S GIO DC V O TO THA THIN HU

THI CHNH THC

K THI CHN HC SINH GII TNH KHI 12 THPT

Mn: HO HC Thi gian lm bi : 150 pht

Bi 1: (4,75 im) 1. Tm cc dng lin kt hydro trong hn hp sau: Etanol, phenol v nc. Dng lin kt hydro no bn nht, km bn nht? Gii thch. 2. Khi trng hp isopren ngi ta thy to thnh 4 loi polyme, ngoi ra cn c mt vi sn phm ph trong c cht X, khi hydro ha hon ton X thu c Y (1-metyl-3isopropyl xiclohexan). Hy vit cng thc cu to ca 4 loi polyme v cc cht X, Y. 3. Xc nh cu to hp cht C 10H10 (A) m khi oxi ha ch cho mt axit CH(CH2COOH)3 (B). Bi 2: (3,25 im) 1. Hydrocacbon X mch thng c m C :m H = 36 :7. Xc nh cu to ca X v hon thnh dy chuyn ha sau: +H 2, Ni +CuO +KMnO4,H+ X Y Z phenol A 0 B D T nilon 6,6. 0 2. Mt mol tripeptit X b thy phn hon ton cho 2 mol Glu, 1 mol Ala v 1 mol NH3. X ch c mt nhm COOH t do v khng phn ng vi 2,4-dinitroflobenzen. Ala c tch ra u tin khi tc dng vi cacboxypeptidaza. Lp lun xc nh cu trc ca X. Bi 3: (4,25 im) 1. T axetylen v cc cht v c cn thit khc hy iu ch: Axit 2,4-diclophenoxi axetic; Axit p-isopropylbenzoic; axit axetyl salixylic (Aspirin). 2. T hp cht ban u 3,4- (CH 3O)2C6H3CH2Cl v cc cht v c cn thit khc hy tng hp papaverin (C20H21O4N) c cng thc cu to sau:
t t

CH3O CH3O

OCH3 OCH3

CH2

Bi 4: (3,25 im) A l mt hydrocacbon thu c khi ch bin du m. Ankyl ha A bng isobutan c mt AlCl3 (xt) to thnh B. Thnh phn % hydro trong A t hn trong B l 1,008%. Trong iu kin ca phn ng Rifominh, A c chuyn ha thnh D, D khng tc dng vi nc brom, nhng D tc dng vi hn hp HNO3 m c v H2SO4 m c sinh ra ch mt dn xut nitro E, D hydro ha cho ra K v c th b oxi ha bi KMnO 4 d trong mi trng H2SO4 to ra axit F. Nung chy mui natri ca F vi NaOH rn sinh ra G, G c th b hydro ha thnh H. Cc hydrocacbon A, H, K c thnh phn % nguyn t nh nhau. Ozon phn A thu c mt hn hp sn phm trong c C 3H6O (M) tham gia phn ng vi iot trong dung dch NaOH un nng sinh ra kt ta mu vng c mi hc kh c trng. Hy xc nh cng thc phn t ca A, B v cng thc cu to cc sn phm c k hiu bng ch t A n M. Vit cc phng trnh phn ng ha hc xy ra. Bit rng cc phn ng u xy ra hon ton. Bi 5: (4,5 im)

t chy hon ton 2,54 gam este E ( khng cha chc khc) mch h, c to ra t axit n chc v ru, thu c 2,688 lt kh CO2 (ktc) v 1,26gam nc. 0,1mol E tc dng va vi 200ml NaOH 1,5M to ra mui v ru. t chy ton b lng ru ny c 6,72 lt CO2 (ktc). 1. Xc nh cng thc phn t, cng thc cu to ca E. 2. A l axit to ra E. Mt hn hp X gm A v 2 ng phn ca n u phn ng c vi dung dch NaOH (va ), c cn dung dch sau phn ng c cht rn B v hn hp hi D. D tc dng vi dung dch AgNO3/NH3 d cho 21,6 gam Ag. Nung B vi NaOH rn, d trong iu kin khng c khng kh c hn hp hi F. a F v nhit thng th c 1 cht ngng t G cn li hn hp kh N. G tc dng vi Na d sinh ra 1,12 lt kh H2. Hn hp kh N qua Ni nung nng cho hn hp kh P. Sau phn ng th tch hn hp kh gim 1,12 lt v d P / H 2 = 8. Tnh khi lng cc cht trong X. Bit rng cc phn ng xy ra hon ton, cc th tch kh o ktc. Cho : Na: 23 ; K: 39 ; Mn: 55 ; Ag: 108 N: 14 ; C: 12 ; O: 16 ; H: 1 (Gim th khng gii thch g thm)