Bi tng hp hu c s 1

Cu 1 : Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l A. 25% B. 20% C. 50% D. 40% Cu 2 : Th tch ca dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4 kg xenluloz trinitrat (hiu sut 80%) l A. 34,29 lt B. 42,86 lt C. 53,57 lt D. 42,34 lt Cu 3 : Cht X c cng thc phn t C4H9O2N . Bit : X + NaOH Y + CH4O Y + HCl (d) Z + NaCl Cng thc cu to ca X v Z ln lt l A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH C. H2NCH2COOC2H5 v ClH3NCH2COOH D. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH Cu 4 : Pht biu no sau y sai ? A. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn. B. Nhit si ca este thp hn hn so vi ancol c cng phn t khi C. S nguyn t hiro trong phn t este n v a chc lun l mt s chn. D. Sn phm ca phn ng x phng ho cht bo l axit bo v glixerol Cu 5 : kh hon ton 200 ml dung dch KMnO4 O,2M to thnh cht rn mu nu en cn V lt kh C2H4 ( ktc). Gi tr ti thiu ca V l A. 1,344 B. 4,480 C. 2,240 D. 2,688 Cu 6 : S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l A. 2 B. 5 C. 4 D. 3 Cu 7 : S hp cht l ng phn cu to, c cng cng thc phn t C 4H8O2, tc dng c vi dung dch NaOH nhng khng tc dng c vi Na l A. 2 B. 1 C. 3 D. 4 Cu 8 : Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l A. CH3COOCH=CHCH3 B. CH2=CHCH2COOCH3 C. CH2=CHCOOC2H5 D. C2H5COOCH=CH2 Cu 9 : Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. axit -aminopropionic B. mety aminoaxetat C. axit - aminopropionic D. amoni acrylat Cu 10 : Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l : A. C2H4(OH)2, CH3OH, CH3CHO B. CH3CHO, C2H5OH, C2H5COOCH3 . C. CH3OH, C2H5OH, CH3CHO D. CH3CHO, C6H12O6 (glucoz), CH3OH Cu 11 : Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH(phenol) (T). Dy gm cc cht c sp xp theo tnh axit tng dn (t tri sang phi) l : A. (X), (Z), (T), (Y) B. (Y), (T), (Z), (X) C. (Y), (T), (X), (Z) D. (T), (Y), (X), (Z) Cu 12 : Cho cc cht : xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi phn ng vi H2 (d, xc tc Ni, to), cho cng mt sn phm l : A. 2-metylpropen, cis-but-2-en v xiclobutan B. but-1-en, 2-metylpropen v cis-but-2-en C. xiclobutan, cis-but-2-en v but-1-en D. xiclobutan , 2-metylbut-2-en v but-1-en Cu 13 : Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l A. 32,0 B. 8,0 C. 3,2 D. 16,0 Cu 14 : Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO3 (d) thu c 0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l A. 4,60 gam B. 1,15 gam C. 5,75 gam D. 2,30 gam Page 1

Bi tng hp hu c s 1
Cu 15 : Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO3 trong NH3 un nng th thu c 21,6 gam Ag. Tn gi ca X l A. axit acrylic B. axit propanoic C. axit etanoic D. axit metacrylic Cu 16 : Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X l A. CH3CHO v C2H5CHO B. HCHO v CH3CHO C. HCHO v C2H5CHO D. C2H3CHO v C3H5CHO Cu 17 : Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 453 B. 382 C. 328 D. 479 Cu 18 : Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi dung dch cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng ht vi Na thu c 3,36 lt kh H2 ( ktc). Hai cht hu c l A. mt este v mt axit B. mt este v mt ancol C. hai axit D. hai este Cu 19 : Cho cc chuyn ho sau
xc tc, t X H2O Y Ni, t Y H2 Sobitol t Y 2AgNO3 3NH3 H2O Amoni gluconat 2Ag 2NH4 NO3
xc tc Y E Z

a nhsa ng Z H2O X G cha t die p lu c

X, Y v Z ln lt l : A. tinh bt, glucoz v ancol etylic B. tinh bt, glucoz v kh cacbonic C. xenluloz, glucoz v kh cacbon oxit D. xenluloz, frutoz v kh cacbonic Cu 20 : Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO2 sinh ra trong qutrnh ny c hp th ht vo dung dch Ca(OH)2 (d) to ra 40 gam kt ta. Nu hiu sut ca qu trnh ln men l 75% th gi tr ca m l A. 48 B. 60 C. 30 D. 58 Cu 21: Qu trnh no sau y khng to ra anehit axetic? A. CH2=CH2 + H2O (to, xc tc HgSO4) B. CH2=CH2 + O2 (to, xc tc) C. CH3-CH2OH + CuO (to) D. CH3-COOCH=CH2 + dung dch NaOH (to) Cu 22 : Cho tng cht H 2 N CH 2 COOH, CH3 COOH, CH3 COOCH3 ln lt tc dng vi dung dch NaOH (t0). S phn ng xy ra l A. 3 B. 5 C. 6 D. 4 Cu 23: Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v CH3CH(OH)CHO. B. C2H5COOH v HCOOC2H5. C. HCOOC2H5v HOCH2CH2CHO. D. HCOOC2H5 v HOCH2COCH3. Cu 24: Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l A. CH3CH2COONH4. B. CH3COONH3CH3. C. HCOONH2(CH3)2. D. HCOONH3CH2CH3. Cu 25: Dy gm cc cht u tc dng vi ancol etylic l: A. NaOH, K, MgO, HCOOH (xc tc). B. Na2CO3, CuO (to), CH3COOH (xc tc), (CH3CO)2O. C. Ca, CuO (to), C6H5OH (phenol), HOCH2CH2OH. Page 2

Bi tng hp hu c s 1
D. HBr (to), Na, CuO (to), CH3COOH (xc tc). Cu 26: Hiro ha hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau trong dy ng ng (MX< MY), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln lt l A. HCHO v 32,44% B. HCHO v 50,56% C. CH3CHO v 67,16% D. CH3CHO v 49,44%. Cu 27: Cho cc cht: CH2=CHCH=CH2; CH3CH2CH=C(CH3)2; CH3CH=CHCH=CH2; CH3 CH =CH2; CH3CH=CHCOOH. S cht c ng phn hnh hc l A. 1. B. 3. C. 4. D. 2. Cu 28: Cho cc cht : saccaroz, glucoz , frutoz, etyl format , axit fomic v anehit axetic. Trong cc cht trn, s cht va c kh nng tham gia phn ng trng bc va c kh nng phn ng vi Cu(OH)2 iu kin thng l A. 3 B. 2 C. 4 D. 5 Cu 29: Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri (d), thu c 2,24 lt kh H2 (ktc). Mt khc, phn ng hon ton vi m gam X cn 100 ml dung dch NaOH 1M. Gi tr ca m l: A. 7,0 B. 14,0 C. 10,5 D.21,0 Cu 30: Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic. Hiu sut qu trnh ln men to thnh ancol etylic l: A. 60% B. 40% C. 80% D. 54% Cu 31: Cho cc polime : (1) polietilen , (2) poli (metyl metacrylat), (3) polibutaien, (4) polistiren, (5) poli(vinyl axetat) v (6) t nilon-6,6. Trong cc polime trn, cc polime c th b thu phn trong dung dch axit v dung dch kim l: A. (2),(3),(6) B. (2),(5),(6) C. (1),(4),(5) D. (1),(2),(5) Cu 32: phn ng ht vi mt lng hn hp gm hai cht hu c n chc X v Y (M x< MY) cn va 300 ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton thu c 24,6 gam mui ca mt axit hu c v m gam mt ancol. t chy hon ton lng ancol trn thu c 4,48 lt CO2 (ktc) v 5,4 gam H2O. Cng thc ca Y l : A. CH3COOC2H5 B. CH3COOCH3 C. CH2=CHCOOCH3 D. C2H5COOC2H5 Cu 33: Cht no sau y c ng phn hnh hc? A. CH2=CH-CH=CH2 B. CH3-CH=CH-CH=CH2 C. CH3-CH=C(CH3)2 D. CH2=CH-CH2-CH3 Cu 34: Amino axit X c dng H2NRCOOH (R l gc hirocacbon). Cho 0,1 mol X phn ng ht vi dung dch HCl (d) thu c dung dch cha 11,15 gam mui. Tn gi ca X l: A. phenylalanin B. alanin C. valin D.glyxin Cu 35: Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s mol 1:1 (c mt bt st) l A. o-bromtoluen v p-bromtoluen B. benzyl bromua C. p-bromtoluen v m-bromtoluen D. o-bromtoluen v m-bromtoluen Cu 36: t chy hon ton mt lng hn hp X gm 3 ancol thuc cng dy ng ng thu c 6,72 lt kh CO2 (ktc) v 9,90 gam H2O. Nu un nng cng lng hn hp X nh trn vi H2SO4 c nhit thch hp chuyn ht thnh ete th tng khi lng ete thu c l: A. 6,45 gam B. 5,46 gam C. 7,40 gam D. 4,20 gam Cu 37: S ancol ng phn cu to ca nhau c cng thc phn t C5H12O, tc dng vi CuO un nng sinh ra xenton l: A. 4 B. 2 C. 5 D. 3 Cu 38: Cng thc ca triolein l: A. (CH3[CH2]16COO)3C3H5 B. (CH3[CH2]7CH=CH[CH2]5COO)3C3H5 C. (CH3[CH2]7CH=CH[CH2]7COO)3C3H5 D. (CH3[CH2]14COO)3C3H5 Cu 39: Pht biu no sau y l ng? A. Amino axit l hp cht c tnh lng tnh. Page 3

Bi tng hp hu c s 1
B. Trong mi trng kim, ipetit mch h tc dng c vi Cu(OH)2 cho hp cht mu tm. C. Trong mt phn t tetrapeptit mch h c 4 lin kt peptit. D. Cc hp cht peptit km bn trong mi trng baz nhng bn trong mi trng axit Cu 40: Hai cht hu c X, Y c thnh phn phn t gm C, H, O (MX<MY <82). C X v Y u c kh nng tham gia phn ng trng bc v u phn ng c vi dung dch KHCO3 sinh ra kh CO2. T khi hi ca Y so vi X c gi tr l: A. 1,47 B. 1,61 C. 1,57 D. 1,91 Cu 41: Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch NaOH 8%, sau khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt ancol. Cng thc ca X l: A. CH3COOC2H5 B. C2H5COOCH3 C. CH2=CHCOOCH3 D. CH3COOCH=CH2 Cu 42: Cho s phn ng:
X(xt,t ) Z(xt,t ) M(xt,t ) CH4 Y T CH3COOH (X, Z, M l cc cht v c, mi mi tn ng vi mt phng trnh phn ng). Cht T trong s trn l: A. C2H5OH B. CH3COONa C. CH3CHO D. CH3OH Cu 43: x phng ho hon ton 52,8 gam hn hp hai este no, n chc , mch h l ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc. Cng thc ca hai este l A. CH3COOC2H5 v HCOOC3H7 B. C2H5COOC2H5 v C3H7COOCH3 C. HCOOC4H9 v CH3COOC3H7 D. C2H5COOCH3 v CH3COOC2H5 Cu 44: Hp cht hu c X c cng thc phn t l C4H8O3. X c kh nng tham gia phn ng vi Na, vi dung dch NaOH v phn ng trng bc. Sn phm thu phn ca X trong mi trng kim c kh nng ho tan Cu(OH)2 to thnh dung dch mu xanh lam. Cng thc cu to ca X c th l: A. CH3CH(OH)CH(OH)CHO B. HCOOCH2CH(OH)CH3 C. CH3COOCH2CH2OH. D. HCOOCH2CH2CH2OH Cu 45: Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH)2 th vn thu c kt ta. Thu phn X bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn trm khi lng ca oxi trong X l: A. 43,24% B. 53,33% C. 37,21% D. 36,36% Cu 46: Cho cc dung dch : C6H5NH2 (amilin), CH3NH2, NaOH, C2H5OH v H2NCH2COOH. Trong cc dung dch trn, s dung dch c th lm i mu phenolphtalein l A. 3 B. 2 C. 4 D. 5 Cu 47: Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohecxan, xiclopropan v xiclopentan. Trong cc cht trn, s cht phn ng uc vi dung dch brom l: A. 4. B. 3. C. 5. D. 6. Cu 48: Hai cht no sau y u tc dng uc vi dung dch NaOH lang? A. ClH3NCH2COOC2H5. v H2NCH2COOC2H5. B. CH3NH2 v H2NCH2COOH. C. CH3NH3Cl v CH3NH2. D. CH3NH3Cl v H2NCH2COONa. Cu 49: Hn hp G gm hai anehit X v Y, trong Mx< My< 1,6 Mx. t chy hn hp G thu c CO2 v H2O c s mol bng nhau. Cho 0,10 mol hn hp G vo dung dch AgNO3 trong NH3 thu c 0,25 mol Ag. Tng s cc nguyn t trong mt phn t Y l A. 10 B. 7. C. 6. D. 9. Cu 50: un si hn hp propyl bromua, kali hiroxit v etanol thu c sn phm hu c l A. propin. B. propan-2-ol. C. propan. D. propen. Cu 51: S hp cht ng phn cu to ca nhau c cng thc phn t C8H10O, trong phn t c vng benzen, tc dng c vi Na, khng tc dng c vi NaOH l A. 4. B. 6. C. 7. D. 5. o o o

Page 4

Bi tng hp hu c s 1
Cu 52: Amin X c phn t khi nh hn 80. Trong phn t X nit chim 19,18% v khi lng. Cho X tc dng vi dung dch hn hp gm KNO2 v HCl thu c ancol Y. Oxi ha khng hon ton Y thu c xeton Z. Pht biu no sau y ng? A. Tch nc Y ch thu c mt anken duy nht. B. Trong phn t X c mt lin kt . C. Tn thay th ca Y l propan-2-ol. D. Phn t X c mch cacbon khng phn nhnh. Cu 53: Cht X tc dng vi benzen (xt, t0) to thnh etylbenzen. Cht X l

A. CH4. B. C2H2. C. C2H4. D. C2H6.

Cu 54: Cho s chuyn ha: CH3CH2Cl X Y Trong s trn, X v Y ln lt l A. CH3CH2CN v CH3CH2OH B. CH3CH2NH2 v CH3CH2COOH C. CH3CH2CN v CH3CH2COOH D. CH3CH2CN v CH3CH2COOH Cu 55: Dy gm cc cht xp theo chiu lc axit tng dn t tri sang phi l: A. HCOOH, CH3COOH, CH3CH2COOH B. CH3COOH, HCOOH, (CH3)2CHCOOH C. C6H5OH, CH3COOH, CH3CH2OH D. CH3COOH, CH2ClCOOH, CHCl2COOH Cu 56: C mt s nhn xt v cacbonhirat nh sau: (1) Saccaroz, tinh bt v xenluloz u c th b thy phn (2) Glucoz, fructoz, saccaroz u tc dng c vi Cu(OH)2 v c kh nng tham gia phn ng trng bc (3) Tinh bt v xenluloz l ng phn cu to ca nhau (4) Phn t xenluloz c ccu to bi nhiu gc -glucoz (5) Thy phn tinh bt trong mi trng axit sinh ra fructoz Trong cc nhn xt trn, s nhn xt ng l A. 2 B. 5 C. 4 D. 3 Cu 57 : Cho dy cc dung dch: axit axetic, phenylamoni clorua, natri axetat, metylamin, glyxin, phenol (C6H5OH). S dung dch trong dy tc dng c vi dung dch NaOH l B. A. 6. B. 3. C. 4. D. 5. Cu 58 : Cho m gam hn hp hoi X gm hai ancol (n chc, bc I, l ng ng k tip) phn ng vi CuO d, thu c hn hp hi Y gm nc v anehit. T khi hi ca Y so vi kh hiro bng 14,5. Cho ton b Y phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 97,2 gam Ag. Gi tr ca m l A. 14,0. B. 14,7. C. 10,1. D. 18,9. Cu 59: Cho s phn ng: AgNO3 / NH3 NaOH NaOH t0 t0 t0 Este X (C4HnO2) Y Z C2H3O2Na. Cng thc cu to ca X tha mn s cho l A. CH2=CHCOOCH3. B. CH3COOCH2CH3. C. HCOOCH2CH2CH3. D. CH3COOCH=CH2. Cu 60: Pht biu no sau y l ng? A. Polietilen v poli (vinyl clorua) l sn phm ca phn ng trng ngng hp B. T visco, t xenluloz axetat u thuc loi t tng hp C. Si bng, t tm thuc loi polime thin nhin. D. T nilon-6,6 c iu ch t hexametyleniamin v axit axetic Cu 61: Trong phn t axit cacboxylic X c s nguyn t cacbon bng s nhm chc. t chy hon ton mt lng X thu c s mol CO2 bng s mol H2O. Tn gi ca X l Page 5

KCN KCN

H3O +, t0

Bi tng hp hu c s 1
A. axit axetic. B. axit oxalic. C. axit fomic. D. axit malonic Cu 62: Cho cc pht biu sau: (1) Fructoz v glucoz u c kh nng tham gia phn ng trng bc; (2) Saccaroz v tinh bt u khng b thy phn khi c axit H2SO4 (long) lm xc tc (3) Tinh bt c to thnh trong cy xanh nh qu trnh quang hp; (4) Xenluloz v saccaroz u thuc loi isaccarit Pht biu ng l A. (3) v (4). B. (1) v (3). C. (1) v (2). D. (2) v (4). Cu 63: Nung mt lng butan trong bnh kn (c xc tc thch hp) thu c hn hp kh X gm ankan v anken. T khi ca X so vi kh hiro l 21,75. Phn trm th tch ca butan trong X l A. 33,33% B. 50,00% C. 66,67% D. 25,00% Cu 64: t chy hon ton m gam hn hp X gm hai ancol n chc, cng dy ng ng, thu c 15,68 lt kh CO2 (ktc) v 17,1 gam nc. Mt khc, thc hin phn ng este ha m gam X vi 15,6 gam axit axetic, thu c a gam este. Bit hiu sut phn ng este ha ca hai ancol u bng 60%. Gi tr ca a l A. 15,48. B. 25,79. C. 24,80. D. 14,88. Cu 65: Cho cc este : etyl fomat (1), vinyl axetat (2), triolein (3), metyl acrylat (4), phenyl axetat (5). Dy gm cc este u phn ng c vi dung dch NaOH (un nng) sinh ra ancol l A. (1), (2), (3). B. (1), (3), (4). C. (2), (3), (5). D. (3), (4), (5). Cu 66: Pht biu no sau y l sai? A. Tripeptit Gly-Ala-Gly c phn ng mu biure vi Cu(OH)2. B. Trong phn t ipeptit mch h c hai lin kt peptit. C. Protein n gin c to thnh t cc gc -amino axit. D. Tt c cc peptit u c kh nng tham gia phn ng thy phn. Cu 67: Pht biu no sau y l ng? A. Ancol etylic tc dng c vi dung dch NaOH B. Axit bo l nhng axit cacboxylic a chc. C. Etylen glicol l ancol no, n chc, mch h D. Este isoamyl axetat c mi chui chn. Cu 68: Ln men 90 kg glucoz thu c V lt ancol etylic (D = 0,8 g/ml) vi hiu sut ca qu trnh ln men l 80%. Gi tr ca V l A. 71,9 B. 46,0 C. 23,0 D. 57,5 Cu 69: Pht biu no sau y l sai? A. Cao su buna-N thuc loi cao su thin nhin. B. Lc baz ca aniline yu hn lc baz ca metylamin. C. Cht bo cn c gi l triglixerit hoc triaxylglixerol. D. Poli(metyl metacrylat) c dng ch to thy tinh hu c. Cu 70: Cho dy cc cht: etan, etanol, etanal, axit etanoic. Cht c nhit si cao nht trong dy l A. etanal B. etan C. etanol. D. axit etanoic. Cu 71: Thy phn hon ton m gam ipeptit Gly-Ala (mch h) bng dung dch KOH va , thu c dung dch X. C cn ton b dung dch X thu c 2,4 gam mui khan. Gi tr ca m l A. 1,22 B. 1,46 C. 1,36 D. 1,64 Cu 72: Cng thc chung ca amin no, n chc, mch h l A. CnH2n-1N (n 2) B. CnH2n-5N (n 6) C. CnH2n+1N (n 2) D. CnH2n+3N (n 1) Cu 73: Cht no sau y va tc dng c vi dung dch NaOH, va tc dng c vi nc Br2? A. CH3CH2CH2OH B. CH3COOCH3 C. CH3CH2COOH. D. CH2=CHCOOH. Cu 74: Ha hi hon ton 4,4 gam mt este X mch h, thu c th tch hi bng th tch ca 1,6 gam kh oxi (o cng iu kin). Mt khc, thy phn hon ton 11 gam X bng dung dch NaOH d, thu c 10,25 gam mui. Cng thc ca X l A. C2H5COOCH3. B. CH3COOC2H5. C. C2H5COOC2H5. D. HCOOC3H7. Cu 75 : Cho dy cc cht : anehit axetic, axetilen, glucoz, axit axetic, metyl axetat. S cht trong dy c kh nng tham gia phn ng trng bc l A. 4 B. 5 C. 2 D. 3 Page 6

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Cu 76: t chy hon ton hn hp X gm hai ancol no, hai chc, mch h cn va V1 lt kh O2, thu c V2 lt kh CO2 v a mol H2O. Cc kh u o iu kin tiu chun. Biu thc lin h gia cc gi tr V1, V2, a l A. V1 = 2V2 - 11,2a B. V1 = V2 +22,4a C. V1 = V2 - 22,4a D. V1 = 2V2 + 11,2a Cu 77: Cho cc cht hu c : CH3CH(CH3)NH2 (X) v CH3CH(NH2)COOH (Y). Tn thay th ca X v Y ln lt l A. propan-2-amin v axit aminoetanoic B. propan-2-amin v axit 2-aminopropanoic C. propan-1-amin v axit 2-aminopropanoic D. propan-1-amin v axit aminoetanoic. Cu 78: Pht biu no sau y l ng? A. nhit thng, cc amino axit u l nhng cht lng B. Cc amino axit thin nhin hu ht l cc -amino axit C. Amino axit thuc loi hp cht hu c tp chc. D. Axit glutamic l thnh phn chnh ca bt ngt Cu 79: Cho cc pht biu: (1) Tt c cc anehit u c c tnh oxi ha v tnh kh; (2) Tt c cc axit cacboxylic u khng tham gia phn ng trng bc (3) Phn ng thy phn este trong mi trng axit l phn ng thun nghch; (4) Tt c cc ancol no, a chc u ha tan c Cu(OH)2 Pht biu ng l A. (2) v (4) B. (3) v (4) C. (1) v (3) D. (1) v (2) Cu 80: Cho 14, 55 gam mui H2NCH2COONa tc dng hon ton vi dung dch HCl d, thu c dung dch X. C cn ton b dung dch X, thu c bao nhiu gam mui khan? A. 16,73 gam B. 25,50 gam C. 8,78 gam D. 20,03 gam Cu 81: t chy hon ton hn hp X gm hai hirocacbon k tip nhau trong dy ng ng, thu c 2,24 lt kh CO2 (ktc) v 3,24 gam H2O. Hai hirocacbon trong X l A. C2H2 v C3H4. B. C2H4 v C3H6. C. CH4 v C2H6 D. C2H6 v C3H8 Cu 82 Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. B. buta-1,3-ien; cumen; etilen; trans-but-2-en. C. stiren; clobenzen; isopren; but-1-en. D. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. Cu 83 : t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 ( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l A. CH3COCH3. B. O=CH-CH=O. C. CH2=CH-CH2-OH. D. C2H5CHO. Cu 84: Pht biu no sau y l ng? A. Trng hp stiren thu c poli (phenol-fomanehit). B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N. C. Poli (etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng. D. T visco l t tng hp. Cu 85: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H 2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOC-CH2-COOH v 70,87%. B. HOOC-COOH v 60,00%. C. HOOC-CH2-COOH v 54,88%. D. HOOC-COOH v 42,86%. Cu 86: Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l: A. CH3CHO, C2H5OH, HCOOH, CH3COOH. B. CH3COOH, HCOOH, C2H5OH, CH3CHO. C. HCOOH, CH3COOH, C2H5OH, CH3CHO D. CH3COOH, C2H5OH, HCOOH, CH3CHO. Cu 87: Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l Page 7

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A. (H2N)2C3H5COOH. B. H2NC2C2H3(COOH)2. C. H2NC3H6COOH. D. H2NC3H5(COOH)2. Cu 88: Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H 2 ( ktc). Cng thc cu to thu gn ca X l A. CH3-C6H3(OH)2. B. HO-C6H4-COOCH3. C. HO-CH2-C6H4-OH. D. HO-C6H4-COOH. Cu 89: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH3-CH=CH-CH3. B. CH2=CH-CH2-CH3. C. CH2=C(CH3)2. D. CH2=CH2. Cu 90: Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong dung dch axit un nng (6). Cc tnh cht ca xenluloz l: A. (3), (4), (5) v (6) B. (1), (3), (4) v (6) C. (2), (3), (4) v (5) D. (1,), (2), (3) v (4). Cu 91: Cho cc hp cht sau : (a) HOCH2-CH2OH (b) HOCH2-CH2-CH2OH (c) HOCH2-CH(OH)-CH2OH (d) CH3-CH(OH)-CH2OH (e) CH3-CH2OH (f) CH3-O-CH2CH3 Cc cht u tc dng c vi Na, Cu(OH)2 l A. (c), (d), (f) B. (a), (b), (c) C. (a), (c), (d) D. (c), (d), (e) Cu 92: S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 2 B. 3 C. 4 D. 1 Cu 93: Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2 . Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z ; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. CH3OH v CH3NH2 B. C2H5OH v N2 C. CH3OH v NH3 D. CH3NH2 v NH3 Cu 94: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3 , thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l: A. 40% B. 20% C. 25% D. 50% Cu 95: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. HCOOH v HCOOC2H5 B. CH3COOH v CH3COOC2H5 C. C2H5COOH v C2H5COOCH3 D. HCOOH v HCOOC3H7 Cu 96: Cho cc hp cht hu c : (1) ankan; (2) ancol no, n chc, mch h; (3) xicloankan; (4) ete no, n chc, mch h; (5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h (7) ankin; (8) anehit no, n chc, mch h; (9) axit no, n chc, mch h (10) axit khng no (c mt lin kt i C=C), n chc Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l : A. (3), (5), (6), (8), (9) B. (3), (4), (6), (7), (10) C. (2), (3), (5), (7), (9) D. (1), (3), (5), (6), (8) Cu 97: Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l Page 8

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A. C2H4O2 v C3H6O2 B. C3H4O2 v C4H6O2 C. C3H6O2 v C4H8O2 D. C2H4O2 v C5H10O2 Cu 98: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HO-CH2-CH2-CHO v HO-CH2-CH2-CH2-CHO B. HO-CH(CH3)-CHO v HOOC-CH2-CHO C. HO-CH2-CHO v HO-CH2-CH2-CHO D. HCOOCH3 v HCOOCH2-CH3 Cu 99: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l A. CH3COOCH3 B. O=CH-CH2-CH2OH C. HOOC-CHO D. HCOOC2H5 Cu 100: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. etylen glicol B. axit aipic C. axit 3-hiroxipropanoic D. ancol o-hiroxibenzylic Cu 101: Pht biu no sau y l ng ? A. Glucoz b kh bi dung dch AgNO3 trong NH3 B. Xenluloz c cu trc mch phn nhnh C. Amilopectin c cu trc mch phn nhnh D. Saccaroz lm mt mu nc brom. Cu 102: Hir ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 10,5 B. 17,8 C. 8,8 D. 24,8 Cu 103: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en B. but-2-en C. propilen D. Xiclopropan Cu 104: Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l: A. 29,75 B. 27,75 C. 26,25 D. 24,25 Cu 105: t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l A. HOOC-CH=CH-COOH B. HO-CH2-CH2-CH=CH-CHO C. HO-CH2-CH2-CH2-CHO D. HO-CH2-CH=CH-CHO Cu 106: Cho s chuyn ho:
HBr Mg,etekhan 2 4 Butan 2 ol X(anken) Y Z Trong X, Y, Z l sn phm chnh. Cng thc ca Z l A. CH3-CH(MgBr)-CH2-CH3 B. (CH3)3C-MgBr C. CH3-CH2-CH2-CH2-MgBr D. (CH3)2CH-CH2-MgBr Cu 107 :Pht biu no sau y khng ng? A. Glucoz tn ti dng mch h v dng mch vng B. Glucoz tc dng c vi nc brom C. Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH D. dng mch h, glucoz c 5 nhm OH k nhau. H SO a c,t o

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Cu 108: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn
ng va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml dung dch NaOH 0,75 M . Khi lng ca CH2=CH-COOH trong X l A. 1,44 gam B. 2,88 gam C. 0,72 gam D. 0,56 gam Cu 109: Ngi ta iu ch anilin bng s sau
Fe HCl 3 Benzen Nitrobenzen Anilin 0 H SO a c 2 4 t HNO a c

Cu 110: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi
ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l A. 15,3 B. 8,5 C. 8,1 D. 13,5

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