BI TP HU C HA 11

I. HIROCACBON NO Cu 1. Vit cc ng phn cu to ca ankan ng vi cng thc phn t C5H12 ? Gi tn cc ng phn theo danh php thay th. Cu 2. Vit phng trnh ha hc ca phn ng xy ra khi: a) Propan tc dng vi clo (theo t l 1:1) khi chiu sng. b) Tch mt phn t hiro t phn t propan. c) t chy hexan. Cu 3. Mt ankan X c t khi hi so vi hiro bng 36. a) Xc nh cng thc phn t ca X. b) Vit cng thc cu to v gi tn tt c cc ankan ng vi cng thc phn t tm c. Cu 4. Cht A l mt ankan th kh. t chy hon ton 1,2 lt A cn dng va ht 6,0 lt oxi ly cng iu kin. a) Xc nh cng thc phn t cht A b) Cho cht A tc dng vi kh clo 250 C v c nh sng. Hi thu c my dn xut monoclo ca A ? Cho bit tn ca mi dn xut . Dn xut no thu c nhiu hn ? Cu 5. t chy hon ton 1,45 g mt ankan X phi dng va ht 3,64 lt oxi (ktc). a) Xc nh cng thc phn t ca X b) Vit cng thc cu to cc ng phn ng vi cng thc phn t . Ghi tn tng ng. Cu 6. t chy hon ton 3,36 lt hn hp kh A gm metan v etan thu c 4,48 lt kh cacbonic (ktc). Tnh thnh phn phn trm v th tch ca mi kh trong hn hp A. Cu 7. t chy hon ton 2,86 g hn hp gm hexan v octan ngi ta thu c 4,48 lt CO2 (ktc). Xc nh thnh phn phn trm v khi lng ca tng cht trong hn hp ankan. Cu 8. t chy hon ton hn hp gm 2 hirocacbon lin tip nhau trong dy ng ng thu c 20,16 lt CO2 (ktc) v 19,8 g H2O. Xc nh CTPT ca 2 hirocacbon. II. HIROCACBON KHNG NO Cu 1. Vit cc ng phn cu to ca anken ng vi cng thc phn t C5H10 ? Gi tn cc ng phn theo tn thay th. Cu 2. Vit PTHH ca phn ng xy ra khi: a) Propilen tc dng vi hiro, un nng (xc tc Ni). b) But-2-en tc dng vi HCl. c) Metylpropen tc dng vi nc c xc tc axit. d) Trng hp but-1-en. Cu 3. Trnh by phng php ha hc : a) Phn bit metan v etilen. b) Tch ly kh metan t hn hp vi etilen. c) Phn bit hai bnh khng dn nhn ng hexan v hex-1-en. d) Vit PTHH ca cc phn ng. Cu 4. Dn t t 3,36 lt hn hp gm etilen v propilen (ktc) vo dung dch brom thy dung dch b nht mu v khng cn kh thot ra. Khi lng dung dch sau phn ng tng 4,90 g. a) Vit cc PTHH v gii thch cc hin tng th nghim trn. b) Tnh thnh phn phn trm v th tch ca mi kh trong hn hp u. Cu 5. Dn 4,48 lt hn hp X gm 2 anken A v B lin tip nhau trong dy ng ng vo nc brom d, thy khi lng bnh nc brom tng 10,50 g. Tm CTPT ca A, B v tnh thnh phn phn trm th tch ca mi anken. Cu 6. Cho etilen vo bnh cha brom lng to ra 1,2-ibrometan. a) Tnh th tch etilen (ktc) tc dng vi brom bit rng sau khi cn li thy bnh brom tng thm 14 g. b) Tnh khi lng brom c th kt hp vi 3,36 lt etilen (ktc). Cu 7. Th no l ankaien, ankaien lin hp ? Vit CTCT v gi tn cc ankaien lin hp c CTPT C4H6, C5H8. Cu 8. Vit PTHH (dng CTCT) ca cc phn ng xy ra khi a) isopren tc dng vi hiro (xc tc Ni). b) isopren tc dng vi brom (trong CCl4).

c) Cc cht c ly theo t l 1:1, to ra sn phm cng theo kiu 1,4. d) Trng hp isopren theo kiu 1,4. Cu 9. Oxi ha hon ton 0,68 g ankaien X thu c 1,12 lt CO2 (ktc). a) Tm CTPT ca X. b) Vit CTCT c th c ca X. Cu 10. Vit CTCT ca: a) a) 2,3-imetylbuta-1,3-ien b) 3-metylpenta-1,4-ien. b) c) 3,3-imetylbuta-1-en. d) 2-etylbut-1-en Cu 11. Vit PTHH minh ha: a) tch metan t hn hp vi mt lng nh etilen, ngi ta dn hn hp kh i qua dung dch brom d. b) Sc kh propilen v dd KMnO4 thy mu ca dd b nht dn, c kt ta nu en xut hin. Cu 12. Trnh by phng php ha hc phn bit ba bnh ng kh ring bit l: metan, etilen v cacbonic. Vit PTHH minh ha. Cu 13. Vit PTHH ca cc phn ng thc hin s chuyn ha sau: ( 1) ( 2) ( 3) ( 4) ( 5) CH 3COONa CH 4 C 2 H 2 C 2 H 4 C 2 H 6 C 2 H 5Cl

Cu 14. Vit PTHH ca cc phn ng iu ch polibuta-1,3-ien t but-1-en. Cu 15. 2,8 g anken X mch cacbon khng nhnhphn ng va vi 200ml dung dch brom 0,25 M. Tm CTPT ca X, vit CTCT ca X bit kh tc dng vi HBr to ra mt dn xut duy nht. Cu 16. a) Vit CTCT v gi tn cc ankin c CTPT C4H6, C5H8. b) Vit CTCT ca cc ankin co tn sau: pent-2-in; 3-metylpent-1-in; 2,5-imetylhex-3-in Cu 17. Vit PTHH ca phn ng gia propin v cc cht sau: a) hiro c xc tc Pd/PbCO3. b) dung dch brom d. c) ung dch bc nitrat trong amonic. d) hiro clorua c xc tc HgCl2. Cu 18. Trnh by phng php ha hc phn bit: a) axetilen vi etilen. b) ba bnh khng dn nhn cha mi kh khng mu sau: metan, etilen, axetilen. c) but-1-in v but-2-in. Cu 19. Dn 3,36 lt hn hp kh A gm propin v etilen i vo mt lng d dd AgNO3 trong NH3 thy cn 0,84 lt kh thot ra v c m gam kt ta. Cc th tch o ktc. a) Tnh phn trm th tch etilen trong A. d) Tnh m. Cu 20. Dn hn hp kh gm metan, etilen, axetilen i vo mt lng dugn dch bc nitrat trong dn dch amoniac. Kh cn li c dn vo dd brom d. Nu v gii thch cc hin tng xy ra trong th nghim. Cu 21. Vit PTHH ca cc phn ng thc hin s chuyn ho sau: ( 1) ( 2) ( 3) ( 4) ( 5) CH 3COONa CH 4 C 2 H 2 C 4 H 4 C 6 H 6 polibutadien Cu 22. Vit PTHH ca cc phn ng t axetieln v cc cht v c cn thit iu ch cc cht sau: a) a) 1.2-icloetan b) 1,1-icloetan c) 1,2-ibrommetan b) d) buta-1,3-ien d) 1,1,2-tribrometan. Cu 23. Dn 6,72 lt hn hp kh gm propan, etilen v axetilen qua dd brom d thy cn 1,68 lt kh khng b hp th. Nu dn 6,72 lt kh X trn qua dd bc nitrat trong amoniac thy c 24,24 g kt ta. Cc th tch o ktc. a) Vit cc PTHH gii thch qu trnh th nghim trn. b) Tnh thnh phn phn trm theo th tch v theo khi lng ca mi kh trong hn hp. Cu 24. Cho bit cc phng php lm sch cht kh: a) metan ln tp cht l axetilen v etilen. b) etilen ln tp cht l axetilen