KIM TRA PHN HP CHT C NHM CHC

BI S 3. Thi gian 90 pht.

Cu 1: un nng hn hp gm 1 mol axit X c cng thc phn t C4H6O4 vi 1 mol CH3OH (xc tc H2SO4 c) thu c 2
este E v F (MF > ME). Bit rng mE = 1,81mF v ch c 72% lng ru b chuyn ho thnh este. S gam E v F tng ng l
A. 47,52 v 26,28.
B. 26,28 v 47,52.
C. 45,72 v 28,26.
D. 28,26 v 45,72.
Cau 2: Trong phn ng este ho gia ru v axit hu c th cn bng s dch chuyn theo chiu to ra este khi
A. gim nng ru hay axit.
B. cho ru d hay axit d.
C. tng nng cht xc tc.
D. chng ct tch este ra.
Cu 3: Hn hp M gm ru no X v axit n chc Y mch h c cng s nguyn t cacbon. t chy 0,4 mol M cn 30,24 lt
O2 (ktc) thu c 52,8 gam CO2 v 19,8 gam H2O. Nu un nng 0,4 mol M vi H2SO4 c l xc tc, thu c m gam hn
hp 2 este (h = 100%).Cng thc phn t ca X v Y tng ng l
A. C3H8O3 v C3H4O2.
B. C3H8O2 v C3H4O2.
C. C2H6O2 v C2H4O2.
D. C3H8O2 v C3H6O2.
Cu 4: Chia hn hp gm mt axit n chc vi mt ru n chc thnh 3 phn bng nhau. Phn 1 cho tc dng ht vi Na
thu c 3,36 lt kh H2(ktc). Phn 2 t chy hon ton thu c 39,6 gam CO2. Phn 3 un nng vi H2SO4 c thu c
10,2 gam este E (h=100%). t chy ht lng este thu c 22 gam CO2 v 9 gam H2O.Nu bit s mol axit ln hn s
mol ru th cng thc ca axit l
A. HCOOH.
B. CH3COOH.
C. C2H5COOH.
D. C3H7COOH.
Cu 5: Thc hin phn ng este ha gia mt axit no X v mt ru no Y c este 0,1 mol E mch h. Cho 0,1 mol E phn
ng hon ton vi dung dch NaOH to ra16,4g mui. t chy hon ton 0,1 mol ru Y cn 0,25 mol O2.Cng thc phn
t ca Y v E ln lt l
A. C2H6O v C6H8O4.
B. C2H6O2 v C6H10O4.
C. C3H8O v C6H10O2.
D. C3H8O3 v C5H8O2.
Cu 6: Cho 24,0 gam axit axetic tc dng vi 18,4 gam glixerin (H2SO4 c v un nng) thu c 21,8 gam glixerin triaxetat.
Hiu sut ca phn ng l
A. 50%.
B. 75%.
C. 25%.
D. 80%.
Cu 7: t chy hon ton hn hp X gm 2 ru n chc, ng ng k tip thu c 14,08 gam CO2 v 9,36 gam H2O.
Nu cho X tc dng ht vi axit axetic th s gam este thu c l
A. 18,24.
B. 22,40.
C. 16,48.
D. 14,28.
Cu 8: t chy hon ton 19,68 gam hn hp Y gm 2 axit l ng ng k tip thu c 31,68 gam CO2 v 12,96 gam H2O.
Nu cho Y tc dng vi ru etylic, vi hiu sut phn ng ca mi axit l 80% th s gam este thu c l
A. 25,824.
B. 22,464.
C. 28,080.
D. 32,280.
Cu 9: Chia 26,96 gam hn hp X gm 3 axit n chc thnh 2 phn bng nhau. Phn 1 cho tc dng vi NaHCO 3 d thu
c 4,48 lt kh CO2 (ktc). Phn 2 cho tc dng ht vi etylen glicol ch thu c gam 3 este tp chc v nc. Gi tr ca m
l
A. 44,56.
B. 35,76.
C. 71,52.
D. 22,28.
Cu 10: Cho 5,76g axit hu c n chc X tc dng ht vi CaCO3 d, thu c 7,28g mui.Nu cho X tc dng vi 4,6 ru
etylic vi hiu sut 80% th s gam este thu c l
A. 6,40.
B. 8,00.
C. 7,28.
D. 5,76.
Cu 11: t chy hon ton m gam hn hp hai ancol n chc X v Y thuc cng mt dy ng ng, ngi ta thu c 70,4
gam CO2 v 37,8 gam H2O. Nu cho m gam hn hp trn tc dng vi 24,0 gam axit axetic (h = 50%) th s gam este thu c
l
A. 20,96.
B. 26,20.
C. 41,92.
D. 52,40.
Cu 12: t chy hon ton mt ru a chc, thu c H2O v CO2 vi t l mol tng ng l 3:2. Nu cho ru tc dng
vi hn hp gm axit axetic v axit fomic th s lng este c th to thnh l
A. 2.
B. 3.
C. 4.
D. 5.
Cu 13: un nng 25,8g hn hp X gm 2 ru no, n chc, bc 1, l ng ng k tip trong H2SO4 c 140oC thu c
21,3g hn hp Y gm 3 ete (h = 100%). Nu cho 25,8g X tc dng ht vi axit fomic th thu c m gam este.Tn gi ca 2
ru trong X l
A. metanol v etanol.
B. etanol v propan-2-ol.
C. etanol v propan-1-ol.
D. propan-1-ol v butan-1-ol.
Cu 14: Cho 37,6 gam hn hp X gm C2H5OH v mt ru ng ng Y tc dng vi Na d thu c 11,2 lt kh H2 (ktc).
Nu cho Y bng lng Y c trong X tc dng ht vi axit axetic th thu c s gam este l
A. 44,4.
B. 22,2.
C. 35,2.
D. 17,6.
Cu 15: t chy hon ton hn hp 2 ru l ng ng k tip thu c 8,8 gam CO2 v 6,3 gam H2O. Cng lng hn
hp trn, nu cho tc dng ht vi axit oxalic th thu c m gam hn hp 3 este khng cha nhm chc khc. Gi tr ca m l

A. 19,10.
B. 9,55.
C. 12,10.
D. 6,05.
Cu 16: Chia 0,9 mol hn hp 2 axit no thnh 3 phn bng nhau. Phn 1 t chy hon ton thu c 11,2 lt kh CO 2 (ktc).
Phn 2 tc dng va vi 500 ml dung dch NaOH 1M. Phn 3 tc dng va vi ru etylic (xc tc H2SO4 c) thu c
m gam hn hp 2 este khng cha nhm chc khc.Gi tr ca m l
A. 36,6.
B. 22,2.
C. 22,4.
D. 36,8.
Cu 17: Chia hn hp X gm 2 axit hu c no n chc, mch h, l ng ng k tip thnh 3 phn bng nhau. Phn 1 tc
dng vi dung dch NaHCO3 d thu c 2,24 lt kh CO2 (ktc). Phn 2 t chy hon ton X thu c 6,272 lt CO2 (ktc).
Phn 3 tc dng va vi etylen glycol thu c m gam hn hp 3 este khng cha nhm chc khc. Gi tr ca m l
A. 9,82.
B. 8,47.
C. 8,42.
D. 9,32.
Cu 18: X, Y l 2 axit no, n chc, mch h, k tip nhau trong dy ng ng. Cho hn hp A gm 5,52 gam X v 10,80
gam Y tc dng ht vi Na thu c 3,36 lt kh H2 (ktc). Nu cho A tc dng ht vi ru etylic th thu c m gam este. Gi
tr ca m l
A. 24,72.
B. 22,74.
C. 27,42.
D. 22,47.
Cu 19: S lng este thu c khi cho etylen glycol tc dng vi hn hp gm CH3COOH, HCOOH v CH2=CH-COOH l
A. 6.
B. 9.
C. 12.
D. 18.
Cu 20 (A-07): Hn hp X gm HCOOH v CH3COOH (t l mol 1:1). Ly 5,3 gam X tc dng vi 5,75 gam C2H5OH (c xc tc
H2SO4 c), thu c m gam hn hp este (hiu sut cc phn ng este ho u bng 80%). Gi tr ca m l
A. 10,12.
B. 16,20.
C. 8,10.
D. 6,48.
Cu 21 (B-07): Cho glixerol (glixerin) phn ng vi hn hp axit bo C17H35COOH v C15H31COOH, s loi trieste ti a c
to ra l
A. 6.
B. 3.
C. 4.
D. 5.
Cu 22: t chy hon ton 0,1 mol hn hp X gm 2 axit cacboxylic ng ng k tip thu c 6,16 gam CO2 v 2,52 gam
H2O. Cng thc ca 2 axit l
A. CH3COOH v C2H5COOH.
B. C2H3COOH v C3H5COOH. C. HCOOH v CH3COOH.
D. C2H5COOH v C3H7COOH.
Cu 23: Chia 0,6 mol hn hp 2 axit no thnh 2 phn bng nhau. Phn 1 t chy hon ton thu c 11,2 lt kh CO2 (ktc).
Phn 2 tc dng va vi 500 ml dung dch NaOH 1M. Cng thc cu to ca 2 axit ban u l
A. CH3-COOH v CH2=CH-COOH.
B. H-COOH v HOOC-COOH.
C. CH3-COOH v HOOC-COOH.
D. H-COOH v CH3-CH2-COOH.
Cu 24: S lng este thu c khi cho etylenglycol tc dng vi hn hp gm 4 axit cacboxylic n chc l
A. 8.
B. 10.
C. 14.
D. 12.
Cu 25: Cng thc chung axit cacboxylic no, a chc, mch h l
A. CnH2n-m(COOH)m.
B. CnH2n+2-m(COOH)m.
C. CnH2n+1(COOH)m
D. CnH2n-1(COOH)m
Cu 26: C4H8O2 c s ng phn axit l
A. 1.
B. 2.
C. 3.
D. 4.
Cu 27 Trn 20 gam dung dch axit n chc X 23% vi 50 gam dung dch axit n chc Y 20,64% thu c dung dch D.
trung ho D cn 200 ml dung dch NaOH 1,1M. Bit rng D tham gia phn ng trng gng. Cng thc ca X v Y tng ng
l
A. HCOOH v C2H3COOH.
B. C3H7COOH v HCOOH. C. C3H5COOH v HCOOH.
D. HCOOH v C3H5COOH.
Cu 28: Axit icacboxylic mch thng c phn trm khi lng ca cc nguyn t tng ng l % C = 45,46%, %H = 6,06%,
%O = 48,49%. Cng thc cu to ca axit l
A. HOOC-COOH.
B. HOOC-CH2-COOH. C. HOOC-CH2-CH2-COOH.
D. HOOC-CH2-CH2-CH2-COOH.
Cu 29: Axit X mch thng, c cng thc thc nghim (C3H5O2)n. Cng thc cu to ca X l
A. C2H4COOH.
B. HOOC-(CH2)4-COOH.
C. CH3CH2CH(COOH)CH2COOH.
D. HOOCCH2CH(CH3)CH2COOH
Cu 30: trung ho 8,8 gam mt axit cacboxylic mch thng thuc dy ng ng ca axit fomic cn 100ml dung dch NaOH
1M. Cng thc cu to ca axit l
A. CH3COOH.
B. CH3(CH2)2COOH. C. CH3(CH2)3COOH. D. CH3CH2COOH.
Cu 31: X, Y l 2 axit no, n chc, mch h, k tip nhau trong dy ng ng. Cho hn hp A gm 4,6 gam X v 6,0 gam Y
tc dng ht vi Na thu c 2,24 lt kh H2 (ktc). Cng thc phn t ca X v Y ln lt l
A. CH2O2 v C2H4O2. B. C2H4O2 v C3H6O2.
C. C3H6O2 v C4H8O2.
D. C4H8O2 v C5H10O2.
Cu 32: t chy hon ton 0,1 mol hn hp 2 axit cacboxylic l ng ng k tip thu c 3,36 lt CO 2 (ktc) v 2,7 gam
H2O. Cng thc phn t ca chng l
A. C2H4O2 v C3H6O2.
B. C3H6O2 v C4H8O2.
C. CH2O2 v C2H4O2.
D. C3H4O2 v C4H6O2.
Cu 33: t chy hon ton 0,1 mol hn hp 2 axit cacboxylic l ng ng k tip thu c 3,36 lt CO 2 (ktc) v 2,7 gam
H2O. S mol ca mi axit ln lt l

A. 0,05 v 0,05.
B. 0,045 v 0,055.
C. 0,04 v 0,06.
D. 0,06 v 0,04.
Cu 34: Cho 14,8 gam hn hp 2 axit hu c no, n chc tc dng vi lng va Na2CO3 to thnh 2,24 lt kh CO2
(ktc). Khi lng mi mui thu c l
A. 23,2.
B. 21,2.
C. 20,2.
D. 19,2.
Cu 35: Mt hn hp hai axit hu c c phn ng trng gng. Axit c khi lng phn t ln khi tc dng vi Cl 2 (as) thu
c ba sn phm monoclo. Cng thc ca hai axit l
A. CH3COOH v HCOOH.
B. CH3COOH v HOOC-COOH.
C. HCOOH v CH3(CH2)2COOH.
D. HCOOH v (CH3)2CHCOOH.
Cu 36: Trung ho 9 gam mt axit n chc bng lng va NaOH thu c 12,3 gam mui. Cng thc cu to ca axit l
A. HCOOH.
B. CH2=CHCOOH. C. CH3COOH.
D. CH3CH2COOH.
Cu 37: Cng thc thc nghim ca mt axit no, a chc l (C3H4O3)n. Cng thc phn t ca axit l
A. C6H8O6.
B. C3H4O3.
C. C9H12O8.
D. C3H4O4.
Cu 38: t chy hon ton mt axit hu c ta thu c: nCO2 = nH2O. Axit l
A. axit hu c c hai chc, cha no.
B. axit vng no.
C. axit n chc, no.
D. axit n chc, cha no.
Cu 39: Trong cc ng phn axit C5H10O2. S lng ng phn khi tc dng vi Cl2 (as) ch cho mt sn phm th monoclo
duy nht (theo t l 1:1) l
A. 4.
B. 2.
C. 3.
D. 1.
Cu 40: t chy hon ton 1,44 gam mui ca axit hu c thm n chc ta thu c 0,53 gam Na 2CO3 v 1,456 lt kh CO2
(ktc) v 0,45 gam H2O. CTCT ca mui axit thm l
A. C6H5CH2COONa.
B. C6H5COONa.
C. C6H5CH2CH2COONa.
D. C6H5CH(CH3)COONa.
Cu 41: X l axit hu c tho mn iu kin:
m gam X + NaHCO3 x mol CO2 v m gam X + O2 x mol CO2. Axit X l
A. CH3COOH.
B. HOOC-COOH.
C. CH3C6H3(COOH)2. D.CH3CH2COOH.
Cu 42: Cho 5,76g axit hu c n chc X tc dng ht vi CaCO3 d, thu c 7,28g mui. Tn gi ca X l
A. axit fomic
B. axit axetic
C. axit butyric.
D. axit acrylic.
Cu 43: trung ho a gam hn hp X gm 2 axit no, n chc, mch thng l ng ng k tip cn 100 ml dung dch NaOH
0,3M. Mt khc, t chy hon ton a gam X thu c b gam nc v (b+3,64) gam CO2. Cng thc phn t ca 2 axit l
A. CH2O2 v C2H4O2.
B. C2H4O2 v C3H6O2.
C. C3H6O2 v C4H8O2.
D. C4H8O2 v C5H10O2.
Cu 44: Thc hin phn ng este ho m gam CH3COOH bng mt lng va C2H5OH (xc tc H2SO4 c, un nng) thu
c 1,76 gam este (h=100%). Gi tr ca m l
A. 2,1.
B. 1,1.
C. 1,2.
D. 1,4.
Cu 45: Hn hp X gm 1 axit no n chc v 2 axit khng no n chc c 1 lin kt i, l ng ng k tip nhau. Cho X tc
dng va vi 100ml dung dch NaOH 2M, thu c 17,04 gam hn hp mui. Mt khc, t chy hon ton X thu c tng
khi lng CO2 v H2O l 26,72 gam. Cng thc phn t ca 3 axit trong X l
A. CH2O2, C3H4O2 v C4H6O2.
B. C2H4O2, C3H4O2 v C4H6O2.
C. CH2O2, C5H8O2 v C4H6O2.
D. C2H4O2, C5H8O2 v C4H6O2
Cu 46: Cho hn hp X gm 2 axit hu c n chc, mch h, l ng ng k tip tc dng va vi dung dch NaHCO3
thu c 1,12 lt kh CO2 (ktc). Nu t chy hon ton X th thu c 3,136 lt CO2 (ktc). Cng thc cu to ca 2 axit trong
X l
A. HCOOH v CH3COOH.
B. CH3COOH v C2H5COOH.
C. C2H3COOH v C3H5COOH.
D. C2H5COOH v C3H7COOH.
Cu 47 (A-07): t chy hon ton a mol mt axit hu c Y c 2a mol CO2. Mt khc, trung ho a mol Y cn va 2a
mol NaOH. Cng thc cu to thu gn ca Y l
A. CH3COOH.
B. HOOC-COOH. C. HOOC-CH2-CH2-COOH.
D. C2H5COOH.
Cu 48 (B-07): trung ho 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng
thc ca Y l
A. CH3COOH.
B. C2H5COOH.
C. C3H7COOH.
D. HCOOH.
Cu 49 (B-07): t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 (ktc), thu c 0,3 mol CO2 v
0,2 mol H2O. Gi tr ca V l
A. 8,96.
B. 11,2.
C. 4,48.
D. 6,72.
Cu 50: Hn hp X gm 1 axit no, mch thng, 2 ln axit (A) v 1 axit khng no c mt ni i trong gc hirocacbon, mch h,
n chc (B), s nguyn t cacbon trong A gp i s nguyn t cacbon trong B. t chy hon ton 5,08g X thu c 4,704
lt CO2(ktc).Trung ho 5,08g X cn 350ml dung dch NaOH 0,2M.Cng thc phn t ca A v B tng ng l
A. C8H14O4 v C4H6O2.
B. C6H12O4 v C3H4O2.
C. C6H10O4 v C3H4O2.
D. C4H6O4 v C2H4O2.