THI TH I HC CAO NG S 01- 2010-2011

Cu 1:

Khi cho n-propylbenzen tc dng vi brom theo t l mol 1 : 1 (nh sng, nhit ) th thu c sn

phm chnh l:
A. 1-brom-1-phenylpropan
B. 2-brom-1-phenylpropan
C. 1-brom-3-phenylpropan
D. 1-brom-4-(n-propyl)benzen
Cu 2:
Nguyn t R thuc phn nhm chnh, R to c ion R2+, trong ion c 34 ht cc loi (p, e, n). Cu
hnh electron ca ion R2+ l:
A. 1s22s22p63s2
B. 1s22s22p6
C. 1s22s22p63s23p4
D. 1s22s22p63s23p6
Cu 3:
Cho cc cht sau: metan (1); etilen (2); axetilen (3); benzen (4); stiren (5); butan (6); isopren (7);
toluen (8). Cc cht lm mt mu dung dch KMnO4 l:
A. 2, 3, 4, 5, 7
B. 1, 4, 6, 7, 8
C. 2, 3, 5, 7, 8
D. 1, 3, 4, 5, 7
Cu 4:
Cho cc phn ng sau:
a). FeO + HNO3 (c, nng)
b). FeS + H2SO4 (c, nng)
c). Al2O3 + HNO3 (c, nng)
d). Cu + dung dch FeCl3
Ni,t

e). CH3CHO + H2
f). Glucoz + AgNO3 (hoc Ag2O) trong dung dch NH3
g). C2H4 + Br2
h). glixerol (glixerin) + Cu(OH)2
Dy gm cc phn ng u thuc loi phn ng oxi ho - kh l:
A. a, b, d, e, f, h
B. a, b, d, e, f, g
C. a, b, c, d, e, h
D. a, b, c, d, e, g
Cu 5:
Cho dung dch cha a mol Al2(SO4)3 tc dng vi dung dch cha b mol Ba(OH)2. thu c lng
kt ta nh nht th cn c t l:
A. a : b = 1 : 4
B. a : b = 1 : 3
C. a : b = 1 : 2
D. a : b = 3 : 4
Cu 6:
Cht X l mt aminoaxit, phn t khng cha nhm chc no khc ngoi nhm amino v nhm
cacboxyl. 100ml dung dch 0,2M ca cht X tc dng va vi 160ml dung dch NaOH 0,25M. C cn dung dch
sau phn ng thu c 3,82g mui. Mt khc X tc dng vi HCl theo t l mol 1 : 1. Cng thc phn t ca X l:
A. C5H9NO4
B. C3H7NO2
C. C5H11NO4
D. C4H7NO4
3
Cu 7:
Trn 0,5lt dung dch axit fomic (HCOOH) 0,2M vi 0,5lt dung dch HCl 2.10 M thu c dung

4
dch A. Nu hng s phn li axit ca HCOOH l KHCOOH = 1,8.10 th gi tr pH ca dung dch A l:
A. 3,2
B. 3,6
C. 2,5
D. 2,3
Cu 8:
Cho 31,84g hn hp NaX v NaY (X, Y l hai halogen hai chu k lin tip) vo dung dch AgNO3
d th thu c mt dung dch ch cha 2 cht tan v 57,34g kt ta. Cng thc ca hai mui NaX v NaY ln lt l:
A. NaF v NaCl
B. NaCl v NaBr
C. NaBr v NaI
D. NaCl v NaI
Cu 9:
T mt loi bt g cha 60% xenluloz c dng lm nguyn liu sn xut ru etylic. Nu dng
1tn bt g trn c th iu ch c bao nhiu lt ancol 70o. Bit hiu sut ca qu trnh iu ch l 70% v khi
lng ring ca ancol nguyn cht l 0,8g/ml.
A. 450lt
B. 426lt
C. 456lt
D. 420lt
Cu 10:
Axit sunfuric l mt trong nhng axit c nhiu ng dng trong cng nghip. sn xut axit sunfuric
trong cng nghip th ngi ta s dng cch no trong nhng cch sau?
A. Cho tinh th natrisunfat tc dng vi dung dch axit nitric c, nng.
B. t chy qung pyrit, oxi ho kh thu c (vi xc tc V2O5) ri cho sn phm tc dng vi nc
C. t chy lu hunh, ri cho sn phm chy tc dng vi nc.
D. t chy hn hp bt st v lu hunh, ri cho sn phm tc dng vi dung dch HNO3 c, nng.
Cu 11:
Hp cht hu c A c cng thc phn t dng CxHyOz trong oxi chim 29,09% v khi lng. Bit
A tc dng vi NaOH theo t l mol 1 : 2 v tc dng vi Br2 trong dung dch theo t l 1 : 3. Tn gi ca A l:
A. ortho - ihiroxibenzen
B. meta - ihiroxibenzen
C. para - ihiroxibenzen
D. axit benzoic
Cu 12:
Sunfuryl iclorua SO2Cl2 l ho cht ph bin trong phn ng clo ho. Ti 350oC, 2atm c phn ng:
SO2Cl2 (kh)
SO2 (kh) + Cl2 (kh)
(1)
Khi tng p sut chung ca h phn ng th cn bng (1) chuyn dch theo chiu no?
A. Chiu thun
B. Chiu nghch
C. Khng chuyn dch
D. Khng xc nh
o

Cu 13:

C 4 hirocacbon l: CxHx (1); CxH2y (2); CyH2y (3); C2xH2y (4). Tng khi lng phn t ca 4
hirocacbon ny l 286vC. Cng thc phn t ca 4 hirocacbon theo th t (1); (2); (3); (4) ln lt l:
A. C2H2; C2H4; C4H8; C4H4
B. C4H4; C4H10; C5H10; C8H10
C. C4H4; C4H10; C6H10; C8H10
D. C2H2; C2H4; C4H8; C4H10
Cu 14:
Mt hn hp X gm Mg v Fe, tch c kim loi Fe ra khi hn hp th ngi ta cho hn hp X
tc dng ln lt vi cc dung dch no trong cc dung dch sau?
A. FeCl2; CuSO4
B. HCl; NaOH
C. FeCl3; FeCl2
D. Zn(NO3)2; NaOH
Cu 15:
Cho 8,3g hn hp X gm Fe v Al vo 1lt dung dch CuSO4 0,21M, sau khi phn ng xy ra hon
ton thu c 15,68g cht rn Y gm 2 kim loi. Thnh phn phn trm theo khi lng ca nhm trong hn hp X
l:
A. 32,53%
B. 53,32%
C. 50%
D. 35,3%
Cu 16:
Xt cc loi hp cht hu c mch h sau: Ru n chc, no (X); anehit n chc, no (Y); ru
n chc, khng no 1 ni i (Z); anehit n chc, khng no 1 ni i (T). ng vi cng thc tng qut CnH2nO ch
c 2 cht sau:
A. X v Y
B. Y v Z
C. Z v T
D. X v T
3+
+
3+
2+
2+
+
Cu 17:
Cho cc ion: Al ; Na ; Fe ; Fe ; Cu ; Ag . Dy no trong cc dy sau c sp xp theo chiu tng
dn tnh oxi ho:
A. Na+; Al3+; Fe2+; Fe3+; Cu2+; Ag+
B. Na+; Al3+; Fe2+; Cu2+; Fe3+; Ag+
3+
+
2+
2+
3+
+
C. Al ; Na ; Fe ; Cu ; Fe ; Ag
D. Al3+; Na+; Fe2+; Fe3+; Cu2+; Ag+
Cu 18:
Thu phn m gam tinh bt, sn phm thu c em ln men sn xut ancol etylic, ton b kh CO2
sinh ra cho qua dung dch Ca(OH)2 d, thu c 750g kt ta. Nu hiu sut qu trnh sn xut ancol etylic l 80% th
gi tr ca m l:
A. 486g
B. 607,5g
C. 759,4g
D. 949,2g
Cu 19:
Ho tan hon ton m gam hn hp X gm Na; K v Al (trong Na v K c t l mol l 1 : 1) vo
mt lng nc d thu c dung dch Y; 2,7g cht rn Z v 8,96lt kh T ktc. Gi tr ca m l:
A. 17g
B. 11,6g
C. 14,3g
D. 16,1g
Cu 20:
Nu khi t chy hon ton 1mol cht X ch thu c CO2 v H2O, vi tng s mol ca CO2 v H2O
l 9 th cng thc phn t ca cht X l:
A. C4H10
B. C2H5OH
C. C5H12
D. CH3 - COOH
Cu 21:
Nguyn t X c ho tr cao nht i vi oxi gp ba ln ho tr trong hp cht kh vi hiro. Gi Y l
cng thc hp cht oxit cao nht, Z l cng thc hp cht kh vi hiro. T khi ca Y i vi Z l 2,353. X l
nguyn t no sau y?
A. Lu hunh
B. Nit
C. Clo
D. Flo
Cu 22:
Ho tan hon ton 10,71g hn hp gm Al, Zn v Fe trong 4lt dung dch HNO3 a(M) th va thu
c dung dch A v 1,792lt hn hp kh gm N2 v N2O c t l mol 1 : 1. C cn dung dch A thu c m gam
mui khan. Gi tr ca m v a l:
A. 55,35g v 0,22M
B. 55,35 v 2,2M
C. 53,55 v 2,2M
D. 53,55 v 0,22M
Cu 23:
Khi lng este metylmetacrylat thu c l bao nhiu khi un nng 215g axit metacrylic vi 100g
ancol metylic, gi tht hiu sut phn ng este ho t 60%.
A. 125g
B. 175g
C. 150g
D. 200g
Cu 24:
Cho 56ml kh CO2 hp th ht vo 100ml dung dch cha NaOH 0,02M v Ba(OH)2 0,02M. Khi
lng kt ta thu c l:
A. 0,0432g
B. 0,4925g
C. 0,2145g
D. 0,394g
Cu 25:
Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1 : 10. t chy hon ton hn hp
trn thu c hn hp kh Y. Cho Y i qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro
bng 19. Cng thc phn t ca X l:
A. C3H8
B. C3H6
C. C3H4
D. C4H8
Cu 26:
Cho mt lng FexSy vo dung dch HNO3 d thu c dung dch A v 3,36lt kh NO2 ktc. Cho
dung dch A tc dng vi dung dch BaCl2 thy c kt ta trng; cn khi cho dung dch A tc dng vi dung dch NH3
d thy c kt ta mu nu . Khi cho dung dch A tc dng vi dung dch Ba(OH)2 d thy xut hin 5,73g kt ta.
Cng thc ca FexSy cho l:
A. FeS
B. FeS2
C. Fe2S3
D. Fe2S

Cu 27:

t chy hon ton mt lng cht hu c X, sau phn ng thu c 3,36lt kh CO2; 0,56lt kh N2
(cc th tch kh o ktc) v 3,15g H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N CH2 - COONa. Cng thc cu to thu gn ca X l:
A. H2N - CH2 - COOC3H7
B. H2N - CH2 - COOCH3
C. H2N - CH2 - CH2COOH
D. H2N - CH2 - COOC2H5
Cu 28:
Ho tan 200g SO3 vo m gam dung dch H2SO4 49% ta thu c dung dch H2SO4 78,4%. Gi tr ca
m l:
A. 133,3g
B. 146,9g
C. 272,2g
D. 300g
Cu 29:
in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32g Cu catt v mt
lng kh X ant. Hp th hon ton lng kh X ni trn vo 200ml dung dch NaOH ( nhit thng). Sau
phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung
dch NaOH l:
A. 0,15M
B. 0,2M
C. 0,1M
D. 0,05M
Cu 30:
t chy hon ton 16g cht X cn dng 44,8lt oxi ktc, thu c sn phm l CO2 v hi nc
theo t l s mol l 1 : 2. Nu cho sn phm chy ln lt i qua ng 1 ng P2O5 d v ng 2 ng KOH d th khi
lng cc ng tng bao nhiu gam?
A. ng 1 tng 18g; ng 2 tng 22g
B. ng 1 tng 18g; ng 2 tng 44g
C. ng 1 tng 36g; ng 2 tng 22g
D. ng 1 tng 36g; ng 2 tng 44g
Cu 31:
Cho cc dung dch c cng nng mol/lt sau: Ba(OH)2; HNO3; H2O; NaOH v H2SO4. Dy no
trong cc dy sau c sp xp theo chiu gim dn pH?
A. NaOH; Ba(OH)2; H2O; H2SO4; HNO3
B. NaOH; Ba(OH)2; H2O; HNO3; H2SO4
C. Ba(OH)2; NaOH; H2O; H2SO4; HNO3
D. Ba(OH)2; NaOH; H2O; HNO3; H2SO4
Cu 32:
Cho m gam hn hp X gm 2 ancol no, n chc k tip nhau trong cng dy ng ng tc dng vi
Na d thu c 0,448lt H2 ktc. t chy hon ton m gam X thu c 2,24lt kh CO2 ktc. Cng thc phn t
ca hai ancol l:
A. CH3OH v C2H5OH
B. C2H5OH v C3H7OH
C. C3H7OH v C4H9OH
D. C4H9OH v C5H11OH
Cu 33:
Ho tan hon ton 7,8g hn hp X gm Mg v Al vo 100g dung dch HCl 33,21%, sau phn ng thu
c 107g dung dch Y. iu khng nh no sau y v th nghim trn l khng ng?
A. Khi lng ca Mg trong hn hp X l 2,4g
B. Th tch kh hiro thu c sau phn ng ktc l 8,96lt
C. Nng phn trm ca AlCl3 trong dung dch Y l 24,95%
D. Dung dch Y ch cha 2 mui clorua
Cu 34:
Hn hp X c C2H5OH; C2H5COOH; CH3CHO (trong C2H5OH chim 50% theo s mol). t chy
m gam hn hp X thu c 3,06g nc v 3,136lt kh CO2 ktc. Mt khc 13,2g hn hp X thc hin phn ng
trng bc thy c p gam kt ta. Gi tr ca p l:
A. 8,64g
B. 6,48g
C. 9,72g
D. 10,8g
Cu 35:
Cho cc ho cht sau: KClO3; KMnO4; H2O2; H2O; KNO3 v HNO3. S cht c th dng iu ch
kh oxi trong phng th nghim l:
A. 2
B. 3
C. 4
D. 6
Cu 36:
Cho polime [ - CO - (CH2)4 - CO - NH - (CH2)6 - NH - ] l poliamit, t poliamit ny ngi ta sn xut
ra t poliamit no trong cc t di y?
A. T visco
B. T capron
C. T enang
D. T nilon
Cu 37:
Mt hirocacbon X mch h c cng thc phn t l C3Hy. Mt bnh kn c dung tch khng i cha
X v O2 d 150oC c p sut 2atm. Bt tia la in t chy X, sau li a bnh v 150oC, p sut trong bnh
vn l 2atm. Cng thc phn t ng ca X l:
A. C3H4
B. C3H6
C. C3H8
D. C3H4 hoc C3H8
Cu 38:
Hn hp X gm hai kim loi A, B (ng trc H2 trong dy hot ng ho hc v c ho tr khng
i trong cc hp cht). Chia m gam X thnh hai phn bng nhau. Phn 1 cho tc dng ht vi dung dch cha hai
axit HCl v H2SO4 (long) thu c 3,36lt kh H2 ktc. Phn 2 cho tc dng vi dung dch HNO3 long, d thu
c Vlt kh NO ktc. Gi tr ca V l:
A. 6,72lt
B. 4,48lt
C. 3,36lt
D. 2,24lt

Cu 39:

t chy mt hn hp cc ng ng ca anehit ta thu c s mol CO2 bng s mol H2O th l

cc anehit thuc dy ng ng:
A. Anehit no, n chc
B. Anehit vng no
C. Anehit hai chc, no
D. C A, B, C u ng
Cu 40:
Ho tan hon ton 17,4g mt oxit st bng dung dch HCl d th thu c 35,34375g mui clorua.
Cng thc ca oxit st dng l:
A. FeO
B. Fe3O4
C. Fe2O3
D. Fe2O3 hoc Fe3O4
Cu 41:
t chy hon ton m gam hn hp X gm 2 este l ng ng. Cho sn phm ln lt i qua bnh 1
ng P2O5 d, bnh 2 ng Ca(OH)2 d thy khi lng bnh 1 tng m1 gam, bnh 2 thy c 34,5g kt ta. Mt khc
cng t chy m gam hn hp X, ri dn sn phm chy ln lt i qua bnh 1 ng Ca(OH)2 d, bnh 2 ng P2O5
d, thy khi lng bnh 1 tng 77,9g v bnh 2 tng m2 gam. iu khng nh no di y l ng?
A. Gi tr ca m2 l 62,1g
B. Hai este thuc dy ng ng este no, hai chc
C. Gi tr ca m1 l 43,4g
D. Hai este thuc dy ng ng este no, n chc
Cu 42:
Chia 20g hn hp X gm Al; Fe; Cu thnh hai phn bng nhau. Phn 1 cho tc dng ht vi dung dch
HCl thu c 5,6lt kh ktc. Phn 2 cho tc dng vi dung dch NaOH d thu c 3,36lt kh ktc. Thnh phn
phn trm theo khi lng ca Cu trong hn hp X l:
A. 8,5%
B. 13%
C. 16%
D. 17%
Cu 43:
Hn hp X gm hai axit hu c no. t chy 0,3mol hn hp X thu c 11,2lt kh CO2 ktc. Nu
trung ho 0,3mol hn hp X th cn 500ml dung dch NaOH 1M. Cng thc cu to ca hai axit l:
A. CH3COOH v C2H5COOH
B. HCOOH v HOOC - COOH
C. CH3COOH v C3H7COOH
D. CH3COOH v HOOC - COOH
Cu 44:
Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng s electron ca anion
v tng s electron trong XY l 20. Bit rng trong mi hp cht, Y ch c mt mc oxi ho duy nht. Cng thc XY
l:
A. MgO
B. LiF
C. NaF
D. AlN
Cu 45:
t chy hon ton 5g mt axit cacboxylic X khng no, n chc, mch h c 1 lin kt i trong
phn t thu c 5,6lt CO2 ktc v 3,6g H2O. S mol ca X l bao nhiu?
A. 0,01mol
B. 0,02mol
C. 0,04mol
D. 0,05mol
Cu 46:
Cho cc cht sau: cacbon; st (II) nitrat; st (II) hiroxit; nhm hiroxit; st (II) cacbonat; natri; qung
pyrit; nhm oxit; st (III) nitrat ln lt tc dng vi dung dch axit nitric c, nng. S phn ng oxi ho kh c th
xy ra l:
A. 4
B. 5
C. 6
D. 7
Cu 47:
Cu to mch h ca phn t glucoz khc cu to mch h ca phn t fructoz l:
A. Phn t glucoz c mt nhm cacbonyl
B. Phn t glucoz c 4 nhm hiroxyl
C. Phn t glucoz c cu to mch nhnh
D. Phn t glucoz c nhm xeton
Cu 48:
Cho cc cht: anehit axetic; etylmetyl ete; axit acrylic; propenol; vinylaxetilen; etanol; axit axetic.
S cht c th lm mt mu dung dch nc brom l:
A. 3
B. 4
C. 5
D. 6
Cu 49:
Natri; kali; canxi c sn xut trong cng nghip bng phng php no sau y?
A. Phng php thu luyn
B. Phng php nhit luyn
C. Phng php nhit phn
D. Phng php in phn nng chy hp cht
Cu 50:
Phng php iu ch etanol no di y ch c dng trong phng th nghim?
A. Cho etylen tc dng vi dung dch H2SO4 long, nng
B. Thu phn dn xut halogen
C. Cho hn hp kh etylen v hi nc i qua thp cha H3PO4
D. Ln men glucoz

p n THI TH I HC CAO NG S 01
------------------- -------------------

1. A
11. B
21. A
31. D
41. D

2. B
12. B
22. A
32. B
42. D

3. C
13. B
23. C
33. D
43. B

4. B
14. D
24. D
34. A
44. C

5. A
15. A
25. D
35. B
45. D

Cu 1:
Cu 2:

p n A
p n B
R
- 2e R2+
(36 ht)
(34 ht)
R l Mg; cu hnh electron ca Mg2+: 1s22s22p6
Cu 3:
p n C
Cu 4:
p n B
Cu 5:
p n A
Al2(SO4)3 + 3Ba(OH)2 3BaSO3 + 2Al(OH)3
a
3a
2a
2Al(OH)3 + Ba(OH)2 Ba(AlO2)2 + 4H2O
2a
a
S mol Ba(OH)2 = 4a T l: a/b = a/4a = 1/4
Cu 6:
p n A
nX = 0,02mol; nNaOH = 0,04mol
X c hai nhm - COOH.
nX : nHCl = 1 : 1 X c mt nhm - NH2
H2NR(COOH)2 + 2NaOH H2NR(COONa)2 + 2H2O
0,02
0,04
0,02(mol)
3,82

R = 0,02 (16 +12.2 +32.2 + 23.2) = 41

X: H2N - C3H5 - (COOH)2 C5H9NO4
Cu 7:
p n C
nHCOOH (ban u) = 0,1mol; nHCl = 0,001mol
Sau khi trn th tch l 1lt nn ta c:
[HCOOH] = 0,1M; [HCl] = 0,001M
HCOOH
H+ + HCOO
B: 0,1M
0,001M
P.li: x
x
x
Cb: (0,1 - x)
(0,001+x)
x
KHCOOH = 1,8.10 4

x (0,001 + x)
=1,8.10 4
0,1 x

x = 3,7.10 3 [H+] = 4,7.10 3 pH = 2,3

Cu 8:
p n C
Dung dch cha hai cht tan l NaNO3 v AgNO3
d, vy X v Y khng phi l Flo.
NaX + AgNO3 AgX + NaNO3
a

a(mol)

31,84
57,34
=
X = 83,13
23 + X
108 + X

Vy X v Y l: Br v I
Cu 18:
p n l C
S mol CO2 = 7,5(mol)
C6H10O5 C6H12O6 2C2H5OH + 2CO2
m/162
0,8m/162

1,6m/162(mol)
1,6m/162 = 7,5 m = 759,4g

6. A
16. B
26. B
35. D
45. C

7. C
17. B
27. B
37. A
47. A

8. C
18. C
28. D
38. D
48. B

9. B
19. C
29. C
39. A
49. D

10. B
20. A
30. D
40. C
50. B

Cu 9:

p n B
1 tn bt g c 0,6 tn xenluloz.
C6H10O5 C6H12O6 2C2H5OH + 2CO2
3,7037.0,7

5,186 (mol)
mancol = 238,56gam
238,56

= 0,8.70 .100 = 426(lt)

Cu 10:
p n B
Cu 11:
p n B
Cng thc phn t ca A c dng: CxHyO2 (theo cc
p n).
Vancol (70

%O = 29,09%

32
.100 = 29,09 R = 78.
R + 32

Cng thc phn t ca A: C6H6O2. Vy A khng th

l axit benzoic A l ancol thm, 2 chc. Vy A l
meta - ihiroxibenzen.
Cu 12:
p n B
Cu 13:
p n B
Cu 14:
p n D
Dng Zn(NO3)2 Mg y Zn ra khi mui, hn hp
kim loi sau phn ng l Zn v Fe. Dng NaOH ho
tan Zn thu c Fe.
Cu 15:
p n A
Nhm phn ng ht do cht rn Y ch c 2 kim loi
l Cu v Fe d (hoc cha phn ng). Do Fe d nn
CuSO4 phn ng ht.
Gi s mol Al l a; s mol Fe phn ng l b ta c:
2Al
3Cu
a
3a/2(mol)
Fe
Cu
b
b(mol)
Khi lng cht rn tng = 7,38g nn ta c:
64.3a/2 - 27a + 64b - 56b = 7,38 (1)
S mol CuSO4 phn ng = s mol Cu nn ta c:
3a/2 + b = 0,21 (2)
T (1) v (2) a = 0,1; b = 0,06.
%Al =

Cu 16:
Cu 17:
Cu 26:

0,1.27
.100 = 32,53%.
8,3

p n B
p n B
p n l B
y
Fe +
- x(3 - y)e xFe3+
x
x
Sy
- y(6 + x)e yS+6
FexSy - (3x + 6y)e xFe3+ + yS+6
a
a(3x + 6y)
ay
ax(mol)

Cu 19:

p n l C
2,7g cht rn Y l Al d
2Na + 2H2O 2NaOH + H2
a
a
a/2(mol)
2K + 2H2O 2KOH + H2
a
a
a/2(mol)

2Al + 2OH
+ 2H2O 2AlO 2 + 3H2
2a 2a

3a(mol)
S mol H2 = 4a = 0,4 a = 0,1 (mol)
mhn hp X = 0,1.23 + 0,1.39 + 0,2.27 + 2,7 = 14,3g
Cu 20:
p n l A
Cu 21:
p n l A
Y: X2On Z: XHn/3. Ta c: n + n/3 = 8 n = 6.
Y: XO3;
Z: XH2
Theo bi ra ta c:

Cu 22:

X + 48
= 2,353 X = 32. (S)
X +2

p n l A
S mol N2 = s mol N2O = 0,04mol
2NO 3 + 10H+ + 8e N2O + 5H2O
0,4 0,32 0,04(mol)

2NO 3 + 12H+ + 10e N2 + 6H2O

0,48 0,4 0,04(mol)
mmui = 10,71 + 0,04.8.62 + 0,04.10.62 = 55,35g
[HNO3] =

0,88
= 0,22 M
4

Cu 23:

p n l C
naxit metacrylic = 2,5(mol); nancol metylic = 5,125(mol)
CH2=C-COOH + CH3OH CH2=C-COOCH3
CH3
CH3
2,5
3,125
(mol)
2,5.0,6
2,5.0,6 (mol)
meste = 2,5.0,6.100 = 150g
Cu 24:
p n l D
S mol OH = 0,006mol; S mol CO2 =
0,0025mol
nOH
0,006
=
= 2,4 to mui trung ho
T l:
nCO2
0,0025
Ba2+ + CO 32 BaCO3
0,002
0,0025
0,002(mol)
mkt ta = 0,002.197 = 0,394g
Cu 25:
p n l: D
Hn hp Z gm O2 d v CO2. T khi ca Z so
vi H2 l 19, nn trong Z, s mol CO2 = O2 d
10a - a(x + y/4)=ax 2x+y/4=10 x=4; y=8.
Cu 30:
p n l D
Theo bi rra ta c:
m

CO 2

+ m

H2 O

= 32.44,8/22,4 + 16 = 80(gam)

nCO 2 : nH 2 O = 1 : 2
mCO 2 = 44g; mH 2 O = 36g

N+5

+1e
N+4
0,15
0,15(mol)
3ax + 6ay = 0,15 (1)
Fe3+ + 3OH Fe(OH)3
ax
ax(mol)
2
2+
SO 4 + Ba BaSO4
by
by(mol)
mkt ta = 5,73g 107ax + 233ay = 5,73 (2)
T (1) v (2) ta c: ax = 0,01; ay = 0,02
x : y = 1 : 2 Cng thc l FeS2
Cu 27:
p n l B
X c th l este hoc axit.
Gi cng thc phn t ca X l CxHyOzNt theo bi ra ta
c:
3,36

2.3,15

2.0,56

x : y : t = 22,4 : 18 : 22,4 = 0,15 : 0,35 : 0,05

x : y : t = 3 : 7 : 1.
Khi cho X tc dng vi NaOH thu c sn phm c
mui H2N - CH2 - COONa nn trong phn t X ch c
mt nguyn t nit.
Nu X l axit (theo p n C) th khng ph hp. Vy
theo cc p n cn li th X ch c th l este. Gi
cng thc cu to ca X c dng:
H2N - CH2COOR. S nguyn t cacbon trong X l 3,
s nguyn t hiro l 7 nn R l CH3 Vy X: H2N - CH2 - COOCH3
Cu 28:
p n l D
SO3 + H2O H2SO4
2,5
2,5(mol)
mcht tan (H2SO4) ban u =

49m
= 0,49m(gam)
100

Khi lng cht tan sau khi thm SO3 l:

mcht tan sau khi thm = 0,49m + 2,5.98 = 2245 + 0,49m
mdung dch sau khi thm = m + 200 (gam)
C% (H2SO4)sau khi thm = 78,4%

245 + 0,49m
.100 = 78,4 m = 300 (gam)
m + 200

Cu 29:

p n l C
S mol Cl2 = s mol Cu = 0,32 : 64 = 0,005(mol)
Cl2 + 2NaOH
NaCl + NaClO
0,005
0,01(mol)
nNaOH (phn ng) = 0,01(mol); nNaOH (d) = 0,01(mol)
nNaOH (ban u) = 0,02(mol)
[NaOH](ban u) = 0,1M

Cu 40:

p n l C

Ta c: nHCl = 2.nH 2 O
p dng nh lut bo ton khi lng ta c:
17,4 + 36,5.nHCl = 35,34375 + 9.nHCl
nHCl = 0,6525(mol)
FexOy + 2yHCl FeCl2y/x + yH2O

Cu 31:

p n l D
Dung dch c nng H+ cng ln th c gi tr pH
cng nh.

0,6526/2y

0,6525
= 17,4
2y
x
2
= cng thc l Fe2O3
y
3

(56x + 16y).

[H+](H2SO4) > [H+](HNO3) pH(H2SO4) < pH(HNO3)

[H+](NaOH)>[H+](Ba(OH)2)pH(NaOH)<pH(Ba(OH)2)

Cu 32:

p n l B

n2ancol = 2.n = 2.0,02 = 0,04(mol)

S nguyn t cacbon trung bnh ca hai ancol l:
nC(2 ancol) = 0,1 : 0,04 = 2,5. Vy cng thc phn t
ca hai ancol l: C2H5OH v C3H7OH
Cu 33:
p n l D
H2

33,21.100

S mol HCl = 100.36,5 = 0,91(mol)

S mol H2 thu c =

7,8 7
= 0,4(mol)
2

S mol HCl phn ng = 2.nH 2 = 0,8(mol)

Vy trong dung dch sau phn ng c HCl d.
Cu 34:
p n l A
C2H5OH 2CO2 + 3H2O
C2H5COOH 3CO2 + 3H2O
CH3CHO 2CO2 + 2H2O
Theo bi ra ta c:

2a + 3b + 2c = 0,14

3a + 3b + 2c = 0,17
a b c = 0

a = 0,03; b = 0,02; c= 0,01

mX = 3,3g. Trong 3,3g X c 0,01mol CH3CHO.

Vy trong 13,2g X c 0,04mol CH3CHO. Khi cho
hn hp tham gia phn ng trng bc s thu c
0,08mol Ag mkt ta = 0,08.108 = 6,84g
Cu 35:
p n l B
Cu 36:
p n l D
Cu 37:
p n l A
Sau khi t chy, a v nhit bam u, p sut
vn nh ban u c ngha l s mol O2 v C3Hy phn
ng bng s mol CO2 v hi nc thu c
a + a(3 +y/4) = 3a + ay/2 y = 4.
Cu 38:
p n l D
S mol electron H+ nhng = 0,3(mol)
S mol electron N+5 nhng = 0,3(mol)
N+5
+3e
N+2
0,3
0,1(mol)
Th tch NO = 0,1.22,4 = 2,24lt
Cu 39:
p n l A

0,6525(mol)

Cu 41:

p n l D

mCO 2 = 34,5g mH 2 O = 77,9 - 34,5 = 43,4g

Nhn thy s mol H2O = s mol CO2, nn hai este l
hai este no, n chc.
Cu 42:
p n l D
Th tch hiro do Fe sinh ra l: 5,6 - 3,36 = 2,24lt
2Al

3H2
0,1
0,15(mol)
Fe

H2
0,1
0,1(mol)
mCu = 10 - 0,1.27 + 0,1.56 = 1,7g
%mCu = 17%
Cu 43:
p n l B
S nguyn t cacbon trung bnh = 1,5.
0,3mol X tc dng vi 0,5mol NaOH nn trong X phi
c mt axit a chc.
Vy p n ph hp l: B
HCOOH v HOOC - COOH
Cu 44:
p n l C
Cu 45:
p n l D
Gi cng thc phn t ca X l: CnH2n - 1COOH
CnH2n - 1COOH (n + 1)CO2 + nH2O
S mol CO2 = 0,25mol; s mol H2O = 0,2mol

n +1 0,25
=
n = 4.
n
0,2

Vy cng thc phn t ca X l: C4H7COOH

nX =

5
= 0,05(mol)
100

Cu 46:

p n l C

Cu 47:

p n l A

Cu 48:

p n l B

Cu 49:

p n l D

Cu 50:

p n l B
--------------

HT---------------