Bi tp chng I: Este Lipit.

Chng I: ESTE - LIPIT

Cu 1. Sp xp nhit si ca cc cht sau theo chiu tng dn: CH3CH2CH2COOH ; CH3[CH2]3CH2OH ; CH3COOC2H5 Cu 2. Nu vai tr ca axit H2SO4 trong phn ng este ha : Cu 3. Vit phng trnh phn ng trc tip iu ch este vinyl axetat: Cu 4. Th no l Este. Ly v d minh ha (ch r axit th u). Cu 5. ng vi CTPT C4H8O2 c bao nhiu este l ng phn ca nhau: A.2 B.3 C.4 D.5 Cu 6. ng vi CTPT C4H8O2 c bao nhiu ng phn phn ng vi NaOH: Cu 7. Cht X c CTPT C4H8O2 . Khi X tc dng vi NaOH sinh ra cht Y c cng thc C 2H3O2Na. Cng thc cu to v tn gi ca X l :.......................................... Cu 8. Thu phn este X c CTPT C4H8O2 trong dung dch NaOH thu c hn hp hai cht hu c Y v Z trong Z c t khi hi so vi H2 bng 23. Tn ca X l : A. etyl axetat B. metyl axetat C. metyl propionat D. propyl fomat Cu 9. t chy hon ton 7,4 gam este X n chc thu c 6,72 lt kh CO2 (ktc) v 5,4 gam nc. a) Xc nh cng thc phn t ca X. (/a:.) b) un 7,4 gam X trong dung dch NaOH va n khi phn ng hon ton thu c 3,2 gam ancol X v mt lng mui Z. Vit CTCT ca X v tnh khi lng ca Z.(/a: ;..). Cu 10. Trong cht bo lun c mt lng nh axit t do. S miligam KOH dng trung ho lng axit t do trong 1 gam cht bo gi l ch s axit ca cht bo. trung ho 2,8 gam cht bo cn 3,0 ml dung dch KOH 0,1M. Tnh ch s axit ca mu cht bo trn. Cu 11. Tng s miligam KOH trung ho ht lng axit t do v x phng ho ht lng este trong 1 gam cht bo gi l ch s x phng ho ca cht bo. Tnh ch s x phng ho ca mu cht bo c ch s axit bng 7 cha tristearoylglixerol cn ln mt lng axit stearic. Cu 12. Cn bao nhiu kg cht bo cha 89% khi lng tristearin (cn 11% tp cht tr b loi b trong qu trnh nu x phng) sn xut c 1 tn x phng cha 72% khi lng natri stearat. /a:.. Cu 13. Thu phn hon ton 8,8 gam este n chc, mch h X vi 100ml dung dch KOH 1M (va ) thu c 4,6 gam mt ancol Y. Tn gi ca X l:.. Cu 14. 10,4 gam hn hp X gm axit axetic v etyl axetat tc dng va vi 150 gam dung dch natrihiroxit 4%. Phn trm khi lng ca etyl axetat trong hn hp bng: A. 22% 1 B.42.3% C. 57,7% D. 88%.

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Bi tp chng I: Este Lipit.

Cu 15. Hp cht X n chc c cng thc n gin nht l CH 2O. X tc dng c vi dung dch NaOH nhng khng tc dng c vi natri. Cng thc cu to ca X l:. Cu 16. Thu phn Este E c CTPT C4H8O2 (c mt H2SO4 long) thu c hai sn phm hu c X v Y. T X c th iu ch trc tip ra Y bng mt phn ng duy nht. Tn gi ca E l:.. Cu 17. Thu phn hon ton hn hp gm hai este n chc X, Y l ng phn cu to ca nhau cn 100ml dung dch NaOH 1M, thu c 7,85 gam hn hp hai mui ca hai axit l ng ng k tip v 4,95 gam hai ancol bc I. CTCT v phn trm khi lng ca hai este l: Cu 18. Este n chc X c phn trm khi lng cc nguyn t C,H,O ln lt l 48,65%; 8,11%; 43,24%. a) Tm CTPT. b. un nng 3,7 gam X vi dung dch NaOH va n khi phn ng xy ra hon ton. T dung dch sau phn ng, thu c 4,1 g mui rn khan. Xc nh CTCT ca X. Cu 19. Cho 4,4g hn hp hai este X,Y l ng phn cu to ca nhau tc dng vi dung dch NaOH va n khi cc phn ng xy ra hon ton, thu c 4,45g cht rn khan v hn hp hai ancol l ng ng k tip. Xc nh CTCT ca X,Y. Bit t khi hi ca X so vi hiro bng 44. /a: Cu 20. Hn hp X gm axit axetic v ancol etylic. Chia X thnh ba phn bng nhau. - Phn 1: Tc dng vi Na d thy c 3,36 lt kh thot ra (ktc). - Phn 2: Phn ng va vi 200ml dung dch NaOH 1M. - Thm vo phn 3 mt lng H2SO4 lm xc tc ri thc hin phn ng este ho, hiu sut t 60%. Tnh khi lng ca hn hp X dng v khi lng este thu c. Cu 21. Trong cht bo lun c mt lng nh axit t do. S miligam KOH dng trung ho lng axit t do trong 1 gam cht bo gi l ch s axit ca cht bo. x phng ho 100kg cht bo c ch s axit bng 7 cn 14,1 kg kali hiroxit. Gi s cc phn ng xy ra hon ton, tnh khi lng mui thu c. /a: Cu 22. Cho cc pht biu sau: a) Cht bo thuc loi hp cht este. b) Cc este khng tan trong nc do chng nh hn nc. c) Cc este khng tan trong nc v ni trn mt nc do chng khng to c lin kt hiro vi nc v nh hn nc. d) Khi un cht bo lng trong ni hp ri sc dng kh hidro vo (c xc tc niken) th chng chuyn thnh cht bo rn.

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Bi tp chng I: Este Lipit.

e) Cht bo lng l cc triglixerit cha gc axit khng no trong phn t. Nhng pht biu ng l: A. a,d,e B.a,b,d C.a,c,d,e D.a,b,c,d,e Cu 23. x phng ho hon ton 19,4 g hn hp hai este n chc A v B cn 200ml dung dch NaOH 1,5M . Sau khi phn ng hon ton, c cn dung dch, thu c hn hp hai ancol ng ng k tip nhau v mt mui khan X duy nht. Tm CTCT, gi tn v tnh phn trm khi lng ca mi este c trong hn hp u. /a : Cu 24.Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l /a :.. Cu 25.Cho tt c cc ng phn n chc , mch h c cng cng thc phn t C 2H4O2 ln lt tc dng vi : Na, NaOH, NaHCO3 . S phn ng xy ra l A. 4 B. 3 C. 2 D. 5 Cu 26.Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C 17H35COOH v C15H31COOH, s loi trieste c to ra ti a l : A. 5 B. 4 C. 3 D. 6 Cu 27. X l mt este no n chc, c t khi hi i vi CH 4 l 5,5 . Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l A. HCOOCH(CH3)2. C. CH3COOC2H5 bo l: A.C15H31COOH v C17H35COOH C.C17H31COOH v C17H33COOH. B. C17H33COOH v C15H31COOH D.C17H33COOH v C17H35COOH B. C2H5COOCH3 D. HCOOCH2CH2CH3

Cu 28. Thu phn hon ton 444 gam mt lipit thu c 46g glixerol v hai loi axit bo. Hai loi axit

Cu 29. X phng ho 8,8 gam etyl axetat bng 200ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton c cn dung dch thu c cht rn khan c khi lng l: A. 8,56gam B. 3,28 gam C. 10,4 gam D. 8,2 gam Cu 30. Hn hp gm axit HCOOH v CH 3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l: A. 10,12 3 B. 6,48 C. 8,10 D. 16,20

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Bi tp chng I: Este Lipit.

Cu 31. Este X c c im sau: t chy hon ton X to thnh CO2 v H2O c s mol bng nhau. Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s

nguyn t cacbon bng mt na s nguyn t cacbon trong X). Pht biu khng ng l: A. Cht X thuc loi este no, n chc. B. t chy hon ton 1 mol X sinh ra sn phm gm 2mol CO2 v 2 mol H2O. C. Cht Y tan v hn trong nc. D. un Z vi dung dch H2SO4 c 170oC thu c anken. Cu 32. Cho s chuyn ho sau: C3H4O2 + NaOH X + X + Y

H2SO4 long Z + T

Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l : /a : Cu 33. Pht biu ng l : A. Phn ng thu phn este trong mi trng axit l phn ng thun nghch. B. Phn ng gia axit v ancol khi c H2SO4 c l phn ng mt chiu. C. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ancol. D. Khi thu phn cht bo lun thu c C2H4(OH)2. Cu 34. Hp cht hu c no, a chc X c cng thc phn t C 7H12O4. Cho 0,1 mol X tc dng va vi 100gam dung dch NaOH 8%, thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l:. Cu 35. X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l: A. 17,80gam Tn gi ca este l: A. metyl fomiat B. etyl axetat C. n-propyl axetat D. metyl axetat Cu 37. X phng ho hon ton 22,2 gam hn hp gm 2 este HCOOC 2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l: B. 18,24gam C. 16,68 gam D. 18,38gam Cu 36. t chy hon ton mt este no, n chc th s mol CO 2 sinh ra bng s mol O 2 phn ng.

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Bi tp chng I: Este Lipit.

A. 300ml B. 200ml C. 150 ml D. 400ml Cu 38. Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X 1 c kh nng phn ng vi : Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng vi Na. Cng thc cu to ca X1 v X2 ln lt l : ;.. Cu 39. Cht hu c X c cng thc phn t C 4H6O4 tc dng vi dung dch NaOH (un nng) theo phng trnh phn ng: C4H6O4 + 2 NaOH 2Z +Y oxi ho ht a mol Y th cn va 2a mol CuO (un nng), sau phn ng thu c a mol cht T (bit Y, Z, T l cc hp cht hu c). Khi lng phn t ca T l A. 44 vC B. 58 vC C. 82 vC D. 118vC Cu 40. Mt hn hp X gm hai cht hu c n chc. Cho X phn ng va vi 500ml KOH 1M. Sau phn ng, thu c hn hp Y gm hai mui ca hai axit cacboxylic v mt ancol. Cho ton b lng ancol thu c trn tc dng vi Na (d), sinh ra 3,36 lt H2 ( ktc). Hn hp X gm : A. Mt este v mt ancol. C. Mt axit v mt ancol B. Mt axit v mt este D. Hai este.

Cu 41. un nng 6,0gam CH3COOH vi 6,0 gam C2H5 OH (c H2SO4 lm xc tc, hiu sut phn ng este ha bng 50%). Khi lng este to thnh l : A. 6,0gam B. 4,4gam C. 8,8 gam D. 5,2 gam Cu 42. X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau . Cng thc ca hai este l: A.CH3COOCH3 v CH3COOC2H5 C. CH3COOC2H5v CH3COOC3H7 B. C2H5COOCH3 vC2H5COO C2H5 D. HCOOCH3 v HCOOC2H5.

Cu 43. X phng ho mt hp cht c CTPT C 10H14O6 trong dung dch NaOH d, thu c glixerol v hn hp gm 3 mui (khng c ng phn hnh hc). Cng thc ca 3 mui l: A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa. B. HCOONa, CHC-COONa v CH3-CH2-COONa C. CH2=CH-COONa, HCOONa v CHC-COONa D. CH3-COONa, HCOONa v CH3-CH=CH-COONa

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Bi tp chng I: Este Lipit.

Cu 44. X phng ho hon ton 66,6 gam hn hp hai este HCOOC 2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm 2 ancol. un nng hn hp X vi H 2SO4c 140oC, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l: A. 4,05. B.8,10. C. 18,00. D. 16,20. Cu 45. Vit cc ptp thc hin dy bin ho sau (cc cht vit di dng CTCT): C5H10O C5H10Br2O C5H9Br3 C5H12O3 C8H12O6. Cho bit cht ng vi CTPT C5H10O l mt ancol bc 3 mch h. Cu 46. a) T axit metacrylic (CH2=C(CH3)COOH) v ancol metylic, vit cc ptp iu ch polimetyl metacrylat. b) iu ch c 120kg polimetyl metacrylat cn bao nhiu kg ancol v axit tng ng? Bit hiu sut ca c qu trnh l 75%. Cu 47. Cht A c CTPT l C11H20O4. A tc dng vi NaOH to ra mui ca axit hu c B mch thng v hai ancol l etanol v propanol-2 Vit CTCT ca A, B v gi tn chng. Cu 48. un nng hai cht A v B c CTPT l C 5H8O2 trong dung dch NaOH c hn hp hai mui natri ca hai axit C3H6O2 (A1) v C3H4O2(B1) v hai sn phm khc. a) A, B thuc chc ho hc g ? Vit phng trnh phn ng. b) So snh s ging nhau v khc nhau v tnh cht ho hc ca A1 v B1. Cu 49. Hai este A v B l dn xut ca benzen c CTPT l C 9H8O2 ; A, B u cng hp vi brom theo t l mol 1 :1. A tc dng vi xt cho mt mui v mt anehit, B tc dng vi xt d cho hai mui v nc, cc mui c khi lng phn t ln hn khi lng phn t ca natri axetat. Xc nh CTCT ca A,B . Vit cc PTP. Cu 50. Cho hai cht A v B c CTPT l C4H7ClO2 . A + NaOH mui hu c (A1) + C2H5OH + NaCl B + NaOH mui hu c (B1) + C2H4(OH)2 + NaCl

a) Vit CTCT ca A v B. b) Vit PTP khi cho A1, B1 tc dng vi H2SO4. Cu 51. a) Lipit l g? b)V mt cu to, lipit lng v lipit rn khc nhau ch no ? Du m dng nu x phng v du m dng bi trn my c khc nhau khng ? Cu 52. C 4 cht ng vi CTPT C3H6O, C3H6O2 ,C3H4O,C3H4O2 c k hiu ngu nhin l A,B,C,D.

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Bi tp chng I: Este Lipit.

A, C c phn ng trng gng ; B, D phn ng c vi NaOH ; D phn ng vi H2 to thnh B ; oxi ho C thu c D. a) Vit CTCT ca A, B, C, D. b) Vit cc PTP khi cho : - A, B ln lt tc dng vi Cu(OH)2 nhit thng. - C, D ln lt tc dng vi CuO nhit thng. - D tc dng vi H2 c xc tc v un nng. - C tc dng vi O2 c xc tc. Cu 53. a)Trong cht bo khng tinh khit c ln mt lng nh axit hu c n chc t do. S miligam KOH cn trung ho cc axit t do c trong mt gam cht bo gi l ch s axit ca cht bo. Hy tnh khi lng NaOH cn trung ho axit t do c trong 5 gam cht bo vi ch s axit bng 7. b) x phng ho 10 kg cht bo c ch s axit bng 7, ngi ta un cht bo vi dung dch cha 1,420 kg NaOH. Sau khi phn ng hon ton, mun trung ho NaOH d cn 500ml HCl 1M . Tnh khi lng glixerol v khi lng x phng nguyn cht to ra. Cu 54. Mt s hp cht c cng thc l CxHyOz c M= 60vC. a) Vit CTCT cc hp cht v cho bit chng c phi l ng phn ca nhau khng ? b) Trong cc cht trn cht no tc dng c vi Na, NaOH? Cu 55: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l A. C2H4O2 v C5H10O2. C. C3H4O2 v C4H6O2. B. C2H4O2 v C3H6O2. D. C3H6O2 v C4H8O2.

Cu 56: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH) 2 (d) thy khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. CH3COOH v CH3COOC2H5. C. HCOOH v HCOOC2H5. B. C2H5COOH v C2H5COOCH3. D. HCOOH v HCOOC3H7.

Cu 57: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO 3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO 2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l

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Bi tp chng I: Este Lipit.

A. O=CH-CH2-CH2OH. C. CH3COOCH3. Cu 58: Pht biu no sau y sai? A. Sn phm ca phn ng x phng ha cht bo l axit bo v glixerol. B. Trong cng nghip c th chuyn ha cht bo lng thnh cht bo rn. C. S nguyn t hiro trong phn t este n v a chc lun l mt s chn. D. Nhit si ca este thp hn hn so vi ancol c cng phn t khi. Cu 59: S hp cht l ng phn cu to, c cng cng thc phn t C 4H8O2, tc dng c vi dung dch NaOH nhng khng tc dng c vi Na l A. 1. B. 2. C. 4. D. 3. Cu 60: Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l A. CH2=CH-CH2COOCH3. C. CH2=CHCOOC2H5. B. CH3COOCH=CHCH3. D. C2H5COOCH=CH2. B. HOOC-CHO. D. HCOOC2H5.

Cu 61: Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi dung dch cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng ht vi Na thu c 3,36 lt kh H2 ( ktc). Hai cht hu c l A. mt este v mt ancol. C. mt este v mt axit. B. hai este. D. hai axit.

Cu 62: Hai hp cht hu c X, Y c cng cng thc phn t C 3H6O2. C X v Y u tc dng vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v HCOOC2H5. C. HCOOC2H5 v HOCH2CH2CHO. B. HCOOC2H5 v HOCH2COCH3. D. C2H5COOH v CH3CH(OH)CHO.

Cu 63: un a gam hn hp 2 cht X v Y l ng phn cu to ca nhau vi 200 ml dung dch NaOH 1M (va ) n khi phn ng hon ton thu c 15 gam hn hp hai mui ca 2 axit n chc l ng ng k tip nhau v b gam mt ancol. Gi tr ca b l: A. 5 gam. B. 3,2 gam. C. 12 gam. D. 1,8 gam. Cu 64: Thy phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l A. HCOOH v C2H5COOH C. C2H5COOH v C3H7COOH. 8 B. HCOOH v CH3COOH. D. CH3COOH v C2H5COOH.

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Bi tp chng I: Este Lipit.

Cu 65: Cho s chuyn ha:
t , xt dich Br2 ,t 2 , xt C3 H 6 dung X NaOH Y CuO Z O T CH 3OH , E (Este a chc).
o o

Tn gi ca Y l A. propan-1,2-iol. B. propan-1,3-iol.
o o

C. glixerol.

D. propan-2-ol.

Cu 66: Cho s chuyn ha:

H 2 du ( Ni , t ) NaOH du , t HCl Triolein + X + Y + Z .

Tn ca Z l A. axit oleic. B. axit linoleic. C. axit stearic. D. axit panmitic. Cu 67: t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l A. 10,56. A.1. B. 7,20. B. 2. C.3. C. 8,88. D.4. D. 6,66. Cu 68: Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l Cu 69: Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nghuyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng este ha (hiu sut 80%) th s gam este thu c l A. 22,80. B. 34,20. C. 27,36. d. 18,24. Cu 70: Hp cht hu c mch h X c cng thc phn t C6H10O4. Thy phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l A. CH3OCO-CH2-COOC2H5. C. CH3OCO-COOC3H7. B. C2H5OCO-COOCH3. D. CH3OCO-CH2-CH2-COOC2H5.

Cu 71: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO 2 (ktc) v 11,7 gam H2O. S mol ca axit lioleic trong m gam hn hp X l A. 0,015. B. 0.010. C. 0.020. D. 0.005. Cu 72: Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (M X < MY). Bng mt phn ng c th chuyn ha X thnh Y. Cht Z khng th l A. metyl propionat. B. metyl axetat. C. etyl axetat. D. vinyl axetat.

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Bi tp chng I: Este Lipit.

Cu 73: Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C 5H10O2, phn ng c vi dung dch NaOH nhng khng phn ng trng bc l A. 4. B. 5. C. 8. D.9. Cu 74:Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy ng ng (MX<MY). t chy hon ton m gam Z cn dng 6,16 lt kh O 2 (ktc), thu c 5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l A. (HCOO)2C2H4 v 6,6. C. CH3COOCH3 v 6,7. v ancol etylic. Cht X l A. CH3COOCH2CH2Cl. C. CH3COOCH(Cl)CH3. B. CH3COOCH2CH3. D. ClCH2COOC2H5. B. HCOOCH3 v 6,7. D. HCOOC2H5 v 9,5.

Cu 75: Thy phn cht hu c X trong dung dch NaOH (d), un nng, thu c sn phm gm 2 mui

Cu 76:Cho 45 gam axit axetic phn ng vi 69 gam ancol etylic (xc tc H 2SO4 c), un nng, thu c 41,25 gam etyl axetat. Hiu sut ca phn ng este ha l: A. 31,25%. B. 40,00%. C. 62,50%. D. 50,00%.

Cu 77: x phng ha hon ton 52,8 gam hn hp hai este no, n chc, mch h l ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc. Cng thc ca hai este l A. C2H5COOC2H5 v C3H7COOCH3. C. HCOOC4H9 v CH3COOC3H7. B. C2H5COOCH3 v CH3COOC2H5. D. CH3COOC2H5 v HCOOC3H7.

Cu 78: phn ng ht vi mt lng hn hp gm hai cht hu c n chc X v Y (M X < MY) cn va 300 ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton thu c 24,6 gam mui ca mt axit hu c v m gam mt ancol. t chy hon ton lng ancol trn thu c 4,48 lt CO 2 (ktc) v 5,4 gam H2O. Cng thc ca Y l A. CH3COOCH3. C. CH2=CHCOOCH3. B. C2H5COOC2H5. D. CH3COOC2H5.

Cu 79: Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch NaOH 8%, sau khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt ancol. Cng thc ca X l A. CH3COOCH=CH2. C. C2H5COOCH3. B. CH3COOC2H5. D. CH2=CHCOOCH3.

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Bi tp chng I: Este Lipit.

Cu 80: Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH) 2 th vn thu c kt ta. Thu phn X bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn trm khi lng ca oxi trong X l A. 37,21%. B. 36,36%. C. 43,24%. D. 53,33%.

Cu 81: Hp cht hu c X c cng thc phn t l C 4H8O3. X c kh nng tham gia phn ng vi Na, vi dung dch NaOH v phn ng trng bc. Sn phm thy phn ca X trong mi trng kim c kh nng ho tan Cu(OH)2 to thnh dung dch mu xanh lam. Cng thc cu to ca X c th l A. CH3COOCH2CH2OH. C. HCOOCH2CH2CH2OH. Cu 82: Cng thc ca triolein l A. (CH3[CH2]14COO)3C3H5. C. (CH3[CH2]16COO)3C3H5 B. (CH3[CH2]7CH=CH[CH2]5COO)3C3H5. D. (CH3[CH2]7CH=CH[CH2]7COO)3C3H5. B. HCOOCH2CH(OH)CH3. D. CH3CH(OH)CH(OH)CHO.

Cu 83: Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tho mn cc tnh cht trn l A. 5. B. 2. C. 4. D. 6.

Cu 84: Pht biu no sau y ng? A. Trong phn ng este ha gia CH 3COOH vi CH3OH, H2O to nn t -OH trong nhm COOH ca axit v H trong nhm -OH ca ancol. B. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c mi thm ca chui chn. C. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ha hc, ch cn dng thuc th l nc brom. D. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng nghip thc phm, m phm. Cu 85: Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l A. 2. 11 B. 4. C. 5. D. 3.

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Bi tp chng I: Este Lipit.

Cu 86: Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l A. 31,45 gam. B. 31 gam. C. 32,36 gam. D. 30 gam.

Cu 87: Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l A. 75%. B. 72,08%. C. 27,92%. D. 25%.

Cu 88: Triolein khng tc dng vi cht (hoc dung dch) no sau y ? A. H2O (xc tc H2SO4 long, un nng). C. Dung dch NaOH (un nng). B. Cu(OH)2 ( iu kin thng). D. H2 (xc tc Ni, un nng).

Cu 89: Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 17,5. B. 14,5. C. 15,5. o-hiroxibenzoic) phn D. 16,5. ng vi anhirit axetic, thu c axit

Cu 90: Cho axit salixylic (axit

axetylsalixylic (o-CH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l A. 0,72. B. 0,24. C. 0,48. D. 0,96.

Cu 91: Cho cc pht biu sau: (a) Cht bo c gi chung l triglixerit hay triaxylglixerol. (b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c. (c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch. (d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5. S pht biu ng l A. 3. B. 2. C. 4. D. 1. Cu 92: t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO 2 v 0,4 mol H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l A. 4,08. B. 6,12. C. 8,16. D. 2,04. Cu 93: Cho s chuyn ha sau: (a) C3H4O2 + NaOH X + Y (b) X + H2SO4 (long) Z + T (c) Z + dung dch AgNO3/NH3 (d) E + Ag + NH4NO3 (d) Y + dung dch AgNO3/NH3 (d) F + Ag +NH4NO3 Cht E v cht F theo th t l A. (NH4)2CO3 v CH3COOH B. HCOONH4 v CH3COONH4

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Bi tp chng I: Este Lipit.

C. (NH4)2CO3 v CH3COONH4 D. HCOONH4 v CH3CHO Cu 94: Kh este no, n chc, mch h X bng LiAlH 4, thu c ancol duy nht Y. t chy hon ton Y thu c 0,2 mol CO2 v 0,3 mol H2O. t chy hon ton 0,1 mol X thu c tng khi lng CO 2 v H2O l : A. 24,8 gam B. 28,4 gam C. 16,8 gam D. 18,6 gam Cu 95: Este X l hp cht thm c cng thc phn t l C 9H10O2. Cho X tc dng vi dung dch NaOH, to ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l A. CH3COOCH2C6H5 B. HCOOC6H4C2H5 C. C6H5COOC2H5 D. C2H5COOC6H5 Cu 96: S trieste khi thy phn u thu c sn phm gm glixerol, axit CH 3COOH v axit C2H5COOH l : A. 9 B. 4 C. 6 D. 2 Cu 97: Thy phn este X mch h c cng thc phn t C 4H6O2, sn phm thu c c kh nng trng bc. S este X tha mn tnh cht trn l: A. 4 B. 3 C. 6 D. 5 Cu 98: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O2, thu c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (My < Mz). Cc th tch kh u o iu kin tiu chun. T l a : b l A. 2 : 3 B. 4 : 3 C. 3 : 2 D. 3 : 5

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