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ee, we find that p, — 0, as it should.
c. Integrating over all space in spherical coordinates, we get
Ohh ae, Ga por 2/489 apt) rdrsin adOdg
=4n “eae exp(-u? )wdu- (4.8 apt)”
m, 9p
=4, my NT 4D nt)? =
Gap ae OS!)
In going from the first to the second line, we have made a change of
variable: 1/,/4D ,5f =u
20-16d. Let n=(1/4® jst). Then Eq. 20B.5-1 becomes
Pa =m, (n/2)"” exp(-nr?)
The limit of this function as 1 © is py = ,6(x)5(y)5(z). That is
we get a delta function in the three spatial variables. In other words,
all the material is "piled up" at the origin. [For more on this, see R. B.
Bird, C. F. Curtiss, R. C. Armstrong, and O. Hassager, Dynamics of
Polymeric Liquids, Vol. 2, Kinetic Theory, Wiley-Interscience, New
York (1987), SE.4, p. 405.]
20-1720B.6 Unsteady diffusion with first-order chemical reaction
(a) the thin disk catalyst particle
‘The reference problem is
20 a°o
=< :0(0,n) = 1;0(£1) =0
or apo) (+1)
‘The problem of interest here is
30 _ Ho
Oc On?
Attempt a solution of the form
Ko; o(0,n) = 1;@(+1) =0
@ = Ocxp(-Kt)
Putting this trial solution into the differential equation for @ gives the original equation
for ©, and the new equation also satisfies the initial an boundary conditions. It is our
desired solution.
(b) diffusion and reaction from a point source
Again we may write the solution by inspection as
st
p= ge
Here g is the normalized probability of finding a diffusing particle, originally at the
coordinate origin, at any point and time,
20-1320B.7 Simultaneous momentum, heat, and mass transfer:
alternate boundary conditions.
(a) With nao = 0, Eq. 20.2-51 gives the mass flux ratio
40 ~ WAco
1—wao
Re
Then with A = Se for binary diffusion, Eq. 20.2-52 gives the following implicit
equation for the dimensionless mass flux,
_ Ace 1
= BeOS.)
which can be solved conveniently with Fig. 22.8-5, Eq. 22.8-21, and Table 20.2-1,
in the manner of the solution given for Problem 20A.6.
(b) With w4 =0 and ngo = —2n,49, Eq. 20.2-51 gives the mass flux ratio
Then with A = Sc for diffusion in the binary gas phase, Eq. 20.2-52 gives the
following implicit equation for the dimensionless mass flux,
1
K = Lepcll(0,8e,K)
which ean be solved directly with the aid of Fig, 22.8-5, as noted in (a).
(c) A steady-state energy balance from the inner to the outer boundary of the
wall gives, for the region of laminar boundary layer,
PovoGpTa = proCpTo + 40
whence - -
G0 = poCp(Te — To) = na0Cp(Ta — To)
for this one-component system. With this substitution, Eq. 20.2-50 gives the energy
flux ratio
Rp = Maelo = Tes)
Then with A = Pr, Eq. 20.2-52 gives the following implicit equation for the dimen-
sionless mass flux,
20-1920B.8 Absorption from a pulsating bubble
a. The essential point here is the calculation of the-integral in
Eq. 20.1-72. Let the surface of the bubble oscillate between S, = 47R?
and S, = 472R}, with S,/S, 21, so that
s(t)=5, 2ns@tS2n+1 for n=0,1,2,-
S(t)=S, 2n+1<@t<2n+2 for n=0,1,2,-
We further let (S,/S,)?=r21. Then in each time region, we can
calculate the value of 1/t times the integral in Eq. 20.1-72 as follows:
2
1p S
O< ots: +2) df=1
1pve( $,) 1p (S 1(1
and the proposed solution can be written as
=A emp (
Eat
‘
q u
Ne 0q/ dt =-—+
~ a/ 2 gKE
a u
a __ 4,
du 2Kt
Sa_ 4, va
du’ Kt 4 K*t?
i
du? Bt 4K
The differential equation is satisfied.
(©) Simple inspection shows that these conditions are met.
lus “IEF fro FY
(b) For the square pulse one need only replace f by f, = P. yg and change
-ese2t!)
dt!
the lower limit of integration to “0