PHN 1: BI TP ANCOL-PHENOL Dng 1: Phn ng iu ch ancol, ru, ancol a chc, phenol: Cu 1: Ha tan hon ton 16 gam ancol etylic

c vo nc c 250 ml dung dch ancol, cho bit khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml. Dung dch ancol c ru l A. 5,12o. B. 6,40o. C. 12,00o. D. 8,00o. Cu 2: em ancol etylic ha tan vo nc c 250 ml dung dch ru c nng 23%, khi lng ring dung dch ru l 0,96 g/ml, khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml.Dung dch ru trn c ru l A. 27,6o. B. 22,08o. C. 24,53o. D. 23,00o. Cu 3: Ln men glucoz iu ch ancol etylic (khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml), hiu sut phn ng ln men ancol etylic l 75%. thu c 80 lt ru vang 12o th khi lng glucoz cn dng l A. 24,3 kg. B. 20,0 kg. C. 21,5 kg. D. 25,2 kg. Cu 5: Mt loi go cha 75% tinh bt. Ly 64 kg go ny i nu ancol etylic 46 o, qu trnh ny b hao ht 19%. Khi lng ring ca ancol etylic l 0,8 g/ml. Th tch ancol 46o thu c l A. 60,0 lt. B. 62,5 lt. C. 52,4 lt. D. 45 lt. Cu 6: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ancol etylic 46 o l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ancol etylic nguyn cht l 0,8 gam/ml) A. 5,4 kg. B. 5,0 kg. C. 6,0 kg. D. 4,5 kg. Cu 7:T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut 80%). Oxi ha 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ha hn hp X cn ht 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l A. 10%. B. 20%. C. 80%. D. 90%. Cu 8: Dung dch ancol X 94% (theo khi lng), t l s mol ancol : nc = 43 : 7. Vy cng thc ca X l A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH. Cu 9: Dn 50 lt dung dch etanol 46 0 (khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml) qua cc cht xc tc thch hp thu c cht hu c X vi hiu sut l 90%. un nng ton b cht X p sut cao vi xc tc Na v hiu sut to thnh cht hu c Y l h%. Cho ton b cht Y lm mt mu hon ton va ti a vi dung dch Br 2 trong CCl4 thy tn ht 0,072 mol Br2 phn ng. Vy gi tr ca h% l (bit Y c tnh n hi v ph bin) A. 00%. B. 40%. C. 60%. D. 80%. Cu 10: Hn hp X gm etilien v propilen vi t l mol tng ng l 1,5 : 1. Hidrat ha hon ton hn hp X thu c hn hp ancol Y trong t l khi lng cc ancol bc 1 so vi ancol bc 2 l 8,4 : 4,5. Vy % theo khi lng ca ancol propylic c trong hn hp Y ni trn l A. 42,05%. B. 53,73%. C. 22,12%. D. 11,63%. Cu 11: Hidrat ha 17,92 lt (ktc) hn hp X gm etilen v propilen sau mt thi gian thu c hn hp Y gm cc cht hu c. Chia hn hp Y thnh 2 phn bng nhau: * t chy hon ton phn I vi kh oxi d thu c 41,8 gam CO2 v 23,13 gam H2O. * Cho phn II phn ng hon ton vi Na d thu c 24,67 gam hn hp mui. Vy hiu sut phn ng cng nc ca etilen v hiu sut phn ng hidrat ha trung bnh ca propilen ln lt l A. 70% v 80%. B. 80% v 90%. C. 90% v 80%. D. 80% v 70%. Cu 12: Hidrat ha hon ton 8,96 lt (ktc) hn hp kh X gm etilen v mt hidrocacbon A vi cht xc tc thch hp thu c hn hp Y gm 2 cht hu c (u cha 3 nguyn t C, H, O). t chy ton b Y vi kh O 2 d th khi phn ng xong thu c 0,8 mol CO 2 v 0,9 mol H2O. Mt khc cho 15,9 gam hn hp kh X hp th hon ton qua dung dch nc brom ly d th thy c a mol Br2 phn ng. Vy gi tr ca a l A. 1,05. B. 0,60. C. 0,75. D. 1,20. Cu 13: Cho V lt etilen (ktc) phn ng hon ton vi dung dch KMnO 4 thu c dung dch X v cht rn Y. Lc ly dung dch X ri cho phn ng hon ton vi Cu(OH) 2 th khi kt thc thy c 4,9 gam Cu(OH) 2 b tan. Vy gi tr ca V l A. 1,12. B. 2,24. C. 3,36. D. 4,48. Cu 14: Cho etilen phn ng hon ton va vi V lt dung dch KMnO 4 0,2M thu c dung dch X v cht rn Y. Lc ly dung dch X ri cho phn ng hon ton vi Cu(OH)2 th khi kt thc phn ng thy c 11,76 gam Cu(OH)2 b tan. Vy gi tr ca V l A. 0,4. B. 0,8. C. 0,9. D. 1,2. Cu 15*: Cho etilen phn ng hon ton vi V lt dung dch KMnO 4 0,4M thu c dung dch X v cht rn Y. Lc ly dung dch X ri chia thnh 2 phn bng nhau.Cho phn I phn ng hon ton va vi 7,35 gam Cu(OH) 2.Cho thm dung dch H2SO4 long tht d vo phn II c dung dch Z.Cho tip 278 gam tinh th FeSO 4.7H2O vo dung dch Z, sau khi cc phn ng xy ra hon ton thu c dung dch T c tng s mol mui l 1 mol.Vy gi tr ca V l A. 1,0 hoc 1,25. B. 1,25 hoc 2,0. C. 2,25 hoc 1,0. D. 1,0 hoc 2,0. Cu 16*: Cho etilen phn ng hon ton vi V lt dung dch KMnO 4 0,25M thu c dung dch X v cht rn Y. Lc ly dung dch X ri chia thnh 2 phn bng nhau. Cho phn I phn ng hon ton va vi 29,4 gam Cu(OH) 2. Cho phn II phn ng hon ton vi 0,5 mol Cr(OH)3 thu c 27,7 gam hn hp rn Z trong c Y.

Vy gi tr ca V l bit hn hp rn Z c phn ng c vi dung dch NaOH. A. 1,6. B. 4,0. C. 4,8. D. 6,4. Cu 17: Cho cht hu c X c cng thc phn t C 6H6O2. Bit X tc dng vi KOH theo t l mol 1 : 2. Vy s ng phn cu to ca X l A. 1. B. 2. C. 3. D. 4. o Br HCl 2 /Fe Cu 18 : Cho dy chuyn ha iu ch sau: Toluen NaOH/ t ,p X Y Z. Cht Z c th l A. benzyl clorua. B. m-metylphenol. C. o-metylphenol. D. o-clotoluen. Cu 19: Mt dung dch X cha 5,4 gam cht ng ng ca phenol n chc. Cho dung dch X phn ng vi nc brom (d) thu c 17,25 gam hp cht cha ba nguyn t brom trong phn t, gi s phn ng xy ra hon ton. Cng thc phn t cht ng ng ca phenol l A. C7H7OH. B. C8H9OH. C. C9H11OH. D. C10H13OH. Cu 20: Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c khng qu 35,2 gam. Bit rng 1 mol X ch tc dng c va ti a vi 2 mol NaOH. Cng thc cu to thu gn ca X l A. HOCH2C6H3(COOH)2. B. (HO)2C6H3COOH. C. HOC6H3(COOH)2. D. C2H5C6H3(OH)2. Dng 2: Phn ng tch nc ca ancol: Cu 1: Tch nc hon ton 1 ankanol X thu c 1 cht hu c Y c dY/X = 14/23. Vy cng thc ca X l A. CH4O. B. C2H6O. C. C3H8O. D. C4H10O. Cu 2: Tch nc hon ton 1 ankanol X thu c 1 cht hu c Y c dY/X = 1,4375. Vy cng thc ca X l A. CH4O. B. C2H6O. C. C3H8O. D. C4H10O. Cu 3: Tch nc hon ton 1 ankanol X thu c hn hp G gm 2 cht hu c E v F (khng tnh ng phn hnh hc) trong nE = 3nF v dG/X = 28/37. Vy tn ca X l A. ancol iso butylic. B. ancol etylic. C. ancol sec butylic. D. 2,3-imetylbutan-2-ol. Cu 4: Tch nc hon ton 1 ankanol X thu c hn hp G gm 2 cht hu c E v F (khng tnh ng phn hnh hc) trong nE = 3nF v dG/X = 79/92. Vy tn ca X l A. ancol iso butylic. B. ancol etylic. C. ancol sec butylic D. 2,3-imetylbutan-2-ol. Cu 5: Tch nc hon ton 1 ankanol X thu c hn hp G gm 2 cht hu c E v F trong M E = MF v khng tnh ng phn hnh hc. Bit dG/X = 35/44. Vy tn ca X khng th l A. 2-metylbutan-2-ol. B. pentan-2-ol. C. 3-metylbutan-2-ol. D. ancol isoamylic. Cu 6: Tch nc hon ton 1 ancol X thu c hn hp G gm 2 cht hu c E v F (khng tnh ng phn hnh hc) trong nE = 3nF v dG/X = 1,45. Bit X l sn phm chnh t qu trnh hidrat ha anken tng ng. Tn X l A. ancol isopropylic. B. ancol secbutylic. C. ancol tertbutylic. D. ancol propylic. Cu 7: Tch nc hon ton 1 ankanol X thu c hn hp G gm 2 cht hu c E v F trong ME +60=MF.F l A. propilen. B. ipropyl ete. C. ietyl ete. D. etilen. Cu 8: Tch nc 1 ankanol X thu c hn hp G gm 2 cht hu c c s mol bng nhau v dG/X=0,85. X l A. CH4O. B. C2H6O. C. C3H8O. D. C4H10O. Cu 9: Tch nc 1 ankanol X thu c hn hp G gm 2 cht hu c c phn t khi hn km nhau 28 vc. X l A. CH4O. B. C2H6O. C. C3H8O. D. C4H10O. Cu 10: Tch nc 1 ankanol X thu c hn hp G gm 3 cht hu c c s mol bng nhau v dG/X=74/69. X l A. CH4O. B. C2H6O. C. C3H8O. D. C4H10O. Cu 11: Tch nc hon ton 1 ancol n chc mch h Y thu c cht hu c Z c 0,67 <dZ/X< 0,69. Vy Y l A. C2H6O. B. C3H8O. C. C3H6O. D. C3H4O. Cu 12: Tch nc 2a mol 1 ankanol X thu c 3a mol hn hp G gm cht hu c Y, H2O v X. Hiu sut l A. 20%. B. 25%. C. 40% D. 50%. Cu 13: Tch nc a mol 1 ankanol X thu c a mol hn hp G gm cht hu c Y, H2O v X. Nhit ph hp A. 1400C. B. 1700C. C. 1800C. D. 2000C. o Cu 14: un 5,75 gam etanol vi H 2SO4 dung dch 170 C. Dn cc sn phm kh va hi ln lt i qua cc bnh cha ring r: CuSO4 khan; NaOH m c; dung dch brm (d) trong CCl 4. Sau th nghim khi lng bnh cui cng tng thm 2,1 gam. Hiu sut chung ca qu trnh ehirat ha etanol l A. 59%. B. 55%. C. 60%. D. 70%. Cu 15: em kh nc 15,48 gam hn hp 2 ancol no n chc k tip nhau trong dy ng ng bng H 2SO4 c, 170oC, thu c hn hp hai olefin v 5,4 gam nc. Cng thc 2 ancol l A. CH3OH v C2H5OH. B. C3H7OH v C4H9OH. C. C2H5OH v C3H7OH. D.C4H9OHv C5H11OH. Cu 16: un nng mt hn hp gm hai ancol no n chc vi H 2SO4 c, 140oC thu c 21,6 gam nc v 72 gam hn hp ba ete. Cho bit 3 ete c s mol bng nhau, gi s cc phn ng hon ton. Cng thc hai ancol la A. CH3OH v C3H7OH. B. CH3OH v C2H5OH. C. CH3OH v C4H9OH. D.C5H11OHvCH3OH. Cu 17: Cho 2 ancol A, B vi MB = 2MA 4. Tch nc hn hp 2 ancol ny, ngoi cc ete ch thu c 1 anken. Xc nh cng thc cu to ca A, B

A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C2H5OH v C4H9OH. D.CH3OHv C3H7OH. Cu 18: Tch nc hon ton 27,2 gam hn hp 2 ankanol thu c 18,2 gam hn hp 2 anken lin tip. Vy cng thc ca 2 ankanol l A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH C. C3H7OH v C4H9OH. D.C4H9OHvC5H11OH. Cu 19: Tch nc hon ton hn hp X gm 2 ankanol thu c hn hp G gm 2 anken c phn t khi khc nhau v t l s mol ca chng l 2 : 3. Bit dG/He = 11,2. Vy trong X chc chn khng cha ankanol no sau y A. ancol etylic. B. ancol propylic. C. ancol butylic. D. ancol pentylic. Cu 20: Chia hn hp gm 2 ancol n chc X v Y (phn t khi ca X nh hn Y) l ng ng k tip thnh 2 phn bng nhau *t chy hon ton phn I thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O. 0 *un nng phn II vi H2SO4 c 140 C to thnh 1,25 gam hn hp 3 ete. Ha hi hon ton hn hp 3 ete trn, thu c th tch hi bng th tch ca 0,42 gam N2 (trong cng iu kin nhit , p sut). Hiu sut phn ng to ete ca X v Y ln lt l A. 30% v 30%. B. 25% v 35%. C. 40% v 20%. D. 20% v 40%. Cu 21: un nng mt ancol n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca X l A. C3H8O. B. C2H6O. C. CH4O. D. C4H8O. Cu 22: un nng hn hp gm hai ancol n chc, mch h, k tip nhau trong dy ng ng vi H 2SO4 c, 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete v 1,8 gam nc. Cng thc phn t ca hai ru trn l A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH. C. C3H5OH, C4H7OH. D. C3H7OH, C4H9OH. Cu 23: ehirat ha 1 ancol bc hai M thu c olefin. Cho 3 gam M tc dng vi Na d thu c 0,56 lt H 2 (ktc). un nng M vi H2SO4 c 140oC th sn phm to thnh l A. propen. B. i isopropyl ete. C. but-2-en. D. i secbutyl ete. Cu 24: iu ch etilen ngi ta un nng ancol etylic 45 o vi dung dch axit sunfuric c nhit 170 oC, hiu sut phn ng t 60%, khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml. Th tch ancol 45 o cn a vo phn ng thu c 6,048 lt etilen (ktc) l A. 20,7 ml. B. 34,5 ml. C. 57,5 ml. D. 46,0 ml. Cu 25: Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y l: A. CH3CH2CH(OH)CH3. B. CH3CH2CH2OH. C. CH3CH2CH2CH2OH. D. CH3CH(OH)CH3. Cu 26: t chy hon ton mt lng hn hp X gm 3 ancol cng thuc dy ng ng thu c 6,72 lt kh CO 2 (ktc) v 9,90 gam H2O. Nu un nng cng lng hn hp X nh trn vi H 2SO4 c nhit thch hp chuyn ht thnh ete th tng khi lng ete thu c l A. 6,45 gam. B. 4,20 gam. C. 7,40 gam. D. 5,46 gam. Cu 27: t chy hon ton m gam hn hp X gm ba ancol (n chc, thuc cng dy ng ng), thu c 8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H 2SO4 c th tng khi lng ete ti a thu c l A. 7,85 gam. B. 7,40 gam. C. 6,50 gam. D. 5,60 gam. Cu 28: X phng ha hon ton 66,6 gam hn hp hai este HCOOC 2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H 2SO4 c 1400C, sau khi cc phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 18,00. B. 8,10. C. 16,20. D. 4,05. Cu 29: un nng hon ton 27,6 gam hn hp X gm 2 ankanol lin tip (trong c khi lng bng nhau v s mol ca chng hn km nhau 0,07 mol) vi H2SO4 c 1400C th khi lng ete to thnh l A. 22,83. B. 21,57. C. 24,09. D. 22,20. Cu 30: Tch nc hn hp gm 0,3 mol metanol v 0,2 mol etanol thu c hn hp X gm hi nc, mt ancol v m gam ete. Vy gi tr ca m khng th l A. 12,0. B. 9,2. C. 14,8. D. 13,8. Cu 31: Tch nc 1 mol hn hp M gm ancol X v etanol (c d X/He = 10,1) thu c hi nc, 2 ancol cn d v m gam hn hp ete. t chy ton b 2 ancol cn d vi O 2 va thu c hn hp CO2 v H2O (trong s mol ca chng hn km nhau 0,4 mol). Bit t l phn trm phn ng ca ancol X v etanol tng ng l 3 : 10. Vy gi tr ca m l A. 14,32. B. 15,40. C. 20,80. D. 33,92. Cu 32:Cho 0,4 mol hn hp X gm 2 ru no, n chc, bc 1, l ng ng k tip un nng vi H2SO4 c 140OC thu c 7,704 gam hn hp 3 ete. Tham gia phn ng ete ho c 50% lng ru c khi lng phn t nh v 40% lng ru c khi lng phn t ln. Tn gi ca 2 ru trong X l

A. metanol v etanol. B. etanol v propan-1-ol. C. propan-1-ol v butan-1-ol. D. pentan-1-ol v butan-1-ol. Dng 3: Ancol phn ng vi kim loi kim Na, K: Cu 1: Cho 0,2 mol 1 ancol Z (no, mch cacbon h v khng phn nhnh) phn ng vi Na d thu c kh H2 thot ra c th tch ti a l 6,72 lt (ktc). Bit Z ch c duy nht 1 ng phn cu to ancol. Vy % khi lng cacbon trong phn t Z ln nht l A. 52,17%. B. 39,13%. C. 37,50%. D. 60,00%. Cu 2: Cho 15,6 gam hn hp hai ancol n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l: A. C3H5OH v C4H7OH. B. C3H7OH v C4H9OH. C. C2H5OH v C3H7OH D. CH3OH v C2H5OH. Cu 3: Cho 1 ancol mch h Z (trong c s nguyn t oxi bng s nguyn t cacbon) phn ng hon ton vi 2,3 gam Na thu c 4,97 gam cht rn v 1,008 lt H2 (ktc). Vy Z l A. C2H6O2. B. C3H8O3. C. C4H10O4. D. C5H10O5. Cu 4: Cho 10 ml dung dch ancol etylic 46o phn ng ht vi kim loi Na (d), thu c V lt kh H 2 (ktc). Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml. Gi tr ca V l: A. 4,256. B. 2,128. C. 3,360. D. 0,896. Cu 5:Cho 100 gam dung dch metanol 64% phn ng hon ton vi K d thu c V lt H2 (ktc).Vy gi tr V l A. 11,2. B. 22,4. C. 44,8. D. 67,2. Cu 6: Cho a mol 1 ancol mch h Z phn ng va vi 1,84 gam Na thu c 2a mol kh H2 v 4,48 gam mui. Vy tng s nguyn t Hidro c trong 1 phn t Z l A. 10. B. 12. C. 14. D. 16. Cu 7: Cho 13,816 gam hn hp X gm 2 ankanol (trong c t l s mol ca 2 ancol l 1:1,5) phn ng va vi K thu c H2 v 22,716 gam mui. Vy hn hp X lun cha ancol no sau y A. C5H11OH. B. C2H5OH. C. C3H7OH. D. C4H9OH. Cu 8: C mt hn hp X nng a gam gm m mol ankanol A v n mol ankanol B ( vi n, m ln lt l s nguyn t cacbon ca A v B). Trn X vi ietylete (C2H5-O-C2H5) ri lm ha hi thu c hn hp hi Y c dY/He= 18,5. Mt khc, cho a gam X phn ng hon ton vi Na d thu c ti a bao nhiu lt H2 (ktc)? A. 89,6 lt. B. 100,8 lt. C. 224,0. D. 268,8 lt. Cu 9: Cho m gam hn hp X gm etanol, etilenglicol v glixerol (trong % khi lng oxi trong hn hp l 48%) phn ng va vi Na thu c kh H2 v (m+132) gam mui. Vy gi tr ca m l A. 132. B. 180. C. 84. D. 200. Cu 10:Cho hn hp X (c dX/He=20) gm etilenglicol, propan-1,2-iol v hidroquinon (benzen-1,4-iol) phn ng va vi Na thu c kh H2 v khi lng mui gp k ln khi lng hn hp X phn ng. Vy gi tr ca k l A. 1,2625. B. 1,2750. C. 1,550. D. 1,8250. Cu 11: Cho 40,7 gam hn hp A gm 3 ancol c cng thc phn t ln lt l C2H6O2, C3H8O2 v C8H10O2 phn ng va vi Na, phn ng xong thu c 11,2 lt H2 (ktc). Vy t khi ca hn hp A so vi Heli l A. 20,53. B. 23,05. C. 20,35. D. 25,03. Cu 12: Cho 42 gam hn hp A gm metanol, etilenglicol v glixerol phn ng va vi K thu c 93,3 gam hn hp mui v V lt H2 (ktc). Vy gi tr ca V l A. 8,40. B. 11,76. C. 18,48. D. 15,12. Cu 13: Cho m gam hn hp A gm etanol, etilenglicol v glixerol phn ng va vi hn hp B gm Na v K (c s mol bng nhau) thu c (m + 27) gam hn hp mui. Nu cho lng hn hp B ni trn tan ht vo trong dung dch HCl d th s mol HCl phn ng l A. 0,225 mol. B. 0,450 mol. C. 0,900 mol. D. 1,350 mol. Cu 14: Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HOC6H4COOCH3. B. CH3C6H3(OH)2. C. HOCH2C6H4OH. D. HOC6H4COOH. PHN 2:CHUYN ANHIT Dng 1:Bi tp l thuyt

Bi 1: C bao nhiu ng phn anehit c cng thc phn t C5H10O ? a. 3 b. 4 c.5 d.6 Bi 2: Khi t cht hon ton anehit no, n chc, mch h bng oxi th t l sn phm chy thu c l: a. =1 b. >1 c. =1/2 d. n H 2O : nCO2 <1

Bi 3:Cng thc no sau y l cng thc ca anhit no n chc a. CnH2nO b. RCHO c. CnH2n+1CHO d. c 3 p n Bi 4:Anhit th hin tnh kh khi tc dng vi cht no sau y a. H2 b. NaOH c. Ag2O d. HCl Bi 5:anhit axetic c to thnh trc tip t a. etilen b. axetilen c. ru etylic d.a,b,c u ng Bi 6:Hp cht cacbonyl C4H8O c bao nhiu ng phn a. 1 b2 c.3 d.4
Bi 7: Chiu gim dn nhit si (t tri qua phi) ca cc cht: CH3CHO , C2H5OH , H2O l a. H2O , C2H5OH , CH3CHO b. H2O , CH3CHO , C2H5OH c. CH3CHO , H2O , C2H5OH d. CH3CHO , C2H5OH , H2O Bi 8: Nh dung dch andehit fomic vo ng nghim cha kt ta Cu(OH)2, un nng nh s thy kt ta gch. Phng trnh ho hc no sau y biu din ng hin tng xy ra? a. b. c.

d. Bi 9: Chn nhm t thch hp in vo ch (...) sau Dung dch cha khong 40% ......... trong nc c gi l fomon hay fomalin a. th tch anehit axetic b. khi lng anehit axetic c. khi lng anehit fomic d. th tch anehit fomic Bi 10: iu ch anehit t ancol bng 1 phn ng, ngi ta dung a. ancol bc 1 b. ancol bc 2 c. ancol bc 3 d. p n khc Bi 11: Cho s phn ng: X, Y, Z, T l cc hp cht hu c, cng thc ca T l: a. CH2O2. b. CH3CHO. c. CH3OH. d. HCHO. Bi 12: Hp cht hu c X khi un nh vi dung dch AgNO3 / NH3 (dng d) thu c sn phm Y, Y tc dng vi dung dch HCl hoc dung dch NaOH u cho 2 kh v c A, B, X l a. HCHO b. HCOOH c. HCOONH4 d. C A, B, C u ng
Dng 2:Bi tp t chy Bi 1:Mt anht no n chc A c 28,57% oxi v khi lng.Tn ca A l A.Etanal B.Metanal C.Propanal D.p n khc Bi 2:Mt anehit hai chc A c 55,2% oxi v khi lng .Cng thc phn t ca A l A.C2H2O2 B.C3H6O2 C.C4H6O2 D.C3H4O2 Bi 3:t chy hon ton 3,42 gam mt anehit no mch thng A thu c 4,032 lt CO2 ktc v 2,7 gam H2O cng thc cu to ca A l A.CH3CHO B.CH3-CH=CHO C.HOC-(CH2)2CHO D.HOC-(CH2)4CHO Bi 4:t chy hon ton 0,36 gam mt anehit, Sn phm chy c hp th hon ton vo bnh I ng P2O5 v bnh II ng KOH.Sau th nghim thy khi lng bnh I tng 0,36 gam v bnh II ng 0,88gam.Mt khc khi ha hi cng mt lng anhit v C5H12 th c hai u c th tch bng nhau .Xc nh cng thc phn t ca anehit. A.C2H2O B.C3H6O C.C4H8O D.p n khc Bi 5 :t chy hon ton 11,4 gam mt anehit no a chc mch thng thu c 0,6 mol CO2 v 0,5 mol H2O.Xc nh cng thc cu to ca anhit A.HOC-CHO B. HOC-CH2-CHO C.HOC-(CH2)2CHO D.HOC-(CH2)4CHO Bi 6:t chy hon ton 5,28 gam mt anehit no n chc A th cn va 6,72 lt O2 ktc Xc nh cng thc phn t ca anddehiit A.C2H2O B.C3H6O C.C4H8O D.C2H4O

Bi 7:Chia m gam hn hp 2 ru no n chc lm 2 phn bng nhau -Phn 1 : t chy hon ton thu c 2,24 lt CO2 ktc -Phn 2:Oxi ha hon ton bng CuO th thu c 2 anehit.t chy hon ton hai anehit ny th thu c bao nhiu gam H2O A.0,36 gam B.0,54 gam C.0,9 gam D.1,8 gam Bi 8: t chy mt hn hp cc ng ng ca anehit ta thu c s mol CO2 = s mol H2O

th

l dy ng ng: A. Anehit n chc no B. Anehit vng no C. Anehit hai chc no D. C A, B, C u ng Bi 9: T khi hi ca mt anehit X i vi hiro bng 28. Cng thc cu to ca anehit l: A. CH3CHO B. CH2=CH-CHO C. HCHO D. C2H5CHO
Dng 3:Bi tp anhit tc dng vi H2 Bi 1:Th tch H2 ( 00C v 2 atm ) cn dung tc dng vi 5,6 gam anhit acrylic l A.4,48 lt B.2,24 lt C.0,448 lt D.0,336 lt Bi 2:Cho 7 gam cht A c cng thc phn t l C4H6O tc dng hon ton vi H2 c xc tc thu c ancol isobutylic a.Tn ca A l A.2-metyl propenal B.But -2-en-1-al C.butanal C. But-2-en-1-ol b.Hiu sut ca phn ng l A.40% B.80% C.60% D.90% Bi 3: Chia hn hp X gm 2 anehit no n chc l ng ng lin tip lm 2 phn bng nhau -Phn 1: en t chy hon ton thu c 5,4 gam H2O - Phn 2 :em hidro ha hon ton ri em t chy th th tch CO2 ktc thu c l bao nhiu A.0,112 lt B.0,224 lt C.0,336 lt D.6,72 lt Bi 4:t chy hon ton hn hp hai anehit no n chc c 0,4 mol CO2 .Khi hidro ha hon ton anehit ny cn 0,2 mol H2 thu c hn hp 2 ru no n chc .t chy hon ton 2 ru ny th s mol nc thu c l A.0,4 mol B.0,6 mol C.0,8 mol D.1 mol Bi 5: Cho 0,1 mol anehit X tc dng hon ton vi H2 thy cn 6,72 lt ktc v thu c sn phm Y.Cho ton b lng Y trn tc dng vi Na th thu c 2,24 lt H2 ktc.Mt khc khi ha hi 8,4 gam X thu c th tch l 2,24 lt ktc.Xc nh cng thc cu to ca X v Y A.CH3CHO v C2H5OH B.CH2=CH-CHO v C3H7OH C.HOC-(CH2)2-CHO v HO-CH2-(CH2)2-CH2-OH D.Kt qu khc Bi 6:Cho mt hp cht hu c X c cha C,H,O.Khi t chy hon ton 0,1 mol X th to thnh 6,72 lt CO2 ktc.Mt khc hidro ha 0,05 mol X cn dng ng 1,12 lt H2 00C v 2 atm .Sau phn ng thu c ru no n chc Z .Cng thc cu to ca X,Z l A.CH3CHO v C2H5OH B.C2H5CHO v C3H7CHO C.C3H5OH v C3H7OH D.C2H3CHO v C3H7OH Bi 7: Trn hn hp gm 3,92 lt hi anehit axetic iu kin tiu chun vi H2 d qua ng Ni nung nng.Hn hp cc cht thu c sau phn ng c ngng t hi nc ri cho tc dng hon ton vi Na d thu c 1,84 lt kh (270C v 1 atm).Hiu sut ca phn ng l A.85,71% B.82,44% C.84,22% D.75,04% Bi 8:Kh hon ton mt anehit n chc mch h A bng H2 th cn V lt H2.Sn phm thu c sau phn ng cho tc dng hon ton vi Na d th thu c V/4 lt kh H2.Cc th tch kh u o cng iu kin.A l A.CH3CHO B.HCHO C.Anhit khng no n chc cha 1 lin kt i trong phn t D.Anhit khng no n chc cha 1 lin kt ba trong phn t Bi 9: Kh hon ton m gam hn hp 2 anehit mch h cn 5,6 lt H2 ktc.Sn phm thu c cho tc dng ht vi Na thu c 1,68 lt H2 ktc.Hai anhit l A.Hai anehit no dn chc B.Hai Anhit khng no n chc cha 1 lin kt i trong phn t C.Mt anehit no n chc v mt anehit khng no n chc D.Hai anehit c cng s nguyn t ccbon Bi 10:Hn hp A gm 2 anehit no X v Y.Cho 0,3 mol hn hp A tc dng vi 1 gam H2.t chy hon ton 0,3 mol hn hp A th thu c 22 gam CO2.Xc nh cng thc ca X v Y A.HCHO v HOC-CHO B.HCHO v CH3CHO C.HCHO v CH2=CH-CHO D.CH3CHO v C2H5CHO

Bi 11:un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon

ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. khng no (cha mt ni i C=C), hai chc. B. no, hai chc. C. no, n chc. D. khng no (cha mt ni i C=C), n chc.
Dng 4:Bi tp trng bc

Bi 1: Cho 0,87 gam mt anehit no n chc phn ng hon ton vi Ag2O trong dung dch NH3 thu c 3,24 gam bc kim loi. Cng thc cu to ca anehit l A. C2H5CHO. B. CH3CHO. C. HCHO. D. C3H7CHO. Bi 2*: Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l A. CH3CHO. B. OHC-CHO. C. CH2=CH-CHO. D. HCHO. Bi 3: T khi hi ca mt anehit X i vi hiro bng 28. Cng thc cu to ca anehit l: A. CH3CHO B. CH2=CH-CHO C. HCHO D. C2H5CHO Bi 4: Cht X cha cc nguyn t C, H, O trong oxi chim 53,33% v khi lng. Khi t chy X u thu c s mol nc bng s mol X; bit 1 mol X phn ng va ht vi 2mol Ag2O trong dung dch amoniac. X l: A. CH3CHO B. C2H5CHO C. H-CHO D. OHC-CH=CH-CHO Bi 5: Ru n chc A c % khi lng oxi l 50. Cht A c iu ch t anehit X. Vy X l: A.CH3CHO B. HCHO C. CH2 = CH CHO D. Cht khc Bi 6: Cho hn hp gm 0,1 mol HCOOH v 0,2 mol HCHO tc dng ht vi dung dch AgNO3/NH3 d th khi lng Ag thu c l a. 108 gam b. 10,8 gam c. 216 gam d. 64,8 gam Bi 7: Cho 1,97 gam fomon tc dng vi dung dch AgNO3/NH3 d, sau phn ng thu c 10,8 gam Ag. Nng % ca anehit fomic l gi tr no di y (coi nng ca axit fomic trong fononl khng ng k) a. . 38,071% b. 76,142% c. 61,929% d. 23,858% Bi 8: Mt hn hp X gm 2 anehit A, B n chc. Cho 0,25 mol hn hp X tc dng vi dung dch AgNO3/NH3 d to ra 86,4 gam kt ta. BitMA<MB . A ng vi cng thc phn t no di y? a. CH3CHO b. HCHO c. C2H5CHO d. C2H3CHO Bi 9: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3,un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l (cho Na = 23, Ag = 108) A. HCHO. B. CH3CH(OH)CHO. C. OHC-CHO. D. CH3CHO. Bi 10: Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l (cho H = 1, C = 12, O = 16) A. CH3CHO. B. HCHO. C. CH2 = CHCHO. D. CH3CH2CHO Bi 11: Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l A. HCHO. B. C2H3CHO. C .C2H5CHO. D. CH3CHO. Bi 12::Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3)trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng

dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. HCHO. C. C4H9CHO. D. C2H5CHO.
PHN 3 :Chuyn bi tp axit cacboxylic Dng 1: Bi tp v phn ng trung ho: Phng php: - Vi axit a chc: t CTTQ R(COOH)x R(COOH)x + xNaOH R(COONa)x + xH2O a ax a ax 2R(COOH)x + xBa(OH)2 R2(COO)2xBax + 2xH2O a ax/2 a/2 ax - Vi axit n chc ( x=1): t CTTQ RCOOH RCOOH + NaOH RCOONa + H2O 2RCOOH + Ba(OH)2 (RCOO)2Ba + 2H2O Nu bi ton cho mt hay mt hn hp cc axit cacboxylic thuc cng mt dy ng ng tc dng vi NaOH theo t l mol 1:1 hoc tc dng vi dung dch Ba(OH)2 theo t l mol 2:1 th l cc axit n chc. nNaOH = ( mmui maxit)/ 22 x = nNaOH/ naxit nBa(OH)2 = (mmui maxit)/ 133 x= 2. nBa(OH)2/naxit Lu : + Nu l axit no, n chc, mch h ta c th t CTTQ l CnH2n+1COOH ( n0) hoc CmH2mO2 (m 1) + Axit fomic c phn ng trng bc do c nhm chc anehit trong phn t. + Khi lng cht rn sau phn ng: mRn = mmui + mNaOH(Ba(OH)2) V d 1: Hn hp Z gm hai axit cacboxylic n chc X v Y (MX > MY) c tng khi lng l 8,2 gam. Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt khc, nu cho Z tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn trm khi lng ca X trong Z l A. C3H5COOH v 54,88%. B. C2H3COOH v 43,90%. C. C2H5COOH v 56,10%. D. HCOOH v 45,12%. V d 2: Trn 20 gam dung dch axit n chc X 23% vi 50 gam dung dch axit n chc Y 20,64% thu c dung dch D. trung ho D cn 200 ml dung dch NaOH 1,1M. Bit rng D tham gia phn ng trng gng. Cng thc ca X v Y tng ng l A. HCOOH v C2H3COOH. B. C3H7COOH v HCOOH. C. C3H5COOH v HCOOH. D. HCOOH v C3H5COOH. Dng 2: Bi tp v phn ng t chy: - Vi axit cacboxylic ni chung: t CTTQ CnH2n+2-2k-2xO2x 3n + 1 k 3 x CnH2n+2-2k-2xO2x + O2 n CO2 + (n+1-k-x) H2O - Vi axit cacboxylic no, n chc, mch h: t 2 CTTQ CnH2nO2 CnH2nO2 + O2 n CO2 + n H2O 3n nCO2 = nH2O 2 Nu bi ton cho t chy hon ton mt hn hp cc axit cacboxylic thuc cng dy ng ng thu c nCO2 = nH2O th l axit no, n chc. vd1: t chy hon ton 0,1 mol hn hp 2 axit cacboxylic l ng ng k tip thu c 3,36 lt CO2 (ktc) v 2,7 gam H2O. Cng thc phn t ca chng l A. C2H4O2 v C3H6O2. B. C3H6O2 v C4H8O2. C. CH2O2 v C2H4O2. D. C3H4O2 v C4H6O2. VD2: t chy hon ton 0,1 mol hn hp 2 axit cacboxylic l ng ng k tip thu c 3,36 lt CO2 (ktc) v 2,7 gam H2O. S mol ca mi axit ln lt l A. 0,05 v 0,05. B. 0,045 v 0,055. C. 0,04 v 0,06. D. 0,06 v 0,04 V d 3: Hn hp X gm axit Y n chc v axit Z a chc ( Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn 1 tc dng vi Na, sinh ra 4,48lt kh H2 (ktc). t chy hon ton phn 2, sinh ra 26,4g CO2. Cng thc cu to thu gn v phn trm khi lng ca Z trong hn hp X l: A. HOOC-CH2-COOH; 70,87% B. HOOC-CH2-COOH; 54,88% C. HOOC-COOH; 60% D. HOOC-COOH; 42,86% Dng 3: Bi tp v phn ng este ho: H 2 SO4 RCOOH + ROH RCOOR + H2O Cu 1: Hn hp X gm axit fomic v axit axetic (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam ancol

etylic (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l A. 10,125. B. 6,48. C. 8,10. D. 16,20. Cu 2: Tnh khi lng este metyl metacrylat thu c khi un nng 215 gam axit metacrylic vi 100 gam ancol metylic. Gi thit phn ng este ho t hiu sut 60%. A. 125 gam B. 175 gam C. 150 gam D. 200 gam Cu 3: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH ( c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l: A. 6,0 gam B. 4,4 gam C. 8,8 gam D. 5,2 Cu 4: Cho bit hng s cn bng ca phn ng este ho: CH3COOH + C2H5OH CH3COOC2H5 + H2O K = 4 Nu cho hn hp cng s mol axit v ancol tc dng vi nhau th khi phn ng t n trng thi cn bng th % ancol v axit b este ho l A. 50%. B. 66,7%. C. 33,3%. D. 65%. Cu 5: Cho cn bng sau: CH3COOH + C2H5OH CH3COOC2H5 + H2O K = 4 Khi cho 1 mol axit tc dng vi 1,6 mol ancol, khi h t n trng thi cn bng th hiu sut ca phn ng l A. 66,67%. B. 33,33%. C. 80%. D. 50%. Cu 6: un nng hn hp X gm 1 mol ancol etylic v 1 mol axit axetic (c 0,1 mol H2SO4 c lm xc tc), khi phn ng t n trng thi cn bng c hn hp Y trong c 0,667 mol etyl axetat. Hng s cn bng KC ca phn ng l A. KC = 2. B. KC = 3. C. KC = 4. D. KC = 5. Cu 7: un 12 gam axit axetic vi 1 lung d ancol etylic ( c H2SO4 c lm xc tc). n khi phn ng dng li thu c 11 gam este. Hiu sut ca phn ng este ho l bao nhiu? A. 70% B. 75% C. 62,5% D. 50% Cu 8:Khi un nng 25,8 gam hn hp ancol etylic v axit axetic c H2SO4 c lm xc tc thu c 14,08 gam este. Nu t chy hon ton lng hn hp thu c 23,4 ml H2O. Tm thnh phn trm mi cht trong hn hp u v hiu sut ca phn ng este ho.A. 53,5% C2H5OH; 46,5% CH3COOH v hiu sut 80% B. 55,3% C2H5OH; 44,7% CH3COOH v hiu sut 80% C. 60,0% C2H5OH; 40,0% CH3COOH v hiu sut 75% D. 45,0% C2H5OH; 55,0% CH3COOH v hiu sut 60% Cu 9: un 12 gam axit axetic vi 13,8 gam etanol ( c H 2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l: A. 55% B. 50% C. 62,5% D. 75% Cu 10: Bit rng phn ng este ho CH3COOH + C2H5OH CH3COOC2H5 + H2O C hng s cn bng K = 4, tnh % Ancol etylic b este ho nu bt u vi [C2H5OH] = 1 M, [CH3COOH] = 2 M. A. 80% B. 68% C. 75% D.

84,5%
BI TP TNG HP Cu: 1 Hn hp X gm 2 axit hu c n chc, ng ng k tip. Ly m gam X em tc dng ht vi 12g Na th thu c 14,27g cht rn v 0,336 lt H2 (ktc). Cng m gam X tc dng va vi 600ml nc Br2 0,05M. Cng thc phn t ca hai axit l: A. C3H2O2 v C4H4O2. B. C3H4O2 v C4H6O2. C. C4H6O2 v C5H8O2 D. C3H6O2 v C4H8O2. Cu: 2. Trn u ancol etylic, axit axetic vo nc c 4g dung dch X. em ton b dung dch X tc dng va vi Na c m gam cht rn v 2,24 lt kh H2 (ktc). Gi tr ca m l: A. 3,54 B. 10,8 C. 8,4 D. 4,14 Cu 3: t chy hon ton 0,15 mol mt axit cacboxylic n chc, cn va V lt O2 (ktc), thu c 0,45 mol CO2 v 0,2 mol H2O. Gi tr ca V l: A. 8,96 B. 11,2 C. 6,72 D.13,44 Cu 4: Cht no sau y c tnh axit mnh nht? A. CH2Cl- CH2-COOH B. CH3-CHCl-COOH C. CH3-CH2-COOH D. CH2Br-CH2-COOH Cu 5: Hn hp X gm 2 axit hu c no, n chc. Trung ho ht 6,7g X bng dung dch NaOH ri c cn dung dch thu c 8,9g mui khan. Cn khi cho 6,7g X tc dng vi lng d dung dch AgNO3/NH3 th thu c 10,8g Ag. Cng thc ca 2 axit l: A. HCOOH v CH3COOH B. HCOOH v C3H7COOH C. HCOOH v C2H5COOH D. HCOOCH3 v CH3COOH Cu 6: Cho 17,6 gam Cht X cng thc C 4H8O2 tc dng hon ton vi 100 ml dung dch cha NaOH 1,5M v KOH 1,0M. Sau phn ng c cn thu 20 gam cht rn. Cng thc X l A. HCOO-C3H7 B. C2H5COOCH3 C. CH3COO-C2H5 D. C3H7COOH Cu 7: t chy hon ton 2,01 gam hn hp gm axit acrylic, vinyl axetat, metyl metacrylat. Ton b sn phm chy cho qua bnh 1 ng H2SO4 c thy khi lng bnh 1 tng m gam, bnh 2 ng Ca(OH)2 d thu c 9 gam kt ta. m c gi tr l: A. 3,54 B. 10,8 C. 1,17 D. 4,14

Cu 8: Cho 3,92 gam mt este n chc X tc dng va vi 100ml KOH 0,4M thu c 6,16 gam mui Y. Axit ha Y thu c cht Z. Z c cng thc phn t l: A. C5H6O2 B. C5H8O3 C. C6H12O2 D. C6H12O3 Cu 9: Hn hp Z gm hai axit cacboxylic n chc X v Y (M X > MY) c tng khi lng l 8,2 gam. Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt khc, nu cho Z tc dng vi mt lng d dung dch AgNO 3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn trm khi lng ca X trong Z l A. C3H5COOH v 54,88%. B. C2H3COOH v 43,90%. C. C2H5COOH v 56,10%. D. HCOOH v 45,12%. Cu 10: Hn hp X gm 2 axit cacboxylic no, n chc A,B. Cho 26,8 gam X ho tan hon ton vo nc ri chia lm 2 phn bng nhau: - Phn 1: Phn ng ht vi dung dch AgNO3 trong NH3 ly d, thu c 21,6 gam Ag kim loi. - Phn 2: Cn ng 100 ml dung dch KOH 2M trung ho. Tm 2 axit. A. C3H2O2 v C4H4O2. B. CH2O2 v C4H8O2. C. C4H6O2 v C5H8O2 D. C3H6O2 v C4H8O2. Cu 11: Hn hp A gm 1 axit v 2 andehit, c 3 u no, n chc. Ly m gam A tc dng ht vi dung dch AgNO3/NH3 c 54g Ag. Dng 2m gam A tc dng vi lng d dung dch Na2CO3 thu c 0,616 lt CO2. Mt khc phi dng 10,472 lt oxi mi t chy ht m gam A. Lng axit sau trng bc c th trung ho c 150 ml dung dch KOH 0,5M. Hy cho bit CTPT, CTCT ca cc cht trong A. Bit cc V kh o 27,30C v p sut 1 atm. H = 100%. S: Cu 12: A l mt hn hp cc cht hu c gm mt parafin, mt ru n chc v mt axit hu c n chC.t chy hon m gam hn hp A bng mt lng khng kh va (khng kh gm 20% Oxi v 80% Nit theo th tch.. Cho cc cht sau phn ng chy hp th vo bnh ng dung dch Ba(OH)2 lng d. C 125,44 lt mt kh tr thot ra (ktc).v khi lng bnh ng dung dch Ba(OH)2 tng thm 73,6 gam. Tr s ca m l: A. 37,76 gam B. Khng d kin tnh C. 25,2 gam D. 28,8 gam

Cu 13: Mt hh X gm 2 axit cacboxylic no A , B c s nguyn t C hn km nhau 1 .Nu trung ha 14,64g X bng 1 lng NaOH va th thu c 20,36g hh Y gm 2 mui .Nu lm bay hi 14,4g X th chim th tch l 8,9l ( o 2730C , 1atm ) Trong 2 axit A , B phi c: a . Hai axit u n chc b. Hai axit u a chc c.Mt axit n chc,1 axit a chc d. Cha khng nh c
Cu 14: Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO3 d th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l A. 0,8. B. 0,3. C. 0,6. D. 0,2. Cu 15 : Cho 13,8 gam glixerol phn ng vi axit hu c n chc B, ch thu c cht hu c E c khi lng bng 1,18 ln khi lng ca glixerol ban u; hiu sut phn ng l 73,35%. C bao nhiu cng thc cu to ph hp vi E? A. 3 B. 5 C. 2 D. 4 Cu 16: Cho 4 mol axit axetic tc dng vi hn hp cha 0,5 mol glixerol v 1 mol etilenglicol (xc tc H 2SO4). Tnh khi lng sn phm thu c ngoi nc bit rng c 50% axit v 80% mi ancol phn ng. A. 312 g B. 156,7 g C. 170,4 g D. 176,5 g Cu 17: t chy hon ton x gam cht hu c Z (cha C, H, O) thu c a gam CO2 v b gam nc. Bit rng 3a = 11b v 11x = 3a +11b v t khi ca Z so vi khng kh nh hn 3. Vy CTPT ca Z l A. C3H4O2 B. C3H8O C. C3H6O2 D. C2H4O2 Cu 18: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. HCOOH v HCOOCH3 B. HCOOH v HCOO C2H5 C. C2H5COOH v C2H5COOCH3 D. CH3COOH v

CH3COOC2H5
Cu 19: Hn hp M gm 2 axit cacboxylic u no, mch h A, B (B hn A mt nhm chc). Ha hi hon ton m gam M thu c th tch hi bng th tch ca 7 gam nit o cng iu kin nhit , p sut. Nu cho m gam M tc dng vi Na d thu c 4,48 lt H 2 (ktc). Khi t chy hon ton m gam M thu c 28,6g CO2. Cng thc phn t ca A v B l: A. C2H4O2 v C3H4O4. B. CH2O2 v C3H4O4 . C. C2H4O2 v C4H6O4 D. CH2O2 v C4H6O2. Cu 20: Hn hp X gm HCOOH, CH3COOH (t l mol 1:1), hn hp Y gm CH 3OH, C2H5OH (t l mol 2:3). Ly 16,96 gam hn hp X tc dng vi 8,08 gam hn hp Y (c xc tc H 2SO4 c) thu c m gam este (hiu sut cc phn ng este ha u bng 80%). Gi tr ca m l: A. 12,064 gam B. 22,736 gam C. 17,728 gam D. 20,4352 gam Cu 21: oxi ho a gam ancol metylic bi CuO nung nng thu c hn hp kh v hi X. Chia X thnh 3 phn bng nhau: Phn 1: Cho tc dng vi dung dch AgNO3/NH3 d thu c 64,8 gam Ag Phn 2: Cho tc dng vi dung dch NaHCO3 d sau phn ng thu c 2,24 lt kh CO2 ktc

Phn 3: Cho tc dng vi Na d thu c 4,48 lt kh H2 ktc. Hiu sut phn ng oxi ho CH3OH l: A. 50% B. 25% C. 75% D. 66,67% Cu 22: t chy hon ton m gam hn hp gm andehit fomic; axit axetic; Glucoz (C6H12O6); axit lactic (C3H6O3). Sn phm chy thu c hp th hon ton vo dung dch Ca(OH)2 d thu c 40g kt ta. Gi tr ca m l: A. 14,1 B. 12 c. 12,4 D. Khng xc nh Cu 23: Cho 16,4 gam hn hp X gm 2 axit cacboxylic l ng ng k tip nhau phn ng hon ton vi 200 ml dung dch NaOH 1M v KOH 1M, thu c dung dch Y. C cn dung dch Y, thu c 31,1 gam hn hp cht rn khan. Cng thc ca 2 axit trong X l: A. C2H4O2 v C3H4O2 B. C2H4O2 v C3H6O2 C. C3H4O2 v C4H6O2 D. C3H6O2 v C4H8O2. Cu 24: Hn hp gm hai andehit n chc A v B c chia thnh 2 phn bng nhau: Phn 1 un nng vi dung dch AgNO3/NH3 th to ra 10,8 gam Ag Phn 2 oxi ho to thnh hai axit tng ng sau cho 2 axit ny phn ng vi 250 ml dung dch NaOH 0,26M c dung dch A. trung ho lng NaOH d trong dung dch A cn dng ng 100 ml dung dch HCl 0,25M. c cn dung dch A, em t chy cht rn c cn to c 3,52 gam CO2 v 0,9 gam H2O. CTPT ca 2 andehit A v B l: A. HCHO v C2H5CHO B. HCHO v C2H3CHO C. HCHO v CH3CHO D. CH3CHO v C2H5CHO Cu 25: Hn hp X gm axit hu c Y no, n chc v axit hu c Z hai chc (Y nhiu hn Z mt nguyn t cacbon). Chia X thnh 2 phn bng nhau. Cho phn 1 tc dng ht vi Na, sinh ra 0,25 mol H2. t chy hon ton phn 2, sinh ra 0,7 mol CO2. CTCT thu gn v % khi lng ca Z trong hn hp X l A. HOOC-COOH v 70,87% B. HOOC-CH2-COOH v 29,13% C. HOOC-COOH v 55,42% D. HOOC-CH2-COOH v 70,87% Cu 26: Hn hp X c C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m gam hn hp X thu c 3,06 gam H2O v 3,136 lt CO2 (ktc). Mt khc 13,2 gam hn hp X thc hin phn ng trng bc thy c p gam Ag kt ta. Gi tr ca p l A. 9,72. B. 8,64. C. 10,8. D. 2,16. Cu 27: Cho m gam hn hp hai axit cacboxylic X,Y k tip nhau trong dy ng ng tc dng vi lng d ancol propylic (trong H2SO4 c nng) thu c 14,25 gam hn hp hai este n chc. Cng cho m gam hn hp hai axt trn tc dng vi Na d to ra 0,075 mol H2. Gi s hiu sut phn ng l 100% v MY > MX. Cng thc cu to X, Y ln lt l A. CH3COOH, C2H5COOH B. HCOOH, CH3COOH C. CH2 = CHCOOH, CH2= CHCH2COOH D. CH3CH2COOH, CH3CH2CH2 COOH Cu 28: Hn hp gm 0,1 mol acrolein, 0,15 mol axit acrylic v 0,32 mol H 2. Nung nng hn hp c Ni lm xc tc. Sau th nghim thu c hn hp hi c khi lng mol trung bnh bng 56,8. Hiu sut H2 tham gia phn ng l: A. 84,38% B. 85% C. 95,32% D. 80% Cu 29: Cho a gam hn hp X gm 2 acid cacboxylic tc dng vi NaHCO3 d thu c V lt CO2. Mt khc, t chy hon ton a gam hn hp X thu c V lt CO2. Th tch CO2 o cng iu kin. Vy 2 acid trong hn hp X l: A. CH2=CH-COOH v HCOOH B. HCOOH v HOOC-COOH C. HCOOH v CH2(COOH)2 D. CH2(COOH)2 v CH2=CH-COOH Cu 30: t chy hon ton 2,76 gam hn hp X gm C xHyCOOH; CxHyCOOCH3 v CH3OH thu c 2,688 lt CO2 ( ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam hn hp X phn ng va vi 30 ml dung dch NaOH 1M, thu c 0,96 gam CH 3OH. Cng thc ca CxHyCOOH l A. C2H3COOH. B. CH3COOH. C. C3H5COOH. D. C2H5COOH.