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CHUYN 9-10 : DNG TON AMINO AXIT, PEPTIT, PROTEIN Bi 1: X l mt Tetrapeptit cu to t Aminoacid A, trong phn t A c 1 nhm(-NH2), 1 nhm (-COOH) ,no, mch h. Trong A Oxi chim 42,67% khi lng. Thy phn m gam X trong mi trng acid th thu c 28,35(g) tripeptit; 79,2(g) ipeptit v 101,25(g) A. Gi tr ca m l? A. 184,5. B. 258,3. C. 405,9. D. 202,95. Bi 2: Thy phn hon ton 143,45 gam hn hp A gm hai tetrapeptit thu c 159,74 gam hn hp X gm cc Aminoacid (Cc Aminoacid ch cha 1nhm -COOH v 1 nhm -NH2 ) . Cho tan b X tc dng vi dung dch HCl d,sau c cn dung dch th nhn c m(gam) mui khan. Tnh khi lng nc phn ng v gi tr ca m ln lt bng? a. 8,145(g) v 203,78(g). b. 32,58(g) v 10,15(g). c. 16,2(g) v 203,78(g) d. 16,29(g) v 203,78(g). Bi 3:Tripeptit M v Tetrapeptit Q c to ra t mt aminoacid X mch h ( phn t ch cha 1 nhm NH2 ). Phn trm khi lng Nito trong X bng 18,667%. Thy phn khng hon ton m(g) hn hp M,Q(c t l s mol 1:1) trong mi trng Acid thu c 0,945(g) M; 4,62(g) ipeptit v 3,75 (g) X.Gi tr ca m? A. 4,1945(g). B. 8,389(g). C. 12,58(g). D. 25,167(g). Bi 4: Tripeptit mch h X v Tetrapeptit mch h Y u c to ra t mt aminoacid no,mch h c 1 nhm COOH v 1 nhm NH2 .t chy hon ton 0,1 mol X thu c sn phm gm H2O,CO2 v N2 trong tng khi lng CO2 v H2O bng 36,3(g) .Nu t chy hon ton 0,2 mol Y th s mol O2 cn phn ng l? a. 2,8(mol). b. 1,8(mol). c. 1,875(mol). d. 3,375 (mol) Bi 5: Thy phn hon ton 60(g) hn hp hai ipeptit thu c 63,6(g) hn hp X gm cc Aminoacid no mch h (H2NRCOOOH). Nu ly 1/10 hn hp X tc dng vi dung dch HCl d thu c m(g) mui. Gi tr ca m l? a. 7,82. b. 8,72. c. 7,09. d.16,3. Bi 6: Thy phn ht m(g) Tetrapeptit Ala-Ala-Ala-Ala thu c hn hp gm 28,48(g) Ala ; 32(g) Ala-Ala v 27,72(g) Ala-Ala-Ala. Gi tr ca m? a. 66,44. b. 111,74. c. 81,54. d. 90,6. Bi 7: X l mt Hexapeptit cu to t mt Aminoacid H2N-CnH2n-COOH(Y). Y c tng % khi lng Oxi v Nito l 61,33%. Thy phn ht m(g) X trong mi trng acid thu c 30,3(g) pentapeptit, 19,8(g) ieptit v 37,5(g) Y. Gi tr ca m l? a. 69 gam. B. 84 gam. c. 100 gam. d.78 gam. Bi 8: X l mt tetrapeptit cu to t mt amino axit (A) no, mch h c 1 nhm COOH ; 1 nhm NH2. Trong A %N = 15,73% (v khi lng). Thy phn m gam X trong mi trng axit thu c 41,58 gam tripeptit ; 25,6 gam ipeptit v 92,56 gam A. Gi tr ca m l : a. 149 gam. b. 161 gam. c. 143,45 gam. d. 159 gam. Bi 9: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp X v Y c t l s mol nX : nY = 1 : 3 vi 780 ml dung dch NaOH 1M (va ), sau khi phn ng kt thc thu c dung dch Z. C cn dung dch thu c 94,98 gam mui. m c gi tr l a.. 68,1 gam. b. 64,86 gam. c. 77,04 gam. d. 65,13 gam. Bi 10. ipeptit mch h X v Tripeptit mch h Y u c to ra t mt Aminoacid no,mch h c 1 nhm COOH v 1 nhm NH2 .t chy hon ton 0,1 mol Y thu c sn phm gm H2O,CO2 v N2 trong tng khi lng CO2 v H2O bng 54,9(g) .Nu t chy hon ton 0,2 mol X,sn phm thu c cho li qua dung dch nc vi trong d th c m(g) kt ta . Gi tr ca m l? a. 45. b. 120. c.30. d.60. Bi 11: X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h, c mt nhm COOH v mt nhm NH2. t chy hon ton 0,1 mol Y thu c sn phm gm CO2, H2O, N2, trong tng khi lng ca CO2 v H2O l 47,8 gam. Nu t chy hon ton 0,3 mol X cn bao nhiu mol O2 ? a. 2,8 mol. b. 2,025 mol. c. 3,375 mol. d. 1,875 mol. Bi 12: Thy phn 14(g) mt Polipeptit(X) vi hiu sut t 80%,thi thu c 14,04(g) mt - aminoacid (Y). Xc nh Cng thc cu to ca Y? a. H2N(CH2)2COOH.b. H2NCH(CH3)COOH. c. H2NCH2COOH d. H2NCH(C2H5)COOH Bi 13: un nng alanin thu c mt s peptit trong c peptit A c phn trm khi lng nit l 18,54%. Khi lng phn t ca A l : a. 231. b. 160. c. 373. d. 302. Bi 14: Khi thy phn hon ton 55,95 gam mt peptit X thu c 66,75 gam alanin (amino axit duy nht). X l : a. tripeptit. b. tetrapeptit. c. pentapeptit. d. ipeptit.

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Bi 15: Khi thy phn hon ton 65 gam mt peptit X thu c 22,25 gam alanin v 56,25 gam glyxin. X l : a. tripeptthu c. b. tetrapeptit. c. pentapeptit. d. ipeptit. Bi 16: Thu phn hon ton 500 gam mt oligopeptit X (cha t 2 n 10 gc -amino axit) thu c 178 gam amino axit Y v 412 gam amino axit Z. Bit phn t khi ca Y l 89. Phn t khi ca Z l : a. 103. b. 75. c. 117. d. 147. Bi 17: Tripeptit X c cng thc sau : H2NCH2CONHCH(CH3)CONHCH(CH3)COOH Thy phn hon ton 0,1 mol X trong 400 ml dung dch NaOH 1M. Khi lng cht rn thu c khi c cn dung dch sau phn ng l : a. 28,6 gam. b. 22,2 gam. c. 35,9 gam. d. 31,9 gam. Bi 18: Protein A c khi lng phn t l 50000 vC. Thu phn 100 gam A thu c 33,998 gam alanin. S mt xch alanin trong phn t A l : a. 191. b. 38,2. c. 2.3.1023 d. 561,8. Bi 19: Thy phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100000 vC th s mt xch alanin c trong X l : a. 453. b. 382. c. 328. d. 479. Bi 20: Xc nh Phn t khi gn ng ca mt Polipeptit cha 0,32% S trong phn t. Gi s trong phn t ch c 2 nguyn t S? a. 20.000(vC) b.10.000(vC). c. 15.000(vC).d. 45.000(vC). Bi 21: Mt hemoglobin (hng cu ca mu) cha 0,4% Fe (mi phn t hemoglobin ch cha 1 nguyn t Fe). Phn t khi gn ng ca hemoglobin trn l : a. 12000. b. 14000. c. 15000. d. 18000. Bi 22: Thy phn hon ton 1 mol Pentapeptit(X) thu c 3 mol Gli; 1 mol Ala; 1 mol Phe. Khi thy phn khng hon ton (X) thu c hn hp gm Ala-Gli ; Gli-Ala v khng thy to ra Phe-Gli. Xc nh CTCT ca Petapeptit? Bi 23: Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin ; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly ; Gly-Ala v tripeptit Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l : a. Gly, Val. b. Ala, Val. c. Gly, Gly. d. Ala, Gly. Bi 24: Thu phn khng hon ton tetrapeptit (X), ngoi cc a-amino axit cn thu c cc ipetit: Gly-Ala ; Phe-Val ; Ala-Phe. Cu to no sau y l ng ca X ? a. Val-Phe-Gly-Ala. b. Ala-Val-Phe-Gly. c. Gly-Ala-Val-Phe. d. Gly-Ala-Phe-Val. Bi 25: Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. ht X c cng thc l a. Gly-Phe-Gly-Ala-Val. b. Gly-Ala-Val-Val-Phe. c. Gly-Ala-Val-Phe-Gly. d. Val-Phe-Gly-Ala-Gly. Bi 26: Cng thc no sau y ca pentapeptit (A) tha iu kin sau ? hy phn hon ton 1 mol A th thu c cc - amino axit l : 3 mol glyxin, 1 mol alanin, 1 mol valin. Thy phn khng hon ton A, ngoi thu c cc amino axit th cn thu c 2 ipeptit : Ala-Gly ; Gly-Ala v 1 tripeptit Gly-Gly-Val. a. Ala-Gly-Gly-Gly-Val. b. Gly- Gly-Ala-Gly-Val. c. Gly-Ala-Gly-Gly-Val. d. Gly-Ala-Gly-Val-Gly. Bi 27: Thu phn hp cht : H2NCH2CONHCH(CH3)CONHCH(CH(CH3)2)CONHCH2CONHCH2COOH s thu c bao nhiu loi amino axit no sau y ? a. 3. b. 4. c. 5. d. 2. Bi 28: Thu phn hp cht : s thu c bao nhiu loi amino axit no sau y ? H2NCH(CH3)CONHCH(CH(CH3)2)CONHCH(C2H5)CONHCH2CONHCH(C4H9)COOH. a. 2. b. 3. c. 4. d. 5. Bi 29: Cho 3 cht X,Y,Z vo 3 ng nghim cha sn Cu(OH)2 trong NaOH lc u v quan st th thy: Cht X thy xut hin mu tm, cht Y th Cu(OH)2 tan v c mu xanh nht, cht Z th Cu(OH)2 tan v c mu xanh thm. X, Y, Z ln lt l : a. H tinh bt, HCOOH, mantoz. b. Protein, CH3CHO, saccaroz. c. Anbumin, C2H5COOH, glyxin. d. Lng trng trng, CH3COOH, glucoz. Bi 30: Thuc th c dng phn bit Gly-Ala-Gly v Gly-Ala l : a. dd HCl. b. Cu(OH)2/OH-c. dd NaCl. d. dd NaOH.

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Bi 31: Khi thu phn hon ton 0,1mol peptit A mch h(A to bi cc aminoaxit c 1 nhm -COOH v 1 nhm -NH2)=lng dd NaOH gp i lng cn phn ng,c cn dd thu c hh cht rn tng so vi khi lng A l 78,2g.Xc nh s lin kt peptit trong A. A.7 B.8 C.9 D.10 Bi 32: X v Y ln lt l tetrapeptit v hexapeptit c to thnh t cng 1 alpha aminoaxit no mch h c 1 nhm -COOH v 1 nhm -NH2. t 0,1 mol X bng Oxi thu c sn phm gm CO2 , H 2O v N 2 c tng khi lng bng 40,5 gam. Nu cho 0,15 mol Y tc dng hon ton vi NaOH( ly d 20% so vi lng cn thit) sau phn ng c cn thu c bao nhiu gam ? A. 87,75g B. 80,82g C. 79,21 g D.98,2 gam Bi 33.khi thu phn khng hon ton 1 peptit A c khi lng phn t 293g/mol v cha 14,3%N(theo khi lng) thu c 2 peptit B v C.Mu 0,472g peptit B khi em nung nng,phn ng hon ton vi 18ml dd HCl 0,222M.Mu 0,666g peptit C khi un nng,phn ng hon ton vi 14,7ml dd NaOH 1,6% (khi lng ring l 1,022g/ml).Cu to c th c ca A l ? A. Gly - Phe - Ala hoc Ala - Phe Gly B. Val - Phe - Ala hoc Ala - Phe - Gly C. Gly - Phe - Gly hoc Ala - Phe Gly D. Val - Phe - Gly hoc Ala - Phe Gly Bi 34. X l tettrapeptit Ala-gly-val-ala, Y la tripeptit Val-gly-val, un nng m gam hn hp X v Y c t l s mol l nX/ nY=1:3 vi 780 ml dd NaOH 1M (va ), sau khi phn ng kt thc th thu c dd Z.C cn dung dch Z th thu c 94,98 gam mui.Ga tr ca m la: A.68,1 B.64,86 C.77,04 D.65,13 Bi 35. X l ipeptit Ala-Glu, Y l tripeptit Ala-Ala-Gly. un nng m(g) hn hp cha X,Y c t l s mol tng ng l 1:2 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 56,4 g cht rn khan. gi tr ca m l A.39,12 B.38,68 C.40,27 D.45,6 Bi 36: Cho X l hexapeptit AlaGlyAlaValGlyVal v Y l tetrapeptit GlyAlaGlyGlu. Thy phn hon ton m gam hn hp gm X v Y thu c 4 amino axit, trong c 30 gam glyxin v 28,48 gam alanin. Gi tr ca m l A. 77,6. B. 83,2. C. 87,4. D. 73,4. Bi 37: Peptit X b thy phn theo phng trnh phn ng X + 2H2O 2Y + Z (trong Y v Z l cc amino axit). Thy phn hon ton 4,06 gam X thu c m gam Z. t chy hon ton m gam Z cn va 1,68 lt kh O2 (ktc), thu c 2,64 gam CO2; 1,26 gam H2O v 224 ml kh N2 (ktc). Bit Z c cng thc phn t trng vi cng thc n gin nht. Tn gi ca Y l A. glyxin. B. lysin. C. axit glutamic. D. alanin. Bi 38: Tripeptit X v tetrapeptit Y u mch h. Khi thy phn hon ton hn hp gm X v Y ch to ra mt amino axit duy nht c cng thc H2NCnH2nCOOH. t chy 0,05 mol Y trong oxi d, thu c N2 v 36,3 gam hn hp gm CO2, H2O. t chy 0,01 mol X trong oxi d, cho sn phm chy vo dung dch Ba(OH)2 d, thu c m gam kt ta. Bit cc phn ng u xy ra hon ton. Gi tr ca m l A. 23,64. B. 17,73. C. 11,82. D. 29,55. Bi 39: Amino axit X c cng thc H2NCxHy(COOH)2. Cho 0,1 mol X vo 0,2 lt dung dch H2SO4 0,5M, thu c dung dch Y. Cho Y phn ng va vi dung dch gm NaOH 1M v KOH 3M, thu c dung dch cha 36,7 gam mui. Phn trm khi lng ca nit trong X l A. 11,966%. B. 9,524%. C. 10,526%. D. 10,687%. Bi 40: Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m gam mui. Gi tr ca m l A. 22,35. B. 50,65. C. 44,65. D.33,50. Bi 41: un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol tripeptit mch h Y vi 600 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch thu c 72,48 gam mui khan ca cc amino axit u c mt nhm COOH v mt nhm NH2 trong phn t. Gi tr ca m l A. 66,00. B. 54,30. C. 51,72. D.44,48.

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Bi 42: Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH2 trong phn t), trong t l mO : mN = 80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch HCl 1M. Mt khc, t chy hon ton 3,83 gam hn hp X cn 3,192 lt O2 (ktc). Dn ton b sn phm chy (CO2, H2O v N2) vo nc vi trong d th khi lng kt ta thu c l A. 20 gam. B. 10 gam. C. 13 gam. D. 15 gam. Bi 43: Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trmkhi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l A. 3,56. B. 5,34. C. 2,67. D. 4,45. Bi 44:: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm x7anh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l (cho H = 1, C = 12, N = 14, O = 16, Na = 23) A. 8,9 gam. B. 14,3 gam. C. 16,5 gam. D. 15,7 gam. Bi 45:: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 8 v 1,5. B. 7 v 1,5. C. 7 v 1,0. D. 8 v 1,0. Bi 46:: Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l Bi 4:: Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. axit 2-aminopropionic v amoni acrylat. B. amoni acrylat v axit 2-aminopropionic. C. vinyl amonifomat v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic.

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