Chng 1: Este - Lipit

Lp 12-CFC&U

KIEM TRA KIEN THC CHNG I: ESTE - LIPIT

1. S hp cht n chc, ng phn cu to ca nhau c cng CTPT C4H8O2, u tc dng c vi dd NaOH l (C 2007): A. 6. B. 4. C. 5. D. 3. 2. Pht biu ng l: (H 2008A) A. Phn ng gia axit v ru khi c H2SO4 c l phn ng mt chiu. B. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ru (ancol). C. Khi thy phn cht bo lun thu c C2H4(OH)2. D. Phn ng thy phn este trong mi trng axit l phn ng thun nghch. 3. Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na, Cu(OH)2, CH3OH, dung dch Br2, dung dch NaOH. Trong iu kin thch hp, s phn ng xy ra l (H 2008A): A. 2. B. 3. C. 5. D. 4. 4. Cho dy cc cht: HCHO, CH3COOH,CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l (C 2008): A. 3. B. 6. C. 4. D. 5. 5. Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l (H 2010A): A. 1. B. 2. C. 4. D. 3. 6. s hp cht hu c no, n chc, mch h, c cng cng thc phn t C5H10O2, phn ng c vi dung dch NaOH nhng khng c phn ng trng bc l (H 2010B): A. 4. B. 5. C. 8. D. 9. 7. Hai cht X v Y c cng cng thc phn t C2H4O2. Cht X phn ng c vi kim loi Na v tham gia phn ng trng bc. Cht Y phn ng c vi kim loi Na v ho tan c CaCO3. Cng thc ca X, Y ln lt l: (C 2010): C. HOCH2CHO, A. HCOOCH3, CH3COOH. B. HCOOCH3, HOCH2CHO. CH3COOH. D. CH3COOH, HOCH2CHO. 8. Thu phn cht hu c X trong dd NaOH (d), un nng, thu c sn phm gm 2 mui v ancol etylic. Cht X l (C 2010): C. ClCH2COOC2H5. D. CH3COOCH2CH3. A. CH3COOCH(Cl)CH3. B. CH3COOCH2CH2Cl. 9. Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hh X tc dng vi 5,75 gam
C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l (H 2007A):

A. 10,12. B. 6,48. C. 8,10. D. 16,20. 10. t chy hon ton m gam hn hp X gm hai ancol n chc, cng dy ng ng, thu c 15,68 lt kh CO2 (ktc) v 17,1 gam nc. Mt khc, thc hin phn ng este ha m gam X vi 15,6 gam axit axetic, thu c a gam este. Bit hiu sut phn ng este ha ca hai ancol u bng 60%. Gi tr ca a l (C2012) A. 15,48. B. 25,79. C. 24,80. D. 14,88. 11. Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l (H 2011B): A. 75%. B. 72,08%. C. 27,92%. D. 25%. 12. Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O2 (ktc), thu c 5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l (C 2010): A. HCOOCH3 v 6,7. B. CH3COOCH3 v 6,7. C. (HCOO)2C2H4 v 6,6. D. HCOOC2H5 v 9,5. 13. Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l (C 2007): A. isopropyl axetat. B. etyl propionat. C. metyl propionat. D. etyl axetat. 14. X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l (H 2008B): A. 17,80 gam. B. 18,24 gam. C. 16,68 gam. D. 18,38 gam. 15. Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l (C 2008): A. CH2=CH-CH2-COO-CH3. B. CH2=CH-COO-CH2-CH3. C. CH3 -COO-CH=CHCH3. D. CH3-CH2-COO-CH=CH2. 16. Mt hn hp X gm hai cht hu c n chc. Cho X phn ng va vi 500 ml dung dch KOH 1M. Sau phn ng, thu c hn hp Y gm hai mui ca hai axit cacboxylic v mt ru

Gv Phan Van Nhan

Chng 1: Este - Lipit

Lp 12-CFC&U

(ancol). Cho ton b lng ru thu c trn tc dng vi Na (d), sinh ra 3,36 lt H2 ( ktc). Hn hp X gm (C 2008): A. mt axit v mt este. B. mt este v mt ru. C. hai este. D. mt axit v mt ru. 17. X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l (H 2009A): A. CH3COOCH3 v CH3COOC2H5. B. C2H5COOCH3 v C2H5COOC2H5. C. CH3COOC2H5 v CH3COOC3H7. D. HCOOCH3 v HCOOC2H5. 18. hh M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (nY>nX). Nu t chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2g H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng este ho (hiu sut l 80%) th s gam este thu c l (H 2010A): A. 22,80. B. 34,20. C. 27,36. D. 18,24. 19. trung ho 15 gam mt loi cht bo c ch s axit bng 7, cn dng dd cha a gam NaOH. Gi tr ca a l (C 2010): A. 0,075. B. 0,280. C. 0,200. D. 0,150. 20. Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, c axit axetylsalixylic (oCH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2g axit axetylsalixylic cn va V lt dd KOH 1M. Gi tr ca V l (H 2011A): A. 0,72. B. 0,24. C. 0,48. D. 0,96. 21. Cho cc pht biu sau: (H 2012A): (a) Cht bo c gi chung l triglixerit hay triaxylglixerol. (b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c. (c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch. (d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5. S pht biu ng l A. 3. B. 2. C. 4. D. 1. 22. t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO 2 v 0,4 mol H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l (H 2012A): A. 4,08. B. 6,12. C. 8,16. D. 2,04. 23. Cho cc este : etyl fomat (1), vinyl axetat (2), triolein (3), metyl acrylat (4), phenyl axetat (5). Dy gm cc este u phn ng c vi dung dch NaOH (un nng) sinh ra ancol l (C2012) A. (1), (2), (3). B. (1), (3), (4). C. (2), (3), (5). D. (3), (4), (5). 24. Cho s phn ng: (C2012) Este X (C4HnO2)
+ AgNO3 / NH 3 + NaOH + NaOH Z Y C2H3O2Na. t0 t0 t0

Cng thc cu to ca X tha mn s cho l A. CH2=CHCOOCH3. B.CH3COOCH2CH3. C. HCOOCH2CH2CH3. D. CH3COOCH=CH2. 25. un nng m gam hn hp X gm cc cht c cng mt loi nhm chc vi 600 ml dung dch NaOH 1,15M, thu c dung dch Y cha mui ca mt axit cacboxylic n chc v 15,4 gam hi Z gm cc ancol. Cho ton b Z tc dng vi Na d, thu c 5,04 lt kh H 2 (ktc). C cn dung dch Y, nung nng cht rn thu c vi CaO cho n khi phn ng xy ra hon ton, thu c 7,2 gam mt cht kh. Gi tr ca m l (H 2012B): A. 40,60 B. 22,60 C. 34,30 D. 34,51 26. Cho s cc phn ng: (H 2013A): to t o ,CaO X + NaOH (dung dch) Y + NaOH (rn) Y + Z; T + Z;
1500 C t , xt T Q + H2O Q + H 2; Z. Trong s trn, X v Z ln lt l: A. CH3COOCH=CH2 v CH3CHO. B. HCOOCH=CH2 v HCHO. C. CH3COOCH=CH2 v HCHO D. CH3COOC2H5 v CH3CHO. 27. Pht biu no sau y khng ng? (H 2013B) A. Cht bo l trieste ca etylen glicol vi cc axit bo. B. Cc cht bo thng khng tan trong nc v nh hn nc. C. Triolein c kh nng tham gia phn ng cng hiro khi un nng c xc tc Ni. D. Cht bo b thy phn khi un nng trong dung dch kim. 28. Este no sau y khi phn ng vi dung dch NaOH d, un nng khng to ra hai mui? (H 2013B) A. C6H5COOC6H5 (phenyl benzoat). B. CH3COOC6H5 (phenyl axetat).
o o

Gv Phan Van Nhan

Chng 1: Este - Lipit

Lp 12-CFC&U

C. CH3COO[CH2]2OOCCH2CH3. D. CH3OOCCOOCH3. 29. Hn hp X gm mt axit cacboxylic no, n chc, mch h v mt ancol n chc, mch h. t chy hon ton 21,7 gam X, thu c 20,16 lt kh

CO2 (ktc) v 18,9 gam H2O . Thc hin phn

ng este ha X vi hiu sut 60%, thu c m gam este. Gi tr ca m l (H 2013B) A. 15,30 B. 12,24 C. 10,80 D. 9,18 30. Thy phn hon ton m1 gam este X mch h bng dung dch NaOH d, thu c m 2 gam ancol Y (khng c kh nng phn ng vi Cu(OH) 2) v 15 gam hn hp mui ca hai axit cacboxylic n chc. t chy hon ton m2 gam Y bng oxi d, thu c 0,3 mol CO2 v 0,4 mol H2O. Gi tr ca m1 l (H 2013B) A. 11,6. B. 16,2. C. 10,6. D. 14,6.

HO TEN : AP AN
1 16 2 17 3 18 4 19 5 20 6 21 7 22 8 23 9 24 10 25 11 26

LP :
12 27 13 28 14 29 15 30

Gv Phan Van Nhan