I. KHI NIM - DANH PHP II.

CU TO PHN T - TNH CHT VT L

III. TNH CHT HA HC

IV. NG DNG

I. KHI NIM - DANH PHP 1. Khi nim

L hp cht tp chc phn t cha ng thi nhm amino (NH2) v nhm cacboxyl (COOH)

I. KHI NIM - DANH PHP 2. Danh php

a. Tn thay th Axit + s ch v tr NH2 + amino

+ tn axit cacboxylic tng ng b. Tn bn h thng Axit + ch ci Hi Lp ch v tr NH2 + amino + tn thng axit cacboxylic tng ng

I. KHI NIM - DANH PHP 2. Danh php

b. Tn bn h thng

ch ci Hi Lp ch v tr NH2

Tn thay th

Tn bn h thng

Tn thng

K hiu

Axit 2-amino etanoic Axit 2-amino propanoic Axit 2-amino-3 -metylbtanoic Axit 2-amino petandioic Axit 2,6-iamino hexanoic

Axit amino axetic Axit -amino propionic Axit -amino isovaleric Axit -amino glutamic

glyxin
alanin

gly

ala

valin axit glutamic

val

glu

Axit ,-iamino caproic

lysin

lys

II. CU TO - TNH CHT VT L

dng phn t dng ion lng cc Hy in (ng) hoc S(sai) vo cc vung sau mi mnh di y:
Do c cu to ion lng cc nn iu kin thng cc aminoaxit: 1. l cht lng 2. d tan trong nc 3. c nhit nng chy thp S S 4. l cht rn 5. kh tan trong nc 6. c nhit nng chy cao S

III. TNH CHT HA HC

Tnh cht chung ca cc hp cht hu c cha nhm NH2 l Tnh cht chung ca cc hp cht hu c cha nhm COOH l

a. Lm i mu qu tm thnh xanh b. Phn ng vi baz mnh to mui c. Phn ng vi axit mnh to mui

a. Lm i mu qu tm thnh b. Phn ng vi baz mnh to mui c. Phn ng vi axit mnh to mui d. Tham gia phn ng este ha

III. TNH CHT HA HC

1. Tnh lng tnh 2. Tnh axit - baz 3. Tham gia phn ng este ha

4. Tham gia phn ng trng ngng

III. TNH CHT HA HC

1. Tnh cht lng tnh

Vit PTHH chng minh tnh lng tnh ca glyxin (H2NCH2COOH)?

III. TNH CHT HA HC

2. Tnh axit - baz ca dung dch aminoaxit
Th nghim 1: glyxin + quz tm Hin tng: Quz tm khng i mu Th nghim 2: axit glutamic + quz tm Hin tng: Quz tm chuyn sang mu hng Mi trng trung tnh

Mi trng axit

III. TNH CHT HA HC

2. Tnh axit - baz ca dung dch aminoaxit

x=y

mi trng trung tnh

(H2N)x R (COOH)y

x>y
x<y

mi trng baz
mi trng axit

III. TNH CHT HA HC

3. Phn ng ca nhm COOH (phn ng este ha)

III. TNH CHT HA HC

4. Phn ng trng ngng
+H-HN-[CH2]5-CO-OH + H-HN-[CH2]5-CO-OH + H-HN-[CH2]5-CO-OH+ -HN-[CH2]5-CO-HN-[CH2]5-CO-HN-[CH2]5-CO- + nH2O

nH-HN-[CH2]5-CO-OH
Axit -aminocaproic Policaproamit (nilon-6; t capron)

IV. NG DNG

Mui mono natri c axit glutamic

Axit glutamic l thuc h tr thn kinh

Nguyn liu sn xut nilon-6; nilon-7. c dng lm li nh c, o qun

Vit PTHH ca cc phn ng gia analin vi: NaOH, HCl v CH3OH c mt kh HCl bo ha.