CEMENTING PRODUCTS AND ADDITIVES (March 1999)

The 1999 Cementing Supplement is a comprehensive listing of cementing products and additives available from mayor suppliers. This most recent update now comprises seven companies, including two companies new to the listing. American Fracmaster Ltd. Is the U.S. affiliate of Fracmaster in Calgary, Canada. The firms have separate but complementary products lines. Argentinas s San Antonio is listed in Cementing this year for the first time as well.

HOW TO USE THIS REFERENCE

Listings reflect available cement additives from seven service companies. Products are grouped into functional categories. Some products are unique to a company, and many are protected by patent rights or other legal means. They may be chemically similar, but not identical, and provide comparable performance in cement slurry formulations. Exact equivalence is not implied. Where applicable, products are subdivided into groups having similar performance within each functional category. Performance groups have been subdivided to reflect significant differences in chemical nature of additives and emphasize uniqueness within each company s product line. What can not be reflected are differences in product performance with different cements, or performance variations resulting from different sources of the same material around the world. Materials should be tested according to accepted procedures to ensure that performance requirements are met. Also, users are cautioned that it is generally not possible or prudent to make translations of cement formulations between service companies based solely on additive descriptions. Products are grouped in 15 functional categories: Basic cements Accelerators and salts Extenders and density-reducing additives Free water control and solids suspending agents Dispersants Bond improving and expanding additives Fluid-loss control additives Silica to reduce or prevent high temperature strength retrogression Retarders Anti-gas migration agents Anti-foam and defoaming agents Density increasing or weighting agents Additives and mixtures to reduce or prevent lost circulation Spacers and chemical washes or preflushes Specialty cement blends

Temperature has a significant effect on many cementing additives and is the single most important variable affecting cement hydration. This is particularly for retarders, but also applies to fluid loss control additives, anti-gas migration, expanding and other agents. Salt tolerance is particularly important in fluid loss control additive selection. When applicable, this reference

includes temperature ranges groupings, salt tolerance and other variables critical to additive performance. Temperature and salt tolerance are broad groupings and actual performance may vary somewhat depending on cement, other additives in formulations and well conditions. Important note. Fluid loss control additives are listed according to maximum temperature and salt tolerance for that product. For example, if an additive is shown to be effective up at about 250 F in the presence of over 18% salt (by weight of mix water), it is very likely that this product is also effective at higher temperatures with lower salt concentrations. There are several examples of this in the table. Finally, if a company does not have an equivalent to a competitors product listing, it does not mean that the company can not come up with a cement formulation that achieves similar performance. Our recommendation is to call the company, describe the application or problem and let them work on a solution. Even though additive technology has advanced, it is still best applied with a measure of experience.

BASIC CEMENTS
Material Description API Class A, B and ASTM Type I or II cements Portland cement API Class G or H API Class C and ASTM type III High aluminate cement Commercial lightweight cements Commercial expanding cements Microfine Portland cement Microfine Portland cement and microfine blast furnace slag blend High fineness cement Blast furnace slag (BFS) Microfine blast furnace slag Blend of Portland cement and blast furnace slag Storable liquid cement slurry Acid soluble cement Synthetic resin cement Calcium aluminate cement TXI lightweight or equivalent Chem Comp, ASTM type K or similar MC-300 or equivalent MC-500 or equivalent Cements ground finer than normal but not as microfine cements Ground, granulated or pelletized blast furnace slag MC-100 or equivalent Blend to improve poor quality Portland cements and improve additive response Water-based liquid cement slurry Non-Portland inorganic cement soluble in acid Epoxi resin cement Slagment Liquid stone Magne Plus Acid soluble cement Synthetic cement Available on request Acid soluble cement EPSEAL, Stratalock Magna cement Available on request Available on request MC-300 MC-500 Fine Grind Class C cement Blast Furnace Slag cement Microfine cement Microfine cement Channelma ster Channelma ster CS Micromatrix cement Matrix cement Microcem 1000 American Fracmaster Ltd A H C Fondu TXI Lightweight BJ Services Dowell Fracmaster Normal Portland G, H C Fondu TXI Lightweight Halliburton Nowsco Canada A, B Type I, II G, H C, Type III Ciment Fondu TXI Lightweight Ciment Fondu Lightweight San Antonio A, B G, H

A, B Type I, II G, H C, Type III Lumnite, Ciment Fondu TXI Lightweight

A, B Type I, II G, H C, Type III Lumnite, Ciment Fondu TXI Lightweight

Standard Premium Premium Plus Ciment Fondu TXI Lightweight

Blast Furnace Slag (D930)

Slag cement

Slag-10, 20, 30, 40

ACCELERATORS AND SALTS

Material Description Reduces thickening time of cement at concentrations between 1% and 10% by weight in the mix water Accelerator. Reduces thickening time of cement. Typically used at 1% to 3% by weight of cement Accelerator. Reduces thickening time of cement. Increases slurry viscosity Accelerator. Reduces thickening time of cement. Often used to create thixtropic cement slurries KCl NH4Cl Product Form American Fracmaster Ltd BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

Sodium chloride (salt)

Granular

Salt

A-5 or salt or Sodium Chloride

D44

Salt

Salt

Cement Grade salt

Salt

Solid

CaCl2

A-7 or CaCl2

S1

CaCl2

Calcium Chloride Calcium Chloride Liquid Econolite, Diacel A Liquid Econolite

Calcium Chloride

Calcium Chloride Calcium Chloride Liquid Sodium Metasilicate Diacel A SE-1L Sodium silicate

Calcium Chloride

Liquid Powder or Beads Liquid

CaCl2-L Sodium Metasilicate Liquid sodium silicate

A-7L or CaCl2-L A-2, Sodium Metasilicate, Diacel A A-3L or Sodium Silicate

D77

CaCl2-L

D79, Diacel A

TXC-1

EXC

Sodium silicate

D75

EXT-100

EXC-L

Calcium sulfate hemihydrate or gypsum

Powder

Gypsum

A-10 or Gypsum

D53

Ultracal 60

Cal-Seal, EA-2

Gyp-Cem, Quik Gyp

Gypsum

Potassium chloride Ammonium chloride Proprietary accelerator

Granular Granular

KCl Available on request

A-9 or Potassium Chloride Available on request AEF-100L, T-40L

M117 Available on request

KCl Available on request CA-3 CA-4

KCl Available on request

KCl Available on request

KCl NH4Cl

EXTENDERS AND DENSITY-REDUCING ADDITIVES

Material Bentonite Attapulgite Description Naturally colloidal clay Naturally colloidal clay Pozzolanic material product of burning coal. Lower in lime content than type C Pozzolanic material product of burning coal For use with microfine cements Siliceous material produced from volcanic activity Lightweight, friable siliceous material derived from diatom remains Volcanic glass, spherelitic and hollow High surface area, amorphous silica Product Form Powder Powder American Fracmaster Ltd Bentonite Salt Gel BJ Services Bentonite Attapulgite Dowell D20 D128 Fracmaster Bentonite Salt gel Halliburton Gel Attapulgite Nowsco Canada Bentonite Salt Gel Sepiolite NowPoz San Antonio Bentonite Attapilgite

Type F flyash

Powder

Pozzolan

Flyash

D35

Pozzolan

Pozmix A Calss C Flyash Microflyash

Pozzolan

Type C, flyash Microfine flyash Natural pozzolan Diatomaceous earth Perlite/expand perlite Fumed silica (dry) Glass microspheres Pozzolan microspheres

Powder Powder

Flyash

D132

NowPoz

Powder Powder Granular Granules Beads Powder Liquid Suspension Small beads Powder-like Small beads Powder or beads

Pozzolan

D61

Pozzolan

Diacel D

Diacel D

D56

Diacel D

D.E.

Diacel D

Perlite Fumed Silica On request On request

Perlite BA-58 CSE BA-58L LW-8L LW-7-2, LW-7-4 LW-6 Thrifty Mix, Diacel A, Sodium Metasilicate Thrifty Mix-L, Sodium Silicate Liquid T-40 Black-Lite BJ Blue

D72 D154 D155 On request D124

Perlite FS-1 FS-101

Perlite Silicalite Liquid silicalite, Microblock Galss Spheres Spherelite Microsil-10P Microsil-22P Microsil-15L Nowspheres 2000 Nowspheres 7000

Perlite Microsilica

Scotchlite or similar Spherulitic, expanded pozzolanic material produce from burning coal

Esfelite

C Spheres

Ceramic Spheres

Sodium Metasilicate Liquid sodium silicate

D79, Diacel A D75

TXC-1

Econolite, Diacel A Liquid Econilite Versaset GasCon 469 Versaset L

EXC

SE-15

Sodium silicate Liquid Proprietary extender Solid Liquid

EXT-100

EXC-L D-20

D111

FREE WATER CONTROL AND SOLIDS SUSPENDING AGENTS

Application Product type Product Form Dry powders, granules, beads, etc American Fracmaster Ltd Sodium metasilicate, Diacel A BJ Services A-2 or sodium metasilicate, Diacel A, T-40, FWC-47, ASA301 A-3L or sodium silicate, T-40L, FWC-47L, ASA301L, BJ Blue Dowell Fracmaster Halliburton Econolite, Diacel A, VersaSet, FWCA, Suspend HT, SA-541 Liquid Econolite, VersaSet L, VersaSet LXP, GasCon 469 Gel, Attapulgite, Silicalite, Compacted silicalite, Microblock Liquid silicalite, Microblock Nowsco Canada San Antonio Sodium metasilicate, Diacel A, SE 18

Free water control and solids suspension

Polymers, sodium silicates, biopolymers, proprietary chemicals

D79, Diacel A, D153

TXC-1

FW-1, EXC

Liquid

Liquid Sodium Silicate

D75, D162

EXT-100

FW-2, EXC-L

SE IL

Bentonite, attapulgite, fumed silica, etc. See also: Extenders and density reducing agents

Powder

Bentonite, Attapulsite

Bentonite, attapulgite, BA58, CSE, BA-90 BA-58L, Microblock

D20, D128, D154

Bentonite, FS-1, TXC-1, Salt gel, FWC-3 FS-101, EXT-100

Bentonite, Attapulgite, Microsil 10P, Microsil 22P Microsil 15L

Microsilica, Bentonite

Liquid

Available on request

D155

SE IL

DISPERSANTS
Application Product type Product Form American Fracmaster Ltd Available on request BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio 1W, 3W, FT-4, Granular Powder, FT4-L

Polynapthalene sulfonate (PNS) type. Example products: Lomar-D, Daxad-19 or equivalent

Powder

CD-31

D65

FRC-3

CFR-2

T-10

Liquid Powder

Available on request FMD-1300

CD-31L, CD-31NL, CD-31LS CD-33

D80

FRC-100

CFR-2L CFR-3 CFR-3L

T-10L

General Application

Proprietary, nonPNS, nonlignosulfonate

Liquid Liquid Powder CD-32 D145A

Proprietary Liquid Proprietary: for use above about 200 F circulating temperature Citric acid, citrate salt or similar Polimetric materials (not citric acid, citrate salt, etc)

Powder Powder Granular Powder Liquid Powder

FMD-1300 FM-MTB 1500 FM-MTB 1600

D121

XR-2 CD-33

D45 D65A D80A, D604AM

FRC-2

FE-2 CFR-3 CFR-3L CFR-2

T-11

Dispersant for salt-saturated slurries Dispersant with non-setting or anti-setting characteristics for easily dispersed cements

CD-32

Liquid

CD-33L

D604AM

CFR-2L

BOND IMPROVING AND EXPANDING ADDITIVES

Application Product type Latex: Styrene/butadiene copolymer Latex: Acrylic or equivalent Improve cement bonding to surfaces: Non-expanding additives Product Form Liquid American Fracmaster Ltd LAC-1 BJ Services Dowell D600, D134 Fracmaster Halliburton Nowsco Canada San Antonio

BA-86L BA-10, BA-56, BH-56HT, FLAG-56 BA-10L

Latex-1

Latex 2000 LAP-1, FloBlock 210, Halad 447 LA-2 NL-2 Microsil 10P, Microsil 22P Microsil 15L Nowlite Nowlite NL-2

Powder Liquid Powder

LAC-1P

Fumed silica Available on request Nowlite

Fumed silica Liquid Fumed silica/flyash blend Improve bonding to salt formations Calcium sulfate hemihydrate or gypsum Powder Powder Liquid

BA-58, CSE, BA-90 BA-58L BA-91

D154 D155

FS-1 FS-101

Silicalite, Compacted silicalite Liquid silicalite, Microblock Silicalite blend

D65A D80A, D604AM, D604M Gypsum Available on request A-10 or Gypsum EC-1, EC-2 D53 Ultracal 60 Cal-Seal, EA-2 Microbond, Microbond M, Microbond HT Gyp-Cem, Quik Gyp

Powder

Expanding agents, may also improve bonding

Pwder Metal oxide Liquid Gas-generating agents: Aluminum powder or similar Powder Liquid Powder

Available on request Available on requesr

BA-29, BA-61

CPC-1

Super CBL Gas-Check, Inhibited GasCheck

SPC-12000

Other materials

Proprietary Liquid

BA-92, BA-100, MPA-1, MPA-2 BA-100L

Bondmaster

FLUID-LOSS CONTROL ADDITIVES

Appication Circulating temperature range Compatibility with salt (NaCl): Salt concentration and temperature limitations Use in fresh water or with less than 5% salt by weight Low temperature when little or no retarding effect is desired Use up to 10% salt by weight Product form American Fracmaster Ltd FM-FL-1200 BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

Powder Liquid Powder

FL-62, BA-10 BA-10L, FL-45LS/LN

D127, D156 UniflexL UniflexS UniflexL

FLC-1, FLC-5 FLC-100

LAP-1 LA-2

D-25

LTX LTXL

D19, D30 LD-30 Halad 322, 344,413,567, Gas Stop HT Halad 322L, 322LXP, 344LXP, 413L, 361A, 600LE LAP-1, Halad 447, GasStop HT LA-2 GasStop HT Halad-10L Halad 9, 332, 413, 567 Halad 9L, 9LXP, 322L, 322LXP FLC4, 7, 8 FLC-107 NFL-2 LD-18 D-24, NFL-2 LD-18, LD-24 NFL-2, NFL-3, D-33

60 F to 120 F

Liquid FM-HTFL1270

D19,D30 FC-19, FC-22, Sarf-100

Powder Use up to 18% salt by weight Liquid

FL-33, FL-63

D146, UniflexS

FLC-7

FL-33L, FL-63L

UniflexL

FLC-107

LTX

Only for fresh water

Powder Liquid

FM-FL-1200

FL-62, BA-10 BA-10L FL-45LN, FL-45LS FL-52, FL-25

UniflexS UniflexL UniflexS D300, UniflexL D60, UniflexS UniflexL

FLC-1,7,4,8 FLC-100

LTXL

Use up to 10% salt by weight General application 80 F to 200 F

Powder Liquid Powder

Use up to 18% salt by weight

Liquid FM-HTFL1270

Use over 18% salt by weight

Powder Liquid

FL-33, FL-63 FL-33L, FL63L

D59, UniflexS UniflexL

D-24 LD-24

Sarf 3, FC-22, FC-2

FLUID-LOSS CONTROL ADDITIVES (CONT. 1)

Appication Circulating temperature range Compatibility with salt (NaCl): Salt concentration and temperature limitations Only for fresh water Product form American Fracmaster Ltd FM-HTFL1250 BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

Powder Liquid

FL-62 BA-10L

UniflexS UniflexL UniflexS UniflexL D160, UniflexS D603, D159, UniflexL D65A, UniflexS D80A, D604AM UniflexL UniflexS UniflexL

GasStop HT, Halad 413, 567 GasStop HT, Halad 413, 567 Halad 22A, 344 Halad 22AL, 22ALXP

D-30 LD-30

Sarf 2 LD-30 FC-9

Use up to 10% salt by weight General application Effective up to 250 F

Powder Liquid Powder

Use up to 18% salt by weight

FM-HTFL1270

FL-52, FL-25

FC-22

Liquid Powder FM-HTFL1270 FL-32, FL-33, FL-63 FL-32L, FL-33L, FL-63L FM-HTFL1250/1270 FM-HTFL1270 FM-HTFL1270

Use over 18% salt by weight

Liquid Powder Liquid

Only for fresh water Use up to 10% salt by weight General application Effective up to 300 F

GasStopHT, Halad 413

Diacel, LWL

Powder Liquid Powder Liquid

UniflexS UniflexL FL-52, FL-25 UniflexS UniflexL FL-32, FL-33, FL-63 FL-32L, FL-33L, FL-63L UniflexS UniflexL FLC-7 FLC-107 Halad-14, GasStop HT, Halad 413 Halad-14LXP, Halad 600LE GasStop HT, Halad 413 D-24 LD-24

Use up to 18% salt by weight

Use over 18% salt by weight

Powder Liquid

FLUID-LOSS CONTROL ADDITIVES (CONT. 2)

Appication Circulating temperature range Compatibility with salt (NaCl): Salt concentration and temperature limitations
Only for fresh water

Product form

American Fracmaster Ltd

FM-HTFL1250 FM-HTFL1270 FM-HTFL1270 FM-HTFL1270 FM-HTFL1270, Diacel LWL

BJ Services

Dowell

Fracmaster

Halliburton

Nowsco Canada

San Antonio

Powder Liquid

UniflexS UniflexL UniflexS UniflexL UniflexS D73, D73.1,D158, UniflexL FL-33, FL-63, FL-32 FL-33L,FL63L FL-32L D8, Diacel LWL,D143, UniflexS D158, UniflexL

FLC-7 FLC-107

GastStop HT, Halad 413 GasStop HT, Halad 413 GasStop HT, Halad 413

Up to 10% salt by weight General application Efective over 300 F

Powder Liquid Powder

D-28 LD-28

Up to 18% salt by weight

Liquid

Over 18% salt by weight

Powder

Liquid General and special application Latex: Styrene/ butadiene copolymer General and special application Latex: Acrilic Fluid loss control in highly extended or low density slurries Fluid loss control in blast furnace slag slurries (containing no Portland cement) From 100 F to 400 F depending upon product and stabilizers Up to 200/250 F

Halad 413, 100A, Diacel LWL, Gas Stop HT Halad-413L, 361A, 600LE

Diacel LWL

Recommended for fresh water. May be used up to 18% salt by weight

Liquid

LAC-1

BA-86L

D600, D134, UniflexL

Latex-1

Latex 2000

Recommended for fresh water

Powder Liquid Powder FL-52

UniflexS UniflexL D112,D156 UniflexS D159,D300 UniflexL UniflexS FLC-4, FLC-7, FLC-8 FLC-100

LAP-1, Halad 447 LA-2 D23, D24 NFL-2 LD-24

Variable limits

Variable limits Liquid BL Blue

Powder Variable limits Variable limits Liquid

UniflexL

FLUID-LOSS CONTROL ADDITIVES (CONT. 3)

Appication Circulating temperature range Compatibility with salt (NaCl): Salt concentration and temperature limitations Product form American Fracmaster Ltd BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

Stabilizer for latex in the presence of salt or at high temperature Stabilizer for latex in low density slurries Fluid loss aid Fluid loss aid Up to 200 F Over 200 F

Liquid

LS-1, LS-2

D135, UniflexL

Stabilizer 434B, Stabilizer 434C

Liquid

CD-32, CD-33

D138, UniflexL D136, UniflexS D121, UniflexS FLC-2 FLC-2

Stabilizer 434B, Stabilizer 434C

Powder Powder

SILICA TO REDUCE OR PREVENT HIGH TEMPERATURE STRENGTH RETROGRESSION

Material Product type Crystalline silica approximately 100 mesh. SG 2.65 nominal Cristalline silica approximately 200 mesh or finer SG 2.65 nominal Crystalline silica SG 2.65 nominal Product form Granular solid American Fracmaster Ltd FM-SR-1150 BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

Sand

S-8C

D30

SFA-100

SSA-2

L-10

SF-100

Silica flour Microfine silica: For use with microfine cements

Fine Powder

FM-SR-1100

S-8

D66

SFA-200

SSA-1

SFA-200, SFA-325

SF-200, SF-225

Fine Powder

Available on request

FS-1

Microsand

RETARDERS
Appication Low temperature Mid-range, moderate temperature Moderate to hight temperature Moderate to hight temperature Hight temperature Circulating temperature range Up 180 F 125 to 225 F Product type Lignosulfonate, mofified lignosulfonate Lignosulfonate. Modified lignosulfonate blend Organic acid or organic acid salt blend Diacel LWL (carboxymethyl hydroxyethyl cellulose) Modified lignosulfonate blend Blend of lignosulfonate or modified lignosulfonate with borax or borate salt Borax/borate salt Non-borax/norate salt Proprietary, synthesized polymer or copolymer. Nonlignosulfonate Product form Powder Liquid Powder Liquid Powder Liquid Powder Liquid Powder Liquid Powder Liquid Powder Powder Powder Liquid Powder Liquid Powder SR-30 D161 SR-30 R-14L, R15LS, R-20L SR-30 Borax R-9 or sodium borate D93 D121 CR-3 Component R HR-25 SCR-100 SCR-100L HR-25 HR-25L SCR-100 R-35 FM-R-1400 R-8 R-8L D28 D150 CR-5 CR-105 CR-5, CR-3 HR-12, HR-15 HR-12L, HR13L HR-20 R-55 R-55L R-57 SR-10 Diacel LWL R-6 or Diacel LWL FM-R-4 FM-R-22 D110 D8 American Fracmaster Ltd FM-R-1400 BJ Services R-3 R-21L R-3, R-11 R-10L, R-12, R-21L Dowell D13 D81 D800 D801 Fracmaster CR-1 CR-100 CR-2 CR-102 CR-5 CR-105 CMHEC Diacel LWL Diacel LWL SR-12 Halliburton HR-4, HR-7 HR-4L, HR-7L HR-5 HR-6L R-40L Nowsco Canada R-6 R-6L SR-6 SR6-1 Diacel LWL San Antonio SR-2

175 to 300 F

175 to 300 F

Over 225 F

Hight temperature Retarder aid for lignosulfonates Retarder aid for lignosulfonates Synthetic retarder Synthetic retarder Retarder for improved compressive strength in long cement columns

Over 300 F

Up to 250 F

Up to 425 F Helps early compressive strength where significant temperature differential exists

Liquid

D110

SCR-100L

RETARDERS (CONT.)
Appication Retarder for microfine cements Thixotropic cement retarder Permafrost cement retarder Permafrost For slurries containing calcium sulfate hemihydrate or gypsum Citric acid or citrate salt or similar, nonlignosulfonate Lignosulfonate Circulating temperature range Product type Product form Powder Liquid Powder Powder Liquid Powder Liquid D13 D81 CR-1 CR-100 HR-4 HR-4L R-7 R-18, SR-30 R-7 D74 CR-4 FRC-2 Sodium citrate R-15 MMCR American Fracmaster Ltd BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

ANTI-GAS MIGRATION AGENTS

General mechanism of action Fluid loss control only Product type See: fluid loss control additives Polymeric blends: (Non-Latex) Latex: Styrene/butadiede copolymer or similar Matrix flow restriction/blocking Latex: Acrylic Powder Liquid Liquid Powder Liquid Powder Fumed silica Liquid Fumed silica/polymer blends Calcium sulfate hemihydrate or gypsum Cross-linked or complexed polymeric materials Powder Liquid Powder Powder Liquid Powder Other Liquid Powder Proprietary polymeric additives Liquid D604AM BA-46L D65A On request BA-46 Telmaster, Thixmaster, FastMaser2 Thix Set 31 Thix-Set A, VersaSet Versaset L, VersaSet LXP GasStop, GasStop HT GasStop L, GasStop LXP Thix-Mix, Thix-O-Gel, Thermal Thix-Mix Gypsum A-10 or gypsum D53 Ultracal 60 Cal-seal, EA-2 Gyp-cem On request BA-58L D155 FS-101 Fumed silica LAC-1 BA-56, BA-56HT, BA-100, FLAG-56 BA-100L, FL-45LS LN, BJ Blue BA-86L BA-10 BA-10L BA-58, CSE, BA-90 D154 FS-1 GasblockLT Product form American Fracmaster Ltd BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

D600, D134

Latex-1

Latex 2000 LAP-1, Halad-447 LA-2 Silicalite, compacted silicalite Liquid silicalite, Microblock

Microsil10P Microsil 22P Microsil 15L

Gel strength modification: Thixotropic additives/slurries

Gel-strength modification: Delayed gelling

ANTI-GAS MIGRATION AGENTS (CONT.)

General mechanism of action Alteration of cement slurry compressibility: Gas-generating agents Alteration of cement slurry compressibility: Foamed cement Supplemental agents for gas migration control Supplemental agents for gas migration control Stabilizer for Latex in the presence of salt or at high temperature Stabilizer for Latex in low-density slurries Product type Product form Powder Aluminum powder or similar Liquid Foamed cement Foamed cement Foamed cement American Fracmaster Ltd On request BJ Services BA-29, BA-61 Dowell Fracmaster CPC-1 Halliburton Super CBL Gas-check, Inhibited GasCheck Foamed cement Foamed cement Stabilizer 434B, Stabilizer 434C Stabilizer 434B, Stabilizer 434C Foamed cement Nowsco Canada SPC-12000 San Antonio

LS-1, LS-2

D135

CD-32, CD-33

D138

CF-1

ANTI-FOAM AND DEFOAMING AGENTS

General mechanism of action Product type Product form Dry-powders, granules, beads, etc. Liquid American Fracmaster Ltd FM-AF-P BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

Prevent or decrease foaming during mixing

High molecular weight alcohols, polyalcohols, silicones, etc.

FP-11 FP-6L, FP-9L, FP-12L, FP-10L, AFA-3

D46 D47, M45, D144

DEF-3 DEF-1, DEF-5

D-Air 1 D-Air 2, D-Air 3, NF-3, NF-4, NF-6, NF-7 AFA-2, AFA-3

FM-AF-L

DENSITY INCREASING OR WEIGHTING AGENTS

Material Product type Cirstalline silica approximately 40-70, 20-40 mesh or similar coarse material SG 2.65 nominal Crystalline silica approximately 100 mesh SG 2.65 nominal Crystalline silica approximately 200 mesh or finer SG 2.65 nominal Crystalline silica SG 2.65 nominal Iron Titanium oxide SG 4.4 4.5 nominal Iron oxide SG 5 5.2 nominal Barium sulfate SG 4.2 nominal SG 4.6 4.9 nominal SG 4.9 SG 2.75 Product form American Fracmaster Ltd BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

Sand

Granular solid

Sand

Sand

Sand

Sand

Sand

Sand

Sand

Granular solid

FM-SR-1150

S-8C

D30

SFA-100

SSA-2

L-10

Silica flour Microfine silica: For use with microfine cements Ilmenite Hematite Barite Manganese oxides Microfine weighting agents for use with microfine cements Calcium carbonate for use in spacers

Fine powder Fine powder Powder Powder Fine powder Fine powder Fine powder Granular solid

FM-SR-1100

S-8

D66

SFA-200

SSA-1

SFA-200, SFA-325

Microsand Ilmenite Hematite Barite Ilmenite Hematite Barite W-10 D76 D31 D157 D157 D151 Ilmenite Hematite Barite Hi-Dense 3, Hi-Dense 4 Barite Micromax Micromax Ilmenite Hematite Barite

ADDITIVES AND MIXTURES TO REDUCE OR PREVENT LOST CIRCULATION

Material
Cements

Description
SEE: Basic cements

Product form
Slurries

American Fracmaster Ltd

BJ Services

Dowell

Fracmaster

Halliburton

Nowsco Canada
Thix-Mix, Thix-O-Gel, Thermal Thix-Mix, Rapid Gel SPC, Rapid Set Foamed cement Diesel Gel, Diesel cement

San Antonio

Thixotropic cement slurries: Aqueous

Slurries

Available custom blend

Sure Fill, Sure Plug, Thixofill, Thixofume, Gypsum cement, BJ Thixo

RFC

Thixmaster, Telmaster, Plugmaster

Thix-Set, ThixSet 31, Thixlite 373, Cal-Seal cement, VersaSet Foamed cement BDO, BDOC, DOC, Flexplug MOC-1

Foamed cement Diesel oil cements, diesel oil bentonite cements, gunk squeeze, etc. Made with regular grind cements Made with microfine cements Sodium silicate solutions, complexed sodium silicate solutions, polymer solutions Graded and sized to meet needs

Slurries

Foamed cement

Foamed cement Diesel oil cement, Visqueeze Mark II, Diesel oil/bentonite, Zone check

Foamed cement Polymer Plug, SOS

Foamed cement Diesel cement systems

Non-aqueous slurries Non-aqueous cement slurries Reactive washes, polymer solutions

Slurries

Diesel cement

Slurries Flo-guard L, Stop Block, SAF Mark III, Siljel V Sand Mica Celloflake Gilsonite Kol seal On request On request On request On request Wood chips Flex Seal, Hi-Seal, Mud save F, Mud save M D130 Nut plug Perlite D72 Perlite LCM-2 Wood chips On request D29 D24 D42 Gel Seal, Masterflush, Mastersweep Sand Mica Celloflake Gilsonite

Liquid mixtures

Custom Flush

Zonelock, Permablock

Superflush

Thixseal

Sand Mica Cellophane flake Gilsonite Ground coal Walnut plugs Perlite Fibers: Nylon, Polypropinele, cellulose, etc. Wood chips Polyester, rubber, Kwik seal Proprietary

Granular Flake/ Powder Flake Granular Granular

Sand Mica Celloflake Gilsonite

Sand

Sand Mica Flocele Gilsonite Kollite Tuf Plug Perlite Tuf additive No. 2 Wood chips Granulite TR 1/4 Kwik Seal

Sand Mica Celloflake Gilsonite NLC-1

Tuf plug or equivalent

Granular Beads Fibrous/ poeder Granular/ Flake Granular Granular

Wood chips

Acid soluble, expanding bridging agenbt

Flakes

Cuttings K

Perfect seal

SPACERS AND CHEMICAL WASHES/PREFLUSHES

Spacer or wash type Description Reactive containing sodium silicate or similar reactive materials Aqueous containing surfactants and solvents. No fluid loss control Aqueous containing surfactants and solvents. Contains agents to reduce fluid loss to formations Non-aqueous blend or surfactants, solvents, etc in hydrocarbon carrier fluid American Fracmaster Ltd Chekmaster BJ Services Flowcheck, Flo Guard Mud clean, MRS-2 Mud sweep, Ultraflush II Dowell Zonelock, Zonelock SC CW-7, CW-8, CW-8ES CW-100, CW101 Masterflush O Chemwash D Aqueous formulations containing a freeze point depressant Formulated for turbulent flow at low pump rates Formulated for laminar flow Flow regime not specified Water continuous phase Spacers Emulsion, weighted Spacers Recommended in wells drilled with OBM Spacers Formulations compatible with high salt concentrations Spacers Fluids containing blast furnace slag for use with SlagMix and slag cement Oil continuous phase Solvent continuous phase FOMS-200 FOMS-100 FOMS-300 MCS-2, MCS-3 MCS-4, MCS-5 Ultraflush II, Turbo Flo 3 Weighted mud sweep APS-1 OB-1, RSB Turbo-Solvent MCS-3, MCS-4 RSB, Turbo-Solvent Mudpush XLO Mudpush XTO Mudpush XEO Mudpush XS Mastersweep O Dual Spacer, Alpha spacer, SAM-4, Tuned spacer Dual spacer, Dual spacer E Nowflush 6, Nowflush 7 Mudpush XT Mudpush XTO Mudpush XS Mudpush XSO Mudpush XL Mudpush XLO MudpushWHT Mudpush XEO SAM-4 Dual Spacer, SD Spacer, Spacer 500 Mastersweep W Tuned Spacer Alpha spacer Nowsweep W Supersweep CW-8, CW-8ES, CW-101 Masterflush O Fracmaster Halliburton Nowsco Canada Thix-Seal Flush Nowflush 6, Nowflush 7 San Antonio

Gel Seal Masterflush W

Super flush

Chemwash-1

Mud Flush

Chemical washes (Not weighted with solid weighting agents)

Alpha Preflush N-Ver-Sperse O N-Ver-Sperse O, Alpha Preflush Nowflush 6, Nowflush 7

Chemical washes recommended for wells drilled with OBM Chemical washes design for mixability at sub-zero temperatures

Spacers Aqueous, weighted

OMR-2

SPECIALTY CEMENT BLENDS

General formulation Blends of Portland cement with commercial lightweight cements such us TXI Lightweight Ratio of flyash: cement at 15:85 with bentonite up to 8% Ratio of flyash: cement at 35:65 with bentonite up to 6% Ratio of flyash: cement at 50:50 with bentonite up to 4% Other ratios Blends of cement. Flyash and silica fume Blends containing cement, silica fume and pozzolan microspheres Blends of containing lightweight pozzolan microspheres Blends containing lightweight glass beads Blends of cement, flyash, lime and silica for high temperature applications Low density cement blend with superior compressive strength (10.5 to 12.5 ppg) High density cement blend with superior mixing and rheological properties (17.5 to 24 ppg) Expanding cements containing calcium sulfate hemihydrate or similar Proprietary blend On request FM-Lite 15:85:8 FAC (2) (Flyash cement) FAC (2) Specific formulation American Fracmaster Ltd BJ Services Dowell Fracmaster Thriftmaster, Thriftmaster LT Halliburton Nowsco Canada Tru-Lite R, Tru-Lite HS San Antonio

(1)

(1) Halliburton Light cement Fillmaster Halliburton Pozment A

Nowlite 2

Blends of Portland cement, Flyash and Gel (Bentonite)

AFL-Lite

(1)

Nowlite 1

50:50:4

FAC (2) FAC (2), Econofill WMC-1, WMC-1B

(1) (1)

Nowlite 3

HILITE Litemaster, Litemaster 2

My-T-Lite 1200 SpheraLite Cement

Nowlite 1200

On request

Cenolite Lite Set

LITEFILL

On request

HTLD (High temperature Low Density Cement) LiteCRETE On request

Proprietary blend

LW-6/MPA-1, Portland Blend

LiteCRETE

On request

Self Stress Cement

Bondmaster

On request

Expand-O-Mix

SPECIALTY CEMENT BLENDS (CONT. 1)

General formulation Expanding cements containing metal oxide expanding agents Expanding cement containing gas generating agents Containing calcium sulfate hemihydrate or gypsum Crosslinked polymer complexes Proprietary additives Sure Fill RFC (Regulated fill-up cement Thixmaster On request Thix-Set 31 Thixofil Cold Set Containing polymeric additives such us latex, polyvinyl alcohol, etc. Salt containing or salt saturated cements Proprietary additives to improve bonding to salt formations Saltbond cement CO2 resistant cement Portland cements with additives to reduce acid solubility Epoxy resin cement Non-Portland inorganic cement completely soluble in acid Water-based liquid cement slurry Magne Plus Liquid Stone Synthetic cement Acid soluble cement On request On request Flexcem, Thermalock Flexcem, Epseal Epseal, Atratalock Acid soluble cement Arcticset cement Wellbond Service Telmaster Versaset Permafrost cement BVC-30 Polarset Cement Latex Cement Salt Saturated Cement Specific formulation American Fracmaster Ltd BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

Rapid Gel SPC Thix-Mix

Thixotropic cements

Permafrost cement Cements to improve bonding

Cements to improve bonding to salt formations

Carbon dioxide resistant cements Acid resistant cement Synthetic resin cement Acid soluble cement Storable liquid cement

SPECIALTY CEMENT BLENDS (CONT. 2)

General formulation Specific formulation Cement containing fibers to increase resistance to mechanical shock and tensile stress Blend for cold temperature of deep water drilling where shallow water flow zones are a problem American Fracmaster Ltd BJ Services Dowell Fracmaster Halliburton Nowsco Canada San Antonio

Fiber cement

Fiber cement

On request

On request

On request

Deepwater cement

Deep Set

RAS

Flow Stop I, Flow Stop 4000

(1) No compositional name used. Blends are referred to by their actual composition (35:65:6, 50:50:2, etc). (2) Flyash cement or FAC is used to describe all blends of flyash and cement. The ratio is specific for the appication.