V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.

com

Tuyn tp n luyn mn ha hc dp tt nguyn n nm hc 20112012

A/ Cc dng bi tp cn n luyn
I. Chuyn cu to nguyn t v h thng tun hon II. Chuyn in ly v ph dung dch III. Chuyn HNO3 v mui nitrat IV. Chuyn kim loi v cc phi kim in hnh V. Chuyn p ca CO2, SO2 vi dd kim VI. Chuyn hirocacbon VII. Chuyn bi tp ancol, anhit, xeton, VIII. Chuyn bi tp axit hu c, este, amin

B. Bi tp
Bi tp ancol
Bi 1. Vit cc phng trnh phn ng v gi tn sn phm hu c trong cc trng hp sau: a. propan-2-ol tc dng vi H2SO4 c 1400C b. metanol tc dng vi H2SO4 c to imetyl sunfat c. propan-2-ol tc dng vi HBr v H2SO4 c (un nng) d. 2-metyl butan-2-ol tc dng vi H2SO4 c 1800C Bi 2. Vit cc phng trnh phn ng v gi tn sn phm hu c trong cc trng hp sau: a. butan-2-ol tc dng vi Na b. etanol tc dng vi CuO (t0) c. 3-metylbutan-2-ol + CuO (t0) d. t chy ancol no a chc C2H5Cl e. C2H5OH + ? f. hn hp (metanol, etanol) 1400C, H2SO4 c g. CH3-CH=CH-CH3 + H2O/H+ h. glixerol + HNO3 d/ H2SO4 c Bi 3. Vit cc phng trnh phn ng theo s a.
CH4 C2H2 C2H4 C2H5OH

CH3CHO

b.

Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com
C2H5ONa C2H5OH (C2H5)2O C4H6 CH3COOH C2H5Br
C3H6 CH3CH2CH2OH

Cao su Buna CH3COONa CH4

c. CH3CHCH3
OH

C3H5Cl

C3H7Cl

d. C4H10O e.

C4H8

C4H8Br2

C4H8(OH)2

dixeton
Andehit da chuc

C3H6

C3H6Br2

C3H6(OH)2

f. A l hp cht hu c c hai nguyn t cacbon. B E

A G

A R

Mt s dng bi tp c bn Ancol tc dng vi Na Bi 4. Mt ancol no X mch h c s nguyn t cacbon bng s nhm chc. Cho 9,3g ancol X tc dng vi natri d thu c 3,36 lt kh. Xc nh cng thc cu to ca ancol . Bi 5. Cho 11g hn hp X gm 2 ancol no, n chc, mch h k tip nhau trong dy ng ng tc dng vi natri d thu c 3,36 lt kh ktc a. Xc nh CTPT v CTCT ca cc ancol. Gi tn cc ancol b. Tnh % khi lng mi ancol Bi 6. Cho 1,52g hn hp 2 ancol n chc l ng ng k tip ca nhau tc dng vi natri va thu c 2,18g cht rn v V lt kh hiro ktc. a. Tnh V? b. Tm CTPT v phn trm khi lng mi ancol trong hn hp Ancol tc dng vi oxi Bi 7. t chy hon ton p (g) hn hp 2 ancol no n chc k tip nhau trong dy ng ng thu c 4,48 lt kh CO2 v 4,95g nc a. Tm CTPT, vit CTCT ca 2 ancol b. Tnh phn trm khi lng mi ancol Bi 8. t chy hon ton m(g) hn hp X gm 2 ancol A, B thuc cng dy ng ng v k tip nhau, thu c 6,72 lt kh CO2 v 7,65g nc Mt khc, m(g) hn hp X tc dng ht vi Na thu c 2,8 lt hiro a. Xc nh CTCT ca A, B b. Tnh phn trm khi lng mi ancol trong hn hp Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Bi ton tch nc Bi 9. un nng 16,6g hn hp A gm 3 ancol, n chc vi H2SO4 c 1400C thu c 13,9g hn hp 6 ete c s mol bng nhau. Mt khc, un nng hn hp A vi H2SO4 c 1800C th thu c hn hp kh ch gm 2 olefin a. Xc nh CTPT, CTCT ca cc ancol, coi H = 100% b. Tnh % khi lng mi ancol c. Tnh % th tch mi olefin trong hn hp thu c Bi 10. Cho 12,9g hn hp 3 ancol no, n chc, mch h tham gia phn ng tch nc iu kin thch hp thu c hn hp X gm 2 kh l ng ng k tip, c t khi so vi hn hp ancol ban u l 0,651 a. Xc nh CTPT ca cc ancol b. Nu cho ton b lng ancol trn phn ng vi CuO un nng, sn phm thu c cho tc dng vi lng d ddAgNO3/NH3 d thu c 37,8g kim loi bc. Xc nh phn trm khi lng mi ancol trong hn hp ban u Bi tp luyn tp Bi 11. t chy hon ton 0,1mol hchc A thu c nc v 4,48 lt CO2 ktc. Mt khc cho Na d vo 0,15mol A thy thot ra 1,69 lt kh H2-ktc. a. Xc nh CTPT, CTCT, tn A bit A ch c mt nhm chc, A khng lm chuyn mu qu b. Nu cc phng php iu ch A hc. Vit ptp Bi 12. Khi cho 9,2g hn hp gm ancol propylic v mt ancol B thuc cng dy ng ng ca ancol no, n chc, mch h tc dng vi natri d thy c 2,24 lt kh thot ra ktc a. Xc nh CTPT ca B v phn trm khi lng mi ancol trong hn hp b. un nng hn hp 2 ancol trn vi H2SO4 c, 1400C c th thu c bao nhiu ete. Vit ptp v gi tn ete. Bi 13. Chia m(g) hn hp 2 ancol l ng ng k tip thuc dy ng ng ca ancol metylic tc dng vi Na d thu c 0,448 lt H2 ktc. t chy hon ton m(g) hn hp trn thu c 2,24 lt CO2- ktc. Tm CTPT ca 2 ancol v m. Bi 14. un nng m(g) hn hp 2 ancol no, n chc, mch h c KLPT hn km nhau 14 .v.c vi H2SO4 c 1400C thu c 13,2g hn hp 3 ete c s mol bng nhau v 2,7g nc. a. Vit phng trnh phn ng b. Xc nh CTPT ca 2 ancol v tnh % khi lng mi ancol Bi 15. Cho 18,2g hn hp gm ancol propylic v mt ancol a chc X tc dng vi Na d thy c 4,48 lt kh thot ra ktc, bit lng kh thot ra t 2 phn ng bng nhau a. Xc nh CTPT, vit CTCT v gi tn X b. Nu cch phn bit ancol propylic vi X c. Hon chnh dy bin ho sau bng cc phng trnh phn ng
dd Br2 CuO,t NaOH A Y B X (3) (1) (2)
0

Bi 16. Cho 28,2g hn hp A gm 2 ancol no, a chc, mch h k tip nhau trong dy ng ng, tc dng vi Na d thu c 8,4 lt kh hiro ktc a. Xc nh CTCT v gi tn 2 ancol b. Tnh % khi lng cc cht trong hn hp A c. Oxi ho 14,1g hn hp A bng oxi d vi xc tc CuO un nng c hn hp B. Cho B tc dng vi lng d ddAgNO3/NH3. Tnh khi lng bc to thnh. Bit cc p xy ra hon ton. Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Bi 17. Hn hp A cha glixerol v mt ancol no, n chc, mch h B. Cho 20,3g A tc dng vi Na d thu c 5,04 lt hiro- ktc. Mt khc 8,12g A ho tan va ht 1,96g Cu(OH)2. Xc nh CTPT, CTCT B v thnh phn % khi lng ca mi ancol trong hn hp Bi 19. Cho V lt hn hp kh- ktc gm 2 olefin lin tip nhau trong dy ng ng hp nc (c mi trng axit) thu c 12,9g hn hp A gm 3 ancol. Chia A thnh 2 phn bng nhau * Phn 1. em nung nng trong H2SO4 c, 1400C th thu c 5,325g B gm 6 ete khan. Xc nh CTCT ca cc olefin, ancol v ete * Phn 2. em oxi ho hon ton bng oxi khng kh nung nng c xc tc Cu thu c hn hp sn phm D ch gm anehit v xeton. Sau cho D tc dng vi ddAgNO3/NH3 d th thu c 17,28g bc kim loi. Tnh khi lng mi ancol trong hn hp A v tnh V. * Cho thm 0,05mol ancol no n chc, bc mt khc vo phn 2 ri tin hnh phn ng oxi ho bng oxi khng kh, sau thc hin phn ng trng bc nh trn th thu c bao nhiu gam bc? (Cc phn ng c H = 100%) Bi 20. Cht X c CTPT C7H8O2 - Khi cho 0,62g X tc dng ht vi Na thu c V lt hiro- ktc - Khi cho 0,62g X tc dng va ht vi dung dch NaOH 0,1M th s mol NaOH cn dng bng s mol hiro thot ra trn v cng bng s mol X tham gia phn ng a. Tm CTCT c th c ca X? b. Tnh V v th tch NaOH dng Bi 21. a. t chy hon ton mt lng ancol n chc A, thu c 13,2g CO2 v 8,1g H2O. Xc nh CTCT ca A b. Hn hp X gm A, B l ng ng ca nhau. Khi cho 18,8g hn hp X tc dng vi Na d thu c 5,6 lt kh hiro ktc. Xc nh CTCT ca B v s mol mi ancol trong hn hp X c. t chy hon ton hn hp X trn, ri cho sn phm chy qua bnh ng nc vi trong d, thu c 35g kt ta. Tnh khi lng hn hp X em t e. Oxi ho m(g) hn hp X trn bng oxi khng kh c bt ng nung nng lm xc tc, thu c hn hp Y. Cho hn hp Y tc dng vi ddAgNO3/NH3 d thu c 8,64g kt ta. Tnh m? Bi 22. TN1. Trn 0,015mol ancol no, mch h A vi 0,02mol ancol no, mch h B ri cho hn hp tc dng ht vi Na c 1,008 lt kh H2 TN2. Trn 0,02mol A vi 0,015mol B ri cho hn hp tc dng vi Na c 0,952 lt H2 TN3. t chy hon ton mt lng hn hp nh TN1 ri cho tt c sn phm chy qua bnh ng CaO mi nung, d thy khi lng bnh tng thm 6,21g Xc nh CTPT, CTCT v gi tn cc ancol. Bi 23. t chy hon ton hn hp A gm 2 ancol n chc, mch h, k tip nhau trong dy ng ng thu c kh CO2 v hi nc c t l th tch tng ng l 5:7 a. Xc nh CTPT cu 2 ancol b. Tnh % khi lng mi ancol trong hn hp A Bi 24. t chy hon ton m(g) hn hp hai ancol no, n chc th thu c 17,92 lt kh CO2- ktc v 19,8g nc a. Tnh m? b. Tnh phn trm khi lng mi ancol trong hn hp, bit t khi hi ca mi ancol so vi oxi u nh hn 2

Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Bi 25. Ho hi hon ton 6,42g hn hp X gm 2 ancol no, mch h A, B 81,90C v 1,3 atm c mt hn hp hi ca 2 ancol c th tch 2,352 lt. Cho cng lng hn hp ancol ny tc dng vi kali d thu c 1,848 lt kh hiro- ktc. Mt khc, t chy hon ton cng lng hn hp X thu c 11,22g kh CO2. Xc nh CTPT v khi lng mi ancol, bit rng s nhm chc trong B nhiu hn trong A mt n v. Bi 26. Trong mt bnh kn dung tch 16 lt cha hn hp hi ca 3 ancol n chc, k tip nhau trong dy ng ng. Gi nhhit bnh 136,50C ri bm thm vo bnh 17,92g oxi, thy p sut bnh t 1,68 atm. Bt tia la in t chy ht hn hp, sn phm chy cho qua bnh ng dung dch Ca(OH)2 d thy khi lng bnh tng ln 22,92g, ng thi xut hin 30g kt ta. a. Nu sau khi bt tia la in t chy ht hn hp, gi bnh 2730C, th p sut trong bnh l bao nhiu? b. Xc nh cng thc ca 3 ancol Bi 27. un nng hn hp 3 ancol X, Y, Z vi H2SO4 c 1700C thu c hn hp hai olefin l ng ng lin tip. Ly hai trong s 3 ancol trn un vi H2SO4 c 1400C c 1,32g hn hp 3 ete. Mt khc lm bay hi 1,32g hn hp 3 ete ny c th tch ng bng th tch ca 0,48g oxi cng iu kin. a. Xc nh CTCT ca 3 ancol X, Y, Z b. t chy hon ton 1,32g ete ni trn, hp th ton b lng kh CO2 sinh ra vo 250ml dung dch Ba(OH)2 a mol/l th thu c 9,85g kt ta. Tnh a? Bi 28. Mt hn hp gm 2 ancol n chc l ng ng k tip nhau, mi ancol chim mt na v khi lng. S mol 2 ancol trong 27,6g hn hp khc nhau 0,07 mol. a. Tm cng thc ca 2 ancol b. Nu un nng hn hp 1400C, H2SO4 c th lng ete thu c ti a l bao nhiu? Bi 29. Cho hn hp X gm 6,4g ancol metylic v b mol hn hp 2 ancol no, n chc, mch h l ng ng k tip ca nhau. Chia X thnh 2 phn bng nhau: * Phn 1: Cho tc dng ht vi Na thu c 4,48 lt kh H2 * Phn 2: t chy hon ton ri cho sn phm chy ln lt qua 2 bnh kn ng P2O5 v ddBa(OH)2 d, sau phn nhn thy 2 bnh tng ng c khi lng tng thm l a (g) v (a + 22,7)g. a. Vit cc phng trnh phn ng b. Xc nh CTPT, CTCT v gi tn 2 ancol. c. Tnh phn trm khi lng cc cht trong hn hp X Bi 30. Hn hp X gm 2 anken k tip nhau trong dy ng ng. t chy hon ton 5 lt hn hp X cn va 18 lt oxi (cc th tch o cn iu kin nhit v p sut) a. Xc nh CTPT ca 2 anken b. Hirat ho hon ton mt th tch X vi iu kin thch hp thu c hn hp ancol Y, trong t l v khi lng ancol bc 1 so vi bc 2 l 28:15 - Xc nh % khi lng mi ancol trong hn hp Y - Cho hhY th hi qua CuO un nng, nhng ancol no b oxi ho thnh anehit? Ptp D.C2H4O cc dang bi tp ch-ng este- lipit. 7/16/2011 Dng i- bi tp xc nh cng thc cu to. Cu 1. Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com axetanehit. Cng thc cu to thu gn ca este l A. CH2=CH-COO-CH3. B. HCOO-C(CH3)=CH2. C. HCOO-CH=CH-CH3. D. CH3COO-CH=CH2. Cu 2. Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. ru metylic . B. etyl axetat . C. axit fomic. D. ru etylic Cu 3.Este X c cng thc phn t C7H12O4, khi cho 16 gam X tc dng va vi 200 gam dung dch NaOH 4% th thu c mt ancol A v 17,8 gam hn hp hai mui. Cng thc cu to ca X l A. CH3COO(CH2)2OOCC2H5. B. HCOO(CH2)3OOCC2H5. C. HCOO(CH2)3OOCCH3. D. CH3COO(CH2)3OOCCH3 Cu 4.Cht X c cng thc phn t C7H6O3 . Bit 27,6 gam X tc dng va vi 600 ml dung dch NaOH 1M. Cng thc cu to ca X l A. (HO)2C6H3CHO. B. HOC6H4CHO. C. (HO)3C6H2CH3. D. HCOOC6H4OH. Cu 5.Cho hn hp X gm 2 este c cng thc phn t C4H8O2 v C3H6O2 tc dng vi NaOH d thu c 6,14 gam hn hp hai mui v 3,68 gam ru Y duy nht c t khi hi so vi oxi l 1,4375. Khi lng mi este trong X ln lt l A. 4,4 gam v 2,22 gam. B. 3,33 gam v 6,6 gam. C. 4,44 gam v 8,8 gam. D. 5,6 gam v 11,2 gam. Cu 6: A,B co cung CTPT C2H4O2 ,trong o A phan ng c Na va dung dch NaOH con B phan ng c vi Na vaAgNO3/NH3 . CTCT cua A, B lan lt la: A. CH3COOH,HO-CH2-CH=O B. HCOOCH3,HO-CH2-CH=O C. CH3COOH,HCOOCH3 D. HCOOCH3 ,CH3COOH Cu 7: A,B co cung CTPT C3H6O2 ,trong o A phan ng c Na vadung dch NaOH con B phan ng c vi dung dch NaOH, AgNO3/NH3 . CTCT cua A, B lan lt la A. CH3CH2COOH,CH3COOCH3 B. CH3CH2COOH,HCOO CH2CH3 C. CH3COOCH3,HO-CH2-CH2CH=O D. CH3COOCH3 ,CH3CH2COOH Cu 8: A,B co cung CTPT C3H6O2 ,trong o A phan ng c Na vadung dch NaOH con B ch phan ng c vi dung dch NaOH, khong phan ng vi Ag2O/NH3 . CTCT cua A, B lan lt la A. CH3CH2COOH,HO-CH2-CH2CH=O B. CH3 CH2COOH,CH3COOCH3 C. CH3COOCH3 ,CH3CH2COOH D. CH3COOCH3,HO-CH2-CH2CH=O Cu 9 :So ong phan mach h este co phan ng trang bac cua C 5H10O2 la A. 3 B. 4 C. 5 D. 6 Dng 2. bai tp xc nh ctpt da vo tnh cht ca este. cu 1.X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23) A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam Cu 2.Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l A. CH2=CH-CH2-COO-CH3. B. CH2=CH-COO-CH2-CH3. C. CH3 -COO-CH=CH-CH3. D. CH3-CH2-COO-CH=CH2. Cu 3. Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com cu to ca X1, X2 ln lt l: A. CH3-COOH, CH3-COO-CH3. B. (CH3)2CH-OH, H-COO-CH3. C. H-COO-CH3, CH3-COOH. D. CH3-COOH, H-COO-CH3. Cu 4. X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l A. 17,80 gam. B. 18,24 gam. C. 16,68 gam. D. 18,38 gam Cu 5: 0,01 mol este X(ch cha chc este) tc dng va vi 200 ml dung dch NaOH 1M to sn phm ch c mt ru v mt mui c s mol bng nhau. Mt khc khi x phng ha 1,29 g este X cn va 60 ml dung dch KOH 0,25M v thu c 1,665 (g) mui. Este X c CT l: A. (COO)2C2H4 B. CH2(COO)2C2H4 C. C2H4(COO)2C2H4 D. C4H8(COO)2C2H4 Cu 6: Khi thy phn 0,01 mol este X(ch cha este) cn va 1,2 (g) NaOH thu c ru a chc v mt mui ca axit n chc. Mt khc khi thy phn 6,35 g (X) cn va 3 g NaOH v 7,05 g mui. Xc nh este X: A. (C2H3COO)3C3H5 B. (CH3COO)3C3H5 C. (HCOO)3C3H5 D. (C2H5COO)3C3H5 Cu 7: Hn hp X gm axit fomic v axit axetic c t l mol 1:1. Ly 5,3 gam hn hp X tc dng vi 5,75 gam ancol etylic (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l A. 10,125. B. 6,48. C. 8,10. D. 16,20. Cu 8: Cho 21,8 gam cht hu c X mch h ch cha mt loi nhm chc tc dng vi 1 lt dung dch NaOH 0,5M thu c 24,6 gam mui v 0,1 mol ancol. Lng NaOH d c trung ho va ht bi 0,5 lt dung dch HCl 0,4M. Cng thc cu to ca X l A. (HCOO)3C3H5. B. (CH3COO)2C2H4. C. (CH3COO)3C3H5. D. C3H5(COOCH3)3. Cu 9: thu phn 0,01 mol este to bi mt ancol a chc v mt axit cacboxylic n chc cn dng 1,2 gam NaOH. Mt khc thy phn 6,35 gam este cn 3 gam NaOH, sau phn ng thu c 7,05 gam mui. Cng thc cu to ca este l A. (CH3COO)3C3H5. B. (CH2 = CHCOO)3C3H5. C. (CH2 = CHCOO)2C2H4. D. (C3H5COO)3C3H5. Cu10: X phng ha hon ton 9,7 gam hn hp hai este n chc X, Y cn 150 ml dung dch KOH 1M. Sau phn ng c cn dung dch thu c hn hp hai ancol ng ng k tip v mt mui duy nht. Cng thc cu to thu gn ca X, Y ln lt l A. HCOOCH3, HCOOC2H5. B. C2H5COOCH3, C2H5COOC2H5. C. CH3COOCH3, CH3COOC2H5 D. C2H3COOCH3, C2H3COOC2H5. Cu 11: Mt este to bi axit n chc v ancol n chc c t khi hi so vi CO2 bng 2. Khi un nng este ny vi dung dch NaOH to ra lng mui c khi lng ln hn lng este phn ng . Este l A. Metyl axetat. B. Propyl axetat. C. Metyl propionat. D. Etyl axetat Cu 12: Cho lng CO2 thu c khi t chy hon ton 0,1 mol hn hp gm hai este etyl fomiat v metyl axetat qua 1 lt dung dch NaOH 0,4M thu c m gam mui. Gi tr ca m l A. 25,2. B. 42,4. C. 27,4. D. 33,6. Cu 13: un nng hp cht X vi H2O (xc tc H+) c axit hu c Y v ancol Z n chc. Cho hi Z i qua ng ng CuO, t0 c hp cht T c kh nng tham gia phn ng trng bc. t chy hon ton 2,8 gam X phi dng ht 3,92 lt oxi ( ktc), c kh CO2 v hi nc theo t l th tch: VCO2 : VH 2O 3 : 2 . Bit d Y 2,57 .
N2

Cng thc cu to ca Xl A. CH2 = CHCOOC3H7. B. CH2 = CHCOOCH2CH = CH2. C. C2H5COOCH = CH2. D. CH2 = CHCH2COOCH = CH2. Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Cu 14: X l este ca mt axit cacboxylic n chc v ancol etylic. Thy phn hon ton 7,4 gam X ngi ta dng 125 ml dung dch NaOH 1M. Lng NaOH d 25% so vi lng cn thit. Cng thc cu to ca X l A. HCOOC2H5. B. CH3COOC2H5. C. C2H5COOC2H5. D. HCOOCH3. Cu 15: Cho 45 gam trieste ca glixerol vi mt axit bo tc dng va vi 100 ml dung dch NaOH 1,5M c m1 gam x phng v m2 gam glixerol. Gi tr m1, m2 l A. m1 = 46,4; m2 = 4,6. B. m1 = 4,6; m2 = 46,4. C. m1 = 40,6; m2 = 13,8. D. m1 = 15,2; m2 = 20,8. Cu 16: Cho 10,4 gam este X (cng thc phn t: C4H8O3) tc dng va vi 100 ml dung dch NaOH 1M c 9,8 gam mui khan. Cng thc cu to ca X l A. HCOOCH2CH2CHO. B. CH3COOCH2CH2OH. C. HOCH2COOC2H5. D. CH3CH(OH)COOCH3. Cu 17 Mt este n chc X c phn t khi l 88 vC. Cho 17,6 gam X tc dng vi 300 ml dung dch NaOH 1M. Khi phn ng xy ra hon ton, c cn dung dch sau phn ng thu c 23,2 gam cht rn khan. Cng thc cu to ca X l A. HCOOCH2CH2CH3. B. HCOO CH(CH3)2. C. CH3CH2COOCH3. D . CH3COOCH2CH3. Cu 18: Hn hp M gm mt axit X n chc, mt ancol Y n chc v mt este to ra t X v Y. Khi cho 25,2 gam hn hp M tc dng va vi 100 ml dung dch NaOH 2M c 13,6 gam mui khan. Nu un nng Y vi H2SO4 c th thu c cht hu c Y1 c t khi hi so vi Y bng 1,7 (coi hiu sut t 100%). Cng thc cu to ca este l: A. HCOOCH2CH2CH3. B. CH3COO CH(CH3)2. C. HCOOCH(CH3)2. D. HCOOC2H4CH3 hoc HCOOCH(CH3)2. Cu 19: Chat hu c mach h no A cha cac nguyen to C,H,O co phan t khoi la 74. A phan ng c vi : Na , dung dch AgNO3 /NH3 , dung dch NaOH . Cong thc phan t cua A la A. C4H10O B. C3H6O2 C. C2H2O3 D. C3H8O2 Cu 20: Cho s sau:
C2 H5OH X
Na OH

Z F

CH4 Poli(metyl metacrylat)

axit metacrylic

Cng thc cu to ca X l A. CH2 = C(CH3) COOC2H5. C. CH2 = C(CH3)COOCH3. Cu 21: Cho s sau:
0

B. CH2 = CHOOCC2H5. D. CH2 = CHCOOC2H5

H2O/ Hg 1500 C NaOH CH4 X Y Z T M CH4

Cng thc cu to ca Z l A. C2H5OH. B. CH3COOH. Cu 22: Cho s sau: Cng thc cu to ca X l A. C2H4(OH)2. B. C2H5OH.

C. CH3COOC2H5.

D. C A, B, C u ng.

C2H 2 C2H 4Cl 2 X C2H 4O2 CH 2 CHOOCCH 3

C. CH3CHO. D. HOCH2CHO.

Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com 3.Bi tp xc nh cng thc phn t da vo phn ng chy. cu 1.Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tnca X l A. etyl propionat. B. metyl propionat. C. isopropyl axetat. D. etyl axetat cu 2.Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. metyl fomiat. B. etyl axetat. C. n-propyl axetat. D. metyl axetat Cu 3: Khi t chy hon ton 4,4 gam hp cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l A. etyl propionat. B. Metyl propionat. C. Isopropyl axetat. D. Etyl axetat. Cu 4: t chy 1,6 gam mt este X n chc thu c 3,52 gam CO2 v 1,152 gam H2O. Cho 10 gam X tc dng vi dung dch NaOH (va ), c cn dung dch sau phn ng thu c 14 gam mui khan Y. Cho Y tc dng vi axit v c long thu c Z khng phn nhnh. Cng thc cu to ca Z l A. CH3(CH2)3COOH. B. CH2 = CH(CH2)2COOH. C. HO(CH2)4COOH. D. HO(CH2)4OH. Cu 5. t chy hon ton 0,2 mol este n chc X ri cho sn phm chy ln lt qua bnh 1 ng 100 gam dung dch H2SO4 96,48%; bnh 2 ng dung dch KOH d. Sau th nghim thy nng H2SO4 bnh 1 gim cn 87,08%; bnh 2 c 82,8 gam mui. Cng thc phn t ca X l A. C2H4O2. B. C3H6O2. C. C4H8O2. D. C3H4O2. Cu 6: t chy hon ton 4,44 gam cht hu c X n chc (cha C, H, O). Cho ton b sn phm chy hp th hon ton vo bnh ng dung dch Ca(OH)2 d thy khi lng bnh tng 11,16 gam ng thi thu c 18 gam kt ta. Ly m1 gam X cho tc dng vi dung dch NaOH (va ), c cn dung dch sau phn ng c m2 gam cht rn khan. Bit m2 < m1. Cng thc cu to ca X l A. HCOOC2H5. B. CH3COOCH3. C. C2H5COOH. D. CH2 = CHCOOCH3. 5.Cc dng bi tp c bn khc Dng 1: Xc nh CTCT ca mt este hu c n chc mch h v x phng ha mt este cho mt mui v mt ru HNG DN: - Este no n chc c CT l : CnH2nO2 - Este n chc c CTTQ l : CxHyO2 . t este no n chc th nCO2 = nH2O v neste = nO2 c trong este - Cch gii : + Tnh M axit hoc Mmui Gc hidrocacbon trong axit +Tnh Mru Gc hidrocacbon trong ru +Tnh Meste 1;Hai este l ng phn ca nhau do cc axit no n chc v ru no n chc to thnh. x phng ha 22,2 gam hn hp hai este phi dng ht 12 gam NaOH nguyn cht. Cc mui thu c c khi lng 21,8 gam. Xc nh CTCT ca hai este ? 2; Hp cht hu c X cha cc nguyn t C , H , O c MX = 146 . X khng tc dng vi Na kim loi . Ly 14,6 gam X tc dng va vi 100 ml dd NaOH 2M thu c hn hp gm mt mui v mt ru . Xc nh CTCT ca X ? Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com 3; Hai cht hu c X v Y u n chc l ng phn ca nhau . t chy hon ton 5,8gam hn hp X v Y cn 8,96 lit O2 (ktc) thu c VCO2 : VH2O = 1 : 1 o cng iu kin . Xc nh cng thc n gin ca X v Y? 4; X l hn hp hai este l ng phn ca nhau. cng iu kin 1 lit hi X nng gp hai ln 1 lit O2 .Thy phn 35,2 gam X bng 4 lit dd NaOH 0,2M c dd Y . C cn ddY thu c 44,6 gam cht rn khan . Bit hai este do ru no n chc v axit no n chc to thnh. Xc nh CTCT ca cc este ? 5; Hn hp y l hai este n chc mch h l ng phn ca nhau . Cho m gam Y tc dng va vi 100 ml dd NaOH 0,5M thu c mt mui v hn hp hai ru. t chy hon ton m gam Y cn 5,6 lit O2 4,48 lit CO2 (u ktc). Xc nh CTCT ca hai este trong Y ? 6; Mt este n chc c thnh phn khi lng mC : mO = 9 : 8 a. Xc nh CTCT thu gn ca este ? b. Cho este trn tc dng va vi mt lng NaOH thu c mui c khi lng bng 41/37 khi lng este . Xc nh CTCT ng ca este ? 7; Hai hp cht A ,B mch h ( cha C ,H ,O ) n chc u tc dng vi NaOH , khng tc dng vi Na . t chy hon ton m gam hn hp X gm A ,B cn 8,4 lit O2 thu c 6,72 lit CO2 v 5,4 gam H2O . A v B thuc loi cht g ? 8; Hn hp E gm hai cht hu c A , B cng chc. un 13,6 gam E vi dd NaOH thu c sn phm gm mt mui duy nht ca mt axit n chc ,khng no v hn hp hai ru no n chc k tip nhau . t hon ton 27,2 gam E cn dng ht 33,6 lit O2 thu c 29,12 lit CO2 v H2O ( cng ktc ). Xc nh CTPT ca A v B ? Dng 2: Xc nh CTCT ca este hai chc mch h HNG DN: X phng ha mt este cho mt trong cc iu kin sau: - Mt mui v hai ru axit hai chc R(COOR)2 th nOH- = 2neste = n ru , neste=nmui Hai mui v mt ru ru trong este l ru hai chc (RCOO)2R th neste=nru - nOH-= 2 neste Ty theo k bi cho m gii theo hai trng hp trn c bit este hai chc mch vng do axit hai chc v ru hai chc to thnh R (COO)2R -

nOH- = 2neste = n mui ,

1;un nng a gam mt hp cht hu c X cha C , H , O mch h khng phn nhnh vi dd cha 11,2 gam KOH n khi phn ng hon ton thu c ddB . trung ha KOH d cn 80 ml HCl 0,5M . un hn hp sau khi trung ha thu c 7,36 gam hai ru n chc v 18,34 gam hn hp hai mui . Xc nh CTCT ca X? 2; Cho hp cht X ( cha C , H , O ) mch thng ch cha mt loi nhm chc tc dng ht vi 152,5 ml dd NaOH 25% ( d = 1,28 g/ml) . Sau khi phn ng xy ra hon ton thu c dd A cha mt mui v hai ru no n chc ng n ca nhau. trung ha hon ton dd A cn 255ml dd HCl 4M . C cn dd sau trung ha thu c hn hp hai ru c t khi so vi H2 l 26,5 v 78,67 gam hn hp mui khan. Xc nh CTCT ca X ? 3; Mt hp cht huc c X c CTPT l C7H12O4 . Bit X ch cha mt loi nhm chc . Cho 16 gam X tc dng va vi 200 gam dd NaOH 4% thu c mt ru Y v 17,8 gam hn hp hai mui . Xc nh CTCT thu gon ca X ? Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com HNG DN: Dng 3: nhca CTCT ca ba: chc - Xc CTCT este c este dng RCOOC6H5 1; Khi thy phn 0,01 mol este ca mt ru a chc mt trong axit n chc phi dng 1,2 gam NaOH . Mt - Nu xc nh CTCT ca tng este nv chc hn hp bit nNaOH >n este th t khc thy phn 6,35 gam este cn 3 gam NaOH thu c 7,05 gam mui . Xc nh CTPT v CTCT ca este ? nht mt trong hai este l este ca phnol. 2; thy phn 25,4 gam este X cn dng 200 gam dd NaOH 6%. Mt khc khi thy phn 6,35 gam este A bng xt thu c 7,05 gam mui duy nht . Bit rng mt trong hai cht to thnh este l n chc. Meste = 254 vC . Cho bit CTCT thu gn ca este ? 3;Khi x phng ha 2,18 gam Z c CTPT l C9H14O6 dng 40 ml NaOH 1M . trung ha lng xt d sau phn ng x phng ha phi dng ht 20ml ddHCl 0,5M.Sau phn ng x phng ha ngi ta thu c mt ru no B v mui Natri ca axit hu c n chc. Bit rng 11,5 gam B th hi chim th tch bng ca 3,75 gam etan trong cng iu kin . Tm CTCT ca B ? Dng 4: Dng c bit Trng hp 1: X phng ha 1 este cho hn hp hai mui v ru 1; Cho 2,76 gam cht hu c A cha C , H , O tc dng vi dd NaOH va , sau khi chng ct th phn bay hi ch c nc , phn cht rn cha hai mui Natri chim khi lng 4,44 gam . Nung nng hai mui ny trong Oxi d thu c 3,18 gam Na2CO3 ; 2,464 lit CO2 (ktc) v 0,9 gam nc. Bit CTPT ca A trng CTG nht . Xc nh CTCT ca A ? 2; Mt cht hu c X c cng thc n gin l C4H4O tc dng va vi dd KOH 11,666% . Sau phn ng thu c dd Y . C cn ddY th phn bay hi ch c nc vi khi lng 86,6 gam cn li l cht rn Z c khi lng 23 gam. Xc nh CTCT ca X ? 3;Mt hn hp gm hai este u n chc . Ly 0,25 mol hai este ny phn ng vi 175ml dd NaOH 2M un nng thu c mt andehit no mch h v 28,6 gam hai mui huc c . Cho bit khi lng ca mui ny bng 1,4655 ln mui kia. Phn trm ca Oxi trong andehit l 27,58% . Xc nh CTCT ca este ? 4;t 1,7 agm este X cn 2,52 lit O2 (ktc) ch sinh ra CO2 v H2O vi t l s mol tng ng l 2:1 . un nng 0,01 mol X cn 0,02 mol NaOH. X khng c chc este , khng phn ng vi Na trong iu kin thng v khng kh c AgNO3 /NH3 ngay c un nng. Bit MX < 140 vC . Xc nh CTCT ca X ? Trng hp 2: X phng ha mt este cha r s nhm chc m cho mui v ru thu c dng khi lng. HNG DN : gam cht hu c A ch cha mt loi nhm chc tc dng vi 1 lit dd NaOH 0,5M thu c Bi tp: Cho 21,8 CTCT ca este dng : Rn (COO) R 24,6 gam mui v 0,1 mol c ru B. Lng NaOHmn d c m th trung ha ht 0,5 lit dd HCl 0,4M . xc nh CTCT - ? Vit pt este tc dng vi bazo v d kin bi cho tm mi lin h gia R vi m v ca A R vi n . T tm R v R. Trng hp 3:X phng ha mt este hu c no n chc ch cho mt sn phm duy nht . Xc nh cu to ca este. HNG DN: X phng ha mt este hu c no n chc ch cho mt sn phm duy nht th este khng phi l este no n chc mch vng c CTTQ l: CnH2n C = O O 1; x phng ha mt este X n chc no bng mt lng va dd NaOH ch thu c mt sn phm duy nht Y khng c sn phm th hai d l mt lng nh.C cn dd sau phn ng nung cht Y vi vi ti xt thu c ru Z v mt mui v c. t chy hon ton ru Z thu c VCO2 : VH2O = 3 : 4 . Xc nh cng thc thu gn ca X ? 2; Mt este n chc X bit dX/O2 = 3,125 . Xc nh CTCT ca X trong mi trng hp sau: Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com a. 20 gam X tc dng vi 300 ml dd NaOH 1M . C cn dd sau phn ng thu c 23,2 gam b rn. b. 0.15 mol X tc dng va vi dd NaOH . C cn dd sau phn ng thu 21 gam mui khan ( mch khng nhnh ). Trng hp 4: X phng ha mt este sn phm ch gm mt mui v mt ru c s mol bng s mol ca este. Xc nh CTCT ca este bit neste = 1/2 n OH HNG DN: T l s mol este bng s mol bazo kim suy ra este c hai nhm este v c th thuc loi sau: R(COOR)2 , (RCOO)2R , R(COO)2R Nu bi cho neste = nmui = nr ch c cng thc R(COO)2R l tha mn 1;Cho 0,1 mol mt este X phn ng ht vi 100 ml dd NaOH 0,2M. Sn phm to ra ch gm mt mui v mt ru c s mol bng nhau v bng s mol ca este , u c cu to thng. Mt khc khi x phng ha hon ton 2,58 gam este bng lng KOH va phi dng ht 20ml dd KOH 1,5M thu c 3,3 gam mui. Xc nh CTCT ca este ? 2;Cho 0,01 mol mt este ca axit hu c phn ng va vi 100 ml dd NaOH 0,2M . sn phm to thnh ch gm mt ru v mt mui vi s mol bng nhau. Mt khc khi x phng ha 1,29 gam este bng mt lng va l 60 ml dd KOH 0,25M thu c 1,665 gam mui khan. Xc nh CTCT ca este ? Ch 3:Xc nh CTCT ca este n chc hoc este v cc cht h c trong hn hp Dng 1: Hai este tc dng vi dd bazo thu c hai mui v mt ru HNG DN: C hai kh nng : (1) RCOOR , R1COOR v (2) RCOOR , RCOOH a. Khi nru = nNaOH th l hai este (1) b. Khi nru < nNaOH th l (2) 1; Mt hn hp X gm hai cht hu c . Cho hn hp X phn ng va vi 100ml dd KOH 5M thu c hn hp hai mui ca hai axit no n chc v mt ru no n chc Y . Cho ton b Y tc dng ht vi vi Natri thu c 3,36 lit H2 (ktc). Cho bit hai hp cht hu c l hp cht g? 2; Cho hn hp M gm hai cht hu c mch thng X , Y ( ch cha C ,H ,O ) tc dng va vi 8 gam NaOH thu c mt ru n chc v hai mui ca hai axit hu c n chc k tip nhau trong dy ng ng . Lng ru thu c tc dng vi Na d thu c 2,24 lit kh H2 (ktc). X v Y thuc loi cht no? Dng 2: Vi u bi cho d kin hai cht hu c n chc mch h tc dng vi bazo cho mt mui v mt ru . Xc nh CTCT ca hai cht hu c. HNG DN: Ta c th bin lun nh sau: C ba kh nng hai cht hu c l: - Mt este v mt ru c gc hidrocacbon ging ru trong este - Mt este v mt axit c gc hidrocacbon ging axit trong este - Mt axit v mt ru Ty theo d kin bi cho m ta xc nh c hai cht hu c Bi tp: Cho hn hp M gm hai cht hu c no , n chc cha cc nguyn t C , H , O tc dng va vi 20 ml dd NaOH 2M thu c mt mui v mt ru. un nng lng ru trn vi H2SO4 c 170oC to 369,6 ml kh 27,3oC v 1 atm. Nu t chy hon ton M ri dn sn phm qua bnh ng CaO d th khi luwongj bnh tng 7,75 gam. Cho bit hai hp cht hu c l hp cht g?

Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Dng 3: Vi u bi cho d kin hai cht hu n chc mch h tc dng vi bazo cho mt mui v hai ru. Xc nh CTCT hai cht hu c. HNG DN: C hai trng hp xy ra: (1) : RCOOR v RCOOR1 (2) : RCOOR v R1OH Bi tp : t chy hon ton mt lng hn hp hai cht hu c n chc , no , mch h cn 3,976 lit O2 (ktc) thu c 6,38 gam CO2 . Cho lng este ny tc dng va vi KOH thu c hn hp hai ru k tip nhau v 3,92 gam mui ca mt axit huc c. Xc nh CTCT ca hai hp cht hu c ? 4.bi tp ch s axit- ch s x phng ha LIPIT V X PHNG L thuyt bi tp: (RCOO)3C3H5 + 3KOH 3RCOOK + C3H5(OH)3 (1) Cht bo RCOOHt do + KOH RCOOK + H2O (2) Bo + KOH mui(x phng) + C3H5(OH)3 + H2O (3) Cn nm r cc khi nim 1. Ch s axit: l s mg KOH(2) cn trung ho ht axit t do c trong 1 gam cht bo 2. Ch s este: l s mg KOH(1) cn thu phn ht este bo c trong 1 gam cht bo 3. Ch s x phng = ch s axit + ch s este 4. Khi lng x phng thu c khi x phng ha. p dng nh lut bo ton khi lng cho phng trnh s (3) mbo + mKOH = mx phng + mH2O + mglixerol mx phng = mbo + mKOH - mH2O - mglixerol Bi tp luyn tp Cu 1: Trung ho 2,8 gam cht bo cn 3ml dung dch KOH 0,1 M. Tnh ch s axit ca cht bo? A. 6 B. 0,6 C. 0,06 D. 0,006 Cu 2: Khi x phng ho hon ton 2,52 gam cht bo trung tnh cn 90 ml dung dch KOH 0,1M. Tnh ch s x phng ca cht bo trn? A. 200 B. 192 C. 190 D. 198 Cu 3: khi x phng ho hon ton 2,52 gam cht bo trung tnh thu c 0,265gam glixerol. Tnh ch s x phng ca cht bo? A. 18 B. 80 C. 180 D. 8 Cu 4: x phng ho hon ton 100gam cht bo c ch s axit bng 7 ngi ta dng ht 0,32 mol KOH. Khi lng glixerol thu c l bao nhiu gam? A. 9,4 gam B. 9,3gam C. 8,487 gam D. 9,43 gam Cu 5: Tnh khi lng KOH cn dng trung ho 4 gam cht bo c ch s axit l 7? A. 28mg B. 14mg C. 82mg D. p n khc. Cu 6: Tnh khi lng NaOH cn dng trung ho axit t do c trong 5 gam bo vi ch s axit bng 7? A. 0,025mg B. 0,025g C. 0,25mg D. 0,25g Cu 7: X phng ho 1kg lipit c ch s axit l 2,8 ngi ta cn dng 350 ml KOH 1M. Khi lng glixerol thu c l bao nhiu? A. 9,2gam B. 18,4 gam C. 32,2 gam D. 16,1 gam Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Cu 8: Mt loi m cha 40% triolein, 20% tripanmitin, 40% tristearin. X phng ho hon ton m gam m trn bng NaOH thu c 138 gam glixerol. Gi tr ca m l? A. 1209 B. 1304,27 C. 1326 D. 1335 Cu 9: Mt loi m cha 70% triolein v 30% tristearin v khi lng. Tnh khi lng x phng thu c khi x phng ho hon ton 100kg cht m bng NaOH? A. 90,8kg B. 68kg C. 103,16kg D. 110,5kg Cu 10: X phng ho hon ton 0,1 mol cht hu c X ( cha C, H, O) cn va 300 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c 24,6 gam mui khan. Xc nh CTPT ca X? A. (HCOO)3C3H5 B. (CH3COO)3C3H5 C. C3H5(COOCH3)3 D. (CH3COO)2C2H4 Cu 11: Tnh ch s este ca mt loi cht bo cha 89% tristearin? A. 168 B. 84 C. 56 D. p n khc Cu 12: un 20 gam lipit vi dung dch cha 10 gam NaOH. Sau khi kt thc phn ng trung ho 1/10 dung dch thu c cn dng 90 ml dung dch HCl 0,2 M. Tnh ch s x phng ho v phn t khi trung bnh ca axit bo trong lipit? A. 140 v 273 B. 120 v 273 C. 130 v 273 D. p n khc Cu 13: Cho 0,25 mol NaOH vo 20 gam bo trung tnh ri un nng ln, khi phn ng xy ra hon ton ngi ta thu c dung dch c tnh baz, trung ho dung dch ny phi dng ht 0,18 mol HCl. Tnh khi lng NaOH cn x phng ho 1 tn cht bo trn? A. 0,14 tn B. 1,41 tn C. 0,41 tn D. p n khc Cu 14: x phng ho 63mg cht bo trung tnh cn 10,08 mg NaOH. Tnh ch s x phng ho ca cht bo? A. 200 B. 224 C. 220 D. 150 Cu 15: trung ho axit t do c trong 5,6 gam cht bo cn 6 ml dung dch NaOH 0,1 M. Tnh ch s axit ca cht bo ni trn? A. 3,2 B. 4 C. 4,7 D. p n khc Cu 16: phn ng vi 100 gam cht bo c ch s axit bng 7 phi dng ht 17,92 gam KOH. Tnh khi lng mui (x phng) thu c? A. 108,265g B. 100,265g C. 100g D. 120g Cu 17: Tnh khi lng NaOH cn dng trung ho cc axit bo t do c trong 200 gam cht bo, bit cht bo c ch s axit bng 7? A. 5g B. 9g C. 1g D. 15g bi tp tng hp v este- lipit Cu1.Cho phn ng este ha : RCOOH + ROH R-COO-R + H2O . phn ng chuyn di u tin theo chiu thun, cn dng cc gii php sau : A.Tng nng ca axit hoc ancol B.Dng H2SO4 c xc tc v ht nc. C.Chng ct tch este ra khi hn hp phn ng . D.C A,B v C Cu2. C4H6O2 c bao nhiu ng phn mch h phn ng c vi dung dch NaOH? A. 5 ng phn. B.6 ng phn. C.7 ng phn. D.8 ng phn. Cu3 .Cng thc tng qut ca este to bi axit n chc no mch h v ancol n chc no mch h c dng. A. CnH2n+2O2 ( n 2) B.CnH2nO2 (n 2) C.CnH2nO2 ( n 3) D.CnH2n-2O2 ( n 4) Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Cu4 .Hn hp A gm 2 este n chc no, ng phn. Khi trn 0,1 mol hn hp A vi O2 va ri t chy thu c 0,6 mol sn phm gm CO2 v hi nc. Cng thc phn t 2 este l A.C4H8O2. B. C5H10O2. C.C3H6O2. D.C3H8O2. Cu5 .Mt hp cht hu c n chc c cng thc C3H6O2 khng tc dng vi kim loi mnh, ch tc dng vi dung dch kim, n thuc dy ng ng : A.Acol B. Este. C. Andehit. D. Axit. Cu6 .X l este mch h do axit no A v ancol no B to ra. Khi cho 0,2 mol X phn ng vi NaOH thu c 32,8 gam mui. t chy 1 mol B cn dng 2,5 mol O2. Cng thc cu to ca X l A. (CH3COO)2C2H4. B.(HCOO)2C2H4. C. (C2H5COO)2C2H4. D. (CH3COO)3C3H5. Cu7. iu ch thy tinh hu c, ngi ta trng hp t : A. CH2= CH-COOCH3 B.CH2= CH-COOH C. CH2= C-COOCH3 D.CH2= C-COOH CH3 CH3 Cu8. Cho s : C4H8O2 X YZC2H6. Cng thc cu to ca X l A. CH3CH2CH2COONa. B. CH3CH2OH C. CH2=C(CH3)-CHO D. CH3CH2CH2OH. Cu9. Este X c cng thc C4H8O2 c nhng chuyn ho sau : . + H2O .+O2 Y2 X Y1 + Y2 Y1 .+ xt H tha mn iu kin trn th X c tn l : A. Isopropyl fomiat B .Etyl axetat. C. Metyl propyonat. D. n-propyl fomiat. Cu10. A c cng thc phn t trng vi cng thc n gin. Khi phn tch A thu c kt qu: 50% C, 5,56% H, 44,44%O theo khi lng. Khi thu phn A bng dung dch H2SO4 long thu c 2 sn phm u tham gia phn ng trng bc. Cng thc cu to ca A l A. HCOO-CH=CH-CH3. B. HCOO-CH=CH2. C. (HCOO)2C2H4. D.CH2=CH-CHO. Cu11. Cho 13,2 g este n chc no E tc dng ht vi 150 ml dung dch NaOH 1M thu c 12,3 g mui . Xc nh E. A.HCOOCH3 B.CH3-COOC2H5 C.HCOOC2H5 D.CH3COOCH3 Cu12.X c cng thc phn t C3H4O2. Khi cho X phn ng vi dung dch NaOH thu c 1 sn phm duy nht. Xc nh cng thc cu to ca X ? A.CH2=CH-COOH. B.HCOOCH=CH2.
H H3C C C O

O C. . D. C A, B v C Cu13.Thy phn 1 este n chc no E bng dung dch NaOH thu c mui khan c khi lng phn t bng 24/29 khi lng phn t E.T khi hi ca E i vi khng kh bng 4. Cng thc cu to. A. C2H5COOCH3. B.C2H5COOC3H7 C.C3H7COOCH3 D.CH3COOCH3 Cu14. X cc cng thc phn t C4H6O2Cl2. Khi cho X phn ng vi dung dch NaOH thu c CH2OHCOONa, etylenglicol v NaCl. Cng thc cu to ca X? A CH2Cl-COO-CHCl-CH3. B. CH3-COO-CHCl-CH2Cl. C.CHCl2-COO-CH2CH3. D.CH2Cl-COO-CH2-CH2Cl.

Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Cu15. Este X c cha vng benzen v c cng thc phn t l C8H8O2. Hy cho bit X c bao nhiu cng thc cu to ? A. 7 B. 4 C. 5 D. 6 Cu16. X l este to t ancol no n chc v axit no u mch h. X khng tc dng vi NaOH. Trong phn t X c cha 2 lin kt . Hy cho bit cng thc chung no ng nht vi X ? A. CnH2n-2O2 B. CnH2n-2O4 C. R(COOR)2 D. CnH2n(COOCmH2m+1)2 Cu17. Cht hu c X c CTPT l C3H5Cl3. un nng X trong dung dch NaOH thu c cht hu c n chc. Vy tn gi ca X l : A. 1,2,3-triclo propan B. 1,1,1-triclo propan C. 1,1,3-triclo propan D. 1,2,2-triclo propan Cu18. Thy phn hon ton este X trong NaOH thu c mui ca mt axit no v mt ancol no (u mch h). X khng tc dng vi Na. t chy hon ton X thu c s mol CO2 gp 4 ln s mol X. Hy cho bit c bao nhiu cht tha mn. A. 4 B. 5 C. 6 D. 7 Cu19 un nng este X trong NaOH thu c natri acrylat v ancol n chc Y. Oxi ha Y trong iu kin thch hp thu c axit acrylic. Hy cho bit cng thc phn t ca X. A. C6H10O2 B. C6H12O2 C. C6H6O2 D. C6H8O2. Cu20. Thy phn hon ton hn hp X gm 2 lipit thu c glixerol v 2 mui natri oleat v natri stearat. Hy cho bit c bao nhiu cp lipit tha mn ? A. 2 B. 3 C. 4 D. 5 Cu21. Mt este to t axit no n chc v ancol bc III n chc mch h. Vy cng thc chung ca este l : A. CnH2nO2 ( n5) B. CnH2nO2 ( n4) C. CnH2nO2 ( n3) D. CnH2nO2 (n2) Cu22. Este X c cng thc phn t l C4H6O2. un nng X trong dung dch NaOH v Cu(OH)2 d thu c s mol Cu2O gp i s mol X phn ng. Hy cho bit c bao nhiu cht tha mn. A. 1 B. 3 C. 2 D. 4 Cu23. Cht X c cng thc phn t l C10H`10O2. un nng X trong NaOH thu c 2 mui u c phn t khi > 100. Hy cho bit c bao nhiu cht tha mn. A. 3 B. 4 C. 5 D. 2 Cu24. Este X c cng thc phn t l C5H10O2. un nng X thu c ancol Y v mui Z. hirat ha Y thu c anken Y1. Cho Y1 tc dng vi H2O li thu c ancol Y (duy nht). Vy tn gi ca X l : A. Etyl propionat B. n-propylaxetat C. iso-propyl axetat D. sec-butyl fomat Cu25. Cho 0,1 mol este X n chc vo 100 gam dung dch NaOH 8%, un nng phn ng thy phn hon ton thu c 110 gam dung dch. C cn dung dch sau phn ng thu c 14,8 gam cht rn khan. Hy cho bit X c th c bao nhiu cng thc cu to ? A. 1 B. 2 C. 3 D. 4 Cu26. Cho cc cht sau: CH3COOC2H3 (I) , C2H3COOH (II) , CH3COOC2H5 (III) v CH2=CH-COOCH3 (IV). Cht no va tc dng vi dung dch NaOH, dung dch nc brom. A. I, II, IV B. I, II, III C. I, II, III, IV D. I v IV. Cu27. Thy phn hon ton 0,1 mol este X cn 200 ml dd NaOH 1M thu c 9,2 gam glixerol v 16,2 gam hh Y gm 2 mui. Vy 2 mui trong hh Y l : A.CH3COONa v CH2=CHCOONa B. HCOONa v CH2=CH-COONa C. HCOONa v CH3CH2COONa D. HCOONa v CH3COONa Cu28. Cht hu c X c cng thc phn t l C5H8O2. Cho X tc dng vi dung dch Br2 thu c cht hu c Y c cng thc l C5H8O2Br2. un nng Y trong NaOH d thu c glixerol, NaBr v mui cacboxylat ca axit Z. Vy cng thc cu to ca X l : Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com A. CH3COOCH2-CH=CH2 B. CH3-COOCH=CH-CH3 C. CH2=CH-COOCH2CH3 D. HCOOCH(CH3)-CH=CH2. Cu29. Hn hp X gm etyl axetat v n-propyl axetat. un nng hn hp X vi NaOH (va ) thu c 13,12 gam mui v 8,76 gam hn hp ancol Y. Vy % khi lng ca etyl axetat trong hn hp X l : A. 56,85% B. 45,47% C. 39,8% D. 34,1% Cu30. Thy phn hon ton 17,6 gam hh X gm metyl axetat v etyl fomiat bng dd NaOH 2M. Tnh th tch dd NaOH 2M cn dng. A. 75 ml B. 100 ml C. 125 ml D. 200 ml Cu31. Cht X n chc c CT n gin l l C2H4O. X tc dng vi AgNO3/ NH3 cho kt ta Ag. Xc nh s cht hu c tha mn? A. 1 B. 2 C. 3 D. 4 Cu32. Thc hin phn ng este ho gia axit axetic vi 2 ancol no n chc l ng ng k tip nhau thu c hn hp 2 este. t chy hon ton 0,1 mol hn hp 2 este thu c 10,08 lt CO 2. Hy la chn cng thc cu to ca 2 ancol ? A. CH3OH v C2H5OH B. C2H5OH v CH3CH(OH)CH3 C. CH3-CH2-CH2 OH v CH3CH2CH2CH2 OH D. C2H5OH v CH3CH2CH2OH Cu33. Hn hp X gm 2 cht hu c n chc. tc dng vi 0,1 mol hn hp X cn 0,1 mol NaOH thu c dung dch cha 2 mui v mt ancol. Tch ly ton b lng ancol ri cho phn ng vi Na d thu c 1,12 lt H2 (ktc). Hy cho bit kt lun no sau y ng ? A. X gm 1 axit v 1 este. B. X gm 2 este C. X gm mt axit v mt ancol. D. X gm 1 este v mt ancol. Cu34. Cht X c cng thc cu to sau: CH2=CH-O-CH=O. Hy cho bit khi un nng 0,1 mol X trong dung dch NaOH c cha Cu(OH)2 d. Tnh s mol Cu2O thu c. A. 0,1 mol B. 0,15 mol C. 0,2 mol D. 0,3 mol Cu35. Thy phn hon ton 0,1 mol este X cn 200 ml dd NaOH 1,5M. C cn dung dch sau phn ng thu c glixerol v 24,6 gam cht rn khan. Hy cho bit X c bao nhiu CTCT ? A. 1 B. 4 C. 7 D. 6 Cu36. X l este to t axit n chc v ancol 2 chc. X khng tc dng vi Na. Thu phn hon ton 0,1 mol X bng NaOH (va ) thu c hn hp sn phm c tng khi lng l 21,2 gam. Hy cho bit c nhiu este tho mn iu kin ? A. 1 B. 2 C. 3 D. 4 Cu37. Hn hp X gm etyl axetat v n-propyl axetat. Thy phn hon ton X trong 200 ml dung dch NaOH 1M. Trung ha lng kim d cn 50 ml dung dch HCl 1M. C cn cn thn dung dch sau phn ng thu c cht rn khan c khi lng l: A. 15,225 gam B. 12,525 gam C. 15,252 gam D. 12,255 gam Cu38. Thy phn hon ton hn hp X gm 2 este n chc A, B cn dng 100 ml dung dch NaOH 1M thu c 6,8 gam mui duy nht v 4,04 gam hn hp 2 ancol l ng ng lin tip nhau. Cng thc cu to ca 2 este l: A. HCOOCH3 v HCOOC2H5 B. CH3COOCH3 v CH3COOC2H5 C. C2H3COOCH3 v C2H3COOC2H5 D. HCOOC2H5 v HCOOC3H7 Cu39. C cc cht lng sau: etyl axetat, etyl fomat, glixerol trifomat v glixerol triaxetat. Hy cho bit cp ha cht no c th s dng phn bit cc cht lng trn ? A. Cu(OH)2 v dd NaOH. B. Cu(OH)2 v dd H2SO4. C. CuSO4 v dd NH3 D. Ag2O/ NH3 v dd NaOH. Cu40. X l ancol bc ba, mch h c cng thc l C5H10O. T X ngi ta thc hin s bin ha sau: X C5H9Br C5H9Br3 C5H12O3 Y(C8H12O6). Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Hy cho bit trong cc cht sau : Na, Ag2O/ NH3, t0 ; Cu(OH)2/ dd NaOH,t0 ; NaOH t0 ; CH3COOH (xt H2SO4 c, t0) ; CH3OH (xt H2SO4 c, t0 ) ; NaHCO3 . Cht Y tc dng c vi bao nhiu cht ? A. 6 B. 3 C. 4 D. 5 Cu41. Cho cc cht sau : CH3-COOCH=CH2 ; CH2=CH-Cl ; CH3-CHCl2 ; CH3-CCl3 ; (CH3COO)2CH-CH3 ; CH3COOCH=CH-CH3. Hy cho bit c bao nhiu cht khi un nng vi dung dch NaOH thu c mui v anehit ? A. 5 B. 6 C. 4 D. 3 Cu42. Thy phn hon ton hn hp X gm 2 este n chc cn dng 100 ml dung dch NaOH 1M thu c 8,2 gam mui duy nht v 4,04 gam hn hp 2 ancol l ng ng lin tip nhau. Cng thc cu to ca 2 este l: A. HCOOCH3 v HCOOC2H5 B. CH3COOCH3 v CH3COOC2H5 C. C2H3COOCH3 v C2H3COOC2H5 D. HCOOC2H5 v HCOOC3H7 Cu43. C cc cht lng sau: Triolein, axit axetic, ancol etylic, benzen. Ha cht no sau y c th s dng nhn bit cc cht . A. dd NaOH v CaCl2 B. dd Na2CO3 v dd NaOH C. dd H2SO4 v dd NaOH D. dd NaOH v Cu(OH)2. Cu44. Este X c cng thc phn t l C4H8O2. un nng X trong dung dch NaOH thu c mui X1 v ancol X2. Oxi ha X2 thu c cht hu c X3. X3 khng c phn ng trng gng. Vy tn gi ca X l : A. metyl propionat B. etyl axetat C. n-propyl fomiat D. isopropyl fomiat. Cu45. Mt este c cng thc phn t l C4H8O2, khi thy phn trong mi trng axit thu c ru Y. Oxi ha ru Y thnh anehit Y1 sau cho Y1 tham gia phn ng trng gng thu c s mol Ag gp 4 ln s mol Y1. Vy tn gi ca este l : A. metyl propionat B. etyl axetat C. n-propyl fomiat D. isoproyl fomiat. Cu46. Hn hp X gm 2 cht hu c n chc. Cho 0,1 mol X tc dng va 0,1 mol NaOH, c cn dung dch sau phn ng thu c 7,36 gam hn hp mui v ancol Y. Oxi ha hon ton ancol Y bng CuO thu c anehit. Cho ton b lng anehit tc dng vi Ag2O/ NH3 thu c 25,92 gam Ag. Xc nh cng thc ca 2 cht trong hn hp X. A. CH3COOH v HCOOC2H5. B. CH3COOH v HCOOCH3 C. CH3COOCH3v CH3COOC3H7 D. HCOOH v CH3COOCH3. Cu47. un nng 10 gam este X n chc vi 200 ml dung dch NaOH 1,5M (ly d). C cn dung dch sau phn ng thu c cht rn G c khi lng 17,4g v mt ancol Y. hirat ha Y thu c 2,24 lt anken. (Hiu sut tch nc t 100%). Vy cng thc ca X l: A. CH3COOC2H5 B. CH2=CH-COOC2H5 C. HCOOCH2-CH2CH3 D. HCOOCH2-CH3 Cu48. Cho 4,6 gam ancol X tc dng vi Na d thu c 1,12 lt H2. Cho 9,0 gam axit hu c Y tc dng vi Na d thu c 1,68 lt H2. un nng hn hp X gm 4,6 gam ancol X v 9 gam axit Y ( xt H2SO4 c,t0 ) thu c 6,6 gam este E. t chy hon ton E thu c CO2 v nc theo t l mol l 1: 1. Xc nh hiu sut phn ng to thnh este. A. 50% B. 60% C. 75% D. 80% Cu49. Este X cu to t ancol X1 n chc v axit X2 a chc c cng thc n gin l C2H3O2. Hy cho bit c bao nhiu cht tho mn ? A. 1 B. 2 C. 3 D. 4 Cu50.un nng 0,1 mol cht X ch cha mt loi nhm chc tc dng va vi NaOH trong dd thu c 13,4 gam mui ca axit hu c Y mch thng v 9,2 gam ancol n chc. Cho ton b lng ancol tc dng vi Na thu c 2,24 lt H2 (ktc). Xc nh CTCT ca X. A. ietyl oxalat B. Etyl propionat C. ietyl aipat D. imetyl oxalat. Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Cu51. Thy phn hon ton 0,1 mol este E (mch h v ch cha mt loi nhm chc) cn dng va 100 ml dung dch NaOH 3M, thu c 24,6 gam mui ca mt axit hu c v 9,2 gam mt ancol. Cng thc ca E l : A. C3H5(COOC2H5)3 B. (HCOO)3C3H5 C. (CH3COO)3C3H5 D. (CH2=CH-COO)3C3H5 Cu52. Ngi ta iu ch etyl axetat t xenluloz theo s sau: xenluloz glucoz ancol etylic axit axetic etyl axetat. Tnh khi lng xenluloz cn dng c th iu ch c 1 mol etyl axetat. Bit hiu sut chung ca qu trnh t 40%. A. 405 gam B. 202,5 gam C. 162 gam D. 506,25 gam Cu53. Cho s sau : C4H7ClO2 + NaOH mui X + Y + NaCl. Bit rng c X, Y u tc dng vi Cu(OH)2 . Vy cng thc cu to ca cht c cng thc phn t C4H7ClO2 l : A. Cl-CH2-COOCH=CH2 B. CH3COO-CHCl-CH3 C. HCOOCH2-CH2-CH2Cl D. HCOO-CH2-CHCl-CH3 Cu54. Nhng cht no sau y tc dng vi ancol etylic (xt H2SO4 c) to thnh este? A. axit phenic, axit benzoic; axit axetic. B. axit picric, axit benzoic; axit axetic. C. axit benzoic; axit axetic v axit aipic D. axit picric; axit axetic v axit aipic. Cu55. Cho cc cht sau: (1) CH3-CO-O-C2H5; (2) CH2=CH-CO-O-CH3 ; (3) C6H5-CO-O-CH=CH2; (4) CH2=C(CH3)-O-CO-CH3 (5) C6H5O-CO-CH3 (6) CH3-CO-O-CH2-C6H5. Hy cho bit cht no khi cho tc dng vi NaOH un nng thu c khng thu c ancol? A. (1) (2) (3) (4) B. (3) (4) (5) C. (1) (3) (4) (6) D. (3) (4) (5) (6). Cu56. Cht no sau y tc dng vi NaOH thu c mui c khi lng ln nht? A. CH3COOCH2-C6H5 B. CH2=C(CH3)-COOCH3 C. HCOOC6H5 D. C2H5COO-CH=CH-CH3 Cu57. Cht hu c X mch h, phn nhnh c cha C, H, Br. MX = 135. Thy phn X trong dung dch NaOH un nng thu c anehit Y. Vy cng thc cu to ca X l: A. CH2=C(CH3) -CHBr2 B. CH2=C(CH3)-CH=CH-Br C. Br-CH=C(CH3)2 D. Br2CH-CH=C(CH3)2 Cu58. Cho s phn ng sau: C4H6O2Cl2 + dd NaOH d(t0) mui ca axit X (n chc) + H2O + NaCl. CTCT ca mui l: A. CH3COONa B. HCOONa C. HO-CH2- COONa D. C2H3COONa. Cu59. t chy hon ton 0,1 mol este n chc X cn 0,5 mol O2 thu c 8,96 lt CO2 v b mol H2O. a/ Vy s mol H2O thu c l : A. 0,3 mol B. 0,35 mol C. 0,2 mol D. 0,4 mol b/ un nng 0,1 mol X vi 200 ml dd NaOH 1M , c cn dd sau phn ng thu c 12,2 gam cht rn khan. Vy cng thc ca X l : A. CH3COOCH3 B. CH2=CH-COOCH3 C. CH3COOC2H5 D. CH3CH2COOCH3 Cu60. Este X to t hn hp 2 axit n chc X1, X2 v glixerol. un nng X vi dung dch NaOH thu c 9,2 gam glixerol v 15 gam hn hp 2 mui. Hy cho bit cng thc ca 2 axit . A. HCOOH v CH3COOH B. HCOOH v C2H5COOH C. CH3COOH v C2H3COOH D. HCOOH v C2H3COOH. Cu61. Este X n chc tc dng vi NaOH un nng thu c mui Y c cng thc phn t l C3H5O2Na v ru Y1. Oxi ha Y1 bng CuO nung nng thu c anehit Y2. Y2 tc dng vi Ag2O d, un nng thu c s mol Ag gp 4 ln s mol Y2. Vy tn gi ca X l : A. Etyl propionat B. metyl propionat C. metyl axetat Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com D. propyl propionat. Cu62. un nng hn hp X gm 2 este n chc vi NaOH thu c 7,36 gam hn hp 2 mui ca 2 axit k tip nhau trong dy ng ng v 3,76 gam hn hp 2 ancol k tip nhau trong dy ng ng. Vy 2 este l : A. HCOOCH3 v CH3COOC2H5 B. CH3COOCH3 v HCOOC2H5 C. CH3COOC2H5 v C2H5COOCH3 D.HCOOC3H7 v CH3COOC2H5 Cu63. Este X c cng thc phn t l C5H8O2. un nng 0,1 mol X vi 200 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c 13,4 gam cht rn khan. Vy cng thc ca este l : A. CH3COO-CH2-CH=CH2 B. CH2=CH-COOC2H5 C. CH2=C(CH3)-COOCH3 D. HCOOCH=C(CH3)2. Cu64. Este X c cng thc phn t C7H10O4 mch thng. Khi cho 15,8 gam X tc dng va vi 200 gam dd NaOH 4% th thu c mt ancol Y v 17,6 gam hn hp 2 mui. Cng thc cu to ca 2 mui no sau y c th tha mn : A. C2H3COONa v C2H5COONa B. CH3COONa v C2H3COONa C. CH3COONa v C3H5COONa D. HCOONa v C2H3COONa

C. Cc kim tra t luyn

I. s 01
(thi gian lm bi 60 pht) Cu 01: Ha tan 4,84 gam Mg bng dd HCl thy thot ra 0,4gam H2 a) xc nh nguyn t lng ca Mg b) Mg kim loi cho trn gm 02 ng v trong c ng v 24 12 Mg. xc nh s khi ca ng v cn li, bit t s ca 2 loi ng v l 4:1 Cu 02: 1. Cho dd HCl c ph=4. hi phi pha long dd trn bng nc ct bao nhiu ln thu c dd HCl c Ph =6 2. cho a mol NO2 hp th vo dd cha a mol NaOH. X khong ca Ph dd Cu 03: A l hn hp dng bt gm Fe v kim loi M. chom 8,64 gam hn hp A tc dng va vi 80ml dd CuSO4 1,5M. mt khc ly lng A nh trn ha tan ht trong dd HNO3 thu c 3,136 lit NO duy nht ktc v trong dd khng c NH4NO3 Vit cc pt p xy ra , xc nh M bit M c ha tr khng i Cu 04: Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com 1. Ha tan hon ton 11,2 gam CaO vo nc thu c dd A, nu cho CO2 sc qua A thu c 2,5 gam kt ta. tm th tch ca CO2 2. cho 10,38 g hn hp gm Fe, Al,Ag chia lm 2 phn bng nhau - phn 01: tc dng vi H2SO4 d thu c 2,352 lit khi (ktc) - phn 02: tc dng vi dd H2SO4 c, nng, d thu c 2,912 lt kh ktc tnh thnh phn hn hp u Cu 05: tin hnh p nhit nhm hn hp nhm gm Al v Fe2O3 khng c khng kh. Chia hn hp sau p trn u thnh 02 phn khng bng nhau. Phn 01 tc dng vi dd NaOH d c 1,68 lt kh ktc. Phn 02 tc dng va vi 1,95 lit dd HCl 1M thot ra 11,76 lt kh ktc. Hiu sut cc p l 100%. Tnh khi lng Fe to thnh trong p nhit nhm Cu 06: ha tan va ht hn hp X gm Cu, CuO, Cu(NO3)2 (trong s mol Cu bng s mol CuO) vo 350ml dd H2SO4 2M (long) th thu c dd ch cha 1 mui duy nht v c kh NO. tnh khi lng Cu trong hn hp X

II/ s 02
(thi gian lm bi 60 pht) Cu 01: Cu hnh electron ngoi cng cua ntnt X l 5p5. t s notron v proton bng 1,3962. s notron trong nt X gp 3,7 ln s notron trong ntnt Y. khi cho 1,0725 gam Y tc dng vi lng d X thu c 4,565 gam sn phm c ct XY Cu 02: 1. Cn bng ptpu sau bng pp thng bng electron: - FexOy + HNO3 Fe(NO3)3 + NO + H2O - Mg + HNO3 Mg(NO3)2 + NH4NO3 + H2O - KMnO4 + FeSO4 + H2SO4 Fe2(SO4)3 +.+.+.. - Cl2 + Ca(OH)2 CaOCl2 + H2O 2. Mt dd cha hai cation l Fe2+ (0,1 mol) v Al3+ ( 0,2 mol) v hai anion l Cl- v SO42- . tnh s mol mi anion trong dd Cu 03: Ha tan 50 gam hn hp gm Al-Zn vo dd A cha NaNO3 v NaOH, thy thot ra hn hp kh B gm H2 v NH3 c th tch l V a) vit ptpu dng pt v ion b) tnh khong x ca V Cu 04: 1. ha tan m gam hn hp gm Fe v kim loi M c ha tr khng i trong dd HCl d th thu c 1,008 lit kh ktc v dd cha 4,575 gam mui khan. Tnh m 2. ha tan hn hp trn trong dd HNO3 c v H2SO4 nhit thch hp th thu c 1,8816 lit hn hp 2 kh ktc c t khi so vi hiro l 25,25. hy x kim loi M Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN

V Thanh Tng_k56cnghh_i Hc Tng Hp H Ni_Luyn thi i hc nm hc 2011-2012. mi thc mc v bi lin h st 0985556536 hoc e-mail vuthanhtung.tb@gmail.com Cu 05: 8,96 lt hn hp A gm N2 v H2 c t khi hi so vi oxi bng 17/64, cho A vo mt bnh kn c cht xc tc thch hp ri un nng th thu c hn hp kh B gm N2, H2, NH3 c th tch 8,064 lt, cc kh u o ktc. Tnh hiu sut qu trnh iu ch NH3 v % th tch mi kh trong B

III. s 03:
(thi gian lm bi 60 pht) Cu 01: Hp cht M c to thnh t cation X+ v anion X2-. Mi ion u do 5 nt ca 2 nguyn t to thnh. Tng s proton trong X+ l 11 v tng s electron trong Y2- l 50. xc nh ctpt v gi tn M Cu 02: 1. Hon thnh cc p sau dng pt , ion - Cu(NO3)2 + NaOH - NaHCO3 + NaHSO4 - NaAlO2 + AlCl3 - NaCl + AgNO3 2. dn lung kh CO i qua ng kh cha m gam hn hp rn X gm CuO v Fe2O3 un nng. Sau mt thi gian ng s cn li n gam hn hp cht rn Y. kh thot ra c hp th bng dd Ca(OH)2 d thu c p gam kt ta. lp biu thc lin h m,n,p Cu 03: Chia hn hp 2 kim loi ha tr 2 v 3 thnh 3 phn bng nhau - phn 1 cho tc dng vi 1lit dd HCl 2M thu c dd A v 17,92 lt kh H2 (ktc) - phn 02 cho tc dng vi dd NaOH d thu c 13,44 lt H2(ktc)v cn li 30,76% khi lng kim loi ha tr 2 khng tan - oxi ha hon ton phn 3 thu c 28,4 gam hn hp oxit tnh khi lng kim loi ban u v x tn kim loi Cu 04: cho 500ml dd A gm BaCl2 v MgCl2 p vi 120ml dd Na2SO4 0,5M d thi thu c 11,65 gam kt ta. em phn dd c cn th thu c 16,77 gam hn hp mui khan. Xc nh nng mol cc cht trong dd A cu 05: ly 31,8 gam hn hp X gm MgCO3 v CaCO3 bng 0,8 lt dd HCl 1M thu c dd Y. hy chng minh rng hn hp X b ha tan ht. cho dd Y vo mt lng d NaHCO3 thu c 2,24 lt CO2 ktc. Tnh thnh phn phn trm khi lng hn hp X

Tuyn tp bi tp ha hc trung hc ph thong. Ngi son: V Thanh Tng sv khoa ha HKHTN_HQGHN