TRNG I HC VINH

THI KHO ST CHT LNG LP 12 LN 2, NM 2013

TRNG THPT CHUYN

Mn: HA HC
(Thi gian lm bi: 90 pht; 50 cu trc nghim)

H v tn .................................................................. S bo danh ..........................

M thi 133

Cho khi lng nguyn t ca cc nguyn t (theo vC): C = 12; H = 1; O = 16; S = 32; Cu = 64; Fe = 56;
Al = 27; N = 14; Ca = 40; Ba = 137; Na = 23; Mg = 24; Cl = 35,5; Zn = 65; K = 39; Ag = 108; Br = 80; Be =
9; P = 31; Se = 79.
A. PHN CHUNG CHO TT C TH SINH (40 cu: T cu 1 n cu 40)
Cu 1: Vi cng thc phn t C3H6Cl2 th c bao nhiu cht khi tc dng vi dung dch NaOH d, un
nng, cho sn phm c phn ng vi Cu(OH)2 iu kin thch hp?
A. 3.

B. 1.

C. 2.

D. 4.

Li gii:
C 2 cht: CH3 CH2 CHCl2 v CH3 CHCl CH2Cl Chn C
Cu 2: Cho hi nc i qua than nng thu c 0,8 mol hn hp kh X gm CO, CO2 v H2. Cho ton
b X phn ng ht vi CuO d, un nng thu c hn hp cht rn Y. Ha tan ht Y bng dung dch HNO3
long, d thu c 0,4 mol kh NO (sn phm kh duy nht). T khi ca X so vi H2 l
A. 7,875.

B. 10,0.

C. 3,9375.

D. 8,0.

Li gii:
Bo ton e: 4.nC = 3nNO nC = 0,3 mol
Phn ng: C + H2O CO + H2
x

C + 2H2O CO + 2H2
y

2y

x + y = 0,3
x = 0,1
28.0,1 + 44.0,1 + 2.0,3

d X
=
.100 = 7,875%
H
2
0,8
2 x + 3 y = 0,8 y = 0,2
Cu 3: Trong cc cht sau: cumen, vinylbenzen, vinylaxetilen, axit fomic, phenol, axit acrylic, isopren.
C bao nhiu hirocacbon c th lm mt mu nc brom?
A. 6.

B. 5.

C. 4.

D. 3.

Li gii:
Gm cc cht: vinylbenzen, vinylaxetilen, isopren Chn D
Cu 4: Hp cht hu c X c cng thc phn t C6H9O4Cl. Bit rng:
X + NaOH d
Mui ca axit X1 + X2 + X3
C). Khi lng phn t (vC) ca X1 l:
A. 134.
Li gii:

B. 90.

C. 143.

+ NaCl (X2, X3 l cc ancol c cng s nguyn t

D. 112.

 bt bo ha ca X = 2 CTCT ca X: C2H5 OOC COO C2H4Cl

X1 l: HOOC COOH Chn B
Cu 5: Cho cn bng sau xy ra trong bnh kn c dung tch khng i:

2SO 3 (k) <

2SO2 (k) + O2 (k)
Yu t no sau y lm cho cn bng trn dch chuyn theo chiu nghch v tc phn ng thun tng?
A. Gim nhit ca h phn ng.

B. Thm cht xc tc phn ng.

C. Thm SO3 vo h phn ng.

D. Tng p sut.

Li gii: Loi A v lm gim tc phn ng. Loi B v khng lm thay i dch chuyn cn bng. Loi D v
cn bng dch chuyn theo chiu thun. Ch c C tha mn. Chn C
Cu 6: Cho 18,75 gam Al2S3 vo 600 ml dung dch NaOH 2M, sau khi cc phn ng kt thc, khng c
kh thot ra th s mol ca NaOH cn li l
A. 0,20.

B. 0,05.

C. 0,75.

D. 0,45.

Li gii:
mol Al2S3 = 0,125 mol.
Phn ng: Al2S3 + 8NaOH 2NaAlO2 + 3Na2S + 4H2O
mol NaOH phn ng = 8.0,125 = 1 mol. nNaOH d = 0,2 mol Chn A.
Cu 7: Thy phn mt loi cht bo thu c axit panmitic, axit linoleic v axit oleic. Ch s iot (s gam
iot c th cng vo lin kt bi trong mch cacbon ca 100 gam cht bo) ca loi cht bo trn l
A. 89,0.

B. 54,0.

C. 44,5.

D. 53,3.

Li gii:
Ta c n I 2 = 3.n cht bo ch s iot =

127.2 .3.100
= 89 Chn A
856

Cu 8: Cho cc th nghim sau:

(1) Sc O3 vo dung dch KI.

(2) Nhit phn KMnO4.

(3) Nhit phn NaHCO3.

(4) Cho H2O2 vo dung dch KMnO4 trong H2SO4 long.

(5) in phn NaOH nng ch y.

nghim to ra sn phm c O2?

(6) Nhit phn KClO3

A. 4.

B. 3.

C. 5.

c xc tc MnO2. C bao nhiu th

D. 6.

Li gii:
(1) Sc O3 vo dung dch KI O2

(2) Nhit phn KMnO4 O2

(3) Nhit phn NaHCO3 CO2

(4) Cho H2O2 vo dung dch KMnO4 trong H2SO4 long O2

(5) in phn NaOH nng ch y O2

(6) Nhit phn KClO3 c xc tc MnO2 O2

Chn C
Cu 9: Thc hin phn ng nhit nhm (trong iu kin khng c khng kh) hn hp X gm Al v Fe3O4

sau mt thi gian thu c m gam hn hp Y. Chia Y thnh hai phn bng nhau. Phn 1 tc dng va vi
100 ml dung dch NaOH 0,5M. Phn 2 tc dng ht vi dung dch HNO3 c nng, d thu c 3,696 lt
kh NO2 ( ktc, sn phm kh duy nht). Gi tr ca m l

A. 4,83.

B. 8,46.

C. 9,66.

D. 19,32.

Li gii:
Ta c: nAl = nNaOH = 0,05 mol.
Bo ton e : 3nAl + nFe3O4 = nNO2 nFe3O4 =

3.696
- 3.0,05 = 0,015 mol
22.4

m = 2(27.0,05 + 232.0,015) = 9.66 gam Chn C

Cu 10: Ha tan Fe3O4 trong dung dch H2SO4 long, d thu c dung d ch X. Dung dch X tc dng
c vi bao nhiu cht trong cc cht sau: Br2, H2S, K2Cr2O7, NaNO3, BaCl2, NaOH, KI?
A. 6.

B. 7.

C. 5.

D. 4.
3

Li gii: C 7 cht u phn ng Chn B

4
Cu 11: Cho (x + 1,5y) mol Ba(OH)2 vo dung dch x mol ch
a x mol NH 4+ , y mol Ba2+ v z mol HCO3 . Sau khi cc phn ng kt thc, un nng nh th dung dch thu c cha:

A. Ba(HCO3)2 v NH4HCO3.

B. (NH4)2CO3.

C. Ba(HCO3)2.

D. Ba(OH)2.

Li gii:
Ta c: nOH- = 2x + 3y mol.
n NH+ = x mol.
nHCO3- = z = x + 2y mol (Theo bo ton in tch)
Sau phn ng OH- d dung dch thu c khng th c A, B, C m ch c D Chn D
Cu 12: Oxi ha 26,6 gam hn hp X gm mt ancol n chc v mt anehit n chc, thu c mt axit
hu c duy nht (hiu sut phn ng l 100%). Cho ton b lng axit ny tc dng vi 100 gam dung
dch cha NaOH 4% v Na2CO3 26,5% th thu c dung dch ch cha mt mui ca axit hu c. Phn
trm khi lng ca ancol trong X l
A. 13,53%.

B. 86,47%.

C. 82,71%.

Li gii:
4 2.265
Ta c mol axit = nNa+ = 40 + 106 = 06 mol
266
nX = mol axit = 0,6 mol M X = 06 = 4433

CH 3CH 2 OH : x x + y = 0,6
x = 0,1

46 x + 44 y = 26,6 y = 0,5
CH 3CHO : y
%mAncol = 46.0,1/26,6 .100 = 17,29% Chn D

D. 17,29%.

Cu 13: Cho cc loi t sau: nilon-6, enang, visco, lapsan, olon, nilon-6,6. C bao nhiu t thuc loi t
poliamit?
A. 5.

B. 3.

C. 4.

D. 2.

Li gii:
Cc t thuc loi t poliamit l: nilon-6, enang, nilon-6,6 Chn B
Cu 14: Ha tr cao nht trong hp cht vi oxi ca nguyn t R gp 3 ln ha tr ca n trong hp cht kh vi
hiro. Phn trm khi lng ca R trong hp cht kh vi hiro nhiu hn trong hp cht c ha tr cao nht vi oxi
l 54,11%. Nguyn t R l
A. Se.

B. P.

C. Cl.

D. S.

Li gii: Loi B, C. Th trng hp S tha mn Chn D.

Cu 15: Cho s phn ng: P + NH4ClO4
H3PO4

+ Cl2

+ N2

+ H2O

Sau khi lp phng trnh ha hc, ta c tng s nguyn t b oxi ha v tng s nguyn t b kh ln lt l
A. 8 v 5.

B. 10 v 18.

C. 18 v 10.

D. 5 v 8.

Li gii:
Phn ng: 8P + 10NH4ClO4
8H3PO4

+ 5 Cl2

+ 5N2

+ 8H2O

Tng s nguyn t b oxi ha gm 8 nguyn t P v 10 nguyn t N

Tng s nguyn t b kh: 10 nguyn t Cl Chn B
Cu 16: Thy phn hon ton m gam tetrapeptit X mch h thu c hn hp Y gm 2 amino axit (no,
phn t cha 1 nhm COOH v 1 nhm NH2) l ng ng k tip. t chy hon ton hn hp Y cn va
4,5 mol khng kh (cha 20% O2 v th tch, cn li l N2) thu c CO2, H2O v 82,88 lt kh N2 (
ktc). S cng thc cu to tha mn ca X l
A. 8.

B. 4.

C. 12.

D. 6.

Li gii:
S CTCT tha mn : 24 2 = 14 Khng c p n.
Cu 17: trng thi c bn:
- Phn lp electron ngoi cng ca nguyn t nguyn t X l np2n+1.
- Tng s electron trn cc phn lp p ca nguyn t nguyn t Y l 7.
- S ht mang in trong nguyn t nguyn t Z nhiu hn s ht mang in trong nguyn t nguyn t
X l 20 ht. Nhn xt no sau y l sai?
A. Nguyn t X v Y thuc 2 chu k k tip.
B. S oxi ha cao nht ca X trong hp cht l +7.
C. Oxit v hiroxit ca Y c tnh lng tnh.
D. m in gim dn theo th t X, Y, Z.
Li gii : D thy X l Flo B sai Chn B
Cu 18: Tin hnh in phn (vi in cc tr, hiu sut l 100%) dung dch X cha 0,02 mol CuCl2; 0,02

mol CuSO4 v 0,005 mol H2SO4 trong thi gian 32 pht 10 giy vi cng dng in khng i l 2,5
ampe th thu c 200 ml dung dch Y. Gi tr pH ca dung dch Y l :
A. 1,08.

B. 1,00.

C. 0,70.

D. 1,78.

Li gii:
D thy Cu in phn cha ht. Cl- in phn ht v nc bn cc dng in phn.
Ta c: ne trao i =

25.1930
96500 = 005 mol

2H2O 4H+ + O2 + 4e
nH+ = 0,005.2 + 0,05 0,04 = 0,02 mol [H+] = 0,1 PH = 1 Chn B.
Cu 19: Cho m gam hn hp kim loi gm Al, Mg, Zn phn ng ht vi dung dch H2SO4 long, d th
thu c dung dch X cha 61,4 gam mui sunfat v 5m/67 gam kh H2. Gi tr ca m l
A. 20,10.

B. 13,40.

C. 10,72.

D. 17,42.

Li gii:
Bo ton khi lng : m + 98.5m/67 = 61,4 + 5m/67 m = 13,4 Chn B
Cu 20: Amin X khi tc dng vi dung dch HCl d thu c mui dng CnHm(NH3Cl)2. t chy 0,1 mol
X bng mt lng oxi d, ri cho hn hp sau phn ng (gm CO2, H2O, N2 v O2 d) li chm qua
nc vi trong d thy khi lng dung dch sau phn ng gim 7,8 gam so vi khi lng nc vi trong
ban u v thu c 30 gam kt ta. S cng thc cu to tha mn iu kin trn ca X l
A. 4.

B. 2.

C. 3.

D. 1.

Li gii :
Ta c : mol CO2 = 0,3 mol
mdung dch gim = mkt ta - (mCO2 + mH2O) nH2O =
03
S C = 01 = 3.

30 78 44.03
= 05mol
18

2.05
S H = 01 = 10 X: C3H10N2 C 4 ng phn amin Chn A

Cu 21: Khi cho cng mt lng hp cht hu c X tc dng vi Na d v vi NaHCO3 d th s mol kh

H2 thu c nhiu gp 2 ln s mol CO2. Cng thc no sau y l cng thc phn t ca X?
A. C8H16O4.

B. C7H16O4.

C. C8H16O5.

D. C6 H14O5.

Li gii:
Loi B v D v c bt bo ha = 0.
S chc axit = 1 S chc phn ng vi Na = 4 S chc OH = 3 S O trong X = 5 Chn D.
Cu 22: Cho 39,6 gam hn hp gm K2CO3 v KHSO3 vo 147 gam dung dch H2SO4 20%, un nng
n khi kt thc cc phn ng thu c dung dch X. Dung dch X cha cc cht tan l
A. K2SO4, KHSO3.

B. K2SO4, KHSO3, KHSO4.

C. K2SO4.

D. K2SO4 v H2SO4.

Li gii: D chng minh axit d Chn D

Cu 23: Cho cc pht biu sau:

(1) t chy hon ton este X thu c s mol CO2 bng s mol H2O th X l este no, mch h, n chc.
(2) Glucoz, mantoz, saccaroz u c c cu to dng mch h v dng mch vng.
(3) X phng v cht git ra tng hp u khng to kt ta vi nc cng.
(4) Phenol v anilin u d phn ng vi nc brom do nh hng ca gc hirocacbon n nhm chc.
S pht biu ng l
A. 2.

B. 1.

C. 4.

D. 3.

Li gii:
1: ng. 2 sai v saccaroz khng c cu to dng h (do khng c nhm OH t do). 3 sai v x
phng c to kt ta vi nc cng. 4 sai (Phenol v anilin u d phn ng vi nc brom do nh hng
ca nhm OH, v nhm NH2 ch khng phi do nh hngca gc hirocacbon n nhm chc)
Chn B.
Cu 24: Cho 3,834 gam mt kim loi M vo 360 ml dung dch HCl, lm kh hn hp sau phn ng thu
c 16,614 gam cht rn khan. Thm tip 240 ml dung dch HCl trn vo ri lm kh hn hp sau phn ng
th thu c 18,957 gam cht rn khan. Bit cc phn ng xy ra hon ton, b qua s thy phn ca cc ion
trong dung dch. Kim loi M l
A. Mg.

B. Be.

C. Al.

D. Ca.

Li gii:
D thy M + 360 ml dung dch HCl th M d. Cn M + 360 ml + 240 ml dung dch HCl th M ht.
nH+ = nCl- =
Bo ton e:

18957 3834
= 0426 mol
355

3834.n
= 0426 M = 9n (n l ha tr ca M) Chn cp n = 3 v M = 27 (Al) Chn C.
M

Cu 25: Chia m gam hn hp X gm mt ancol v mt axit thnh 3 phn bng nhau. Phn 1 tc dng ht
vi Na d thu c 0,15 mol H2. t chy hon ton phn 2 thu c 0,9 mol CO2. un phn 3 vi dung
dch H2SO4 c th thu c este Y c cng thc phn t C5H10O2 khng c kh nng tham gia phn ng
trng bc. Gi tr ca m l
A. 62,4.

B. 72,0.

C. 58,2

D. 20,8.

Li gii:
T phn 3: Y no, n, h trong X, ancol v axit u no, n, h. Tng s C trong X l 5C.
T phn 1 nX = 0,3.
T phn 2 s C = 3. Trong X ancol c 1 C v axit c 4 C (do Y khng phn ng trng gng)
Trong1/3 X: C3H7COOH: x mol x + y = 0,3
CH3OH: y mol
m = 3(88.0,2 + 32.0,1) = 62,4 gam

4x + y = 0,9

x = 0,2
y = 0,1

Cu 26: Hn hp X gm SO2 v O2 c t khi so vi H2 bng 28. Nung nng hn hp X mt thi gian (c

xc tc V2O5) thu c hn hp Y c t khi so vi X bng 16/13. Hiu sut ca phn ng tng hp SO3 l
A. 60,0%.

B. 50,0%.

C. 62,5%.

D. 75,0%.

Li gii:
Bng phng php ng cho mol SO2 : mol O2 = 3 :1 T phn ng Tnh hiu sut theo O2
Gi mol X = 1 mol. Ta c:

molY MX
=
mol Y = 13/16 = 0,8125 mol.
molX MY

mol hn hp gim = mol O2 phn ng = 1 0,8125 = 0,1875 mol

01875
H% = 025 .100 = 75% Chn D
Cu 27: Cho hn hp hai axit cacboxylic hai chc tc dng vi dung dch NaOH va thu c dung
dch cha m gam hn hp mui. Cho ton b lng mui thu c tc dng ht vi NaOH d c mt CaO
un nng thu c cht rn X v hn hp hirocacbon Y c t khi so vi H2 bng 18,5. Cho ton b cht
rn X tc dng vi dung dch H2 SO4 long, d thu c 0,4 mol CO2. Gi tr m l
A. 33,8.

B. 61,8.

C. 25,0.

D. 32,4.

Li gii:
Gi CT chung ca axit: R(COOH)2
R(COOH)2 + 2NaOH R(COONa)2 + 2H2O
R(COONa)2 + 2NaOH RH + 2Na2CO3
x

2x

2x

Ta c mol Na2CO3 = mol CO2 = 2x = 0,4 x = 0,2 mol

Bo ton khi lng: mmui = 106.0,4 + 18,5.2.0,2 40.0,4 = 33,8 gam Chn A
Cu 28: Cho cc hn hp bt, mi hn hp gm hai cht c s mol bng nhau: Ba v Al2 O3; Cu v
Fe3O4; NaCl v KHSO4; Fe(NO3)2 v AgNO3. S hn hp khi ha tan vo nc rt d ch thu c dung
dch l
A. 3.

B. 4.

C. 1.

D. 2.

Li gii:
C 2 cp m sn phm ch thu c dung dch l: Ba v Al2 O3; NaCl v KHSO4 Chn D
Cu 29: Cho cc cht sau: Cr2O3, Al, CH3COONH4, (NH4)2CO3, Na2HPO3, H2NCH2COOH, KHCO3,
Pb(OH)2. C bao nhiu cht l cht lng tnh?
A. 8.

B. 6.

C. 7.

D. 5.

Li gii:
Cc cht lng tnh: : Cr2O3, CH3COONH4, (NH4)2CO3, H2NCH2COOH, KHCO3, Pb(OH)2. Chn B
Cu 30: Cho cc pht biu sau:
(1) Vi cng thc phn t C2H2O3 c hai hp cht hu c mch h c th tham gia phn ng trng bc.

(2) Cng thc phn t C3H5Cl c 4 ng phn cu to.

(3) Vi cng thc phn t C4H10O2 c 3 ancol ng phn c th ha tan Cu(OH)2.
(4) Tinh bt v xenluloz l ng phn ca nhau.
S pht biu ng l
A. 3.

B. 2.

C. 1.

D. 4.

Li gii: Chn A (cc ng l 1, 2 v 3)

Cu 31: Trong cc cht sau: CuSO4, S, SO2, H2S, Fe2(SO4)3, SO3. C bao nhiu cht c th to ra H2SO4 bng
mt phn ng?
A. 2.

B. 5.

C. 6.

D. 4.

Li gii : Chn C (bn d dng vit cc phn ng ny)

Cu 32: t chy hon ton m gam hn hp T gm 3 ancol thu c x mol CO2 v y mol H2O. Mt khc
cho m/2 gam hn hp T tc dng vi Na d thu c z mol H2. Mi lin h gia m, x, y, z l
A. m = 12x + y + 64z.

B. m = 24x + 2y + 64z.

C. m = 12x + 2y +32z.

D. m = 12x + 2y + 64z.

Li gii:
Ta c: mol OH trong m gam T l 4z mol.
Bo ton nguyn t O mol O2
Bo ton khi lng m = 12x + 2y + 64z. Chn D.
Cu 33: Cho cc cht: ancol etylic, axit axetic, phenol, etylamin, trimetylamin, tristearin. C bao nhiu cht
c th to lin kt hiro gia cc phn t ca n?
A. 4.

B. 6.

C. 3.

D. 5.

Li gii:
Cc cht c th to lin kt hiro gia cc phn t ca n l: ancol etylic, axit axetic, phenol, etylamin
Chn A.
Cu 34: t chy hon ton m gam qung pirit st (cha 80% FeS2 v khi lng, cn li l tp cht
tr) bng mt lng oxi d. Ly ton b lng SO2 thu c cho hp th ht vo 100 ml dung dch cha
Ba(OH)2 1,5M v NaOH 1M th thu c 26,04 gam kt ta. Gi tr ln nht ca m l
A. 13,44.

B. 18,00.

Li gii:
SO2 + OH- HSO-3
0,16 0,16
SO2 + 2OH- SO320,12
m=

0,24

0,12

120.(016 + 012).100
= 21 gam chn D
2.80

C. 16,80.

D. 21,00.

Cu 35: Cho 28,8 gam hn hp X gm propinal, glucoz, fructoz tc dng vi lng d dung dch
AgNO3 trong NH3 th thu c 103,6 gam cht rn. Phn trm khi lng ca propinal trong X l:
A. 37,5%.

B. 40,0%.

C. 42,5%.

D. 85,6%.

Li gii:

CH C CHO : x + AgNO3 / NH 3 CAg C COONH 4 + 2 Ag

Gi

C 6 H 12 O6 : y
2 Ag
54 x + 180 y = 28,8
x = 0,2
54.0,2

%CH C CHO =
.100 = 37,5% / a : A

28,8
194 x + 216 x + 216 y = 103,6 y = 0,1
Cu 36: Thc hin phn ng tch 15,9 gam hn hp gm butan v pentan (c t l mol tng ng l 3 :
2) iu kin thch hp thu c hn hp X gm cc hirocacbon mch h v hiro c t khi so vi
H2 bng 15. X phn ng ti a vi bao nhiu gam brom trong CCl4?
A. 40,0 gam.

B. 44,8 gam.

C. 56,0 gam.

D. 84,8 gam.

Li gii:
15,9
n
0,25
Ta c: nbutan = 0,15 mol; npentan = 0,1 mol. X =
n X = 0,53
0,25
30
ntng

= nH2 = nBr2 = 0,53 0,25 = 0,28 mol mBr2 = 44,8 gam. Chn B

Cu 37: Cho m kg mt loi qung apatit (cha 93% khi lng Ca3(PO4)2, cn li l tp cht tr khng
cha photpho) tc dng va vi dung dch H2SO4 c sn xut supephotphat n. dinh dng
ca supephotphat thu c sau khi lm kh hn hp sau phn ng l:
A. 26,83%.

B. 42,60%.

C. 53,62%.

D. 34,20%.

Li gii:
Ca3(PO4)2 + 2H2SO4 Ca(H2PO4)2 + 2CaSO4

dinh dng ca supephotphat = %P2O5 =

142.93%
= 426% Chn B.
310

Cu 38: un nng hn hp tt c cc ancol c cng thc phn t C2 H6O, C3H8O vi dung dch H2SO4
c iu kin thch hp, thu c hn hp X ch gm ete v anken. X cha ti a bao nhiu hp cht?
A. 6.

B. 3.

C. 8.

D. 5.

Li gii:
3 ancol cho ti a:

3(3 + 1)
= 6 v 2 anken: CH2 = CH2 v CH2 = CH CH3 Chn C.
2

Cu 39: Ha tan hn hp X gm CuSO4 v Fe2(SO4)3 vo n c c dung dch Y. Cho Fe d vo dung

dch Y n khi cc phn ng kt thc thu c dung dch Z c khi lng bng khi lng dung dch Y
(b qua s th y phn ca cc ion trong dung dch v s bay hi ca nc). Phn trm khi lng ca
CuSO4 trong X l

A. 26,32%.

B. 73,68%.

C. 63,20%.

D. 5,40%.

Li gii:
Gi mol CuSO4 = x mol; mol Fe2(SO4)3 = y mol; nFetan = z
Bo ton e: 2x + 2y = 2z

(1)

64x = 56z 8x = 7z

Thay (1) vo pt: 8x = 7(x + y) x = 7y mol.

160.7y
%mCuSO4 = 160.7y + 400.y .100 = 7368 % Chn B

Cu 40: Khi thy phn pentapeptit X (Gly-Ala-Val-Ala-Gly) th thu c ti a bao nhiu sn phm cha
gc glyxyl m dung dch ca n c phn ng mu biure?
A. 9.

B. 5.

C. 4.

D. 2.

Li gii: Chn p n C
B. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II) Phn I. Theo
chng trnh Chun (10 cu: T cu 41 n cu 50)
Cu 41: t chy hon ton mt ete c to bi 2 ancol n chc X, Y (Y mch nhnh) ri cho sn
phm chy hp th ht vo nc vi trong d th thu c 20 gam kt ta v khi lng dung dch sau
phn ng gim 6,88 gam so vi khi lng nc vi trong ban u. Khi lng phn t ca X (vC) l
A. 74.

B. 46.

C. 32.

D. 58.

Li gii:
nCO2 = 0,2
n H 2O =

ete no v 2 ancol u no n chc

20 6,88 44.0,2
= 0,24
18

nete = 0,04 CTPT ete:C5H12O

2ancol l X: CH3OH v Y: CH3 CH2 CH2 CH2 OH (do Y khng phn nhnh)
MX = 32 Chn C.
Cu 42: t chy hon ton m gam hn hp X gm hai ancol hai chc thuc cng dy ng ng, thu
c 39,6 gam CO2 v 18,9 gam H2O. Nu khi cho m gam X tc dng va vi Na th thu c bao
nhiu gam cht rn?
A. 24,3 gam.

B. 24,6 gam.

C. 25,9 gam.

D. 32,9 gam.

Li gii:
nAncol = nnc nCO2 = 0,15 mol.
Bo ton nguyn t O: nO2 = 1,275 mol.
Bo ton khi lng: m = 39,6 + 18,9 32.1,275 = 17,7 gam.
mrn = mAncol + mNa mH2 = 17,7 + 23.0,3 2.0,15 = 24,3 gam Chn A

Cu 43: Cht no trong cc cht sau y m phn t lun c 9 lin kt xch ma?
A. C3H8O3.

B. C3H6.

C. C2H4O2.

D. C2 H7N.

Li gii: Chn D. C2 H7N.

Cu 44: Ha cht thng c dng khc ch ln thy tinh l
A. CaF2 v dung dch H2SO4 c.
C. NaOH nng chy.

B. dung d ch H2SO4 c.
D. Na3AlF6.

Li gii:
Ha cht thng c dng khc ch ln thy tinh l HF (CaF2 v dung dch H2SO4c.)

Chn A
Cu 45: Hn hp X gm axit oxalic, axetilen, propanial v vinyl fomat (trong s mol ca axit
oxalic v axetilen bng nhau). t chy hon ton m gam hn hp X cn dng va 1,125 mol O2,
thu c H2O v 55 gam CO2. Nu cho m gam hn hp X tc dng vi dung dch NaHCO3 d th thu
c ti a bao nhiu lt CO2 ( ktc)?
A. 2,8 lt.

B. 5,6 lt.

C. 8,6 lt.

D. 11,2 lt.

Li gii:
Do s mol ca axit oxalic v axetilen bng nhau nn ta c th gi CT chung ca X : CnH2n 2O2
Phn ng: CnH2n 2O2 +

3n 3
O2 nCO2 + (n-1)H2O
2

n H O = 0,75
3n 3 1125
=

n = 2,5 2
2n
125
n X = 0,5

Bo ton khi lng: mX = 55 + 18.0,75 32.1,125 = 32,5 gam

HOOC COOH : x
2 x + y = 0,5
x = 0,125

Quy hn hp X gm CH CH : x

90 x + 26 x + 72 y = 32,5 y = 0,25
OHC CH CHO : y
2

V = 0,125.2.22,4 = 5,6 lt Chn B

Cu 46: Trong cc cht sau: tristearin, benzyl fomat, etyl clorua, tinh bt, anbumin, cao su buna. S cht
km bn trong c mi trng axit v baz l
A. 3.

B. 2.

C. 5.

D. 4.

Li gii:
Cc cht km bn trong c mi trng axit v baz l: tristearin, benzyl fomat, anbumin Chn A

Cu 47: Nhm kim loi no sau y m iu ch chng th ch c th dng phng php in phn
nng chy?

A. Zn, Cu, Cr, Fe. B. Fe, Al, Ca, Cu.

C. Na, Al, Ca, Mg.

D. Na, Zn, Mg, Al.

Li gii: Chn p n C
Cu 48: Pht biu no sau y sai?
A. Trong y khoa, ozon c dng cha su rng.
B. Kh sunfur va c tnh oxi ha va c tnh kh.
C. Lu hunh tc dng c vi thy ngn nhit thng.
D. H2S ch th hin tnh kh khi tham gia phn ng ha hc.
Li gii:
p n A, B, C ng. D sai (ngoi tnh kh cn th hin tnh axit yu)
Cu 49: Nung m gam hn hp X gm bt st v lu hunh thu c hn hp Y gm FeS, Fe, S. Chia Y
thnh 2 phn bng nhau. Cho phn 1 tc dng vi dung dch H2SO4 long, d thy thot ra 2,8 lt hn hp
kh ( ktc). Cho phn 2 tc dng ht vi lng d dung dch HNO3 c, nng thy thot ra 16,464 lt kh ch
c NO2 ( ktc, sn phm kh duy nht). Gi tr m l
A. 14,00.

B. 17,84.

C. 8,92.

D. 7,00.

Li gii:
Trong Y: nFe = nH2 = 0,125 mol
16464
3.0125
224
= 006 mol
Bo ton e: 3nFe + 6.nS = nNO2 nS =
6

m = 2.(56.0,125 + 32.0,06) = 17,84 gam. Chn B

Cu 50: Cho s chuyn ha:
o

H 2 ( xtPd / PbCO3 )
O2
O2
C
X
CH 4 1500

X +
Y +

Z +

T +
M

Bit X, Y, Z, T, M l cc hp cht hu c. Cc cht Z, M l n lt l

A. CH3CHO v CH3COOC2H3.

B. CH3CHO v C2H3COOC2H3.

C. C2H2 v CH3 COOH.

D. C2H5OH v CH3COOC2H3.

Li gii:
o

H 2 ( xtPd / PbCO3 )
C
O2
CH 4 1500

CH CH +
CH 2 = CH 2 +

CH 3 CHO
O2
+X
+

CH 3COOH
CHCOOC 2 H 3
/ a : A