CC DNG BI TP CA PEPTIT-PROTEIN Vn 1: Xc nh loi peptit nu cho khi lng phn t M:(ipeptit, tripetit, tetrapetit, pentapeptit) Th d 1: Cho peptit X ch do n gc glyxin

in to nn c khi lng phn t l 303 vC. Peptit X thuc loi ? A. tripetit. B. ipetit. C. tetrapeptit. D. pentapepit. Th d 2: Cho peptit X ch do m gc alanin to nn c khi lng phn t l 231 vC. Peptit X thuc loi ? A. tripetit. B. ipetit. C. tetrapeptit. D. pentapepit. Th d 3: Cho mt (X) peptit c to nn bi n gc glyxin v m gc alanin c khi lng phn t l 274 vC. Peptit (X) thuc loi ? A. tripetit. B. ipetit. C. tetrapeptit. D. pentapepit Th d 4: Cho mt (X) peptit c to nn bi n gc glyxin v m gc alanin c khi lng phn t l 345 vC. Peptit (X) thuc loi ? A. tripetit. B. ipetit. C. tetrapeptit. D. pentapepit. Vn 2: Xc nh loi peptit nu cho khi lng ca aminoaxit, peptit. Th d 1:Cho 9,84 gam peptit (X) do n gc glyxyl to thnh, thy phn hon ton trong mi trng axit long thu c 12 gam glyxin( l aminoaxit duy nht). (X) thuc loi ? A. ipetit. B. tripetit. C. tetrapeptit. D. pentapepit. Th d 2:Cho 20,79 gam peptit (X) do n gc alanyl to thnh, thy phn hon ton trong mi trng axit long thu c 24,03gam alanin( l aminoaxit duy nht). (X) thuc loi ? A. ipetit. B. tripetit. C. tetrapeptit. D. pentapepit. Th d 3:Khi thy phn hon ton 20,3 gam mt oligopeptit (X) thu c 8,9 gam alanin v 15 gam glyxin. (X) l ? A. tripeptit. B. tetrapeptit. C. pentapeptit. D. ipeptit. Th d 4:Cho 14,472 gam peptit (X) do n gc glyxyl v m gc alanyl to thnh, thy phn hon ton trong mi trng axit long thu c 8,1 glyxin v 9,612 gam alanin( khng cn aminoaxit no khc v X thuc oligopeptit). Trong (X) c ? A. 1 gc gly v 1 gc ala. B. 2 gc gly v 2 gc ala. C. 3 gc gly v 3 gc ala. D. 4 gc gly v 4 gc ala. Th d 5:Thu phn hon ton 500 gam mt oligopeptit X (cha t 2 n 10 gc -amino axit) thu c 178 gam amino axit Y v 412 gam amino axit Z. Bit phn t khi ca Y l 89 vC. Khi lng phn t ca Z l ? A. 103 vC. B. 75 vC. C. 117 vC. D. 147 vC. Vn 3: Xc nh loi peptit nu cho s mol hoc khi lng sn phm chy: Th d 1:t chy hon ton 0,12 mol mt peptit (X) do n gc glyxyl to nn thu c sn phm chy hp th vo bnh ng nc vi trong d th thu c 72 gam kt ta. (X) thuc loi ? A. ipetit. B. tripetit. C. tetrapetit. D. pentapetit. Th d 2: t chy hon ton 0,06 mol mt peptit (X) do n gc glyxyl to nn thu c sn phm chy hp th vo bnh ng nc vi trong d th khi lng bnh tng l 11,88 gam. (X) thuc loi ? A. ipetit. B. tripetit. C. tetrapetit. D. pentapetit. Th d 3: t chy hon ton 0,08 mol mt peptit (X) do n gc alanyl to nn thu c sn phm chy hp th vo bnh ng nc vi trong d th khi lng bnh tng l 58,08 gam. (X) thuc loi ? A. ipetit. B. tripetit. C. tetrapetit. D. pentapetit. Th d 4: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 45. B. 60. C. 120. D. 30. Vn 4: Tnh khi lng peptit. Th d 1: Thy phn ht m gam tripeptit : Gly-Gly-Gly ( mch h) thu c hn hp gm 13,5 gam Gly;15,84 gam GlyGly . Gi tr m l ? A. 26,24. B. 29,34. C. 22,86. D. 23,94. Th d 2: Thy phn ht 59,04 gam tetrapeptit: Gly-Gly-Gly-Gly (mch h) thu c hn hp gm 30 gam Gly; 21,12 gam Gly-Gly v m gam Gly-Gly-Gly. Gi tr ca m l A. 15,12. B. 15,04. C. 16,06. D. 16,44. Vn 5: Xc nh KLPT ca Protein (M) Th d 1: Mt protein c cha 0,312 % kali. Bit 1 phn t protein ny c cha 1 nguyn t kali. Xc nh khi lng phn t ca protein ? A. 14000 vC. B. 12500. C. 13500 vC. D. 15400 vC. Th d 2:Mt protein c cha 0,1 % nit. Bit 1 phn t protein ny c cha 1 nguyn t nit. Xc nh khi lng phn t ca protein ? A. 14000 vC. B. 12500. C. 13500 vC. D. 15400 vC. Th d3: Xc nh khi lng phn t gn ng ca Protein X c 0,16 % lu hunh, bit rng c 1 phn t X ch cha 1 nguyn t lu hunh. A. 20000 vC. B. 26000 vC. C. 13500 vC. D. 15400 vC. Th d4: Xc nh khi lng phn t gn ng ca Protein X c 0,4 % st, bit rng c 1 phn t X ch cha 1 nguyn t st. A. 12000 vC. B. 13000 vC. C. 12500 vC. D. 14000 vC. Vn 6: Tnh s mt xch (s gc) amino axit trong protein. Th d 1: Khi thy phn 500 gam protein (X) th thu c 170 gam alanin. Nu khi lng phn t ca protein l 500000 vC th s mc xch alanin trong (X) l bao nhiu ? A. 191. B. 200. C. 250. D. 181. Th d 2: Khi thy phn 40 gam protein (X) th thu c 10,5 gam glyxin. Nu khi lng phn t ca protein l 50000 vC th s mc xch alanin trong (X) l bao nhiu ?A. 191. B. 200. C. 175. D. 180. Th d 3: Protein (X) c 0,5 % km, bit rng c 1 phn t (X) ch cha 1 nguyn t km. Khi thy phn 26 gam protein (X) th thu c 15 gam glyxin vy th s mc xch glyxin trong 1 phn t (X) l bao nhiu ?

A. 200. B. 240. C. 250. D. 180. Th d 4: Bit rng c 1 phn t X ch cha 1 nguyn t ng. Protein X c 0,25 % ng, Khi thy phn 25,6 gam protein (X) th thu c 12,828 gam glyxin. Tnh s mt xch trong loi X ny ? A. 200. B. 260. C. 256. D. 171. Vn 7: Thy phn peptit. Th d 1: Thy phn hon ton 27,52 gam hn hp ipeptit th thu c 31,12 gam hn hp X gm cc aminoaxit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho lng hn hp X ny tc dng vi dung dung dch HCl d, c cn cn thn dung dch, th lng mui khan thu c l ? A. 45,72 gam. B. 58,64 gam. C. 31,12 gam. D. 42,12 gam. Th d 2: Thy phn hon ton 12,18 gam hn hp tripeptit th thu c 14,34 gam hn hp X gm cc aminoaxit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu ly 1/2 cho lng hn hp X ny tc dng vi dung dung dch HCl d, c cn cn thn dung dch, th lng mui khan thu c l ? A. 12,65 gam. B. 10,455 gam. C. 10,48 gam. D. 26,28 gam. Th d 4: Thy phn hon ton gam m g hn hp hai tripeptit thu c 82,08 gam hn hp cc a.a (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/2 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c 50,895 gam, m l : A. 75,6 gam. B. 74,18 gam. C. 77,61 gam. D. 75,42 gam. Th d5: Thy phn hon ton 13,86 gam hn hp hai tripetit thu c m gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1/3 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l 7,53 gam, m l: A. 17,09 gam. B. 16,30 gam. C. 16,02 gam. D. 17,82 gam. BI TP Cu 1: Cho s bin ha :
HNO 2 X Y NaOH Z CaO,t 0 NaOH T

, X l 1 aminoaxit mch thng c 1 nhm NH2 v 1 nhm COOH, T l 1 ancol v % khi lng oxi trong T l 34,78%.M l este ca X v T c phn trm khi lng oxi l : A. 35,955% B. 27,350% C. 22,069% D. 18,497% Cu 2: Mt peptit X to thnh t 1 aminoaxit no mch h c 1 nhm COOH v 1 nhm NH2 trong phn trm khi lng oxi l 19,324%. X l :A. ipeptit B. tripeptit C. tetrapeptit D. pentapeptit Cu 3: Hn hp A gm hai aminoaxit no cha mt chc amin, mt cha axit, lin tip nhau trong dy ng ng. Dng khng kh d t chy hon ton 3,21 g hn hp A. Hn hp thu c sau phn ng em lm kh c hn hp kh B. Cho B qua dung dch Ca(OH)2 d thu c 9,5 g kt ta. Phn trm s mol cc amino axit trong hn hp A ln lt l A. 50% v 50% B. 62,5% v 37,5% C. 40% v 60% D.27,5% v 72,5% Cu 4: tc dng va vi 29,94 gam hn hp X gm 1 s amino axit (ch c nhm chc COOH v NH2 , khng c nhm chc khc) cn 380 ml dung dch KOH 1M. Mt khc t chy 29,94 gam hn hp X cn 24,528 lt O2 (ktc) thu c m gam CO2; p gam H2O v 3,36 lt N2(ktc). a)m c gi tr l : A.39,60 gam B. 42,24 gam C. 52,80 gam D.38,72 gam b)p c gi tr l : A. 18,54 gam B. 18,72 gam C. 19,44 gam D. 20,16 gam Cu 5: Hn hp X gm 1 s amino axit no (ch c nhm chc COOH v NH2 , khng c nhm chc khc) c t l khi lng mO:mN=48:19. tc dng va vi 39,9 gam hn hp X cn 380 ml dung dch HCl 1M. Mt khc t chy 39,9 gam hn hp X cn 41,776 lt O2 (ktc) thu c m gam CO2. m c gi tr l : A. 66 gam B. 59,84 gam C. 61,60 gam D. 63,36 gam Cu 6: X v Y l 2 tetrapeptit, khi thy phn trong mi trng axit u thu c 2 loi amino axit no n chc mch h l A v B. Phn trm khi lng oxi trong X l 23,256% v trong Y l 24,24%.A v B ln lt l : A. alanin v valin B. glixin v alanin C. glixin v axit aminobutiric D. alanin v axit aminobutiric Cu 7: X v Y ln lt l tripeptit v tetrapeptit to thnh t 1 loi aminoaxit no mch h c 1 nhm NH2 v 1 nhm COOH. t chy 0,1 mol Y thu c CO2, H2O v N2 trong tng khi lng CO2 v H2O l 47,8 gam. Nu t 0,1 mol X cn bao nhiu mol O2? A. 0,560 mol B. 0,896 mol C. 0,675 mol D. 0,375 mol Cu 8: X l hexapeptit AlaGliAlaValGliVal. Y l tetrapeptit GliAlaGliGlu Thy phn m gam hn hp gm X v Y trong mi trng axit thu c 4 loi aminoaxit trong c 30 gam glixin v 28,48 gam alanin. m c gi tr l : A. 87,4 gam B. 73,4 gam C. 77,6 gam D. 83,2 gam Cu 9: Cht hu c A c 1 nhm amino v 1 chc este. Hm lng nit trong A l 15,73%.X phng ha m gam cht A, hi ancol bay ra cho i qua CuO nung nng c anehit B. Cho B thc hin phn ng trng bc thy c 16,2 gam Ag kt tA. Gi tr ca m l :A. 7,725 gam B. 3,375 gam C.6,675 gam D. 5,625 gam Cu 10: X l 1 pentapeptit cu to t 1 amino axit no mch h c 1 nhm COOH v 1 nhm NH2 (A), A c tng phn trm khi lng oxi v nit l 51,685%. Khi thy phn ht m gam X trong mi trng axit thu c 30,2 gam tetrapeptit; 30,03 gam tripeptit; 25,6 gam ipeptit v 88,11 gam A. m c gi tr l : A. 149,2 gam B. 167,85 gam C. 156,66 gam D. 141,74 gam Cu 11: Thy phn ht 1 lng pentapeptit trong mi trng axit thu c 32,88 gam AlaGliAlaGli; 10,85 gam AlaGliAla; 16,24 gam AlaGliGli; 26,28 gam AlaGli; 8,9 gam Alanin cn li l GliGli v Glixin. T l s mol GliGli:Gli l 5:4. Tng khi lng GliGli v Glixin trong hn hp sn phm l : A. 43,2 gam B. 32,4 gam C. 19,44 gam D. 28,8 gam

 xut bn vo 08-09-2013 [1]. Mt peptit X to thnh t mt aminoaxit no mch h c mt nhm --COOH v mt nhm --NH2, trong phn trm khi lng oxi l 19,324%. X l A: ipeptit B: tripeptit C: tetrapeptit D: pentapeptit [13]. ipeptit X, pentapeptit Y u mch h v cng c to ra t 1 amino axit no, mch h trong phn t c 1 nhm NH2 v 1 nhm -COOH. Cho 16 gam X tc dng ht vi dung dch HCl d, lm kh cn thn dung dch sau phn ng thu c 25,1 gam cht rn. Vy khi t chy hon ton 0,2 mol Y th cn t nht bao nhiu mol O2 nu sn phm chy thu c gm CO2, H2O, N2 ? A: 3,75 mol. B: 3,25 mol. C: 4,00 mol. D: 3,65 mol. [14]. Tripeptit mch h X v tetrapeptit mch h Y u c to nn t mt -aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,2 mol Y thu c tng khi lng CO2 v H2O bng 95,6 gam. t chy hon ton 0,1 mol X, sn phm thu c cho hp th vo dung dch Ba(OH)2 d, sau phn ng khi lng dung dch ny A: gim 81,9 gam B: Gim 89 gam C: Gim 91,9 gam D: gim 89,1 gam [17]. X l mt -Aminoaxit no, cha 1 nhm -COOH v 1 nhm -NH2. T m gam X iu ch c m1 gam ipeptit. T 2m gam X iu ch c m2 gam tripeptit. t chy m1 gam ipeptit thu c 0,3 mol nC. t chy m2 gam tripeptit thu c 0,55 mol H2O. Gi tr ca m l: A: 11,25 gam B: 13,35 gam C: 22,50 gam D: 26,70 gam

KIM TRA - MN HA HC

Thi gian 15 pht

Cu 30. t chy hon ton este X n chc, mch thng cn dng 4,704 lt O2 (ktc), sn phm chy dn qua dung dch Ca(OH)2 d thu c 18 gam kt ta; ng thi khi lng dung dch gim 7,92 gam. Mt khc un nng 16,8 gam este X trong 200 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c rn khan c khi lng 16,1 gam v phn hi cha cht hu c Z. Cng thc cu to ca Z l. A. C2H5OH B. CH3CHO C. C2H5CHO D. CH3-CO-CH3 Cu 31. Hp cht hu c X cha 1 loi nhm chc c CTPT l C8H14O4. Khi thy phn X trong dung dch NaOH thu c 1 mui v hn hp 2 ancol A v B. Phn t ancol B c s nguyn t cacbon nhiu gp i ancol A.Khi un nng vi H2SO4 c 1700C; A cho 1 anken cn B cho 2 anken ng phn. Cng thc cu to ca A l. A. C2H5OH B. CH3-CH2-CH2OH C. (CH3)2CH-OH D. (CH3)3COH Cu 32. Cho x mol axit cacboxylic no X tc dng NaHCO3 sinh ra x mol CO2; y mol ancol no Y tc dng vi Na thot ra y mol H2. Z l este thun chc to bi X v Y (X, Y u mch h). t chy hon ton m gam Z bng lng O2 d, sn phm chy dn qua bnh cha dung dch Ca(OH)2 d thu c 22,5 gam kt ta; ng thi khi lng bnh tng 13,5 gam. Gi tr m l. A. 3,76 gam B. 5,64 gam C. 4,70 gam D. 6,58 gam Cu 33. t chy hon ton a mol triglyxerit X, thu c x mol CO2 v y mol H2O.

Bit x = y + 8a. Hydo ha hon ton a mol X cn 0,18 mol H2 (Ni, t0) thu c 26,7 gam Y. Khi lng x phng thu c khi un nng 4,39 tn X bng dung dch NaOH d l. A. 4,99 tn B. 3,93 tn C. 3,61 tn D. 4,53 tn Cu 34. Thc hin cc th nghim sau: + t chy hon ton x mol axit cacboxylic mch h X thu c 4x mol CO2 v 3x mol H2O. + Cho y mol ancol Y tc dng Na d thu c 0,5y mol H2. + un nng X v Y c mt H2SO4 c lm xc tc thu c cht hu c Z. Z khng tc dng vi Na v khng lm mt mu dung dch Br2. Bit rng s cacbon trong X gp i s cacbon trong Y. Phn trm khi lng ca oxi trong Z l. A. 28,07% B. 36,78% C. 43,84% D. 22,56% Cu 35. X, Y l 2 hp cht hu c cha vng benzen v l ng phn ca nhau. t chy hon ton 1,83 gam Y cn dng 3,36 lt O2 (ktc), thu c 5,28 gam CO2. Y c cng thc phn t trng vi cng thc n gin. Bit rng X khng tc dng vi dung dch NaOH, tch nc t X thu X tham gia phn ng trng hp to polime; Y tc dng c vi dung dch NaOH. Tng s ng phn cu to ca X, Y l. A. 9 B. 12 C. 11 D. 10 Cu 36. Hn hp M cha 2 andehit X, Y (MX < MY). t chy a mol X cng nh Y u thu c a mol H2O. Cho 21,9 gam hn hp M tc dng dung dch AgNO3 trong NH3 d thu c kt ta trng c khi lng 151,2 gam. Cho dung dch HCl d vo dung dch sau phn ng thy thot ra kh khng mu c th tch l 4,48 lt (ktc). Cng thc phn t ca Y l. A. C2H2O2 B. C2H2O C. C6H2O2 D. C4H2O2 Cu 37. Cho cc phn ng sau: (1) CH3COO-CH2COOCH3 + NaOH (2) HCOO-CH2-OOCCH3 + NaOH (3) CH3OOC-COOC2H5 + NaOH (4) CH3COOCCl2-CH3 + NaOH (5) C6H5COOCHCl-CH2 + NaOH (6) CH3COOC6H4-OH + NaOH

(7) HCOO-CHCl-COOCH3 + NaOH (8) HCOOCH2-CCl3 + NaOH S phn ng u sinh ra 2 mui hu c l. A. 4 B. 6 C. 3 D. 5