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□ Describe the idea that some reversible reactions can reach dynamic
equilibrium and predict the effect of changing the conditions.
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Prepared by Kartini Ishak
Reversible Reactions
EXPERIMENT 1
To prove that the reaction of ammonia gas with hydrogen chloride is a
reversible reaction.
Procedure
Part 1: All the experimental procedure had to be done in the fume
cupboard.
1) Pour 2 cm3 of concentrated hydrochloric acid into a crucible.
2) Using a test tube holder to hold the cotton wool plug, immerse it
into the crucible containing the concentrated acid.
3) Put the cotton wool plug near the mouth of the bottle of solution
containing concentrated ammonia.
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⇒ What is the product formed in the reaction?
_______________________________________________________
Procedure
Part 2:
1) Place some solid ammonium chloride in a test tube. Push some glass
wool into the tube. Clamp the tube vertically as shown in the set-up
above.
2) Place pieces of damp red and blue litmus papers at the mouth of
the test tube.
3) Heat the ammonium chloride strongly so that it disappears.
4) Record the changes that take place in the pieces of litmus paper.
____________________________________________________
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Prepared by Kartini Ishak
Since the reaction can go either direction, we say that it is a
_________________. A double arrow, ______, is used to indicate a
reversible reaction.
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Another example of reversible reaction;
I2 in aqueous potassium iodide I2 in trichloroethane
EXPERIMENT 2
To study the reversible reaction of potassium chromate (VI)
Procedure
1) Place 2 cm3 of potassium chromate (VI) solution in a boiling tube.
Record the colour of the solution. (Colour: _______________)
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Prepared by Kartini Ishak
2) Add in dilute sulphuric acid slowly. Stop adding when the solution
changes colour. Record the colour of the solution.(Colour:
______________)
3) Add aqueous sodium hydroxide slowly to the resulting solution
obtained in Step 2. Stop adding when the solution changes colour.
Record the colour of the solution. (Colour: _______________)
Questions:
1. What is the colour of potassium chromate (VI) in the presence of
a) an acid - ____________________
b) an alkali - ___________________
2. The chromate ion, CrO42- (aq) is yellow in colour. The dichromate ion
Cr2O72- is orange in colour. Write the ionic equations for the reversible
reaction occurring in this experiment.
1) CONCENTRATION
If the concentration of a reactant is increases the forward reaction
will be increased. For example
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Prepared by Kartini Ishak
If the concentration of the Fe3+ is increases by adding a more
concentrated solution, the speed of the forward reaction will increase.
This will make more products.
d) add AgNO3 (aq) [ Ag+(aq) will form a precipitate with CrO42- (aq)]
_______________________
2) TEMPERATURE
All the reactions (both forward and reverse) will increase in speed
with an increase in temperature.
Example 1:
a) forward reaction?___________________
b) reverse reaction?___________________
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Prepared by Kartini Ishak
If the temperature is increased what happens to the rate of
Example 2:
a) forward reaction?___________________
b) reverse reaction?___________________
3) PRESSURE
2NO2(g) N2O4(g)
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If the pressure is decreases what happens to the speed of both
reactions? _______________
Example 1:
Why? __________________________________________________
Example 2:
_________________
Why? __________________________________________________
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Prepared by Kartini Ishak