Bi tp ankin Bi 1 : t chy hon ton 0,25 mol hn hp kh gm ankin A v anken B thu c sn phm ln lt qua bnh 1 ng P2O5 d v bnh hai

ng KOH d m c th thy bnh 1 khi lng tng 11,7 gam, bnh 2 khi lng tng 30,8 gam. Xc nh CTPT ca A, B bit rng A km hn B mt nguyn t C. Bi 2 : a) Gii thch ti sao Al4C3 thu phn to CH4 cn CaC2 li thu phn to C2H2. b) Tch ri hn hp gm : metan, etilen v axetilen Butin-1, butin-2 v butan. c) iu ch PVC t than , vi, NaCl v H2O. Bi 3 : Mt bnh kn dung tch 17,92 lit ng hn hp kh H 2 v axetilen (00C v 1 atm) v mt t bt Ni. Nung nng bnh mt thi gian sau lm lnh n 00C . a) Nu cho lng kh trong bnh sau khi nung qua dung dch AgNO 3 trong NH3 d s to 2,4 gam kt ta vng. Tnh khi lng axetilen cn li sau phn ng . b) Nu cho lng kh trong bnh sau khi nung qua dung dch nc brom ta thy khi lng dung dch tng ln 0,82 gam. Tnh khi lng etylen to thnh trong bnh c) Tnh th tch etan v th tch H 2 cn li, bit rng hn hp kh ban u c t khi so vi H2 bng 4 . Bi 4 : t chy hon ton 0,1 mol cht hu c A cn 12,8 gam O 2. Sau phn ng thu c 16,8 lit hn hp hi (136 0C ; 1atm) gm CO2 v hi nc. Hn hp ny c t khi so vi CH4 l 2,1. a) Xc nh CTPT ca A. Vit CTCT c th c ca A. b) Xc nh ng CTCT ca Av gi tn A bit rng A to kt ta vng khi cho tc dng vi dung dch AgNO3 trong NH3. Tnh lng kt ta khi cho 0,1 mol A phn ng vi hiu sut 90%. Bi 5 : Mt hn hp gm axetilen , propilen, v metan. - t chy hon ton 11 gam hn hp th thu c 12,6 gam nc. - Mt khc 5,6 lit hn hp (ktc) phn ng va vi dung dch cha 50 gam brom. Xc nh thnh phn % th tch ca hn hp u. Bi 6: a) Hidrocacbon A, B u dng mch h. Trong phn t A c 5 lin kt v 4 lin kt . Trong phn t B c 7 lin kt v 3 lin kt . Xc nh CTCT ca A,B v gi tn. b) Hn hp A gm hai hidrocacbon mch h A, B (l nhng cht trong dy ng ng ankan, anken, ankin). - Dn 336 ml (ktc) A t t qua dung dch nc brom d thy c 4 gam brom tham gia phn ng v khng c kh thot ra. - Nu t chy hon ton 336 ml (ktc) A ri dn sn phm thu c qua nc vi trong c d th thu c 4 gam kt ta . 1) Tnh thnh phn % v th tch X, Y trong A. 2) Xc nh CTPT ca X, Y. Bi 7: Mt hn hp kh X gm mt ankan, mt anken v mt ankin c th tch 1,792 lit ( ktc) c chia lm hai phn bng nhau: - Phn 1 cho qua dung dch AgNO3 trong NH3 d to ra 0,735 gam kt ta v th tch hn hp gim 12,5 %. - Phn 2 em t chy hon ton ri hp th ton b sn phm vo 9,2 lit dung dch Ca(OH)2 0,0125 M thy c 11 gam kt ta. Xc nh CTPT ca cc hidrocacbon. Bi 8 : Cho 4,96 gam hn hp gm Ca, CaC 2 tc dng ht vi H2O thu c 2,24 lit ( ktc) hn hp kh X. a) Tnh % khi lng CaC2 trong hn hp u b) un nng hn hp kh X c mt xc tc thch hp mt thi gian c hn hp kh Y. Chia Y lm hai phn bng nhau. - Ly phn 1 cho qua t t dung dch nc brom d thy cn li 0,448 lit (ktc) hn hp kh Z c t khi hi vi H2 bng 4,5. Hi khi lng bnh nc brom tng ln bao nhiu.

Phn hai trn vi 1,68 lit oxi ( ktc) vo bnh kn c th tch 4 lit. Sau khi bt tia la in t chy, gi nhit 109,2 0C. Tnh p sut bnh nhit ny. Bit rng dung tch bnh khng i

Bi 9 : t chy hon ton hn hp X gm hai hidrocacbon A, B thuc cng mt dy ng ng thu c 19,712 lit CO2 (ktc) v 10,08 gam nc. a) Xc nh ng ng ca A, B bit rng chng c th l anken, ankan, ankin. b) Xc nh CTPT, CTCT c th c ca A, B bit chng u th kh iu kin thng. c) Tnh th tch O2 cn thit t chy ht lng hn hp X bng hai phng php khc nhau. d) Chn CT ng ca A, B bit rng khi cho lng hn hp X tc dng vi dung dch AgNO3 trong NH3 d th ta thu c 4,8 gam kt ta Bi 10 : Mt hn hp X gm hai ankin v hidro c V = 35,84 lit (ktc). Chia X lm hai phn bng nhau. Phn 1 c un nng vi Ni xc tc thu c hn hp Y khng lm phai mu nc brom v c th tichs gim 50% so vi th tch ban u. t chy hon ton hn hp Y ri cho sn phm chy tc dng vi dung dch NaOH thu c hai mui ccbonat. Thm Ca(OH)2 d vo dung dch hai mui ny c 70 gam kt ta. Phn hai cho qua dung dch AgNO3 d trong NH3 thu c 14,7 gam kt ta . Cho bit hai an kin ny u th kh ktc v c th tch bng nhau. a) Xc nh CTCT ca hai ankin. b) Tnh t khi ca hn hp Y so vi khng kh. Bi 11 : Mt hn hp X gm hai hidrocacbon cng mt dy ng ng (ankan, anken hoc ankin) u th kh ktc. Cn 20,16 lit O 2 t chy ht X v phn ng to ra 7,2 gam nc. a) Xc nh dy ng ng ca A, B v vit CTPT c th c ca A, B. b) Xc nh CTCT ca A,B bit rng khi cho mt lng hn hp X nh trn tc dng vi dung dch AgNO3 trong NH3 d thu c 62,7 gam kt ta. c) Mt hn hp Y gm A, B nh cu (b) v mt hidrocacbon D. T khi ca D so vi H2 bng 15,17. t chy hn hp Y thu c 57,2 gam CO2 v 23,4 gam nc. Chng minh rng D thuc dy ng ng ankan. Bit rng D c cng s nguyn t C vi A hoc vi B, n D = nA + nB . Xc nh CTPT ca D v thnh phn hn hp Y. Bi 12 : a) Khi t chy mt hidrocacbon A bng lng O2 d 20% so vi lng cn thit th thu dc t l CO2 v nc l 2 :1. Sau khi lm ngng t hi nc th th tch cn li bng 2,5 ln th tch ca A. Xc nh CTPT ca A bit cc kh o cng k. b) X l hn hp A ( trn) v B ( l ng ng ca A) c V X = 17,92 lit (ktc) v m X = 29,2 gam. Cho hn hp ny qua dung dch AgNO 3 trong NH3 d thu c 120 gam kt ta. Tm CTPT, CTCT ca B v gi tn B theo theo hai cch c)Hn hp Y gm ton b lng X trn v H2 . Cho Y vo mt bnh dung tch 11,2 lit c cha mt t Ni th p sut P1 = 5,6 atm 00C. Nung bnh mt thi gian sau a v 00C th thu c hn hp Z c p sut gim 4/7 so vi p sut ban u. Phn ng cng H2 c hon ton hay khng? Tnh t khi ca Z so vi Y. Bi 13 : t chy hon ton hn hp A gm hai hidrocacbon X, Y cng dy ng ng mch h. Hp th ton b sn phm chy vo 4,5 lt dung dch Ca(OH) 2 0,02M, thu c kt ta v khi lng dung dch tng 3,78 gam. Cho dung dch Ba(OH)2 va vo dung dch thu c kt ta li tng thm, tng khi lng kt ta hai ln l 18,85 gam. T khi hi ca hn hp A so vi He < 10. Xc nh CTCT ca X, Y bit rng s mol ca X bng 60% tng s mol ca X v Y c trong hn hp A, cc phn ng xy ra hon ton. Bi 14 : Trong mt bnh kn dung tch 20 lit cha 9,6 gam O 2 v m gam hn hp ba hidrocacbon A, B, C. Nhit v p sut trong bnh l ) 0C v 0,448 atm. Bt tia la in t chy ht cc hidrocacbon v gi nhit 136,5 0C, p sut trong bnh lc ny l P. Cho hn hp kh trong bnh sau phn ng ln lt qua bnh 1 ng

H2SO4 c v bnh hai ng KOH d thy khi lng bnh 1 tng 4,05 gam v bnh hai tng 6,16 gam. 1) Tnh P gi thit dung tch bnh khng i. 2) Xc nh CTPT ca cc hidrocacbon, bit B, C cng s nguyn t cacbon v s mol ca A gp 4 ln tng s mol ca B v C. Bi 15 : Cho a gam CaC2 cha b % tp cht tr, tc dng vi H2O thu c V lit kh C2H2 (ktc). 1) Lp biu thc tnh B theo A v V. 2) Nu cho V lt kh trn vo bnh kn c than hot tnh xc tc nung nng n t0C th p sut l P 1. Sau phn ng thu c hn hp kh trong sn phm phn ng chim 60% th tch, nhit t 0C, p sut l P2. Tnh hiu sut h ca phn ng. 3) Gi s dung tch bnh khng i, th tch cht rn khng ng k hy lp biu thc tnh P2 theo P1 v h l hiu sut ca phn ng . Tm khong xc nh ca P2 theo P1.