Trng THPT Khanh Hng Ten

Gv: Tran Quoc

Tiet 1 Tuan 1: ON TAP AU NAM I- MUC CH YEU CAU: 1. Kien thc : -On tap nhng noi dung c ban cua thuyet CTHH -ong phan, ac iem ve cau tao, tnh chat cua moi loai hirocacbon la nhng phan lien quan en lp 12 e chuan b tiep thu kien thc mi ve cac hp chat hu c co nhom chc. Trong tam Ba luan iem chnh cua thuyet CTHH Cac loai ong phan: mach cacbon; v tr noi oi, ba, nhom the va nhom chc; ong phan nhom chc va ong phan cis-trans cua HC va dan xuat cua chung. ac iem CT, tnh chat hoa hoc cua ba loai C xHy: no, khong no va thm. 2. Ky nang : Giai mot so bai tap ap dung kien thc. II- PHNG PHAP DAY HOC: am thoai, neu van e III- CHUAN B CUA THAY VA TRO: Chuan b cua GV : S o lien quan gia cau tao cac loai HC va tnh chat. Chuan b cua tro: On tap kien thc Hoa hu c 11. IV- TIEN TRNH TIET DAY: 1. On nh to chc : 2. Noi dung Hoat ong cua tro 0 I-NHNG IEM C BAN CUA THUYET CAU TAO HOA HOC: 1 HS trnh bay: 1. Trong phan t chat hu c, cac nguyen t lien ket vi nhau theo ung hoa tr va theo mot th t nhat nh. Th t lien ket o c goi la cau tao hoa hoc. S thay oi th t lien ket o se tao ra chat mi. 2. Trong phan t chat hu c, cacbon co hoa tr 4. Nhng ngt C co the ket hp khong nhng vi nhng cua nngto khac ma con ket hp trc tiep vi nhau tao thanh nhng mach C khac nhau (mach khong nhanh, co nhanh va mach vong). 3. Tnh chat cua cac chat phu thuoc vao thanh phan (ban chat va so lng C ) va cau tao hoa hoc ( th t lien ket C ). V vay, thuyet CTHH lam c s e nghien cu cac hp chat hu c: Hs: thao luan v du minh hoa: 1. VD : C 2H6O CH3CH2 OH CH3 OCH3 Ru etylic imetylete 2. IV IV IV VI VI VD : CH4 , CH3CH2OH , CHCH CH3CH2CH2CH3 , CH3CHCH3 , CH3 CH2CH2 Hoat ong cua thay I-NHNG IEM C BAN CUA THUYET CAU TAO HOA HOC: Hoat ong 1: Hoi: Hay neu noi dung c ban cua thuyet cau tao hoa hoc ?

Gv: Nhan xet, bo xung GV: hng dan hoc sinh lay v du minh hoa.

GV: Cho hs thay s thay oi: ban chat, so lng, th t ngt --- thay oi chat.

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CH2CH2 3. VD: Tnh chat phu thuoc vao: - Ban chat: CH4: Kh, de chay,CCl4: Long , khong chay -So lng nguyen t : C4H10:kh, C5H12 : long -Th t lien ket: CH3CH2OH: Long, khong tan. CH3OCH3: Kh, khong tan II- ONG ANG, ONG PHAN: 1. ong ang: ong ang: la hien tng cac chat co cau tao va tnh chat tng t nhau nhng ve thanh phan phan t khac nhau mot hay nhieu nhom: - CH 2 -. VD: Tm cong thc chung day ong ang cua ru etylic? Giai : Ta co: C2H5OH + xCH2 = C2+xH5+2xOH at : n =2+x. Do o: 6 + 2x = 2n + 2. Vay cong thc chung day ong ang ru etylic la: CnH2n+1OH Hay CnH2n+2O. 2. ong phan:2. ong phan : la hien tng cac chat co cung CTPT, nhng co cau tao khac nhau nen co tnh chat khac nhau. - Phan loai ong phan: a) ong phan cau tao: (3 loai) - ong phan mach cacbon: mach khong nhanh, mach co nhanh. - ong phan v tr: noi oi, ba, nhom the va nhom chc. - ong phan nhom chc: cac ong phan khac nhau ve nhom chc, tc la oi t nhom chc nay sang nhom chc khac. VD: Ankaien Ankin - Xicloanken Anken Xicloankan. b) ong phan hnh hoc : (cis trans): VD: Buten 2 H H H C H3 \ / \ / C=C C=C / \ / \ CH3 CH3 CH 3 H Cis Trans * ieu kien e co ong phan cis trans: a \ / C=C / \ b d Phng phap viet ong phan cua
Mach vong

Gv: Tran Quoc

Gv: Nhan xet, bo xung II- ONG ANG, ONG PHAN Hoat ong 2: Hoi: Em hay nhac lai nh ngha ong ang ? lay v du Gv: Nhan xet, bo xung

Hoi: Em hay nhac lai nh ngha ong phan ? co may loai phan, lay v du. VD: C4H10 co 2 ong phan: CH3CH2CH2CH3 Butan CH3CHCH3 iso-butan CH3 VD: icloetan C2H4Cl2 co 2p: CH2CH2 CH3CHCH3 Cl Cl CH 3 1,2-icloetan 1,1-icloetan VD: C3H6 co 2p CH2=CHCH3, propen CH2 / \ CH2 CH2

xiclopropan

ay la cac ong phan ma th t lien ket cua cac trong phan t hoan toan giong nhau, nhng s phan bo hay nhom nguyen t trong khong gian khac nhau. Neu 2 hay nhom nguyen t mot pha cua noi oi giong nhau No:lk n ta co
h dang cis, khac nhau ta co dang Khong no :Lk trans. oi ba Mach Ankan

e ab ed

CxHy

Anken,ankn, an kanien

Vong no :lk n Xiclo ankan

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Thm: Co nhan Benzen A ten

Trng THPT Khanh Hng Ten

mot chat : VD: Viet cac ong phan cua C4H10O Giai : + ong phan ru : OH (4p) CH3CH2CH2CH2OH CH3CHCH2 OH CH3 CH3CH2CH OH CH3 CH3 CH3C OH CH3 + ong phan ete : O (3p) CH3OCH2CH2CH3 CH3OCHCH3 CH3

Gv: Tran Quoc

GV: Trc het xac nh xem chat a cho thuoc loai chat g : no, khong no, co the cha nhng loai nhom chc nao ? * Th t viet: - ong phan mach cacbon - ong phan v tr. - ong phan nhom chc. - Cuoi cung xem trong so cac ong phan va viet, ong phan nao co ong phan cis-trans (hp chat cha noi oi). Hoat ong 3: GV: lp 11 cac em a nghien cu nhng hirocacbon nao? H:Tnh chat hoa hoc cua nhng hp chat hu c o?

CH3CH2OCH2CH3

III- CAU TAO VA TNH CHAT HOA HOC CUA CAC HIROCACBON : 1. ANKAN (PARAFIN): CnH2n+2 ( n 1) a) Cau tao: Mach C h, ch co lien ket n (lk ). b) Hoa tnh: - Phan ng the: Cl2, Br2. - Phan ng huy. - Phan ng tach H2. - Phan ng crackinh. 2. ANKEN (OLEFIN): CnH2n ( n 2) a) Cau tao: mach C h, co 1 lien ket oi ( 1 lk va 1 lk ). b) Hoa tnh: - Phan ng cong: H2, X2, HX, H2O - Phan ng trung hp. - Phan ng oxi hoa khong hoan toan : Lam mat mau dung dch thuoc tm. 3. ANKIN: CnH2n-2 (n 2) a) Cau tao : mach C h, co 1 lien ket ba ( 1lk va 2lk ). b) Hoa tnh: - Phan ng cong - Phan ng trung hp. ( nh hp va tam hp)

Chu y : Phan ng the cua Ankan co 3 cacbon tr len u tien the cacbon co bac cao nhat. Can lu y: phan ng cong anken khong oi xng vi tac nhan khong oi xng (HX, H2O) tuan theo qui tac Maccopnhicop: 3CH2=CH2 + 2KMnO4 + 4H2O CH2CH2 + 2MnO2 +2KOH OH OH Co kha nang tham gia phan ng cong hp 2 lan: VD : NH HCCH + Ag2O AgCCAg + H2O Bacaxetilua(vang) Chu y: qui luat the vong benzen
3

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Phan ng the bi ion kim loai. Phan ng oxi hoa: lam mat mau dung dch KMnO4. 4. AREN: CnH2n-6 (n 6) a) Cau tao: mach C vong, cha nhan benzen. b) Hoa tnh: - Phan ng the : Br2, HNO3. - Phan ng cong: H2, Cl2. 4). Cung co kien thc :( 3 phut ) On lai ky tnh chat hoa hoc cua cac hirocacbon. 5). Hng dan hoc nha : ( 1 phut) BAI TAP 1. Viet cac p co the co cua: a) C6H14 ; b) C5H10 c) C5H12O ; d) C4H11N e) C4H9Cl ; f) C4H8Cl2 Viet cac phng trnh phan ng theo s o sau: CH3CHO C 2H4 PE CH4 C 2H 2

Gv: Tran Quoc

CH2 = CH Cl PVC C6H6 666

CH3COOCH=CH2

Tiet: (tuan: ) Bai 6: ESTE I. Muc tieu bai hoc: 1. Kien thc: Hs biet: Khai niem, tnh chat cua este. Hs hieu: Nguyen nhan este khong tan trong nc va co nhiet o soi thap hn nhieu so vi cac axit ong phan. 2. K nang: Van dung kien thc ve lien ket hiro e giai thch nguyen nhan este khong tan trong nc va co nhiet o soi thap hn nhieu so vi cac axit ong phan. II. Chuan b: Gv : Dung cu th nghiem, hoa chat: Dau an, m ong vat, dd axit sunfuric, dd natri hiroxit, ong nghiem, en con,... Hs : On tap kien thc cu va chuan b bai mi. III. Hoat ong day hoc: 1. On nh: 2. Kiem tra bai cu: 3. Bai mi: Hoat ong thay tro Noi dung kien thc can at

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Hoat ong 1 GV: Cho hs viet ptp lan lt gia ancol etylic, ancol amylic vi axit axetic. HS: Viet ptp phan tch c che p i en phng trnh p este hoa tong quat GV: Hoi este c hnh thanh nh the nao? HS: Phan tich phan ng rut ra ket luan: Gv hd cach goi ten este. HS: Goi ten cac este sau ay: HCOOCH3 C2H3COO CH3 C2H5COOCH3 Hoat ong 2 HS: oc sgk phan tch cac thong tin GV: Lien he thc te. Hoat ong 3 GV: Thc hien th nghiem(sgk) HS: Quan sat hien tng TN, giai thch, viet ptp vi etyl axetat. Gv: Cho hs hieu c ban chat cua hai phan ng, tai sao lai co s khac biet o Gv hd hs hnh thanh pt phan ng thuy phan dang tong quat. Hoat ong 4 GV: Gii thieu pp /c este HS: Viet ptp dang tong quat /c este

Gv: Tran Quoc

I. KHAI NIEM, DANH PHAP CH3COOH + C2H5 OH H 2O ............................................................................... ................ RCO OH + H OR H 2O

H2SO4 ,to CH3COOC2H5 +

H2SO4 ,to

RCOOR +

Thay the nhom OH nhom COOH cua axit bang OR este. Ten goc R + ten goc axit co uoi at HCOOCH3 : Metyl focmiat C2H3COOCH3 : M etyl acrylat C2H5COOCH3 : Metyl propionat II. TNH CHAT VAT L SGK III. TNH CHAT HOA HOC 1. Phan ng thuy phan : RCOOR + H2O RCOOH + R OH Ban chat: Phan ng thuan nghch (hai chieu)

H2SO4, to

2. Phan ng xa phong hoa(mt baz) : RCOOR + NaOH to RCOONa + R OH Ban chat: P xay ra mot chieu III. IEU CHE + Phng phap chung: RCOOH H 2O + ROH H2SO4, to RCOOR +

+ /c Vinyl axetat HS: Viet ptp /c vinyl axetat HS: Tham khao sgk CH3COOH + HCCH CH3COOCH=CH2 IV. NG DUNG: SGK Hoat ong 5 GV:Hng dan hoc sinh lam bai tap HS: Bai tap ve nha Bai tap 1, 2, 5 Bai tap 3, 4,6 xt, t0

K duyet

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Gv: Tran Quoc

Tiet: (tuan: ) Bai 2 : LIPIT I. Muc ch yeu cau : + Cho h/s nam c ban chat cau tao cua chat beo. + T/c cua no phu thuoc vao so lng nhom chc trong pht. II. Chuan b: + Gv: Ly thuyet va ptp. + Hs: Chuan b bai theo yeu cau. III. Len lp: 1. On nh: 2. 3. Bai mi: Hoat ong thay tro Noi dung kien thc can at Hoat ong 1 I. KHAI NIEM : Gv gii thieu cho hs biet c khai SGK niem va cac loai lipit . Hs: oc sgk Gv: Cho hs biet ch nghien cu chat beo (triglixerit) II. CHAT BEO Hoat ong 2 1. Khai niem Gv gii thieu cho hs biet c khai Chat beo la trieste cua glixerol vi niem chat beo cac axit beo, goi chung la triglixerit Gv: T khai niem hng dan hs (triaxylglixerol). viet cong thc chat beo dang Cong thc cau tao chung: tong quat: CH2 COOR Hs: Viet chung cua chat beo. CH COOR CH2 COOR R, R, R la cac goc cua cac axit beo co the giong hoac khac nhau. Cac axit beo tieu bieu : Gv gii thieu cho hs biet c mot C17H35COOH : axit stearic so axit beo thng gap. C17H33COOH : axit oleic Hs: Viet cac chat beo tao ra t C15H31COOH : axit panmitic ,...... glixerol vi cac axit beo tren (th du 2. T/c vat l : sgk). Chat long ( dau thc vat ), chat ran ( m ong vat ), nhe hn nc, Hs: oc sgk khong tan trong nc, tan nhieu trong cac Gv: Cho hs hieu c m V (goc HC dm hu c, nhiet o soi thap ( v khong no) the ran t0 thng, dau TV (goc co lk Hyro ). HC ko no) the long t0 thng.

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Hoat ong 3 Gv: Y/c hs nhac lai t/chh cua este. Hs : Trnh bay Gv : Hoi chat beo cung la este, vay t/chh nh the nao ? HS: Giai thch, viet ptp vi tristearin (CH3 [CH2]16CHOO)3 C3H5 + 3H2O (CH3 [CH2]16CHOO)3 C3H5 + NaOH Hs: Cho biet ban chat cua hai phan ng, tai sao lai co s khac biet o? Gv gii thieu phan ng xa phong hoa. Gv hd hs hnh thanh pt phan ng thuy phan dang tong quat. Hs: Viet ptp vi triolein tristearin Hs : oc sgk

Gv: Tran Quoc

3. Tnh chat hoa hoc: a. Phan ng thuy phan trong moi trng axit: CH2 COOR CH COOR + 3H2O C3H5(OH)3 CH2 COOR baz) : CH2 COOR CH COOR + 3NaOH C3H5(OH)3 CH2 COOR
to

axit,t 0

RCOOH RCOOH + RCOOH

b. Phan ng xa phong hoa(mt RCOONa RCOONa +

RCOONa xa phong c. Cong hiro vao chat beo long (goc HC cha no): sgk 4. ng dung: Hoat ong 4

Cung co bai : Chat beo la g ? t cau tao cac em co nhan xet g ? Tnh chat hoa hoc ac trng cua chat beo la g , vet ptp Hs lam bai tap 1-3. Hng dan : Ve nha cac em lam cac bt 4 va soan bai mi .

K duyet

Tiet: ( tuan:) Bai 3: KHAI NIEM VE XA PHONG VA CHAT GIAT RA TONG HP I. Muc tieu: II. Chuan b: III. Cac hoat ong day hoc: 1. On nh: 2. Vao bai: Hoat ong thay tro

Kien thc can at

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Hoat ong 1 Hs: oc k/ n xa phong (sgk), lien he bai lipit cho v du minh hoa chat thanh phan chnh cua xa phong. Gv: Giup cho hs hieu c ban ve xa phong. Hs: oc k/ n xa phong(sgk), lien he bai lipit cho v du minh hoa chat thanh phan chnh cua xa phong.sgk Hs: oc ppsx xa phong (sgk), lien he bai lipit viet ptp thuy phan chat beo xa phong. Gv: Gii thieu ppsx xa phong hien nay Hs: Xem qui trnh va ptp sgk Hoat ong 2 Hs: oc k/ n chat tay ra tong hp (sgk), Gv: Giup hs hieu c xa phong khac chat tay ra ve thanh phan, nhng chung co cung muc ch s dung. Hs: oc ppsx chat tay ra tong hp (sgk), xem s o ieu che ptp sgk. Gv: Gii thieu mot so chat tay ra tong hp hien nay Hoat ong 3 Hs: oc sgk e hieu ro tac dung cua xa phong va chat tay ra tong hp, t o rut ra ng dung trong /s va sx. Gv: Giai thch minh hoa thc te. Hoat ong 4 Hs: Lam bai tap sgk trang 15 (1, 2, 3, 4, 5) Gv: Nhan xet, anh gia

Gv: Tran Quoc

I. XA PHONG: 1. Khai niem: Xa phong: hh RCOOM (R goc HC axit beo, M la: Na hoac K) + phu gia. V du thanh phan chnh thong thng: C17H35COONa C15H31COONa 2. Phng phap san xuat: (RCOO)C3H5 + 3 NaOH to 3 RCOONa + C3H5 (OH)3

II. CHAT GIAT RA TONG HP: 1. Khai niem: 2. Phng phap san xuat:

III. TAC DUNG CUA XA PHONG VA CHAT TAY RA TONG HP: SGK

Bai tap 1, 2, 3, 4, 5

Tiet: (tuan: ) Bai 4: Luyen tap ESTE VA CHAT BEO I.Muc tieu II. Chuan b III. Hoat ong day hoc: 1. On nh 2. Kiem tra bai cu: 3. Vao bai mi: Hoat ong thay tro Hoat ong 1 Hs: Nhac lai khai niem este, chat beo. Cong thc phan t. Hs: Nh lai tnh chat hoa hoc ac trng cua este, chat beo: thuy phan trong MT axit va trong MT baz (xa phong hoa), phan ng cong hiro vao goc HC cha no /v chat beo long. Kien thc can at I. KIEN THC CAN NH 1. Khai niem: 2. Tnh chat hoa hoc:

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Hoat ong 2 Gv: Hng dan cho hs mau so sanh Hs: So sanh trnh bay len bang phu Gv va hs: nhan xet bo xung Hs: Viet phng trnh phan ng bt 2 Hs: Trnh bay ptp bt 3, sau o chon phng an ung. Gv va hs: nhan xet bo xung Hoat ong 3 Gv: Hng dan cho hs phng phap giai bai tap Hs: Viet ptp, giai toan hoa hoc Gv va hs: nhan xet bo xung Gv: Hng dan cho hs phng phap giai bai tap Hs: Viet ptp, giai toan hoa hoc, sau o chon phng an ung Gv va hs: nhan xet bo xung Dan do: Bai tap ve nha: 5, 7 (sgk trang 18) Chuan b kien thc chng mi

Gv: Tran Quoc

Bai tap l thuyet: Bai tap 1: So sanh chat beo va este ve: Than phan ng.to, . cau tao phan t va t/c hh. Bai tap 2,3(sgk - trang 18)

Bai toan Bai tap4(sgk trang 18)

Bai tap 6, 8(sgk trang 18)

Tiet: (tuan: )

Chng 1: CACBOHIRAT Bai 1: Glucoz

I. MUC TIEU BAI HOC 1. Kien thc: Hs biet: - Cau truc phan t dang mach h cua glucoz. - Tnh chat cac nhom chc co trong phan t glucoz, van dung tnh chat cua cac nhom chc o e giai thch cac tnh chat hoa hoc cua glucoz. Hs hieu: - Phng phap /c, ng dung cua glucoz va fuctoz. 2. K nang: - Khai thac moi quan he: cau truc phan t va tnh chat hoa hoc - Ren luyen k nang quan sat, phan tch cac ket qua th nghiem. - Giai cac bai tap co lien quan en hp cha glucoz va fuctoz. II. CHUAN B: - Dung cu: kep go, ong nghiem, ua thuy tinh, en con, tha, ong nho giot, ong th nghiem nho. - Hoa chat: glucoz, cac dung dch: AgNO 3, NH3, CuSO4, NaOH. - Mo hnh, hnh ve, tranh anh lien quan en bai hoc. III. CAC HOAT ONG DAY HOC: 1. On nh: 2. Kiem tra bai cu: 3. Bai mi: Hoat ong cua thay va tro Hoat ong 1: GV: Cho hs quan sat mau glucoz va t nghien cu SGK. GV: Em hay cho biet nhng tnh chat vat l va trang thai thien nhien cua glucoz? Hs: Quan sat mau glucoz va nghien Noi dung kien thc can at I. TNH CHAT VAT L VA TRANG THAI THIEN NHIEN: Glucoz la chat ran ket tinh, khong mau , nong chay 1460C ( dang ) va 1500C ( dang ) de tan trong nc. Co v ngot, co trong hau het cac bo phan cua cay

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cu sgk t o rut ra nhan xet

Gv: Tran Quoc

( la, hoa, re).Co nhieu trong qua nho, mat ong... Trong mau ngi co mot lng nho glucoz, t le hau nh khong oi la 0,1% II. CAU TAO PHAN T:

Hoat ong 2: GV: Yeu cau hoc sinh nghien cu k sgk ?: Cho biet e xac nh c CTCT cua glucoz phai tien hanh cac th nghiem nao? Hs tham khao va i en ket luan. Hs: Tra li: - Glucoz co phan ng trang bac, vay trong phan t glucoz co nhom CHO. - Glucoz tac dung vi Cu(OH)2 cho dung dch mau xanh lam, vay trong phan t glucoz co nhieu nhom OH v tr ke nhau. - Glucoz tao este cha 5 goc axit vay trong phan t co 5 nhom OH . - Kh hoan toan phan t glucoz thu c n - hexan. Vay 6 nguyen t C cua phan t glucoz tao thanh mot mach khong phan nhanh. GV lu y hs: -Thc te glucoz ton tai 2 dang mach vong la va . Hoat ong 3: GV: Cho hs lam TN sgk HS: Nghien cu TN SGK , trnh bay TN, neu hien tng viet ptp Gv: Nhan xet, bo xung, lu y hs p xay ra nhiet o thng. Gv: cho hs hieu c trong phan t glucoz cha 5 nhom OH, cac nhom OH v tr lien ke. GV: Hs thao luan ket luan

5 nhom - OH Glucoz 1 nhom - CHO Hs ket luan: Phan t glucoz co CTCT dang mach h thu gon la: CH2OH-CHOH-CHOH-CHOH-CHOH-CHO

III. TNH CHAT HOA HOC: 1. Tnh chat cua ancol a chc (poliancol) a. Tac dung vi Cu(OH)2: 2C6H12O6 2 H 2O + Cu(OH)2 (C6H12O)2Cu +

b. Phan ng tao este:(sgk) Qua cac p hs ket luan: Glucoz la ancol a chc trong phan t co cha 5 nhom chc OH. 2 .Tnh chat cua nhom anehit: a. Oxi hoa glucoz:

Hoat ong 4: GV: Bieu dien th nghiem oxi hoa glucoz bang dd AgNO3 trong dung dch NH3 ( chu y ong nghiem phai sach va un CH2OH(CHOH)4CHO + 2AgNO3 + 3NH3 + H2O nhe hon hp phan ng ) to HS: Theo doi gv lam th nghiem, neu CH2OH(CHOH)4COONH4 + 3NH3NO3 + hien tng, giai thch va viet phng 2Ag trnh phan ng. GV: Bieu dien th nghiem oxi hoa glucoz bang Cu(OH)2 trong dung dch NaOH . CH2OH(CHOH)4 CHO + Cu(OH)2 + NaOH to HS: Theo doi gv lam th nghiem, neu CH2OH(CH2OH)4COONa + Cu2O + hien tng, giai thch va viet phng H 2O trnh phan ng. GV: yeu cau hoc sinh viet phng trnh hoa hoc cua phan ng kh glucoz bang hiro. b. Kh glucoz bang hiro: . Ni,to CH2OH(CHOH)4CHO + H2 CH2OH(CHOH)4CH2OH

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10

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GV: Hs thao luan ket luan

Gv: Tran Quoc

Sobitol Qua cac p hs ket luan: Phan t glucoz co cha nhom chc anehit CHO. 3. Phan ng len men: 2 C6H12O6 CO2
. enzim, 30-35 C

GV: yeu cau hoc sinh viet phng trnh hoa hoc len men glucoz.

2 C2H5OH

Hoat ong 5: GV: Cho hs oc sgk

IV. IEU CHE VA NG DUNG: 1. ieu che:(sgk) 2. ng dung: (sgk) V. ONG PHAN CUA GLUCOZ: LA FRUCTOZ: Ket luan : - Fructoz la polihiroxixeton - Co the ton tai dang vong 5 canh hoac 6 canh ( dang 5 canh co 2 ong phan va ) - Fuctoz co tnh chat tng t glucoz va co s chuyen hoa gia 2 dang ong phan trong mt baz:
- OH

HS: Hay nghien cu SGK cho biet ac iem cau tao cua ong phan quan trong nhat cua glucoz la fructoz. HS: Cho biet tnh chat vat l va trang thai t nhien cua fructoz. HS: cho biet cac tnh chat hoa hoc ac trng cua fructoz. Giai thch nguyen nhan gay ra cac tnh chat o.

Glucoz Hoat ong 6: Cung co & hng dan bai tap HS: Xem them t lieu ve glucoz va fructoz Bai tap: 1-6 (sgk-25)

Fructoz

Duyet

Tiet 4 (tuan:

) Bai 2:

SACCAROZ, TINH BOT VA

XENLULOZ
I. MUC TIEUCUA BAI HOC: 1. Kien thc: - Biet c tcvl, cau truc phan t cua tttn, saccaroz, tinh bot, xenluloz. - Hieu cac phan ng hoa hoc ac trng cua chung. - Biet c vai tro ng dung cua no 2. K nang: - Ren luyen cho hoc sinh phng phap t duy khoa hoc, t cau tao cua cac hp chat hu c phc tap ( d oan tnh chat hoa hoc cua chung). - Quan sat phan tch cac ket qua th nghiem. - Viet cau truc phan t cua tinh bot - Nhan biet tinh bot - Phan tch va nhan dang cau truc phan t cua xenluloz

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- Quan sat phan tch cac hien tng th nghiem, viet phng trnh hoa hoc. - Giai cac bai tap ve saccaroz va mantoz, tinh bot, xenluloz II. CHUAN B: - Hnh ve phong to cau tao dang vong saccaroz, mantoz. - S o san xuat ng saccaroz trong cong nghiep. - Dung cu: ong nghiem , dao, ong nho giot. - Hoa chat: Tinh bot, dung dch iot. - Cac hnh ve phong to ve cau truc phan t cua tinh bot va cac tranh anh co lien quan en bai hoc. III. TO CHC CAC HOAT ONG DAY HOC: 1. On nh trat t. 2. Kiem tra bai cu 3. Vao bai mi: Hoat ong 1 I. Tnh chat vat l va tttn Gv: Hs oc va so sanh tnh chat vat l va trang thai t nhien cua saccaroz, tinh bot, xenluloz ve: trang thai, mau sac, mui v, o tan trong nc. Hs: oc sgk tong hp so sanh rut ra ket luan. Gv: Phan tch bo xung. Saccaroz Tinh bot Xenluloz - Chat ran ket tinh, ko - Chat ran vo nh - Chat ran dang si, mau, ko mui, ngot, to nc hnh, mau trang , ko mui. mau trang , ko mui. Ko tan 185oC. Tan tot trong nc. Ch tan trong nc nong trong nc, dm hu c. - Co trong ma ng, --> ho tb. - Co trong si bong, cu cai ng, hoa thot - Co trong cac loai ngu than thc vat not. coc, Hoat ong 2 II. Cau truc phan t Gv: Hs oc va so sanh cau tao phan t cua saccaroz, tinh bot, xenluloz Hs: oc sgk tong hp, phan tch hnh cau tao, so sanh rut ra ket luan ac iem cau tao quan trong can nh: Saccaroz Disaccarit : Goc - glucoz va fructoz Ko co mot nhom CHO, co nhieu nhom OH CTPT C12H22O11 Tinh bot Polisaccarit (gom 2loai) Aamiloz : mach khong phan nhanh Amiloz peptin : mach phan nhanh. CTPT (C6H10O5 ) n Xenluloz Polisaccarit Gom cac mac xch glucozo Moi mac xch C6H10O5 co 3 nhomOH t do, CTPT (C6H10O5 )n hay[C6H7O2(OH)3]n

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Gv: Tran Quoc

Hoat ong 3 III. Tnh chat hoa hoc Gv: Hs oc va so sanh tnh chat hoa hoc: saccaroz, tinh bot, xenluloz . Hs: Thao luan viet ptp rut ra tchh cua cac chat. Gv: Lam TN th mau vi iot HS: Giai thch hien tng va viet phan ng hoa hoc. Saccaroz 1. Phan ng thuy phan: a. Thuy phan nh xuc tac axit: C12H22O11 H+ C6H12O6 + C6H12O6 Saccaroz Glucoz Fructoz b. Thuy phan nh enzim: enzim Saccaroz Tinh bot 1. Phan ng thuy phan: a. Thuy phan nh xuc tac axit: (C6H10O5)n + nH2O H+,to nC6H12O6 b. Thuy phan nh enzim: enzim Tinh bot Glucoz. Xenluloz 1. Phan ng thuy phan: a. Thuy phan nh xuc tac axit: (C6H10O5)n + nH2O H+,to nC6H12O6 b. Thuy phan nh enzim SGK 2. Phan ng este hoa:

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Glucoz. 2.. Phan ng cua ancol a chc: Phan ng vi Cu(OH)2: 2C12H22O11 + Cu(OH)2 (C12H21O11)2Cu + H2O 2. Phan ng mau vi iot: - Cho dd iot vao dd ho tinh bot dd mau xanh lam.

Gv: Tran Quoc

HNO3(xuc tac, H2SO4 , t0 ) (SGK)

Hoat ong 4 Hs oc sgk ng dung cua saccaroz, tinh bot, xenluloz . Hs: oc sgk san xuat saccaroz, xem tranh minh hoa sx t ma ng. Gv: Phan tch bo xung, cho hs thay c vai tro cac chat tren trong /s va sx. Saccaroz Tinh bot Xenluloz IV. ng dung va san IV. ng dung IV. ng dung xuat Hoat ong 5 Hng dan hs lam bai tapve nha Tiet: (tuan: ) Bai 5: LUYEN TAP CAU TAO VA TNH CHAT CUA MOT SO CACBOHIRAT TIEU BIEU. I. MUC TIEU CUA BAI HOC: 1. Kien thc: - Biet ac iem cau truc phan t cua cac hp chat cacbohirat tieu bieu - Hieu moi lien quan gia cau truc phan t va tnh chat hoa hoc cua cac hp chat cacbohirat tieu bieu. - Hieu moi lien he gia cac hp chat cacbohirat tren 2. K nang: - Lap bang tong ket chng. - Giai cac bai toan ve cac hp chat cacbohirat. II. CHUAN B: - HS lam bang tong ket ve chng cacbohirat theo mau thong nhat - HS chuan b cac bai tap SGK va SBT - GV chuan b bang tong ket. III. CAC HOAT ONG DAY HOC: 1. ON nh trat t 2. Kiem tra l thuyet can nh ( co the ket hp bai tap) 3. Vao bai mi:

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Hoat ong cua thay Hoat ong 1: GV: Chuan b bang on tap l thuyet theo SGK. GV: Goi 3 hs len bang HS th 1: Viet cong thc phan t cua monosaccarit va neu nhng ac iem cua hp chat nay. HS th 2: Viet cong thc phan t cua isaccarit va neu nhng ac iem cua hp chat nay. HS th 3: Viet cong thc phan t cua poli saccarit va neu nhng ac iem cua hp chat nay. GV: Sa cha cau truc phan t cua hoc sinh, ghi vao bang tong ket va neu nhng ac iem ve cau truc phan t hoc sinh can lu y. GV: Qua o cac em co ket luan g ve cau truc cua cac cacbohirat? HS: Len bang trnh bay cau tra li cua mnh Hoat ong 2: H: Em hay cho biet nhng hp chat cacbohirat nao tac dung c vi dd AgNO3/ NH3 , tai sao? H: Em hay cho biet nhng hp chat cacbohirat nao tac dung c vi CH3OH/HCl, tai sao? H: Em hay cho biet nhng hp chat cacbohirat nao co tnh chat cua ancol a chc. Phan ng nao ac trng nhat? H: Em hay cho biet nhng hp chat cacbohirat nao thuy phan trong moi trng H+ ? H: Em hay cho biet nhng hp chat cacbohirat nao co phan ng mau vi I2 ? GV: Qua o em co ket luan g ve tnh chat cua cac cacbohirat?

Gv: Tran Quoc

Hoat ong cua tro A. L THUYET CAN NH:

Ket luan: - Cac hp chat cacbohirat eu co cau truc phan t mach vong, nguyen nhan do s ket hp cua nhom OH vi nhom C =O cua chc anehit hoac xeton . - Glucozo, fructozo, mantozo co cha nhom OH hemiaxetal, hoac nhom OH hemixetal.

Ket luan: - Glucozo, fuctozo, mantozo con nhom OH hemiaxetal, hoac nhom OH hemixetal khi m vong tao ra chc anehit, do o: . Co phan ng vi dd AgNO3/ NH3 . Co phan ng vi H2 . Co phan ng vi CH3OH/HCl tao este. - Glucozo, fuctozo, mantozo, saccaroz, xenlulozo co phan ng hoa tan ket tua Cu(OH)2 do co nhieu nhom OH v tr lien ke nhau. - Cac isaccarit, polisaccarit: mantozo, saccaroz, xenlulozo, tinh bot eu b thuy phan trong moi trng axit tao ra san pham cuoi cung la glucozo.

- Tinh bot tac dung vi dd I2 cho mau xanh lam

B. BAI TAP CUNG CO: HS: Giai cac bai tap SGK va SBT HS: Giai bai tap bo sung

Hoat ong 3: GV: Hng dan hoc sinh giai mot so bai tap SGK va SBT GV: Cho bai tap bo sung i t cac hp chat cacbohirat tieu bieu glucozo, fuctozo, mantozo, saccaroz, xenlulozo va tinh bot hay neu s o tong hp ra etanol. Hoat ong 4: CUNG CO KIEN THC - Cac em ve nha hoan thanh cac bai tap con lai trong SGK va SBT

Hs: Thc hien

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- Cac em hoan thanh bang tong ket e dung lam dung cu hoc tap.

Gv: Tran Quoc

Tiet: (tuan: ) Bai 6: BAI THC HANH SO 1 MOT SO TNH CHAT CUA CACBOHIRAT I. MUC TIEU: - Cung co tnh chat ve mot so tnh chat hoa hoc cua glucozo, saccarozo, tinh bot. - Ren luyen k nang tien hanh th nghiem lng nho hoa chat trong ong nghiem. II. CHUAN B DUNG CU VA HOA CHAT:

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DUNG CU TH NGHIEM - ong nghiem - coc thuy tinh 100ml - cap ong nghiem go - en con - ong hut nho giot - tha xuc hoa chat - gia e ong nghiem 6 1 1 1 1 2 1 HOA -

Gv: Tran Quoc

CHAT TH NGHIEM dd NaOH 10% dd CuSO45% dd glucozo 1% H2SO410% NaHSO4 Tinh bot dd I2 0,05%

III. CAC HOAT ONG DAY HOC: 1. On nh trat t: 2. Chia lp ra lam 4 nhom nho theo to e tien hanh lam th nghiem. 3. Vao lam th nghiem: HOAT ONG CUA THAY Th nghiem 1: Phan ng cua glucozo vi Cu(OH)2 GV: lu y - Cac em co the dung ong nho giot e c lng hoa chat thc hien phan ng. - Cho vao ong nghiem 3 giot dd CuSO45% va 6 giot dd NaOH 10%. Lac nhe e co ket tua Cu(OH)2. Gan bo phan dd - Cho them vao ong nghiem 10 giot dd glucozo 1% lac nhe. - un nong dd en soi, e nguoi. Th nghiem 2: Phan ng thuy phan cua saccarozo: GV: lu y Co the dung ong nho giot e thc hien phan ng. - Nho 8 giot dd CuSO4 5% vao ong nghiem (1) cha 8 giot dd NaOH 10%. Lac eu e Cu(OH)2 lam th nghiem tiep. Gan bo phan dd. - Nho 8 giot dd saccarozo 1% vao ong nghiem 2 cha mot t Cu(OH)2 quan sat hien tng phan ng xay ra. un nong dd thu c. - Nho 3 giot dd H2SO4 10% vao ong nghiem 3 co cha 10 giot dd saccarozo va thc hien cac bc tiep theo nh SGK a viet. HOAT ONG CUA TRO Th nghiem 1: Phan ng cua glucozo vi Cu(OH)2 HS: Tien hanh th nghiem nh SGK HS: Quan sat hien tng - Tao dd xanh lam - Sau khi un nong tao ket tua o gach. HS: Giai thch hien tng, viet phng trnh hoa hoc.

Th nghiem 2: Phan ng thuy phan cua saccarozo: HS: Tien hanh th nghiem nh SGK HS: Quan sat hien tng xay ra va giai thch. - Khi un nong vi axit, saccarozo b thuy phan thanh glucozo va fructozo. Chung b oxihoa bi Cu(OH)2 va cho Cu2O ket tua mau o gach.

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Th nghiem 3: Phan ng cua HTB vi I2

Gv: Tran Quoc

Th nghiem 3: Phan ng cua HTB vi I2 - Nho vai giot dd iot 0,05% vao ong nghiem cha 2ml dd ho tinh bot 2% roi lac. Do cau tao ac biet, tinh bot hap thu iot cho san pham mau xanh lam. - un nong dd iot b thoat ra khoi phan t tinh bot lam mat mau xanh lam. - e nguoi, tinh bot lai hap thu iot, co mau xanh lam nh cu. HS: Tien hanh th nghiem nh SGK HS: Quan sat hien tng xay ra va giai thch.

Chu y: Saccarozo phai that la tinh khiet, khong con lan glucozo, fructozo va SO2 trong qua trnh san xuat.

GV: Hng dan hoc sinh lam tng trnh.

Tiet 9(tuan: ) BAI VIET SO 1 PHAN I: Trac nghiem khach quan (3 iem) Khoanh tron vao ch cai A hoac B,C,D ch phng an ung trong cac cau sau ay: Cau 1: Hay chon mot thuoc th trong so cac thuoc th sau ay e nhan biet cac dung dch : glucoz, anehit axetic, glixerol va propanol. A. Na kim loai B. Cu(OH)2 C. dung dch AgNO3 trong NH3 D. Nc brom Cau 2: Saccarozo co the tac dung c vi chat nao sau ay: (1) Cu(OH)2 ; (2) [Ag(NH3)2]OH ; (3) H2/Ni, t0C ; (4) CH3COOH( H2SO4 ac) A. (1), (2) ; B. (3), (4) ; C. (1), (4) ; D. (2), (3) ; Cau 3: Phan ng nao chng to glucozo co dang mach vong? A. Phan ng vi CH3OH/ HCl B. Phan ng vi Cu(OH)2. C. Phan ng vi [Ag(NH3)2]OH D. Phan ng vi H2/Ni, t0C Cau 4: Tinh bot va xenlulozo khac nhau cho: A. Phan ng thuy phan. B. Cau truc mach phan t. C. o tan trong nc . D. Thanh phan phan t. Hay chon cau ung. Cau 5:Hay chon phng an ung e phan biet Saccarozo, Tinh bot va Xelulozo dang bot: A. Hoa tan tng chat vao nc, sau o un nong va th vi dung dch iot B. Cho tng chat tac dung vi HNO3/ H2SO4 C. Cho tng chat tac dung vi dung dch iot D. Cho tng chat tac dung vi voi sa Ca(OH) 2 Cau 6: Hay chon ap an ung: Mot cacbohirat (A) co cac phan ng dien ra theo s o chuyen hoa sau: ( OH ) 2 / NaOH A t 0 ket tua o gach Cu dung dch xanh lam Vay A co the la : A. Tinh bot ; B. Glucozo ; C. Xenlulozo ; D. Tat ca eu sai II. T LUAN: ( 7 iem) Cau 1:Viet phng trnh phan ng theo s o sau: ( Chat hu c viet di dang cong thc cau tao thu gon, ghi ro ieu kien phan ng can thiet) Tinh bot C6H12O6 C2H6O C4H6 Cao su bu na C2 H 4

C2H6O2

C2H2O2

C2H2O4

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Gv: Tran Quoc

Cau 2:Viet phng trnh phan ng hoa hoc xay ra ( neu co) gia mantozo vi Cu(OH)2 ( nhiet o thng va un nong), vi dung dch AgNO 3 trong NH3 ( un nhe), va vi dung dch H2SO4 ( loang , un nhe) Cau 3: Len men 1 tan tinh bot cha 10% tap chat thanh ru etylic, hieu suat cua moi qua trnh len men la 85% a)Tnh khoi lng ru thu c. b) em pha loang ru o thanh ru 40 0, biet khoi lng rieng cua ru etylic la 0,8 gam /cm3.Hoi the tch dung dch ru thu c bang bao nhieu. Tiet 10 + 11 Chng II. AMIN AMINO AXIT PROTEIN Bai 7: AMIN

I. MUC TIEU BAI HOC: 1. Kien thc: - Biet cac loai amin, danh phap cua amin. - Hieu cau tao phan t, tnh chat, ng dung va ieu che cua amin. 2. K nang: - Nhan dang cac hp chat cua amin. - Goi ten theo danh phap IUPAC cac hp chat amin. - Viet chnh xac cac phng trnh phan ng hoa hoc cua amin. - Quan sat, phan tch cac th nghiem chng minh. II. CHUAN B: - Dung cu: ong nghiem, ua thuy tinh, ong nho giot. - Hoa chat: cac dd: CH3NH2, HCl, anilin, nc brom. - Mo hnh phan t anilin, cac tranh ve, hnh anh co lien quan en bai hoc. III. CAC HOAT ONG DAY HOC: 1. On nh trat t: 2. Kiem tra bai cu: 3. Vao bai mi. Hoat ong cua thay tro Hoat ong 1: GV: Viet CTCT cua NH3 va 4 amin khac . Hs: Nghien cu k cac chat trong v du tren va cho biet moi quan he gia cau tao amoniac va cac amin. Gv: nh hng cho hs sinh phan tch. Hs: T o hs hay cho biet nh ngha tong quat ve amin? HS: Tra li va ghi nhan nh ngha Kien thc can at I. NH NGHA , PHAN LOAI, DANH PHAP VA ONG PHAN: 1. Khai niem, phan loai:

Amin la hp chat hu c c tao ra khi thay the mot hoac nhieu nguyen t hiro trong phan t NH3 bang mot hoac nhieu goc hirocacbon. Amin c phan loai theo 2 cach: Theo goc hirocacbon: - Amin beo: CH3NH2, C2H5NH2 - Amin thm: C6H5NH2 Theo bac cua amin. - Bac 1: CH3NH2, C2H5NH2, C6H5NH2 - Bac 2: (CH3)2 NH - Bac 3: (CH3)3 N 2. Danh phap:

GV: Cac em hay nghien cu k SGK va t cac v du tren .Hay cho biet cach phan loai cac amin va cho v du? HS: Nghien cu va tra li, cho cac v du minh hoa.

GV: Cac em hay theo doi bang 2.1 SGK ( danh phap cac amin) t o cho biet: Qui luat goi ten cac amin theo danh

Cach goi ten theo danh phap Goc chc: Ankyl + amin

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phap goc chc. Qui luat goi ten theo danh phap thay the. GV: Nhan xet, bo xung . H: Tren c s tren, em hay goi ten cac amin sau: GV: Lay vai amin co mach phc tap e hoc sinh goi ten. Hoat ong 2: GV: Cac em hay nghien cu SGK phan tnh chat vat l cua amin va anilin. Hs: Cho biet cac tnh chat vat l ac trng cua amin va chat tieu bieu la anilin?

Gv: Tran Quoc

Thay the: Ankan + v tr + amin Ten thong thng ch ap dung cho mot so amin.

II. TNH CHAT VAT L: Metylamin, imetylamin, trimetylamin va etylamin la nhng chat kh co mui kho chu, oc , de tan trong nc, cac amin ong ang cao hn la chat long hoac ran, Anilin la chat long, nhiet o soi la 1840C, khong mau , rat oc,t tan trong nc, tan trong ru va benzen. III. CAU TAO VA TNH CHAT HOA HOC: 1. Cau tao phan t: Cac amin mach h eu co cap electron t do cua nguyen t nit trong nhom chc, do o chung co tnh baz. Nen amin mach h va anilin co kha nang phan ng c vi cac chat sau ay: 2. Tnh chat hoa hoc : a. Tnh baz:

Hoat ong 3: GV: Gii thieu biet CTCT cua vai amin . Hs: Hay phan tch ac iem cau tao cua amin mach h va anilin. GV: Bo sung va phan tch k e hoc sinh hieu k hn. Hs: T CTCT va nghien cu SGK em hay cho biet amin mach h va anilin co tnh chat hoa hoc g? GV: Chng minh TN 1 cho quan sat. Hs :, cho biet khi tac dung vi metylamin va anilin qu tm hoac phenolphtalein co hien tng g? V sao? Hs: Neu hien tng Gv: Giai thch hien tng GV: Bieu dien th nghiem gia C6H5NH2 vi dd HCl. Hs: Quan sat th nghiem va neu cac hien tng xay ra trong th nghiem tren va giai thch va viet phng trnh phan ng xay ra. Hs: So sanh tnh baz cua metylamin, amoniac va anilin. GV: Bo sung va giai thch . GV: Bieu dien th nghiem cua anilin vi nc brom: Hs: Quan sat va neu hien tng xay ra? Hs: Nghien cu va viet phng trnh phan ng. Hs: Giai thch tai sao nguyen t brom lai the vao 3 v tr 2,4,6 trong phan t anilin. HS: Do anh hng cua nhom NH2, nguyen t brom de dang thay the cac nguyen t H v tr 2,4,6 trong nhan thm cua phan t anilin. Hoat ong 4: Hs: Lam bai tap tai lp (sgk trang 44)

C6H5NH2 + HCl [C6H5NH3]+Cl

Tnh baz : CH3NH2 > NH3 >C6H5NH2 b. Phan ng the nhan thm cua anilin:

C6H5NH2 + tribromanilin

Br2

C6H2 Br 3NH2 2,4,6

Bai tap 1,2,3

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Hs: lam bai tap ve nha (sgk trang 44) Hs: Chuan b bai Amino axit Bai tap 4,5,6

Gv: Tran Quoc

Tiet 12 + 13. Bai 8: AMINO AXIT I. MUC TIEU CUA BAI HOC: 1. Kien thc: - Biet ng dung va vai tro cua amino axit. - Hieu cau truc phan t va tnh chat hoa hoc c ban cua amino axit. 2. K nang: - Nhan dang va goi ten cac amino axit. - Viet chnh xac cac phng trnh phan ng cua amino axit. - Quan sat va ciai thch cac th nghiem chng minh. II. CHUAN B: - Dung cu: ong nghiem, ong nho giot. - Hoa chat: dd glixin 10%, dd NaOH10%, CH 3COOH tinh khiet. - Cac hnh ve, tranh anh lien quan en bai hoc. III. CAC HOAT ONG DAY HOC: 1. On nh trat t: 2. Kiem tra bai ci. 3. Vao bai mi: Hoat ong cua thay tro Kien thc can at Hoat ong 1: I- NH NGHA: GV: Viet mot vai cong thc aminoaxit Aminoaxit la nhng HCHC tap chc thng gap sau o cho hoc sinh nhan va cha nhom chc amin (-NH2) va xet nhom chc. cha nhom chc cacboxyl (-COOH) Hs: Hay nh ngha aminoaxit (HSTB) Hoat ong 2: Hs: Tham khao sgk xem cac v du hieu c cach goi ten amino axit. II- CONG THC CAU TAO TEN GOI: VD: H2N-CH2-COOH Axit aminoaxetic (Glixin) H2N-CH-COOH Axit aminopropionic(Alamin) CH3 H2N-CH2-CH2-COOH Axit - aminopropionic HOCO-(CH2)2-CH-COOH GV: Phan tch cach oc ten sau o hnh thanh cac oc ten tong quat. Axit glutamic

NH2 Cach oc ten Axit + v tr nhom NH2 + amino + ten axit III- TNH CHAT VAT LY: Aminoaxit la nhng chat ran ket tinh, tan tot trong nc, co v ngot

Hoat ong 3: GV: Hay nghien cu SGK va cho biet tnh chat vat ly?

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Hoat ong 4: GV: Da vao cau tao aminoaxit hay cho biet cac aminoaxit tham gia phan ng hoa hoc nao? HS: Phan tch cau tao biet c aminoaxit va co tnh chat axit va co tnh baz (lng tnh). Hs: Hay viet phng trnh phan ng NH2CH2COOH + HCl ? NH2CH2COOH + NaOH ? Gv:Trong phan t Aminoaxit va cha nhom - NH2 va cha nhom -COOH vay gia cac phan t aminoaxit co the tac dung vi nhau c khong (HSTB) Viet dang tong quat ntn? Hs: Viet ptp (sgk) Hoat ong 5: HS: oc SGK va rut ra ng dung cua amino axit

Gv: Tran Quoc

IV- TNH CHAT HOA HOC: Aminoaxit va co tnh chat axit va co tnh baz (lng tnh) 1- Tnh baz: Tac dung axit manh HOOC-CH2-NH2 + HCl HOOC-CH2-NH3Cl 2- Tnh axit: Tac dung vi baz manh H2N-CH2COOH + NaOH H2N-CH2COONa + H2O) 3- Phan ng trung ngng: Khi un nong: Nhom - COOH cua phan t nay tac dung vi nhom -NH2 cua phan t kia cho san pham co khoi lng phan t ln, ong thi giai phong H 2O V- NG DUNG: SGK

4. CUNG CO: - T cong thc amino axit 1 nhom - NH 2, mot nhom -COOH, goc HC no hnh thanh cong thc TQ: CnH2n+1O2N - Viet phng trnh phan ng trung ngng: - Lam bai tap 1, 2, 4 5. HNG DAN HOC NHA: Bai tap 3, 5, 6 trang 71 (SGK)

Tiet 14 + 15 Bai 9: PEPTIT VA PROTEIN I. MUC TIEU BAI HOC: 1. Kien thc: - Biet khai niem ve peptit va protein, enzim va axit nucleicva vai tro cua chung trong cuoc song. - Biet cau truc phan t va tnh chat c ban cua protein. 2. K nang: - Goi ten peptit. - Phan biet cau truc bac 1 va cau truc bac 2cua protein. - Viet cac phng trnh hoa hoc cua protein. - Quan sat th nghiem chng minh. II. CHUAN B: - Dung cu: ong nghiem , ong hut hoa chat. - Hoa chat: dd CuSO4 2%, dd NaOH 30%, long trang trng. - Cac tranh anh , hnh ve phong to lien quan en bai hoc. III. CAC HOAT ONG DAY HOC: 1. On nh to chc. 2. Kiem tra bai cu. 3. Vao bai mi.

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Hoat ong cua thay tro Hoat ong 1: GV: Cac em hay nghien cu SGK va cho biet k/n cua peptit? HS: Nghien cu SGK va tra li GV: Lay v du ve mot mach peptit va yeu cau hoc sinh ch ra lien ket peptit cho biet nguyen nhan hnh thanh mach peptit tren? HS: Theo doi va tra li GV: Yeu cau cac em hoc sinh nghien cu SGK va cho biet cach phan loai peptit. HS: Nghien cu SGK va tra li: GV: Cac em hay nghien cu SGK va cho biet qui luat cua phan ng thuy phan cua peptit trong moi trng axit, baz hoac nh xuc tac enzim? HS: Khi un nong vi dung dch axit baz hay nh xuc tac cua enzim peptit b thuy phan thanh hon hp cac - aminoaxit. Hs: Viet phng trnh phan ng thuy phan mach peptit trong phan t protein co cha 3 amino axit khac nhau? Gv: Gii thieu phan ng mau cua peptit. Hoat ong 2 GV: Cac em hay nghien cu SGK cho biet nh ngha ve protein va phan loai. HS: oc SGK e nam c thong tin GV: Treo hnh ve phong to cau truc phan t protein cho HS quan sat, so sanh vi hnh ve trong SGK Hs: Nghien cu SGK cho biet cau tao phan t protein Hoat ong 3: GV: Cac em hay nghien cu SGK va cho biet nhng tnh chat ac trng cua protein? HS: oc SGK va suy ngh tra li Hs : Xem phan ng hoa hoc phan peptit Hs: oc sgk e hieu vai tra cua protein trong i song.

Gv: Tran Quoc

Kien thc can at I. PEPTIT 1. Khai niem: Peptit la loai chat cha t 2 en 50 goc - ainoaxit lien ket vi nhau bi cac lien ket peptit. Lien ket peptit: CONH

Tuy theo so lng n v amino axit chia ra: i peptit, tri peptit, . . . va poli peptit (tren 10 ). 2. Tnh chat hoa hoc: a. Phan ng thuy phan

b. Phan ng mau biure II. PROTEIN 1.Khai niem Protein la nhng polipeptit cao phan t co phan t khoi t vai chuc ngan en vai trieu vC. Protein c chia lam 2 loai: protein n gian va protein phc tap . 2. Cau tao phan t :

3. Tnh chat a. Tnh chat vat l b. Tnh chat hoa hoc 4. Vai tro cua protein /v i song

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Gv: Tran Quoc

Hoat ong 4: 1. Enzim: GV: Cac em hay nghien cu SGK va cho biet : - nh ngha ve enzim - Cac ac iem cua enzim.

HS: Nghien cu SGK va tra li.

2. Axit nucleic: GV: Cac em hay nghien cu SGK va cho biet ac iem chnh cua axit nucleic H: Cho biet s khac nhau cua phan t AND va ARN khi nghien cu SGK?

IV. Khai niem ve enzim va axit nucleic: 1. Enzim: Enzim la nhng chat hau het co ban chat protein, co kha nang xuc tac cho cac qua trnh hoa hoc, ac biet trong c the sinh vat. Xuc tac enzim co 2 ac iem : + Co tnh chon loc cao, moi enzim ch xuc tac cho mot s chuyen hoa nhat nh, + Toc o phan ng nh xuc tac enzim rat ln gap 109 1011 toc o phan ng nh xuc tac hoa hoc. 2. Axit nucleic: - Axit nucleic la polieste cua axit photphoric va pentoz ( monosaccarit co 5 C)moi pentoz lai co mot nhom the la mot baz nit. + Neu pentoz la riboz: tao axit ARN. + Neu pentoz la eoxiriboz: tao axit ADN. + Khoi lng ADN t 4 8 trieu vC, thng ton tai dang xoan kep. Khoi lng phan t ARD nho hn ADN, thng ton tai dang xoan n.

Hoat ong 7: Cung Co HS: Giai cac bai tap1,2,3, 4,5,6 - sgk trang 55

Tiet 16.(tuan :) Bai 10 : Luyen tap CAU TAO VA TNH CHAT CUA AMIN, AMINOAXIT, PROTEIN. I. MUC TIEU BAI HOC: 1. Kien thc: Nam c tong quat ve cau tao va tnh chat hoa hoc c ban cua amin, amino axit, protein. 2. K nang: - Lam bang tong ket ve cac hp chat trong chng. - Viet phng trnh phan ng dang tong quatcho cac hp chat: amin, amino axit.protein. - Giai cac bai tap ve phan amin,amino axit va protein. II. CHUAN B: - Sau khi ket thuc bai 9, GV yeu cau hoc sinh on tap toan bo chng va lam bang tong ket theo qui nh cua GV. - Chuan b them mot so bai tap cho hoc sinh e cung co kien thc trong chng. III. CAC HOAT ONG DAY HOC: 1. On nh to chc. 2. Kiem tra bai cu.

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3. Vao bai mi. Hoat ong cua thay Hoat ong 1: GV: Cac em a nghien cu va hoc l thuyet cua cac bai trong toan chng em hay cho biet: H: CTCT chung cua amin, amino axit va protein? H: Cho biet ac iem cau tao cua cac hp chat amin, amino axit, protein va ien vao bang sau? HS: Tra li va ghi vao bang Loai hp Amin Aminoaxit Protein chat Cau tao Tnh chat hoa hoc H: T bang tren va bang sgk hs rut ra nhan xet ve nhom ac trng va t/c hh cua cac chat.

Gv: Tran Quoc

Hoat ong cua tro I. KIEN THC CAN NH: 1. Nhom chc ac trng:

Nhan xet - Nhom chc ac trng cua amin la NH2 - Nhom chc ac trng cua amino axit la NH2, - COOH - Nhom chc ac trng cua protein la NH-CO2. Tnh chat: - Amin co tnh baz. - Amino axit co tnh chat cua nhom NH2(baz) va COOH(axit); tham gia phan ng trung ngng. - Protein co tnh chat cua nhom peptit CO- NH- ; tham gia phan ng thuy phan; co phan ng mau ac trng vi HNO3 ac va Cu(OH)2 Bai tap 1,2 sgk trang 58

GV: Cac em hay cho biet tnh chat hoa hoc ac trng cua amin, aminoaxit va protein? H: Em hay cho biet nguyen nhan gay ra phan ng hoa hoc cua cac hp chat amin, aminoaxit va protein? H: Em hay so sanh tnh chat hoa hoc cua amin va aminoaxit? H: Em hay cho biet nhng tnh chat giong nhau gia anilin va protein? Nguyen nhan cua s giong nhau ve tnh chat hoa hoc o? Hoat ong 2: Gv: Hs lam bai tap 1,2 Hs: Giai bai tap bang phng phap t luan, chon phng an ung khoanh tron. Gv va hs nhan xet bo xung Hoat ong 3: GV: Cac em hay thao luan nhom giai cac bai tap 3, 4,5 SGK GV: Goi 3 em hoc sinh ai dien 3 nhom len bang giai 3 bai tap tren. Gv va hs nhan xet bo xung Hoat ong 4 Hs: Chuan b kien thc chng polime

Bai tap3, 4,5 sgk trang 58

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Gv: Tran Quoc

Tiet 18 + 19 Chng 4: POLIME VA VAT LIEU POLIME Bai 12: AI CNG VE POLIME I. MUC TIEU CUA BAI HOC: 1. Kien thc - Biet c khai niem chung ve polime :nh ngha, phan loai, cau truc, tnh chat. - Hieu phan ng trung hp, trung ngng va nhan dang c polime e tong hp c polime. 2. K nang: - phan loai, goi ten cac polime. - So sang phan ng trung hp vi phan ng trung ngng, - Viet phng trnh phan ng tong hp ra cac polime. II. CHUAN B: - Nhng bang tong ket s o, hnh ve lien quan en tiet hoc. - He thong cau hoi cua bai. III. CAC HOAT ONG DAY HOC: 1. On nh trat t: 2. Kiem tra bai cu ( ket hp giang bai mi) 3. Vao bai mi HOAT ONG CUA THAY TRO Hoat ong 1: GV: Em hay tm hieu SGK va cho biet the nao la polime? Hs: oc sgk va cho mot vai v du ve polime GV: Cac em hay nghien cu SGK va cho biet cach phan loai polime? Hs: cho vd minh hoa ve polime nao thuoc polime thien nhien, polime tong hp, ban tong hp. KIEN THC CAN AT I- KHAI NIEM: Polime la nhng hp chat hu c co khoi lng phan t rat ln do nhieu v c so (goi la mach xch) lien ket vi nhau tao nen. Vd: PE, Tinh bot... Phan loai: Thien nhien Polime Tong hp( trung hp, trung ngng) Ban trung hp Hoat ong 2 II. AC IEM CAU TRUC: Dang mach thang : PE, PVC, xenluloz Dang phan nhanh: amilopectin cua tinh bot... Dang mang li khong gian: VD: Cao su lu hoa (cac mach thang trong cao su lu hoa gan vi nhau bi nhng cau noi isunfua SS). III. TNH CHAT VAT L - Cac polime la nhng chat ran, khong bay hi, t0nc co khoang kha rong. - a so polime khong tan trong cac dung moi thong thng. - Nhieu polime co tnh deo (PE, PVC) co tnh an hoi (cao su), cach nhiet, cach ien(PE, PVC..).

Hs: oc sach giao khoa trang 60, rut ra Cac polime thien nhien va tong hp co the co 3 dang cau truc c ban: kien thc quan trong ve ac iem
cau truc polime

Hs: oc sach giao khoa trang 61, rut ra kien thc quan trong ve l tnh polime.

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Hoat ong 3: Hs: Viet ptp the hien cac tnh chat hoa hoc cua polime Phan cat, gi nguyen va tang mach polime. Hs: Chon v du minh hoa.

Gv: Tran Quoc

IV.TNH CHAT HOA HOC: 1. Cac p phan cat mach polime : - Phan ng thuy phan: Tinh bot, xenluloz - P nhiet phan(giai trung hp) 2. Cac phan ng gi nguyen mach polime : o la phan ng the va cong vao mach polime. 3. Cac phan ng lam tang mach polime : phan ng khau mach cacbon. V- ieu che polime : 2pp. 1. Phan ng trung hp: Phan ng trung hp la qua trnh cong lien hp lien tiep nhieu phan t nho (monome) giong nhau hay tng t nhau thanh phan t ln (polime). VD: ,t , P nCH2=CH xt (CH2CH)n PVC Cl Cl 2. Phan ng trung ngng: Phan ng trung ngng la qua trnh cong hp lien tiep nhieu phan t nho thanh phan t ln ong thi tao ra nhng phan t nho (H2O0
0

Hoat ong 4: GV: Em hay cho biet phan ng nao co the ieu che c polime t monome? (Hs) HS: Nh vay, ieu kien ve cau tao monome tham gia phan ng trung hp la phai co noi oi. HS: Viet phng trnh phan ng

Gv: Gii thieu phan ng trung ngng hoac xay ra gia 2 loai monome co cau tao khac nhau, hoac t cung mot loai monome. Nh vay, ieu kien can ve cau tao monome tham gia phan ng trung ngng la phai co t 2 nhom chc tr len trong phan t . VI. NG DUNG (sgk) Hs: Viet ptp. Hs: oc sgk Hoat ong 5: Cung co kien thc: - Phng phap ieu che Polime - Hay cho biet cong thc cau tao cac polime : PE; PVC; PP; PVA. - Tnh chat cac polime? - Viet phan ng tao : Cao su Buna-S; Cao su Buna-N; Thuy tinh hu c. - Bai tap 1-6 sgk trang 64

Tiet 20 + 21. Bai 13: CAC VAT LIEU POLIME I. MUC TIEU BAI HOC: 1. Kien thc: - Biet khai niem ve cac vat lieu: chat deo, cao su, t, si va keo dan. - Biet thanh phan, tnh chat, ng dung cua chung. 2. K nang: - So sanh cac vat lieu. - Viet phng trnh phan ng hoa hoc tong hp ra cac vat lieu tren. - Giai cac vat bai tap ve vat lieu polime. II. CHUAN B: - Chuan b cac vat lieu polime: chat deo, cao su, t, si va keo dan. - Cac tranh anh , hnh ve, t lieu, lien quan en bai hoc. - He thong cau hoi cua bai. III. CAC HOAT ONG DAY HOC: 1. On nh trat t: 2. Kiem tra bai cu ( ket hp giang bai mi) 3. Vao bai mi

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4. Phan Tiet 1: Tiet 2: -

Gv: Tran Quoc

bo noi dung tiet hoc : Chat deo. T tong hp va t nhan tao. Cao su thien nhien va cao su tong hp. Keo dan. HOAT ONG CUA THAY TRO Hoat ong 1: GV: yeu cau: - HS nghien cu SGK cho biet nh ngha chat deo. - HS cho biet tnh deo la g? HS: Tm hieu SGK va cho biet thanh phan cua vat lieu mi(compozit) va nhng thanh phan phu them cua chung.

KIEN THC A- CHAT DEO: I- Kh niem ve chat deo va vat lieu compozit Chat deo la nhng vat lieu polime co tnh deo. Tnh deo la nhng vat the b bien dang khi chu tac dung nhiet o va ap suat va van gi nguyen s bien dang o khi thoi tac dung. VD: PE, PVC, Cao su buna ... Thanh phan compozit: 1- Chat nen (Polime): Nha nhiet deo hay nha nhiet ran. 2- Chat on: Si hoac bot 3- Chat phu gia II - Mot so hp chat polime dung lam chat deo: 1- Polietilen (PE) nCH2 = CH2 (-CH2 - CH2 -)n 2- Polivinylclorua (PVC) nCH2 = CH (-CH2 - CH -)n Cl Cl 3- Polimetyl meta crylat (Thuy tinh hu c) COOCH3 nCH2 = C - COOCH3 (-CH2-C-)n CH3 CH3 4- Nha phenol fomandehit: SGK 5- Polistiren: nCH = CH2 (-CH - CH2 -)n C6 H 5 C 6H 5 B- T : I. Khai niem: T la nhng polime hnh si dai va manh vi o ben nhat nh. II.Phan loai: 1- T t nhien: T tam, si, bong, len 2- T hoa hoc: ieu che t phan ng hoa hoc. a- T nhan tao: T vat lieu co san trong t nhien va che bien bang phng phap hoa hoc. VD: Xenluoz. b- T tong hp: T cac polime tong hp III-Vai loai t tong hp thng gap: Xem sgk trang 68-69

Hoat ong 2 Hs: Lien he kien thc a hoc xac nh cong thc cua cac polime sau: PE, PVC, thuy tinh hu c, PPF. Gv: T CT tren hs xac nh monome tao ra cac polime tren. Hs: Viet ptp ieu che Hs: Tham khao sgk e nam tnh chat, ng dung cua cac polime.

Hoat ong 3: GV : yeu cau - HS: Lay VD mot so vat lieu bang t

GV thong bao

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Gv: Tran Quoc

GV hng dan hoc sinh viet phng trnh phan ng

GV viet phan ng tao t nilon .6

C- CAO SU THIEN NHIEN VA CAO SU TONG HP: Hoat ong 3: I. nh ngha: GV: thong bao va lien he thc te Cao su la loai vat lieu polime co tnh an cho HS thay ro hoi II. Cao su thien nhien: Cao su thien nhien lay t mu cua cay cao su III. Cao su tong hp: D. KEO DAN: La loai vat lieu co kha nang ket dnh 2 manh vat lieu giong nhau hoac khac nhau ma khong lam bien chat cac vat lieu c ket dnh 4. CUNG CO: - Phan ng ieu che chat deo, ieu che cac loai t - T Xenluloz hay viet phng trnh phan ng ieu che nha PE, PP, PVC, - T CaCO3 va cac chat vo c can thiet ieu che nha phenolfomandehit. 6. RUT KINH NGHIEM: Ngay 20/11/2007 Tiet 22 Bai 14: LUYEN TAP CAU TRUC VA TNH CHAT CUA POLIME I. MUC TIEU CUA BAI HOC: 1. Kien thc: - cung co khai niem ve cau truc va tnh chat cua polime. 2. K nang: - so sanh cac loai vat lieu chat deo, cao su, t va keo dan. - Viet cac phng trnh hoa hoc tong hp ra cac vat lieu. - Giai cac bai tap ve cac hp chat cua polime II. CHUAN B: - Chuan b he thong cac cau hoi ve l thuyet. - Chon cac bai tap chuan b cho tiet luyen tap. III. CAC HOAT ONG DAY HOC: 1. On nh trat t: 2. Kiem tra bai cu: ( Ket hp vi day bai mi) 3. Vao bai mi: HOAT ONG CUA THAY Hoat ong 1: 1. Khai niem: GV: Yeu cau hoc sinh: - Hay neu nh ngha polime. Cac khai niem ve he so polime hoa. - Hay cho biet cach phan biet cac polime. - Hay cho biet cac loai phan ng tong hp polime. So sanh cac loai phan ng o? HOAT ONG CUA TRO 1. Khai niem: HS: Tra li - Polime la loai hp chat co khoi lng phan t ln do s ket hp cua nhieu n v nho( mac xch lien ket) tao nen. - Polime c phan thanh polime thien nhien, polime tong hp va polime nhan tao. - Hai loai phan ng tao ra polime la

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2. Cau truc phan t: GV: Em hay cho biet cac dang cau truc phan t cua polime, nhng ac iem cua dang cau truc o? Hoat ong 2: 3. Tnh chat : a. Tnh chat vat l: GV: Em hay cho biet tnh chat vat l ac trng cua polime? b. Tnh chat hoa hoc: HS: Cho biet cac loai phan ng cua polime, cho v du, cho biet ac iem cua cac loai phan ng nay?

Gv: Tran Quoc

phan ng trung hp va phan ng trung ngng 2. Cau truc phan t: HS: Tra li 3. Tnh chat : a. Tnh chat vat l: b. Tnh chat hoa hoc: HS: Polime co 3 loai phan ng: - Phan ng cat mach polime ( polime b giai trung). - Phan ng gi nguyen mach polime: phan ng cong vao lien ket oihoac thay the cac nhom chc ngoai mach - Phan ng tang mach polime: tao ra cac cau noi S- S- hoac CH2HS: Giai bai tap

Hoat ong 3: GV: Goi hs giai cac bai tap 1,2,5,6 (SGK) Hoat ong 4: Cung co va dan do. Cac em ve nha giai cac bai tap con lai trong SGK va SBT

Tiet 23. BAI VIET SO 2 PHAN I: Trac nghiem khach quan Khoanh tron vao ch cai A hoac B,C,D ch phng an ung trong cac cau sau ay: 1. Khi nho dung dch HNO3 ac vao long trang trng co hien tng: A.. Ket tua mau vang. C. Co mau tm ac trng B . Dung dch mau vang D. Co mau xanh lam. 2. Cong thc C3H9N co : A. Bon ong phan. B. Ba ong phan. C. hai ong phan. D. Nam ong phan. 3. Cho cac dung dch va cac chat long sau: glixerol, protein, glucoz, fomon, etanol. Dung thuoc th nao trong so cac thuoc th sau ay e nhan biet c cac chat tren A. Dung dch NaOH B. Dung dch HNO 3 C. Dung dch AgNO3/ NH3 D. Cu(OH)2/OH4. Cho cac chat: CH3NH2, NH3, C6H5NH2, (CH3 )2NH2. Tnh baz cua cac chat tang dan theo th t : A. NH3, CH3NH2, , (CH3 )2NH2 , C6H5NH2 . B. (CH3 )2NH2, CH3NH2, NH3, C6H5NH2. C. NH3, C6H5NH2, (CH3 )2NH2, CH3NH2. D. C6H5NH2, NH3 , CH3NH2, (CH3 )2NH2 . 5. Thuy phan tng phan mot penta peptit c ipeptit va tripeptit sau: AD BE CB DC DCB Hay xac nh trnh t cac amino axit trong pentapeptit tren: A. A D B E C B. A B C D E C. A D - C B E D. A D B- C E 6. Khi clo hoa PVC ta thu c mot loai t clorin cha 63,964% clo ve khoi lng. Hoi trung bnh mot phan t clo tac dung c vi bao nhieu mac xch PVC. Trong cac so di ay: 1. 1 B. 2 C. 3 D. 4

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Gv: Tran Quoc

7. T nilon - 6.6 E. Poli este cua axit ipic va etylen glicol. F. Hexa clo xiclo hexan. G. Poli amit cua axit ipic vi hexa metylen iamin H. Poliamit cua axit - amino Caproic 8. Cho phan ng : C6H5NO2 + . . . [H+] . . . C 6H5NH2 + . . .H2O ien cac he so e hoan thanh phng trnh hoa hoc tren. A. 1;6;1;2 B. 1;6;1;1 C. 1;4;1;2 D. 1;4;1;1 9. e Cho cac dung dch HCl, KOH, K2SO4, C2H5OH: axit amino axetic phan ng c vi nhng dung dch nao? Viet phng trnh phan ng xay ra va ghi ro ieu kien neu co. 10. T tinh bot va cac chat vo c can thiet khac. Hay viet s o va phng trnh phan ng ieu che ra: PE, axeton, cao subuna . 11. Cho 10,3 gam 1 amino axit no ( trong phan t ch cha mot nhom NH 2 va mot nhom COOH) tac dung vi dung dch HCl d ta thu c dung dch A trong o co cha 13,95 gam muoi. a. Xac nh CTPT cua amino axit. b. Tnh the tch dung dch NaOH 1M u tac dung vi dung dch A. Biet HCl a lay d 25% so vi lng can thiet. Ngay soan 28/11/2007 Tiet 24 + 25 Chng 4 AI CNG VE KIM LOAI Bai 15. KIM LOAI . HP KIM I. MUC TIEU CUA BAI HOC: 1. Kien thc: - Biet v tr cua cac nguyen to kim loai trong bang tuan hoan. - Hieu c nhng tnh chat vat l va tnh chat hoa hoc cua kim loai. 2. K nang: - Biet van dung l thuyet chu ao e giai thch nhng tnh chat cua kim loai. - Dan ra nhng phan ng hoa hoc va th nghiem hoa hoc chng minh cho nhng tnh chat hoa hoc. - Biet cach giai cac bai tap trong SGK. II. CHUAN B: - Chuan b mot so th nghiem chng minh cho tnh kh cua kim loai: + Dung cu: ong nghiem c nho, ong nho giot, en con. + Hoa chat: cac kim loai Al, Cu, Fe ( inh sat sach), Na, Mg, cac phi kim: kh O2, Cl2; cac axit: ddH2SO4 loang va H2SO4 ac, dung dch HNO3, dd muoi CuSO4. - Chuan b tranh ve 3 loai mang tinh the cua kim loai: mang tinh the lap phng tam khoi, mang lap phng tam dien va mang luc phng trong SGK hoa hoc 10. III. CAC HOAT ONG DAY HOC: 1. On nh trat t: 2. Kiem tra bai cu: 3. Vao bai mi: HOAT ONG CUA THAY TRO I. V TR , CAU TAO VA TNH CHAT CUA KIM LOAI: Hoat ong 1: GV: em hay da vao s phan bo cac electron vao nhng phan lp ben ngoai cua nguyen t th kim loai bao gom nhng nhom nguyen to nao? H: hay ch ra nhng v tr cua cac nhom nguyen to kim loai trong bang he thong tuan hoan. KIEN THC I. V TR , CAU TAO VA TNH CHAT CUA KIM LOAI:

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GV: cac em hay da vao bang HTTH e ch ra v tr cua cac nguyen to kim loai s, p, d, f .? GV: Ket luan Kim loai bao gom cac nguyen to s ( tr H) d, f va mot phan cua nguyen to p GV: Cac em hay cho biet nhng ac iem ve cau tao nguyen t kim loai, nhng kieu mang tinh the cua kim loai? Hoat ong 2: GV: Yeu cau hoc sinh nhac lai tnh chat vat ly cua kim loai a hoc lp 9 GV: bo sung: deo, dan ien, dan nhiet va anh kim. GV: Giai thch tnh deo cua kim loai do cac e t do. GV: Yeu cau hoc sinh kha giai thch v sao kim loai dan ien c. Gi y: Dong ien la g? - Do cac kim loai khac mat o e t do khac - Khi nhiet o tang cac Ion (+) dao ong ln can tr s chuyen ong cac e t do.

Gv: Tran Quoc

- Qua tnh chat vat ly chung cua kim loai hay cho biet yeu to nao gay ra tnh chat vat ly chung cua kim loai. - Khoi lng, o cng, nhiet o nong chay cua cac kim loai co giong nhau hay khong?

II. TNH CHAT VAT L CUA KIM LOAI: 1. Tnh deo: Khi tac dung mot lc u manh len mot vat bang KL no b bien dang. Nguyen nhan: Khi tac dung mot lc th cac mang tinh the trt len nhau, nhng nh cac e t do chuyen ong qua lai gia cac lp mang ma chung khong tach ri nhau. 2. Tnh dan ien: - Noi au KL vi 1 nguon ien th kim loai cho dong ien chay qua. Do cac e t do chuyen ong thanh dong. Lu y: + Cac KL khac nhau th chung dan ien khac nhau. + Khi nhiet o cang cao th kha nang dan ien cang giam. 3. Tnh dan nhiet: Khi KL b un nong cac e t do chuyen ong nhanh va cham vao cac Ion(+) va truyen nang lng cho cac Ion co nang lng thap hn. 4. Anh kim: Cac e t do co kha nang phan xa cac anh sang va bc song ma mat nhn thay c. Ket luan: Cac e t do la thanh phan c ban gay nen tnh chat vat ly chung cua kim loai. * Tnh chat vat ly rieng cua kim loai: 1- T khoi: Cac KL co ty khoi khac nhau (nang, nhe khac nhau) d<5 kim loai nhe. VD: K, Na, Mg, Al d>5 kim loai nang VD: Fe, Pb, Ag 2- o cng: Cac kim loai co o cng khac nhau Kim loai mem: Na, K Kim loai cng: Cr, W 3- Nhiet o nong chay: Cac kim loai co nhiet o nong chay khac nhau VD: t0nc W = 34100C t0nc Hg = -390C Nguyen nhan do: R va Z + khac III- TNH CHAT HOA HOC CHUNG CUA KIM LOAI: Kim loai de nhng e M - ne = Mn+ kim loai the hien tnh kh manh nen

Hoat ong 3: III- TNH CHAT HOA HOC CHUNG CUA KIM LOAI: Yeu cau hoc sinh nhan xet khi kim loai tac dung vi axit thong thng, sau

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o cho v du.

Gv: Tran Quoc

tac dung vi chat oxi hoa ((PK, dd axit, dd muoi) 1- Tac dung vi PK: (O2, Cl, S, P ...) a- Vi oxi oxit KL 4M + nO2 2M2On VD: 2Al + 3/2 O2 = Al2O3 Tac dung vi phi kim khac Muoi khong co Oxy Cu + Cl2 = CuCl2 2Fe + 3Cl2 = 2FeCl3 2- Tac dung vi axit: Axit thong thng: HCl, H2SO4 KL HCl muoi + H2 H2SO4 K: KL ng trc Hidro - Trong muoi KL co mc oxi hoa thap VD: Fe + 2HCl = FeCl2 + H2 Fe + H2SO4l = FeSO4 + H2 b- Vi axit co tnh oxh manh HNO3, H2SO4 SO2 M + H2SO4 M2(SO4)n + S + H 2O H 2S NO M + HNO3 M(NO3)n + Lu y: Tr Au, pt NO2 N2O + H2O N2 NH4NO3

Phan nay giao vien yeu cau hoc sinh cho biet san pham tao thanh khi kim loai tac dung tng loai axit nay.

- Giao vien lu y cho hoc sinh Vay e chuyen ch axit ac t nha may san xuat en ni tieu thu ngi ta dung bnh g e ng.

Giao vien bieu dien TN: Fe + dd CuSO 4 cho hoc sinh quan sat va nhan xet hien tng - Viet phng trnh phan ng va giai thch.

- Kim loai trong muoi co mc oxh cao nhat - Fe, Al, Cu khong tac dung HNO3, H2SO4 ac nguoi - HNO3 ac NO2 VD: Fe + 4HNO3 Fe(NO3)3 + NO + 2H2O 3- Tac dung vi dung dch muoi: a- TN: Cho Fe + dd CuSO4 Hien tng: Cu co mau o bam vao Fe Dung dch co mau xanh luc PTPU: Fe + CuSO4 = FeSO4 + Cu Fe + Cu2+ = Fe2+ + Cu b- TN: Cu + dd AgNO3 Hien tng: Ag tao thanh bam vao Cu Dd co mau xanh tham PTPU: 2AgNO3 + Cu = Cu(NO3)2 + 2Ag 2Ag+ + Cu = Cu2+ + 2Ag Nhan xet: Kim loai ng trc co the ay kim loai ng sau ra khoi dung dch muoi cua no. Lu y: Tr kim loai tac dung c vi nc nh: Na; K; Ca; Ba

Hoat ong 6 : Cung co tiet 1

CHNG 5:

AI CNG VE KIM LOAI

32

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Gv: Tran Quoc

Bai 1: V TR CUA KIM LOAI TRONG HTTH

CAU TAO CUA KIM LOAI

I. Muc tieu:

+ Nam c nhng kien thc ve cau tao cua kim loai.

+ Nhn vao bang HTTH, hs co the biet c v tr cua kl. II. Chuan b: + Gv: B.HTTH + Hs: HTTH. III. Tien trnh len lp: 1. On nh: 2. Kiem tra bai cu: 3. Bai mi: Hoat ong cua thay va tro Noi dung kien thc Hoat ong 1 I. V TR CUA KIM LOAI TRONG BANG Gv: Cho hs xem bang ht tuan hoan TH: phong to hng dan hs xac nh kl. Hs: Xac nh v tr cua ng.to kim loai IA, IIA, mot phan PNC IIIA trong BTH VIA. Gv va hs: Nhan xet Kim loai: IB VIIIB, Ho lantan va ho actini Hoat ong 2 Gv: Hs viet cau hinh e cua: Na(z=11), Mg(z=12), Al(z=13). Hs: Viet cau hinh e. Xac nh ac iem e ngoai cung Gv va hs: Nhan xet Hoat ong 3 Gv: Gii thieu mo hnh cac loai mang tinh the tng ng vi cac kim loai. Hs: Tham khao sgk Gv: Gii lien ket kim loai Hs: oc nh ngha sgk II. CAU TAO CUA KIM LOAI: 1. Cau tao nguyen t: + Co t e lp ngoai cung. + Trong cung 1 chu k co ban knh ngt ln, ien tch hat nhan nho hn cac ngt phi kim. 2. Cau tao tinh the: SGK 3. Lien ket kim loai: La lien ket c hnh thanh gia cac ng.t va ion kim loai trong mang tinh the do s tham gia cua cac e t do. Bai tap: 1-3 trang 82 sgk. Bai tap: 4-6 trang 82 sgk.

Hoat ong 4: Cung co Hs: Trnh bay bai tap: 1-3 trang 82 sgk. Hs: Giai t luan roi khoanh tron phng an ung cac bai tap 4-6 sgk trang 82.

K duyet

Tuan: 18 Tiet : 35 Bai 2: TNH CHAT VAT L CUA KIM LOAI I. Muc tieu:

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Gv: Tran Quoc

+ Hs biet van dung nhng kien thc ve cau tao cua kl e giai thch nguyen nhan cua nhng t/c vat l chung cua kl. + /vi nhng t/c vat l khac cua kl, hs biet c nhng t/c nay khong h phu thuoc vao cac e t do trong kl, ma con phu thuoc vao ban knh, ien tch, khoi lng cua kl va kieu mang tinh the cua kl. II. Chuan b: + Gv: He thong cau hoi + Hs: Xem bai trc nha III. Tien trnh len lp: 1. On nh: 2. Kiem tra bai cu: V tr cua kl trong HTTH, lk kl, ac iem cau tao ? 3. Bai mi: Hoat ong cua thay Noi dung va tro I. Nhng t/c vat l chung cua kl: 1. Tnh deo: The nao la tnh deo ? Khi td 1 lc c hoc u manh len kl, no b Cho vd. bien dang. Ng/nhan: Do cac lp mang tinh the kl b trt len nhau nhng khong tach ri nhau, ma van lk vi nhau nh cac e t do luon luon chuyen ong qua lai gia cac lp Tnh dan ien la g ? mang tinh the. Cho vd va cho biet 2. Tnh dan ien: nhng ng dung cu Noi kl vi 1 nguon ien, cac e t do the cua no trong i trong kl chuyen ong hanh dong, to cua kl song va SX ? cang cao tnh dan ien cua kl cang giam. Do to cao toc o dao ong cua cac ion dng kl cang ln, s chuyen ong cua dong e t do Tnh dan nhiet la g ? cang b can tr: Ag, Cu, Au, Al, Fe,... ng dung cua chung. 3. Tnh dan nhiet: un nong1 au day kl, nhng e t do Theo em nhng kl nao ay chuyen ong nhanh hn. Trong qua trnh co tnh dan ien tot ? chuyen ong, nhng e nay truyen nang V sao. lng cho cac ion dng vung co t o thap hn, v vay kl dan nhiet c. Tinh dan nhiet cua kl t le thuan vi tnh Anh kim la g ? Cho vd. dan ien: Ag, Cu, Al, Zn, Fe,... 4. Anh kim: V sao kl co nhng t/c Hau het cac kl eu co anh kim, v cac vat l chung nh tren ? kl t do trong kl a phan xa tot nhng tia Hay neu nhng t/c sang co bc song ma mat ta co the nhn vat l khac cua kl ? thay. Tom lai: Nhng t/c vat l chung cua kl noi tren la do cac e t do trong kl gay ra. II. Nhng t/c vat l chung khac cua kl: T khoi, to nong chay, tnh cng,... 4. Cung co: Nam t/c vat l chung va giai thch c. 5. Bai tap: 4 tr 87 sgk.

Tuan: 18 Tiet : 36 Bai 3: TNH CHAT HOA HOC CHUNG

CUA KIM LOAI

I. Muc tieu: Nam ac iem chung ve cau tao cua ngt kim loai, t o suy ra t/c hoa hoc chung. II. Chuan b:

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Gv: Tran Quoc

+ Gv: L thuyet va pt p. + Hs: Hoa tr cua ngto va pt p. III. Len lp: 1. On nh: 2. Kiem tra bai cu: Neu t/c vat l chung cua kim loai ? Giai thch. 3. Bai mi: Hoat ong cua thay Noi dung va tro I. ac iem ve cau tao cua ngt kim loai: + Ban knh ngt tng oi ln so vi ngt Hd cho hs neu, chu y phi kim. so sanh ve so e ngoai + So e hoa tr thng t (t 1 en 3e), lc cung, lc lk vi hat lk vi hat nhan cua nhng ion nay tng oi nhan ? yeu. Nang lng can dung e tach cac e ra khoi ngt kl (nang lng ion hoa) la nho. Goi hs viet s o tong II. T/c hoa hoc chung cua kim loai: quat va nhan xet ? La tnh kh (hay tnh de b oxi hoa): Mo ne Mn+ (n = 1, 2, 3) 1. Td vi phi kim (O2, Cl2, S): Goi hs viet ay u 4Al + 3O2 4Al2O3 cac pt p ? Cu + Cl2 CuCl2 Fe + S FeS 2. Td vi axit: Cho hs viet pt p va a. Dd Hcl, H2SO4 loang: Kh H+ H2 nhan xet ve s thay Zn + 2HCl ZnCl2 + H2 oi so oxi hoa ? Hay: Zno + 2H+ Zn2+ + H2 b. Dd HNO3; H2SO4 ac (tr Au, Pt): Kh N+5, S+6 xuong mc oxi hoa thap hn. Cu + 4HNO3 Cu(NO3)2 + NO2 + H2O Goi hs viet pt p ? 3. Td vi dd muoi: Cu + 2AgNO3 Cu(NO3)2 + 2Ag Hay: Cuo + 2Ag+ Cu2+ + 2Ag 4. Cung co: Nam c t/c hoa hoc chung. 5. Bai tap: 3, 4, 5 tr 90 sgk. Ngay . K duyet

Tuan: 18 Tiet : 37

Bai 4: DAY IEN HOA CUA KIM LOAI

I. Muc tieu: + Hieu c s cua s thanh lap day ien hoa cua kl. + Nam trnh t cac cap oxi hoa kh trong day. + Hs nam c chieu cua p hh gia cac cap oxi hoa kh. II. Chuan b: + Gv: He thong cau hoi + Hs: Xem bai trc nha. III. Tien trnh len lp: 1. On nh: 2. Kiem tra bai cu: T/c hh chung cua kl la g ? Viet cac pt p c/minh.

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3. Bai mi: Hoat ong cua thay va tro Noi dung

Gv: Tran Quoc

Goi hs viet cac pt cho e va cho biet chat kh, chat oxi hoa ?

Hd cho hs viet pt p va rut ra ket luan ? Cho hs thc hien tng t nh tren ? T 2 trng hp tren, hay rut ra ket luan chung ? Hd cho hs neu /n. Goi hs neu laiday hoat ong hoa hoc cua kl ? Goi hs viet cac pt p c/minh ? Trnh bay qui tac

I. Cap oxi hoa kh cua kl: Fe2+ + 2e Fe + Ag + e Ag Chat oxi hoa Chat kh Fe2+/ Fe ; Ag+/ Ag; ... tao nen cap oxi hoa kh. II. So sanh t/c nhng cap oxi hoa kh: 1. Fe2+/ Fe va Cu2+/ Cu: Fe + Cu2+ Fe2+ + Cu Fe2+: la ion co t/c oxi hoa yeu hn ion 2+ Cu Fe : la kl co t/c kh manh hn Cu. 2. Cap Cu2+/ Cu va Ag+/ Ag: Cu + 2Ag+ Cu2+ + 2Ag Cu2+la ion co t/c oxi hoa yeu hn ion Ag +. Cu la kl co t/c kh manh hn Ag. Kl: T/c oxi hoa cua ion: Fe2+ < Cu2+ < Ag+ T/c kh cua kl: Fe > Cu > Ag 3. Mot so cap oxi hoa kh khac: Sgk. III. Day ien hoa cua kim loai: 1. /n: La 1 day nhng cap oxi hoa kh c sap xep theo chieu tang t/c oxi hoa cua cac ion kl va chieu giam t/c kh cua kl. K+ Na+ Mg2+Al3+Zn2+ Fe2+ Ni2+Sn2+ Pb2+2H+ Cu2+ Hg2+Ag+ Pt2+Au3+ K Na Mg Al Zn Fe Ni Sn Pb H 2 Cu Hg Ag Pt Au T/c oxi hoa cua ion kl tang. T/c kh

cua kl giam

2. Y ngha: D/oan c chieu cua p gia hai cap oxi hoa kh. 4. Cung co: Nam /n va y ngha, ong thi viet c cac pt c/minh. 5. Bai tap: 2, 3, 4 tr 92, 93 sgk.

Tuan: 19 Tiet : 38

Bai 5: HP KIM I. Muc tieu: + Nam c /n va cau tao cua hp kim. + So sanh va giai thch c t/c cua hp kim. II. Chuan b: + Gv: He thong cau hoi + Hs: Xem bai trc nha III. Tien trnh len lp: 1. On nh: 2. Kiem tra 15: Cau 1: Neu t/c hh chung cua kl ? Viet cac pt p c/minh. Cau 2: So sanh t/c cua cac cap oxi hoa kh: Mg 2+/ Mg; Fe2+/ Fe; + 2H / H2. 3. Bai mi: Hoat ong cua thay Noi dung va tro I. nh ngha: Hd cho hs neu / n ? Hp kim la chat ran thu c sau khi nung

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Gv: Tran Quoc

nong chay mot hon hp nhieu kl khac nhau hoac hon hp kl va phi kim. Hp kim co cau tao II. Cau tao cua hp kim: nh the nao ? Sau o 1. Tinh the hon hp: Nhng tinh the cua cho vd. cac n chat khi nung nong chay khong tan vao nhau. 2. Tinh the dd ran: Nhng tinh the cua cac n chat khi nong chay hoa tan vao nhau. 3. Tinh the hp chat hoa hoc: La tinh the cua nhng hp chat hoa hoc c tao ra khi nung nong chay cac n chat trong hon hp. Trong hp kim co III. Lien ket hoa hoc trong hp kim: nhng loai lk hh nao ? + Tinh the hon hp va tinh the dd ran: Lk kim loai. Hp kim co nhng t/c + Tinh the hp chat hoa hoc:Lk cong hoa nao so vi n chat kl ? tr. IV. T/ c cua hp kim: Hp kim co nhng ng + Tnh dan ien, dan nhiet: Thng kem dung g ? hn cac kl. + Cng va gion hn cac kl. + Nhiet o nong chay thng thap hn cac kl. V. ng dung cua hp kim: Sgk. 4. Cung co: Nam /n, cau tao va ng dung. 5. Bai tap: 2, 3, 4 tr 96 sgk. Ngay . K duyet

Tuan: 20 Tiet : 39, 40 Bai 6: AN MON KIM LOAI VA CHONG AN MON I. Muc tieu: + Nam c khai niem chung ve an mon kl va cac khai niem rieng ve an mon hoa hoc, an mon ien hoa. + Nam c k, c che va ban chat cua an mon kl, ac biet /vi an mon ien hoa. + Nam c ng/tac bao ve kl chong an mon va so bien phap cu the, quan trong nhat la ngan cach kl can bao ve vi moi trng. II. Chuan b: + Gv: He thong cau hoi + Hs: Xem bai trc nha III. Tien trnh len lp: 1. On nh: 2. Kiem tra bai cu: Khong. 3. Bai mi: Hoat ong cua thay Noi dung va tro I. S an mon kl: Hd cho hs neu /n va La s pha huy kl hoac hp kim do td hoa

KIM LOAI

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viet qua trnh ? Theo em an mon kl co may loai ? An mon hoa hoc la g ? ac iem, ban chat va cho vd.

Gv: Tran Quoc

An mon ien hoa la g ?

Hd cho mo ta TN va neu hien tng ? V sao la Zn b an mon, con la Cu th khong ?

Gv hd cho hs neu va dien giang.

e bao ve kl, ta dung nhng pp nao ? Cho vd.

hoc cua moi trng xung quanh : M0 ne Mn+ (n = 1, 2, 3). Ket qua : Lam mat nhng t/c quy bao cua kl. Phan loai: Co hai loai chnh: 1. An mon hoa hoc: La s pha huy kl do kl p hh vi chat kh hoac hi nc t o cao. 2: Khong phat sinh dong ien, toc o an mon phu thuoc vao to. Ban chat: La mot qua trnh oxi hoa kh. Vd: 3Fe + 2O2 Fe3O4 Fe + 3/2Cl2 FeCl3 2. An mon ien hoa: La s pha huy cua kl do kl tiep xuc vi dd chat ien li tao nen dong ien. a. TN: Hnh ve sgk. Mo ta: Hien tng: + La Zn cc am: B an mon nhanh trong dd. + Kim von ke b lech hoac bong en sang. + La Cu cc dng: Co bot kh hro thoat ra. Giai thch: + Cc am: La Zn b am mon nhanh 0 v: Zn 2e Zn2+ va i vao dd. + Kim von ke lech: Cac e di chuyen t la Zn Cu. + Cc dng: Cac ion H+ trong dd axit di chuyen en va b kh thanh hiro t do va thoat ra khoi dd: 2H+ + 2e H2. b. Cac k an mon ien hoa: + Cac ien cc phai khac chat nhau. + Cac ien cc phai tiep xuc nhau trc tiep hoac gian tiep. + Cac ien cc phai cung tiep xuc vi 1 dd ien li. c. C che cua an mon ien hoa: Xet mot vat bang gang (hoac thep: Fe C) trong moi trng khong kh am ( H 2O, CO2, SO2, O2, ...). + Cc am (tinh the Fe): Xay ra s oxi hoa Fe (an mon Fe) thanh ion Fe2+: Fe0 2e Fe2+ va i vao dd ien li. Tai ay b oxi hoa tiep: Fe2+ -- 1e Fe3+ (G sat mau nau o). + Cc dng (tinh the C): Cac ion H + trong dd chat ien li (neu la dd axit ) di chuyen en, b kh: 2H+ + 2e H2 va thoat ra khoi dd. Neu nc co hoa tan O2, hoac dd trung tnh, hoac dd baz th xay ra s kh O 2: 2H2O + O2 + 4e 4OH d. Ban chat cua an mon ien hoa: La 1 qua trnh oxi hoa kh xay ra tren be mat cac ien cc. II. Chong an mon kim loai: 1. Cach li kl vi moi trng. 2. Dung hp kim chong g.

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Gv: Tran Quoc

3. Dung chat chong an mon (Chat km ham). 4. Dung pp ien hoa. 4. Cung co: Giai thch c c che an mon ien hoa (co ve hnh) 5. Bai tap: 2, 3, 6, 7 tr 100, 101 sgk. Ngay K duyet

Tuan: 21 Tiet: 41 Bai 7: IEU CHE KIM LOAI I. Muc tieu: + Nam ngtac va nhng pp ieu che kim loai pho bien. + Tnh toan lng kl ieu che c theo cac pp va theo nh luat Fraay. II. Chuan b: + Gv: He thong cau hoi + Hs: Xem bai trc nha III. Tien trnh len lp: 1. On nh: 2. Kiem tra bai cu: An mon ien hoa: /n, c che, ieu kien, ban chat ? Xet c che an mon cua hp kim Al Cu khi e trong kk am. 3. Len lp: Hoat ong cua thay Noi dung va tro I. Nguyen tac: Hd cho hs neu ng tac Kh cac ion kl thanh kl t do: Mn+ + ne M0 va viet s o ? (n = 1, 2, 3) II. Phng phap ieu che kim loai: Goi hs viet cac pt 1. PP thuy phan (/che kl co tnh kh yeu: Kl p minh hoa ? sau H2): Dung kl t do co tnh kh manh e kh ion kl khac trong dd muoi. Cac chat kh Zn + CuSO4 ZnSO4 + Cu thng s dung, sau 2. PP nhiet luyen (/che kl co tnh kh yeu va o viet pt p ? trung bnh: Kl sau nhom): Dung chat kh ( CO, H2, C,...) hoac kl Al e kh cac ion kl trong oxit to cao. CuO + H2 Cu + H2O Goi hs cho vd, sau 2Al + Fe2O3 2Fe + Al2O3 o hd cho hs viet pt 3. PP ien phan (ieu che hau het cac kl ): p. a. Kl co tnh kh manh (Li Al): ien phan nong chay muoi, kiem, oxit (goc axit khong co oxi): Gv nhac lai cho hs NaCl Na + Cl2 nam kl manh, kl yeu 4NaOH 4Na + O2 + H2O theo day HHH. 2Al2O3 4Al + 3O2 b. /che kim loai co tnh kh yeu va trung bnh: ien phan dd muoi ma goc axit khong co Hd hs ve s o va oxi. qui tac tren s o. K CuCl 2 A

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Gv: Tran Quoc

(H2O) Cu2+, H2O Cl , H2O Cu2+ + 2e Cu0 Cl + 1e Cl2 Pt ien phan: CuCl2 Cu + Cl2 nh luat Faraday: AIt m= nF 4. Cung co: Nam ngtac va cac pp /che, tnh c theo nh luat Faraday. 5. Bai tap: 2 6 tr 103 sgk. Ngay .. K duyet

Tuan: 21 Tiet: 42

ON TAP
I. Muc tieu: + Ren k nang van dung va giai bai tap cho hs. + Giup hs nam mot so noi dung kien thc c ban a hoc e chuan b tot cho tiet kiem tra sap ti. II. Chuan b: + Gv: L thuyet va bai tap. + Hs: L thuyet va van dung. III. Len lp: 1. On nh: 2. Kiem tra bai cu: Khong. 3. Bai mi: Noi dung Hoat ong cua thay va tro I. L thuyet: 1. Kl co nhng t/c vat l Gv lan lt a ra tng cau hoi cac hs chung nao? Giai thch ? trali theo yeu cau. 2. T/c hh chung cua kl la g ? Viet cac pt p c/minh. Sau o gv chnh sa va cho hs lam 3. Day ien hoa cua kl la g e cng on tap. ? Y ngha. 4. Ngtac va cac pp /che kl ? Viet pt p. II. Bai tap: Hd 1. Bai 2 tr 103 sgk. 2AgNO3 + Cu Cu(NO3)2 + 2Ag Co can dd MgCl2 en khang, sau o pnc: MgCl2 Mg + Cl2 2. Bai 5 tr 103 sgk. Hd Pt p: CuCl2 Cu + Cl2 0,05 0,05 0,05 mol Fe + CuCl2 FeCl2 + Cu 56g 64g So mol Cl2 = 1,12 : 22,4 = 0,05 mol. Sau p khoi lng inh sat tang = 64 56 = 8g. Nhng bai cho tang 1,12g So mol Fe p = 1,2 : 8 = 0,15 mol Khoi lng Cu thu c = 64 x ( 0,05 +

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3. Bai 2 tr 100 sgk.

Gv: Tran Quoc

0,15) = 12,8g So mol CuCl2 = 0,05 + 0,15 = 0,2 mol Nong o CuCl2 = 0,2 : 0,2 = 1M Hd + Zn _ Cu : an mon ien hoa. + Cc am: Zn0 2e Zn2+ va i vao dd 4. Bai 3 tr 103 sgk. chat ien li. + Cc dng: Cac ion H+ di chuyen en, nhan e t la Zn chuyen sang va b kh: 2H+ + 2e H2 va thoat ra khoi dd. (Hs t ve hnh) Hd ieu che: Cu(OH)2 + 2HCl CuCl2 + 2H2O Sau o pdd: CuCl2 Cu + Cl2 MgO + 2HCl MgCl2 + H2O Co can dd sau o pnc: MgCl 2 Mg + Cl2 4FeS2 + 11O2 2Fe2O3 + 8SO2 Fe2O3 + 6HCl 2FeCl3 + 3H2O 3Zn + 2FeCl3 3ZnCl2 + 2Fe 4. Dan do: Hoc va xem lai cac dang bai tap a giai, tiet sau kiem tra. Ngay K duyet

Tuan: 22 Tiet: 43

KIEM TRA
I. Muc tieu: Ren k nang van dung va giai bai tap cho hs. II. Noi dung e: HCM

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