng hn hp X gm mt s ancol thuc cng dy ng ng cn dng 10,08 lit kh O2 (ktc) thu c 6,72 lt kh CO2 (ktc) v 9,90 gam H2O. Nu un nng 10,44g hn hp X nh trn vi H2SO4 c nhit thch hp chuyn ht thnh ete th tng khi lng ete thu c l: A. 7,74 gam B. 6,55 gam C. 8,88 gam D. 5,04 gam Cu 48: Hai cht hu c X, Y c thnh phn phn t gm C, H, O (MX <MY <74). C X v Y u c kh nng tham gia phn ng trng bc v u phn ng c vi dung dch KOH sinh ra mui. T khi hi ca Y so vi X c gi tr l: A. 1,403 B. 1,333 C. 1,304 D. 1,3 Cu 49: Hn hp X gm CaO,Mg ,Ca, MgO. Ha tan 5,36 gam hn hp X bng dung dch HCl va thu c 1,624 lt H2 (ktc) v dung dch Y trong c 6,175 gam MgCl2 v m gam CaCl2. Gi tr ca m l A. 7,4925 gam B. 7,770gam C. 8,0475 gam D. 8,6025 gam Cu 50: Este X c cng thc phn t dng CnH2n-2O2 . t chy 0,42 mol X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c cha 68,376 gam Ca(OH)2 th thy dung dch nc vi trong vn c. Thu phn X bng dung dch NaOH thu c 2 cht hu c khng tham gia phn ng trng gng. Pht biu no sau y v X l ng: A. X l ng ng ca etyl acrylat B. Thnh phn % khi lng O trong X l 36,36% C. Khng th iu ch c t ancol v axit hu c tng ng D. Tn ca este X l vinyl axetat ----------- HT ----------

 THI TH VO I HC, CAO NG

( thi c? 05 trang)

Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao )

PHN CHUNG: (44 c?u t c?u 1 n c?u 44) 1. Nhng nh?m nguy?n t n?o di ?y ngo?i nguy?n t kim loi c?n c? nguy?n t phi kim ? A. Ph?n nh?m ch?nh (PNC) nh?m IA (tr hiro) v? PNC nh?m II (IIA) B. PNC nh?m III (IIIA) n PNC nh?m VIII (VIIIA) C. Ph?n nh?m ph (PNP) nh?m I (IB) n PNP nh?m VIII (VIIIB) D. H lantan v? h actini 2. T?nh cht vt l? n?o di ?y ca kim loi KH?NG phi do c?c electron t do trong kim loi g?y ra ? A. ?nh kim B. T?nh do C. T?nh cng D. T?nh dn in v? dn nhit 3. Ln lt cho tng kim loi Mg, Al, Fe v? Cu (c? s mol bng nhau), t?c dng vi lng d dung dch HCl. Khi phn ng ho?n to?n th? th t?ch H2 (trong c?ng iu kin) tho?t ra nhiu nht l? t kim loi : A. Mg B. Al C. Fe D. Cu

4. H?a tan ho?n to?n m gam Na kim loi v?o 100 ml dung dch HCl 1M thu c dung dch A. Trung h?a dung dch A cn 100 mL dung dch H2SO4 1M. T?nh m. A. 2,3 gam B. 4,6 gam C. 6,9 gam D. 9,2 gam 5. Th?m t t tng git dung dch cha 0,05 mol HCl v?o dung dch cha 0,06 mol Na2CO3. Th t?ch kh? CO2 (ktc) thu c bng : A. 0,000 l?t. B. 0,560 l?t. C. 1,120 l?t. D. 1,344 l?t. 6. H?a tan ht 7,6 gam hn hp hai kim loi kim th thuc hai chu k? li?n tip bng dung dch HCl d th? thu c 5,6 l?t kh? (ktc). Hai kim loi n?y l? : A. Be v? Mg. B. Mg v? Ca. C. Ca v? Sr. D. Sr v? Ba. 7. Nc cng kh?ng g?y ra t?c hi n?o di ?y ? A. G?y ng c nc ung. B. L?m mt t?nh ty ra ca x? ph?ng, l?m h hi qun ?o. C. L?m hng c?c dung dch pha ch, l?m thc phm l?u ch?n v? gim m?i v thc phm. D. G?y hao tn nhi?n liu v? kh?ng an to?n cho c?c ni hi, l?m tc c?c ng ng dn nc.
8. Cho 0,8 mol nh?m t?c dng vi dung dch HNO3 thu c 0,3 mol kh? X (kh?ng c? sn phm kh n?o kh?c). Kh? X l? : A. NO2. B. NO. C. N2O. D. N2.

9. H?a tan 47,4 gam ph?n chua KAl(SO4)2.12H2O v?o nc c dung dch A. Th?m n ht dung dch cha 0,2 mol Ba(OH)2 v?o dung dch A th? lng kt ta thu c bng : A. 7,8 gam. B. 46,6 gam. C. 54,4 gam. D. 62,2 gam. 10. Cho 0,015 mol bt Fe v?o dung dch cha 0,04 mol HNO3 thy tho?t ra kh? NO duy nht. Khi phn ng ho?n to?n th? khi lng mui thu c bng : A. 2,42 gam. B. 2,70 gam. C. 3,63 gam. D. 5,12 gam. 11. Phn ng n?o di ?y KH?NG th to sn phm l? FeO ? A. Fe(OH)2 Error: Reference source not found B. FeCO3 Error: Reference source not found C. Fe(NO3)2 Error: Reference source not found D. CO + Fe2O3 Error: Reference source not found
12. Ph?t biu n?o di ?y l? ?ng (gi thit c?c phn ng u ho?n to?n) ? A. 0,1 mol Cl2 t?c dng vi dung dch NaOH d to 0,2 mol NaClO B. 0,3 mol Cl2 t?c dng vi dung dch KOH d (70oC) to 0,1 mol KClO3 C. 0,1 mol Cl2 t?c dng vi dung dch SO2 d to 0,2 mol H2SO4 D. 0,1 mol Cl2 t?c dng vi dung dch Na2SO3 d to 0,2 mol Na2SO4 13. Tin h?nh th? nghim nh h?nh v b?n : Sau mt thi gian th? ng nghim cha dung dch Cu(NO3)2 quan s?t thy : A. kh?ng c? hin tng g? xy ra. B. c? xut hin kt ta m?u en. C. c? xut hin kt ta m?u trng. D. c? si bt kh? m?u v?ng lc, m?i hc. 14. Thi 0,4 mol kh? etilen qua dung dch cha 0,2 mol KMnO 4 trong m?i trng trung t?nh, khi lng etylen glicol (etilenglicol) thu c bng :

A. 6,2 gam. B. 12,4 gam. C. 18,6 gam. D. 24,8 gam. 15. T?n gi n?o di ?y l? ?ng cho hp cht sau? A. buten-3 (but-3-en) CH2 = CH CH2 CH CH3 | B. penten-3 (pent-3-en) CH3 C. 4-metylpenten-1 (4-metylpent-1-en) D. 2-metylpenten-3 (2-metylpent-3-en)
16. T?nh lng kt ta ng(I) oxit to th?nh khi un n?ng dung dch hn hp cha 9,00 gam glucoz v? lng d ng(II) hiroxit trong m?i trng kim. A. 1,44 gam B. 3,60 gam C. 7,20 gam D. 14,4 gam 17. Nhn x?t n?o sau ?y kh?ng ?ng ? A. Rut b?nh m? ngt hn v b?nh. B. Khi n cm, nu nhai k s thy v ngt. C. Nh dung dch iot l?n ming chui xanh thy xut hin m?u xanh. D. Nc ?p chui ch?n cho phn ng tr?ng bc. 18. im ging nhau gia phn ng thy ph?n tinh bt v? thy ph?n xenluloz l? : A. sn phm cui c?ng thu c. B. loi enzim l?m x?c t?c. C. sn phm trung gian ca qu? tr?nh thy ph?n. D. lng nc tham gia phn ng thy ph?n. 19. Amin n?o di ?y c? bn ng ph?n cu to ? A. C2H7N B. C3H9N C. C4H11N D. C5H13N 20. 0,01 mol aminoaxit A phn ng va vi 0,02 mol HCl hoc 0,01 mol NaOH. C?ng thc ca A c? dng : A. H2NRCOOH. B. (H2N)2RCOOH. C. H2NR(COOH)2. D. (H2N)2R(COOH)2. 21. Sn phm v? t?n gi ca c?c cht trong phn ng polime h?a n?o di ?y l? ho?n to?n ?ng ? Error: Reference source not found Error: Reference source not found Error: Reference source not found Error: Reference source not found 22. Polime n?o di ?y c? cu to kh?ng iu h?a ? A. Error: Reference source not found B. Error: Reference source not found C. Error: Reference source not found D. Error: Reference source not found 23. Theo ngun gc, loi t n?o di ?y c?ng loi vi len ? A. b?ng B. capron C. visco D. xenluloz axetat

24. T?n gi n?o di ?y KH?NG ?ng vi hp cht (CH3)2CHCH2CH2OH ? A. 3-metylbutanol-1 (hay 3-metylbutan-1-ol) B. 2-metylbutanol-4 ( hay 2-metylbutan-4-ol) C. ancol i-pentylic D. ancol i-amylic 25. C? c?c hp cht hu c : (X) CH3CH(OH)CH2CH3 (Y) CH3CH2OH (Z) (CH3)3COH (T) CH3CH(OH)CH3 Cht ehirat h?a to th?nh ba olefin ng ph?n l? : A. X B. Y v? Z C. T D. kh?ng c? 26. Cho 0,01 mol phenol t?c dng vi lng d dung dch hn hp HNO3 c v? H2SO4 c. Ph?t biu n?o di ?y KH?NG ?ng ? A. Axit sunfuric c ?ng vai tr? x?c t?c cho phn ng nitro h?a phenol. B. Sn phm thu c c? t?n gi 2,4,6-trinitrophenol. C. Lng HNO3 ? tham gia phn ng l? 0,03 mol. D. Khi lng axit picric h?nh th?nh bng 6,87 gam. 27. C? c?c anehit : (X) HCH=O (Y) CH3CH=O
(Z) CH2=CH-CH=O (T) OHC-CH2-CHO C?c cht thuc loi anehit mch h, no, n chc l? : A. (X) v? (Y). B. (Y). C. (Z). D. (Z) v? (T). 28. Phng tr?nh ho? hc n?o di ?y c vit KH?NG ?ng ? Error: Reference source not found Error: Reference source not found Error: Reference source not found Error: Reference source not found 29. trung h?a 28,8 gam hn hp gm axit axetic, ru n-propilic v? p-cresol cn 150 mL dung dch NaOH 2 M. H?a tan 28,8 gam hn hp tr?n trong n-hexan ri cho Na d v?o th? thu c 4,48 L kh? hiro

(ktc). Lng axit axetic trong hn hp bng : A. 0,1 mol. B. 0,2 mol. C. 0,3 mol. D. 0,4 mol. 30. Thy ph?n este X trong m?i trng axit thu c hai cht hu c A v? B. Oxi h?a A to sn phm l? cht B. Cht X kh?ng th l? : A. etyl axetat B. vinyl axetat C. etilenglicol oxalat D. isopropyl propionat 31. Cho d?y chuyn h?a iu ch : Error: Reference source not found Cht X l? : A. CH3CH2CH(OH)CH(CH3)2 B. n-C3H7OC3H7-i C. CH3CH2COOCH(CH3)2 D. C2H5COOC3H7-n
32. Nung n ho?n to?n 0,05 mol FeCO 3 trong b?nh k?n cha 0,01 mol O 2 thu c cht rn A. h?a tan ht A bng dung dch HNO3 c, n?ng th? s mol HNO3 ti thiu cn d?ng l? : A. 0,14 mol. B. 0,15 mol. C.0,16 mol. D. 0,18 mol. 33. H?a tan ho?n to?n hn hp gm Na2O, BaCl2, NaHCO3, NH4Cl c? s mol mi cht bng nhau v?o nc ri un n? ng nh. Sau khi kt th?c th? nghim c dung dch A. Dung dch A cha : A. NaCl. B. Na2CO3 v? NaOH. C. BaCl2, NaHCO3 v? NaOH. D. NaOH, BaCl2, NaHCO3 v? NH4Cl. 34. Cho 1,2 gam Mg v?o 100 mL dung dch hn hp gm HCl 1,5M v? NaNO 3 0,5M. Sau phn ng ch thu c V l?t kh? dng n cht (kh?ng c? sn phm kh n?o kh?c). Th t?ch V (ktc) bng : A. 0,224 l?t. B. 0,560 l?t. C. 1,120 l?t. D. 5,600 l?t. 35. H?a tan ht hn hp cha 10 gam CaCO 3 v? 17,4 gam FeCO3 bng dung dch HNO3 lo?ng, n?ng. S mol HNO 3 ? tham gia phn ng bng : A. 0,2 mol. B. 0,5 mol C. 0,7 mol D. 0,8 mol

36. ph?n bit ba b?nh kh? mt nh?n ln lt cha c?c kh? N2, O2 v? O3, mt hc sinh ? d?ng c?c thuc th (c? trt t) theo bn c?ch di ?y. C?ch n?o l? KH?NG ?ng ? A. l? Ag n?ng, que ?m. B. que ?m, l? Ag n?ng. C. dung dch KI/ h tinh bt, que ?m. D. dung dch KI/ h tinh bt, l? Ag n?ng. 37. C? mt mu NH3 b ln hi nc. c? NH3 khan, th? cht l?m khan n?n d?ng l? : A. Na. B. CaO. C. P2O5. D. H2SO4 c.
38. C? bn hp cht X, Y, Z v? T. Ngi ta cho mu th ca mi cht n?y ln lt qua CuO t n?ng, CuSO 4 khan v? b?nh cha dung dch Ca(OH)2. Sau th? nghim thy mu X ch l?m CuSO4 i qua m?u xanh ; mu Y ch to kt ta trng b?nh cha nc v?i ; mu Z to hin tng c hai b?nh n?y, c?n mu T kh?ng to hin tng g?. Kt lun ?ng cho ph?p ph?n t?ch n?y l? : A. X ch cha nguy?n t cacbon. B. Y ch cha nguy?n t hiro C. Z l? mt hirocacbon. D. T l? cht v? c. 39. Cht Z cha C, H v? O. Khi lng mi nguy?n t (ng vi m gam cht Z) v? ph?n t khi bng : mC mH mO MZ 2,88 0,48 3,84 60 C?ng thc ph?n t ca Z l? : A. CH2O. B. C3H8O. C. C2H4O2. D. C2H6O2. 40. C?ng thc ph?n t n?o di ?y c? nhiu ng ph?n cu to nht ? A. C4H10 B. C4H9Cl C. C4H10O D. C4H11N 41. Hiro h?a anehit acrilic bng lng d H2 (x?c t?c Ni, t) th? sn phm l? : A. CH2=CHCH2OH B. CH3CH2CH2OH C. CH3CH2CH=O D. CH3COCH3 42. Cho d?y chuyn h?a :

CH3COONa
+ NaOH, CaO, t 1500oC + H2

T
H2SO, 180oC

N Pd/PbCO O 3
+ H2O + KOH/C2H5OH, t

+ H2O

Ph?t biu n?o sau ?y l? ?ng ? A. X l? CaC2 B. Y l? CH3CH2OH C. Z l? CH3CH2Cl D. T l? Al4C3 43. Th?m dung dch HCl (c? ZnCl2 x?c t?c) ln lt v?o ba mu th cha ru (ancol) etylic, ancol i-propylic

v? ancol t-butylic. Kt lun n?o sau ?y KH?NG ?ng ? A. Mu th vn c ngay lp tc l? ru (ancol) etylic. B. Mu th c? s ph?n lp ngay lp tc l? ru (ancol) t-butylic. C. Mu th c? s vn c sau nm ph?t l? ru (ancol)l i-propylic. D. Kh nng phn ng ca ru (ancol) bc 3 cao hn bc 2, cao hn bc 1.
44. Trong s c?c kim loi Mg, Al, Fe v? Cr, th? kim loi c? kh nng phn ng vi dung dch HNO 3 (c, ngui) v? H2SO4 (c, ngui) l? : A. Mg. B. Al. C. Fe. D. Cr. PHN RI?NG (th? sinh ch c l?m mt trong hai phn: phn I hoc phn II) Phn I: d?nh cho th? sinh chng tr?nh ph?n ban (6 c?u- t c?u 45 n c?u 50)

45. Lng H2O2 v? KOH tng ng c s dng oxi h?a ho?n to?n 0,01 mol KCr(OH)4 th?nh K2CrO4 l? : A. 0,015 mol v? 0,01 mol B. 0,030 mol v? 0,04 mol C. 0,015 mol v? 0,04 mol D. 0,030 mol v? 0,04 mol 46. Nh?ng thanh Cu v?o dung dch cha 0,02 mol Fe(NO3)3. Khi Fe(NO3)3 phn ng ht th? khi lng thanh Cu : A. kh?ng i. B. gim 0,64 gam. C. gim 1,92 gam. D. gim 0,80 gam. 47. X?t phn ng h?a tan v?ng bng xianua (phn ng cha c c?n bng) : Au + O2 + H2O + NaCN Na[Au(CN)2] + NaOH Khi lng v?ng b h?a tan l? 1,97 gam th? lng NaCN ? d?ng l? : A. 0,01 mol. B. 0,02 mol. C. 0,03 mol. D. 0,04 mol. 48. Cho bit c?c gi? tr th in cc chun :
Error: Reference source not found Error: Referen ce source Error: Referen ce source Error: Reference source not found Error: Refere nce source

not found

not found

not

found E (V) 2,37 0,44 + 0,34 + 0,77 + 0,80 D?y n?o di ?y gm c?c kim loi khi phn ng vi dung dch Fe(NO3)3, th? ch c? th kh Fe3+ th?nh Fe2+ ? A. Mg v? Fe. B. Fe v? Cu. C. Cu v? Ag. D. Ag v? Mg.
o

49. X?t c?c cht ru (ancol) etylic, ru (ancol) i-propylic, ru (ancol) n-propylic, anehit axetic, anehit propionic, axeton. S cht to kt ta v?ng ioofom khi t?c dng vi I2/NaOH l? : A. 2 cht. B. 3 cht. C. 4 cht. D. 5 cht. 50. ph?n bit c?c dung dch BaCl2?v? CaCl2, tt nht n?n d?ng thuc th : A. Na2CO3. B. Na2SO4. C. (NH4)2C2O4. D. K2CrO4.
Phn II: d?nh cho th? sinh chng tr?nh kh?ng ph?n ban (6 c?u-t c?u 51 n c?u 56) 51. H?a tan 16,4 gam hn hp Fe v? FeO trong lng d dung dch HNO 3 ch to sn phm kh l? 0,15 mol NO. S mol mi cht trong hn hp ln lt bng : Fe FeO A. 0,100 mol 0,150 mol B. C. D. 0,150 mol 0,225 mol 0,020 mol 0,110 mol 0,053 mol 0,030 mol

52. Th?m 2,16 gam Al v?o dung dch HNO3 rt lo?ng, va th? thu c dung dch A v? kh?ng thy kh? tho?t ra. Th?m dung dch NaOH d v?o dung dch A n khi kt ta va tan ht th? s mol NaOH ? d?ng l? : A. 0,16 mol B. 0,19 mol C. 0,32 mol D. 0,35 mol 53. Cho trt t d?y in h?a : Error: Reference source not found Khi cho hn hp kim loi Mg, Al v?o dung dch hn hp cha c?c mui AgNO 3 v? Cu(NO3)2, th? phn ng oxi h?a kh xy ra u ti?n s l? : A. Mg + 2Ag+ Mg2+ + 2Ag B. Mg + Cu2+ Mg2+ + Cu 2+ 3+ + C. 2Al + 3Cu 2Al + 3Cu D. Al + 3Ag Al3+ + 3Ag 54. D?y n?o di ?y ch gm c?c cht c? kh nng tham gia phn ng tr?ng hp? A. stiren, clobenzen B. etyl clorua, butaien-1,3 B. 1,1,2,2-tetrafloeten, propilen D. 1,2-iclopropan, vinylaxetilen 55. Khi lng dung dch HNO3 65% cn s dng iu ch 1 tn TNT, vi hiu sut 80% l? :

A. 0,53 tn B. 0,83 tn C. 1,04 tn D. 1,60 tn 56. C ch n?o di ?y m? t ?ng phn ng gia propilen v? axit clohiric to sn phm ch?nh? A. CH3CH=CH2 Error: Reference source not found CH3CH2CH2+ Error: Reference source not CH3CH2CH2Cl B. CH3CH=CH2 Error: Reference source not found CH3+CHCH3 Error: Reference source not CH3CHClCH3 C. CH3CH=CH2Error: Reference source not foundCH3CHClCH2- Error: Reference source not CH3CHClCH3 D. CH3CH=CH2Error: Reference source not foundCH3-CHCH2Cl Error: Reference source not CH3CH2CH2Cl

found found found found

 09
( thi c? 05 trang)

THI TH V?O I HC, CAO NG M?n thi: H?A HC Thi gian l?m b?i: 90 ph?t (kh?ng k thi gian giao )

PHN CHUNG: (44 c?u t c?u 1 n c?u 44) 1. Cp cht n?o sau ?y kh?ng xy ra phn ng? A. Fe2+ v? Cr2+ B. Fe3+ v? Cu C. Mg v? Ni2+ D. Zn v? Cr3+ 2. Cho 5,6 g bt Fe phn ng hon tn vi dung dch H2SO4 m c, n?ng ngi ta thu c 9,6g sn phm kh cha lu hunh. Sn phm cha lu hunh l?: A. H2S B. SO2 C. S D. Fe2(SO4)3 3. Khi vt bng th?p b n m?n in h?a trong kh?ng kh? m, nhn nh n?o sau ?y kh?ng ?ng ? A. cc dng xy ra qu? tr?nh kh : 2H+ + 2e H2 B. cc dng xy ra qu? tr?nh kh : O2 + 2H2O 4OH C. cc ?m xy ra qu? tr?nh oxi h?a : Fe Fe2+ + 2e D. cc ?m xy ra qu? tr?nh oxi h?a : Fe Fe3+ + 3e 4. Cho 0,1 mol Fe phn ng hon tn vi dung dch HNO 3 d ngi ta thu c mui. Bit s mol Fe phn ng gn bng 27,78% s mol HNO3. Vy th t?ch kh? tht ra ktc l?: A. 0,672 L B. 0,84 L C. 6,72 L D. 2,24 L 5. Cho kh? H2 qua ng s cha a gam Fe2O3 un n?ng, sau mt thi gian thu c 5,200g hn hp X gm 4 cht rn. H?a tan ht hn hp X bng HNO3 c n?ng thu c 0,785 mol kh? NO2. Vy a l?: A. 11,480g B. 24,040g C. 17,760g. D. 8,340g 6. Al c? th phn ng vi tt c c?c cht trong d?y n?o sau ?y iu kin th?ch hp ? A. CuO, Cr2O3, dung dch K2SO4 B. dung dch CuSO4, dung dch CaCl2, CO C. dung dch FeCl2, FeO, dung dch SrCl2 D. Ca(OH)2, CuSO4, Cr2O3 7. H?a tan hn tn hn hp 3 kim loi : K, Sr, Ba v?o nc ta c 0,448 l?t kh? (ktc) v? dung dch X. Th t?ch dung dch HCl 0,5M cn d?ng trung h?a dung dch X l? : A. 80 ml. B. 40 ml. C. 20 ml. D. 125 ml. 8. C? bao nhi?u cht to kt ta vi kh? H2S trong c?c cht sau: FeCl2 , FeCl3 , ZnCl2, CuSO4? A. 1 B. 2 C.3 D. 4 9. Phn ng n?o sau ?y xy ra c iu kin th?ch hp ? A. 2Fe + 3S (d) Fe2S3 B. 2FeCl3 + 3H2S Fe2S3 + 6HCl C. Fe2O3 + CO 2FeO + CO2 D. 2FeS + 10H2SO4 Fe2(SO4)3 + 9SO2 + 10H2O 10. Cho 3,36 gam bt Mg v?o dung dch cha hn hp gm CuCl 2 0,12 mol v? FeCl3 0,02 mol. Sau khi phn ng xy ra hon tn c cht rn A. Khi lng cht rn A l? : A. 8,24 g. B. 8,16 g. C. 8,46 g. D. 7,92g 11. Fe c? ln Al, Be, Cr2O3 dng bt. tinh ch Fe, ta c? th d?ng : A. Dung dch H2SO4 lng B. Dung dch Ba(OH)2 C. Dung dch FeCl2 D. HNO3 c ngui. 12. D?y c?c cht n?o sau ?y u phn ng c vi dung dch NH3 ? A. dung dch FeCl3, dung dch HCOOH, dung dch BaCl2 B. kh? clo, kh? oxi, kh? sunfur C. AgCl, CuO, Zn(OH)2 D. CuSO4, Be(OH)2, Al(OH)3 13. Th? nghim n?o sau ?y kh?ng to ra H2SO4 A. Sc kh? SO2 v?o dung dch brom B. un n?ng lu hunh bt vi H3PO4 c, n?ng C. Sc kh? clo v?o dung dch H2S D. Pha lng oleum bng nc 14. Cho 1 ml dung dch brom m?u v?ng v?o ng nghim, th?m v?o 1 ml benzen ri lc tht k. Sau ? y?n ta c 2 lp cht lng kh?ng tan v?o nhau. Quan s?t 2 lp cht lng ta thy : A. Lp tr?n c? m?u v?ng, lp di kh?ng m?u. B. Lp di c? m?u v?ng, lp tr?n kh?ng m?u. B. C 2 lp u kh?ng m?u. D. C 2 lp u c? m?u v?ng nhng nht hn. 15. C? bao nhi?u cht thuc loi aren trong c?c C2H5 CH=CH2 cht sau ?
CH2

A. 2 B. 3 16. Ph?t biu n?o sau ?y kh?ng ?ng ?

C. 4

D. 5

A. nhit thng glucoz, fructoz, saccaroz u ho tan Cu(OH)2 to dung dch xanh lam B. Glucoz, fructoz u t?c dng vi H2 (x?c t?c Ni, t) cho poliancol C. Glucoz, fructoz, saccaroz u tham gia phn ng tr?ng gng D. Glucoz, fructoz, mantoz u b oxi ho bi Cu(OH)2 khi un n?ng cho kt ta gch 17. Cho xenluloz phn ng hon tn vi anhiric axetic th? sn phm to th?nh gm 6,6 g CH 3COOH v? 11,1 g hn hp X gm xeluloz triaxetat v? xenluloz iaxetat. Th?nh phn phn trm v khi lng ca xenluloz triaxetat trong hn hp X l? : A. 77,84%. B. 22,16%. C. 75%. D. 25% 18. S ng ph?n cu to ca amin bc nht ng vi c?ng thc ph?n t C4H11N l? : A. 3 B. 4 C. 5 D. 6 19. Hin tng n?o sau ?y kh?ng ?ng ? A. Protein u d tan trong nc to th?nh dung dch keo B. Lp v?ng ni l?n khi nu tht c? l? hin tng ?ng t protein C. L?ng trng trng gp Cu(OH)2 to th?nh m?u t?m D. L?ng trng trng gp HNO3 to th?nh hp cht c? m?u v?ng. 20. C? bao nhi?u cht trong d?y : CH 3NH2, CH3CH(NH2)COOH, HI, C2H5OH, Na2CO3, CH3NH3Cl phn ng vi axit 2-aminopropanioic ? B. 3 B. 4 C. 5 D. 6 21. D?y chuyn h?a n?o sau ?y kh?ng ?ng ? A. CH4C2H2C4H4C4H6Cao su buna B. CH4C2H2CH3CHOC2H5OHC4H6Cao su buna C. CH4C2H2C2H3OHC2H5OHC4H6Cao su buna D. CH4C2H2C2H6C2H5ClC2H5OHC4H6Cao su buna 22. T cht u l? ? v?i v? c?c nguy?n liu v? c kh?c c? th iu ch PVC vi s phng tr?nh h?a hc ti thiu l? : A. 4 B. 5 C. 6 D. 7 23. t ch?y ht hn hp A gm 0,1 mol etilenglicol (etylen glicol) v? 0,2 mol ancol X thu c 35,2 gam CO2. Nu cho hn hp A t?c dng ht vi natri th? thu c 0,4 mol H2. Vy X l? : CH2 CH CH2 CH CH CH CH2 2 A. CH3CH2CH2OH B.CH2 CH2 CH2 C. D. OH OH OH OH OH OH OH OH OH 24. Trong c?c cht sau : HCHO, CH3Cl, CO, CH3COOCH3, CH3ONa, CH3OCH3, CH2Cl2 c? bao nhi?u cht to ra metanol bng 1 phn ng ? A. 3 B. 4 C. 5 D. 6 25. Cho 12 g hn hp anehit fomic v? metyl fomiat c? khi lng bng nhau t?c dng vi mt lng tha dung dch AgNO3/NH3 . Khi lng Ag sinh ra l? : A. 108,0 g B. 64,8 g C. 86,4 g D. 43,2 g 26. Ph?t biu n?o sau ?y kh?ng ?ng v d?y ng ng axit ankanoic ? A. Mch C c?ng d?i nhit s?i c?c axit c?ng tng B. Khi lng ph?n t c?ng ln mnh t?nh axit c?ng gim C. Mch C c?ng d?i c?c axit c?ng kh? tan trong nc [H O+ ][ROO ] 3 D. C?ng thc t?nh hng s in li axit l? : K a = [RCOOH][H O]
2

27. C? bao nhi?u ng ph?n cu to thuc loi anehit thm ng vi c?ng thc ph?n t C8H8O ? A. 2 B. 3 C. 4 D. 5 28. Cho c?c cht phn ng vi nhau theo t l mol 1 : 1 trong s chuyn h?a sau : A Error: Reference source not found B Error: Reference source not found CH4 C? ng thc kh?ng ph? hp vi cht A l? : A. CH3OOCCH3. B. CH3COOH. C. CH3COONH4. D. HCOOCH3 29. C?n bng h?a hc ca phn ng este h?a gia ancol v? axit hu c s dch chuyn theo chiu thun khi : A. pha lng hn hp bng nc. B. th?m dung dch NaOH v?o hn hp. C. chng ct t?ch este ra khi hn hp. D. un n?ng hn hp. 30. S phn ng n?o sau ?y kh?ng to ra HBr ? A. PBr3 + H2O B. Zn3P2 + H2O PH3 + Zn(OH)2 B. NaBr (rn) + H2SO4 c D. C6H5-CH3 + Br2 Error: Reference source not found o-BrC6H4-CH3 + HBr 31. nhn bit hai b?nh kh? CO2 v? SO2, c?ch n?o sau ?y kh?ng ?ng ?

A. Thi t t n d mi kh? v?o dung dch Ca(OH)2 B. Cho mi kh? v?o dung dch KMnO4 C. Cho mi kh? v?o dung dch Br2 D. Cho mi kh? v?o dung dch H2S 32. C?c dung dch (dung m?i l? nc) trong d?y n?o sau ?y u c? th l?m qu t?m h?a xanh ? A. AlCl3, NH4Cl, C2H5ONa B. NH4Cl, C2H5ONa, Mg(OH)2 C. NaF, C6H5ONa, Na2CO3 D. Na3PO4, NH3, BaI2 33. Phn ng n?o sau ?y kh?ng ?ng ? A. CaCl2 + CO2 + H2O CaCO3 + 2HCl B. CuCl2 + H2S CuS + 2HCl C. NaHSO4 + Na2CO3 Na2SO4 + NaHCO3 D. BaSO3 + 2HCl BaCl2 + SO2 + H2O 34. Nhn x?t n?o ?ng khi in ph?n dung dch cha hn hp HCl v? H2SO4? A. pH dung dch gim dn trong sut qu? tr?nh in ph?n. B. pH dung dch tng l?n n gi? tr nht nh ri kh?ng thay i na. C. pH dung dch gim xung n gi? tr nht nh ri tng l?n D. pH dung dch tng dn n gi? tr nht nh ri gim xung 35. Thy ph?n hn tn hp cht 13,75 g PCl3 thu c dung dch X cha hn hp 2 axit. Th t?ch dung dch NaOH 0,1M trung h?a dung dch X l? : A. 300 ml B. 400 ml C. 500 ml D. 600 ml 36. C?c hp cht trong d?y n?o sau ?y u c? t?nh axit ? A. AlCl3, Ca(HCO3)2, NaHSO4 B. H2SO4, Na2HPO3, CH3COOH. C. HClO, CO2, C6H5ONa D. NH4Cl, SO2, Na2ZnO2 (hay Na2[Zn(OH)4] ) 37. D?y n?o sau ?y gm c?c cht u t?c dng c vi ru (ancol) etylic iu kin th?ch hp ?

A. CuO, CH3COOH, NaOH. B. Ca, CaO, CH3COOH. C. CuO, CH3OH, HCl. D. CuSO4, CH3COOH, HCl.
38. Phng ph?p nhn bit n?o kh?ng ?ng ?

A. ph?n bit c ru (ancol) isopropylic v? n- propylic ta oxi h?a nh mi cht ri cho t?c dng vi dung dch AgNO3/NH3 . B. ph?n bit metanol, metanal, axetilen ta cho c?c cht phn ng vi dung dch AgNO3/NH3
C. ph?n bit benzen v? toluen ta d?ng dung dch brom. D. ph?n bit axit metanoic v? axit etanoic ta cho phn ng vi Cu(OH)2/NaOH 39. Chuyn h?a hn tn 4,6 g hn hp cha c?ng s mol 2 ankanol bc nht th?nh ankanal cn d?ng 0,1 mol CuO. Cho tn b ankanal thu c cho phn ng tr?ng gng thu c 0,3 mol Ag. Hai ankanol ? l? : A. CH3OH v? C2H5OH. B. CH3OH v? C3H7OH. C. C2H5OH v? C3H7OH. D. C2H5OH v? C4H9OH. T?nh cht n?o sau ?y kh?ng ?ng vi cht NH3 CH COOH A. Phn ng vi NaOH v? HCl B. Phn ng vi ancol COO C. Phn ng vi NaOH, kh?ng phn ng vi HCl D. Cho phn ng tr?ng ngng 40. Nhn x?t n?o di ?y kh?ng ?ng ? A. Phenol cho phn ng th d hn toluen. B. Toluen cho phn ng th d hn benzen C. Benzen cho phn ng th d hn anilin D. Anilin cho phn ng th d hn axit benzoic 42. Khi cho c?c cht sau phn ng vi clo c? x?c t?c bt st, chiu mi t?n ch v tr? nguy?n t clo gn v?o to sn phm ch?nh. H?nh v n?o di ?y OCH kh?ng ?ng? COOH CH3 CH2CH3 3 A. (I) NO2 B. (I), (II) C. (III) D. (III), (IV)
(I) (II) (III) (IV)

43. t ch?y a gam hn hp 3 kim loi Mg, Zn, Cu thu c 34,5 gam hn hp rn X gm 4 oxit kim loi. h?a tan ht hn hp X cn d?ng va dung dch cha 0,8 mol HCl. Vy gi? tr ca a l?: A. 28,1g B. 21,7g C. 31,3g D. 24,9g 44. Hai ng ph?n X v? Y c? c?ng thc ph?n t C3H8O2. T?nh cht ca X v? Y th hin trong bng sau: dung dch NaOH Na AgNO3/NH3 X c? phn ng c? phn ng kh?ng phn ng Y c? phn ng kh?ng phn ng c? phn ng C?ng thc cu to ca X v? Y ln lt l?:

A. CH3CH2COOH v? HCOOCH2CH3 B. CH3CH2COOH v? HOCH2CH2CHO C. CH3COOCH3 v? HOCH2CH2CHO D. CH3COOCH3 v? HCOOCH2CH3 PHN RI?NG (th? sinh ch c l?m mt trong hai phn: phn I hoc phn II) Phn I: d?nh cho th? sinh chng tr?nh ph?n ban (6 c?u- t c?u 45 n c?u 50) 45. Phn ng n?o di ?y c d?ng sn xut axeton trong c?ng nghip ? A. (CH3COO)2Ca Error: Reference source not found CH3COCH3 + CaCO3 B. CH3CHOHCH3 + CuO Error: Reference source not found CH3COCH3 + Cu + H2O C. C6H5CH(CH3)2 Error: Reference source not found C6H5OH + CH3COCH3 D. CH3CCl2CH3 + 2KOH Error: Reference source not found CH3COCH3 + 2KCl + 2H2O 46. in ph?n dung dch CuSO4 vi anot bng ng, cng d?ng l? 5 A, trong thi gian 9650 gi?y. iu n?o sau ?y ? ng ? A. Khi lng ng thu c catot l? 16 g. B. Khi lng kh? oxi thu c anot l? 4 g. C. Nng CuSO4 gim dn trong qu? tr?nh in ph?n. D. Phng tr?nh in ph?n l? : 2CuSO4 + 2H2O 2Cu + 2H2SO4 + O2 47. Cho c?c phn ng sau: 2SO2 (k) + O2 (k) 2SO3 (k) c? hng s c?n bng K1 SO2 (k) + ? O2 (k) SO3 (k) c? hng s c?n bng K2 2SO3 (k) 2SO2 (k) + O2 (k) c? hng s c?n bng K3 Mi li?n h gia c?c hng s c?n bng n?o sau ?y kh?ng ?ng? A. Error: Reference source not found B. Error: Reference source not found C. Error: Reference source not found D. Error: Reference source not found 48. So s?nh pin in h?a v? n m?n kim loi, iu n?o sau ?y kh?ng ?ng ? A. T?n c?c in cc ging nhau : catot l? cc ?m v? anot l? cc dng B. Pin in h?a ph?t sinh d?ng in, n m?n kim loi kh?ng ph?t sinh d?ng in. C. Kim loi c? t?nh kh mnh hn lu?n l? cc ?m D. Cht c? t?nh kh mnh hn b n m?n 49. Cho Ka ca NH4+ bng 5,56.1010. Vy nng mol H+ trong dung dch NH4Cl 0,1M l? : A. 0,1M. B. 0,556.10-10 M. C. 0,746.10-5 M. D. 1,34.10-9 M . 50. D?y c?c kim loi n?o sau ?y u c? 1 electron h?a tr ? A. K, Al, Cr, Cu. B. Cr, Cu, Sc, Ga. C. Li, Na, K, Ag. D. Cr, Cu, Sc, Ag. Phn II: d?nh cho th? sinh chng tr?nh kh?ng ph?n ban (6 c?u-t c?u 51 n c?u 56) 51. chng n m?n kim loi, phng ph?p n?o sau ?y kh?ng ?ng ? A. V t?u bin bng st c gn mt l? Sn l?m vt hi sinh. B. M crom c?c vt bng st. C. Ph mt lp nha l?n c?c vt bng st. C. B?i du m l?n b mt kim loi 52. S h?a cht ti thiu cn d?ng nhn bit 4 l mt nh?n cha c?c dung dch: NaOH, H2SO4, HCl, NaCl l?: A. 0 B. 1 C. 2 D. 3 53. Trong c?c kim loi : Fe, Zn, Pb, Mn, Mg, Sr, Cr. S lng kim loi c? th iu ch bng phng ph?p nhit nh? m l? : A. 3 B. 4 C. 5 D. 6 54. Nu ch x?t sn phm ch?nh th? s chuyn h?a n?o sau ?y KH?NG ?ng ? A. CH3CHOHCH3Error: Reference source not foundCH3CH=CH2Error: Reference source not foundCH3CH2CH2OH B. CH3CH2CH2OHError: Reference source not foundCH3CH=CH2Error: Reference source not foundCH3CHOHCH3 C. CH3CH2CH2OHError: Reference source not foundCH3CH=CH2Error: Reference source not foundCH3CHClCH3Error: Reference source not foundCH3CHOHCH3 D. CH3CH2CH2OHError: Reference source not foundCH3CH2CH2ClError: Reference source not foundCH3 CH2CHOH 55. C?c cht trong d?y n?o sau ?y u to kt ta vi dung dch AgNO3/NH3 ? A. vinylaxetilen, glucoz, metyl fomiat, anehit axetic B. glucoz, metyl fomiat, imetylaxetilen, anehit axetic C. vinylaxetilen, glucoz, metyl fomiat, axit propionic D. vinylaxetilen, glucoz, metyl fomiat, imetylaxetilen 56. Cho 0,10 mol Fe v? 0,10 mol FeO phn ng vi dung dch cha 0,15 mol AgNO3. Sau khi phn ng xy ra hon tn th? khi lng cht rn thu c l? : A. 21,6 g B. 23,4 g C. 24,8 g D.26,0g

 10
( thi c 04 trang)

THI TH VO I HC, CAO NG Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao )

PHN CHUNG: (44 cu t cu 1 n cu 44) 1. Tnh kh ca cc kim loi : Al, Mg, Fe, Cu, Ag, Zn c xp tng dn theo dy : A. Al < Mg < Fe < Zn < Cu < Ag. B. Ag < Cu < Fe < Zn < Al < Mg. C. Cu < Ag < Fe < Al < Zn < Mg. D. Mg < Al < Zn < Fe < Cu < Ag. 2. Cho CO d phn ng vi hn hp gm : MgO, Al 2O3, Fe3O4, CuO nhit cao. Sau phn ng cht rn thu c gm : A. MgO, Al2O3, FeO, Cu. B. MgO, Al2O3, Fe, Cu. C. MgO, Al, Fe, Cu. D. Mg, Al, Fe, Cu. 3. Cho hn hp 18,4g bt st v ng vo dung dch cha 0,4 mol AgNO 3, sau khi phn ng hon ton thu c 49,6g hai kim loi. Vy khi lng st v ng trong hn hp u ln lt l : A. 5,6 g v 12,8 g. B. 5,6 g v 9,6 g. C. 11,2 g v 3,2 g. D. 11,2 g v 6,4 g. 4. Cho hn hp bt gm 2,7g Al v 11,2g Fe vo dung dch cha 0,6 mol AgNO3. Sau khi phn ng xy ra hon ton c cht rn A. Khi lng cht rn A l : A. 67,6 g B. 70,4 g C. 64,8 g D. 67,5 g 5. Cc kim loi trong dy no sau y u phn ng c vi dung dch NaOH long, ngui ? B. Zn, Be, Ba, Al. B. Zn, Al, Cr, Be C. Li, Be, Fe, Ca D. Mg, Zn, Na, Pb. 6. Cho dung dch cha 0,05 mol FeSO 4 phn ng vi dung dch NaOH d. Sau phn ng lc ly kt ta ri em nung trong khng kh n khi khi lng khng i. Khi lng cht rn thu c sau khi nung l : A. 4,00 gam. B. 5,35 gam. C. 4,50 gam. D. 3,60 gam. 7. Phng php no sau y khng th loi b ng thi c cng tm thi ln cng vnh cu ca nc A. Chng ct B. Dng Na2CO3 C. Dng Na3PO4 D. Dng HCl trc v Na2SO4 sau 8. Nhit nng chy v khi lng ring ca cc kim loi PNC nhm II (nhm IIA) khng tun theo mt quy lut nht nh l do cc kim loi kim th : A. c kiu mng tinh th khc nhau. B. c bn knh nguyn t khc nhau. C. c nng lng ion ha khc nhau. D. tnh kh khc nhau 9. Nc cng khng gy ra tc hi no di y ? B. Lm hao tn cht git ra tng hp. B. Lm gim mi v thc phm. C. Lm gim an ton cc ni hi. D. Lm tc cc ng dn nc trong cc ng c hi nc . 10. Cho 4,5 gam kim loi X tc dng ht vi dung dch HNO 3, thu c 0,0625 mol kh N2O (sn phm kh duy nht). Vy X l B. Zn B. Fe C. Al D. Mg 11. Hn hp no sau y khng tan ht trong nc nhng tan hon ton trong nc c ha tan CO2 A. MgSO3, BaCO3, CaO B. MgCO3, CaCO3, Al(OH)3 C. Al2O3, CaCO3, CaO D. CaSO4, Ca(OH)2, MgCO3 12. Ty theo nhit , n cht lu hunh c th tn ti dng no sau y ? A. Ch c S v S8 B. Ch c S2 v S8 C. Ch c S8 v Sn D. C 4 dng : S ; S2 ; S8 ; Sn 13. Phn ng no sau y khng ng ? A. 2FeCl3 + 3H2S Fe2S3 + 6HCl B. Al2S3 + 6H2O 2Al(OH)3 + 3H2S B. Zn3P2 + 6H2O 3Zn(OH)2 + 2PH3 D. AlN + 3H2O Al(OH)3 + NH3 14. Cho 4 cht sau y : S cht c th CH3 lm mt mu dung CH3 dch brom l : A. 1 CH3 C. 3 15. C9H12 c th c bao nhiu ng phn thm ? A. 5 B. 6 16. Glucoz ha tan c Cu(OH)2 v : D. 4 C. 7 D. 8

B. 2

A. glucoz c tnh axit yu. B. glucoz c nhm CHO. C. glucoz c th chuyn ha t mch vng sang mch h. D. glucoz c nhiu nhm OH k nhau . 17. ng dng no sau y khng ng ? A. Trong cng nghip ngi ta dng saccaroz trng gng B. Dung dch saccaroz c truyn vo tnh mch cho ngi bnh. C. Xenluloz dng sn xut vi may mc. D. T g ngi ta sn xut cn. 16. Phn ng no sau y khng to ra t ? A. Trng hp caprolactam. B. Trng ngng axit -aminocaproic. C. Trng hp vinyl xianua. D. Trng hp vinyl axetat. 17. Bc ca amin l : A. s nguyn t nit thay th nguyn t hiro gc hirocacbon. B. s gc hirocacbon thay th s nguyn t hiro trong phn t NH3. C. bc ca nguyn t C gn vi nhm NH2. D. s nhm NH2 gn vo gc hirocacbon. 18. Cho (CH3)2NH vo nc, lc nh, sau yn th c A. hn hp c nh sa. B. hai lp cht lng khng tan vo nhau. C. dung dch trong sut ng nht. D. cc ht kt tinh khng mu lng xung y ng nghim. 19. Hp cht no sau y tham gia phn ng thy phn trong mi trng kim? A. Poli(vinly axetat) B. Cao su buna-S. C. Nha PE. D. Poli(metylmetacrilat) 20. Cng thc no sau y l ca mt loi cao su ? Cl A.
n

B.
n

C.
CN n

D.
n

21. Hp cht no sau y khng th phn ng vi dung dch NaOH iu kin thch hp? COOCH3 CH3 A. CH2OCH3 B. C. Cl D.
OH

22. Cho 15,4g hn hp gm ancol etylic v etilenglicol (etylen glicol) tc dng va vi Na th thot ra 4,48 lt kh H2 (ktc) v dung dch mui. C cn dung dch mui ta c cht rn c khi lng l : A. 22,2 g B. 24,4 g C. 15,2 g D. 24,2 g 23. S ancol bc hai trong cc ancol c cng thc phn t C5H12O l : A. 1 B. 2 C. 3 D. 4 24. Cho 1 mol X phn ng vi dung dch AgNO3/NH3 d ta c 2 mol Ag. Vy X l : A. OHCCHO B. HCOONa C. HCHO D. CH2(CHO)2 25. Hng s ca 3 axit (K a) c xp theo trt t sau 25 oC:1,75.10-3; 17,72.10-5; 1,33.10-5. Vy trt t ca dy axit tng ng vi 3 hng s trn l : A. HCOOH, CH3COOH, CH3CH2COOH B. CH3CH2COOH, HCOOH, CH3COOH C. CH3COOH, HCOOH, CH3CH2COOH D. CH3CH2COOH, CH3COOH, HCOOH t,H2O 26. Cho phn ng : NH4OOCCH2CHBrCH2COOH + NaOH X (sn phm hu c) +.... Vy X l : A. NaOOCCH2CHBrCH2COONa B. NaOOCCH2CHOHCH2COONa C. NH4OOCCH2CH=CHCOOH D. NaOOCCH2CH=CHCOONa 27. Thu phn este A c cng thc phn t C4H6O2 to sn phm c kh nng tham gia phn ng trng gng. A c cng thc cu to no trong nhng cng thc cu to di y ? A. CH3COOCH=CH2 hay CH2=CHCOOCH3 B. HCOOCH2CH=CH2 hay CH2=CHCOOCH3 C. HCOOCH=CHCH3 hay CH2=CHCOOCH3 D. CH3COOCH=CH2 hoc HCOOCH=CHCH3 28. Tng s ng phn cu to chc axit v este ca hp cht c cng thc phn t C3H6O2 l : A. 1. B. 2. C. 3 D. 4. 29. Cho cc dung dch sau: dung dch HCl, dung dch Ca(NO 3)2, dung dch FeCl3, dung dch AgNO3, dung dch cha hn hp HCl v NaNO3, dung dch cha hn hp NaHSO4 v NaNO3. S dung dch c th tc dng vi ng kim loi l:

A. 2 B. 3 C. 4 D. 5 30. Cho 1,21g hn hp Zn v Fe tc dng vi bnh cha dung dch cha 0,01 mol H 2SO4 long. Sau khi phn ng xy ra hon ton khi lng bnh thay i l: A. tng 1,01g B. gim 1,01g C. tng 1,19g D. gim 1,19g 31. Ha tan hn hp gm 0,01 mol Fe2O3 v 0,02 mol Fe bng dung dch HCl d thu c dung dch X. Cho dung dch X tc dng vi dung dch NaOH d, lc ly kt ta v nung trong chn khng n khi lng khng i th c m gam cht rn. Vy m c gi tr l : A. 3,20g B. 3,92 g C. 4,00 g D. 3,04 g 32. Phn ng no sau y khng to ra HBr ? A. SO2 + Br2 + H2O B. Br2 + H2O C. PBr3 + H2O D. NaBr (rn) + H2SO4 (c, nng) 33. Nhn nh no sau y ng? A. Cc nguyn t c phn lp ngoi cng ng vi ns2 (n 2) u l cc kim loi B. Cc nguyn t cc kim loi u c phn lp ngoi cng l ns1 hay ns2 (n 2) C. Cc nguyn t kim loi khng nm cc PNC ca nhm VI, VII (ca nhm VIA, VIIA). D. Cc nguyn t c electron cui cng nm phn lp (n-1)dx u l cc kim loi. 34. Thi t t n d kh X vo dung dch Ba(OH)2 thy c kt ta, sau kt ta tan. Vy X c th l: A. CO2 hay SO2 B. CO2 hay H2S C. SO2 hay NO2 D. CO2 hay NO2 35. Cng thc no sau y khng ng ? O O C. O D. P A. B. H O O P O S
S

36. Nhn nh no sau y khng ng ? A. Lin kt kim loi ging lin kt cng ha tr im : dng chung cc electron ha tr. B. Lin kt kim loi ging lin kt ion im : c hnh thnh do lc ht tnh in. C. Lin kt ion ging lin kt cng ha tr im : c hnh thnh do lc ht tnh in. D. Lin kt kim loi ging lin kt ion im : c hnh thnh do lc ht tnh in gia cc ion. 37. Hp cht no sau y ch c th l ancol ? A. C2H6O B. C3H6O C. C3H8O D. CH4O 38. Cho hp cht hu c A (cha C, H, O) c t khi hi so vi nit l 2 tc dng vi dung dch AgNO 3 trong NH3 thu c mui ca mt axit hu c n chc. Vy cng thc cu to ca A l : A. CH3CH2CH=O B. HCOOCH=CH2 C. CH2=CHCH=O D. OHC-CHO 39. Phn ng no sau y khng xy ra ? A. C2H5OH + HBr C2H5Br + H2O C. C2H5OH + NaOH C2H5ONa + H2O B. C2H5OH + CH3OH C2H5OCH3 + H2O D. 2C2H5OH (C2H5)2O+ H2O 40. Trong cc cht sau: etylamin, ancol etylic, anehit axetic, imetyl ete. Cht c nhit si cao nht l: A. etylamin B. ru (ancol) etylic C. anehit axetic D. imetyl ete 41. Khi thc hin phn ng tch nc hon ton 0,5 mol hn hp C2H5OH v C3H7OH bng H2SO4 c nng. Sn phm to thnh lun c: A. s mol H2O = 0,5 mol B. s mol hn hp anken = 1,0 mol C. s mol H2O 0,5 mol D. s mol hn hp ete + s mol nc = 1,0 mol 42. iu ch glixerin (hay glixerol), dy chuyn ha no sau y ng ? A. CH2=CHCH3 CH2BrCHBrCH3 CH2BrCHBrCH2Cl CH2OHCHOHCH2OH B. CH2=CHCH3 CH2=CHCH2Cl CH2ClCHOHCH2Cl CH2OHCHOHCH2OH C. CH2=CHCH3 CH3CHOHCH3 CH2ClCHOHCH2Cl CH2OHCHOHCH2OH D. CH2=CHCH3 CH3CH2CH3 CH2ClCHClCH2Cl CH2OHCHOHCH2OH PHN RING (th sinh ch c lm mt trong hai phn: phn I hoc phn II) Phn I: dnh cho th sinh chng trnh phn ban (6 cu- t cu 45 n cu 50) 45. Pht biu no sau y ng ? A. Xenluloz l polime c to thnh bi cc lin kt (1,6) glicozit. B. Amiloz l polime c to thnh bi cc lin kt (1,6) glicozit. C. Amilopectin l polime c to thnh bi cc lin kt (1,4) v (1,6) glicozit . D. Amiloz l polime c to thnh bi cc lin kt (1,4) v (1,6) glicozit. 46. Khi c cn dung dch cha hn hp gm : 0,200 mol Na+ ; 0,100 mol Mg2+; x mol Cl v y mol SO42 th thu

c 23,7 g mui. Vy tr s ca x, y ln lt l : A. 0,200 v 0,100. B. 0,100 v 0,150. C. 0,050 v 0, 175. D. 0,300 v 0,050. 47. Cht no sau y khng th to ra axit axetic bng 1 phn ng? A. Axetilen B. Anhiric axetic C. Ancol metylic D. Butan 48. Bit Kb ca CH3COO l 5,71.1010. Vy nng mol H+ trong dung dch NaCH3COO 0,100M l : A. 0,000M B. 0,571.1010 M C. 0,756.105 M D. 1,323.109 M 49. Nhn xt no sau y khng ng ? A. in cc ca pin in ha tri du vi in cc ca bnh in phn. B. in phn dung dch CuSO4 vi anot bng ng th nng Cu2+ khng i. C. Cc electron di chuyn c hng trong cu mui. D. o th in cc chun ca kim loi, in cc chun hiro lun t bn tri vn k. 50. Tnh cht ha hc ca cc cht trong bng sau l : Cht Tnh kh Tnh oxi ha Tnh baz Tnh axit A. CrO c c c khng B. C. D. Cr2O3 CrO Cr2O3 khng khng c c c c c c c c khng khng

Phn II: dnh cho th sinh chng trnh khng phn ban (6 cu-t cu 51 n cu 56) 51. Mt kim loi X tc dng vi Cl2 c mui B. Cho X tc dng vi axit HCl ta c mui C. Cho X tc dng vi dung dch mui B ta c mui C. Vy X l : A. Al. B. Zn. C. Fe. D. Mg. 52. Cho ankan A phn ng th vi Br2 c chiu sng ngi ta thu c hn hp kh gm mt dn xut mono brom v HBr c t khi hi so vi khng kh bng 4. Vy A l A. etan B. propan C. butan D. pentan 53. Ha tan hon ton mt oxit kim loi bng dung dch H 2SO4 c, nng thu c 2,24 lt kh SO2 (ktc) v 120g mui khan. Cng thc ca oxit kim loi l : A. Al2O3 B. Fe2O3 C. Fe3O4 D. CuO 54. Phn ng no sau y ca benzen l ng ? A. C6H6 + 3H2 C6H12 Ni,t B. C6H6 + 4H2 C6H14 nh sng C. C6H6 + Cl2C6H5Cl + HCl D. C6H6 + Cl2C6H6Cl2 55. C bao nhiu ru (ancol) ng vi cng thc C3H8Ox vi x 3 c th ha tan c Cu(OH)2 ? A. 1 B. 2 C. 3 D.4 56. Nhn nh no sau y khng ng ? V Al(OH)3 l hiroxit lng tnh nn c th A. phn li kiu axit hay kiu baz. B. nhng hay nhn proton. C. tc dng vi tt c cc axit v baz. D. tan trong dung dch Sr(OH)2.

P N
10
1 B 2 1 A 4 1 B 2 B 2 2 B 4 2 B 3 A 2 3 A 4 3 C 4 A 2 4 D 4 4 B 5 A 2 5 C 4 5 C 6 A 2 6 B 4 6 A 7 D 2 7 A 4 7 A 8 A 2 8 B 4 8 D 9 A 2 9 D 4 9 C 1 0 C 3 0 C 5 0 A 1 1 A 3 1 C 1 2 D 3 2 C 1 3 A 3 3 D 1 4 A 3 4 D 1 5 D 3 5 D 5 1 C 1 6 D 3 6 A 5 2 A 1 7 B 3 7 C 5 3 C 1 8 D 3 8 D 5 4 A 1 9 B 3 9 D 5 5 B 2 0 C 4 0 C 5 6 C

 012
( thi c 04 trang)

THI TH VO I HC, CAO NG Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao )

PHN CHUNG: (44 cu t cu 1 n cu 44) Phn chung cho tt c cc th sinh 1. Dy ch gm cc nguyn t kim loi chuyn tip l : A. Ca, Sc, Fe, Ge. B. Zn, Mn, Cu, Sc. C. Ca, Sc, Fe, Zn. D. Sn; Cu, Pb, Ag. 2. Dy gm cc kim loi m nguyn t ca chng u c 2 electron ha tr l : B. Ca, Ti, Cr, Zn. B. Mg, Zn, Sc, Ga. C. Fe, Zn, Pb, Cu. D. Zn, Sr, Cd, Hg. 3. Cho Ba vo cc dung dch sau : NaHCO3, CuSO4, (NH4)2CO3, NaNO3, MgCl2. S dung dch to ra kt ta l : A. 1. B. 2. C. 3. D. 4. 4. Ha tan ht 4,7 g hn hp X cha 1 kim loi kim v 1 kim loi kim th trong 4 kim loi sau : Na, K, Ca, Ba vo nc ta c 3,36 lt kh (ktc). X phi cha : C. Na. B. Li. C. Ca. D. Ba. 5. Cho Fe3O4 vo dung dch cha hn hp HCl v H2SO4 long d, s cht c trong dung dch thu c sau khi phn ng kt thc l : D. 3. B. 4. C. 5. D. 6. 6. t chy hon ton 26,8 g hn hp 3 kim loi Fe, Al, Cu thu c 41,4 g hn hp 3 oxit. Th tch dung dch H2SO4 1M cn dng ha tan va hn hp oxit trn l E. 1,8250 lt. B. 0,9125 lt. C. 3,6500 lt. D. 2,7375 lt. 7. Hin tng xy ra khi cho t t bari kim loi n d vo dung dch MgCl2 l : F. c kh thot ra v c kt ta keo trng khng tan. G. c kh thot ra to dung dch trong sut. H. c Mg kim loi to thnh bm vo mu bari v kh bay ra. I. c kh thot ra, to kt ta keo trng sau kt ta tan. 8. Ho tan hon ton 4,11 gam mt kim loi M vo nc thu c 0,672 L kh ktc. Vy M l J. Na . B. K. C. Ba . D. Ca. 9. in phn nng chy mui clorua kim loi thu c 0,672 lt kh (ktc) anot v 0,72 gam kim loi. Vy kim loi l : K. Li. B. Ca. C. Mg. D. Rb. 10. Th nghim no sau y sau khi hon thnh c kt ta ? L. Cho dung dch AlCl3 d vo dung dch NaAlO2 (hay Na[Al(OH)4] M. Cho Al kim loi vo dung dch NH4HCO3 N. Zn vo dung dch KOH O. Cho dung dch Ba(OH)2 vo dung dch NaAlO2 (hay Na[Al(OH)4]) 11. Dung dch cha mui X khng lm qu tm ha ; dung dch cha mui Y lm qu tm ha . Trn chung hai dung dch trn to kt ta v c kh bay ra. Vy X v Y c th l cp cht no trong cc cp cht di y ? P. Na2SO4 v Ba(HCO3)2 B. Ba(HCO3)2 v KHSO4 C. Ba(NO3)2 v (NH4)2CO3 D. Ba(HSO4)2 v K2CO3 12. Cho 0,08 mol dung dch KOH vo dung dch cha 0,06 mol H3PO4. Sau phn ng, dung dch c cc cht : Q. KH2PO4 v K2HPO4 B. KH2PO4 v K3PO4 C. K2HPO4 v K3PO4 D. K3PO4 v KOH 13. C bao nhiu ng phn cu to ca xicloankan c cng thc phn t C5H10 lm mt mu dung dch brom R. 0 B. 2 C. 3 D. 4 14. Ch xt sn phm chnh th phng trnh ho hc no sau y ng ? A. C.
Cl Cl2 Fe

Cl2

Fe

CH3
Cl HCl

CH2Cl Cl2 Fe
Cl Cl2 Fe NO2 + HCl

B. D.
NO2

+ HCl

Cl Cl + HCl

2 2 A dung d ch xanh lam 15. Cho dy chuyn ha : B A c th l nhng cht no trong dy sau y ? A. Glucoz, saccaroz, mantoz. B. Fructoz, saccaroz, xenluloz. C. Saccaroz, mantoz, tinh bt. D. Glucoz, fructoz, mantoz. 16. Tin hnh thy phn m gam bt go cha 80% tinh bt, ri ly ton b dung dch thu c thc hin phn ng trng gng th c 5,4 gam bc kim loi. Bit hiu sut ton b qu trnh l 50%. Vy gi tr ca m l : S. 1,620 gam. B. 10,125 gam. C. 6,480 gam. D. 2,531 gam. 17. Dy no sau y gm cc cht u c th phn ng vi Cu(OH)2 iu kin thch hp ? T. Axit axetic, saccaroz, anehit fomic, mantoz. B. Glucoz, h tinh bt, anehit fomic, mantoz. C. Glucoz, fructoz, saccaroz, xenluloz. D. Axit fomic, h tinh bt, glucoz, saccaroz. 18. Cho 20 g hn hp 3 aminoaxit no, n chc, mch h l ng ng k tip tc dng va vi dung dch HCl 1M. C cn dung dch thu c 31,68 g hn hp mui. Vy th tch HCl dng : U. 0,32 lt B. 0,33 lt C. 0,032 lt D. 0,033 lt 19. Cht no sau y khng phn ng vi dung dch brom ?

+ H O, H+, to

Cu(OH)

CH3

NH2

OH

CH=CH2

A.

B.

CH3

C.

Cl

D.

20. Phng php iu ch polime no sau y ng ? A. Trng ngng caprolactam to ra t nilon-6. B. ng trng hp axit terephtalic v etilenglicol (etylen glicol) c poli(etylen terephtalat) C. ng trng hp butaien-1,3 (buta-1,3-ien) v vinyl xianua c cao su buna-N D. Trng hp ancol vinylic c poli(vinyl ancol) 21. Phn ng polime ha no sau y khng ng ? CH2 CH2 C=O A. n CH2 NH [CH2 ] 5 CO CH2 CH NH n B. n CH2 CH2 CH2 CH2 O n O C. n CH2=CH CH=CH2 + nCH=CH2 CH2 CH=CH CH2 CH CH
2

n OH 22. S ng phn cu to ca cc ru (ancol) mch h bn c cng thc phn t C4H8O l : A. 3 B. 4 C. 5 D. 6 23. Theo s :X . Z
C2H5OH Y T Vi mi mi tn l mt phn ng, th X, Y, Z, T l : A. Etilen, axetilen, glucoz, etyl clorua. B. Etilen, natri etylat, glucoz, etyl axetat. B. Anehit axetic, vinyl axetat, etyl clorua. D. Etilenglicol , natri etylat, glucoz, anehit axetic. 24. Phng trnh no sau y khng ng (C6H5 l gc phenyl) ? A. C6H5ONa + CO2 + H2O C6H5OH + NaHCO3 B. C6H5ONa + CH3COOH C6H5OH + NaCH3COO C. C6H5OH + CH3COOH C6H5OOCCH3 + H2O D. C6H5OH + 3Br2 2,4,6-Br3C6H2OH + 3HBr 25. Trong iu kin thch hp, sn phm chnh ca phn ng no sau y khng phi anehit ? A. CH3-CCH + H2O B. C6H5CH2OH + CuO C. CH3OH + O2 D. CH4 + O2 26. Cho 20,16 g hn hp 2 axit no n chc tc dng va vi dung dch Na 2CO3 th thu c V L kh CO2

D. n NH2[CH2]5COOH

NH2

[CH2]5

CO

(o ktc) v dung dch mui. C cn dung dch th thu c 28,96g mui. Gi tr ca V l : A. 1,12 lt B. 8,96 lt C. 2,24 lt D. 5,60 lt 27. Cc cht trong dy cht no sau y u tham gia phn ng trng gng ? A. Axit fomic; metyl fomiat; benzanehit B. imetyl xeton; metanal; mantoz. C. Saccaroz; anehit fomic; metyl fomiat D. Metanol; metyl fomiat; glucoz 28. Phn ng no sau y to ra este? t,xt A. CH3COOH + CH2=CHOH B. CH3COOH + C6H5OH t,xt C. CH3COOH + CHCH D. [C6H7O2(OH)3] + CH3COOH 29. Hp cht no sau y khng tham gia phn ng trng gng ? A. HCOONa B. HCOOCH3 C. CH2(CHO)2 D. CHCH 30. Thi t t cho n d kh NH3 vo dung dch X th c hin tng : lc u xut hin kt ta sau kt ta tan. Vy dung dch X cha hn hp : A. Cu(NO3)2 v AgNO3. B. Al(NO3)3 v AgNO3. C. Al2(SO4)3 v ZnSO4. D. AlCl3 v BeCl2. 31. Dy cc nguyn t c xp theo chiu tng dn m in l : A. K, Na, Mg, Al. B. K, Mg, Na, Al. C. Al, Na, Mg, K. D. Al, Mg, Na, K. 32. C bao nhiu nguyn t m nguyn t c lp ngoi cng l lp th t v lp ny ch cha 1 electron ? A. 1 B. 2 C. 3 D. 4 33. Cht no sau y c th tan trong dung dch NH3 nhit phng ? A. CuO B. AgCl C. Al(OH)3 D. Ag 34. Hn hp no sau y tan ht trong lng d nc ? A. 1,15 g Na v 5,40 g Al B. 3,90 g K v 8,10 g Al C. 6,85 g Ba v 5,4 g Al D. 1,40 g Li v 5,40 g Al 35. Hai dung dch cha hai cht in li AB v CD (A v C u c s oxi ha +1) c cng nng . Mt cht in li mnh, mt cht in li yu. Phng php no sau y c th phn bit c chng ? A. Dng giy qu tm. B. Dng my o pH. C. Dng dng c o dn in. D. in phn tng dung dch. 36. Ha tan hon ton 11g hn hp gm Fe v mt kim loi M c ha tr khng i bng dung dch HCl thu c 0,4 mol kh H2. Cn khi ha tan 11g hn hp trn bng dung dch HNO 3 long, d th thu c 0,3 mol kh NO (sn phm kh duy nht). Kim loi M l : A. Cu B. Cr C. Mn D. Al 37. Dng ha cht no sau y khng th phn bit c 3 cht rn : Na2CO3, NaHCO3, CaCO3 ? A. Nc, nc vi trong. B. Dung dch HCl. C. Nc, dung dch CaCl2 D. Nc, dung dch MgSO4 38. Ch xt sn phm chnh th dy chuyn ha no sau y ng ? A. C6H6 C6H5Cl C6H5ONa C6H5OH Ba(C6H5O)2 B. C6H6 C6H5Cl o-NO2C6H4Cl m-NO2C6H4OH C. C6H6 C6H5NO2 m-NO2C6H4Cl m-NO2C6H4ONa D. C6H6 C6H5NO2 o-NO2C6H4NO2 o-NH2C6H4NH2 39. Cc cht c xp theo chiu tng dn v nhit si l : A. C3H7COOH; CH3COOC2H5; C3H7OH B. CH3COOC2H5; C3H7OH; C3H7COOH C. CH3COOC2H5; C3H7COOH; C3H7OH D. C3H7OH ; C3H7COOH ; CH3COOC2H5; 40. t chy hon ton este X thu c s mol CO2 bng s mol H2O. Vy X l : A. este n chc, c 1 vng no B. este n chc no, mch h. C. este hai chc no, mch h. D. este n chc, mch h, c mt ni i. 41. Hp cht thm A c cng thc phn t C8H8O2 khi phn ng vi dung dch NaOH thu c 2 mui. Vy A c bao nhiu ng phn cu to ph hp vi gi thit trn ? A. 2 B. 3 C. 4 D. 5 42. t chy hon ton 6g hp cht hu c n chc no A ta c 0,2 mol kh CO2 v 0,2 mol H2O. Vy A l A. C2H4O2 hay CH2O. B. C2H4O2 hay C4H8O2 . C. C2H4O2 hay C3H6O3. D. CH2O hay C4H8O2. 43. Cp cht no sau y khi phn ng to ra phenol ? t,p A. C6H5Cl + NaOH B. C6H5ONa + NaHSO4 C. C6H5OOCCH3 + KOH D. C6H5ONa + NaHCO3 44. C cc cp cht sau: Cu v dung dch FeCl 3; H2S v dung dch CuSO4; H2S v dung dch FeCl3; dung dch AgNO3 v dung dch FeCl3. S cp cht xy ra phn ng iu kin thng l: A. 1 B. 2 C. 3 D. 4

PHN RING (th sinh ch c lm mt trong hai phn: phn I hoc phn II) Phn I: dnh cho th sinh chng trnh phn ban (6 cu- t cu 45 n cu 50) 45. Nng mol H+ trong dung dch NaCH3COO 0,1M (Kb ca CH3COO l 5,71.10-10) l : A. 0,00M B. 0,571.10-10 M C. 0,756.10-5 M D. 1,323.10-9 M 46. Crom khng phn ng vi H2O iu kin thng do : A. lp oxit ph bn ngoi B. th in cc chun m C. th in cc chun dng D. c mng tinh th lc phng 47. Cho Cu vo dung dch c cha ion NO3- trong mi trng axt to thnh dung dch ion Cu2+, cn ion Cu2+ tc dng vi I- to thnh Cu+. Tnh oxi ha trong mi trng axt ca cc ion c sp xp theo chiu gim dn l: A. NO3- > Cu2+ > IB. Cu2+ > NO3- > I- C. NO3 - > I- > Cu2+ D. Cu2+ > I- > NO348. Nhn xt no sau y lun ng v cc kim loi nhm B? A. C t 3 lp electron tr ln B. C s electron ha tr l 1 hay 2 C. C electron ngoi cng thuc phn lp s D. C 2 electron lp ngoi cng 49. iu ch Cu bng cch kh 8 g CuO bng kh CO nhit cao thu c 5,84 g cht rn. Hiu sut qu trnh iu ch l : A. 90% B. 80% C. 73% D. 91,25% 50. Theo phn ng : K[Cr(OH)4] + H2O2 + KOH K2CrO4 + H2O Lng H2O2 v KOH tng ng c s dng oxi ha hon ton 0,01 mol K[Cr(OH)4] thnh K2CrO4 ln lt l : A. 0,15 mol v 0,1 mol. B. 0,3 mol v 0,1 mol. C. 0,3 mol v 0,2 mol. D. 0,3 mol v 0,4 mol. Phn II: dnh cho th sinh chng trnh khng phn ban (6 cu-t cu 51 n cu 56) 51. Ha tan ht 0,02 mol Al v 0,03 mol Cu vo dung dch HNO 3 ri c cn v un n khi lng khng i th thu c cht rn nng : A. 3,42 g B. 2,94 g C. 9,9 g D. 7,98 g 52. im ging nhau gia s in phn v s in li l : A. u l qu trnh oxi ha kh. B. u c mt cc ion. C. u nh vo dng in 1 chiu. D. u phi c dung mi. 53. Cho 5,6 g Fe vo 250 mL dung dch AgNO 3 1M th c dung dch A. Nng mol cc cht trong dung dch A l : A. 0,20M v 0,20M. B. 0,40M v 0,20M. C. 0,33M. D. 0,40M. 54. Cng thc chung cc cht ng ng ca xiclobuten l A. C4nH6n B. CnHn+2 C. CnH2n-2 D. C2nH3n 55. t chy hon ton 0,1mol kh C2H4 ri dn ton b sn phm vo dung dch cha 0,15mol Ca(OH)2. Khi lng dung dch sau phn ng thay i nh th no ? A. Tng 12,4 g B. Gim 10 g C. Tng 2,4 g D. Gim 1,2 g 56. Cng thc cu to no sau y khng ph hp vi cht c cng thc phn t l C6H10 ? A. B.
CH3 CH3

C.
CH3

D.

CH3 CH3

 12
( thi c 05 trang)

THI TH VO I HC, CAO NG Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao )

PHN CHUNG: (44 cu t cu 1 n cu 44) 1. Trn bt nhm d vo hn hp gm : MgO, Fe3O4, CuO ri nung nhit cao. Sau khi phn ng hon ton cht rn thu c gm : A. MgO, Al2O3, FeO, Cu, Al B. MgO, Al2O3, Fe, Cu, Al C. MgO, Al, Fe, CuO, Al2O3 D. Mg, Al, Fe, Cu, Al2O3 2. ng dng no sau y ca kim loi l khng ng ? B. Ch c dng ngn cn cht phng x. C. Thic c trng ln cc vt bng st chng n mn in ha. D. Niken dng lm cc in cc trong bnh cquy. E. Km c dng ch to pin in ha. 3. Khi gang, thp b n mn in ha trong khng kh m, nhn nh no sau y khng ng ? F. Tinh th Fe l cc dng xy ra qu trnh kh. B. Tinh th C l cc dng xy ra qu trnh kh. C. Tinh th Fe l cc m xy ra qu trnh oxi ha. D. Tinh th C l cc m xy ra qu trnh kh. 4. Cho 2,32g hn hp gm FeO; Fe2O3 v Fe3O4 (s mol FeO = s mol Fe2O3) tc dng va vi V(L) dung dich HCl 1M. Gi tr V l: A. 0,04 lt B. 0,08 lt C. 0,12 lt D. 0,16 lt 5. Cho 2,16 gam bt Al vo dung dch cha hn hp gm CuCl2 0,12 mol v FeCl3 0,06 mol. Sau khi phn ng xy ra hon ton c cht rn A. Khi lng cht rn A l: A. 5,76 g B. 1,92 g C. 5,28 g D. 7,68 g 6. Kim loi Al phn ng c tt c cc cht trong nhm no sau y nhit thng? A. dung dch Ba(OH)2, KHSO4, dung dch FeSO4 * B. dung dch H2SO4 long, dung dch NaOH, dung dch MgCl2 C. HNO3 c, dung dch CH3COOH, dung dch CuSO4 D. dung dch FeCl3, CrCl3, Fe3O4 7. Th nghim no sau y khi hon thnh khng c kt ta? A. Cho dung dch AlCl3 d vo dung dch NaOH B. Cho Ba kim loi vo dung dch NH4HCO3 C. Zn vo dung dch KOH D. Cho dung dch NH4Cl vo dung dch NaAlO2 (hay Na[Al(OH)4]) 8. chuyn ch an ton lng ln dung dch HNO3 m c, ngi ta thng dng bn cha lm bng : A. st. B. st trng km. C. st m niken. D. ng. 9. Nhn nh no sau y ng ? A. sn xut Al, ta khng in phn nng chy AlCl3 v AlCl3 nng chy khng in li. B. Khi in phn Al2O3, phi trn thm criolit v Al2O3 nng chy khng dn in. C. ngn khng cho Al to ra tip xc vi khng kh, thng in phn phi y kn. D. Khi in phn Al2O3 , in cc than ch b hao ht lin tc. 10. t nng hn hp gm bt Al v bt Fe 3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton thu c hn hp X. Cho hn hp X tc dng vi dung dch NaOH d thu c kh H 2 bay ln. Vy, trong hn hp X c nhng cht sau : A. Al, Fe, Fe3O4, Al2O3. B. Al, Fe, Al2O3. C. Al, Fe, Fe2O3, Al2O3. D. Al, Fe, FeO, Al2O3. 11. Kim loi M thuc nhm A c 1 electron c thn trng thi c bn. Cng thc oxit ca M c th l : A. M2O hay MO. B. MO hay M2O3. C. M2O3 hay MO2. D. M2O hay M2O3. 12. pht hin cc kh sau trong hn hp kh, phng php no khng ng? A. Dng dung dch KI v h tinh bt nhn ra O3 B. Dng dung dch CuSO4 nhn ra H2S C. Dng dung dch phenolphtalein nhn ra NH3 D. Dng dung dch BaCl2 nhn ra CO2 13. Phn ng no sau y khng phi l phn ng oxi ha - kh ? A. CaOCl2 + CO2 CaCO3 + Cl2 B. (NH4)2CO3 2NH3 + CO2 + H2O C. 4KClO3 KCl + 3KClO4 D. CO + Cl2 COCl2 14. Nu ch xt sn phm chnh th phn ng ng l :

CH2CH3

+ Br2

as

CHBrCH CHCH 3 3 CH2CH3 Br

A.

B.
CHCH3 2Br as

+ + HBr

+ Br2

+ HBr
Br

C. D. 15. t chy hon ton mt hirocacbon A, ri dn ton b sn phm chy qua bnh cha dung dch nc vi trong (d), th khi lng dung dch trong bnh gim 2,48 g v c 7 g kt ta to ra. Cng thc phn t ca A l : A. C6H12. B. C6H14. C. C7H14. D. C7H16. 16. Cc hin tng ca th nghim no sau y c m t ng ? A. Cho dung dch I2 vo h tinh bt : mu xanh xut hin, un nng : mu xanh mt, ngui : li c mu xanh. B. Cho fructoz vo ng nghim cha dung dch AgNO3/ NH3 ri un nng khng c Ag to ra, cho tip vi git axit sunfuric vo ri un nng : c Ag xut hin. C. Nh dung dch I2 ln mu chui chn : khng c mu xanh. Cho mu chui vo dung dch H 2SO4 rt long un nng mt lc, ngui ri nh dung dch I2 vo : mu xanh xut hin D. Cho Cu(OH)2 vo dung dch glucoz : Cu(OH) 2 tan to thnh dung dch xanh lam, un nng, hn hp : mu xanh mt i v c kt ta gch. Lm lnh hn hp kt ta tan v mu xanh xut hin tr li. 17. iu no sau y khng ng khi ni v xenluloz ? A. Tan trong dung dch [Cu(NH3)4](OH)2 B. C th dng iu ch ancol etylic C. Dng sn xut t enan D. To thnh este vi HNO3 c 18. Phn ng no sau y ng ? A. ClNH3 R COOH + NaOH ClNH3 R COONa + H2O B. ClNH3 R COOH + 2NaOH NH2 R COONa + H2O + NaCl C. ClNH3 R COOH + NaOH ClNH3 R COONa + H2O D. 2NH2 R COONa + H2SO4 2NH2 R COOH + Na2SO4 19. Cc cht trong dy no sau y u c tnh lng tnh ? A. NH2CH2COONa, ClNH3CH2COOH , NH2CH2COOH B. NH2CH2COOH, NH2CH2COONH4 , CH3COONH4 C. CH3COOCH3 , NH2CH2COOCH3 , ClNH3CH2 CH2NH3Cl D. ClNH3CH2COOH, NH2CH2COOCH3, NH2CH2CH2ONa 20. Cht hu c X phn ng c vi : dung dch AgNO 3/NH3, dung dch NaOH, dung dch HCl. Vy cng thc no sau y khng ph hp ? A. NH2CH(CHO)COOH B. HCOOCH(NH2)COOH C. HCOOCH2COONH4 D. ClNH3CH(CHO)CH2OH 21. Cch phn loi no sau y ng ?
A. Cc loi si vi, si len u l t thin nhin B. T nilon-6 l t nhn to

C. T visco l t tng hp D. T xenluloz axetat l t ha hc 22. Trong cc cht sau, cht no khng th dng iu ch cao su bng mt phn ng?
A. ivinyl B. i-pren C. cloropren D. propaien

23. Cng thc chung no sau y l ng ? A. Cng thc chung ca ancol n chc no l CnH2n+1OH (n 1) B. Cng thc chung ca ancol no, mch h l CnH2n+2 -a (OH)a (n a) C. Cng thc chung ca ancol no, n chc, mch h, c 1 ni i l CnH2n-1OH (n 2) D. Cng thc chung ca ancol thm, n chc l CnH2n-7OH (n 6) 24. Oxi ho 4 g ancol n chc th c 5,6 g mt hn hp X gm anehit, nc v ancol d. Cho hn hp X tc dng ht vi dung dch AgNO3/ NH3 d th c bao nhiu gam Ag ?
A. 43,20 g 20,52 g B. 21,60 g D. 10,80 g C.

25. Trong cc ancol c cng thc phn t C4H8O, s ancol bn, khi b oxi ha to thnh anehit l : A. 2 B. 3 C. 4 D. 5 26. un nng hn hp 2 ancol n chc mch nCO2 : nH 2O = 3 : 4 h vi H2SO4 c 140oC thu c hn hp 3 ete. t chy 1 trong 3 ete thu c kh cacbonic v hi nc c t l mol l . Cng thc phn t

ca 2 ancol l: A. CH3OH v C2H5OH * B. C2H5OH v CH3CH2OH C. CH3OH v CH3CH2CH2OH D. C2H5OH v CH3CHOHCH3 27. S ng phn cu to ca cc anehit no, mch h, a chc ng vi cng thc n gin nht C2H3O l
A. 2 C. 4 D. 5 B. 3

28. mnh tnh axit c xp tng dn theo dy sau : A. CH3COOH < HCOOH < H2CO3 < HClO B. HCOOH < CH3COOH < H2CO3 < HClO C. HClO < H2CO3 < CH3COOH < HCOOH D. H2CO3 < CH3COOH < HCOOH < HClO 29. Cho 0,1 mol mt este X tc dng va vi dung dch cha 0,2 mol NaOH, thu c hn hp hai mui ca hai axit hu c u n chc v 6,2 g mt ancol Y. Y l cht no trong cc cht sau ? A. C2H4(OH)2 B. CH2(CH2OH)2 C. CH3CH2CH2OH D. CH3CH2 CHOHCH2OH 30. Dy gm cc cht no sau y u l este ?
A. Vinyl axetat, natri axetat, lipit phenolat, metyl fomiat, etyl acrilat B. Etyl

B. Etyl acrilat, etylen iaxetat, xenluloz trinitrat D. Etylen iaxetat, lipit, etyl phenolat 31. Th nghim no sau y ch 1 hin tng: ch c kt ta hoc ch c kh bay ra ? A. Cho dung dch H2SO4 phn ng vi dung dch Ba(HCO3)2 B. Cho dung dch Na2CO3 vo dung dch AlCl3 C. Cho Ba vo dung dch NaHSO3 D. Cho Mg vo dung dch NaHSO4 32. Ha tan ht 0,02 mol Al v 0,03 mol Ag vo dung dch HNO 3 ri c cn v un n khi lng khng i th thu c cht rn nng :
A. 4,26 g. C. 3,78 g. 7,38 g. B. 4,50 g. D.

33. Cho phn ng : 3H2(kh) + Fe2O3 (rn) 2Fe + 3H2O (hi) Nhn nh no sau y l ng? A. Tng p sut cn bng ha hc chuyn dch theo chiu thun B. Thm Fe2O3 cn bng ha hc chuyn dch theo chiu thun C. Nghin nh Fe2O3 cn bng ha hc chuyn dch theo chiu thun D. Thm H2 vo h cn bng ha hc chuyn dch theo chiu thun 34. Trn 6 g Mg bt vi 4,5 g SiO2 ri un nng nhit cao cho n khi phn ng xy ra hon ton. Ly hn hp thu c cho tc dng vi dung dch NaOH d. Th tch kh hiro bay ra iu kin tiu chun l :
A. 1,12 lt C. 0,56 lt 3,92 lt B. 5,60 lt D.

35. Kim loi c cu hnh electron no sau y c tnh kh mnh nht ? X : 1s2 2s2 2p6 3s2 3p6 3d10 4s1 ; Y : 1s2 2s2 2p6 3s2 3p1 ; 2 2 6 2 6 2 Z : 1s 2s 2p 3s 3p 4s ; T : 1s2 2s2 2p6 3s1
A. X B. Y C. Z D. T

36. in phn dung dch CuSO4 vi in cc tr, cng dng l 5A. Khi anot c 4 g kh oxi bay ra th ngng in phn. iu no sau y lun ng ? A. Khi lng ng thu c catot l 16 g B. Thi gian in phn l 9650 giy C. pH ca dung dch trong qu trnh in phn lun tng ln D. Ch c kh thot ra anot 37. Cho CO qua ng s cha m gam Fe 2O3 un nng. Sau mt thi gian ta thu c 5,2 g hn hp X gm Fe v 3 oxit kim loi. Ha tan X bng HNO3 c nng th c 0,05 mol kh NO2. Vy gi tr ca m l :
A. 5,60 g C. 7,60g 9,84g B. 6,00 g D.

38. tinh ch I2 c ln cc tp cht l : BaCl2, MgBr2, KI ngi ta c th s dng cch no sau y ? A. Dng dung dch h tinh bt hp th I2 B. Nung nng hn hp sau lm lnh C. Ho tan hn hp vo nc ri cho tc dng vi dung dch AgNO3 D. Dng dung dch Na2CO3 ri lc b kt ta, cho dung dch phn ng vi kh clo

39. Pht biu no sau y v ancol thm l ng ? A. Cng thc chung ca ancol thm l C6H6z(OH)z vi n 6 B. Do nh hng ca vng benzen nn ancol thm phn ng c vi dung dch kim C. Khi th cc nguyn t H ca vng benzen bng cc nhm OH ta c ancol thm a chc D. Cc ancol thm u phn ng vi Ba. 40. Phn ng no sau y ng? CH2Br CH2OH 41. Phn ng no sau y Br Br to + NaOH chng t A. + NaBr trong phn t ru CH2Br CH2OH (ancol) etylic c ,p to Br Br nhm + NaOH + NaBr B . hiroxyl ? A. 2C2H5O H + CH2Br CH2OH 2Na 2C2H5O ,p to Br OH Na + H2 + NaOH + NaBr B. C. C2H5O H + CH2Br CH2ONa CuO CH3CH ,p to Br ONa + + 4NaOH H O O + Cu + 2NaBr 2 2 D. + H2O C. C2H5OH + O2 CH3COOH + H2O D. C2H5OH + HBr C2H5Br + H2O 42. Dy no sau y c cha cht khng tham gia phn ng este ha ?
A. Saccaroz, etilenglicol (etylen glicol), xenluloz, axetilen

B. Alanin, axit fomic, glixerin (glixerol)

C. Etilenglicol (etylen glicol), glucoz, glyxin

D. Ancol metylic, metylamin, axit fomic 43. ng vi cng thc phn t C5H8O2 c bao nhiu ng phn axit cu to mch nhnh ?
A. 3 B. 4 C. 5 D. 6

44. Nhn xt no sau y l ng? A. Cu thng c s oxi ha +2 trong hp cht v lp electron ngoi cng l 4s2 B. Ion Cu2+ c cu hnh electron l 1s2 2s2 2p6 3s2 3p6 4s1 3d8 C. Ion Cu+ c 10 electron lp ngoi cng. D. Cu c xp vo nhm B v electron cui cng phn lp d PHN RING (th sinh ch c lm mt trong hai phn: phn I hoc phn II) Phn I: dnh cho th sinh chng trnh phn ban (6 cu- t cu 45 n cu 50) 45. PTHH no sau y khng ng ? A. CH2=CHCH2Cl + H2O CH2=CHCH2 t OH + HCl B. CH3CHCH2Cl + H2O CH3CHCH2 t OH + HCl H2O t,p C. C6H5Cl + 2NaOH C6H5ONa + NaCl + t,p D. CH2=CH Cl + NaOH CH3CHO + NaCl 46. Phng php no sau y thng c dng iu ch Ag t Ag2S ? + HNO NaCN + Zn t 3 A. Ag2SNa[Ag(CN)2]Ag AgNO3Ag + + HCl as O CO C. Ag2SAg2OAg D. 2 Ag2S AgClAg 47. C 4 cht lng ng trong 4 l b mt nhn : toluen, ru (ancol) etylic,

B.

Ag2S

dung dch phenol, dung dch axit fomic. phn bit 4 cht trn c th dng thuc th t nht l : A. ch dng nc brom.
qu tm, nc brom.

B.

B. qu tm, nc brom, dung dch kali cacbonat. 48. Nhn xt no sau y lun ng ?

D. nc brom, natri kim loi.

A. Cc nguyn t nhm B u l cc kim loi. B. Cc kim loi nhm B khng phn ng vi nc.

B. Cc kim loi nhm B c tnh kh trung bnh. D. Cc kim loi nhm B u c 2 electron lp ngoi cng. 49. Nhn nh no sau y trong pin in ha l ng ? A. in cc xy ra s oxi ha, c tn l anot, ni sinh ra electron. B. in cc xy ra s kh, c tn l anot, ni sinh ra electron. C. in cc xy ra s oxi ha, c tn l catot, ni sinh ra electron. D. in cc xy ra s kh, c tn l catot, ni sinh ra electron. 50. Tc hi i vi mi trng ca nhm cc cht no sau y lit k khng ng ?
A. Mt s cht ph hy tng ozon : CFC, NO, CO, halogen...

B. Mt s cht to ma axit : SO2, CO2, NO, NO2, HCl... C. Mt s cht gy hiu ng nh knh : CO2, SO2, C2H6, CH4... D. Mt s cht gy m quang ha : O3, SO2, H2S, CH4... Phn II: dnh cho th sinh chng trnh khng phn ban (6 cu-t cu 51 n cu 56) 45. Pht biu no sau y ng ? A. Cht c cng thc chung CnH2n thuc dy ng ng anken B. Dy ng ng ankin c cng thc chung CnH2n-2 C. Hirocacbon no c cng thc chung l CnH2n+2 D. Cng thc chung ca hirocacbon thm l CnH2n-6 46. Cho hn hp X gm 2 oxit kim loi tc dng vi dung dch H2SO4 (long, d), c mt dung dch va lm mt mu dung dch KMnO4, va ha tan bt Cu. Vy X l hn hp no trong cc hn hp sau ? A. FeO v Al2O3 B. Fe3O4 v MgO C. Fe2O3 v CuO D. FeO v CuO 47. Phn ng no sau y khng ng ? t A. Fe + H2O FeO B. Fe + H2O Fe3O4 t C. Fe + I2 FeI2 Fe2S3 D. Fe + S 48. Kh hon ton 0,1 mol Fe2O3 bng CO d, sn phm kh thu c cho hp th hon ton vo dung dch cha 0,2 mol Ca(OH)2 th c a gam kt ta. Gi tr ca a l :
A. 10 g. C. 25 g. 30 g. B. 20 g. D.

49. X, Y l cc ng phn c cng thc phn t C5H10. X lm mt mu dung dch brom iu kin thng to sn phm tng ng l 1,3-ibrom-2-metylbutan. Y phn ng vi brom khi chiu sng to mt dn xut monobrom duy nht. X v Y ln lt l :
A. 3-metylbuten-1 v xiclopentan. metylbuten-2 v metylxiclobutan. B. 2-

B. metylxiclopropan v metylxiclobutan. D. 1,2-imetylxiclopropan v xiclopentan. 50. Cho 6,80 g hn hp CaO, CuO phn ng hon ton vi cacbon d nhit cao thu c 2,24 L kh CO duy nht (ktc). Khi lng kim loi to thnh l A. 6,4 g. B. 5,2 g. C. 3,2 g. D. 4,0 g.

 13
( thi c 05 trang)

THI TH VO I HC, CAO NG

Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao )

PHN CHUNG: (44 cu t cu 1 n cu 44) 1. Nhng nhm nguyn t no di y ngoi nguyn t kim loi cn c nguyn t phi kim ? A. Phn nhm chnh (PNC) nhm IA (tr hiro) v PNC nhm II (IIA) B. PNC nhm III (IIIA) n PNC nhm VIII (VIIIA) C. Phn nhm ph (PNP) nhm I (IB) n PNP nhm VIII (VIIIB) D. H lantan v h actini 2. Tnh cht vt l no di y ca kim loi KHNG phi do cc electron t do trong kim loi gy ra ? A. nh kim B. Tnh do C. Tnh cng D. Tnh dn in v dn nhit 3. Ln lt cho tng kim loi Mg, Al, Fe v Cu (c s mol bng nhau), tc dng vi lng d dung dch HCl. Khi phn ng hon ton th th tch H2 (trong cng iu kin) thot ra nhiu nht l t kim loi : A. Mg B. Al C. Fe D. Cu

4. Ha tan hon ton m gam Na kim loi vo 100 ml dung dch HCl 1M thu c dung dch A. Trung ha dung dch A cn 100 mL dung dch H2SO4 1M. Tnh m. A. 2,3 gam B. 4,6 gam C. 6,9 gam D. 9,2 gam 5. Thm t t tng git dung dch cha 0,05 mol HCl vo dung dch cha 0,06 mol Na2CO3. Th tch kh CO2 (ktc) thu c bng : A. 0,000 lt. B. 0,560 lt. C. 1,120 lt. D. 1,344 lt. 6. Ha tan ht 7,6 gam hn hp hai kim loi kim th thuc hai chu k lin tip bng dung dch HCl d th thu c 5,6 lt kh (ktc). Hai kim loi ny l : A. Be v Mg. B. Mg v Ca. C. Ca v Sr. D. Sr v Ba. 7. Nc cng khng gy ra tc hi no di y ? A. Gy ng c nc ung. B. Lm mt tnh ty ra ca x phng, lm h hi qun o. C. Lm hng cc dung dch pha ch, lm thc phm lu chn v gim mi v thc phm. D. Gy hao tn nhin liu v khng an ton cho cc ni hi, lm tc cc ng ng dn nc.
8. Cho 0,8 mol nhm tc dng vi dung dch HNO 3 thu c 0,3 mol kh X (khng c sn phm kh no khc). Kh X l : A. NO2. B. NO. C. N2O. D. N2.

9. Ha tan 47,4 gam phn chua KAl(SO4)2.12H2O vo nc c dung dch A. Thm n ht dung dch cha 0,2 mol Ba(OH)2 vo dung dch A th lng kt ta thu c bng : B. 7,8 gam. B. 46,6 gam. C. 54,4 gam. D. 62,2 gam. 10. Cho 0,015 mol bt Fe vo dung dch cha 0,04 mol HNO3 thy thot ra kh NO duy nht. Khi phn ng hon ton th khi lng mui thu c bng : A. 2,42 gam. B. 2,70 gam. C. 3,63 gam. D. 5,12 gam. 11. Phn ng no di y KHNG th to sn phm l FeO ? t oC A. Fe(OH)2 B. FeCO3 C. 500600 Fe(NO3)2 D. CO + Fe2O3
12. Pht biu no di y l ng (gi thit cc phn ng u hon ton) ? A. 0,1 mol Cl2 tc dng vi dung dch NaOH d to 0,2 mol NaClO B. 0,3 mol Cl2 tc dng vi dung dch KOH d (70oC) to 0,1 mol KClO3 C. 0,1 mol Cl2 tc dng vi dung dch SO2 d to 0,2 mol H2SO4 D. 0,1 mol Cl2 tc dng vi dung dch Na2SO3 d to 0,2 mol Na2SO4 13. Tin hnh th nghim nh hnh v bn : Sau mt thi gian th ng nghim cha dung dch Cu(NO3)2 quan st thy : A. khng c hin tng g xy ra. B. c xut hin kt ta mu en. C. c xut hin kt ta mu trng. D. c si bt kh mu vng lc, mi hc. 14. Thi 0,4 mol kh etilen qua dung dch cha 0,2 mol KMnO 4 trong mi trng trung tnh, khi lng etylen glicol (etilenglicol) thu c bng :

A. 6,2 gam. B. 12,4 gam. C. 18,6 gam. D. 24,8 gam. 15. Tn gi no di y l ng cho hp cht sau? A. buten-3 (but-3-en) CH2 = CH CH2 CH CH3 | B. penten-3 (pent-3-en) CH3 C. 4-metylpenten-1 (4-metylpent-1-en) D. 2-metylpenten-3 (2-metylpent-3-en)
16. Tnh lng kt ta ng(I) oxit to thnh khi un nng dung dch hn hp cha 9,00 gam glucoz v lng d ng(II) hiroxit trong mi trng kim. A. 1,44 gam B. 3,60 gam C. 7,20 gam D. 14,4 gam 17. Nhn xt no sau y khng ng ? A. Rut bnh m ngt hn v bnh. B. Khi n cm, nu nhai k s thy v ngt. C. Nh dung dch iot ln ming chui xanh thy xut hin mu xanh. D. Nc p chui chn cho phn ng trng bc. 18. im ging nhau gia phn ng thy phn tinh bt v thy phn xenluloz l : A. sn phm cui cng thu c. B. loi enzim lm xc tc. C. sn phm trung gian ca qu trnh thy phn. D. lng nc tham gia phn ng thy phn. 19. Amin no di y c bn ng phn cu to ? A. C2H7N B. C3H9N C. C4H11N D. C5H13N 20. 0,01 mol aminoaxit A phn ng va vi 0,02 mol HCl hoc 0,01 mol NaOH. Cng thc ca A c dng : A. H2NRCOOH. B. (H2N)2RCOOH. C. H2NR(COOH)2. D. (H2N)2R(COOH)2. 21. Sn phm v tn gi ca cc cht trong phn ng polime ha no di y l hon ton ng ?

A. n H 2N[CH 2]5COOH HN[CH 2]5CO + nH 2O n B. n H ]5COOH HN[CH2]6CO + nH2O axit 2N[CH -aminocaproic CH2 2 CH Tnilon-7 n 2 C O axit -aminoenantoic Tenan n HN[CH ]5CO + nH2O C. n CH 2 D. H N[CH HN[CH 2 2 2]6COOH 2] 6CO n + nH 2O 22. Polime no di y n CH CH NH 2 2 T capron axit 7-aminoheptanoic c cu to khng Tnilon-7 caprolactam iu ha ? A. B. H H HH H H H C. D. | | H | H | |H H | H H | CH CH C CCH C C CH CH2 23. Theo ngun gc, loi t CH | C | | | | CH C2 C 2 2 2 2 2 |2 | | | | C | CH |2 CH CH =2C C CH CH C CH =C CH2 C |C no di y cng loi CH 2 2 2 C 2 2 CH Cl Cl Cl CH CH CH | vi len ? | | |Cl | | 3 3 3 3 Cl Cl OOCCH3 OOCCH OOCCH OOCCH A. bng 3 3 3
C. visco D. xenluloz axetat

B.

capron

24. Tn gi no di y KHNG ng vi hp cht (CH3)2CHCH2CH2OH ? A. 3-metylbutanol-1 (hay 3-metylbutan-1-ol) B. 2-metylbutanol-4 ( hay 2-metylbutan-4-ol) C. ancol i-pentylic D. ancol i-amylic 25. C cc hp cht hu c : (X) CH3CH(OH)CH2CH3 (Y) CH3CH2OH (Z) (CH3)3COH (T) CH3CH(OH)CH3 Cht ehirat ha to thnh ba olefin ng phn l : A. X B. Y v Z C. T D. khng c 26. Cho 0,01 mol phenol tc dng vi lng d dung dch hn hp HNO3 c v H2SO4 c. Pht biu no di y KHNG ng ? A. Axit sunfuric c ng vai tr xc tc cho phn ng nitro ha phenol. B. Sn phm thu c c tn gi 2,4,6-trinitrophenol. C. Lng HNO3 tham gia phn ng l 0,03 mol. D. Khi lng axit picric hnh thnh bng 6,87 gam. 27. C cc anehit : (X) HCH=O (Y) CH3CH=O
(Z) CH2=CH-CH=O Cc cht thuc loi anehit mch h, no, n chc l : (T) OHC-CH2-CHO

A. (X) v (Y). B. (Y). C. (Z). D. (Z) v (T). 28. Phng trnh ho hc no di y c vit KHNG ng ? HH HH+ HOH B. A.CH CH CH CH CH OCH OH 3 3 3 C C+ HOCH 3 33 CH D. C. CH CH + + HCN CH CH CH OSO CN 29. trung ha 28,8 gam 3 3 CC 3Na 33 CH 2Na O OHSO OH OH hn hp gm axit axetic, OO OH OH ru n-propilic v p-cresol cn 150 mL dung dch NaOH 2 M. Ha tan 28,8 gam hn hp trn trong n-hexan ri cho Na d vo th thu c 4,48 L kh hiro (ktc). Lng axit axetic trong hn hp bng : A. 0,1 mol. B. 0,2 mol. C. 0,3 mol. D. 0,4 mol. 30. Thy phn este X trong mi trng axit thu c hai cht hu c A v B. Oxi ha A to sn phm l cht B. Cht X khng th l : A. etyl axetat B. vinyl axetat C. etilenglicol oxalat D. isopropyl propionat 31. Cho dy chuyn ha iu ch : Cht X l : + O2, Mn2+ A B A. CH3CH2CH(OH)CH(CH3)2 B. + O2, Pt n-C3H7OC3H7-i C. H2SO4 CH3CH2COOCH(CH3)2 D. CH3CH2CH2OH X o C2H5COOC3H7-n H2SO4, 180 C

32. Nung n hon ton 0,05 mol FeCO 3 D E trong bnh kn cha 0,01 mol O2 thu + HOH, H+ c cht rn A. ha tan ht A bng dung dch HNO3 c, nng th s mol HNO3 ti thiu cn dng l : A. 0,14 mol. B. 0,15 mol. C.0,16 mol. D. 0,18 mol. 33. Ha tan hon ton hn hp gm Na 2O, BaCl2, NaHCO3, NH4Cl c s mol mi cht bng nhau vo nc ri un nng nh. Sau khi kt thc th nghim c dung dch A. Dung dch A cha : A. NaCl. B. Na2CO3 v NaOH. C. BaCl2, NaHCO3 v NaOH. D. NaOH, BaCl2, NaHCO3 v NH4Cl. 34. Cho 1,2 gam Mg vo 100 mL dung dch hn hp gm HCl 1,5M v NaNO 3 0,5M. Sau phn ng ch thu c V lt kh dng n cht (khng c sn phm kh no khc). Th tch V (ktc) bng : A. 0,224 lt. B. 0,560 lt. C. 1,120 lt. D. 5,600 lt. 35. Ha tan ht hn hp cha 10 gam CaCO 3 v 17,4 gam FeCO3 bng dung dch HNO3 long, nng. S mol HNO3 tham gia phn ng bng : A. 0,2 mol. B. 0,5 mol C. 0,7 mol D. 0,8 mol

36. phn bit ba bnh kh mt nhn ln lt cha cc kh N2, O2 v O3, mt hc sinh dng cc thuc th (c trt t) theo bn cch di y. Cch no l KHNG ng ? A. l Ag nng, que m. B. que m, l Ag nng. C. dung dch KI/ h tinh bt, que m. D. dung dch KI/ h tinh bt, l Ag nng. 37. C mt mu NH3 b ln hi nc. c NH3 khan, th cht lm khan nn dng l : A. Na. B. CaO. C. P2O5. D. H2SO4 c.
38. C bn hp cht X, Y, Z v T. Ngi ta cho mu th ca mi cht ny ln lt qua CuO t nng, CuSO 4 khan v bnh cha dung dch Ca(OH) 2. Sau th nghim thy mu X ch lm CuSO 4 i qua mu xanh ; mu Y ch to kt ta trng bnh cha nc vi ; mu Z to hin tng c hai bnh ny, cn mu T khng to hin tng g. Kt lun ng cho php phn tch ny l : A. X ch cha nguyn t cacbon. B. Y ch cha nguyn t hiro C. Z l mt hirocacbon. D. T l cht v c. 39. Cht Z cha C, H v O. Khi lng mi nguyn t (ng vi m gam cht Z) v phn t khi bng : mC mH mO MZ 2,88 0,48 3,84 60 Cng thc phn t ca Z l : A. CH2O. B. C3H8O. C. C2H4O2. D. C2H6O2. 40. Cng thc phn t no di y c nhiu ng phn cu to nht ? A. C4H10 B. C4H9Cl C. C4H10O D. C4H11N 41. Hiro ha anehit acrilic bng lng d H2 (xc tc Ni, t) th sn phm l : A. CH2=CHCH2OH B. CH3CH2CH2OH C. CH3CH2CH=O D. CH3COCH3 42. Cho dy chuyn ha :

CH3COONa
+ NaOH, CaO, t 1500oC + H2

T
H2SO, 180oC

N Pd/PbCO O 3
+ H2O + KOH/C2H5OH, t

+ H2O

Pht biu no sau y l ng ? A. X l CaC2 B. Y l CH3CH2OH C. Z l CH3CH2Cl D. T l Al4C3 43. Thm dung dch HCl (c ZnCl2 xc tc) ln lt vo ba mu th cha ru (ancol) etylic, ancol i-propylic

v ancol t-butylic. Kt lun no sau y KHNG ng ? A. Mu th vn c ngay lp tc l ru (ancol) etylic. B. Mu th c s phn lp ngay lp tc l ru (ancol) t-butylic. C. Mu th c s vn c sau nm pht l ru (ancol)l i-propylic. D. Kh nng phn ng ca ru (ancol) bc 3 cao hn bc 2, cao hn bc 1.
44. Trong s cc kim loi Mg, Al, Fe v Cr, th kim loi c kh nng phn ng vi dung dch HNO 3 (c, ngui) v H2SO4 (c, ngui) l : A. Mg. B. Al. C. Fe. D. Cr. PHN RING (th sinh ch c lm mt trong hai phn: phn I hoc phn II) Phn I: dnh cho th sinh chng trnh phn ban (6 cu- t cu 45 n cu 50)

45. Lng H2O2 v KOH tng ng c s dng oxi ha hon ton 0,01 mol KCr(OH)4 thnh K2CrO4 l : A. 0,015 mol v 0,01 mol B. 0,030 mol v 0,04 mol C. 0,015 mol v 0,04 mol D. 0,030 mol v 0,04 mol 46. Nhng thanh Cu vo dung dch cha 0,02 mol Fe(NO3)3. Khi Fe(NO3)3 phn ng ht th khi lng thanh Cu : A. khng i. B. gim 0,64 gam. C. gim 1,92 gam. D. gim 0,80 gam. 47. Xt phn ng ha tan vng bng xianua (phn ng cha c cn bng) : Au + O2 + H2O + NaCN Na[Au(CN)2] + NaOH Khi lng vng b ha tan l 1,97 gam th lng NaCN dng l : A. 0,01 mol. B. 0,02 mol. C. 0,03 mol. D. 0,04 mol. 48. Cho bit cc gi tr th in cc chun : 3+ Fe2+ Cu2+ Mg2+ Ag+ Fe Fe Cu Mg Ag Fe2+
Eo (V) 2,37 0,44 + 0,34 + 0,77 + 0,80 Dy no di y gm cc kim loi khi phn ng vi dung dch Fe(NO3)3, th ch c th kh Fe3+ thnh Fe2+ ? A. Mg v Fe. B. Fe v Cu. C. Cu v Ag. D. Ag v Mg.

49. Xt cc cht ru (ancol) etylic, ru (ancol) i-propylic, ru (ancol) n-propylic, anehit axetic, anehit

propionic, axeton. S cht to kt ta vng ioofom khi tc dng vi I2/NaOH l : A. 2 cht. B. 3 cht. C. 4 cht. D. 5 cht. 50. phn bit cc dung dch BaCl2 v CaCl2, tt nht nn dng thuc th : A. Na2CO3. B. Na2SO4. C. (NH4)2C2O4. D. K2CrO4.
Phn II: dnh cho th sinh chng trnh khng phn ban (6 cu-t cu 51 n cu 56) 51. Ha tan 16,4 gam hn hp Fe v FeO trong lng d dung dch HNO 3 ch to sn phm kh l 0,15 mol NO. S mol mi cht trong hn hp ln lt bng : Fe FeO A. 0,100 mol 0,150 mol B. C. D. 0,150 mol 0,225 mol 0,020 mol 0,110 mol 0,053 mol 0,030 mol

52. Thm 2,16 gam Al vo dung dch HNO3 rt long, va th thu c dung dch A v khng thy kh thot ra. Thm dung dch NaOH d vo dung dch A n khi kt ta va tan ht th s mol NaOH dng l : A. 0,16 mol B. 0,19 mol C. 0,32 mol D. 0,35 mol 2+ + 53. Cho trt t dy in ha : Mg Ag Al3+ Cu2+ Khi cho hn hp kim loi Mg Al Cu Ag Mg, Al vo dung dch hn hp cha cc mui AgNO3 v Cu(NO3)2, th phn ng oxi ha kh xy ra u tin s l : A. Mg + 2Ag+ Mg2+ + 2Ag B. Mg + Cu2+ Mg2+ + Cu 2+ 3+ + C. 2Al + 3Cu 2Al + 3Cu D. Al + 3Ag Al3+ + 3Ag 54. Dy no di y ch gm cc cht c kh nng tham gia phn ng trng hp? A. stiren, clobenzen B. etyl clorua, butaien-1,3 B. 1,1,2,2-tetrafloeten, propilen D. 1,2-iclopropan, vinylaxetilen 55. Khi lng dung dch HNO3 65% cn s dng iu ch 1 tn TNT, vi hiu sut 80% l :

A. 0,53 tn B. 0,83 tn C. 1,04 tn D. 1,60 tn 56. C ch no di y m t ng phn ng gia propilen v axit clohiric to sn phm chnh? + Cl H A. CH3CH=CH2 CH3CH2CH2+ + CH3CH2CH2Cl + + Cl B. CH3CH=CH2 CH3+CHCH3 H CH3CHClCH3 + Cl H C. CH3CH=CH2CH3CHClCH2 + CH3CHClCH3 + + Cl D. CH3CH=CH2CH3-CHCH2Cl H CH3CH2CH2Cl
+ + + +

 s 14

TRNG CHUYN L THI TH I HC-CAO NG LN I QU N Mn thi: Ha hc - Khi A TNH B RA-VNG TU THi gian lm bi: 90 pht M : 493 I - PHN DNG CHUNG CHO TT C CC TH SINH (T cu 1-40) 1. Mt dy st ni vi mt dy ng mt u, u cn li nhng vo dung dch mui n. Ti ch ni ca hai dy kim loi xy ra hin tng g? A. Electron di chuyn t Fe sang Cu. B. Ion Fe2+ thu thm 2e to ra Fe C. Ion Cu2+ thu thm 2e to ra Cu D. Electron di chuyn t Cu sang Fe 2. in phn dung dch hn hp gm 0,2 mol CuSO4 v 0,12 mol NaCl vi in cc tr trong thi gian 4 gi v I=1,34A. Khi lng lim loi thu c catot v khi lng kh thot ra anot(ktc) ln lt l A. 6,4 gam Cu v 13,44 l kh B. 6,4 gam Cu v 1,792 l kh C. 3,2 gam Cu v 1,344 l kh A. 3,2 gam Cu v 1,792 l kh 3. Chia hn hp hai andehit no n chc thnh hai phn bng nhau - t chy hon ton phn th nht thu c 0,54 gam nc. - Phn th hai cng H2 (Ni, t0) thu c hn hp X gm 2 ancol no v andehit d Nu t chy hon ton hn hp X th th tch kh CO2 (ktc) thu c l A. 1,68 lit B. 0,112 lit C. 0,672 lit D. 2,24 lit 4.Nhn nh no sau y khng ng A. Gi tr Ka ca mt axit ph thuc vo nng axit B. Gi tr Ka ca mt axit ph thuc vo bn cht axit C.Gi tr Ka ca mt axit ph thuc vo nhit D. Gi tr Ka ca mt axit cng ln th lc axit cng mnh 5. Hp kim Cu-Zn (45% Zn) c tnh cng, bn hn Cu dng ch to cc chi tit my, ch to thit b dng trong ng tu bin gi l A. ng thau B. ng bch C. Vng 9 cara D. ng thanh 6. tc dng ht vi 100g lipit c ch s axit bng 7 phi dng 17,92 gam KOH. Tnh khi lng x phng thu c. A. 100,745 gam B. 108,625 gam C. 109,813 gam D. 98,25 gam 0 7. Khi iu ch etylen t ancol etylic v H2SO4 c khong 170 C th kh etylen thu c thng c ln CO2, SO2, hi nc. loi b cc cht trn cn dng cch no sau y A. Dn hn hp kh i qua dung dch brom d v bnh cha H2SO4 c, d B. Dn hn hp kh i qua dung dch KMnO4 d v bnh cha Ca(OH)2, d C. Dn hn hp kh ln lt qua dung dch brom d, NOH d v bnh cha Ca(OH)2, d D. Dn hn hp kh ln lt qua dung dch NOH d v bnh cha P2O5 khan VCO : VH O = 2 : 3 8. C hao amin bc nht. A l ng ng ca anilin v B l ng ng ca metylamin. t chy hon ton 3,21 gam A thu c336 cm3 N2 (ktc) v t chy hon ton B cho hn hp kh trong t l . Cng thc ca A, B ln lt l A. CH3C6H4NH2 v CH3(CH2)3NH2 B. C2H5C6H5NH2 v CH3(CH2)2NH2 C. CH3C6H4NH2 v CH3(CH2)4NH2 D. CH3C6H4NH2 v CH3(CH2)2NH2 9. Cho 11,6 gam mui FeCO3 tc dng vi dung dch HNO3, thu c hn hp kh CO2, NO
2 2

v dung dch X. Thm vo dung dch X mt lng HCl (d) th thu c dung dch ho tan ti a bao nhiu gam bt ng, bit rng kh bay ra la NO. A. 3,2 gam B. 32 gam C. 28,8 gam D. 14,4 gam HNO dd(1:1) HNO Zn / HCl X Y Z 10. Cho chui chuyn ha C7 H 8 H SO dd sau . X,Y,Z l cc hp cht hu c, thnh phn ch yu ca Z l A. o- Metylanilin, p-Metylanilin B. o-Crezol, m-Crezol C. o-Crezol, p-Crezol D. Axit o-phtalic, Axit p-phtalic 11. Nhit si ca cc cht c xp theo th t tng dn A. C2H5Cl < CH3COOCH3 < C2H5OH < CH3COOH B. CH3COOCH3 < C2H5Cl < C2H5OH < CH3COOH C. C2H5Cl < CH3COOH< CH3COOCH3 < CH3CHO D.CH3COOH < HCOOH < CH3COOH < C2H5F 12. C 2,62 gam cao su Buna-S phn ng va ht vi 1,6 gam brom trong dung dch CCl4. T l s mt xch butadien v stiren trong phn t cao su Buna_S l A. 2: 3 B. 1: 2 C. 1: 3 D. 3: 5 13. Kt lun no sau y l sai A. Dung dch HCl c pH = 2 th CM = 0,01M B. Dung dch H2SO4 c pH = 0,7 th CM = 0,50M C.Dung dch Ba(OH)2 c pH = 11 th CM = 0,0005M D. Dung dch NaOH c pH = 12,3 th CM = 0,020M 14. Nguyn t ca nguyn t X c lp ngoi cng l 3p. Nguyn t ca nguyn t Y c phn lp ngoi cng l 3s. Tngr s electron ca 2 phn lp ngoi cng ca X v Y l 7. Bit rng X v Y d dng phn ng vi nhau. S hiu nguyn t X v Y tng ng l A. 13 v 15 B. 18 v 11 C. 17 v 12 D. 11 v 16 15. Cho cc cn bng (1)3Fe(r ) + 4 H 2O Fe3O4 ( r ) + 4 H 2 ( k ) H = +35 Kcal sau: H 2O(h) + CO (k ) H = +10 Kcal (2)CO2 (k ) + H 2 (k ) Chn phn ng khi 2 SO2 (k ) + O2 (k ) H = +22, 08 Kcal (3)2 SO3 (k ) tng p sut cn bng 2 H 2O(h) H = 115, 6 Kcal (4)O2 ( k ) + 2 H 2 (k ) chuyn dch theo chiu nghch A. (3) v (4) B. (4) A. (3) A. (1) v (2) 16. Hp th Vlit CO2 (ktc) vo 200ml dung dch NaOH 1M thu c dung dch X. Khi cho CaCl2 d vo dung dch X thu c kt ta v dung dch Y, un nng Y li thy kt ta xut hin.Gi tr ca V l A. 1,12 < V < 2,24 B. 2,24 < V < 4,48 C. 4,48 V D. V 1,12 17. Sacarozo c tnh cht no trong s cc tnh cht sau: 1. Polisacarit 2. Khi tinh th khng mu 3. khi thu phn to thnh glucoz v fructoz 4. Tham gia phn ng trng gng 5. Phn ng vi Cu(OH)2. Nhng tnh cht no ng A. 1,2,3,4 B. 2,3,5 C. 1,2,3,5 D. 3,4, 5. 18. Cho 0,1 mol cht X (C2H8O3N2) tc dng vi dung dch cha 0,2 mol NaOH un nng thu c cht kh lm xanh gy qu tm t v dung dch Y. C cn dung dch Y thu c m gam cht rn khan. Chn gi tr ng ca m. A. 12,5 gam B. 21,8 gam C. 5,7 gam D.
3 2 2 4

15 gam 19. Cho dancol = 0,8g/ml v dnc = 1,0g/ml . Nu cho natri d vo 115 ml ancol etylic 150 th th tch kh thot ra l(ktc) A. 60,816 lit B. 64,18 lit C. 65,16 lit D. 3,36 lit 20. Cho cc dung dch sau X1 : NH4Cl X2 : CH3COONa X3 : Na2CO3 X4 : NaHSO4 X5 : NaCl` Cc dung dch c pH ln hn 7 l A. X1,X2 ,X3 ,X4 , X5 B. X1,X4 , X5 C. X2 ,X3 ,X4 D. X2 ,X3 21. Trn 12,0 gam hn hp bt Cu, Fe vi 8,0gam S thu c hn hp X. Nung X trong bnh kn khng c khng kh, sau mt thi gian thu c hn hp Y. Ho tan ht Y trong dung dch HNO3 c, nng, d thu c kh NO2 duy nht l hai mui sunfat. Phn trm khi lng Cu trong hn hp u l A. 61,36% B. 63,52% C. 55,14% D. 53,33% 22. Kh 1,6 gam hn hp 2 andehit no bng kh H2 thu c hn hp 2 ru. un nng hn hp hai ru ny vi H2SO4 c 1800 C thu c hn hp 2 olefin l ng ng k tip. t chy hai olefin ny c 3,52gam CO2. Bit cc phn ng xy ra hon ton. Cng thc ca hai andehit l A. CH3CHO, C2H5CHO B. CH3CHO, CH2(CHO)2 C. C2H5CHO, C3H7CHO D.HCHO, CH3CHO 23. Cho 30 gam hn hp CaCO3 v KHCO3 tc dgn ht vi HNO3 thu c kh Y, dn kh Y qua 500ml dung dch Ba(OH)2 2M thu c kt ta Z, khi lng ca Z l (gam) A. 59,6 B 59,5 C. 59,1 D. 59,3 24. iu no sau y khng ng? A. Cht do l vt liu b bin dng di tc dng ca nhit p sut m vn gi nguyn bin dng khi khng tc dng B. T tm, bng, len l polime thin nhin C. T visco, t axetat l t tng hp D. Nilon 6-6 v t capron l poliamit 25. Cho 0,92 gam hn hp X gm C2H2 v CH3CHO tc dng va vi dung dch AgNO3/NH3 thu c 5,64 gam cht rn. Phn trm theo khi lng ca C2H2 v CH3CHO cht trong X ln lt l A. 60% v 40% B. 25% v 75% C. 30,67% v 69,33% D. 28,26% v 71,74% 26. Cho dung dch NH3 d vo dung dch X cha hn hp AlCl3, ZnCl2, FeCl3 thu c kt ta Y. Nung kt ta bY n khi lng khng i c cht rn Z, cho lung H2 d i qua Z nung nng n phn ng hon ton thu c cht rn T. Trong T c cha A. Fe B. Al2O3, ZnO v Fe C. Al2O3, Zn D. Al2O3 v Fe 27. Dy no sau y xp theo chiu gim dn bn knh ion A. O2-, F-, Na+,Mg2+,Al3+ B. Al3+,Mg2+, Na+, O2-, FC. Mg2+,O2-,Al3+, F- , Na+ D. Al3+,Mg2+, Na+, F-, O228. Nc clo c tnh ty mu v st trng l do A. Clo l cht oxy ha mnh B. Clo l cht kh tan trong nc C. C cha oxi nguyn t l tc nhn oxy ha mnh D. C cha axit hipoclor l

tc nhn oxy ha mnh 29. Ho ran hn hp cha 0,15 mol Mg v 0,15 mol Al vo dung dch hn hp cha 0,15 mol Cu(NO3)2 v 0,525 mol AgNO3 . Khi phn ng xong cht rn thu c l (gam) A. 32,4 B. 66,3 C. 56,7 D. 63,9 30. Ho tan hon ton m gam bt Al vo dung dch HNO3 va thu c 8,96 lt (ktc) hn hp kh X gm NO v N2O c t khi so vi H2 l 20,25. Lng dung dch HNO3 31,5% cn ly l (gam) A. 300 B. 680 C. 600 D. 340 31.Thnh phn chnh ca amophot, mt loi phn bn phc hp l A. (NH4)2HPO4 v Ca(HPO4)2 B. Ca(HPO4)2 C. NH4H2PO4 v (NH4)2HPO4 D. NH4H2PO4 v Ca(HPO4)2 32. Gi tr pH tng dn ca cc dung dch c cng nng mol/l no sau y l ng (xt 250C) A. C6H5NH2, CH3NH2, NaOH, Ba(OH)2 B. NH3, CH3NH2, C6H5NH2, NaOH, Ba(OH)2 C. Ba(OH)2, NaOH, CH3NH2, C6H5OH D. NaOH, CH3NH2,NH3, Ba(OH)2, C6H5OH 33.X phng ha este C5H10O2 thu c mt ancol. un ancol ny vi H2SO4 c 1700C c hn hp cc olefin, este l A. CH3COOCH(CH3)2 B.HCOOCH(CH2)3CH3 C. HCOOCH(CH3)C2H5 D. CH3COOCH2CH2CH3 34. Cho phng trnh ion thu gon nh sau: aZn + bNO3- + cOH- ZnO22- + NH3 + H2O. Tng h s (s nguyn ti gin) cc cht tham gia phn ng l A. 11 B. 10 C. 9 D.12 35. Cho 3,625 gam hp kim ca Fe, Cr, Al tc dng vi dung dch NaOH d thot ra 2,25l H2 (ktc) v mt phn cht rn khng tan. Lc ly phn cht rn khng tan em phn ng ht vi dung dch HCl (d, khng c khng kh) thy thot ra 0,672 lit kh ktc. % khi lng ca Cr trong hp kim l (%) A. 28,69 B. 12,29 C. 82,29 D. 4,05 36. Ho tan ht 2,08 gam hn hp Fe v Cu bng dung dch HNO3 thu c dung dch X v 672ml NO (ktc). Thm t t 1,2 gam Mg vo dung dch X n khi phn ng hon ton thu c 224ml kh NO, dung dch Y v m gam cht rn khng tan. Gi tr ca m l (gam) A. 1,71 B. 1,44 C. 1,52 D. 0,84 37. Cho cc th nghim sau (1) Sc kh CO2 vo dung dch NaAlO2 (hay Na[Al(OH)4]) (2) Sc kh NH3 vo dung dch AlCl3 (3) Nh t t n d dung dch HCl long vo dung dch NaAlO2 (hay Na[Al(OH)4]) Nhng th nghim c hin tng ging nhau l A. (1), (2) v (3) B. (2) v (3) C. (1) v (3) D. (1) v (2) 38. Hn hp X gm FeO, Fe3O4 v Fe2O3 . kh hon ton 3,04 gam hn hp X cn va 0,1gam H2. Ho tan ht 3,04g X bng H2SO4 c, nng thu c kh SO2 ktc, th tch kh SO2 thu c l (ml) A. 336 B. 448 C. 224 D. 112

39. Thuc th duy nht no sau y ( iu kin thch hp) c th dng phn bit cc cht lng sau: Stiren, benzen, toluen A. Dung dch KMnO4 B. Dung dch Brom C. Dung dch AgNO3/NH3 D. Cu(OH)2 40. Ion X2+ c tng s ht p,e,n bng 90. K hiu ha hc ca nguyn t X l 64 59 56 58 Co Fe Ni A. B. C. D. 27 29 26 28Cu II. Phn ring: Th sinh ch c lm mt trong hai phn: Phn A hoc phn B Phn A. Theo chng trnh chun(10 cu, t cu 41 n 50) 41. C bao nhiu ng phn este mch thng c cng thc phn t C6H10O4 khi tc dng vi NaOH to ra mt mui v mt rc. A. 5 B. 4 C. 3 D.2 42. un nng 0,1mol este ch cha mt loi nhm chc X vi lng va dung dch NaOH thu c 13,4 gam mui ca axit hu c a chc B v 9,2 gam ru n chc C. Cho C bay hi 1270C v 600mmHg s chim th tch 8,32 lit. CTCT ca X l A. (COOC3H5)2 B. (CH2)2 (COOC2H5)2 C.(COOC2H5)2 D. CH(COOCH3)2 43. Cho glyxin tc dng vi alanin th to ra ti a bao nhiu tripeptit A. 5 B. 8 C. 4 D.6 44. Khi trn cc cht kh: H2 v O2 (1), NO v O2 (2), CO v O2(3) v NH3 vi HCl th cc trng hp c th tch gim ngay nhit thng so vi tng th tch ca tng kh l A. (3) v (4) B. (1) v (2) C.(1), (2) v (4) D. (2) v (4) 45.Khi in phn dung dch hn hp MgCl2, FeCl3 v CuCl2 th th t b kh catot l A. Fe3+ , Cu2+, Fe2+ , H2O B. Fe3+ , Cu2+, Mg2+ , H2O C. Cu2+,Fe3+ , Mg2+ , H2O D. 3+ 2+ 2+ 2+ Fe , Cu ,Fe , Mg 46. Cho s phn ng: C2H2 X Y CH3COOH. Trong s cc cht C2H6, C2H4, CH3CHO, CH3COOCH=CH2 th s cc cht ph hp theo s trn l A. 3 B. 4 C.2 D.1 47. Dy gm cc hidrocacbon tc dng vi Clo theo t l s mol 1:1 (chiu sng) u thu c 4 dn xut monoclo l A. Metylxiclopentan v isopentan B. 2,2-imetylpentan v 2,3imetylbutan C. isopentan v 2,2-imetylbutan D. 2,3-imetylbutan v metylxiclopentan. 48. Hn hp X gm HCHO v CH3CHO. d X / Y = a khi xy ha (hiu sut 100%) m gam X thu c hn hp Y gm 2 axit tng ng c , gi tr ca a l A. 1,36 < a < 1,53 B. 1,26 < a < 1,47 C. 1,62 < a < 1,75 D. 1,45 < a < 1,50 49.Trong dy cc cht sau, cht no l polime A. Sacaroz, PE, t tm, protein B. vi, cht bo, du n, glucoz, du ho C. X phng, protein, cht bo, xenluloz, t nhn to. D. Tinh bt, xenluloz, cao su, t, PVC 50. Hn hp M gm hai cht CH3COOH v NH2CH2COOH. trung ho m gam hn hp M cn 100ml dung dch HCl 1M. Ton b sn phm thu c sau phn ng li tc dng va vi 300ml dung dch NaOH 1M. Thnh phn phn trm theo khi lng ca cc cht CH3COOH v NH2CH2COOH trong hn hp M ln lt l (%)

A. 40 v 60 55,56

B. 72,8 v 27,2

C. 61,54 v 38,46

D. 44,44 v

Phn B Theo chng trnh nng cao, 10 cu, t cu 51 n 60 51. Ho tan 2,7 gam bt Al vo 100 ml dung dch gm NaNO3 0,3M v NaOH 0,8M, sau khi kt thc phn ng thu c V lit hn hp kh ktc. Gi tr ca V l A. 1,344 B. 1,008 C. 0,672 D. 1,512 52. Cho mi cht CH3I (X), HCl (Y), nc brom (Z), NaNO2/HCl (T) tc dng vi anilin. Cc cht phn ng c vi anilin l A. X,Y,Z v T B. Y,Z v T C. Y v Z D. Z 53. Trong s cc phn t amiloz cc mt xch glucoz lin kt vi nhau bng lien kt no sau y A. - 1,6-glicozit B. - 1,4-glicozit C. - 1,6-glicozit D.- 1,4-glicozit 54. Hai este A, B l ng phn ca nhau v u do axit cacboxylic no, n chc v ru no n chc to thnh. x phng ha 33,3 gam hn hp hai este trn cn va 450ml dung dch NaOH 1M. Tn gi ca 2 este l A. etylaxetat v propyl fomat B. Metylaxetat v metylfomat C. Butylfomat v etyl propyonat D. etyl fomat v metyl axetat 55. Sn phm trung ngng axit -amino anantoic v axit -amino caproic ln lt l A. v B. v [ HN [CH 2 ]6 7 4 3CO-] n C. v D. v [ HN [CH 2 ]65CO-] n CO Mg ,ete HCl C2 H 5 Br A B C 56. Cho s sau . Cng thc ca C l A. CH3CH2COOH B. . CH3COOH C. . CH3CH2OH D. . CH3CH2CH2COOH 57.Cho cc cht sau: axit glutamic, valin, glin, alanin, trimetylamin, anilin. S cht lm qu tm chuyn mu hng, xanh, khng i mu ln lt l A. 1,2,3 B. 2,1,3 C. 3,1,2 D. 1,1,4 58. thc hin s chuyn ha sau axit axetic axit cloaxetic glyxin. Cn thm cc cht phn ng no di y. A. Clo v amin B. HCl v mui amoni C. Clo v amoniac D. Hidro v amoniac 59. Ch s iod ca triolein l A. 28,73 B. 287,30 C. 86,20 D. 862,00 60. Phn ng no sau y khng xy ra A. (NH4)2Cr2O7 Cr2O3 + N2 + 4 H2O B. Fe2O3 + 6HI 2FeI3 + 3 H2O C. 3CuO + 2NH3 3Cu + N2 + 3H2O D. 2CrO3 + 2NH3 Cr2O3 + N2 + 3H2O.
2

 S 15

TRNG THPT CHUYN H TNH

THI TH I HC CAO NG Lp : 12 Mn thi : Ho Hc Thi gian lm bi : 90 pht S cu trc nghim : 50 cu thi c 4 trang M thi: 001

H , tn th sinh:. S bo danh:

Cu 1. Cho lung kh H2 i qua 14,4gam MO (M l kim loi) nung nng thu c 12,8gam hn hp X. Cho hn hp X tan ht trong dung dch HNO3 d, sn phm kh thu c l 4,48 lt (ktc) hn hp kh Y(gm NO v NO2). T khi ca Y so vi H2 l 19. Cng thc phn t ca MO l: A. CuO. B. FeO. C. ZnO. D. C A,B,C u sai. Cu 2. Cho a gam hn hp Fe,Cu (trong Cu chim 44% v khi lng) vo 500ml dd HNO3, un nng. Sau khi phn ng xy ra hon ton thu c 4,48 lt (ktc) kh NO(sn phm kh duy nht), cht rn c khi lng 0,12a gam v dung dch X. Gi tr ca a l: A. 15. B. 20. C. 25. D. 30. Cu 3. Ha tan hon ton 17,4 gam hn hp Al,Fe,Cu c s mol bng nhau trong dung dch HNO3. Sau khi kt thc phn ng thu c 5,6 lt (ktc) kh NO (sn phm kh duy nht) v dung dch X. Lm kh dung dch X thu c m gam mui khan. Gi tr ca m l: A. 63,9. B. 67. C. 60,8. D. 70,1. Cu 4. Nung 13,6 gam hn hp Mg, Fe trong khng kh mt thi gian thu c hn hp X gm cc oxit c khi lng 19,2gam. ha tan hon ton X cn V ml dd HCl 1M ti thiu l: A. 800ml. B. 600ml. C. 500ml. D. 700ml. Cu 5. t chy hon ton m gam hn hp 2 ru ng ng lin tip thu c 0,33 gam CO2 v 0,225
gam H2O.Nu tin hnh xi ho m gam hn hp trn bng CuO th khi lng andehit to thnh ti a l: A. 0,185g B. 0,205g C. 0,195g D. 0,215g

Cu 6. S ng phn ng vi cng thc phn t ca C2H2ClF l A. 2 B. 3 C. 5 D. 4 Cu 7. Cho 3 axit: axit fomic, axit axetic v axit acrylic. nhn bit 3 axit ny ta dng: A. dd AgNO3/ NH3, nc brom. B. dd AgNO3/ NH3, qu tm C. Na, nc brom D. Nc brom, qu tm Cu 8. Hirocacbon X c cng thc phn t C8H10 khng lm mt mu dd brom. Khi un nng X trong dd thuc tm to thnh hp cht C7H5KO2 (Y). Cho Y tc dng vi dd axit clohiric to thnh hp cht C7H6O2. Tn ca X l: A. 1,3-imetylbenzen. B. etylbenzen. C. 1,4-imetylbenzen. D. 1,2imetylbenzen. Cu 9. Khi sc kh clo vo nc th thu c nc clo. Nc clo l hn hp gm cc cht: A. Cl2 v H2O B. Cl2, HCl, H2O v HClO C. HCl, HClO3 v H2O D. HCl v HClO. Cu 10. Cho 6,5gam Zn vo 120ml dd HNO3 1M v H2SO4 0,5M thu c NO (sn phm kh duy nht) v dung dch cha x gam mui. Sau em c cn dung dch c y gam mui khan, th

A. x > y. B. x < y. C. x=y. D. C A,B,C u sai. Cu 11. Chia m gam 1 este E thnh 2 phn bng nhau Phn 1 t chy hon ton thu c 4.48 lt kh CO2 (dktc) v 3.6 gam H2O Phn 2 tc dng va vi 100ml dd NaOH 0.5M. Gi tr ca m l A. 3.6 B. 4.4 C. 7.2 D. 8,8 Cu 12. t chy hon ton 0,1 mol hn hp gm etilen v ancol n chc X thu c 4,48 lt kh CO2 v 4,5 gam nc. X thuc loi A. no, n chc, mch h. B. khng no, n chc, mch h. C. no, n chc, mch vng D. khng no, n chc, mch vng. Cu 13.
H SO , ,t Cho cn bng ha hc sau: CH3COOH + C2H5OH CH3COOC2H5 + H2O Nhn xt no ng v cn bng trn? A. Sn phm ca phn ng trn c tn l etyl axetic B. cn bng trn xy ra theo chiu thun c th dng d axit axetic hoc ancol etylic C. Axit H2SO4 ch gi vai tr xc tc. D. Nhm OH ca ancol kt hp vi H ca axit to ra nc.
2 4 0

Cu 14. Khi un nng ancol X no, n chc. mch h vi axit H 2SO4 thu c cht hu c Y. T khi hi ca X so vi Y bng 0,62. Cng thc phn t ca X l : A. CH4O. B. C2H6O. C. C3H8O. D. C4H10O. Cu 15. t chy hon ton 7,2 gam mt axit cacboxylic X mch thng thu c 13,2 gam CO 2 v 3,6 gam H2O. Cng thc phn t ca X l: A. C2H4O2. B. C3H6O2. C. C6H8O4. D. C6H12O2. Cu 16. Sc kh CO2 vo dung dch natri phenolat ta thy c hin tng:
A . Dung dch vn trong sut do khng xy ra phn ng. B . Dung dch ha c do phenol sinh ra t tan trong nc. C . Dung dch ha c do c NaHCO3 sinh ra. D . Si bt kh do phn ng c sinh ra kh.

Cu 17. O Cho s chuyn ha sau: Tn ca X l: C2H4 X A. andehit axetic. B. axit axetic. O C. etylen glicol. D. axit oxalic. Cu 18. Trn 200 ml dung dch gm HCl 0,1M v H2SO4 0,05 M vi 300 ml dung dch Ba(OH)2 a M thu c m gam kt ta v 500 ml dung dch c pH=13. Cc gi tr a, m tng ng l: A. 0,25 v 4,66 B. 0,15 v 2,33 C. 0,15 v 3,495 D. 0,2 v 2,33 Cu 19. Cht X: C2H7NO2. A tc dng vi dung dch HCl v dung dch NaOH. X thuc loi hp cht A. Mui B. Aminoaxit C. C A v B D. Tt c u sai + NaOH + Cu ( NO ) Cu 20. Cho s phn ng sau: H2S X
3 2

Y Z.

X, Y, Z l cc hp cht cha lu hunh. X,Y,Z l : A. Na2S, NaHS, CuS2. B. Na2S, NaHS, CuS. C. NaHS, Na2S, CuS. D. NaHS, Na2S, CuS2. H O Cu 21. Cho s phn ng sau: S X + H2S X l: A. Na2S. B. CaS. C. Na2S2O3. D. Al2S3. Cu 22. Cho dung dch X cha 0,1 mol FeCl2, 0,2 mol FeSO4. Th tch dung dch KMnO4 0,8M trong H2SO4 long va oxi ha ht cc cht trong X l: A. 0,075 lt. B. 0,125 lt. C. 0,3 lt. D. 0,03 lt. Cu 23. kt ta hon ton hidroxit c trong dung dch A cha 0,1 mol FeSO4 v 0,1 mol CuCl2 cn V ml dung dch Ba(OH)2 0,1M + NaOH 0,2M thu c kt ta B. Nung B nhit cao n khi lng khng i th thu c cht rn c khi lng l: A. 15,2 gam. B. 39,3 gam. C. 16,0 gam. D. 38,5 gam. Cu 24. Bit rng 5,668gam cao su Buna-S phn ng va ht vi 3,462gam Brom trong dung mi CCl4. T l s mt xch butaien : stiren trong cao su Buna-S l: A. 1:2. B. 2:1. C. 2:3. D. 1:3. Cu 25. Hai hirocacbon X,Y c cng cng thc phn t C5H8. X l monome dng iu ch caosu, Y c mch cacbon phn nhnh v tc dng vi dd AgNO3 trong NH3 to kt ta mu vng nht. Tn gi ca X,Y ln lt l: A. isopren v 2-metylbutin-3. B. isopren v 3-metylbutin-1. C. 2-metylbutaien-1,3 v 2-metylbutin-3. D. isopentan v 3-metylbutin-1. Cu 26. Cho hn hp gm 6,4gam Cu v 5,6gam Fe vo cc ng dung dch HCl long d. tc dng ht vi cc cht c trong cc sau phn ng vi dung dch HCl (sn phm kh duy nht l NO), cn t nht khi lng NaNO3 l A. 8,5gam. B. 17gam. C. 5,7gam. D. 2,8gam. Cu 27. Cho 18,32 gam axit picric vo mt bnh ng bng gang c dung tch khng i 560cm3(khng c khng kh), ri gy n 19110C. p sut trong bnh ti nhit l P atm, bit rng sn phm n l hn hp CO, CO2, N2, H2 v p sut thc t nh hn p sut l thuyt 8%. P c gi tr l A. 207,365. B. 211,968. C. 201,000. D. 223,635. Cu 28. Thc hin phn ng este ha gia ru butantriol 1,2,4 v hn hp 2 axit CH3COOH v HCOOH th thu c ti a dn xut ch cha chc este l A. 5 B. 6 C. 7 D. 8 Cu 29. Cht no sau y khi phn ng vi H2O khng to ru etylic A. C2H5ONa. B. C2H4. C. CH3COOC2H5. D. C2H2. Cu 30. Dung dch A cha a mol Na+, bmol NH4+, c mol HCO3-, d mol CO32-, e mol SO42-. Thm dn dn dung dch Ba(OH)2 f M n khi kt ta t gi tr ln nht th dng ht V ml dd Ba(OH)2. C cn dung dch sau khi cho V ml dd Ba(OH)2 trn th thu c s gam cht rn l: A. 35b gam. B. 40a gam. C. 20a gam. D. c A,B,C u sai. Cu 31. Cho 1 mol KOH vo dd cha m gam HNO3 v 0,2 mol Al(NO3)3. thu c 7,8 gam kt ta th gi tr ca m l: A. 18,9gam. B. 19,8gam. C. 18,9 gam hoc 44,1 gam. D. 19,8gam hoc 44,1gam. Cu 32. Oxi ha 4,6 gam hn hp hai ru no n chc mch h thnh andehit th dng ht 8 gam CuO. Cho ton b andehit tc dng vi Ag2O/NH3 d thu c 32,4 gam Ag (hiu sut phn ng l 100%). Cng thc ca hai ru l: A. CH3OH v C2H5OH. B. C2H5OH v CH3CH2CH2OH. C. C3H7CH2OH v C4H9CH2OH. D. CH3OH v C2H5CH2OH Cu 33. Dung dch A cha 0,02mol Fe(NO3)3 v 0,3mol HCl c kh nng ha tan c Cu vi khi lng ti a l: A. 7,20gam. B. 6,40gam. C. 5,76gam. D. 7,84gam. Cu 34. Mt hn hp X gm Cl2 v O2. X phn ng va ht vi 9,6gam Mg v 16,2 gam Al to ra 74,1 gam hn hp mui Clorua v oxit. Thnh phn % theo th tch ca Cl2 trong X l A. 50%. B. 55,56%. C. 66,67%. D. 44,44%. Cu 35. Nung nng hn hp gm 0,5mol N2 v 1,5mol H2 trong bnh kn (c xc tc) ri a v nhit t0C thy p sut trong bnh lc ny l P1. Sau cho mt lng d H2SO4 c vo bnh (nhit lc ny
2

trong bnh l t0C) n khi p sut n nh th thy p sut trong bnh lc ny l P2 (P1 = 1,75P2). Hiu sut tng hp NH3 l: A. 65%. B. 70%. C. 50%. D. 60%.

Cu 36. Mt hn hp X gm hai cht hu c. X phn ng va vi 200ml dd KOH 5M sau phn ng thu c hn hp hai mui ca hai axit no n chc v mt ru no n chc Y. Cho Y tc dng vi Na d thu c 6,72 lt H2 ktc. Hai cht hu c trong X l A. mt axit v mt ru. B. hai este. C. mt este v mt ru. D. mt axit v mt este. Cu 37. Hp th 4,48 lt (ktc) kh CO2 vo 0,5 lt dung dch NaOH 0,4M v KOH 0,2M th thu c dd X. Cho X tc dng vi 0,5 lt dd Y gm BaCl2 0,3M v Ba(OH)2 0,025M. Kt ta thu c l A. 19,700 gam. B. 39,400 gam. C. 24,625gam. D. 32,013gam. Cu 38. Cho bt Ag c ln Fe v Cu. tch Ag tinh khit (c khi lng khng thay i so vi ban
u) ra khi hn hp ban u th cn dng dung dch l: A. HNO3 d B. H2SO4 c, d. C. AgNO3 d. D. FeCl3 d Cu 39. Mt este ti a ba chc c to ra t mt axit v ru n chc. Khi thy phn este ny thu c 1,24 gam hn hp hai ru ng ng. Khi ha hi 1,24 gam hn hp hai ru th th tch thu c bng th tch ca 0,96 gam O2 cng iu kin. Hai ru trong hn hp l: A. c th l CH3OH v C2H5OH hoc CH3OH v C3H7OH. B. Ch c l CH3OH v C2H5OH. C. c th l CH3OH v C2H5OH hoc C2H5OH v C3H7OH. D. Ch c l CH3OH v C3H7OH.

Cu 40.

Ha tan hon ton 21 gam hn hp hai kim loi (Al v mt kim loi kim M) vo nc d th thu c dd B v 11,2 lt kh H2 ktc. Cho t t dd HCl vo dd B thy thu c kt ta ln nht l 15,6gam. Kim loi M l: A. Na. B. Li. C. Cs. D. K. Cu 41. Ha tan ht 0,3mol Fe bng mt lng dd HNO3 thu c V lt kh NO l sn phm kh duy nht ktc. V c gi tr nh nht l: A. 13,44. B. 4,48. C. 8,96. D. 6,72. Cu 42. Cho bn cht X,Y,Z,T c cng thc l C2H2On (n ( 0). X, Y, Z u tc dng c dd AgNO3/NH3; Z, T tc dng c vi NaOH; X tc dng c H2O. X, Y, Z, T tng ng l A. HOOC-COOH; CH(CH; OHC-COOH; OHC-CHO. B. OHC-CHO; CH(CH; OHC-COOH; HOOC-COOH. C. OHC-COOH; HOOC-COOH; CH(CH; OHC-CHO. D. CHCH; OHC-CHO; OHC-COOH; HOOC-COOH. Cu 43. Mt hn hp X gm mt Hidrocacbon mch h (A) c hai lin kt ( trong phn t v H2 c t khi so vi H2 bng 4,8. Nung nng X vi xc tc Ni phn ng xy ra hon ton ta thu c hn hp Y c t khi so vi H2 bng 8. Cng thc v thnh phn % theo th tch ca (A) trong X l A. C3H4; 80%. B. C3H4; 20%. C. C2H2; 20%. D. C2H2;80%. Cu 44. Cho cc cht sau: H2N-CH2COOCH3; Al(OH)3; H2NCH2COOH;(NH4)2CO3. Cht khng phi l cht lng tnh l: A. (NH4)2CO3. B. H2NCH2COOH. C. Al(OH)3. D. H2N-CH2COOCH3. Cu 45. Cho cc dung dch sau: (1): dd C6H5NH2; (2): dd CH3NH2; (3): dd H2N-CH2COOH; (4): dd C6H5ONa; (5): dd Na2CO3; (6): dd NH4Cl. Dung dch lm xanh qu tm l: A. (2); (5). B. (3); (4); (6). C. (2); (4); (5). D. (1); (2); (4); (5). Cu 46. Mt axit c cng thc n gin nht C2H3O2 th c cng thc phn t l: A. C2H3O2. B. C4H6O4. C. C6H9O6. D. C8H12O8 Cu 47. X l cht lng khng mu, khng lm i mu cht ch th phenolphtalein. X tc dng c vi dd Na2CO3, dd NaOH v dd AgNO3/NH3. X c cng thc cu to l: A. HCHO. B. HCOOCH3. C. CH3COOH. D. HCOOH. Cu 48. Gia Saccaroz v glucoz c c im ging nhau l: A. u c ly t c ci ng. B. u c trong bit dc huyt thanh ngt

C. u b oxi ha bi dd Ag2O/NH3. D. u ha tan Cu(OH)2 nhit thng cho dd mu xanh lam. Cu 49. Cho cc cht sau: CH3COOH, CH2=CHCOOH, CH2=CHOOCCH3, CH2OH-CH2OH, CHCl3, HOOC(CH2)4COOH, HCHO. S cht c th to thnh polime bng phn ng trng hp hoc trng ngng l: A. 7. B. 6. C. 5. D. 4. Cu 50. phn bit cc cht rn ring bit sau: FeS, FeS2, FeCO3, Fe2O3 ta c th dng: A. dd HNO3. B. dd H2SO4 c nng. C. dd HCl. D. dd NaOH.

 16 ( thi c 05 trang)

THI TH VO I HC, CAO NG Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao )

PHN CHUNG: (44 cu t cu 1 n cu 44) 1. Trong cc kiu mng tinh th kim loi, kiu mng c cu trc km c kht nht l : A. lp phng tm din. B. lp phng tm khi. C. lc phng (lng tr lc gic u). D. lp phng tm din v lp phng tm khi. 2. Dy so snh tnh cht vt l ca kim loi no di y l KHNG ng ? A. Kh nng dn in v nhit ca Ag > Cu > Au > Al > Fe B. T khi ca Li < Fe < Os. C. Nhit nng chy ca Hg < Al < W D. Tnh cng ca Cs > Fe > Cr 3. Ln lt cho tng kim loi Mg, Ag, Fe v Cu (c s mol bng nhau), tc dng vi lng d dung dch H2SO4 c nng. Khi phn ng hon ton th th tch SO 2 thot ra t nht (trong cng iu kin) l t kim loi : E. Mg B. Fe C. Cu D. Ag
4. Pht biu no di y khng hon ton ng ? A. Cc kim loi kim gm H, Li, Na, K, Rb, Cs v Fr. B. Kim thoi kim thuc PNC nhm I (nhm IA) trong bng tun hon. C. Cc kim loi kim u c cu hnh electron ha tr l ns1. D. Trong hp cht, kim loi kim c mc oxi ha +1. 5. in phn nng chy mui clorua kim loi kim, thu c 0,896 L kh (ktc) v 3,12 g kim loi. Cng thc mui l : A. LiCl. B. NaCl. C. KCl. D. RbCl. 6. M t ng dng ca Mg no di y KHNG ng ? A. Dng ch to dy dn in. B. Dng to cht chiu sng. C. Dng trong cc qu trnh tng hp hu c. D. Dng ch to hp kim nh, cn cho cng nghip sn xut my bay, tn la, t. 7. Cho cc phn ng m t cc phng php khc nhau lm mm nc cng (dng M2+ thay cho Ca2+ v Mg2+) : t (2) M2+ + + OHMCO3 + H2O (1) M2+ + 2MCO3 + H2O + CO2 HCO 3 3 2 (3) M2+ + MCO3 (4) CO 3M2+ + 2 M3(PO4)2 PO 3 4 Phng php no c th p dng vi nc c cng tm thi ? A. (1) B. (2) C. (1) v (2) D. (1), (2), (3) v (4)

8. Dung dch ca cht no di y lm qu tm i mu xanh ? A. kali sunfat B. phn chua KAl(SO4)2.12H2O C. natri aluminat D. nhm clorua 9. Ha tan hon ton m gam Al vo dung dch HNO 3 long, d thu c 672 mL (ktc) kh N2 (khng c sn phm kh no khc). Gi tr m bng : A. 0,27 gam B. 0,81 gam C. 1,35 gam D. 2,70 gam
10. Nhng thanh Fe vo dung dch CuSO4, sau mt thi gian quan st thy : A. thanh Fe c mu trng hi xm v dung dch nht mu xanh. B. thanh Fe c mu v dung dch nht mu xanh. C. thanh Fe c mu trng hi xm v dung dch c mu xanh. D. thanh Fe c mu v dung dch c mu xanh.

11. Nhn xt v tnh cht ha hc ca cc hp cht Fe (III) no di y l ng (ch xt tnh cht ca nguyn t Fe) ? Hp cht Tnh axit - baz Tnh oxi ha - kh A. Fe2O3 Axit Ch c tnh oxi ha B. C. D. Fe(OH)3 FeCl3 Fe2(SO4)3 Baz Trung tnh Axit Ch c tnh kh Va oxi ha va kh Ch c tnh oxi ha

12. T mui n KHNG th trc tip iu ch cht, hoc hn hp cht no di y ? A. NaClO B. H2, Cl2 v NaOH C. Na v Cl2 D. Na2O2 13. Di y l mt s cch c ngh pha long H2SO4 c :

Cch pha long no m bo an ton th nghim ? A. Cch 1 B. Cch 2 C. Cch 3

D. Cch 1 v 2

14. Dn 6,72 L (ktc) hn hp A gm hai anken l ng ng k tip vo bnh nc brom d, thy khi lng bnh tng thm 15,4 g. Cng thc ca hai anken l : A. C2H4 v C3H6 B. C3H6 v C4H8 C. C4H8 v C5H10 D. C5H10 v C6H12 15. Thi hn hp gm 0,01 mol CH4, 0,02 mol C2H4 v 0,03 mol C2H2 ln lt i qua bnh (1) cha dung dch AgNO3 trong NH3 d; bnh (2) cha dung dch Br2 d. tng khi lng ca cc bnh ln lt l : (1) (2) (1) (2) A. 0 gam 1,34 gam B. 0,78 gam 0,56 gam C. 0,16 gam 1,34 gam D. 0,78 gam 0,16 gam

16. Tnh lng glucoz dng to ra 1,82 gam socbitol vi hiu sut 80%. A. 2,25 gam B. 1,44 gam C. 22,5 gam D. 14,4 gam 17. T 10 kg go np (c 80% tinh bt), khi ln men s thu c bao nhiu lt cn 96 o ? Bit hiu sut qu trnh ln men t 80% v khi lng ring ca ru (ancol) etylic l 0,807 g/ml C. 4,3 lt A. 4,7 lt B. 4,5 lt D. 4,1 lt 18. Loi polime no di y khng c ngun gc l xenluloz ? 1. T visco B. T ng amoniac C. Xenluloz triaxetat D. T lapsan 19. Cc gii thch quan h cu trc - tnh cht no sau KHNG hp l ? a. Do c cp electron t do trn nguyn t N m amin c tnh baz. b. Do nhm NH2 y electron nn anilin d tham gia phn ng th vo nhn thm hn v u tin v tr o-, p-. c. Tnh baz ca amin cng mnh khi mt electron trn nguyn t N cng ln. d. Vi amin RNH2, gc R ht electron lm tng mnh tnh baz v ngc li. 20. Cho 0,1 mol A (-amino axit dng H 2NRCOOH) phn ng ht vi HCl to 11,15 gam

mui. A l : A. glixin. B. alanin. C. phenylalanin. D. valin. 21. ng dng no ca amino axit di y c pht biu KHNG ng ? i. Amino axit thin nhin (hu ht l -amino axit) l c s kin to protein ca c th sng. ii. Mui inatri glutamat l gia v thc n (gi l bt ngt hay m chnh). iii. Axit glutamic l thuc b thn kinh, methionin l thuc b gan. iv. Cc amino axit (nhm amin v tr s 6, 7, ...) l nguyn liu sn xut t nilon. 22. Polime no di y c cng cu trc mch polime vi nha bakelit ? 1. amiloz B. glicogen C. cao su lu ha D. xenluloz 23. Hp cht no di y KHNG th tham gia phn ng trng hp ? a. Axit -amino enantoic B. Caprolactam C. Metyl metacrylat D. Butaien-1,3 (Buta-1,3-ien)
24. Trng hp no di y c s ph hp gia cu to ca ancol v tn gi thng thng ? A. CTCT ca ancol CH3CH2CH2CH2OH CH3 CH CH2OH CH3 tn gi ancol t-butylic B. CTCT ca ancol CH3 CH2 CH CH3 OH ancol n-butylic D. CH3 OH C CH3 25. C cc ru (ancol) CH3OH, CH3CH2OH, CH3CH(OH)CH3 v (CH3)3COH. Cht tham gia phn ng este ha vi HCl d dng nht l : A. CH3OH B. CH3CH2OH C. CH3CH(OH)CH3 D. (CH3)3COH 26. Hin tng ca th nghim no di y c m t KHNG ng ? A. Cho Br2 vo dung dch phenol xut hin kt ta mu trng. B. Cho qu tm vo dung dch phenol, qu chuyn qua mu . C. Cho phenol vo dung dch NaOH lc u phn lp, sau to dung dch ng nht. D. Thi kh CO2 qua dung dch natri phenolat xut hin vn c mu trng. 27. Cng thc no di y KHNG ng ? dy ng ng ankanal ankanial cng thc CnH2n+1CHO CnH2n1(CHO)2 B. D. dy ng ng ankenal ankenial cng thc CnH2n1CHO CnH2n2(CHO)2 CH3 tn gi ancol sbutylic ancol ibutylic

C.

A. C.

28. Cho 10 gam fomon tc dng vi lng d AgNO3/NH3 thy xut hin 54 gam kt ta. Nng phn trm ca dung dch ny bng : A. 37,0%. B. 37,5%. C. 39,5%. D. 75,0%. 29. Phng trnh ho hc biu din phn ng este ha no di y c vit ng ? O CH3 H2SO4 O C2H5 C CH=CH A. CH3COOH + CH3CH2OH H2SO4 +2H2O H SO 2 4CH B. CH3COOH + CH2=CHOH C +O H2O 3 C. (COOH)2 + 2CH3CH2OH H2SO4 (COOC2O H5)2 + 2H 2 O H ) + 2H O CH3(COOC 2 4 2 2 30. Phn ng ca D. 2CH3COOH + C2H4(OH)2 cp cht no di y to sn phm l mui v ancol ? A. CH3COOCH=CH2 (vinyl axetat) + dung dch t NaOH 360 C , 315 atm B. C6H5Cl (phenyl clorua) + NaOH t C. CH3COOC6H5 (phenyl axetat) + dung dch NaOH
o

D. HCOOCH2-CH=CH2 (anlyl fomiat) + dung t dch NaOH 31. Chn cc cm t thch hp in vo cc ch trng trong nh ngha : Cht bo l trieste (este ba chc) ca ..... (1) ..... v cc ..... (2) ...... (1) (2) (1) A. glixerin axit bo B. etilenglicol (glixerol) (etylen glicol) B. glixerin axit cao no D. etilenglicol (glixerol) (etylen glicol)

(2) axit bo axit cao no

32. Nhit phn cng s mol mi mui nitrat di y, th trng hp no sinh ra th tch kh O2 nh nht (trong cng iu kin) ? i. KNO3 B. Fe(NO3)2 C. Fe(NO3)3 D. AgNO3 33. Gii php no di y KHNG th lm mm nc c cng tm thi ? A. un nng B. thm dung dch NaOH C. thm dung dch Na3PO4 D. thm dung dch HCl 34. Trong phn ng no di y, nc ng vai tr cht oxi ha ? as t A. C + 2H2O CO2 + H2 B. Cl2 + H2O 2HCl + 1/2O2 pdd C. H2O H2 + 1/2O2 D. + 2H2O H3O + OH 35. Ha tan hn hp gm 16,0 gam Fe2O3 v 6,4 gam Cu bng 300 mL dung dch HCl 2M. Khi phn ng xy ra hon ton, th khi lng cht rn cha b ha tan bng : A. 0,0 gam. B. 3,2 gam. C. 5,6 gam. D. 6,4 gam.
36. phn bit bn bnh mt nhn ng ring cc kh CO2, SO3, SO2 v N2, mt hc sinh d nh dng thuc th (mt cch trt t) theo bn cch di y. Cch no ng ? A. dung dch BaCl2, dung dch Br2 v dung dch Ca(OH)2. B. dung dch Ca(OH)2, dung dch Ba(OH)2 v dung dch Br2. C. qu tm m, dung dch Ca(OH)2 v dung dch Br2. D. dung dch Br2, dung dch BaCl2 v que m. 37. Thi mt hn hp kh gm CO2, CO, N2, H2O (hi) v H2 ln lt vo ng ng lng d CuO nng, bnh cha dung dch nc vi d v bnh cha lng d dung dch H2SO4 c. Kh ra khi bnh cha H2SO4 l : A. CO. B. N2. C. H2. D. H2O.

38. un nng cht hu c A vi axit sunfuric c th to ra sn phm, m khi cho tc dng vi dung dch NaOH th to kh mi khai. Cn nu t chy A, ri hp th sn phm vo dung dch AgNO3 th thy xut hin kt ta trng. Cht A ny chc chn cha cc nguyn t : A. N v Cl. B. C, N v Cl. C. C, H, N v Cl. D. C, H, O, N v Cl. 39. t chy hon ton 200 mL hp cht hu c X (cha C, H, O) vi 1200 mL kh O 2 (ly d). Sau phn ng th tch kh cn 1700 mL, sau khi qua dung dch H 2SO4 c cn 900 mL v sau khi qua KOH cn 100 mL. Xc nh cng thc phn t ca X, bit cc th tch kh o trong cng iu kin. A. C4H8O2 B. C3H8O C. C3H6O2 D. C4H8O 40.S ng phn cu to ca axit cacboxylic v este c cng cng thc C4H8O2 bng : A. 3 B. 4 C. 5 D. 6 41. Xt cc phn ng : Ni,t (1) CH3CHO + H2 CH3CH2OH (2) CH3CHO + H2O CH3CH(OH)2 2+ Mn ,t (3) CH3CHO + O2 CH3COOH (4) CH3CHO + CH3OH CH3CH(OH)OCH3 Phn ng m trong anehit axetic ng vai tr cht oxi ha l : A. (1) B. (2) C. (3) D. (4)

NaOH,t,p Cl2 CO ,Fe,1 :1 42. Cho dy chuyn ha : Benzen X 2 Y Z Z l hp cht thm c cng thc : B. C6H5OH B. C6H5CO3H C. O2CC6H4ONa D. C6H5ONa

43. phn bit cc cht anilin, phenol v benzen, KHNG nn dng cc thuc th (theo trt t) di y : A. dung dch NaOH, dung dch Br2. B. dung dch HCl, dung dch Br2. C. dung dch NaOH, dung dch HCl. D. dung dch Br2, dung dch NaCl.

44. Trong s cc hp cht FeO, Fe 3O4, Fe2O3 v FeCO3, th cht ch th hin mt tnh (hoc tnh kh, hoc tnh oxi ha ch xt vai tr ca nguyn t st) trong phn ng oxi ha kh l A. FeO. B. Fe3O4. C. Fe2O3. D. FeCO3. PHN RING (th sinh ch c lm mt trong hai phn: phn I hoc phn II) Phn I: dnh cho th sinh chng trnh phn ban (6 cu- t cu 45 n cu 50)
45. Lng Cl2 v NaOH tng ng c s dng CrO2 oxi ha hon ton 0,01 mol CrCl3 thnh l : 4 A. 0,015 mol v 0,04 mol B. 0,030 mol v 0,16 mol A. 0,015 mol v 0,10 mol D. 0,030 mol v 0,14 mol 46. Ha tan 10 gam ng thau (hp kim Cu-Zn; Cu chim 55% khi lng; gi thit khng c tp cht khc) vo dung dch HCl d. Th tch kh thu c (ktc) bng : A. 1,55 lt. B. 1,89 lt. C. 1,93 lt. D. 3,47 lt. 47. kh ht lng trong dung dch, phi Au(CN) 2 dng n 0,65 gam Zn. Lng Au kim loi sinh ra t phn ng ny bng : A. 0,985 gam. B. 1,970 gam. C. 2,955 gam. D. 3,940 gam. o 48. Cho = 0,76V, = 0,13V. Xc nh E 2+
Pb / Pb Zn sut in ng chun ca pin in ha Zn Zn-Pb A. + 0,63V B. 0,63V C. 0,89V

D. + 0,89V

49. Thm dung dch Br2 ln lt vo bn mu th cha cc dung dch fructoz, saccaroz, mantoz v dung dch h tinh bt. Mu th c kh nng lm nht mu dung dch Br2 l : A. dung dch fructoz. B. dung dch mantoz. C. dung dch saccaroz. D. dung dch h tinh bt. 50. phn bit cc dung dch Al(NO3)3 v Zn(NO3)2, tt nht nn dng thuc th : A. dung dch NaOH. B. dung dch NH3. C. dung dch HCl. D. dung dch Ba(OH)2.

Phn II: dnh cho th sinh chng trnh khng phn ban (6 cu-t cu 51 n cu 56) 51. Trn 100 mL dung dch FeCl2 2 M vi 100 mL dung dch NaOH 2 M. Lc tch kt ta v nung kt ta trong khng kh n khi lng khng i thu c cht rn A. Khi lng ca A bng : a. 8 gam. B. 24 gam. C. 16 gam. D. 32 gam. 52. Cho 2,16 gam Al vo dung dch cha 0,4 mol HNO3 thu c dung dch A v kh N2O (khng c sn phm kh no khc). Thm dung dch cha 0,25 mol NaOH vo dung dch A th lng kt ta thu c bng : A. 3,90 gam. B. 4,68 gam. C. 5,46 gam. D. 6,24 gam. 53. Cho dy in ha :
Zn2+ Zn Fe2+ Fe Cu2+ Cu Fe3+ Fe2+ Ag+ Ag

Phn ng gia cp cht no D. Cu v

di y l khng xy ra ? A. Zn v AgNO3 B. Cu v Fe(NO3)3

C. Fe(NO3)2 v AgNO3

Fe(NO3)2 54. Khi cho toluen tc dng vi Cl2 (as) th thu c sn phm no sau y ? A. benzyl clorua B. o-metyltoluen C. p-metyltoluen D. m-metyltoluen 55. Xt mt s nhm th trn vng benzen : CH3, COOH, OCH3, NH2, COCH3, COOC2H5, NO2,
Cl, v SO3H. Trong s ny, c bao nhiu nhm nh hng th vo v tr meta ? A. 3 B. 4 C. 5 D. 6 56. H s trng hp ca loi polietilen c khi lng mol phn t 3000 g/mol bng: A. 100 B. 107 C. 115 D. 125

 17 ( thi c 05 trang)

THI TH VO I HC, CAO NG Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao )

PHN CHUNG: (44 cu t cu 1 n cu 44) Phn chung cho tt c th sinh 1. Pht biu no di y l khng ng ? A. Lin kt kim loi c hnh thnh bi lc ht tnh in gia ion dng kim loi v cc electron t do. B. Cc ion dng kim loi v electron t do u dao ng lin tc cc nt mng tinh th kim loi. C. Lin kt cng ha tr do nhng cp electron to nn, cn lin kt kim loi l do tt c cc electron t do trong kim loi tham gia. D. Lin kt ion do tng tc tnh in gia ion dng v ion m, cn lin kt kim loi l do tng tc tnh in gia ion dng v electron t do. 2. c im no di y khng tng ng vi tnh cht ha hc c trng ca kim loi l tnh kh ? A. m in ln B. Nng lng ion ha nh C. Bn knh nguyn t tng i ln D. S electron ha tr nh (t 1 n 3 electron) 3. Khi ln lt cho tng hn hp kim loi di y vo lng d nc, th khi phn ng hon ton, trng hp no thu c lng kh H2 (ktc) ln nht ? A. hn hp cha 1 mol Na v 1 mol K B. hn hp cha 1 mol Na v 1 mol Ca C. hn hp cha 1 mol Na v 1 mol Al D. hn hp cha 1 mol Na v 1 mol Fe 4. Gii thch no di y khng ng ?
A. Nguyn t kim loi kim c nng lng ion ha I1 nh nht so vi cc kim loi khc do kim loi kim c bn knh ln nht. B. Do nng lng ion ha nh nn kim loi kim c tnh kh rt mnh. C. Nguyn t kim loi kim c xu hng nhng 1 electron do I2 ca nguyn t kim loi kim ln hn nhiu so vi I1 v do ion kim loi kim M+ c cu hnh bn. D. Tinh th kim loi kim c cu trc rng do c cu to mng tinh th lp phng tm din.

5. Trn 200 ml dung dch H2SO4 0,05M vi 300 ml dung dch NaOH 0,06M. pH ca dung dch to thnh bng : A. 2,7 B. 1,6 C. 1,9 D. 2,4
6. Xc nh phn trm khi lng CaCO3.MgCO3 c trong qung lmit, bit nhit phn hon ton 40 gam qung trn thu c 11,2 L kh CO2 (0oC v 0,8 atm) A. 42% B. 46% C. 50% D. 92% 7. Dng m gam Al kh ht 1,6 gam Fe2O3 (phn ng nhit nhm). Cc cht sau phn ng nhit nhm tc dng vi lng d dung dch NaOH to 0,672 lt kh (ktc). Khi lng m bng : A. 0,540 gam. B. 0,810 gam. C. 1,080 gam. D. 1,755 gam.

8. Trng hp no di y to ra kt ta sau khi phn ng xy ra hon ton ? A. Thm d NaOH vo dung dch AlCl3 B. Thm d AlCl3 vo dung dch NaOH C. Thm d HCl vo dung dch Na[Al(OH)4] (hay NaAlO2) D. Thm d CO2 vo dung dch Ca(OH)2
9. Cu hnh electron no di y c vit ng ?

A. Fe [Ar] 4s23d6 B. Fe2+ [Ar] 4s23d4 C. [Ar] 3d44s2 D. Fe3+ [Ar] 3d5 10. Nhng thanh Fe vo 100 mL dung dch Cu(NO3)2 0,1 M. khi Cu(NO3)2 phn ng ht th thy khi lng thanh Fe : A. tng 0,08 gam B. tng 0,80 gam C. 0,08 gam D. gim 0,56 gam 11. Dung dch mui FeCl3 khng tc dng vi kim loi no y ? A. Zn B. Fe C. Cu

HF(19,5) Nhi?t ? si ( C)
o

Fe2+
HI(-35,8) HBr(-66,7) HCl(-84,9)

n gim di

H?p ch?t hiro halogenua

D. Ag

12. Di y l gin nhit si ca cc hiro halogenua, Gii thch no di y l khng ng ? A. T HCl n HI nhit si tng do khi lng phn t tng B. HF c nhit si cao nht l do to c lin kt H lin phn t C. Lin kt gia cc phn t HCl (hoc HBr, HI) l lin kt cng ha tr D. bn lin kt lin phn t nh hng n nhit si nhiu hn khi lng phn t 13. S mol H2SO4 trong dung dch H2SO4 (c, nng) dng trong phn ng no di y l nhiu nht, khi s mol cht kh trong mi phn ng l bng nhau ? A. Fe + H2SO4 B. Cu + H2SO4 C. S + H2SO4 D. HI + H2SO4 I2 + ... 14. Phn ng no di y to sn phm KHNG tun ng quy tc Mac-cp-nhi-cp ?
A. CH3CH=CH2 + HCl CH3CHClCH3 B. (CH3)2C=CH2 + HBr CH3CH(CH3)CH2Br C. CH3CH2CH=CH2 + H2O H CH3CH2CH(OH)CH3 D. (CH3)2C=CH-CH3 + HI (CH3)2CICH2CH3 15. Cho xicloankan A c kh nng lm nht mu nc brom. T khi hi ca A so vi khng kh bng 1,931. Tn gi ca A l : A. xiclopropan B. xiclobutan C. metylxiclopropan D. xiclopentan
+

16. Ln men a gam glucoz vi hiu sut 90%, lng CO2 sinh ra hp th ht vo nc vi trong thu c 10 gam kt ta v khi lng dung dch gim 3,4 gam. Khi lng a bng : A. 13,5 gam. B. 15,0 gam. C. 20,0 gam. D. 30,0 gam. 17. Th tch dung dch HNO3 96% (D = 1,52 g/mL) cn dng tc dng hon ton vi lng d xenluloz to 29,7 gam xenluloz trinitrat l : A. 12,95 ml. B. 29,50 ml. C. 2,950 ml. D. 1,295 ml. 18. Gii thch no sau y l khng ng ? 1. Rt H2SO4 c vo vi si bng, vi b en v thng ngay do phn ng : H SO (C6H10O5)n 6nC + 5nH2O 2. Rt HCl c vo vi si bng, vi mn dn ri mi bc ra do phn ng : HCl (C6H10O5)n + nH2O nC6H12O6 3. Xenluloz hnh thnh xenluloz triaxetat nh phn ng [C6H7O2(OH)3]n + 3nCH3COOH [C6H7O2(OOCCH3)3]n + 3nH2O 4. Xenluloz hnh thnh xenluloz trinitrat nh phn ng SO + 3nHONO2 [C6H7O2(ONO2)3]n + 3nH2O [C6H7O2(OH)3]n H 19. Trt t tng dn mnh tnh baz ca dy no di y KHNG ng ? a. NH3 < C6H5NH2 B. NH3 < CH3NH2 < CH3CH2NH2 C. CH3CH2NH2 < CH3NHCH3 D. p-O2NC6H4NH2 < p-CH3C6H4NH2 20. Khng nh v tnh cht vt l no ca amino axit di y KHNG ng ? A. Tt c u l nhng tinh th rn B. Tt c u c mu trng C. Tt c u tan trong nc D. Tt c u c nhit nng chy cao
2 4 2 4

21. A. 22. A. B. C. D. 23. A. C.

Trong cc protein di y, protein no tn ti dng hnh cu ? Keratin B. Mizoin C. Fibroin D. Anbumin Nhn xt v tnh cht vt l chung ca polime no di y khng ng ? Hu ht l nhng cht rn, khng bay hi. a s nng chy mt khong nhit rng, hoc khng nng chy m b phn hy khi un nng. a s khng tan trong cc dung mi thng thng, mt s tan trong dung mi thch hp to dung dch nht. Hu ht polime u ng thi c tnh do, tnh n hi v c th ko thnh si dai, bn. Hp cht hoc cp hp cht no di y khng th tham gia phn ng trng ngng ? Phenol v fomanehit B. Butaien-1,3 (Buta-1,3-ien) v stiren Axit aipic v hexametileniamin D. Axit -aminocaproic

24. Trng hp no di y khng c s ph hp gia CTCT ca ancol v nhn nh v bc ca ancol ? CTCT ca ancol bc CTCT ca ancol bc CH3OH CH3 CH CH2OH 2 A. 1 B. CH
3

C.

CH3

CH CH3 OH

D. CH3

OH C CH3 CH3

25. Ru (ancol) no di y khi oxi ha khng hon ton to sn phm l mt xeton ? i. ancol n-butylic B. ancol i-butylic C. ancol s-butylic D. ancol t-butylic 26. Phenol v anilin u c th tham gia phn ng vi cht no di y ? A. dung dch HCl B. dung dch NaOH C. dung dch Br2 D. dung dch CuSO4 27. Cng thc CnH2n-2O c th l cng thc cho dy ng ng ca anehit mch h : A. no, n chc B. no, hai chc C. cha no (1 lin kt i), n chc D. cha no (1 lin kt i), hai chc 28. C cc phn ng : Ni, to (X) RCH=O + H2 RCH2OH 2 + ,t o (Y) RCH=O + 1/2O2 RCOOH Mn (Z) RCH=O + HOH RCH(OH)2 (T) RCH=O + HSO3Na RCH(OH)SO3Na minh ha rng anehit va c tnh oxi ha, va c tnh kh, th dng cc phn ng : A. X v Y B. Y v Z C. Z v T D. Y v T 29. Bin php no di y khng lm tng hiu sut qu trnh tng hp etyl axetat t phn ng gia ru (ancol) etylic v axit axetic ? A. Dng d axit hoc ancol B. Dng H2SO4 c hp th nc C. Chng ct ui este D. Tng p sut chung ca h 30. Cht A c cng thc C11H20O4. A tc dng vi NaOH to ra mui ca axit hu c B mch thng v hai ru l etanol v propanol-2 (propan-2-ol). Cu to ca A l : A. C2H5OOC[CH2]4COOCH(CH3)2 B. (CH3)2CHOOC[CH2]3COOC2H5 C. C2H5OOC[CH2]4COOC3H7-n D. C2H5COO[CH2]4COOCH(CH3)2 31. Cht no di y thuc loi axit bo ? A. (CH3)2CH[CH2]14COOH B. HOOC[CH2]14COOH C. CH3[CH2]7CH=CH[CH2]7COOH D. CH3[CH2]15COOH

32. Nhit phn hon ton mi hp cht di y trong cc bnh kn ring bit, khng cha khng kh. Sau thm dung dch HNO 3 c nng vo sn phm rn thu c. Trng hp no c thot ra kh mu nu ?

A. 33. A. C.

Fe(NO3)2 B. Fe(OH)2 C. FeSO4 D. Fe2(SO4)3 Gii php tt nht lm mm nc c cng vnh cu l : un nng nc B. dng dung dch NaOH hoc Ca(OH)2 dng dung dch Na2CO3 hoc Na3PO4 D. dng dung dch HCl hoc NaCl
2 4

34. C bao nhiu cht v ion c th va ng vai tr ng oxi ha - kh (khng xt vai tr ca nguyn Fe2+, SO2, SO, HCl v HNO3 ?

cht oxi ha, va ng vai tr cht kh trong phn t oxi) trong s cc cht v ion sau : Na, Na+, S2-,

A. 1 B. 2 C. 3 D. 4 35. Ha tan mt hn hp bt kim loi c cha 5,6 gam Fe v 6,4 gam Cu vo 350 ml dung dch AgNO3 2M. Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c bng : A. 21,6 gam B. 43,2 gam C. 54,0 gam D. 64,8 gam
36. phn bit kh SO2 v kh CO2, th thuc th nn dng l : A. dung dch Ca(OH)2 B. dung dch nc Br2 C. dung dch BaCl2 D. dung dch Ba(OH)2 37. C mt mu SO2 b ln hi nc. c SO2 khan, th cht lm khan khng nn dng l : A. CaO B. P2O5 C. H2SO4 c D. Mg(ClO4)2

38. Nung 4,65 mg cht hu c X trong O 2 th thu c 13,20 mg CO2 v 3,16 mg H2O. Mt khc, nung 5,58 mg hp cht A vi CuO th thu c 0,67 mL kh N 2 (ktc). Hm lng % cc nguyn t C, H, O v N c trong cht X bng : %C %H %N %O %C %H %N %O A. 77,42 7,55 18,0 2,02 B. 64,52 6,29 15,01 14,18 1 C. 77,42 7,55 15,0 0,02 D. 64,52 6,29 18,01 11,18 1 39. Cp cht no di y l ng ng ? A. propen (C3H6) v xiclobutan (C4H8) B. butaien-1,3 (buta-1,3-ien) (C4H6) v propin (C3H4) C. n-butan (C4H10) v i-butan (C4H10) D. benzen (C6H6) v cumen (C9H12) 40. S ng phn cu to ng vi cng thc phn t C3H8O bng : A. 2 B. 3 C. 4 D. 5 41. Ha tan hn hp cha 0,1 mol HCHO v 0,1 mol HCOOH vo lng d dung dch AgNO3/NH3. Khi phn ng xy ra hon ton, khi lng Ag thu c bng : A. 21,6 gam B. 43,2 gam C. 64,8 gam D. 86,4 gam Y 42. Cho dy chuyn ha iu ch ancol etylic : + NaOH Pht biu no di y l ng ? + + H2, xt, t + H2O, H A. X l C6H12O6 (glucoz) B. Y l X C2H5OH Z CH2=CH2 men C. Z l CH3CH=O D. T l T CH3CH2Cl
43. phn bit cc axit l axit fomic v axit acrilic, nn dng thuc th : A. qu tm B. dung dch Br2 C. dung dch KMnO4 D. dung dch AgNO3/NH3

44. Qu trnh kh Fe2O3 bng CO trong l cao, nhit khong 500-600 oC, c sn phm chnh l : A. Fe. B. FeO. C. Fe3O4. D. Fe2O3. PHN RING (th sinh ch c lm mt trong hai phn: phn I hoc phn II) Phn I: dnh cho th sinh chng trnh phn ban (6 cu- t cu 45 n cu 50)
45. Lng kim loi km cn thit kh ht dung dch cha 0,02 mol CrCl3 trong mi trng axit l :

A. 0,325 gam B. 0,650 gam C. 0,975 gam D. 1,300 gam 46. Ha tan 9,4 gam ng bch (hp kim Cu-Ni, gi thit khng c tp cht khc) vo dung dch HNO3 long d. Khi phn ng xy ra hon ton, thu c 0,09 mol NO v 0,003 mol N2. Phn trm khi lng Cu trong hp kim bng : A. 74,89% B. 69,04% C. 27,23% D. 25,11% 47. Ion Ag+ (d nng rt nh 10-10 mol/L) c kh nng st trng, dit khun l v ion Ag+ : A. c tnh oxi ha mnh B. c tnh kh mnh C. c tnh axit mnh D. c tnh baz mnh 48. C hai phn ng xy ra nh sau : Co + Ni2+ Co2+ + Ni v Zn + Co2+ Zn2+ + Co Trt t tng dn tnh oxi ha (t tri sang phi) ca cc cp oxi ha - kh c lin quan n hai phn ng ny l : A. , , B. , , Co Ni 2+ Zn 2+ + C. , , D. , , Co Zn Ni Co Ni2 Zn 49. Cht no di y c th c s dng Co Zn Ni phn bit glucoz v fructoz ? A. dung dch Br2 B. Cu(OH)2/NaOH C. dung dch NaHSO3 D. dung dch AgNO3/NH3 50. Trong s cc cht l propan, etyl clorua, axeton, v etyl axetat, th cht tan tt nht trong nc l : A. propan B. etyl clorua C. axeton D. etyl axetat

Phn II: dnh cho th sinh chng trnh khng phn ban (6 cu-t cu 51 n cu 56) 51. Nhit phn cng s mol mi mui nitrat di y, th mui no sinh ra th tch kh O 2 nh nht (trong cng iu kin) ? ii. KNO3 B. Fe(NO3)2 C. Fe(NO3)3 D. AgNO3 52. Cho 2,7 gam Al vo 100 ml dung dch NaOH 2M thu c dung dch A. Thm dung dch cha 0,35 mol HCl vo dung dch A th lng kt ta thu c bng : A. 0,0 gam B. 3,9 gam C. 7,8 gam D. 11,7 gam 53. Cho dy in ha :
Zn2+ Zn Fe2+ Fe Cu2+ Cu Fe3+ Fe2+ Ag+ Ag

Phn ng gia cp cht no

di y c th xy ra ? A. Fe v Zn(NO3)2 B. Ag v Fe(NO3)3 C. Fe(NO3)2 v AgNO3 D. Cu v Fe(NO3)2 54. Cht no di y c kh nng lm mt mu dung dch brom v dung dch KMnO4 ? A. benzen B. toluen C. stiren D. naphtalen 55. to ra cumen, khng th tin hnh ankyl ha benzen bng cht no di y ?
A. isopropyl clorua B. 2-brompropan C. propilen D. propan 56. iu ch c 1 tn polietilen (hiu sut phn ng bng 80%) cn khi lng etilen (ktc) bng : A. 1,25 tn. B. 0,80 tn. C. 2,00 tn. D. 1,80 tn

P N S 17

1 0 B A C D D D C C D A 2 2 2 2 2 2 2 2 2 3 1 2 3 4 5 6 7 8 9 0 D D B C C C C A D A

1 1 D 3 1 C

1 2 C 3 2 B

1 3 A 3 3 C

1 4 B 3 4 C

1 5 C 3 5 C

1 6 B 3 6 B

1 7 A 3 7 A

1 8 C 3 8 B

1 9 A 3 9 D

2 0 B 4 0 B

4 4 4 4 1 2 3 4 C C D B

4 5 B

4 4 4 4 5 6 7 8 9 0 A A A A C

5 1 B

5 2 B

5 5 5 5 3 4 5 6 C C D A

 THI TH VO I HC, CAO NG Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao ) ( thi c 05 trang) PHN CHUNG: (44 cu t cu 1 n cu 44)

18

1. Pht biu no di y l khng ng ? A. Hp kim l cht rn thu c sau khi nung nng chy mt hn hp nhiu kim loi khc nhau hoc hn hp kim loi v phi kim. B. Hp kim thng c cu to bi ba loi tinh th l tinh th hn hp, tinh th dung dch rn v tinh th hp cht ha hc. C. Lin kt kim loi hay gp trong hp kim tinh th hn hp hay dung dch rn, cn lin kt cng ha tr hay gp trong tinh th hp cht ha hc. D. So vi kim loi ban u, hp kim thng dn in v nhit tt hn; do hn v c nhit nng chy cao hn. 2. Kim loi no di y c th tan trong dung dch HCl (khi khng c mt khng kh) ? A. Sn B. Cu C. Ag D. Hg 3. Nhng thanh Al trong dung dch cha 0,09 mol Cu(NO3)2 mt thi gian (kim loi ng sinh ra bm ht ln thanh nhm). Khi s mol Cu(NO3)2 cn li 0,03 mol th thanh Al c khi lng : A. gim i 1,08 gam. B. tng ln 1,38 gam. C. tng ln 2,76 gam. D. tng ln 3,84 gam. 4. Cho 0,001 mol NH4Cl vo 100 ml dung dch NaOH c pH = 12 v un si, sau lm ngui, thm vo mt t phenolphtalein, dung dch thu c : A. c mu xanh . B. c mu hng. C. c mu trng. D. khng mu. 5. Khi so snh vi kim loi kim cng chu k, nhn xt no v kim loi kim th di y l ng ? A. cng ln hn B. Nng lng ion ha th nht (I1) thp hn C. Khi lng ring nh hn (nh hn) D. Nhit nng chy v nhit si thp hn 6. Thi V lt (ktc) kh CO2 vo 300 mL dung dch Ca(OH)2 0,02M th thu c 0,2 gam kt ta. Gi tr ca V l : A. 44,8 mL hoc 89,6 ml. B. 224 ml. C. 44,8 ml hoc 224 ml. D. 44,8 ml. 7. M t no di y v tnh cht vt l ca nhm l khng ng ? A. Mu trng bc B. L kim loi nh C. Mm, d ko si v dt mng D. Dn in v nhit tt hn Ag kim loi 8. Thm HCl vo dung dch cha 0,1 mol natri hidroxit v 0,1 mol natri aluminat. Khi kt ta thu c l 0,08 mol th s mol HCl dng l : A. 0,08 mol hoc 0,16 mol B. 0,16 mol C. 0,26 mol D. 0,18 mol hoc 0,26 mol 9. 28 gam bt st ngoi khng kh mt thi gian thy khi lng tng ln thnh 34,4 gam. Tnh % st b oxi ha, gi thit sn phm oxi ha ch l oxit st t. A. 48,8% B. 60,0% C. 81,4% D. 99,9% 10. Trng hp no di y khng c s ph hp gia tn qung st v cng thc hp cht st chnh c trong qung ? A. Hematit nu cha Fe2O3 B. Manhetit cha Fe3O4 C. Xierit cha FeCO3 D. Pirit cha FeS2 11. Thm dung dch NaOH d vo dung dch cha 0,015 mol FeCl 2 trong khng kh. Khi cc phn ng xy ra hon ton th khi lng kt ta thu c bng : A. 1,095 gam. B. 1,350 gam. C. 1,605 gam. D. 13,05 gam. 12. Di y l hnh v minh ha qu trnh iu ch v thu kh Cl2 trong phng th nghim : Pht biu no sau y l khng ng ? A. Phn ng xy ra : 4HCl + MnO2 Cl2 + MnCl2 + 2H2O

B. Bnh cha dung dch NaCl c s dng lc bi trong khng kh. C. Bnh cha H2SO4 c hp th hi nc. D. Bng tm dung dch NaOH ngn kh Cl2 thot ra ngoi. 13. Phn ng no di y to sn phm l hai kh ? t A. C + HNO3 (c) B. P + HNO3 (c) t C. S + HNO3 (c) D. I2 + HNO3 (c) 14. Cho ankan A tc dng vi brom c un nng, ch thu c 12,08 gam mt dn xut monobrom duy nht. trung ha ht HBr sinh ra cn va ng 80ml dung dch NaOH 1M. A c tn gi : A. pentan B. 2-metylbutan C. 2,2-imetylpropan D. 2,2,3,3-tetrametylbutan HNO Br / /H FeSO 15. Thc hin hai dy chuyn ho di y : C6H6 ? A
32 2 4

C6H6 ? B Bit rng cc phn ng xy ra vi t l mol 1 :1. Tn gi ca cc sn phm A, B thu c ln lt l :

A. (A) m-bromnitrobenzen; (B) o-bromtoluen v p-bromtoluen

Cl AlCl3 2 / Fe CH 3Br

B. (A) o-bromnitrobenzen v o-bromnitrobenzen; (B) m-bromtoluen C. (A) m-bromnitrobenzen : (B) m-bromtoluen D. (A) p-bromnitrobenzen; (B) o-bromtoluen v p-bromtoluen 16. Pht biu no di y cha chnh xc ? A. Khng th thy phn monosaccarit. B. Thy phn isaccarit sinh ra hai phn t monosaccarit. C. Thy phn polisaccarit ch to nhiu phn t monosaccarit. D. Tinh bt, mantoz v glucoz ln lt l poli-, i- v monosaccarit. 17. ng dng no di y khng phi l ng dng ca glucoz ? A. Trng gng, trng phch B. Nguyn liu sn xut ancol etylic C. Nguyn liu sn xut cht do PVC D. Lm thc phm dinh dng v thuc tng lc 18. Cho 6,84 gam hn hp saccaroz v mantoz tc dng vi lng d dung dch AgNO 3 trong NH3 thu c 1,08 gam Ag kim loi. S mol saccaroz v mantoz trong hn hp ln lt bng : A. 0,005 mol v 0,015 mol B. 0,010 mol v 0,010 mol C. 0,015 mol v 0,005 mol D. 0 mol v 0,020 mol 19. Cc hin tng no sau y c m t khng chnh xc ? A. Nhng qu tm vo dung dch etyl amin thy qu tm chuyn mu xanh. B. Phn ng gia kh metylamin v kh hiro clorua lm xut hin "khi trng". C. Nh vi git nc brom vo ng nghim ng dung dch anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dung dch imetylamin xut hin mu xanh. 20. Cho -amino axit mch thng A c cng thc H 2NR(COOH)2 phn ng ht vi 0,1 mol NaOH to 9,55 gam mui. A l : A. axit 2-aminopropanioic. B. axit 2-aminobutanioic. C. axit 2-aminopentanioic. D. axit 2-aminohexanioic. 21. Trong cc protein di y, protein no tan trong nc ? A. Hemoglobin B. Keratin C. Fibroin D. Mizoin 22. Khi clo ha nha PVC ta thu c mt loi t clorin cha 66,17% clo. Hi trung bnh 1 phn t clo tc dng vi bao nhiu mt xch PVC ? A. 1 B. 2 C. 3 D. 4 23. Polime no di y cn c tn gi t nitron hay olon, c dng dt vi may qun o m ? A. Polimetacrylat B. Poliacrilonitrin C. Poli(vinyl clorua) D. Poliphenolfomanehit 24. S ng phn ancol ng vi cng thc phn t C3H8O, C4H10O ln lt bng : A. 2, 4 B. 1, 3 C. 2, 3 D. 1, 4 25. Cht no sau y khng nn s dng lm khan ancol etylic ? A. CaO B. C2H5ONa C. H2SO4 c D. Mg(ClO4)2 26. phn bit phenol, anilin, benzen, stiren ngi ta ln lt s dng cc thuc th : A. qu tm, dung dch brom. B. dung dch NaOH, dung dch brom. C. dung dch brom, qu tm. D. dung dch HCl, qu tm. 27. Anehit fomic v anehit axetic tan tt trong nc l v cc cht ny : A. phn ng c vi nc to sn phm l nhng cht d tan trong nc. B. l nhng phn t c cu to khng phn cc.

C. u c cu trc hnh hc phn t cng knh. D. c kh nng to lin kt hiro vi nc, qua nguyn t hiro linh ng ca mi phn t. 28. Trng hp no di y c s tng ng gia cht v ng dng ch yu ca n ? cht ng dng cht ng dng A. metanol sn xut B. etanal sn xut anehit fomic poliphenolfomanehit C. metanal sn xut axit axetic D. propanon lm dung mi 29. Cht no di y khng th dng iu ch trc tip axit axetic ? A. CH3CH2OH B. CH3CHO C. CH3CH2CH2CH3 D. CHCH 30. Cht A c cng thc phn t C4H7ClO2. Cho A tc dng vi dung dch NaOH nng to mui hu c, etilenglicol (etylen glicol) v natri clorua. Cu to ca A l :

A. ClCH2COOCH2CH3 B. CH3COOCHCl-CH3 D. ClCH2CH2COOCH3

C. CH3COOCH2CH2Cl

31. Xt cu to : CH3[CH2]4CH=CHCH2CH=CH[CH2]7COOH Tng ng vi cu to ny c bao nhiu dng ng phn hnh hc ? A. 2 B. 3 C. 4 D. 6 32. Khi ly cng s mol cc cht KClO3, KMnO4, CaOCl2 v HNO3 em nhit phn iu ch kh O2, th cht sinh ra lng O2 ln nht l : 1. KClO3 B. KMnO4 C. CaOCl2 D. HNO3 33. Dung dch CH3COOH 0,1M c in li = 1,34%. Gi tr pH ca dung dch ny bng : a. 0,9. B. 1,0. C. 1,9. D. 2,9. 34. A l hn hp kim loi Fe v Cu. Ha tan m gam A vo dung dch HCl d (khng c khng kh) thu c 3,36 L kh (ktc). Cng ha tan m gam ny vo dung dch HNO 3 c, nng d, thu c 15,456 L kh mu nu (ktc). Khi lng m bng : i. 16,08 gam. B. 20,88 gam. C. 42,96 gam. D. 90,32 gam. 35. Ha tan 3,8 gam hn hp C v S trong dung dch HNO 3 c nng, d thu c 19,04 L hn hp hai kh (ktc). Khi lng C trong hn hp ban u bng : t A. 0,12 gam B. 0,60 gam C. 0,90 gam D. 1,20 gam 36. phn bit kh SO2 v kh H2S, th nn s dng thuc th no di y ? A. dung dch KMnO4 B. dung dch Br2 C. dung dch CuCl2 D. dung dch NaOH 37. Ha tan ht hn hp hai kim loi A, B trong dung dch HCl d, thm tip vo lng d dung dch NaOH. Lc tch kt ta, nhit phn kt ta, ri kh cht rn thu c bng CO th thu c kim loi A. Thi kh CO2 vo dung dch nc lc, tch kt ta, nung n khi lng khng i, ri em in phn nng chy cht rn, thu c kim loi B. A, B c th l cp kim loi no di y ? A. Mg v Al B. Mg v Zn C. Fe v Al D. Fe v Zn 38. Trng hp no di y c s ph hp gia t khi hi (d) v phn t khi (M) ? d M d M M X = 18 M Z = 30 A. d X / H 2 = 36 d Z / N 2 = 2,1428 B. M Y = 35 M T = 62 C. d Y / O 2 = 2,1875 D. d T / kk = 2,1379 39. Cng thc cho dy ng ng no di y KHNG ng ? hp cht mch h cng thc A. ancol no, n chc CnH2n+1OH B. C. D. anehit cha no (1 lin kt i), n chc axit cacboxylic no, hai chc amin no, n chc, bc nht CnH2nCHO CnH2n(COOH)2 CnH2n+1NH2

40. Oxi ha 0,045 mol ru (ancol) i-propylic (thnh xeton tng ng) bng dung dch K 2Cr2O7 trong H2SO4. Khi phn ng xy ra hon ton, s mol K2Cr2O7 phn ng bng : A. 0,015 mol. B. 0,030 mol. C. 0,045 mol. D. 0,135 mol. 41. Cho 7,2 gam axit cacboxylic n chc A tc dng vi lng d dung dch Na 2CO3 thu c 1,12 L CO2

(ktc). Axit A l : A. HCOOH. B. CH3COOH. C. CH3CH2COOH. D. CH2=CHCOOH. 42. phn bit bn bnh kh mt nhn cha CH 4, N2, H2 v CO ngi ta cho cc mu th ln lt qua CuO t nng, CuSO4 khan v bnh cha dung dch Ca(OH)2. Sau th nghim thy mu (1) ch lm CuSO4 i qua mu xanh; mu (2) ch to kt ta trng bnh cha nc vi; mu (3) to hin tng c hai bnh ny, cn mu (4) khng to hin tng g. Cc mu (1), (2), (3) v (4) ln lt l : (1) (2) (3) (4) (1) (2) (3) (4) A. CH4 N2 H2 CO C. H2 CO CH4 N2 B. CO CH4 N2 H2 D. N2 H2 CO CH4 43. Cht no di y khng to kt ta trng bc khi tc dng vi dung dch AgNO3/NH3 ? A. axetilen B. glucoz C. axit fomic D. anehit axetic 44. Pht biu no di y khng ng ? A. Bn knh nguyn t Fe nh hn bn knh ion Fe2+. B. Mc oxi ha c trng ca Fe trong hp cht l +2 v +3. C. Cu hnh electron ca ion Fe2+ l [Ar] 3d6. D. Ion Fe3+ c cha 5 electron c thn. PHN RING (th sinh ch c lm mt trong hai phn: phn I hoc phn II) Phn I: dnh cho th sinh chng trnh phn ban (6 cu- t cu 45 n cu 50) 45. Hin tng no di y c m t khng ng ? A. Thm d NaOH vo dung dch K2Cr2O7 th dung dch chuyn t mu vng thnh mu da cam. B. Thm d NaOH v Cl2 vo dung dch CrCl2 th dung dch t mu xanh chuyn thnh mu vng. C. Thm t t dung dch NaOH vo dung dch CrCl 3 thy xut hin kt ta lc xm v kt ta ny tan li trong NaOH d. D. Thm t t dung dch HCl vo dung dch Na[Cr(OH)4] thy xut hin kt ta lc xm, sau tan li. 46. Trong khng kh m, kim loi ng b bao ph bi lp mng : A. CuO (mu en). B. CuS (mu en). C. CuCl2 (mu xanh). D. CuCO3.Cu(OH)2 (mu xanh). 47. Ha tan ht m gam hn hp Ag-Fe trong dung dch H 2SO4 (c, nng, d) sinh ra 0,25 mol kh, cn nu ha tan m gam hn hp ny trong dung dch H2SO4 long d th sinh ra 0,1 mol kh. Khi lng m bng : A. 16,4 gam. B. 21,8 gam. C. 27,2 gam. D. 38,0 gam. 48. Ha tan m gam hn hp Zn v Fe trong dung dch H2SO4 long d, thy thot ra 4,48 l kh (ktc). Nu ha tan m gam hn hp ny trong dung dch NaOH d, th khi phn ng hon ton c 0,10 mol NaOH phn ng. Gi tr m bng : A. 11,65 gam. B. 12,10 gam. C. 12,55 gam. D. 13,00 gam. 49. phn bit dung dch C6H5ONa v cc cht lng C2H5OH, C6H6, C6H5NH2, mt hc sinh ln lt thm dung dch HCl vo mu th ca cc cht ny. Kt lun no di y khng ng ? A. Mu th c vn c mu trng l natri phenolat. B. Mu th to dung dch ng nht l ancol etylic. C. Mu th hnh thnh hin tng phn lp l benzen. D. Mu th to dung dch ng nht ngay lp tc l anilin. 50. phn bit axeton v anehit propionic th khng nn dng thuc th : A. dung dch AgNO3/NH3. B. dung dch Br2. C. Cu(OH)2 trong NaOH. D. dung dch NaHSO3. Phn II: dnh cho th sinh chng trnh khng phn ban (6 cu-t cu 51 n cu 56) 51. t hon ton m gam bt nhm trong lng S d, ri ha tan ht sn phm thu c vo nc th thot ra 6,72 lt kh (ktc). Tnh m. B. 2,70 gam B. 4,05 gam C. 5,40 gam D. 8,10 gam 52. Thc t, phn ng in phn nng chy iu ch kim loi, nn p dng cho cht no trong s cc cht di y ? A. CaCl2 B. Mg(OH)2 C. AlCl3 D. CuSO4 53. Gi X l nhm kim loi tc dng c vi dung dch HCl v Y l nhm kim loi tc dng c vi dung dch Fe(NO3)2. Hy cho bit nhm kim loi X, Y no di y ph hp vi quy c trn ? A. C. X Fe, Pb Mg, Zn Y Mg, Zn Sn, Ni B. D. X Sn, Ni Mg, Ag Y Al, Mg Zn, Cu

54. Pht biu no di y khng ng ?

A. Ankan kh tr v mt ha hc do phn t ch cha lin kt xichma () bn. B. Hirocacbon cha no hot ng ha hc mnh do cc phn t loi ny c cha lin kt pi () km bn. C. Khc vi hirocacbon cha no, nguyn t cacbon trong cc phn t ankan bo ha lin kt, nn ankan khng tham gia phn ng cng. D. Do phn t c cha lin kt pi () km bn, nn nhn chung cc aren d tham gia phn ng cng hn phn ng th.

55. Di y l cc dy chuyn ha iu ch:

2 2 4 + HONO + Br / Fe H SO

benzoic
2 2 oC 3 + ZnO,600 + CH = CH ,AlCl

(X) benzen X1 m-bromnitrobenzen + KMnO + Cr2O //H Al (Y) n-hexan Y1 axit 4 3 2SO 2O4 3 (Z) benzen Z1 stiren + HONO KMnO4 (T) toluen T1 axit o- 2 / H2SO4

nitrobenzoic Dy c vit hon ton ng l A. X B. Y C. Z D. T 56. Tin hnh phn ng tch nc t ru CH3CH2CH(OH)CH3 th sn phm chnh thu c l : A. CH3CH=CHCH3 B. CH2=CHCH2CH3 C. (CH3)2C=CH2 D. CH3CH=CH2

 19 ( thi c 04 trang)

THI TH VO I HC, CAO NG Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao )

PHN CHUNG: (44 cu t cu 1 n cu 44) 1. Phn ng sau y t xy ra : Zn + 2Cr3+ Zn2+ + 2Cr2+ . Phn ng ny cho thy : A. Zn c tnh kh mnh hn Cr2+ v Cr3+ c tnh oxi ha mnh hn Zn2+. B. Zn c tnh kh yu hn Cr2+ v Cr3+ c tnh oxi ha yu hn Zn2+. C. Zn c tnh oxi ha mnh hn Cr2+ v Cr3+ c tnh kh mnh hn Zn2+. D. Zn c tnh oxi ha yu hn Cr2+ v Cr3+ c tnh kh yu hn Zn2+. 2. Kim loi no di y khng phn ng vi nc iu kin thng ? A. Na. B. Ba. C. Ca. D. Al. 3. Ha tan hon ton 0,81 g kim loi M (ha tr n) vo dung dch H 2SO4 c, nng thu c 1,008 lt (ktc) kh SO2. Kim loi M l : A. Be. B. Al. C. Mn. D. Ag. 4. Cho a mol CO2 hp th hon ton vo dung dch cha 2a mol NaOH. Dung dch thu c c gi tr pH : A. bng 0. B. ln hn 7. C. nh hn 7. D. bng 7. 5. M t no di y khng ph hp cc nguyn t phn nhm A nhm II ? A. Cu hnh electron ha tr l ns2. B. Tinh th cc kim loi kim th u c cu trc lc phng. C. Gm cc nguyn t Be, Mg, Ca, Sr, Ba, Ra. D. Mc oxi ha c trng trong cc hp cht l +2. 6. Cho 0,2 mol Na chy ht trong O2 d thu c sn phm rn A. Ha tan ht A trong nc thu c 0,025 mol O2. Khi lng ca A bng : A. 3,9 gam. B. 6,2 gam. C. 7,0 gam. D. 7,8 gam. 7. Phn ng no sau y khng xy ra ? A. CaSO4 + Na2CO3 B. Ca(OH)2 + MgCl2 C. CaCO3 + Na2SO4 D. CaSO4 + BaCl2 8. Thm NaOH vo dung dch hn hp cha 0,01 mol HCl v 0,01 mol AlCl 3. S mol NaOH ti thiu dng kt ta thu c l ln nht v nh nht ln lt bng : A. 0,01 mol v 0,02 mol. B. 0,02 mol v 0,03 mol.C. 0,03 mol v 0,04 mol.D. 0,04 mol v 0,05 mol. 9. Phng trnh ho hc no sau y c vit khng ng ? A. 3Fe + 2O2 Fe3O4 B. 2Fe + 3Cl2 2FeCl3 C. 2Fe + 3I2 2FeI3 D. Fe + S FeS 10. Cho 0,02 mol bt st vo dung dch cha 0,07 mol AgNO 3. Khi phn ng hon ton th khi lng cht rn thu c bng : A. 1,12 gam. B. 4,32 gam. C. 6,48 gam. D. 7,56 gam. 11. Tnh khi lng kt ta S thu c khi thi 3,36 L (ktc) kh H2S qua dung dch cha 0,2 mol FeCl3. Bit phn ng xy ra hon ton. A. 3,2 gam B. 4,8 gam C. 6,4 gam D. 9,6 gam 12.Trong dy no di y, cc cht khng c xp theo trt t tng dn mnh tnh axit t tri sang phi ? A. HClO, HClO2, HClO3, HClO4 B. HI, HBr, HCl, HF C. H3PO4, H2SO4, HClO4 D. NH3, H2O, HF

13.

Sn phm phn ng nhit phn no di y l khng ng ? t A. NH4Cl NH3 + HCl B. NH4HCO3 NH3 + H2O + CO2 t C. NH4NO3 NH3 + HNO3 D. NH4NO2 N2 + 2H2O 14. Th tch ca m gam O2 gp 2,25 ln th tch hi ca m gam hirocacbon A cng iu kin. iclo ho A thu c 2 sn phm l ng phn. Tn ca A l : A. neopentan B. isobutan C. propan D. isopentan 15. Phn ng no di y khng to thnh etylbenzen ? AlCl B. benzen + CH3CH2Cl A. toluen + CH3CH3 AlCl H , Ni /t 2 C. stiren + H2 D. benzen + CH2=CH2 16. Cacbohirat (gluxit, saccarit) nhn chung l : A. hp cht a chc, c cng thc chung l Cn(H2O)m. B. hp cht tp chc, a s c cng thc chung l Cn(H2O)m. C. hp cht cha nhiu nhm hiroxyl v nhm cacboxyl. D. hp cht ch c ngun gc t thc vt. 17. Thuc th duy nht no di y c th phn bit bn dung dch mt nhn cha glucoz, glixerin (glixerol), fomanehit, etanol ? A. Cu(OH)2 trong kim nng B. Dung dch AgNO3/NH3 C. Na kim loi D. Nc brom 18. Hn hp m gam glucoz v fructoz tc dng vi lng d AgNO 3/NH3 to ra 4,32 gam Ag. Cng m gam hn hp ny tc dng va ht vi 0,80 gam Br 2 trong dung dch. S mol glucoz v fructoz trong hn hp ny ln lt bng : A. 0,005 mol v 0,015 mol. B. 0,01 mol v 0,01 mol. C.0,005 mol v 0,035 mol. D. 0,02 mol v 0,02 mol. 19. Cho lng d anilin phn ng hon ton vi dung dch long cha 0,05 mol H 2SO4, lng mui thu c bng : 1. 7,1 gam B. 14,2 gam C. 19,1 gam D. 28,4 gam 20. Cho 0,1 mol A (-amino axit dng H2NRCOOH) phn ng ht vi dung dch NaOH to 11,1 gam mui khan. A l : A. alanin B. glixin C. phenylalanin D. valin 21. Tn gi cho peptit l : H2NCH2CONHCHCONHCH2COOH
3 3

A. glixinalaninglyxin B. alanylglyxylalanin C. glixylalanylglyxin D. alanylglyxylglyxyl 22. Trong phn ng vi cc cht hoc cp cht di y, phn ng no gi nguyn mch polime ? 150 300 C A. nilon-6,6 + H2O B. cao su buna + HCl C. polistiren D. resol 23. Trng hp no di y c s tng ng gia loi vt liu polime v tnh c trng v cu to hoc tnh cht ca n ? A. Cht Si di, mnh v Cao su ; Tnh n hi do ; bn B. C. T C kh nng kt Keo dn ; Tnh do dnh D. 24.Pha 74,88 gam ru (ancol) etylic (d = 0,78 g/mL) vo 4 mL H 2O. ru ca dung dch thu c bng : A. 20o. B. 24o. C. 75o D. 96o. hs35% hs60% hs80% 25. GC6H12O6C2H5OHC4H6Cao su buna
o

CH3

Khi lng g cn sn xut 1 tn cao su l : a. 24,8 tn. B. 22,3 tn C. 12,4 tn. D. 1,0 tn. 26. Cho dy chuyn ho iu ch sau : NaOH HCl / t ,p Br / Fe ToluenBCD. Cht D l : A. Benzyl clorua B. m-metylphenol C. o-cresol v p-cresol D. o-clotoluen v p-clotoluen 27. Cht no di y c gi ng tn bng c hai loi danh php ? cng thc tn gi A. CH3-CH=O anehit axetic (metanal)
2

B. C. D.

CH2=CH-CH=O CH3-CH(CH3)CH=O O=HC-CH=O

anehit acrylic (propanal) anehit isobutiric (metylpropanal) anehit malonic (etanial)

28. Cho 1,78 gam hn hp fomanehit v axetanehit phn ng hon ton vi lng d Cu(OH)2 trong NaOH nng, thu c 11,52 gam kt ta. Khi lng fomanehit trong hn hp bng : A. 0,45 gam. B. 0,60 gam. C. 0,88 gam. D. 0,90 gam. 29. X cha mt loi nhm nh chc, c cng thc C 8H14O4. Thy phn X trong NaOH thu c mt mui v hai ancol A, B. Phn t B c s nguyn t C nhiu gp i A ; un nng vi H2SO4 c, A cho mt olefin v B cho hai olefin ng phn. Cu to ca X l : A. C2H5OOCCOOCH(CH3)CH2CH3 B. C2H5OOC[CH2]3COOCH3 C. CH3CH(CH3)2OOCCOOCH2CH3 D. CH3CH2OOC[CH2]2COOCH2CH3 30. Phng trnh ho hc no di y c vit ng ?
as4 BrCH=CHCOOH KMnO B. CH COOH + HBr + Br COOH 2=CHCOOH 2 A. CH COOH + Cl CH COCl C. CH =CHCOOH H23 C CH+ HOCl COOH 3 2 2 1:1 H2O 31. S dng ha NO OH OH 2 H2SO4 cht no di y D. + HONO2 + H2O

phn bit du m ng thc vt v du m bi trn my ? A. nc nguyn cht B. benzen nguyn cht C. dung dch NaOH nng D. dung dch NaCl nng 32. Th tch kh (ktc) sinh ra khi nung nng hn hp mui cha 0,2 mol (NH 4)2SO4 v 0,2 mol NaNO2 l : A. 1,12 L. B. 2,24 L. C. 4,48 L. D. 8,96 L. + 33. Cho phng trnh in li ca nc : 2H2O H3O + OH . Theo thuyt proton ca Brsted th nc l mt : A. axit. B. baz. C. cht lng tnh. D. cht trung tnh. 34. A l hn hp kim loi Ba v Al. Ha tan m gam A vo lng d nc thy thot ra 8,96 L kh H2 (ktc). Cng ha tan m gam ny vo dung dch NaOH th thu c 12,32 L kh H 2 (ktc). Khi lng m bng : A. 13,70 gam. B. 21,80 gam. C. 58,85 gam. D. 57,50 gam. 35. un nng 0,3 mol bt Fe vi 0,2 mol bt S n phn ng hon ton c hn hp A. Ha tan ht A bng dung dch HCl d thu c kh D. T khi hi ca D so vi khng kh bng : A. 0,8046. B. 0,7586. C. 0,4368. D. 1,1724. 36. Trong s cc kh Cl2, HCl, CH3NH2, O2 th c bao nhiu kh to khi trng khi tip

xc vi kh NH3 ? A. 1 B. 2 C. 3 D. 4 37. tinh ch kh CO2 c ln tp cht l kh SO2, nn thi hn hp hai kh ny qua bnh cha : A. dung dch nc vi trong. B. dung dch axit sunfuric. C. dung dch nc brom. D. dung dch xt. 38. Khi t chy hon ton mt lng hp cht hu c X cn 0,8 gam O 2, ngi ta thu c 1,1g CO2; 0,45g H2O v khng c sn phm no khc. Hm lng % cc nguyn t trong phn t X bng : %mC %mH %mO %mC %mH %mO A. 3,33 43,34 53,33 B. 40,00 6,67 53,33 C. 3,33 1,88 94.79 D. 40,00 1,88 58,12 39. Trng hp no di y vit ng cng thc chung ca hirocacbon : hidrocacbon Cng thc hidrocacbon Cng thc A. anken B. Ankatrien CnH2n 2 CnH2n 4 C. ankin CnH2n D. aren CnH2n 6 40. Cho cc cht :
X. CH3 CH CH CH3 Y. CH3 CH3 Z. CH3 CH Br C CH3 T. CH3 Cl CH3

Cc cht c ng phn hnh hc l : A. X v Y. B. Y v Z. C. Z v T. D. T v X. 41. A l dung dch hn hp cha CH2(COOH)2, c nng mol aM v CH2=CHCOOH c nng mol bM. Trung ha 100 mL A cn 250 mL dung dch NaOH 1M. Mt khc, 100 mL dung dch A cng lm mt mu va ht dung dch Br 2, cha 24 gam Br2. Cc gi tr a, b ln lt bng; a b a b a b a b (M) (M) (M) (M) (M) (M) (M) (M) A. 0,5 1,5 B. 1,0 1,0 C. 1,0 1,5 D. 2,0 1,0 42. Cho dy chuyn ha iu ch axit axetic :
+ O2

Y
+ O 2, 180 oC, 70atm + O2, men

Pht biu no di y l ng ? X CH3COOH Z Mn 2+, t A. X l CH3COONa + H2SO4 B. Y l CH3CH2CH2CH3 T C. Z l CH3CH2OH D. T l CH3CHO 43. Khi cho cc cht : axit axetic, etilenglicol (etylen glicol), glixerin (glixerol) v glucoz ln lt tc dng vi Cu(OH)2, th cht ha tan Cu(OH)2 to dung dch c mu xanh nht l : A. axit axetic. B. etilenglicol (etylen glicol). C. glixerin (glixerol) D. glucoz. 44. Cho m gam Fe tc dng vi dung dch H 2SO4 long to 1,792 L kh (ktc). Nu cng cho m gam Fe tc dng vi dung dch HNO3 long th th tch kh N2O duy nht (ktc) sinh ra l : A. 0,03 mol. B. 0,06 mol. C. 0,18 mol. D. 0,30 mol . PHN RING (th sinh ch c lm mt trong hai phn: phn I hoc phn II) Phn I: dnh cho th sinh chng trnh phn ban (6 cu- t cu 45 n cu 50)

45. Thi kh NH3 d qua 1 gam CrO 3 t nng n phn ng hon ton th thu c lng cht rn bng : A. 0,52 gam. B. 0,68 gam. C. 0,76 gam. D. 1,52 gam. 46. Cho Cu ln lt tc dng ht vi mi cht oxi ha di y c cng s mol. Trng hp no thu c s mol hp cht Cu(II) nh nht ? i. Cu + O2 B. Cu + Cl2 C. Cu + t H2SO4 c D. Cu + HNO3 c 47. Ha tan 12 gam mt mu qung cha Au vo hn hp cng thy c d. Khi phn ng hon ton thy c 0,0015 mol HCl tham gia phn ng. Phn trm khi lng Au trong mu qung trn bng : A. 0,41%. B. 0,82% . C. 1,23%. D. 1,64%. 48. Xt cc phn ng : t0 SO2 (X) ZnCO3.ZnS + 3/2O2 2ZnO + CO2 + (Y) ZnO + CO Zn + CO2 0 p t (Z) ZnO + H2SO4 ZnSO4 + H2 (T) ZnSO4 + H2OZn + 1/2O2 + H2SO4 Qu trnh iu ch Zn t qung ZnCO3.ZnS bng phng php in luyn khng dng phn ng : A. X. B. Y. C. Z. D. T. 49. phn bit ba dung dch mt nhn cha H 2NCH2COOH, CH3[CH2]3NH2 v CH3CH2COOH, bng mt thuc th duy nht th nn dng : A. Na. B. qu tm. C. NaHCO3. D. NaNO2/HCl. 50. Ch dng qu tm (v cc cc mu th nhn bit c) th nhn ra c bao nhiu dung dch, trong s 4 dung dch mt nhn : BaCl2, NaOH, AlNH4(SO4)2, KHSO4 ? A. 1. B. 2. C. 3. D. 4. Phn II: dnh cho th sinh chng trnh khng phn ban (6 cu-t cu 51 n cu 56) 45. Nung n hon ton 0,05 mol FeCO3 trong bnh kn cha 0,01 mol O2 thu c cht rn A. ha tan ht A bng dung dch HNO3 (c nng), th s mol HNO3 ti thiu cn dng l : A. 0,14 mol. B. 0,15 mol. C. 0,16 mol. D. 0,18 mol. 46. So snh bn knh nguyn t (hay ion) no di y l khng ng ? rAl rr r > > rCl A. B. C. Se P> Cl O K Al D. 47. Ln lt nhng bn thanh kim loi Zn, Fe, Ni v Ag vo dung dch Cu(NO 3)2. Sau mt thi gian ly cc thanh kim loi ra. Nhn xt no di y KHNG ng ? A. Khi lng thanh Zn gim i. B. Khi lng thanh Fe tng ln. C. Khi lng thanh Ni tng ln. D. Khi lng thanh Ag gim i. 48. Hirocacbon no di y khng th lm nht mu dung dch brom ? A. Etilen B. Xiclopropan C. Xiclohexan D. Stiren 49. Mt hirocacbon thm X c cng thc C9H12. Oxi ha mnh lit X to axit c cng thc C8H6O4. un nng vi brom c mt bt st, X cho hai sn phm monobrom. X l : A. 1,2,3-trimetylbenzen. B. p-etylmetylbenzen C. m-etylmetylbenzen D. isopropylbenzen 50. Thi 0,4 mol kh etilen qua dung dch cha 0,2 mol KMnO 4 trong mi trng trung tnh, khi lng etilenglicol thu c bng : A. 6,2 gam B. 12,4 gam C. 18,6 gam D. 24,8 gam
+ 3 +

 THI TH I HC 2013 MN HA
Thi gian lm bi: 90 pht Ngy thi: ........./........./.......... 1. tc dng ht vi 100 gam lipit c ch s axit bng 7 phi dng 17,92 gam KOH. Khi lng mui thu c sau phn ng l A. 108,107 gam. B. 103,178 gam. C.108,265 gam. D. 110,324 gam. 2. in phn dung dch cha m gam hn hp 2 mui CuSO4 v NaCl bng in cc tr n khi nc b in phn c 2 in cc th dng li. Dung dch thu c sau in phn ha tan va 1,6 gam CuO v anot ca bnh in phn c 448 ml kh bay ra (ktc). Gi tr ca m l A. 5,97 gam. B. 7,14 gam. C. 4,95 gam. D. 3,875 gam. 3. Hp cht X l cht kh iu kin thng. X lm xanh qi tm tm t. Hy cho bit X c th l cht no trong s cc cht sau: NH3 (I); CH3NH2 (II); (CH3)2NH (III); (CH3)3N (IV); CH3CH2NH2 (V)? A. (I). (V). 4. Cho cc cht benzen (X), toluen (Y),nitrobenzen (Z), phenol (T) phn ng vi brom th kh nng phn ng xy ra d dn theo trnh t no sau y? A. Z, X, Y, T. B. T, Z, X, Y. C. Z, T, X, Y. D. Y, Z, T, X. 5. Cho 1,68 gam hn hp X gm Mg v Fe vo cc cha 100ml dung dch HCl. Sau khi phn ng xy ra hon ton, c cn thu c 3,455 gam cht rn khan. Nng mol ca dung dch HCl dng l A. 0,25M. B. 0,27M. C. 0,36M. D. 0,5M. 6. Hy cho bit nhng pht biu no sau y ng? (1) Phenol c kh nng th vo vng (vi HNO3, Br2) d hn nhiu so vi benzen, phn ng xy ra i khi cn xc tc hay un nng. (2) Phenol c tnh axit nn cn c gi l axit phenic.Tnh axit ca phenol mnh hn ca ru l do nh hng ca ca gc phenyl n nhm OH. (3) Tnh axit ca phenol yu hn H2CO3 nn khi sc kh CO2 d vo dung dch C6H5ONa s thu c C6H5OH v Na2CO3. (4) Phenol trong nc cho mi trng axit, lm qu tm ha . A. (1); (2) ; (3). B. (1); (2). C. (1); (2); (3); (4). D. (2); (3). 7. Phn ng no sau y khng dng chng minh c im cu to ca phn t glucoz? A. Ha tan Cu(OH)2 chng minh phn t c nhiu nhm chc OH. B. Phn ng vi CH3COOH theo t l mol 1:5 chng minh phn t c 5 nhm OH. B.(I); (II); (V). C. (I); (II); (III); (IV). D. (I); (II); (III); (IV);

C. tc dng vi Na chng minh phn t c nhm OH. D. Phn ng trng gng chng minh phn t c nhm CHO. 8.Cho dung dch cha m gam hn hp gm nhng lng bng nhau v s mol ca mantoz v saccaroz tc dng vi lng d dung dch AgNO3/NH3 thu c 21,6 gam Ag. Gi tr ca m l A. 17,1 gam. B. 34,2 gam. C. 36,0 gam. D. 68,4 gam. 9. Ha tan hon ton 10,08 gam mt oxit kim loi cn dng va ht 42 ml dung dch hn hp gm HCl 3M v H2SO4 1,5M. Oxit ban u c th l A. FeO. B. MgO. C. CuO. D. Fe 2O3. 10. Nung hn hp A gm x mol Fe v 0,15 mol Cu trong khng kh mt thi gian, thu c 63,2 gam hn hp cht rn B. Ha tan ht hn hp B bng dung dch H2SO4 c, nng, d thu c 6,72 lt kh SO2 (ktc). Gi tr ca x l A. 0,4 mol. B. 0,5 mol. C. 0,6 mol. D. 0,7 mol. 11. Dung dch A c cha Ba2+ (x mol);H+ (0,2 mol); Cl- (0,1 mol) v NO3- (0,4 mol). Cho t t dung dch K2CO3 1M vo dung dch A n khi lng kt ln nht thy tiu tn V lt dung dch K2CO3.Gi tr ca V l A. 150 ml. b nhit phn l A. 40%. B. 30%. C. 75%. D. 50%. 13. S ng phn c cha vng benzen ca hp cht C7H9N l A. 3 cht. B. 4 cht. C. 5 cht. D. 6 cht. 14. Cho hp cht X tc dng vi NaOH to ra kh Y lm xanh qu tm. Mt khc X tc dng vi axit HCl to ra kh Z va lm c nc vi trong, va lm mt mu dung dch KmnO4. Cht X khng tc dng vi dung dch BaCl2. Vy cht X c th l A. (NH4)2SO4. B. NH4HSO4. C. (NH4)2CO3. D. NH4HCO3. 15. Khi t chy hon ton mt ancol no mch h thu c th tch hi nc gp 1,5 ln th tch CO 2 o cng iu kin. S cht tha mn tnh cht ca X l A. 1 cht. B. 2 cht. C. 3 cht. D. 4 cht. 16. Cho s iu ch phenol: Ancol propylic propen Y phenol. Cng thc ca cht Y trong s trn l A. C6H6. B. C6H5CH(CH3)2. C. C6H5CH2CH2CH3. D. C6H5CH3. 17. X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l A. 8,2 gam. B. 8,56 gam. C. 12,2 gam. D. 16,8 gam. 18. Trong s cc cht c cng thc phn t C7H8O2 c bao nhiu cht tc dng vi dung dch NaOH B. 400 ml. C. 200 ml. D. 250 ml. 12. Nung 316 gam KMnO4 mt thi gian thy cn li 300 gam cht rn. Vy % khi lng KmnO4

 ngay nhit o thng? A. 1 cht. B. 2 cht. B. 3 cht. D. 4 cht. 19. Cho 8,12 gam mt oxit ca mt kim loi tc dng ht vi CO khi t nng. Ton b kim loi to ra phn ng ht vi dung dch axit HCl thu c 2,352 lt H2 (ktc). Oxit kim loi dng l A. ZnO. B. Fe3O4. C. FeO. D. Fe 2O3. 20. Oxi ha hn hp X gm HCHO v CH3CHO bng O2 (xt) n phn ng hon ton thu c hn hp axit tng ng Y c t khi so vi X bng 145/97. Thnh phn % s mol ca HCHO trong hn hp u l A. 16,7 %. B. 22,7 %. C. 83,3 %. D. 50,2 %. 21. Hp cht hu c C4H7O2Cl khi thy phn trong mi trng kim thu c cc sn phm trong c hai cht c kh nng tham gia phn ng trng Ag. Cng thc ng ca cht hu c trn l A. HCOO CHCl CH2 CH3. C. CH3COO CHCl CH3. B. HCOO CH2 CHCl CH3. D. HCOO CHCl CH2 CH3.

22. Cho dung dch Ca(OH)2 d vo 200 ml dung dch KHCO3 1,5M thu c kt ta X. Lc kt ta X em nung n khi lng khng i thu c m gam cht rn. Gi tr ca m l A. 8,4 gam. ta thu c l A. 6,02 gam. B. 6,06 gam. C. 5,50 gam. D. 2,79 gam. 24. hai hp cht X v Y l hai ancol, trong khi lng mol ca X nh hn ca Y. Khi t chy hon ton mi cht X, Y u to ra s mol CO2 t hn s mol H2O. t chy hon ton hn hp Z gm nhng lng bng nhau v s mol ca X v Y thu c t l s mol CO2 v H2O tng ng l 2:3. S hp cht tha mn tnh cht ca Y l A. 2 cht. 25. Cho cc phn ng: B. 4 cht. Ag+ + Fe2+ Ag + kim loi A. Cu2+/ Cu < Fe3+/ Fe2+ < Ag+/ Ag. . B. Ag+/ Ag < Cu2+/ Cu < Fe3+/ Fe2+. D. Ag+/ Ag < Fe3+/ Fe2+ < Cu2+/ Cu. C. 1,6 gam. D. 10,7 gam. C. Fe2+/ Fe2+ < Cu2+/ Cu < Ag+/ Ag. A. 10,4 gam. B. 3,2 gam. C. 5 cht. D. 6 cht. Cu + 2Fe3+ Cu2+ + 2Fe2+ B. 16,8 gam. C. 15,0 gam. D. 30,0 gam. 23. Thm dung dch CaCl2 d vo 100 ml dung dch kali stearat 0,1M; sau phn ng khi lng kt

Fe3+.

Hy sp xp ba cp oxi ha kh trong cc phn ng trn theo cch sp xp dy hot ng ha hc ca

26. Dn H2S va vo dung dch c cha 16,25 gam FeCl3 thu c kt ta c khi lng bng 27. Ha tan ht 20,8 gam hn hp X gm FeS v FeS2 c cng s mol bng lng d dung dch HNO3 c, nng thu c dung dch Y. Thm dung dch Ba(OH)2 d vo Y thu c kt ta Z. Nung Z n khi lng khng i c m gam cht rn. Gi tr ca m l

A. 16 gam.

B. 69,9 gam.

C. 85,9 gam.

D. 91,3 gam.

28. Hp cht X (cha C, H, O) c khi lng mol nh thua 150 gam, trong oxi chim 32% khi lng. Cht X khng phn ng vi H2 khi c Ni xc tc v un nng ti 1500C. S hp cht tha mn tnh cht ca X l A. 4 cht. 1) N2 + O2 2NO2 2) 2N2 + 5O2 2N2O5 3) 6Li + N2 2Li3N 4) NaNO2 (bo ha) + NH4Cl (bo ha) N2 + Cc phn ng ng l A. (1) v (2). B. (1) v (3). C. (3) v (4). D. (1),(3) v (4). 30. Thc hin phn ng trong bnh kn c dung tch 500 ml vi 1mol N2 , 4mol H2 v mt t xc B. 3 cht. C. 2 cht.
C 500 C 3000 C 30
0 0 0

D. 1 cht.

29. Cho cc phn ng (vi cc iu kin cho km theo): (1) (2) (3)

NaCl + 2H2O (4)

tc ( c th tch khng ng k). Khi phn ng t ti trng thi cn bng th p sut trong bnh bng 0,8 ln p sut ban u khi cha xy ra phn ng cng nhit . Hng s cn bng ca phn ng N 2 +3H2 2NH3 xy ra trong bnh l A. 0,016. B. 0,032. C. 0,128. D. 0,80. 31. Cho 19,2 gam Cu vo 500 ml dung dch NaNO3 1M, sau thm 500 ml dung dch HCl 2M n phn ng hon ton thu c kh NO v dung dch X. Phi thm bao nhiu lt dung dch NaOH 0,4M kt ta ht ion Cu2+ trong dung dch X? A. 1 lt. 32. T enang thuc loi A. t axetat. B. t poliamit. C. t tm. D. t polieste. 33. Ha tan hon ton m gam hn hp bt gm Fe3O4 v FeCO3 trong dung dch HNO3 d, thu c 3,36 lt hn hp X gm hai kh (ktc) v dung dch Y. T khi hi ca X i vi hiro bng 22,6. Gi tr ca m l A. 6,96 gam. B. 13,92 gam. C. 15,24 gam. D. 69,6 gam. 34. Cho hn hp kh X gm mt anken v hiro (trong hiro chim 60% th tch) i qua ng s cha Ni un nng, thu c hn hp Y. t chy hon ton hn hp Y ri hp th sn phm chy vo bnh nc vi trong d th khi lng bnh tng 3,02 gam v trong bnh to ra 4 gam kt ta. Th tch kh X o iu kin tiu chun l A. 0,448 lt. B. 0,4032 lt. C. 1,12 lt. D. 0,672 lt. 35. Cho qu tm vo mi dung dch sau: phn chua; xo- a; nc gia-ven; nc cng toan; nc oxi gi. S lng dung dch lm qu tm chuyn thnh mu hng () l A. 2. B. 3. C. 4. D. 5. B. 1,5 lt. C. 2 lt. D. 1,25 lt.

36. Cho lung kh CO d i qua ng s ng hn hp Fe3O4 v CuO un nng n phn ng hon ton, thu c 2,32 gam hn hp kim loi. Kh thot ra cho hp th vo bnh ng dung dch Ca(OH)2d thy to ra 5 gam kt ta. Khi lng hn hp hai oxit kim loi ban u l A. 3,12 gam. B. 3,92 gam. C. 3,22 gam. D. 4,20 gam. 37. Nung hn hp bt gm Al v Fe2O3 trong bnh kn mt thi gian thu c hn hp X gm Fe, FeO, Fe2O3, Fe3O4 v Al. Ha tan ht X bng dung dch HNO3 d thu c 1,344 lit (ktc) kh No 9 l sn phm kh duy nht). Khi lng ca Al trong hn hp ban u l A. 0,81 gam. B. 1,62 gam. C. 3,24 gam. D. 0,27 gam. 38. Hp cht X ch cha mt loi nhm chc, c 1mol X phn ng va ht vi 2mol NaOH. Khi t chy hon ton a mol cht X cn dng va ht b mol O2, sn phm ch gm c mol CO2 v dmol H2O, trong c+0,5d-b=2a. Vy X c th thuc loi A. iphenol. ng. 39. Nguyn t nguyn t R c cu hnh c cu hnh electron lp v ngoi cng l ns 2np3 v c tng s electron lp v t hn 30. Khi cho R phn ng vi clo to ra RCl3 hoc RCl5. vy R l A. rn. Gi tr ca m l A. 13,6 gam. B. 15,2 gam. C. 20,0 gam. D. 43,6 gam. 41. Cho 21,6 gam cht X (C2H8O3N2) tc dng vi 400 ml dung dch NaOH 1M, un nng. Sau phn ng thu c dung dch Y v cht kh Z lm xanh giy qu tm tm t. C cn dung dch Y th khi lng cht rn khan thu c l A. 11,4 gam. B. 25,0 gam. C. 30,0 gam. D. 21,8 gam. 42. Cho glixerol tc dng vi hn hp 3 axt bo gm C17H35COOH , C17H33COO v C17H31COOH th c th to ra ti a bao nhiu este 3 ln este? A. 9. tran- ? A. 2. B. 3. C. 4. D. 5. 44. t chy hon ton 4,4 gam hirocacbon X thu c tng th tch kh CO2 v hi nc (ktc) l 15,68 lt. Vy X c th to ra s lng dn xut iclo l A. 1 cht. B. 2 cht. C. 3 cht. D. 4 cht. 45. Chia hn hp X gm Cu v Fe thnh 3 phn bng nhau. Phn 1 tc dng vi dung dch H 2SO4 long, d, to ra 4,48 lt kh H2 (ktc). Phn 2 cho vo 200ml dung dch FeCl3 1M, sau khi phn ng B. 15. C. 12. D. 18. 43. Hy cho bit ankaien CH3CH = CHCH = CHCH3 c bao nhiu ng phn hnh hc cis- , N. B. P. C. Al. D. As. 40. Nhit phn hon ton 25,2 gam amoni icromat n phn ng hon ton thu c m gam cht B. ieste hoc iaxit. C. Este n chc ca phenol. D. C A,B,C u

xy ra hon ton thy cn li 12 gam cht rn khng tan. Cho phn 3 tc dng ht vi clo th thu c m gam cht rn. Gi tr ca m l A. 28,4 gam. A. 0,001. B. 38,9 gam. B. 0,01. C. 40,4 gam. C. 0,1. D. 46,0 gam. D. 0,3. 46. Dung dch CH3COOH 0,1M c pH=3.

in li ca CH3COOH trong dung dch bng

47. C 4 l ha cht b mt nhn ng ring bit 4 dung dch khng mu sau y: NH4Cl, KCl, BaCl2 , K2CO3. C th s dng thuc th no sau y phn bit cc l dung dch trn? A. HCl. B. H2SO4. C. NaOH. D. Qu tm. 48. Hy cho bit trong cc phn ng sau, khi ly cng s mol H2SO4 tc dng hon ton vi mi cht th phn ng no c lng CuSO4 thu c l t nht? A. H2SO4 + CuO C. H2SO4 + CuCO3 B. H2SO4 + Cu(OH)2 D. H2SO4 c + Cu

49. Trn 18 gam axit axetic vi 23 gam ancol etylic ri un nng mt thi gian. Sau khi ngui hn hp v tch ring ht este th c hn hp lng X. Cho ton b X tc dng ht vi Na thu c 6,72 lit H2 (ktc). Vy s gam este to ra l A. 8,8 gam. B. 17,6 gam. C. 26,4 gam. D. 44 gam. 50. Ha tan ht 30,4 gam hn hp gm CuO v FeO bng dung dch HCl d, thu c dung dch X. Chia dung dch X thnh 2 phn bng nhau. Phn 1 cho tc dng vi dung dch NH3 d, sau lc ly kt ta, nung trong khng kh n khi lng khng khng i thu c 16gam cht rn. C cn phn 2 thu c cht rn khan Z. un nng ton b cht rn Z vi lng d H2SO4 c ri dn kh v hi i qua bnh ng lng d P2O5, th th tch kh (ktc) cn li i qua bnh ng P2O5 l A. 11,648 lt. p n: 1.C 11.D 21.A 31.C 41.B 2.A 12.D 22.B 32.B 42.D 3.D 13.C 23.B 33.B 43.B 4.A 14.B 24.D 34.C 44.D 5.D 15.B 25. A 35.A 45.D 6.B 16.B 26.B 36.A 46.B 7.C 17.C 27.C 37.B 47.D 8.D 18.C 28.A 38.B 48.D 9.C 19.B 29.C 39.B 49.B 10.D 20.C 30.B 40.B 50.A B. 9,408 lt. C. 8,96 lt. D. 11,2 lt. Ht..

THI TH I HC CAO NG LN 2 NM 2013

MN HO HC

Thi gian lm bi: 90 pht; 50 cu trc nghim

H, tn th sinh:........................................................................ Lp : .. S bo danh:
Cu 1: Ha tan ht 0,03 mol mt oxit st c cng thc Fe xOy vo dung dch HNO3 long d thu c 0,01 mol mt

oxit nit c cng thc NzOt (sn phm kh duy nht). Mi quan h gia x, y, z, t l A. 9x -6y = 5z 2t. B. 9x -8y = 5z 2t. C. 27x -18y = 5z 2t. D. 3x -2y = 5z 2t. Cu 2: Tn gi hp cht CTCT sau: CH3-OOC-CH2-COO-CH(CH3)2 A. metylisopropylbutaioat. B. metylisopropylmalonat C. metylisopropyloxalat D. propylmetylmalonat Cu 3: sn xut c 16,9 tn oleum H2SO4.3SO3 phi dng m tn qung pirit cha 16% tp cht tr, hiu sut ca qu trnh sn xut l 80%. Gi tr ca m l: A. 8,64 tn B. 17,85 tn C. 16,67 tn D. 12 tn Cu 4: Pht biu no sau y khng ng? A. Nhng hp cht hnh thnh bng cch ngng t hai hay nhiu -aminoaxit c gi l peptit B. Phn t c hai nhm - CO-NH- c gi l ipeptit, ba nhm th c gi l tripeptit C. Cc peptit c t 10 n 50 n v amino axit cu thnh c gi l polipeptit D. Trong mi phn t protit, cc aminoaxit c sp xp theo mt th t xc nh Cu 5: Hn hp X gm 0,1 mol propenal v a mol kh hidro. Cho hn hp X qua ng s nung nng c cha Ni lm xc tc, thu c hn hp Y gm propanal, propan-1-ol, propenal v 0,15 mol hidro. T khi hi ca hn hp Y so vi metan bng 1,55. Gi tr ca a l A. 0,20 B. 0,35 C. 0,3 D. 0,25 Cu 6: Oxi ha m gam ancol etylic mt thi gian thu c hn hp X. Chia X thnh 3 phn bng nhau: - Phn 1 tc dng va vi dung dch NaHCO3 thot ra 4,48 lt kh. - Phn 2 tc dng vi Na d thot ra 8,96 lt kh- Phn 3 tc dng vi dung dch AgNO3/NH3 d to thnh 21,6 gam Ag. Cc phn ng ca hn hp X xy ra hon ton. Th tch kh o ktc. Gi tr ca m v hiu sut phn ng oxi ha ancol etylic l A. 82,8 v 50% B. 96,8 v 42,86% C. 96 v 60% D. 124,2 v 33,33% Cu 7: t chy hon ton 0,1 mol hn hp R gm 1 andehit X v 1 axit cacboxylic Y (trong phn t X hn Y mt nguyn t cacbon) thu c 3,36 lt (ktc) CO2 v 1,8 gam nc. Khi cho 0,2 mol R tc dng vi dung dch. AgNO3/NH3 d thu c m gam Ag. Gi tr m l: A. 64,8. B. 86,4. C. 43,2. D. 32,4. Cu 8: Ha tan m gam hn hp Na2CO3 v KHCO3 vo nc c 400 ml dung dch X. Cho t t 100 ml dung dch HCl 1,5M vo dung dch X, thu c dung dch Y v 1,008 lt kh (ktc). Cho Y tc dng vi Ba(OH) 2 d thu c 29,55 gam kt ta. Cho t t dung dch X vo bnh ng 100 ml dung dch HCl 1,5M, thu c V lt kh (ktc). Gi tr ca m v V l: A. 20,13 v 2,688. B. 20,13 v 2,184. C. 18,69 v 2,184. D. 18,69 v 2,688. Cu 9: Cho hn hp X gm 11,6 gam oxit st t v 3,2 gam Cu tc dng vi 400 ml dung dch HCl 1M. Kt thc phn ng, cho dung dch thu c tc dng vi dung dch AgNO3 d th khi lng kt ta thu c l A. 28,7 gam. B. 73,6 gam. C. 57,4 gam. D. 114,8 gam. Cu 10: Trong cc pht biu sau, c bao nhiu pht biu ng ? (a) Cho dung dch KMnO4 tc dng vi dung dch HF (c) thu c kh F2. (b) Dng phng php sunfat iu ch c : HF, HCl, HBr, HI. (c) Hn hp tecmit l hn hp bt Al vi Fe2O3. (d) Amophot (hn hp cc mui NH4H2PO4 v (NH4)2HPO4 ) l phn hn hp. (e) Trong phng th nghim, kh CO c iu ch bng cch cho H2SO4 c vo axit fomic v un nng. (f) Thp l hp cht ca st v cacbon trong cacbon chim t 0,01-2% khi lng cng vi mt s nguyn t khc (Si, Mn, Cr, Ni...). (g) Cho oxit st t tc dng hon ton vi dung dch axit HI d, sn phm thu c l st(II) iotdua v st(III) iotdua. A. 4 B. 2 C. 3 D. 5 Cu 11: Trong s cac phat biu sau v anilin : (1) Anilin tan it trong nc nhng tan nhiu trong dung dich NaOH. (2) Anilin co tinh baz, dung dich anilin khng lam i mau quy tim. (3) Anilin dung san xut phm nhum, dc phm, polime. (4) Anilin tham gia phan ng th brom vo nhn thm d hn benzen. Cac phat biu ung la

A. (2), (3), (4) B. (1), (2), (3) C. (1), (3), (4) D. (1), (2), (4) Cu 12: Hn hp gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc, un nng c hn hp Y. Dn Y qua nc brom thy bnh nc brom tng 10,8 gam v thot ra 4,48 lit hn hp kh (ktc), c t khi so vi hidro l 8. Th tch kh O2 (ktc) va t chy hon ton hn hp Y l A. 26,88 lit B. 44,8 lit C. 33,6 lt D. 22,4 lit Cu 13: Cho cc trng hp sau: (1) O3 tc dng vi dung dch KI. (2) Axit HF tc dng vi SiO2. (3) MnO2 tc dng vi dung dch HCl c, un nng. (4) Kh SO2 tc dng vi nc Cl2. (5) KClO3 tc dng vi dung dch HCl c, un nng. (6) un nng dung dch bo ha gm NH4Cl v NaNO2. (7) Cho kh NH3 qua CuO nung nng. (8) dung dch FeCl2 + dung dch AgNO3 (9) dung dch CuSO4 + dung dch NaI S trng hp to ra n cht l A. 5. B. 4. C. 6. D. 7. Cu 14: Nguyn t nguyn t Xc tng ht c bn l 76 ht. Trong X, s ht mang in nhiu hn s ht khng mang in l 20. trng thi c bn X c s electron c thn l: A. 5 B. 3 C. 6 D. 4 Cu 15: Cho m gam hn hp bt X gm Fe, Cu vo 600 ml dung dch AgNO 3 1M. Sau khi kt thc phn ng thu c dung dch Y gm 3 mui (khng cha AgNO3) c khi lng gim 50 gam so vi ban u. Gi tr ca m l A. 64,8. B. 17,6. C. 114,8. D. 14,8. Cu 16: Ha tan ht m gam hn hp cc kim loi gm Zn, Al, Fe, Cu, Ag, Ni, Cr c cng s mol trong dung dch HNO3 long, nng d th thu c dung dch X. Cho dung dch X tc dng vi dung dch NaOH d n phn ng hon ton, tip tc ly phn khng tan trong tc dng vi dung dch NH 3 d th cn li 2,14 gam cht rn. Gi tr ca m l A. 4,61. B. 8,96. C. 4,40. D. 8,62. Cu 17: X,Y,Z l ba hp cht thm c cng thc phn t l C 7H6Cl2. Khi un nng vi dung dch NaOH long th X phn ng theo t l mol 1:2. Y phn ng theo t l mol 1:1. Z khng phn ng. S ng phn cu to ca X,Y,Z l: A. 1,3,6. B. 1,3,5. C. 1,3,4. D. 1,2,3. Cu 18: Tin hnh cc th nghim sau: (a) NO2 + NaOH (d) ; (b) NaHSO4 + KOH (d) ; (c) Ca(HCO3)2 + NaOH (d) ; (d) Ca(OH)2 (d) + NaHCO3 S th nghim c hai mui sau phn ng l A. 2 B. 3 C. 1 D. 4 Cu 19: Cho 0.3 mol hn hp axitglutamic v glyxin vo dung dch 400 ml HCl 1M thu c dung dch Y.Y tc dng va 800 ml dung dch NaOH 1M thu c dung dch Z. Lm bay hi Z thu c m (g) rn khan? A. 61,9 gam B. 55,2 gam C. 31,8 gam D. 28,8 gam Cu 20: S iu ch PVC trong cng nghip hin nay l TH ,Cl t , Pcao 2 A. C2H4 C2H3Cl PVC o TH HCl , t , Pcao 1500 C B. CH4 C2H2 C2H3Cl PVC TH ,Cl t HCl , Pcao 2 C. C2H6 C2H5Cl C2H3Cl PVC TH ,Cl t HCl , Pcao 2 D. C2H4C2H4Cl2 C2H3Cl PVC Cu 21: Trong cc cht: Cl2, Cr2(SO4)3, HCl, FeCl3, Fe(NO3)2, Cu(NO3)2, FeSO4, Fe2(SO4)3. S cht c c tnh oxi ha v tnh kh l: A. 4 B. 6 C. 7 D. 5 Cu 22: Cho cn bng (trong bnh kn) sau: > 0t: (1) gim nhit ; (2) thm mt lng CO; (3) CH4(k) + H2O (k) CO(k) + 3 H2(k) . Trong cc yu H thm mt lng H2O; (4) tng p sut chung ca h; (5) dung xc cht xc tc. Dy gm yu t lm cn bng ca h dich theo chiu nghch l: A. (2), (3), (4). B. (1), (2), (5). C. (1), (4), (5). D. (1), (2), (4). Cu 23: Nhit phn hon ton a mol CaCO3 thu c CaO v CO2. Cho CaO vo dung dch cha b mol HCl thu c dung dch X. Hp th ton b kh CO2 trn vo dung dch X thu c m gam kt ta. Mi quan h gia m,a,b l: A. m = 100(a-b) B. m = 50(a-2b) C. m = 50(2a-b) D. m = 100(a-2b)

Cu 24: Cho hn hp M gm Fe3O4 v Cu vi t l khi lng tng ng l 3,625/1 tc dng vi dung dch H2SO4 long d thu c dung dch X. Cho dung dch X ln lt phn ng vi cc cht: KMnO 4, Na2CO3, AgNO3, KI, Cu, Ag, NaOH, Br2, MgSO4, Mg(NO3)2, Al. S trng hp c phn ng xy ra l: A. 5. B. 6. C. 7 D. 8. Cu 25: thu ly Ag tinh khit t hn hp X (gm a mol Al 2O3, b mol CuO, c mol Ag2O), ngi ta ho tan X bi dung dch cha (6a + 2b + 2c) mol HNO 3 c dung dch Y, sau thm (gi thit hiu sut cc phn ng u l 100%) A. 2c mol bt Cu vo Y. B. 2c mol bt Al vo Y. C. c mol bt Cu vo Y. D. c mol bt Al vo Y. Cu 26: Cho hn hp X gm hai hidrocacbon l ng ng k tip, t khi X so v H 2 l 15,8. Cho 6,32 g hn hp X qua 100 g dung dch Y un nng, c xc tc thch hp, sau phn ng thu c dung dch M v 2,688 (l) kh N (ktc) thot ra. T khi ca N so vi H2 l 16,5. Cho bit dung dch M cha andehit vi C% l : A. 3,4 % B. 2,64 % C. 2,58 % D. 3,52 % Cu 27: Cho cc phn ng nhit thng? (1) Mg(HCO3)2 + Ca(OH)2 d MgCO3+ CaCO3+ 2H2O. (2) Ca(HCO3)2 + Ba(OH)2 CaCO3+ BaCO3 + 2H2O. (3) Ca(OH)2 + 2NH4Cl CaCl2 + 2H2O + 2NH3. (4) CaCl2 + 2 NaHCO3 CaCO3+ 2NaCl + 2HCl. (5) 2CrCl3 + 3Cl2 + 14NaOH Na2Cr2O7 + 12NaCl + 7H2O. C bao nhiu phn ng cha chnh xc? A. 4. B. 1. C. 2. D. 3. Cu 28: Cho dy cc hp cht thm: p-HO-CH2-C6H4-OH, p-HO-C6H4-COOC2H5, p-HO-C6H4-COOH, p-HCOO-C6H4-OH, p-CH3O-C6H4-OH. C bao nhiu cht trong dy tha mn ng thi 2 iu kin sau? (a) Ch tc dng vi NaOH theo t l mol 1 : 1. (b) Tc dng c vi Na (d) to ra s mol H2 bng s mol cht phn ng. A. 2. B. 4. C. 1. D. 3. Cu 29: Ha tan hon ton m gam AlCl3 vo nc c dung dch X. Nu cho 130 ml dung dch NaOH 1M vo X th c m1 gam kt ta. Mt khc, nu cho 150 ml dung dch NaOH 1M vo X th thu c m 2 gam kt ta. Bit m1 = 3m2. Gi tr ca m l: A. 5,34 B. 5,49 C. 10,65 D. 12,84 Cu 30: Cho cc nguyn t M(Z = 11); X(Z = 17); Y(Z = 9) v R(Z = 19). m in ca cc nguyn t tng dn theo th t: A. M<X<Y<R B. R<M<X<Y C. Y<M<X<R D. M<X<R<Y Cu 31: Cho cc cht p-crezol, anilin, benzen, axit acrylic, axit fomic, axetilen, andehit metacrylic S cht phn ng vi Br2 iu kin thng trong dung mi nc vi t l 1:1 l: A. 2 B. 3 C. 5 D. 4 Cu 32: Cho 2,7 gam Al tc dng vi 150 ml dung dch X cha Fe(NO 3)3 0,5 M v Cu(NO3)2 0,5 M. Sau khi kt thc phn ng thu c m gam cht rn. Gi tr ca m l: A. 6,9 gam. B. 18,0 gam. C. 13,8 gam. D. 9,0 gam. Cu 33: Pht biu no sau y ng? A. Dung dch saccaroz to c kt ta gch khi phn ng vi Cu(OH)2. B. Sobitol l hp cht a chc. C. Xenluloz thuc loi polime tng hp. D. Tinh bt v xenluloz u khng c phn ng ca ancol a chc. Cu 34: Nhng 5 thanh Fe vo 5 dung dch sau: Cu(NO 3)2; (FeCl3, HCl); (CuSO4, H2SO4); (Pb(NO3)2, HNO3); (MgCl2, HCl). S trng hp n mn in ha l: A. 1 B. 2 C. 3 D. 4 Cu 35: Khi thu phn 1 peptit, ch thu c cc ipeptit Glu-His ; Asp-Glu ; Phe-Val v Val-Asp. Cu to peptit em thu phn l A. His- Asp- Glu-Phe-Val-Asp-Glu. B. Asp-Glu-Phe-Val-Asp-Phe-Val-Asp. C. Phe-Val-Asp-Glu-His. D. Glu-Phe-Val-Asp-Glu-His-Asp-Val-Asp. Cu 36: Cho cc phn ng sau trong dung dch (1) Na2CO3 + AlCl3 ; (2) Na2CO3 + H2SO4 ; (3) NaHCO3 + Ba(OH)2 (4) Na2S + AlCl3

(7) CuCO3 + dung dch HF (5) (NH4)2CO3 + Ba(OH)2 (6) Na2CO3 + CaCl2 Cc phn ng to ng thi kt ta v kh l: A. (1),(4),(6). B. (1),(2),(5). C. (1),(4),(5), (7). D. (2),(3),(5). Cu 37: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco, t nitron, cao su buna, t capron Trong , s polime c iu ch bng phn ng trng hp l: A. 7 B. 5 C. 6 D. 4 Cu 38: Nung 35,8 gam hn hp X gm FeCO3 v MgCO3 trong khng kh n khi lng khng i, cm li 22 gam cht rn. Hp th ton b lng kh CO2 sinh ra vo dung dch Y cha 0,1 mol Ba(OH) 2 v 0,2 mol NaOH. Khi lng kt ta thu c sau phn ng l A. 19,7 gam. B. 17,73 gam. C. 39,4 gam. D. 9,85 gam. Cu 39: Hn hp X gm 2 anehit no n chc mach h Y,Z (MY <MZ). Chia X thanh 2 phn bng nhau. Phn 1. tac dung vi dung dich AgNO3 trong NH3 d thu c 64,8 gam Ag Phn 2. oxi hoa hoan toan thanh hn hp axit R. Trung hoa R cn 200ml dung dich NaOH 1M thu c dung dich M. C can M, t chay hoan toan cht rn sinh ra thu c 8,96 lit CO2 (ktc). Cng thc phn t cua Z la: A. C3H7CHO B. CH3CHO C. C2H5CHO D. C4H9CHO Cu 40: Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m gam X phn ng ht vi dung dch NaHCO3 thu c 1,344 lt CO2 (ktc). t chy hon ton m gam X cn 2,016 lt O 2 (ktc), thu c 4,84 gam CO2 v a gam H2O. Gi tr ca a l A. 3,60. B. 1,80. C. 1,62. D. 1,44. Cu 41: Ho tan cng mt lng oxit ca kim loi M (c ho tr khng i) trong dung dch HCl v dung dch HNO3. C cn 2 dung dch thu c 2 mui khan, thy khi lng mui nitrat nhiu hn khi lng mui clorua mt lng bng 99,38 % khi lng oxit em ho tan. Cng thc oxit l A. MgO B. Fe2O3 C. Al2O3 D. CuO Cu 42: Ha tan ht 52 gam kim loi M trong 739 gam dung dch HNO3, kt thc phn ng thu c 0,2 mol NO ; 0,1 mol N2O v 0,02 mol N2. Bit khng c phn ng to mui NH4NO3 v HNO3 ly d 15% so vi lng cn thit. Kim loi M v nng phn trm ca HNO3 ban u ln lt l A. Zn v 17,39 B. Cr v 20 C. Cr v 21,96 D. Zn v 20 Cu 43: Khi nung butan vi xc tc thch hp n phan ng hoan toan thu c hn hp T gm CH 4, C3H6, C2H4, C2H6, C4H8, H2 v C4H6. t chy hon ton hn hp T thu c 8,96 lt CO 2 (o ktc) v 9,0 gam H 2O. Mt khc, hn hp T lm mt mu va ht 19,2 gam Br2 trong dung dch nc brom.Phn trm v s mol cua C4H6 trong T la: A. 16,67%. B. 9,091%. C. 22,22%. D. 8,333%. Cu 44: Cc pht biu sau: a) C 3 xeton c CTPT C5H10O b) Andehit v xeton u khng lm mt mu nc Br2 c) t chy hon ton andehit thu c n H2O = n CO2 th andehit l no, n chc, mch h. d) HCN, H2, KMnO4, nc Br2, Br2 khan/CH3COOH , s cht phn ng vi axeton iu kin thch hp l 2. e) HCHO iu kin thng l cht kh khng mu tan tt trong nc f) Andehit va c tnh OXH, va c tnh kh g) Andehit cng hp H2 to ancol bc 2, xeton cng hp H2 to ancol bc 1 Pht biu ng l: A. c,d,f,g B. a,c,d,g C. b,c,e,f D. a,c,e,f Cu 45: Fructoz khng c tnh cht no sau y? A. Lm mt mu dung dch Br2. B. B oxi ho bi phc bc amoniac v Cu(OH)2 un nng. C. Tnh cht ca poliol. D. Tc dng vi CH3OH/HCl. Cu 46: t chy hon ton 2,76 (g) hn hp X gm C xHyCOOH, CxHyCOOCH3 v CH3OH thu c 2,688 (l) CO2 v 1,8 (g) H2O. Mt khc, 2,76 (g) X phn ng va vi 30 ml dung dch NaOH 1M, thu c 0,96 (g) CH3OH. Cng thc ca CxHyCOOH l: A. C3H5COOH B. C2H3COOH C. C2H5COOH D. CH3COOH Cu 47: Crackinh hoan toan mt th tich ankan X thu c 3 th tich hn hp Y. Ly 6,72 lit Y(kc) lam mt mau va u dung dich cha a mol Br2. Gia tri cua a la:

A. 0,1 B. 0,3 C. 0,6 D. 0,2 2+ Cu 48: Cho a mol Al vo dung dch cha b mol Fe v c mol Cu2+. Kt thc phn ng thu c dung dch cha 2 loi ion kim loi. Kt lun no sau y l ng ? 2cb 2(b + c) a < A. . B. . C. . D. . 3 3 Cu 49: X l hp cht hu c n chc C,H,O . Cho 1 lng cht X tc dng hon ton vi 500 ml dung dch KOH 2,4M ri c cn c 105(g) rn khan Y v m(g) ancol. Oxi ha m(g) ancol bng oxi c xc tc c hn hp Z, chia Z thnh 3 phn bng nhau : Phn 1: tc dng vi AgNO3/NH3 d thu c 21,6(g) Ag Phn 2: tc dng vi NaHCO3 d thu c 2,24(l) kh (ktc) Phn 3:tc dng vi Na (va ), thu c 4,48(l) kh (ktc) & 25,8(g) rn khan. Xc nh CTPT ca X. Bit ancol un vi axit sunfuric c nng,170oC to olefin: A. C6H12O2 B. C3H6O2 C. C4H8O2 D. C5H10O2 Cu 50: Cho 8(g) bt Cu vo 200ml dung dch AgNO3, sau 1 thi gian phn ng lc c dung dch A v 9,52(g) cht rn. Cho tip 8 (g) bt Pb vo dung dch A, phn ng xong lc tch c dung dch B ch cha 1 mui duy nht v 6,705(g) cht rn. Nng mol/l ca AgNO3 ban u l: A. 0,25M. B. 0,1M C. 0,35M. D. 0,20M.
-------- Ht ------Cho bit khi lng nguyn t (theo vC) ca mt s nguyn t : H = 1 ; C = 12 ; N = 14 ; O = 16 ;Na = 23; Mg = 24; Al = 27 ; S = 32 ; Cl = 35,5 ; K = 39 ; Ca = 40; Cr = 52; Fe = 56 ; Cu = 64; Br = 80; Ag = 108; I = 127; Ba = 137 ; Pb = 207; KK = 29

 THI TH I HC MN: HA HC H, tn th sinh:..................................................................... S bo danh: .............................

Cho bit: H = 1, C=12, N= 14, O =16, Na = 23, Mg =24, Al = 27, S= 32, Ca = 40, Cr= 52, Ni= 59, Cu =64 , Ag =108, Ba= 137, Pb= 207, Br =80, P =31, Fe =56, Cl =35,5.
Cu 1: Hp th hon ton V lit CO2 (ktc) vo bnh ng 200ml dung dch NaOH 1M v Na 2CO3 0,5M. C cn dung dch sau phn ng thu c 19,9 gam cht rn khan. Gi tr V l A. 2,24 B. 3,36 C. 5,6 D. 1,12 Cu 2: X, Y la 2 nguyn t kim loai cung mt phn nhom chinh (nhom A). Bit Z X < ZY va ZX + ZY = 32. Kt lun nao sau y la ung i vi X, Y? A. X, Y u co 2 electron lp ngoai cung B. Tinh lim loai cua X > Y . C. Ban kinh nguyn t cua X > Y. D. Nng lng ion hoa I1 cua X < Y Cu 3: Cho Cacbon (C) ln lt tc dng vi Al, H 2O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 6. B. 5. C. 4. D. 7. Cu 4: Tin hnh cc th nghim sau : (1) Thu phn tinh bt thu c hp cht A. (2) Ln men gim ancol etylic thu c hp cht hu c B. (3) Hyrat ho etylen thu c hp cht hu c D. (4) Hp th C2H2 vo dung dch HgSO4 800C thu c hp cht hu c E. Chn s phn ng ng biu din mi lin h gia cc cht trn. Bit mi mi tn l mt phn ng A. D E B A B. A D B E C. E B A D D. A D E B Cu 5: Cho cc monome sau: stiren, toluen, metyl axetat, vinyl axetat, metyl metacrylat, metyl acrylat, propilen, benzen, axit etanoic, axit -aminocaproic. S monome tham gia phn ng trng hp l A. 8. B. 7. C. 5. D. 6. Cu 6: C bao nhiu ng phn mch h ng vi CTPT C 4H8O tc dng vi H2 (Ni, toC) to ra butan-1-ol. A. 1 B. 3 C. 6 D. 4 0 +H + a lit+ dd NaOH 2O t 0,1M O du, Cu 7: Cho s : Photpho (a gam) X dd Y 2 dd Z Cht tan trong dung dich Z gm: A. Na3PO4 va NaHPO4. B. Na3PO4 va NaOH. C. Na2HPO4 va NaH2PO4. D. NaH2PO4 va H3PO4. Cu 8: Nhit phn hon ton 44,1 gam hn hp X gm AgNO 3 v KNO3 thu c hn hp kh Y. Trn Y vi a mol NO2 ri cho ton b vo nc ch thu c 6 lt dung dch (cha mt cht tan duy nht) c pH = 1. Gi tr ca a l: A. 0,5. B. 0,2. C. 0,3. D. 0,4. Cu 9: Trn 100ml dung dch CH3COOC2H5 1M vi 100ml dung dch NaOH. Sau 15 pht nng ca CH3COOC2H5 cn li l 0,2M. Tc trung bnh ca phn ng trong 15 pht l A. 0,0533 mol/lt.pht B. 0,033 mol/lt.pht C. 0,02 mol/lt.pht D. 0,0133 mol/lt.pht Cu 10: t chy hon ton 25,3 gam hn hp X gm RCOOH, C 2H3COOH, v (COOH)2 thu c m gam H2O v 15,68 lt CO2 (ktc). Mt khc, 25,3 gam hn hp X phn ng hon ton vi NaHCO 3 d thu c 11,2 lt (ktc) kh CO2.Gi tr ca m l A. 10,8 gam. B. 7,2 gam. C. 16,2 gam. D. 8,1gam. Cu 11: Cho 47 gam hn hp X gm 2 ancol i qua Al 2O3, nhit , thu c hn hp Y gm 3 ete, 0,27 mol 2 olefin, 0,33 mol 2 ancol d v 0,42 mol nc. Bit rng hiu sut tch nc to olefin i vi mi ancol nh nhau v s mol cc ete l bng nhau. Ancol c khi lng phn t ln trong X l: A. C3H7OH. B. C4H9OH. C. C5H11OH. D. C6H13OH. Cu 12: Cho 13,8 gam cht hu c X c cng thc phn t C 7H8 tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn? A. 2. B. 6. C. 4. D. 5. Cu 13: Trung ho 5,4 gam X gm CH 3COOH, CH2=CHCOOH, C6H5OH v C6H5COOH cn dung Vml dung

dch NaOH 0,1M. C cn dung dch sau phn ng thu c 6,94 gam hn hp cht rn khan. Gi tr V l A. 669,6. B. 700,0. C. 334,8. D. 350,0. Cu 14: Nung m gam gm Al v Fe xOy trong iu kin khng c khng kh cho n khi phn ng hon ton thu c hn hp X. Trn u X, chia X thnh 2 phn. Phn 1 (c khi lng 14,49 gam) ha tan ht trong dung dch HNO3 d thu c 0,165 mol kh NO (sn phm kh duy nht). Phn 2 tc dng ht vi dung dch NaOH nhit thy gii phng 0,015 mol H2 v cn li 2,52 gam cht rn. Cng thc st oxit v gi tr m l: A. Fe2O3 ; 19,32. B. Fe3O4 ; 28,98. C. Fe2O3 ; 28,98. D. Fe3O4 ; 19,32. Cu 15: Nu vt lm bng hp kim Fe-Zn b n mn in ho th trong qu trnh n mn A. Km ng vai tr catot v b oxi ho. B. St ng vai tr catot v b oxi ho. C. St ng vai tr anot v b oxi ho. D. Km ng vai tr anot v b oxi ho. Cu 16: Cho X + Cu(OH)2/OH- dung dch Y xanh lam. Dung dch Y un nng kt ta Z gch Trong tt c cc cht: glucoz, saccaroz, mantoz, fructoz, tinh bt, andehit axetic, glixerol s cht X tho mn l. A. 2 B. 4 C. 3 D. 5 Cu 17: Trong cc pht biu sau: (1) Ging nh H2SO4, H2CrO4 cng rt bn. (2) Crom tan trong dung dch HCl d to ra dung dch CrCl 3. (3) Ion CrO42- c mu vng, ion Cr2O72- c mu da cam nn cc dung dch Na 2CrO4 v K2Cr2O7 c mu tng ng. (4) Mui Cr (III) c c tnh oxi ha v tnh kh. (5) Cr2O3 cng nh CrO3 tan d dng trong dung dch kim long. Cc pht biu ng l: A. (1) v (3). B. (3) v (4). C. (2), (4) v (5). D. (3), (4) v (5). Cu 18: Cho m gam Al tc dng vi dung dch HCl 18,25% va thu c dung dch A v kh H2. Thm m gam Na vo dung dch A thu c 3,51 gam kt ta. Khi lng ca dung dch A l: A. 71,76 gam B. 70,84 gam C. 74,86 gam D. 72,105 gam Cu 19: Nhn nh no sau y ng? A. Cc nguyn t c 2 electron lp ngoi cng u nhm IIA hoc IIB B. Cc nguyn t nhm VIIIA u c 8 electron lp ngoi cng C. Cc nguyn t c 6 electron ha tr u nhm VIB D. Cc nguyn t c 9 electron ha tr u nhm VIIIB Cu 20: Pht biu no sau y l sai? A. Thch cao sng (CaSO4.2H2O) c dng b bt, c tng. B. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh. C. Thnh phn chnh ca qung olomit l CaCO3.MgCO3. D. Cc kim loi kim u c cu trc mng tinh th lp phng tm khi. Cu 21: Tm pht biu sai trong cc pht biu sau: A. Phenol l cht rn kt tinh iu kin thng B. Nhit si ca ankanol cao hn so vi ankanal c phn t khi tng ng. C. Metylamin l cht lng c mi khai, tng t nh amoniac. D. Etylamin d tan trong H2O Cu 22: Thc hin cc th nghim sau: (1) t dy st trong kh clo d. (2) t nng hn hp bt Fe v S (trong iu kin khng c oxi). (3) Cho FeO vo dung dch HNO3 long. (4) Cho Fe vo dung dch AgNO3 d. (5) Cho Fe3O4 vo dung dch HCl (long, d). C bao nhiu th nghim to ra mui st (III)? A. 1. B. 3. C. 2. D. 4. Cu 23: Ho tan Fe3O4 trong lng d dung dch H 2SO4 long thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br 2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al? A. 5. B. 6. C. 8. D. 7. Cu 24: in phn dung dch CuCl2 bng in cc tr, sau mt thi gian thu c m gam Cu catot v mt lng kh X duy nht anot. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH 0,1M ( nhit thng). Sau phn ng thu c dung dch Y cha 1,065 gam cht tan. Gi tr ca m l: A. 0,64. B. 1,28. C. 0,32. D. 0,16. Cu 25: Cho cn bng ha hc sau: N 2 (kh) + 3H2 (kh) 2NH3 (kh) ; H < 0. Vi cc bin php:

(1) tng nhit ; (2) tng p sut chung ca h phn ng; (3) h nhit ; (4) dng thm cht xc tc bt Fe; (5) gim nng NH3; (6) gim p sut chung ca h phn ng. S bin php no lm cn bng trn chuyn dch theo chiu thun? A. 5. B. 3. C. 6. D. 4. Cu 26: Hn hp X gm SO2 v O2 c t khi so vi H 2 bng 28. Ly 4,48 lit hn hp X (ktc) cho i qua bnh ng V2O5 nung nng. Hn hp thu c li qua dung dch Ba(OH) 2 d thy c 33,19 gam kt ta. Hiu sut phn ng oxh SO2 l A. 25% B. 60% C. 75% D. 40% Cu 27: Cho cc phn ng : (1) O3 + dung dch KI (2) F2+ H2O ( 3) KClO3 (rn) + HCl c (4) SO2 + dung dch H2S (5) Cl2 + dung dch H2S (6) NH3(d) + Cl2 (7) NaNO2 ( bo ho) +NH4Cl (bo ho) (8) NO2 + NaOH (dd) S phn ng to ra n cht l. A. 4 B. 5 C. 6 D. 7 Cu 28: Cho dy cc cht: benzyl axetat, vinyl axetat, metyl fomat, anlyl clorua, phenyl fomat, isopropyl clorua, triolein. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l: A. 4 B. 6 C. 5 D. 3 Cu 29: Cho t t dung dch HCl c pH = 1 vo dung dch cha 5,25 gam hn hp mui cacbonat ca 2 kim loi kim k tip nhau n khi c 0,015 mol kh thot ra th dng li. Cho dung dch thu c tc dng vi dung dch Ca(OH)2 d sinh ra 3 gam kt ta. Cng thc 2 mui v th tch dung dch HCl dng l A. Na2CO3 v K2CO3 ; 0,30 lt B. Na2CO3 v K2CO3 ; 0,60 lt C. Li2CO3 v Na2CO3 ; 0,30 lt D. Li2CO3 v Na2CO3 ; 0,60 lt Cu 30: Oxi ha 15,0 gam 1 anehit n chc thu c 21,4 gam hn hp X gm axit v anehit d. Cho hn hp X tc dng vi lng d AgNO 3 trong dung dch NH 3 un nng, sau khi phn ng hon ton th khi lng Ag thu c l: A. 43,2 gam. B. 129,6 gam. C. 64,8 gam. D. 21,6 gam. Cu 31: Trong cc loi polime sau. (1) t tm, (2) si bng, (3) Len, (4) T enang, (5) t visco, (6) nilon 6.6 , (7) t axetat. S t c ngun gc xenluloz l A. 3. B. 4. C. 2. D. 5. Cu 32: Hn hp X gm Fe2O3, Cr2O3, Al2O3. Cho 20,7 gam X vo dung dch NaOH c (d), sau khi kt thc phn ng thu c 8,0 gam cht rn v dung dch Y. Cho Br 2 d vo Y thu c dung dch Z. Cho dung dch BaCl2 d vo Z thu c 25,3 gam kt ta. Khi lng Al 2O3 trong 20,7 gam X l: A. 7,6 gam. B. 10,2 gam. C. 12,7 gam. D. 5,1 gam. Cu 33: Chn nhn xt ng? A. Nhit si ca CH3COOC2H5 < CH3CH2CH2COOH < CH3(CH2)3OH. B. Ging nh x phng, cht git ra tng hp khng th git ra trong nc cng. C. Ngy nay x phng cn c sn xut t ankan. D. M b i l do l do lin kt C-C ca gc axit bo b oxi ha chm bi oxi trong khng kh. Cu 34: Cho t t tng git ca dung dch cha b mol HCl vo dung dch cha a mol Na 2CO3 thu c V lt kh CO2. Ngc li, cho t t tng git ca dung dch cha a mol Na 2CO3 vo dung dch cha b mol HCl thu c 2V lt kh CO2 (cc th tch kh o cng iu kin). Mi quan h gia a v b l: A. a = 0,75b. B. a = 0,35b. C. a = 0,8b. D. a = 0,5b. Cu 35: Cho 15,84 gam este no, n chc, mch h tc dng va vi 30ml dung dch MOH 20% (d=1,2g/ml) vi M l kim loi kim. Sau phn ng hon ton, c cn dung dch thu c cht rn X. t chy hon ton X thu c hn hp kh v hi gm CO 2, H2O v 9,54 gam M2CO3. Kim loi M v cng thc cu to ca este ban u l : A. Na v HCOO-C2H5. B. Na v CH3COOC2H5. C. K v HCOO-CH3. D. K v CH3COOCH3. Cu 36: t chy hon ton 0,1 mol triglixerit X ta thu c 250,8 gam CO 2 v 90 gam H2O. Mt khc 0,1 mol X phn ng va vi V lt dung dch Br2 1M. Gi tr ca V l: A. 0,4. B. 0,5. C. 0,7. D. 0,3. Cu 37: Hn hp bt X gm BaCO3, Fe(OH)2, Al(OH)3, CuO, MgCO3. Nung X trong khng kh n khi lng khng i c hn hp rn A 1. Cho A1 vo nc d khuy u c dung dch B cha 2 cht tan v phn khng tan C1. Cho kh CO d qua bnh cha C 1 nung nng c hn hp rn E (Cho cc phn ng xy ra hon ton). E cha ti a: A. 2 n cht v 2 hp cht B. 1 n cht v 2 hp cht. C. 2 n cht v 1 hp cht D. 3 n cht Cu 38: Pht biu no sau y khng ng?

A. Aminoaxit l nhng cht rn kt tinh, tan tt trong nc v c v ngt. B. Trong dung dch, H2N-CH2-COOH cn tn ti dng lng cc H3N+-CH2-COO-. C. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin. D. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. Cu 39: Cho 0.1 mol cht X (CH6O3N2) tc dng vi dd cha 0.2 mol NaOH un nng thu c cht kh lm xanh giy qu tm m v dd Y. C cn dd Y thu c m gam rn khan. Gi tr ca m l: A. 15 gam. B. 8,5 gam. C. 12,5 gam. D. 21,8 gam. + 2 + Cu 40: Dung dch X cha 0,025 mol CO; 0,1 mol 3 Na ; 0,3 mol Cl , cn li l ion NH. Cho 270 ml dung 4 dch Ba(OH)2 0,2 M vo dung dch X v un nng nh. Hi tng khi lng dung dch X v dung dch Ba(OH)2 gim bao nhiu gam? Gi s nc bay hi khng ng k. A. 6,761 gam. B. 4,215 gam. C. 5,269 gam. D. 7,015 gam. Cu 41: Cht hu c X mch h, khng cha lin kt (-O-O-) v c cng thc phn t l C 3H6On. Bit X ch cha mt loi nhm chc. S ng phn cu to c th c ca X l A. 4 B. 6 C. 5 D. 3 Cu 42: C cc nhn inh sau: (1) C th iu ch anehit fomic bng phn oxi ha metanol. (2) C th iu ch ancol etylic bng phn ng hirat ha etilen. (3) Glucoz v saccaroz u tham gia phn ng trng gng. (4) Khng th nhn bit etanal v axit acrylic bng nc brom. S nhn inh ng l A. 4 B. 3 C. 2 D. 1 Cu 43: Thy phn m gam tinh bt, sn phm thu c em ln men sn xut ancol etylic, ton b kh CO 2 sinh ra cho qua dung dch Ca(OH) 2 d, thu c 850 gam kt ta. Bit hiu sut mi giai on l 85%. Gi tr ca m l: A. 810,0. B. 688,5. C. 952,9 D. 476,5. Cu 44: Thy phn hon ton m gam hn hp X gm saccaroz v mantoz thu c dung dch Y. Cho Y tc dng vi lng d dung dch AgNO3 trong NH3 thu c 0,2 mol Ag. Mt khc, thy phn m gam hn hp X mt thi gian (hiu sut thy phn mi cht u l 80%) thu c dung dch Z. Cho Z tc dng vi lng d dung dch AgNO3 trong NH3 thu c 0,168 mol Ag. Thnh phn %v khi lng ca saccaroz trong hn hp l: A. 55%. B. 45%. C. 40%. D. 60%. Cu 45: Chn nhn xt sai? A. Phn bn nitrophotka l hn hp ca 2 mui K 2HPO4 v NH4NO3. B. CO, CO2, SO2, H2S, oxit NOx, CFC (clorofluorocacbon) u l cc cht gy nhim khng kh. C. nhit cao silic tc dng vi Mg, Ca, Fe to thnh silixua kim loi. D. Amphetanin, ancol etylic, nicotin, cafein, mophin l nhng cht c tc dng gy kch thch thn kinh. Cu 46: t chy hon ton 0,1 mol hn hp X gm: etan, propan, propilen, propin, axetilen th thu c s mol H2O t hn s mol CO 2 0,02 mol. Mt khc 0,1 mol hn hp X c th lm mt mu ti a m gam dung dch Br 2 16%. Gi tr ca m l: A. 120. B. 100. C. 60. D. 180. Cu 47: trung ho m gam hn hp X gm hai axit no, n chc, mch h k tip nhau trong dy ng ng cn dung 100ml dung dch NaOH 0,3 M. Mt khc t chy m gam X ri cho ton b sn phm chy ln lt qua bnh (1) ng P2O5, bnh (2) ng dung dch KOH d thy khi lng bnh (1) tng a gam, bnh (2) tng (3,64+ a) gam. Thnh phn % v khi lng ca axit c nguyn t cacbon nh hn trong X l A. 66,67% B. 69,86% C. 30,14% D. 33,33% Cu 48: Cho 27 gam hn hp X gm: axit axetic, 2-hiroxyl etanal, propan-2-ol phn ng vi Na d sau khi phn ng kt thc thu c V lt (ktc). Gi tr ca V l: A. 10,08. B. 8,96. C. 5,04. D. 6,72. Cu 49: Cho cc dung dch sau NaOH, NaHCO 3, BaCl2, Na2CO3, NaHSO4. Nu trn cc dung dch vi nhau theo tng i mt th tng s cp c th xy ra l. A. 4 B. 5 C. 6 D. 7 Cu 50: C dung dch X gm (KI v mt t h tinh bt). Cho ln lt tng cht sau: O 3, Cl2, H2O2, FeCl3, HCl tc dng vi dung dch X. S cht lm dung dch X chuyn sang mu xanh l A. 3 B. 2 C. 5 D. 4 ----------- HT ----------

 THI TH I HC LN I NM 2012-2013 MN HA HC Thi gian lm bi: 90 pht, khng k thi gian pht (60 cu trc nghim) M thi 132 Cho bit khi lng nguyn t (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16;Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39;Ca = 40; Cr = 52; Fe = 56;Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137

H, tn th sinh:....................................................................................... S bo danh .............................phng thi

I. PHN CHUNG DNH CHO TT C TH SINH (t cu 1 n cu 40) Cu 1: t chy hon ton 0,03 mol hn hp X gm HCOOH, C2H5OH v CH3COOH, sau phn ng thu c 2,20 gam CO2 v 1,08 gam H2O. Nu nh t t dung dch Na2CO3 0,50M vo 0,30 mol hn hp X, n khi khng c kh thot ra th thu c V lt kh CO2 (ktc). Gi tr V l A. 4,48. B. 2,24. C. 0,448. D. 0,224. Cu 2: Cho m gam Mg vo dung dch c cha 0,8 mol Fe(NO 3)3 v 0,05 mol Cu(NO3)2 , n phn ng hon ton thu c 14,4 gam cht rn.Gi tr ca m l A. 15,6 gam. B. 8,4 gam. C. 6 gam. D. 24 gam Cu 3: t chy hon ton m gam hn hp X gm hai ancol thu c 0,35 mol CO 2 v 0,6 mol H2O. Mt khc, nu cho m gam X tc dng ht vi 10,35 gam Na thu c (10+m) gam cht rn. Cng thc phn t ca hai ancol trong X l. A. C2H5OH v C3H6(OH)2 B. CH3OH v C2H4(OH)2 C. C2H5OH v C3H5(OH)3 D. CH3OH v C3H6(OH)2 Cu 4: Hn hp X gm hai anhit. t chy hon ton 0,25 mol X thu c 0,3 mol CO2. Mt khc, nu cho 0,25 mol X tc dng ht vi dung dch AgNO 3/NH3 d, thu c 0,9 mol Ag. Cng thc cu to thu gn ca hai anhit trong X l. A. HCHO v CH3-CHO B. HCHO v CH3 -CH2-CHO C. CH3CHO v OHC-CHO D. HCHO v HOC-CHO Cu 5: Cho 0,5 gam hn hp X gm Li, Na, K vo nc thu c 2 lt dung dch c pH = 12. Trn 8 gam hn hp X v 5,4 gam bt Al ri cho vo nc n phn ng hon ton c V lt kh thot ra(ktc).Gi tr ca V l: A. 8,064 B. 10,304 C. 11,648 D. 8,160 Cu 6: Cho 4,48 gam hn hp gm CH3COOC2H5 v CH3COOC6H5 (c t l mol l 1:1) tc dng vi 800 ml dung dch NaOH 0,1 M thu c dung dch X. C cn dung dch X th khi lng cht rn thu c l A. 4,88 gam. B. 6,4 gam C. 5,6 gam. D. 3,28 gam Cu 7: R l nguyn t m nguyn t c phn lp electron ngoi cng l np 2n+1 (n l s th t ca lp electron). C cc nhn xt sau v R: (I) Tng s ht mang in ca nguyn t R l 18. (II) S electron lp ngoi cng trong nguyn t R l 7. (III) Cng thc ca oxit cao nht to ra t R l R2O7. (IV) Dung dch NaR tc dng vi dung dch AgNO3 to kt ta. S nhn xt ng l: A. 4 B. 3 C. 2 D. 1 Cu 8: Khi cho Cu vo dung dch FeCl3; H2S vo dung dch CuSO4; HI vo dung dch FeCl3; dung

dch AgNO3 vo dung dch FeCl3; dd HCl vo dung dch Fe(NO3)2. s cc cht phn ng c vi nhau l: A. 4 B. 2 C. 5 D. 3 Cu 9: Cho dy cc cht: andehit fomic, axit axetic, etyl axetat, axit fomic, ancol etylic, metyl fomiat, axetilen, vinyl axetilen, etylen, glucozo, saccarozo. S cht trong dy tham gia phn ng c vi dung dch AgNO3/NH3 l A. 3 B. 6 C. 7 D. 5. Cu 10: Cho V lt hn hp kh X gm H 2, C2H2, C2H4 , trong s mol ca C 2H2 bng s mol ca C2H4 i qua Ni nung nng (hiu sut t 100%) thu c 11,2 lt hn hp kh Y ( ktc), bit t khi hi ca hn hp Y i vi H2 l 6,6. Nu cho V lt hn hp X i qua dung dch Brom d th khi lng bnh Brom tng A. 5,4 gam. B. 4,4 gam. C. 2,7 gam. D. 6,6 gam. Cu 11: Pht biu no sau y l ng? A. Nhng nguyn t c cng s khi thuc cng mt nguyn t ho hc. B. Trong tt c cc nguyn t, s proton bng s ntron. C. Ht nhn ca tt c cc nguyn t u c proton v ntron. D. Nguyn t M c Z = 11 thuc chu k 3 nhm IA. Cu 12: Cho cc cht: C2H4(OH)2, CH2OH-CH2-CH2OH, CH3CH2CH2OH, C3H5(OH)3, (COOH)2, CH3COCH3, CH2(OH)CHO. C bao nhiu cht u phn ng c vi Na v Cu(OH) 2 nhit thng ? A. 3. B. 2. C. 5. D. 4. Cu 13: Thc hin cc th nghim sau: (1) Ni mt thanh Zn vi mt thanh Fe ri trong khng kh m. (2) Th mt vin Fe vo dung dch CuSO4. (3) Th mt vin Fe vo dung dch cha ng thi ZnSO4 v H2SO4 long. (4) Th mt vin Fe vo dung dch H2SO4 long. (5) Th mt vin Fe vo dung dch cha ng thi CuSO4 v H2SO4 long. Trong cc th nghim trn nhng th nghim Fe b n mn in ha hc l A. (2) v (5). B. (1) v (3). C. (1), (2), (3), (4), (5). D. (3) v (5). Cu 14: Ly 0,3 mol hn hp X gm H 2NC3H5(COOH)2 v H2NCH2COOH cho vo 400ml dung dch HCl 1M th thu c dung dch Y. Y tc dng va vi 800ml dung dch NaOH 1M thu c dung dch Z. Lm bay hi Z thu c m gam cht rn khan, gi tr ca m l A. 38,5 gam B. 71,3 gam C. 47,9 gam D. 61,9 gam Cu 15: Cho m gam Na vo 160 ml dung dch gm Fe 2(SO4)3 0,125M v Al2(SO4)3 0,25M, sau khi cc phn ng kt thc, lc kt ta ri nung n khi lng khng i, thu c 4,73 gam cht rn. Gi tr ln nht ca m l A. 10,35. B. 9,43. C. 11,50. D. 9,20. Cu 16: Cho phng trinh phan ng aFe(NO3)2 + bKHSO4 xFe(NO3)3 + yFe2(SO4)3 + zK2SO4 + tNO + uH2O Trong a, b, x, y, z, t, u l b h s nguyn dng, ti gin ca phng trnh. Tng a + b la A. 43. B. 21. C. 27. D. 9. Cu 17: Cho cc pht biu sau v phenol (C6H5OH): (a) Phenol va tc dng vi dung dch NaOH va tc dng c vi Na. (b) Phenol tan c trong dung dch KOH. (c) Nhit nng chy ca phenol ln hn nhit nng chy ca ancol etylic. (d) Dung dch natriphenolat tc dng vi CO2 to thnh Na2CO3. (e) Phenol l mt ancol thm. S pht biu ng l A. 4. B. 3. C. 5. D. 2.

Cu 18: trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15 ml dung dch KOH 0,1M. Ch s axit ca mu cht bo trn l A. 5,5. B. 4,8. C. 7,2. D. 6,0. Cu 19: A l hn hp kh gm SO2 v CO2 c t khi hi so vi H2 l 27. Dn a mol hn hp kh A qua bnh ng 1 lt dd NaOH 1,5a M, sau phn ng c cn dung dch thu c m gam mui. Biu thc lin h gia m v a l A. m=103.5a B. m=105a C. m=141a D. m=116a Cu 20: Cho dy cc cht: Cu, CuO, Fe 3O4, C, FeCO3, Fe(OH)3. S cht trong dy tc dng vi H2SO4 c, nng, d khng to kh SO2 l A. 3. B. 4. C. 2. D. 1. Cu 21: Qu trnh sn xut amoniac trong cng nghip da trn phn ng thun nghch sau: N 2(k) + 3H2(k) H = -92 kJ 2NH3(k). Khi phn ng t ti trng thi cn bng, nhng thay i no di y lm cho cn bng chuyn dch theo chiu thun to ra nhiu amoniac: (1) Tng nhit ; (2) Tng p sut; (3) Thm cht xc tc; (4) Gim nhit ; (5) Ly NH3 ra khi h A. (1), (2), (3), (5). B. (2), (4), (5). C. (2), (3), (4), (5). D. (2), (3), (5). 2Cu 22: Phn ng c phng trnh ion rt gn: HCO3 + OH CO3 + H2O l A. NaHCO3 + HCl NaCl + CO2 + H2O. B. Ca(HCO3) + 2NaOH CaCO3 + Na2CO3 + 2H2O. C. 2NaHCO3 + Ca(OH)2 CaCO3 + Na2CO3 + 2H2O.D. 2NaHCO3 + 2KOH Na2CO3 + K2CO3 +
2H2O

Cu 23: Cho t t 150 ml dd HCl 1M vo 500 ml dd A gm Na 2CO3 v NaHCO3 th thu c 1,008 lt kh (ktc) v dd B. Cho dd B tc dng vi dd Ba(OH) 2 d th thu c 29,55 g kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dd A ln lt l: A. 0,2M v 0,4M B. 0,18M v 0,26M C. 0,21M v 0,32M D. 0,21M v 0,18M Cu 24: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. ancol o-hiroxibenzylic. B. axit aipic. C. etylen glicol D. axit 3-hiroxipropanoic. Cu 25: Trong cc cht: xiclopropan, xiclohexan, benzen, stiren, axit axetic, axit acrylic, anehit axetic, anehit acrylic, axeton, etyl axetat, vinyl axetat, imetyl ete. S cht c kh nng lm mt mu nc brom l: A. 6. B. 7. C. 4. D. 5. Cu 26: Cho cc phn ng: K2Cr2O7 + 14HBr 3Br2 + 2KBr + 2CrBr3 + 7H2O Br2 +2NaI 2NaBr + I2 Khng nh no sau y l ng?

A. Tnh kh: Cr3+ >

I Cr O Br
2 7
C. Tnh kh: > Cr3+

B. Tnh oxi ho: I2 > Br2 D. Tnh oxi ho: I2 >

Cu 27: Ho tan ht m gam Fe bng 400 ml dung dch HNO 3 1M. Sau khi phn ng xy ra hon ton thu c dung dch cha 26,44 gam cht tan v kh NO (sn phm kh duy nht). Gi tr ca m l A. 12,24. B. 5,60. C. 6,12. D. 7,84. Cu 28: Ha tan ht 15,55 gam hn hp X gm Fe, Mg, Al v Zn vo dung dch HCl d, sau phn ng thu c 0,4 mol H2 . Mt khc, nu oxi ha hon ton hn hp X trn trong O 2 d, thu c 23,15 gam cht rn Y. Phn trm khi lng ca Fe trong X l. A. 81,03 B. 36,01 C. 64,82 D. 54,02 Cu 29: t chy hon ton mt hn hp X (gm glucoz, anehit fomic, axit axetic) cn 2,24 lt O 2 (ktc). Dn sn phm chy qua bnh ng dung dch Ca(OH) 2 (d), thy khi lng bnh tng m gam. Gi tr ca m l A. 12,4 B. 3,1 C. 6,2 D. 4,4 Cu 30: in phn (in cc tr, mng ngn xp) dung dch X thy pH tng, dung dch Y thy pH gim. Vy dung dch X v dung dch Y no sau y ng: A. (X) KBr, (Y) Na2SO4 B. (X) BaCl2, (Y) CuSO4 C. (X) NaCl, (Y) HCl D. (X) AgNO3, (Y) BaCl2 Cu 31: Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn ng c vi dung dch HCl, dung dch NaOH l A. 5. B. 4. C. 7. D. 6 Cu 32: un nng cht H2N-CH2 -CONH-CH(CH3)-CONH-CH2 -COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH2-CH2-COOH. B. H3N+-CH2-COOHCl-, H3N+-CH2-CH2COOHCl-. C. H2N-CH2-COOH, H2N-CH(CH3)-COOH. D. H3N+-CH2-COOHCl-, H3N+-CH(CH3)COOHCl-.

Cu 33: Nhit phn cc mui sau: NH4NO2, NaHCO3, CaCO3, KMnO4, NaNO3, Cu(NO3)2. S phn ng nhit phn thuc loi phn ng oxi ho - kh l A. 3. B. 4. C. 5. D. 6. Cu 34: Thu phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32gam Ala-Ala v 27,72 gam Ala-Ala-Ala .Gi tr m l A. 88,2 B. 90,6 C. 81,54 D. 111,74 Cu 35: Cho hn hp gm 3,36 gam Mg v 0,4 gam MgO tc dng vi dung dch HNO 3 long d thu c 0,448 lt kh X duy nht (ktc). C cn dung dch sau phn ng thu c 23 gam cht rn khan. S mol HNO3 phn ng l: A. 0,32 mol B. 0,28 mol C. 0,34 mol D. 0,36 mol Cu 36: S ng phn ca C3H9O2N khi tc dng vi NaOH un nng cho sn phm kh c th lm xanh qu tm m . A. 4 B. 3 C. 2 D. 1 Cu 37: Cho cc cp cht sau: (a) Kh Cl2 v kh O2. (b) Kh H2S v kh SO2. (c) Kh H2S v dung dch Pb(NO3)2. (d) CuS v dung dch HCl. (e) Kh Cl2 v dung dch NaOH. S cp cht xy ra phn ng ho hc nhit thng l A. 3. B. 1. C. 4. D. 2. Cu 38: T m (kg) khoai c cha 25% tinh bt, bng phng php ln men ngi ta iu ch c 100 lt dung dch ancol etylic 600. Bit khi lng ring ca C2H5OH l 0,8 g/ml, hiu sut chung ca c qu trnh l 90%. Gi tr ca m l A. 338,09kg B. 375,65kg C. 93,91kg D. 676,2kg. Cu 39: Cho 17,80 gam bt Fe vo 400 ml dung dch gm Cu(NO 3)2 0,40M v H2SO4 0,50M. Sau phn ng thu c m gam hn hp kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr

m v V l A. 11,20 v 3,36. B. 11,20 v 2,24. C. 10,68 v 3,36. D. 10,68 v 2,24. Cu 40: Hn hp X gm: Na, Ca, Na2O v CaO. Ha tan ht 5,13 gam hn hp X vo nc thu c 0,56 lt H2 (ktc) v dung dch kimY trong c 2,8 gam NaOH. Hp th 1,792 lt kh SO 2 (ktc) vo dung dch Y thu c m gam kt ta. Gi tr ca m l A. 5,4. B. 6,0. C. 7,2. D. 4,8.

II. PHN RING. Th sinh ch c lm mt trong hai phn: phn 1 hoc phn 2 1.PHN 1: DNH CHO TH SINH THEO CHNG TRNH CHUN (10 cu, t cu 41 n cu 50) Cu 41: So snh no di y khng ng?
A. Al(OH)3 v Cr(OH)3 u l cht lng tnh v va c tnh oxi ha va c tnh kh.

B. BaSO4 v BaCrO4 u l nhng cht khng tan trong nc. C. Fe(OH)2 v Cr(OH)2 u l baz v l cht kh. D. H2SO4 v H2CrO4 u l axit c tnh oxi ha mnh. Cu 42: Ch dng thm mt thuc th trnh by cch nhn bit cc cht rn sau. NaOH, Al, ZnO, CaCO3 A. Qu tm B. Dung dch kim C. Nc D. Dung dch axit Cu 43: Dn khi CO d qua hn hp nung nong Al, Al 2O3, MgO, FeO. Sau khi phan ng hoan toan thu c hn hp rn gm A. Al, Al2O3, MgO, Fe. B. Al, MgO, Fe C. Al, Mg, Fe D. Fe Cu 44: Cho 6,9 gam hn hp X gm 2 ancol no, n chc (Y v Z) tc dng vi Na d thu c 1,68 lt H2(ktc). Cn khi oxi ho 6,9 gam hn hp X bi CuO d, nung nng thu c hn hp T gm 2 sn phm hu c tng ng vi Y v Z. Cho T tc dng vi lng d dung dch AgNO 3 trong NH3 th thu c 43,2 gam Ag. Cng thc hai ancol trong axit l: A. CH3OH v CH3CH(CH3)CH2OH B. CH3OH v CH3CH(OH)CH3 C. CH3OH v CH3CH(OH)CH2CH3 D. CH3CH2OH v CH3CH2CH3OH Cu 45: Cho dy cc cht: but-2-en, axit acrylic, propilen, ancol anlylic, 2-metylhex-3-en, axit oleic, hexa-1,4-ien, stiren. S cht trong dy c ng phn hnh hc l A. 5. B. 6. C. 4. D. 7. Cu 46: S ng phn ca dn xut halogen c cng thc phn t C4H9Br l: A. 5 B. 2 C. 4 D. 3
Cu 47: Hn hp gm hai anhit n chc X v Y c chia thnh hai phn bng nhau: - Phn 1: un nng vi dd AgNO3/NH3 d th to ra 10,8 gam Ag. - Phn 2: oxi ha to thnh hai axit tng ng, sau cho hai axit ny phn ng vi 250 ml dung dch NaOH 0,26M c dung dch Z. trung ha lng NaOH d trong dung dch Z cn dng ng 100 ml dung dch HCl 0,25M. C cn dung dch Z ri em t chy cht rn thu c sau khi c cn, c 3,52 gam CO2 v 0,9 gam H2O. Cng thc phn t ca hai anhit X v Y l: A. HCHO v C2H5CHO. B. HCHO v C2H3CHO C. HCHO v CH3CHO D. CH3CHO v C2H5CHO.

Cu 48: Cho 0,1 mol hp cht ha c c CTPT CH 6O3N2 tc dng vi dd cha 0,2 mol NaOH un nng, sau khi phn ng xy ra hon ton thu c cht kh lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m gam rn khan. Gi tr ca m l A. 12,5 B. 21,8 C. 8,5 D. 15 Cu 49: Cho dng H2 i qua ng s ng 0,2 mol hn hp FeO v Fe 2O3 nung nng sau mt thi gian thu c 1,89 gam H 2O v 22,4 gam hn hp cht rn X. Ho tan hon ton cht rn X trong dung dch HNO3 thu c V lit kh NO (ktc) l sn phm kh duy nht. Gi tr ca V l A. 0,75 B. 2,24 C. 3,73 D. 4,48 Cu 50: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na 2O v Al2O3; Cu v Fe2(SO4)3; BaCl2 v CuCl2 ; Ba v NaHSO4. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l A. 2. B. 4. C. 1. D. 3.

2. PHN 2. DNH CHO TH SINH THEO CHNG TRNH NNG CAO (t cu 51 n cu

60) Cu 51: Dung dch Y gm CH3COOH 0,1M v HCl 0,005M. Bit 25 oC Ka ca CH3COOH l 1,75.10-5. Gi tr pH ca dung dch Y 25oC l A. 1,77. B. 2,30. C. 2,33. D. 2,27. Cu 52: Hp cht X c cng thc phn t C4H8O3. Cho 10,4 gam X tc dng vi dung dch NaOH (va ) thu c 9,8 gam mui. cng thc cu to ng ca X l A. CH3COOCH2CH2OH B. HOCH2COOC2H5. C. HCOOCH2CH2CHO D. CH3CH(OH)COOCH3 Cu 53: X l mt tripeptit c to thnh t 1 aminoaxit no, mch h c 1 nhm -COOH v 1 nhm -NH2 .t chy hon ton 0,3 mol X cn 2,025 mol O 2 thu c sn phm gm CO2 ,H2O , N2. Vy cng thc ca amino axit to nn X l A. H2NCH2COOH B. H2NC3H6COOH C. H2NC4H8COOH D. H2NC2H4COOH Cu 54: Hn hp kh A gm CO v H 2 c t khi i vi hiro bng 4,25, hn hp kh B gm O 2 v O3 c t khi i vi H2 l 20. t chy hon ton 10V lt kh A cn lng th tch hn hp kh B l: (cc kh o cng iu kin nhit , p sut) A. 10V B. 6V C. 4V D. 8V Cu 55: Ancol bc ba, mch h X c cng thc phn t C5H10O. T X ngi ta thc hin s bin ho sau: +Br +NaOH X C5H10OBr2 C5H12O3 (cht Y). Dy cc cht u c th tc dng c vi Y l: A. Na2O, NaHCO3, v CH3OH (xc tc H2SO4 c, to). B. Na, NaOH, v CH3COOH (xc tc o H2SO4 c, t ). C. NaHCO3, NaOH v Cu(OH)2. D. Na, Cu(OH)2, v C2H5OH (xc tc H2SO4
2

c, to).

Cu 56: Cp dung dch no sau y u c pH nh hn 7? A. Dung dch AlCl3 v dung dch NaHSO4. B. Dung dch NH3 v dung dch NH4Cl. C. Dung dch Na2SO4 v dung dch NaHSO4. D. Dung dch NaOH v dung dch Na2CO3. o Cu 57: Cho 3 kim loi X,Y,Z bit E ca 2 cp oxihoa - kh X2+/X = -0,76V v Y2+/Y = +0,34V. Khi cho Z vo dung dch mui ca Y th c phn ng xy ra cn khi cho Z vo dung dch mui X th khng xy ra phn ng. Bit Eo ca pin X-Z = +0,63V. Tnh Eo ca pin to bi hai in cc kim loi Y v Z A. +1,73V B. +0,47 V C. +2,49V D. +0,21V Cu 58: C 6 gi bt ring bit c mu tng t nhau: CuO, FeO, Fe 3O4, MnO2, Ag2O v hn hp Fe + FeO. Thuc th phn bit c 6 gi bt trn l: A. dd HNO3 c B. dd H2O2 C. dd H2SO4 long D. dd HCl Cu 59: Nhng mt l st nh vo dung dch cha mt trong cc cht sau: FeCl 3, ZnCl2, CuSO4, Pb(NO3)2, HCl, NaCl, HNO3, H2SO4 c nng, NH4NO3 (cc dung dch cho u d). S trng hp phn ng to mui Fe(II) l A. 3. B. 5. C. 4. D. 6. Cu 60: in phn 500 ml dung dch hn hp CuSO 4 a mol/l v NaCl 1 mol/l vi in cc tr, mng ngn xp, cng dng in khng i 5A trong thi gian 96,5 pht (hiu sut qu trnh in phn l 100%, nc bay hi khng ng k) thu c dung dch c khi lng gim so vi ban u l 17,15 gam. Gi tr ca a l A. 0,4. B. 0,5. C. 0,2. D. 0,3.
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 THI TH I HC MN: HA HC (Thi gian lm bi: 90 pht; 50 cu trc nghim) H v tn .................................................................. S bo danh .......................... M thi 133 Cho khi lng nguyn t ca cc nguyn t (theo vC): C = 12; H = 1; O = 16; S = 32; Cu = 64; Fe = 56; Al = 27; N = 14; Ca = 40; Ba = 137; Na = 23; Mg = 24; Cl = 35,5; Zn = 65; K = 39; Ag = 108; Br = 80; Be = 9; P = 31; Se = 79. A. PHN CHUNG CHO TT C TH SINH (40 cu: T cu 1 n cu 40) Cu 1: Vi cng thc phn t C3H6Cl2 th c bao nhiu cht khi tc dng vi dung dch NaOH d, un nng, cho sn phm c phn ng vi Cu(OH)2 iu kin thch hp? A. 3. B. 1. C. 2. D. 4. Cu 2: Cho hi nc i qua than nng thu c 0,8 mol hn hp kh X gm CO, CO2 v H2. Cho ton b X phn ng ht vi CuO d, un nng thu c hn hp cht rn Y. Ha tan ht Y bng dung dch HNO3 long, d thu c 0,4 mol kh NO (sn phm kh duy nht). T khi ca X so vi H2 l A. 7,875. B. 10,0. C. 3,9375. D. 8,0. Cu 3: Trong cc cht sau: cumen, vinylbenzen, vinylaxetilen, axit fomic, phenol, axit acrylic, isopren. C bao nhiu hirocacbon c th lm mt mu nc brom? A. 6. B. 5. C. 4. D. 3. Cu 4: Hp cht hu c X c cng thc phn t C6H9O4Cl. Bit rng: X + NaOH d Mui ca axit X1 + X2 + X3 + NaCl (X2, X3 l cc ancol c cng s nguyn t C). Khi lng phn t (vC) ca X1 l A. 134. B. 90. C. 143. D. 112. Cu 5: Cho cn bng sau xy ra trong bnh kn c dung tch khng i: 2SO2 (k) + O2 (k) t n v v 2SO3 (k) ; H 0 Yu t no sau y lm cho cn bng trn dch chuyn theo chiu nghch v tc phn ng thun tng? A. Gim nhit ca h phn ng. B. Thm cht xc tc phn ng. C. Thm SO3 vo h phn ng. D. Tng p sut. Cu 6: Cho 18,75 gam Al2S3 vo 600 ml dung dch NaOH 2M, sau khi cc phn ng kt thc, khng c kh thot ra th s mol ca NaOH cn li l A. 0,20. B. 0,05. C. 0,75. D. 0,45. Cu 7: Thy phn mt loi cht bo thu c axit panmitic, axit linoleic v axit oleic. Ch s iot (s gam iot c th cng vo lin kt bi trong mch cacbon ca 100 gam cht bo) ca loi cht bo trn l A. 89,0. B. 54,0. C. 44,5. D. 53,3. Cu 8: Cho cc th nghim sau: (1) Sc O3 vo dung dch KI. (2) Nhit phn KMnO4. (3) Nhit phn NaHCO3. (4) Cho H2O2 vo dung dch KMnO4 trong H2SO4 long. (5) in phn NaOH nng chy. (6) Nhit phn KClO3 c xc tc MnO2. C bao nhiu th nghim to ra sn phm c O2? A. 4. B. 3. C. 5. D. 6. Cu 9: Thc hin phn ng nhit nhm (trong iu kin khng c khng kh) hn hp X gm Al v Fe3O4 sau mt thi gian thu c m gam hn hp Y. Chia Y thnh hai phn bng nhau. Phn 1 tc dng va vi 100 ml dung dch NaOH 0,5M. Phn 2 tc dng ht vi dung dch HNO3 c nng, d thu c 3,696 lt kh NO2 ( ktc, sn phm

kh duy nht). Gi tr ca m l A. 4,83. B. 8,46. C. 9,66. D. 19,32. Cu 10: Ha tan Fe3O4 trong dung dch H2SO4 long, d thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong cc cht sau: Br2, H2S, K2Cr2O7, NaNO3, BaCl2, NaOH, KI? A. 6. B. 7. C. 5. D. 4. Cu 11: Cho (x + 1,5y) mol Ba(OH)2 vo dung dch cha x mol NH4 , y mol 2 Ba v z mol HCO3 . Sau khi cc phn ng kt thc, un nng nh th dung dch thu c cha A. Ba(HCO3)2 v NH4HCO3. B. (NH4)2CO3. C. Ba(HCO3)2. D. Ba(OH)2. Cu 12: Oxi ha 26,6 gam hn hp X gm mt ancol n chc v mt anehit n chc, thu c mt axit hu c duy nht (hiu sut phn ng l 100%). Cho ton b lng axit ny tc dng vi 100 gam dung dch cha NaOH 4% v Na2CO3 26,5% th thu c dung dch ch cha mt mui ca axit hu c. Phn trm khi lng ca ancol trong X l A. 13,53%. B. 86,47%. C. 82,71%. D. 17,29%. Cu 13: Cho cc loi t sau: nilon-6, enang, visco, lapsan, olon, nilon-6,6. C bao nhiu t thuc loi t poliamit? A. 5. B. 3. C. 4. D. 2. Cu 14: Ha tr cao nht trong hp cht vi oxi ca nguyn t R gp 3 ln ha tr ca n trong hp cht kh vi hiro. Phn trm khi lng ca R trong hp cht kh vi hiro nhiu hn trong hp cht c ha tr cao nht vi oxi l 54,11%. Nguyn t R l A. Se. B. P. C. Cl. D. S.Trang 2/5 - M thi 133 Cu 15: Cho s phn ng: P + NH4ClO4 H3PO4 + Cl2 + N2 + H2O Sau khi lp phng trnh ha hc, ta c tng s nguyn t b oxi ha v tng s nguyn t b kh ln lt l A. 8 v 5. B. 10 v 18. C. 18 v 10. D. 5 v 8. Cu 16: Thy phn hon ton m gam tetrapeptit X mch h thu c hn hp Y gm 2 amino axit (no, phn t cha 1 nhm COOH v 1 nhm NH2) l ng ng k tip. t chy hon ton hn hp Y cn va 4,5 mol khng kh (cha 20% O2 v th tch, cn li l N2) thu c CO2, H2O v 82,88 lt kh N2 ( ktc). S cng thc cu to tha mn ca X l A. 8. B. 4. C. 12. D. 6. Cu 17: trng thi c bn: - Phn lp electron ngoi cng ca nguyn t nguyn t X l np2n+1 . - Tng s electron trn cc phn lp p ca nguyn t nguyn t Y l 7. - S ht mang in trong nguyn t nguyn t Z nhiu hn s ht mang in trong nguyn t nguyn t X l 20 ht. Nhn xt no sau y l sai? A. Nguyn t X v Y thuc 2 chu k k tip. B. S oxi ha cao nht ca X trong hp cht l +7. C. Oxit v hiroxit ca Y c tnh lng tnh. D. m in gim dn theo th t X, Y, Z. Cu 18: Tin hnh in phn (vi in cc tr, hiu sut l 100%) dung dch X cha 0,02 mol CuCl2; 0,02 mol CuSO4 v 0,005 mol H2SO4 trong thi gian 32 pht 10 giy vi cng dng in khng i l 2,5 ampe th thu c 200 ml

dung dch Y. Gi tr pH ca dung dch Y l A. 1,08. B. 1,00. C. 0,70. D. 1,78. Cu 19: Cho m gam hn hp kim loi gm Al, Mg, Zn phn ng ht vi dung dch H2SO4 long, d th thu c dung dch X cha 61,4 gam mui sunfat v 5m/67 gam kh H2. Gi tr ca m l A. 20,10. B. 13,40. C. 10,72. D. 17,42. Cu 20: Amin X khi tc dng vi dung dch HCl d thu c mui dng CnHm(NH3Cl)2. t chy 0,1 mol X bng mt lng oxi d, ri cho hn hp sau phn ng (gm CO2, H2O, N2 v O2 d) li chm qua nc vi trong d thy khi lng dung dch sau phn ng gim 7,8 gam so vi khi lng nc vi trong ban u v thu c 30 gam kt ta. S cng thc cu to tha mn iu kin trn ca X l A. 4. B. 2. C. 3. D. 1. Cu 21: Khi cho cng mt lng hp cht hu c X tc dng vi Na d v vi NaHCO3 d th s mol kh H2 thu c nhiu gp 2 ln s mol CO2. Cng thc no sau y l cng thc phn t ca X? A. C8H16O4. B. C7H16O4. C. C8H16O5. D. C6H14O5. Cu 22: Cho 39,6 gam hn hp gm K2CO3 v KHSO3 vo 147 gam dung dch H2SO4 20%, un nng n khi kt thc cc phn ng thu c dung dch X. Dung dch X cha cc cht tan l A. K2SO4, KHSO3. B. K2SO4, KHSO3, KHSO4. C. K2SO4. D. K2SO4 v H2SO4. Cu 23: Cho cc pht biu sau: (1) t chy hon ton este X thu c s mol CO2 bng s mol H2O th X l este no, mch h, n chc. (2) Glucoz, mantoz, saccaroz u c c cu to dng mch h v dng mch vng. (3) X phng v cht git ra tng hp u khng to kt ta vi nc cng. (4) Phenol v anilin u d phn ng vi nc brom do nh hng ca gc hirocacbon n nhm chc. S pht biu ng l A. 2. B. 1. C. 4. D. 3. Cu 24: Cho 3,834 gam mt kim loi M vo 360 ml dung dch HCl, lm kh hn hp sau phn ng thu c 16,614 gam cht rn khan. Thm tip 240 ml dung dch HCl trn vo ri lm kh hn hp sau phn ng th thu c 18,957 gam cht rn khan. Bit cc phn ng xy ra hon ton, b qua s thy phn ca cc ion trong dung dch. Kim loi M l A. Mg. B. Be. C. Al. D. Ca. Cu 25: Chia m gam hn hp X gm mt ancol v mt axit thnh 3 phn bng nhau. Phn 1 tc dng ht vi Na d thu c 0,15 mol H2. t chy hon ton phn 2 thu c 0,9 mol CO2. un phn 3 vi dung dch H2SO4 c th thu c este Y c cng thc phn t C5H10O2 khng c kh nng tham gia phn ng trng bc. Gi tr ca m l A. 62,4. B. 72,0. C. 58,2 D. 20,8. Cu 26: Hn hp X gm SO2 v O2 c t khi so vi H2 bng 28. Nung nng hn hp X mt thi gian (c xc tc V2O5) thu c hn hp Y c t khi so vi X bng 16/13. Hiu sut ca phn ng tng hp SO3 l A. 60,0%. B. 50,0%. C. 62,5%. D. 75,0%. Cu 27: Cho hn hp hai axit cacboxylic hai chc tc dng vi dung dch NaOH va thu c dung dch cha m gam hn hp mui. Cho ton b lng mui thu c tc dng ht vi NaOH d c mt CaO un nng thu c cht rn X v hn hp hirocacbon Y c t khi so vi H2 bng 18,5. Cho ton b cht rn X tc dng vi dung dch H2SO4 long, d thu c 0,4 mol CO2. Gi tr m l A. 33,8. B. 61,8. C. 25,0. D. 32,4. Cu 28: Cho cc hn hp bt, mi hn hp gm hai cht c s mol bng nhau: Ba v Al2O3; Cu v Fe3O4;

NaCl v KHSO4; Fe(NO3)2 v AgNO3. S hn hp khi ha tan vo nc rt d ch thu c dung dch l A. 3. B. 4. C. 1. D. 2. Cu 29: Cho cc cht sau: Cr2O3, Al, CH3COONH4, (NH4)2CO3, Na2HPO3, H2NCH2COOH, KHCO3, Pb(OH)2. C bao nhiu cht l cht lng tnh?Trang 3/5 - M thi 133 A. 8. B. 6. C. 7. D. 5. Cu 30: Cho cc pht biu sau: (1) Vi cng thc phn t C2H2O3 c hai hp cht hu c mch h c th tham gia phn ng trng bc. (2) Cng thc phn t C3H5Cl c 4 ng phn cu to. (3) Vi cng thc phn t C4H10O2 c 3 ancol ng phn c th ha tan Cu(OH)2. (4) Tinh bt v xenluloz l ng phn ca nhau. S pht biu ng l A. 3. B. 2. C. 1. D. 4. Cu 31: Trong cc cht sau: CuSO4, S, SO2, H2S, Fe2(SO4)3, SO3. C bao nhiu cht c th to ra H2SO4 bng mt phn ng? A. 2. B. 5. C. 6. D. 4. Cu 32: t chy hon ton m gam hn hp T gm 3 ancol thu c x mol CO2 v y mol H2O. Mt khc cho m/2 gam hn hp T tc dng vi Na d thu c z mol H2. Mi lin h gia m, x, y, z l A. m = 12x + y + 64z. B. m = 24x + 2y + 64z. C. m = 12x + 2y +32z. D. m = 12x + 2y + 64z. Cu 33: Cho cc cht: ancol etylic, axit axetic, phenol, etylamin, trimetylamin, tristearin. C bao nhiu cht c th to lin kt hiro gia cc phn t ca n? A. 4. B. 6. C. 3. D. 5. Cu 34: t chy hon ton m gam qung pirit st (cha 80% FeS2 v khi lng, cn li l tp cht tr) bng mt lng oxi d. Ly ton b lng SO2 thu c cho hp th ht vo 100 ml dung dch cha Ba(OH)2 1,5M v NaOH 1M th thu c 26,04 gam kt ta. Gi tr ln nht ca m l A. 13,44. B. 18,00. C. 16,80. D. 21,00. Cu 35: Cho 28,8 gam hn hp X gm propinal, glucoz, fructoz tc dng vi lng d dung dch AgNO3 trong NH3 th thu c 103,6 gam cht rn. Phn trm khi lng ca propinal trong X l A. 37,5%. B. 40,0%. C. 42,5%. D. 85,6%. Cu 36: Thc hin phn ng tch 15,9 gam hn hp gm butan v pentan (c t l mol tng ng l 3 : 2) iu kin thch hp thu c hn hp X gm cc hirocacbon mch h v hiro c t khi so vi H2 bng 15. X phn ng ti a vi bao nhiu gam brom trong CCl4? A. 40,0 gam. B. 44,8 gam. C. 56,0 gam. D. 84,8 gam. Cu 37: Cho m kg mt loi qung apatit (cha 93% khi lng Ca3(PO4)2, cn li l tp cht tr khng cha photpho) tc dng va vi dung dch H2SO4 c sn xut supephotphat n. dinh dng ca supephotphat thu c sau khi lm kh hn hp sau phn ng l A. 26,83%. B. 42,60%. C. 53,62%. D. 34,20%. Cu 38: un nng hn hp tt c cc ancol c cng thc phn t C2H6O, C3H8O vi dung dch H2SO4 c iu kin thch hp, thu c hn hp X ch gm ete v anken. X cha ti a bao nhiu hp cht? A. 6. B. 3. C. 8. D. 5. Cu 39: Ha tan hn hp X gm CuSO4 v Fe2(SO4)3 vo nc c dung dch Y. Cho Fe d vo dung dch Y n khi cc phn ng kt thc thu c dung dch Z c khi lng bng khi lng dung dch Y (b qua s thy phn ca cc

ion trong dung dch v s bay hi ca nc). Phn trm khi lng ca CuSO4 trong X l A. 26,32%. B. 73,68%. C. 63,20%. D. 5,40%. Cu 40: Khi thy phn pentapeptit X (Gly-Ala-Val-Ala-Gly) th thu c ti a bao nhiu sn phm cha gc glyxyl m dung dch ca n c phn ng mu biure? A. 9. B. 5. C. 4. D. 2. B. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II) Phn I. Theo chng trnh Chun (10 cu: T cu 41 n cu 50) Cu 41: t chy hon ton mt ete c to bi 2 ancol n chc X, Y (Y mch nhnh) ri cho sn phm chy hp th ht vo nc vi trong d th thu c 20 gam kt ta v khi lng dung dch sau phn ng gim 6,88 gam so vi khi lng nc vi trong ban u. Khi lng phn t ca X (vC) l A. 74. B. 46. C. 32. D. 58. Cu 42: t chy hon ton m gam hn hp X gm hai ancol hai chc thuc cng dy ng ng, thu c 39,6 gam CO2 v 18,9 gam H2O. Nu khi cho m gam X tc dng va vi Na th thu c bao nhiu gam cht rn? A. 24,3 gam. B. 24,6 gam. C. 25,9 gam. D. 32,9 gam. Cu 43: Cht no trong cc cht sau y m phn t lun c 9 lin kt xch ma? A. C3H8O3. B. C3H6. C. C2H4O2. D. C2H7N. Cu 44: Ha cht thng c dng khc ch ln thy tinh l A. CaF2 v dung dch H2SO4 c. B. dung dch H2SO4 c. C. NaOH nng chy. D.Na3AlF6. Cu 45: Hn hp X gm axit oxalic, axetilen, propanial v vinyl fomat (trong s mol ca axit oxalic v axetilen bng nhau). t chy hon ton m gam hn hp X cn dng va 1,125 mol O2, thu c H2O v 55 gam CO2. Nu cho m gam hn hp X tc dng vi dung dch NaHCO3 d th thu c ti a bao nhiu lt CO2 ( ktc)? A. 2,8 lt. B. 5,6 lt. C. 8,6 lt. D. 11,2 lt.Trang 4/5 - M thi 133 Cu 46: Trong cc cht sau: tristearin, benzyl fomat, etyl clorua, tinh bt, anbumin, cao su buna. S cht km bn trong c mi trng axit v baz l A. 3. B. 2. C. 5. D. 4. Cu 47: Nhm kim loi no sau y m iu ch chng th ch c th dng phng php in phn nng chy? A. Zn, Cu, Cr, Fe. B. Fe, Al, Ca, Cu. C. Na, Al, Ca, Mg. D. Na, Zn, Mg, Al. Cu 48: Pht biu no sau y sai? A. Trong y khoa, ozon c dng cha su rng. B. Kh sunfur va c tnh oxi ha va c tnh kh. C. Lu hunh tc dng c vi thy ngn nhit thng. D. H2S ch th hin tnh kh khi tham gia phn ng ha hc. Cu 49: Nung m gam hn hp X gm bt st v lu hunh thu c hn hp Y gm FeS, Fe, S. Chia Y thnh 2 phn bng nhau. Cho phn 1 tc dng vi dung dch H2SO4 long, d thy thot ra 2,8 lt hn hp kh ( ktc). Cho phn 2 tc dng ht vi lng d dung dch HNO3 c, nng thy thot ra 16,464 lt kh ch c NO2 ( ktc, sn phm kh duy nht). Gi tr m l A. 14,00. B. 17,84. C. 8,92. D. 7,00. Cu50: Cho s chuyn ha: 222 000 3 0HOOX Pd/PbCO ,t 1500 C 4 xt,t xt t, CH X Y Z T M

Bit X, Y, Z, T, M l cc hp cht hu c. Cc cht Z, M ln lt l A. CH3CHO v CH3COOC2H3. B. CH3CHO v C2H3COOC2H3. C. C2H2 v CH3COOH. D. C2H5OH v CH3COOC2H3. Phn II. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60) Cu 51: Nhn xt no sau y l sai v enzim? A. Hot ng xc tc ca enzim c tnh chn lc cao. B. Cc enzim hu ht c bn cht l protein. C. Tc phn ng nh xc tc enzim thng rt ln. D. L polieste ca axit photphoric v pentoz. Cu 52: Nhn xt no sau y l sai? A. Trong pin in ha, anot l cc m cn catot l cc dng. B. Sut in ng ca pin in ha lun c gi tr dng. C. in cc hiro lun c th in cc bng 0,00 V. D. Khi pin in ha hot ng, cation cu mui chuyn dch v cc dng. Cu 53: Cho dy axit sau: HClO, HClO2, HClO3, HClO4. Theo chiu t tri sang phi th A. tnh axit gim, bn phn t tng, tnh oxi ha tng. B. tnh axit tng, bn phn t gim, tnh oxi ha tng. C. tnh axit tng, bn phn t gim, tnh oxi ha gim. D. tnh axit tng, bn phn t tng, tnh oxi ha gim. Cu 54: Cho cc cht: H2S, Na2CO3, Cu, KI, Ag, SO2, Mg. C bao nhiu cht tc dng c vi dung dch Fe2(SO4)3 d cho sn phm c FeSO4? A. 4. B. 5. C. 2. D. 3. Cu 55: Nhn xt no sau y l sai? A. Khi tch H2CrO4 v H2Cr2O7 ra khi dung dch th chng s b phn hy thnh CrO3. B. Cc oxit v hiroxit ca crom u l cht lng tnh. C. Cho dung dch H2SO4 vo dung dch K2CrO4 th dung dch thu c c mu da cam. D. Cho CrCl3 vo dung dch cha NaOH d v Br2 thu c dung dch c mu vng. Cu 56: Cht no trong cc cht sau m trong phn t khng c lin kt 1, 4 glicozit ? A. Xenluloz. B. Amiloz. C. Mantoz. D. Amilopectin. Cu 57: Cho 16,75 gam hn hp X gm FeCl3, CuCl2 vo dung dch H2S d, sau khi phn ng xy ra hon ton thu c 9,92 gam cht rn (b qua s thy phn ca cc ion kim loi). T hn hp X c th iu ch c ti a bao nhiu gam kim loi? A. 9,23 gam. B. 7,52 gam. C. 6,97 gam. D. 5,07 gam. Cu 58: Thy phn hon ton 0,15 mol mt este X cn dng va 100 gam dung dch NaOH 18%, thu c mt ancol v 36,9 gam hn hp mui ca hai axit cacboxylic n chc. Cng thc phn t ca hai axit l A. HCOOH v C2H5COOH. B. C2H5COOH v C3H7COOH. C. HCOOH v C3H7COOH. D. CH3COOH v C2H5COOH. Cu 59: t chy hon ton hn hp hai ancol no, mch h X, Y (phn t Y nhiu hn phn t X mt nguyn t cacbon) cn dng va 1,05 mol O2, thu c 0,75 mol CO2 v 18,9 gam H2O. C bao nhiu cp X, Y tha mn iu kin trn? A. 4. B. 3. C. 2. D. 1. Cu 60: thu c 500 ml dung dch c pH bng 5 cn phi ha tan bao nhiu gam NH4Cl vo nc, bit hng s phn li 250C ca NH4 l Ka = 10-9,24 ?Trang 5/5 - M thi 133 A. 3,32 gam. B. 4,64 gam. C. 2,32 gam. D. 2,14 gam. n -----------------------------------------------\ ----------- HT ----------

 THI TRC NGHIM - MN HA HC Thi gian lm bi: 90 pht (50 cu trc nghim) H v tn hc sinh:...................................................lp:.................................................... S cu ng:..............................im:...................... Cu 1: Cho hn hp A gm Al, Fe vo dung dch B c cha Cu(NO3)2 v AgNO3. Sau khi phn ng xy ra hon ton thu c dung dch C; Cho dung dch NaOH d vo C c kt ta D gm hai hiroxit kim loi. Trong dung dch C c cha: A. Al(NO3)3, Fe(NO3)2 v Cu(NO3)2. B. Al(NO3)3 v Fe(NO3)2. C. Al(NO3)3 v Fe(NO3)3. D. Al(NO3)3 v Fe(NO3)3 v Fe(NO3)2. Cu 2: Cho cc cht: CH3CH2OH (1), H2O (2), CH3COOH (3), C6H5OH (4), HCl (5). Th t tng dn tnh linh ng ca nguyn t hiro trong cc cht l A. (4), (1), (2), (5), (3). B. (1), (2), (4), (3), (5). C. (1), (2), (3), (4), (5). D. (2), (1), (4), (5), (3). Cu 3: Cho cc cht sau: FeO, Fe2O3, HI, SO2, SiO2, CrCl2, FeCl3, Br2. S cht va c tnh oxi ha va c tnh kh l A. 3. B. 5. C. 4. D. 6. Cu 4: Kh hon ton 4,8 gam oxit ca mt kim loi nhit cao, cn dng 2,016 lt kh hiro ( ktc). Cng thc phn t ca oxit dng l A. FeO B. Fe3O4 C. CuO D. Fe2O3 Cu 5: Hn hp X gm mt axit no, n chc, mch h v 2 este no, n chc mch h. phn ng ht vi a gam X cn 400ml dung dch NaOH 0,75M. Cn t chy hon ton a gam X th thu c 20,16 lt CO2 (ktc). Gi tr ca a l: A. 14,8 gam. B. 22,2 gam. C. 46,2 gam. D. 34,2 gam. Cu 6: Trong bnh kn dung tch 5 lt khng i cha 12,8 gam SO2 v 3,2 gam oxi (c mt t xc tc V2O5 th tch khng ng k) nung nng. Sau khi tin hnh phn ng oxi ha SO2 t trng thi cn bng th phn trm th tch oxi cn li trong bnh chim 20%. Hng s cn bng ca phn ng: 2SO2 + O2 2SO3 ti iu kin trn l: A. 50. B. 20. C. 100. D. 10. Cu 7: Ln men 45 gam ng glucoz thy c 4,48 lt CO2 (ktc) bay ra v cn hn hp cht hu c X gm C2H5OH v glucoz d. t chy hon ton X th s mol CO2 thu c l A. 1,3 mol B. 1,15 mol C. 1,5 mol D. 1,2 mol Cu 8: Cho cc dung dch sau: NaOH, BaCl2, KHSO4, Al2(SO4)3, (NH4)2SO4. phn bit cc dung dch trn, dng thuc th no trong s cc thuc th sau th s cn tin hnh t th nghim nht A. H2SO4 B. KOH C. qu tm D. Ba(OH)2 Cu 9: Hn hp X cha glixerol v mt ancol no, n chc mch h Y. Cho 20,3 gam X tc dng vi Na d thu c 5,04 lt H2 (ktc). Mt khc 8,12 gam X ho tan va ht 1,96 gam Cu(OH)2. Cng thc phn t ca Y v thnh phn phn trm khi lng ca Y trong hn hp l A. C3H8O v 77,34% B. C5H12O v 65,94% C. C4H10O v 54,68% D. C2H6O v 81,87% Cu 10: Cho 4,291 gam hn hp A gm Fe3O4, Al2O3 v CuO tc dng va vi 179 ml dung dch HCl 1M. C cn dung dch thu c khi lng mui khan l A. 9,1415 gam B. 9,2135 gam C. 9,5125 gam D. 9,3545 gam Cu 11: Trong cc cht sau: C2H5OH, CH3CHO, CH3COONa, HCOOC2H5, CH3OH. S cht t iu ch trc tip c CH3COOH (bng mt phn ng) l A. 5 B. 4 C. 3 D. 6 Cu 12: Ha cht phn bit 3 cc cha: nc nguyn cht, nc cng tm thi, nc cng vnh cu l A. Na2CO3 B. HCl v Na2CO3 C. Na2CO3 v Na3PO4 D. Na3PO4 Cu 13: un nng a gam mt hp cht hu c cha C; H; O mch khng phn nhnh vi dung dch cha 11,2 gam KOH n khi phn ng xy ra hon ton, thu c dung dch B, trung ho dung dch KOH d trong B cn dng 80 ml dung dch HCl 0,5M. Lm bay hi hn hp sau khi trung ho mt cch cn thn, ngi ta thu c 7,36 gam hn hp hai ancol n chc v 18,34 gam hn hp hai mui. Gi tr ca a l A. 14,86 gam B. 16,64 gam C. 13,04 gam D. 13,76 gam Cu 14: phn bit 2 dung dch AlCl3 v ZnSO4 c th dng bao nhiu dung dch trong s cc dung dch sau: dung dch NaOH, dung dch Ba(OH)2, dung dch NH3, dung dch BaCl2, dung dch Na2S

A. 2 dung dch B. 3 dung dch C. 4 dung dch D. c 5 dung dch Cu 15: Cho cc kim loi v ion sau: Cr, Fe2+, Mn, Mn2+, Fe3+. Nguyn t v ion c cng s electron c thn l A. Cr v Mn B. Mn2+, Cr, Fe3+ C. Mn, Mn2+ v Fe3+ D. Cr v Fe2+ Cu 16: Cho 15 gam glyxin tc dng va vi 8,9 gam alanin thu c m gam hn hp tripeptit mch h. Gi tr ca m l A. 22,10 gam B. 23,9 gam C. 20,3 gam D. 18,5 gam Cu 17: Pht biu no sau y l ng A. Phn t peptit mch h c s lin kt peptit bao gi cng nhiu hn s gc -amino axit B. Phn t peptit mch h to bi n gc -amino axit (cha mt nhm -COOH v mt nhm -NH2) c cha (n 1) lin kt peptit C. Cc peptit u c phn ng vi Cu(OH)2 to thnh phc cht c mu tm c trng D. Phn t tripeptit c ba lin kt peptit Cu 18: in phn c mng ngn 200 gam dung dch X cha KCl v NaCl n khi t khi kh ant bt u gim th dng li. Trung ha dung dch sau in phn cn 200 ml dung dch H2SO4 0,5M, c cn dung dch thu c 15,8 gam mui khan. Nng phn trm mi mui c trong dung dch X ln lt l A. 18,625% v 14,625% B. 7,5% v 5,85 % C. 3,725% v 2,925% D. 37,25% v 29,25% Cu 19: t chy hon ton 7,3 gam mt axit no, a chc mch h thu c 0,3 mol CO2 v 0,25 mol H2O. Cho 0,2 mol axit trn tc dng vi ancol etylic d c xc tc H2SO4 c. Tnh khi lng este thu c (gi s hiu sut phn ng t 100%). A. 40,4 gam B. 37,5 gam C. 28,6 gam D. 34,7 gam Cu 20: Nung 39,3 gam Na2Cr2O7, sau mt thi gian thu c 34,5 gam cht rn. Phn trm ca Na2Cr2O7 b nhit phn l A. 33,33% B. 66,67% C. 55% D. 45% Cu 21: Cho 0,1 mol cht X (CTPT C2H8O3N2) tc dng vi dung dch cha 0,2 mol NaOH un nng thu c cht kh lm xanh qu m v dung dchY (ch cha cc cht v c). C cn dung dch Y thu c m gam cht rn khan. Gi tr ca m l A. 8,5 gam B. 21,8 gam C. 5,7 gam D. 12,5 gam Cu 22: Hn hp X gm hiro v mt hirocacbon. Nung nng 14,56 lt hn hp X (ktc), c Ni xc tc n khi phn ng hon ton thu c hn hp Y c khi lng 10,8 gam. Bit t khi ca Y so vi metan l 2,7 v Y c kh nng lm mt mu dung dch brom. Cng thc phn t ca hirocacbon l A. C3H6 B. C4H6 C. C3H4 D. C4H8 Cu 23: Cho s sau: Cht A + NaOH trong s trn l A. CH2=CHCOOC2H5 B. CH2=C(CH3)COOCH3 C. CH2=CHCOOC4H9 D. CH2=C(CH3)COOC2H5 Cu 24: Cp ancol v amin c cng bc l A. C6H5NHCH3 v C6H5CH(OH)CH3 B. (CH3)2CHOH v (CH3)2CH-NH2 C. (C6H5)2NH v C6H5CH2OH D. (CH3)3COH v (CH3)3CNH2 Cu 25: Cho Ba (d) ln lt vo cc dung dch sau: NaHCO3, CuSO4, (NH4)2SO4, Al2(SO4)3, MgCl2. Tng s cc cht kt ta thu c l A. 6 B. 5 C. 7 D. 4 Cu 26: Cho cc ng phn anken mch nhnh ca C5H10 hp nc (xc tc H+). S sn phm hu c thu c l A. 6 B. 7 C. 5 D. 4 Cu 27: Trong cc tn gi di y, tn no khng ph hp vi cht c cng thc

(CH3)2CHCH(NH2)COOH A. axit -amino isovaleric B. axit 2-amino-3-metyl butanoic C. Valin D. axit 2-metyl-3-amino butanoic Cu 28: C bao nhiu cht trong cc cht sau lm qu tm chuyn mu xanh: phenol, natri phenolat, alanin, anilin, imetyl amin, phenylamoni clorua, natri axetat. A. 6 B. 3 C. 5 D. 4 Cu 29: Ho tan ht 7,8 gam hn hp bt Mg, Al bng 400 ml dung dch hn hp HCl 0,5M v H2SO4 0,75M thu c dung dch X v 8,96 lt kh H2 ( ktc). C cn dung dch X thu c lng mui khan l A. 35,9 gam B. 43,7 gam C. 100,5 gam D. 38,5 gam Cu 30: Ha tan hn hp Fe v FeCO3 trong dung dch HNO3 thu c hn hp 2 kh c t khi so vi H2 l 22,5. Hai kh l A. CO2 v NO2 B. CO2 v N2O C. NO2 v N2O D. NO v NO2 Cu 31: Nguyn liu iu ch axeton trong cng nghip l A. isopropylbenzen B. propan 2 ol C. propan 1 ol D. propin Cu 32: Dy cc ion sp xp theo chiu tnh oxi ha gim dn l A. Fe3+, Ag+, Cu2+, Fe2+, Al3+, Mg2+ B. Fe3+, Ag+, Fe2+, Cu2+, Al3+, Mg2+ C. Ag+, Fe3+, Cu2+, Fe2+, Al3+, Mg2+ D. Ag+, Cu2+, Fe2+, Fe3+, Al3+, Mg2+ Cu 33: t chy hon ton 0,08 mol hn hp 2 ancol bc mt, sau phn ng thu c 6,16 gam CO2. Nu oxi ho 0,08 mol hn hp 2 ancol trn bng oxi, xc tc Cu, un nng (gi s hiu sut 100%). Sau cho sn phm tc dng vi dung dch AgNO3/NH3 d, thu c m gam Ag. Gi tr ca m l A. m = 34,56 gam B. 17,28 gam < m < 34,56 gam C. m = 17,28 gam D. 21,6 gam m < 34,56 gam Cu 34: So snh khi lng Cu tham gia phn ng trong hai trng hp sau: - Ha tan m1 gam Cu cn va 200 ml dung dch hn hp HNO3 1,2M v H2SO4 0,3M - Ha tan m2 gam Cu cn va 200 ml dung dch hn hp NaNO3 1,2M v H2SO4 0,8M. Bit rng c 2 trng hp sn phm kh u l kh NO duy nht. T l m1 : m2 c gi tr bng A. m1 : m2 = 9 : 8 B. m1 : m2 = 8 : 9 C. m1 : m2 = 1 : 1 D. m1 : m2 = 10 : 9 Cu 35: Thy phn hon ton mt cht bo bng dung dch NaOH, sau phn ng thu c 2,78 gam C15H31COONa; m2 gam C17H31COONa v m3 gam C17H35COONa. Gi tr ca m2 v m3 ln lt l A. 3,02 gam v 3,05 gam B. 6,04 gam v 6,12 gam C. 3,02 gam v 3,06 gam D. 3,05 gam v 3,09 gam Cu 36: Ha tan 19,5 gam hn hp gm Na2O v Al2O3 trong nc thu c 500 ml dung dch A trong sut. Thm dn dung dch HCl 1M vo dung dch A n khi xut hin kt ta th dng li thy th tch dung dch HCl cn dng l 100 ml. Phn trm s mol mi cht trong A ln lt l A. 45% v 55% B. 25% v 75% C. 30% v 70% D. 60 % v 40% Cu 37: Cho V lt (ktc) hn hp kh gm 2 olefin lin tip nhau trong cng dy ng ng hp nc (xc tc H+) thu c 12,9 gam hn hp X gm 3 ancol. un nng X trong H2SO4 c 1400C thu c 10,65 gam hn hp Y gm 6 ete khan. Gi s hiu sut cc phn ng l 100%. Cng thc phn t ca 2 olefin v gi tr ca V l A. C2H4, C3H6, 5,60 lt B. C4H8, C5H10, 5,6 lt C. C2H4, C3H6, 4,48 lt D. C3H6, C4H8, 4,48 lt Cu 38: Trong s cc dung dch sau: K2CO3, KHCO3, Al2(SO4)3, FeCl3, Na2S, C6H5ONa, K2HPO3 s dung dch c pH>7 l A. 7 B. 5 C. 6 D. 4 Cu 39: iu khng nh no sau y l ng A. Pha long dung dch axit yu th hng s Ka khng i B. Pha long dung dch axit yu th in li khng i C. Pha long dung dch axit yu th hng s Ka gim D. Pha long dung dch axit yu th pH ca dung dch khng i Cu 40: Cho 11,2 lt hn hp X gm axetilen v anehit axetic ( ktc) qua dung dch AgNO3/NH3 d. Sau khi phn ng hon ton thu c 112,8 gam kt ta. Dn lng hn hp X nh trn qua dung dch nc brom d, s gam brom tham gia phn ng l (gi s lng axetilen phn ng vi nc l khng ng k) A. 64 gam B. 112 gam C. 26,6 gam D. 90,6 gam

Cu 41: phn bit phenol, anilin, benzen, stiren ngi ta s dng cc thuc th l A. qu tm, dung dch brom B. dung dch brom, qu tm C. dung dch NaOH, dung dch brom D. dung dch HCl, qu tm Cu 42: Dung dch nc ca cht A lm xanh qu tm, cn dung dch nc ca cht B khng lm i mu qu tm. Trn ln dung dch ca hai cht li th xut hin kt ta. A, B ln lt l A. Na2CO3 ; FeCl3 B. NaOH ; K2SO4 C. KOH; FeCl3 D. K2CO3; Ba(NO3)2 Cu 43: Hn hp kh X gm 0,1 mol vinylaxetilen v 0,4 mol H2. Nung nng hn hp X (c xc tc Ni) mt thi gian, thu c hn hp Y c t khi so vi hiro bng 10. Nu dn hn hp Y qua dung dch Brom th khi lng Brom tham gia phn ng l A. 24 gam B. 0 gam (khng phn ng) C. 8 gam D. 16 gam Cu 44: Chia 23,6 gam hn hp gm HCHO v cht hu c X l ng ng ca HCHO thnh 2 phn bng nhau. Phn 1, cho tc dng vi H2 d (t0C, xc tc), sau phn ng thu c 12,4 gam hn hp ancol. Phn 2, cho tc dng vi dung dch AgNO3/NH3 d thu c 108 gam bc. Cng thc phn t ca X l A. CH3CHO B. (CHO)2 C. C2H5CHO D. C2H3CHO Cu 45: Ha tan 20 gam mui sunfat ngm nc ca kim loi M (cha r ha tr) vo nc ri em in phn hon ton, thy catot tch ra 5,12 gam kim loi, anot thot ra 0,896 lit kh ( ktc). Cng thc ca mui ngm nc l A. Al2(SO4)3 B. CuSO4.5H2O C. CuSO4.3H2O D. FeSO4.7H2O Cu 46: Cn bao nhiu tn qung hematit cha 5% tp cht sn xut 1 tn gang c cha 95% Fe (Bit rng hiu sut ca qu trnh luyn gang l 90%) A. 1,537 tn B. 1,457 tn C. 1,587 tn D. 1,623 tn Cu 47: Cho a gam hn hp bt gm Ni v Cu vo dung dch AgNO3 (d). Sau khi kt thc phn ng thu c 54 gam cht rn. Mt khc cng cho a gam hn hp 2 kim loi trn vo dung dch CuSO4 (d), sau khi kt thc phn ng thu c cht rn c khi lng (a + 0,5) gam. Gi tr ca a l A. 15,5 gam B. 42,5 gam C. 33,7 gam D. 53,5 gam Cu 48: Cho V lt dung dch A cha ng thi FeCl3 1M v Fe2(SO4)3 0,5M tc dng vi dung dch Na2CO3 d, phn ng kt thc thy khi lng dung dch sau phn ng gim 69,2 gam so vi tng khi lng ca cc dung dch ban u. Gi tr ca V l A. 0,2 lt. B. 0,24 lt. C. 0,237 lt. D. 0,336 lt. Cu 49: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc l axit sunfuric c nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng l 90%). Gi tr ca m l A. 21 kg B. 30 kg C. 42 kg D. 10 kg Cu 50: Oxi ho ancol etylic bng xc tc men gim, sau phn ng thu c hn hp X (gi s khng to ra anehit). Chia hn hp X thnh 2 phn bng nhau. Phn 1, cho tc dng vi Na d, thu c 6,272 lt H2 (ktc). Trung ho phn 2 bng dung dch NaOH 2M thy ht 120ml. Hiu sut phn ng oxi ho ancol etylic l A. 42,86% B. 66,7% C. 85,7% D. 75%

Cho: H = 1; He = 4; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Ag = 108; Zn = 65; Ni = 59; Br = 80; Ba = 137; Pb = 207; P = 31; I = 127 v Cl = 35,5 ----------------------------------------------------------------------- HT -----------------------p n 1A 2B 3D 4D 11B 12B 13D 14C 21D 22C 23A 24A 31A 32C 33D 34A 41C 42D 43D 44C

5B 6C 7A 8D 9C 10B

15C 16C 17B 18C 19A 20B

25D 26D 27D 28B 29B 30A

35C 36D 37A 38B 39A 40B

45B 46C 47A 48A 49A 50D

S GD - T H TNH TRNG THPT L QUNG CH ( thi c 04 trang)

THI KHO ST CHT LNG LN II NM 2013 Mn: HO HC; Khi A, B Thi gian lm bi: 90 pht, khng k thi gian pht Kha ngy 30,31/03/2013 MT 132

H, tn th sinh:.................................................................................................................................................. S bo danh:..........................................................................................................................................................

- Th sinh khng s dng bng HTTH cc nguyn t ha hc - Cho bit nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137. Cu 1: Phenol phn ng c vi bao nhiu cht trong s cc cht sau: NaOH, HCl, Br 2, (CH3CO)2O, CH3COOH, Na, NaHCO3, CH3COCl. A. 4. B. 6. C. 5. D. 7. Cu 2: - Cho a gam Fe ( d) vo V1 lit Cu(NO3)2 1M thu c m gam rn. - Cho a gam Fe (d) vo V2 lit AgNO3 1M, sau phn ng thu c m gam rn. Mi lin h V1 v V2 l: A. V1 = 2V2 B. V1 = 10V2 C. V1 = V2 D. 10V1 = V2 Cu 3: Cho 8,04 gam hn hp hi gm CH3CHO v C2H2 tc dng hon ton vi dung dch AgNO 3/NH3 thu c 55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam cht khng tan. Gi tr ca m l: A. 61,78. B. 41,69. C. 55,2. D. 21,6. Cu 4: Do tc dng dit khun, c bit l vi khun gy thi ra nn dung dch ca hp cht X c dng ngm xc ng vt, thuc da, ty u X l: A. Ancol metylic. B. Ancol etylic. C. Anehit fomic. D. Anehit axetic. Cu 5: Cht hu c X c 1 nhm amino, 1 chc este. Hm lng N c trong X l 15,73%. X phng ho m gam X thu c hi ancol Z, cho Z qua CuO d thu c andehit Y ( phn ng hon ton), cho Y phn ng hon ton AgNO3/NH3d thu c 16,2 gam Ag . gi tr m l. A.7,725. B. 3,3375. C. 6,675. D. 5,625. Cu 6: Hai cht c dng lm mm nc cng vnh cu l: A. Na2CO3, HCl. B. NaCl, Ca(OH)2. C. Na2CO3, Ca(OH)2. D. Na2CO3, Na3PO4. Cu 7: Hn hp X gm Al, Fe2O3 c khi lng 21,67 gam. Tin hnh phn ng nhit nhm hn hp X trong iu kin khng c khng kh. Ha tan hon ton hn hp cht rn sau phn ng bng dung dch NaOH d thu c 2,016 lt H2 (ktc) v 12,4 gam cht rn khng tan. Hiu sut ca phn ng nhit nhm l: A. 80%. B. 75%. C. 60%. D. 71,43%. Cu 8: Hin tng no xy ra trong th nghim sau: Cho 0,1 mol Na vo 100 ml dung dch cha CuSO 4 1M v H2SO4 1M (long). A. Ch c kh bay ln. B. C kh bay ln v c kt ta mu xanh. C. Ch c kt ta. D. C kh bay ln v c kt ta mu xanh sau kt ta li tan. Cu 9: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung dch HNO3 th thu c 0,448 lt mt kh duy nht (o ktc) v dung dch Y. C cn cn thn dung dch Y thu c 23 gam cht rn khan T. Xc nh s mol HNO3 phn ng ? A. 0,28. B. 0,34. C. 0,36. D. 0,32. Cu 10: Trong cc cht Xiclopropan, xiclohexan, benzene, stiren, axit axetic, axit acrylic, andehit axetic, Andehit acrylic, axeton, etyl axetat, vinyl axetat, imetyl ete s cht c kh nng lm mt mu nc brom l. A. 5. B. 7. C. 6. D. 4. Cu 11: Oxi ha anehit X n chc bng O2 (xc tc thch hp) vi hiu sut phn ng l 75% thu c hn hp Y gm axit cacboxylic tng ng v anehit d. Trung ha axit trong hn hp Y cn 100 ml dung dch NaOH 0,75M ri c cn dung dch sau phn ng thu c 5,1 gam cht rn khan. Nu cho hn hp Y tc dng hon ton vi dung dch AgNO3 trong NH3 d, un nng th thu c khi lng Ag l A. 27,0 gam. B. 21,6 gam. C. 5,4 gam. D. 10,8 gam. Cu 12: in phn (in cc tr) dung dch NaCl v CuSO4 (t l mol tng ng l 3:1) n khi catot xut

hin bt kh th dng li .sn phm kh thu c Anot l A. kh Cl2. B. kh H2 v kh O2. C. kh Cl2v H2. D. kh Cl2v O2. Cu 13: Nhit phn hon ton m gam hn hp X gm KNO3 v Fe(NO3)2 . Hn hp kh thu c em dn vo bnh cha 2 lit H2O th khng thy kh thot ra khi bnh . Dung dich thu c c g tr pH=1 v ch cha mt cht tan duy nht, coi th tch dung dch khng thay i . gi tr m l A. 28,1. B. 23,05. C.46,1. D. 38,2. Cu 14: Nhn nh no sau y khng ng: A. Hn hp Fe3O4 v Cu c th tan ht trong dung dch HCl. B. Hn hp Al2O3 v K2O c th tan ht trong nc. C. Hn hp CuS v FeS c th tan ht trong dung dch HCl d. D. Hn hp Al v BaO c th tan ht trong nc. Cu 15: Cho a gam hn hp X gm Fe 2O3 v Cu tc dng vi 240 ml dung dch H 2SO4 long 0,5M. Sau khi phn ng xy ra hon ton, lc thu c 4,48 gam hn hp rn Y dung dch Z. Cho hn hp rn Y tc dng vi kh CO d thu c 3,52 gam hn hp rn A cha b gam Fe. Cc phn ng xy ra hon ton. Gi tr ca a v b ln lt l: A. 10,88 gam v 2,24 gam. B. 23,68 gam v 1,68 gam. C. 13,44 gam v 1,68 gam. D. 13,44 gam v 2,24 gam. Cu 16: Cho cc dung dch long sau (c cng nng mol): (1) CH 3COONa; (2) ClCH2COONa; (3) CH3CH2COONa v (4) NaCl. Th t pH tng dn ca cc dung dch trn l: A. (4)<(3)<(2)<(1). B. (4)<(2)<(3)<(1). C. (1)<(2)<(3)<(4). D. (4)<(2)<(1)<(3). Cu 17: Nh t t 500 ml dung dch H2SO4 1M long d vo bnh X cha m gam hn hp gm Fe 3O4 v Cu (c trn theo t l nol 1:2) khuy u thy hn hp tan dn v cn li 3,84 gam cht rn. Cho tip dung dch cha NaNO3 t t vo bnh X (sau phn ng ca hn hp X vi H 2SO4) khuy u cho n khi kh va ngng thot ra thu c V lt kh NO (sn phm kh duy nht). Tnh m v V: A. 21,6 gam; 2,24 lt. B. 21,6 gam; 0,896 lt. C. 10,8 gam; 0,896 lt. D. 10,8 gam; 1,344 lt. Cu 18: t chy ht 9,984 gam kim loi M (c ho tr II khng i ) trong hn hp kh Cl2 v O2. Sau phn ng thu c 20,73 gam cht rn v th tch hn hp kh phn ng l 3,4272 lit (ktc). Kim loi M l. A. Ca. B. Mg. C. Zn. D. Cu. Cu 19: Nhit si ca cc cht CH3Cl, CH3OH, HCOOH, CH4 tng theo th t l: A. CH3Cl < CH4< CH3OH < HCOOH. B. CH4 < CH3Cl < CH3OH < HCOOH. C. CH3Cl < CH3OH < CH4 < HCOOH. D. CH4 < CH3OH < HCOOH < CH3Cl. Cu 20: Cht hu c E c cng thc cu to l HCOOCH=CH 2. un nng m gam E sau ly ton b cc sn phm sinh ra thc hin phn ng trng gng thu c tng khi lng Ag l 108g Ag. Hiro ha m gam E bng H2 xc tc Ni,t0 va thu c E. t chy ton b lng E ri dn sn phm vo bnh ng dung dch NaOH d th khi lng bnh tng thm bao nhiu gam? A. 55,8g. B. 46,5g. C. 42g. D. 48,2g. Cu 21: Hn hp A gm CH4, C2H4, C3H4. Nu cho 26,8 gam hn hp X tc dng vi dung dch AgNO3/NH3 d th thu c 29,4 gam kt ta. Nu cho 8,4 lt hn hp X (ktc) tc dng vi dung dch Brom th thy c 54 gam brom phn ng. Phn trm th tch ca CH4 trong hn hp X l: A. 40%. B. 25%. C. 35%. D. 30%. Cu 22: Cho tng cht: C, Fe, BaCl2, Fe3O4, FeCO3, FeS, H2S, HI, AgNO3, HCl, Na2CO3, NaNO3, FeSO4 ln lt tc dng vi H2SO4 c, nng. S phn ng thuc loi oxi ha kh l: A. 9. B. 6. C. 7. D. 8. Cu 23: t chy hon ton 2,24 lt (ktc) hn hp kh gm: CH4, C2H4, C2H6, C3H8 thu c 6,16 gam CO2 v 4,14 gam H2O. S mol C2H4 trong hn hp trn l: A. 0,08 mol. B. 0,09 mol. C. 0,01 mol. D. 0,03 mol. Cu 24: Cho hn hp Fe3O4 v Cu vo dung dch HCl d. Sau khi phn ng xy ra hon ton thu c dung dch X v cht rn Y. Nh vy trong X cha: A. HCl, FeCl2, FeCl3. B. HCl, FeCl3, CuCl2. C. HCl, CuCl2, FeCl2. D. HCl, CuCl2. Cu 25: t chy hon ton m gam mt cacbohirat cn 13,44 lt kh O2 (ktc) sau em hp th hon ton sn phm chy trong 200 ml dung dch cha ng thi NaOH 1,75M v Ba(OH)2 1M thu c kt ta c khi lng l: A. 39,4 gam. B. 9,85 gam. C. 19,7 gam. D. 29,55 gam. Cu 26: C bao nhiu cht c th phn ng vi axit fomic trong s cc cht sau: KOH, NH3, CaO, Mg, Cu,

Na2CO3, Na2SO4, CH3OH, C6H5OH, dd Br2, AgNO3/NH3? A. 8. B. 9. C. 7. D. 6. Cu 27: Dung dch Y gm Al3+; Fe2+; 0,05 mol Na+; 0,1 mol SO42-; 0,015 mol Cl-. Cho V lt dung dch NaOH 1M vo dung dch Y thu c kt ta ln nht th gi tr ca V l: A. 0,30. B. 0,25. C. 0,40. D. 0,35. Cu 28: Cho x gam P2O5 tc dng ht vi 388 ml dung dch NaOH. C cn dung dch sau phn ng thu c 3x gam cht rn. Gi tr ca x l: A. 14,2. B. 12,78. C. 11,36. D. 17,04. Cu 29: Hn hp kh X gm SO2 v O2 c t khi so vi H2 l 24. Cho hn hp X (ktc) i qua bnh cha V2O5 nung nng. Hn hp thu c sau phn ng c t khi so vi H2 l 30. Hiu sut ca phn ng gia SO2 v O2 l: A. 20%. B. 60%. C. 40%. D. 80%. Cu 30: t chy hon ton m gam hn hp X gm ancol etylic, axetanehit, metyl fomat thu c 0,1 mol CO2 v 0,13 mol H2O. Cho m gam X trn vo mt lng d dung dch AgNO3/NH3 thu c a gam kt ta. Gi tr ca a l: A. 4,32. B. 1,08. C. 10,08. D. 2.16. Cu 31: Xt phn ng thun nghch sau: SO2(k) + NO2(k) SO3(k) + NO(k). Cho 0,11 mol SO2; 0,1 mol NO2; 0,07 mol SO3 vo bnh kn dung tch 1 lt. Khi t trng thi cn bng th cn li 0,02 mol NO2. Vy hng s cn bng KC l: A. 23,00. B. 20,00. C. 18,00. D. 0,05. Cu 32: X l mt pentapeptit mch h. Thy phn hon ton X ch thu c 1 aminoaxit no Y, mch h, c mt nhm amino v mt nhm cacboxyl (tng % khi lng ca O v N trong Y l 51,685%). Khi thy phn ht m gam X trong mi trng axit thu c 30,2 gam tetrapeptit; 30,03 gam tripeptit; 25,6 gam ipeptit v 88,11 gam Y. Gi tr ca m l: A. 156,66. B. 167,85. C. 141,74. D. 186,90. Cu 33: Tng s proton trong ht nhn nguyn t X v Y l 25. Y thuc nhm VIIA. dng n gin n cht X tc dng vi Y. khng nh no sau y ng? A. X l kim loi, Y l phi kim. B. trng thi c bn X c 2 electron c thn. B. Cng thc oxit cao nht ca X l XO3. C. Cng thc oxit cao nht ca X l Y2O. Cu 34: Cho phn ng CO(k) + H2O(k) CO2 (k) + H2 (k) + H <0 Trong cc yu t (1) Tng nhit , (2) thm lng CO, (3) thm mt lng H 2, (4) gim p sut chung ca h, (5) dung cht xc tc. S yu t lm thay i cn bng l. A. 2. B. 4. C. 3. D. 5. Cu 35: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo dung dch X, thu c 2a gam kt ta. Mt khc, nu cho 400 ml dung dch NaOH 1M vo dung dch th thu c a gam kt ta. Cc phn ng xy ra hon ton, gi tr ca m l: A. 20,52. B. 19,55. C. 15,39. D. 18,81. Cu 36: Cc nguyn t thuc nhm IA, theo chiu tng dn ca in tch ht nhn th: A. Bn knh nguyn t tng dn. B. Nng lng ion ho tng dn. C. Tnh kh gim dn. D. m in tng dn. Cu 37: Cho hn hp X gm 2 amin n chc l ng ng k tip nhau tc dng va vi dung dch HCl thu c 14,2 gam hn hp mui. Cho hn hp mui vo dung dch AgNO3 d thu c 28,7 gam kt ta. Hy cho bit cng thc phn t ca cc cht trong hn hp X l: A. C2H7N, C3H9N B. C3H9N, C4H11N C. CH5N, C2H7N D. C4H11N, C5H13N Cu 38: Dy gm cc kim loi u tc dng vi dung dch Fe(NO3)3 l: A. Cu,Ag,Au,Mg. B. Fe,Mg,Cu,Ag,Al. C. Fe,Zn,Cu,Al,Mg. D. Au,Cu,Al,Mg,Zn. Cu 39: Fructoz v saccaroz u c: A. phn ng trng bc. B. 5 nhm hiroxyl trong phn t. C. phn ng kh brom trong dung dch nc. D. phn ng ha tan Cu(OH)2 nhit thng. Cu 40: Cho m gam anilin tc dng vi 150ml dung dch HCl 1M thu c hn hp X c cha 0,05 mol anilin. Hn hp X ny tc dng va vi V ml dung dich NaOH 1M. Gi tr ca m v V ln lt l: A. 9,3 v 300. B. 18,6 v 150. C.18,6 v 300. D. 9,3 v 150. Cu 41: Dy gm cc kim loi u tc dng vi nc nhit thng to ra cc mi trng kim l: A. Li, K, Ca. B. Zn, Na, Ba. C. Fe, K, Ba. D. Be, Na, Ca.

Cu 42: Cho Na tc dng vi 100ml dd AlCl 3 thu c 5,6 lt H2(ktc) v kt ta . Lc kt ta ri em nung n khi lng khng i thu c 5,1 gam cht rn. Nng mol/l ca dd AlCl3 l: A. 1,5M. B. 2,5M. C. 2,0M. D. 1,0M. Cu 43: Cho cc hp cht: amoniac; p nitroanilin; p aminotoluen; metylamin; imetylamin. Dy no trong cc dy sau c sp xp theo th t tng dn tnh baz? A. p O2N-C6H4-NH2 < C6H5-NH2 < p CH3-C6H4-NH2 < NH3 < (CH3)2NH < CH3-NH2 B. C6H5-NH2 < p O2N-C6H4-NH2 < p CH3-C6H4-NH2 < NH3 < CH3-NH2 < (CH3)2NH C. (CH3)2NH < CH3-NH2 < NH3 < p CH3-C6H4-NH2 < C6H5-NH2 < p O2N-C6H4-NH2 D. p O2N-C6H4-NH2 < C6H5-NH2 < p CH3-C6H4-NH2 < NH3 < CH3-NH2 < (CH3)2NH Cu 44: Cho dung dich NH3 d ln lt vo tng dung dch FeCl 3, AgNO3, NaCl, Cu(NO3)2. S trng hp thu c kt ta sau phan ng la: A. 1. B. 4. C. 3. D. 2. Cu 45: Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na 2O v Al2O3; Cu v FeCl3; BaCl2 v CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l: A. 4. B. 1. C. 3. D. 2 Cu 46: t chy hon ton hn hp gm 2 este no h n chc cn 5,68 g kh oxi v thu c 3,248 lt kh CO2 (ktc). Cho hn hp este trn tc dng va vi KOH thu c 2 ru l ng ng k tip v 3,92 g mui ca mt axit hu c. Cng thc cu to ca 2 este l : A. HCOOCH3 v HCOOC2H5. B. C3H7COOCH3 v CH3COOC2H5. C. CH3COOCH3 v CH3COOC2H5. D. C2H5COOCH3 v C2H5COOC2H5. Cu 47: Thc th cn dng phn bit ancol etylic nguyn cht v cn 960 l A. HCl. B. Cu(OH)2. C. Na. D. CuSO4. Cu 48: Cho 7,68g hn hp gm FeO, Fe3O4 v Fe2O3 tc dng va ht vi 260ml dung dch HCl 1M thu c dung dch X. Cho X tc dng vi dung dch NaOH d, lc kt ta, nung trong khng kh n khi lng khng i thu c m gam cht rn, gi tr ca m l: A. 8g. B. 12g. C. 16g. D. 24g. Cu 49: Trong dy bin ha: C2H6 C2H5Cl C2H5OH CH3CHO CH3COOH CH3COOC2H5 C2H5OH C2H5OC2H5. S phn ng oxi ha- kh trn dy bin ha trn l A. 3. B. 4. C. 5. D. 2. Cu 50: Trong phng th nghim, hirohalogenua (HX) c iu ch t phn ng sau: NaX(rn) + H2SO4 (c, nng) NaHSO4 (hoc Na2SO4) + HX (kh). Hy cho bit phng php trn c th dng iu ch c hirohalogenua no sau y ? A. HBr v HI. B. HF v HCl. C. HCl, HBr v HI. D. HF, HCl, HBr, HI. ------------------------ HT---------------------(Cn b coi thi khng gii thch g thm)

 THI TH I HC LN 2 KHI A,B (2012-2013) Thi gian lm bi:90 pht; (60 cu trc nghim) (Th sinh nh ghi m thi v khng c s dng ti liu) H, tn th sinh:..................................................................... ............................. PHN I Phn chung cho tt c th sinh [40 cu]: H = 1; He = 4; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137; Au = 197 Cu 1: Cho 3,84 gam Cu tc dng vi 100 ml dung dch hn hp HNO3 0,6M v H2SO4 0,6 M, sn phm kh duy nht l kh NO. S gam mui khan thu c khi c cn dung dch sau phn ng l: A. 8,84 B. 7,90 C. 9,74 D. 10,08 Cu 2: Tin hnh cc th nghim sau: - TN1: Cho hi nc i qua ng ng bt st nung nng. - TN2:Cho inh st nguyn cht vo dung dch H 2SO4 long c nh thm vi git dung dch CuSO4. - TN 3: Cho tng git dung dch Fe(NO3)2 vo dung dch AgNO3 . - TN 4: thanh thp (hp kim ca st vi cacbon) trong khng kh m. - TN 5:Nhng l km nguyn cht vo dung dch CuSO4. S trng hp xy ra n mn in ho hc l: A. 2. B. 1. C. 4. D. 3. Cu 3: Dn 3,36 lt hn hp kh X gm C 2H2 v C3H6 qua dung dch AgNO3/NH3 d thu 12 g kt ta. Nu trn 1/2 hn hp X trn vi 2,8 lt kh H 2 (kc) sau un nng hn hp vi xc tc Ni thu hn hp kh Y, t khi hi ca Y so vi H 2 l 12. Cho 0,1mol Y qua dung dch Brm d s gam Brm tham gia phn ng l: A. 2,4 B. 6,4 C. 1,6 D. 3,2 Cu 4: nhn bit ba l mt nhn cha cc cht Benzen, toluen, stiren ngi ta dng mt thuc th duy nht lA. Na B. Nc brom C. Dung dch NaOH D. Dung dch KMnO4 Cu 5: Hn hp X gm propin v H2 ly cng s mol. Ly mt lng hn hp X cho i qua cht xc tcNi, un nng c hn hp Y gm 4 cht. Dn Y qua bnh ng nc brom d thy khi lung bnh tng 6,48 gam v thot ra 2,688 lt kh Z (ktc) c t khi so vi H 2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 13,44lt. B. 11,2 lt. C. 17,92lt. D. 20,16lt Cu 6: Trn u 6,102 gam hn hp Al, Fe 3O4 v CuO (cc cht c cng s mol) ri tin hnh phn ng nhit nhm thu c hn hp X. Cho X tc dng vi x lt dung dch HNO 3 1M d c V ml ( ktc) hn hp kh NO2 v NO theo t l mol tng ng l 1:1. Tnh gi tr ca x ( bit dng d 5% so vi lng phn ng) A. 0,288. B. 0,3024. C. 0,1134 D. 0,2646 Cu 7: Chn pht biu khng ng A. Hp cht hu c C4H8 c tt c 4 ng phn mch h. B. Hp cht hu c C2H7O2N khng phi l amino axit C. Hp cht hu c C4H10O c 7 ng phn D. C7H8O c 5 ng phn cha vng thm tc dng vi Na Cu 8: Thy phn dung dch cha 10,26 gam mantoz mt thi gian. Ly ton b sn phm thu c sau phn ng thy phn cho tc dng vi lng d dung dch AgNO 3 trong NH3, sau phn ng hon ton thu c 9,396 gam Ag. Hiu sut ca phn ng thy phn mantoz l: A. 55% B. 50% C. 45% D. 25% Cu 9: Ch t cc ho cht: KMnO4 (rn) ; Zn ; FeS ; dung dch HCl c, cc thit b v iu kin M thi132

cn thit c , ta c th iu ch c ti a bao nhiu kh: A. 7. B. 6. C. 8. D. 5. Cu 10: t chy hon ton hn hp M gm : ancol X, axit cacboxylic Y v este Z (u no n chc mch h v Y, Z c cng s nguyn t C) cn dng va 12,32 lt O 2 (kc) sinh ra 11,2 lt CO 2 (kc). Cng thc ca Z l : A. HCOOCH3 B. CH3COOCH3 C. HCOOC2H5 D. CH3COOC2H5 Cu 11: Ancol etylic c th iu ch t etylen(ly t kh crackinh du m)hoc ln men nguyn liu cha tinh bt. Hy tnh lng ng cc cha 65% tinh bt hoc th tch kh crackinh du m (ktc) cha 60% kh etilen cn thit sn xut 2,3 tn ancol etylic .(Bit hao ht trong qu trnh sn xut l 25%) A. 6,23 tn hoc 1,87.106 lt B. 6,23 tn hoc 1,88.106 lt 6 C. 8,3 tn hoc 2,49.10 lt D. 8,3 tn hoc 2,48.106 lt Cu 12: Oxi ho 51,2 gam CH3OH (c xc tc) thu c hn hp sn phm X. Chia X thnh hai phn bng nhau Phn 1 tc dng vi AgNO3 d trong NH3 un nng thu c m gam Ag. Phn 2 tc dng va vi 200ml dung dch KOH 1M. Hiu sut qu trnh oxi ho CH3OH l 75%. Gi tr ca m l A. 216. B. 108 C. 129,6. D. 172,8 Cu 13: Cho cc polime sau: t capron; poli(vinyl clorua); thy tinh plexiglas; teflon; t lapsan, t nitron, t enang,caosubuna. Trong , s polime c iu ch bng phn ng trng hp l A. 4. B. 6. C. 7. D. 5. Cu 14: Thc hin cc th nghim sau: (1). Sc kh C2H4 vo dung dch KMnO4. (2). Sc CO2 d vo dung dch NaAlO2 (3). Chiu sng vo hn hp kh (CH4; Cl2). (4). Sc kh H2S vo dung dch FeCl3. (5). Cho NH3 tc dng vi CrO3 (6). Sc kh SO2 vo dung dch H2S. (7) glixerol tc dng vi Cu(OH)2 (8)Sc kh SO2 vo dung dch Ca(OH)2 (9)Cho K2SO3 tc dng vi dd H2SO4 c (10)Sc kh Cl2 vo dung dch KI S th nghim c phn ng oxi ho- kh xy ra l A. 5 B. 6. C. 4 D. 7 Cu 15: Trong cc ho cht Cu, P, S, Na2SO3, FeS2 , O2, H2SO4 c. Cho tng cp cht phn ng vi nhau trong iu kin thch hp th s cp cht c phn ng to ra kh SO2 l A. 9 B. 8 C. 7 D. 6 Cu 16: Hn hp X c C2H5OH, HCOOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m gam hn hp X thu c 2,52 gam H 2O v 2,464 lt CO2 (ktc). Mt khc 10,88gam hn hp X cho tc dng vi Na d th thu c V lt H2 (ktc). Gi tr ca V l: A. 1,792 B. 2,24 C. 0,448 D. 0,896. Cu 17: t chy hon ton mt hn hp X (glucoz, fructoz, metylfomat, metanal v axitetanoic) cn 2,688 lt O2 (iu kin chun). Dn sn phm chy qua bnh ng dung dch Ba(OH) 2 d, sau phn ng hon ton thu c m gam kt ta. Gi tr ca m l A. 35,46 B. 39,4 C. 23,64 D. 35,46 Cu 18: Cho dy cc cht: etanal, eten, etin, axit fomic, axit benzoic, axit crilic,anilin, metylfomat, etanol, benzen, isopren. S cht trong dy lm mt mu dung dch brom l A. 5 B. 8 C. 7 D. 6 Cu 19: Hn hp kh X gm CO2 v NO2 hp th vo dung dch NaOH va to thnh cc mui trung ha, sau em c cn dung dch thu c 36,6 gam mui khan. Nung mui khan nhit cao n khi lng khng i thu c 35 gam cht rn khan. % th tch mi kh trong hn hp l A. 20% v 80% B. 75% v 25% C. 80% v 20% D. 50% v 50% Cu 20: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch X. Cho 320 ml dung dch KOH 1M vo X, thu c 3a gam kt ta. Mc khc, nu cho 400 ml dung dch KOH 1M vo X, thu c a gam kt ta. Cc phn ng xy ra hon ton, gi tr ca m l

A. 37,62 B. 15,39 C. 18,81 D. 20,52 Cu 21: Cho s phn ng : C2H2 X Y CH3COOH Trong cc cht sau CH 2=CH-OOCCH3 , C2H4, C2H6, C2H5OH, CO2 , CH3CHO, C6H6 S cht ph hp vi X l: A. 3 B. 5 C. 4 D. 2 Cu 22: Cho cc cht sau: axetilen, axit fomic, fomanehit, phenyl fomat, glucz, axeton, anehit axetic, metyl axetat, mantz, natri fomat. S cht c th tham gia phn ng trng gng l A. 6 B. 7 C. 8 D. 5 Cu 23: Dy ch cha nhng amino axit m dung dch khng lm i mu qu tm l? A. Gly, Ala, Glu B. Gly, Glu, Lys C. Gly, Val, Ala D. Val , Lys, Ala Cu 24: tch c CH3COOH t hn hp gm CH 3COOH v C2H5OH ta dng ho cht no sau y? A. Ca(OH)2 v dung dch H2SO4 B. CuO (to) v AgNO3/NH3 d C. Na v dung dch HCl D. Na v H2SO4 c Cu 25: Cho 14,4g hn hp Fe, Mg, v Cu (s mol mi kim loi bng nhau) tc dng ht vi dung dch HNO3 (ly d 10% so vi lng phn ng) thu c dung dch X v 2,688 lt hn hp 4 kh N 2, NO, NO2, N2O trong 2 kh N2 v NO2 c s mol bng nhau. C cn cn thn dung dch X thu c 58,8g mui khan. Tnh s mol HNO3 ban u dng. A. 0,9823 B. 0,804 C. 0.4215 D. 0,893 Cu 26: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A. C2H4(OH)2, CH3OH, CH3CHO. B. CH3CHO, C2H5OH, C2H5COOCH3. C. CH3OH, C2H5OH, CH3CHO. D. CH3CHO, C6H12O6 (glucoz), CH3OH. Cu 27: Ha tan mt lng ancol X vo nc thu c 6,4 gam dung dch Y, nng ca X trong Y l 71,875%. Cho 25,6 gam dung dch Y tc dng vi lng d Na thu c 11,2 lt H2 (dktc). S nguyn t H c trong cng thc phn t ancol X l: A. 8 B. 4 C. 6 D. 10 Cu 28: Xt cc cht: imetylete (1), ancol etylic (2),ancol metylic (3), axit axetic (4), Cc cht trn c xp theo nhit si tng dn (t tri sang phi) l: A. 4, 2, 3, 1 B. 2, 3, 4, 1 C. 1, 3, 2, 4 D. 1, 2, 3, 4 dung tch 500ml vi 1 mol N2 , 4 mol H2 v Cu 29: Thc hin phn ng trong bnh kn c mt t xc tc (c th tch khng ng k). Khi phn ng t ti trng thi cn bng th p sut trong bnh bng 0,8 ln p sut ban u khi cha xy ra phn ng cng nhit . Hng s cn bng (KC ) ca phn ng N2 + 3H2 2NH3 xy ra trong bnh l A. 0,800. B. 0,128. C. 0,032. D. 0,016. Cu 30: X l hn hp cc mui Cu(NO3)2, Zn(NO3)2, Fe(NO3)2 , Al(NO3)3 c mol bng nhau. Trong O chim 9,6% v khi lng. Ha tan 90 gam X vo nc ,thm dung dich NH 3 d , ly kt ta thu c em nung ngoi khng kh n khi lng khng i m gam oxit. Gi tr ca m l A. 4,46 B. 3,92 C. 2,62 D. 4,68 Cu 31: X l hp cht hu c, mch h ch cha mt loi nhm chc. t chy hon ton X ch thu c CO2 v H2O. Khi lm bay hi hon ton 4,5 gam X thu c th tch bng th tch ca 2,1 gam kh N 2 cng iu kin. S cng thc cu to ca X tha mn l: A. 3 B. 5 C. 6 D. 4 Cu 32: Ha tan hon ton 6,44 gam hn hp bt X gm Fe xOy v Cu bng dung dch H 2SO4 c nng (d). Sau phn ng thu c 0,504 lt kh SO 2 (sn phm kh duy nht, ktc) v dung dch cha 16,6 gam hn hp mui sunfat. Cng thc ca oxit st l: A. FeO B. Fe3O4 C. FeO hoc Fe3O4. D. Fe2O3 Cu 33: in phn 500 ml dung dch cha hn hp gm CuCl 2 0,06 M v Fe2(SO4)3 0,03 M vi in cc tr, c mng ngn vi cng dng in l 5A trong thi gian 41 pht 49 giy th dng in phn . Tnh pH dung dch sau in phn v gim khi lng ca dung dch .( gi s V dung

dch thay i khng ng k) A. 1,15 5,92 gam B. 1,15 ; 5,73 gam C. 0,85 5,92 gam D. 0,85 ; 5,73 gam Cu 34: Ch dng mt thuc th phn bit cc kim loi sau: Mg, Al, Cr, Ba? A. Dung dch NaCl B. Nc C. Dung dch NaOH D. Dung dch H2SO4 long Cu 35: Cho phng trnh ho hc: FeSO4 + KMnO4 + KHSO4 Fe2(SO4)3 + MnSO4 + K2SO4 + H2O. Tng h s ( s nguyn t, ti gin) ca cc cht c trong sn phm phn ng l: A. 52 B. 76 C. 24 D. 28 Cu 36: Hn hp X gm CO v CO 2 c t khi so vi H2 l 19. Sc V lt hn hp X (ktc) vo 200 ml dung dch X gm Ba(OH)2 1M v NaOH 1M. Sau phn ng thu c 19,7 gam kt ta, gi tr ln nht ca V l: A. 13,44 B. 17,92 C. 20,16 D. 11,2 Cu 37: Tnh lng FeS2 cn dng iu ch mt lng SO 3 ha tan vo 100g dung dch H2SO4 91% thnh oleum cha 12,5 % khi lng SO3 (gi thit cc phn ng hon ton) A. 22,5 g B. 90 g C. 60 g D. 45 gam Cu 38: Ha tan hon ton 27,84 gam hn hp X gm MgO, FeO , Fe 2O3 phi dng va ht 520 ml dung dch 2M. Mt khc , khi ly 0,54 mol hn hp X t nng trong ng s khng c khng kh ri thi mt lung H2 d i qua phn ng xy ra hon ton th thu c m gam cht rn v 9,72 gam nc. Tnh m ? A. 22,08 B. 20,88 C. 15,24 D. 14,52 Cu 39: Trieptit mch h X v tetrapeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol X thu c sn phm gmN2,CO2 v H2O trong tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol Y cn bao nhiu mol oxi ? A. 3,2 B. 2,7 C. 3,0 D. 1,5 Cu 40: C cc nhn nh sau: 1) Cu hnh electron ca ion X3+ l 1s22s22p63s23p63d5. Trong bng tun hon cc nguyn t ho hc, nguyn t X thuc chu k 4, nhm VIIIB. 2) Cc ion v nguyn t: Ne , Na+ , F c im chung l c cng s electron. 3) Cu hnh electron ca ion 29Cu+ l 1s22s22p63s23p63d94s1 4) Phn ng xy ra gia kim loi v bt S u cn phi c nhit 5) C 9 nguyn t c cu hnh electron sau cng l 4s2 Cho: N (Z = 7), F (Z=9), Ne (Z=10), Na (Z = 11), S (Z = 16). S nhn nh ng: A. 3. B. 5. C. 4. D. 2. PHN II Th sinh c chn mt trong hai phn sau
Chng trnh phn ban [10 cu]:

Cu 41: Thy phn hon ton 1 mol oligopeptit X mch h thu c 2 mol Gly, 1 mol Ala, 1 mol Val, 1 mol Tyr. Mt khc, nu thy phn khng hon ton th thu c sn phn c cha Gly-Val, Val-Gly. S cng thc cu to ph hp ca X l. A. 4 B. 8 C. 2 D. 6 Cu 42: Pht biu no sau y khng ng: A. nh hng ca nhm -NH2 n vng thm lm cho anilin phn ng vi dung dch brom. B. Phn ng cng xy ra gia benzen v clo khi c xc tc l nh sng C. Anilin khng lm i mu qu tm m. D. nh hng ca vng benzen n nhm -OH lm cho phenol phn ng vi dung dch brom. Cu 43: Ngi ta c th iu ch cao su Buna t g theo s sau: TH 35 60 % Cao su Buna XenlulozglucozC2H5OHButa-1,3-ien 80 Khi lng xenluloz cn sn xut 2 tn cao su Buna l

A. 25,625 tn. B. 37,875 tn. C. 6,000 tn. D. 35,714tn. Cu 44: Cho 46,5 gam hn hp X gm Al, Fe, Cr vo cc ng dung dch NaOH d thu c 0,45 mol H2 . Cho tip vo cc dung dch HCl d thu thm c 0,7 mol H 2 . Tnh V Cl2 (kc) tc dng ht vi 15,5 gam hn hp X trn : A. 11,2 B. 22,4 C. 44,8 D. 33,6 Cu 45: Ha tan 6,96 gam Fe 3O4 bng dung dch HCl va thu c dung dch X . Cho 500 ml dung dch AgNO3 0,51 mol/l tc dng vi dung dch X. Sau khi phn ng kt thc thu c m gam cht rn v dung dch Y. Gi tr ca m l A. 36,06 B. 34,44 C. 36,6 D. 38 Cu 46: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n khi phn ng xy ra hon ton, thu c cht rn v hn hp kh Y c thnh phn th tch: N2 = 84,77%; SO2 = 10,6% cn li l O2. Thnh phn % theo khi lng ca FeS trong X l A. 68,75% B. 59,46% C. 26,83% D. 42,3% Cu 47: Cho s phn ng sau: + HCN + H3O+, to + H2SO4 , to xt, to, p CH3CH=O A B D E D c tn l A. axit metacrylic. B. axit acrylic. C. anehit acrylic. D. axit axetic. Cu 48: t chy hon ton mt lng hn hp hai este n chc no, mch h cn 3,976 lt oxi (ktc) thu c 6,38 gam CO2. Cho lng este ny tc dng va vi KOH thu c hn hp hai ancol k tip v 3,36gam mui ca mt axit hu c. Cng thc ca hai cht hu c trong hn hp u l: A. CH3COOCH3 v CH3COOC2H5 B. HCOOC2H5 v HCOOCH3 C. CH3COOC2H5 v CH3COOC3H7 D. HCOOC3H7 v HCOOC2H5 0 Cu 49: Cho ba kim loi: M, R, X . Bit E ca 2 cp oxi ho - kh M2+/M = -0,76V v R2+/R = +0,34V; khi cho X vo dung dch mui ca R th c phn ng xy ra cn khi cho X vo dung dch mui ca M th khng xy ra phn ng; E0 ca pin M-X = +0,63V th E0 ca pin X-R bng A. 0,47V. B. 1,10V. C. 0,21V. D. 1,05V. Cu 50: Pht biu no sau y l ng? A. Amin bc mt c phn ng vi axit nitr nhit thng cho ancol bc mt hoc phenol v gii phng nit. B. Kh este CH3COOC2H5 bng LiAlH4 thu c hn hp 2 ancol l ng ng k tip C. Dng ho cht Cu(OH)2/OH-, c th phn bit c ht cc dung dch khng mu: Gly-Ala; mantoz; glixerol; etanol ng trong cc l mt nhn. D. Hn hp rn gm cc cht: CuCl2, AgNO3, ZnCl2 cng s mol khng th tan ht trong dung dch NH3 d.
Chng trnh khng phn ban [10 cu]:

Cu 51: T CH3COONa v cc cht v c cn thit, cn phi dng t nht bao nhiu phn ng iu ch c polivinylaxetat? A. 5 B. 6 C. 7 D. 4 Cu 52: Cho phn ng sau: 2SO2(k) + O2(k) 2SO3(k) ;H < 0 cn bng trn chuyn dch theo chiu thun th: (1): tng tng nhit , (2): tng p sut, (3): h nhit , (4): dng xc tc l V2O5, (5): Gim nng SO3. Bin php ng l: A. 1, 2, 3, 4, 5. B. 2, 3, 5. C. 1, 2, 5. D. 2, 3, 4, 5. Cu 53: Cho t t 150 ml dung dch HCl 1M vo 500 ml dung dch X gm Na 2CO3 v NaHCO3 th thu c 1,008 lt kh (ktc) v dung dch Y. Cho dung dch Y tc dng vi dung dch Ba(OH) 2 d th thu c 39,4 gam kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dung dch X ln lt l: A. 0,21M v 0,18M B. 0,21M v 0,28M C. 0,2M v 0,26M D. 0,2M v 0,4M

Cu 54: Cho m gam Fe tc dng ht vi dung dch cha y mol CuSO 4 v z mol H2SO4 long, sau phn ng hon ton thu c kh H 2, m gam Cu v dung dch ch cha mt cht tan duy nht. Mi quan h gia y v z l A. y = 7z. B. y = z. C. y = 3z. D. y = 5z. Cu 55: Hn hp bt X gm BaCO3, Fe(OH)2, Al(OH)3, CuO, MgCO3. Nung X trong khng kh n khi lng khng i c hn hp rn A1. Cho A1 vo nc d khuy u c dung dch B cha 2 cht tan v phn khng tan C1. Cho kh CO d qua bnh cha C1 nung nng c hn hp rn E (Cho cc phn ng xy ra hon ton). E cha ti a: A. 3 n cht. B. 1 n cht v 2 hp cht. C. 2 n cht v 2 hp cht. D. 2 n cht v 1 hp cht. Cu 56: Cho 40,8 gam hn hp gm phenylaxetat v metyl benzoat (t l mol 1:1) tc dng vi 800 ml dung dch NaOH 0,7M thu c dung dch X. C cn dung dch X th khi lng cht rn thu c l A. 50,9 B. 50,6 C. 55,7 D. 58,4 Cu 57: Hp cht X cha mt nhm chc anehit trong phn t. Cho 0,52 gam X tc dng vi dung dch AgNO3 trong NH3 d to ra 1,08 gam Ag. Mt khc cho 3,12 gam X tc dng ht vi Na to ra 672 ml H2 (ktc). S lng cht c cu to mch thng tha mn tnh cht ca X l A. 2 cht B. 3 cht C. 4 cht D. 6 cht Cu 58: Thy phn triglixerit X trong NaOH ngi ta thu c hn hp 2 mui natrioleat v natristearat theo t l mol 1: 2. Khi t chy a mol X thu c b mol CO 2 v c mol H2O. Lin h gia a, b, c l A. b c = 4a B. b - c = 3a C. b c = 2a D. b = c a Cu 59: Hn hp M gm hai cht hu c X, Y n chc cng cha C, H, O. X, Y khng tc dng vi Na nhng tc dng vi NaOH. Cho 21g M tc dng va vi 300ml dung dch NaOH 1M thu c hai mui hu c v mt ancol Z. Khi lng 2 mui l 28gam, khi lng ancol l 3,2 gam. Bit Mx > My khi lng ca X c th l: A. 12,2 gam B. 7.4 g C. 11,8 g D. 13,6 g Cu 60: Mt hn hp X gm Na, Al v Cr (vi t l mol Na v Al tng ng l 4: 5) tc dng vi H2O d th thu c V lt kh, dung dch Y v cht rn Z. Cho Z tc dng vi dung dch H 2SO4 long d th thu c 0,25V lt kh (cc kh o cng iu kin). Thnh phn % theo khi lng ca Cr trong hn hp X l A. 34,8%. B. 10,28 % C. 20,07% D. 14,4%
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TRNG THPT CHUYN NGUYN HU THI TH I HC LN TH HAI NM HC 2012-2013 MN : HA HC - KHI A, B Thi gian lm bi: 90 pht; (60 cu trc nghim) H, tn th sinh:.......................................................................... S bo danh:............................................................................... M thi 132 (Th sinh khng c s dng ti liu) I. Phn chung cho tt c cc th sinh( 40 cu, t cu {<1>} n cu {<40>}) Cu 1: Dung dch phenol phn ng vi my cht trong s cc cht sau y: Na, dung dch brom, dung dch NaCl, dung dch NaOH, axit HNO3 /H2SO4 c, dung dch NaHCO3, dung dch Na2CO3, CH3COOH, HCl. A. 4 B. 6 C. 5 D. 7 Cu 2: Anehit th hin tnh kh khi tc dng vi cht no trong s cc cht sau? A. H2/Ni, t0 B. NaOH C. AgNO3/NH3, t0 D. HCN Cu 3: Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d dung dch AgNO3 trong NH3, to ra 48,6g Ag. Phn trm khi lng ca propan-1-ol trong X l: A. 65,2%. B. 16,3%. C. 48,9%. D. 34,5%. Cu 4: cim ca phn ng este ha l: A. Phn ng hon ton, cn un nng, c H2SO4 long xc tc. B. Phn ng hon ton, cn un nng, c H2SO4 m c xc tc. C. Phn ng thun nghch, cn un nng, c H2SO4 m c xc tc. D. Phn ng thun nghch cn un nng v c xc tc bt k. Cu 5: Cho 46,6 gam hn hp X gm Na, K, Ba v Al2O3 (trong oxi chim 30,9% v khi lng) tan ht vo nc thu c dung dch Y v 8,96 lt H2 (ktc). Cho 3,1 lt dung dch HCl 0,5M vo dung dch Y thu c m gam kt ta. Gi tr ca m l: A. 7,8. B. 35,1. C. 27,3. D. 0. Cu 6: Cho hn hp X gm hai hp cht hu c no, n chc A, B tc dng va vi 100 ml dung dch KOH 0,40M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 d th khi lng bnh tng 5,27 gam. Cng thc ca A, B l: A. HCOOH v HCOOC3H7. B. HCOOH v HCOOC2H5. C. C2H5COOH v C2H5COOCH3. D. CH3COOH v CH3COOC2H5. Cu 7: Cho Na d vo V (ml) cn etylic 460 (khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml; ca nc l 1 g/ml) thu c 42,56 lt H2 (ktc). Gi tr ca V l: A. 475 ml B. 200 ml C. 100 ml D. 237,5 ml Cu 8: Dy cht no sau y u th hin tnh oxi ha khi phn ng vi SO2? A. Magie, hiro sunfua, cacbon. B. Oxi, nc brom, dung dch thuc tm C. Magie, clo, hiro sunfua. D. Bari hiroxit, natri oxit, oxi. Cu 9: Cho m gam hn hp X gm axit acrylic, ancol anlylic, axit aipic v hiroquinon (p-ihiroxibenzen) tc dng vi kali d thu c 6,72 lt H2 (ktc). Nu t chy hon ton m gam hn hp X trn th th tch kh CO2 (ktc) thu c l: A. 40,32 lt. B. 49,28 lt. C. 13,44 lt. D. 20,16 lt. Cu 10: Nhn xt no sau y ng: A. Nhm kim loi khng tc dng vi nc do th in cc chun ca nhm ln hn th in cc chun ca nc. B. Trong phn ng ca nhm vi dung dch NaOH th NaOH l cht oxi ha C. Do c tnh kh mnh Al tc dng vi cc axit HCl, HNO3, H2SO4 trong mi iu kin D. Cc vt dng bng nhm khng b oxi ha v khng tan trong nc do c lp mng oxit bo v Cu 11: Cht T l mt dn xut ca benzen c cng thc phn t C7H6Cl2 v khng c kh nng tc dng vi

dung dch NaOH long. S cht tha mn tnh cht ca T l:Trang 2/5 - M thi 132 A. 5 B. 6 C. 4 D. 7 Cu 12: Cho m gam hn hp X gm Fe2O3; CuO; MgO; FeO; Fe3O4 vo dung dch H2SO4 c nng thu c 3,36 lt kh SO2 (ktc). Mt khc nung 2m gam hn hp X vi kh CO d thu c cht rn Y v hn hp kh Z. Cho Z vo dung dch Ca(OH)2 d thu c 70 gam kt ta. Cho cht rn Y vo dung dch HNO3 c nng, d thu c V lt kh NO2 (l sn phm kh duy nht ktc). Gi tr ca V l: A. 44,8 lt B. 22,4 lt C. 17,92 lt D. 89,6 lt. Cu 13: Cng dng no sau y khng phi ca NaCl : A. Lm gia v B. iu ch Cl2, HCl, nc Javen C. Kh chua cho t D. Lm dch truyn trong y t Cu 14: R l nguyn t m nguyn t c phn lp electron ngoi cng l np2n+1 (n l s th t ca lp electron). Trong s cc nhn xt sau y v R: (I) Tng s ht mang in ca nguyn t R l 18. (II) S electron c thn trong nguyn t R l 3. (III) Oxit cao nht to ra t R l R2O7. (IV) NaR tc dng vi dung dch AgNO3 to kt ta. (V) Hp cht kh vi hidro ca R trong dung dch nc c tnh axit mnh S nhn xt ng l : A. 3. B. 1. C. 2. D. 4. Cu 15: Mt hn hp X gm Na, Al, Fe (vi t l Na : Al l 5 : 4) tc dng vi H2O d thu c V lt kh, dung dch Y v cht rn Z. Cho cht rn Z tc dng vi dung dch H2SO4 long d thu c 0,25V lt kh (cc kh o cng iu kin). Thnh phn % khi lng ca Fe trong hn hp X l: A. 14,4% B. 33,43% C. 34,8% D. 20,07% Cu 16: Cho cht X (C3H9O3N) tc dng vi dung dch NaOH un nng thu c cht kh lm xanh giy qu tm m t v mt mui v c. S cng thc cu to ca X tha mn l: A. 4 B. 1 C. 2 D. 3 Cu 17: Thy phn hon ton 9,46 gam mt este X trong lng d dung dch NaOH th thu c 10,34 gam mui. Mt khc 9,46 gam cht X c th lm mt mu va ht 88 gam dung dch Br2 20%. Bit rng trong phn t ca X c cha 2 lin kt . Tn gi ca X l: A. vinyl axetat. B. vinyl propionat. C. metyl aipat. D. metyl acrylat. Cu 18: Nh rt t t 250 ml dung dch X (cha Na2CO3 0,4M v KHCO3 0,6M) vo 300 ml dung dch H2SO4 0,35M v khuy u, thy thot ra V lt CO2 (ktc) v dung dch Y. Cho BaCl2 d vo Y c m gam kt ta. Gi tr ca V v m ln lt l: A. 3,36 lt v 32,345gam B. 2,464 lt v 52,045 gam C. 3,36 lt v 7,88 gam D. 2,464 lt v 24,465 gam Cu 19: Cho 2,07 gam cht hu c A (c cng thc phn t C7H6O3) tc dng vi dung dch NaOH va , sau lm kh, phn bay hi ch c nc, phn rn khan cn li cha hn hp 2 mui. Nung 2 mui ny trong oxi d, thu c 2,385 gam Na2CO3 v m gam hn hp kh v hi. S ng phn cu to ca A l A. 3. B. 5. C. 4. D. 2. Cu 20: C cc pht biu sau: (1) Tt c cc kim loi kim th u tan v hn trong nc (2) Cc kim loi kim c th y cc kim loi yu hn ra khi dung dch mui. (3) Na+ , Mg2+, Al3+ c cng cu hnh electron v u c tnh oxi ho yu. (4) Kim loi kim c dng nhiu trong tng hp hu c. (5) Cho dung dch NaOH d vo dung dch AlCl3, sau phn ng thu c dung dch trong sut. Nhng pht biu ng l: A. (3), (4), (5) B. (3), (5) C. (1), (2), (5) D. (1), (3), (4)

Cu 21: Mt hn hp X gm 0,07 mol axetilen; 0,05 mol vinylaxetilen; 0,1 mol H2 v mt t bt Ni trong bnh kn. Nung hn hp X thu c hn hp Y gm 7 hirocacbon c t khi hi i vi H2 l 19,25. Cho ton b hn hp Y i qua bnh ng dung dch AgNO3/NH3 d, thu c m gam kt ta vng nht v 1,568 lt hn hp kh Z (ktc) gm 5 hirocacbon thot ra khi bnh. lm no hon ton hn hp Z cn va ng 60 ml dung dch Br2 1M. Gi tr ca m l : A. 9,57. B. 16,8. C. 11,97. D. 12. Cu 22: Cho cc pht biu sau y: (a) Heptan tan tt trong dung dch H2SO4 long (b) Cu to ha hc cho bit th t, bn cht lin kt v v tr khng gian ca cc nguyn t trong phn tTrang 3/5 - M thi 132 (c) Phn ng C6H6 + Br2/Fe, to l phn th v xy ra s phn ct d li (d) Phn ng hu c thng xy ra chm; theo mt hng nht nh (e) Dng phng php kt tinh lm ng ct; ng phn t ma (f) Hp cht hu c no cng c c 3 tn: tn thng thng; tn gc- chc v tn thay th (g) Cacbocation v cacbanion u bn vng v c kh nng phn ng cao S pht biu ng l: A. 5 B. 4 C. 3 D. 2 Cu 23: Nhit phn hon ton 80g mt loi qung lmit c ln tp cht tr, ha tan cht rn vo nc d thy cn li 22,4 gam cht rn khng tan. Thnh phn % v khi lng ca tp cht trong loi qung nu trn l: A. 8% B. 25% C. 5,6% D. 12% Cu 24: Cho cc cht sau: Cu, FeS2, Na2SO3, Al4C3, K2S, S, NaCl, Cu2O, KBr, Fe3O4, Fe(OH)2, tc dng vi dung dch H2SO4 c, nng. S trng hp xy ra phn ng oxi ha - kh l: A. 7 B. 10 C. 8 D. 9 Cu 25: Cho cc cht: pentan, etyl clorua, etylamin, etyl axetat, axit crotonic, hirobromua, hiroflorua, anehit benzoic, axeton, ancol etylic, p-crezol, glixerol, phenol, nc. S cht to c lin kt hiro lin phn t l: A. 10. B. 8. C. 6. D. 13. Cu 26: Trong t nhin Cl tn ti ch yu 2 ng v 37Cl v 35Cl, c khi lng mol trung bnh l 35,45. Thnh phn phn trm v khi lng ca 35Cl trong clorua vi l (Cho O: 16, Ca: 40): A. 43,3%. B. 56,7%. C. 42,75%. D. 41,4%. Cu 27: Dy no sau y gm cc polime c cu trc mch phn nhnh? A. Cao su Buna-S, xenluloz, PS B. Amilopectin, glicogen C. Nha rezol, cao su lu ha D. T nilon-6,6; t lapsan, t olon Cu 28: Bit rng khi nhit tng ln 100C th tc tng ln 2 ln. Vy tc phn ng tng ln bao nhiu ln khi tng nhit t 200C n 1000C A. 64 ln B. 256 ln C. 14 ln D. 16 ln Cu 29: Thy phn hon ton 1 mol oligopeptit X mch h thu c 2 mol Gly, 1 mol Ala, 1 mol Val, 1 mol Tyr. Mt khc, nu thy phn khng hon ton th thu c sn phm c cha Gly-Val v Val-Gly. S cng thc cu to ph hp ca X l A. 4 B. 5. C. 2 D. 6 Cu 30: Amin X c cha vng benzen v c cng thc phn t l C8H11N. X c phn ng th H trong vng benzen vi dd Br2. Khi cho X tc dng vi HCl thu c mui Y c cng thc dng RNH3Cl. X c bao nhiu cng thc cu to? A. 7 B. 9 C. 8 D. 6 Cu 31: Dung dch cha mui X lm qu tm ha . Dung dch cha mui Y khng lm qu tm ha . Trn hai dung dch trn vi nhau thy c kt ta v kh bay ra. Vy cc dung dch X v Y ph hp l: A. NH4Cl v AgNO3 . B. NaHSO4 v Ba(HCO3 )2 .

C. NaHSO4 v NaHCO3 D. CuSO4 v BaCl 2 . Cu 32: T xeluloz ngi ta iu ch cao su Buna theo s : Xenluloz H2O/H X men Y xt, t 0 Z THCao su Buna iu ch c 1 tn cao su t nguyn liu ban u c 19% tp cht, hiu sut ca ton b qu trnh t 80% th khi lng nguyn liu cn l: A. 38,55 tn B. 16,20 tn C. 4,63 tn D. 9,04 tn Cu 33: Cho a gam hn hp A gm Fe2O3, Fe3O4 v Cu vo dung dch HCl d thy c 1 mol axit phn ng v cn li 0,256a gam cht rn khng tan. Mt khc, kh hon ton a gam hn hp A bng H2 d thu c 42g cht rn. Tnh % khi lng Cu trong hn hp A: A. 44,8% B. 50% C. 32% D. 25,6% Cu 34: Pht biu no di y l khng ng? A. C th phn bit da tht v da gi (lm t PVC) bng cch t chy v hp th sn phm chy vo dung dch AgNO3/HNO3. B. C th phn bit tripeptit (Ala-Gly-Val) v lng trng trng bng phn ng mu vi Cu(OH)2. C. C th phn bit benzen, anilin, glucoz bng dung dch nc brom D. C th phn bit du m ng thc vt v du m bi trn my bng dung dch kimTrang 4/5 - M thi 132 Cu 35: Ly 5,2 gam hn hp FeS2 v Cu2S tc dng hon ton vi dung dch HNO3 th thu c dung dch ch cha 2 mui nitrat v 12,208 lt hn hp NO2 v SO2 (ktc). Xc nh % v khi lng ca FeS2 trong hn hp ban u A. 93,23% B. 71,53% C. 69,23% D. 81,39% Cu 36: Cho cc phn ng sau : 1. H2O2 + KMnO4 + H2SO4 2. Ag + O3 3. KI + H2O + O3 4. Ca(d) + O3 5. Nhit phn Cu(NO3)2 6. in phn dung dch H2SO4 7. in phn dung dch CuCl 2 8. Nhit phn KClO3(xt MnO2) 9. C6H5NH2 +HNO2 S phn ng m sn phm to ra c O2 A. 6 B. 7 C. 5 D. 8 Cu 37: Cho 11,2 lt hn hp X gm axetilen v anehit axetic ( ktc) qua dung dch AgNO3/NH3 d. Sau khi phn ng hon ton thu c 112,8 gam kt ta. Dn lng hn hp X nh trn qua dung dch nc brom d, s gam brom tham gia phn ng l (gi s lng axetilen phn ng vi nc l khng ng k) A. 64 gam B. 112 gam C. 26,6 gam D. 90,6 gam Cu 38: Cho cc cp cht phn ng vi nhau: (1) Pb(NO3) 2 +H2S. (2) Zn(NO3)2 + Na2S. (3) H2S + SO2. (4) FeS2 + HCl. (5) AlCl3 + NH3 . (6) NaAlO2 +AlCl3 . (7) FeS + HCl. (8) Na2SiO3 + HCl. (9)NaHCO3 + Ba(OH)2d. (10)NaHSO4 + BaCl2 S lng cc phn ng to ra kt ta l: A. 6. B. 8. C. 4. D. 9. Cu 39: in phn dung dch X cha 0,03 mol Cu(NO3)2; 0,01 mol Fe2(SO4)3 v 0,05 mol NaCl trong thi gian 12 pht 52 giy vi cng dng in 5A. Hi khi lng dung dch sau in phn gim bao nhiu gam? A. 2,38 B. 14,22 C. 1,28 D. 2,06 Cu 40: Dn 0,5 mol hn hp kh gm H2 v CO c t khi so vi H2 l 4,5 qua ng ng 0,4 mol Fe2O3 v 0,2

mol CuO un nng. Sau phn ng hon ton cho cht rn trong ng vo dung dch HNO3 long, d thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l: A. 20,907 lt B. 3,730 lt C. 34,720 lt D. 7,467 lt Phn ring( 10 cu). Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II ) Phn I: Theo chng trnh Chun ( t cu {<41>} n cu {<50>}) Cu 41: C th phn bit HCOOCH3 v CH3COOCH3 bng: A. Na. B. AgNO3/NH3 C. CaCO3. D. NaOH Cu 42: Ba cht hu c A, B, D c khi lng phn t tng dn. Ly cng s mol mi cht cho tc dng ht vi dung dch AgNO3/NH3 u thu c Ag v 2 mui X, Y. Bit rng: - Lng Ag sinh ra t A gp hai ln lng Ag sinh ra t B hoc D - Mui X tc dng vi dung dch NaOH gii phng kh v c - Mui Y tc dng vi dung dch NaOH hoc H2SO4 u to kh v c. Ba cht A, B, D ln lt l: A. HCHO, HCOOH, HCOONH4 B. HCHO, CH3CHO, C2H5CHO C. HCHO, HCOOH, HCOOCH3 D. HCHO, CH3CHO, HCOOCH3 Cu 43: Cho hn hp gm Fe v Cu tc dng vi cc ha cht sau: (1) dung dch HCl; (2) kh oxi, t o ; (3) dung dch NaOH; (4) dung dch H2SO4 c, ngui; (5) dung dch FeCl3. S ha cht ch tc dng vi 1 trong 2 kim loi l: A. 3 B. 5 C. 2 D. 4 Cu 44: Cho phn ng sau: FeSO4 + KMnO4 + KHSO4 Fe2(SO4)3 + MnSO4 + K2SO4 + H2O Sau khi cn bng phng trnh ha hc trn, tng h s nguyn ti gin ca cc cht phn ng l A. 46. B. 36. C. 52. D. 16. Cu 45: Pht biu no sau y ng A. Bc c mu en khi tip xc vi khng kh hoc hi nc c mt kh lu hunh ioxit B. Crom c iu ch bng phng php in phn nng chy Cr2O3 c tch ra t qung cromit C. Trong khng kh, nhit thng Ag, Au, Sn, Ni, Zn, Cr u khng b oxi ha do c lp mng oxit bo v D. Ch c tc dng hp th tia gama ( ) nn c dng ngn cn tia phng x Cu 46: Thy phn 5,13 gam mantoz vi hiu sut a%, sau tin hnh phn ng trng bc (hiu sut 100%) i vi dung dch sau phn ng thu c 4,374 gam Ag. Gi tr ca a l:Trang 5/5 - M thi 132 A. 65,7% B. 30% C. 35% D. 67,5% Cu 47: C cc dung dch sau (dung mi nc) : CH3NH2 (1); anilin (2); amoniac (3); HOOC-CH(NH2)COOH (4); H2N-CH(COOH)-NH2(5), lysin (6), axit glutamic (7). Cc cht lm qu tm chuyn thnh mu xanh l: A. (1), (3), (5), (6) B. (1), (2), (3), (4), (5) C. (1), (2), (3) D. (1), (2), (3), (5) Cu 48: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, NaOH, Cu(OH)2( iu kin thng), NaHCO3 (trong iu kin thch hp). S phn ng xy ra l : A. 6 B. 5 C. 7 D. 4 Cu 49: Cho m gam hn hp A gm Fe, Au tc dng vi dung dch HCl c, d thu c kh H2 v hn hp X. Thm t t dung dch HNO3 vo hn hp X n khi kh NO (sn phm kh duy nht) ngng thot ra th dng li. Bit th tch kh NO thu c bng th tch kh H2 trn (o cng iu kin nhit p sut). Phn trm theo khi lng ca Fe trong hn hp A l: A. 22,13% B. 15,93% C. 19,93 % D. 29,89% Cu 50: chng minh s c mt ca ion NO3 trong dung dch gm Na+ , OH, NO3 ta nn dng:

A. Cu B. H2SO4 C. phenolphtalein D. Bt Al v qu m Phn II: Theo chng trnh nng cao Cu 51: Thy phn ht 1 lng pentapeptit X trong mi trng axit thu c 32,88 gam AlaGlyAlaGly; 10,85 gam AlaGlyAla; 16,24 gam AlaGlyGly; 26,28 gam AlaGly; 8,9 gam Alanin cn li l GlyGly v Glyxin. T l s mol GlyGly:Gly l 10:1. Tng khi lng GlyGly v Glyxin trong hn hp sn phm l: A. 27,9 gam B. 28,8 gam C. 29,7 gam D. 13,95 gam Cu 52: Trong s cc cht: clobenzen, toluen, nitrobenzen, anilin, phenol, axit benzoic, benzanehit, naphtalen, p-xilen, cumen, p-crezol,s cht tham gia phn ng th nhn thm d hn so vi benzen l A. 8. B. 9. C. 7. D. 6. Cu 53: C bao nhiu gam KClO3 tch ra khi dung dch khi lm lnh 350 gam dung dch KClO3 bo ha 80oC xung 20oC. Bit tan ca KClO3 80oC v 20oC ln lt l 40 gam/100 gam nc v 8 gam/100 gam nc. A. 170 gam. B. 115 gam. C. 95 gam. D. 80 gam. Cu 54: Cho m gam Al tan ht vo dung dch cha NaNO3 v KOH(un nng) thy thot ra hn hp kh X(gm 2 kh) c t khi i vi H2 bng 4,75. Lng kh X trn c th kh c ti a 30 gam CuO. Gi tr ca m l: A. 33,75 gam B. 12,15 gam C. 13,5 gam D. 14,85 gam Cu 55: Hp kim X gm Au, Ag, Cu. Cho 47,8 gam hp kim X tc dng vi nc cng toan d, sau phn ng thu c 5,376 lt kh NO (l sn phm kh duy nht, ktc); 8,61 gam kt ta Y v dung dch Z. Thnh phn phn trm v khi lng ca Au trong hp kim X l: A. 86,55% B. 82,43% C. 92,73% D. 61,82% Cu 56: Trong s cc cht: H2O, CH3COONa, Na2HPO3, NaH2PO3, Na2HPO4, NaHS, Al2(SO4)3, NaHSO4, CH3COONH4, Al(OH)3, ZnO, CrO, HOOC-COONa, HOOC-CH2NH3Cl. S cht lng tnh l: A. 7. B. 9. C. 8. D. 10. Cu 57: Cho s : Etilen O2/PdCl 2,CuCl2,to X1 HCN X2 H2O/H X3 H2O X4 X4 l 1 axit cacboxylic n chc. Vy CTCT ca X4 l: A. CH3COOH B. CH3CH2COOH C. CH3CH=CHCOOH D. CH2=CHCOOH Cu 58: Thy phn hon ton 7,02 gam hn hp X gm glucoz v saccaroz trong dung dch H2SO4 thu c dung dch Y. Trung ha ht lng axit trong dung dch Y ri cho phn ng ng hon ton vi lng d dung dch AgNO3 trong NH3 th thu c 8,64 gam Ag. Thnh phn % v khi lng ca saccaroz trong hn hp X l A. 97,14%. B. 24,35%. C. 12,17%. D. 48,71%. Cu 59: Cho dung dch Fe(NO3)2 ln lt tc dng vi cc dung dch: Na2S; H2S; H2SO4 (long); H2SO4 (c); CH3NH2; AlCl3; AgNO3; Na2CO3; Br2. S trng hp xy ra phn ng ha hc l: A. 7 B. 8 C. 6 D. 9 Cu 60: Trong s cc cht: phenylamoni clorua, natri phenolat, vinyl clorua, anlyl clorua, benzyl clorua, phenyl clorua, phenyl benzoat, t nilon-6, propyl clorua, ancol benzylic, alanin, tripeptit Gly-Gly-Val, mcrezol. S cht phn ng c vi dung dch NaOH long, un nng l: A. 10 B. 9 C. 7 D. 8-------------------------------------------------------- HT ----------

 THI TH TUYN SINH I HC NM 2013 Mn: HA HC; Khi B Thi gian lm bi: 90 pht, khng k thi gian pht H, tn th sinh: S bo danh:. Cho bit nguyn t khi (theo vC) ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; F = 19; Na = 23; Mg =12; Al = 27; S= 32; Cl = 35,5; K = 39; Ca = 40; Mn = 55; Fe = 56; Ni = 59; Cu = 64; Zn = 65; Br = 80; Ag = 108, Ba =137. I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Ha tan hon ton hn hp Mg v kim loi M (ha tr II), bng mt lng va dung dch HCl 15%, thu c dung dch X. Trong X, nng ca MgCl2 l 13,04%; nng ca MCl2 l 7,47%. Phn trm khi lng kim loi M c trong hn hp ban u l A. 48%. B. 52%. C. 42%. D. 58%. Cu 2: C cc pht biu sau: (1) Clo oxi ha c nc to thnh hn hp hai axit HCl v HClO. (2) Flo phn ng vi oxi to thnh kh OF2. (3) Bt nhm t bc chy khi tip xc vi kh clo. (4) Mg tc dng chm vi nc nhit thng to ra Mg(OH)2. (5) Khi un nng, axit nitric c th oxi ha c nhiu hp cht nh H2S, SO2, FeCl2. (6) Trong phng th nghim, axit photphoric c iu ch bng cch cho P2O5 tc dng vi nc. (7) Trong cng nghip, kh hiro sunfua c iu ch t hiro v lu hunh. (8) Cr tan trong HCl long nng nhng khng tan trong NaOH long nng. (9) Cr2O3 tan trong dung dch HCl nhng khng tan trong dung dch NaOH. S pht biu ng l A. 6. B. 7. C. 5. D. 8. Cu 3: Hn hp X gm cc mui NaHCO3, KHCO3 v MgCO3. Ha tan hon ton m gam X vo dung dch HCl d, thy thot ra 13,44 lt CO2 (ktc). Mt khc, nhit phn hon ton m gam X, thu c 34 gam hn hp cht rn Y; 17,6 gam CO2 v mt lng hi nc. Phn trm khi lng KHCO3 trong X l A. 29,07%. B. 27,17%. C. 14,53%. D. 54,35%. Cu 4: Este X mch h c cng thc phn t l C5H8O2, thy phn X trong dung dch NaOH thu c hai cht hu c Y v Z, bit Y lm mt mu dung dch brom. Vy: A. Y l mui, Z l anehit. B. Y l ru, Z l mui ca axit cha no. C. Y l mui, Z l ru cha no. D. Y l ru, Z l mui ca axit ankanoic. Cu 5: Hp th V lt CO2 vo 400 ml dung dch Ba(OH)2 0,6M, thu c a gam kt ta v dung dch X. Dn 0,7V lt kh CO2 vo dung dch X, thu c thm 0,3a gam kt ta. Cc th tch o ktc. Gi tr ca V l A. 3,360 lt. B. 3,584 lt. C. 3,136 lt. D. 3,840 lt. Cu 6: Cht hu c X c cng thc phn t C4H6O4 (ch cha mt loi nhm chc) tc dng vi NaOH theo phn ng : X + 2NaOH 2Y + Z Bit Y, Z l cc hp cht hu c. Pht biu khng ng l A. Y c th tham gia phn ng trng gng. B. Y c th l ancol. C. Z c th tham gia phn ng trng gng. M thi 381 Nguyn Thanh Tn Ninh Kiu- Cn Th M 381 trang 1/6 D. Z c th l ancol. Cu 7: Cho cc cht sau: Al2O3, Cr(OH)3, KHS, Zn, ZnO, Cr2O3, NH4Cl, (NH4)2CO3, NaH2PO4, NaHCO3, NaHSO4. S cht lng tnh l A. 8. B. 6. C. 7. D. 9. Cu 8: t chy hon ton 21,6 gam hn hp gm mt axit cacboxylic n chc, mch h v mt ancol n chc, mch h (mch cacbon ca 2 cht u c mt lin kt i), thu c 44 gam CO2 v 14,4 gam H2O. Thc hin este ha 21,6 gam hn hp trn thu c 9,45 gam este. Hiu sut phn ng este ha l A. 75%. B. 42,2%. C. 80%. D. 84,4%.

Cu 9: Cho lung kh CO qua m gam hn hp gm Fe3O4 v CuO (c t l s mol tng ng l 1:2), sau phn ng thu c 17,2 gam hn hp cht rn A. Ha tan ht A trong dung dch HNO3 c (d) thu c 7,84 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l A. 20,40. B. 22,00. C. 21,56. D. 19,60. Cu 10: Pht biu no sau y khng ng ? A. Nitrophotka thuc loi phn hn hp, cn Amophot thuc loi phn phc hp. B. dinh dng ca phn ln c nh gi bng hm lng % P2O5 tng ng vi lng photpho c trong thnh phn ca n. C. dinh dng ca phn kali c nh gi bng hm lng % K2O tng ng vi lng kali c trong thnh phn ca n. D. dinh dng ca phn m c nh gi bng hm lng % N2O5 tng ng vi lng nit c trong thnh phn ca n. Cu 11: Hn hp X gm 2 cht hu c c cng thc phn t l CH6O3N2 v C3H12O3N2. Cho 6,84 gam X phn ng hon ton vi lng d dung dch NaOH, thu c V lt hn hp Y (gm 3 kh) v dung dch Z. Nu cho dung dch HCl d vo dung dch Z th c 0,896 lt (ktc) kh thot ra. Nu hp th hon ton V lt hn hp kh Y vo dung dch HCl d th khi lng mui thu c l A. 7,87 gam. B. 7,59 gam. C. 6,75 gam. D. 7,03 gam. Cu 12: Thc hin cc th nghim sau : (1) Cho dung dch Fe(NO3)3 vo dung dch AgNO3. (2) Sc kh H2S vo dung dch FeCl3. (3) Sc kh H2S vo dung dch Cu(NO3)2. (4) un nng toluen vi dung dch thuc tm. (5) Cho dung dch H2SO4 vo dung dch Na2S2O3. (6) Cho dung dch NH3 d vo dung dch ZnSO4. (7) Cho dung dch Ba(OH)2 d vo dung dch Al2(SO4)3. (8) Cho dung dch AgNO3 vo dung dch H3PO4. (9) Dn kh H2S vo dung dch HNO3 long, un nng. (10) Sc kh CO2 vo dung dch Na2SiO3. S th nghim to ra kt ta l A. 8. B. 7. C. 6. D. 5. Cu 13: Tng s proton trong 2 ion XA3 2v XA4 2ln lt l 40 v 48. Pht biu ng l: A. X l cht kh iu kin thng. B. m in ca X ln hn m in ca A. C. X chu k 2, A chu k 3. D. Nng lng ion ha th nht ca A ln hn nng lng ion ha th nht ca X. Cu 14: Hn hp X gm cc axit : fomic, axetic, oleic v malonic (trong axit oleic v axit malonic c t l s mol tng ng l 4 : 3). Cho m gam X vo dung dch NaHCO3 (va ) thu c 1,6576 lt CO2 (ktc) v dung dch Y cha 6,068 gam mui. Mt khc t chy hon ton m gam X th tng khi lng sn phm chy thu c l 9,112 gam. Phn trm khi lng axit fomic c trong X l A. 62,16%. B. 50,41%. C. 25,41%. D. 74,59%. Cu 15: S cht hu c (cha C, H, O), mch h, c phn t khi 60g/mol l A. 5. B. 4. C. 3. D. 6.Nguyn Thanh Tn Ninh Kiu- Cn Th M 381 trang 1/6 Cu 16: Ha tan hon ton mt lng Ba vo 500ml dung dch Al2(SO4)3 0,1M . Sau phn ng thu c dung dch X , kt ta Y v kh Z. Khi lng dung dch X gim i so vi khi lng dung dch ban u l 19,59 gam. Sc kh CO2 (d) vo X th thy xut hin m gam kt ta. Gi tr ca m l A. 1,56. B. 3,94. C. 5,50. D. 7,80. Cu 17: Thc hin cc th nghim sau: (a) Ha tan Al2S3 vo nc. (b) Cho dung dch Na2CO3 vo dung dch AlCl3. (c) Cho dung dch Fe(NO3)2 vo dung dung dch HCl. (d) Cho dung dch HCl vo dung dch NaClO.

(e) Sc kh Cl2 vo dung dch Na2CO3. (f) Cho dung dch FeCl3 vo dung dch K2CO3. (g) Ha tan ure vo dung dch HCl. S th nghim c cht kh thot ra l A. 6. B. 5. C. 7. D. 4. Cu 18: Ha tan hon ton 3,12 gam mu qung sunfua ca st vo dung dch HNO3 c nng thu c dung dch X v 8,064 lt kh NO2 ( ktc). Cho lng d dung dch Ba(OH)2 vo X th thu c m gam kt ta. Gi tr ca m l A. 13,695. B. 8,595. C. 10,485. D. 16,903. Cu 19: Hn hp A cha x mol amin no, n chc, mch h X ; 0,03 mol ancol anlylic; 0,04 mol ankan Y; 0,05 mol ankin Z v 0,06 mol anken M . t chy hon ton A thu c 25,52 gam CO2 ; 224 ml N2 (ktc) v m gam H2O. Gi tr ca m l A. 10,80 gam. B. 10,44 gam. C. 10,62 gam. D. 11,70 gam. Cu 20: Dy cc kim loi no sau y u c kiu mng tinh th lp phng tm din ? A. Li, Na, K. B. Mg, Cu, Al. C. Ca, Sr, Ba. D. Al, Ca, Sr. Cu 21: Hn hp X gm CH3OH, HCOOCH3 v HCHO. Ha hi m gam X thu c th tch hi bng vi th tch ca 1,68 gam kh N2 (o trong cng iu kin nhit , p sut). t chy hon ton m gam X thu c 1,68 lt CO2 (ktc) v 1,71 gam H2O. Nu cho 3,435 gam X vo lng d dung dch AgNO3 trong NH3, th khi lng Ag to ra l A. 16,20 gam. B. 12,96 gam. C. 21,06 gam. D. 18,63 gam. Cu 22: Cc halogen c iu ch t nc bin l A. clo, iot. B. clo, brom C. clo, brom, iot. D. flo, clo, brom. Cu 23: Cho m gam mt ancol no, hai chc, mch thng X i qua bnh ng CuO (d) nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim a gam. Hn hp hi thu c c t khi i vi hiro l M. Biu thc lin h gia cc gi tr a, M v m l A. m = a(3M - 16)/16. B. m = a(M 8)/8. C. m = 3a(M 16)/16. D. m = 3a(M 8)/8. Cu 24: X c cng thc phn t C5H10 . T X c s sau : X ru A ( bc 2 ) Y ru B ( bc 3 ) . Vi A, B, Y l cc sn phm chnh. Cng thc phn t ca X l A. CH2-CH=CH-CH2-CH3. B. CH3-CH2-CH2-CH=CH2. C. CH3-C(CH3)=CH-CH3. D. CH3-CH(CH3)-CH=CH2. Cu 25: Cho a mol K2Cr2O7 phn ng hon ton vi dung dch HCl c, thy thot ra V1 lt kh Cl2. Cho b mol KMnO4 phn ng hon ton vi dung dch HCl c, thy thot ra V2 lt kh Cl2 (V1, V2 o cng iu kin) . Nu V1 = 2V2 th t l a : b l A. 1 : 2. B. 5 : 3. C. 5 : 6. D. 5 : 12. Cu 26: C cc pht biu sau: (a) T capron c iu ch bng phn ng trng hp hoc phn ng trng ngng. (b) Poli(metyl metacrylat) c iu ch t metyl metacrylat bng phn ng trng ngng. (c) un nng hn hp fomanehit v phenol ly d vi xc tc axit c nha rezol. (d) T bn tng hp c ngun gc t polime thin nhin.Nguyn Thanh Tn Ninh Kiu- Cn Th M 381 trang 1/6 (e) T olon thuc loi t vinylic c tng hp t vinyl xianua. Cc pht biu ng l A. (a), (c), (e). B. (b), (c), (d), (e). C. (a), (c), (d). D. (a), (d), (e). Cu 27: Nung 26,85 gam hn hp X gm cc kim loi Cu, Al, Zn v Fe trong oxi, sau mt thi gian thu c 31,65 gam rn Y. Ha tan hon ton Y vo dung dch H2SO4 (c nng, d) thu c dung dch Z (cha 89,25 gam mui) v V lt SO2 (duy nht, ktc). Gi tr ca V l A. 7,84. B. 6,72. C. 10,08. D. 8,96. Cu 28: Ha tan hon ton 23,2 gam hn hp cc oxit ca st vo 800 ml dung dch HCl (va ), thu c dung dch Z. Dung dch Z tc dng c vi ti a x mol KMnO4 trong dung dch H2SO4 (khng to kh SO2). Gi tr ca x l A. 0,18. B. 0,02. C. 0,20. D. 0,06. Cu 29: t chy hon ton mt lng ancol no, n chc, mch h X v hirocacbon Y ( u c s nguyn t C < 4), cn dng 5,92 gam O2 v thu c 4,84 gam CO2. S cp cht X v Y tha mn l A. 3. B. 6. C. 5. D. 4.

Cu 30: Hn hp X gm C3H7OH v ancol n chc Y. Nu cho m gam X phn ng ht vi Na d th thu c 5,6 lt H2 (ktc). Nu un nng m gam X vi H2SO4 c, n khi phn ng xy ra hon ton th thu c 3,36 lt anken Z (ktc) v 9,45 gam cc ete. Gi tr ca m l A. 20,20. B. 21,60. C. 20,40. D. 18,90. Cu 31: Pht biu no di y khng ng ? A. Vinylaxetilen phn ng vi hiro d (xc tc Pd , t ), khi phn ng hon ton thu c butan. B. Axetilen phn ng vi hiro d (xc tc Ni, t ), khi phn ng hon ton thu c etan. C. Vinylaxetilen phn ng vi hiro (xc tc Pd/PbCO3 , t ) , thu c buta1,3-ien D. Axetilen phn ng vi hiro d (xc tc Pd, t ) , khi phn ng hon ton thu c etilen. Cu 32: Cho hn hp X gm 0,002 mol FeS2 v 0,003 mol FeS phn ng hon ton vi lng d H2SO4 c nng, c kh A. Hp th ht kh A bng lng va dung dch KMnO4, c V lt dung dch khng mu c pH bng 2. Gi tr ca V l A. 1,92. B. 1,14. C. 2,28. D. 3,84. Cu 33: Chia mt dung dch nc brom c mu vng thnh hai phn. Dn kh A khng mu i qua phn mt th dung dch mt mu. Dn kh B khng mu i qua phn hai th dung dch c mu sm hn. Hai kh A v B ln lt l A. Cl2 v HI. B. SO2 v Cl2. C. SO2 v HI. D. H2S v SO2. Cu 34: t chy hon ton hn hp X (gm ivinyl, vinylaxetilen v hiro), thu c 4,48 lt CO2 (ktc) v 5,94 gam nc. Mt khc, nung nng hn hp X (xc tc Ni) mt thi gian, thu c hn hp kh Y c t khi so vi hiro l 8,5 (bit lng hiro tham gia phn ng hiro ha l 35%). T khi ca X so vi hiro l A. 7,65. B. 6,80. C. 6,12. D. 10,20. Cu 35: Hn hp X gm hirocacbon Y ( mch h, c s nguyn t C < 4) v hiro, t khi X so vi hiro bng 3. un X vi Ni, n khi phn ng hon ton thu c hn hp kh Z c t khi so vi hiro bng 4,5. Cng thc phn t ca Y l A. C2H4. B. C2H2. C. C3H4. D. C3H6. Cu 36: Nguyn t Cl c hai ng v bn l 35Cl v 37Cl trong 35Cl chim 75,77% s nguyn t. T l % v khi lng ca 37Cl trong phn t HClOn l 13,09%. Gi tr ca n l A. 1. B. 2. C. 3. D. 4. Cu 37: Khi thy phn hon ton 0,02 mol peptit A mch h ( c to bi cc amino axit ch c mt nhm -NH2 v mt nhm -COOH) bng dung dch NaOH (d 40% so vi lng phn ng) , c cn dung dch sau phn ng thu c hn hp cht rn c khi lng tng so vi khi lng A ban u l 8,60 gam. S lin kt peptit c trong A l A. 7. B. 8. C. 9. D. 10. Cu 38: iu ch kh clo trong phng th nghim, ngi ta oxi ha cht no sau y? A. NaCl. B. HCl. C. KClO3. D. MnO2.Nguyn Thanh Tn Ninh Kiu- Cn Th M 381 trang 1/6 Cu 39: Ha tan 10,65 gam hn hp gm oxit kim loi kim v oxit kim loi kim th bng lng d dung dch HCl, sau c cn dung dch ly mui khan em in phn nng chy hon ton, thu c 3,36 lt kh (ktc) anot v a gam hn hp kim loi catot. Gi tr ca a l A. 5,85. B. 8,25. C. 9,45. D. 7,75. Cu 40: Ch dng phenolphtalein khng phn bit c cc dung dch trong nhm no sau y ? A. NaOH, BaCl2, Na2SO4, H2SO4. B. K2SO4, HCl, KOH, Na2CO3. C. KOH, BaCl2, Na2CO3, K2SO4. D. KCl, NaNO3, H2SO4, Ba(OH)2. II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc phn B) A. Theo chng trnh chun (10 cu, t cu 41 n cu 50) Cu 41: Nung m gam hn hp A gm FeS v FeS2 trong bnh kn cha 1 mol khng kh (trong khng

kh c 20% O2 v 80% N2 theo th tch), n khi phn ng xy ra hon ton thu c cht rn B v hn hp kh C (84,74% N2, 10,6% SO2 v 4,66% O2 theo th tch). Gi tr ca m l A. 8,2. B. 7,4. C. 9,0. D. 9,8. Cu 42: Cng thc cu to ca valin l A. CH3-CH(CH3)-CH2-CH(NH2)-COOH. B. CH3-CH(CH3)-CH(NH2)-COOH. C. H2N-[CH2]4-CH(NH2)COOH. D. HOOC-[CH2]3CH(NH2)COOH. Cu 43: Hn hp hai este X v Y l hp cht thm c cng cng thc phn t l C8H8O2. Cho 4,08 gam hn hp trn phn ng va vi dung dch cha 1,6 gam NaOH, thu c dung dch Z (trong Z c 3 cht hu c). Khi lng mui c trong dung dch Z l A. 4,96 gam. B. 5,50 gam. C. 5,32 gam. D. 3,34 gam. Cu 44: S so snh no sau y l ng ? A. Tnh axit: HClO < HBrO ; tnh oxi ha : HClO > HBrO. B. Tnh axit: HClO > HBrO ; tnh oxi ha : HClO < HBrO. C. Tnh axit: HClO < HBrO ; tnh oxi ha : HClO < HBrO. D. Tnh axit: HClO > HBrO ; tnh oxi ha : HClO > HBrO. Cu 45: Thy phn hon ton 0,035 mol hn hp glucoz v mantoz trong mi trng axit, sau khi trung ha axit, cho dung dch phn ng vi lng d AgNO3 trong NH3, thu c 0,1 mol Ag. S mol ca glucoz trong hn hp ban u l A. 0,01 mol. B. 0,015 mol. C. 0,02 mol. D. 0,005 mol. Cu 46: S ng phn amino axit ng vi cng thc phn t C4H9O2N l A. 2. B. 3. C. 4. D. 5. Cu 47: Hp th hon ton 8,96 lt CO2 (ktc) vo dung dch NaOH thu c dung dch X (cha 38,44 gam mui). Nh t t n ht 300 ml dung dch HCl 1M vo dung dch X, thy c kh thot ra v thu c dung dch Y. Khi lng mui khan thu c khi un si c cn dung dch Y l A. 44,43 gam. B. 33,78 gam. C. 34,51 gam. D. 23,86 gam. Cu 48: C cc pht biu sau: (1) Glucoz tn ti dng mch h v mch vng. (2) Tng t nh glucoz, fructoz cng c phn ng trng bc v lm mt mu dung dch brom. (3) Khc vi mantoz, saccaroz khng c tnh kh. (4) Xenluloz v tinh bt u c phn t khi rt ln, nhng phn t khi ca xenluloz ln hn nhiu so vi tinh bt. (5) Xenluloz c tnh cht ca ancol a chc. S pht biu ng l A. 2. B. 3. C. 4. D. 5. Cu 49: S ng phn ng vi cng thc phn t C7H12 phn ng vi dung dch AgNO3 trong NH3 to kt ta l ? A. 8. B. 5. C. 6. D. 7. Cu 50: Pht biu no di y khng ng ? A. FeCl2 lm mt mu KMnO4 trong dung dch H2SO4 long. B. FeCl3 lm mt mu KMnO4 trong dung dch H2SO4 long.Nguyn Thanh Tn Ninh Kiu- Cn Th M 381 trang 1/6 C. FeSO4 lm mt mu KMnO4 trong dung dch H2SO4 long. D. Na2CO3 lm mt mu KMnO4 trong dung dch H2SO4 long. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho cc cht sau: axit picric; cumen; xiclohexanol; 1,2-ihiroxi-4-metylbenzen; o-crezol; 4-metylphenol; -naphtol; hiroquinon; catechol. S cht thuc loi phenol l A. 7. B. 4. C. 5. D. 6. Cu 52: Khi thy phn trong mi trng kim (un nng) cc ng phn c cng cng thc phn t C4H8Cl2. S ng phn cho sn phm c kh nng phn ng vi Cu(OH)2 l A. 3. B. 4. C. 5. D. 6. Cu 53: Khi un nng t t, H3PO4 b mt nc. Qu trnh mt nc ca H3PO4 c tm tt theo s sau : H3PO4 X Y Z. X, Y, Z ln lt l A. HPO3; H4P2O7; P2O5. B. H4P2O7; HPO3; P2O5. C. P2O5; HPO3; H4P2O7. D. P2O5; H4P2O7; HPO3 Cu 54: Mt bnh kn dung tch khng i cha hn hp cng th tch kh N2 v H2 (0oC, 100 atm).

Sau khi tin hnh phn ng tng hp amoniac, a bnh v 0oC, thy p sut mi trong bnh l 90 atm. Hiu sut tng hp amoniac l A. 30%. B. 20%. C. 25%. D. 10%. Cu 55: Cho m gam hn hp Mg, Cu v Al tc dng vi 190 ml dung dch HNO3 1M (va ), thu c dung dch X (cha 12,03 gam mui) v 0,56 lt hn hp kh NO v N2 (ktc), nng 0,74 gam. Cho t t mt lng va dung dch NaOH vo X, thy xut hin a gam kt ta. Gi tr ln nht ca a l A. 7,43. B. 5,77. C. 4,88. D. 5,37. Cu 56: Pht biu no di y khng ng ? A. Benzylamin tan v hn trong nc. B. Etylamin tc dng vi axit nitr nhit thng gii phng kh nit. C. lu trong khng kh, anilin chuyn sang mu vng. D. Amin bc mt tc dng vi CH3I thu c amin bc hai. Cu 57: Cho 1,152 gam hn hp Fe, Mg vo 0,1 lt dung dch AgNO3 0,5M. Phn ng hon ton, thu c 5,792 gam hn hp 2 kim loi. Phn trm khi lng Fe trong hn hp ban u l ? A. 58,33%. B. 68,33%. C. 41,67%. D. 31,67%. Cu 58: C cc pht biu sau (1) CH3Cl, CH3Br, CH3I l nhng cht kh iu kin thng. (2) CH3CH2CH2Cl b thy phn khi un si vi nc. (3) Benzyl bromua b thy phn khi un si vi nc. (4) un si clobenzen vi dung dch NaOH, sc kh CO2 (d) vo s thu c phenol. (5) Cho bt magie vo ietyl ete (C2H5OC2H5) khan, khuy mnh, thy bt magie tan hon ton. (6) un si vinyl clorua trong dung dch NaOH, thu c anehit axetic. S pht biu ng l A. 1. B. 2. C. 3. D. 4. Cu 59: Nung 16 gam hn hp X gm Fe(NO3)3, Zn(NO3)2 v Cu(NO3)2 ( trong X oxi chim 54% khi lng) trong bnh kn, n khi phn ng xy ra hon ton thu c m gam oxit. Gi tr ca m l A. 14,56. B. 6,28. C. 8,96. D. 12,56. Cu 60: Dy cc cht no sau y ch ton nhng hp cht hu c tp chc ? A. Glucoz, anilin, axit oxalic, fructoz. B. Axit lactic, axit malonic, lysin, axit aipic. C. Axit lactic, valin, glucoz, axit glutamic. D. Alanin, axit metacrylic, aixt lactic, sobitol. -------------HT------------Nguyn Thanh Tn Ninh Kiu- Cn Th

 32 ( thi c 04 trang)

THI TH VO I HC, CAO NG Mn thi: HA HC Thi gian lm bi: 90 pht (khng k thi gian giao )

PHN CHUNG: (44 cu t cu 1 n cu 44) 1. Phn ng sau y t xy ra : Zn + 2Cr3+ Zn2+ + 2Cr2+ . Phn ng ny cho thy : A. Zn c tnh kh mnh hn Cr2+ v Cr3+ c tnh oxi ha mnh hn Zn2+. B. Zn c tnh kh yu hn Cr2+ v Cr3+ c tnh oxi ha yu hn Zn2+. C. Zn c tnh oxi ha mnh hn Cr2+ v Cr3+ c tnh kh mnh hn Zn2+. D. Zn c tnh oxi ha yu hn Cr2+ v Cr3+ c tnh kh yu hn Zn2+. 2. Kim loi no di y khng phn ng vi nc iu kin thng ? A. Na. B. Ba. C. Ca. D. Al. 3. Ha tan hon ton 0,81 g kim loi M (ha tr n) vo dung dch H 2SO4 c, nng thu c 1,008 lt (ktc) kh SO2. Kim loi M l : A. Be. B. Al. C. Mn. D. Ag. 4. Cho a mol CO2 hp th hon ton vo dung dch cha 2a mol NaOH. Dung dch thu c c gi tr pH : A. bng 0. B. ln hn 7. C. nh hn 7. D. bng 7. 5. M t no di y khng ph hp cc nguyn t phn nhm A nhm II ? A. Cu hnh electron ha tr l ns2. B. Tinh th cc kim loi kim th u c cu trc lc phng. C. Gm cc nguyn t Be, Mg, Ca, Sr, Ba, Ra. D. Mc oxi ha c trng trong cc hp cht l +2. 6. Cho 0,2 mol Na chy ht trong O2 d thu c sn phm rn A. Ha tan ht A trong nc thu c 0,025 mol O2. Khi lng ca A bng : A. 3,9 gam. B. 6,2 gam. C. 7,0 gam. D. 7,8 gam. 7. Phn ng no sau y khng xy ra ? A. CaSO4 + Na2CO3 B. Ca(OH)2 + MgCl2 C. CaCO3 + Na2SO4 D. CaSO4 + BaCl2 8. Thm NaOH vo dung dch hn hp cha 0,01 mol HCl v 0,01 mol AlCl 3. S mol NaOH ti thiu dng kt ta thu c l ln nht v nh nht ln lt bng : A. 0,01 mol v 0,02 mol. B. 0,02 mol v 0,03 mol.C. 0,03 mol v 0,04 mol.D. 0,04 mol v 0,05 mol. 9. Phng trnh ho hc no sau y c vit khng ng ? A. 3Fe + 2O2 Fe3O4 B. 2Fe + 3Cl2 2FeCl3 C. 2Fe + 3I2 2FeI3 D. Fe + S FeS 10. Cho 0,02 mol bt st vo dung dch cha 0,07 mol AgNO 3. Khi phn ng hon ton th khi lng cht rn thu c bng : A. 1,12 gam. B. 4,32 gam. C. 6,48 gam. D. 7,56 gam. 11. Tnh khi lng kt ta S thu c khi thi 3,36 L (ktc) kh H2S qua dung dch cha 0,2 mol FeCl3. Bit phn ng xy ra hon ton. A. 3,2 gam B. 4,8 gam C. 6,4 gam D. 9,6 gam 12.Trong dy no di y, cc cht khng c xp theo trt t tng dn mnh tnh axit t tri sang phi ? A. HClO, HClO2, HClO3, HClO4 B. HI, HBr, HCl, HF C. H3PO4, H2SO4, HClO4 D. NH3, H2O, HF

13.

Sn phm phn ng nhit phn no di y l khng ng ? t A. NH4Cl NH3 + HCl B. NH4HCO3 NH3 + H2O + CO2 t C. NH4NO3 NH3 + HNO3 D. NH4NO2 N2 + 2H2O 14. Th tch ca m gam O2 gp 2,25 ln th tch hi ca m gam hirocacbon A cng iu kin. iclo ho A thu c 2 sn phm l ng phn. Tn ca A l : A. neopentan B. isobutan C. propan D. isopentan 15. Phn ng no di y khng to thnh etylbenzen ? AlCl B. benzen + CH3CH2Cl A. toluen + CH3CH3 AlCl H , Ni /t 2 C. stiren + H2 D. benzen + CH2=CH2 16. Cacbohirat (gluxit, saccarit) nhn chung l : A. hp cht a chc, c cng thc chung l Cn(H2O)m. B. hp cht tp chc, a s c cng thc chung l Cn(H2O)m. C. hp cht cha nhiu nhm hiroxyl v nhm cacboxyl. D. hp cht ch c ngun gc t thc vt. 17. Thuc th duy nht no di y c th phn bit bn dung dch mt nhn cha glucoz, glixerin (glixerol), fomanehit, etanol ? A. Cu(OH)2 trong kim nng B. Dung dch AgNO3/NH3 C. Na kim loi D. Nc brom 18. Hn hp m gam glucoz v fructoz tc dng vi lng d AgNO 3/NH3 to ra 4,32 gam Ag. Cng m gam hn hp ny tc dng va ht vi 0,80 gam Br 2 trong dung dch. S mol glucoz v fructoz trong hn hp ny ln lt bng : A. 0,005 mol v 0,015 mol. B. 0,01 mol v 0,01 mol. C.0,005 mol v 0,035 mol. D. 0,02 mol v 0,02 mol. 19. Cho lng d anilin phn ng hon ton vi dung dch long cha 0,05 mol H 2SO4, lng mui thu c bng : 1. 7,1 gam B. 14,2 gam C. 19,1 gam D. 28,4 gam 20. Cho 0,1 mol A (-amino axit dng H2NRCOOH) phn ng ht vi dung dch NaOH to 11,1 gam mui khan. A l : A. alanin B. glixin C. phenylalanin D. valin 21. Tn gi cho peptit l : H2NCH2CONHCHCONHCH2COOH
3 3

A. glixinalaninglyxin B. alanylglyxylalanin C. glixylalanylglyxin D. alanylglyxylglyxyl 22. Trong phn ng vi cc cht hoc cp cht di y, phn ng no gi nguyn mch polime ? 150 300 C A. nilon-6,6 + H2O B. cao su buna + HCl C. polistiren D. resol 23. Trng hp no di y c s tng ng gia loi vt liu polime v tnh c trng v cu to hoc tnh cht ca n ? A. Cht Si di, mnh v Cao su ; Tnh n hi do ; bn B. C. T C kh nng kt Keo dn ; Tnh do dnh D. 24.Pha 74,88 gam ru (ancol) etylic (d = 0,78 g/mL) vo 4 mL H 2O. ru ca dung dch thu c bng : A. 20o. B. 24o. C. 75o D. 96o.
o

CH3

25. GC6H12O6C2H5OHC4H6Cao

buna Khi lng g cn sn xut 1 tn cao su l : a. 24,8 tn. B. 22,3 tn C. 12,4 tn. D. 1,0 tn. 26. Cho dy chuyn ho iu ch sau : NaOH HCl / t ,p Br / Fe ToluenBCD. Cht D l : A. Benzyl clorua B. m-metylphenol C. o-cresol v p-cresol D. o-clotoluen v p-clotoluen 27. Cht no di y c gi ng tn bng c hai loi danh php ? cng thc tn gi A. CH3-CH=O anehit axetic (metanal)
2

hs35% hs60% hs80% su

B. C. D.

CH2=CH-CH=O CH3-CH(CH3)CH=O O=HC-CH=O

anehit acrylic (propanal) anehit isobutiric (metylpropanal) anehit malonic (etanial)

28. Cho 1,78 gam hn hp fomanehit v axetanehit phn ng hon ton vi lng d Cu(OH)2 trong NaOH nng, thu c 11,52 gam kt ta. Khi lng fomanehit trong hn hp bng : A. 0,45 gam. B. 0,60 gam. C. 0,88 gam. D. 0,90 gam. 29. X cha mt loi nhm nh chc, c cng thc C 8H14O4. Thy phn X trong NaOH thu c mt mui v hai ancol A, B. Phn t B c s nguyn t C nhiu gp i A ; un nng vi H2SO4 c, A cho mt olefin v B cho hai olefin ng phn. Cu to ca X l : A. C2H5OOCCOOCH(CH3)CH2CH3 B. C2H5OOC[CH2]3COOCH3 C. CH3CH(CH3)2OOCCOOCH2CH3 D. CH3CH2OOC[CH2]2COOCH2CH3 30. Phng trnh ho hc no di y c vit ng ?
as4 BrCH=CHCOOH KMnO B. CH COOH + HBr + Br COOH 2=CHCOOH 2 A. CH COOH + Cl CH COCl C. CH =CHCOOH H23 C CH+ HOCl COOH 3 2 2 1:1 H2O 31. S dng ha NO OH OH 2 H2SO4 cht no di y D. + HONO2 + H2O

phn bit du m ng thc vt v du m bi trn my ? A. nc nguyn cht B. benzen nguyn cht C. dung dch NaOH nng D. dung dch NaCl nng 32. Th tch kh (ktc) sinh ra khi nung nng hn hp mui cha 0,2 mol (NH 4)2SO4 v 0,2 mol NaNO2 l : A. 1,12 L. B. 2,24 L. C. 4,48 L. D. 8,96 L. + 33. Cho phng trnh in li ca nc : 2H2O H3O + OH . Theo thuyt proton ca Brsted th nc l mt : A. axit. B. baz. C. cht lng tnh. D. cht trung tnh. 34. A l hn hp kim loi Ba v Al. Ha tan m gam A vo lng d nc thy thot ra 8,96 L kh H2 (ktc). Cng ha tan m gam ny vo dung dch NaOH th thu c 12,32 L kh H 2 (ktc). Khi lng m bng : A. 13,70 gam. B. 21,80 gam. C. 58,85 gam. D. 57,50 gam. 35. un nng 0,3 mol bt Fe vi 0,2 mol bt S n phn ng hon ton c hn hp A. Ha tan ht A bng dung dch HCl d thu c kh D. T khi hi ca D so vi khng kh bng :

A. 0,8046. B. 0,7586. C. 0,4368. D. 1,1724. 36. Trong s cc kh Cl2, HCl, CH3NH2, O2 th c bao nhiu kh to khi trng khi tip xc vi kh NH3 ? A. 1 B. 2 C. 3 D. 4 37. tinh ch kh CO2 c ln tp cht l kh SO2, nn thi hn hp hai kh ny qua bnh cha : A. dung dch nc vi trong. B. dung dch axit sunfuric. C. dung dch nc brom. D. dung dch xt. 38. Khi t chy hon ton mt lng hp cht hu c X cn 0,8 gam O 2, ngi ta thu c 1,1g CO2; 0,45g H2O v khng c sn phm no khc. Hm lng % cc nguyn t trong phn t X bng : %mC %mH %mO %mC %mH %mO A. 3,33 43,34 53,33 B. 40,00 6,67 53,33 C. 3,33 1,88 94.79 D. 40,00 1,88 58,12 39. Trng hp no di y vit ng cng thc chung ca hirocacbon : hidrocacbon Cng thc hidrocacbon Cng thc A. anken B. Ankatrien CnH2n 2 CnH2n 4 C. ankin CnH2n D. aren CnH2n 6 40. Cho cc cht :
X. CH3 CH CH CH3 Y. CH3 CH3 Z. CH3 CH Br C CH3 T. CH3 Cl CH3

Cc cht c ng phn hnh hc l : A. X v Y. B. Y v Z. C. Z v T. D. T v X. 41. A l dung dch hn hp cha CH2(COOH)2, c nng mol aM v CH2=CHCOOH c nng mol bM. Trung ha 100 mL A cn 250 mL dung dch NaOH 1M. Mt khc, 100 mL dung dch A cng lm mt mu va ht dung dch Br 2, cha 24 gam Br2. Cc gi tr a, b ln lt bng; a b a b a b a b (M) (M) (M) (M) (M) (M) (M) (M) A. 0,5 1,5 B. 1,0 1,0 C. 1,0 1,5 D. 2,0 1,0 42. Cho dy chuyn ha iu ch axit axetic :
+ O2

Y
+ O 2, 180 oC, 70atm + O2, men

Pht biu no di y l ng ? X CH3COOH Z Mn 2+, t A. X l CH3COONa + H2SO4 B. Y l CH3CH2CH2CH3 T C. Z l CH3CH2OH D. T l CH3CHO 43. Khi cho cc cht : axit axetic, etilenglicol (etylen glicol), glixerin (glixerol) v glucoz ln lt tc dng vi Cu(OH)2, th cht ha tan Cu(OH)2 to dung dch c mu xanh nht l : A. axit axetic. B. etilenglicol (etylen glicol). C. glixerin (glixerol) D. glucoz. 44. Cho m gam Fe tc dng vi dung dch H 2SO4 long to 1,792 L kh (ktc). Nu cng cho m gam Fe tc dng vi dung dch HNO3 long th th tch kh N2O duy nht (ktc) sinh ra l : A. 0,03 mol. B. 0,06 mol. C. 0,18 mol. D. 0,30 mol .

PHN RING (th sinh ch c lm mt trong hai phn: phn I hoc phn II) Phn I: dnh cho th sinh chng trnh phn ban (6 cu- t cu 45 n cu 50) 45. Thi kh NH3 d qua 1 gam CrO 3 t nng n phn ng hon ton th thu c lng cht rn bng : A. 0,52 gam. B. 0,68 gam. C. 0,76 gam. D. 1,52 gam. 46. Cho Cu ln lt tc dng ht vi mi cht oxi ha di y c cng s mol. Trng hp no thu c s mol hp cht Cu(II) nh nht ? i. Cu + O2 B. Cu + Cl2 C. Cu + t H2SO4 c D. Cu + HNO3 c 47. Ha tan 12 gam mt mu qung cha Au vo hn hp cng thy c d. Khi phn ng hon ton thy c 0,0015 mol HCl tham gia phn ng. Phn trm khi lng Au trong mu qung trn bng : A. 0,41%. B. 0,82% . C. 1,23%. D. 1,64%. 48. Xt cc phn ng : t0 SO2 (X) ZnCO3.ZnS + 3/2O2 2ZnO + CO2 + (Y) ZnO + CO Zn + CO2 0 tp (Z) ZnO + H2SO4 ZnSO4 + H2 (T) ZnSO4 + H2OZn + 1/2O2 + H2SO4 Qu trnh iu ch Zn t qung ZnCO3.ZnS bng phng php in luyn khng dng phn ng : A. X. B. Y. C. Z. D. T. 49. phn bit ba dung dch mt nhn cha H 2NCH2COOH, CH3[CH2]3NH2 v CH3CH2COOH, bng mt thuc th duy nht th nn dng : A. Na. B. qu tm. C. NaHCO3. D. NaNO2/HCl. 50. Ch dng qu tm (v cc cc mu th nhn bit c) th nhn ra c bao nhiu dung dch, trong s 4 dung dch mt nhn : BaCl2, NaOH, AlNH4(SO4)2, KHSO4 ? A. 1. B. 2. C. 3. D. 4. Phn II: dnh cho th sinh chng trnh khng phn ban (6 cu-t cu 51 n cu 56) 45. Nung n hon ton 0,05 mol FeCO3 trong bnh kn cha 0,01 mol O2 thu c cht rn A. ha tan ht A bng dung dch HNO3 (c nng), th s mol HNO3 ti thiu cn dng l : A. 0,14 mol. B. 0,15 mol. C. 0,16 mol. D. 0,18 mol. 46. So snh bn knh nguyn t (hay ion) no di y l khng ng ? rAl rr r > > rCl A. B. C. Se P> Cl O K Al D. 47. Ln lt nhng bn thanh kim loi Zn, Fe, Ni v Ag vo dung dch Cu(NO 3)2. Sau mt thi gian ly cc thanh kim loi ra. Nhn xt no di y KHNG ng ? A. Khi lng thanh Zn gim i. B. Khi lng thanh Fe tng ln. C. Khi lng thanh Ni tng ln. D. Khi lng thanh Ag gim i. 48. Hirocacbon no di y khng th lm nht mu dung dch brom ? A. Etilen B. Xiclopropan C. Xiclohexan D. Stiren 49. Mt hirocacbon thm X c cng thc C9H12. Oxi ha mnh lit X to axit c cng thc C8H6O4. un nng vi brom c mt bt st, X cho hai sn phm monobrom. X l : A. 1,2,3-trimetylbenzen. B. p-etylmetylbenzen C. m-etylmetylbenzen D. isopropylbenzen 50. Thi 0,4 mol kh etilen qua dung dch cha 0,2 mol KMnO 4 trong mi trng trung tnh, khi lng etilenglicol thu c bng : A. 6,2 gam B. 12,4 gam C. 18,6 gam D. 24,8 gam
+ 3 +