wWw.VipLam.

Net
1

PHN I: L THUYT TNG HP
CHNG 3: AMIN AMINO AXIT - PROTEIN

Cu 1: Cng thc ca amin cha 15,05% khi lng nit l cng thc no sau?
A. C
2
H
5
NH
2
B. (CH
3
)
2
NH C. C
6
H
5
NH
2
D. (CH
3
)
3
N
Cu 2: Cng thc phn t C
3
H
9
N ng vi bao nhiu ng phn?
A. 5 B. 4 C. 3 D. 2
Cu 3: Cho amin c cu to: CH
3
-CH(CH
3
)-NH
2
. Chn tn gi khng ng?
A. Prop-1-ylamin B. Propan-2-amin
C. isoproylamin D. Prop-2-ylamin
Cu 4: Tn gi ng C
6
H
5
NH
2
ng?
A. Benzyl amoni B. Phenyl amoni C. Hexylamin D. Anilin
Cu 5: Hp cht hu c X mch h cha cc nguyn t C, H, N trong c 23,72% khi lng N. X tc
dng vi HCl theo t l mol 1:1. Chn cu pht biu sai?
A. X l hp cht amin.
B. Cu to ca X l amin no, n chc
C. Nu cng thc X l C
x
H
y
N
z
thz = 1
D. Nu cng thc X l C
x
H
y
N
z
th: 12x - y =45
Cu 6: Pht biu no sau y khng ng?
A. Amin c cu to bng cch thay th H ca amoniac bng 1 hay nhiu gc H-C.
B. Bc ca amin l bc ca nguyn t cacbon lin kt vi nhm amin.
C. Ty thuc vo gc H-C, c th phn bit thnh amin thnh amin no, cha no v thm.
D. Amin c t 2 nguyn t cacbon trong phn t bt u xut hin ng phn.
Cu 7: Amin no di y l amin bc 2?
A. CH
3
-CH
2
NH
2
B. CH
3
-CHNH
2
-CH
3

C. CH
3
-NH-CH
3
D. CH
3
-NCH
3
-CH
2
-CH
3

Cu 8: Cng thc no di y l cng thc chung ca dy ng ng amin thm (cha 1 vng bezen) n
chc bc nht?
A. C
n
H
2n-7
NH
2
B. C
n
H
2n+1
NH
2

C. C
6
H
5
NHC
n
H
2n+1
D. C
n
H
2n-3
NHC
n
H
2n-4

Cu 9: Tn gi cc amin no sau y l khng ng?
A. CH
3
-NH-CH
3
imetylamin B. CH
3
-CH
2
-CH
2
NH
2
n-propylamin
C. CH
3
CH(CH
3
)-NH
2
isopropylamin D. C
6
H
5
NH
2
alanin
Cu 10: Amin no di y c 4 ng phn cu to?
A. C
2
H
7
N B. C
3
H
9
N C. C
4
H
11
N D. C
5
H
13
N
Cu 11: Pht biu no sau y v tnh cht vt l ca amin l khng ng?
A. Metyl-, etyl-, imetyl-, trimetylamin l nhng cht kh, d tan trong nc.
B. Cc amin kh c mi tng t amoniac, c.
C. Anilin l cht lng, kh tan trong nc, mu en.
D. tan ca amin gim dn khi s nguyn t cacbon trong phn t tng.
Cu 12: Cc gii thch v quan h cu trc, tnh cht no sau y khng hp l?
A. Do c cp electron t do trn nguyn t N m amin c tnh baz.
B. Do nhm NH
2
- y e nn anilin d tham gia vo phn ng th vo nhn thm hn v u tin v tr
o- v p-.
C. Tnh baz ca amin cng mnh khi mt electron trn nguyn t N cng ln.
D. Vi amin R-NH
2
, gc R ht electron lm tng mnh ca tnh baz v ngc li.
Cu 13: Nhn xt no di y khng ng?
wWw.VipLam.Net
2

A. Phenol l axit cn anilin l baz.
B. Dung dch phenol lm qu tm ha cn dung dch anilin lm qu tm ha xanh.
C. Phenol v anilin u d tham gia phn ng th v u to kt ta trng vi dung dch brom.
D. Phenol v anilin u kh tham gia phn ng cng v u to hp cht vng no khi cng vi hiro.
Cu 14: S d anilin c tnh baz yu hn NH
3
l do yu t no?
A. Nhm NH
2
- cn 1 cp electron t do cha tham gia lin kt.
B. Nhm NH
2
- c tc dng y electron v pha vng benzen lm gim mt electron ca N.
C. Gc phenyl c nh hng lm gim mt electron ca nguyn t N.
D. Phn t khi ca anilin ln hn so vi NH
3

Cu 15: Hy ch ra iu sai trong cc iu sau?
A. Cc amin u c tnh baz
B. Tnh baz ca anilin yu hn NH
3

C. Amin l hp cht hu c c tnh cht lng tnh
D. Amin tc dng vi axit cho ra mui
Cu 16: Dung dch etylamin tc dng vi dung dch nc ca cht no sau y?
A. NaOH B. NH
3

C. NaCl D. FeCl
3
v H
2
SO
4

Cu 17: Hp cht no di y c tnh baz yu nht?
A. Anilin B. Metylamin C. Amoniac D. imetylamin
Cu 18: Cht no di y c tnh baz mnh nht?
A. NH
3
B. CH
3
CONH
2
C. CH
3
CH
2
CH
2
OH D. CH
3
CH
2
NH
2

Cu 19: Sp xp cc cht sau y theo tnh baz gim dn?
(1) C
6
H
5
NH
2
(2) C
2
H
5
NH
2
(3) (C
6
H
5
)
2
NH (4) (C
2
H
5
)
2
NH (5) NaOH (6) NH
3

A. 1>3>5>4>2>6 B. 6>4>3>5>1>2
C. 5>4>2>1>3>6 D. 5>4>2>6>1>3
Cu 20: Phn ng no di y khng th hin tnh baz ca amin?
A. CH
3
NH
2
+ H
2
O CH
3
NH
3
+
+ OH
-

B. C
6
H
5
NH
2
+ HCl C
6
H
5
NH
3
Cl
C. Fe
3+
+ 3CH
3
NH
2
+ 3H
2
O Fe(OH)
3
+ 3CH
3
NH
3
+
D. CH
3
NH
2
+ HNO
2
CH
3
OH + N
2
+ H
2
O
Cu 21: Dung dch no di y khng lm qu tm i mu?
A. C
6
H
5
NH
2
B. NH
3

C. CH
3
CH
2
NH
2
D. CH
3
NHCH
2
CH
3

Cu 22: Phng trnh ha hc no sau y khng ng?
A. 2CH
3
NH
2
+ H
2
SO
4
(CH
3
NH
3
)
2
SO
4

B. FeCl
3
+ 3CH
3
NH
2
+ 3H
2
O Fe(OH)
3
+ 3CH
3
NH
3
Cl
C. C
6
H
5
NH
2
+ 2Br
2
3,5-Br
2
-C
6
H
3
NH
2
+ 2HBr
D. C
6
H
5
NO
2
+ 3Fe +7HCl C
6
H
5
NH
3
Cl + 3FeCl
2
+ 2H
2
O
Cu 23: Phng trnh ha hc no sau y khng ng?
A. 2CH
3
NH
2
+ H
2
SO
4
(CH
3
NH
3
)
2
SO
4

B. CH
3
NH
2
+ O
2
CO
2
+ N
2
+ H
2
O
C. C
6
H
5
NH
2
+ 3Br
2
2,4,6-Br
3
C
6
H
2
NH
3
Br + 2HBr
D. C
6
H
5
NO
2
+ 3Fe +6HCl C
6
H
5
NH
2
+ 3FeCl
2
+ 2H
2
O
Cu 24: Dung dch etylamin khng tc dng vi cht no sau y?
A. axit HCl B. dung dch CuCl
2

C. dung dch HNO
3
D. Cu(OH)
2

wWw.VipLam.Net
3

Cu 25: Dung dch etylamin tc dng c vi cht no sau y?
A. Giy pH B. dung dch AgNO
3

C. Dung dch NaCl D. Cu(OH)
2

Cu 26: Pht biu no sai?
A. Anilin l baz yu hn NH
3
v nh hng ht electron ca nhn ln nhm NH
2
-
bng hiu ng lin hp.
B. Anilin khng lm i mu giy qu tm.
C. Anilin t tan trong nc v gc C
6
H
5
- k nc.
D. Nh tnh baz, anilin tc dng vi dung dch Brom.
Cu 27: Dng nc brm khng phn bit c 2 cht trong cc cp no sau y?
A. dung dch anilin v dung dch NH
3
B. Anilin v xiclohexylamin
C. Anilin v phenol D. Anilin v benzen.
Cu 28: Cc hin tng no sau y m t khng chnh xc?
A. Nhng qu tm vo dung dch etylamin thy qu tm chuyn sang xanh.
B. Phn ng gia kh metylamin v kh hiroclorua lm xut hin khi trng.
C. Nh vi git nc brm vo ng nghim ng dung dch anilin thy c kt ta trng.
D. Thm vi git phenolphtalein vo dung dch imetylamin thy xut hin mu xanh.
Cu 29:Khng th dng thuc th trong dy no sau y phn bit cht lng: phenol, anilin, benzen?
A. Dung dch Brm B. dung dch HCl v dung dch NaOH
C. dung dch HCl v dung dch brm D. dung dch NaOH v dung dch brm
Cu 30: tinh ch anilin t hn hp: phenol, anilin, benzen cch thc hin no sau y l ng?
A. Ha tan dung dch HCl d, chit ly phn tan. Thm NaOH d v chit ly anilin tinh khit.
B. Ha tan dung dch Brm d, lc ly kt ta, dehalogen ha thu c anilin.
C. Ha tan NaOH d v chit ly phn tan v thi CO
2
vo sau n d thu c anilin tinh khit.
D. Dng NaOH tch phenol, sau dng brm tch anilin ra khi benzen.
Cu 31:Cho mt hn hp A cha NH
3
, C
6
H
5
NH
2
v C
6
H
5
OH. A c trung ha bi 0,02 mol NaOH hoc
0,01 mol HCl. A cng phn ng va vi 0,075 mol Br
2
to kt ta. Lng cc cht NH
3
, C
6
H
5
NH
2
v
C
6
H
5
OH ln lt bng?
A. 0,01 mol; 0,005 mol v 0,02 mol B. 0,005 mol; 0,005 mol v 0,02 mol
C. 0,005 mol; 0,02 mol v 0,005 mol D. 0,01 mol; 0,005 mol v 0,005 mol
Cu 32:Cho mt lng anilin d phn ng hon ton vi dung dch cha 0,05 mol H
2
SO
4
long. Khi lng
mui thu c?
A. 7,1 g B. 14,2 g C. 19,1 g D. 28,4 g
Cu 33: phn bit phenol, anilin, benzen, stiren ngi ta s dng ln lt cc thuc th no sau?
A. Qu tm, brm B. dung dch NaOH v brom
C. brm v qu tm D. dung dch HCl v qu tm
Cu 34: t chy hon ton mt amin n chc, bc mt thu c CO
2
v nc theo t l mol 6:7. Amin
c tn gi l g?
A. Propylamin B. Phenylamin
C. isopropylamin D. Propenylamin
Cu 35: t chy hon ton mt ng ng metylamin ngi ta thy t l th tch cc kh v hi ca cc sn
phm sinh ra l
2 2
CO H O
V : V = 2:3. Cng thc phn t ca amin?
A. C
3
H
9
N B. CH
5
N C. C
2
H
7
N D. C
4
H
11
N
Cu 36: Cho 20 gam hn hp 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl
1M, c cn dung dch thu c 31,68 gam hn hp mui. Th tch ca dung dch HCl 1M dng?
A. 100ml B. 50ml C. 200ml D. 320ml
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4

Cu 37: Cho 20 gam hn hp 3 amin no, mch h, n chc, ng ng k tip nhau tc dng va vi
dung dch HCl 1M, c cn dung dch thu c 31,68 gam hn hp mui. Bit khi lng phn t cc amin
u nh hn 80. Cng thc phn t ca cc amin?
A. CH
3
NH
2
, C
2
H
5
NH
2
v C
3
H
7
NH
2
B. C
2
H
3
NH
2
, C
3
H
5
NH
2
v C
4
H
7
NH
2

C. C
2
H
5
NH
2
, C
3
H
7
NH
2
v C
4
H
9
NH
2
D. C
3
H
7
NH
2
, C
4
H
9
NH
2
v C
5
H
11
NH
2

Cu 38: Cho 10 gam hn hp 3 amin no, mch h, n chc, ng ng k tip nhau tc dng va vi
dung dch HCl 1M, c cn dung dch thu c 15,84 gam hn hp mui. Nu 3 amin trn c t l mol
1:10:5 theo th t phn t khi tng dn th cng thc phn t ca cc amin?
A. CH
5
N, C
2
H
7
N v C
3
H
7
NH
2
B. C
2
H
7
N, C
3
H
9
N v C
4
H
11
N
C. C
3
H
9
N, C
4
H
11
N v C
5
H
11
N D. C
3
H
7
N, C
4
H
9
N v C
5
H
11
N
Cu 39: t chy hon ton 6,2 gam mt amin no, mch h, n chc phi dng ht 10,08 lt kh O
2
ktc.
Cng thc phn t ca amin?
A. C
2
H
5
NH
2
B. CH
3
NH
2
C. C
4
H
9
NH
2
D. C
3
H
7
NH
2

Cu 40: Mt HCHC to bi C, H, N, l cht lng, khng mu, rt c, t tan trong nc, d tc dng vi
dung dch HCl v c th tc dng vi dung dch brm to kt ta trng. Cng thc phn t ca HCHC c th
l?
A. C
2
H
7
N B. C
6
H
13
N C. C
6
H
7
N D. C
4
H
12
N
2

Cu 41: t chy hon ton 100ml hn hp gm imetylamin v 2 H-C l ng ng k tip thu c
140ml CO
2
v 250ml hi nc (cc kh o cng iu kin). Cng thc phn t ca 2 hirocacbon?
A. C
2
H
4
v C
3
H
6
B. C
2
H
2
v C
3
H
4
C. CH
4
v C
2
H
6
D. C
2
H
6
v C
3
H
8

Cu 42: Trung ha 3,1 gam mt amin n chc X cn va 100ml dung dch HCl 1M. Cng thc phn t
X l?
A. C
2
H
5
N B. CH
5
N C. C
3
H
9
N D. C
3
H
7
N
Cu 43: t chy hon ton hn hp gm 2 amin no n chc l ng ng k tip nhau trong dy ng
ng, thu c CO
2
v hi nc t l th tch CO
2
: H
2
O = 8 : 17. Cng thc phn t ca 2 amin?
A. C
2
H
5
NH
2
v C
3
H
7
NH
2
B. C
3
H
7
NH
2
v C
4
H
9
NH
2

C. CH
3
NH
2
v C
2
H
5
NH
2
D. C
4
H
9
NH
2
v C
5
H
11
NH
2

Cu 44: t chy hon ton mt amin n chc, cha no, c mt lin kt i mch cacbon, thu c CO
2

v hi nc t l th tch CO
2
: H
2
O = 8 : 9. Cng thc phn t ca amin?
A. C
3
H
6
N B. C
4
H
9
N C. C
4
H
8
N D. C
3
H
7
N
Cu 45: Cho 9,3 gam mt ankylamin tc dng vi dung dch FeCl
3
d thu c 10,7 gam kt ta.
Ankylamin Cng thc phn t?
A. CH
3
NH
2
B. C
2
H
5
NH
2
C. C
3
H
7
NH
2
D. C
4
H
9
NH
2

Cu 46: Cho 1,52 gam hn hp 2 amin no n chc (trn vi s mol bng nhau) tc dng va vi 200ml
dung dch HCl, thu c 2,98 gam mui. Kt lun no sau y khng chnh xc?
A. Nng mol/l dung dch HCl 0,2M
B. S mol ca mi cht 0,02 mol
C. Cng thc ca 2 amin CH
5
N v C
2
H
7
N
D. Tn gi ca 2 amin metylamin v etylamin
Cu 47: Phn tch nh lng 0,15 gam hp cht hu c X thy t l khi lng cc nguyn t C:H:O:N =
4,8:1:6,4:2,8. Nu phn tch nh lng m gam cht X th t l khi lng cc nguyn t C:H:O: N l bao
nhiu?
A. 4 : 1 : 6 : 2 B. 2,4 : 0,5 : 3,2 : 1,4
C. 1,2 : 1 : 1,6 : 2,8 D. 1,2 : 1,5 : 1,6 : 0,7
Cu 48: Ngi ta iu ch anilin bng cch nitro ha 500 g benzen ri kh hp cht nitro sinh ra. Khi
lng anilin thu c l bao nhiu? Bit hiu sut phn ng mi giai on l 78%, 80%, 97,5%.
A. 346,7 g B. 362,7 g C. 463,4 g D. 358,7 g
wWw.VipLam.Net
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------------
AMINO AXIT
Cu 49: Glyxin khng tc dng c vi dung dch no sau y?
A. NaHSO
4
. B. NaHCO
3
. C. NH
3
. D. KNO
3
.
Cu 50:Cht dng lm gia v thc n gi l m chnh hay bt ngt c cng thc cu to l
A. NaOOCCH
2
CH
2
CH(NH
2
)COONa. B. NaOOCCH
2
CH
2
CH(NH
2
)COOH.
C. NaOOCCH
2
CH(NH
2
)CH
2
COOH. D. NaOOCCH
2
CH(NH
2
)CH
2
COONa.
Cu 51:iu no sau y SAI?
A. Dung dch amino axit khng lm giy qu tm i mu.
B. Cc amino axit u tan c trong nc.
C. Khi lng phn t ca amino axit gm mt nhm NH
2
v mt nhm COOH lun l s l.
D. Hp cht amino axit c tnh lng tnh.
Cu 52:Pht biu khngng l
A. Trong dung dch, H
2
NCH
2
COOH cn tn ti dng ion lng cc H
3
N
+
CH
2
COO

.
B. Amino axit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl.
C. Amino axit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt.
D. Hp cht H
2
NCH
2
COOH
3
NCH
3
l este ca glyxin.
Cu 53: chng minh amino axit l hp cht lng tnh ta c th dng phn ng ca cht ny vi
A. dung dch HCl v dung dch Na
2
SO
4
. B. dung dch NaOH v CuO.
C. dung dch Ba(OH)
2
v dung dch HCl. D. dung dch NaOH v dung dch NH
3
.
Cu 54:Cp cht no ng thi tc dng c vi dung dch HCl v vi dung dch NaOH?
A. H
2
NCH
2
COOH v C
6
H
5
NH
2
. B. CH
3
COONH
4
v C
2
H
5
NH
2
.
C. CH
3
COONH
4
v HCOOH
3
NCH
3
. D. CH
3
CH(NH
2
)COOH v C
6
H
5
OH.
Cu 55: Hp chtC
3
H
7
O
2
N tc dng c vi NaOH, H
2
SO
4
v khng lm mt mu dung dch Br
2
c cng
thc cu to l
A. HCOOH
3
NCH
2
CH
3
. B. CH
2
=CHCOONH
4
.
C. H
2
NCH
2
CH
2
COOH. D. CH
3
CH
2
CH
2
NO
2
.
Cu 56:Cht X c cng thc phn t C
3
H
7
O
2
N v lm mt mu dung dch brom. Tn gi ca X l
A. metyl amino axetat. B. axit amino propionic.
C. axit amino propionic. D. amoni acrylat.
Cu 57:Cht X c cng thc phn t C
4
H
9
O
2
N. Bit: X + NaOH Y + CH
4
O; Y + HCl (d) Z + NaCl.
Cng thc cu to ca X v Z ln lt l
A. H
2
NCH
2
CH
2
COOCH
3
v CH
3
CH(NH
3
Cl)COOH.
B. CH
3
CH(NH
2
)COOCH
3
v CH
3
CH(NH
3
Cl)COOH.
C. CH
3
CH(NH
2
)COOCH
3
v CH
3
CH(NH
2
)COOH.
D. H
2
NCH
2
COOC
2
H
5
v ClH
3
NCH
2
COOH.
Cu 58:Cho cc cht: phenylamoni clorua, alanin, lysin, glyxin, etylamin. S cht lm qu tm i mu l
A. 2. B. 3. C. 4. D. 5.
Cu 59:C cc dung dch ring bit sau: C
6
H
5
NH
3
Cl (phenylamoni clorua), H
2
NCH
2
CH
2
CH(NH)COOH,
ClH
3
NCH
2
COOH, H
2
NCH
2
COONa, HOOCCH
2
CH
2
CH(NH
2
)COOH. S lng cc dung dch
c pH < 7 l
A. 2. B. 5. C. 4. D. 3.
Cu 60:T cc amino axit c cng thc phn t C
3
H
7
O
2
N c th to thnh ti a bao nhiu loi polime khc
nhau?
A. 3 loi. B. 6 loi. C. 4 loi. D. 5 loi.
Cu 61:Phn bit cc dung dch keo: h tinh bt, x phng, lng trng trng, ta dng
A. HCl, bt Al. B. NaOH, HNO
3
. C. NaOH, I
2
. D. HNO
3
, I
2
.

Cu 62: Amino axit l hp cht hu c trong phn t
A. cha nhm cacboxyl v nhm amino. B. ch cha nhm amino.
C. ch cha nhm cacboxyl. D. ch cha nit hoc cacbon.
Cu 63: C
4
H
9
O
2
N c my ng phn amino axit c nhm amino v tr ?
A. 4. B. 3. C. 2. D. 5.
wWw.VipLam.Net
6

Cu 64: C bao nhiu amino axit c cng cng thc phn t C
4
H
9
O
2
N?
A. 3 B. 4 C. 5. D. 6
Cu 65: Pht biu no di y v amino axit l khng ng:
A. Aminoaxit l hp cht hu c tp chc trong phn t cha ng thi nhm amino v nhm
cacboxyl
B. Hp cht H
2
NCOOH l aminoaxit n gin nht.
C. Aminoaxit ngoi dng phn t (H
2
NRCOOH) cn c dng ion lng cc (H
3
N
+
RCOO
-
)
D. Thng thng dng ion lng cc l dng tn ti chnh ca aminoaxit.
Cu 66: Tn gi ca aminoaxit no sau y l ng
A. H
2
N-CH
2
-COOH (glixerin) B. CH
3
-CH(NH
2
)-COOH (anilin)
C. CH
3
-CH(CH
3
)-CH(NH
2
)COOH (valin) D. HCOO-(CH
2
)
2
-CH(NH
2
)COOH (axit glutaric)
Cu 67: C bao nhiu amino axit c cng cng thc phn t C
3
H
7
O
2
N?
A. 3 cht. B. 4 cht. C. 2 cht. D. 1
Cu 68: chng minh tnh lng tnh ca NH
2
-CH
2
-COOH (X) , ta cho X tc dng vi
A. HCl, NaOH. B. Na
2
CO
3
, HCl. C. HNO
3
, CH
3
COOH. D. NaOH, NH
3
.
Cu 69: Khng nh no v tnh cht vt l ca aminoaxit di y khng ng
A. Tt c u l cht rn. C. Tt c u l tinh th mu trng.
B. Tt c u tan trong nc. D. Tt c u c nhit nng chy cao.
Cu 70: Aminoaxit khng th phn ng vi loi cht no sau y
A. Ancol C. Dung dch Brom
B. Axit v axit nitr D. Kim loi, oxit baz v mui.
Cau 71. Co bao nhieu ten goi phu hp vi cong thc cau tao:
(1). H
2
N-CH
2
-COOH : Axit amino axetic.
(2). H
2
N-[CH
2
]
5
-COOH : axit e - amino caporic.
(3). H
2
N-[CH
2
]
6
-COOH: axit c - amino enantoic.
(4). HOOC-[CH
2
]
2
-CH(NH
2
)-COOH : Axit o - amino Glutaric.
(5). H
2
N-[CH
2
]
4
-CH (NH
2
)-COOH : Axit o,c - iamino caporic.
A. 2 B. 3 C. 4 D.5
Cu 72: Trong cc cht di y, cht no l glixin?
A. H
2
N-CH
2
-COOH B. CH
3
CH(NH
2
)COOH
C. HOOC-CH
2
CH(NH
2
)COOH D. H
2
NCH
2
-CH
2
COOH
Cu 73: Dung dch ca cht no sau y khng lm i mu qu tm :
A. Glixin (CH
2
NH
2
-COOH) B. Lizin (H
2
NCH
2
-[CH
2
]
3
CH(NH
2
)-COOH)
C. Axit glutamic (HOOCCH
2
CHNH
2
COOH) D. Natriphenolat (C
6
H
5
ONa)
Cu 74: Cho 0,1 mol mt -aminoaxit A dng H
2
NRCOOH phn ng ht vi HCl to thnh 11,15gam
mui. A l cht no sau y
A. Glixin B. Alanin C. Phenylalanin D. Valin
Cu 75: Cht no sau y va tc dng c vi H
2
NCH
2
COOH, va tc dng c vi CH
3
NH
2
?
A. NaCl. B. HCl. C. CH3OH. D. NaOH.
Cu 76: X l mt -aminoaxit no ch cha mt nhm NH
2
v mt nhm COOH. Cho 10,3gam X tc
dng vi dung dch HCl d thu c 13,95gam mui clohidrat ca X. Cng thc cu to thu gn ca X l
CH
3
CH(NH
2
)COOH B. NH
2
CH
2
COOH
C. NH
2
CH
2
CH
2
COOH D.CH
3
CH
2
CH(NH
2
)COOH
Cu 77: Bradikinin c tc dng lm gim huyt p, l mt nonapeptit c cng thc l:
Arg Pro Pro Gly-Phe-Ser-Pro-Phe-Arg.
Khi thy phn khng hon ton peptit ny c th thu c bao nhiu tri peptit m thnh phn c cha
phenyl alanin ( phe) ?
A. 4 B. 6 C. 5 D. 3
wWw.VipLam.Net
7

Cu 78: Cht rn khng mu, d tan trong nc, kt tinh iu kin thng l
A. C
6
H
5
NH
2
. B. C
2
H
5
OH. C. H
2
NCH
2
COOH. D. CH
3
NH
2
.
Cu 79: Cht tham gia phn ng trng ngng l
A. C
2
H
5
OH. B. CH
2
= CHCOOH. C. H
2
NCH
2
COOH. D. CH
3
COOH.
Cu 80: Cho dy cc cht: C
6
H
5
NH
2
(anilin), H
2
NCH
2
COOH, CH
3
CH
2
COOH, CH
3
CH
2
CH
2
NH
2
, C
6
H
5
OH
(phenol). S cht trong dy tc dng c vi dung dch HCl l
A. 4. B. 2. C. 3. D. 5.
Cu 81: chng minh aminoaxit l hp cht lng tnh ta c th dng phn ng ca cht ny ln lt vi
A. dung dch KOH v dung dch HCl. B. dung dch NaOH v dung dch
NH
3
.
C. dung dch HCl v dung dch Na
2
SO
4
. D. dung dch KOH v CuO.
Cu 82: X l mt cht hu c c cng thc phn t C
5
H
11
O
2
N. un X vi NaOH thu c mt hn hp
cht c cng thc phn t C
2
H
4
O
2
NNa v cht hu c (Y), cho hi Y qua CuO thu c cht hu
c Z c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l
A. CH
3
(CH
2
)
4
NO
2
. C.NH
2
-CH
2
-COO-CH
2
-CH
2
-CH
3
.
B. NH
2
-CH
2
-COO(CHCH
3
)
2
D. H
2
N-CH
2
-CH
2
-COOC
2
H
5

Cu 83: Axit aminoaxetic (H
2
NCH
2
COOH) tc dng c vi dung dch
A. NaNO
3
. B. NaCl. C. NaOH. D. Na
2
SO
4
.
Cu 84: Dung dch ca cht no trong cc cht di y khng lm i mu qu tm ?
A. CH
3
NH
2
. B. NH
2
CH
2
COOH
C. HOOCCH
2
CH
2
CH(NH
2
)COOH. D. CH
3
COONa.
Cu 85: phn bit 3 dung dch H
2
NCH
2
COOH, CH
3
COOH v C
2
H
5
NH
2
ch cn dng mt thuc th l
A. dung dch NaOH. B. dung dch HCl. C. natri kim loi. D. qu tm.
Cu 86: C cc dung dch ring bit sau:
C
6
H
5
-NH
3
Cl (phenylamoni clorua), H
2
N-CH
2
-CH
2
-CH(NH
2
)-COOH, ClH
3
N-CH
2
-COOH, HOOC-CH
2
-
CH
2
-CH(NH
2
)-COOH, H
2
N-CH
2
-COONa. S lng cc dung dch c pH < 7 l
A. 2. B. 5. C. 4. D. 3.
Cu 87: Thy phn hp cht H
2
N-CH
2
-CO-NH-CH-CO-NH-CH-CO-NH-CH
2
-COOH

thu c cc aminoaxit no sau y
A. H
2
N-CH
2
-COOH B. HOOC-CH
2
-CH(NH
2
)COOH
C. C
6
H
5
CH
2
CH(NH
2
)COOH D. Hn hp 3 aminoaxit trn
Cu 88: Pht biu no di y v amino axit l khng ng?
A. Hp cht H
2
NCOOH l amino axit n gin nht
B. Thng thng dng ion lng cc l dng tn ti chnh ca amino axit
C. Amino axit ngoi dng phn t (H
2
NRCOOH) cn c dng ion lng cc (H
3
N
+
RCOO
-
)
D.Amino axit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl
Cu 89: Glixin khng tc dng vi
A. H
2
SO
4
long. B. CaCO
3
. C. C
2
H
5
OH. D. NaCl.
Cu 90: Trong cc cht sau: Cu, HCl, C
2
H
5
OH, HNO
2
, KOH, Na
2
SO
3
, CH
3
OH/kh HCl. Axit aminoaxetic
tc dng c vi nhng cht no
A. HCl, HNO
2
, KOH, Na
2
SO
3
, CH
3
OH/kh HCl
B. C
2
H
5
OH, HNO
2
, KOH, Na
2
SO
3
, CH
3
OH/kh HCl, Cu
C. HNO
2
, KOH, Na
2
SO
3
, CH
3
OH/kh HCl, Cu, HCl
D. Tt c cc cht
Cau 91. Cho cac nhan nh sau:
(1). Alanin lam quy tm hoa xanh. (2). Axit Glutamic lam quy tm hoa o.
CH
2
-COOH CH
2
-C
6
H
5

wWw.VipLam.Net
8

(3). Lysin lam quy tm hoa xanh. (4). Axit c - amino caporic la nguyen lieu e
san xuat nilon 6.
So nhan nh ung la:
A. 1 B. 2 C.3 D.4
Cau 92. Mot amino axit co cong thc phan t la C
4
H
9
NO
2
. So ong phan amino axit
la
A. 3 B. 4 C. 5 D.6
Cau 93: 1 thuoc th co the nhan biet 3 chat hu c : axit aminoaxetic, axit propionic,
etylamin la
A. NaOH. B. HCl. C. Qu tm. D. CH
3
OH/HCl.
Cau 94: Hp chat A co cong thc phan t CH
6
N
2
O
3
. A tac dung c vi KOH tao ra
mot baz va cac chat vo c. CTCT cua A la
A. H
2
N COO NH
3
OH. B. CH
3
NH
3
+
NO
3
-
.
C. HONHCOONH
4
. D. H
2
N-CHOH-NO
2
.
Cau 95: Cho cac cau sau:
(1). Peptit la hp chat c hnh thanh t 2 en 50 goc o amino axit.
(2). Tat ca cac peptit eu phan ng mau biure.
(3). T 3 o- amino axit ch co the tao ra 3 tripeptit khac nhau.
(4). Khi un nong dung dch peptit vi dung dch kiem, san pham se co phan ng
mau biure.
So nhan xet ung la:
A. 1 B. 2 C. 3 D. 4
Cau 96: Peptit co cong thc cau tao nh sau:
H
2
N-CH-CO-NH-CH
2
-CO-NH-CH-COOH
CH
3
CH(CH
3
)
2
.
Ten goi ung cua peptit tren la:
A. Ala-Ala-Val. B. Ala-Gly-Val. C. Gly Ala Gly. D. Gly-Val-Ala.
Cau 97: Cong thc nao sau ay cua pentapeptit (A) thoa ieu kien sau:
+ Thuy phan hoan toan 1 mol A th thu c cac o- amino axit la: 3 mol Glyxin , 1 mol
Alanin, 1 mol Valin.
+ Thuy phan khong hoan toan A, ngoai thu c cac amino axit th con thu c 2 i
peptit: Ala-Gly ; Gly- Ala va 1 tripeptit Gly-Gly-Val.
A. Ala-Gly-Gly-Gly-Val. B. Gly-Gly-Ala-Gly-Val.
C. Gly-Ala-Gly-Gly-Val. D. Gly-Ala-Gly-Val-Gly.
Cau 98: Thuy phan khong hoan toan tetra peptit (X), ngoai cac o- amino axit con thu
c cac i petit: Gly-Ala; Phe-Va; Ala-Phe. Cau tao nao sau ay la ung cua X.
A. Val-Phe-Gly-Ala. B. Ala-Val-Phe-Gly.
C. Gly-Ala-Val-Phe D. Gly-Ala-Phe Val.
Cau 99: e phan biet xa phong, ho tinh bot, long trang trng ta se dung thuoc
th nao sau ay:
A. Ch dung I
2
. B. Ch dung Cu(OH)
2
.
C. Ket hp I
2
va Cu(OH)
2
. D. Ket hp I
2
va AgNO
3
/NH
3
.
Cau 100: Cho cac cau sau:
(1) Amin la loai hp chat co cha nhom NH
2
trong phan t.
(2) Hai nhom chc COOH va NH
2
trong amino axit tng tac vi nhau thanh ion
lng cc.
(3) Poli peptit la polime ma phan t gom 11 en 50 mac xch o-amino axit noi
vi nhau bi cac lien ket peptit.
(4) Protein la polime ma phan t ch gom cac polipeptit noi vi nhau bang
lien ket peptit.
Co bao nhieu nhan nh ung trong cac nhan nh tren:
A.1 B.2 C.3 D.4
Cau 101: Hp chat nao sau ay khong phai la amino axit.
A. H
2
N-CH
2
-COOH. B. CH
3
-NH-CH
2
-COOH.
C. CH
3
CH
2
-CO- NH
2
D.HOOC-CH
2
(NH
2
)-CH
2
COOH.
Cau 102: Cho cac cong thc sau: So CTCT ng vi ten goi ung
(1). H
2
N CH
2
-COOH: Glyxin
(2). CH
3
-CHNH
2
-COOH : Alanin.
(3). HOOC- CH
2
-CH
2
-CH(NH
2
)-COOH:Axit Glutamic.
(4). H
2
N (CH
2
)
4
-CH(NH
2
)COOH : lysin.
A. 1 B.2 C.3 D.4
Cau 103: Polipeptit (-NH-CH
2
-CO-)
n
la san pham cua phan ng trung ngng:
A. axit glutamic B. glyxin. C. axit |-amino propionic D.alanin.
wWw.VipLam.Net
9

Cau 104: Hp chat H
2
N-CH
2
-COOH phan ng c vi:
(1). NaOH. (2). CH
3
COOH. (3). C
2
H
5
OH
A. (1,2) B. (2,3) C. (1,3). D. (1,2,3).
Cau 105: Cho cac chat sau ay: (1). Metyl axetat. (2). Amoni axetat.
(3). Glyxin.
(4). Metyl amoni fomiat. (5). Metyl amoni nitrat (6). Axit Glutamic.
Co bao nhieu chat lng tnh trong cac chat cho tren:
A.2 B.3 C.4 D.5
Cau 106: Amino axit co bao nhieu phan ng cho sau ay : phan ng vi axit, phan
ng vi baz, phan ng trang bac, phan ng trung hp, phan ng trung ngng,
phan ng vi ancol, phan ng vi kim loai kiem.
A. 3 B.4 C.5 D.6
Cau 107: Cho s o bien hoa sau: Alanin
NaOH +
X
HCl +
Y. Chat Y la chat nao
sau ay:
A. CH
3
-CH(NH
2
)-COONa. B. H
2
N-CH
2
-CH
2
-COOH.
C. CH
3
-CH(NH
3
Cl)COOH D.CH
3
CH(NH
3
Cl)COONa.


PHN II: PHN LOI, CNG C CC DNG BI TP
CHNG 3: AMIN AMINO AXIT PEPTIT PROTEIN

DNG 1: TON T CHY AMIN
* PHN NG T CHY AMIN
- Amin no n chc:
C
n
H
2n+3
N +
6 3
4
n +
O
2
nCO
2
+
2 3
2
n +
H
2
O +
1
2
N
2

- Amin thm:
C
n
H
2n-5
N +
6 5
4
n
O
2
nCO
2
+
2 5
2
n
H
2
O +
1
2
N
2

- Amin tng qut:
C
x
H
y
N
t
+
4
y
x
| |
+
|
\ .
O
2
xCO
2
+
2
y
H
2
O +
1
2
N
2

* LU :
- Khi t chy mt amin ta lun c: n
O 2 phn ng
= n
CO2
+ n
H2O

- Khi t chy mt amin ngoi khng kh th: n
N2 sau p
= n
N2 sinh ra t p chy amin
+ n
N2 c sn trong khng kh

CC V D:
Cu 1: t chy hon ton mt amin no, n chc, bc 1 mch h thu c t l mol CO
2
v H
2
O l 4:7.
Tn amin l?
A. Etyl amin B. imetyl amin C. Metyl amin D. Propyl amin
Cu 2: t chy hon ton a mol amin no, n chc thu c 13,2g CO
2
v 8,1g H
2
O. Gi tr ca a l?
A. 0,05 B. 0,1 C. 0,07 D. 0,2
Cu 3: t chy hon ton amin no, n chc vi t l s mol CO
2
v hi H
2
O l T. T nm trong khong no
sau y?
A. 0,5 T < 1 B. 0,4 T 1 B. 0,4 T < 1 D. 0,5 T 1
Cu 4: t chy hon ton mt ng ng X ca Anilin th t l n
CO2
: n
H2O
= 1,4545. CTPT ca X l?
A. C
7
H
7
NH
2
B. C
8
H
9
NH
2
C. C
9
H
11
NH
2
D. C
10
H
13
NH
2

Cu 5: t chy hon ton m (g) hn hp gm 3 amin thu c 3,36 (l) CO
2
(ktc); 5,4(g) H
2
O v 1,12 (l)
N
2
(ktc). Gi tr ca m l?
A. 3.6 B. 3,8 C. 4 D. 3,1
Cu 6 (HKA-2007): Khi t chy hon ton mt amin n chc X, thu c 8,4 (l) CO
2
, 1,4 (l) N
2
(cc
th tch o ktc) v 10,125g H
2
O. Cng thc phn t ca X l?
A. C
3
H
7
N B. C
2
H
7
N C. C
3
H
9
N D. C
4
H
9
N
Cu 7 (HKB 2010): t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va thu c 0,5
mol hn hp Y gm kh v hi. Cho 4,6g X tc dng vi dung dch HCl d, s mol HCl phn ng l?
A. 0,1 B. 0,4 C. 0,3 D. 0,2
wWw.VipLam.Net
10

Cu 8: t chy amin A vi khng kh (N
2
v O
2
vi t l mol 4:1) va , sau phn ng thu c 17,6g
CO
2
; 12,6g H
2
O v 69,44 lt N
2
(ktc). Khi lng ca amin l?
A. 9,2g B. 9g C. 11g D. 9,5g
Cu 9 (HKA 2010): t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt
hn hp gm kh CO
2
; N
2
v hi H
2
O (cc th tch o cng iu kin). Amin X tc dng vi axit nitr
nhit thng gii phng kh N
2
. Cht X l?
A. CH
2
=CH-NH-CH
3
B. CH
3
-CH
2
-NH-CH
3

C. CH
3
-CH
2
-NH
2
D. CH
2
=CH-CH
2
-NH
2

Cu 10 (HKA 2010): Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c
kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO
2
, x
mol H
2
O v y mol N
2
. Cc gi tr x v y tng ng l?
A. 8 v 1,0 B. 8 v 1,5 C. 7 v 1,0 D. 7 v 1,5

wWw.VipLam.Net
11


DNG 2: AMIN TC DNG VI AXIT, MUI
1. PHN NG VI DUNG DCH AXIT
Vi amin A, bc 1, c a nhm chc:
R(NH
2
)
a
+ aHCl R(NH
3
Cl)
a

S nhm chc amin: a =
HCl
A
n
n
v m
mui
= m
amin
+ m
HCl
(LBTKL)
2. VI DUNG DCH MUI CA KIM LOI
Mt s mui d to kt ta hidroxit vi dung dch amin.
AlCl
3
+ 3CH
3
NH
2
+ 3H
2
O Al(OH)
3
+ + 3CH
3
NH
3
Cl
* Lu : tng t NH
3
, cc amin cng to phc cht tan vi Cu(OH)
2
, Zn(OH)
2
, AgCl...
V D: Sc kh CH
3
NH
2
ti d vo dung dch CuCl
2
th hin tng xy ra?
2CH
3
NH
2
+ CuCl
2
+ 2H
2
O Cu(OH
)2 +
+ 2CH
3
NH
3
Cl
Xanh nht
Cu(OH)
2
+ 4CH
3
NH
2
[Cu(CH
3
NH
2
)
4
](OH)
2
Phc tan mu xanh thm
CC V D
Cu 1: Cho 9,3g mt amin no, n chc, bc 1 tc dng vi dung dch FeCl
3
d, thu c 10,7g kt ta. CTPT
ca amin l?
A. CH
3
NH
2
B. C
2
H
5
NH
2
C. C
3
H
7
NH
2
D. C
4
H
9
NH
2

Cu 2: Cho 0,4 mol mt amin no, n chc tc dng vi dung dch HCl va thu c 32,6g mui. CPTP
ca amin l?
A. CH
3
NH
2
B. C
2
H
5
NH
2
C. C
3
H
7
NH
2
D. C
4
H
9
NH
2

Cu 3(HKA 2009): Cho 10g mt amin n chc X phn ng hon ton vi HCl d, thu c 15g mui.
S ng phn cu to ca X l?
A. 8 B. 7 C. 5 D. 4
Cu 4 (C 2007): trung ha 25g dung dch ca mt amin n chc X nng 12,4% cn dng 100ml
dung dch HCl 1M. CTPT ca X l?
A. C
3
H
5
N B. C
2
H
7
N C. CH
5
N D. C
3
H
7
N
Cu 5: (HKB 2008): Mui C
6
H
5
N
2
+
Cl
-
(Phenyliazoni) c sinh ra khi cho C
6
H
5
NH
2
tc dng vi
NaNO
2
trong HCl nhit thp (0 5
o
C). iu ch c 14,05g C
6
H
5
N
2
+
Cl
-
( H = 100%) th lng
C
6
H
5
NH
2
v NaNO
2
cn dng va l?
A. 0,1 mol v 0,4 mol B. 0,1 mol v 0,2 mol
C. 0,1 mol v 0,1 mol D. 0,1 mol v 0,3 mol
Cu 6 (C 2010) : Cho 2,1g hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn
ng ht vi dung dch HCl d, thu c 3,925g hn hp mui. Cng thc ca 2 amin trong hn hp X l?
A. CH
3
NH
2
v C
2
H
5
NH
2
B. C
2
H
5
NH
2
v C
3
H
7
NH
2

C. C
3
H
7
NH
2
v C
4
H
9
NH
2
D. CH
3
NH
2
v (CH
3
)
3
N
Cu 7 (HKB 2010) : Trung ha hon ton 8,88g mt amin bc 1, mch cc bon khng phn nhnh bng
axit HCl to ra 17,64g mui. Amin c cng thc l?
A. H
2
N(CH
2
)
4
NH
2
B. CH
3
CH
2
CH
2
NH
2

C. H
2
NHCH
2
CH
2
NH
2
D. H
2
NCH
2
CH
2
CH
2
NH
2

Cu 8: Hn hp X gm 2 mui AlCl
3
v CuCl
2
. Ha tan hn hp X vo nc thu c 200ml dung dch A.
Sc kh metyl amin ti d vo dung dch A thu c 11,7g kt ta. Mt khc, cho t t dd NaOH ti d vo
dung dch A thu c 9,8g kt ta. Nng mol/l ca AlCl
3
v CuCl
2
trong dd A ln lt l?
A. 0,1M v 0,75M B. 0,5M v 0,75M C. 0,75M v 0,5M D. 0,75M v 0,1M
Cu 9: Cho 20g hn hp 3 amin no n chc l ng ng k tip c t l mol tng ng l 1 : 10 : 5, tc
dng va vi dung dch HCl thu c 31,68g hn hp mui. CTPT ca amin nh nht l?
A. CH
3
NH
2
B. C
2
H
5
NH
2
C. C
3
H
7
NH
2
D.C
4
H
9
NH
2


wWw.VipLam.Net
12


DNG 3: GII TON AMINOAXIT
- Cng thc chung ca amino axit: (H
2
N)
a
R (COOH)
b

- Da vo phn ng trung ho vi dung dch kim xc nh b
PTPU: (H
2
N)
a
R (COOH)
b
+bNaOH (H
2
N)
a
R (COONa)
b
+ bH
2
O
min
NaOH
a
n
n
= b = s nhm chc axit COOH
- Da vo phn ng vi dd axit xc nh a
PTPT: (H
2
N)
a
R (COOH)
b
+ aHCl (ClH
3
N)
a
R (COOH)
b
min
HCl
a
n
n
= a = s nhm chc bazo NH
2

CC V D:
Cu 1: Cho 0,1 mol o -aminoaxit phn ng va vi 200ml dung dch HCl 0,5M thu c dung dch A.
Cho dung dch NaOH 0,5M vo dung dch A th thy cn va ht 600ml. S nhm NH
2
v COOH ca
axitamin ln lt l?
A. 1 v 1 B. 1 v 3 C. 1 v 2 D. 2 v 1
Cu 2: Cho 0,01 mol amino axit A tc dng va vi 80ml dung dch HCl 0,125M. C cn dung dch
c 1,835g mui. Khi lng phn t ca A l?
A. 97 B. 120 C. 147 D. 157
Cu 3 (C 2008): Trong phn t amino axit X c mt nhm amino v mt nhm cacboxyl. Cho 15g X tc
dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4g mui khan. Cng thc ca
X l?
A. H
2
NC
3
H
6
COOH B. H
2
NCH
2
COOH
C. H
2
NC
2
H
4
COOH D. H
2
NC
4
H
8
COOH
Cu 4 (HKB 2009): Cho 0,02 mol amino axit X tc dng va vi 200ml dung dch HCl 0,1M thu
c 3,67g mui khan. Mt khc, 0,02 mol X tc dng va vi 40g dung dch NaOH 4%. Cng thc ca
X l?
A. (H
2
N)
2
C
3
H
5
COOH B. H
2
NC
2
H
3
(COOH)
2

C. H
2
NC
3
H
6
COOH D. H
2
NC
3
H
5
(COOH)
2

Cu 5: Hp cht Y l mt o aminoaxit. Cho 0,02 mol Y tc dng va vi 80ml dd HCl 0,25M. Sau c
cn c 3,67g mui. Mt khc, trung ha 1,47g Y bng mt lng va dung dch NaOH,c cn dung
dch thu c 1,91g mui. Bit Y c cu to mch khng nhnh. CTCT ca Y l ?
A. H
2
NCH
2
CH
2
COOH B. CH
3
CH(NH
2
)COOH
C. HOOCCH
2
CH
2
CH(NH
2
)COOH D. HOOCCH
2
CH(NH
2
)COOH
Cu 6: Cho 0,2 mol o amino axit X phn ng va vi 100ml dd HCl 2M thu c dung dch A. Cho
dung dch A phn ng va vi dd NaOH, sau phn ng, c cn sn phm thu c 33,9g mui. X c tn
gi l?
A. Glyxin B. Alanin C. Valin D. Axit glutamic
Cu 7 (HKA 2009): Cho 1 mol amino axit X phn ng vi dung dch HCl d thu c m
1
gam mui Y.
Cng 1 mol amino axit X phn ng vi dung dch NaOH d, thu c m
2
gam mui Z. Bit m
2
m
1
= 7,5. Cng
thc phn t ca x l?
A. C
4
H
10
O
2
N
2
B. C
5
H
9
O
4
N C. C
4
H
8
O
4
N
2
D. C
5
H
11
O
2
N
Cu 8 (HKB 2010): Hn hp X gm Alanin v axit glutamic. Cho m g X tc dng hon ton vi dd
NaOH d, thu c dd Y cha ( m + 30,8) g mui. Mt khc, nu cho m g X tc dng hon ton vi dung
dch HCl, thu c dd Z cha ( m + 36,5)g mui. Gi tr ca m l?
A. 112,2 B. 165,6 C. 123,8 D. 171,0
Cu 9 (HKA 2010): Cho 0,15 mol H
2
NC
3
H
5
(COOH)
2
(axit glutamic) vo 175ml dd HCl 2M thu c
dd X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l?
A. 0,50 B. 0,65 C. 0,70 D. 0,55
Cu 10: X l mt o amino axit c cng thc tng qut dng H
2
N R COOH. Cho 8,9g X tc dng vi
200ml dung dch HCl 1M , thu c dung dch Y. phn ng vi ht vi cc cht trong dd Y cn dng
300ml dd NaOH 1M. Cng thc cu to ng ca X l ?
A. H
2
N-CH
2
-COOH B. H
2
N-CH
2
-CH
2
-COOH
wWw.VipLam.Net
13

C. CH
3
CH(NH
2
)COOH D. CH
3
CH
2
CH(NH
2
)COOH

DANG 4: GII TON MUI AMONI, ESTE CA AMINO AXIT

- Cng thc chung ca mui amoni: H
2
N R COONH
4
hoc H
2
N R COOH
3
NR
- Cng thc chung este ca amino axit: H
2
N R COOR
- Mui amoni, este ca amino axit l hp cht lng tnh:
H
2
N R COONH
3
R + HCl ClH
3
N R COONH
3
R
H
2
N R COONH
3
R + NaOH H
2
N R COONa + RNH
2
+ H2O
* CH : Thng s dng nh lut bo ton khi lng gii cc bi ton dng ny.

CC V D:

Cu 1 (C-2010): ng vi CTPT C
2
H
7
O
2
N c bao nhiu cht va phn ng c vi dung dch NaOH va
phn ng c vi HCl?
A. 2 B. 3 C. 1 D. 4
Cu 2 (C-2009): Cht X c CTPT C
3
H
7
O
2
N v lm mt mu dung dch brom. Tn gi ca X l
A. Axit -aminopropionic B. Mety aminoaxetat
C. Axit o -aminopropionic D. Amoni acrylat
Cu 3: Cho 2 hp cht hu c X, Y c cng cng thc phn t l C
3
H
7
NO
2
. Khi phn ng vi NaOH, X to
ra H
2
NCH
2
COONa v hp cht hu c Z; cn Y to ra CH
2
=CH COONa v kh T. Cc cht Z v T ln lt
l
A. CH
3
OH v CH
3
NH
2
B. C
2
H
5
OH v N
2

C. CH
3
OH v NH
3
D. CH
3
NH
2
v NH
3

Cu 4 (C-2009): Cht X c CTPT C
4
H
9
O
2
N. Bit:
X + NaOH Y + CH
4
O
Y + HCl (d) Z + NaOH
CTCT ca X v Z ln lt l:
A. H
2
NCH
2
CH
2
COOCH
3
v CH
3
CH(NH
3
Cl)COOH
B. CH
3
CH(NH
2
)COOCH
3
v CH
3
CH(NH
3
Cl)COOH
C. H
2
NCH
2
COOC
2
H
5
v ClH
3
NCH
2
COOH
D. CH
3
CH(NH
2
)COOCH
3
v CH
3
CH(NH
2
)COOH
Cu 5 (HKA- 2009): Hp cht X mch h c CTPT C
4
H
9
NO
2
. Cho 10,3 g X phn ng va vi dung
dch NaOH sinh ra mt kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu
xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan.
Gi tr ca m l:
A. 8,2 B. 10,8 C. 9,4 D. 9,6
Cu 6 (HKB-2009): Este X (c KLPT=103 vC) c iu ch t mt ancol n chc (c t khi hi so
vi oxi >1) v mt amino axit. Cho 25,75 g X phn ng ht vi 300ml dung dch NaOH 1M, thu c dung
dch Y. C cn Y thu c m gam cht rn. Gi tr ca m l
A. 29,75 B. 27,75 C. 26,25 D. 24,25
Cu 7 (C-2009): Cho 1,82 gam hp cht hu c n chc, mch h X c CTPT C
3
H
9
O
2
N tc dng va
vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan.
CTCT thu gn ca X l
A. CH
3
CH
2
COONH
4
B. CH
3
COONH
3
CH
3

C. HCOONH
2
(CH
3
)
2
D. HCOONH
3
CH
2
CH
3

Cu 8 (HKA-2007): Cho hn hp X gm 2 cht hu c c cng CTPT C
2
H
7
NO
2
tc dng va vi dung
dch NaOH v un nng, thu c dung dch Y v 4,48l hn hp Z (kc) gm 2 kh (u lm xanh giy qu
m). t khi hi ca Z i vi H
2
= 13,75. c cn dung dch Y thu c khi lng mui khan l
A. 16,5 gam B. 14,3 gam C. 8,9 gam D. 15,7 gam
Cu 9 (CKA,B-2007): Hp cht X c CTPT trng vi cng thc n gin nht, va tc dng c vi axit
va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng
ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73% cn li l oxi. Khi cho 4,45 gam X
wWw.VipLam.Net
14

phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan.
CTCT thu gn ca X l:
A. CH
2
=CHCOONH
4
B. H
2
N-COOCH
2
-CH
3

C. H
2
N-CH
2
-COOCH
3
D. H
2
NC
2
H
4
COOH
Cu 10 (HKB-2008): Cho cht hu c X c CTPT C
2
H
8
O
3
N
2
tc dng vi dung dch NaOH, thu c
cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l:
A. 85 B. 68 C. 45 D. 46

DNG 5: BI TON PROTEIN PEPTIT
- Peptit c cu to t cc gc o -aminoaxit
- T n phn t o -aminoaxit khc nhau th c n! ng phn peptit (s peptit cha cc gc o -aminoaxit khc
nhau)
- T n phn t o -aminoaxit khc nhau th c n
2
s peptit c to thnh
- Phn ng thy phn khng hon ton peptit cho sn phm c th l o -aminoaxit, hoc ipeptit, hoc
tripeptit ...
- Phn ng thy phn hon ton peptit cho sn phm l cc gc o -aminoaxit.

CC V D:

Cu 1 (HKB-2009): S ipeptit ti a c th to ra t 1 hn hp gm alanin v glyxin l:
A. 2 B. 3 C. 4 D. 1
Cu 2 (HKA-2010): C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c
3 aminoaxit: glyxin, alanin v phenylalanin?
A. 3 B.9 C. 4 D. 6
Cu 3(HKA-2009): Thuc th c dng phn bit gly-ala-gly vi gly-ala l:
A. Cu(OH)
2
trong mi trng kim B. Dung dch NaCl
C. Dung dch HCl D. Dung dch NaOH
Cu 4 (HKB-2008): un nng cht H
2
N-CH
2
-CONH-CH(CH
3
)-CONH-CH
2
-COOH trong dung dch HCl
d, sau khi cc phn ng kt thc thu c sn phm l:
A. H
2
N-CH
2
-COOH, H
2
N-CH
2
-CH
2
-COOH
B. H
3
N
+
-CH
2
-COOHCl
-
, H
3
N
+
-CH
2
-CH
2
-COOHCl
-

C. H
3
N
+
-CH
2
-COOHCl
-
, H
3
N
+
-CH(CH
3
)-COOHCl
-

D. H
2
N-CH
2
-COOH, H
2
N-CH(CH
3
)-COOH
Cu 5 (C-2010): Nu thy phn khng hon ton pentapeptit gly-ala-gly-ala-gly th thu c ti a bao
nhiu ipeptit khc nhau?
A. 3 B. 1 C. 2 D. 4
Cu 6 (HKB-2010): Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (gly), 1 mol alanin
(ala), 1mol valin (val) v 1 mol phenylalanin (phe). Thy phn khng hon ton X thu c ipeptit val-phe
v tripeptit gly-ala-val nhng khng thu c ipptit gly-gly. Cht X c cng thc l:
A. gly-phe-gly-ala-val B. gly- ala-val- val-phe
C. gly- ala-val-phe-gly D. val-phe-gly-ala-gly
Cu 7(C-2009): Thy phn 1250gam protein X thu c 425gam alanin. Nu phn t khi ca X bng
100000 vC th s mt xch alanin c trong phn t X l
A. 453 B. 382 C. 328 D. 479
Cu 8 (HKB-2010): ipeptit mch h X v tripeptit mch h Y u c to nn t 1 aminoaxit (no,
mch h, trong phn t cha 1 nhm NH
2
v 1 nhm COOH). t chy hon ton 0,1 mol Y, thu c
tng khi lng CO
2
v H
2
O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t
qua nc vi trong d, to ra m gam kt ta. Gi tr m l:
A. 120 B. 60 C. 30 D. 45