30 de Thi HSG Cac Tinh Co Dap An

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vn/leviethung76/
1
THI CHN HC SINH GII CP TNH
NM HC 2011-2012
MN THI: HA HC- LP 9 THCS
Ngy thi: 01/4/2012 Thi gian lm bi:150 pht
(Khng k thi gian giao )
S GIO DC V O TO
BC GIANG
CHNH THC
Cu 1: (4,0 im)
1. Cho hn hp X gm Mg, Fe2O3 v Al2O3 tc dng vi dung dch CuSO4 (d), sau phn ng thu
c dung dch Y v cht rn Z. Cho ton b Z tc dng vi dung dch HCl (d), sau phn ng thu c
dung dch A v phn khng tan B. Ho tan B trong dung dch H 2SO4 c, nng (d) thu c kh C. Hp
th kh C vo dung dch Ba(OH)2 thu c kt ta D v dung dch F. Cho dung dch KOH (d) vo dung
dch F li thy xut hin kt ta D. Cho t t dung dch KOH n d vo dung dch A, c kt ta G.
Hy vit cc phng trnh ho hc ca cc phn ng xy ra.
2. t chy hon ton 13,2 gam hn hp gm hai hp cht hu c: A (C nH2nO) v B (CnH2n+2O), thu
c 29,7 gam CO2. Tm cng thc phn t ca A, B v vit cng thc cu to mch h c th c ca
chng.
Cu 2: (4,0 im)
1. Vit phng trnh ho hc hon thnh s phn ng sau:
(1)
(2)
(3)
(4)
(5)
(6)
Ru etylic
axit axetic
natri axetat
metan
axetilen
etilen
PE
(7)
vinyl clorua
(8)
PVC
2. Ha tan ht 17,2 gam hn hp X gm Fe v mt oxit st vo 200 gam dung dch HCl 14,6% thu
c dung dch A v 2,24 lt kh H2 (ktc). Thm 33,0 gam nc vo dung dch A c dung dch B.
Nng phn trm ca HCl trong dung dch B l 2,92%. Mt khc, cng ha tan ht 17,2 gam hn hp
X vo dung dch H2SO4 c, nng th thu c V lt kh SO2 duy nht (ktc).
a) Xc nh cng thc ha hc ca oxit st trong hn hp X.
b) Tnh khong gi tr ca V?
Cu 3: (4,0 im)
1. Ha tan 2,16 gam hn hp Y gm Na, Fe v Al vo nc (d), thu c 0,448 lt kh H 2 thot ra
(ktc) v mt lng cht rn khng tan. Tch lng cht rn ny cho phn ng ht vi 60 ml dung dch
CuSO4 1M thu c 3,2 gam ng kim loi v dung dch A. Tch ly dung dch A cho phn ng vi mt
lng va dung dch NaOH thu c kt ta ln nht. Lc kt ta em nung nhit cao trong
khng kh n khi lng khng i thu c cht rn B.
a) Xc nh % khi lng mi kim loi trong hn hp Y.
b) Tnh khi lng cht rn B.
2. t chy hon ton 44,4 gam hn hp X gm ba axit: CH 3COOH, CnHmCOOH v HOOCCOOH, thu c 21,6 gam H 2O v a gam CO2. Mt khc, cho 44,4 gam hn hp X phn ng hon ton
vi NaHCO3 (d) thu c 16,8 lt kh CO2 (ktc). Tnh gi tr ca a?
Cu 4: (4,0 im)
1. Cho 5,04 lt hn hp kh A (ktc) gm C2H2 v H2 qua xc tc Ni un nng, sau phn ng thu
c hn hp kh B ch gm 3 hirocacbon c t khi so vi H2 bng 14,25.
a) Xc nh khi lng trung bnh ca A.
b) Cho hn hp kh B phn ng hon ton vi dung dch Br 2 (d). Tnh s mol Br2 tham gia
phn ng.
2. Hp th hon ton V lt kh CO2 (ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH 1,4M,
sau khi cc phn ng xy ra hon ton thu c dung dch X. Cho ton b X tc dng vi dung dch
BaCl2 (d), thu c 11,82 gam kt ta. Tnh gi tr ca V?
Cu 5: (4,0 im)
1. Trong phng th nghim c cc dung dch ng trong cc l ring bit b mt nhn: KCl, Al(NO 3)3,
NaOH, MgSO4, ZnCl2, AgNO3. Dng thm mt thuc th, hy nhn bit cc dung dch trn. Vit cc phng
trnh phn ng (nu c).
2. Ha tan 2,56 gam kim loi ng vo 25,20 gam dung dch HNO 3 nng 60% thu c dung
dch A. Thm 210 ml dung dch NaOH 1M vo dung dch A. Sau khi cc phn ng kt thc, em c cn
hn hp thu c cht rn X. Nung X n khi lng khng i c 17,40 gam cht rn Y. Tnh nng
to
to
% ca cc cht trong dung dch A. Bit: 2NaNO 3
2NaNO2 + O2; 2Cu(NO3)2
2CuO +
TI LIU BD HSG HA
Trang 1
L Vit Hng
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4NO2 + O2.
------------- Ht ----------------
HNG DN CHM
BI THI CHN HC SINH GII CP TNH
NM HC 2011-2012
NGY THI 01/4/2012
HDC CHNH THC
MN THI: HA HC LP 9 THCS
Bn hng dn chm c 06 .trang
S GIO DC V O TO
BC GIANG
Cu 1
(4,0
im)
(4 im)
1.1 (3,0 im)
X + dd CuSO4 d dd Y + cht rn Z:
Mg + CuSO4 MgSO4 + Cu
Dung dch Y gm MgSO4 v CuSO4 d.
Cht rn Z gm Cu, Fe2O3 v Al2O3.
Cho Z tc dng vi dung dch HCl d:
Al2O3 + 6HCl 2AlCl3 + 3H2O;
Fe2O3 + 6HCl 2FeCl3 + 3 H2O
Cu + 2FeCl3 2FeCl2 + CuCl2
Do HCl d nn Al2O3, Fe2O3 tan ht, cht rn B l Cu d.
B + H2SO4 c, nng, d kh B l SO2
to
Cu + 2H2SO4
CuSO4 + SO2 + 2 H2O
Sc SO2 vo dd Ba(OH)2:
Ba(OH)2 + SO2 BaSO3 + H2O; BaSO3 + SO2 + H2O Ba(HSO3)2
Kt ta D l BaSO3, dd F cha Ba(HSO3)2
dd F + dd KOH d:
Ba(HSO3)2 + 2KOH BaSO3 + K2SO3 + 2H2O
dd A + dd KOH d:
HCl + KOH KCl + H2O;
CuCl2 + 2KOH Cu(OH)2 + 2KCl
FeCl2 + 2KOH Fe(OH)2 + 2KCl; AlCl3 + 3KOH Al(OH)3 + 3KCl
Al(OH)3 +KOH KAlO2 + 2H2O
Kt ta G gm: Cu(OH)2, Fe(OH)2
TI LIU BD HSG HA
Trang 2
L Vit Hng
Mi
PTHH
ng cho
0,25.
(tr phn
ng HCl
vi
KOH)
1.2
Gi s mol ca A, B ln lt l x, y mol.
(14n+16)x + (14n + 18)y = 13,2
14nx+16x + 14ny + 18y = 13,2 (*)
29, 7
= 0, 675 mol (**)
44
T (*) v (**) 16x + 18y = 13,2 - 14 x 0,675 = 3,75
16(x+y) <16x+18y < 18(x+y)
3, 75
3, 75
< x+ y <
18
16
0, 675.16
0, 675.18
<n<
T (**)
3, 75
3, 75
2,88 < n < 3, 24 n = 3
Vy cng thc phn t v cng thc cu to ca:
- A l C3H6O: CH3CH2CH=O; CH3COCH3; CH2=CH-CH2-OH; CH2=CH-O-CH3
- B l C3H8O: CH3-CH2-CH2-OH; CH3CHOHCH3; CH3CH2-O-CH3
Bo ton nguyn t cacbon: n CO2 = nx + ny =
Cu 2
(4,0
im)
0,25
0,25
0,25
0,25
(4 im)
2.1
(1)
(2)
(3)
mengim
C2H5OH + O2
CH3COOH + H2O
CH3COOH + NaOH
CH3COONa + H2O
CaO, t o
CH3COONa + NaOH
CH4 + Na2CO3
(4)
1500 C
C2H2 + 3H2
2CH4
LLN
(5)
C2H2 + H2 C2H4
(6)
(-CH2-CH2-)n
nC2H4
to
(7)
C2H2 + HCl CH2=CH-Cl
Mi
PTHH
ng cho
0,25.
Pd
to
xt , p
(PE)
HgCl2
150o 200o C
xt , p
to
(-CH2-CHCl-)n (nha PVC)

(8)
nCH2=CH-Cl
2.2
a) Gi cng thc ca oxit st l FexOy.
Cc PTHH khi X vo dung dch HCl:
Fe + 2HCl FeCl2 + H2
(1)
FexOy + 2yHCl FeCl2y/x + yH2O
(2)
200.14,6
nHCl ban u = 100.36,5 = 0,8 (mol)
n H2 =
2,24
=0,1(mol) m H2 =0,1.2=0,2(g)
22,4
T (1): nFe = nH 2 = 0,1(mol) => mFe = 0,1 . 56 = 5,6(g)

mFex Oy = 17, 2 5, 6 = 11, 6( g )
nFe x O y =
11,6
( mol ) (*)
56 x +16 y
0,25
T (1): nHCl = 2 nH 2 = 2.0,1= 0,2 (mol)

mddA = 200 + 17, 2 0, 2 = 217( g )
mddB = 217 + 33 = 250 (g)
250.2,92
nHCl d = 100.36,5 = 0,2(mol )
nHCl (2) = 0,8 - 0,2 - 0,2 = 0,4(mol)
1
1
0,2
nFe x O y =
.nHCl =
.0,4 =
( mol )
2
y
2
y
y
T (2):
(**)
T (*) v (**) ta c phng trnh

11,6
0,2
x
3
= y y =4
56 x +16 y
Vy cng thc Oxit st l: Fe3O4

b)Cc PTHH khi cho X vo dung dch H2SO4 c nng:
TI LIU BD HSG HA
Trang 3
L Vit Hng
0,25
t
2Fe + 6H2SO4 c
Fe2(SO4)3 + 3SO2 + 6H2O

t
2Fe3O4 + 10H2SO4 c 3Fe2(SO4)3 + SO2 + 10H2O
C th:
Fe + Fe2(SO4)3 3FeSO4
Nu H2SO4 d (5) khng xy ra:
o
nSO
max
(3)
0,25
(4)
(5)
3
1
3
1
n Fe + n Fe3O4 = .0,1 + .0,05 = 0,175(mol) VSO2
2
2
2
2
max
= 3,92 (lt)
Nu H2SO4 khng d: (5) xy ra:

n Fe ( SO ) 3
nSO2
(3) v (4)
min nFe (5) =
t nFe (5) = x(mol) => nFe (3) = 0,1 - x
1
3
n
Fe ( SO ) 3 (3) v (4) = 2 (0,1 x) + 2 .0,05
2
0,25
0,25
1
3
0,25
(0,1 x ) + .0,05 = x => x =
2
2
3
0,25 0,05
nFe (3) = 0,1 =
3
3
3 0,05 1
+ .0,05 = 0,05 (mol)
Khi nSO2 min = .
2 3
2
c pt:
0,25
=> VSO min = 0,05 . 22,4 = 1,12 (lt)

Vy khong gi tr c th nhn gi tr ca V l: 1,12 V 3,92
2
Cu 3
(4,0
im)
0,5
(4 im)
3.1
- Gi trong 2,16 gam hn hp c x mol Na, y mol Al.
n H2 = 0, 448 : 22, 4 = 0, 02 mol
nCuSO4 = 0,06.1= 0,06mol; nCuSO4 pu = nCu=3,2:64 = 0,05 mol
nCuSO4 du = 0,06 - 0,05 = 0,01mol
PTHH:
2Na + 2H2O 2NaOH + H2
(1)
x
x
0,5x
(mol)
2Al + 2H2O + 2NaOH 2NaAlO2 + 3H2
(2)
x
x
x
1,5x (mol)
2Al
+ 3CuSO4 2Al2(SO4)3 + 3Cu
(3)
(y-x)
1,5(y-x)
(y-x)
1,5(y-x)
(mol)
Fe
+ CuSO4
FeSO4 + Cu
(4)
a) Gi s khng xy ra phn ng (3) cht rn ch l Fe
Theo (4) nFe= nCu = 0,05 mol mFe= 0,05.56 = 2,8 gam > 2,16 (khng ph hp bi)
Vy c xy ra phn ng (3) v v CuSO4 cn d nn Al v Fe phn ng ht theo (3) v (4)
Theo (1) v (2): n H2 = 0,5x + 1,5x = 0, 02 mol x = 0,01
Theo (3): nAl(3) = y - 0,01 mol
n CuSO4 =1,5 ( y 0, 01) mol
Theo (4): n Fe = n CuSO4 (4) = 0, 05 1,5 ( y 0, 01) mol
Ta c : mNa + mAl + mFe = 23.0,01 + 27y + 56[0,05-1,5(y - 0,01)] = 2,16 y = 0,03
trong hn hp ban u:
mNa = 23.0,01 = 0,23 gam
mAl = 27.0,03 = 0,81 gam
mFe = 2,16 - 0,23 -0,81 = 1,12 gam
TI LIU BD HSG HA
Trang 4
L Vit Hng
0,5
0,25
0,25
0,25
Vy:
0,23
0,81
.100%=10,65%; %m Al =
.100%=37,5%
2,16
2,16
1,12
%m Na =
.100%=51,85%
2,16
%m Na =
0,25
b) Trong dung dch A c:

n Al2 (SO4 )3 = 0,03- 0,01= 0,02 mol
n CuSO4 du = 0,01mol
n FeSO4 = n Fe =1,12:56 = 0,02 mol
Ta c s
CuSO4 Cu(OH)2 CuO
mCuO = 0,01.80 = 0,8 gam

0, 02
.160 = 1, 6 gam
2FeSO4 2Fe(OH)2 2Fe(OH)3 Fe2O3 m Fe2O3 =
2
0, 02
m Al 2 O3 =
.102 = 1, 02 gam
Al2(SO4)3 2Al(OH)3 Al2O3
2
Vy mB = 0,8 + 1,6 + 1,02 = 3,24 gam
3.2
Gi trong 44,4 gam X c x mol CH3COOH, y mol CnHmCOOH v z mol HOOC-COOH
PTHH
CH3COOH + NaHCO3 CH3COONa + CO2 + H2O
(1)
mol:
x
x
CnHmCOOH + NaHCO3 CnHmCOONa + CO2 + H2O (2)
mol:
y
y
HOOC-COOH + 2NaHCO3 NaOOC-COONa + 2CO2 + 2H2O (3)

mol:
z
2z
Theo (1), (2) v (3): nCO2 = x + y + 2 z =
- n H2O =
1,0
0,25
16,8
= 0, 75 mol
22, 4
21,6
=1,2 mol n H = 2n H2O = 2,4 mol
18
0,25
- Bo ton nguyn t oxi:

n O =2n CH3COOH +2n Cn H mCOOH +4n HOOC-COOH
=2x+2y+4z
=2.0,75=1,5 mol
0,25
- LBT khi lng:

mX = mC + mH + mO = 44, 4 gam
nC =
nCO2
44, 4 2, 4 1,5.16
= 1,5 mol
12
= nC = 1,5 mol
0,5
Vy a = 1,5.44= 66 gam
Cu 4
(4,0
im)
0,25
(4 im)
4.1
a) Hn hp B gm C2H2; C2H4; C2H6
Gi cng thc chung ca B l C2 H x
d B/H 2 = 14,25 => MB = 14,25 x 2 = 28,5
=> 24 + x = 28,5 => x = 4,5
Gi s c 1 mol B => mB = 28,5 gam

Ni
C2H4,5 (1)
PTHH:
C2H2 + 1,25H2
t0
1
1,25
1
TI LIU BD HSG HA
Trang 5
L Vit Hng
28,5 38
= 12,67
LBT khi lng: mA = mB = 28,5 gam m nA = 2,25 mol => M A =
1,0
2,25 3
5,04
=0,225(mol)
22,4
T (1) => nB = 0,1 (mol)
3
PTHH
C2H4,5 +
Br2
C2H4,5Br1,5
4
theo (2): nBr2 = 0,1.0, 75 = 0, 075 mol.
b) Theo bi ra: n A =
(2)
1,0
4.2
Ta c: n K 2CO3 =0,1.0,2=0,02 (mol); n KOH = 0,1.1,4 = 0,14 (mol)
PTHH
CO2 + 2KOH K2CO3 + H2O
(1)
C th c:
CO2 + K2CO3 + H2O 2KHCO3
(2)
BaCl2 + K2CO3 BaCO3 + 2KCl (3)
0,25
11,82
= 0,06 mol> n K 2CO3 ban u = 0,02 mol
Theo (3): n K 2CO3 (3) = n BaCO3 =
197
C hai trng hp xy ra.
0,25
- TH1: khng xy ra phn ng (2)

Theo (1): n CO2 = n K 2CO3 (3) - n K 2CO3 b = 0,06 -0,02 = 0,04mol
V=0,04.22,4=0,896 lit
- TH2: c xy ra phn ng (2)
1
0,14
= 0, 07 mol
Theo (1): nCO2 (1) = nK 2CO3 (1) = nKOH =
2
2
nK 2CO3 p (2) = nK 2CO3 (1) + nK 2CO3 b nK2CO3 (3) = 0, 07 + 0, 02 0, 06 = 0, 03 mol
0,5
Theo (2): nCO2 (2) = nK2CO3 (2) = 0, 03mol

V = (0,07 + 0,03).22,4 = 2,24 lit
Cu 5
(4,0
im)
0,5
0,5
(4 im)
1. Dng phenolphtalein nhn bit cc dung dch: KCl, Al(NO3)3, NaOH, MgSO4, ZnCl2,
AgNO3.
Nhn bit
Ln lt nh vi git phenolphtalein vo tng dung dch mu th.
ng mi
- Nhn ra dung dch NaOH do xut hin mu hng.
cht cho
0,5
Ln lt cho dung dch NaOH vo mi dung dch mu th cn li:
- Dung dch AgNO3 c kt ta mu nu:
AgOH + NaNO3
AgNO3 + NaOH
Ag2O + H2O + 2NaNO3
hoc 2 AgNO3 + 2NaOH
- Dung dch MgSO4 c kt ta trng:
Mg(OH)2 + Na2SO4
MgSO4 + 2NaOH
- Cc dung dch Al(NO3)3, ZnCl2 u c chung hin tng to ra kt ta trng, tan trong
dung dch NaOH (d).
Al(OH)3 + 3NaCl
AlCl3 + 3NaOH
NaAlO2 + 2H2O
Al(OH)3 + NaOH
Zn(OH)2 + 2NaNO3
Zn(NO3)2 + 2NaOH
Na2ZnO2 + 2H2O
Zn(OH)2 + 2NaOH
TI LIU BD HSG HA
Trang 6
L Vit Hng
- Dung dch KCl khng c hin tng.
- Dng dung dch AgNO3 nhn ra dung dch ZnCl2 do to ra kt ta trng
3AgCl + Zn(NO3)2
3AgNO3 + ZnCl2
- Cn li l dung dch Al(NO3)3.
5.2
nCu = 0,04 mol; nNaOH = 0,21 mol; n HNO3 = 0, 24 mol.
Dung dch A c Cu(NO3)2, c th c HNO3.
Cu(OH) 2
CuO
0
+ dd NaOH
t
NaNO3
NaNO 2
Ta c: ddA
c can
c th c NaOH hoac Cu(NO )
c th c NaOH du
3 2
PTHH:
NaOH + HNO3 NaNO3 + H2O
2NaOH + Cu(NO3)2 Cu(OH)2 + 2NaNO3
0,08
0,04
0,04
0,08
mol
to
2NaNO2 + O2
2NaNO3
0,25
to
CuO + H2O
Cu(OH)2
Gi s mol NaNO2 trong cht rn sau khi nung l x. Theo bo ton nguyn t ta c:
nCuO = 0, 04 mol; nNaOH d = 0,21-x mol mY = 80. 0,04 + 69x + 40(0,21 - x) = 17,4 gam
x = 0,2 n NaNO2 = 0, 2 mol
nHNO3
d = 0,2 0,08 = 0,12mol
nHNO3
phn ng = 0,240,12 = 0,12mol
n H 2O
1
n HNO
m
=2
=0,06 mol
3
=> mkh= mCu +
H 2O
0,25
= 1,08g
m HNO - mCu(NO ) - m H O = 2,56+7,56-7,52-1,08 = 1,52g

3
3 2
Trong dung dch A c:

n Cu ( NO3 ) = n Cu = 0, 04 mol
2
0,25
n HNO3 du = 0, 24 0,12 = 0,12 mol.

mdd A = 2,56 + 25,2 mkh = 26,24 gam.
Vy trong dung dch A c:
0,12.63
C% HNO3 du =
.100%= 28,81%
26, 24
0, 04.188
C% Cu ( NO3 ) =
.100%=28, 66%
2
26, 24
0,25
im ton bi
TI LIU BD HSG HA
Trang 7
L Vit Hng
(20
im)
2
UBND TNH BC NINH
S GIO DC V O TO
CHNH THC
( thi c 01 trang)

NM HC 2011 2012
MN THI : HA HC-LP 9
Thi gian lm bi: 150 pht (khng k thi gian giao )
Ngy thi: 20 thng 3 nm 2012
===========
Cu I (2 im): Mt hn hp cha Fe, FeO, Fe2O3. Nu ho tan a gam hn hp trn bng dung dch HCl
d th khi lng H2 thot ra bng 1,00% khi lng hn hp em th nghim. Nu kh a gam hn hp
trn bng H2 d th thu c khi lng nc bng 21,15% khi lng hn hp em th nghim. Xc
nh phn trm v khi lng mi cht c trong a gam hn hp trn.
Cu II (2 im): Cho 1 anken A kt hp vi H2 (Ni lm xc tc) ta c ankan B.
a/ Xc nh cng thc phn t ca A, B bit rng t chy ht B bng mt lng O 2 va th
th tch kh CO2 thu c bng 1/2 tng th tch ca B v O2.
b/ Mt hn hp X gm A, B v H 2 c th tch l 22,4 lt. Cho X i qua Ni nung nng xc tc thu
c hn hp Y, bit t khi ca X so vi Y bng 0,70. Tnh th tch hn hp Y, s mol H 2 v A phn
ng vi nhau.
c/ Bit rng hn hp Y khng lm phai mu nc Br 2 v t khi dY/H2= 16. Xc nh thnh phn
trm th tch ca cc kh trong hn hp X.
Cc th tch kh u o iu kin tiu chun.
Cu III (2 im): Cho 316,0 gam dung dch mt mui hirocacbonat (A) 6,25% vo dung dch H 2SO4
long va , sau khi phn ng xy ra hon ton thu c 16,5 gam mui sunfat trung ho. Mt khc
cng cho lng dung dch mui hirocacbonat (A) nh trn vo dung dch HNO 3 va , ri c cn t t
dung dch sau phn ng th thu c 47,0 gam mui B. Xc nh A, B.
Cu IV (2 im): Cho cc ha cht CaCO3, NaCl, H2O v cc dng c cn thit lm th nghim, trnh
by phng php iu ch dung dch gm 2 mui Na2CO3 v NaHCO3 c t l s mol l 1:1.
Cu V (2 im): Ba cht kh X, Y, Z u gm 2 nguyn t, phn t cht Y v Z u c 3 nguyn t. C 3
cht u c t khi so vi hiro bng 22. Y tc dng c vi dung dch kim, X v Z khng c phn ng
vi dung dch kim. X tc dng vi oxi khi t nng sinh ra Y v mt cht khc. Z khng chy trong oxi.
a/ Lp lun tm cng thc phn t cc cht X, Y, Z.
b/ Trnh by cch phn bit ba bnh ng ring bit ba kh trn b mt nhn.
Cu VI (2 im): Vit phng trnh phn ng trong 0,75 mol H2SO4 tham gia phn ng sinh ra
a/ 8,4 lt SO2 (ktc).
b/ 16,8 lt SO2 (ktc).
c/ 25,2 lt SO2 (ktc).
d/ 33,6 lt SO2 (ktc).
Cu VII (2 im): Dn lung kh CO qua ng s c cha m gam hn hp cht rn X gm CuO v Fe 2O3
nung nng, sau mt thi gian trong ng s cn li n gam hn hp cht rn Y. Kh thot ra c hp th
ht vo dung dch Ca(OH)2 d c p gam kt ta. Vit cc phng trnh ha hc ca phn ng v thit
lp biu thc lin h gia n, m, p.
Cu VIII (2 im): Hai cc thy tinh A, B ng dung dch HCl d t trn hai a cn, thy cn trng
thi thng bng. Cho 5,00 gam CaCO 3 vo cc A v 4,79 gam M2CO3 (M l kim loi) vo cc B. Sau khi
cc mui ha tan hon ton thy cn tr li v tr thng bng. Hy xc nh M.
Cu IX (2 im): Trnh by cc th nghim xc nh thnh phn nh tnh v nh lng ca nc.
Cu X (2 im): Nu cch pha ch 500,0 ml dung dch NaCl 0,9% (nc mui sinh l) t mui n
nguyn cht v nc ct. Nu tn cc dng c th nghim cn thit v m phng cch tin hnh bng hnh
v.
============== Ht ==============
Cho bit s khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; Si = 28;
P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Ni = 58; Cu = 64; Zn = 65; Ag = 108; Ba = 137
Th sinh c s dng bng HTTH v my tnh cm tay thng thng.
TI LIU BD HSG HA
Trang 8
L Vit Hng
UBND TNH BC NINH
S GIO DC V O TO
HNG DN CHM
NM HC 2011 2012
MN THI : HA HC-LP 9
Ngy thi: 20 thng 3 nm 2012
===========
Cu I (2 im): Mt hn hp cha Fe, FeO, Fe2O3. Nu ho tan a gam hn hp trn bng dung dch HCl
d th khi lng H2 thot ra bng 1,00% khi lng hn hp em th nghim. Nu kh a gam hn hp
trn bng H2 d th thu c khi lng nc bng 21,15% lng hn hp em th nghim. Xc nh
phn trm v khi lng mi cht c trong a gam hn hp trn.
CU
NI DUNG
IM
I
Gi s a = 100 gam. Gi x, y, z ln lt l s mol Fe, FeO, Fe2O3 trong a gam
Ho tan a g hn hp trn bng dung dch HCl d
Fe + 2 HCl
FeCl2 + H2
0,50
x
2x
x
x
FeO + 2 HCl FeCl2 + H2O
y
2y
y
y
Fe2O3+ 6HCl
2FeCl3 + 3H2O
z
6z
2z
3z
Ta c 2x = 1(*)
Kh a g hn hp trn bng H2 d
FeO + H2 Fe + H2O
0,50
y
y
y
y
Fe2O3 + 3 H2 2Fe + 3 H2O
z
3z
2z
3z
Ta c 18y + 54z = 21,15(**)
Li c 56x + 72y + 160z = 100(***)
T (*), (**), (***) c h phng trnh:
2x = 1
0,50
18y + 54z = 21,15
56x + 72y + 160z = 100
Gii h PT ta c x = 0,5; y = 0,5; z = 0,225
0,50
%Fe = 28%; %FeO = 36%; %Fe2O3 = 36%
Cu II (2 im): Cho 1 anken A kt hp vi H2 (Ni lm xc tc) ta c ankan B.
a/ Xc nh cng thc phn t ca A, B bit rng t chy ht B bng mt lng O 2 va th
th tch kh CO2 thu c bng 1/2 tng th tch ca B v O2.
b/ Mt hn hp X gm A, B v H 2 c th tch l 22,4 lt. Cho X i qua Ni nung nng xc tc thu
c hn hp Y, bit t khi ca X so vi Y bng 0,70. Tnh th tch hn hp Y, s mol H 2 v A phn
ng vi nhau.
c/ Bit rng hn hp Y khng lm phai mu nc Br 2 v t khi dY/H2= 16. Xc nh thnh phn
trm th tch ca hn hp X.
Cc th tch kh u o iu kin tiu chun.
CU
NI DUNG
IM
Ni
II
a CnH2n + H2 CnH2n+2
t chy B(CnH2n+2 )
0,25
3n +1
O2 t0 nCO2 + (n+1) H2O
2
3n +1
Nu ly 1 mol B, nO2 =
, nCO2 = n.
2
1
1
3n +1
nCO2 =
(nB + nO2) n =
(1+
).
2
2
2
CnH2n+2 +
n = 3 , A l C3H6, B l C3H8
0,50
Ta s dng kt qu
TI LIU BD HSG HA
Trang 9
L Vit Hng
ny
=
nx
dx/y =
Mx
My
dx/y =
nY
MX mX nY
=
.
=
(do mX = mY)
nX mY
nX
MY
nY
= 0,7 nY = 0,7 mol
nX
VY = 0,7 . 22,4 = 15,68 lt.
nH2 v nA phn ng
Ta s dng: nX nY = nH2 p = nA p
nX nY = 1- 0,7 = 0,3.
Vy n H2 p = nA p = 0,3 mol
C3H6 + H2 Ni,t 0 C3H8
0,3
0,3
0,3
V hn hp Y sau phn ng khng lm phai mu nc Br 2, chng t C3H6
phn ng ht.
Vy n C3H6 b = 0,3 mol = a.
(2)
Hn hp Y sau phn ng gm:
C3H8 (b + 0,3) v H2 d (c 0,3)
dx/y =
44(b + 0,3) + 2(c 0,3)

= 2.16 = 32 g
b + 0,3 + c 0,3
44b +13,2 + 2c 0,6
= 32
b +c
0,50
0,25
MX =
Thay b + c = 1- 0,3 = 0,7 44b + 2c = 9,8

Hay: 22b + c = 4,9 (3)
b + c = 0,7 (4)
T (3) v (4) b = 0,2 mol ( C3H8 ), c = 0,5 mol H2
0,50
Vy thnh phn % th tch ca hn hp X l: 30% C3H6 ; 20% C3H8 v 50% H2
Cu III (2 im): Cho 316 gam dung dch mt mui hirocacbonat (A) 6,25% vo dung dch H 2SO4
long va , sau khi phn ng xy ra hon ton thu c 16,5 gam mui sunfat trung ho. Mt khc
cng cho lng dung dch mui hirocacbonat (A) nh trn vo dung dch HNO 3 va , ri c cn t t
dung dch sau phn ng th thu c 47 gam mui B. Xc nh A, B.
CU
NI DUNG
IM
III
Gi cng thc ca mui A: R(HCO3)n
0,25
C: mA = 316.6,25% = 19,75 gam
0,25
2R(HCO3)n + nH2SO4 R2(SO4)n + 2nCO2 + 2nH2O
19,75gam
16,5gam
=> 16,5.(2R + 2.61n) = 19,75.(2R + 96n)
suy ra: R= 18n
Ta c bng sau:
n
1
2
3
0,5
R
18
36
54
KL
NH4
Khng tho mn
Khng tho mn
mui A l: NH4HCO3
- Theo bi: nA = 19,75 : 79 = 0,25 mol
0,25
NH4HCO3 + HNO3 NH4NO3 + H2O + CO2
0,25 mol
0,25 mol
0,25
m(NH4NO3) = 80 0,25 = 20 gammui B l mui ngm nc.
- t CTPT ca B l: NH4NO3.xH2O
m(H2O) = 47 20 = 27 gam n(H2O) = 27/18= 1,5 mol
0,50
x=6
Cng thc ca B: NH4NO3.6H2O
Cu IV (2 im): Cho cc ha cht CaCO3, NaCl, H2O v cc dng c cn thit lm th nghim, trnh
by phng php iu ch dung dch gm 2 mui Na2CO3 v NaHCO3 c t l s mol l 1:1.
TI LIU BD HSG HA
Trang 10
L Vit Hng
CU
IV
IM
0,25
NI DUNG
To ra v thu ly kh CO2: Nhit phn CaCO3
to
CaCO3
CaO + CO2
To ra dung dch NaOH: in phn dd NaCl bo ha c mng ngn
pdd
2NaOH + Cl2 + H2
2NaCl + 2H2O
mnx
Vit cc phng trnh to mui
1.
CO2(d) + NaOH NaHCO3
(1)
2a
2a
(mol)
2.
NaHCO3 + NaOH Na2CO3 + H2O
(2)
a
a
a
(mol)
- Trnh by cch tin hnh th nghim: ly 2 th tch dung dch NaOH cho vo
cc A v cc B sao cho VA = 2VB (dng cc chia )
Gi s mol NaOH cc A l 2a mol th s mol NaOH cc B l a mol
Sc CO2 d vo cc A, xy ra phn ng (1)
Sau cc A vo cc B: xy ra phng trnh (2)
Kt qu thu c dung dch c s mol NaHCO3 l a mol v s mol Na2CO3 l a
mol => t l 1:1
-
0,25
0,25
0,25
1,00
Cu V (2 im): Ba cht kh X,Y, Z u gm 2 nguyn t, phn t cht Y v Z u c 3 nguyn t. C 3

cht u c t khi so vi hiro bng 22. Y tc dng c vi dung dch kim, X v Z khng c phn ng
vi dung dch kim. X tc dng vi oxi khi t nng sinh ra Y v mt cht khc. Z khng chy trong oxi.
a/ Lp lun tm cng thc phn t cc cht X, Y, Z.
b/ Trnh by cch phn bit ba bnh ng ring bit ba kh trn b mt nhn.
CU
NI DUNG
IM
V
a M = 22.2 = 44
Y l hp cht gm hai nguyn t, tc dng c vi kim c th l oxit axit.
Ch c trng hp Y l CO2 tho mn v cht gm 2 nguyn t, phn t gm 3
0,50
nguyn t v M = 44. ( Cc oxit, axit, mui khc khng tho mn)
X chy sinh ra 2 sn phm trong c CO 2 vy X l CXRY, trong R l H tho
0,25
mn. X l C3H8 c M = 44.
Z l N2O tho mn v cht gm 2 nguyn t, phn t gm 3 nguyn t v M = 44.
0,50
b Cch phn bit:
Cho qua nc vi trong d, kh no lm dung dch vn c l CO 2, 2 kh cn li
0,25
l C3H8 v N2O.
Ca(OH)2 + CO2 CaCO3 + H2O
0,25
em t 2 kh cn li ri dn sn phm chy vo dung dch nc vi trong, sn
phm chy no lm c nc vi trong l sn phm chy ca C3H8, cn N2O
khng chy
C3H8 + 5O2 3CO2 + 4H2O
0,25
Kh cn li l N2O
Cu VI (2 im): Vit phng trnh phn ng trong 0,75 mol H2SO4 tham gia phn ng sinh ra
a/ 8,4 lt SO2 (ktc).
b/ 16,8 lt SO2 (ktc).
c/ 25,2 lt SO2 (ktc).
d/ 33,6 lt SO2 (ktc).
CU
NI DUNG
IM
VI
n SO2
0,375 1
=
= Cu + 2H2SO4 c t CuSO4 + SO2 + 2H2O
a)
0,50
n H 2 SO4
0,75
2
0
b)
c)
n SO2
n H 2 SO4
n SO2
n H 2 SO4
0,75
= 1 Na2SO3 + H2SO4
0,75
1,125 3
= S + 2H2SO4 c
0,75 2
TI LIU BD HSG HA
Trang 11
Na2SO4 + SO2 + H2O
0,50
0,50
3SO2 + 2H2O
L Vit Hng
d)
n SO2
n H 2 SO4
1,5
= 2 2NaHSO3 + H2SO4
0,75
0,50
Na2SO4 + 2SO2 + H2O
Ch : Hc sinh chn cht khc v vit phng trnh ha hc ng, cho im ti

a tng ng.
Cu VII (2 im): Dn lung kh CO qua ng s c cha m gam hn hp cht rn X gm CuO v Fe 2O3
nung nng, sau mt thi gian trong ng s cn li n gam hn hp cht rn Y. Kh thot ra c hp th
ht vo dung dch Ca(OH)2 d c p gam kt ta. Vit cc phng trnh ha hc ca phn ng v thit
lp biu thc lin h gia n, m, p.
CU
NI DUNG
IM
VII
PTHH:
(1) 3Fe2O3 + CO 2Fe3O4 + CO2
1,00
(2) Fe2O3 + CO t 2FeO + CO2
(3) Fe2O3 + 3 CO 2Fe + 3 CO2
(4) CuO + CO Cu + CO2
(5) Ca(OH)2 + CO2 CaCO3 + H2O
p dng nh lut bo ton khi lng:
mx + mco = my + mCO2
m n = mCO2 mCO
m n = 44.n CO2 28.nCO
0,50
p
M nCO = nCO2 = nCaCO3 =
100
0
(44 28) p 16.p

=
100
100
m = n + 0,16p
0,50
Cu VIII (2 im): Hai cc thy tinh A, B ng dung dch HCl d t trn hai a cn, thy cn trng
thi thng bng. Cho 5 gam CaCO 3 vo cc A v 4,79 gam M 2CO3 (M l kim loi) vo cc B. Sau khi cc
mui ha tan hon ton thy cn tr li v tr thng bng. Hy xc nh M.
CU
NI DUNG
IM
VIII
CaCO3 + 2HCl CaCl2 + H2O + CO2
(1)
0,50
M2CO3 + 2HCl 2 MCl + H2O + CO2
(2)
0,50
(100 44).5
= 2,8
T(1) ta c: Khi lng cc A tng
100
T (2) Ta c: Khi lng cc B tng
0,50
(2M + 60 44).4,79 (2M + 16).4,79
=
= 2,8
2M + 60
2M + 60
0,50
M = 23 vy M l Na
mn =
TI LIU BD HSG HA
Trang 12
L Vit Hng
Cu IX (2 im): Trnh by cc th nghim xc nh thnh phn nh tnh v nh lng ca nc.
CU
NI DUNG
IM
IX
0,75
(1)
(2)
(3)
S phn hy nc.
Lp thit b phn hy nc nh hnh (1). Khi cho dng in mt chiu i qua
nc ( c pha thm mt t dung dch axit sunfuric lm tng dn in ca
nc), trn b mt hai in cc (Pt) xut hin bt kh. Cc kh ny tch t trong
hai u ng nghim thu A v B. t kh trong A, n chy km theo ting n nh,
l H2. Kh trong B lm cho tn m bng chy, l kh oxi.
S tng hp nc:
Cho nc vo y ng thy tinh hnh tr. Cho vo ng ln lt 2 th tch kh
hiro v 2 th tch kh oxi. Mc nc trong ng vch s 4 (hnh (2)). t bng
0,75
tia la in hn hp hi ro v oxi s n. Mc nc trong ng dng ln. Khi nhit
trong ng bng nhit bn ngoi th mc nc dng li vch chia s 1
(Hnh (3)), kh cn li lm tn m bng chy l oxi.
Xc nh thnh phn nh lng ca H2O
T cc d kin th nghim trn ta c phng trnh ha hc to thnh H2O
2H2 + O2 2H2O
Do t l v th tch bng t l v s mol nn ta c
0,50
nH2:nO2 = 2:1 mH2:mO2 = 4:32 = 1:8. Vy phn trm khi lng mi nguyn t
trong nc l
1*100%
= 11,1% %O = 100%-%H = 88,9%
%H =
1+ 8
Cu X (2 im): Nu cch pha ch 500 ml dung dch NaCl 0,9% (d = 1,009g/cm 3) (nc mui sinh l) t
mui n nguyn cht v nc ct. Nu tn cc dng c th nghim cn thit v m phng cch tin hnh
bng hnh v.
CU
NI DUNG
IM
X
Khi lng NaCl cn dng: 500.1,009.0,9% = 4,54 gam
- (1) Cn ly 4,54g NaCl ri cho vo cc thy tinh.
- (2) Cho t t nc ct (lng nh hn 500 ml) vo v lc u
1,00
- (3) Dng a thy tinh khuy u cho mui tan ht
- (4) dung dch va pha vo bnh nh mc 500 ml.
- (5) Cho tip nc ct va n vch 500ml.
- (6) y nt nhp kn, lc k ta c 500 ml dung dch nc mui sinh l nh
yu cu.
Cc dng c th nghim: cn in t, cc thy tinh, a thy tinh, bnh nh
mc 500 ml c nt nhm,
TI LIU BD HSG HA
Trang 13
L Vit Hng
a thy tinh
1,00
(3)
500 ml
H2O
(2)
NaCl
(4,54 gam)
(1)
(4), (5), (6)
Ch : Hc sinh c th m phng bng hnh v khc nhng vn m bo cc ni
dung ny.
Ch : Hc sinh lm cch khc ng cho im ti a tng ng.
TI LIU BD HSG HA
Trang 14
L Vit Hng
3
THI HSG MN HA 9 BNH PHC 2011-2012: (150 PHT).(28/3/2012)
Cu I: (2 ):
1. Nc clo va mi iu ch lm mt mu giy qu tm, nhng nc clo lu ngoi nh sng lm
cho qu tm ha . Ti sao?
2. Hy chn mt ha cht thch hp phn bit cc dung dch mui sau: NH4Cl, (NH4)2SO4, NaNO3,
MgCl2, FeCl3. Vit cc PTHH xy ra.
Cu II: ( 2 ):
1. Cho mt kim loi A tc dng vi mt dung dch mui B. Kim loi mi sinh ra bm trn kim loi A.
Ly hn hp kim loi ny ha tan trong dung dch HNO3 c nng thu c kh D duy nht v dung dch
G cha 3 mui. Hy xc nh A,B,D,G? Vit PTHH xy ra.
2. Bng png php ha hc, hy tch kh SO2 ra khi hn hp kh: SO2,SO3,O2.
Cu III: ( 4 )
1. T dung dch A cha a mol CuSO4 v b mol FeSO4, thc hin cc th nghim sau:
Th nghim 1: thm c mol Mg vo dd A, sau p thu c dd c 3 mui.
Th nghim 2: thm 2c mol Mg vo dd A, sau p thu c dd c 2 mui.
Th nghim 3: thm 3c mol Mg vo dd A, sau p thu c dd c 1 mui.
Hy tm mi quan h gia a,b,c trong tng th nghim trn?
2. Thm 100 gam nc vo dung dch cha 20 gam CuSO4 th thy nng ca dd gim i 10%. Xc
nh nng % ca dd ban u.
Cu IV: (4 )
Chia 26,88 gam MX2 thnh 2 phn bng nhau:
Phn I: cho vo 500 ml dd NaOH d thu c 5,88 gam M(OH)2 kt ta v dd D.
Phn II: cho vo 360 ml dd AgNO3 1M thu c dd B v 22,56 gam AgX kt ta. Cho thanh Al
vo dd B thu c dd E, khi lng thanh Al sau khi ly ra cn li tng ln m gam so vi ban
u( ton b kim loi thot ra bm vo thanh Al). Cho dd D vo dd E thu c 6,24 gam kt ta.
( p xy ra hon ton).
a. Xc nh cng thc phn t MX2 v gi tr m?
b. Tnh nng mol/lt ca dung dch NaOH dng.
Cu V: (4 )
Ha tan hon ton m gam hn hp X gm Fe v Zn trong m1 gam dd H2SO4 98% (ly d) thu c dd Y
( bit rng khi lng dd trc v sau p khng i) v V lt SO2 (ktc).
a. Vit PTHH cc p xy ra.
b. Xc nh thnh phn % theo khi lng mi kim loi trong hn hp X.
c. Cho dd Y ha tan va m2 gam MgCO3 thu c 4,48 lt kh (ktc) v dd Z. Cho tip BaCl2 d vo
dd Z thu c 239,99 gam kt ta. Xc nh m,m1,m2, V?
Cu VI: (4 )
1. Vit CTCT c th c ca cc cht c CTPT C4H6.
2. Dn 6,72 lt hn hp kh gm 2 hirocacbon mch h qua dd brom d, sau khi p xy ra hon ton
thy khi lng bnh ng dd brom tng thm 5,6 gam ng thi thot ra 2,24 lt mt cht kh. Mt khc
t chy hon ton 2,24 lt kh cn li trn thy to ra 8,96 lt CO2. (th tch cc kh o ktc).
a. Xc nh CTPT ca 2 H-C.
b. Tnh thnh phn % theo th tch ca mi kh trong hn hp.
- HT-
TI LIU BD HSG HA
Trang 15
L Vit Hng
S GIO DC & O TO
C MAU
CHNH THC
( thi gm c 2 trang)
4
THI HC SINH GII VNG TNH LP 9 THCS
NM HC 2011-2012
Mn thi: Ho hc
Ngy thi: 22 4 2012
Thi gian: 150 pht (Khng k thi gian giao )
Cu I (3,5 im)
1. Vit phng trnh ha hc ca cc phn ng thc hin s chuyn i trc tip sau:
a. FeS H2S SO2 H2SO4 E
b. vi CaO X Y Z T
Cho bit E l mui sunfat ca kim loi R c phn t khi l 152 ; X, Y, Z, T u l mui
ca canxi vi cc gc axit khc nhau.
2. Vit phng trnh ha hc ca 5 phn ng khc nhau trc tip iu ch FeCl3.
Cu II (3,0 im)
1. Tnh cht ca hp cht hu c ph thuc vo trt t sp xp cc nguyn t trong phn t .
Hy ly th d chng minh.
2. Axit lactic c cng thc cu to : CH3 CHOH COOH. Da vo tnh cht cc cht hu c
hc, hy vit phng trnh ha hc ca phn ng gia axit lactic vi:
a. Mg
b. C2H5OH
c. Na
3. Cht hu c c cng thc phn t: C3H9N. Hy vit cc cng thc cu to ng vi cng thc
phn t trn.
Cu III (3,5 im)
1. C hn hp gm cc cht rn: SiO 2, CuO, BaO. Nu phng php tch ring tng cht ra
khi hn hp vi iu kin khng lm thay i khi lng cc cht. Vit phng trnh phn ng
xy ra (nu c).
2. C 4 dung dch khng mu b mt nhn: MgSO 4, NaOH, BaCl2, NaCl. Hy nu phng php
ha hc nhn ra tng dung dch khi ch c dng thm axit HCl lm thuc th, vit phng
trnh ha hc. Du hiu ta nhit trong phn ng trung ha khng c coi l du hiu nhn bit.
Cu IV (3,5 im)
1. Nhng cht no sau y c dng lm kh v khng lm kh kh CO 2. Ti sao ? Vit
phng trnh phn ng (nu c): P2O5, Fe3O4, H2SO4 (c), Na, CaO.
2. C 2 vt bn trn qun o: vt du nhn v vt du n. Hy chn trong s cc cht sau
lm sch vt bn, gii thch: nc, nc x phng, gim n, t-xng, cn 90o.
3. Dn hn hp kh gm: Hidro v CO ly d qua bnh ng cc oxit: Fe 2O3, Al2O3 v CuO
nung nng. Kt thc phn ng thu c cht rn B v hn hp kh C. Ha tan cht rn B vo
dung dch HCl thu c dung dch D, kh v rn khng tan. Dn kh C qua dung dch nc vi
trong ly d thu c cht kt ta. Cho dung dch NaOH ly d vo dung dch D thu c kt
ta c thnh phn mt cht duy nht. Vit cc phng trnh phn ng xy ra.
Cu V (2,0 im)
Trn a cn 2 cc ng dung dch HCl v H2SO4, cn v tr thng bng. Cho vo cc ng
dung dch HCl 25 gam CaCO3. Cho vo cc ng dung dch H2SO4 a gam Al cn vn v tr
thng bng. Tnh a ?
Cu VI (2,5 im)
Ly m gam hn hp E gm Al v Cu chia lm 2 phn:
- Phn 1 cho vo dung dch H2SO4 long, d thu c 2,688 lt kh.
- Phn 2 (nhiu hn phn 1 l 14,16 gam) cho tc dng ht vi H 2SO4 c, nng, ly d thu
c 14,336 lt kh. Tnh m v thnh phn phn trm khi lng mi kim loi c trong E. Bit
cc phn ng xy ra hon ton v th tch cc kh u o iu kin tiu chun.
Cu VII (2,0 im)
t chy hon ton cht hu c Y ngi ta thu c 14,336 lt kh CO 2 (ktc) v 5,76
gam H2O. cng iu kin nhit v p sut th tng th tch CO 2 v hi nc thu c bng
tng th tch ca Y v O2 tham gia phn ng.
TI LIU BD HSG HA
Trang 16
L Vit Hng
1. Xc nh cng thc phn t ca Y. Bit Y mch h, vit cng thc cu to ca Y.
2. Khi Y tc dng vi dung dch nc Brom theo t l s mol 1:2 thu c cht hu c Z.
Vit cng thc cu to c th c ca Z.
Cho C = 12; O = 16; H = 1; Ca = 40; S = 32;
Al = 27; Cu = 64; Fe = 56; Cl = 35,5.
---------- HT ----------
CHNH THC
GIO DC V O TO
TNH K NNG
5
K THI CHN HC SINH GII CP TNH LP 9 THCS
NM HC 2011-2012
Kha thi ngy: 17/3/2012
Mn thi: HA HC
Thi gian: 150 pht (khng k thi gian giao )
Cu 1. (3.0im)
1. mt hn hp gm Al, Fe, Cu, va Ag. Bng phng php ha hc hy tch ri hon ton cc
kim loi ra khi hn hp trn.
2. c 5 l mt nhn ng dung dch: NaOH, KCl, MgCl2, CuCl2, AlCl3.Hy nhn bit tng dung
dch trn m khng dng thm ha cht khc.vit c phng trnh phn ng xy ra.
Cu 2 (3.0 im)
Hon thnh cc phng trnh phn ng theo dy chuyn ha sau:
H2S + O2 (A)(rn) +(B)(lng)
(A)+ O2 (C)
MnO2 +HCl
(D)+(E)+(B)
(B)+(C)+(D)
(F)+(G)
(G)+ Ba
(H)+(I)
Cu 3(5.0 im)
Ly V1 lt HCl 0.6M trn V2 lt NaOH 0,4M. Tng V1+V2= 0,6 lt thu c dung dch A.bit rng 0,6 lt
dung dung dch A tc dng va vi 0,02 mol Al2O3.
Cu 4 (4.0 im):
Chia hn hp kim loi Cu, Al thnh 2 phn bng nhau :
Phn th nht nung nng trong khng kh ti phn ng hon ton thu c 18.2 g hn hp 2 Oxit. Ha
tna phn th hai va dung dch H2SO4 c nng thy bay ra 8,96 lit kh SO2 ktc
1. tnh % khi lng mi kim loi trong hn hp.
2. nu ha tan hon ton 14,93 gam kim loi X bng dung dch H2SO4 c nng v thu c mt
lng SO2 nh trn th X l kim loi g?
Cu 5(5.0 im)
Ha tan hn hp A thu c t s nung bt Al v S bng dung dch HCl ly d thy cn li 0.04 gam
cht rn v c 1,344 lt kh bay ra ktc.Cho ton b kh i qua dung dch Pb(NO3) ly d, sau phn
ng thu c 7,17 gam kt ta mu en.
Xc nh % Al v S trc khi nung
------HT-----(Hc sinh c s dng my tnh b ti v bng h thng tun hon cc nguyn t ha hc)
H v tn th sinh .....................................................S bo danh.........................................
TI LIU BD HSG HA
Trang 17
L Vit Hng
S GIO DC V O TO
IN BIN
CHNH THC
( thi c 02 trang)
6
K THI CHN HC SINH GII
NM HC 2011 -2012
Mn: Ha hc Lp 9
Ngy thi: 18/4/2012
Cu 1. (3 im)
1. Vit phng trnh ha hc cho dy chuyn ha sau (ghi r iu kin phn ng, nu c)
(6)
Cu (1) CuCl2 (2) Cu(OH)2 (3) CuO (4) CuSO4 (5) Cu(NO3)2
Cu
2. A, B, C l 3 cht hu c mch h c cc tnh cht sau: B lm mt mu dung dch brom, C tc

dng c vi Na, A tc dng c vi Na v NaOH. A, B, C l nhng cht no trong s cc cht sau:
C4H8, C2H4O2, C2H6O. Hy vit cng thc cu to ca cc cht trn.
Cu 2. (4,5 im)
1. Nu hin tng v vit cc phng trnh ha hc c th xy ra khi tin hnh cc th nghim sau:
a) t dy st trong trong bnh ng kh clo, ngui, sau nc vo bnh lc nh, ri nh t
t dung dch natri hidroxit vo bnh.
b) Cho mu vi vo dung dch axit axetic.
c) Sc lng d kh axetilen vo bnh ng dung dch nc brom.
d) Nh vi git dung dch phenolphtalein vo cc ng dung dch Ca(OH)2 long, sau nh t t
dung dch axit clohiric ti d vo cc.
2. Ch dng thm qu tm hy nhn bit cc dung dch sau ng trong cc l ring bit b mt nhn:
Na2SO4, KOH, BaCl 2, H2SO4, MgCl2. Vit cc phng trnh ha hc dng.
Cu 3. (3,5 im)
1. T etilen, cc ha cht v dng c cn thit c y , hy vit cc phng trnh ha hc (ghi
r iu kin) iu ch cc cht sau : axit axetic, etylaxetat.
2. t chy hon ton m gam hp cht hu c A cn va 8,96 lt O 2 thu c 8,96 lt CO2 (cc
kh o ktc) v 7,2 gam nc. Xc nh cng thc phn t ca A, bit trong cng iu kin nhit v
p sut m gam A c th tch hi ng bng th tch ca 6,4 gam O2.
Cu 4. (4,5 im)
1. Ha tan 23,2 gam mui RCO 3 bng dung dch axit H2SO4 long va , sau phn ng thu c
30,4 gam mui v V lt CO2 ( ktc).
a) Tnh V v tm R.
b) Nhng mt thanh kim loi Zn nng 20 gam vo dung dch mui sunfat thu c trn, sau khi
phn ng xy ra hon ton ly thanh kim loi Zn ra ra sch, sy kh, cn nng bao nhiu gam? Gi s
kim loi sinh ra bm ht vo thanh Zn.
2. t chy hon ton V lt etilen ( ktc), cho tt c sn phm chy hp th hon ton vo bnh
ng 500 ml dung dch Ca(OH)2 0,2M thy to thnh 8 gam kt ta .
a) Tnh V.
b) Sau th nghim khi lng bnh ng dung dch Ca(OH)2 tng hay gim bao nhiu gam?
Cu 5. (4,5 im)
1. Cho 30,4 gam hn hp X gm Fe, Fe2O3, FeCO3 tc dng va vi 1,8 lt dung dch HCl, thy
thot ra mt hn hp kh c t khi i vi H2 l 15 v to thnh 51,55 gam mui clorua.
a) Tnh thnh phn % khi lng ca mi cht trong hn hp X.
b) Tnh nng mol ca dung dch HCl dng.
2. Cho 0,92 gam Na vo 400 gam dung dch CuSO4 3,2%, thu c kh A, kt ta B v dung dch C.
a) Tnh th tch kh A ( ktc) v khi lng kt ta B.
b) Tnh nng % cht tan trong dung dch C.
Cho nguyn t khi: H =1; C = 12; O = 16; Na = 23; Mg = 24; Al =27; S = 32; Cl = 35,5; Ca =
40; Fe = 56; Cu = 64; Zn= 65; Ba = 137.
....................... Ht ......................
Ghi ch: Th sinh khng c php s dng bng tun hon cc nguyn t ho hc
TI LIU BD HSG HA
Trang 18
L Vit Hng
S GIO DC V O TO GIA LAI

CHNH THC
Cu 1. (3,0 im)
a. Hon thnh chui chuyn ho:
A
G
+B S
(lu hunh)
+ NaOH, , t
(1)
(2)
7
K THI CHN HC SINH GII LP 9 CP TNH
Nm hc 2011-2012
MN: HO HC
Thi gian: 150 pht (khng k thi gian pht )
+ HCl
(3)
+ HCl
(7)
B
G
+NaOH
(4)
+NaOH
(8)
C +NaOH
+Ba(OH)2
H +NaOH
+AgNO3
(5)
(9)
(6)
(10)
E kt ta trng
J kt ta en
b. Ch dng thm nc v kh cacbonic hy trnh by phng php nhn bit cc cht rn: Na 2CO3,
Na2SO4, NaCl, BaCO3 v BaSO4.
Cu 2. (3,0 im) a. Nu hin tng, gii thch, vit phng trnh phn ng xy
Hn hp kh
ra khi p ng nghim cha y hn hp kh C 2H2 v C2H4 vo chu thu tinh cha
C2H2 v C2H4
dung dch nc brom (nh hnh bn).
Dung dch
nc brom
b. T nhm cacbua v cc cht v c cn thit hy vit phng trnh phn ng
iu ch vinyl axetat v hexacloxiclohexan.
Cu 3. (2,0 im) t chy hon ton cht hu c Z (cha C, H v O) thu c CO 2 v H2O c t l khi
lng l 88:45.
- Tm cng thc phn t ca Z, bit trong phn t Z c mt nguyn t oxi.
- Vit cng thc cu to c th c ca Z, bit Z c mt s tnh cht ho hc ging ru etylic.
Cu 4. (2,0 im) Y l cht hu c cha cc nguyn t C, H, O v N. t chy hon ton 0,75 gam Y thu
c hn hp sn phm gm CO2, H2O v N2, cho hon ton sn phm chy vo dung dch Ca(OH)2 d
thu c 2 gam kt ta v khi lng bnh tng 1,33 gam. Tm cng thc phn t ca Y (bit MY = 75).
Cu 5. (3,0 im) Cho 3,07 gam hn hp bt kim loi X gm Al v Fe vo 150 ml dung dch hn hp
gm Fe(NO3)3 1,0 M v AgNO3 0,5 M, khuy u, sau phn ng thu c m gam kim loi v dung dch
Y (cha ba mui). Cho t t dung dch NaOH d, ly kt ta nung n khi lng khng i c 16,0
gam cht rn khan. Bit cc phn ng xy ra hon ton.
a. Vit phng trnh phn ng c th xy ra.
b. Tnh m v phn trm khi lng ca Al v Fe trong X.
Cu 6. (3,0 im)
a. Cho 14,4 gam hn hp Z gm mui cacbonat v hidrocacbonat ca cng mt kim loi kim (M) phn
ng vi dung dch HCl d, phn ng hon ton thu c 2,8 lt kh CO 2 (ktc). Tm M, tnh phn trm
khi lng cc mui trong Z.
b. X l dung dch HCl 0,3 M, Y l dung dch hn hp Na 2CO3 0,15 M v NaHCO3 0,1 M. Tnh th tch
CO2 sinh ra (ktc) khi:
- Cho t t 100 ml dung dch X vo 100 ml dung dch Y v khuy u.
- Cho t t 100 ml dung dch Y vo 100 ml dung dch X v khuy u.
Cu 7. (2,0 im) Trn 0,2 lt dung dch H 2SO4 x M vi 0,3 lt dung dch NaOH 1,0 M thu c dung
dch A. phn ng vi A cn ti a 0,5 lt dung dch Ba(HCO 3)2 0,4 M, sau phn ng thu c m gam
kt ta. Tnh gi tr ca x v m.
Cu 8. (2,0 im) Ho tan hon ton 5,28 gam hn hp X gm Cu v mt oxit st (Fe xOy) trong H2SO4
c nng (d). Sau khi phn ng xy ra hon ton thu c 448 ml kh SO 2 (ktc) v dung dch. C cn
dung dch thu c 13,6 gam hn hp mui khan Y.
a. Vit phng trnh phn ng xy ra.
b. Tm cng thc phn t ca oxit st, tnh phn trm khi lng cc cht trong Y.
Ht
TI LIU BD HSG HA
Trang 19
L Vit Hng
Hc sinh c s dng bng h thng tun hon v my tnh b ti.
Kt qu:
Cu 1:
a. G: H2S; B: SO2 ; A; Na2SO3; C: NaHSO3; E; BaSO3; F: Na2S; G; H2S; H; NaHS; Na2S; J: Ag2S
b. T nghin cu
Cu 2:a. Dung dch nhc mu, nc dng ln trong ng nghim.. T vit spTHH
. b:C6H6Cl6 (Thuc su 666, hin nay cm s dng v phn hy trong mi trng chm);
CH3COOCH=CH2 Vynyl etat
Cu 3: C4H10O, tm h s bt bo ha k =
4 x 2 10 + 2
= 0 => Khng c lin kt pi, ru n chc
2
no,Vit 4 ng phn
Cu 4: C2H5O2N (HS nhm v c N2 trong bnh nn lm d sai). y cho sn phm chy l c c N 2 vo
nhng khi lng bnh tng l ta ch tnh khi lng hp th vo nc vi, cn nito khng tnh. SP chy
khng phi l CO2 v H2O
Cu 5: a. Vit 10 PTHH
b. %mFe = 91,2%; %mAl = 8,8%
Cu 6: a. M l K; %m K2CO3 = 47,92%; mui cn li ly 100% tr
Cu 7: TH1: NaOH ht => H2SO4 d => m = 46,6g
TH2: NaOH d, H2SO4 ht => m= 43g
Cu 8: Fe3O4; %mCuSO4 = 11,76% cn li tr ra
Cu 4 nn sa li "cho hon ton sn phm chy vo dung dch Ca(OH)2 d thu" nn thay bng t
cho hon ton sn phm chy qua dung dch Ca(OH)2 d thu
TI LIU BD HSG HA
Trang 20
L Vit Hng
8
K THI CHON HOC SINH GIOI TINH
LP 9 THCS NM HOC 2011-2012
Mn: Hoa hoc
Thi gian: 150 phut (khng k giao )
Ngay thi: 23/3/2012
S GIAO DUC VA AO TAO

HAI DNG
THI CHINH THC
Cu I. ( 2,0 im)
1. Nung nong hn hp Cu, Ag trong O2 d, sau phan ng thu c cht rn A. Cho A vao dung
dich H2SO4 c nong d thu c dung dich B va khi C. Khi C tac dung vi dung dich KOH thu c
dung dich D. Dung dich D va tac dung vi BaCl2, va tac dung vi NaOH.
Xac inh thanh phn cac cht co trong A, B, C, D. Vit phng trinh cac phan ng xay ra trong thi
nghim trn.
2. Ch dng mt thuc th, trnh by cch nhn bit cac cht bt mau trng ng trong cac lo ring
bit mt nhan sau: BaCO3, BaSO4, Na2SO4, Na2CO3, MgCO3, CuSO4 (khan).
Vit cac phng trinh phan ng xay ra (nu co).
Cu II. ( 1,75 im)
1. Cho hn hp gm ru etylic, axit axetic, nc. Trinh bay phng phap tach ring ru etylic
nguyn cht va axit axetic (c th ln nc) t hn hp trn? Vit phng trinh phan ng minh hoa (nu
c).
2. Khi thc hin phan ng chuyn hoa metan thanh axetilen thu c hn hp khi X gm metan,
axetilen va hidro. t chay hoan toan X cn 6,72 lt O 2 (ktc). San phm chay c hp thu ht vao dung
dich cha 0,1 mol Ca(OH)2.
a. Tinh khi lng cua hn hp X?
b. Hay cho bit dung dich thu c sau khi hp thu san phm chay co khi lng thay i nh th
nao so vi dung dich Ca(OH)2 ban u?
Cu III. ( 2,0 im)
Cho 37,2 gam hn hp X gm: R, FeO, CuO (R la kim loai chi co hoa tri II, hidroxit cua R khng
co tinh lng tinh) vao 500 gam dung dich HCl 14,6 % (HCl dung d), sau phan ng thu c dung dich
A, cht rn B nng 9,6 gam (chi cha mt kim loai) va 6,72 lt H 2 (ktc). Cho dung dich A tac dung vi
dung dich KOH d, thu c kt tua D. Nung kt tua D trong khng khi n khi lng khng i thu
c 34 gam cht rn E gm hai oxit.
1. Tim R va % khi lng cua mi cht trong hn hp X .
2. Tinh nng phn trm cua cac cht trong dung dich A.
Cu IV. ( 2,0 im)
Hn hp X gm (Al va oxit Fe xOy). Nung m gam X trong iu kin khng co khng khi, khi o
t0
xay ra phan ng: Al + FexOy
Al2O3 + Fe (phan ng cha c cn bng). Sau phan ng thu c
hn hp cht rn Y. Chia Y thanh hai phn:
Phn 1: cho tac dung vi dung dich NaOH d, sau phan ng thu c 1,68 lit khi va 12,6 gam cht rn.
Phn 2: cho tac dung vi dung dich H2SO4 c nong d, sau phan ng thu c 27,72 lt SO 2 va dung
dich Z c cha 263,25 gam mui sunfat. Bit cac phan ng xay ra hoan toan, cac khi o ktc.
1. Vit phng trinh cac phan ng xay ra.
2. Tim m va cng thc phn t cua oxit FexOy
Cu V. ( 2,25 im)
t chay hoan 6,72 lt hn hp kh gm hai hidrocacbon mach h co cng thc C nH2n+2 (A) va
CmH2m (B) thu c 13,44 lit CO2 va 14,4 gam nc. Cc th tch kh o ktc.
1. Tim cng thc phn t cua hai hidrocacbon.
2. T B (mach khng nhanh) vit cac phng trinh phan ng iu ch CH 3COONa khng qua 3
giai oan (khng qua 3 phan ng), cac cht v c va iu kin phan ng xay ra co u.
3. Tim cng thc cu tao co th co cua B thoa man: khi cho B tac dung vi H 2O, xuc tac H2SO4
thi thu c hn hp hai san phm hu c. Vit cac phng trinh phan ng.
Cho: Ag = 108; Al = 27; Ba = 137; C=12; Ca = 40; Cl =35,5; Cu = 64; Fe = 56;H = 1;
Mg = 24; Mn = 55; Na = 23; O = 16; Pb= 207; S = 32; Zn = 65.
Ht
TI LIU BD HSG HA
Trang 21
L Vit Hng
Hng dn chm v biu im
KI THI CHON HOC SINH GIOI TINH
LP 9 THCS NM HOC 2011-2012
Mn: ha hc
Ngy thi 23/3/2012
S gio dc & o to
Hi Dng
Cu
I
Ni dung
im
2,0
- Cht rn A gm CuO, Ag
t0
2Cu + O2
2CuO
(Ag khng phn ng vi kh oxi)
- Cho A vo dd H2SO4 c nng:
t0
CuO + H2SO4()
CuSO4 + H2O
t0
2Ag + 2H2SO4()
Ag2SO4 + SO2 + 2H2O
- Dung dch B gm CuSO4, Ag2SO4, H2SO4 d.
- Kh C l SO2. Cho C tc dng vi dd KOH.
SO2 + 2KOH K2SO3 + H2O
SO2 + KOH KHSO3
- Dung dch D gm 2 cht tan K2SO3, KHSO3.
K2SO3 + BaCl2 BaSO3 + 2KCl
KHSO3 + NaOH Na2SO3 + K2SO3
0,25
0,25
0,25
0,25
- Dng dung dch H2SO4 long nhn bit.

- Ly mu th ra cc ng nghim khc nhau, nh du tng ng. Nh dung dch
H2SO4 long, d vo cc ng nghim.
+ Cht rn phn ng to kt ta trng, gii phng kh l BaCO3
+ Cht rn khng tan trong dung dch H2SO4 l BaSO4.
+ Cht rn tan tan to dung dch khng mu, khng gii phng kh l Na2SO4
+ Cht rn tan tan to dung dch mu xanh, khng gii phng kh l CuSO4.
+ 2 cht rn tan, gii phng kh l MgCO3 v Na2CO3.
- Cho tip t t n d 2 cht rn cha nhn bit c (MgCO3 v Na2CO3) vo 2
dung dch ca chng va to thnh.
+ Cht rn no khi ngng thot kh m vn tan l Na2CO3
+ Cht rn no khi ngng thot kh m khng tan thm l MgCO3.
BaCO3 + H2SO4 BaSO4 + CO2 + H2O
MgCO3 + H2SO4 MgSO4 + CO2 + H2O
Na2CO3 + H2SO4 Na2SO4 + CO2 + H2O
II
0,75
0,25
1,75
- Cho hn hp tc dng vi dung dch NaOH d, chng ct thu ly ru etylic ln

nc v cht rn khan cha CH3COONa, NaOH d.
CH3COOH + NaOH CH3COONa + H2O
- Cho CuSO4 khan, d vo hn hp ru v nc, lc b cht rn thu c ru
1
etylic nguyn cht.
- Cho hn hp cht rn tc dng vi dung dch H2SO4 d. Chng ct thu ly
CH3COOH (ln nc).
2CH3COONa + H2SO4 CH3COOH + Na2SO4
- V khi lng ca nguyn t C, H c bo ton trong cc phn ng ho hc nn
khi lng ca kh metan ban u bng vi khi lng ca hn hp X.
2a - Khi t chy lng kh CH4 ban u v t chy X s cho cng lng CO2, H2O
v cng cn lng kh oxi phn ng nh nhau nn ta coi t chy X chnh l t
lng kh CH4 ban u.
TI LIU BD HSG HA
Trang 22
L Vit Hng
0,25
0,25
0,25
0,25
6, 72
nO 2 = 22, 4 = 0,3 mol
t0
CH4 + 2O2
CO2 + H2O
0,15
0,3
0,15
0,3
Vy khi lng ca hn hp X l: mX = 0,15.16 = 2,4 gam.
- Khi lng ca CO2 v nc c hp th vo dung dch Ca(OH)2 l:
0,15.44 + 0,3.18 = 12 gam.
- Cc phng trnh phn ng:
CO2 + Ca(OH)2 CaCO3 + H2O
0,1
0,1
2b 0,1
CO2 + H2O + CaCO3 Ca(HCO3)2
0,05
0,05
0,05
- Khi lng dung dch sau phn ng tng ln so vi dung dch Ca(OH)2 ban u
l: 12 (0,1- 0,05).100 = 7 gam.
III
0,25
0,25
0,25
2,0
Tim R va % khi lng cac cht trong X

nHCl = (500.14,6)/(100.36,5) = 2 mol;
nH 2 = 6,72/22,4= 0,3 mol
-Cho X + dd HCl d:
Vi san phm co H2, nn R la kim loai ng trc H trong day hot ng ho hc,
nn R ng trc ca Cu.
Vi axit d nn sau phan ng khng th co R d, m 9,6 gam cht rn B chi cha
mt kim loai, suy ra phai co phan ng cua R vi mui CuCl2 tao ra Cu kim loai v
hiroxit ca R s khng tan trong nc ( y FeCl2 cha phan ng vi R do mc
phan ng cua CuCl2 vi R cao hn so vi FeCl2). Do o B l Cu.
Dung dich A co RCl2, FeCl2 va HCl d. V dung dich A tac dung vi KOH d thu
kt tua D, sau o nung D n hoan toan thu c 34 gam cht rn E gm 2 oxit,
suy ra 2 oxit nay la RO va Fe2O3. Nh vy trong dung dich A khng co CuCl2.
R + 2HCl RCl2 + H2
(1)
FeO + 2HCl FeCl2 + H2O (2)
CuO + 2HCl CuCl2 + H2O (3)
R + CuCl2 RCl2 + Cu
(4)
- Cho dung dich A tac dung dung dich KOH d:
1
HCl + KOH KCl + H2O
(5)
RCl2 + 2KOH R(OH)2 + 2KCl (6)
FeCl2 + 2KOH Fe(OH)2 + 2KCl (7)
Nung kt tua ngoai khng khi:
t0
R(OH)2
(8)
RO + H2O
t0
2Fe(OH)2 + O2
Fe2O3 + 2H2O (9)
E gm hai oxit: RO va Fe2O3
nCu = 9,6/64 = 0,15 mol
Theo p (3),(4): nCuO = nCuCl2 = nCu = 0,15 mol
Theo p (1), (4): nRCl2 = nR = nH2 + nCuCl2 = 0,3 + 0,15 = 0,45 mol
Theo p (6)(8): nRO = nR(OH)2 = nRCl2 = 0,45 mol
t nFeO ban u = x mol
Theo cac phan ng (2),(7),(9): nFe2O3 = .nFeO = 0,5x (mol)
Ta co: mE = mRO + mFe2O3 = 0,45.(MR + 16) + 0,5x.160 = 34 gam (*)
mX = mR + mFeO + mCuO = 0,45.MR + 72x + 80.0,15 = 37,2 gam
(**)
Giai h (*), (**) ta c: MR = 24;
x = 0,2
Vy R la Mg
T o tinh c % khi lng cac cht trong hn hp X:
TI LIU BD HSG HA
Trang 23
L Vit Hng
0,25
0,5
0,5
%mMg = mMg.100/mX = (0,45.24.100)/37,2 = 29,0%
%mFeO = 0,2.72.100/37,2 = 38,7%
%mCuO = 32,3%
0,25
Tinh nng phn trm cac cht trong dung dich A:

A co : MgCl2, FeCl2, HCl d
mMgCl2 = 0,45. 95 = 42,75 gam
mFeCl2 = 0,2.127 =25,4 gam
Ta co: nHCl p = nCl trong mui = 2.nMgCl2 + 2.nFeCl2 = 1,3 mol
=> mHCl d = 500.0,146- 1,3.36,5 =25,55 gam
2 Ap dung inh lut BTKL:
mddA = mX + mdd HCl ban u mB mH2 = 527 gam
T o tinh c nng phn trm cua cac cht trong dung dich A:
C%(MgCl2) = 8,11%
C%(FeCl2) = 4,82%
C%(HCl) = 4,85%
IV
0,25
0,25
2,0
Cac phng trinh phan ng:

t0
3FexOy + 2yAl
(1)
3xFe + yAl2O3
Cho phn 1 vao dung dich NaOH d co khi, suy ra trong cht rn co Al d. Vi Al
con d, ma phan ng xay ra hoan toan nn FexOy ht. Vy thanh phn cua Y co:
Al2O3, Fe va Al d.
Phn 1 tc dng vi dung dich NaOH d:
Al2O3 + 2NaOH 2NaAlO2 + H2O
(2)
1
2Al + 2NaOH + 2H2O 2NaAlO2 + 3H2 (3)
12,6 gam cht rn khng tan la Fe
Phn 2 tac dung vi H2SO4 c nong d:
t0
Al2O3 + 3H2SO4()
Al2(SO4)3 + 3H2O (4)
0
t
2Al + 6H2SO4()
Al2(SO4)3 + 3SO2 + 6H2O (5)
t0
2Fe + 6H2SO4()
Fe2(SO4)3 + 3SO2 + 6H2O (6)
T p(3) co nAl = 2/3.nH 2 = 0,05 mol
Lai co: nFe = 12,6/56 = 0,225 mol
Vy trong phn 1 co ( Al2O3, Fe (0,225 mol), Al(0,05 mol))
- Gia s phn 2 co khi lng gp a ln phn 1. T o suy ra trong phn 2 co:
( Al2O3, Fe(0,225a mol) va Al (0,05a mol)
T p (5) va (6) suy ra:
0,5
0,5
nSO 2 = 3/2.(nAl + nFe) = 3/2.(0,05a + 0,225a) = 27,72/22,4= 1,2375 .

T o tinh c a = 3.
Suy ra trong phn 2 co: 0,675 mol Fe va 0,15 mol Al
Mt khac, tng khi lng mui sunfat = m Al2 ( SO4 )3 + m Fe2 ( SO4 )3 = 263,25 gam (7)
2 Theo p (4), (5): n Al2 ( SO4 )3 = n Al2O3 + . nAl = n Al2O3 + 0,075
Theo p (6): n Fe2 ( SO4 )3 = .nFe = 0,3375 mol
Thay cac s mol vao pt(7) se tinh c n Al2O3 = 0,3 mol
0,5
Vy khi lng cua phn 2 la: mphn 2 = m Al2O3 + mFe + mAl = 0,3.102 + 0,675.56 +
0,15.27 = 72,45 gam
=> khi lng cua phn 1 la: mphn 1 = 72,45/3 =24,15 gam
T o tinh c m = mphn 1 + m phn 2 = 96,6 gam
* Tim oxit:
Xet phn 2: t pt (1) co:
3x : y = nFe : n Al2O3 = 0,675 : 0,3 => x : y = 3: 4 Vy oxit la Fe3O4
TI LIU BD HSG HA
Trang 24
L Vit Hng
0,5
2,25
V
nhh = 0,3 mol; n(CO2) = 0,6 mol; n(H2O) = 0,8 mol
t s mol hai cht CnH2n+2 va CmH2m ln lt la x va y mol
=> nhh = x + y = 0,3 mol (*)
t hn hp:
t0
CnH2n+2 + O2
n CO2 + (n+1) H2O (1)
Mol
x
nx
(n+1)x
3m
t0
CmH2m +
O2
(2)
m CO2 + m H2O
2
Mol
y
my
my
1
0,25
T cac p (1) va (2) ta co:

nCO2 = nx + my = 0,6
(**)
nH2O = (n+1)x + my = 0,8 (***)
Ly (***)-(**) ta c x = 0,2;
Thay x vao (*) suy ra y = 0,1
Thay x, y vao (**) ta c: 0,2n + 0,1m = 0,6 hay 2n + m = 6
Th cac gia tri cua m, ta c n:
n
1
2
3
m
4
2
0
CTPT A (CH4); B(C4H8) A(C2H6); B(C2H4)
Loai
T B vit phng trinh iu ch CH3COONa (khng qua 3 giai oan):
- Nu B la C4H8:
C4H8 + H2 C4H10
xt , t 0
2 C4H10 + 5 O2
4 CH3COOH + 2 H2O
- Nu B la C2H4:
axit
C2H4 + H2O
C2H5OH
men
C2H5OH + O2
CH3COOH + H2O
0,25
0,5
0,25
0,25
Vi B tac dung H2O co H2SO4 lam xuc tac thu c hn hp 2 san phm hu c, cho
nn B khng th la C2H4. Vy B phai la C4H8.
Vi co hai san phm c tao ra nn CTCT cua B thoa man la:
CH2 =CH-CH2-CH3 va CH2=C(CH3)2
Ptp:
3
axit
CH2 =CH-CH2-CH3 + H2O
CH3-CHOH-CH2-CH3
axit
CH2 =CH-CH2-CH3 + H2O HO-CH2-CH2-CH2-CH3
axit
CH2=C(CH3)2 + H2O
(CH3)3C-OH
axit
CH2=C(CH3)2 + H2O HO-CH2-CH(CH3)2
0,25
0,25
0,25
Ch :
-
Nu phng trnh khng cn bng th tr na s im ca phng trnh . Hc

sinh c cch gii khc tng ng ng vn cho im ti a.
im ton bi lm trn n 0,25
TI LIU BD HSG HA
Trang 25
L Vit Hng
S GIO DC V O TO
LNG SN
9
K THI CHN HC SINH GII CP TNH
LP 9 THCS NM HC 2011 2012
CHNH THC
Mn thi: HA HC
Ngy thi: 22/03/2012
( thi gm 2 trang v c 6 cu)
Cu 1. (3,5 im)
1. Trong cng nghip, kh NH3 mi iu ch thng ln hi nc. lm kh kh NH3 ngi ta
c th dng ha cht no sau y: H2SO4 c, dung dch HCl c, P2O5, CaO, KOH khan? Gii thch, vit
phng trnh ha hc ca phn ng xy ra ( nu c).
2. C mt hn hp kh gm: CO2, CH4, C2H4. Hy trnh by phng php ha hc :
a. Thu c kh CH4 tinh khit t hn hp trn.
b. Thu c CO2 tinh khit t hn hp trn.
Cu 2. ( 3,5 im)
Nhng mt thanh st v mt thanh km vo cng mt cc cha 500ml dung dch CuSO4. Sau mt
thi gian ly ng thi hai thanh kim loi ra khi cc th mi thanh u c kim loi ng bm vo, khi
lng dung dch gim i 0,22 gam so vi ban u. Trong dung dch sau phn ng, nng mol ca
ZnSO4 ln gp 2,5 ln nng mol ca FeSO4 ( th tch dung dch coi nh khng i so vi trc phn
ng). Thm dung dch NaOH d vo cc, lc ly kt ta ri nung trong khng kh ti khi lng khng
i, thu c 14,5 gam cht rn.
a. Vit phng trnh ha hc ca phn ng c th xy ra.
b. Tnh s gam Cu bm ln mi thanh kim loi v nng mol ca dung dch CuSO4 ban u.
Cu 3. (3,5 im)
1. Vit cc phng trnh ha hc hon thnh s phn ng sau (Bit A1, A2, A3, A4, A5 l cc
cht v c):
+ A3 ti l1:1 ( t o , Pd )
+ A2
+ A3 til1:1(t o , Ni )
A1 C2 H 2
C2 H 4
C2 H 6
(1)
(2)
+ A4 d
(3)
(4)
+A2
(5)
H2SO4 long
+ A5
C2H2Br4
C2H5OH
A3
(6)
2. t chy hon ton 224 ml (ktc) mt hidrocacbon th kh c cng thc tng qut l CnH2n + 2,
sn phm chy hp th vo 2 lt dung dch Ba(OH)2 0,01M, sau phn ng hon ton thu c 1,97 gam
kt ta. Xc nh cng thc phn t ca hidrocacbon.
Cu 4. ( 3 im)
90oC c 540 gam dung dch CuSO4 bo ha. Lm lnh dung dch xung cn 15oC. Hi c bao
nhiu gam tinh th CuSO4.5H2O tch ra khi dung dch trong qu trnh lm lnh. Bit tan SCuSO4 (90oC)
= 80 gam v SCuSO4 (15oC) = 25 gam.
Cu 5 ( 3,5 im)
Dung dch A cha hn hp Na2CO3 0,75M v NaHCO3 0,5M. Dung dch B cha H2SO4 1M. Tnh
th tch kh CO2 (ktc) thot ra khi:
a. rt t t 100 ml dung dch A vo 150 ml dung dch B.
b. rt t t 200 ml dung dch A vo 150 ml dung dch B.
c. rt t t 150 ml dung dch B vo 200 ml dung dch A.
Cu 6. ( 3 im)
TI LIU BD HSG HA
Trang 26
L Vit Hng
C 7 l ng 7 dung dch mt nhn c nh s t (1) n (7) gm: (NH4)2CO3, BaCl2, MgCl2,
H2SO4, Ba(OH)2, NaOH, Na2CO3. Thc hin cc th nghim c kt qu nh sau:
- Cht (1) tc dng vi cht (4) hoc (5) u to ra kt ta; tc dng vi cht (2) hoc (7) u to
ra kh.
- Cht (2) tc dng vi cht (4) hoc (5) u to ra kt ta; tc dng vi cht (3) to ra kh; tc
dng vi cht 6 th to ra c kt ta ln kh.
- Cht (5) tc dng vi cht (3), (6) hoc (7) u to ra kt ta.
- Cht (7) tc dng vi cht (4) hoc (6) u to ra kt ta.
Hy bin lun xc nh cc cht t (1) n (7). ( Hc sinh khng cn vit phng trnh ha hc ca
cc phn ng xy ra cu ny).
HT
Hc sinh c s dng bng tun hon
TI LIU BD HSG HA
Trang 27
L Vit Hng
S GIO DC V O TO
LONG AN
CHNH THC
10
MN THI: HA HC
NGY THI: 11/ 4/ 2012
THI GIAN:150 PHT (khng k thi gian pht )
Cu 1: (2 im) Hp cht A c cng thc R2X, trong R chim 74,19% v khi lng. Trong ht
nhn ca nguyn t R c s ht khng mang in nhiu hn s ht mang in l 1 ht. Trong ht nhn
nguyn t X c s ht mang in bng s ht khng mang in. Tng s proton trong phn t R 2X l 30.
Tm cng thc phn t ca R2X.
Cu 2: (6 im)
2.1/ (3 im) Hn hp A gm cc dung dch: NaCl, Ca(HCO3)2, CaCl2, MgSO4, Na2SO4. Lm th
no thu c mui n tinh khit t hn hp trn?
2.2/ (3 im) Ha tan hon ton 13,45g hn hp 2 mui hidro cacbonat v cacbonat trung ca 1 kim
loi kim bng 300ml dung dch HCl 1M. Sau phn ng phi trung ha HCl d bng 75ml dung dch
Ca(OH)2 1M.
a. Tm cng thc 2 mui.
b. Tnh khi lng mi mui c trong hn hp ban u.
Cu 3: (5 im)
3.1/ (2 im) Xc nh B, C, D, E, G, M. Bit A l hn hp gm Mg v Cu. Hy vit phng trnh
ha hc thc hin s chuyn ha sau:
Dung dch D
+
Na
+O2 d
+ dd HCl
A
B
C
Kh E
Nung
+ E, t0
Kt ta G
B
M
3.2/ (3 im) Cho M l kim loi to ra hai mui MClx, MCly v to ra 2 oxit MO0,5x, M2Oy c thnh
phn v khi lng ca Clo trong 2 mui c t l 1 : 1,173 v ca oxi trong 2 oxit c t l
1 : 1,352.
a. Xc nh tn kim loi M v cng thc ha hc cc mui, cc oxit ca kim loi M.
b. Vit cc phng trnh phn ng khi cho M tc dng ln lt vi MCly; H2SO4 c, nng.
Cu 4: ( 3 im) t chy hon ton 2,24 l (ktc) mt hirocacbon A th kh. Sau dn ton b sn
phm chy qua bnh ng dung dch Ca(OH)2 c cha 0,2 mol Ca(OH)2 th c 10g kt ta to nn, ng
thi thy khi lng bnh tng thm 18,6g.
a. Xc nh cng thc phn t ca A.
b. Vit cng thc cu to c th c ca A.
Cu 5: (4 im) Cho 13,6g hn hp gm Fe v Fe2O3 tc dng hon ton vi 91,25g dung dch HCl
20% va .
a. Tnh thnh phn phn trm v khi lng ca mi cht c trong hn hp ban u.
b. Tnh nng phn trm ca cht tan c trong dung dch sau phn ng.
c. Nu ha tan hon ton 13,6g hn hp ni trn vo H 2SO4 c, nng, khi phn ng kt thc dn
ton b kh sinh ra vo 64 ml dung dch NaOH 10% (D = 1,25g/ml) th thu c dung dch A. Tnh nng
mol ca cht tan c trong dung dch A.( Bit rng th tch dung dch thay i khng ng k)
---HT--Ch : Hc sinh c php s dng bng tun hon cc nguyn t ha hc.
TI LIU BD HSG HA
Trang 28
L Vit Hng
S GIO DC V O TO
LONG AN
CHNH THC
TI LIU BD HSG HA

MN THI: HA HC
NGY THI: 11/ 4/ 2012
THI GIAN: 150 PHT (khng k thi gian pht )
HNG DN CHM
Trang 29
L Vit Hng
Cu
Cu 1
2
Cu 2
2.1
3
2.2
3
p n
t s proton, notron l P, N
2 M R x100
= 74,19
Ta c:
(1)
2M R + M X
NR - PR = 1 => NR = PR + 1
(2)
PX = N X
(3)
2PR + PX = 30 => PX = 30 - 2PR (4)
M M = P + N
(5)
Th (2),(3),(4), (5)vo (1) ta c:
PR + N R
= 0, 7419
PR + N R + PX
2 PR + 1
= 0, 7419
2 PR + 1 + 30 2 PR
2P + 1
= 0,7419
R
31
PR = 11 (Na)
Th PR vo (4) => PX = 30 22 = 8 ( Oxi)
Vy CTHH: Na2O
im
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
Cho dung dch BaCl2 d vo dung dch A, lc b kt ta, dung dch cn

li: NaCl, MgCl2, BaCl2 d, CaCl2, Ca(HCO3)2.
BaCl2 + MgSO4 BaSO4 + MgCl2
Na2SO4 + BaCl2 BaSO4 + 2NaCl
- Cho dung dch Na2CO3 d vo dung dch cn li, lc b kt ta, dung
dch cn li: NaCl, NaHCO3, Na2CO3 d.
MgCl2 + Na2CO3 MgCO3 + 2NaCl
BaCl2 + Na2CO3 BaCO3 + 2NaCl
CaCl2 + Na2CO3 CaCO3 + 2NaCl
Ca(HCO3)2 + Na2CO3 CaCO3 + 2NaHCO3
- Cho dung dch HCl d vo dung dch cn li.
- c cn dung dch thu c NaCl tinh khit.
NaHCO3 + HCl NaCl + CO2 + H2O
Na2CO3 + 2HCl 2NaCl + CO2 + H2O
a. nHCl = 0,3 x 1 = 0,3 mol
nCa ( OH )2 = 0,075 x 1 = 0,075 mol
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
AHCO3 + HCl ACl + CO2 + H2O

x
x
(mol)
0,25
A2CO3 + 2HCl 2ACl + CO2 + H2O

y
2y
(mol)
0,25
Ca(OH)2 + 2HCl CaCl2 + 2H2O

0,075
0,15
(mol)
Ta c: x + 2y = 0,15
Vi 0 < y < 0,075
Mt khc: Ax + 61x + 2Ay +60y = 13,45
A ( 0,15 2y) + 61 ( 0,15 2y ) + 2Ay +60y = 13,45
0,15A - 2Ay + 9,15 - 122y + 2Ay + 60y = 13,45
0,15A - 4,3 = 62y
0,15 A 4,3
y=
62
0,15 A 4,3
Vi y > 0 =>
>0
62
A > 28,7 (1)
0,15 A 4,3
TI LIU BD HSG
Vi yHA
< 0,075
=>0 0 Trang 30< 0,075
00 0
tt t t t 62
0,25
0,25
0,25
0,25
0,25
L Vit Hng
0,25
Ch :
Hc sinh c th gii cch khc, ng vn hng trn s im.
Ht
TI LIU BD HSG HA
Trang 31
L Vit Hng
S GD&T NGH
AN
11
K THI CHN HC SINH GII TNH LP 9 CP THCS
NM HC 2011 2012
Mn thi: HA HC - BNG A
Thi gian lm bi: 120 pht
chnh thc
Bi 1: (4,5 im)
1. Vit bn phng trnh ha hc trc tip to ra HCl t Cl2 bng bn cch khc nhau (cc cch
khc nhau nu cht tc dng vi Cl2 khc loi).
2. Chn 7 cht rn khc nhau m khi cho mi cht tc dng vi dung dch H 2SO4 c, nng, d
u cho sn phm l Fe2(SO4)3, SO2 v H2O. Vit cc phng trnh ha hc.
Bi 2: (4,0 im)
Mt hn hp rn A gm 0,2 mol Na2CO3; 0,1 mol BaCl2 v 0,1 mol MgCl2. Ch c dng thm
nc hy trnh by cch tch mi cht trn ra khi hn hp. Yu cu mi cht sau khi tch ra
khng thay i khi lng so vi ban u (Cc dng c, thit b cn thit k c ngun nhit, ngun
in cho y ).
Bi 3: (2,5 im)
T Metan, mui n, (cc cht xc tc, dng c cn thit cho y ) vit cc phng trnh ha hc
iu ch ra: iclometan, nha P.V.C, nha P.E, icloetilen, etan, etylclorua. Ghi r iu kin
ca phn ng nu c.
Bi 4: (4,5 im)
Trn u 30,96 gam hn hp bt X gm MgCO 3 v kim loi R c ha tr khng i ri chia
lm hai phn bng nhau.
- t nng phn I trong khng kh, sau khi cc phn ng xy ra hon ton thu c 15 gam hn
hp cc oxit kim loi.
- ha tan va ht phn II cn 500ml dung dch cha hn hp HCl 1,2M v H 2SO4 0,24M
c dung dch A v c V lt kh B bay ra.
1. Vit cc phng trnh ha hc.
2. Xc nh kim loi R v t khi ca B so vi H2.
3. Cho 61,65 gam Ba kim loi vo dung dch A. Sau khi cc phn ng kt thc, lc c m
gam rn F khng tan v 500 ml dung dch E. Tnh gi tr ca m v nng C M ca mi cht tan c
trong dung dch E.
Bi 5: (4,5 im)
Chia 9,84 gam hn hp kh X gm Etilen v 1 hirocacbon mch h A thnh hai phn bng
nhau.
- Dn phn I qua dung dch Brom d, sau khi phn ng kt thc c V lt kh A thot ra, khi
lng Brom tham gia phn ng l 8 gam.
- t chy hon ton phn II ri cho ton b sn phm chy vo bnh c cha 500 ml dung dch
Ba(OH)2 0,66M. Sau khi phn ng kt thc thu c 63,04 gam kt ta. Dung dch sau khi lc b
kt ta b gim i m gam so vi khi lng ca dung dch Ba(OH)2 ban u.
1. Vit cc phng trnh ha hc.
2. Xc nh cng thc phn t ca A.
3. Tnh gi tr ca m v gi tr ca V KTC.
Cho H:1; C:12; O:16; Mg:24; Al:27; S:32; Cl:35,5; Ca:40; Fe:56; Cu:64; Zn: 65;
Ba:137.
.......... Ht ..........
TI LIU BD HSG HA
Trang 32
L Vit Hng
S GD&T NGH AN
K THI CHN HC SINH GII TNH LP 9 CP THCS

NM HC 2011 2012
HNG DN CHM THI CHNH THC
Mn: HA HC BNG A
(Hng dn chm gm c 04 trang)
Bi
Bi 1
4.5
Bi 2
4
Ni dung
as
Cl2 + H2
2 HCl
Cl2 + H2O
HCl + HClO
askt
Cl2 + CH4 CH3Cl + HCl
t0
Cl2 + SO2 + 2H2O
2HCl + H2SO4
Hc sinh c th chn mt s cht khc nh: NH3, H2S
Cc cht rn c th chn: Fe;FeO;Fe3O4;Fe(OH)2;FeS;FeS2;FeSO4
Cc pthh :
t0
2Fe + 6H2SO4(c)
Fe2(SO4)3 + 3SO2 + 6H2O
t0
2FeO + 4H2SO4(c)
Fe2(SO4)3+SO2+ 4H2O
t0
2Fe3O4 + 10H2SO4(c)
3 Fe2(SO4)3 + SO2 + 10H2O
t0
2Fe(OH)2 + 4H2SO4(c)
Fe2(SO4)3 + SO2 + 6H2O
t0
2FeS + 10H2SO4(c)
Fe2(SO4)3 + 9SO2 + 10H2O
0
t
2FeS2 + 14H2SO4(c)
Fe2(SO4)3 + 15SO2 + 14H2O
t0
2FeSO4 + 2H2SO4(c)
Fe2(SO4)3 + SO2+ 2H2O
Cho hn hp ha tan vo nc c dung dch B ( cha 0,4 mol NaCl )

Lc ly rn C gm 0,1 mol BaCO3 v 0,1 mol MgCO3
BaCO3 + 2NaCl
Na2CO3 + BaCl2
Na2CO3 + MgCl2
MgCO3 + 2NaCl
in phn dung dch B c mng ngn n khi ht kh Cl2 th dng li thu c
dung dch D (cha 0,4 mol NaOH) v thu ly hn hp kh Cl2 v H2vaof bnh kn
to iu kin phn ng xy ra hon ton c kh HCl. Cho nc vo thu
c dung dch E c 0,4 mol HCl.
dpddcomangngan
2NaCl + 2H2O
2NaOH + H2 + Cl2
H2 + Cl2 2HCl
Chia dd E thnh 2 phn bng nhau E1 v E2 . Nhit phn hon ton rn C trong
bnh kn ri thu ly kh ta c 0,2 mol CO2. Cht rn F cn li trong bnh gm
0,1 mol BaO v 0,1mol MgO
t0
BaCO3
+ CO2
BaO
t0
MgCO3
MgO + CO2
Cho CO2 sc vo dd D phn ng xy ra hon ton ri un cn dd sau phn
ng ta thu c 0,2 mol Na2CO3
2NaOH + CO2 Na2CO3 + H2O
Ha tan rn F vo nc d, lc ly phn khng tan l 0,1 mol MgO v dd sau khi
lc b MgO cha 0,1 mol Ba(OH)2
TI LIU BD HSG HA
Trang 33
L Vit Hng
im
Mi
pt
ng
cho
0,25
Mi
pt
ng
cho
0,5
mi
pt
khng
cn
bng
hoc
cn
bng
sai
u
tr
0,25
0,75
0,75
0,75
Bi 3
2.5
Bi 4
4.5
Cho MgO tan hon ton vo E1 ri un cn dd sau phn ng ta thu c 0,1 mol
MgCl2
MgO + 2HCl MgCl2 + H2O
Cho dd Ba(OH)2 tc dng vi E2 ri un cn dd sau phn ng c 0,1 mol
BaCl2
BaO + H2O Ba(OH)2
0,75
Ba(OH)2 + 2HCl BaCl2 + 2H2O
Cc pthh:
Vit
15000 c
ng
C2H2+3H2
2CH4
Lamlanhnhanh
mi
dienphanNC
2NaCl
2Na + Cl2
pt cho
as
CH4 + Cl2
CH2Cl2 + 2HCl
0,25
thiu
C2H2 + HCl
C2H3Cl
t hn
trunghop
3 k
C
H
Cl
] n (P.V.C)
n(C2H3Cl)
[ 2 3
tr
Pd ,t 0
C2H2 + H2
C2H4
0,25
trunghop
n(C2H4)
; t
[ C2 H 4 ] n
3 k
C2H2 + Cl2 C2H2Cl2
tr
Ni,t o
C2H4 + H2
C2H6
ln
C2H4 + HCl C2H5Cl
tr
0,5
Cc pthh :
t0
4R + xO2
(1)
2R 2Ox
o
t
MgCO3
(2)
MgO + CO2
0,5
2 R + 2xHCl
2 R Clx + xH2
(3)
MgCO3 + 2HCl MgCl2 + CO2 + H2O
(4)
2 R + xH2SO4
R 2(SO4)x + xH2
(5)
MgCO3 + H2SO4 MgSO4 + CO2 + H2O
(6)
61, 65
nHCl = 0,5.1,2 = 0,6 (mol) ; nBa =
= 0, 45( mol )
137
0,25
30,96
nH 2 SO4 = 0,5.0,24 = 0,12(mol) ; m mi phn =
= 15, 48( g )
2
Gi M l khi lng mol ca kim loi R
t nR mi phn l a (mol); nMgCO3 mi phn l b (mol)
mX mi phn = Ma +84b = 15,48
1
1
T (1): nR2Ox =
nR = a mR2Ox = ( M+ 8x).a
2
2
(2): nMgO = nMgCO3 = b mMgO = 40b
M.a+ 8ax+40b = 15
T (3) v (5): nH = x. nR = ax
1
(4) v (6): nH = 2 nMgCO3 = 2b
ax+ 2b = 0,84
44b 8ax = 0, 48
Ta c hpt:
2b + ax = 0,84
44b 8t = 0, 48
t ax= t c h
2b + t = 0,84
Gii h ny ta c: b = 0,12; t = 0,6
0,5
0, 6
Vi t = 0,6 a =
x
b = 0,12 mMgCO3 = 0,12.84 = 10,08 (g) mR = 15,48 10,08 =5,4 (g)
TI LIU BD HSG HA
Trang 34
L Vit Hng
0, 6
= 5,4 M = 9x.
x
Chn: x= 1 M=9 (loi)
x=2 M=18 (loi)
x=3 M=27 R l Al
3
T (3) v (5) c nH2 = nAl = 0,3 mol
2
T (4) v (6) c nCO2 = nMgCO3 = 0,12 mol
0,3.2 + 0,12.44
T khi ca B so vi H2 =
=7
(0,3 + 0,12).2
Ba + 2H2O Ba(OH)2 + H2
(7)
3Ba(OH)2 + Al2(SO4)3 3BaSO4 + 2Al(OH)3
(8)
Ba(OH)2 + MgSO4
BaSO4 + Mg(OH)2
(9)
3Ba(OH)2 + 2AlCl3 3BaCl2 + 2Al(OH)3
(10)
Ba(OH)2 + MgCl2 BaCl2 + Mg(OH)2
(11)
C th Ba(OH)2 + 2Al(OH)3
Ba(AlO2)2 + 4H2O
(12)
Trong dd A c cha 4 cht tan: MgCl2; MgSO4; AlCl3; Al2(SO4)3, trong :
Tng nMg = 0,12; nAl = 0,2
nCl = 0,6; nSO4 = 0,12
Theo pt(7) nBa (OH )2 = nBa = 0,45; nOH trong Ba(OH)2 = 2.0,45 = 0,9 mol
Ma = 5,4 hay M .
0,25
0,5
T (8) v (9): nBa (OH )2 = nSO4 = nBaSO4 = 0,12 mol < 0,45 mol
nBa (OH )2 d: Cc phn ng (10 v (11) xy ra cng (8); (9)
3
3
nAl (OH )3 = nAl = 0,3
2
2
n
n
T (9) v (11) Ba (OH )2 = Mg ( OH )2 = nMg = 0,12
Sau (8); (9); (10); (11) nBa (OH )2 cn d = 0,45 - 0,3 - 0,12 = 0,03 (mol)
T (8) v (10) nBa (OH )2 =
phn ng (12) xy ra
T (12) nAl (OH )3 b tan = 2 nBa (OH )2 = 2.0,03 = 0,06 (mol) < 0,2 (mol)
Sau khi cc phn ng kt thc nAl (OH )3 cn li = 0,2 - 0,06 = 0,14 (mol)
Vy khi lng kt ta F chnh l gi tr ca m v
m = 0,12.233 + 0,12.58 + 0,14.78 = 45,84(g)
1
1
T (10) v (11) nBaCl2 = nCl = .0,6 = 0,3 (mol)
2
2
Vy nng CM ca cc cht tan trong dd E ln lt l:
CM BaCl = 0,3:0,5 = 0,6 M
2
T (12) nBa ( AlO2 )2 = nBa (OH )2 d =0,03
CM Ba ( AlO ) = 0,03:0,5 = 0,06 M
0,5
2 2
Bi 5
4.5
Cu ny gii v l lun bng nhiu phng php khc nhau. Nu bi lm da

vo nh lut bo ton nguyn t , nhm nguyn t v lp lun, tnh ton chnh
xc cho cng kt qu vn cho im ti a
Khi lng mi phn = 9,84: 2= 4,92(g); nBr2 = 8:160 = 0,05 ( mol)
V cho phn I qua dd Brom vn c kh bay ra nn A khng tc dng vi brom
trong dung dch
t cng thc tng qut ca A l CxHy ta c cc pthh
C2H4 + Br2 C2H4Br2 (1)
t0
C2H4 + 3O2
2CO2 + 2H2O (2)
CxHy +
4x + y
y
t
O2
xCO2 + H2O
4
2
0
CO2 + Ba(OH)2 BaCO3 + 2H2O (4)

TI LIU BD HSG HA
Trang 35
(3)
L Vit Hng
0,5
c th 2CO2 + Ba(OH)2 Ba(HCO3)2 (5)

nBa (OH )2 = 0,5.0,66 = 0,33 (mol); nBaCO3 = 63,04:197 = 0,32(mol)
V nBaCO3 < nBa (OH )2 phi xt hai trng hp
TH 1: Ba(OH)2 d khng c phn ng (5)

T (1): nC2 H 4 mi phn = nBr2 = 0,05 (mol ) 1,4(g)
T (2) nCO2 = 2 nC2 H 4 = 2.0,05 = 0,1 (mol)
T (4) nCO2 = nBaCO3 = 0,32 (mol)
nCO2 (3) = 0,32-0,1 = 0,22 (mol) nC trong CxHy = 0,22 (mol) 2,64 (g)
mt khc mCx H y = 4,92-1,4 = 3,52 (g) mHtrong CxHy = 3,52-2,64 = 0,88 (g)
0,88 (mol)
x 0, 22 1
= vy cng thc phn t ca A l CH4;
T CT ca CxHy =
y 0,88 4
TH2: CO2 d c phn ng (5)
T (4): nCO2 = nBa (OH )2 = nBaCO3 = 0,32 (mol)
1,25
nBa (OH )2 (5) = 0,33-0,32 =0,01 (mol)

T (5): nCO2 = 2 nBa (OH )2 = 2.0,01 = 0,02 (mol)
Tng nCO2 = 0,32 + 0,02 = 0,34 (mol)
1,25
nCO2 (3) = 0,34 - 0,1 = 0,24 (mol) nCtrong CxHy = 0,24 (mol) 2,88(g)
mH trong CxHy = 3,52 - 2,88 = 0,64 (g) 0,64 (mol)
x 0, 24 3
=
T CT ca CxHy =
y 0, 64 8
vy cng thc phn t ca A l C3H8;
C 2 trng hp A u l an kan khng tc dng vi Br2 trong dd nn u tha
mn, ph hp bi
Nu A l CH4 th nCH 4 = nCO2 = 0,22 (mol) V = 4,928 lt
T (2) v (3) n H 2O = 0,1 + 0,44 =0,54 mol
Tng m sn phm chy = 0,32.44 + 0,54.18 = 23,8 (g)
khi lng dung dch b gim = 63,04 23,8 = 39,24 (g)
Nu A l C3H8
1
1
nC3 H8 = . nCO2 = .0,24 = 0,08 (mol) V = 1,792 lt
3
3
T (2) v (3) n H 2O = 0,1 + 0,32=0,42 mol
Tng m n phm chy = 0,34.44 + 0,42 .18 = 22,52 (g)
khi lng dung dch b gim = 63,04 22,52 = 40,52 (g)
cu ny nu bi lm l lun: v A mch h v khng cng brom trong dd nn
suy ra A l an kan nn cng thc tng qut l CnH2n+2 ri gii ra 2 trng hp
n =1; n=3 vn cho im ti a
---------- Ht --------* Lu : Bi lm cch khc ng vn cho im ti a.
TI LIU BD HSG HA
Trang 36
L Vit Hng
0,75
0,75
S GIO DC V O
TO PH TH
chnh thc
12
THI CHN HC SINH GII CP TNH LP 9 THCS NM
HC 2011 2012
Mn: Ha hc
Thi gian: 150 pht khng k thi gian giao
( thi c: 01 trang)
Cu I: (2,0 im)
Cho ln lt tng cht: Fe, BaO, Al 2O3, v KOH vo ln lt cc dung dch: NaHSO 4, CuSO4. Hy
vit PTHH ca cc phn ng xy ra.
Cu II: (3,0 im)
1) C 1 hh gm 5 kim loi: Al, Mg; Fe, Cu, Ag. Hy dng PPHH tch ring tng kim loi vi khi
lng khng i. Vit PTHH xy ra trong qu trnh tch.
2) Vit PTP trong mi trng hp sau
a. Oxit + Axit 2 mui + oxit
b. Mui + kim loi 2 mui
c. Mui + baz 2 mui + 1oxit
d. Mui + kim loi 1 mui
Cu III: (3,0 im)
1) Trn V1 lit dd HCl 0,6M vi V2 lt dd NaOH 0,4M thu c 0,6 lit dd A. Tnh V 1, V2 bit 0,6 lt
dd A c th ho tan ht 1,02 gam Al2O3 (coi s pha trn khng lm thay i th tch)
2) Sc t t a mol kh CO 2 vo 800 ml dd X gm KOH 0,5M v Ca(OH) 2 0,2M. Tm gi tr ca a
thu c khi lng kt ta ln nht.
Cu IV: (10,0 im)
1) Ho tan cc cht gm Na2O, NaHCO3, BaCl2, NH4Cl c cng s mol vo nc d c dd A v
kt ta B. Hi dd A v kt ta B cha nhng cht g? Vit PTHH ca cc phn ng minh ho.
2) Ho tan ht 3,2 gam oxit M2On trong lng va dd H 2SO4 10%, thu c dd mui c nng
12,903%. Sau phn ng em c bt dd v lm lnh thu c 7,868 gam tinh th mui vi hiu
sut 70%. Xc nh cng thc ca tinh th mui .
3) Cho x gam mt mui halogenua ca mt kim loi kim tc dng vi 200ml dd H 2SO4 c, nng
va . Sau khi phn ng xy ra hon ton, thu c hn hp sn phm A trong c mt kh B
(mi trng thi). Cho kh B tc dng vi dd Pb(NO 3)2 (d) thu c 47,8 gam kt ta mu en.
Phn sn phm cn li, lm kh thu c 342,4 gam cht rn T. Nung T n khi lng khng
i thu c 139,2 gam mui duy nht.
a) Tnh nng mol/lit ca dd H2SO4 ban u.
b) Xc nh cng thc phn t ca mui halogenua.
c) Tnh x.
Cu V: (2,0 im)
C hn hp kh A gm metan, etilen v axetilen.
- Cho 5,6 lt hn hp kh a li qua dd nc brm d th c 52 gam brm tham gia phn ng.
- t chy hon ton 2,6 gam hn hp kh A th cn va 30,24 lt khng kh.
Xc nh thnh phn trm theo th tch cc kh trong hn hp A, bit cc kh o iu kin tiu
chun, trong khng kh oxi chim 20% v th tch cn li l ni t.
(Cho NTK: H = 1 ; Li=7; C = 12 ; O = 16 ; F=19; Ca=40; Br=80; I=127; Ba=137; Pb=207; N=14; Na =
23 ; Al = 27 ; S = 32 ; K = 39 ; Cl = 35,5 ; Fe = 56 ; Cu = 64)
Ht
Cn b coi thi khng gii thch g thm.
TI LIU BD HSG HA
Trang 37
L Vit Hng
S GIO DC V O
TO PH TH
THI CHN HC SINH GII CP TNH LP 9 THCS NM

HC 2011 2012
p n chnh thc
Mn: Ha hc
Thi gian: 150 pht khng k thi gian giao
( thi c: 01 trang)
Cu I: (2,0 im)
Cho ln lt tng cht: Fe, BaO, Al 2O3, v KOH vo ln lt cc dung dch: NaHSO 4, CuSO4. Hy
vit PTHH ca cc phn ng xy ra.
CU
NI DUNG
IM
2,0
* Vi NaHSO4:
Fe + 2NaHSO4 FeSO4 + Na2SO4 + 2H2
Ba(OH)2 + 2NaHSO4 BaSO4 + Na2SO4 + 2H2O
0,5
Ba(OH)2 + NaHSO4 BaSO4 + NaOH + H2O
BaO + H2O Ba(OH)2
Al2O3+ 6NaHSO4 Al2(SO4)3 + 3Na2SO4 + 3H2O
2KOH + 2NaHSO4 K2SO4 + Na2SO4 + 2H2O
0,5
* Vi CuSO4:
Fe + CuSO4 FeSO4 + Cu
BaO + H2O Ba(OH)2
0,5
Ba(OH)2 + CuSO4 BaSO4 + Cu(OH)2
2KOH + CuSO4 Cu(OH)2 + K2SO4
0,5
Cu II: (3,0 im)
1) C 1 hh gm 5 kim loi: Al, Mg; Fe, Cu, Ag. Hy dng PPHH tch ring tng kim loi vi khi
lng khng i. Vit PTHH xy ra trong qu trnh tch.
2) Vit PTP trong mi trng hp sau
a. Oxit + Axit 2 mui + oxit
b. Mui + kim loi 2 mui
c. Mui + baz 2 mui + 1oxit
d. Mui + kim loi 1 mui
? PNC
Al
Mg
Fe
Cu
Ag
CO2,H2?Od
NaAlO 2
Mg
Fe
Cu
Ag
HCl d ?
to
Al(OH)3
Cu
Ag
O2 d ?
CuO
Ag
HCl d ?
Ag
? P DD
Cu Cl2
MgCl 2
FeCl2
HCl
Zn d ?
Fe
Zn
MgCl 2
ZnCl2
TI LIU BD HSG HA
Al
Al2O3
Trang 38
Cu
NaOH d ?
Fe
? P DD
Mg
Zn
L Vit Hng
NaOH d ?
Mg
CU
2. 1,0
NI DUNG
a. Fe3O4 + 8HCl FeCl2 + 2FeCl3 + 4H2O
b. FeCl3 + 2Cu FeCl2 + 2CuCl2
c. 2NaHCO3 + Ca(OH)2 CaCO3 + Na2CO3 + 2H2O
d. 2FeCl3 + Fe 3FeCl2
IM
Cu III: (3,0 im)

1) Trn V1 lit dd HCl 0,6M vi V2 lt dd NaOH 0,4M thu c 0,6 lit dd A. Tnh V 1, V2 bit 0,6 lt
dd A c th ho tan ht 1,02 gam Al2O3 (coi s pha trn khng lm thay i th tch)
2) Sc t t a mol kh CO 2 vo 800 ml dd X gm KOH 0,5M v Ca(OH) 2 0,2M. Tm gi tr ca a
thu c khi lng kt ta ln nht.
CU
NI DUNG
IM
1. (2,0) nHCl=0,6V1 (mol)
nNaOH=0,4V2 (mol)
nAl2O3=0,1 (mol)
- Theo bi ta c: V1+V2=0,6 lt
- PTHH: HCl + NaOH NaCl + H2O
(1)
* Trng hp 1: Trong dd A cn d axit HCl
6HCl + Al2O3 2AlCl3 + 3H2O
(2)
- Theo (1) v (2) ta c V1 + V2 = 0,3 lt (*)
1,0
* Trng hp 2: Trong dd A cn d axit NaOH
2NaOH + Al2O3 2NaAlO2 + H2O
(3)
- Theo (1) v (3) ta c nNaOH = nHCl + 2nAl2O3
=> 0,4V2 = 0,6V1 + 0,02 (**)
1,0
- T (*) v (**) ta c: V1 = 0,22 lit, V2 = 0,38 lt
2(1)
nKOH = 0,8.0,5 = 0,4 mol
nCa(OH)2 = 0,8.0,2 = 0,16 mol
Sc t t a mol kh CO2 vo 800 ml dd X c cc phng trnh phn ng
CO2
+
Ca(OH)2
CaCO3 + H2O
(1)
Mol
0,16
0,16
0,16
CO2
+
2KOH
K2CO3 + H2O
(2)
Mol
0,2
0,4
0,2
CO2
+
K2CO3 + H2O 2KHCO3
(3)
Mol
0,2
0,2
0,5
- Theo (1) ta c: Nu 0 a 0,16 th s mol CaCO3 tng t 0 n 0,16 mol
- Theo (2) v (3) ta c: Nu 0,16 a 0,56 th s mol CaCO3 = 0,16 mol
Vy thu c khi lng kt ta ln nht l 0,16.100 = 16 gam th 0,16 a
0.56
0,5
Cu IV: (10,0 im)
3) Ho tan cc cht gm Na2O, NaHCO3, BaCl2, NH4Cl c cng s mol vo nc d c dd A v
kt ta B. Hi dd A v kt ta B cha nhng cht g? Vit PTHH ca cc phn ng minh ho.
4) Ho tan ht 3,2 gam oxit M2On trong lng va dd H2SO4 10%, thu c dd mui c nng
12,903%. Sau phn ng em c bt dd v lm lnh thu c 7,868 gam tinh th mui vi hiu
sut 70%. Xc nh cng thc ca tinh th mui .
5) Cho x gam mt mui halogenua ca mt kim loi kim tc dng vi 200ml dd H 2SO4 c, nng
va . Sau khi phn ng xy ra hon ton, thu c hn hp sn phm A trong c mt kh B
(mi trng thi). Cho kh B tc dng vi dd Pb(NO 3)2 (d) thu c 47,8 gam kt ta mu en.
Phn sn phm cn li, lm kh thu c 342,4 gam cht rn T. Nung T n khi lng khng i
thu c 139,2 gam mui duy nht.
a) Tnh nng mol/lit ca dd H2SO4 ban u.
b) Xc nh cng thc phn t ca mui halogenua.
c) Tnh x.
CU
NI DUNG
IM
TI LIU BD HSG HA
Trang 39
L Vit Hng
1. (2,0)
2(3)
3(5)
Phng trnh ho hc
Na2O + H2O 2NaOH
Mol
a
2a
NaHCO3 + NaOH -> Na2CO3 + H2O
Mol
a
a
a
NH4Cl + NaOH NaCl + NH3 + H2O
Mol
a
a
a
a
Mol
a
a
a
2a
=> Dung dch A ch c NaCl
Kt ta B ch c BaCO3
- PTHH:
M2On
+
n H2SO4
M2(SO4)n + nH2O
Nu c 1 mol M2On th s gam dd H2SO4 10% l 980n gam
S gam dd mui l 2M+996n (gam)
(2M + 96n).100
56n
= 12,903 M =
Ta c: C% =
2M + 996n
3
Vy n = 3, M = 56 => oxits l Fe2O3
PTHH: Fe2O3 + 3H2SO4 Fe2(SO4)3 + 3H2O
a. nPb(NO3)2 =0,2 mol
- V kh B c mi trng thi khi tc dng vi dd Pb(NO 3)2 to kt ta en => B l
H2S
- Gi CTTQ ca mui halogenua kim loi kim l RX
- PTHH 8RX + 5H2SO4 c 4R2SO4 + H2S + 4X2 + 4H2O (1)
1,6
1,0
0,8
0,2
0,8
(c th HS vit 2 phng trnh lin tip cng c)
- Khi B tc dng vi dd Pb(NO3)2
H2S + Pb(NO3)2 PbS + 2HNO3
(2)
0,2
0,2
1, 0
= 5, 0M
- Theo (1) ta c: CM H2SO4 =
0, 2
b. Sn phm gm c: R2SO4, X2, H2S => cht rn T c R2SO4 v X2, nung T n
khi lng khng i => m R 2SO 4 = 139, 2g
m X 2 = 342, 4 - 139, 2 = 203, 2(g)
203, 2
= 254 M X =127 . Vy X l it(I)
0,8
139, 2
= 174 R = 39 R l kali (K)
- Ta c: M R 2SO4 = 2R + 96 =
0,8
- Vy CTPT mui halogenua l KI
c. Tm x:
- Theo (1) n RX = 1, 6(mol) x = (39 +127).1, 6 = 265, 6(g)
- Theo (1) n X2 = 0,8(mol)
0,5
0,5
0,5
0,5
1,0
1,0
1.0
0,5
0,5
0,5
0,5
0,5
0,5
0,5
0,5
1,0
Cu V: (2,0 im)
C hn hp kh A gm metan, etilen v axetilen.
- Cho 5,6 lt hn hp kh a li qua dd nc brm d th c 52 gam brm tham gia phn ng.
- t chy hon ton 2,6 gam hn hp kh A th cn va 30,24 lt khng kh.
Xc nh thnh phn trm theo th tch cc kh trong hn hp A, bit cc kh o iu kin tiu
chun, trong khng kh oxi chim 20% v th tch cn li l ni t.
CU
NI DUNG
IM
(2,0)
- Gi a, b, c ln lt l s mol ca CH4, C2H4, C2H2 trong 5,6 lt hn hp A
5, 6
= 0, 25
- Ta c: a + b + c =
(1)
22, 4
TI LIU BD HSG HA
Trang 40
L Vit Hng
(2)
(3)
0,5
(4)
- PTHH
C2H4 + Br2 C2H4Br2

C2H2 + 2Br2 C2H2Br4
52
n Br2 = b + 2c =
= 0,325
160
- gi ka, kb, kc ln lt l s mol ca CH4, C2H4, C2H2 trong 2,6 gam hn hp A.
- Ta c
16ka + 28kb + 26kc = 2,6
(5)
2CH4 + 4O2 2CO2 + 4H2O
(6)
C2H4 + 3O2 2CO2 + 2H2O
(7)
2C2H2 + 5O2 4CO2 + 2H2O
(8)
n O2 = 2ka + 3kb + 2,5kc = 0, 27
(9)
- Gii h PT (1), (4), (5), v (9) ta c
a = 0,025 mol %VCH 4 = 10%
0,5
0,5
b = 0,125 mol %VC2H 4 = 50%

c = 0,1 mol %VC2 H2 = 40%
0,5
Ch : Th sinh lm bi theo phng php khc: Cho kt qu ng, lp lun cht ch gim kho
cn c thang im ca hng dn chm cho im sao cho hp l.
TI LIU BD HSG HA
Trang 41
L Vit Hng
13
TI LIU BD HSG HA
Trang 42
L Vit Hng
S GIO DC V O TO
QUNG NAM
14
K THI CHN HC SINH GII LP 9 THCS
NM HC 2011-2012
Mn thi : HO HC
Thi gian : 150 pht (khng k thi gian giao )
Ngy thi : 03/4/2012
CHNH THC
Cu I.(3 im)
1.Cho cc kim loi Mg, Al, Fe ln lt tc dng vi cc dung dch HCl, NaOH, CuSO4, AgNO3.Vit cc
phng trnh phn ng xy ra (nu c).
2.C bn cht sau: KCl, H2O, MnO2, H2SO4 c .T nhng cht trn lm th no c th iu ch :HCl ;
Cl2 ; KClO3. Vit phng trnh phn ng dng.
Cu II.(3 im)
1.Hon thnh cc phng trnh phn ng ca s sau. Ghi r iu kin ( nu c):
Saccaroz (1) glucoz (2) ancol etylic (3) axit axetic (4) natriaxetat (5) metan (6) axetilen (7)
benzen (8) nitrobenzen.
2.Mt trong nhng cch lm sch tp cht c ln trong nc ma dng sn xut ng phn theo
phng php th cng trc y c thc hin bng cch cho bt than xng v mu b vo nc p
ma. Sau khuy k un nh ri lc ly phn nc trong. Phn nc trong ny mt hn mu xm v mi
ma. C cn nc lc th thu c ng phn. Hy gii thch vic s dng than xng v mu b trong
cch lm ny?
3.Butan c ln tp cht l cc kh etilen, cacbonic, axetilen. Nu cch tin hnh v vit cc phng trnh
phn ng xy ra trong qu trnh lm sch kh.
Cu III.(4 im)
1.Cho 0,1g canxi tc dng vi 25,0cm3 nc lnh nhit phng. Th tch kh hyro o c trong
thi gian 4 pht, mi ln o cch nhau 30 giy. Kt qu thu c nh sau:
Thi gian(gy) 0
30
60
90
120
150
180
210
240
Th tch(cm3) 0
20
32
42
50
56
59
60
60
a.Da vo bng s liu cho bit: tc phn ng thay i th no v sau bao nhiu giy phn ng kt
thc.
b.Tm th tch kh hyro thu c nhit phng v nng phn trm ca dung dch sau khi phn ng
kt thc. Bit iu kin nhit phng 1,0 mol kh c th tch 24000cm 3 v khi lng ring ca nc
l 1,0g/cm3.
2.Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch
NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc
dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. Tm x,y.
Cu IV.(3 im)
1.C cc cht lng A, B, C, D, E. Cht no l benzen, ancol etylic, axit axetic, dung dch glucoz, nc.
Bit kt qu ca nhng th nghim nh sau:
-Cho tc dng vi Na th A, B, C, D c kh bay ra; E khng phn ng
- Cho tc dng vi CaCO3 th A, B, C, E khng phn ng; D c kh bay ra
-Cho tc dng vi dung dch AgNO3/NH3 th A, C, D, E bc khng xut hin; B c bc xut hin
-t trong khng kh th A, E chy d dng; D c chy ; B,C khng chy
Xc nh A, B, C, D, E v vit cc phng trnh phn ng ho hc theo cc kt qu th nghim trn.
2.t chy hon ton m(g) cht hu c A ch thu c a(g) CO 2 v b(g) H2O. Bit 3a = 11b v 7m =
3(a + b). Xc nh cng thc phn t (A), bit t khi hi ca (A) i vi khng kh : dA/KK < 3 .
Cu V.(4 im)
Cho V lt(ktc) kh CO i qua ng s ng 5,8g st oxit nung , mt thi gian thu c hn hp kh A
v cht rn B. Cho B tc dng ht vi axit HNO3 long d thu c dung dch C v 0,784 lit (ktc) kh
NO l sn phm kh duy nht. C cn dung dch C thu c 18,15g mui st III khan. Nu ho tan hon
ton B bng axit HCl d thu c 0,672 lit kh (ktc)(xem qu trnh st tc dng vi mui st III v mui
st II khng ng k).
1.Tm cng thc st oxit v phn trm khi lng cc cht trong B.
2.Tm V v phn trm th tch cc kh trong hn hp A, bit t khi ca A i vi hyro l 17,2.
Cu VI.( 3 im)
Mt hn hp kh (A) gm mt hirocacbon (X) mch h v H2. Cho 17,6g hn hp (A) vo dung dch
nc brom , sau khi phn ng hon ton thy dung dch brom nht mu v khi lng brom tham gia
TI LIU BD HSG HA
Trang 43
L Vit Hng
phn ng l 96,0g. Khi t chy hon ton 17,6g hn hp (A), dn sn phm chy vo nc vi trong th
ton b sn phm chy b hp th ht v to c 20,0g kt ta. Lc b kt ta thy khi lng dung dch
nc vi tng thm m(gam) so vi ban u. un si dung dch cn li to thm 50,0g kt ta na.
1.Tm cng thc phn t ca (X) v tnh thnh phn phn trm s mol hn hp (A).
2. Tnh m.
Ghi ch : Th sinh c php dng bng tun hon v my tnh b ti.
S GIO DC V O TO
QUNG NAM
K THI HC SINH GII LP 9 NM HC : 2011-2012
HNG DN CHM V BIU IM MN HA HC
CHNH THC
(Hng dn chm c 4 trang)
STT
Cu I
3
im
p n
1.Cc phn ng:
Mg + 2HCl
MgCl2 + H2
Mg + CuSO4
MgSO4 +Cu
Mg + 2AgNO3
Mg(NO3)2 +2Ag
2Al + 6HCl
2AlCl3 + 3H2
2Al + 2NaOH +2H2O
2NaAlO2 + 3H2
2Al + 3CuSO4
Al2(SO4)3 + 3Cu
Al+ 3AgNO3
Al(NO3)3 +3Ag
Fe+ 2HCl
FeCl2 + H2
Fe + CuSO4
FeSO4 +Cu
Fe+ 2AgNO3
Fe(NO3)2 +2Ag
Nu AgNO3 d th : Fe(NO3)2 + AgNO3
Fe(NO3)3 + Ag
2.
2KCl + H2SO4 c nng
(0,25.4)
MnO2 + 4HCl
toC
MnCl2 +Cl2 + 2H2O
pmangngan
2KCl + 2H2O 2KOH +H2+Cl2
oC
3Cl2 + 6KOH
100
5KCl+ KClO3 + 3H2O
im
2,0
(0,2.10)
1,0
K2SO4
Cu II 1.
3
im
2HCl
toC
C12H22O11 + H2O H2 SO
(0,125.8)
4;
2C6H12O6
enzim; 30 35oC
C6H12O6
2C2H5OH + 2CO2
C2H5OH + O2
enzim
CH3COOH + H2O
CH3COOH + NaOH
CH3COONa + H2O
CaO; toC
CH3COONa + NaOH
CH4 + Na2CO3
1500 oC ; l ln
2CH4
C2H2 +3H2
600 oC; btthan
C6H6
3C2H2
C6H6 +HNO3 c
H2SO
4 C6H5NO2 +H2O
2.Than xng (C v nh hnh) c c tnh hp ph cc cht mu v mi.Mu b(protein) khi
tan trong nc ma to thnh dung dch keo, c kh nng gi cc tp cht nh l lng, khng
lng ng.Khi un nng protein b ng t,ko nhng ht tp cht ny lng xung, nh khi
lc b phn khng tan, thu c nc ma trong, khng c mu ,mi v cc tp cht.
3.Cho hn hp kh C4H10,C2H4 ,C2H2 ,CO2 i qua dung dch brom d. Kh i ra l C4H10 v
CO2, cho hn hp thu c vo dung dch nc vi d. Kh i ra l C4H10 nguyn cht.
C2H4 + Br2
C2H4Br2
C2H2 + 2Br2
C2H2Br4
CO2 + Ca(OH)2
CaCO3 + H2O
TI LIU BD HSG HA
Trang 44
L Vit Hng
1,0
1,0
1,0
Cu
III
4
im
1.a.-Tc phn ng gim dn theo thi gian.

(0,25)
-Phn ng kt thc sau 210 giy
(0,25)
b.Phng trnh phn ng:
Ca + 2H2O
Ca(OH)2 +H2
S mol H2 = s mol Ca(OH)2 = s mol Ca = 0,1:40 =0,0025mol
Th tch kh H2 = 0,0025.24000 =60cm3
( hoc nhn vo bng s liu th tch kh H2 =60cm3)
(0,25)
Khi lng Ca(OH)2 =74.0,0025=0,185g
(0,25)
Khi lng dung dch sau phn ng = 25.1 + 0,1 0,0025.2 = 25,095g
(0,25)
Nng % dung dch = (0,185:25,095).100 = 0,737%
(0,25)
2. Phng trnh in li
AlCl3
(1)
Al3+ + 3Cl(0,20.5)
0,4x
0,4x
: (mol)
3+
2Al2(SO4)3
2Al +3SO4 (2)
0,4y
1,2 y
: (mol)
0,8y
Khi tc dng vi NaOH:
Al3+ + 3OH-
(3)
Al(OH)3
Nu NaOH d th c phn ng:
Al3+ + 4OH-
AlO2- + 2H2O (4)
Khi cho BaCl2 d vo :
Ba2+ + SO42-
(5)
BaSO4
: (mol)
1,2 y
1,2 y
S mol Al3+ = 0,4x +0,8y;
S mol BaSO4 =33,552 :233 = 0,144 mol nSO42- =1,2y = 0,144 y= 0,12(mol)
(0,5)
nOH = nNaOH = 0,612 mol;
nAl(OH)3 =8,424:78= 0,108 mol nOH to kt ta (3) = 0,108.3 =0,324 < 0,612
c phn ng (3) &(4)
(0,5)
s mol OH- to AlO2- = 0,612- 0,324 = 0,288 mol
0,4x +0,8y=0,108 + (0,288:4) x= 0,21mol
5)
Cu
IV
1.T cc kt qu xc nh c A:C2H5OH; B: dung dch glucoz(C6H12O6 ); C:H2O

;D:CH3COOH ; E : C6H6(benzen)
(0,5)
3im
2C2H5OH + 2Na
(0,125.8)
2C2H5ONa + H2
2H2O + 2Na
2NaOH + H2
2CH3COOH + 2Na
2CH3COONa + H2
2CH3COOH + CaCO3
(CH3COO)2Ca + H2O + CO2
NH 3, toC
C6H12O6 + Ag2O
C6H12O7 + 2Ag
C2H5OH + 3O2
2CO2 + 3H2O
CH3COOH + 2O2
2CO2 + 2H2O
TI LIU BD HSG HA
Trang 45
L Vit Hng
0,5
1,0
1,0
1,5
( 0,
1,5
1,5
2C6H6 + 15O2
12CO2 + 6H2O
2. mC =12a/44 =3a/11 =b(g)
mH = 2b/18 =b/9(g)
(0,25)
mO = m-( b + b/9 ) = m -10b/9
theo : 7m =3a +3b =11a +3b = 14b m=2b(g)
mO =2b 10b/9 = 8b/9(g)
(0,25)
Gi cng thc phn t ca A l CxHyOz
Ta c t l : x:y:z = b/12 :b/9:8b/9.16
= 3:4:2
(0,5)
cng thc phn t A : (C3H4O2)n; vi n nguyn dng
theo : 72n < 29.3 n < 1,208 ch c n = 1 ng iu kin
Vy cng thc phn t ca A l: C3H4O2
(0,5)
Cu V 1. Gi cng thc phn t st oxit l FexOy
HNO 3
CO
Ta c s FexOy FexOy;Fe;FexOy d Fe(NO3)3;NO
4im p dng s bo ton vi nguyn t Fe: s mol Fe(FexOy) = s mol Fe trong Fe(NO3)3
= 18,15:242=0,075mol
(0,5)
S mol O = (5,8-56.0,075):16 = 0,1mol
(0,25)
Ta c x:y = 0,075:0,1 = 3:4
Vy cng thc cn tm Fe3O4
(0,25)
Cht rn B c th gm:Fe,FeO,Fe3O4 d
Phng trnh phn ng:
Fe + 4HNO3
(1)
Fe(NO3)3 + NO + 2H2O
3FeO + 10HNO3
(2)
3Fe(NO3)3 + NO + 5H2O
3Fe3O4 + 28HNO3
(3)
9Fe(NO3)3 + NO + 14H2O
Fe + 2 HCl
(4)
FeCl2 + H2
FeO + 2 HCl
(5)
FeCl2 + H2O
Fe3O4 + 8HCl
(6)
2FeCl3 + FeCl2 + 4H2O

(0,5)
Gi a,b,c ln lt l s mol Fe,FeO,Fe3O4 d trong B
T (4) s mol H2 = a = 0,03
T (1),(2),(3) s mol NO = a + b/3+ c/3 = 0,035
S mol Fe = a + b + 3c = 0,075
Gii h phng trnh ta c: a=0,03 ; b = 0 ; c= 0,015
Khi lng B = 56.0,03 + 232.0,015 = 5,16g
(0,75)
% khi lng hn hp : %Fe = 32,56% ; %Fe3O4 = 67,44%
(0,25)
2.Phng trnh phn ng:
Fe3O4 + 4CO toC
(7)
3Fe + 4CO2
Theo phn ng: s mol CO phn ng = s mol CO2
Gi d l % th tch CO2 ; % th tch CO = 1-d
Ta c : 44d + 28(1-d) = 17,2.2
d= 0,4 . %VCO2=40% ; %VCO =60%
(0,75)
Theo (7) s mol CO phn ng = (4/3).s mol Fe =(4/3).0,03=0,04mol
Do s mol CO ban u = (0,04.100):40=0,1mol
V=0,1.22,4= 2,24lit
(0,75)
TI LIU BD HSG HA
Trang 46
L Vit Hng
1,0
1,5
1,5
Cu
VI
3
im
1.Gi cng thc phn t tng qut ca (X) l :CnH2n+2-2k ; vi: 2n4; 1 k n
CnH2n+2-2k + kBr2
(1)
CnH2n+2-2kBr2k
x
kx
: mol
2CnH2n+2-2k +(3n+1-k)O2
(2)
2nCO2 + 2(n+1-k)H2O
x
nx
: mol
2H2 + O2
(3)
2 H2O
CO2 + Ca(OH)2
(4)
CaCO3 + H2O
2CO2 + Ca(OH)2
(5)
Ca(HCO3)2
toC
Ca(HCO3)2 CaCO3 + H2O +CO2 (6)
Gi x l s mol (X) trong hn hp
S mol CO2 =nx = 0,2 + 2.0,5 =1,2 (a)
S mol Br2 =kx = 0,6 (b)
T (a) & (b) n =2k
+ khi k=1 n =2 CTPT C2H4
x = 0,6 s mol H2 =(17,6 28.0,6):2 = 0,4 mol
% C2H4 = 60% ; %H2 = 40%
+ khi k=2 n = 4 CTPT C4H6
x = 0,3 s mol H2 =(17,6 54.0,3):2 = 0,7 mol
% C4H6 = 30% ; %H2 = 70%
2.S mol nguyn t H trong 2 trng hp: 4.0,6+2.0,4= 6.0,3+2.0,7=3,2mol
s mol H2O= 1,6mol
S mol CO2 = nx =1,2mol
m = mCO2 + mH2O mCaCO3 =44.1,2 +18.1,6 -20 =61,6gam
Ghi ch: Cc bi ton cu III,IV,V ,VI : Hc sinh c th gii theo cch khc nhng lp lun ng v
cho kt qu ng vn t im ti a nh trn.
- Phng trnh ho hc khng cn bng hoc cn bng sai th tr na s im ca phng trnh .
Trong mt phng trnh vit sai 1 cng thc ha hc th khng tnh im phng trnh.
TI LIU BD HSG HA
Trang 47
L Vit Hng
0,5
0,5
0,5
0,5
0,5
0,25
0,25
S GIO DC V OTO
QUNG NINH
-------------------- THI CHNH THC
15
LP 9 THCS NM HC 2011-2012
MN HA HC 9
(BNG B)
Ngy thi: 23/03/2012
(Khng k thi gian giao )
( thi ny c 01 trang)
H v tn, ch k
ca gim th s 1
Cu 1 : (3,5 im)
Cho s phn ng sau :
A (2) FeCl2 (3) B
(1)
(4)
Fe
Fe2O3
(5)
D (6) C
Bit A,B,C,D l cc hp cht khc nhau ca st v khng phi l FeCl 2, Fe2O3. Xc nh cng thc ha
hc ca cc hp cht v vit cc phng trnh phn ng minh ha.
(7)
Cu 2: (5,0 im)
1/ Nhit phn hn hp gm BaCO3, MgCO3, Al2O3 c cht rn A v kh B. Ha tan A vo nc d
c dung dch D v cht rn khng tan C. Cho t t n d dung dch HCl vo dung dch HCl vo dung
dch D th xut hin kt ta, sau kt ta tan dn. Cht rn C tan mt phn trong dung dch NaOH d,
phn cn li tan ht trong dung dch HCl d . Xc nh cc cht trong A,B,C,D v vit phng trnh ha
hc xy ra. Bit cc phn ng xu ra hon ton.
2/ Bng phng php ha hc, hy phn bit 4 cht kh ng trong 4 bnh mt nhn sau: CO, CO 2, N2,
SO2.
Cu 3 (3,5 im)
Hn hp X gm Fe, FeO, Fe 3O4 , Fe2O3 c s mol bng nhau. Ly 52 gam hn hp X cho vo dung
dch HCl d thu c dung dch A. Cho dung dch NaOH n d vo dung dch A thu c kt ta B.
Lc ly kt ta B nung ngoi khng kh n khi lng khng i c m gam cht rn C. Tm gi tr ca
m. Bit cc phn ng xy ra hon ton.
Cu 4: (3,5 im)
Ha tan hon ton a gam oxit ca mt kim loi ha tr (II) trong 48 gam dung dch H 2SO4 long, nng
6,125% thu c dung dch A cha 2 cht tan trong H 2SO4 c nng 0,98%. Mt khc, dng 2,8
lt cacbon (II) oxit kh hon ton a gam oxit trn thnh kim loi thu c kh B duy nht. Nu ly
0,896 lt kh B cho vo dung dch Ca(OH) 2 d thu c 0,8 gam kt ta. Tm gi tr ca a v xc nh
cng thc ca oxit kim loi . Bit cc th tch kh u o iu kin tiu chun.
Cu 5: (4,5 im)
t chy hon ton 5,6 lt hn hp gm 2 hidrocacbon (t l th tch l 2:3) c cng s nguyn t
cacbon trong phn t thu c 11,2 lt kh cacbonic v 11,2 gam nc. Xc nh cng thc phn t ca 2
hidrocacbon bit cc th tch kh u o iu kin tiu chun.
TI LIU BD HSG HA
Trang 48
L Vit Hng
S GIO DC & O TO
QUNG TR
CHNH THC
16
K THI CHON HOC SINH GIOI TINH
NM HC 2011 - 2012
MN: HOA HOC LP 9 THCS
Kho ngy: 12/4/2012
thi c 01 trang, gm 05 cu
Cu 1. (4,0 im)
1. Hn hp A gm CaCO3, Cu, FeO, Al. Nung nng A (trong iu kin khng c khng kh) mt
thi gian thu ly cht rn B. Cho B vo nc d c dung dch C v cht rn D (khng thay i khi
lng khi cho vo dung dch NaOH). Cho D tc dng vi dung dch H 2SO4 c nng, d. Xc nh B, D
v vit cc phng trnh phn ng xy ra.
2. Ho tan hon ton 4 gam FexOy cn 52,14 ml dung dch HCl 10% (D = 1,05g/ml). Xc nh
cng thc FexOy.
3. Mt hn hp gm Al2(SO4)3 v K2SO4, trong s nguyn t oxi chim 20/31 tng s nguyn
t c trong hn hp. Tnh % theo khi lng mi mui trong hn hp.
Cu 2. (4,0 im)
1. Vit cc phng trnh phn ng xy ra khi cho ln lt cc cht kh sau: SO 2, Cl2, NO2, H2S,
CO2 tc dng vi dung dch Ca(OH)2 d.
2. Hn hp kh A gm a mol SO2 v 5a mol khng kh. Nung nng hn hp A vi V 2O5 xc tc
thu c hn hp kh B. Bit rng t khi hi ca A so vi B bng 0,93. Hy tnh hiu sut phn ng gia
SO2 v O2. Cho khng kh c cha 80% N2 v 20% O2 theo th tch.
3. Nh t t 3V1 lt dung dch Ba(OH)2 xM (dung dch X) vo V 1 lt dung dch Al2(SO4)3 yM
(dung dch Y) th phn ng va v thu c kt ta ln nht l m gam.
a) Tnh gi tr x/y.
b) Nu trn V2 lt dung dch X vo V1 lt dung dch Y ( trn ) th kt ta thu c c khi lng
bng 0,9m gam. Xc nh gi tr V2/V1.
Cu 3. (4,0 im)
1. Kh hon ton 24 gam hn hp Fe2O3 v CuO nung nng bng lng CO d, ton b CO2 sinh
ra cho hp th hon ton vo dung dch Ca(OH)2 d th thu c 40 gam kt ta.
Vit cc phng trnh phn ng xy ra v tnh s mol mi oxit trong hn hp ban u.
2. Vit cc phng trnh phn ng chng minh:
a) Tnh axit ca dung dch HCl mnh hn CH3COOH b) hot ng ca O3 mnh hn O2
c) Tnh baz ca dung dch Ba(OH)2 mnh hn NH3 d) hot ng ca Fe mnh hn Cu
3. Cho hn hp A gm 3 kim loi X, Y, Z c ha tr ln lt l III, II, I v t l s mol tng ng
l 1:2:3, trong s mol ca X bng x mol. Ha tan hon ton A bng dung dch c cha y (gam) HNO 3
(ly d 25%). Sau phn ng thu c V lt kh NO 2 v NO (ktc, khng c sn phm kh khc). Da vo
s phn ng chng minh rng: y = 1,25(10x + V/22,4)63.
Cu 4. (4,0 im)
1. Ha tan hon ton 8,7 gam mt hn hp gm kali v mt kim loi M (thuc nhm IIA) trong
dung dch HCl d, th thu c 5,6 dm 3 H2 (ktc). Nu ha tan hon ton 9 gam kim loi M trong dung
dch HCl d, th th tch kh H2 sinh ra cha n 11 lt (ktc).Hy xc nh kim loi M.
(Cho cc kim loi nhm IIA: Be=9, Mg=24, Ca=40, Sr=88, Ba=137)
2. T tinh bt, cc cht v c cn thit v cc iu kin c , hy vit cc phng trnh phn ng
iu ch cc cht sau: etyl axetat, etilen, PVC.
Cu 5. (4,0 im)
Cho 76,2 gam hn hp A gm 1 ancol n chc (ROH) v 1 axit cacboxylic n chc (R /COOH).
Chia A thnh 3 phn bng nhau. em phn 1 tc dng ht vi Na, thu c 5,6 lt H 2 (ktc). t chy ht
phn 2 th thu c 39,6 gam CO2. em phn 3 thc hin phn ng este ha vi hiu sut 60%, sau phn
ng thy c 2,16 gam nc sinh ra. Vit cc phng trnh phn ng xy ra, xc nh cng thc phn t,
cng thc cu to ca cc cht trong A.
Cho: H=1, O=16, C=12, N=14, Na=23, Mg=24, Al=27, S=32, Cl=35,5; Ca=40, Fe=56, Cu=64.
(Th sinh khng c dng bng HTTH v bng Tnh tan)
TI LIU BD HSG HA
Trang 49
L Vit Hng
HNG DN CHM THI CHN HSG TNH THCS
NM HC: 2011-2012
Kho
ngy
12 thng 4 nm 2012
CHNH THC
Mn: HO HC Lp 9
(Hng dn chm c 05 trang)
Cu
Ni dung
im
Cu 1
4,0 im
to
1
2,5
CaO + CO2
Phn ng: CaCO3
to
Al2O3 + 3Fe
2Al + 3FeO
(B: CaO, Al2O3, Cu, FeO, CaCO3 d, Fe, Al)
CaO + H2O Ca(OH)2
2Al + Ca(OH)2 + 2H2O Ca(AlO2)2 + 3H2
Al2O3 + Ca(OH)2 Ca(AlO2)2 + H2O
Do D khng thay i khi lng khi cho vo dung dch NaOH, nn
D khng cn Al v Al2O3. Suy ra: D gm Cu, FeO, CaCO3, Fe.
to
CaSO4 + CO2 + H2O
CaCO3 + H2SO4 c
S GD&T QUNG TR
t
CuSO4 +2H2O + SO2
Cu + 2H2SO4 c
to
Fe2(SO4)3 + SO2 +4 H2O
2FeO + 4H2SO4 c
o
t
Fe2(SO4)3 + 3SO2 +6H2O
2Fe + 6H2SO4 c
Theo (1) v bi ra:

3
Cu 2
1
0,25
1, 05.52,14.10
= 0,15 mol
100.36,5
Phn ng: Fe x O y + 2yHCl x FeCl2y x + yH2O (1)
Ta c: nHCl =
0,25
56x + 16y
2y
x 2
=
= . Vy cng thc Fe2O3
4
0,15
y 3
Gi x, y ln lt l s mol ca Al2(SO4)3 v K2SO4 trong hn hp.

12x + 4y 20
x 1
=
=
Ta c:
17x + 7y 31
y 2
342.1
.100% = 49,57%
Vy: %(m) Al2(SO4)3 =
342.1 + 174.2
%(m)K2SO4 = 50,43%
0,25
0,25
Gi s mol SO2 phn ng l x

Theo (1): S mol gim = s mol O2 phn ng = 0,5x (mol)
nB= 6a-0,5x (mol)
Theo LBTKL: mA= mB = m
m
m
x
= 0,93 = 0,84 .
dA/B = :
6a 6a 0,5x
a
a a
V < , nn H% ca phn ng tnh theo SO2. Vy H%= 84%
2 1
Trang 50
0,5
4,0 im
1,5
Ca(OH)2 + SO2 CaSO3 + H2O

2Ca(OH)2 + 2Cl2 CaCl2 + Ca(ClO)2 + H2O
t0
6Ca(OH)2 + 6Cl2
5CaCl2 + Ca(ClO3)2 + 6H2O
Ca(OH)2 + H2S
CaS
+ 2H2O
2Ca(OH)2 + 4NO2 Ca(NO2 )2 + Ca(NO3)2 + 2H2O
ng mi pt 0,25 0,25x6= 1,5 im
2)Hn hp A ban u c SO2: amol, N2 : 4a mol v O2: a mol.
Phn ng : 2SO2 + O2 2SO3 (1) (C th chn a=1 mol)
TI LIU BD HSG HA
0,25
L Vit Hng
0,25
0,25
0,25
0,5
Phn ng: 3Ba(OH)2 + Al2(SO4)3 3BaSO4 + 2Al(OH)3 (1)
3V1x
V1y
3
1
x
=
x=y = 1
Ta c:
3V1x V1 y
y
Chn x = y =1, khi m=3V1.233+ 2.V1.78=855V1gam (I)
Do 0,9m<m(gam) nn c 2 trng hp xy ra
Trng hp 1: Al2(SO4)3 d, Ba(OH)2 ht
2
Theo(1): 0,9m=V2.233+ V2 .78 = 285V2 gam(II)
3
V2
= 2, 7
T (I, II) :
V1
Trng hp 2: Kt ta tan mt phn
Sau (1) xy ra tip phn ng: 2Al(OH)3+Ba(OH)2 Ba(AlO2)2+4H2O(2)
Theo(1,2): Khi lng kt ta tan l 0,1m= (V2 3V1 ).2.78 = 0,1m (III)
V2
= 3,548 (=3,55)
T (I, III) :
V1
Cu 3
1
40
=0,4 mol
100
Gi x, y ln lt l s mol ca Fe2O3 v CuO trong 24 gam hn hp
Ta c: nCO2 = nCaCO3 =
0,5
0,5
4,0 im
1,0
t
2Fe + 3CO2 (1)
Phn ng : Fe2O3 + 3CO
x
3x
to
Cu + CO2 (2)
CuO + CO
y
y
Ca(OH)2 + CO2 CaCO3 + H2O (3)
Theo bi ra ta c h phng trnh:
y =0,1
160x +80y =24

3x +y =0,4
x =0,1
2
1,0
Phn ng : a) HCl + CH3COONa NaCl + CH3 COOH

b) O3 + 2KI + H2O 2KOH + I2 + O2
c) Ba(OH)2 + 2NH4Cl BaCl2 + 2NH3 + 2H2O
d) Fe + CuSO4 Cu + FeSO4
y.100
y
=
Ta c: nHNO3 (phn ng) =
63.125 63.1,25
1,0
S : X+Y+Z + HNO3 X(NO3)3 + Y(NO3)2 + ZNO3 + NO2 + NO (1)

y
V
V
).63
y =1,25.(10x+
p dng LBT:
=3x+4x + 3x +
22,4
63.1,25
22,4
0,5
0,5
Cu 4
1
2K + 2HCl 2KCl + H2 (1)

M + 2HCl MCl2 + H2 (2)
Theo (1,2) v bi ra:
a+2b=0,5
11
9
18,3 < M < 34,8 (do 0 < b < 0,25)
<
M 22, 4
39a+b.M =8,7
4,0 im
0,5
Phn ng:
TI LIU BD HSG HA
Trang 51
1,0
Vy M l Mg
L Vit Hng
- iu ch etyl axetat: CH3COOC2H5

axit, t o
(-C6H10O5-)n + nH2O nC6H12O6
2,5
men
C6H12O6 2C2H5OH + 2CO2
men gia
m
CH3COOH + H2O
C2H5OH + O2
H 2SO 4 , t o
CH3COOC2H5 + H2O
CH3COOH + C2H5OH
- iu ch etilen
H2SO4d ,1700 C
C2H5OH
CH2=CH2 + H2O
- iu ch PVC: (-CH2-CHCl-)n
t0
CaO
CH3COONa + NaOH(rn)
CH4 + Na2CO3
15000 C
CH CH
LLN
2CH4
+ 3H2
xt , t o
CH CH + HCl
CH2=CHCl
o
xt , p , t
nCH2=CHCl (-CH2-CHCl-)n
C th theo cch khc cng cho im ti a:
C2H4 C2H4Cl2 C2H3Cl PVC
Mi phng trnh 0,25 im 0,25x10= 2,5 im
Cu 5
t ancol ROH l: CxHyO, axit RCOOH: CaHbO2
Phn 1: 2ROH + 2Na 2RONa + H2 (1)
2 RCOOH + 2Na 2RCOONa + H2 (2)
Phn 2: CxHyO + (x+y/4 -1/2)O2 xCO2 + y/2H2O (3)
CaHbO2 + (a+b/4 - 1)O2 aCO2 +b/2H2O (4)
H 2SO4 , t o
RCOOR + H2O (5)

Phn 3: ROH + RCOOH
ng mi phng trnh phn ng 0,25 im 5x0,25=1,25 im

Theo (1, 2): n(1/3A)= 2nH2=2.5,6/22,4= 0,5 mol
Nu H%(5)=100% th n(ROH p)=n(R/COOH p)=0,12.100/60=0,2 mol
C hai trng hp:
Trng hp 1: nROH = 0, 2mol nR 'COOH = 0,3mol
Theo(3, 4): 0,2x + 0,3a = 39,6/44 = 0,9 (= nCO2 khi t phn 2)
2x + 3a = 9 x = 3 , a = 1
Trong A: C3HyO : 0,2 mol v HCOOH : 0,3 mol
mA= 3[(12.3+y+16)0,2 + 46.0,3]=76,2 y=6
4,0 im
1,25
0,5
0,5
0,5
Vy CTPT, CTCT cc cht trong A: C3H6O (CH2=CH-CH2-OH)

HCOOH
0,25
Trng hp 2: nR ' COOH = 0, 2mol nROH = 0,3mol

Theo(3, 4): 3x + 2a = 9 x = 1, a= 3
Trong A: CH4O : 0,3 mol v C3HbO2 : 0,2 mol
mA= 3[32.0,3 + (68+b)0,2]=76,2 b=11 (loi v b l)
0,5
0,5
Ghi ch: Th sinh c th lm cch khc, nu ng vn t im ti a trong mi cu. Nu PTHH

thiu iu kin hoc thiu cn bng hoc thiu c hai th tr mt na s im ca PTHH .
. HT .
TI LIU BD HSG HA
Trang 52
L Vit Hng
17
UBND TNH TIN GIANG
CNG HA X HI CH NGHA VIT NAM
S GIO DC V O TO
c lp T do Hnh phc
P N K THI CHN HC SINH GII LP 9 THCS CP TNH
Kha ngy : 20/3/2012
p n chnh thc
Mn : HA HC
p n c 3 trang, gm 4 cu.
Cu 1( 5 im)
a.C cc phn ng sau:
MnO2 + HClc kh X +
t0
kh Y +
KClO3
MnO2
0
t
NH4Cl(r) + NaNO2(r)
kh Z +
0
t
FeS + HCl
kh M + ...
Cho cc kh X, Y, Z , M phn ng vi nhau (tng i mt) iu kin thch hp .Hy hon thnh v
vit cc phng trnh phn ng ha hc xy ra.
b. Ho tan hon ton hn hp X gm x mol Na v y mol Al vo nc thu c V lt kh H 2 (ktc) v
dung dch Y. Hy vit cc phng trnh phn ng ha hc xy ra v lp biu thc tnh V theo x v y.
p n:
a.MnO2 + 4HClc Cl2 (X) + MnCl2 +2H2O
0,5
t0
3O2 (Y) + 2KCl
2KClO3
0,5
MnO2
0
t
NH4Cl(r) + NaNO2(r)
N2 (Z) + NaCl + 2H2O
0
t
FeS + 2HCl
H2S (M) + FeCl2
Cl2 + H2S
2HCl + S
3O2 + 2H2S 2H2O + 2SO2
t0
2 NO
N2 + O2
b.
Na + H2O NaOH + H2
x
0,5
0,5
x/2
NaOH + Al + H2O NaAlO2 + 3/2 H2

y
0,5
0,5
0,5
0,5
3y/2
Do ha tan ht hn hp nn nhm phn ng ht.

V = 22,4(x/2 +3y/2)
0,5
0,5
Cu 2( 5 im)
a.Vit cc ng phn cha vng benzen ca hp cht hu c c cng thc phn t l C7H8O .
b. Han thnh s sau v vit cc phng trnh phn ng ha hc xy ra di dng cng thc cu
to(c km iu kin phn ng).
B+C
A
B+C
D
2
D+HO
E
E + O2
F + H2O
4 8 2
F+E
C H O +H2O
p n:
a. 5 cu to x 0,5
TI LIU BD HSG HA
Trang 53
L Vit Hng
CH 3
CH 2OH
CH 3
OH
OH
CH 3
OCH 3
OH
b. 5 phn ng x 0,5
A: CH4
B: C2H2
C:H2
D:C2H4
E:C2H5OH
F: CH3COOH
C4H8O2: CH3COOC2H5
iu kin ca phn ng
0
1.1500 C, lm lnh nhanh

0
2.Pd, t
3.H2SO4 l
4.Men gim.
0
5.H2SO4 ,t
Cu 3:( 5 im)
Cho 5,4 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO 4. Sau mt thi gian, thu c
dung dch Y v 5,68 gam cht rn Z. Cho ton b Z vo dung dch HCl (long, d), sau khi cc phn ng
kt thc th khi lng cht rn gim 0,56 gam v dung dch thu c ch cha mt mui duy nht.
a.Vit cc phng trnh phn ng ha hc xy ra v xc nh cc cht c trong Y v Z.
b.Tnh phn trm khi lng ca cc cht trong X .
p n:
a.
Do Zn c tnh kh mnh hn Fe v mZ > mX nn Zn ht,Fe d.
Dung dch thu c ch c 1 mui duy nht l FeCl2
Vy Z gm: Fe d v Cu.
0,5
Gi a,b v x ln lt l s mol Zn b, Fe b v Fe phn ng.
Zn + CuSO4
ZnSO4
0,5
Cu +
a
a
a
Fe + CuSO4
FeSO4
0,5
Cu +
x
x
x
Fe + 2HCl
0,5
FeCl2 + H2
0,01
0,01
Y gm: ZnSO4 v FeSO4
0,5
b.
nFe d = 0,01
Ta c:
65a + 56b = 5,4 (1)
0,5
64(a +x) + 0,56 = 5,68
a + x = 0,08 (2)
0,5
b x = 0,01 (3)
0,5
Gii h:
a =0,04
b= 0,05
TI LIU BD HSG HA
Trang 54
L Vit Hng
x= 0,04
0,5
% Fe =51,85
% Zn =48,15
0,5
Cu 4:( 5 im):
t chy hon ton 2,4 gam mt hirocacbon X iu kin thng l cht kh, dn sn phm chy
qua bnh ng dung dch nc vi trong. Sau phn ng thu c 15 gam kt ta v thy khi lng dung
dch gim 4,92 gam.
a. Xc nh cng thc phn t ca X.
b.Cho hn hp A gm 0,1 mol C2H4, 0,2 mol X (tm c trn) v 0,7 mol H2. X c nung trong
bnh kn c xc tc l Ni. Sau mt thi gian thu c 0,8 mol hn hp Y, Y phn ng va vi 100ml
dung dch Br2 aM. Tnh a.
p n:
a.
m ddgim=m CaCO3 m CO2 m H2O
0,5
mCO2 + mH2O =15 4,92 =10,08 gam
0,5
LBTKL: mO2 = 10,08 2,4 =7,68 gam
nO2 = 0,24 mol
0,5
CxHy + (x + y/4) O2
0,5
xCO2 +y/2H2O
a
a( (x + y/4)
Ta c:
a( 12x + y) = 2,4 (1)
a( (x + y/4) = 0,24 (2)
0,5
Gii (1) & (2)
x/y = .Do X iu kin thng l cht kh nn :
x=3,y=4 Vy:X l C3H4
0,5
b.
nH2 p=0,2 mol
BT s lin kt pi
nH2 p + nBr2 p = 0,1 + 0,2.2
1
nBr2 p = 0,3 mol
a= 3M
1
LU :Hc sinh gii ng bng bt c cch gii no cng cho trn im
TI LIU BD HSG HA
Trang 55
L Vit Hng
18
S GD & T VNH PHC
K THI CHN HSG LP 9 THCS NM HC 2011 -2012
THI MN: HO HC
CHNH THC
Thi gian lm bi: 150 pht, khng k thi gian giao .
Cu 1 ( 2,0 im). Vit cc phng trnh phn ng theo s sau.

1500oC
B
A (kh) Lm
CH3COOC2H5
E
D
C
lnh nhanh
CH3COONa
NaOH
CaO
X (r
n)
Y (kh)
Cu 2 (1,5 im).
1. C 5 dung dch khng c nhn v cng khng c mu: NaCl, HCl, NaOH, Na 2SO4 , H2SO4 . nhn
ra tng dung dch, ngi ta a ra cc phng n sau:
a/ Dng qu tm v dung dch AgNO3 .
b/ Dng qu tm v dung dch BaCl2 .
Phng n no ng ? Gii thch ? Vit phng trnh phn ng ?
2. i t cc cht ban u l vi, than v c dng thm cc cht v c cn thit, hy vit cc
phng trnh phn ng iu ch ra polivinyl clorua, 1,2- icloetan.
Cu 3 (1,5 im). Oxi ha m gam hp cht hu c A bng CuO ri cho sn phm sinh ra gm CO 2 v hi
H2O ln lt i qua bnh 1 ng H 2SO4 c v bnh 2 ng 2 lt Ca(OH) 2 0,0225 M. Kt thc cc qu
trnh ngi ta thy khi lng bnh 1 tng 1,08 gam, bnh 2 thu c 2 gam kt ta v khi lng CuO
gim 3,2 gam.
Xc nh cng thc phn t ca A bit MA < 100.
Cu 4 (1,5 im)
th hnh bn biu din tan S trong nc
ca cht rn X.
a/ Hy cho bit trong khong nhit t 00C
n 700C c nhng khong nhit no ta thu
c dung dch bo ha v n nh ca X?
b/ Nu 130 gam dung dch bo ha X ang
700C h nhit xung cn 300C. Hi c bao
t0(0C)
nhiu gam X khan tch ra khi dung dch?
Cu 5 (1,0 im). Hn hp kh A gm 2
hirocacbon. t chy hon ton 1 lt A trong kh oxi thu c 1,6 lt kh CO2 v 1,4 lt hi nc.
Xc nh cng thc phn t cc hirocacbon c trong hn hp kh A, bit rng th tch cc kh v
hi nc o cng iu kin nhit v p sut.
Cu 6 (1,5 im). t chy hon ton a gam S ri cho sn phm sc qua 200 ml dung dch NaOH bM thu
c dung dch X. Chia X lm hai phn bng nhau. Phn 1 cho tc dng vi dung dch CaCl 2 d thy
xut hin c gam kt ta. Phn 2 tc dng vi dung dch nc vi trong d thy xut hin d gam kt ta.
Bit d > c. Tm biu thc quan h gia a v b.
Cu 7 (1,0 im). Mt hn hp X gm Na, Ca, Na 2O v CaO. Ha tan ht 25,65 gam hn hp X vo
nc thu c 2,8 lt H2 (ktc) v dung dch Y trong c 14 gam NaOH. Hp th hon ton 16,8 lt
CO2(ktc) vo dung dch Y tnh khi lng kt ta thu c.
Ht
Cho: C = 12; H = 1; O = 16; Na = 23; Mg =
TI LIU BD HSG HA
Trang 56
L Vit Hng
S GD&T VNH PHC
K THI CHN HSG LP 9 THCS NM HC 2011-2012

HNG DN CHM: MN HA HC
Cu 1 ( 2,0 im) Vit cc phng trnh phn ng theo s sau.

1500oC
B
A (kh) Lm
CH3COOC2H5
E
D
C
lnh nhanh
CH3COONa
NaOH
CaO
X (r
n)
Y (kh)
Ni dung
im
S bin ha:
Cc phng trnh ha hc biu din s trn:
0,5
CaO
CH4 + Na2CO3
1. CH3COONa + NaOH
to
o
1500 C
C2H2 + 3H2
2. 2CH4
lm lnh nhanh
Pd/ PbCO
3
C2H4
3. C2H2 + H2
to
0,25
H2SO4
4. C2H4 + H2O
CH3CH2OH
men gim
5. C2H5OH + O2
CH3COOH + H2O
0,25
H2SO
4 CH3COOC2H5 + H2O
6. CH3COOH + C2H5OH
to
0,25
7. Na2CO3 + 2HCl
2NaCl + CO2 + H2O
Hc sinh khng vit s vn cho s im (nu ng), hc sinh c th chon s khc
(nu ng) vn cho s im.
0,25
0,25
0,25
Cu 2(2,0 im). 1) C 5 dung dch khng c nhn v cng khng c mu : NaCl, HCl, NaOH, Na2SO4 ,
H2SO4 . nhn ra tng dung dch ngi ta a ra cc phng n sau :
a/ Dng qu tm v dung dch AgNO3 .
b/ Dng qu tm v dung dch BaCl2 .
Phng n no ng ? Gii thch ? Vit phng trnh phn ng ?
2. i t cc cht ban u l vi, than v c dng thm cc cht v c cn thit, hy vit
phng trnh phn ng iu ch ra polivinyl clorua, 1,2 - icloetan.
Ni dung
1/ V 5 dung dch nhn bit gm : 1 baz, 2 axit mnh, 2 mui tan tt nn u tin dng qu
tm phn nhm.
- Trong 2 axit cng nh 2 mui u c gc axit l Cl- v SO42- nn ta c th dng
tip mui AgNO3 hay BaCl2 u c.
- Dng qu tm :
+ Ha xanh : NaOH ( nhm 1 )
+ Ha : HCl, H2SO4 ( nhm 2 )
+ Khng i mu : NaCl, Na2SO4
a/ Dng qu tm v dung dch AgNO3 :
- Nhm 1 : kt ta trng l HCl, cn li l H2SO4
- Nhm 2 : kt ta trng l NaCl, cn li l Na2SO4
HCl + + AgNO3 HNO3 + 2AgCl
NaCl + AgNO3 NaNO3 + 2AgCl
b/ Dng qu tm v dung dch BaCl2 :
- Nhm 1 : kt ta trng l H2SO4, cn li l HCl
- Nhm 2 : kt ta trng l Na2SO4 , cn li l NaCl
TI LIU BD HSG HA
Trang 57
L Vit Hng
im
0.5
0.5
BaCl2 + H2SO4 2HCl + BaSO4
BaCl2 + Na2SO4 2NaCl + BaSO4
t0
2. CaCO3 CaO + CO2
CaO + 3C t0 CaC2 + CO
CaC2 + 2H2O C2H2 + Ca (OH)2
H C C H + HCl CH2 = CHCl
0 , p , xt
(- CH2 - CHCl-)n
nCH2 = CHCl t
t 0, Pd / PbCO3
H C C H + H2
CH2 = C H2
CH2 = C H2 + Cl2 CH2Cl -CH2Cl
1.0
Cu 3 (1,5 im). Oxi ha m gam hp cht hu c A bng CuO ri cho sn phm sinh ra gm CO2 v hi
H2O ln lt i qua bnh 1 ng H2SO4 c v bnh 2 ng 2 lt Ca(OH)2 0,0225 M. Kt thc cc qu
trnh ngi ta thy khi lng bnh 1 tng 1,08 gam, bnh 2 thu c 2 gam kt ta v khi lng CuO
gim 3,2 gam.
Xc nh cng thc phn t ca A bit MA < 100.
Ni dung
im
1. n(H2O) = 0,06 mol n(H) = 0,12 mol
T cc phn ng :
0,25
2CO2 + Ca(OH)2 Ca(HCO3)2
0,25
vi n Ca ( OH ) 2 = 0,045mol v n CaCO3 = 0,02mol n(CO2) bng 0,02 mol hoc 0,07
mol.
3,2gam
n(O) tham gia phn ng bng 16gam / mol = 0,2mol

Vy s mol O trong A bng :
Trng hp 1: nu s mol CO2 bng 0,02 mol
n(O) = 0,02mol 2 + 0,06 mol 0,2 mol < 0 (loi)
Trng hp 2: nu s mol CO2 bng 0,07mol
n(O) = 0,07mol 2 + 0,06 mol 0,2 mol = 0 mol
A l hidrocacbon c cng thc n gin C7H12
V MA < 100, nn cng thc phn t ca A chnh l C7H12
0,5
0,5
Bi 4 (1,5 im)
th biu din tan S trong nc ca cht
rn X nh sau:
a/ Hy cho bit trong khong nhit t 00C
n 700C c nhng khong nhit no ta thu
c dung dch bo ha v n nh ca X?
b/ Nu 130 gam dung dch bo ha X ang
700C h nhit xung cn 300C. Hi c bao
nhiu gam X khan tch ra khi dung
t0(0C)
Ni dung
a. Dung dch bo ha trong khong nhit t 00C
100C; 300C
400C; 600C
700C.
b.Khi lng X kt tinh:
+ S gam cht tan v s gam nc c trong 130 g dd 700C:
C 100 g nc ha tan 25 g X to thnh 125 g dd
xg nc ha tan y g X to thnh 130 g dd bo ho
=> x = 104 g v y = 26 g.
+ Tnh s gam cht tan X c trong 104 g nc 300C :
mct X = 15 . 104 : 100 = 15,6 (g)
+ S gam X tch ra khi h nhit t 700C xung 300C = 26 15,6 = 10,4 (g)
TI LIU BD HSG HA
Trang 58
L Vit Hng
im
0,75
0,75
Cu 5(1,0 im). Hn hp kh A gm 2 hirocacbon. t chy hon ton 1 lt A trong kh oxi thu c
1,6 lit kh CO2 v 1,4 lt hi nc.
Ni dung
1/ t cng thc chung ca cc cht trong hn hp l CxHy.
PTHH : CxHy.+ ( x +
im
y
y
) O2 t0 xCO2 +
H2O (1)
4
2
T (1) : th tch CO2 = x . th tch CxHy 1,6 = x.

Do A phi cha 1 cht c s nguyn t C < 1,6 => A cha CH4.
Th tch hi H2O =
y
y
. th tch CxHy 1,4 =
2
2
0,25
=> y = 2,8
Trong A c 1 hidrocacbon c s nguyn t H < 2,8, cht cn li cha 2 nguyn t H.

t cng thc l CnH2.
Gi th tch ca ring CH4 trong 1 lit A l a lit.
Th tch ring ca CxH2 = 1 a (lit).
[ 4.a + 2(1 a )]
y=
= 2,8 a = 0,4.
1
[1.0,4 + n(1 0,4)]
n=
= 1,6 n = 2.
1
Cng thc ca CnH2 l C2H2 .
Vy cng thc phn t ca cc cht trong hn hp A l CH4 v C2H2 .
0,25
0,5
Cu 6(1,5 im). t chy hon ton a gam S ri cho sn phm sc qua 200 mL dung dch NaOH b M
thu c dung dch X. Chia X lm hai phn bng nhau. Phn 1 cho tc dng vi dung dch CaCl 2 d thy
xut hin c gam kt ta. Phn 2 tc dng vi dung dch nc vi d thy xut hin d gam kt ta. Bit d >
c. Tm biu thc quan h gia a v b.
Ni dung
im
Phng trnh :
(1) S + O2 SO2
0,25
(2) SO2 + NaOH NaHSO3
(3) SO2 + 2 NaOH Na2SO3 + H2O
Phn I tc dng vi dung dch CaCl2 sinh kt ta, chng t dung dch X c cha
0,25
Na2SO3, phn II tc dng vi dung dch Ca(OH) 2 sinh nhiu kt ta hn chng t
dung dch X c mui NaHSO3
(4) Na2SO3 + CaCl2 CaSO3 + 2NaCl
0,25
(5) Na2SO3 + Ca(OH)2 CaSO3 + 2NaOH
(6) NaHSO3 + Ca(OH)2 CaSO3 + NaOH + H2O
0.25
ns = a/32 (mol) , nNaOH = 0,2 b ( mol)
Theo (2),(3), SO2 tc dng vi dung dch NaOH sinh 2 loi mui th :
0, 2b 6, 4b
n
n
1 < NaOH = NaOH < 2 1 < a = a < 2
n SO2
nS
32
0.5
a
a
<b<
Vy :
3,2b < a < 6,4b
6, 4
3, 2
Cu 7(1,0 im). Mt hn hp X gm Na, Ca, Na 2O v CaO. Ha tan ht 25,65 gam hn hp X vo nc
thu c 2,8 lt H2 (ktc) v dung dch Y trong c 14 gam NaOH. Hp th hon ton 16,8 lt
CO2(ktc) vo dung dch Y tnh khi lng kt ta thu c.
Ni dung
im
Quy i hn hp ban u gm Na, Ca v O2. t s mol tng ng mi cht c trong
hn hp l x,y,z.
TI LIU BD HSG HA
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Khi lng hn hp: mhh = 23x+ 40y + 32z = 25,65 (1)
nh lut bo ton e: x + 2y = 4z + 0,125x2 (2)
nh lut bo ton nguyn t: nNaOH = x = 0,35 (3)
Gii h phng trnh ta thu c : x= 0,35 mol, y = 0,3 mol v z= 0,175 mol
Vy dung dch Y cha 0,35 mol NaOH, 0,3 mol Ca(OH)2
Hp th CO2 vo dung dch Y c cc phn ng
Ca(OH)2 + CO2 CaCO3 + H2O (1)
CO2 : 2NaOH + CO2 Na2CO3 + H2O (2)
CO2 : Na2CO3 + CO2 + H2O 2NaHCO3 (3)
CO2 : CaCO3 + CO2 + H2O Ca(HCO3)2 (4)
Da vo cc phn ng ta tnh c khi lng kt ta l 20gam.
0,5
0,5
* Ch
Hc sinh lm theo cc cch khc ( nu ng vn cho s im). Nu cha ra n kt qu th ng n
u chm n .
---------------------Ht--------------------24; Ca = 40; Fe = 56; Br = 80; N = 14; Al = 27;
Ba = 137; Cr = 52; Cu = 64; Ag = 108.
H v tn th sinh:SBD:..
Cn b coi thi khng gii thch g thm!
Th sinh khng c dng bt c ti liu no k c BTH cc nguyn t ha hc.
TI LIU BD HSG HA
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19
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TI LIU BD HSG HA
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L Vit Hng
S GIO DC V OTO
LO CAI
20
LP 9 THCS NM HC 2011-2012
Cu 1. (4,0 im)
1. Nung nng Cu trong khng kh mt thi gian c cht rn A. Ha tan A bng H 2SO4 c nng
d c dung dch B v kh C. Kh C tc dng vi dung dch KOH thu c dung dch D. Dung dch D
va tc dng vi dung dch BaCl2, va tc dng vi dung dch NaOH. Cho B tc dng vi dung dch
KOH. Vit cc phng trnh ha hc xy ra.
2. T pirit st, nc bin, khng kh v cc thit b cn thit khc. Hy vit phng trnh ha hc
iu ch cc cht: nc Javen, FeSO4, FeCl3.
Cu 2. (4,0 im)
1. Bng phng php ha hc, hy nhn bit cc hn hp sau: (Fe + Fe 2O3), (Fe + FeO), (FeO +
Fe2O3).
2. Nu hin tng xy ra trong mi trng hp sau v vit phng trnh ha hc xy ra:
a. Cho kh CO2 li chm qua nc vi trong, sau thm tip nc vi trong vo dung dch thu
c.
b. Cho t t dung dch HCl vo dung dch Na2CO3.
Cu 3. (4,0 im)
1. Tm cc cht k hiu bng ch ci trong s sau v hon thnh s bng phng trnh ha
hc:
1500oC
B
A (kh) Lm
CH3COOC2H5
E
D
C
lnh nhanh
CH3COONa
NaOH
CaO
X (r
n)
Y (kh)
2. T mt loi tinh du ngi ta tch ra c hp cht hu c A. t chy hon ton 2,64 gam A
cn va 4,704 lt kh oxi (ktc) ch thu c CO2 v H2O vi t l khi lng l
mCO2
mH2O
11
. Bit
2
M A < 150. Xc nh cng thc phn t ca A.

Cu 4. (3,0 im)
1. Ha tan 5,72 gam Na2CO3.xH2O trong 44,28 gam nc ta thu c dung dch c nng
4,24%. Xc nh cng thc ca hirat.
2. Kh 3,48 gam oxit mt kim loi M cn dng 1,344 lt H 2 (ktc). Ton b lng kim loi thu
c cho tc dng vi dung dch HCl d thu c 1,008 lt H 2 (ktc). Xc nh kim loi M v oxit ca
n.
Cu 5. (2,0 im)
Cho 87 gam dung dch ru etylic tc dng vi Na ly d th thu c 28 lt kh H2 (ktc).
a. Tnh khi lng ca ru etylic v nc trong dung dch.
b. Tnh ru ca dung dch ru trn (bit khi lng ring ca ru nguyn cht l 0,8 g/ml)
Cu 6. (3,0 im)
Cho 5,12 gam hn hp X gm 3 kim loi Mg, Fe v Cu dng bt tc dng vi 150 ml dung dch
HCl 2M, sau khi phn ng kt thc thy ch thot ra 1,792 lt kh H 2 (ktc). em lc ra thu c 1,92
gam cht rn B.
a. Tnh khi lng mi kim loi c trong hn hp X.
b. Cho 2,56 gam hn hp X tc dng vi 250 ml dung dch AgNO 3 0,34M. Khuy k hn hp
cho phn ng xy ra hon ton, thu c dung dch v cht rn E. Tnh khi lng ca cht rn E.
-------------------- Ht -------------------Ch :
- Th sinh c s dng bng tun hon cc nguyn t ha hc.
- Cn b coi thi khng gii thch g thm.
TI LIU BD HSG HA
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L Vit Hng
S GIO DC & O TO
HI DNG
-------------- CHNH THC
21
K THI TUYN SINH LP 10 THPT CHUYN NGUYN TRI
NM HC 2012-2013
MN THI: HO HC
( thi gm: 01 trang)
Cu 1 (2 im)
1. Cho hn hp gm Al2O3, Cu, Fe2O3 vo dung dch H2SO4 long d thu c dung dch X v cht rn
Y. Cho t t dung dch NaOH ti d vo dung dch X thu c dung dch Z v kt ta M. Nung kt ta
M ngoi khng kh ti khi lng khng i thu c cht rn N. Cho kh H 2 d i qua N nung nng thu
c cht rn P. Sc kh CO2 ti d vo dung dch Z thu c kt ta Q.
a. Xc nh thnh phn cc cht c trong X, Y, Z, M, N, P, Q. Bit cc phn ng xy ra hon ton.
b. Vit cc phng trnh phn ng ho hc xy ra.
2. Cho hn hp kim loi Mg, Fe vo dung dch cha hn hp mui Cu(NO 3)2, AgNO3. Phn ng xy ra
hon ton, thu c hn hp cht rn A gm 3 kim loi v dung dch B cha 2 mui. Trnh by phng
php tch ring tng kim loi ra khi hn hp A. Vit phng trnh ho hc.
Cu 2 (2 im)
Cho hai hp cht hu c X, Y cha (C,H,O) ch cha mt loi nhm chc hc v c khi lng
mol phn t u bng 46 gam.
1. Xc nh cng thc cu to ca X, Y. Bit X, Y u phn ng vi Na, dung dch ca Y lm qu tm
ho .
2. T X vit cc phng trnh ho hc iu ch Polivynylclorua (PVC) v Polietylen (PE).
Cu 3 (2 im)
1. Hy chn cc cht thch hp v vit cc phng trnh phn ng hon thnh s bin ha sau:
Cho bit:
+ (X)
+(X) +
(B)
(D)
(P)
(A)
Cc cht A, B, D l hp cht ca Na;
Cc cht M v N l hp cht ca Al;
+(Y)
Cc cht P, Q, R l hp cht ca Ba;
+(Y)
+(X) +
Cc cht N, Q, R khng tan trong nc.
(N)
(Q)
(R)
(M)
- X l cht kh khng mi, lm c dung dch nc vi trong;
- Y l mui Na, dung dch Y lm qu tm.
2. T 9 kg tinh bt c th iu ch c bao nhiu lit ru (ancol) etylic 46 o? Bit hiu sut ca c qu
trnh iu ch l 72%, khi lng ring ca ru etylic nguyn cht l 0,8g/ml.
Cu 4 (2 im)
Nung 9,28 gam hn hp A gm FeCO3 v mt oxit st trong khng kh n khi lng khng i.
Sau khi phn ng xy ra hon ton, thu c 8 gam mt oxit st duy nht v kh CO 2. Hp th ht lng
kh CO2 vo 300 ml dung dch Ba(OH)2 0,1M, kt thc phn ng thu c 3,94 gam kt ta.
1. Tm cng thc ho hc ca oxit st.
2. Cho 9,28 gam hn hp A tc dng vi dung dch HCl d, sau khi phn ng kt thc thu c dung dch B.
Dn 448ml kh Cl2 (ktc) vo B thu c dung dch D. Hi D ho tan ti a bao nhiu gam Cu?
Cu 5 (2 im)
Thu phn hon ton 19 gam hp cht hu c A (mch h, phn ng c vi Na) thu c m 1 gam
cht B v m2 gam cht D cha hai loi nhm chc.
- t chy m1 gam cht B cn 9,6 gam kh O2 thu c 4,48 lit kh CO2 v 5,4 gam nc.
- t chy m2 gam cht D cn 19,2 gam kh O2 thu c 13,44 lit kh CO2 v 10,8 gam nc.
1. Tm cng thc phn t A, B, D.
2. Xc nh cng thc cu to ca A, B, D.
Cho bit: Fe = 56; Ba = 137; C = 12; O = 16; H = 1; Na = 23; Cl = 35,5; Cu = 64
TI LIU BD HSG HA
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L Vit Hng
------------------------------ Ht ------------------------------H v tn th sinh: .. S bo danh:
.
Ch k ca gim th 1: . Ch k ca gim th 2:
.
S GIO DC & O TO
HI DNG
--------------P N CHNH THC
Cu/
1
1
(1)
2
(1)
HNG DN CHM V BIU IM THI TUYN SINH LP

10 THPT CHUYN NGUYN TRI
NM HC: 2012 1013
MN THI: HO HC
( p n gm: 05 trang)
HNG DN
a. Dung dch X : Al2(SO4)3, CuSO4, FeSO4, H2SO4 Cht rn N

: CuO, Fe2O3
Cht rn Y : Cu
Cht rn P
: Cu, Fe
Dung dch Z : NaAlO2, Na2SO4, NaOH
Kt ta Q
: Al(OH)3
Kt ta M
: Cu(OH)2, Fe(OH)2
b. PTHH: Al2O3 + 3H2SO4
Al2(SO4)3 +3H2O
Fe2O3 + 3H2SO4
Fe2(SO4)3 +3H2O
Cu + Fe2(SO4)3
CuSO4 + 2FeSO4
6NaOH + Al2(SO4)3
2Al(OH)3+ 3Na2SO4
NaOH + Al(OH)3
NaAlO2 + 2H2O
2NaOH + FeSO4
Fe(OH)2+ Na2SO4
2NaOH + CuSO4
Cu(OH)2+ Na2SO4
to
Cu(OH)2
CuO + H2O
to
4Fe(OH)2 + O2
2Fe2O3 + 4H2O
to
CuO + H2
Cu + H2O
to
Fe2O3 + 3H2
2Fe + 3H2O
CO2 + NaOH
NaHCO3
CO2 + H2O + NaAlO2
Al(OH)3 + NaHCO3
PTHH:
Mg + AgNO3
Mg(NO3)2 + 2Ag
Mg + Cu(NO3)2
Mg(NO3)2 + Cu
Fe + AgNO3
Fe(NO3)2 + 2Ag
Fe + Cu(NO3)2
Fe(NO3)2 + Cu
Cht rn A : Ag, Cu, Fe
Dung dch B : Mg(NO3)2, Fe(NO3)2
Cho cht rn A vo dung dch HCl d. Thu c phn cht rn l kim loi Cu, Ag v
phn dung dch FeCl2 v HCl
Fe + 2HCl
FeCl2 + H2
Cho NaOH d vo phn dung dch, thu c kt ta l Fe(OH)2
NaOH + HCl
NaCl + H2O
NaOH + FeCl2
Fe(OH)2 + NaCl
Nung kt ta ngoi khng kh n khi lng khng i. Cho lung kh H 2 d i qua
cht rn, nung nng, thu c Fe.
to
4Fe(OH)2 + O2
2Fe2O3 + 4H2O
TI LIU BD HSG HA
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L Vit Hng
Biu
im
0,25
0,25
0,25
0,25
0,25
0,25
to
1
(1,0
)
Fe2O3 + 3H2
2Fe + 3H2O
Nung 2 kim loi trong khng kh ti khi lng khng i thu c cht rn gm CuO
v Ag. Cho cht rn sau phn ng vo dung dch HCl d thu c kim loi Ag.
to
2Cu + O2
2CuO
CuO + 2HCl
CuCl2 + H2O
Cho dung dch NaOH d vo dung dch sau phn ng thu c kt ta, lc ly kt ta
em nung ngoi khng kh ti khi lng khng i, cho lung H 2 d i qua cht rn,
nung nng thu c Cu tinh khit.
NaOH + HCl
NaCl + H2O
CuCl2 + 2NaOH
2NaCl + Cu(OH)2
o
t
Cu(OH)2
CuO + H2O
to
CuO + H2
Cu + H2O
Gi cng thc tng qut ca X, Y l CxHyOz (x, y, z N*)
Ta c: MX, Y = 46 12x + y + 16z = 46.
46 (12 x + y )
z=
16
46 14
z
=2
16
Cho z = 1 12x + y = 30 ( C2H6)
Cho z = 2 12x + y = 14 ( CH2)
Vy cng thc phn t ca X, Y c th l C2H6O, CH2O2.
V Y phn ng vi Na, lm qu tm, Y c nhm -COOH CTPT Y: CH2O2 =>
CTCT ca Y: H-COOH
PTHH: 2HCOOH + 2Na
2HCOONa + H2
X phn ng vi Na, X phi c nhm -OH. CTPT Y: C2H6O
=> CTCT ca X : CH3-CH2-OH
PTHH: 2CH3-CH2-OH + 2Na
2CH3-CH2-ONa + H2
Vit PTHH iu ch polietilen (P.E)
H 2 SO4 d
CH3-CH2-OH
CH2 = CH2 + H2O
170o
0,25
0,25
0,25
0,25
0,25
0,25
0,25
xt , t , p
nCH2 = CH2
(-CH2 = CH2-)n
2
(1,0
)
iu ch polivinylclorua (P.V.C)
men giam
CH3-CH2-OH + O2
CH3COOH + H2O
CH3COOH + NaOH
CH3COONa + H2O
CaO , t o
CH3COONa + NaOH
Na2CO3 + CH4
o
1500 , lamlanh nhanh
2CH4
CH CH + 3H2
CH CH + HCl
CH2=CHCl
o
xt , t , p
nCH2=CHCl
(-CH2-CHCl-)n
Kh X khng mi, lm c dung dch nc vi trong l CO2
Dung dch mui Na m lm qu tm ( mi trng axit) phi l NaHSO4.
(Cc dung dch mui Na khc khng lm i mu qu tm hoc qu tm i mu xanh).
Cc cht tha mn iu kin l:
+ CO2
CO2 + H 2 O
NaOH
Na 2 CO3 +

0,25
0,25
0,25
0,25
0,25
NaHCO3 Ba(HCO3)2
+ NaHSO4
1
+CO + H O
+ NaHSO
Al (OH ) 3
BaSO4
BaCO3
(1,25 NaAlO2
Cc cht c cng thc tng ng nh trn
)
PTHH:
2
TI LIU BD HSG HA
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L Vit Hng
0,25
Na2CO3 + CO2 + H2O 2 NaHCO3
2NaOH + 2Al + 2H2O 2NaAlO2 + 3H2
NaHCO3 + NaOH Na2CO3 + H2O
NaAlO2 + CO2 d + 2H2O Al(OH)3 + NaHCO3
3Na2CO3 + 2AlCl3 + 3H2O 2Al(OH)3 + 6NaCl + 3CO2
2NaHCO3 + Ba(OH)2 d BaCO3 + Na2CO3+ 2H2O
BaCO3 + 2NaHSO4 BaSO4 + Na2SO4 + CO2 + H2O
Ba(HCO3)2 + 2NaHSO4 BaSO4 + Na2SO4 + 2CO2+2H2O
Ba(HCO3)2 + Na2SO4 BaSO4 + 2NaHCO3
2
PTHH:
men
(0,75
(-C6H10O5)n + nH2O
nC6H12O6
)
C6H12O6
2C2H5OH + CO2
=>
(-C6H10O5)n
2nC2H5OH
162n (g)
92n(g)
9(kg)
m(kg)
1
(1,5
)
0,25
0,25
92n 9 46
46 72
= (kg ) ; v H= 72% nn mru thc t =
= 3, 68(kg ) = 3680( g )
162n
9
9 100
3680
= 4600(ml )
Vru =
0,8
4600 100
Vruou 46o =
= 10000(ml ) = 10(lit )
46
Gi cng thc tng qut ca oxit st l FxOy ( x, y N*)
to
PTHH: 4FeCO3 + O2
(1)
2Fe2O3 + 4CO2
3x 2 y)
to
) O2
2FxOy + (
(2)
xFe2O3
2
0,25
8
3,94
= 0, 05(mol ); nBa (OH )2 = 0,3 0,1 = 0, 03( mol ); nBaCO3 =
= 0, 02( mol )
160
197
Cho CO2 vo dung dch Ba(OH)2
PTHH: CO2 + Ba(OH)2
(3)
BaCO3
C th:
2CO2 + Ba(OH)2
(4)
Ba(HCO3)2
Trng hp 1: Xy ra cc phn ng 1, 2, 3
Theo PT(1), (3): nFeCO3 = nCO2 = nBaCO3 = 0, 02( mol )
0,25
m=
0,25
nFe2O3 =
0,25
0,25
0,25
1
nFeCO3 = 0, 01(mol )
2
nFe2O3 ( pu 2) = 0, 05 0, 01 = 0, 04( mol )
Theo (1): nFe2O3 =
Theo PT(2): nFex Oy =
2
2
0, 08
nFe2O3 = 0, 04 =
(mol )
x
x
x
Theo bi ra: mhn hp = mFeCO3 + mFexOy = 9, 28( gam)

0, 08
0, 02 116 +
(56 x + 16 y ) = 9, 28
x
x 16
= (loai )
y 31
Trng hp 2: Xy ra cc phn ng 1, 2, 3, 4
Theo PT (3): nCO2 = nBaCO3 = 0, 02( mol )
nCO2( 4) = 2(0, 03 0, 02) = 0, 02( mol )
0,25
0,25
nCO2 = 0, 04(mol )
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L Vit Hng
Theo PT(1), (3): nFeCO3 = nCO2 = 0, 04(mol )
1
Theo (1): nFe2O3 = nFeCO3 = 0, 02(mol )
2
nFe2O3( 2) = 0, 05 0, 02 = 0, 03( mol )
2
2
0, 06
nFe2O3 = 0, 03 =
( mol )
x
x
x
Theo bi ra: mhn hp = mFeCO3 + mFexOy = 9, 28( gam)
0, 06
0, 04 116 +
(56 x + 16 y ) = 9, 28
x
x 3
= x = 3; y = 4
y 4
Vy cng thc oxit st l Fe3O4 ( st t oxit)
Cho 9,28 gam hn hp A vo dung dch HCl d.
FeCO3 + 2HCl
(5)
FeCl2 + CO2 + H2O
0,04
0,04
Fe3O4 + 8HCl
(6)
FeCl2 + 2FeCl3 + 4H2O
0,02
0,02
0,04
Dung dch B gm: FeCl2 0,06 mol; FeCl3 0,04 mol; HCl d
Cho kh Cl2 = 0,02 (mol) vo dung dch B
2FeCl2 + Cl2
(7)
2FeCl3
0,04
0,02
0,04 (mol)
0,25
Dung dch D c cha: nFeCl3 = 0, 08(mol ) ; nFeCl2 = 0, 02(mol )

2FeCl3 + Cu
(8)
CuCl2 + 2FeCl2
0,08
0,04 (mol)
=> mCu = 0,04.64 = 2,56 gam
Gi cng thc tng qut ca B l CxHyOz (x, y, z N*)
nO2 = 0,3(mol ) ; nCO2 = 0, 2(mol ) ; nH 2O = 0,3( mol )
0,25
Theo PT(2): nFex Oy =
2
(0,5
)
1
(1,5
)
0,25
0,25

m1 + mO2 = mCO2 + mH 2O => m1 = 4, 6( gam)
=> mO ( B ) = 4, 6 (0, 2.12 + 0,3.2) = 1, 6( gam) => nO ( B ) = 0,1( mol )
=> x:y:z = nC: nH: nO = 0,2: 0,6: 0,1 = 2:6:1
=> Cng thc thc nghim (C2H6O)n => 6n 2.2n + 2 => n 1 => n = 1
=> B c cng thc phn t: C2H6O
Do B l sn phm ca phn ng thu phn nn B c CTCT: CH3CH2OH
Gi cng thc tng qut ca D l CaHbOc (a, b, c N*)
nO2 = 0, 6( mol ) ; nCO2 = 0, 6( mol ) ; nH 2O = 0, 6(mol )
0,25
0,25

m2 + mO2 = mCO2 + mH 2O => m2 = 18( gam)
=> mO ( D ) = 18 (0, 6.12 + 0, 6.2) = 9, 6( gam) => nO ( D ) = 0, 6( mol )
=> a:b:c = nC: nH: nO = 0,6: 1,2: 0,6 = 1:2:1
=> Cng thc thc nghim (CH2O)k
Gi cng thc tng qut ca A l CmHnOp (m, n, p N*)
mA + mHO2 = mB + mD => mH 2O = m1 + m2 m A = 4, 6 + 18 19 = 3, 6( gam)
=> mH 2O = 0, 2(mol )
p dng nh lut bo ton nguyn t:
mC(A) = mC(B) + mC(D) = 0,2.12 +0,6.12 = 9,6(g) => nC = 0,8 (mol)
mH(A) = mH(B) + mH(D) - mH ( H 2O ) = 0,6 + 1,2 - 2.0,2= 1,4(g) => nH = 1,4 (mol)
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L Vit Hng
0,25
0,25
2
(0,5
)
mO(A) = 19 mC(A) + mH(A) = 19 - 0,8.12 - 1,4= 8(g) => nO = 0,5 (mol)
m:n:p = nC : nH : nO = 0,8 : 1,4 : 0,5 = 8 : 14 : 5
Do A c Cng thc phn t trng vi cng thc n gin nht
CTPT A: C8H14O5
0,25
nA = 0,1 (mol); nB = 0,1 (mol)
nH 2O = 0, 2(mol ) => nA : nH 2O : nB = 0,1: 0, 2 : 0,1 = 1: 2 :1
A c 2 nhm chc este, khi thu phn cho 1 phn t C2H5OH
D c 2 loi nhm chc v c cng thc thc nghim (CH2O)k v D l sn phm ca
phn ng thu phn => k= 3 => D c cng thc phn t C3H6O3
0,25
B c cng thc cu to CH3-CH2-OH
D c cng thc cu to CH3-CH(OH)-COOH hoc HO-CH2-CH2-COOH
A c CTCT:
CH3-CH(OH)-COO-CH(CH3)-COOC2H5
hoc HO-CH2-CH2-COO-CH2-CH2-COOC2H5
Phng trnh phn ng
0,25
+H+
CH3-CH(OH)-COO-CH(CH3)-COOC2H5 + 2H2O
2CH3-CH(OH)-COOH +
C2H5OH
+
+H
HO-CH2-CH2-COO-CH2-CH2-COOC2H5 + 2H2O
2HO-CH2-CH2-COOH +
C2H5OH
Lu :
Hc sinh c cc phng php gii khc v ng vn cho im ti a theo tng phn
TI LIU BD HSG HA
Trang 69
L Vit Hng
22
S GIO DC V O TO K THI TUYN SINH VO LP 10 NM HC 2012-2013
QUNG NGI
Mn thi : Ha hc (h chuyn )
CHNH THC
Thi gian lm bi :120(khng k thi gian giao )
Cu 1 :(3 im )
1/Chn cc cht A,B,C,D,Ethch hp ri hon thnh cc phng trnh ha hc sau ( bit A l kim loi ,
G l phi kim ):
A + B C+ D+E
D + E + G B+X
BaCl2 + C Y + BaSO4
Z + Y T+A
T + G FeCl3
2/ T cc cht : Na2SO3,NH4HCO3,Al,KMnO4, dung dch HCl c ,dung dch NaOH, vit tt c cc
phng trnh phn ng iu ch cht kh (iu kin phn ng c )
Cu 2 :(2,0 im )
1/Ch dng thm mt ha cht , hy phn bit 5 cht rn :Al ,FeO, BaO, ZnO, Al4C3 ng trong cc l
ring bit .Vit cc phng trnh phn ng xy ra
2/ Trnh by phng php tinh ch NaCl t hn hp rn gm :NaHCO3, Na2CO3, CaCl2, NaCl
Cu 3 : (1,5 im )
1/ C dung dch NaOH , kh CO2, ng ong chia v cc thy tinh cc loi . Trnh by phng php
iu ch dung dch Na2CO3
2/ Ha tan hon ton 11,96 gam mt kim loi kim trong 73 gam dung dch HCl 20%.C cn dng dch
sau phn ng thu c 28,2 gam cht rn .Xc nh tn kim loi kim
Cu 4 : (1,5 im )
Nung hn hp X gm C v CuO n khi phn ng hon ton thu c cht rn A . Cho cht rn A
phn ng va vi 0,5 lt dung dch HCl 0,4M . lc ly phn khng tan sau phn ng cho tc dng vi
dung dch H2SO4 c nng d thu c 1,344l kh ( ktc)
a/ Tnh khi lng ca hn hp X
b/ Cho lng hn hp X nh trn tc dung vi dung dch H2SO4 c 5M va .Tnh th tch kh thot ra
ktc v th tch dung dch axit dng
Cu 5 :( 2,0 im )
Hn hp kh X gm H2,C2H2, C2H4 ,trong s mol ca C2H2 bng s mol ca C2H4 . Cho V lt hn
hp kh X i qua Ni nung nng ( hiu sut phn ng t 100%) thu c 2,24 lt hn hp kh Y c khi
lng 1,32 gam. Xc nh gi tr ca V.(cc th tch o iu kin tiu chun )
Cho:H = 1,O = 16, S = 32 ,Cu = 64,Li = 7 , Na = 23 Cl = 35,5, K = 39
--------Ht -------Th sinh khng c s dng ti liu.Cn b coi thi khng gii thch g thm
HNG DN GII
Cu 1
1/ A: Cu B: H2SO4 C: CuSO4 D : SO2 E :H2O
G:Cl2
X : HCl Y : CuCl2
Z : Fe
T : FeCl2
PTHH: Cu + 2H2SO4 c, nng CuSO4 + SO2 + 2 H2O
SO2 + Cl2 + 2H2O H2SO4 + 2 H2O
BaCl2 + CuSO4 BaSO4 + CuCl2
Fe + CuCl2 FeCl2 + Cu
FeCl2 + Cl2 FeCl3
2/ PTHH :Na2SO3 + 2HCl 2NaCl + H2O + SO2
NH4HCO3 + HCl NH4Cl + H2O + CO2
2 NH4HCO3 + 2NaOH Na2CO3 + 2NH3 + 2H2O
2Al + 2NaOH + 2H2O 2NaAlO2 +3 H2
2Al + 6HCl 2 AlCl3 + 3H2
2KMnO4 + 16 HCl 2 KCl + 2 MnCl2 + 5 Cl2 + H2O
Cu 2
1/Ha cht :H2O
TI LIU BD HSG HA
Trang 70
L Vit Hng
Cch phn bit :
-Trch mi cht ra mt t lm mu th
- Cho cc cht vo nc , cht no tan l BaO, cht no tan to v c l Al4C3
- Cho dung dch Ba(OH)2 thu c trn tc dng vi cc cht khng tan , cht no tan v c l Al ,
cht no tan khng to l ZnO, cht no khng tan l FeO
PTHH:
BaO + H2O Ba(OH)2
Al4C3 + 12 H2O 4 Al(OH)3 + 3 CH4
Ba(OH)2 + 2Al + 2H2O Ba(AlO2)2 + 3H2
Ba(OH)2 + ZnO BaZnO2 + H2O
2/Cch tinh ch :Cho hn hp ha tan vo nc , cho Na2CO3 vo n d , lc b kt ta. Dung dch thu
c sau phn ng cho tc dng vi dung dch HCl d , c cn dung dch sau phn ng thu c NaCl
tinh khit
Cu 3
1/ Sc CO2 n d vo dung dch NaOH , sau c cn ri nung cht rn thu c n khi khng cn
kh thot ra , ha tan cht rn thu c vo nc thu c dung dch Na2CO3
2/Gi tn kim loi kim l M
73 x 20
nCl = nHCl = 100 x35,5 = 0,4 mol

v khi lng kim loi + khi lng clo < khi lng cht rn thu c cht rn c MOH v MCl
mOH = m rn m kim loi m clo = 28,2 11,96 0,4 x 35,5 = 2,04 gam
ta c n MOH = n OH =
2,04
= 0,12 mol , n MCl = 0,4 mol
17
ta c : (M + 35,5) x 0,4 + (M + 17 ) x 0,12 = 28,2 M = 23 : Natri

Cu 4
a/ PTHH:
CuO + C Cu + CO2
CuO + 2 HCl CuCl2 + H2O
Cu + 2H2SO4 c, nng CuSO4 + SO2 + 2 H2O
n CuO d =
1
1
n HCl =
x 0,5 x 0,4 =0,1 mol
2
2
n Cu sinh ra = n SO2 = 0,06 mol ; n C = n Cu = 0,06 mol

n CuO ban u = 0,16 mol
khi lng hn hp X = 0,16 x 80 + 0,06 x 12 = 13,52 gam
b/ tc dng vi H2SO4 c ,nng
CuO + H2SO4 CuSO4 + H2O
C + 2 H2SO4 c,nng CO2 + 2 SO2 + 2 H2O
n kh thot ra = 3 nC trong X = 3 x 0,06 = 0,18 mol V kh = 4,032 lt
s mol H2SO4 dng = 2 x 0,06 + 0,16 = 0,28 mol
th tch dung dch H2SO4 5 M dng = 0,056 lt
Cu 5
Ni . t 0
PTHH : C2H2
+ H2
C2H6
b mol
b mol
b mol
Ni . t 0
C2H4
+ H2
C2H6
b mol
b mol
b mol
Gi a l s mol H2 ban u , b l s mol ca C2H6 , cng l s mol ca C2H4 trong hn hp
S mol hiddro cn li sau phn ng = a 2b mol
S mol hn hp kh ban u = a + 2b
2,24
S mol hn hp kh sau phn ng = 2b + (a -2b) = a mol = 22,4 = 0,1 mol

Khi lng hn hp kh sau phn ng = 2(a 2b) + 2b x 30 = 1,32 gam
2a 4b + 60b = 1,32 gam
56b
= 1,32 2.0,1=1,12
b
= 0,02
S mol hn hp kh ban u = 0,1 + 0,02 x 2 = 0,14 mol V hn hp ban u = 3,136 lt
TI LIU BD HSG HA
Trang 71
L Vit Hng
23
S GIO DC V O TO
THI HC SINH GII
CAO BNG
CP TNH LP 9 NM HC 2010-2011
Mn : Ha hc
Thi
gian
:
150
pht
( khng k thi gian giao )
D B
BI
( gm 02 trang)
Cu 1 : (4,0 im)
1. Trnh by phng php ha hc tch ring tng oxit ra khi hn hp gm: CuO, Al 2O3 v
Fe2O3.
2. Nu hin tng v vit phng trnh phn ng xy ra khi :
a) Sc kh CO2 t t vo dung dch nc vi trong.
b) Cho t t dung dch KOH vo dung dch Al2(SO4)3.
c) Cho t t dung dch Al2(SO4)3 vo dung dch KOH.
Cu 2: (4,0 im)
C 5 l ha cht b mt nhn cha cc cht sau: BaCl2, Na2CO3, H2SO4, NaOH, (NH4)2SO4.
Khng dng thm thuc th hy nhn bit cc cht trn?
Cu 3: ( 4,0 im)
t hn hp C v S trong Oxi d c hn hp kh A. Chia hn hp kh A lm 2 phn.
- Cho phn 1( kh A) li qua dung dch NaOH thu c dung dich B v kh C.
- Cho kh C qua hn hp cha CuO, MgO nung nng thu c cht rn D v kh E.
- Cho kh E li qua dung dch Ca(OH) 2 thu c kt ta F v dung dch G thm dung dch
KOH vo G li thy c kt ta F xut hin. un nng G cng thy kt ta F.
Cho phn 2 (kh A) cn li qua xc tc V 2O5 nhit 450 0 C thu c kh M. Dn M qua
dung dch BaCl2 thy c kt ta N.
Xc nh thnh phn A, B, C, D, E, F, G, M, N v vit tt c cc phng trnh phn ng xy
ra.
Cu 4: (2,0 im)
Ha tan mt lng mui cacbonat ca kim loi ha tr (II) trong mt lng va dung dch
H2SO4 20% thu c mt dung dch mui c nng 28,196%.
Tm cng thc ha hc ca mui cacbonat trn.
Cu 5. ( 2,0 im).
Cho hn hp 2 kim loi Fe v Cu tc dng vi kh Clo d thu c 59,5 gam hn hp mui.
Cng lng hn hp trn cho tc dng vi lng d dung dch HCl 10% thu c 25,4 gam mt
mui.
a. Tnh khi lng mi mui trong hn hp thu c.
b. Tnh th tch dung dch HCl 10% (d = 1,0 g/ml) phn ng.
Cu 6 : (1,0 im)
Hn hp X gm metan, axetilen theo t l th tch l 1: 1. Hy:
a) Tinh ch CH4 t hn hp X.
b) Tinh ch C2H2 t hn hp X.
Cu 7 : (3,0 im)
t chy hon ton 7,3 gam mt hp cht hu c thu c 13,2 gam CO 2 v 4,5 gam H2O.
Mt khc ha hi hon ton 29,2 gam cht hu c trn thu c th tch hi bng th tch ca 6,4
gam O2 (trong cng iu kin).
Tm cng thc phn t hp cht hu c trn.
Cho : H=1, C=12, O=16, S=32, Cl=35,5, Fe=56, Cu=64
(Hc sinh khng c s dng bng tun hon v bng tnh tan. Gim th khng gii thch g thm)
______________________________Ht_______________________________
TI LIU BD HSG HA
Trang 72
L Vit Hng
S GIO DC V O TO
CAO BNG
Cu
Cu 1 (4.0 1
im)
Cu 2
(4.0 im)
HNG DN CHM THI HC SINH GII

CP TNH LP 9 THCS NM HC 2010-2011
Mn: Ha hc
(Hng dn chm gm 04 trang)
Ni dung
Cho hn hp vo trong dung dch NaOH d. Ch c Al2O3 phn ng:
Lc ly cht rn khng tan l CuO, Fe2O3 v dung dch nc lc A.
Nung nng cht rn ri kh bng cch cho lung kh H2 ( hoc CO) d
i qua ta thu c hn hp cht rn gm 2 kim loi Cu, Fe.
t0
CuO + H2
Cu + H2O.
0
t
Fe2O3 + 3H2
2 Fe + 3 H2O.
- Ho tan hn hp kim loai bng dung dch axit HCl ( d) .
Xy ra phn ng: Fe + 2 HCl FeCl2 + H2.
Cu khng phn ng. Lc ly Cu v dung dch nc lc B.
Nung Cu trong khng kh nhit cao ta c CuO :
t0
2Cu + O2
2CuO.
- Ly dung dch B thu c cho tc dung vi dd NaOH d thu c
kt ta Fe(OH)2
FeCl2 + 2 NaOH Fe(OH)2 + 2 NaCl.
- Lc ly kt ta Fe(OH)2 v nung trong khng kh nhit cao ta
thu c Fe2O3.
t0
4Fe(OH)2 + O2 + 2H2O
4Fe(OH)3
t0
2Fe(OH)3
Fe2O3 + 3H2O
- Thi t t n d kh CO2 ( hoc nh t t dd HCl vo va ) vo
dung dch A thu c kt Al(OH)3 . Lc kt ta v nung nhit cao
thu c Al2O3.
NaAlO2 + CO2 + 2 H2O Al(OH)3 + NaHCO3
t0
2Al(OH)3
Al2O3 + 3H2O.
a) Kt ta xut hin, kt ta tng dn sau tan dn.
b) Kt ta xut hin, kt ta tng dn, sau tan dn.
6KOH + Al2(SO4)3 2Al(OH)3 + 3K2SO4
KOH + Al(OH)3 KAlO2 + 2H2O
c) Kt ta xut hin ri tan ngay, li xut hin ri li tan ngay, lu sau
kt ta khng tan na v tng dn.
Al2(SO4)3 + 6KOH 2Al(OH)3 + 3K2SO4
Nhn bit ng mi cht t 1,0 im
Ly mi dung dch ra1 t lm thuc th, cho cc cht tc dng
ln lt vi nhau tng i mt. Kt qu:
BaCl2
BaCl2
Na2CO3
H2SO4
NaOH
(NH4)2SO4
TI LIU BD HSG HA
_
BaCO3
BaSO4
_
BaSO4
Na2CO3
BaCO3
H2SO4
BaSO4
_
CO2
_
_
Trang 73
NaOH
(NH4)2SO4
BaSO4
CO2
_
_
_
_
_
NH3
_
NH3
_
L Vit Hng
Thang im
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,75
0,75
0,5
1,0
Cu 3
(4.0 im)
Cu 4
(2.0 im)
Dung dch to 3 kt ta trng vi 3 dung dch khc l BaCl2

BaCl2 + H2SO4 BaSO4 + 2HCl
BaCl2 + (NH4)2SO4 BaSO4 + 2NH4Cl
Dung dch to 1 cht kh c mi khai vi 1 dung dch khc l NaOH
2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O
Dung dch to 1 cht kh c mi khai v 1 kt ta trng vi 2 dung dch
khc l (NH4)2SO4
Ly BaCl2 cho phn ng vi 2 mu th cn li l Na2CO3 v H2SO4.
Sau ly nc lc ca 2 mu th trn cho phn ng vi cc cht cn
li. Nu mu no c kh thot ra th mu l Na2CO3, mu cn li l
H2SO4
Na2CO3 + 2HCl 2NaCl + CO2 + H2O
( Hc sinh c th trnh by cch nhn bit ri vit 5 PT ring)
+ t hn hp C v S trong Oxi d :
2C + O2 = 2 CO
C + O2 = CO2
S + O2 = SO2
Hn hp kh A: CO2 , SO2, CO v O2 d
+ Cho hn hp kh A qua dung dch NaOH:
CO2 + 2NaOH = Na2CO3 + H2O
SO2 + 2NaOH = Na2SO3 + H2O
Dung dch B cha Na2CO3, Na2SO3
cn kh C cha: O2, CO
C qua CuO, MgO nng. Ch c CuO phn ng vi CO
CuO + CO = Cu + CO2
Cht rn D ( MgO, Cu ) v kh E c: CO2, O2, CO d
E li qua Ca(OH)2 :
CO2 + Ca(OH)2 = CaCO3 + H2O
2CO2 + Ca(OH)2 = Ca(HCO3)2
Kt ta F l CaCO3
Dung dch G: Ca(HCO3)2
Ca(HCO3)2+ 2KOH = CaCO3 + K2CO3 + H2O
Ca(HCO3)2 = CaCO3 + CO2 + H2O
A qua xc tc V2O5 v nhit
2SO3 + O2 = 2SO3 ( kh M)
M qua dung dch BaCl2
SO3 + H2O + BaCl2 = BaSO4 + 2HCl
Kt ta N : BaSO4
Gi kim loi ha tr II l M c khi lng mol l M, x l s mol ca
MCO3
MCO3 + H2SO4 MSO4 + CO2 + H2O
x (mol)
x (mol)
x (mol)
x (mol)
(
)
M
+
60
m MCO3 =
x = Mx + 60x (g)
m ddH 2 SO4 =
1,0
1,0
1,0
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,25
0,5
0,25
0,25
0,25
0,25
0,5
98 x 100%
= 490x (g)
20%
m MSO = ( M + 96 ) x = Mx + 96x (g)

4
0,75
m CO2 = 44x (g)

Theo bi ta c: 28,196 =
M = 65 (Zn)
( Mx + 96 x )100
Mx + 60 x + 490 x 44 x
0,75
Vy: CTHH cn tm l ZnCO3

TI LIU BD HSG HA
Trang 74
L Vit Hng
Cu 5
(2.0 im)
2Fe + 3Cl2 2FeCl3

x
x
t
Cu + Cl2 CuCl2
y
y
Fe + 2HCl
FeCl2 + H2
x
x
162,5x + 135 y = 59,5
127x = 25,4
Gii h PT c
t0
0,5
0,5
162,5x + 135 y = 59,5
127 x = 25,4
x = 0,2 mol; y=0,2 mol

m FeCl3 = 0,2 162,5 = 32,5 gam; mCuCl2 = 0,2 135 = 27 gam
b.
d=
m
m n.M
V = =
;
V
d
d
n HCl = 2n FeCl2 = 2 0,2 mol

Vddaxit10% =
Cu 6
a.
1,0
0,2.2.36,5.100
=146ml
1,0 10
Cho hn hp A qua nc Br2 d th C2H2 b gi li cn kh i CH4 .

C2H2 + 2Br2 C2H2Br2
0,5
Cho hn hp A qua dung dch AgNO3 (NH3) sau lc ly kt ta ri

em ha tan bng HNO3 ta thu c C2H2
C2H2 + Ag2O ddAgNO
/ NH
C2Ag2
C2Ag2 + 2HNO3
2AgNO3 + C2H2
0,5
(1.0 im)
b.
Cu 7
(3.0 im)
13,2
Ta c : nCO 2 = 44 = 0,3 (mol) mC = 0,3 12 = 3,6(g)

nH 2
4,5
= 18 = 0,25(mol ) mH = 0,25 2 =0,5(g)

1,0
Khi lng oxi c trong hp cht :

mO = 7,3 3,6 0,5 = 3,2(g)
Gi cng thc ca hp cht l CxHyOz
Ta c : x : y : z =
3,6 0,5 3,2

:
:
= 0,3 : 0,5 : 0,2 = 3: 5 : 2
12 1 16
cng thc n gin ca hp cht l : C3H5O2

Cng thc nguyn : (C3H5O2)n
1,0
6,4
Theo bi : nO 2 = 32 = 0,2(mol )
V : V(29,2g hp cht) = V(6,4g O 2 ) n(29,2g hp cht) = n(6,4g O 2
29,2
M
(C
3 H 5 O2
)n
= 0,2 M(C 3 H 5 O 2
0,5
= 146 73n = 146
n=2
TI LIU BD HSG HA
Trang 75
L Vit Hng
Vy cng thc phn t ca hp cht l : C6H10O4
0,5
Lu :
Gii bi ton bng cc phng php khc nhau nhng nu tnh ng, lp lun v n kt qu
ng vn tnh theo biu im.
Trong khi tinh ton nu lm ln mt cu hi no dn n kt qu sai th tr na s im
dnh cho cu hi .
Nu tip tc dng kt qu sai gii tip cc vn tip theo th khng tnh im cc phn sau
.
Cch cho im ton bi :tng im c bi 20 im
Sau khi hai gim kho chm xong thng nht im th im ton bi khng lm trn.
im ton bi l s nguyn, hoc s thp phn, vit bng s v bng ch, ghi vo ch quy nh.
TI LIU BD HSG HA
Trang 76
L Vit Hng
S GIO DC & O TO
LM NG
CHNH THC
( thi gm c 02 trang)
24
NM HC 2010-2011
Mn : Ho hc THCS
Ngy thi : 18/02/2011
Cu 1 : (1,5 im)
Cho cc cht Al2O3, Al(NO3)3, NaAlO2, Al2(SO4)3, Al(OH)3, AlCl3, Al. Hy la chn cht thch
hp sp xp thnh mt dy chuyn ho v vit phng trnh phn ng minh ha (ghi r iu kin nu c).
Cu 2: (1,5 im)
i t cc cht ban u l vi, than v c dng thm cc cht v c cn thit, hy vit
phng trnh phn ng iu ch ra polivinyl clorua, icloetan.
Cu 3: (2,5 im)
a/ C mt ming kim loi natri ngoi khng kh m mt thi gian bin thnh sn phm A. Cho
A tan vo nc c dung dch B. Cho dung dch B vo dung dch NaHSO 4.Vit cc phng trnh ha
hc ca qu trnh th nghim trn.
b/ Cho 100ml nc vo cc thu tinh. Sau cho thm 40 gam mui n vo khuy u cho n
khi cn mt t mui khng tan, lng xung y. Sau un nh, thy ton b mui trong cc u tan.
ngui dung dch n nhit phng th thy mui kt tinh tr li. Gii thch hin tng nu trn.
Cu 4: (2,5 im)
a/ Ch dng nc v kh cacbonic, bng phng php ha hc em hy phn bit 5 cht bt mu
trng sau: NaCl, Na2CO3 , Na2SO4 , BaCO3 , BaSO4 .
b/ Nhng kh thi (CO2, SO2) trong qu trnh sn xut gang thp c nh hng nh th no n
mi trng xung quanh? Dn ra mt s phn ng gii thch. Em hy ngh bin php chng
nhim mi trng khu dn c gn c s sn xut gang thp.
Cu 5: (1,5 im)
Em hy dng cc phng trnh ha hc gii thch v sao khng c bn chung cc loi phn
m: NH4NO3, (NH4)2SO4 v CO(NH2)2 vi vi hoc tro bp (cha K 2CO3). Bit rng trong nc,
CO(NH2)2 chuyn ha thnh (NH4)2CO3.
Cu 6: (2,5 im)
Hn hp A gm CaCO3, Cu, Fe3O4. Nung nng A (trong iu kin khng c khng kh) mt thi
gian c cht rn B v kh C. Cho kh C hp th vo dung dch NaOH c dung dch D. Dung dch D
tc dng c vi BaCl2 v dung dch KOH. Ho tan B vo nc d c dung dch E v cht rn F. Cho
F vo dung dch HCl d c kh C, dung dch G v cht rn H. Nu ho tan F vo dung dch H 2SO4 c,
d thu c kh I v dung dch K. Xc nh B, C, D, E, F, G, H, I, K v vit cc phng trnh phn ng
xy ra.
Cu 7 : (2 im)
th biu din tan S trong nc ca cht rn X nh sau:
a/ Hy cho bit dung dch bo ha trong
khong nhit no?
b/ Nu 130 gam dung dch bo ha ang
700C h nhit xung cn 300C. Hi c
bao nhiu gam X tch ra khi dung dch?
Cu 8 : (2,5 im)
TI LIU BD HSG HA
t0(0C)
Trang 77
L Vit Hng
Hn hp kh A gm 2 hirocacbon. t chy hon ton 1 lt A trong kh oxi thu c 1,6 lit kh
CO2 v 1,4 lt hi nc.
Cu 9 : (3,5im)
X l hn hp hai mui cacbonat trung ha ca kim loi ho tr (I) v kim loi ha tr (II). Ha tan
hon ton 18 gam hn hp X bng dung dch HCl (va ) th thu c 3,36 lit kh (ktc) v dung dch
Y.
a/ Nu c cn dung dch Y th thu c bao nhiu gam hn hp mui khan?
b/ Nu t l s mol ca mui cacbonat kim loi ho tr (I) vi mui cacbonat kim loi ha tr (II)
trong hn hp X l 2:1. Nguyn t khi ca kim loi ha tr (I) ln hn nguyn t khi ca kim loi ha
tr (II) l 15 .v.C. Hy tm cng thc phn t ca hai mui.
(Cho bit: C =12, O = 16, Ca = 40, H=1, Mg = 24, Cu = 64, Fe = 56, Na =23, K =39, Li = 4)
--------------------------Ht-------------------------H v tn th sinh:S bo danh.
Gim th 1:K tn.
Gim th 2:K tn.
S GIO DC & O TO
LM NG
Cu
Cu 1
(1,5 im)
Cu 2
(1,5 im)

NM HC 2010-2011
HNG DN CHM CHNH THC

Mn : Ho hc THCS
Ngy thi : 18/02/2011
Hng dn chm
NaAlO2 Al(OH)3 Al2(SO4)3 AlCl3
Al Al2O3
+ 3O2 t0 2 Al2O3
Al2O3 + 2NaOH NaAlO2 + H2O
NaAlO2 + 2H2O + CO2 Al(OH)3 + NaHCO3
2Al(OH)3 + 3 H2SO4 Al2(SO4)3 + 6H2O
Al2(SO4)3 + 3 Ba Cl2 2 AlCl3 + 3BaSO4
AlCl3 + 3 Ag NO3 Al(NO3)3 + 3AgCl
( Th sinh c phng n khc hp l vn t im ti a)
Al(NO3) 4Al
CaCO3
CaO + CO2
CaO + 3C t0 CaC2 + CO
CaC2 + 2H2O C2H2 + Ca (OH)2
H C C H + HCl CH2 = CHCl
0, p , xt
(- CH2 - CHCl-)n
nCH2 = CHCl t
t 0 , Pd
H C C H + H2 CH2 = C H2
CH2 = C H2 + Cl2 CH2Cl -CH2Cl
t 0
a/ Khi ming Na ngoi khng kh m c th xy ra cc phng

Cu 3
(2,5 im)
TI LIU BD HSG HA
Trang 78
L Vit Hng
im
1,5
0,25
0,25
0,25
0,25
0,25
0,25
1,5
0,125
0,125
0,25
0,25
0,25
0,25
0,25
2.0
0,125
0,125
0,25
0,25
0,25
trnh ho hc sau:
4Na + O2 2Na2O
Na2O+H2O 2NaOH
Na2O + CO2 Na2CO3

Hn hp A gm Na, NaOH, Na2CO3, Na2O
Khi cho hn hp A vo nc, tt c tan trong nc v c cc phng trnh
ho hc sau:
Na2O + H2O 2NaOH
Vy dung dch B cha NaOH v Na2CO3
Cho dung dch B dung dch NaHSO4 :
NaHSO4 + NaOH Na2SO4 + H2O
2NaHSO4 + Na2CO3 2Na2SO4 + CO2 + H2O
NaHSO4 + Na2CO3 Na2SO4 + NaHCO3 (nu NaHSO4 thiu)
b/ Ho tan d NaCl to ra dung dch bo ho, phn khng tan c s
lng xung.
Khi tng nhit tan ca mui tng nn NaCl tan thm.
0,25
0,25
0,25
0,25
0,5
0,25
0,25
Khi gim nhit tan ca mui gim nn phn khng tan

c kt tinh tr li.
Cu 4
(2,5 im)
a/ Ho tan 5 cht bt trng vo nc c nhm 1(gm cc dung dch NaCl,
Na2CO3 Na2SO4) v nhm 2 (BaCO3, BaSO4 khng tan).
Sc kh CO2 d v nc vo nhm 2 nhn bit c BaCO 3 tan (to dd Ba(HCO3)2 ,
cht cn li khng tan l BaSO4.
CO2 + H2O + BaCO3 Ba(HCO3)2
Cho dd Ba(HCO3)2 vo nhm 1 th Na2CO3 v Na2SO4 to kt ta trng, nhn bit
c NaCl
Ba(HCO3)2 + Na2CO3 BaCO3 + 2NaHCO3
Sc kh CO2 d v nc vo hai kt ta, kt ta tan ta nhn bit c Na 2CO3, kt ta
khng tan l Na2SO4
b/
+ Kh CO2, SO2 gy nhim khng kh, nh hng n sc kho con ngi, c hi
cho ng vt, thc vt.
+ nhng kh thi ny khi gp ma s nhanh chng to thnh H 2CO3, H2SO3 lm cho
nng axit trong nc ma cao hn mc bnh thng, rt c hi cho mi trng:
SO2 + H2O H2SO3
CO2 + H2O H2CO3
+ Bin php chng nhim mi trng: xy dng h thng x l kh thi c hi trc
khi thi ra ngoi khng kh ( cho kh thi i qua dung dch kim nh NaOH, Ca(OH) 2,
hai kh SO2, CO2 b gi li). Trng nhiu cy xanh hp th kh CO2.
Trang 79
0,125
0,25
0,125
0,25
0,25
Ba(HCO3)2 + Na2SO4 BaSO4 + 2NaHCO3
TI LIU BD HSG HA
2,5
1,5
0,125
L Vit Hng
0,125
0,25
1,0
0,25
0,25
0,125
0,125
0,25
Cu 5
(1,5 im)
Cu 6
(2,5 im)
1,5
* Nu bn chung vi vi th :
2NH4NO3 + Ca(OH)2 Ca(NO3)2 + 2NH3 + 2H2O
(NH4)2SO4 + Ca(OH)2 CaSO4
+ 2NH3 + 2H2O
(NH4)2CO3 + Ca(OH)2 CaCO3 + 2NH3 + 2H2O
* Nu bn chung vi tro bp ( cha K2CO3)
2NH4NO3 + K2CO3 2KNO3 + H2O + CO2 + 2NH3
(NH4)2SO4 + K2CO3 K2SO4 + H2O + CO2 + 2NH3
(NH4)2CO3 + K2CO3 2KHCO3 + 2NH3
Nh vy bn chung phn m vi vi hoc tro bp th lun b tht thot m do gii
phng NH3.
Cu 8
(2,5 im)
0,25
0,25
0,25
2,5
0,125
0,25
0,125
0,25
CaCO3 t0 CaO + CO2

(B: CaO,Cu, Fe3O4 CaCO3 d; C:CO2)
CO2 + NaOH NaHCO3
CO2 + 2NaOH Na2CO3 + H2O
2NaHCO3 + 2KOH Na2CO3 + K2CO3 + 2H2O
Na2CO3 + BaCl2 BaCO3 + 2 NaCl (D: Na2CO3 v NaHCO3 )
CaO + H2O Ca(OH)2
(E: Ca(OH)2 ; F:Cu, Fe3O4 CaCO3 d)
CaCO3 + 2HCl CaCl2 + 2H2O + CO2
Fe3O4 + 8 HCl FeCl2 + 2FeCl3 + 4 H2O (C: CO2 ; G:CaCl2, FeCl2, 2FeCl3, HCl d;
H: Cu )
CaCO3 + H2SO4 c t0 CaSO4 + H2O + CO2
Cu+ 2H2SO4 c t0 CuSO4 +2H2O + SO2
2Fe3O4 + 10H2SO4 c t0 3Fe2(SO4)3 +10 H2O + SO2
Cu 7
(2,0 im)
0,25
0,25
0,25
a. Dung dch bo ha trong khong nhit t 0 C n 10 C; 30 C n 40 C; 60 C n

700C.
b.Khi lng X kt tinh:
+ S gam cht tan v s gam nc c trong 130 g dd 700C:
C 100 g nc ha tan 25 g X to thnh 125 g dd
xg nc ha tan y g X to thnh 130 g dd bo ho
=> x = 104 g v y = 26 g.
+ Tnh s gam cht tan X c trong 104 g nc 3O0C :
mct X = 15 . 104 : 100 = 15,6 (g)
+ S gam X tch ra khi h nhit t 700C xung 3O0C = 26 15,6 = 10,4 (g)
0,25
0,25
0,25
0,25
0,25
0,25
0,25
2,0
0,5
0,75
0,5
0,25
2,5
t cng thc chung ca cc cht trong hn hp l CxHy.

PTHH : CxHy.+ ( x +
0,25
y
y
) O2 t0 xCO2 +
H2O (1)
4
2
T (1) : th tch CO2 = x . th tch CxHy 1,6 = x.

Do A phi cha 1 cht c s nguyn t C < 1,6 => A cha CH4.
Th tch hi H2O =
y
y
. th tch CxHy 1,4 =
2
2
=> y = 2,8
Trong A c 1 hidrocacbon c s nguyn t H < 2,8, cht cn li cha 2 nguyn t

H. t cng thc l CnH2.
Gi th tch ca ring CH4 trong 1 lit A l a lit.
Th tch ring ca CxH2 = 1 a (lit).
TI LIU BD HSG HA
Trang 80
L Vit Hng
0,25
0,25
0,25
0,25
[ 4.a + 2(1 a )]
y=
= 2,8 a = 0,4.
1
[1.0,4 + n(1 0,4)]
n=
= 1,6 n = 2.
1
Cu 9
(3,5 im)
0,5
0,5
Cng thc ca CnH2 l C2H2 .

Vy cng thc phn t ca cc cht trong hn hp A l CH4 v C2H2 .
0,25
a.
Gi X l kim loi ha tr I Cng thc ca mui l X2CO3 , c s mol l x.
Gi Y l kim loi ha tr II Cng thc ca mui l YCO3 , c s mol l y.
PTHH :
X2CO3 + 2HCl 2XCl + CO2 + H2O (1)
x
2x
2x
x
x
YCO3 + 2HCl YCl2 +CO2 + H2O (2)
y
2y
y
y
y
Ta c: nCO2 = x + y = 0,15 (mol) => mCO2 = 6,6 (g)
nH2O = x + y = 0,15 (mol) => m H2O = 2,7 (g)
nHCl = 2x + 2y = 2.0,15 = 0,3 (mol) => m HCl = 10,95 (g)
Theo nh lut bo ton khi lng :
Khi lng hai mui khan thu c :
mXCl v YCl2 = mhhA + mHCl - mCO2- mH2O
= 18 + 10,95 6,6 2,7
= 19,65 (g)
b.
V t l s mol ca mui cacbon nat kim loi ho tr (I) vi mui cacbon nat kim loi
ho tr (II) trong hn hp X l 2:1 nn x = 2y.
x + y = 0,15 => 2y + y = 0,15 => y = 0,05 (mol) ; x = 0,1 (mol).
V nguyn t khi ca kim loi ho tr (I) ln hi ca kim loi ho tr (II) l 15 vc nn
X = Y + 15 .
mX2CO3 = 0,1. ( 2X + 60) = 0,1.(2Y + 90 ) = 0,2Y + 9
mYCO3 = 0,05. ( Y + 60) = 0,05Y + 3
mA= mX2CO3 + mYCO3 = (0,2Y + 9 ) + ( 0,05Y + 3 )
= 0,25Y = 6 => Y = 24 ( kim loi Mg)
X = 24 + 15 = 39 ( kim loi K)
Cng thc ca hai mui l K2CO3v MgCO3.
3,5
0,25
0,25
0,75
0,75
0,5
0,5
0,5
Lu :
- Phng trnh phn ng: nu sai cn bng hay thiu iu kin th tr s im dnh cho phng
trnh phn ng
- Bi ton gii theo cch khc ng kt qu, lp lun hp l vn t im ti a. nu tnh ton
nhm ln dn n kt qu sai tr s im dnh cho ni dung . Nu dng kt qu sai gii tip th
khng chm im cc phn tip theo.
TI LIU BD HSG HA
Trang 81
L Vit Hng
25
Nm hc 2010-2011
S GIO DC O TO
SC TRNG
chnh thc
Mn: Ha hc - Lp 9
(Thi gian lm bi 150 pht, khng k pht )
thi ny c 01 trang
Cu I (5 im):
1. Ch dng kim loi Bari hy nhn bit cc l ng dung dch mt nhn sau:
FeCl3 , Na2SO4 , CuCl2 , NaNO3.
(2,5 im)
2. m gam bt Fe ngoi khng kh mt thi gian thu c 6 gam hn hp gm st v cc oxit ca st.
Ha tan hon ton hn hp bng dung dch HNO 3 long thu c 1,12 lt kh NO duy nht (ktc). Tm
m?
(2,5 im)
Cu II (5 im):
1. Nu hin tng v vit phng trnh phn ng xy ra khi :
(2,0 im)
a. Sc kh CO2 t t vo dung dch nc vi trong.
b. Cho t t dung dch KOH vo dung dch Al2(SO4)3.
2. Hn hp A gm 2 kim loi Al v Mg. Cho 1,29 gam A vo 200 ml dung dch CuSO 4. Sau khi phn
ng xy ra hon ton thu c 3,47 gam cht rn B gm hai kim loi v dung dch C. Lc ly dung dch
C ri thm dung dch BaCl2 d vo thu c 11,65 gam kt ta.
(3,0 im)
a. Vit cc phng trnh phn ng c th xy ra.
b. Tnh nng mol/lt ca dung dch CuSO4.
c. Tnh khi lng tng kim loi trong hn hp A.
Cu III(5 im):
1. Trn hai a cn t hai cc dung dch HCl v H 2SO4 long c khi lng bng nhau, cn thng
bng.
-Cho vo cc ng dung dch HCl 25gam CaCO3.
-Cho vo cc ng dung dch H2SO4 (a) gam Al.
Sau khi phn ng kt thc, cn vn gi v tr thng bng. Hy vit phng trnh phn ng v tnh (a),
bit cc phn ng xy ra hon ton.
(2,5 im)
2. Khi ho tan mt lng ca mt oxit kim loi ho tr II vo mt lng va dung dch axit H 2SO4
4,9%, ngi ta thu c mt dung dch mui c nng 5,78%. Xc nh cng thc ca oxit trn.
(2,5 im)
Cu IV (5 im):
1. Hon thnh cc phng trnh phn ng (ghi iu kin phn ng nu c) ca chui chuyn ho sau:
(2,0 im)
C6H5Br
CaC2
C2H2
C6H6
C6H12
2. Hn hp X (ktc) gm mt ankan v mt anken. Cho 3,36 lt hn hp X qua bnh nc Brom d

thy c 8 gam Brm tham gia phn ng. Bit 3,36 lt hn hp X nng 6,5 gam.
(3,0 im)
a. Tm cng thc phn t ca ankan v anken, bit s nguyn t cacbon trong mi phn t khng qu
4.
b. t chy hon ton 3,36 lt hn hp X v cho tt c sn phm chy hp th vo dung dch NaOH
(d), sau thm BaCl2 d th thu c bao nhiu gam cht kt ta? Vit phn ng.
(Cho Fe=56, Al=27, Mg=24, Cu=64, Ba=137, Ca=40, Zn=65, O=16, S=32, H=1, C=12)
---Ht--Ghi ch: Hc sinh c s dng Bng h thng tun hon ca NXB Gio dc.
TI LIU BD HSG HA
Trang 82
L Vit Hng
Nm hc 2010-2011
S GIO DC O TO
SC TRNG
chnh thc
CU
I(5)
1(2,5)
2. (2,5)
Mn: Ha hc - Lp 9
(Thi gian lm bi 150 pht, khng k pht )
________________
HNG DN CHM MN HA HC
NI DUNG
Cho kim loi Ba vo cc mu th trn, u tin c phn ng:
Ba + 2 H2O
Ba(OH)2+ H2(k)
Mu no c kt ta nu l FeCl3
3Ba(OH)2+ 2FeCl3 2Fe(OH)3(r)nu + 3BaCl2
Mu c kt ta trng l Na2SO4
Ba(OH)2) + Na2SO4
BaSO4(r) + 2NaOH
Mu no cho kt ta xanh l CuCl2
Ba(OH)2 + CuCl2
Cu(OH)2( r) + BaCl2
Mu khng c hin tng g l NaNO3
Ta c : nFe =
1,12
m
(mol) ; nNO = 22,4 = 0,05(mol)
56
mO 2 = 6 m (g)
nO 2 =
Ta c : Fe
3m
56
3e
6 m
32
0,5
0,5
0,5
0,5
0,25
0,25
0,25
N+2
3 0,05
O2
0,5
0,25
Fe+3 + 3e
m
56
N+5
6 m
32 (mol)
IM
0,05
4e
2O
0,25
-2
4 (6 m)
32
Theo nh lut bo ton electron ta c :

4 (6 m )
32
3m
= 3 0,05 +
56
1,25
m = 5,04 (g)
II(5)
1.(2)
2.(3)
a) Kt ta xut hin, sau tan dn.

b) Kt ta xut hin, sau tan dn.
6KOH + Al2(SO4)3 2Al(OH)3 + 3K2SO4
0,5
0,25
0,25
0,5
0,25
0,25
a. Cc phng trnh phn ng:
TI LIU BD HSG HA
Trang 83
L Vit Hng
Mg + CuSO4 MgSO4 + Cu
0,25
(1)
2Al + 3CuSO4 Al2(SO4)3 + 3Cu
(2)
MgSO4 + BaCl2 MgCl2 + BaSO4
(3)
Al2(SO4)3 + 3BaCl2 2AlCl3 + 3BaSO4
(4)
0,25
0,25
0,25
b. Tnh nng CuSO4 : V BaCl2 d nn ion SO42- s kt ta ht vi

ion Ba2+.
0,5
11,65
S mol CuSO4 = S mol SO4 = s mol BaSO4 =
= 0,05
233
0,05
0,5
Nng dung dch CuSO4 =
= 0,25 M
0,2
2-
c. Tnh khi lng tng kim loi :

Gi s mol Mg, Al tham gia phn ng ln lt l x, y, theo phng
trnh phn ng (1), (2) s mol Cu to thnh : x + 1,5y.
Ta c : (x + 1,5y) 64 (24x + 27y) = 3,47 1,29 = 2,18
(*)
Theo phng trnh phn ng (3) , (4): (x + 1,5y) 233 =11,65 0,5
(**)
Kt hp (*) v (**) ta c h :
40x + 69y = 2,18
233x + 349,5y = 11,65
0,25
0,25
Gii h ta c: x = y = 0,02 (mol)

Khi lng Mg = 0,02. 24 = 0,48 g.
Khi lng Al = 1,29 0,48 = 0,81 g.
III(5)
1(2,5)
- Cc th nht: S mol CaCO3 = 25 :100 = 0,25 mol.

CaCO3 + 2HCl CaCl2 + CO2 + H2O
0.25
0,25
khi lng tng thm :
25 0,25 x 44 = 14gam.
0,25
0,5
- cn thng bng , cc th hai , sau khi H2 bay i , th khi

lng cng phi tng 14gam
2 Al + 3 H2SO4 Al2(SO4)3 + 3H2
a 3
.
a/27
27 2
a .3 .2
=>
a = 14
27 . 2
2(2,5)
Gii c
a = 15,75gam.
Ta c RO
+ H2SO4 RSO4 + H2O
(R + 16)
98g
(R + 96)g
Gi s ho tan 1 mol RO
Khi lng dd thu c = (R + 16) + (98 : 4,9).100 = R + 2016
R + 96
C%( RSO4) =
.100% = 5,87%
R + 2016
Gii phng trnh ta c: R = 24, kim loi ho tr II l Mg.
TI LIU BD HSG HA
Trang 84
0,25
0, 5
1
0,25
1.0
1,0
0,25
L Vit Hng
IV(5)
1.(2)
2.(3)
CaC2 + 2H2O C2H2 + Ca(OH)2

to
3C2H2
C6H6
xt ,t o
C6H6 + 3 H2
C6H12
0
Fe ,t
C6H6 + Br2
C6H5Br + HBr
0,5
0,5
0,5
0,5
t CTPT ca X, Y ln lt l CnH2n + 2 v CmH2m

iu kin: 1 n 4 v 2 m 4 ( m, n nguyn dng)
Cho hn hp kh qua dd nc brom
X:
CnH2n + 2 + Br2
Y:
CmH2m
Br2
Khng phn ng
0,25
CmH2mBr2
Gi s mol X, Y trong hn hp ln lt l a v b ta c:
0,25
3,36
a + b =
= 0,15 (mol)
22,4
8
= 0,05 (mol)
160
Theo khi lng hn hp:
(14n + 2)0,1 + 14m . 0,05 = 6,5
Rt gn: 2n + m = 9
nY = nBrom = b =
0,25
a = 0,1 mol
0,25
V cn tho mn iu kin: 1 n 4 v 2 m 4 ( m, n nguyn

dng)
0,5
Ch hp l khi n = m = 3
0,25
Vy cng thc phn thc phn t X l C3H8; Y l C3H6.
2/ Ta c cc PTHH xy ra:
0,25
C3H8 + 5O2
3CO2 + 4H2O
0,1
0,3 mol
0,25
2C3H6 + 9O2 6CO2 + 6H2O
0,05
0,15 mol
0,25
0,45
0,9
0,45 mol
0,5
0,45
0,45 0,45 mol
mrn = 0,45 . 197 = 88,65g
* Ghi ch :
- Khng cn bng phn ng hoc thiu iu kin tr 1/2 s im.

- Hc sinh c th gii cch khc nhng ng vn cho im ti a.
TI LIU BD HSG HA
Trang 85
L Vit Hng
UBND TNH THI NGUYN

S GIO DC V OTO
26
THI CHN HSG LP 9
NM HC 2010 2011
MN HA HC
(Thi gian lm bi 150 pht khng k thi gian giao )
CU 1: (4,0 im)
1. Cho A l oxt, B l mui, C v D l cc kim loi. Hy chn cht thch hp vi A, B, C, D v hon
thnh phng trnh ho hc (PTHH) ca cc phn ng sau:
a) A + HCl 2 Mui + H2O
b) B + NaOH 2 Mui + H2O
c) C + Mui 1 Mui
d) D + Mui 2 Mui
2. T vi, mui n, nc v cc iu kin cn thit, hy vit PTHH iu ch:
a) Natri cacbonat.
b) Natri hirocacbonat.
c) Canxi clorua.
d. Nc gia-ven.
CU 2: (5,0 im)
1. Cho 7 l cha cc dung dch (ring bit): NH 4Cl; Zn(NO3)2; (NH4)2SO4; phenolphtalein; K2SO4;
HCl, NaCl khng nhn. Ch dng thm dung dch Ba(OH)2 lm thuc th c th nhn bit c bao
nhiu cht trong s cc cht cho? Vit PTHH ca cc phn ng minh ha.
2. Khi lng ring ca mt dung dch CuSO 4 l 1,206g/ml. em c cn 414,594ml dung dch ny
thu c 140,625g tinh th CuSO4 .5H2O. Tnh nng C% v CM ca dung dch ni trn.
CU 3: (3,0 im)
T khi hi ca hn hp X gm CO 2, SO2 so vi kh nit bng 2. Cho 0,112 lt X ( ktc) li t t qua
500ml dung dch Ba(OH)2. Sau th nghim phi dng 50ml dung dch axit HCl 0,1M trung ha lng
Ba(OH)2 d.
a) Tnh % th tch mi kh trong X.
b) Tnh nng CM ca dung dch Ba(OH)2 trc th nghim.
c) Hy tm cch nhn bit mi kh c trong hn hp X, vit PTHH ca cc phn ng.
CU 4: (4,0 im)
1. Bit axit lactic c cng thc cu to: CH3-CH(OH)-COOH. Hy vit phng trnh ho hc ca cc
phn ng xy ra khi cho axit lactic ln lt tc dng vi cc cht:
a) Na d.
b) C2H5OH (H2SO4c, un nng nh).
c) Dung dch Ba(OH)2.
d) Dung dch KHCO3.
2. Cho 32,8 gam hn hp A gm 2 cht hu c X, Y tc dng va vi 0,2 lt dung dch NaOH 1M
thu c hn hp 2 ru R1OH, R2OH v 18,8 gam mt mui RCOONa (trong R, R1, R2 ch cha
cacbon, hiro v R2 = R1 + 14). Cho ton b 2 ru tc dng vi Na d thu c 6,72 lt H 2 ( ktc). Xc
nh cng thc cu to ca 2 cht X, Y.
CU 5: (4,0 im)
1. Hn hp X (gm CxHy (A) v H2). Nung nng X vi cht xc tc Ni thu c kh Y duy nht. T
khi hi ca Y so vi H2 gp 3 ln t khi hi ca X so vi H2.
t chy han ton mt lng khc kh Y thu c 22g CO2 v 13,5g H2O. Xc nh A.
2. Trn 10ml mt hydrocacbon kh vi mt lng oxi d ri cho n hn hp ny bng tia la in .
Lm cho hi nc ngng t th th tch ca hn hp thu c sau phn ng gim i 30ml. Phn kh cn
li cho i qua dung dch KOH d th th tch ca hn hp gim i 40ml na (cc th tch kh c quy v
cng iu kin v nhit v p sut).
a) Xc nh cng thc phn t ca hydrocacbon.
b) Vit Cng thc cu to ca cc ng phn mch h ng vi cng thc phn t va tm c.
(Bit: H=1, O=16, C=12,Cl=35,5, Mg=24, Fe=56, Zn=65, Ca=40)
H tn thi sinh . . . . . . . . . . . . . . . . . . . . . . . . . Phng thi . . . . . SBD . . . . . . . . .
Gim th 1 (k, ghi r h tn)
TI LIU BD HSG HA
Trang 86
L Vit Hng
UBND TNH THI NGUYN
S GIO DC V OTO
HD CHM THI CHN HSG LP 9

NM HC 2010 2011
MN HA HC
(Thi gian 150 pht khng k thi gian giao )
CU
NI DUNG
IM
1.
1
(4,0
)
2,0
a) Fe3O4 + 8HCl FeCl2 + 2FeCl3 + 4H2O

b) Ca(HCO3)2 + 2NaOH CaCO3 + Na2CO3 + 2H2O
c) Fe + 2FeCl3 3FeCl2
d) Cu + 2FeCl3 CuCl2 + 2FeCl2
2. Cc PTHH
CaCO3
to
2,0
CaO + CO2
pnc
2 NaCl + 2 H2O 2 NaOH + H2 + Cl2
CaO + H2O Ca(OH)2
as
H2 + Cl2
2HCl
2NaOH
NaOH
(c HCl)
+ CO2 Na2CO3 + 2 H2O

+ CO2 NaHCO3
(c Na2CO3)
(c NaHCO3)
Ca(OH)2 + 2HCl CaCl2 + 2H2O

(c CaCl2)
2NaOH + Cl2 NaCl + NaClO + H2O (nc gia-ven)
2
(5,0
)
1. Dng thuc th Ba(OH)2 cho n d:

*Trc ht nhn c 5 cht
- Ch c kh mi khai NH4Cl
2NH4Cl + Ba(OH)2 2NH3 + BaCl2 + 2H2O
- C kh mi khai + trng (NH4)2SO4
(NH4)2SO4 + Ba(OH)2 2NH3 + BaSO4 + 2H2O
- Ch c trng K2SO4
2K2SO4 + Ba(OH)2 2KOH + BaSO4
- Dung dch c mu hng phenolphtalein
- C , sau tan Zn(NO3)2
Zn(NO3)2 + Ba(OH)2 Ba(NO3)2 + Zn(OH)2
Zn(OH)2 + Ba(OH)2 BaZnO2 + 4H2O
*Sau , ly mt t dd (Ba(OH)2 + phenolphtalein) cho vo 2 ng nghim. Cho t t
tng git dung dch HCl v dd NaCl vo mi ng nghim:
- ng nghim mt mu hng sau mt thi gian dd HCl
- dung dch cn li l NaCl.
2.
Khi lng ca CuSO4 ( cht tan ) l :
160
mCuSO4 =
.140, 625 = 90 g
250
m 90
=
= 0,5625mol
S mol CuSO4 l : nCuSO4 =
M 160
Khi lng dung dch : mdd = d .V = 414,594.1, 206 = 500 g
TI LIU BD HSG HA
Trang 87
L Vit Hng
3,0
(ng
mi
cht
0,4)
(ng
ht
cho
im
ti a)
2,0
Nng phn trm v nng mol ca dung dch l :
mCuSO4
90.100
C %CuSO4 =
.100 =
= 18%
mdd
500
n
0,5625
CM = =
= 1,35675 M
V 0, 414594
Hoc : CM =
3
(3,0
)
4
(4,0
)
C %.d .10 18.10.1, 206

=
= 1,35675mol
M
160
- %V mi kh trong X:
t x , y l s mol CO2, SO2 trong X, ta c:
44 x + 64 y
x 2
=2
=
28( x + y )
y 3
Vy trong X c : %VCO2 = 40% ; %VSO2 = 60%
1,0
- CM ca dung dch Ba(OH)2 trc khi th nghim:

Trong 0,112 lt (X) c 0,002 mol CO2 v 0,003 mol SO2.
t a l CM ca Ba(OH)2, ta c:
S mol Ba(OH)2 ban u l: 0,5a (mol).
S mol HCl : 0,05 x 0,1 = 0,005 (mol)
PTP: Ba(OH)2 + 2HCl BaCl2 + 2H2O
0,0025
0,005
S mol Ba(OH)2 phn ng: (0,5a - 0,0025) mol.
V Ba(OH)2 d nn: Ba(OH)2 + CO2 BaCO3 + H2O
0.002
0,002
Ba(OH)2 + SO2 BaSO3 + H2O
0.003
0,003
Ta c: 0,5a - 0,0025 = 0,002 + 0,003 => a = 0,015(M)
- Nhn bit CO2 v SO2 trong X:
Bng cch cho li qua dung dch nc brm, dung dch b mt mu, v:
SO2 + Br2 + 2H2O H2SO4 + 2HBr
Kh cn li ra khi dung dch lm c nc vi trong:
1.
Vit phng trnh phn ng:
a) CH3-CH(OH)-COOH + 2Na CH3-CH(ONa)-COONa + H2
H2SO4
c
CH3CH(OH)COOC2H5 + H2O
b) CH3CH(OH)COOH + C2H5OH
o
tC
1,0
1,0
2,0
c) 2CH3-CH(OH)-COOH + Ba(OH)2 (CH3-CH(OH)-COO)2Ba + 2H2O

d) CH3-CH(OH)-COOH + KHCO3 CH3-CH(OH)-COOK + H2O + CO2
2.
Gi cng thc trung bnh ca 2 ancol: R OH
+
Na
1/2 H2
R OH
R ONa +
0,6 mol
0,3 mol
n(NaOH) = 0,21 = 0,2 mol < 0,6 mol = n(2 ru)
suy ra trong hn hp ban u gm 1 este v 1 ru
RCOOR + NaOH RCOONa + ROH
ROH
ROH
p dng bo ton khi lng suy ra:
m(2ancol) = m(2cht ban u) + m(NaOH) m(mui) = 32,8 + 0,240- 18,8 = 22 gam
M ( R OH)= 22/0,6 = 36,67 32(CH3OH) < M ( R OH)= 36,67
TI LIU BD HSG HA
Trang 88
L Vit Hng
2,0
ru R1OH l CH3OH; suy ra R2OH l C2H5OH
CH3OH : x mol ta c h
x +y
= 0,6 suy ra
C2H5OH: y mol
32x + 46y = 22
x = 0,4
y = 0,2
n(NaOH) = 0,21 = 0,2 mol = n(este) = n(C2H5OH)

suy ra gc ru trong este l C2H532,8 gam
RCOOC2H5 : 0,2 mol

CH3OH: 0,4 mol
Suy ra: (R + 73)0,2 + 320,4 = 32,8

R = 27
R l C2H3
Vy cng thc ca X, Y l:
CH2=CH-COOC2H5
CH3OH
1. Khi chy Y thu c:
5
(4,0
)
2,0
22
13,5
nCO2 =
= 0.5 (mol) < nH2O =
= 0,75 mol)
44
18
Hydrocacbon Y l hydrocacbon no ( v chy cho nCO2 < nH2O)

Cng thc phn t ca Y l CnH2n+2.
3n + 1
CnH2n+2 +
O2 nCO2 + (n+1)H2O
2
0,5
0,75
n n +1
1,5n = n +1 n =2
=
0,5 0, 75
Vy cng thc ca Y l C2H6
* Nu A ( C2H4) :
C2H4 + H2 C2H6
dY

Theo bi :
H2
=(
dX
30
) : 2 = 2 < 3 ( lai )
28 + 2
H2
* Nu A ( C2H2) :
dY
Theo bi :
H2
dX
C2H2 + 2H2 C2H6

=(
30
) : 3 = 3 ( tha mn )
26 + 4
H2
Vy A l C2H2
2.
y
y
CxHy + ( x+
) O2 xCO2 +
H2O
4
2
CO2 + 2KOH K2CO3 + H2O

T (1) :
2,0
1,0
(1)
(2)
1 mol + ( x+
y
y
)mol x mol +
mol
4
2
V trong cng iu kin :

Vml + ( x+
y
y
)Vml x Vml +
Vml
4
2
10 ml
40 ml
30 ml
(Bit th tch CO2 to thnh sau phn ng l 40ml (do KOH hp thu)
(Bit th tch hi nc l 30ml)
Vy: x = 4.
y = 6.
=> CTPT ca hydrocacbon l : C4H6.
TI LIU BD HSG HA
Trang 89
L Vit Hng
b. ng vi CTPT C4H6 c 4 ng phn mch thng sau:

CH3 C = C CH3
CH C CH2 - CH3
CH = C CH2 CH3
CH3 - C C - CH3
CH2 = CH CH = CH2
CH2 = C = CH CH3
1,0
Ch : Th sinh lm bi theo phng php khc: Cho kt qu ng; lp lun cht ch gim kho cn
c thang im ca HD chm cho im sao cho hp l.
TI LIU BD HSG HA
Trang 90
L Vit Hng
S GIO DC V O TO
H NAM
27
K THI CHN HC SINH GII TNH
LP 9 THCS NM 2011
Mn: HO HC
THI CHNH THC

BI 1.(3,0 im)
1. Trnh by phng php v vit phng trnh phn ng tch ring tng cht t hn hp
sau: Al2O3, SiO2, CuO.
2. Khng dng thm thuc th hy phn bit cc dung dch ring bit sau: FeCl2, FeCl3,
CuCl2, MgCl2, ZnCl2, NaOH, KCl, NaNO3. Vit phng trnh phn ng minh ho.
BI 2.(3,0 im)
1. Cho dung dch NaOH 20% tc dng va vi dung dch FeCl 2 10%. un
nng trong khng kh cho phn ng xy ra hon ton. Tnh C% ca dung dch
mui to thnh sau phn ng (Coi nc bay hi khng ng k).
2. Ho tan 25,2 gam Fe vo dung dch H2SO4 10% va . Sau phn ng thu c dung dch Y
c nng phn trm ca FeSO 4 l 9,275% ng thi tch ra 55,6 gam mui sunfat kt tinh. Xc nh
cng thc ca mui kt tinh.
BI 3.(3,0 im)
Cho m gam hn hp A gm: Al, Na, Mg tc dng vi nc d thu c 2,24 lt kh H 2. Nu ly
2m gam hn hp A tc dng vi dung dch NaOH d thu c 8,96 lt kh H 2. Nu ly 3m gam hn hp
A tc dng vi dung dch HCl va thu c 22,4 lt kh H 2. Bit cc th tch kh o ktc, tnh m v
phn trm v khi lng ca tng kim loi trong A.
BI 4.(4,0 im) Hy trnh by cch lm ngn gn cho cc sau:
1. Cho hn hp gm 0,3 mol Cu2S v x mol FeS2 tc dng va vi dung dch HNO3
long. Sau phn ng thu c kh NO duy nht v dung dch ch c hai mui sunfat. Tnh x.
2. Crackinh 10 mol C5H12 sau mt thi gian thu c 16 mol hn hp A gm cc ankan
CH4, C2H6, C3H8, C5H12 v cc anken C2H4, C3H6, C4H8.
a. Xc nh t l phn trm s mol C5H12 tham gia phn ng?
b. Chia A thnh hai phn bng nhau, phn 1 t chy hon ton thu c a gam CO2 v b
gam H2O. Phn 2 tc dng va ht 500 ml dung dch Br2 C (M). Tnh a, b, C.
3. Tnh khi lng SO3 cn thm vo 500 gam dung dch H2SO4 22,5 % thu c dung
dch H2SO4 42,5%.
BI 5.(3,0 im)
Tm cc cht v iu kin thch hp hon thnh s phn ng sau:
A
C2H2
G
CH3COOH
B
C
D
E
I
K
Bit A l kh c trong thnh phn chnh ca kh thin nhin, B l kh dng cu ho.
BI 6.(4,0 im)
1. Hp cht hu c A c cha C, H, O. C 0,37 gam hi cht A th chim th
tch bng th tch ca 0,16 gam O2 cng iu kin. Cho 2,22 gam cht A phn ng
vi 100 ml dung dch NaOH 1M c
d = 1,0262 g/ml. Sau khi phn ng xy ra hon ton, nng nhit t t cho n
kh, lm lnh phn hi cho ngng t ht. Sau th nghim thu c cht rn B khan
v 100 gam cht lng. Xc nh cng thc cu to ca A.
2. Mt hn hp A gm 1 ankan v 1 anken. Dn A vo bnh ng 500 gam dung dch Br 2 4%, sau
khi brm phn ng ht thy khi lng bnh brm tng 3,50 gam v thu c kh bay ra khi bnh c
khi lng 7,30 gam. t chy hon ton kh bay ra thu c 21,56 gam CO 2. Xc nh cng thc phn
t ca hai cht ban u.
Cho H = 1; C = 12; O = 16; Mg = 24; Na = 23; Al = 27; S = 32; Fe = 56; Br = 80.
------------------------------------HT--------------------------------H v tn .............................................. S bo danh......................................................
Ch k ca gim th s1........................... Ch k ca gim th s1................................
TI LIU BD HSG HA
Trang 91
L Vit Hng
S Gio dc v o to
Thi Bnh
28
thi chn hc sinh gii lp 9 THCS nm hc 2010-2011
Mn: HO hc
Cu 1. (3 im)
a) un nng nh dung dch HCl m c d vi 3,48 gam MnO 2, kh Clo sinh ra c hp th ht
bng 800 ml dung dch NaOH 0,1M nhit thng. Tnh nng mol/l ca cc cht trong dung
dch sau phn ng.
b) Qung boxt c thnh phn chnh l Al2O3 c ln mt lng Fe2O3 v SiO2. Bng phng php ho
hc hy tch Al2O3 ra khi hn hp. Vit phng trnh phn ng minh ho.
Cu 2. (3 im) Ho tan hon ton mt oxit kim loi M (ho tr khng i) vo lng va dung dch
H2SO4 10% to dung dch X cha mt mui nng 11,243%.
a) Xc nh oxit kim loi trn.
b) Vit phng trnh phn ng trong cc trng hp sau (km iu kin phn ng, nu c).
+ iu ch kim loi tng ng t oxit trn.
+ Ho tan oxit trn trong dung dch NaOH d.
+ Cho dung dch X tc dng vi dung dch Na2CO3.
Cu 3. (2 im) Cho ba bnh mt nhn:
Bnh X cha dung dch KHCO3 v K2CO3.
Bnh Y cha dung dch KHCO3 v K2SO4.
Bnh Z cha dung dch K2CO3 v K2SO4.
Ch dng qu tm, dung dch HCl, dung dch Ba(OH) 2 v ng nghim; hy phn bit cc dung
dch cha trong cc bnh trn? Vit phng trnh phn ng minh ho.
Cu 4. (3 im) Cho hirocacbon X c cng thc phn t C nH2n+2 (c tnh cht tng t metan) tc dng
vi clo (nh sng) thu c 15,75 gam hn hp cc sn phm th monoclo v iclo. Kh HCl sinh ra
c hp th hon ton bng nc sau trung ha bng dung dch NaOH thy tn ht 250 ml dung
dch NaOH 1,2M. Xc nh cng thc phn t ca X.
Cu 5. (2 im) Trn V1 lt dung dch HCl 1M vi V 2 lt dung dch NaOH 2M c dung dch X.
Dung dch X ho tan c ti a a mol Al(OH)3. Tm biu thc lin h gia V1, V2 v a?
Cu 6. (3 im) Hn hp A gm 3 kim loi: K, Al, Fe c chia thnh 3 phn bng nhau:
Phn 1 cho tc dng vi nc d thu c 4,48 lt kh.
Phn 2 tc dng vi dung dch KOH d thu c 7,84 lt kh.
Phn 3 ho tan hon ton trong 0,5 lt dung dch H2SO4 1,2M thu c 10,08 lt kh v dung dch B.
a) Tnh % khi lng mi kim loi trong hn hp A (Cho cc kh u o ktc).
b) Cho dung dch B tc dng vi 240 gam dung dch NaOH 20%. Lc kt ta nung trong khng kh
n khi lng khng i c m gam cht rn. Tnh gi tr m? (gi s cc mui to kt ta ng
thi vi NaOH).
Cu 7. (2 im) Hp th ht V lt kh CO2 (ktc) vo 200 ml dung dch hn hp NaOH 1M v Ba(OH)2
0,5M thu c 11,82 gam kt ta. Xc nh gi tri ca V?
Cu 8. (2 im) Cho kh etan (C2H6) qua xc tc ( nhit cao) thu c mt hn hp kh X gm etan
d, etilen, axetilen v H2. T khi ca hn hp X i vi etan l 0,4. Nu cho 0,6 mol hn hp X qua
dung dch Br2 d th c ti a bao nhiu mol Br2 tham gia phn ng.
Cho: H=1; C=12; O=16, Na=23; Al=27; S=32; Cl=35,5;
K=39; Mn=55; Fe=56; Ba=137.
--- Ht --H v tn th sinh:.................................................................. S bo danh:................
TI LIU BD HSG HA
Trang 92
L Vit Hng
S Gio dc v o to
Thi Bnh
K thi chn hc sinh gii lp 9 THCS nm hc 2010-2011

hNG DN V BIU Im MN HO hc
Cu
Ni dung
Cu 1. a) S mol MnO2 = 3,48 : 87 = 0,04 mol
(3) S mol NaOH = 0,1.0,8 = 0,08 mol
Ptp: MnO2 + 4HCl MnCl2 + Cl2 + 2H2O
Cl2 + 2NaOH NaCl + NaClO + H2O
Theo ptp: mol NaOH = 2mol Cl2 phn ng va
mol NaCl = mol NaClO = mol Cl2 = 0,04 mol
CM(NaCl) = CM(NaClO) = 0,04 : 0,8 = 0,05(M)
b) un hn hp vi dung dch NaOH c d
toC
SiO2 + 2NaOH
Na2SiO3 + H2O
Lc tch phn dung dch ri dn kh CO2 ti d vo
CO2 + NaOH NaHCO3
CO2 + NaAlO2 + 2H2O Al(OH)3 + NaHCO3
Lc tch kt ta ri nung nhit cao
toC
2Al(OH)3
Al2O3 + 3H2O
Cu 2. a) t cng thc oxt M2On
(3) Ptp: M2On + nH2SO4 M2(SO4)n + nH2O
mol
1
n
1
mddH2SO4 = n.98.100/10 = 980n gam
mdd mui = 2M + 996n (gam)
C% mui = (2M + 96n) : (2M + 996n) = 0,11243
M = 9n M = 27 (Al)
Cng thc oxt: Al2O3
dpnc
2Al + 3/2O2
b) ptp: Al2O3
criolit
Al2(SO4)3 + 3Na2CO3 + 3H2O 2Al(OH)3 + 3Na2SO4 + 3CO2
Cu 3. - iu ch dung dch BaCl2: Cho dung dch Ba(OH)2 vo ng nghim, cho tip qu tm
(2) vo, qu tm ho xanh. Cho t t dung dch HCl vo n khi qu chuyn sang mu tm
th dng li, ta iu ch c dd BaCl2
Ptp: Ba(OH)2 + 2HCl BaCl2 + 2H2O
- Ly mt lng nh tng dung dch X, Y, Z cho vo tng ng nghim ring bit nh
s th t
+ Cho dd BaCl2 vo tng ng nghim n d, cc ng nghim u to kt ta trng: Kt ta
t X cha BaCO3; t Y cha BaSO4; t Z cha hn hp BaCO3 v BaSO4.
Ptp: K2CO3 + BaCl2 BaCO3 + 2KCl
K2SO4 + BaCl2 BaSO4 + 2KCl
+ Cho dung dch HCl ti d vo tng ng nghim cha cc kt ta: Nu kt ta no
tan ht th ban u l dd X, nu kt ta tan mt phn th l dd Z, cn li l dd Y
BaCO3 + 2HCl BaCl2 + CO2 + H2O
askt
Cu 4. Ptp CnH2n+2 + Cl2
CnH2n+1Cl + HCl
askt
(3)
CnH2n+2 + 2Cl2 CnH2nCl2 + 2HCl
HCl + NaOH NaCl + H2O
S mol NaOH = mol HCl = mol Cl2 = 0,3 mol
Theo LBTKL: mankan = 15,75 + 36,5.0,3 71,0,3 = 5,4 gam
0,15 < molankan < 0,3
5,4/0,3 < Mankan < 5,4/0,15
18 < 14n + 2 < 36
1,14 < n < 2,43 n = 2 CTPT ankan: C2H6
TI LIU BD HSG HA
Trang 93
L Vit Hng
(03 trang)
im
0,25
0,5
0,25
0,25
0,25
0,5
0,5
0,5
1,5
0,5.3
0,5
Nhn
c
mi dd
v vit
pthh
cho
0,5
2.0.5
0,25
1,75
im
Cu
Ni dung
Cu 5. S mol HCl = V1 mol
(2) S mol NaOH = 2V2 mol
Trng hp 1: Dung dch X cha HCl d
2V2
2V2
3HCl + Al(OH)3 AlCl3 + 3H2O
3a
a
S mol HCl = 2V2 + 3a = V1
Trng hp 2: Dung dch X cha NaOH
V1
V1
Al(OH)3 + NaOH NaAlO2 + 2H2O
a
a
S mol NaOH = V1 + a = 2V2
Cu 6. a) Gi x, y, z ln lt l s mol K, Al, Fe trong mt phn
(3)
Phn 2: K + H2O KOH + 1/2H2
(1)
x
x
x/2
Al + KOH + H2O KAlO2 + 3/2H2 (2)
y
3y/2
S mol H2 = x/2 + 3y/2 = 7,84/22,4 = 0,35 mol
Phn 1: S mol H2 (1) = x/2
S mol H2 (2) = 3/2mol KOH (1) = 3x/2
Tng mol H2 = x/2 + 3x/2 = 0,2 x = 0,1 mol y = 0,2 mol
Phn 3: S mol H2SO4 = 0,6 mol
2K + H2SO4 K2SO4 + H2
x
x/2
2Al + 3H2SO4 Al2(SO4)3 + 3H2
y
y/2
3y/2
Fe + H2SO4 FeSO4 + H2
z
z
z
S mol H2 = x/2 + 3y/2 + z = 10,08/22,4 = 0,45 mol
z = 0,1 mol
Khi lng ca 1 phn = 0,1.39 + 0,2.27 + 0,1.56 = 14,9 gam
%mK = 26,17%; %mAl = 36,24%; %mFe = 37,59%
b) S mol H2SO4 p = mol H2 = 0,45 mol
mol H2SO4 d = 0,6 0,45 = 0,15 mol
S mol NaOH = 1,2 mol
Ptp: H2SO4 + 2NaOH Na2SO4 + 2H2O
0,15
0,3
FeSO4 + 2NaOH Fe(OH)2 + Na2SO4
0,1
0,2
0,1
Al2(SO4)3 + 6NaOH 2Al(OH)3 + 3Na2SO4
0,1
0,6
0,2
Al(OH)3 + NaOH NaAlO2 + 2H2O
0,1
0,1
S mol Al(OH)3 d = 0,2 0,1 = 0,1 mol
toC
4Fe(OH)2 + O2
2Fe2O3 + 4H2O
0,1
0,05
toC
2Al(OH)3 Al2O3 + 3H2O
0,1
0,05
Khi lng cht rn = 160.0,05 + 102.0,05 = 13,1 gam
Cu 7. S mol NaOH = 0,2 mol
(2,0) S mol Ba(OH)2 = 0,1 mol
TI LIU BD HSG HA
Trang 94
L Vit Hng
1,0
1,0
0,5
0,5
0,5
0,5
Vit
ng
Ptp
0,5
Tnh
ton
n
p
n 0,5
Cu
Ni dung
S mol BaCO3 = 11,82/197 = 0,06 mol
Trng hp 1: CO2 thiu so vi Ba(OH)2
CO2 + Ba(OH)2 BaCO3 + H2O
0,06
0,06
VCO2 = 0,06.22,4 = 1,344 lt
Trng hp 2: CO2 d so vi Ba(OH)2
CO2 + Ba(OH)2 BaCO3 + H2O
0,1
0,1
0,1
0,1
0,2
0,1
CO2 + Na2CO3 + H2O 2NaHCO3
0,1
0,1
0,04
0,04
VCO2 = 0,34.22,4 = 7,616 lt
Cu 8. Ptp
(2,0)
im
0,75
1,25
0,5
p,t
C2H4 + H2
C2H6
xt
p,t
. C2H2 + 2H2
C2H6
xt
C2H4 + Br2 C2H4Br2
C2H2 + 2Br2 C2H2Br4
Gi s nung 1 mol C2H6
C KLPTTB ca X = 0,4.30 = 12 (g/mol)
Theo BTKL c mX = mC2H6 = 30 gam
s mol hn hp X = 30/12 = 2,5 mol
Khi nung 1 mol C2H6 thu c 2,5 mol hn hp X
Vy x mol. 0,6 mol
x = 0,6/2,5 = 0,24 mol
Theo ptp: s mol Br2 p = mol H2 = tng s mol = 0,6 0,24 = 0,36 mol.
Ghi ch:
1. Hc sinh lm cch khc ng vn cho im ti a
2. Vit phng trnh thiu iu kin hoc cn bng sai cho na s im.
TI LIU BD HSG HA
Trang 95
L Vit Hng
1,5
S GIO DC V O TO
BN TRE
CHNH THC
29
THI CHN HC SINH GII LP 9
TRUNG HC C S CP TNH NM HC 2010-2011
Mn: HA HC
Thi gian: 150 pht ( Khng k chp )
Cu 1 ( 4,0 im):
R l nguyn t thuc nhm A ca bng tun hon. T l % khi lng ca R trong oxit cao nht v ca R
trong hp cht kh vi hidro l 0,425.
1) Xc nh nguyn t R v cng thc ha hc ca oxit cao nht ca R ( oxit X)
2) Y l oxit khc ca R c t khi hi i vi X l 0,8. Hy vit 3 phn ng ha hc iu ch Y t 3 cht
( kim loi, phi kim, mui).
Cu 2 (3,0 ):
Cho chui bin ha sau:
(A) + (B) (C) + (D) + (E)
(C) + NaOH (G) + ....
(G) + (T) + (E) (M)
(M) (L) + (E)
(X) + (T) (L) + (D)
(L)
+ H2 Fe + .....
Tm cng thc cc cht k hiu bng ch ci in hoa trong du ngoc (A), (B),.... Vit cc phng trnh
phn ng ph hp vi s trn.
Cu 3 ( 4,0 im) :
Dung dch A cha CuSO4 8% v (NH4)2SO4 6,6%. Cho 15,07 gam Ba vo 100gam dung dch A, sau
phn ng thu c dung dch B, kh C v kt ta D. Tnh nng phn trm cht tan trong dung dch B.
Cu 4 ( 3,0 im) :
Dn V lt CO2 ( ktc) vo bnh cha 200ml dung dch Ba(OH) 2 2M, sau phn ng thu c 39,4 gam kt
ta. Tm gi tr V.
Cu 5 ( 2,0 im) :
A l mt mui c cc tnh cht sau : tan c trong nc v thng hoa hon ton khi un nng. Tm 2
cht ph hp vi A v vit cc phng trnh trnh phn ng nhit phn A
Cu 6 (4,0 im) :
Ch dng mt thuc th hy phn bit cc cht rn sau : Na2SO4, FeCl3, NH4NO3, NaCl.
Cho : H=1 ; C=12 ; N= 14 ; O= 16 ;, S=32 ; Cl=35,5 ; Na=23 ; Mg=24 ; Al =27 ; K =39 ;
Ca = 40 ; Fe =56 ; Cu=64 ; Zn=65 ; Ba = 137
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TI LIU BD HSG HA
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L Vit Hng
30
K THI CHN LC HC SINH GII CP TNH
LP 9 THCS NM HC 2010 2011
MN THI: HA HC
S GD & T TR VINH
***
thi chnh thc
Cu 1.(2 im)
a)Trong phng th nghim c nhng cht sau: vi sng CaO, sa Na 2CO3 v nc H2O. T
nhng cht c, hy vit phng trnh ha hc iu ch NaOH.
b)Cho 4 ng nghim mt nhn cha ring bit cc dung dch HCl, Ba(OH) 2, NaCl, Na2SO4. Bng
phng php ha hc hy nhn bit cc dung dch trn (vit phng trnh ha hc nu c).
Cu 2. (2 im)
Cho s biu din chuyn i sau:
Phi kim (1) Oxit axit (2) Oxit axit (3) Axit (4) mui sunfat tan (5)
mui sunfat khng tan.
a)Tm cng thc cc cht thch hp thay th cho tn cc cht trong s .
b)Vit cc phng trnh ha hc biu din chuyn i trn. (ghi r iu kin nu c).
Cu 3. (2 im)
a)Bit rng c mt mol kh metan chy ta ra 200 Kcal v 1 kg than chy ta ra 8000 Kcal. Hy
so snh nhit ta ra khi t chy hon ton 1 kg kh metan v 2 kg than.
b)T metan, ngi ta c th iu ch H2 ( v CO) theo 2 cch sau:
- Cch 1: CH4 + O2 800
/Ni CO + 2H2 (Hiu sut 80%)
-Cch 2: CH4 + H2O 800
/Ni CO + 3H2 (Hiu sut 75%)
Hi cch no thu c nhiu H2 hn ?
Cu 4. (3 im)
t chy hon ton mt phi kim X trong bnh cha kh oxi d. Khi phn ng kt thc, thu c
mt oxit tng ng trong oxi chim 56,338% theo khi lng. Xc nh cng thc ca oxit thu c.
Cu 5.(3 im)
t chy a gam st trong khng kh thu c 1,35 a gam cht rn Y gm F 3O4 v Fe d. Tnh
thnh phn phn trm theo khi lng ca kim loi st c trong cht rn Y.
Cu 6. (2,5 im)
T axetilen c th tng hp ra benzen nh phn ng:
, 600 C
3C2H2
C
C6H6
a)Vit cc phng trnh ha hc biu din qu trnh tng hp benzen t canxi cacbua.
b)Tnh khi lng canxi cacbua cn dng iu ch 117 gam bezen. Bit rng hiu sut ca qu
trnh tng hp ny l 60%.
Cu 7. (3 im)
Nhng thanh kim loi A ha tr II vo dung dch CuSO 4. Sau mt thi gian ly thanh kim loi ra
thy khi lng gim 0,05%. Mt khc cng ly thanh kim loi nh trn nhng vo dung dch Pb(NO 3)2
th thy khi lng thanh kim loi tng ln 7,1%.
Xc nh tn kim loi A. Bit rng s mol CuSO 4 v Pb(NO3)2 tham gia 2 trng hp bng
nhau.
Cu 8.(2,5 im)
Cho men ru vo 2 lt dung dch glucoz. Sau mt thi gian, men ru tc dng ln glucoz lm
thot ra 8,96 lt kh cacbonic (ktc)
a)Vit phng trnh ha hc xy ra.
b)Tnh nng mol/ lt ca dung dch glucoz. Bit rng hiu sut ca qu trnh ln men ch t
20%.
--------Ht----------0
TI LIU BD HSG HA
Trang 97
L Vit Hng

30 de Thi HSG Cac Tinh Co Dap An

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C2H2 + HCl CH2=CH-Cl

(-CH2-CHCl-)n (nha PVC)

nHCl ban u = 100.36,5 = 0,8 (mol)

T (1): nFe = nH 2 = 0,1(mol) => mFe = 0,1 . 56 = 5,6(g)

T (1): nHCl = 2 nH 2 = 2.0,1= 0,2 (mol)

mddB = 217 + 33 = 250 (g)

T (*) v (**) ta c phng trnh

Vy cng thc Oxit st l: Fe3O4

Fe2(SO4)3 + 3SO2 + 6H2O

Nu H2SO4 khng d: (5) xy ra:

=> VSO min = 0,05 . 22,4 = 1,12 (lt)

b) Trong dung dch A c:

mCuO = 0,01.80 = 0,8 gam

HOOC-COOH + 2NaHCO3 NaOOC-COONa + 2CO2 + 2H2O (3)

- Bo ton nguyn t oxi:

- LBT khi lng:

=> 24 + x = 28,5 => x = 4,5

Gi s c 1 mol B => mB = 28,5 gam

- TH1: khng xy ra phn ng (2)

Theo (2): nCO2 (2) = nK2CO3 (2) = 0, 03mol

d = 0,2 0,08 = 0,12mol

phn ng = 0,240,12 = 0,12mol

=> mkh= mCu +

m HNO - mCu(NO ) - m H O = 2,56+7,56-7,52-1,08 = 1,52g

Trong dung dch A c:

n HNO3 du = 0, 24 0,12 = 0,12 mol.

THI CHN HC SINH GII CP TNH

44(b + 0,3) + 2(c 0,3)

Thay b + c = 1- 0,3 = 0,7 44b + 2c = 9,8

Cu V (2 im): Ba cht kh X,Y, Z u gm 2 nguyn t, phn t cht Y v Z u c 3 nguyn t. C 3

Na2SO4 + SO2 + H2O

Ch : Hc sinh chn cht khc v vit phng trnh ha hc ng, cho im ti

(44 28) p 16.p

2. A, B, C l 3 cht hu c mch h c cc tnh cht sau: B lm mt mu dung dch brom, C tc

S GIO DC V O TO GIA LAI

S GIAO DUC VA AO TAO

- Dng dung dch H2SO4 long nhn bit.

- Cho hn hp tc dng vi dung dch NaOH d, chng ct thu ly ru etylic ln

Tim R va % khi lng cac cht trong X

Tinh nng phn trm cac cht trong dung dich A:

Cac phng trinh phan ng:

nSO 2 = 3/2.(nAl + nFe) = 3/2.(0,05a + 0,225a) = 27,72/22,4= 1,2375 .

T cac p (1) va (2) ta co:

Nu phng trnh khng cn bng th tr na s im ca phng trnh . Hc

K THI CHN HC SINH GII LP 9 CP TNH

Cho dung dch BaCl2 d vo dung dch A, lc b kt ta, dung dch cn

AHCO3 + HCl ACl + CO2 + H2O

A2CO3 + 2HCl 2ACl + CO2 + H2O

Ca(OH)2 + 2HCl CaCl2 + 2H2O

K THI CHN HC SINH GII TNH LP 9 CP THCS

Cho hn hp ha tan vo nc c dung dch B ( cha 0,4 mol NaCl )

Cu ny gii v l lun bng nhiu phng php khc nhau. Nu bi lm da

CO2 + Ba(OH)2 BaCO3 + 2H2O (4)

c th 2CO2 + Ba(OH)2 Ba(HCO3)2 (5)

TH 1: Ba(OH)2 d khng c phn ng (5)

nBa (OH )2 (5) = 0,33-0,32 =0,01 (mol)

THI CHN HC SINH GII CP TNH LP 9 THCS NM

Cu III: (3,0 im)

C2H4 + Br2 C2H4Br2

b = 0,125 mol %VC2H 4 = 50%

5KCl+ KClO3 + 3H2O

1.a.-Tc phn ng gim dn theo thi gian.