S Gio dc v o to

h nam
chnh thc

K thi thnh lp i tuyn d thi chn hc sinh

gii quc gia lp 12 THPT

Nm hc 2007-2008

( thi c 02 trang)

Mn: HO HC (Thi gian lm bi 180 pht).

Cu 1 (2im).
Cho 2 nguyn t A v B. A thuc chu k 2, B thuc chu k 4. Trong bng di
y c ghi cc gi tr nng lng ion ho lin tip In (n=1,, 6) ca chng (theo
KJ/mol).
In
Nguyn t
A

I1

I2

I3

I4

I5

I6

1086

2352

4619

6221

37820

47260

590

1146

4942

6485

8142

10519

1. Xc nh A v B.
2. Tnh bc sng ca bc x phi dng c th tch c electron th nht ra
khi nguyn t B.
3. Tnh nng lng ca ion A+ v nguyn t A.
Cu 2. (2 im).
Cho ion phc [ Cr(H2O)2(NH3)2Br2]+
1. Vit v gi tn cc ng phn hnh hc ca ion phc.
2. p dng thuyt lai ho gii thch dng hnh hc ca ion phc?
Cu 3. (2 im).
Cho cc cht: BF3, CF4, NH3.
1. Vit cng thc Liuyt, cho bit cu trc hnh hc ca cc phn t, trng
thi lai ho ca nguyn t trung tm.
2. Cc cht c tc dng c vi nhau khng? N c vit phng trnh phn
ng.
Cu 4. (2 im).
Trong dung dch nc c pha axit v 1 cht xc tc, H 2O2 b phn hu theo phng trnh phn ng:

H2O2(l)

H2O(l)

+ 1/2O2(k)

Ngi ta cho dung dch ni trn vo 1 bnh c gi 250C, nng ca

H2O2 l 1M. Hng s tc ca phn ng bng 7,689.10-3 pht-1.
1. Sau bao lu th nng ca H2O2 cn 0,794 M?
2. Tnh tc phn ng lc u v sau 90 pht.
3. 500C hng s tc phn ng l 0,129 pht -1. Tnh nng lng hot ho
ca phn ng?
Cu 5. (2 im).
Cho E0AgI/Ag = -0,145V;
= 1,19V
E0
ClO4-, H +/ ClO3-

1. Tnh EoAg+/Ag bit pKsAgI = 16.

2. Thit lp s pin gm in cc Pt nhng trong dung dch NaClO 4
0,001M v NaClO3 0,1M pH=8,3 ghp vi in cc Ag nhng trong dung dch KI
0,01M c cha kt ta AgI. Tnh sc in ng ca pin v vit phng trnh
phn ng xy ra khi pin hot ng.

Cu 6 (2 im).
Vit cng thc cu to ca sn phm chnh v gii thch s hnh thnh ca
sn phm ?

NaCN/HCN

1. OHC - CH2 - CH2 - COOH

NBS

2. Octen-1

C5H5NO2

2 sn phm

3. C6H5 - CH = CH 2
4. CH2 = CH - CF3

HCHO

C9H12O2
dd H2SO4
HCl
C3H4ClF3

Cu 7. (2 im).
Hy so snh:
1. Tnh axit ca cc cht: phenol, m- NO2C6H4OH; p-NO2C6H4OH; m-ClC6H4OH;
p-CH3C6H4OH; m-CH3C6H4OH.
2. Nhit si ca pentaien-1,4 v pentaien- 1,3.
Cu 8. (2 im).
Hy cho bit cch thc hin cc chuyn ho sau y thu c sn phm
c hiu sut cao?

1. HOCH2C(CH3)2CH2Br
2. Br[CH2]3CHO

HOCH2C(CH3)2CH2D
CH2 = CH - CH 2 - CHO

Cu 9. (2 im).
Hp cht A c cng thc phn t C12H22O11, c th b thu phn nh xc tc
axit hoc enzim emusin hoc enzim mantaza v thu c sn phm hu c duy
nht l D- Glucozo. Cho A tc dng vi CH3I d trong mi trng kim thu c sn
phm B. Thu phn B ch thu c 2, 3, 4, 6 tetra O metylglucozo. Cht A tc
dng vi thuc th Tollen thy kt qu m. T cc d kin c hc sinh
ngh cu trc ca A nh sau:

OH

HO
HO

H
H

O
H
OH O

HO

OH
OH

HO

Hy nhn xt v cu trc trn?

Cu 10. (2 im).
A, B, C, D, E l nhng axit xiclobutanicacboxylic ng phn ca nhau. A
d dng to anhidrit ni phn t. B ch to anhidrit khi un nng lu. un khan C
sinh ra CO2, cn D v E khng thay i. Vit cu trc ca 5 axit trn, bit rng c
th tch D thnh 2 cht i quang.
---------------HT------------H v tn th sinh:................................................................................S bo
danh:...................................
Ch k ca gim th s 1:..............................................Ch k ca gim th s
2:.......................................