TRNG THPT MINH KHAI T HO HC

THI TH I HC LN 1 NM 2013
Mn thi: Ho hc M 357 Thi gian lm bi: 90 pht; (50 cu trc nghim)

( thi c 05 trang)

Ho, tn thi sinh:.........................................................................S bao danh:................................... Cho bit: H = 1; He = 4; Li = 7; Be = 9; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Br = 80; Rb = 85; Sr = 88; Ag = 108; Sn = 119; Cs = 133; Ba = 137; Pb = 207. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Cho cn bng ho hc sau: 2NH3 (k) N2 (k) + 3H2 (k). Khi tng nhit ca h th t khi ca hn hp so vi hiro gim. Nhn xt no sau y l ng? A. Khi tng p sut ca h, cn bng chuyn dch theo chiu thun. B. Khi tng nng ca NH3, cn bng chuyn dch theo chiu nghch. C. Phn ng thun l phn ng to nhit. D. Khi tng nhit ca h, cn bng chuyn dch theo chiu thun. Cu 2: t 4,2 gam st trong khng kh thu c 5,32 gam hn hp X gm st v cc oxit st. Ha tan ht X bng 200 ml dung dch HNO3 a mol/l sinh ra 0,448 lt NO ( ktc, sn phm kh duy nht ca N +5). Gi tr ca a l A. 1,5. B. 1,3. C. 1,1. D. 1,2. Cu 3: Pht biu no sau y l ng? A. Trong tt c cc nguyn t, s proton bng s ntron. B. Ht nhn ca tt c cc nguyn t u c proton v ntron. C. Nguyn t M c Z = 11 thuc chu k 3 nhm IA. D. Nhng nguyn t c cng s khi thuc cng mt nguyn t ho hc. Cu 4: Dung dch cc cht sau c cng nng mol/lt: glyxin (1), lysin (2) v axit oxalic (3). Gi tr pH ca cc dung dch trn tng dn theo th t l: A. (3), (2), (1). B. (1), (2), (3). C. (2), (3), (1). D. (3), (1), (2). Cu 5: Nhit phn cc mui sau: NH4NO2, NaHCO3, CaCO3, KMnO4, NaNO3, Cu(NO3)2. S phn ng nhit phn thuc loi phn ng oxi ho - kh l A. 6. B. 5. C. 4. D. 3. Cu 6: Khi cho cht bo X phn ng vi dung dch brom th 1 mol X phn ng ti a vi 4 mol Br 2. t chy hon ton a mol X thu c b mol H2O v V lt CO2 (ktc). Biu thc lin h gia V vi a, b l A. V = 22,4(b + 6a). B. V = 22,4 (4a b). C. V = 22,4(b + 3a). D. V = 22,4(b + 7a) Cu 7: Cho cc pht biu sau v phenol (C6H5OH): (a) Phenol va tc dng vi dung dch NaOH va tc dng c vi Na. (b) Phenol tan c trong dung dch KOH. (c) Nhit nng chy ca phenol ln hn nhit nng chy ca ancol etylic. (d) Phenol phn ng c vi dung dch KHCO3 to ra CO2. (e) Phenol l mt ancol thm. S pht biu ng l A. 3. B. 5. C. 4. D. 2. Cu 8: Nhn xt no sau y ng? A. Cc mui Ca3(PO4)2 v CaHPO4 u tan trong nc. B. Trong cng nghip, photpho c iu ch t Ca3P2, SiO2, v C. C. iu kin thng, photpho tc dng vi O2 to sn phm P2O5. D. Thnh phn chnh ca qung apatit l 3Ca3(PO4)2.CaF2. Cu 9: Cho cc pht biu sau: (a) Cc kim loi kim u tan tt trong nc. (b) Cc kim loi Mg, Fe, K v Al ch iu ch c bng phng php in phn nng chy. (c) Cc kim loi Mg, K v Fe u kh c ion Ag+ trong dung dch thnh Ag. (d) Khi cho Mg vo dung dch FeCl3 d thu c kim loi Fe. S pht biu ng l A. 3. B. 1. C. 4. D. 2.
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Cu 10: Th tch dung dch FeSO4 0,2M cn phn ng va vi 100 ml dung dch KMnO 4 0,1M trong H2SO4 d l A. 200 ml. B. 300 ml. C. 250 ml. D. 400 ml. Cu 11: t chy hon ton mt axit cacboxylic no, mch h thu c s mol CO 2 - s mol H2O = s mol axit. S nhm COOH c trong mt phn t axit l A. 3. B. 1. C. 2. D. 4. Cu 12: Hn hp X gm: CuO, FeO v Fe3O4. Dn kh CO d qua 4,56 gam hn hp X nung nng. em ton b lng CO2 to ra cho hp th vo dung dch Ba(OH)2 thu c 5,91 gam kt ta v dung dch Y. un nng Y li thu thm 3,94 gam kt ta. Cho 4,56 gam hn hp X phn ng va vi dung dch H2SO4 long thu c dung dch cha m gam mui. Bit cc phn ng xy ra hon ton. Gi tr ca m l A. 7,20. B. 10,16. C. 11,28. D. 6,86. Cu 13: Hn hp X gm HCHO, CH3COOH, HCOOCH3 v CH3CH(OH)COOH. t chy hon ton X cn V lt O2 (ktc), hp th ht sn phm chy vo mt lng d nc vi trong thu c 50 gam kt ta. Gi tr ca V l A. 16,8. B. 7,84. C. 8,40. D. 11,2. Cu 14: Cho hn hp gm 0,04 mol Zn v 0,03 mol Fe vo dung dch cha 0,1 mol CuSO 4 n phn ng hon ton, thu c dung dch X v cht rn Y. Cho ton b X phn ng vi mt lng d dung dch Ba(OH)2, kt ta thu c trong khng kh ti khi lng khng i cn c m gam. Gi tr ca m l A. 29,45. B. 29,20. C. 28,94. D. 30,12. Cu 15: Cho dy cc cht: Cu, CuO, Fe 3O4, C, FeCO3, Fe(OH)3. S cht trong dy tc dng vi H 2SO4 c, nng, d khng to kh SO2 l A. 2. B. 4. C. 1. D. 3. Cu 16: Hirocacbon X c cng thc phn t C6H10. X tc dng vi dung dch AgNO 3 trong dung dch NH3 to kt ta vng. Khi hiro ho hon ton X thu c 2,2-imetylbutan. X l A. 2,2-imetylbut-3-in. B. 3,3-imetylbut-1-in. C. 2,2-imetylbut-2-in. D. 3,3-imetylpent-1-in. Cu 17: Cho dung dch cht X vo dung dch cht Z n d thy c kt ta keo trng, sau tan. Cho dung dch cht Y vo dung dch cht Z n d thy to thnh kt ta keo trng khng tan. Cho dung dch cht X vo dung dch cht Y khng c phn ng xy ra. Cc cht X, Y, Z ln lt l: A. HCl, AlCl3, NaAlO2. B. NaAlO2, AlCl3 , HCl. C. AlCl3, NaAlO2, NaOH. D. Na2CO3, NaAlO2, AlCl3. Cu 18: Amin bc mt X c cng thc C xHyN. t chy hon ton 8,85 gam X thu c 1,68 lt kh N 2 (ktc). S cng thc cu to ca X tha mn tnh cht trn l A. 5. B. 2. C. 4. D. 3. Cu 19: Thc hin cc th nghim sau: (a) Cho t t n d dung dch NaOH long vo dung dch gm CuCl2 v AlCl3. (b) Cho t t n d dung dch Ba(OH)2 vo dung dch Al2(SO4)3. (c) Cho t t n d dung dch HCl vo dung dch Na[Al(OH)4] (hay NaAlO2). (d) Sc kh H2S vo dung dch CuCl2. (e) Sc t t n d kh CO2 vo dung dch Ca(OH)2. (f) Cho dung dch BaCl2 vo dung dch NaHSO4. S th nghim thu c kt ta sau khi cc th nghim kt thc l A. 4. B. 3. C. 2. D. 1. Cu 20: Hn hp X gm: Na, Ca, Na 2O v CaO. Ha tan ht 5,13 gam hn hp X vo nc thu c 0,56 lt H2 (ktc) v dung dch kimY trong c 2,8 gam NaOH. Hp th 1,792 lt kh SO 2 (ktc) vo dung dch Y thu c m gam kt ta. Gi tr ca m l A. 6,0. B. 7,2. C. 5,4. D. 4,8. Cu 21: Ha tan Fe3O4 trong lng d dung dch H2SO4 long thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong dy: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al, H2S? A. 6. B. 5. C. 8. D. 7. Cu 22: Hn hp X gm mt anehit, mt axit cacboxylic v mt este (trong axit v este l ng phn ca nhau). t chy hon ton 0,2 mol X cn 0,625 mol O2, thu c 0,525 mol CO2 v 0,525 mol nc.
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Nu em ton b lng anehit trong X cho phn ng hon ton vi mt lng d dung dch AgNO 3 trong NH3 th khi lng Ag to ra l A. 64,8 gam. B. 21,6 gam. C. 16,2 gam. D. 32,4 gam. Cu 23: Kim loi va tc dng vi dung dch HCl va tc dng vi dung dch NaOH iu kin thng l A. Mg. B. Cu. C. Fe. D. Al. Cu 24: Ha tan mt hn hp gm Al v Fe vo dung dch HCl va thu c 8,96 lt kh (ktc) v dung dch X. Cho t t dung dch NaOH 1M vo dung dch X, khi lng kt ta thu c cc i th ht V lt. Gi tr ca V l A. 1,0. B. 0,8. C. 0,6. D. 0,4. Cu 25: Cho cc cp cht sau: (a) Kh Cl2 v kh O2. (b) Kh H2S v kh SO2. (c) Kh H2S v dung dch Pb(NO3)2. (d) CuS v dung dch HCl. (e) Kh Cl2 v dung dch NaOH. S cp cht xy ra phn ng ho hc nhit thng l A. 1. B. 2. C. 4. D. 3. Cu 26: Hn hp X gm mt axit hu c v mt este (u no, mch h, n chc). X tc dng va vi 10 ml dung dch KOH 4M thu c mt mui v mt ancol. un ton b lng ancol trn vi H 2SO4 c thu c 0,015 mol mt anken. Nu t chy hon ton X ri hp th ton b sn phm vo dung dch Ca(OH)2 d th khi lng bnh tng 6,82 gam (hiu sut cc phn ng u 100%). Cng thc ca hai cht hu c trong X l A. C2H5COOH v C2H5COOC3H7. B. HCOOH v HCOOC3H7. C. HCOOH v HCOOC2H5. D. CH3COOH v CH3COOC2H5. Cu 27: Xenluloz trinitrat c iu ch t axit nitric v xenluloz (hiu sut phn ng 90% tnh theo axit nitric). c 14,85 kilogam xenluloz trinitrat cn dung dch cha m kilogam axit nitric. Gi tr ca m l A. 9,45. B. 11,50. C. 8,51. D. 10,50. Cu 28: Cho m gam Na vo 160 ml dung dch gm Fe 2(SO4)3 0,125M v Al2(SO4)3 0,25M, sau khi cc phn ng kt thc, lc kt ta ri nung n khi lng khng i, thu c 4,73 gam cht rn. Gi tr ln nht ca m l A. 11,50. B. 10,35. C. 9,20. D. 9,43.
+NaOH;t +CuO;t +HCl Y Z. Tn gi ca Z l X Cu 29: Cho s phn ng: Propen A. axeton. B. anehit acrylic. C. propan-2-ol. D. ancol anlylic. Cu 30: Cho x mol Ba(OH)2 vo dung dch cha y mol KHCO 3 (x < y < 2x). Sau khi kt thc cc phn ng thu c kt ta T v dung dch Z. C cn Z c m gam cht rn. Mi quan h gia m, x, y l A. m = 82y - 43x. B. m = 60(y - x). C. m = 82y - 26x. D. m = 43y - 26x. Cu 31: Tn gi ca hp cht c cng thc H2N [CH2]4 CH(NH2) COOH l A. axit glutamic. B. lysin. C. glyxin. D. alanin. Cu 32: Kh hon ton 0,3 mol FeO bng lng bt Al va trong iu kin khng c khng kh thu c cht rn X. Ton b lng X tc dng va ht vi dung dch cha a mol HCl. Gi tr ca a l A. 0,6. B. 1,2. C. 0,9. D. 1,5. Cu 33: X l mt anehit mch h c s nguyn t C trong phn t nh hn 4. Cho 1 mol X tc dng vi lng d dung dch AgNO3 trong NH3 thu c 2 mol Ag; mt khc 1 mol X phn ng ti a 2 mol H 2. Phn t khi ca X l A. 44. B. 72. C. 56. D. 54. Cu 34: Cho cc polime sau: Poli(vinylclorua), thu tinh plexiglas, teflon, nha novolac, t visco, t nitron, cao su buna, t nilon -6,6. Trong , s polime c iu ch bng phn ng trng hp l A. 5. B. 7. C. 6. D. 4. Cu 35: Mt peptit X mch h khi thu phn hon ton ch thu c glyxin. Khi t chy 0,1 mol X thu c 12,6 gam nc. S nguyn t oxi c trong 1 phn t X l A. 5. B. 2. C. 3. D. 4. Cu 36: Phn ng no trong cc phn ng sau phn t SO2 khng th hin tnh kh, tnh oxi ho? A. SO2 + Cl2 SO2Cl2.
o o

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B. 3SO2 + 2Ba(OH)2 BaSO3 + Ba(HSO3)2 + H2O. C. 5SO2 + 2KMnO4 + 2H2O K2SO4 + 2MnSO4 + 2H2SO4. D. SO2 + 2H2S 3S + 2H2O. Cu 37: Phn trm khi lng ca nguyn t R trong oxit cao nht ca n l 25,93%. Nguyn t R l A. cacbon. B. nit. C. silic. D. lu hunh. Cu 38: Cho cc dy cht: etyl axetat, etilen, buta-1,3-ien, vinyl axetat, etyl acrylat. S cht trong dy lm nht mu dung dch brom l A. 4. B. 3. C. 5. D. 2. Cu 39: Cho dy cc cht: but-2-en, axit acrylic, propilen, ancol anlylic, 2-metylhex-3-en, axit oleic, hexa-1,4-ien, stiren. S cht trong dy c ng phn hnh hc l A. 7. B. 5. C. 6. D. 4. Cu 40: Hn hp X gm hai este n chc l ng phn ca nhau. ung nng m gam X vi 300 ml dung dch NaOH 1M, kt thc cc phn ng thu c dung dch Y v (m 8,4) gam hn hp hi gm hai anehit no, n chc, ng ng k tip c t khi hi so vi H 2 l 26,2. C cn dung dch Y thu c (m 1,1) gam cht rn. Cng thc ca hai este l A. HCOOC(CH3)=CH2 v HCOOCH=CHCH3. B. CH3COOCH=CHCH3 v CH3COOC(CH3)=CH2. C. C2H5COOCH=CH2 v CH3COOCH=CHCH3. D. HCOOCH=CHCH3 v CH3COOCH=CH2. PHN RING A. Chng trnh chun (t cu 41 n cu 50) Cu 41: Cho dy cc cht: benzen, stiren, propin, etilen, vinyl axetilen, butan. S cht trong dy c kh nng tham gia phn ng cng H2 iu kin thch hp l A. 5. B. 2. C. 4. D. 3. Cu 42: Cho dy cc cht NaOH, Na, NaHCO3, (NH4)2SO4, AgNO3 (trong dung dch NH3). S cht trong dy phn ng c vi dung dch axit fomic l A. 5. B. 2. C. 4. D. 3. Cu 43: Cho 0,1 mol O2 tc dng ht vi 14,4 gam kim loi M (ho tr khng i), thu c cht rn X. Ha tan ton b X bng dung dch HCl d, thu c 13,44 lt H2 (ktc). Kim loi M l A. Ca. B. Mg. C. Al. D. Fe. Cu 44: Dn lung kh CO d i qua 2,4 gam hn hp CuO v Fe 2O3 nung nng n phn ng xy ra hon ton, thu c 1,76 gam cht rn. Phn trm khi lng CuO c trong hn hp ban u l A. 33,33%. B. 45,72%. C. 55,28%. D. 66,67%. Cu 45: Cho 27,6 gam hp cht thm X c cng thc C 7H6O3 tc dng vi 800 ml dung dch NaOH 1M thu c dung dch Y. trung ha ton b Y cn 100 ml dung dch H 2SO4 1M thu c dung dch Z. Khi lng cht rn khan thu c khi c cn dung dch Z l A. 62,2 gam. B. 31,1 gam. C. 58,6 gam. D. 56,9 gam. Cu 46: Hp cht X cha cc nguyn t C, H, O v N c phn t khi l 89. Khi t chy 1 mol X thu c 3 mol CO2, 0,5 mol N2 v 1 lng hi nc. Bit X l hp cht tc dng c vi nc brom. Cng thc cu to ca X l A. H2N CH2 COOH. B. CH2 = CH COONH4. C. H2N CH = CH COOH. D. CH2 = C(NH2) COOH. Cu 47: Pht biu no sau y l ng? A. T lapsan v t nilon-6,6 c iu ch bng phn ng trng ngng. B. Si bng v si t tm u c chung ngun gc t xenluloz. C. Nha novolac (PPF) cha nhm NH-CO- trong phn t. D. Polime l nhng cht rn, c nhit nng chy xc nh. Cu 48: Tt c cc cht trong dy no sau y u c phn ng trng bc? A. Metanol, metyl fomat, glucoz. B. Saccaroz, anehit fomic, metyl fomat. C. Axit fomic, metyl fomat, benzanehit. D. Axetilen, metanal, mantoz. Cu 49: Trong phng trnh phn ng c s : KMnO 4 + HCl MnCl2 + Cl2 + KCl + H 2O. S phn t HCl ng vai tr cht kh bng n ln tng s phn t HCl tham gia phn ng. Gi tr ca n l A. 5/8. B. 1/8. C. 7/8. D. 3/8.
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Cu 50: in phn vi cc in cc tr dung dch hn hp gm 0,2 mol CuSO 4 v 0,12 mol HCl trong thi gian 2000 giy vi dng in c cng l 9,65A (hiu sut ca qu trnh in phn l 100%). Khi lng Cu thot ra catot v th tch kh (ktc) thot ra anot l A. 6,4 gam v 1,792 lt. B. 6,4 gam v 1,120 lt. C. 3,2 gam v 0,448 lt. D. 8,0 gam v 0,672 lt. B. Chng trnh Nng cao (t cu 51 n cu 60) Cu 51: in phn 500 ml dung dch hn hp CuSO4 a mol/l v NaCl 1 mol/l vi in cc tr, mng ngn xp, cng dng in khng i 5A trong thi gian 96,5 pht (hiu sut qu trnh in phn l 100%, nc bay hi khng ng k) thu c dung dch c khi lng gim so vi ban u l 17,15 gam. Gi tr ca a l A. 0,5. B. 0,2. C. 0,3. D. 0,4. Cu 52: Ancol bc ba, mch h X c cng thc phn t C5H10O. T X ngi ta thc hin s bin ho sau: +Br2 +NaOH X C5H10OBr2 C5H12O3 (cht Y). Dy cc cht u c th tc dng c vi Y l: A. Na2O, NaHCO3, v CH3OH (xc tc H2SO4 c, to). B. Na, NaOH, v CH3COOH (xc tc H2SO4 c, to). C. Na, Cu(OH)2, v C2H5OH (xc tc H2SO4 c, to). D. NaHCO3, NaOH v Cu(OH)2. Cu 53: S hirocacbon lm mt mu dung dch brom v s hirocacbon lm mt mu dung dch KMnO4 iu kin thng c cng cng thc phn t C4H8 ln lt l A. 3 v 3. B. 4 v 3. C. 5 v 4. D. 6 v 4. Cu 54: S ng phn cu to c cng cng thc phn t C3H5Br3 l A. 6. B. 5. C. 4. D. 3. Cu 55: Tin hnh cc th nghim: (a) Cho bc kim loi vo dung dch st(III) nitrat. (b) Cho dung dch bc nitrat vo dung dch st(III) nitrat. (c) Cho st kim loi vo dung dch st(III) clorua. (d) Cho dung dch bc nitrat vo dung dch st(II) nitrat. (e) Cho ng kim loi vo dung dch st(III) nitrat. o o o o Cho bit: E Ag+ = + 0,80V, E Fe2+ = -0,44V, E Cu 2+ = +0,34V, E Fe3+ = +0,77V.
Ag

Fe

Cu

Fe2+

S th nghim xy ra phn ng l A. 2. B. 4. C. 5. D. 3. Cu 56: Khi thu phn hon ton 0,1 mol peptit X mch h (to bi cc -aminoaxit c mt nhm NH2 v mt nhm COOH) bng dung dch NaOH (d 25% so vi lng cn phn ng). C cn dung dch thu c hn hp rn c khi lng nhiu hn khi lng X l 78,2 gam. S lin kt peptit trong mt phn t X l A. 9. B. 15. C. 10. D. 16. o Cu 57: Dung dch Y gm CH3COOH 0,1M v HCl 0,005M. Bit 25 C Ka ca CH3COOH l 1,75.10-5. Gi tr pH ca dung dch Y 25oC l A. 1,77. B. 2,30. C. 2,33. D. 2,27. Cu 58: Cp dung dch no sau y u c pH nh hn 7? A. Dung dch NH3 v dung dch NH4Cl. B. Dung dch NaOH v dung dch Na2CO3. C. Dung dch Na2SO4 v dung dch NaHSO4. D. Dung dch AlCl3 v dung dch NaHSO4. Cu 59: Cho 5,52 gam hn hp X gm Fe3O4 v Fe2O3 vo 200 ml dung dch H2SO4 1,5M thu c dung dch Y. Nh t t dung dch KMnO4 0,1M vo dung dch Y n khi bt u xut hin mu hng th ht 20 ml. Phn trm theo khi lng Fe3O4 trong X l A. 57,97%. B. 21,01%. C. 28,98%. D. 42,03%. Cu 60: Dy cc cht c sp xp theo chiu tng dn lc axit l: A. HCOOH, CH3COOH, CH3CH2COOH. B. CH3CH2COOH, CH3COOH, HCOOH. C. CH3CH2COOH, HCOOH, CH3COOH. D. CH3COOH, CH3CH2COOH, HCOOH.
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