S 1 Cu 1 (2 im) Hon thnh s phn ng sau: KMnO4 Cl2 NaCl Cl2 FeCl2 FeCl3 Fe(NO3)3 Fe(OH)3 Fe2O3 Cu 2 (2 im)

2 (2 im) Nu phng php ha hc nhn bit cc cht kh cha trong cc bnh mt nhn sau: SO2, CO2, H2S, O2 v O3. Cu 3 (2 im) T nguyn liu ban u l mui n, qung pirit, nc, khng kh (iu kin c ). Hy vit phng trnh iu ch natri hiroxit, nc Javen, st (II) sunfat, st (III) sunfat. Cu 4 (1 im) Cho cn bng ha hc: N2 (k) + 3H2 (k)

2NH3(k) H < 0

Nu cc yu t lm cho cn bng trn chuyn dch theo chiu thun. Cu 5 (3 im) Cho m gam hn hp X gm Fe v Mg. Thc hin 2 th nghim: - Th nghim 1: Cho m gam X tc dng vi dd HCl va thy gii phng ra 11,2 lt kh. - Th nghim 2: Cho m gam X tc dng vi dd H2SO4 96% th thy gii phng ra kh SO2 duy nht vi th tch o c l 13,44 lt. Bit cc kh o ktc. 1. Tnh m v % khi lng mi kim loi trong hn hp X. 2. Sc t t kh B trn vo 400 ml dd KOH 2M. C cn dd thu c bao nhiu gam mui khan. S 2 Cu 1 ( 2 im) Hon thnh s phn ng sau: FeS2 SO2 SO3 H2SO4 Fe2(SO4)3 Fe(OH)3 Fe2(SO4)3 FeCl2 Fe(NO3)2. Cu 2 (2 im) Ch dng qu tm nu phng php ha hc nhn bit cc dd mt nhn sau: Na2SO4, NaOH, Ba(OH)2, H2SO4, NaCl, HCl. Cu 3 (2 im) Vit 2 phng trnh phn ng chng minh: 1. SO2 va c tnh oxi ha, va c tnh kh. 2. HCl c tnh axit v tnh kh. Cu 4 (1 im) Cho cn bng 2SO2 (k) + O2 (k)

2SO3(k) H < 0

Khi tng nhit , tng p sut, gim nng SO3 v tng nng SO2 th cn bng ln lt chuyn dch theo chiu no? Gii thch. Cu 5 (3 im) Dd A gm 3 mui NaCl, NaBr v NaI. Tin hnh 3 th nghim . TN1 : Ly 20 ml dd A c cn th thu c 1,732 gam mui khan. TN2 : Ly 20 ml dd A lc k vi brm d sau c cn th thu c 1,685 gam mui khan. TN3 : Ly 20 ml dd A tc dng vi Clo d, sau c cn thu c 1,4625 gam mui khan. Tnh nng mol/l ca tng mui trong 200 ml dd A. S 3 Cu 1 (2 im) Vit cc phng trnh phn ng chng minh rng: 1. Cl2 c tnh oxi ha mnh hn Br2; Br2 c tnh oxi ha mnh hn I2. 2. H2S c tnh kh. 3. H2SO4 c tnh oxi ha mnh. 4. O3 c tnh oxi ha mnh hn O2. Cu 2 ( 2 im) Ch dng phenolphtalein nu phng php ha hc nhn bit cc dd mt nhn sau: NaOH, NaCl, BaCl2, Na2SO4, Ba(OH)2. Cu 3 (2 im) T MnO2, NaCl, H2SO4 c, Fe, Cu v H2O ngh cch iu ch nhng cht sau: FeCl2, FeCl3, CuSO4 Cu 4 (1 im) Nu cc phng php ha hc gip tng hiu sut qu trnh iu ch NH3. Bit c phng trnh: N2 (k) + 3H2 (k)

2NH3(k) H < 0 Cu 5 ( 3 im) Cho 1,92 gam hp kim X gm ng, km, magie tc dng va vi HCl ta c 0,03 mol kh v dd A. Cho NaOH d tc dng vi dd A th thu c 1 kt ta. Nung kt ta ti khi lng khng i c 0,8 gam cht rn. 1. Xc nh thnh phn ca hn hp. 2. Ha tan 1,92 gam hp kim X trn bng H2SO4 c, nng th thu c V lt kh SO2 (ktc). Tnh V. S 4 Cu 1 (2 im) Cho cc kh sau, cha trong cc bnh mt nhn: O2, H2S, SO2, Cl2, CO2. 1. Nu phng php vt l nhn bit cc kh. 2. Nu phng php ha hc nhn bit cc kh. Cu 2 (2 im) 1. Nu cch tin hnh pha long axit H2SO4 c. Gii thch cch lm . 2. thu c dd H2SO4 25% cn ly m1 gam dd H2SO4 45% pha vi m2 gam dd H2SO415%. Xc nh t l m1/m2. Cu 3 (2 im) Vit cc phng trnh phn ng sau (ghi r iu kin, nu c) 1. Cho H2S tc dng vi O2 2. t qung pirit. 3. Cho Fe3O4 tc dng vi HCl long 4. Sc kh H2S vo dd KMnO4.

Nhng ngy u H 2013

thi th Ha 10 HK2

Trang 1/13

 CaO (r) + CO2 (k) Cu 4 (1 im) Trong qu trnh nung vi xy ra phn ng: CaCO3 (r)

H > 0 . Nu cc phng php gip tng

hiu sut phn ng. Cu 5 (3 im) Cho 16,5 gam hn hp mui Na2S v Na2SO3 tc dng vi 100 ml dd HCl un nng ta c hn hp kh X c t khi i vi hiro l 27. Lng axit d trung ho va 500 ml dd NaOH 1M. 1. Tm khi lng mi mui trong hn hp? 2. Tm nng mol ca dd HCl? 3. Hn hp kh X trn c kh nng lm mt mu va V lt dd KMnO4 2M. Tnh V. S 5 Cu 1 (2 im) Ch dng qu tm nu phng php ha hc nhn bit cc dd cha trong cc l mt nhn sau: KOH, KCl, K2SO4, HCl, H2SO4, Ba(OH)2. Cu 2 (2 im) Hon thnh dy bin ha sau:
MnO2 ,t 1. A B+D
0

E + F + G 2. B + M co mang ngan
dpdd

3. E + HCl B + M
t 5. D + X Y
0

4. D + G M 6. Y + Br2 + M Q + P

7. X + Q 8. F + M Y + M ... Cu 3 (2 im) Nu phng php iu ch oxi trong phng th nghim v trong cng nghip. Vit phng trnh minh ha (nu c). Cu 4 (1 im) Nu cc yu t lm cho tc phn ng tng. Mi yu t ly 1 v d lin h. Cu 5 (3 im) Cho m gam hn hp gm Fe, Zn, Cu tc dng ht vi dd H2SO4 long thu c 13,44 lt kh X (ktc)v 9,6g cht rn. Mt khc cng ly m gam hn hp ni trn cho tc dng ht vi dd H2SO4 c ngui thu c 7,84 lt kh (ktc) Y. 1. Tnh thnh phn % theo khi lng mi kim loi. 2. Sc t t kh Y vo 500ml dd KOH 0,25M ri c cn thu c bao nhiu gam mui khan. S 6 Cu 1 (2 im) Cho cc cht sau: KMnO4, KClO3, MnO2 v K2Cr2O7 ln lt tc dng vi dd HCl c. 1. Nu cc cht oxi ha c khi lng bng nhau th chn cht no iu ch lng clo nhiu nht? Gii thch. 2. Nu cc cht oxi ha c s mol bng nhau th chn cht no iu ch lng clo nhiu nht? Gii thch. Cu 2 (2 im) Nu phng php ha hc nhn bit cc dd sau: NaCl; NaI; Na2SO4; NaNO3; HCl v H2SO4 Cu 3 (2 im) Hon thnh s phn ng sau: KMnO4 O2 SO2 H2SO4 H2S SO2 S A H2S Cu 4 (1 im) Xt h cn bng ha hc:

CO

(k)

CO 2 (k) + H 2 (k) + H 2 O (k)

H<0
4. Dng xc tc.

Cn bng s chuyn dch theo chiu no nu: 1. Tng nghit . 2. Gim p sut 3. Thm kh CO vo Cu 5 (3 im) Chia 15,57g hn hp gm Al, Fe, Ag lm 2 phn bng nhau: - Phn 1: Tc dng vi dd HCl long d th c 3,528 lt H2v 3,24g mt cht rn. - Phn 2: Tc dng vi dd H2SO4 c nng d. 1. Tnh khi lng mi kim loi. 2. Sc t t kh SO2 trn vo 500 ml dd Ca(OH)2 1M. Tnh khi lng mui thu c. S 7

Cu 1 (2 im) iu ch oxi trong phng th nghim ngi ta c th thc hin nhit phn cc cht giu oxi nh KMnO4, KClO3, KNO3 1. Nu cc cht c khi lng bng nhau th chn cht no iu ch lng O2 nhiu nht? Gii thch. 2. Nu cc cht c s mol bng nhau th chn cht no iu ch lng O2 nhiu nht? Gii thch. Cu 2 (2 im) Nu hin tng v vit phng trnh ha hc xy ra khi a. Dn kh clo vo dd NaI c nh vi git h tinh bt b. Dn t t kh SO2 v dd brom c. Dn t t kh SO2 vo dd H2S. d. Cho kim loi Cu tc dng vi dd H2SO4 c Cu 3 (2 im) Dn t t 2,24 lt kh SO2 (kc) vo 75 ml dd NaOH 2 M thu c dd A. Tnh khi lng cht trong dd A. Cu 4 (1 im) Khi bt u phn ng, nng ca mt cht l 0,0012 mol/l; sau 20 giy nng cht cn 0,0080 mol/l. Tnh vn tc trung bnh ca phn ng trong khong thi gian trn. Cu 5 (3 im) Ha tan 16 gam hn hp gm Mg, Fe trong dd H2SO4 c, nng, d thu c 11,2 lt SO2 (ktc) v dd A. a. Vit phng trnh phn ng xy ra b. Tnh % (m) mi kim loi trong hn hp ban u. Tnh khi lng mui khan thu c trong dd A. S 8 Cu 1 (2 im) Vit phng trnh phn ng ha hc chng minh: a. Tnh oxi ha ca Cl2 > Br2 > I2 Nhng ngy u H 2013 thi th Ha 10 HK2

Trang 2/13

b. HCl, SO2 va c tnh kh, va c tnh oxi ha. Cu 2 (2 im) Bng phng php ha hc, hy nhn bit cc dd ng trong cc l mt nhn sau: NaCl, Na2SO4, NaNO3, HCl, BaCl2, NaOH, MgCl2 Cu 3 (2 im) t chy hon ton 12 gam qung pirit st (FeS 2) ri dn ton b sn phm chy vo 80 gam dd NaOH 25 % th thu c dd A. Tnh nng phn trm cc cht trong dd A.
A +2B C ?M Cu 4 (2im) Cho phn ng: t1 = 15ph 0, 008M 0, 009M t 2 = 45ph 0, 005M ?M 0, 004M

1. Tnh tc trung bnh ca phn ng (tnh theo cht A) trong khong thi gian t t1 n t2 2. Tnh nng cht C ti thi im t1, nng cht C ti thi im t2 Cu 5 (2 im) Ha tan 6,32 gam hn hp gm Fe v Fe 3O4 trong dd H2SO4 c, nng, d. Sau phn ng thu c 1,232 lt SO 2 (kc) v dd A. 1. Vit phng trnh phn ng xy ra. 2. Tnh %(m) mi kim loi trong hn hp ban u. Tnh khi lng mui khan thu c trong dd A S 9

SO2 H2SO4 Na2SO4 BaSO4 Cu 1 (2 im) Hon thnh s phn ng H2S Cu 2 (2 im) So snh tnh oxi ha ca F2, Cl2, Br2, I2. Gii thch tnh cht theo: - Cu hnh electron. Bit s hiu nguyn t ca F (Z=9); Cl (Z=17); Br (Z=35); I (Z=53). - Phng trnh phn ng. Cu 3 (2 im) Nhn bit cc cht kh cha trong cc bnh mt nhn sau (theo tnh cht ha hc): O2; SO2; H2; CO2; Cl2 v HCl
(1) (2) (3) (4)

Cu 4 (1 im) Cho cn bng ha hc:

N2O4 (k) 2NO2 (k) (khng mu) (mu nu ) Khi tng nhit , gim p sut, gim nng NO2 phn ng c xu hng bin i mu sc nh th no? Cu 5 (3 im) Cho 11,3 gam hn hp Mg v Zn tc dng vi dd HCl d th thu c 6,72lt kh H2( ktc) 1. Tnh thnh phn phn trm theo khi lng ca tng kim loi trong hn hp u ? 2. Tnh khi lng mui khan thu c sau phn ng? 3. Nu ha tan hon ton hn hp11,3 gam 2 kim loi trn bng 100ml dd H2SO4 c nng sinh ra sn phm kh SO2 duy nht. Tnh th tch kh SO2 thu c ( ktc) v nng mol ca dd axit dng ? S 10 Cu 1 (2 im) Vit phng trnh hon thnh cc phn ng ha hc sau ( ghi r iu kin, nu c) a) Cl2 + Fe b) Br2 + NaI c) Cl2 + NaOH (long) d) HCl + Na2CO3 Cu 2 (2 im) t chy hon ton 4,8 gam S ri dn ton b sn phm chy vo 200 ml dd NaOH 2M thu c dd A. Tnh nng mol ca cht trong dd A. Cu 3 (2 im) 1. Vit cc phng trnh phn ng trong qu trnh sn xut axit sunfuric 2. Ngi ta c th iu ch c bao nhiu tn H 2SO4 t 5 tn qung pirit st c cha 10 % tp cht. Gi s hiu sut c qu trnh l 85%. Cu 4 (1 im) Trong qu trnh bo qun mui st (III) ngi ta phi thm axit vo (thm nng ion H+). Gii thch ti sao. Bit Fe(OH)3 + 3H + trong dd mui st (III) xy ra cn bng: Fe3+ + 3H 2O Cu 5 (3 im) Cho 8,8 gam hn hp A gm (Cu v Fe) tc dng vi dd H2SO4 long d. Sau phn ng thu c 2,24 lt kh H2 (ktc). Hy: 1. Tnh thnh phn % theo khi lng trong hn hp ban u. 2. Nu thay H2SO4 long bng H2SO4 98% (d = 1,84 g/ml), nng ha tan ht hn hp A th thu c V lt kh khng mu, mi hc (ktc). Tnh a) V. b) Th tch H2SO4 98% dng. c) Nng % ca cc mui thu c S 11 Cu 1 (2 im) Hon thnh cc phng trnh phn ng sau: FeS2 + O2 (A) + (B) (rn) (A) + O2 (C) + (D) (lng) (E) (E) + Cu (F) + (A) + (D) (A) + NaOH (d) (H) + (D) (H) + HCl (A) + (D) + (I) Cu 2 (2 im) Nhn bit cc cht rn sau: CuO, Cu, Fe3O4, MnO2 v Fe. Cu 3 (2 im) Cho 5,6 lt kh H2S ( ktc) li chm qua bnh ng 350 ml dd NaOH 1M, tnh khi lng mui sinh ra? Cu 4 (1 im) Cho cc cn bng sau: Nhng ngy u H 2013 thi th Ha 10 HK2 Trang 3/13
V2O5 ,t (C)
0

H = 58kJ

a. N2 (k) + 3H2(k) c. N2(k) + O2(k)

2 NH3(k) H < 0 2NO(k) H < 0. C2H5OH(k) H < 0.

b. CaCO3(r) d. CO2(k)

CaO(r) + CO2(k) H > 0. H2O(k) + CO(k) H > 0. + H2(k) 2NO2(k) H < 0.

e. C2H4(k) + H2O(k)

f. 2NO(k) + O2(k)

Cn bng ca phn ng sau s chuyn dch v pha no khi: + Tng nhit ca h. + H p sut ca h . + Tng nng cc cht tham gia phn ng. Cu 5 (3 im) Cho 12g hn hp hai kim loi Cu, Fe tan hon ton trong H 2SO4 c,nng, d thu c 5,6 lt SO 2 sn phm kh duy nht ktc v dd X. Cho KOH d vo dd X thu c m gam kt ta, nung kt ta ngoi khng kh thu c a gam mt cht rn. Tnh % theo khi lng ca mi kim loi trong hn hp? Tnh gi tr ca m v ca a? S 12 Cu 1 (2 im) Vit phn ng th hin s thay i s oxi ha ca nguyn t: S0S-2S0S+4S+6S+4S0S+6 Cu 2 (2 im) Nu phng php ha hc nhn bit cc cht bt mu trng sau: BaCO3, Na2CO3, NaCl, Na2SO4, CaCl2 v KNO3 Cu 3 (2 im) t chy ht 1 g n cht R cn dng lng va l 0,7 lit O2 ( ktc). a/ Hy xc nh n cht R. Vit cng thc phn t v gi tn hp cht to thnh. b/ Trnh by tnh axit v tnh kh ca hp cht . Vit cc phng trnh phn ng minh ho. Cu 4 (1 im) Nn 2mol N2 v 8mol H2 vo bnh kn c th tch 2 lit(cha sn cht xc tc vi th tch khng ng k)v gi cho nhit ko i. Khi phn ng trong bnh t ti trng thi cn bng, p sut cc kh trong bnh bng 0,8 ln p sut lc u(khi mi cho vo bnh, cha xy ra phn ng). Nng ca kh NH3 ti thi im cn bng bng bao nhiu? Cu 5 (3 im) Ho tan 10,54 gam hn hp X gm Cu, Mg , Fe bng mt lng d dd HCl thu c 4,48 lit kh A(ktc) , 2,54 gam cht rn B v dd C. C cn dd C thu c m gam mui. 1. Tnh phn trm khi lng kim loi v m. 2. Nu dng H2SO4 c, ngui ha tan hn hp X th thu c bao nhiu lt kh SO2 (ktc)? S 13 Cu 1 (2 im) Hon thnh cc phng trnh phn ng sau: KMnO4 + (A) (B) + (C) + Cl2 + (D) (B) (E) + Cl2 (E) + (D) (F) + H2 MnO2 + (A) (C) + Cl2 + (D) Cl2 + (F) (B) + KClO + (D) Cu 2 (2 im) Bng phng php ha hc nu cch nhn bit cc dd mt nhn sau:Na2SO3, Na2CO3, NaCl, MgSO4, NaNO3. Cu 3 (2 im) Ho tan 6,7g oleum vo H2O thnh 200ml dd H2SO4 ; 10 ml dd ny trung ho va ht 16 ml NaOH 0,5M. 1). Tnh n. 2).Tnh % ca SO3 c trong oleum trn. 3).Cn bao nhiu gam oleum c hm lng SO3 nh trn pha vo 100ml dd H2SO4 40% (d = 1,31 g/ml) to ra oleum c hm lng SO3 l 10%. Cu 4 (1 im) Cn bng phn ng CO2 + H2 sau: [CO2] = 0,2 M; [H2] = 0,8 M ; [CO] =0,3 M; [H2O] = 0,3 M. Tnh nng H2, CO2 ban u. Cu 5 (3 im) Ha tan hon ton 5,65 gam hn hp Mg v Zn vo dd HCl 2M thu c 3,36 lt kh (ktc). a) Tnh phn trm theo khi lng mi kim loi trong hn hp ban u. b) Tnh th tch dd HCl 2M dng. c) Dn ton b kh sinh ra trn i qua ng ng 16 gam CuO, un nng. Tnh khi lng cht rn thu c sau phn ng. S 14 Cu 1 (2 im) : Thc hin nhng bin i ha hc sau bng cch vit nhng PTHH v ghi r iu kin ca phn ng, nu c: (1) (3) (6) H2SO4 SO3 H2SO4 SO2 (4) (7) FeS2 S SO2 (2) (5) H2SO4 (8) BaSO4 Cu 2 (2 im) Nu phng php nhn bit cc kim loi mu trng sau: Ca, Al, Mg, Fe, Ag Cu 3 (2 im) 1. Ho tan 33,8 gam oleum H2SO4.nSO3 vo nc, sau cho tc dng vi lng d BaCl 2 thy c 93,2 gam kt ta. Xc nh cng thc ng ca oleum. 2. Vit cc phng trnh iu ch HCl trong phng th nghim v trong cng nghip. Cu 4 (1 im) Cho phn ng thun nghch xy ra trong bnh kn: CO(k) + H2O(k)

CO + H2O c thit lp t0C khi nng cc cht trng thi cn bng nh

CO2(k) + H2(k)

Ban u trong bnh ch c CO v H 2O. Khi phn ng t n trng thi cn bng th [CO] = 0,08M; [CO 2] = 0,12M v hng s cn bng KC = 1. Tnh nng mol ban u ca CO v H2O. Cu 5 (3 im) 1. Ho tan hon ton 8,3 gam hn hp X gm Al v Fe trong dd HCl (ly d), thu c 0,25 mol kh H 2.Vit cc phng trnh phn ng xy ra v tnh khi lng mi kim loi trong hn hp X. Nhng ngy u H 2013 thi th Ha 10 HK2 Trang 4/13

2. Ho tan ht 8,8 gam mt mui sunfua (c dng MS, trong M l kim loi c s oxi ho +2 v +3 trong cc hp cht ho hc) trong dd H2SO4 (c. nng, d), thu c 0,45 mol kh SO2. Vit phng trnh phn ng ho hc xy ra v tm cng thc phn t ca mui sunfua. S 15 Cu 1 (2 im) Hon thnh cc phng trnh phn ng sau: Mg + H2SO4 (c) (A) + (B)+ (C) (B) + (D) S + (C) (A) + (E) (F) + K2SO4 (F) + (H) (A) + (C) (B) + O2 (G) (G) + (C) (H Cu 2 (2 im) Bng phng php ho hc hy phn bit cc dd sau: NaCl, BaCl2, Na2CO3, Na2SO3 Cu 3 (2 im) Hp th hon ton 6,8 gam H2S vo 250 ml dd NaOH 1M. Tnh khi lng mui to thnh sau phn ng. Cu 4 (1 im) Cho phn ng sau: H2O (k) + CO (k)

H2(k) + CO2 (k).

7000C hng s cn bng KC = 1,873. Bit rng hn hp ban u gm: 0,300 mol H2O v 0,300 mol CO trong bnh 10 lt 7000C. Cu 5 (3 im) Hn hp A gm Cu, Fe. Cho m gam A vo dd H 2SO4 long d thu c 4,48 lit kh (ktc). Cng m gam A cho vo dd H2SO4 c, nng, ly d 10% so lng cn thit c 10,08 lt kh SO2 (ktc). Cc phn ng xy ra hon ton. a. Vit cc phng trnh phn ng xy ra b. Tnh thnh phn % khi lng cc cht trong A c. Tnh khi lng FeS2 cn thit to ra c lng axit c trn bit qu trnh sn xut hao ht 20%. S 16 Cu 1 (2 im) Vit phng trnh phn ng v nu hin tng: 1. Sc t kh SO2 vo dd KMnO4. 2. Cho mt mu ng vo dd H2SO4 c, nng. 3. t kh H2S trong iu kin oxi thiu. 4. Nh vi git dd phenolphtalein vo dd NaOH, ri cho dd HCl n d. Cu 2 (2 im) T mui n, nc, H2SO4 c. Vit cc phng trnh phn ng (ghi iu phn ng nu c) iu ch: Kh Cl 2, H2S, SO2 , nc Javen, Na2SO4 Cu 3 (2 im) Cho 32 g hn hp Fe v FeS tc dng va vi dd HCl 2M. Sau phn ng thu c V lt hn hp kh A (ktc) v dd B. Cho hn hp kh A i qua dd Pb(NO3)2 d th thu c 71,7 g kt ta mu en. 1. Tnh khi lng cc cht trong hh ban u. 2. Tnh Vdd HCl dng. Cu 4 (1 im) Cho 2SO2(k) + O2(k) 1. Tng nhit ca h. 2. Tng nng ca O2 ln gp i .

2SO3(k) + 44 Kcal. Cho bit cn bng ca phn ng chuyn dch theo chiu no khi:

Cu 5 (3 im) Ho tan hon ton 11,5 gam hn hp Cu, Al, Mg vo dd HCl d, thu c 5,6 lt kh(ktc) v phn khng tan .Cho phn khng tan vo H2SO4 c nng, d thu c 2,24 lt kh (ktc). 1. Xc inh khi lng mi kim loi trong hn hp. 2. Nhn bit 3 kim loi trn bng phng php ha hc S 17 Cu 1 (2 im) Vit phng trnh phn ng khi H2SO4 long v H2SO4 c nng tc dng vi cc cht sau: Fe, Cu, FeO, Na2CO3. Cu 2 (2 im) Ch dng thm mt thuc th (khng dng cht ch th mu), hy nhn bit cc dd sau: natri sunfat, axit sunfuric, natri cacbonat, axit clohiric. Cu 3 (2 im) t chy hon ton 12,8 g S. Kh sinh ra c hp th ht bi 150 ml dd NaOH 20% (D = 1,28 g/ml). Tm C M, C% ca cc cht trong dd thu c sau phn ng. Cu 4 (1 im) Phn ng thun nghch: N2 + O2 2NO.C hng s cn bng 24000C l Kcb=35.10-4. Bit lc cn bng, nng ca N2 v O2 ln lt bng 5M v 7M trong bnh kn c dung tch khng i. Nng mol ca NO lc cn bng bng bao nhiu? Cu 5 (3 im) Mt hn hp A gm Fe v mt kim loi M ho tr 2. - Ha tan hon ton 12,1g hn hp A bng H2SO4 long th thu c 4,48lt kh H2(kc). - Ha tan hon ton 12,1g hn hp A bng H2SO4 c nng th thu c 5,6 lt kh SO2(kc). 1. Vit cc phng trnh phn ng c th xy ra. 2. Xc nh kim loi M. S 18 Cu 1 (2 im) Hon thnh s phn ng sau: FeS H2S S Na2S ZnS ZnSO4 SO2 SO3 H2SO4 Nhng ngy u H 2013 thi th Ha 10 HK2 Trang 5/13

Cu 2 (2 im) Mui n b ln tp cht l: Na 2SO4, MgCl2, BaCl2, CaSO4. Hy trnh bi phng php ho hc loi b tp cht, thu c NaCl tinh khit.Vit phng trnh ho hc. Cu 3 (2 im) 1. Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dd X. trung ho 100 ml dd X cn dng 200 ml dd NaOH 0,15M. Xc nh cng thc oleum v phn trm v khi lng ca nguyn t lu hunh trong oleum trn. 2. Cho 10,8 gam kim loi M (ha tr III) tc dng ht Cl2 to thnh 53,4 gam mui.Xc nh kim loi M? Cu 4 (1 im) Trong bnh kn th tch 1 lit , t0C c phn ng phn ng thun nghch sau: CO(k) +H2O(h) CO2 + H2 , Kc=1 Nu nng ca CO2 v H2 lc cn bng l 2M. Hy tnh nng ban u ca CO v H2O, bit rng nng ban u ca CO b hn H2O l 3M Cu 5 (3 im) Cho 12,6 gr hn hp A cha Mg v Al c trn theo t l mol 3:2 tc dng va vi dd H 2SO4 c, nng thu c kh SO2 (kc). 1. Tnh % khi lng mi kim loi trong hn hp A? 2. Tnh VSO2 ( 270 C; 5 atm). 3. Cho ton b kh SO2 trn vo 400 ml dd NaOH 2,5 M. Tnh CM cc cht trong dd thu c. S 19 Cu 1 (2 im) Hon thnh cc phng trnh phn ng sau: 1. Cho dd HI tc dng vi dd H2SO4 c. 2. Sc kh Clo vo dd KOH un nng. 3. Cho MnO2 tc dng vi HCl c. 4. Sc t t kh SO2 vo nc clo Cu 2 (2 im) So snh tnh cht ha hc ca axit sunfuric long v axit sunfuric c. Dn ra phng trnh phn ng minh ha. Cu 3 (2 im) 1. Hy xc nh cng thc oleum to thnh khi cho 180g dd H 2SO4 98% hp th ht 22,4 lt SO 3 (ktc). Tnh % khi lng SO 3 trong oleum. 2. Cho 300 ml dd H2SO4 98% (D = 1,84 g/cm 3). Vy mun pha long th tch H 2SO4 trn thnh dd H2SO4 15%.Tnh th tch nc cn dng pha long Cu 4 (1 im) Mt bnh phn ng c dung tch khng i, cha hn hp kh N 2 v H2 vi nng tng ng l 0,3M v 0,7M. sau khi phn ng tng hp NH 3 t trng thi cn bng t oC, H2 chim 50 % th tch hn hp thu c. Hng s cn bng K c toC c gi tr l bao nhiu? Cu 5 (3 im) Cho 12,6 gr hn hp A cha Mg v Al c trn theo t l mol 3:2 tc dng va vi dd H 2SO4 c, nng thu c kh SO2 (kc). 1. Tnh % khi lng mi kim loi trong hn hp A? 2. Tnh VSO2 ( 270 C; 5 atm). 3. Cho ton b kh SO2 trn vo 400 ml dd NaOH 2,5 M. Tnh CM cc cht trong dd thu c. S 20 Cu 1 (2 im) Khi cho cht A tc dng vi H2SO4 c, un nng sinh ra cht kh B khng mu. Kh B tan rt nhiu trong nc, to thnh dd axit mnh. Nu cho dd B m c tc dng vi mangan dioxit th sinh ra kh C mu vng nht, mi hc. Khi cho mt mu natri tc dng vi kh C trong bnh, li thy xut hin cht rn A ban u. Xc nh tn cc cht A, B, C v vit cc phng trnh phn ng minh ha ? Cu 2 (2 im) 1. Trong 2 phn ng sau y H2S th hin tnh axit hay tnh baz, tnh oxi ho hay tnh kh? Gii thch? 2NaOH + H2S = Na2S + 2H2O 2FeCl3 + H2S = 2FeCl2 + S +2HCl 2. Vit 8 phng trnh phn ng to ra kh clo Cu 3 (3 im) 1. C 185,40g dd HCl 10,00%. Cn ha tan thm vo dd bao nhiu lt kh HCl (ktc) thu c dd axit clohidric 16,57%. 2. Nung nng Cu trong khng kh, sau mt thi gian c cht rn A. Ho tan A trong H 2SO4 c nng c dd B v kh C. Kh C tc dng vi dd KOH c dd D. D va tc dng c vi BaCl 2 va tc dng c vi NaOH. Cho B tc dng vi dd KOH. Vit cc phng trnh phn ng xy ra. Cu 4 (1 im) ha tan ht mt mu km trong dd axit HCl 20 oC cn 27 pht. Cng mu km tan trong dd axit ni trn 40 oC trong 3 pht. Hi ha tan ht mu km trong dd ni trn 55oC th cn bao nhiu pht? Cu 5 (2 im) . Cho 7,6 g hn hp gm Fe, Mg, Cu vo dd H2SO4 , ngui d th thu c 6,16 lit kh SO2 (kc). Phn khng tan cho tc dng vi dd HCl d thu c 1,12 lit kh (kc).Tnh % khi lng hn hp u. S 21 Bi1(1,0): Cho cc dung dch: NaCl, HCl, H2SO4, Na2SO4, Ba(NO3)2 ng trong cc l mt nhn. Hy trnh by phng php ha hc nhn bit cc dung dch trn? Bi2(1,0): Cho cc cht: Canxi oxit, axit sufuric c, nc, mui n v MnO2. Hy vit phng trnh ha hc ca phn ng iu ch clorua vi t cc cht trn (ghi r iu kin phn ng). Bi3(1,0): C 200 ml H2SO4 98%, khi lng ring l 1,84 g/ml. Ngi ta mun pha long th tch H2SO4 trn thnh dung dch H2SO4 40%. Tnh th tch nc cn dng pha long (bit
(1)

DH 2O = 1 g/ml)

(2) (3) Bi4(2,0): Cho s ca ba phn ng: FeS2 SO2 SO3 H2SO4 a/ Vit phng trnh ha hc ca cc phn ng biu din s trn (ghi r iu kin). b/ Tnh khi lng FeS2 cn iu ch 50gam dung dch H2SO4 49%.

Nhng ngy u H 2013

thi th Ha 10 HK2

Trang 6/13

c/ Nu hp th ton b kh SO2 to thnh t phn ng (1) bng 300 ml dung dch NaOH 1M th khi lng mui to thnh sau phn ng bng bao nhiu?

S 22 Cu 1: ( 3 im) Vit PTHH thc hin s chuyn ha sau (ghi y iu kin nu c) (1) (2) (3) (4) (5) MnO2 Cl2 HCl H2 HBr AgBr (6) AlCl3 Cu 2: ( 2 im) Trnh by phng php ha hc phn bit 3 dung dch CaCl2, NaNO3, HCl ng ring bit trong 3 l mt nhn. Cu 3: ( 1 im) Vit PTHH chng minh Br2 c tnh oxi ha yu hn Cl2 nhng mnh hn I2 Cu 4: ( 4 im) Ha tan hon ton 8,4 gam st trong 800 ml dung dch HCl. Sau phn ng thu c dung dch A v kh B. a. Tnh th tch kh thu c ktc? b. trung ha dung dch A cn dung va 400 ml NaOH 0,25M. Tnh nng ca dung dch HCl dung? (Coi th tch dung dch thay i khng ng k) S 23 Cu 1 (2 im) Hon thnh chui phn ng sau, ghi r iu kin phn ng (nu c) Cl2 KClO3 O2 NaCl HCl

H2S

H2SO4

SO2

Cu 2 (1,5 im) a) Vit phng trnh chng minh tnh kh ca cc hidro halogenua tng dn t HF n HI. b) Vit phng trnh chng minh O2 v O3 u c tnh oxi ha nhng O3 c tnh oxi ha mnh hn O2. Cu 3 (2,5 im) Cho 5,25g hn hp A gm Zn, Cu, Mg ha tan va trong 58,4g dung dch HCl 10% thu c dung dch X v 1,28g cht rn khng tan. a) Tnh phn trm khi lng mi kim loi trong hn hp. (61,91%; 24,38%; 13,71%) b) Tnh nng phn trm cc cht trong dung dch X. (10,93%; 4,58%) c) Tnh th tch dung dch H2SO4 15M cn dng ha tan ht 7,875g hn hp A v th tch kh SO2 (sn phm kh duy nht) thu c iu kin tiu chun. (20 ml; 3,36 lt) S 24 Cu 1: (2 im). Hon thnh cc phng trnh ha hc ca cc phn ng sau (ghi r iu kin nu c). a. Fe + Cl2 b. Al + H2SO4 long c. H2S + O2 d d. FeS + H2SO4 c Cu 2: (2 im). Bng phng php ha hc, nhn bit cc dung dch mt nhn ng ring bit sau (vit cc phng trnh ha hc xy ra): KCl, Na2S, H2SO4, MgSO4. Cu 3: (3 im). Ha tan hon ton 13,2 gam hn hp A gm Fe v Mg bng 100 gam dd H 2SO4 98% d thu c dd B v 9,52 lt kh SO2 (ktc). a. Tnh % khi lng mi cht trong hn hp A. b. Tnh C% cc cht trong dd B. c. Dn ton b lng SO2 thu c trn vo 119 gam NaOH 20% thu c dung dch D. Thm vo dung dch D, 200 ml dung dch cha Ba(OH)2 0,35M v BaCl2 1M thu c m gam kt ta. Tnh m. S 25 Cu 1: Thc hin chui phan ng sau (ghi ro k nu co): ( 1) ( 2) ( 3) ( 4) ( 5) Na2 SO3 SO2 H 2 SO4 CuSO4 CuCl2 Cu ( NO3 ) 3 ( 9) ( 6)
( ) ( ) ( ) S H 2 S NaHS Na2 S Cu 2: Bng phng phap hoa hoc, hay nhn bit cac lo dd mt nhan sau: Na2 S , Na2 SO3 , Na2 SO4 , NaCl , NaNO3 . Cu 3: T FeS2, nc, khng khi, cac cht xuc tac, dung cu cn thit co u. Vit phng trinh phan ng hoa hoc iu ch: a. Axit sunfuric b. St (III) sunfat Cu 4: Cho cn bng hoa hoc: C ( r ) + H 2O( k ) CO( k ) + H 2 ( k ) ; H > 0
10 7 8

Cn bng se chuyn dich theo chiu nao nu ta thay i cac yu t sau (khng giai thich): a. Ha ap sut chung cua h b. Ly bt H2 ra khoi h c. Thm C vao h c. Tng nhit Nhng ngy u H 2013 thi th Ha 10 HK2 Trang 7/13

Cu 5: Vit phng trinh phan ng hoa hoc chng to: a. H2S co tinh kh b. SO2 va co tinh oxi kh, va co tinh hoa c. S co tinh oxi hoa (mi y chi vit 1 phng trinh, cn bng va ghi y u s oxi hoa) Cu 6: Cho 17,6g hn hp gm Fe va Cu tac dung vi lng d H2SO4 98% un nong, thu c 8,96 lit khi SO2(kc) a. Tinh phn trm khi lng mi kim loai trong hn hp ban u? b. Dn toan b lng SO2 thu c trn vao 200 ml dung dich NaOH 3M. Tinh CM cac mui thu c sau phan ng? Cu 7: Hn hp A gm cac cht Fe, Cu, Al c chia lam 2 phn bng nhau: - Phn I: cho tac dung vi dd H2SO4 c, ngui, d thu c 0,448 lit SO2 (kc) va 1,10 g cht rn B - Phn II: cho tac dung vi dd H2SO4 loang, d thu c dd C va cht rn D. C can C thu c 4,94 g mui khan Goi tn cac cht trong B, C, D va tinh khi lng hn hp A S 26 Cu 1. (3,0 im) Vit cc phng trnh ha hc ca cc phn ng hon thnh dy chuyn ha sau (ghi r iu kin, nu c): KClO3 O2 SO2 SO3 H2SO4 BaSO4 Na2SO4 Cu 2. (3,5 im) a. Bng phng php ha hc, hy nhn bit cc dung dch ng trong cc l mt nhn sau: NaCl, Na2SO4, NaNO3, HCl. (vit phng trnh nu c) b. Vit phng trnh chng minh: + Tnh oxi ha Cl2 > Br2 + Tnh oxi ha Br2 > I2 + Tnh oxi ha O3 > O2 Cu 3. (1,5 im) Cho 100ml dung dch NaOH 3M tc dng va vi V lt dung dch H2SO4 1M. Sau khi phn ng hon ton tnh: a. V (ml). b. Nng mol (CM) ca dung dch thu c. Cu 4. (2,0 im) Cho 8,8 gam hn hp A gm (Cu v Fe) tc dng vi dung dch H2SO4 long d. Sau phn ng thu c 2,24 lt kh H2 (ktc). Hy: a. Xc nh khi lng tng kim loi trong hn hp A ban u. b. Tnh thnh phn % theo khi lng trong hn hp ban u. S 27 Bi1(1,0): Cho cc dung dch: NaCl, HCl, H2SO4, Na2SO4, Ba(NO3)2 ng trong cc l mt nhn. Hy trnh by phng php ha hc nhn bit cc dung dch trn? Bi2(1,0): Cho cc cht: Canxi oxit, axit sufuric c, nc, mui n v MnO2. Hy vit phng trnh ha hc ca phn ng iu ch clorua vi t cc cht trn (ghi r iu kin phn ng). Bi3(1,0): C 200 ml H2SO4 98%, khi lng ring l 1,84 g/ml. Ngi ta mun pha long th tch H2SO4 trn thnh dung dch H2SO4 40%. Tnh th tch nc cn dng pha long (bit
(1)

DH 2O = 1 g/ml)

(2) (3) Bi4(2,0): Cho s ca ba phn ng: FeS2 SO2 SO3 H2SO4 a/ Vit phng trnh ha hc ca cc phn ng biu din s trn (ghi r iu kin). b/ Tnh khi lng FeS2 cn iu ch 50gam dung dch H2SO4 49%. c/ Nu hp th ton b kh SO2 to thnh t phn ng (1) bng 300 ml dung dch NaOH 1M th khi lng mui to thnh sau phn ng bng bao nhiu?

S 28 Bi 1: (2 im) Thc hin chui phng trnh phn ng sau: KClO3 O2 S

6

SO2 H2S

H2SO4 H2SO4

Fe2(SO4)3 CO2

Bi 2: (3 im) Cho 28,1 gam hn hp A gm Zn v Ag phn ng va vi dung dch H 2SO4 c, nng thu c 4,48 lt kh SO2 ( ktc). a, Vit phng trnh phn ng v tnh % khi lng mi kim loi trong hn hp ban u. b, Dn lng kh SO2 trn qua dung dch Brom d, sau nh tip BaCl 2 n d vo dung dch. Tnh khi lng kt ta thu c. c, C mt loi qung pyrit cha 90 % FeS 2. iu ch H2SO4 tc dng vi hn hp A th khi lng qung pyrit trn l bao nhiu. Bit hiu sut qu trnh iu ch H2SO4 l 85 %. S 29 Cu 1: (1,5 im) Hon thnh s phn ng sau: (5) (1) (2) (3 ) ( 4) (6) FeS SO2 NaHSO3 Na2SO4 NaCl NaClO Cl2 Nhng ngy u H 2013 thi th Ha 10 HK2 Trang 8/13

Cu 2: (2,5 im) Ha tan hon ton 11,2 gam hn hp X gm Mg v Cu vo dung dch HCl d thu c 4,48 lt H 2 (ktc), dung dch B v rn Y. Ha tan hon ton rn Y vo dung dch H2SO4 c nng d thu c V lt SO2 (ktc). Bit cc phn ng xy ra hon ton. a. Vit phng trnh ha hc xy ra. (0,5 im) b. Tnh thnh phn % khi lng ca mi kim loi trong X (1 im) c. Dn ton b V lt SO2 thu c trn vo 150ml dung dch NaOH 2M. Tnh nng C M ca cc cht c trong dung dch sau phn ng (1 im) Cu 3: (1,0 im) Dng mt thuc th nhn bit cc dung dch sau: Na2SO4, H2SO4, NaCl, Na2SO3, Ba(OH)2 S 30 Bi 1: (2 im) Thc hin chui phng trnh phn ng sau: KMnO4 Cl2
5

NaCl Clorua vi

HCl Cl2

AgCl Br2 AlBr3

Bi 2: (3 im) Cho 23,6 gam hn hp A gm Cu v Ag phn ng va vi dung dch H 2SO4 c, nng thu c 5,6 lt kh SO2 ( ktc). a, Vit phng trnh phn ng v tnh % khi lng mi kim loi trong hn hp ban u. b, Dn lng kh SO2 trn qua dung dch Clo d, sau nh tip BaCl 2 n d vo dung dch. Tnh khi lng kt ta thu c. c, C mt loi qung pyrit cha 98% FeS 2. iu ch H2SO4 tc dng vi hn hp A th khi lng qung pyrit trn l bao nhiu. Bit hiu sut qu trnh iu ch H2SO4 l 80%. S 31 Vit phng trnh phn ng hon thnh s bin ho sau (ghi r iu kin, nu c) SO3 SO2 ZnS H2S SO2 H2SO4 H2SO4 Cu 2: (3)Trong phng th nghim c 4 ng nghim mt nhn cha cc dung dch sau: KOH, H2SO4, K2SO4, KNO3. Bng phng php ho hc, em hy ch ra mi ng nghim cha dung dch g? Cu 3: (4)Cho m (g) st tan va trong 100 gam dung dch axit sunfuric, sau phn ng thu c 2,24 (l) kh hiro ktc. 1)Tnh m 2) Tnh nng phn trm ca dung dch axit sunfuric. 3) Tnh nng phn trm ca dung dch mui thu c? Cu 1: (3) S 32 Cu 1. Hon thnh cc phng trnh phn ng trong dy chuyn ha sau : MnO2
(1) (2) (3) (4) (5) Cl2 Br2 H2SO4 Na2SO4 BaSO4

(6)
Cu 2.

(7)

(8) FeCl3 SO2 Na2SO3 1. Hon thnh cc phng trnh phn ng sau : (t )
0

a. H2S + SO2

b. H2SO4 + Mg H2S +

c. H2SO4 + Cu SO2 + d. O3 + KI + H2O 2. Vit cc pt phn ng xy ra khi cho dung dch HCl tc dng vi cc cht dd NaOH, CuO, Fe, CaCO3. Cu 3: a) Phn bit cac dung dich sau bng phng phap hoa hoc: HCl; H2SO4; NaCl; NaNO3. b) Nu hin tng va vit phng trinh phan ng cho thi nghim sau: Dn t t n d khi SO2 vao dung dich nc brom. Cu 4: Cho 11,2g bt Fe tac dung vi 4,8g bt lu huynh, un nong (khng co khng khi) thi thu c hn hp rn A. Tinh khi lng tng cht trong hn hp A. Cu 5: Cho 20,8g hn hp X gm Mg va Fe2O3 tac dung v u vi 500ml dung dich H2SO4 loang thi thu c 4,48 lit khi (ktc). a. Tinh % khi lng cac cht trong hn hp X. b. Tinh nng mol cua dung dich H2SO4 a dung. Cu 6. Xt h cn bng sau trong mt bnh kn: C(r) + H2O(k) CO(k) + H2(k) ,H> O Cn bng s dch chuyn theo chiu no nu ta thay i mt trong cc iu kin sau: a.tng nhit . b.thm lng hi nc vo. c.tng p sut chung ca h. d. dng cht xc tc . S 33 Cu 1: Axit H2SO4 c nng tc dng c vi nhng cht no sau y:Cu, P, NaNO 3, Al, FeO, dd KMnO4, dd S, CaO, Ba(OH)2, KOH. Vit phng trnh phn ng nu c. Cu 2: Bng phng php ho hc hy trnh by phng php nhn bit cc dung dch ring bit sau: Nhng ngy u H 2013 thi th Ha 10 HK2 Trang 9/13

K2S, K2SO3, K2SO4. Cu 3: Ho tan hon ton hn hp Mg v MgS, tc dng ht vi dung dch H 2SO4 long d thu c 2,464 lt hn hp kh Y(ktc). Cho hn hp kh Y trn i qua dung dch Pb(NO3)2 th thu c 23,9 gam kt ta mu en. a, Tnh th tch mi kh trong hn hp Y. b, Tnh khi lng mi cht trong hn hp u. Cu 4: Hon thnh cc phn ng theo s sau : FeS2 SO2 SO3 H2SO4 CuSO4 Cu Cu 5 : Bng phng php ha hc Nhn bit cc dung dch mt nhn sau: HCl, NaCl, NaOH, CuSO4 Cu 6 : Bi ton Cho 12,8g SO2 vo 250ml dung dch NaOH 1M. Vit phng trnh ho hc ca phn ng ?Tnh khi lng mui to thnh sau phn ng ? S 34 Cu 1. Hon thnh s phn ng sau: FeS H2S SO2 KHSO3 K2SO3 KOH KClO3 Cl2 CaOCl2 CaCO3 CaBr2 AgBr Br2 Cu 2. Hy nhn bit cc dung dch sau ch bng mt thuc th duy nht : MgCl2, Ba(NO3)2, K2CO3, NaCl, H2SO4 Cu 3. Nu hin tng v gii thch khi cho: a. a ra nh sng ng nghim ng dung dch bc clorua c nh thm t git dung dch qu tm ? b. Dn kh H2S qua dung dch KMnO4 v H2SO4 ? Cu 4. Chia 15,57 gam hn hp X ( gm Al, Fe v Ag ) thnh hai phn bng nhau. Phn I: Tc dng va vi H2SO4 long d to ra 3,528 lt H2 ( ktc ) v 3,24 gam cht rn. Phn II: Tc dng va vi m gam dung dch H2SO4 98% c nng thu c V lt kh SO2 ( ktc ) a. Tnh % khi lng cc cht trong X ? b. Tnh m v V ? c. Tnh khi lng qung pirit ( cha 85% FeS2 cn li l tp cht tr ) cn dng iu ch lng H2SO4 trn bit hiu sut ca c qu trnh l 80 % ? S 35 Vit phng trnh ha hc ca cc phn ng sau ( ghi r iu kin , nu c): a- F2 + NaOH c. H2O2 + KMnO4 + H2SO4 b- FeO + H2SO4 (c, nng) d. K2Cr2O7 + HCl Cu 2: (2 im) Nhn bit cc dung dch HCl, AgNO3, NaOH, Na2SO4, Ba(OH)2 bng phng php ha hc Cu 3: (3 im) a- Mui amoni hidrocacbonat nu ng trong chai h s dn dn bay hi ht. Nu y kn chai v np thm CO2 vo th mui ny c bo qun tt.Vn dng nguyn l Le Chatelier gii thch. b- Phi ng nghim cha bc clorua ngoi nh sng. Nh tip vo vi git qu tm. Hin tng g xy ra, gii thch v vit phng trnh minh ha. c- Cho kh clo i qua dung dch natri bromua, ta thy dung dch c mu vng. Tip tc cho kh clo i qua, ta thy dung dch mt mu. Ly vi git dung dch sau th nghim nh ln giy qu tm th giy qu ha . Hy gii thch cc hin tng v vit cc phng trnh ha hc. Cu 4: (3 im) Ha tan hon ton 1,44g kim loi ha tr 2 bng 250ml dung dch H2SO4 0,3M (axit long). Sau phn ng phi dng ht 60ml dung dch NaOH 0,5M trung ha ht axit d. nh khi lng mol nguyn t v tn kim loi. Ha tan mt lng kim loi nh trn trong 149,07g axit sunfuric c , nng, th thy thot ra kh c mi trng thi. Tnh nng % ca dung dch mui thu c sau phn ng Cu 1: ( 2 im) S 36 Cu 1: Hon thnh s chuyn ho sau ( ghi iu kin nu c ) (2im) HCl FeCl2 FeCl3 MnO2 Cl2 H2SO4 SO2 SO3 Na2SO4 Cu 2: Nu hin tng v gii thch bng phng trnh cc trng hp sau : (2im) a. Cho giy qu tm t vo bnh cha kh clo. b. Cho kh H2S lin tc n d vo dung dch KMnO4/H2SO4. Cu 3: Ch dng thm mt cht th hy nhn bit cc l mt nhn ng cc dung dch sau: Na2SO4 , H2SO4, NaCl, BaCl2, (2im) Cu 4: Cho m gam hn hp A gm Mg v Cu tc dng vi dung dch HCl d thu c 2,24lt kh khng mu ( kc) . Cng lng hn hp trn em ho tan trong dung dch H2SO4 c,d thu c 4,48lt kh SO2 ( kc ) a.Xc nh khi lng mi kim loi trong hn hp ban u ? ( 2im) b.Dn lng SO2 trn i qua 300ml dung dch NaOH 1M thu c dung dch B. Xc nh nng mol/l cc cht c trong dung dch B ( V = const ) ( 1im ) c.Xt phn ng : 2 SO2 (K) + O2 (K) 2 SO3 (K) H < 0. thu lng kh SO3 ti u , v l thuyt ta c th dng nhng bin php no ? ( 1im ) Nhng ngy u H 2013 thi th Ha 10 HK2 Trang 10/13

 S 37 Cu 1: (3 im)Ha tan hon ton 1,44g kim loi ha tr 2 bng 250ml dung dch H2SO4 0,3M (axitlong). Sau phn ng phi dng ht 60ml dung dch NaOH 0,5M trung ha ht axit d. nh khi lng mol nguyn t v tn kim loi. Ha tan mt lng kim loi nh trn trong 149,07g axit sunfuric c , nng, th thy thot ra kh c mi trng thi. Tnh nng % ca dung dch mui thu c sau phn ng. Cu 2: Cho t t 2,24 lt (ktc) kh Cl2 vo 100ml dd hn hp gm NaF 1M , NaBr 1M v NaI 1,5M. Ly dd. Cu 3: Ha tan hon ton 36,8 gam hn hp X gm Fe, Fe3O4 v CuO trong dd HCl d thu c dd A v 2,24 lt kh H2 (ktc). Dn kh H2S d vo dd A thu c 12,8 gam kt ta. Nu cho hn hp X trn tc dng vi axit H2SO4 c, nng, d th to ra V lt kh SO2 (sn phm kh duy nht v o ktc). Cc p/ xy ra hon ton. Vit cc phng trnh ha hc ca cc p/ xy ra v xc nh cht kh, cht oxi ha trong cc p/ . Tnh gi tr ca V Cu 4: Cho t t 2,24 lt (ktc) kh Cl2 vo 100ml dd hn hp gm NaF 1M , NaBr 2M v NaI 1M. Ly dd mui sau p/ hon ton cho tc dng vi dd AgNO3 d ta thu c m (g) kt ta. Bit cc p/ xy ra hon ton, hy S 38 Cu 1: (3 im)Ha tan hon ton 1,44g kim loi ha tr 2 bng 250ml dung dch H2SO4 0,3M (axitlong). Sau phn ng phi dng ht 60ml dung dch NaOH 0,5M trung ha ht axit d. nh khi lng mol nguyn t v tn kim loi. Ha tan mt lng kim loi nh trn trong 149,07g axit sunfuric c , nng, th thy thot ra kh c mi trng thi. Tnh nng % ca dung dch mui thu c sau phn ng. Cu 2: Cho t t 2,24 lt (ktc) kh Cl2 vo 100ml dd hn hp gm NaF 1M , NaBr 1M v NaI 1,5M. Ly dd. Cu 3: Ha tan hon ton 36,8 gam hn hp X gm Fe, Fe3O4 v CuO trong dd HCl d thu c dd A v 2,24 lt kh H2 (ktc). Dn kh H2S d vo dd A thu c 12,8 gam kt ta. Nu cho hn hp X trn tc dng vi axit H2SO4 c, nng, d th to ra V lt kh SO2 (sn phm kh duy nht v o ktc). Cc p/ xy ra hon ton. Vit cc phng trnh ha hc ca cc p/ xy ra v xc nh cht kh, cht oxi ha trong cc p/ . Tnh gi tr ca V Cu 4: Cho t t 2,24 lt (ktc) kh Cl2 vo 100ml dd hn hp gm NaF 1M , NaBr 2M v NaI 1M. Ly dd mui sau p/ hon ton cho tc dng vi dd AgNO3 d ta thu c m (g) kt ta. Bit cc p/ xy ra hon ton, hy S 39 Cu 1. Dn 5,6 lt SO2 ktc vo 800ml dung dch NaOH 0,5M c dung dch X. a. Vit cc phng trnh phn ng c th xy ra b. Tnh khi lng ca tng cht tan trong X. Cu 2. Ho tan hon ton 17,6g hn hp X gm Cu v Fe vo H2SO4 c, nng thu c 8,96 lt SO2 ktc( sn phm kh duy nht). a. Vit phng trnh phn ng xy ra b. Tnh % khi lng tng kim loi trong X Cu 3. Cho 50g hn hp gm FeO, Fe3O4 v Fe2O3 tc dng vi dung dch H2SO4 long d. c dung dch Y. C cn dung dch Y c 38g FeSO4 v mg Fe2(SO4)3. a. Vit phng trnh phn ng xy ra b. Tnh m Cu 4: Cho 1,5 hn hp Al, Mg vo dung dch HCl d thu c 1,68 lt kh (ktc). a. Vit cc phng trnh phn ng xy ra. b. Tnh phn trm khi lng mi kim loi. Cu 5: Hon thnh chui p : FeS2SO2SO3 H2SO4Na2SO4 NaCl NaNO3. Cu 6 : C 4 l mt nhn ng 4 dung dch sau: HCl, NaNO3, NaCl. Bng phng php ha hc hy nhn bit 4 dung dch trn. S 40 Bi 1 Ho tan hon ton m gam hn hp gm FeO, Fe2O3, Fe3O4 bng dung dch H2SO4 c, nng, d thu c 448ml kh SO2 ktc v 32g mui sunfat khan. Vit cc phng trnh phn ng xy ra v tnh m. Bi 2 Trong mt bnh kn cha hn hp kh gm SO2 v O2 c t khi so vi hiro l 24, sau khi un nng vi cht xc tc thch hp v a v nhit ban u th thu c mt hn hp kh mi c t khi so vi hiro l 30. a). Tnh thnh phn phn trm theo th tch ca cc hn hp kh trc v sau phn ng. b). Tnh hiu sut ca phn ng. Bi 3 Vit cc phng trnh phn ng nhit phn cc cht sau: KMnO4; KClO3 (xc tc MnO2); HgO v H2O2. Bi 4 Trong cc hp cht i vi oxi v hiro th nguyn t X u c ho tr cao nht bng nhau. Trong hp cht ca X vi hiro th X chim 75% khi lng. Xc nh v tr ca X trong bng tun hon. Bi 5 Ch c dng mt thuc th thch hp, hy trnh by phng php ho hc nhn bit cc l mt nhn ng cc kh sau: Cl2; NH3; HCl v O2. Bi 6 Trong cng nghip amoniac c tng hp theo phng trnh phn ng sau: N2 + 3H2 < 2NH3 (H = 92kJ) Hy nu cc bin php k thut lm tng hiu sut ca phn ng tng hp amoniac theo phng trnh phn ng trn. Bi 7 Ho tan hon ton a mol mt kim loi R ( ho tr n khng i ) bng dung dch c cha a mol H2SO4 th va thu c 31,2g mui sunfat ca kim loi R v mt lng kh X. Lng kh X ny va lm mt mu 500ml dung dch Br2 0,2M. Xc nh kim loi M. Bi 8 Ho tan ht m gam hn hp X gm Na2CO3 v K2SO3 bng Vml dung dch HCl 7,3% th va thu c 0,896lt hn hp kh Y ktc. Hn hp Y c t khi so vi hiro l 29,5. Nhng ngy u H 2013 thi th Ha 10 HK2 Trang 11/13

a). Vit cc phng trnh phn ng xy ra. b). Tnh m v V, bit khi lng ring ca dung dch HCl 7,3% l d = 1,25g/ml.

Xin thy hy dy cho con ti

(Trch th ca Tng thng M Abraham Lincoln gi thy hiu trng ngi trng ni con trai ng theo hc.) Con ti s phi hc tt c nhng iu ny, rng khng phi tt c mi ngi u cng bng, tt c mi ngi u chn tht. Nhng xin thy hy dy cho chu bit c mi mt k v li ta gp trn ng ph th u s c mt con ngi chnh trc; c mi mt chnh tr gia ch k, ta s c mt nh lnh o tn tm. Bi hc ny s mt nhiu thi gian, ti bit; nhng xin thy hy dy cho chu bit rng mt ng la kim c do cng sc lao ng ca mnh b ra cn qu gi hn nhiu so vi nm la nht c trn h ph... Xin thy dy cho chu bit cch chp nhn tht bi v cch tn hng nim vui chin thng. Xin hy dy chu trnh xa s k. Xin dy chu bit c b quyt ca nim vui chin thng thm lng. Dy cho chu bit c rng nhng k hay bt nt ngi khc nht li l nhng k d b nh bi nht... Xin hy gip chu nhn thy th gii k diu ca sch... nhng cng cho chu c thi gian lng l suy t v s b n mun thu ca cuc sng: n chim tung cnh trn bu tri, n ong bay ln trong nh nng v nhng bng hoa n ngt bn i xanh. Xin gip chu c nim tin vo kin ring ca bn thn, d tt c mi ngi xung quanh u cho rng kin hon ton sai lm... Xin hy dy cho chu bit cch i x du dng vi nhng ngi ha nh v cng rn vi nhng k th bo. Xin to cho chu sc mnh khng chy theo m ng khi tt c mi ngi u ch bit chy theo thi th. Xin hy dy cho chu bit phi lng nghe tt c mi ngi nhng cng xin thy dy cho chu bit cn phi sng lc nhng g nghe c qua mt tm li chn l chu ch n nhn nhng g tt p... Xin hy dy cho chu bit cch mm ci khi bun b, xin hy dy chu bit rng khng c s xu h trong nhng git nc mt. Xin hy dy cho chu bit ch giu nhng k ym th v cn trng trc s ngt ngo y cm by. Xin hy dy cho chu rng c th bn c bp v tr tu cho ngi ra gi cao nht, nhng khng bao gi cho php ai ra gi mua tri tim v tm hn mnh... Xin hy dy cho chu ngonh tai lm ng trc mt m ng ang go tht... v ng thng ngi bo v nhng g chu cho l ng... Xin hy i x du dng vi chu nhng ng vut ve nung chiu chu bi v ch c s th thch ca la mi ti luyn nn c nhng thanh st cng rn. Xin hy dy cho chu bit rng chu phi lun c nim tin tuyt i vo bn thn, bi v khi chu s lun c nim tin tuyt i vo nhn loi. y qu l mt yu cu qu ln, ti bit, tha thy. Nhng xin thy c gng ht sc mnh, nu c vy, con trai ti qu tht l mt cu b hnh phc v may mn.

Tnh bn v tnh yu
Tnh bn l khi bn chi vi mt ngi nhng bn li thy no nhit chng km g mt cuc lin hoan. Tnh yu l khi bn i do gia ph ng ngi nhng li cm thy nh ch c 2 ngi. Tnh bn l khi cch xa, cuc sng ca bn vn nh khi ngi gn. Tnh yu l khi cch xa, cuc sng ca bn khng h nh c, d bn vn "cm thy" ngi lun bn bn. Tnh bn l khi bn hy vng ngi lm c nhng iu tt nht. Tnh yu l khi bn thn bn c gng mang n cho ngi nhng iu tt nht. Tnh bn l khi bn "khng nh" bn s c gng bn cnh ngi khi ngi cn. Tnh yu l khi bn sn sng b tt c bn cnh ngi . Tnh bn c th tn ti d khng c tnh yu trong . Nhng tnh yu khng th tn ti nu khng c tnh bn trong .

Hoa hng tng m

Anh dng li tim bn hoa gi hoa tng m qua ng bu in. M anh sng cch ch anh khong 300km. Khi bc ra khi xe, anh thy mt b gi ang ng khc bn va h. Anh n v hi n sao li khc. - Chu mun mua mt hoa hng tng m chu - n nc n - nhng chu ch c 75 xu trong khi gi mt hoa hng n 2 la. Anh mm ci v ni vi n: Nhng ngy u H 2013 thi th Ha 10 HK2 Trang 12/13

- n y, ch s mua cho chu. Anh lin mua hoa cho c b v t mt b hng gi cho m anh. Xong xui, anh hi c b c cn i nh xe v nh khng. N vui mng nhn anh v tr li: - D, ch cho chu i nh n nh m chu. Ri n ch ng cho anh n mt ngha trang, ni c mt phn m va mi p. N ch ngi m v ni: - y l nh ca m chu. Ni xong, n n cn t nhnh hoa hng ln m. Tc th, anh quay li tim bn hoa, hy b dch v gi hoa va ri v mua mt b hng tht p. Sut m , anh li mt mch 300km v nh m anh trao tn tay b b hoa.

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