B GIO DC V O TO

CHNH THC

( thi c 05 trang)

THI TUYN SINH CAO NG NM 2007

Mn thi: HO HC, Khi A
Thi gian lm bi: 90 pht.
M thi 231

H, tn th sinh:..........................................................................
S bo danh:............................................................................

PHN CHUNG CHO TT C TH SINH (44 cu, t cu 1 n cu 44):

Cu 1: Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch H2SO4 20% thu c dung dch
mui trung ho c nng 27,21%. Kim loi M l (Cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56; Cu = 64;
Zn = 65)
A. Cu.
B. Zn.
C. Fe.
D. Mg.
Cu 2: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong
khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh
( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l (Cho H = 1; C = 12; O = 16)
A. 70,0 lt.
B. 78,4 lt.
C. 84,0 lt.
D. 56,0 lt.
Cu 3: SO2 lun th hin tnh kh trong cc phn ng vi
A. H2S, O2, nc Br2.
B. dung dch NaOH, O2, dung dch KMnO4.
C. dung dch KOH, CaO, nc Br2.
D. O2, nc Br2, dung dch KMnO4.
3+
Cu 4: kh ion Fe trong dung dch thnh ion Fe2+ c th dng mt lng d
A. kim loi Mg.
B. kim loi Cu.
C. kim loi Ba.
D. kim loi Ag.
Cu 5: Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng
dung dch c pH > 7 l
B. Na2CO3, NH4Cl, KCl.
A. Na2CO3, C6H5ONa, CH3COONa.
C. KCl, C6H5ONa, CH3COONa.
D. NH4Cl, CH3COONa, NaHSO4.
Cu 6: Khi cho 100ml dung dch KOH 1M vo 100ml dung dch HCl thu c dung dch c cha 6,525
gam cht tan. Nng mol (hoc mol/l) ca HCl trong dung dch dng l (Cho H = 1; O = 16; Cl = 35,5;
K = 39)
A. 0,75M.
B. 1M.
C. 0,25M.
D. 0,5M.
Cu 7: Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau: Fe v Pb; Fe v Zn; Fe v Sn;
Fe v Ni. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim loi trong Fe b ph hu
trc l
A. 4.
B. 1.
C. 2.
D. 3.
Cu 8: Th t mt s cp oxi ho - kh trong dy in ho nh sau:
Fe2+/Fe; Cu2+/Cu; Fe3+/Fe2+.
Cp cht khng phn ng vi nhau l
A. Fe v dung dch CuCl2.
B. Fe v dung dch FeCl3.
C. dung dch FeCl2 v dung dch CuCl2.
D. Cu v dung dch FeCl3.
Cu 9: Phn ng ho hc xy ra trong trng hp no di y khng thuc loi phn ng nhit
nhm?
A. Al tc dng vi Fe3O4 nung nng.
B. Al tc dng vi CuO nung nng.
C. Al tc dng vi Fe2O3 nung nng.
D. Al tc dng vi axit H2SO4 c, nng.
Cu 10: Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit
va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng
ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X
phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan.
Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; N = 14; O =16; Na = 23)
A. CH2=CHCOONH4.
B. H2NCOO-CH2CH3.
D. H2NC2H4COOH.
C. H2NCH2COO-CH3.
Cu 11: Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc
dng c vi nhau l
A. 4.
B. 3.
C. 2.
D. 1.
Trang 1/5 - M thi 231

Cu 12: Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l

B. CH3CHO v CH3CH2OH.
A. CH3CH2OH v CH2=CH2.
C. CH3CH2OH v CH3CHO.
D. CH3CH(OH)COOH v CH3CHO.
Cu 13: Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al2O3, MgO, Fe3O4, CuO
thu c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi
s cc phn ng xy ra hon ton. Phn khng tan Z gm
A. MgO, Fe, Cu.
B. Mg, Fe, Cu.
C. MgO, Fe3O4, Cu.
D. Mg, Al, Fe, Cu.
Cu 14: t chy hon ton mt ru (ancol) X thu c CO2 v H2O c t l s mol tng ng l 3 : 4.
Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng
thc phn t ca X l
A. C3H8O3.
B. C3H4O.
C. C3H8O2.
D. C3H8O.
Cu 15: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam
mui ca axit hu c. Cng thc cu to thu gn ca X l (Cho H = 1; C = 12; O = 16; Ca = 40)
A. CH2=CH-COOH. B. CH3COOH.
C. HCC-COOH.
D. CH3-CH2-COOH.
Cu 16: Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in ca cc
nguyn t tng dn theo th t
A. M < X < Y < R.
B. R < M < X < Y.
C. Y < M < X < R.
D. M < X < R < Y.
Cu 17: Trong cng nghip, natri hiroxit c sn xut bng phng php
A. in phn dung dch NaCl, khng c mng ngn in cc.
B. in phn dung dch NaNO3, khng c mng ngn in cc.
C. in phn dung dch NaCl, c mng ngn in cc.
D. in phn NaCl nng chy.
Cu 18: Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X v 3,36 lt H2
( ktc). Th tch dung dch axit H2SO4 2M cn dng trung ho dung dch X l
A. 150ml.
B. 75ml.
C. 60ml.
D. 30ml.
Cu 19: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm
4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH
va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn
ca X l (Cho H = 1; C = 12; O =16; Na = 23)
A. etyl propionat.
B. metyl propionat.
C. isopropyl axetat.
D. etyl axetat.
Cu 20: Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO3 (hoc
Ag2O) trong dung dch NH3 thu c 2,16 gam bc kt ta. Nng mol (hoc mol/l) ca dung dch
glucoz dng l (Cho H = 1; C = 12; O = 16; Ag = 108)
A. 0,20M.
B. 0,10M.
C. 0,01M.
D. 0,02M.
Cu 21: Thm m gam kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung
dch X. Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c
lng kt ta Y ln nht th gi tr ca m l (Cho H = 1; O = 16; Na = 23; Al = 27; S = 32; K = 39;
Ba = 137)
A. 1,59.
B. 1,17.
C. 1,71.
D. 1,95.
Cu 22: Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp
A. C2H5COO-CH=CH2.
B. CH2=CH-COO-C2H5.
C. CH3COO-CH=CH2.
D. CH2=CH-COO-CH3.
Cu 23: kh ion Cu2+ trong dung dch CuSO4 c th dng kim loi
A. Fe.
B. Na.
C. K.
D. Ba.
63
65
Cu 24: Trong t nhin, nguyn t ng c hai ng v l 29 Cu v 29 Cu. Nguyn t khi trung bnh

ca ng l 63,54. Thnh phn phn trm tng s nguyn t ca ng v 63

29 Cu l
A. 27%.
B. 50%.
C. 54%.
D. 73%.
Cu 25: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung
nng, thu c kh Y. Dn Y vo lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 12
gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy
hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng (Cho H = 1;
C = 12; O = 16; Br = 80; Ag = 108)
A. 11,2.
B. 13,44.
C. 5,60.
D. 8,96.
Trang 2/5 - M thi 231

Cu 26: C th dng NaOH ( th rn) lm kh cc cht kh

A. NH3, SO2, CO, Cl2.
B. N2, NO2, CO2, CH4, H2.
C. NH3, O2, N2, CH4, H2.
D. N2, Cl2, O2 , CO2, H2.
Cu 27: Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung
dch H2SO4 long, thu c 1,344 lt hiro ( ktc) v dung dch cha m gam mui. Gi tr ca m l
(Cho H = 1; O = 16; Mg = 24; S = 32; Fe = 56; Zn = 65)
A. 9,52.
B. 10,27.
C. 8,98.
D. 7,25.
Cu 28: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu
c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3 thu
c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l
A. HCOOCH=CH2.
B. CH3COOCH=CH2.
C. HCOOCH3.
D. CH3COOCH=CH-CH3.
Cu 29: S hp cht n chc, ng phn cu to ca nhau c cng cng thc phn t C4H8O2, u
tc dng c vi dung dch NaOH l
A. 5.
B. 3.
C. 6.
D. 4.
Cu 30: Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x
phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp
vi X? (Cho H = 1; C = 12; O =16)
A. 2.
B. 5.
C. 3.
D. 4.
Cu 31: Mt dung dch cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl v y mol SO42. Tng khi lng cc mui tan
c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l (Cho O = 16; S = 32; Cl = 35,5; K = 39; Cu = 64)
A. 0,03 v 0,02.
B. 0,05 v 0,01.
C. 0,01 v 0,03.
D. 0,02 v 0,05.
Cu 32: Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng
c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol
X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu
gn ca X l
A. C6H5CH(OH)2.
B. HOC6H4CH2OH.
C. CH3C6H3(OH)2.
D. CH3OC6H4OH.
Cu 33: Cho kim loi M tc dng vi Cl2 c mui X; cho kim loi M tc dng vi dung dch HCl
c mui Y. Nu cho kim loi M tc dng vi dung dch mui X ta cng c mui Y. Kim loi M
c th l
A. Mg.
B. Zn.
C. Al.
D. Fe.
Cu 34: Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong dung dch
NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l (Cho H = 1; C = 12; O = 16;
Ag = 108)
A. HCHO.
B. CH2=CH-CHO.
C. OHC-CHO.
D. CH3CHO.
Cu 35: Cho phng trnh ho hc ca phn ng tng hp amoniac
t 0, x t

N2 (k) + 3H2 (k)

2NH3 (k)
Khi tng nng ca hiro ln 2 ln, tc phn ng thun
A. tng ln 8 ln.
B. gim i 2 ln.
C. tng ln 6 ln.
D. tng ln 2 ln.
Cu 36: Cho s phn ng: NaCl (X) NaHCO3 (Y) NaNO3. X v Y c th l
A. NaOH v NaClO.
B. Na2CO3 v NaClO.
C. NaClO3 v Na2CO3.
D. NaOH v Na2CO3.
Cu 37: trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml
dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14)
A. C3H5N.
B. C2H7N.
C. CH5N.
D. C3H7N.
Cu 38: Cc kh c th cng tn ti trong mt hn hp l
A. NH3 v HCl.
B. H2S v Cl2.
C. Cl2 v O2.
D. HI v O3.
Cu 39: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi
clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca
nhau. Tn ca X l (Cho H = 1; C = 12; Cl = 35,5)
A. 2-metylpropan.
B. 2,3-imetylbutan. C. butan.
D. 3-metylpentan.
Cu 40: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc)
thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau
hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng
Trang 3/5 - M thi 231

 ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (Cho: H = 1; C = 12; O = 16; th

tch dung dch thay i khng ng k)
A. C2H5OH v C3H7OH.
B. C3H7OH v C4H9OH.
C. C2H5OH v C4H9OH.
D. C4H9OH v C5H11OH.
Cu 41: un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti
trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l (Cho H = 1; C = 12; O = 16)
A. 55%.
B. 50%.
C. 62,5%.
D. 75%.
Cu 42: Ho tan hon ton hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20%,
thu c dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76%. Nng phn trm ca
MgCl2 trong dung dch Y l (Cho H = 1; Mg = 24; Cl = 35,5; Fe = 56)
A. 24,24%.
B. 11,79%.
C. 28,21%.
D. 15,76%.
Cu 43: C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m
phn t ca chng c phn trm khi lng cacbon bng 68,18%? (Cho H = 1; C = 12; O = 16)
A. 2.
B. 3.
C. 4.
D. 5.
Cu 44: Ch dng Cu(OH)2 c th phn bit c tt c cc dung dch ring bit sau:
A. glucoz, mantoz, glixerin (glixerol), anehit axetic.
B. lng trng trng, glucoz, fructoz, glixerin (glixerol).
C. saccaroz, glixerin (glixerol), anehit axetic, ru (ancol) etylic.
D. glucoz, lng trng trng, glixerin (glixerol), ru (ancol) etylic.
PHN T CHN: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II).
Phn I. Theo chng trnh KHNG phn ban (6 cu, t cu 45 n cu 50):
Cu 45: Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); HOCH2-CH2-CH2OH (Y);
HOCH2-CHOH-CH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc
dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l
A. X, Y, R, T.
B. X, Z, T.
C. Z, R, T.
D. X, Y, Z, T.
Cu 46: Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn
ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v
phn trm th tch ca kh CO2 trong hn hp kh sau phn ng l (Cho H = 1; C = 12; O = 16; Fe = 56)
A. FeO; 75%.
B. Fe2O3; 75%.
C. Fe2O3; 65%.
D. Fe3O4; 75%.
Cu 47: Khi thc hin phn ng tch nc i vi ru (ancol) X, ch thu c mt anken duy nht.
Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu
cng thc cu to ph hp vi X? (Cho H = 1; C = 12; O = 16)
A. 5.
B. 4.
C. 3.
D. 2.
Cu 48: Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c, nng n khi cc phn ng
xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l
A. MgSO4 v FeSO4.
B. MgSO4.
C. MgSO4 v Fe2(SO4)3.
D. MgSO4, Fe2(SO4)3 v FeSO4.
Cu 49: Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp
A. CH2=C(CH3)COOCH3.
B. CH2 =CHCOOCH3.
C. C6H5CH=CH2.
D. CH3COOCH=CH2.
Cu 50: Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang, nhng
loi t no thuc loi t nhn to?
A. T tm v t enang.
B. T visco v t nilon-6,6.
C. T nilon-6,6 v t capron.
D. T visco v t axetat.
Phn II. Theo chng trnh phn ban (6 cu, t cu 51 n cu 56):
Cu 51: Cho cc ion kim loi: Zn2+, Sn2+, Ni2+, Fe2+, Pb2+. Th t tnh oxi ho gim dn l
A. Pb2+ > Sn2+ > Fe2+ > Ni2+ > Zn2+.
B. Sn2+ > Ni2+ > Zn2+ > Pb2+ > Fe2+.
2+
2+
2+
2+
2+
C. Zn > Sn > Ni > Fe > Pb .
D. Pb2+ > Sn2+ > Ni2+ > Fe2+ > Zn2+.
Cu 52: Trong cng nghip, axeton c iu ch t
A. xiclopropan.
B. propan-1-ol.
C. propan-2-ol.
D. cumen.
Trang 4/5 - M thi 231

Cu 53: Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch NaOH c
(d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn
ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn
hp X l (Cho: hiu sut ca cc phn ng l 100%; O = 16; Al = 27; Cr = 52; Fe = 56)
A. 50,67%.
B. 20,33%.
C. 66,67%.
D. 36,71%.
Cu 54: trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH
0,1M. Ch s axit ca mu cht bo trn l (Cho H = 1; O = 16; K = 39)
A. 4,8.
B. 7,2.
C. 6,0.
D. 5,5.
Cu 55: Cc hp cht trong dy cht no di y u c tnh lng tnh?
A. Cr(OH)3, Fe(OH)2, Mg(OH)2.
B. Cr(OH)3, Zn(OH)2, Pb(OH)2.
C. Cr(OH)3, Zn(OH)2, Mg(OH)2.
D. Cr(OH)3, Pb(OH)2, Mg(OH)2.
Cu 56: T l s ngi cht v bnh phi do ht thuc l gp hng chc ln s ngi khng ht thuc
l. Cht gy nghin v gy ung th c trong thuc l l
A. aspirin.
B. moocphin.
C. nicotin.
D. cafein.
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