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9. (C, H, O) mach thang, ch cha mot loai nhom chc tac dung va het 152,5 ml dung dch NaOH 25%. Co d=1,28 g/ml. Sau khi sau phan ng xay ra hoan toan thu c dung dch A cha mot muoi cua axit hu c, hai ru n chc, no ong ang lien tiep e trung hoa hoan toan dung dch A can dung 255ml dung dch HCl 4M. Co can dung dch sau khi trung hoa th thu c hohp hai ru co t khoi so vi H2 la 26,5 va 78,67 gam hon hp muoi khan. Hp chat X co cong thc cau tao la: A. C3H7OOC-C4H8-COOC2H5 B. C3H7OOC- C2H4-COO C2H5 C. CH3OOC- C3H6-COO C3H7 D. C2H5OOC-C4H8-COOC2H5 10. A l mt cht hu c mch thng cha mt loi nhm chc m mui natri ca n khi em nung vi vi ti xt th thu c kh metan. B l mt ru mch h m khi cho a mol B tc dng ht vi Na th thu c a/2 mol H2. a mol B lm mt mu va dung dch c ha tan a mol Br2. t a mol B thu c 3a mol CO2. A tc dng B th thu c mt hp cht hu c a chc X. X l cht no? a) CH3COOCH2CH2CH2OOCCH3 b) CH3CH2CH2OOCCH2COOCH2CH2CH3 c) CH3COOCH2CHCHOOCCH3 d) CH2CHCH2OOCCH2COOCH2CHCH2 11.Hn hp X gm hai este no,n chc,mch h.t chy hon ton mt lng X cn dng va 3,976 lt kh O2 (ktc),thu c 6,38 gam CO2.Mt khc,X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l: A.C2H4O2 v C5H10O2 B.C2H4O2 v C3H6O2 C.C3H4O2 v C4H6O2 D.C3H6O2 v C4H8O2 12. Cho hn hp X gm 2 este n chc mch h tc dng ht vi dung dch KOH thu -c 1,96 gam mt mui v 1,02 gam hn hp 2 anehit no, ng ng k tip. Cho l-ng 2 anehit ny tc dng ht vi bc nitrat trong dung dch NH3 th thu -c 4,32 gam Ag. Cng thc ca 2 este trong X l
A. B. C. D.
13. Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng este ho (hiu sut l 80%) th s gam este thu c l A. 34,20. B. 27,36. C. 22,80. D. 18,24. 14. Cho 0,05 mol hn hp X gm 2 este n chc tc dng va vi 120ml dd NaOH 0.5M, thu c hh Y gm 2 mui v mt ancol . Mt khc, khi t chy han tan 0,1 mol hh X trn thu c 14,08g CO2 . CTCT ca este l :
B. D.
15. Cho 3.52g mt este no, n chc X phn ng va ht vi 40ml dd NaOH 1M, thu c hai cht hu c A v B. Nu t chy 0.6g cht B th thu c 1.32g CO2. Khi oxi ha trong iu kin thch hp, cht B cho sn phm l 1 andehit Y. Xc nh CTCT ca X, A, B, Y. Gi s hiu sut phn ng l 100%. 16. un nng hn hp gm 30g axit axetic v 34,5g etanol vi H2SO4 m c. Tnh lng este thu c v
hiu sut phn ng. Bit nhit trn, phn ng co hng s cn bng l 1/4. A. 17,776g ; 40,4% B. 17,776g ; 66,67% C. 44g ; 40,4% D. 44g ; 40,4%
17. X tc dng c NaOH, nhit v cho phn ng trng gng. 3.7g X c th tch bng th tch 1.6g O2 (cng iu
kin).t 1g X thu VCO2 > 0.7L(ktc). S ng phn tp cht, mch h ca X: A. 4 B.5 C.6 D.7 18. Este (E) c to bi ancol a chc (X) v axit n chc (Y). Bit 8.9g (E) tc dng va vi 0.3 lt dd
NaOH 0.1M thu c ancol (X) v 9.18 g mui ca axit Y. T khi hi ca (E) so vi heli bng 222.5. (E) l: A. glixerol tripanmitat (tripanmitin) B. glixerol tristearat (tristearin) C. glixerol trioleat (triolein) D. glixerol trioxalat
19. Thc hin phn ng este ho 1 mol CH3COOH v 1 mol ru etylic, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (theo axit) khi tin hnh este ho 1 mol CH3COOH th cn s mol C2H5OH l bao nhiu (cho bit cc phn ng este ho thc hin cng nhit ) A.2,925 B.0,456 C.2,412 D.0,342
20. Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gitr ca m l (cho H = 1, C = 12, O = 16)
A. 10,12. B. 6,48. C. 8,10. D. 16,20.
21.Thy phn han tan Este X trng mi trng axit thu c hai cht hu c A v B. Oxi ha A cho ra B. X khng th l cht no sau y:
A. Etyl axetat B.Vinyl axetat C. Etylen oxalat D. Isopropyl propionat 22. X l este khng no, mch h, t khi so vi Oxi l 3,125. X phng ha X c mt andehit v mt mui ca axit hu c. X c th c bao nhiu cng thc cu to: A.4 B.5 C.6 D.7 23. X l 1 este n chc. Thu phn 0,01 mol X vi 300ml dd NaOH 0,1M n khi p.ng xy ra hon ton thu c dd Y. C cn Y thu c phn hi (ch c nc) v 2,38g cht rn khan. S CTCT c th c ca X l: A.1 B. 2 C. 3 D.4
24. un a gam hn hp hai cht X v Y l ng phn cu to ca nhau vi 200ml dd NaOH 1M (va ) n khi phn ng hon ton thu c 15g hh hai mui ca hai axit no, n chc, l ng ng k tip nhau v mt ancol. Gi tr ca a v CTCT ca X,Y ln lt l: a. 12g CH3COOH v HCOOCH3 b. 14,8g CH3COOCH3 v CH3CH2COOH c. 14,8g HCOOC2H5 v CH3COOCH3 d. 9g CH3COOH v HCOOCH3 25. 100 ml dd cha 2 este A, B n chc c nng mol chung l 0,8M. Cho hn hp ny tc dng vi 150 ml dd NaOH 1M. Sau phn ng thu c 2 mui hu c C v D c khi lng l 10,46g (t l MC : MD = 41 :65) ng thi thu c 1 ancol E c khi lng l 2,9g ancol ny khng bn bin thnh anehyt sau phn ng phi dng 200 ml dd HCl 0,2M trung ho NaOH d. Xc nh CTCT ca A, B. 26. E l hn hp ca hai ng phn este c to ra t axit no , n chc v ancol no , n chc. cng nhit v p sut 1 lt hi E nng gp 2 ln 1 lt kh CO2 . Thu phn 35,2(g) E bng 4 lt dd NaOH 0,2 M c dd A . C cn dd A c 44,6 (g) cht rn khan. Xc nh CTCT v tnh % s mol ca 2 este. A. HCOOC3H7 ( 75%) , CH3COOC2H5 ( 25%) B. HCOOC3H7 (87,5%) , C2H5 COOCH3 (12,5 %) C. A v B ng D. A v B sai 27. 1.Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol cn cho phn ng chy) 139,9 C, p sut trong bnh lc ny l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l: A. C4H8O2 B. C3H6O2 C. CH2O2 D. C2H4O2 28.Cho 0,1 mol mt este G1 tc dng va vi 100ml dung dch NaOH 2M, thu c hh 2 mui ca 2 axit hu c mch h G2, G3 u n chc v 6.2g mt ancol G4. Axit hu c G2 no khng tham gia phn ng trng gng. Axit G3 khng no, ch cha lin kt i C=C, c mch cacbon phn nhnh. t chy ht hn hp hai mui thu c trn to ra Na2CO3, CO2 v H2O. Cho hon ton CO2, H2O sinh ra i qua bnh ng Ca(OH)2 d, thu c 100g kt ta. Cng thc cu to ca ancol G4 v este G1 l: A.CH2OH-CH2OH v CH3-COO-CH2-CH2-OOC-(CH3)C=CH2 3
Ngun: Tp th hc sinh 12 A 5 L Hng Phong 2010 - 2011
B.CH2OH-CHOH-CH2OH v CH3-COO-CH2-CH2-OCO-CH3 C.CH2OH-CH2OH v CH3-COO-CH2-CH2-OCO-CH=CH2 D.CH2OH-CH2OH v CH3-CH2-COO-CH2-CH2-OCO-CH=CH2 29. Thc hin phn ng eate ha 1mol CH3COOH v 1 mol C2H5OH c hng s cn bng K= 2,25 . Vy nu tin hnh phn ng este ha 1 mol CH3COOH v a mol C2H5OH t hiu sut l 90% th gi tr a cn l : a. 5,4 b. 4,5 c. 3,6 d. 2,4 30. Hai cht X,Y c cng cng thc phn t C2H4O2.Cht X phn ng c vi kim loi Na v tham gia phn ng trng bc.Cht Y phn ng c vi kim loi Na v ha tan c CaCO3.Cng thc ca X ,Y ln lt l. A.CH3COOH,HOCH2CHO B.HCOOCH3,HOCH2CHO C.HCOOCH3,CH3COOH D.HOCH2CHO,CH3COOH 31.un nng 21,8 g cht X vi 1lt dd NaOH 0,5 M thu c 24,8 g mui ca axit mt ln axit v mt ru B . nu cho lng bay hi kc chim th tch l 2.24 lt . Lng NaOH d c trung ha ht bi 2 lt dd HCl 0,1 M.Cng thc cu to ca A l: a. (HCOO)3C3H5 b.(C2H5COO)5C3H5 c.(CH3COO)3C3H5 d.(CH3COO)2C2H4 e.kt qu khc 32. Chia hn hp X gm 2 axit hu c n chc, mch h, l ng ng k tip thnh 3 phn bng nhau. Phn 1 tc dng vi dung dch NaHCO3 d thu c 2,24 lt kh CO2 (ktc). Phn 2 t chy hon ton X thu c 6,272 lt CO2 (ktc). Phn 3 tc dng va vi etylen glycol thu c m gam hn hp 3 este khng cha nhm chc khc. Tm m. 33. Cho 300ml dd NaOH 1M tc dng va vi hn hp X gm 2 cht hu c n chc, sau phn ng thu hn hp Y gm 1 ancol v 2 mui ca 2 axit cacboxilic. Cho ancol trn tc dng vi Na d, thu 0.896 l H2 0 C, 3 atm. Hn hp X cha: A. 1 ancol v 1 este B.1 axit v 1 este C.2 este cng gc ancol D. 1 axit v 1 ancol 34. X l este ca 1 Axit n chc v mt ancol n chc. Thy phn han tan 6,6 g lng cht X dng 90 ml dd NaOH 1M, lng NaOH ny d 20% so vi lng NaOH cn dng cho phn ng. Dd sau phn ng c cn thu rn 5,7g. Cng thc X l: A. HCOOC3H7 B.HCOOC3H5 C.CH3COOC2H5 D.C2H5COOCH3 35. Cho cht hu c A ch cha 1 loi nhm chc tc dng vi 1 lt dd NaOH 0,5M thu c a gam mui v 0,1 mol
ancol. Lng NaOH d c th trung ha ht 0,5 lt dd HCl 0,4M. Cng thc tng qut ca A l: a)R-COO-R b) (R-COO)2R c) (R-COO)3R d) R(COO-R)3 36. un 1 lng d axit axetic vi 13,8g ancol etylic ( c H2SO4 c lm xc tc). n khi phn ng dng li thu c 11g este. Hiu sut phn ng este ha l: a)75% b)62,5% c)60% d)41,67% 37. Mt este A ( khng c chc khc) c to bi axit no, mch thng (c 2 nhm cacboxyl) vi glixerol. %
khi lng C trong A l 56,03%. Axit to thnh A l : a/ Axt Oxalic b/Axt Malonic c/ Axt Aipic d/ Axt Succinic 38.t 0,2 mol hn hp gm etyl axetat v metyl acrylat thu c CO2 v H2O trong : s mol CO2 s mol H2O =0,08 mol. Nu un 0,2 mol hn hp X trn vi 400ml dung dch KOH 0,75M v c cn thu c m gam cht rn khan. m c gi tr l : A. 26,4 gam B. 26,64 gam C. 20,56 gam D. 26,16 gam 39. Axit acrylic tc dng vi ancol n chc X thu este Y. un nng 7,74g este Y vi dd HCl ( gi s H+ trong dd axit khng ng k). Trung ha dd thu c cn 200ml dd NaOH 1,5M. X phng ha lng este cn li phi dng thm mt th tch gp i NaOH ni trn. X c tn l: A. ancol anlylic B. ancol metylic C. ancol propylic D. ancol etylic 40. Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l A. CH3OOC(CH2)2COOC2H5. B. CH3COO(CH2)2COOC2H5. C. CH3COO(CH2)2OOCC2H5. D. CH3OOCCH2COOC3H7. 41. Lm bay hi 15.3gam mt este A thu c mt th tch ca 4.2gam nito cng iu kin. S cng thc 4
Ngun: Tp th hc sinh 12 A 5 L Hng Phong 2010 - 2011
cu to c th c ca A l: A.8 B.9 C.10 D.11 42. Este ho ancol n no A v axit n no B (MA = MB) thu este D tho iu kin: tng phn t lng ca A, B gp 2
ln khi lng cacbon c trong MD. Nhn xt no sau y sai: A. A hn B mt nguyn t cacbon. B. Ancol A c 2 ng phn cng chc. C. B c 1 ng phn n chc khc chc. D. B + Cl2 (xt nh sng) cho sn phm hu c E c tnh axit yu hn B. 43. Cho 0.1 mol A (C8H12O5) tc dng va vi dung dch NaOK, sau c cn dung dch c 1 ancol 3 chc & 17.6g hn hp cht rn gm mui ca 2 axit n chc (s nguyn t C hn km nhau 1 C). CTCT thu gn ca A: A. (HCOO)(CH3COO)C5H7OH B. (C2H5COO)(CH3CHOO)C3H3OH C.(HCO)(C2H5COO)C4H5OH D.(CH3COO)(C2H3COO)C3H5OH 44.t a mol X l este 3 ln este ca glixerol v 3 axit n chc thu c b mol CO2 v c mol H2O, bit b-c=4a. Hiro ha m gam X cn 5,6 lt H2 ktc thu c 32 gam X. Nu un m gam X vi dung dch NaOH va thu c bao nhiu gam mui khan? A. 35,5 gam B. 39,6 gam C. 30,2 gam D. 40,6 gam 45. X phng ho hon ton 26.4g este etyl oxalat bng dd NaOH, thu hh ancol A, B. Ete ho hh ancol tren thu
m (g) hh 3 ete. Cho hiu sut phn ng to ete ca ancol nh v ln theo th t l 60% v 70 %. Tm m: A. 7,94 B. 5,6 C. 12 D. 9,74 46. t chy hon ton 2,76g hn hp X gm CXHYCOOH, CXHYCOOCH3 v CH3OH thu c 2,688 lt CO2 (ktc) v 1,8g H2O . Mt khc, cho 2,76g X phn ng va vi 30 ml dd NaOH 1M, thu c 0,96g CH3OH. Cng thc ca CXHYCOOCH3 l : A. C2H5COOCH3 B. CH3COOCH3 C. C2H3COOCH3 D. C3H5COOCH3
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