Amin va anilin Bi tp t lun. Cu 1: Vit cng thc cu to c th c ca cc amin c cng thc phn t C3H9N, C4H11N. Gi tn v ch r bc ca chng.

Cu 2: Vit phn ng gia cc cp hp cht sau. CH3NH2 v HCl, CH3NH2 v H2SO4 (t l mol l 1:1), CH3NH2 v H2SO4 (t l mol l 2:1), CH3NH2 v CH3COOH. Cu 3: So snh tnh baz ca cc cht sau: NaOH, NH3, CH3NH2, C2H5NH2, C6H5NH2 Cu 4: Nhn bit cc cht ng trong cc bnh mt nhn sau: a. phenol, anilin, benzen, styren b. anilin, metyl amin, axit axetic, anehit axetic Cu 5: t chy hon ton 1,605 gam hp cht A thu c 4,62 gam CO2 v 1,215 gam H2O v 168 Cm3 N2 (ltc). a. Tnh thnh phn % cc nguyn t. b. Bit 3,21 gam hp cht A phn ng ht 30 ml dung dch HCl 1M. Vit cng thc cu to c th c ca A. Bit A l ng ng ca anilin. Cu 6: Hn hp A gm 4 hp cht hu c no, n chc l ng phn ca nhau. Bn hp cht u d phn ng vi dung dch HCl. Phn t mi cht u cha cc nguyn t C, H, N (chim 23,7% v khi lng). Vit cng thc cu to ca 4 hp cht v tnh khi lng hn hp A, bit t chy hn hp A cho 4,48 lit N2 (ktc). Cu 7: (i hc khi A-2006). t chy hon ton 1,18 gam amin n chc B bng mt lng khng kh va . Dn ton b hn hp kh sau phn ng vo bnh ng dung dch Ca(OH) 2 d, c 6 gam kt ta v c 9,632 lt kh (ktc) duy nht thot ra khi bnh. a. Tm cng thc phn t ca B b. Vit cc cng thc cu to c th c ca B v gi tn. (bit khng kh c 20% O 2 v 80% N2 v th tch) Bi tp trc nghim. Cu 8: Cho cc cu sau cu no sai. a. Cc amin c tnh baz

a. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng v dung dch HCl li thu c phenol. b. axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. c. dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to c cho tc dng vi dung dch NaOH li thu c natri phenolat. d. anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH l thu c anilin

Cu 10: So snh tnh baz ca cc cht sau: CH3NH2, (CH3)2 NH, NH3 a. CH3NH2 < (CH3)2 NH < NH3 b. NH3 < CH3NH2 < (CH3)2 NH c. NH3 < (CH3)2 NH < CH3NH2 d. (CH3)2 NH < CH3NH2 < NH3 Cu 11: So snh tnh baz ca cc cht sau: CH3NH2, C2H5NH2, NH3, C6H5NH2 a. CH3NH2 < C2H5NH2 < NH3 < C6H5NH2 b. NH3 < C6H5NH2 < CH3NH2 < C2H5NH2 c. C6H5NH2 < NH3 < CH3NH2 < C2H5NH2 d. C6H5NH2 < NH3 < C2H5NH2< CH3NH2 Cu 12: (i hc khi B-2007) Dy gm cc cht u lm giy qy tm m chuyn sang mu xanh l: a. metyl amin, amoniac, natri axetat b. anilin, amoniac, natri hiroxit c. amoni clorua, metyl amin, natri hiroxit d. anilin, metyl amin, amoniac. Cu 13: Mt amin c cng thc phn t l C3H9N s ng phn ca amin l: a. 2 b. 3 c. 4 d. 5 Cu 14: ( thi tt nghip- 2007) S ng phn amin bc 1 ng vi cng thc phn t l C3H9N l. a. 4 b. 3 c. 5 d. 2 Cu 15: Mt amin c cng thc phn t l C4H11N, s ng phn ca amin l: a. 7 b. 8 c. 9 d. 10 Cu 16: Mt amin c cng thc phn t l C4H11N, s ng phn amin bc I l: a. 3 b. 4 c. 5 d. 6 Cu 17: (Cao ng khi A-2009) S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l a. 4 b. 5. c. 2 d. 3. Cu 18: (i hc khi A-2009) Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l a. 5. b. 8. c. 7.

b. Cc amin u l xanh qy tm c. amin l nhng hp cht hu c c cu thnh bng cch thay th mt hay nhiu nguyn t hiro trong phn t amoniac bi mt hay nhiu gc hyrocacbon. d. bc ca amin l s nguyn t H trong amonic b thay th bi gc hyrocacbon. Cu 9: ( i hc khi A-2007) Pht biu khng ng l.

d. 4. Cu 19: Cho cc cu sau cu no khng ng: a. Cc amin u c tnh baz. b. Tnh baz ca tt c cc amin u mnh hn NH3. c. Anilin c tnh baz yu hn NH 3. d. Tt c cc amin n chc u cha mt s l nguyn t H trong phn t. Cu 21: S d anilin c tnh baz yu hn NH3 l do: a. Nhm NH2 cn mt cp electron cha lin kt. b. phn t khi ca anilin ln hn NH2. c. Nhm NH2 c tc dng y electron v pha bng benzen lm gim mt electron ca nguyn t N. d. Gc phnyl c nh hng lm gim mt electron ca nguyn t N. Cu 21b: (i hc khi A-2009) Pht biu no sau y l ng? a. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. b. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. c. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. d. Benzen lm mt mu nc brom nhit thng. Cu 22: Cho s phn ng sau:
HNO3, xt H2SO4 dac H A + C6H5NH2 vy cng B + thc phn t ca A l: a. C6H6 b. c. C6H5CH3 d. tt C6H5NH3Cl c u sai

ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? a. 4. b. 5. c. 3. d. 6. Cu 26: t chy hon ton hn hp hai amin bc mt mch h, no, n chc, k tip nhau trong cng dy ng ng thu c CO2 v H2O vi t l s mol nCO2:nH2O = 1: 2. Hai amin c cng thc phn t ln lt l a. C2H5NH2 v C3H7NH2 b. CH3NH2 v C2H5NH2 c. C3H7NH2 v C4H9NH2 d. C4H9NH2 v C5H11NH2 Cu 27: t chy hon ton hn hp 2 amin no n chc, l ng ng lin tip thu c 2,24 lit kh CO2 (ktc) v 3,6 gam H2O. Cng thc phn t ca 2 amin l: a. CH3NH2 v C2H5NH2 b. C2H5NH2 v C3H7NH2 c. C3H7NH2 v C4H9NH2 d. Tt c u sai. Cu 28: Khi t chy hon ton mt amin n chc X, ngi ta thu c 10,125 gam H2O v 8,4 lit kh CO2 v 1,4 lit N2 (ktc). Cng thc phn t ca amin l: a. C4H11N b. C2H7N c. C3H9N d. C5H13N Cu 29: Khi cho 13,95 gam anilin tc dng hon ton vi 0,2 lit dung dch HCl 1M th khi lng ca mui phenylamoniclorua thu c l a. 25,9 b. 20,25 c. 19,425 d. 27,15 Cu 30: ( thi tt nghip -2007) Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l. a. 7,65 b. 0,85 c. 8,10 d. 8,15 gam gam gam gam Cu 31: t chy hon ton m gam mt amin X bng mt lng khng kh va thu c 17,6 gam CO2 v 12,6 gam H2O v 69,44 lit N2 (ktc). Gi thit khng kh ch gm N2 v O2, trong oxi chim 20% th tch khng kh . Vy X c cng thc l. a. C4H11N b. C2H7N c. C3H9N d. CH5N Cu 32: t chy hon ton 1,18 gam amin n chc B bng mt lng khng kh va , dn ton b hn hp kh sau phn ng vo bnh Ca(OH)2 d, c 6 gam kt ta v c 9,632 lit kh (dktc) duy nht thot ra khi bnh. Xc nh cng thc phn t ca B a. C4H11N b. C2H7N c. C3H9N d. CH5N Cu 33: (i hc khi A-2007) Khi t chy hon ton mt amin n chc X, thu c 8,4 lit kh CO2, 1,4 lit kh N2 (cc th tch kh o iu kin tiu chun) v 10,125 gam H2O. Cng thc phn t ca X l. a. C3H7N b. C3H9N c. C4H9N d. C2H7N Cu 34: (Cao ng khi A-2007)

Cu 23: nhn bit cc cht: CH3NH2, C6H5NH2, C6H5OH, CH3COOH trong cc bnh mt nhn ngi ta dng. a. dung dch HCl, v qy tm b. qy tm v dung dch Br2 c. dung dch NaOH v dung dch d. Tt c u ng. Cu 24: (i hc khi B-2007) C 3 cht lng benzen, anilin, stiren ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l. a. dung b. giy c. dung dch d. nc dch qy phenolphtalein brom NaOH Cu 25: (i hc khi A-2009) C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin Br2

 trung ha 25 gam dung dch mt amin n chc X nng 12,4 % cn dng 100 ml dung dch HCl 1M. Cng thc phn t ca X l. a. CH5N b. C2H7N c. C3H7N d. C3H5N Cu 35: (Cao ng khi A-2008) Cho dy cc cht: Phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi dung dch NaOH l. a. 3 b. 4 c. 1 d. 2 Cu 36: (Cao ng khi A-2008) Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y thu c 9,55 gam mui khan. S cng thc cu to tng ng vi phn t ca X l. a. 5 b. 4 c. 3 d. 2 Cu 37: (i hc khi B-2008) Cht phn ng c vi dung dch FeCl3 cho kt ta l. a. b. c. d. CH3NH2 CH3COOH CH3OH CH3COOCH3 Cu 38: (i hc khi B-2009) Ngi ta iu ch anilin bng s sau: H 2 SO4dac , HNO3dac Benzen nitrobenzen Fe + HCl ,t anilin.
O

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l a. 111,6 gam. b. 55,8 gam. c. 93,0 gam. d. 186,0 gam. I. Trc nghim l thuyt: Cu 1: 1: Cng thc ca amin cha 15,05% khi lng nit l cng thc no sau? A. C2H5NH2 B. (CH3)2NH C. C6H5NH2 D. (CH3)3N Cu 2: Cng thc phn t C3H9N ng vi bao nhiu ng phn? A. 5 B. 4 C. 3 D. 2 Cu 3: Cho amin c cu to: CH3-CH(CH3)-NH2 . Chn tn gi khng ng? A. Prop-1-ylamin B. Propan-2-amin C. isoproylamin D. Prop-2-ylamin Cu 4: Tn gi ng C6H5NH2 ng? A. Benzyl amoni B. Phenyl amoni C. Hexylamin D. Anilin Cu 5: Hp cht hu c X mch h cha cc nguyn t C, H, N trong c 23,72% khi lng N. X tc dng vi HCl theo t l mol 1:1. Chn cu pht biu sai? A. X l hp cht amin. B. Cu to ca X l amin no, n chc C. Nu cng thc X l CxHyNz th z = 1 D. Nu cng thc X l CxHyNz th : 12x - y = 45 Cu 6: Pht biu no sau y khng ng? A. Amin c cu to bng cch thay th H ca amoniac bng 1 hay nhiu gc H-C.

B. Bc ca amin l bc ca nguyn t cacbon lin kt vi nhm amin. C. Ty thuc vo gc H-C, c th phn bit thnh amin thnh amin no, cha no v thm. D. Amin c t 2 nguyn t cacbon trong phn t bt u xut hin ng phn. Cu 7: Amin no di y l amin bc 2? A. CH3-CH2NH2 B. CH3-CHNH2-CH3 C. CH3-NH-CH3 D. CH3-NCH3-CH2-CH3 Cu 8: Cng thc no di y l cng thc chung ca dy ng ng amin thm (cha 1 vng bezen) n chc bc nht? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 Cu 9: Tn gi cc amin no sau y l khng ng? A. CH3-NH-CH3 imetylamin B. CH3-CH2-CH2NH2 n-propylamin C. CH3CH(CH3)-NH2 isopropylamin D. C6H5NH2 alanin Cu 10: Amin no di y c 4 ng phn cu to?A. C2H7N B. C3H9N C. C4H11N D. C5H13N Cu 11: Pht biu no sau y v tnh cht vt l ca amin l khng ng? A. Metyl-, etyl-, imetyl-, trimetylamin l nhng cht kh, d tan trong nc. B. Cc amin kh c mi tng t amoniac, c. C. Anilin l cht lng, kh tan trong nc, mu en. D. tan ca amin gim dn khi s nguyn t cacbon trong phn t tng. Cu 12: Cc gii thch v quan h cu trc, tnh cht no sau y khng hp l? A. Do c cp electron t do trn nguyn t N m amin c tnh baz. B. Do nhm NH2- y e nn anilin d tham gia vo phn ng th vo nhn thm hn v u tin v tr o- v pC. Tnh baz ca amin cng mnh khi mt electron trn nguyn t N cng ln. D. Vi amin R-NH2, gc R ht electron lm tng mnh ca tnh baz v ngc li. Cu 13: Nhn xt no di y khng ng? A. Phenol l axit cn anilin l baz. B. Dd phenol lm qu tm ha cn dd anilin lm qu tm ha xanh. C. Phenol v anilin u d tham gia phn ng th v u to kt ta trng vi dd brom. D. Phenol v anilin u kh tham gia phn ng cng v u to hp cht vng no khi cng vi hiro. Cu 14: S d anilin c tnh baz yu hn NH 3 l do yu t no? A. Nhm NH2- cn 1 cp electron t do cha tham gia lin kt. B. Nhm NH2- c tc dng y electron v pha vng benzen lm gim mt electron ca N. C. Gc phenyl c nh hng lm gim mt electron ca nguyn t N. D. Phn t khi ca anilin ln hn so vi NH3 Cu 15: Hy ch ra iu sai trong cc iu sau? A. Cc amin u c tnh baz B. Tnh baz ca anilin yu hn NH3 C. Amin tc dng vi axit cho ra mui D. Amin l hp cht hu c c tnh cht lng tnh

Cu 16: Dd etylamin tc dng vi dd nc ca cht no sau y? A. NaOH B. NH3 C. NaCl D. FeCl3 v H2SO4 Cu 17: Hp cht no di y c tnh baz yu nht? A. Anilin B. Metylamin C. Amoniac D. imetylamin Cu 18: Cht no di y c tnh baz mnh nht? A. NH3 B. CH3CONH2 C. CH3CH2CH2OH D. CH3CH2NH2 Cu 19: Sp xp cc cht sau y theo tnh baz gim dn? (1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH (5) NaOH (6) NH3 A. 1>3>5>4>2>6 B. 6>4>3>5>1>2 C. 5>4>2>1>3>6 D. 5>4>2>6>1>3 Cu 20: Phn ng no di y khng th hin tnh baz ca amin? A. CH3NH2 + H2O CH3NH3+ + OHB. C6H5NH2 + HCl C6H5NH3Cl C. Fe3+ + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3+ D. CH3NH2 + HNO2 CH3OH + N2 + H2O Cu 21: Dd no di y khng lm qu tm i mu? A. C6H5NH2 B. NH3 C. CH3CH2NH2 D. CH3NHCH2CH3 Cu 22: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. FeCl3 + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH3Cl C. C6H5NH2 + 2Br2 3,5-Br2-C6H3NH2 + 2HBr D. C6H5NO2 + 3Fe +7HCl C6H5NH3Cl + 3FeCl2 + 2H2O Cu 23: Phng trnh ha hc no sau y khng ng? A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4 B. CH3NH2 + O2 CO2 + N2 + H2O C. C6H5NH2 + 3Br2 2,4,6-Br3C6H2NH3Br + 2HBr D. C6H5NO2 + 3Fe +6HCl C6H5NH2 + 3FeCl2 + 2H2O Cu 24: Dd etylamin khng tc dng vi cht no sau y? A. axit HCl B. dd CuCl2 D. Cu(OH)2 s C. dd HNO3 Cu 25: Pht biu no sai? A. Anilin l baz yu hn NH 3 v nh hng ht electron ca nhn ln nhm NH2- bng hiu ng lin hp. B. Anilin khng lm i mu giy qu tm. C. Anilin t tan trong nc v gc C6H5- k nc. D. Nh tnh baz, anilin tc dng vi dd Brom. Cu 26: Dng nc brm khng phn bit c 2 cht trong cc cp no sau y? A. dd anilin v dd NH3 B.Anilin v xiclohexylamin C. Anilin v phenol D. Anilin v benzen. Cu 27: Cc hin tng no sau y m t khng chnh xc? A. Nhng qu tm vo dd etylamin thy qu tm chuyn sang xanh. B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng. C. Nh vi git nc brm vo ng nghim ng dd anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dd imetylamin thy xut hin mu xanh.

Cu 28: Khng th dng thuc th trong dy no sau y phn bit cht lng: phenol, anilin, benzen? A. Dd Brm B. dd HCl v dd NaOH C. dd HCl v dd brm D. dd NaOH v dd brm Cu 29: tinh ch anilin t hn hp: phenol, anilin, benzen cch thc hin no sau y l ng? A. Ha tan dd HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit. B. Ha tan dd Brm d, lc ly kt ta, dehalogen ha thu c anilin. C. Ha tan NaOH d v chit ly phn tan v thi CO 2 vo sau n d thu c anilin tinh khit. D. Dng NaOH tch phenol, sau dng brm tch anilin ra khi benzen. Cu 30: tinh ch anilin t hn hp: phenol, anilin, benzen cch thc hin no sau y l ng? A. Ha tan dd HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit. B. Ha tan dd Brm d, lc ly kt ta, dehalogen ha thu c anilin. C. Ha tan NaOH d v chit ly phn tan v thi CO 2 vo sau n d thu c anilin tinh khit. D. Dng NaOH tch phenol, sau dng brm tch anilin ra khi benzen Cu 31: Khng th dng thuc th trong dy no sau y phn bit cht lng: phenol, anilin, benzen? A. Dd Brm B. dd HCl v dd NaOH C. dd HCl v dd brm D. dd NaOH v dd brm Cu 32: Cc hin tng no sau y m t khng chnh xc? A. Nhng qu tm vo dd etylamin thy qu tm chuyn sang xanh. B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng. C. Nh vi git nc brm vo ng nghim ng dd anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dd imetylamin thy xut hin mu xanh. Cu 33: Dng nc brm khng phn bit c 2 cht trong cc cp no sau y? A. dd anilin v dd NH3 B. Anilin v xiclohexylamin C. Anilin v phenol D. Anilin v benzen. Cu 34: Pht biu no sai? A. Anilin l baz yu hn NH 3 v nh hng ht electron ca nhn ln nhm NH2- bng hiu ng lin hp. B. Anilin khng lm i mu giy qu tm. C. Anilin t tan trong nc v gc C6H5- k nc. D. Nh tnh baz, anilin tc dng vi dd Brom. Cu 35: phn bit phenol, anilin, benzen, stiren ngi ta s dng ln lt cc thuc th no sau? A. Qu tm, brm B. dd NaOH v brom C. brm v qu tm D. dd HCl v qu tm Cu 36: Ancol v amin no sau y cng bc? a. (CH3)2CHOH v (CH3)2CHNH2 b. (CH3)3COH v (CH3)3CNH2 c. C6H5NHCH3 v C6H5CH(OH)CH3 d. (C6H5)2NH v C6H5CH2OH Cu 37: Cho dung dch etylamin (c mi khai) tc dng va vi cht X thy c kh bay ra v dung dch sau phn ng c mi thm ca ru. X l:

a. CH3I b. CH3OH c. HNO2 d. HONH2 Cu 38: Cho s phn ng: X C6H6 Y anilin. X v Y tng ng l: a. xiclohexan, C6H5-CH3 b. C2H2, C6H5-NO2 c. CH4, C6H5-NO2 d. C2H2, C6H5-CH3 Cu 39: Khi t chy cc ng ng ca metylamin thu c CO2 v H2O th t l v th tch K=VCO 2:VH2O bin i nh th no theo s lng nguyn t cacbon trong phn t: a. 0,4<K<1 b. 0,25<K<1 c. 0,75<K<1 d. 1<K<1,5 Cu 40: Pht biu no di y v aminoaxit l khng ng? A. Aminoaxit l HCHC tp phc, phn t chc ng thi nhm amino v nhm cacboxyl. B. Hp cht H2NCOOH l aminoaxit n gin nht. C. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc (H3N+RCOO-) D. Thng thng dng ion lng cc l dng tn ti chnh ca aminoaxit trong dung dch. Cu 41: Tn gi ca aminoaxit no di y l ng? A. H2N-CH2-COOH (glixerin) B. CH3-CH(NH2)-COOH (anilin) C. CH3-CH(CH3)-CH(NH2)-COOH (valin) D. HOOC-(CH2)2-CH(NH2)-COOH (axit glutaric) Cu 42: C3H7O2N c my ng phn aminoaxit (Vi nhm amin bc nht)? A.5 B. 2 C. 3 D. 4 Cu 43: Khng nh no sau y khng ng v tnh cht vt l ca aminoaxit? A. Tt c u cht rn. B. Tt c u l tinh th, mu trng. C. Tt c u tan tt trong nc. D. Tt c u c nhit nng chy cao. Cu 44: Aminoaxetic khng th phn ng vi: A. Ancol B. Cu(OH)2 C. axit nitric D. Ba(OH)2 Cu 45: Cho cc dy chuyn ha : +NaOH +HCl Glixin A X; Glixin B Y X v Y ln lt l cht no? A. u l ClH3NCH2COONa B. ClH3NCH2COOH v ClH3NCH2COONa C. ClH3NCH2COONa v H2NCH2COONa D. ClH3NCH2COOH v H2NCH2COONa Cu 46: Cho cc cht sau: (X 1) C6H5NH2; (X2)CH3NH2 ; (X3) H2NCH2COOH; (X4) OOCCH2CH2CH(NH2)COOH (X5) H2NCH2CH2CH2CH2CH(NH2)COOH. Dd no lm qu tm ha xanh? A. X1, X2, X5 B. X2, X3,X4 C. X2, X5 D. X1, X5, X4 Cu 47: Dd no di y lm qu tm ha ? (1) NH2CH2COOH ; (2) Cl-NH3+-CH2COOH ; (3) H3N+CH2COO- ; (4) H2N(CH2)2CH(NH2)COOH; (5) HOOCCH2CH2CH(NH2)COOH A. (3) B. (2) C. (2), (5) D. (1), (4) Cu 48: A l HCHC c cng thc phn t C 5H11O2N. un A vi dd NaOH thu c mt hh cht c CTPT C2H4O2NNa v cht hu c B. Cho hi ca B qua CuO/t 0

thu c cht C bn trong dd hn hp ca AgNO 3 v NH3. CTCT ca A l: A. CH3(CH2)4NO2 B. H2NCH2COOCH2CH2CH3 C. H2NCH2COOCH(CH3)2 D. H2NCH2CH2COOC2H5 Cu 49: Tn gi no sau y l ca peptit H2NCH2CONHCH(CH3)CONHCH2COOH? A. Gly-ala-gly B. Gly-gly-ala C. Ala-gly-gly D. Ala-gly-ala Cu 50: Trong bn ng nghim mt nhn cha ring bit tng dd: glyxin, lng trng trng, tinh bt, x phng. Thuc th phn bit ra mi dd l? A. Qu tm, dd it, Cu(OH)2. B. Qu tm, NaOH, Cu(OH)2 C. HCl, dd it, Cu(OH)2. D. HCl, dd it, NaOH. Cu 51: Cu no sau y khng ng? A. Khi nh axit HNO3 c vo lng trng trng thy xut hin mu vng. B. Phn t cc protein gm cc mch di polipeptit to nn. C. Protein rt t tan trong nc v d tan khi un nng. D. Khi cho Cu(OH)2 v lng trng trng thy xut hin mu tm xanh. Cu 52: Trong cc cht sau Cu, HCl, C 2H5OH, KOH, Na2SO3, CH3OH/ kh HCl. Axit aminoaxxetic tc dng c vi nhng cht no? A. Tt c cc cht. B. HCl, KOH, CH3OH/ kh HCl. C. C2H5OH, KOH, Na2SO3, CH3OH/ kh HCl D. Cu, HCl, KOH, Na2SO3, CH3OH/ kh HCl. Cu 53: Khi thy phn hon ton policapromit (policaproic) trong dd NaOH nng d thu c sn phm no di y? A. H2N(CH2)5COOH B. H2N(CH2)6COONa C. H2N(CH2)5COONa D. H2N(CH2)6COOH Cu 54: Protein (protein) c th c m t nh th no? A. Cht polime trng hp. B. Cht polieste. NaOH +HCl C. Cht polime ng trng hp. D. Cht polime ngng t (trng ngng). Cu 55: Pht biu no di y v protein l khng ng? A. Protein l nhng polipeptit cao phn t (phn t khi t vi chc ngn n vi triu v.C) B. Protein c vai tr l nn tng v cu trc v chc nng ca mi s sng. C. Protein n gin l nhng protein c to thnh ch t cc gc v -aminoaxit. D. Protein phc tp l nhng protein c to thnh t protein n gin v lipit, gluxit, axitnucleic,... Cu 56: Hp cht C3H7O2N tc dng c vi NaOH, H2SO4 v lm mt mu dd brom. CTCT ca hp cht? A. CH3CH(NH2)COOH B. H2NCH2CH2COOH C. CH2=CHCOONH4 D.CH2=CH-CH2COONH4 Cu 57: Cho qu tm vo mi dd di y, dd lm qu tm ha xanh l? A. CH3COOH B. H2NCH2COOH C. H2NCH2(NH2)COOH D. HOOC-CH2-CH2-CH(NH2)-COOH
+

Cu58: Tn gi ca hp cht C6H5-CH2-CH(NH2)-COOH nh th no? A. Axitaminophenyl propionic. B. Axit -amino-3-phenyl propionic. C. Phenylalanin D. Axit 2-amino-3-phenyl propanoic. Cu 59: Cho dd qu tm vo 2 dd sau: (X) H 2N-CH2COOH; (Y) HOOC-CH(NH2)-CH2-COOH. Hin tng xy ra? A. X v Y khng i mu qu tm. B. X lm qu chuyn xanh, Y ha . C. X khng lm qu i mu, Y lm qu ha . D. X, Y lm qu ha Cu 60: Sn phm thu c khi thy phn hon ton t enang trong dd HCl d l: A. ClH3N(CH2)5COOH B.ClH3N(CH2)6COOH C. H2N(CH2)5COOH D. H2N(CH2)6COOH Cu 62: C cc pht biu sau v protein, Pht biu no ng. 1. Protein l hp cht cao phn t thin nhin c cu trc phc tp. 2. Protein ch c trong c th ngi v ng vt. 3. C th ngi v ng vt khng th tng hp c protein t nhng cht v c m ch tng hp c t cc aminoaxit. 4. Protein bn i vi nhit, i vi axit v vi kim. A. 1, 2 B. 2, 3 C. 1, 3 D. 3, 4 Cu 63: Axit -aminopropionic tc dng c vi tt c cc cht trong dy A. HCl, NaOH, C2H5OH c mt HCl, K2SO4, H2NCH2COOH B. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, Cu C. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH D. HCl, NaOH, CH3OH c mt HCl, H2NCH2COOH, NaCl Cu 64: Pht biu no sau y l khng ng v enzim? A. Hu ht cc enzim c bn cht protin B. Enzim c kh nng lm xc tc cho qu trnh ha hc C. Mi enzim xc tc cho rt nhiu chuyn ha khc nhau D. Tc phn ng nh xc tc enzim thng nhanh hn n 109- 1011 ln Cu 65: Thy phn n cng protein n cng ta thu c cc cht no? A. Cc aminoaxit B. aminoaxit C. Hn hp cc aminoaxit D. Cc chui polipeptit Cu 66: M t hin tng no di y l khng chnh xc? A. Nh vi git axit nitric c vo dd lng trng trng thy kt ta mu vng. B. Trn ln lng trng trng, dd NaOH v mt t CuSO 4 thy xut hin mu c trng . C. un nng dd lng trng trng thy hin tng ng t li, tch ra khi dd. D. t chy mt mu lng trng trng thy xut hin mi kht nh mi tc chy. Cu 67: Tn gi ca Sn phm v cht phn ng trong phn ng polime ha no sau y l ng? A. nH2N(CH2)5COOH (-HN(CH2)5CO-)n + n H2O

Axit -aminocaproic t nilon-6 B. nH2N(CH2)5COOH (-HN(CH2)6CO-)n + n H2O Axit -aminoenantoic t enang C. nH2N(CH2)6COOH (-HN(CH2)6CO-)n + n H2O Axit 7-aminoheptanoic t nilon-7 D. B, C ng Cu 68: ng dng no sau y ca aminoaxit l khng ng? A. Aminoaxit thin nhin (hu ht l -aminoaxit) l c s kin to protein trong c th sng. B. Mui inatriglutamat l gia v cho thc n (gi l bt ngt hay m chnh) C. Axitglutanic l thuc b thn kinh, methionin l thuc b gan. D. Cc aminoaxit (nhm NH2 v s 6, 7...) l nguyn liu sn xut t nilon. Cu 69: Pht biu no sau y khng ng: A. Nhng hp cht hnh thnh bng cch ngng t 2 hay nhiu -aminoaxit c gi l peptit. B. Phn t c 2 nhm -CO-NH- c gi l i peptit, 3 nhm -CO-NH- c gi l tri peptit C. Cc peptit c t 10 n 50 n v aminoaxit cu thnh c gi l polipeptit. D. Trong mi phn t peptit, cc aminoaxit c sp xp theo mt th t xc nh. Cu 70: Pht biu no di y v protein l khng ng? A. Protein l nhng polipeptit cao phn t (phn t khi t vi chc ngn n vi triu v.C) B. Protein c vai tr l nn tng v cu trc v chc nng ca mi s sng. C. Protein n gin l nhng protein c to thnh ch t cc gc v -aminoaxit. D. Protein phc tp l nhng protein c to thnh t protein n gin v lipit, gluxit, axitnucleic,... Cu 71: Cc cht no sau y lng tnh? a) Metylaxetat b) amoni axetat c) glixin d) metyl amoni fomiat e) metyl amoni nitrat f) axit glutamic g) natriaxetat A. c, f B. b, d, e, f C. b, c, d, f D. a, b, c, d, f, g Cu 72: tiu ho casein (protein c trong sa) trc ht phi: a. thu phn cc lin kt glucozit b. thu phn cc lin kt peptit c. thu phn cc lin kt este d. kh cc cu ni isunfua Cu 73: nhn bt dung dch cc cht: Glixin, tinh bt, lng trng trng, ta tin hnh theo trnh t: a. dng qu tm, dng dd iot b. Dng dd iot, dng dd HNO3 c. dng qu tm, dng dd HNO3 d. dng Cu(OH)2, dng dd HNO3 Cu 74: HCHC X c cng thc C3H9O2N. Cho X phn ng vi dd NaOH, un nh thu c mui Y v kh Z lm xanh giy qu tm m. Cho Y tc dng vi NaOH rn, un nng c CH4, X c cng thc cu to no sau y? a. C2H5-COO-NH4 b. CH3-COO-NH4 c. CH3-COO-H3NCH3 d. b v c ng

Cu 75: Mt hchc X c cng thc C3H7O2N. X phn ng vi dung dch brom, X tc dng vi dd NaOH v HCl. Cht hu c X c cng thc cu to: a. H2N CH = CH COOH b. CH2 = CH COONH4 c. NH2 CH2 CH2 COOH d. a v b ng. II. Trc nghim tnh ton: Cu 1: Phn tch nh lng 0,15 gam hp cht hu c X thy t l khi lng cc nguyn t C:H:O:N = 4,8:1:6,4:2,8. Nu phn tch nh lng m gam cht X th t l khi lng cc nguyn t C:H:O: N l bao nhiu? A. 4 : 1 : 6 : 2 B. 2,4 : 0,5 : 3,2 : 1,4 C. 1,2 : 1 : 1,6 : 2,8 D. 1,2 : 1,5 : 1,6 : 0,7 Cu 2: Ngi ta iu ch anilin bng cch nitro ha 500 g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu? Bit hiu sut phn ng mi giai on l 78%, 80%, 97,5%. A. 346,7 g B. 362,7 g C. 463,4 g D. 358,7 g Cu 3: Mt HCHC X c t l khi lng C:H:O:N = 9: 1,75: 8: 3,5 tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 nhng ng phn ny c kh nng lm mt mu dd Br 2. Cng thc phn t ca X v cng thc cu to ca X, Y ln lt l: A. C3H7O2N; H2N-C2H4-COOH; H2N-CH2-COO-CH3 B. C3H7O2N; H2N-C2H4-COOH; CH2=CH-COONH4 C. C2H5O2N; H2N-CH2-COOH; CH3-CH2-NO2 D. C3H5O2N; H2N-C2H2-COOH; CHC-COONH4 Cu 4: Este A c iu ch t amino axit B(ch cha C, H, O, N) v ru metylic. t chy hon ton 8,9 gam este A thu c 13,2 gam CO2, 6,3 gam H2O v 1,12 lt N2(o ktc). Bit CTPT ca A trng vi CTGN. CTCT ca A l: A. NH2 - CH2 -COOCH3 B. NH2- CH(CH3)- COOCH3 C.CH3- CH(NH2)-COOCH3 D.NH2-CH(NH2) - COOCH3 Cu 5: Cht A c phn trm khi lng cc nguyn t C,H, O, N ln lt l 32,00%, 6,67%, 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng vi dd NaOH va tc dng vi dd HCl. CTCT ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 6: Cht A c phn trm cc nguyn t C,H, N, O ln lt l 40,45%, 7,86%, 15,73%, cn li l O. Khi lng mol phn t ca A nh hn 100g/mol. A va tc dng vi dd NaOH va tc dng vi dd HCl, c ngun gc t thin nhin. Cng thc cu to ca A l: A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 7: (X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l: A. CH3(CH2)4NO2 B. NH2-CH2COO-CH2-CH2-CH3 C. NH-CH2-COO=CH(CH2)3 D.H2N-CH2-CH2-OOC2H5

Cu 8: Dung dch NH3 1M c = 0,43% . Hng s KB ca dung dch NH3 l: A. 1,85.10-5 B. 1,75.10-5 C. 1,6.10-5 D. 1,9.10-6 Cu 9: Mt hn hp gm 2 amin n chc no k tip nhau trong dy ng ng. Ly 21,4g hn hp cho vo 250ml dung dch FeCl3 (c d) thu c mt kt ta c khi lng bng khi lng hn hp trn. Loi b kt te ru thm t t dung dch AgNO3 v cho n khi phn ng kt thc th phi dng 1lt dd agNO 3 1,5M. Cng thc phn t ca 2 amin trn l: a. CH3NH2 v C2H5NH2 b. C2H5NH2 v C3H7NH2 c. C3H7NH2 v C4H9NH2 d. tt c u sai Cu 10: t chy hon ton m g mt amin X bng lng khng kh va thu c 17,6g CO 2 v 12,6g hi nc v 69,44 lt N2. Gi thit khng kh ch gm nit v oxi trong oxi chim 80% th tch. Cc th tch o ktc. Amin X c cng thc phn t l: a. C2H5NH2 b. C3H7NH2 c. CH3NH2 d. C4H9NH2 Cu 11: C 2 amin bc 1: A (ng ng ca anilin) v B ( ng ng ca metylamin). t chy hon ton 3,21g amin A sinh ra kh CO2, hi nc v 336cm3 kh nit (ktc). Khi t chy hon ton amin B cho VCO 2:VH2O = 2: 3. Cng thc phn t ca 2 amin l: a. CH3C6H4NH2 v CH3CH2CH2NH2 b. C2H5C6H4NH2 v CH3CH2CH2NH2 c. CH3C6H4NH2 v CH3(CH2)4NH2 d. a v b ng Cu 12: Hp cht X l mt - aminoaxit. Cho 0,01 mol X tc dng vi 80ml dung dch HCl 0,125M. Sau em c cn thu c 1,835g mui. Phn t khi ca X bng bao nhiu ? a. 145vC b. 149vC c. 147vC d. 189vC Cu 13: un 100ml dung dch mt aminoaxit 0,2M tc dng va vi 80ml dd NaOH 0,25M. Sau phn ng ngi ta chng kh dung dch thu c 2,5g mui khan. Mt khc, li ly 100g dung dch aminoaxit ni trn c nng 20,6% phn ng va vi 400ml dung dch HCl 0,5M. CTPT ca aminoaxit: a. H2NCH2COOH b. H2NCH2CH2COOH c. H2N(CH2)3COOH d. a v c ng Cu 14: Cho hh M gm 2 amin no n chc bc 1 X v Y. ly 2,28g hh trn tc dng vi 300ml dung dch HCl th thu c 4,47g mui. S mol ca hai amin trong hh bng nhau. Nng mol ca dung dch HCl v tn ca X, Y ln lt l: a. 0,2M; metylamin; etylamin b. 0,06M; metylamin; etylamin c. 0,2M; etylamin; propylamin d. 0,03M; etylamin; propylamin Cu 15: t chy hon ton mt amin thm X thu c 3,08g CO2, 0,99g H2O v 336ml N2 (ktc). trung ho 0,1mol X cn 600ml dd HCl 0,5M. Cng thc phn t ca X l cng thc no? a. C7H11N b. C7H10N c. C7H11N3 d. C7H10N2 Cu 16: t chy hon ton mg hh 3 amin X, y, Z bng mt lng khng kh va (cha 1/5 th tch l oxi, cn

li l nit) thu c 26,4g CO 2, 18,9g H2O v 104,16 lt N2 (ktc). Gi tr ca m? a. 12g b. 13,5g c. 16g d. 14,72g Cu 17: Cho 3 hchc X, Y, z u cha cc nguyn t C, H, N. Thnh phn phn trm khi lng ca N trong phn t X, Y , Z ln lt l: 45,16%; 23,73%; 15,05%. Bit c X, Y, Z khi tc dng vi axit clohiric u cho mui amoni c dng cng thc R NH3Cl. Cng thc X, Y (mch thng), Z ln lt l: a. CH3 NH2, C2H5 NH2, C6H5 NH2 b. C2H5 NH2, CH3 CH2 CH2 NH2, C6H5 NH2 c. CH3 NH2, CH3 CH2 CH2 NH2, C6H5 NH2 d. CH3 NH2, CH3 CH2 CH2 NH2, C6H5 CH2 NH2 Cu 18: Mt mui X c cng thc C 3H10O3N2. ly 14,64g X cho phn ng ht vi 120ml dung dch KOH 1M. C cn dd sau phn ng thu c phn hi v cht rn. Trong phn hi c mt cht hu c Y (bc 1). Trong phn rn ch l mt cht v c. Cng thc phn t ca Y l: a. C2H5NH2 b. C3H7OH c. C3H7NH2 d. CH3NH2 Cu 19: Hn hp X gm 2 amino axit no bc 1 Y v Z. Y cha 2 nhm axit, mt nhm amino; Z cha mt nhm axit, mt nhm amino. MY/MZ = 1,96. t chy 1mol Y hoc 1 mol Z th s mol CO 2 thu c nh hn 6. Cng thc cu to ca hai amino axit l: a. H2NCH2 CH(COOH) CH 2 COOH v H2NCH2 COOH b. H2NCH2 CH(COOH) CH2 COOH v H2N [CH2]2 COOH c. H2N CH(COOH) CH 2 COOH v H2NCH2 COOH d. H2N CH(COOH) CH2 COOH v H2N [CH2]2 COOH Cu 20: t chy 1mol amino axit H2N [CH2]n COOH phi cn s mol oxi l: a. (2n+3)/2 b. (6n+3)/2 c. (6n+3)/4 d. (2n+3)/4 Cu 21: Hp cht hu c X ch cha hai loi nhm chc amino v cacboxyl. Cho 100ml dung dch X 0,3M phn ng va vi 48ml dd NaOH 1,25M. Sau em c cn dung dch thu c c 5,31g mui khan. Bt X c mch cacbon khng phn nhnh v nhm NH 2 v tr alpha. CTCT ca X: a. CH3CH(NH2)COOH b. CH3C(NH2)(COOH)2 c. CH3CH2C(NH2)(COOH)2 d. CH3CH2CH(NH2)COOH Cu 22: Thc hin phn ng este gia amino axit X v ancol CH3OH thu c este Y c t khi hi so vi khng kh bng 3,069. CTCT ca X: a. H2N-CH2-COOH b. H2N-CH2-CH2-COOH c. CH2-CH(NH2)-COOH d. H2N-(CH2)3-COOH Cu 23: t chy ht a mol mt amino axit X n chc bng oxi va ri ngng t ht hi nc c 2,5 mol hh CO2 v N2. CTPT ca X: a. C5H11NO2 b. C3H7N2O4 c. C3H7NO2 d. C2H5NO2 Cu 24: Ly 14,6g mt ipeptit to ra t glixin v alanin cho tc dng va vi dung dch HCl 1M. Th tch dung dch HCl tham gia phn ng:

a. 0,1 lit b. 0,2 lt c. 0,3 lt d. 0,4 lt BI TP AMIN-AMINO AXIT-PROTEIN Phn I : T lun Bi 1: Vit cng thc cu to v gi tn cc amin c cng thc phn t di y bng danh php gc-chc v danh php thay th: (a) CH5N, (b) C2H7N, (c) C3H9N, (d) C4H11N, (e) C6H7N (amin thm). Bi 2: So snh v gii thch tnh cht vt l ca hai cp cht cho di y: Cht C2H5OH C2H5NH2 Cht C6H5OH C6H5NH2 Ts 78,3 oC 16,6 oC t nc o o 43 C -6,2 C tan tan tt tan tt t tan t tan Bi 3: Sp xp cc hp cht ng phn etylimetylamin (A), n-butylamin (B), v ietylamin (C) theo trt t gim dn ca nhit si v gii thch. Bi 4: t chy amin A bng lng khng kh va (cha 80% N2 v 20% O2 v th tch), thu c 0,528 gam CO2 ; 0,54 gam H2O v 2,5536 lit N2 (ktc). Xc nh cng thc cu to v vit phn ng th hin tnh baz ca A. Bi 5: ngh phng php ha hc (c vit cc PTHH minh ha) (a) ra l ng anilin, (b) kh mi tanh ca c trc khi nu. Bit rng mi tanh ca cc amin (nhiu nht l trimetylamin) v mt s tp cht khc. Bi 6: Cho 1,52 gam hn hp hai amin no, n chc, mch h tc dng va vi 200 ml dung dch HCl, thu c 2,98 gam mui. (a) tnh nng mol ca dung dch HCl. (b) xc nh cng thc cu to ca hai amin, bit rng hn hp hai amin c trn vi s mol bng nhau. Bi 7: Khi chng ct than , c mt phn cht lng b tch ra. l dung dch long ca amoniac, phenol, anilin (dung dch A) v mt lng khng ng k cc cht khc. trung ha 1 lit dung dch A cn 100ml dung dch HCl 1M. Mt lit dung dch A cng b trung ha bi 10 ml dung dch NaOH 1M. Mt khc ly 1 lit dung dch A phn ng vi dung dch Br2 d th thu c 19,81 gam kt ta. Hy xc nh nng mol ca amoniac, phenol v anilin c trong dung dch A, gi thit cc phn ng xy ra hon ton. Bi 8: Ha tan hn hp gm anilin, phenol, axit axetic v ancol etylic trong n-hexan, ri chia dung dch thnh 4 phn bng nhau. Phn th nht tc dng vi dung dch brom d cho 9,91 gam kt ta. trung ha phn 3 cn 18,5ml NaOH 11% (d=1,1 g/ml). Thi kh hiro clorua qua phn th t, sau phn ng tch ra c 1,072 gam mui. Vit phn ng v xc nh thnh phn phn trm khi lng mi cht trong hn hp, bit rng cc phn ng xy ra hon ton. Bi 9: Cho chuyn ha sau: C7H16
A H N O H 2S O
3 4

C l2 ,a s 1 :1

N H

Fe

(a) Vit phng trnh v hon thnh dy chuyn ha trn, bit B l ng phn para-. (b) So snh mnh tnh baz ca cc nhm chc trong F. Bi 10: C ba dung dch NH4HCO3, NaAlO2, C6H5ONa, v ba cht lng C2H5OH, C6H6, C6H5NH2 ng trong 6 l

mt nhn. Nu ch dng dung dch HCl th c th nhn bit c cht no trong s 6 cht trn. Bi 11: (a) Trnh by phng php phn bit cc cht lng ng trong cc bnh mt nhn cha benzen, anilin v phenol. (b) Trnh by phng php tch ring cc cht ra khi hn hp gm benzen, phenol v anilin. Bi 12: Ti sao nhit thng cc amino axit u l cht rn v u tan tt trong nc? So snh v gii thch nhit nng chy ca cc hp cht hu c H2NCH2COOH, n-C4H9NH2, C2H5COOH, n-C4H9OH. Bi 13: a) cho nhn xt chung v tnh cht ha hc ca amino axit. b) Vit PTHH ca phn ng xy ra khi cho glyxin ln lt tc dng vi: i) dung dch HCl, ii) dung dch NaOH, iii) CH3OH c mt HCl m c, iv) NaNO2 trong dung dch HCl. Bi 14: Hp cht hu c A cha c nguyn t C, H, O, N v c M = 89u. t chy hon ton 1 mol A thu c 3 mol CO2 v 0,5 mol N2. (a) Tm cng thc phn t v vit cng thc cu to mch h ca A, bit A l hp cht lng tnh, vit phng trnh minh ha tnh cht . (b)A c lm mt mu nc brom hay khng? Nu c, hy vit phng trnh ha hc ca phn ng. Bi 15: Cho 26,1 gam hn hp G gm axit glutamic v glyxin vo 175 ml dung dch HCl 2M, thu c dung dch G1. Dung dch G1 phn ng va vi 200ml dung dch NaOH 3,5M. Vit cc PTHH ca phn ng xy ra v tnh phn trm theo khi lng ca mi amino axit c trong hn hp G. Bi 16: Hp cht A l mt -amino axit. Cho 0,01 mol A tc dng va ht vi 80ml dung dch HCl 0,125M, sau thu c 1,835 gam mui. Mt khc, khi trung ha 2,94 gam A bng dung dch NaOH va th thu c 3,82 gam mui. A c cng thc cu to mch khng phn nhnh, hy gi tn thng dng ca A, dn xut no thng c dng trong cuc sng hng ngy ? Vit phng trnh ha hc ca A vi NaNO2 trong s c mt ca axit clohiric. Bi 17: Cho 0,01 mol mt amino axit A tc dng va vi 100ml dung dch HCl 0,2M, thu c dung dch B. Dung dch ny phn ng va ht vi 100ml dung dch NaOH 0,3M thu c 2,85 gam mui. 1. Xc nh cng thc cu to v gi tn thng dng ca A. Bit rng A l mt loi amino axit thit yu mch cacbon khng phn nhnh c cha nhm amin cui mch. 2. Dung dch A trong nc c mi trng g? Ti sao? 3. Vit phng trnh ha hc ca phn ng xy ra khi cho A tc dng vi H2SO4, Ba(OH)2, C2H5OH trong HCl, NaNO2 trong HCl. Bi 18: Cho bit cu to sn phm to thnh khi un nng: (a) -amino axit, (b) -amino axit, (c) amino axit, (d) -amino axit v (e) -amino axit. Cho v d minh ha. Bi 19: A l mt -amino axit mch khng phn nhnhc khi lng phn t bng 131. Cho 1,965 gam A tc dng va vi dung dch HCl to ra 2,5125 gam mui. Cng lng A trn khi tc dng vi dung dch naOH d thy to thnh 2,295 gam mui. Xc nh cng thc cu to, gi tn A v hon thnh dy chuyn ha: NaOH A t0 B t C (poliamit) + D HCl E
o

Bi 20: Cho ma gam hn hp 2 amino axit no cha mt chc axit v mt chc amin tc dng vi 110 ml dung dch HCl 2M, thu c dung dch A. tc dng ht cc cht trong A cn dng 140ml dung dch KOH 3M. Mt khc, t chy m gam hn hp 2 amino axit trn cho sn phm chy qua dung dch NaOH d th khi lng bnh ny tng thm 32,8 gam. Bit rng khi t chy to nit dng n cht. (a) Xc nh cng thc phn t ca 2 amino axit, bit khi lng phn t ca chng l 1,37. (b) Tnh s mol mi amino axit trong hn hp ban u. Bi 21: Trnh by phng php phn bit cc dung dch mt nhn cha alanin, lysin, axit glutamic v prolin (cng thc cho di y).
N H

COOH

prolin

Bi 22: (a) Lin kt peptit l g ? (b) peptit l g ? (c) Phn bit khi nim oligopeptit v polipeptit. (d) Vit cng thc cu to v gi tn cc tripeptit c th hnh thnh t glyxin, alanin v phenylalanin (C6H5CH2CH(NH2)COOH vit tt l Phe). Bi 23: Thy phn tripeptit A ngi ta thu c 2,25 gam amino axit X c 32%C, 6,67%H v 18,67%N v khi lng, MX =75 ; 1,335 gam -amino axit Y c 40,45%C, 7,87%H v 15,73%N v khi lng, MY=89. (a) Vit cc cng thc cu to c th c ca A. (b) Tnh th tch dung dch HCl 0,5M cn dng thu phn hon ton 3,045 gam A. Bi 24: (a) Khi thu phn tng phn tetrapeptit Ala-MetGly-Val th c th thu c bao nhiu loi peptit mi ? (b) Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin, 1 mol alanin v 1 mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly, Gly-ala v tripeptit Gly-Gly-Val. Hy xc nh trnh t cc -amino axit trong A. Bi 25: Vit cc phng trnh ha hoc theo s phn ng di y :
+ N aO H x t, t , P

(D1)

(A)

(NH-(CH2)5-CO)n

(D3) Bi 26: a) Ti sao khng git qun o lm t t nilon, len, t tm bng x phng c kim cao? b) Phn bit cc khi nim (a) protein, (b) protein n gin v (c) protein phc tp. c) Xt cc phn t protein: keratin, miozin, fibroin, anbumin v hemolobin. Trong cc phn t ny, phn t no c hnh si, phn t no c dng hnh cu? Phn t no tan trong nc? v phn t no khng tan trong nc? Bi 27: Xc nh phn t khi gn ng ca mt hemoglobin (hng cu ca mu) cha 0,4% Fe (mi phn t hemoglobin ch cha 1 nguyn t Fe). (b) Khi thu phn 500 gam protein A thu c 170 gam alanin. Nu phn t khi ca A l 50.000 u th s mt xch alanin trong phn t A l bao nhiu? Phn 2: Bi tp trc nghim Cu 1: Pht biu no sau y khng ng?

+ HCl

A. Amin c cu thnh bng cch thay th mt hay nhiu nguyn t hiro ca NH3 bng mt hay nhiu gc hirocacbon. B. Tu thuc vo cu trc ca gc hirocacbon c th phn bit amin thnh amin no, cha no, thm C. A min c t hai nguyn t cacbon tr ln trong phn t bt u xut hin hin tng ng phn D. Bc amin c nh ngha theo bc ca nguyn t cacbon lin kt trc tip vi nhm chc amin Cu 2: Xt cc amin: (X) etylamin, (Y) isopropylamin, (Z) imetylamin v (T) etylimetylamin. Amin bc 2 l : A. X B. Y C. Z D. T Cu 3: Cng thc no di y l cng thc ca dy ng dng amin thm, cha mt vng bezen, n chc bc nht ? A. CnH2n-7NH2 B. CnH2n+1NH2 C. C6H5NHCnH2n+1 D. CnH2n-3NHCnH2n-4 Cu 4: ng vi cng thc phn t C 4H11N, c x ng phn amin bc nht, y ng phn amin bc 3. Gi tr x, y, z ln lt bng: A. 4, 3 v 1 B. 3, 3 v 0 C. 4, 2 v 1 D. 3, 2 v 1 Cu 5: Tn gi no sau y ng? A. 2-etylpropan-1-amin B. N-propyletanamin C. butan-3amin D. N, N-imetylpropan-2-amin Cu 6: Xt cc kh CH4, CH3Cl, HCHO v CH3NH2 th cht kh d ha lng nht l : A. CH4 B. CH3Cl C. HCHO D. CH3NH2 Cu 7: Trong cc cht di y, cht no l cht kh? A. ancol metylic B. ancol propylic C. trimetylamin D. axit propionic Cu 8: Xt cc cht: benzen (C6H6), anilin (C6H5NH2), phenol (C6H5OH) v axit benzoic (C6H5COOH). Trong bn cht ny, th cng iu kin thng, s cht tn ti trng thi lng l A. 1 B. 2 C. 3 D. 4 Cu 9: Cho bn hp cht hu c l C2H5Cl, C2H5OH, CH3COOH v CH3CH2NH2. Cht c nhit si cao th 2 trong dy trn l A. C2H5OH B. C2H5Cl C. C2H5NH2 D. CH3COOH Cu 10: Pht biu no sau y l cha chnh xc v tnh cht vt l ca amin? A. Cc amin kh c mi tng t amoniac, c. B. Anilin nguyn cht l cht lng, kh tan trong nc, mu en C. tan ca amin gim khi s nguyn t cacbon trong phn t tng D. Metyl, etyl, imetyl, trimetyl amin l nhng cht kh d tan trong nc Cu 11: Cc gii thch quan h cu trc- tnh cht no sau y khng hp l? A. Do c cp electron t do trn nguyn t N m amin c tnh baz B. Tnh baz ca amin cbg mnh khi nguyn t nit c giu electron C. Vi amin RNH2, gc R ht electron lm tng mnh tnh baz v ngc li

D. Do NH2 y electron nn anilin d tham gia phn ng th vo nhn thm hn v u tin th vo cc v tr o-, pCu 12: Trt t tng dn mnh ca tnh baz ca dy no sau y l khng ng? A. C6H5NH2<NH3 B. NH3<CH3NH2<CH3CH2NH2 C. CH3CH2NH2<CH3NHCH3 D. p-CH3C6H4NH2<p-O2NC6H4NH2 Cu 13: Phn ng no di y khng th hin tnh baz ca amin? + A. CH3NH2 + H2O CH3NH 3 + OH B. C6H5NH2 + HCl C6H5NH3Cl + C. Fe3+ + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3NH 3 D. CH3NH2 + HNO2 CH3OH + N2 + H2O Cu 14: Dung dch no di y khng lm i mu qu tm? A. C6H5NH2 B. NH3 C. C2H5NH2 D. CH3NHC2H5 Cu 15: Cho lng d anilin phn ng hon ton vi dung dch cha 0,05 mol H 2SO4 long, lng mui thu c bng: A. 7,1gam B. 14,2 gam C. 19,1 gam D. 28,4 gam Cu 16: Amin bc nht n chc X tc dng va vi lng HCl c trong 120ml dung dch HCl 0,1M thu c 0,81 gam mui X l: A. metanamin B. Etanamin C. propanamin D. benzenamin Cu 17: Cho mt hn hp A cha NH 3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng va vi 0,075 mol Br2, to kt ta trng. Lng cht NH 3, C6H5NH2 v C6H5OH ln lt bng: NH3 C6H5NH2 C6H5OH A. 0,001 mol 0,005 mol 0,02 mol B. 0,005 mol 0,005 mol 0,02 mol C. 0,005 mol 0,02 mol 0,005 mol D. 0,01 mol 0,005 mol 0,02 mol Cu 18: kh mi tanh ca cc, nn s dng loi nc no di y? A. nc ng B. nc mui C. nc gim D. nc ru Cu 19: ra sch ng nghim cn dnh anilin, ngi ta nn ra ng nghim bng dung dch no di y, trc khi ra li bng nc? A. dung dch axit mnh B. dung dch baz mnh C. dung dch mui n D. dung dch ng n Cu 20: Cho CH3NH2 tc dng vi dung dch hn hp NaNO2 v HCl th thu c sn phm hu c no sau y:A. A. CH3NH3Cl B. CH3N2Cl C. CH3OH D. CH3NO2 Cu 21: Phn ng no di y l ng? A. C2H5NH2 + HNO2 + HCl C2H5N2Cl + 2H2O 5 C B. C6H5NH2 + HNO2 + HCl 0 C6H5N2Cl + 2H2O C. C6H5NH2 + HNO2 + HCl C6H5N2Cl + 2H2O 5 C D. C6H5NH2 + HNO2 0 C6H5OH + N2 + H2O Cu 22: Cc hin tng no sau y m t khng chnh xc? A. Nhng mu qu tm vo dung dch etylamin thy qu tm chuyn sang mu xanh
o o

10

B. Phn ng gia metylamin v hiro clorua to ra khi trng C. Nh vi git dung dch brom vo ng nghim ng dung dch anilin thy c kt ta trng. D. Thm vi git phenolphtalein vo dung dch metylamin dung dch khng i mu Cu 23: t chy hon ton hn hp hai amin no, n chc, bc nht, l ng ng lin tip thu c 2,24 lit kh CO2 (ktc) v 3,6 gam H2O. Cng thc phn t ca hai amin l: A. CH3NH2 v C2H5NH2 B. C2H5NH2 v C3H7NH2 C. C3H7NH2 v C4H9NH2 D.C4H9NH2 v C5H11NH2 Cu 24: t chy hon ton m gam mt amin X bng mt lng khng kh (gi thit khng khi c 20% th tch kh O2) va thu c 17,6 gam CO 2, 12,6 gam H2O v 69,44 lit N2 (ktc). Cng thc phn t ca X l A. CH5N B. C2H7N C. C2H8N2 D. C2H7N2 Cu 25: Phn ng iu ch amin no sau y khng hp l? A. CH3I + NH3 CH3NH2 + HI B. 2C2H5I + NH3 (C2H5)2NH + 2HI C. C6H6 + NH3 C6H5NH2 + H2 t D. C6H5CN + 2H2 Ni, C6H5CH2NH2 3 / H 2 SO4 Cu 26: Cho dy chuyn ha: Benzen HNO X NH 3 Fe/HCl Y Z Cht Y l A. anilin B. Phenylamoniclorua C. P-aminoanilin D. p-nitroanilin Cu 27: Pht biu no sau y l khng ng? A. Hp cht H2NCOOH l amino axit n gin nht. B. Amino axit l hp cht hu c tp chc, phn t c ng thi nhm COOH v NH2 C. Amino axit c th tn ti dng H2NRCOOH hoc H3N+RCOOD. Thng thng dng ion lng cc l dng tn ti chnh ca amino axit Cu 28: Amino axit khng th phn ng vi loi cht no di y? A. ancol B. dung dch brom C. axit (H+) v axit nitr D. dung dch HCl, NaOH Cu 29: Xt cc dy chuyn ha: Glyxin NaOH A HCl X HCl Glyxin B NaOH Y X v Y l (bit NaOH va HCl ly d trong cc giai on phn ng) A. u l ClH3NCH2COONa B. ln lt l ClH3NCH2COOH v ClH3NCH2COONa C. ln lt l ClH3NCH2COONa v H2NCH2COONa D. ln lt l ClH3NCH2COOH v H2NCH2COONa Cu 30: Cho 0,1 mol -amino axit A (dng H2NRCOOH) phn ng ht vi HCl to ra 11,15 gam mui. A l A. Gly B. Ala C. Phe D. Val Cu 31: Cho -amino axit mch khng phn nhnh A c cng thc dng H2NR(COOH)2 phn ng ht vi 0,1 mol NaOH to 9,55 gam mui. A l A. axit 2-aminopropanioic B. axit 2-aminobutanioic C. axit 2-aminopentanioic D. axit 2-aminohexanioic
o

Cu 32: X l mt aminoaxit t nhin, 0,01 mol X tc dng va vi 0,01 mol HCl to mui Y. Lng Y sinh ra tc dng va vi 0,02 mol NaOH to 1,11 gam mui hu c Z. X l: A. axit aminoaxetic B. axit -aminopropionic C. axit aminopropionic D. axit aminoglutaric Cu 33: X l mt -aminoaxit mch khng nhnh cha mt nhm amin (NH2) v mt nhm axit (COOH). Cho 0,1 mol X tc dng vi dung dch NaOH d to ra mui hu c Y. Cho ton b lng Y ny tc dng vi HCl thu c 18,15 gam mui hu c Z. T X c th trc tip iu ch A. nilon-6 B. nilon-7 C. nilon-8 nilon-6,6 Cu 34: X l mt -amino axit mch khng nhnh. Cho 0,015 mol X tc dng va vi dung dch HCl to ra 2,5125 gam mui. Cng lng X trn khi tc dng vi dung dch NaOH ly d thy to thnh 2,295 gam mui. Cng thc ca X l A. H2N(CH2)5COOH B. H2N(CH2)3CH(NH2)COOH C. H2N(CH2)6COOH D. H2N(CH2)4CH(NH2)COOH Cu 35: Cho 0,01 mol mt aminoaxit A (mt amino axit thit yu, mch khng nhnh, c cha nhm amin cui mch) tc dng va vi 100 ml dung dch HCl 0,2M, thu c dung dch B. Dung dch ny tc dng va ht vi 100 ml dung dch NaOH 0,3M, thu c 2,85 gam mui. A l A. H2(CH2)3CH(NH2)COOH B. H2N(CH2)4CH(NH2)COOH C. (H2N)2CH(CH2)3COOH D. (H2N)2CH(CH2)4COOH Cu 36: S ng phn va tc dng vi dung dch HCl, va tc dng vi dung dch NaOH bng A. 1 B. 2 C. 3 D. 4 Cu 37: Cht hu c X c cng thc phn t l C3H7O2N. X tc dng vi dung dch NaOH, dung dch HCl nhng khng tc dng vi dung dch Br2, khng tc dng vi dung dch AgNO3/NH3 d. Cng thc cu to ca X l: A. CH3CH(NH2)COOH B. CH2=CHCOONH4 C. H2NCH2CH2COOH D. HCOONH3CH=CH2 Cu 38: C ba l mt nhn, mi l cha mt trong cc amino axit sau: glyxin, lysin v axit glutamic. Thuc th no sau y c th nhn bit c c ba dung dch trn? A. qu tm B. dung dch NaHCO 3 B. Kim loi Al D. dung dch NaNO2/HCl Cu 39: X l mt -amino axit cha mt nhm COOH v mt nhm NH2. Cho 8,9 gam X tc dng vi 200ml dung dch HCl 1M thu c dung dch Y. phn ng vi cc cht c trong Y cn dng 300 mol dung dch NaOH 1M. Cng thc ng ca X l: A. CH3CH(NH2)COOH B. (CH3)2C(NH2)COOH C. CH3CH2CH(NH2)COOH D. (CH3)2CHCH(NH2)COOH Cu 40: Amino axit Y cha mt nhm COOH v 2 nhm NH2. Cho 1 mol Y tc dng ht vi dung dch HCl v c

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cn th thu c 205 gam mui khan. Cng thc phn t ca Y l A. C4H10N2O2 B. C5H12N2O2 C. C6H14N2O2 D. C5H10N2O2 Cu 41: Amino axit X cha a nhm COOH v b nhm NH2. Cho 1 mol X tc dng ht vi dung dch HCl v c cn th thu c 169,5 gam mui khan. Cho X tc dng vi NaOH thu c 177 gam mui. Cng thc phn t ca X l A. C3H7NO2 B. C4H7NO4 C. C4H6N2O2 D. C5H7NO2 Cu 42: Dung dch metylamin c th tc dng vi cht no sau y: Na2CO3, FeCl3, H2SO4 long, CH3COOH, C6H5ONa, qu tm. A. FeCl3, H2SO4 long, CH3COOH, qu tm B. Na2CO3, FeCl3, H2SO4 long, C6H5ONa C. FeCl3, qu tm D. Na2CO3, H2SO4 long, qu tm Cu 43: Cho 0,1 mol cht X (C2H8O3N) tc dng vi dung dch cha 0,2 mol naOH un nng thu c cht kh lm xanh giy qu tm tm t v dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi tr ng ca m l A. 5,7 g B. 12,5 g C. 15 g D. 21,8 g Cu 44: Cho bit glyxin c pK1 = 2,35, pK2 = 9,78. Hi dung dch glyxin (trong nc) c A. pH >7 B. pH = 7 C. pH < 7 D. Khng xc nh, tu nng Cu 45: -aminoaxit X cha mot nhom -NH2. Cho 10,3 gam X tac dung vi axit HCl (d), thu c 13,95 gam muoi khan. Cong thc cau tao thu gon cua X la (cho H = 1, C = 12, N = 14, O = 16, Cl = 35,5) A. H2NCH2COOH B. H2NCH2CH2COOH C. CH3CH2CH(NH2)COOH D. CH3CH(NH2)COOH (Trch thi H khi A 2007) Cu 46: Cho hon hp X gom hai chat hu c co cung cong thc phan t C2H7NO2 tac dung va u vi dung dch NaOH va un nong, thu c dung dch Y va 4,48 lt hon hp Z ( ktc) gom hai kh (eu lam xanh giay, quy am).. T khoi hi cua Z oi vi H2 bang 13,75. Co can dung dch Y thu c khoi lng muoi khan la (cho H = 1, C = 12, N = 14, O = 16, Na = 23) A. 16,5 gam B. 14,3 gam C. 8,9 gam D. 15,7 gam (Trch thi H khi A 2007) Cu 47: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T. (Trch thi H khi B 2007)

Cu 48: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. nc brom. C. dung dch NaOH. D. giy qu tm. (Trch thi H khi B 2007) Cu 49: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. (Trch thi H khi B 2007) Cu 50: Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCOO-CH2CH3. B. CH2=CHCOONH4. C. H2NC2H4COOH. D. H2NCH2COO-CH3 (Trch thi C 2007) Cu 51: Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C4H10O2N2. B. C5H9O4N. C. C4H8O4N2. D. C5H11O2N. (Trch thi H khi A 2009) Cu 52: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. Cu(OH)2 trong mi trng kim. B. dung dch NaCl. C. dung dch HCl. D. dung dch NaOH. (Trch thi H khi A 2009) Cu 53: Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 8,2. B. 10,8. C. 9,4. D. 9,6. (Trch thi H khi A 2009) Cu 54: Pht biu no sau y l ng? A. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. B. Benzen lm mt mu nc brom nhit thng. C. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. D. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. (Trch thi H khi A 2009) Cu 55: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch

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NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3NH2 v NH3. B. C2H5OH v N2. C. CH3OH v CH3NH2. D. CH3OH v NH3. (Trch thi H khi B 2009) Cu 56: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC3H5(COOH)2. B. (H2N)2C3H5COOH. C. H2NC2H3(COOH)2. D. H2NC3H6COOH. (Trch thi H khi B 2009) Cu 57: Ngi ta iu ch anilin bng s sau:

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 111,6 gam. B. 55,8 gam. C. 186,0 gam. D. 93,0 gam. (Trch thi H khi B 2009) Cu 58: Pht biu khng ng l: A. Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N + -CH2-COO B. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. C. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. D. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin). (Trch thi H khi A 2008) Cu 59: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2)-COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l A. 2. B. 3. C. 5. D. 4. (Trch thi H khi B 2008) Cu 60: un nng cht H2N-CH2-CONH-CH(CH3)CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH2-CH2-COOH. B. H3N-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. C. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. D. H2N-CH2-COOH, H2N-CH(CH3)-COOH. (Trch thi H khi B 2008) Cu 61: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. HCOOH3NCH=CH2. B. H2NCH2CH2COOH. C. CH2=CHCOONH4. D. H2NCH2COOCH3. (Trch thi H khi B 2008) Cu 62: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 6. B. 8.

C. 7. D. 5. (Trch thi H khi B 2008) Cu 63: Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l A. 0,1 mol v 0,4 mol. B. 0,1 mol v 0,2 mol. C. 0,1 mol v 0,1 mol. D. 0,1 mol v 0,3 mol. (Trch thi H khi B 2008) Cu 64: Cht X c cng thc phn t C 3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. metyl aminoaxetat. B. axit -aminopropionic. C. amoni acrylat. D. axit -aminopropionic. (Trch thi C khi 2009) Cu 65: S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l A. 4. B. 5. C. 2. D. 3. (Trch thi C khi 2009) Cu 66: Cht X c cng thc phn t C4H9O2N Bit:

Cng thc cu to ca X v Z ln lt l A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH. C. H2NCH2COOC2H5 v ClH3NCH2COOH. (Trch thi C khi 2009) Cu 67: Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 328. B. 453. C. 479. D. 382. (Trch thi C khi 2009) Cu 68: Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C 3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l A. HCOONH3CH2CH3. B. CH3CH2COONH4. C. HCOONH2(CH3)2. D. CH3COONH3CH3. (Trch thi C khi 2009) Cu 69: Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung dch NaOH (t o) v vi dung dch HCl (to). S phn ng xy ra l A. 3. B. 5. C. 6. D. 4. (Trch thi C khi 2009) Cu 70: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC4H8COOH. B. H2NC3H6COOH. C. H2NC2H4COOH. D. H2NCH2COOH. (Trch thi C khi 2008) Cu 71: Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55

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gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5. B. 2. C. 3. D. 4. (Trch thi C khi 2008) Cu 72: Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A. 5. B. 2. C. 3. D. 4. (Trch thi C khi 2008) Cu 73: Cht no sau y va lng tnh, va tc dng vi H2? A. CH2=CH-COONH4 B. H2N-CH2CH2-COOH C. CH3CH(NH2)COOH D. CH3-CH2-CH2-NO2 Cu 74: C 4 dung dch khng mu: glucoz, glixerol, h tinh bt v lng trng trng. Hy chn cht no trong s cc cht cho di y nhn bit c c bn cht? A. HNO3 c, nng, to B. I2 C. Ag2O trong dung dch NH3 D. Cu(OH)2 trong dung dch NaOH, to Cu 75: C 5 dung dch khng mu: axit fomic, glyxin, natri ioua, axit glutamic, lysin. Hy chn cp thuc th thch hp nhn bit c 5 cht. A. HCl v AgNO3 trong NH3 B. HCl v BaCl2 C. qu tm v dung dch BaCl2 D. qu tm v AgNO3/NH3 Cu 76: Cht X c cng thc phn t l C4H10O2NCl. un nng X vi dung dch NaOH thu c sn phm NaCl, H2N-CH2-COONa v ancol Y. Cng thc cu to ca Y l A. CH3CH2COOCH2NH3Cl B. CH3CH2OOCCH2NH3Cl C. CH3COOCH2CH2NH3Cl D. CH3CH(NH2)COOCH2Cl Cu 77: Tin hnh phn ng t hn hp glyxin v alanin. hi c th thu c ti a bao nhiu ipeptit? A. 2 B. 3 C. 4 D. 5 Cu 78: Thu phn hon ton polipeptit sau thu c bao nhiu amino axit? H2N CH2 CO NH CH CO NH CH CONH CH2 COOH

H2C COOH

H 2C

A. 2 B. 3 C. 4 D. 5 Cu 79: Thu phn tng phn mt pentapeptit thu c cc ipeptit v tripeptit gm C-B, D-C, A-D, B-E v D-CB (A, B, C, D, E l k hiu cc gc -amino axit khc nhau). Trnh t cc amino axit trong peptit trn l A. A-B-C-D-E B. D-C-B-E-A C. C-B-E-A-D D. A-D-C-B-E

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