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CHNH THC MN THI: HA HC Thi gian lm bi: 180 pht (khng k thi gian giao ) Cu I (3,0 im): 1) Vit phng trnh ho hc ca cc phn ng xy ra khi cho a) Etylamin tc dng vi HNO2 nhit thng. b) Anilin tc dng vi hn hp HNO2 v HCl nhit 0 - 5oC. c) Triolein tc dng vi H2 (d) nhit cao v p sut cao c Ni xc tc. d) imetyl xeton tc dng vi HCN. 2) Vit phng trnh ho hc (Ghi r iu kin ca phn ng) CO2 (C6H10O5)n C12H22O11 C6H12O6 C2H5OH 3) Khi thu phn hon ton 1 mol pentapeptit X thu c 2 mol glyxin, 1 mol alanin, 1 mol valin, 1 mol tyrosin. Khi thu phn khng hon ton X thy trong hn hp sn phm c cc ipeptit GlyAla, Ala-Gly, tripeptit Tyr-Val-Gly. Cho X tc dng vi HNO 2 nhit thng khng thy gii phng kh N2. Xc nh (c lp lun) trnh t cc amino axit trong phn t X. Cu II (3,0 im): 1) C 6 l ho cht b mt nhn, trong mi l ng mt trong cc dung dch sau: NaCl, NaHCO 3, Na2CO3, NaHSO4, NaOH, BaCl2. Trnh by phng php ho hc nhn bit cc dung dch trn, ch c dng thm thuc th l qu tm, cc dng c cn thit c . Vit cc phng trnh ho hc xy ra. 2) Ho tan Al trong dung dch HNO 3 long, d c dung dch D v kh E khng mu, khng ho nu ngoi khng kh v c iu ch bng un nng dung dch bo ho NH 4NO2. Chia dung dch D lm 2 phn: - Nh t t dung dch NH3 n d vo phn th nht - Nh t t dung dch NaOH n d vo phn th hai, thy c kh thot ra. Vit phng trnh ho hc ca cc phn ng xy ra. 3) Hon thnh cc phng trnh ho hc theo s sau y: a) NaCl + H2SO4 c, nng b) KMnO4 + H2SO4 + HNO2 c) FeSO4 + KHSO4 + KMnO4 d) Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O Cu III: (3,0 im): 1) Hon thnh cc phng trnh ho hc theo s chuyn ho sau (Ghi r iu kin phn ng, cc cht vit dng cng thc cu to thu gn). C8H14O4 + NaOH X1 + X2 + H2O X1 + H2SO4 X3 + Na2SO4 X3 + X4 nilon-6,6 + H2O X2 + X3 X5 + H2O (t l s mol X2: s mol X3 = 2:1) 2) Cht X l mt amino axit c mch cacbon khng phn nhnh. Cho 0,02 mol X tc dng va vi 80 ml dung dch HCl 0,25M. Sau phn ng, em c cn dung dch thu c 3,67 gam mui khan. Mt khc, em trung ho 1,47 gam X vi mt lng va dung dch NaOH. C cn dung dch sau phn ng thu c 1,91 gam mui khan. Xc nh cng thc cu to ca X. (Gi thit cc phn ng xy ra hon ton).
Cu IV (3,0 im): 1) in phn Al2O3 nng chy vi in cc bng than ch, thu c m gam Al v V lt (ktc) hn hp A ch gm 2 kh CO2, CO. Gi thit ton b lng oxi sinh ra tham gia vo qu trnh oxi ho cacbon. a) Vit cc qu trnh oxi ho - kh xy ra ti mi in cc. b) Tm khong xc nh ca m theo gi tr V. c) Cho V = 1,12 lt (ktc). Tnh m. Bit t khi ca A so vi hiro bng 18,8. 2) t chy hon ton mt lng cht X l anehit c mch cacbon khng phn nhnh thu c 38,72 gam CO2 v 7,92 gam nc. Bit rng, c 1 th tch hi cht X phn ng ti a vi 3 th tch kh H2, sn phm thu c nu cho tc dng ht vi Na (d) s cho th tch kh H 2 sinh ra bng th tch hi X tham gia phn ng ban u. Cc th tch kh o cng iu kin nhit , p sut. a) Xc nh cng thc phn t, cng thc cu to ca X. b) Vit phng trnh ho hc xy ra khi cho X ln lt phn ng vi lng d dung dch AgNO3 trong NH3, nc Br2 d. Cu V (4,0 im): Cho 3,6 gam hn hp A gm Fe v Cu tc dng vi 200 ml dung dch AgNO 3. Sau khi cc phn ng xy ra hon ton, thu c dung dch B v 9,92 gam cht rn C. Cho ton b dung dch B tc dng vi dung dch NaOH d, phn ng xong, lc kt ta nung trong khng kh n khi lng khng i c 3,2 gam cht rn. 1) Tnh phn trm khi lng cc kim loi trong A. 2) Tnh nng mol ca dung dch AgNO3 ban u. 3) Cho ht 3,6 gam A vo 200 ml dung dch H 2SO4 0,5 M, sau khi phn ng hon ton cho tip m gam NaNO3 vo hn hp phn ng. Tnh gi tr m ti thiu thu c lng kh NO (sn phm kh duy nht) ln nht. Cu VI (4,0 im): Hn hp X gm 3 este ca cng mt axit hu c n chc v 3 ancol n chc trong c 2 ancol no l ng ng k tip nhau v mt ancol khng no mch h cha mt lin kt i. Cho hn hp X tc dng vi 250 ml dung dch NaOH 1M, un nng. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 20,8 gam cht rn khan. Ngng t ton b phn ancol bay hi, lm khan ri chia thnh 2 phn bng nhau: Phn 1: cho tc dng ht vi Na (d) thu c 1,12 lt kh H 2 (ktc) Phn 2: em t chy hon ton thu c 3,584 lt kh CO 2 (ktc) v 4,32 gam H2O. 1) Xc nh cng thc cu to thu gn ca axit. 2) Xc nh cng thc cu to thu gn ca cc ancol. 3) Vit cng thc cu to v gi tn 3 este. Cho: H = 1; C = 12; N = 14; O = 16; Na = 23; Al = 27; S = 32; Cl = 35,5; Ag = 108.