Bi tp chng 3: Amin-Aminoaxit.

Phm Huy Quang

PHN I: CU HI L THUYT CU HI L THUYT AMIN

Cu 1: S ng phn amin c cng thc phn t C4H11N l A. 5. B. 7. C. 6. D. 8. Cu 2: Hp cht hu c X mch h cha cc nguyn t C, H, N trong c 23,72% khi lng N. X tc dng vi HCl theo t l mol 1:1. Cu tr li no sau y l khng ng A. X l hp cht amin B. Cu to ca X l amin no, n chc C. Nu cng thc ca X l CxHyNz th c mi lin h l 2x - y = 45. D. Nu cng thc ca X l C xHyNz th z = 1. Cu 3: S ng phn amin bc mt ng vi cng thc phn t C3H9N l A. 4. B. 3. C. 2. D. 5. Cau 4: Co 4 hoa chat : metylamin (1), phenylamin (2), iphenylamin (3), imetylamin (4). Th t tang dan lc baz la : A. (4) < (1) < (2) < (3). B. (2) < (3) < (1) < (4). C. (2) < (3) < (1) < (4). D. (3) < (2) < (1) < (4). Cu 5: Phn ng no sau y khng th hin tnh baz ca amin A. CH3NH2 + H2O CH3N H 3 + H2O C. Fe3+ + 3CH3NH2 + 3H2O Fe(OH)3 + 3CH3N H
+ 3 +

B. C6H5NH2 + HCl C6H5NH3Cl D. CH3NH2 + HNO2 CH3OH + N2 + H2O

Cu 6: S ng phn amin bc mt ng vi cng thc phn t C4H11N l A. 4. B. 3. C. 2. D. 5. Cau 7: Phat bieu nao sau ay la ung : A. Khi thay H trong hirocacbon bang nhom NH 2 ta thu c amin. B. Amino axit la hp chat hu c a chc co 2 nhom NH 2 va COOH. C. Khi thay H trong phan t NH3 bang goc hirocacbon ta thu c amin. D. Khi thay H trong phan t H2O bang goc hirocacbon ta thu c ancol. Cu 8: Pht biu no sau y khng ng A. Amin c cu thnh bng cch thay th H ca amoniac bng mt hay nhiu gc hidrocacbon. B. Bc ca amin l bc ca nguyn t cacbon lin kt vi nhm amin. C. Ty thuc vo cu trc ca gc hidrocacbon, c th phn bit amin no, cha no v thm. D. Amin c t hai nguyn t Cacbon trong phn t bt u xut hin hin tng ng phn. Cu 9: C bao nhiu amin cha vng benzen c cng cng thc phn t C 7H9N ? A. 3 amin. B. 5 amin. C. 6 amin. D. 7 amin. Cu 10: Dung dch etylamin tc dng c vi dung dch nc ca cht no sau y? A. NaOH B. NH3 C. NaCl D. FeCl3 v H2SO4 Cu 11: Trong cc cht sau, cht no l amin bc 2? A. H2N-[CH2]6NH2 B. CH3CH(CH3)NH2 C. CH3NHCH3 D. C6H5NH2 Cu 12: C bao nhiu amin bc hai c cng cng thc phn t C 5H13N ? A. 4 amin. B. 5 amin. C. 6 amin. D. 7 amin. Cu 13: Trong cc tn gi di y, tn no ph hp vi cht CH3CH(CH3)NH2? A. Metyletylamin. B. Etylmetylamin. C. Isopropanamin. D. Isopropylamin. Cu 14: Trong cc tn gi di y, cht no c lc baz mnh nht ? A. NH3 B. C6H5CH2NH2 C. C6H5NH2 D. (CH3)2NH Cu 15: Tnh baz ca cc cht tng dn theo th t dy no sau y A. NH3 < C6H5NH2 < CH3NHCH3 < CH3CH2NH2. B. NH3 < CH3CH2NH2 < CH3NHCH3 < C6H5NH2. C. C6H5NH2 < NH3 < CH3CH2NH2 < CH3NHCH3. D. C6H5NH2 < NH3 < CH3NHCH3 < CH3CH2NH2. Cu 16:Pht biu no sau y v tnh cht vt l ca amin l khng ng A. Metyl-, Etyl- , imetyl-, Trimetylamin l nhng cht kh, d tan trong nc. B. Cc amin kh c mi thm tng t amoniac v c. C. Anilin l cht lng, kh tan trong nc, mu en. D. tan ca amin gim dn khi s nguyn t Cacbon trong phn t tng. Cu 17: Trong cc tn gi di y, tn no ph hp vi cht C6H5-CH2-NH2? A. Phenylamin. B. Benzylamin. C. Anilin. D. Phenylmetylamin. Cu 18: Trong cc cht di y, cht no c tnh baz mnh nht ?

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Bi tp chng 3: Amin-Aminoaxit.

Phm Huy Quang

A. C6H5NH2. B. (C6H5)2NH C. p-CH3-C6H4-NH2. D. C6H5-CH2-NH2 Cu 19: Cht khng c kh nng lm xanh nc qu tm l A. Anilin B. Natri hiroxit. C. Natri axetat. D. Amoniac. Cu 20: Cht khng phn ng vi dung dch NaOH l A. C6H5NH3Cl. B. C6H5CH2OH. C. p-CH3C6H4OH. D. C6H5OH. Cu 21: tch ring tng cht t hn hp benzen, anilin, phenol ta ch cn dng cc ho cht (dng c, iu kin th nghim y ) l A. dung dch NaOH, dung dch HCl, kh CO2. B. dung dch Br2, dung dch HCl, kh CO2. C. dung dch Br2, dung dch NaOH, kh CO2. D. dung dch NaOH, dung dch NaCl, kh CO2. Cu 22: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. Cu 23: Anilin, alanin, mononatri glutamat u cho phn ng vi dung dch no sau y? A. dd NH3 B. dd NaOH C. dd HCl D. dd brm Cu 24: Kt ta xut hin khi nh dung dch brom vo A. ancol etylic. B. benzen. C. anilin. D. axit axetic. Cu 25: Cht lm giy qu tm m chuyn thnh mu xanh l A. C2H5OH. B. CH3NH2. C. C6H5NH2. D. NaCl. Cu 26: Anilin (C6H5NH2) phn ng c vi dung dch A. NaOH. B. HCl. C. Na2CO3. D. NaCl. Cu 27: Dung dch cht no sau y khng lm i mu qu tm? A. C6H5NH2 B. NH3 C. CH3CH2NH2 D. CH3NHCH2CH3. Cu 28: Phng trnh ha hc no sau y khng ng A. 2CH3NH2 + H2SO4 (CH3NH3)2SO4. B. 3CH3NH2 + 3H2O + FeCl3 Fe(OH)3 + 3CH3NH3Cl. C. C6H5NH2 + 2Br2 3,5-Brom-C6H3NH2 + 2HBr. D. C6H5NO2 + 3Fe + 7HCl C6H5NH3Cl + 3FeCl2 + 2H2O. Cu 29: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. nc brom. C. dung dch NaOH. D. giy qu tm. Cu 30: Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi A. dung dch NaCl. B. dung dch HCl. C. nc Br2. D. dung dch NaOH. Cu 31: Dung dch metylamin trong nc lm A. qu tm khng i mu. B. qu tm ha xanh. C. phenolphtalein ho xanh. D. phenolphtalein khng i mu. Cu 32: t chy hon ton mt ng ng ca metylamin th thy th tch cc kh v hi ca cc sn phm sinh ra

VCO2 V H 2O

2 .Xc nh cng thc ng ca amin 3

B. C2H7N C. C3H9N D. C4H11N D. C6H5OH. D. N,N-

A. CH5N

Cu 33: Cht c tnh baz l A. CH3NH2. B. CH3COOH. C. CH3CHO. CH3 N CH2CH3 Cau 34 : Hp chat co ten ung la CH3 A. Trimetylmetanamin. B. imetyletanamin. C. N-imetyletanamin. imetyletanamin. Cau 35 : Hp chat CH3 NH CH2CH3 co ten ung la A. imetylamin. B. etylmetylamin. C. N-etylmetanamin. D. imetylmetanamin. Cau 36 : Co the nhan biet lo ng dung dch CH 3NH2 bang cach A. Ngi mui. B. Them vai giot H2SO4. C. Qu tm. vai giot NaOH.

D. Them

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Bi tp chng 3: Amin-Aminoaxit.

Phm Huy Quang

Cau 37 : ng vi cong thc C3H9N co so ong phan amin la A. 3. B. 4. C. 5. D. 6. Cu 38: Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi A. dd HCl B. dd NaOH C. nc Br2 NaCl Cau 39 : Chat nao la amin bac 2 ? A. H2N [CH2] NH2. B. (CH3)2CH NH2. C. CH3CH2NH CH3.D. (CH3)3N. Cau 40 : Chat nao co lc baz manh nhat ? A. CH3NH2. B. (CH3)2CH NH2. C. CH3CH2NHCH3. D. CH3NHCH3. Cau 41 : Chat nao co lc baz yeu nhat ? A. CH3NH2. B. (CH3)2CH NH2. C. CH3CH2NHCH3. D. NH3.

D. dd

CU HI L THUYT AMINOAXIT PEPTIT PROTEIN Cu 1: Amino axit l hp cht hu c trong phn t A. cha nhm cacboxyl v nhm amino. B. ch cha nhm amino. C. ch cha nhm cacboxyl. D. ch cha nit hoc cacbon. Cu 2: C4H9O2N c my ng phn amino axit c nhm amino v tr ? A. 4. B. 3. C. 2. D. 5. Cu 3: C bao nhiu amino axit c cng cng thc phn t C4H9O2N? A. 3 cht. B. 4 cht. C. 5 cht. D. 6 cht. Cu 4: Pht biu no di y v amino axit l khng ng: A. Aminoaxit l hp cht hu c tp chc trong phn t cha ng thi nhm amino v nhm cacboxyl. B. Hp cht H2NCOOH l aminoaxit n gin nht. C. Aminoaxit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc (H3N+RCOO-) D. Thng thng dng ion lng cc l dng tn ti chnh ca aminoaxit. Cu 5: Tn gi ca aminoaxit no sau y l ng A. H2N-CH2-COOH (glixerin) B. CH3-CH(NH2)-COOH (anilin) C. CH3-CH(CH3)-CH(NH2)COOH (valin) D. HCOO-(CH2)2-CH(NH2)COOH (axit glutaric) Cu 6: C bao nhiu amino axit c cng cng thc phn t C3H7O2N? A. 3 cht. B. 4 cht. C. 2 cht. D. 1 cht. Cu 7: chng minh tnh lng tnh ca NH2-CH2-COOH (X) , ta cho X tc dng vi A. HCl, NaOH. B. Na2CO3, HCl. C. HNO3, CH3COOH. D. NaOH, NH3. Cu 8: Khng nh no v tnh cht vt l ca aminoaxit di y khng ng A. Tt c u l cht rn. B. Tt c u l tinh th mu trng. A. Tt c u tan trong nc. D. Tt c u c nhit nng chy cao. Cu 9: Aminoaxit khng th phn ng vi loi cht no sau y A. Ancol B. Dung dch Brom C. Axit v axit nitr D. Kim loi, oxit baz v mui. Cau 10. Co bao nhieu ten goi phu hp vi cong thc cau tao: (1). H2N-CH2-COOH : Axit amino axetic. (2). H2N-[CH2]5-COOH : axit - amino caporic. (3). H2N-[CH2]6-COOH: axit - amino enantoic. (4). HOOC-[CH2]2-CH(NH2)-COOH : Axit amino Glutaric. (5). H2N-[CH2]4-CH (NH2)-COOH : Axit , - iamino caporic. A. 2 B. 3 C. 4 D.5 Cu 11: Trong cc cht di y, cht no l glixin? A. H2N-CH2-COOH B. CH3CH(NH2)COOH C. HOOC-CH2CH(NH2)COOH D. H2NCH2-CH2COOH Cu 12: Dung dch ca cht no sau y khng lm i mu qu tm : A. Glixin (CH2NH2-COOH) B. Lizin (H2NCH2-[CH2]3CH(NH2)-COOH) C. Axit glutamic (HOOCCH2CHNH2COOH) D. Natriphenolat (C6H5ONa) Cu 13: Cho 0,1 mol mt -aminoaxit A dng H2NRCOOH phn ng ht vi HCl to thnh 11,15gam mui. A l cht no sau y A. Glixin B. Alanin C. Phenylalanin D. Valin Cu 14: Cht no sau y va tc dng c vi H2NCH2COOH, va tc dng c vi CH3NH2? A. NaCl. B. HCl. C. CH3OH. D. NaOH.

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Bi tp chng 3: Amin-Aminoaxit.

Phm Huy Quang

Cu 15: X l mt -aminoaxit no ch cha mt nhm NH2 v mt nhm COOH. Cho 10,3gam X tc dng vi dung dch HCl d thu c 13,95gam mui clohidrat ca X. Cng thc cu to thu gn ca X l A. CH3CH(NH2)COOH B. NH2CH2COOH C. NH2CH2CH2COOH D.CH3CH2CH(NH2)COOH Cu 16: Bradikinin c tc dng lm gim huyt p, l mt nonapeptit c cng thc l: Arg Pro Pro Gly-Phe-Ser-Pro-Phe-Arg. Khi thy phn khng hon ton peptit ny c th thu c bao nhiu tri peptit m thnh phn c cha phenyl alanin ( phe) ? A. 4 B. 6 C. 5 D. 3 Cu 17: Cht rn khng mu, d tan trong nc, kt tinh iu kin thng l A. C6H5NH2. B. C2H5OH. C. H2NCH2COOH. D. CH3NH2. Cu 18: Cht tham gia phn ng trng ngng l A. C2H5OH. B. CH2 = CHCOOH. C. H2NCH2COOH. D. CH3COOH. Cu 19: Cho dy cc cht: C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2, C6H5OH (phenol). S cht trong dy tc dng c vi dung dch HCl l A. 4. B. 2. C. 3. D. 5. Cu 20: chng minh aminoaxit l hp cht lng tnh ta c th dng phn ng ca cht ny ln lt vi A. dung dch KOH v dung dch HCl. B. dung dch NaOH v dung dch NH3. C. dung dch HCl v dung dch Na2SO4 . D. dung dch KOH v CuO. Cu 21: X l mt cht hu c c cng thc phn t C 5H11O2N. un X vi NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi Y qua CuO thu c cht hu c Z c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l A. CH3(CH2)4NO2. C.NH2-CH2-COO-CH2-CH2-CH3. B. NH2-CH2-COO(CHCH3)2 D. H2N-CH2-CH2-COOC2H5 Cu 22: Axit aminoaxetic (H2NCH2COOH) tc dng c vi dung dch A. NaNO3. B. NaCl. C. NaOH. D. Na2SO4. Cu 23: Dung dch ca cht no trong cc cht di y khng lm i mu qu tm ? A. CH3NH2. B. NH2CH2COOH C. HOOCCH2CH2CH(NH2)COOH. D. CH3COONa. Cu 24: phn bit 3 dung dch H2NCH2COOH, CH3COOH v C2H5NH2 ch cn dng mt thuc th l A. dung dch NaOH. B. dung dch HCl. C. natri kim loi. D. qu tm. Cu 25: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2)-COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l A. 2. B. 5. C. 4. D. 3. Cu 26: Thy phn hp cht H2N-CH2-CO-NH-CH-CO-NH-CH-CO-NH-CH2-COOH thu c cc aminoaxit no sau y A. H2N-CH2-COOH B. HOOC-CH2-CH(NH2)COOH C. C6H5CH2CH(NH2)COOH D. Hn hp 3 aminoaxit trn Cu 27: Pht biu no di y v amino axit l khng ng? A. Hp cht H2NCOOH l amino axit n gin nht B. Thng thng dng ion lng cc l dng tn ti chnh ca amino axit C. Amino axit ngoi dng phn t (H2NRCOOH) cn c dng ion lng cc (H3N+RCOO-) D. Amino axit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl Cu 28: Glixin khng tc dng vi A. H2SO4 long. B. CaCO3. C. C2H5OH. D. NaCl. Cu 29: Trong cc cht sau: Cu, HCl, C2H5OH, HNO2, KOH, Na2SO3, CH3OH/kh HCl. Axit aminoaxetic tc dng c vi nhng cht no A. HCl, HNO2, KOH, Na2SO3, CH3OH/kh HCl B. C2H5OH, HNO2, KOH, Na2SO3, CH3OH/kh HCl, Cu C. HNO2, KOH, Na2SO3, CH3OH/kh HCl, Cu, HCl D. Tt c cc cht Cau 30. Cho cac nhan nh sau: (1). Alanin lam quy tm hoa xanh. (2). Axit Glutamic lam quy tm hoa o. (3). Lysin lam quy tm hoa xanh. (4). Axit - amino caporic la nguyen lieu e san xuat nilon 6.

CH2-COOH CH2-C6H5

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Bi tp chng 3: Amin-Aminoaxit.

Phm Huy Quang

So nhan nh ung la: A. 1 B. 2 C.3 D.4 Cau 31. Mot amino axit co cong thc phan t la C 4H9NO2. So ong phan amino axit la A. 3 B. 4 C. 5 D.6 Cau 32: 1 thuoc th co the nhan biet 3 chat hu c : axit aminoaxetic, axit propionic, etylamin la A. NaOH. B. HCl. C. Qu tm. D. CH3OH/HCl. Cau 33: Hp chat A co cong thc phan t CH 6N2O3. A tac dung c vi KOH tao ra mot baz va cac chat vo c. CTCT cua A la A. H2N COO NH3OH. B. CH3NH3+NO3-. C. HONHCOONH4. D. H2N-CHOH-NO2. Cau 34: Cho cac cau sau: (1). Peptit la hp chat c hnh thanh t 2 en 50 goc amino axit. (2). Tat ca cac peptit eu phan ng mau biure. (3). T 3 - amino axit ch co the tao ra 3 tripeptit khac nhau. (4). Khi un nong dung dch peptit vi dung dch kiem, san pham se co phan ng mau biure. So nhan xet ung la: A. 1 B. 2 C. 3 D. 4 Cau 35: Peptit co cong thc cau tao nh sau: H2N-CH-CO-NH-CH2-CO-NH-CH-COOH CH3 CH(CH3)2. Ten goi ung cua peptit tren la: A. Ala-Ala-Val. B. Ala-Gly-Val. C. Gly Ala Gly. D. Gly-Val-Ala. Cau 36: Cong thc nao sau ay cua pentapeptit (A) thoa ieu kien sau: + Thuy phan hoan toan 1 mol A th thu c cac - amino axit la: 3 mol Glyxin , 1 mol Alanin, 1 mol Valin. + Thuy phan khong hoan toan A, ngoai thu c cac amino axit th con thu c 2 i peptit: Ala-Gly ; Gly- Ala va 1 tripeptit Gly-Gly-Val. A. Ala-Gly-Gly-Gly-Val. B. Gly-Gly-Ala-Gly-Val. C. Gly-Ala-Gly-Gly-Val. D. Gly-Ala-GlyVal-Gly. Cau 37: Thuy phan khong hoan toan tetra peptit (X), ngoai cac - amino axit con thu c cac i petit: Gly-Ala; Phe-Va; Ala-Phe. Cau tao nao sau ay la ung cua X. A. Val-Phe-Gly-Ala. B. Ala-Val-Phe-Gly. C. Gly-Ala-Val-Phe D. Gly-Ala-Phe Val. Cau 38: e phan biet xa phong, ho tinh bot, long trang trng ta se dung thuoc th nao sau ay: A. Ch dung I2. B. Ch dung Cu(OH)2. C. Ket hp I2 va Cu(OH)2. D. Ket hp I2 va AgNO3/NH3. Cau 39: Cho cac cau sau: (1) Amin la loai hp chat co cha nhom NH 2 trong phan t. (2) Hai nhom chc COOH va NH2 trong amino axit tng tac vi nhau thanh ion lng cc. (3) Poli peptit la polime ma phan t gom 11 en 50 mac xch -amino axit noi vi nhau bi cac lien ket peptit. (4) Protein la polime ma phan t ch gom cac polipeptit noi vi nhau bang lien ket peptit. Co bao nhieu nhan nh ung trong cac nhan nh tren: A.1 B.2 C.3 D.4 Cau 40: Cho cac dung dch sau ay: CH 3NH2; NH2-CH2-COOH; CH3COONH4, long trang trng ( anbumin). e nhan biet ra abumin ta co the dung cach nao sau ay: A. un nong nhe. B. Cu(OH)2. C. HNO3 D. tat ca. Cau 41: Ly do nao sau ay lam cho protein b ong tu: (1) Do nhiet. ; (2). Do axit. ; (3). Do Baz. ; (4) Do Muoi cua KL nang. A. Co 1 l do tren. B. Co 2 l do tren. C. Co 3 l do tren. D. Co 4 l do tren. Cau 42: Hp chat nao sau ay khong phai la amino axit. A. H2N-CH2-COOH. B. CH 3-NH-CH2-COOH. C. CH3CH2-CO- NH2 D.HOOC-CH2(NH2)CH2COOH. Cau 43: Cho cac cong thc sau: So CTCT ng vi ten goi ung (1). H2N CH2-COOH: Glyxin (2). CH3-CHNH2-COOH : Alanin. (3). HOOC- CH2-CH2-CH(NH2)-COOH:Axit Glutamic. (4). H2N (CH2)4-CH(NH2)COOH : lysin. A. 1 B.2 C.3 D.4 Cau 43: Polipeptit (-NH-CH2-CO-)n la san pham cua phan ng trung ngng: A. axit glutamic B. glyxin. C. axit -amino propionic D. alanin. Cau 44: Hp chat H2N-CH2-COOH phan ng c vi:(1). NaOH. (2). CH3COOH. (3). C2H5OH A. (1,2) B. (2,3) C. (1,3). D. (1,2,3).

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Bi tp chng 3: Amin-Aminoaxit.

Phm Huy Quang

Cau 45: Cho cac chat sau ay: (1). Metyl axetat. (2). Amoni axetat. (3). Glyxin. (4). Metyl amoni fomiat. (5). Metyl amoni nitrat (6). Axit Glutamic. Co bao nhieu chat lng tnh trong cac chat cho tren: A.2 B.3 C.4 D.5 Cau 46: Amino axit co bao nhieu phan ng cho sau ay : phan ng vi axit, phan ng vi baz, phan ng trang bac, phan ng trung hp, phan ng trung ngng, phan ng vi ancol, phan ng vi kim loai kiem. A. 3 B.4 C.5 D.6 + NaOH + HCl Cau 47: Cho s o bien hoa sau: Alanin X Y. Chat Y la chat nao sau ay: A. CH3-CH(NH2)-COONa. B. H2N-CH2-CH2-COOH. C. CH3-CH(NH3Cl)COOH D.CH3CH(NH3Cl)COONa.

PHN II: CC DNG BI TP CHNG 3: AMIN AMINO AXIT PEPTIT PROTEIN

DNG 1: TON T CHY AMIN
* PHN NG T CHY AMIN - Amin no n chc: CnH2n+3N +

6n + 3 2n + 3 1 O2 nCO2 + H2O + N2 4 2 2

- Amin thm: CnH2n-5N +

6n 5 2n 5 1 O2 nCO2 + H2O + N2 4 2 2 y y 1 O2 xCO2 + H2O + N2 4 2 2

- Amin tng qut: CxHyNt + x +

* LU : - Khi t chy mt amin ta lun c: nO 2 phn ng = nCO2 + nH2O - Khi t chy mt amin ngoi khng kh th: nN2 sau p = nN2 sinh ra t p chy amin + nN2 c sn trong khng kh CC V D: Cu 1: t chy hon ton mt amin no, n chc, bc 1 mch h thu c t l mol CO 2 v H2O l 4:7. Tn amin l? A. Etyl amin B. imetyl amin C. Metyl amin D. Propyl amin Cu 2: t chy hon ton a mol amin no, n chc thu c 13,2g CO 2 v 8,1g H2O. Gi tr ca a l? A. 0,05 B. 0,1 C. 0,07 D. 0,2 Cu 3: t chy hon ton amin no, n chc vi t l s mol CO 2 v hi H2O l T. T nm trong khong no sau y? A. 0,5 T < 1 B. 0,4 T 1 B. 0,4 T < 1 D. 0,5 T 1 Cu 4: t chy hon ton mt ng ng X ca Anilin th t l nCO2 : nH2O = 1,4545. CTPT ca X l? A. C7H7NH2 B. C8H9NH2 C. C9H11NH2 D. C10H13NH2 Cu 5: t chy hon ton m (g) hn hp gm 3 amin thu c 3,36 (l) CO 2 (ktc); 5,4(g) H2O v 1,12 (l) N2 (ktc). Gi tr ca m l? A. 3.6 B. 3,8 C. 4 D. 3,1 Cu 6 (HKA-2007): Khi t chy hon ton mt amin n chc X, thu c 8,4 (l) CO 2, 1,4 (l) N2 (cc th tch o ktc) v 10,125g H2O. Cng thc phn t ca X l? A. C3H7N B. C2H7N C. C3H9N D. C4H9N Cu 7 (HKB 2010): t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6g X tc dng vi dung dch HCl d, s mol HCl phn ng l? A. 0,1 B. 0,4 C. 0,3 D. 0,2 Cu 8: t chy amin A vi khng kh (N2 v O2 vi t l mol 4:1) va , sau phn ng thu c 17,6g CO 2; 12,6g H2O v 69,44 lt N2 (ktc). Khi lng ca amin l? A. 9,2g B. 9g C. 11g D. 9,5g Cu 9 (HKA 2010): t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh CO2 ; N2 v hi H2O (cc th tch o cng iu kin). Amin X tc dng vi axit nitr nhit thng gii phng kh N2. Cht X l? A. CH2=CH-NH-CH3 B. CH3-CH2-NH-CH3 C. CH3-CH2-NH2 D. CH2=CH-CH2-NH2 Cu 10 (HKA 2010): Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO 2, x mol H2O v y mol N2. Cc gi tr x v y tng ng l?

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Bi tp chng 3: Amin-Aminoaxit.
A. 8 v 1,0 B. 8 v 1,5 C. 7 v 1,0

Phm Huy Quang

D. 7 v 1,5

DNG 2: AMIN TC DNG VI AXIT, MUI 1. PHN NG VI DUNG DCH AXIT Vi amin A, bc 1, c a nhm chc: R(NH2)a + aHCl R(NH3Cl)a S nhm chc amin: a =

nHCl v mmui = mamin + mHCl (LBTKL) nA

2. VI DUNG DCH MUI CA KIM LOI Mt s mui d to kt ta hidroxit vi dung dch amin. AlCl3 + 3CH3NH2 + 3H2O Al(OH)3 + 3CH3NH3Cl * Lu : tng t NH3, cc amin cng to phc cht tan vi Cu(OH)2, Zn(OH)2, AgCl... V D: Sc kh CH3NH2 ti d vo dung dch CuCl2 th hin tng xy ra? 2CH3NH2 + CuCl2 + 2H2O Cu(OH)2 + 2CH3NH3Cl Xanh nht Cu(OH)2 + 4CH3NH2 [Cu(CH3NH2)4](OH)2 Phc tan mu xanh thm CC V D

Cu 1: Cho 9,3g mt amin no, n chc, bc 1 tc dng vi dung dch FeCl3 d, thu c 10,7g kt ta. CTPT ca amin l? A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H9NH2 Cu 2: Cho 0,4 mol mt amin no, n chc tc dng vi dung dch HCl va thu c 32,6g mui. CPTP ca amin l? A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H9NH2 Cu 3(HKA 2009): Cho 10g mt amin n chc X phn ng hon ton vi HCl d, thu c 15g mui. S ng phn cu to ca X l? A. 8 B. 7 C. 5 D. 4 Cu 4 (C 2007): trung ha 25g dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. CTPT ca X l? A. C3H5N B. C2H7N C. CH5N D. C3H7N Cu 5: (HKB 2008): Mui C6H5N2+Cl- (Phenyliazoni) c sinh ra khi cho C 6H5NH2 tc dng vi NaNO2 trong HCl nhit thp (0 5 oC). iu ch c 14,05g C 6H5N2+Cl- ( H = 100%) th lng C 6H5NH2 v NaNO2 cn dng va l? A. 0,1 mol v 0,4 mol B. 0,1 mol v 0,2 mol C. 0,1 mol v 0,1 mol D. 0,1 mol v 0,3 mol Cu 6 (C 2010) : Cho 2,1g hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl d, thu c 3,925g hn hp mui. Cng thc ca 2 amin trong hn hp X l? A. CH3NH2 v C2H5NH2 B. C2H5NH2 v C3H7NH2 C. C3H7NH2 v C4H9NH2 D. CH3NH2 v (CH3)3N Cu 7 (HKB 2010) : Trung ha hon ton 8,88g mt amin bc 1, mch cc bon khng phn nhnh bng axit HCl to ra 17,64g mui. Amin c cng thc l? A. H2N(CH2)4NH2 B. CH3CH2CH2NH2 C. H2NHCH2CH2NH2 D. H2NCH2CH2CH2NH2 Cu 8: Hn hp X gm 2 mui AlCl 3 v CuCl2. Ha tan hn hp X vo nc thu c 200ml dung dch A. Sc kh metyl amin ti d vo dung dch A thu c 11,7g kt ta. Mt khc, cho t t dd NaOH ti d vo dung dch A thu c 9,8g kt ta. Nng mol/l ca AlCl3 v CuCl2 trong dd A ln lt l? A. 0,1M v 0,75M B. 0,5M v 0,75M C. 0,75M v 0,5M D. 0,75M v 0,1M Cu 9: Cho 20g hn hp 3 amin no n chc l ng ng k tip c t l mol tng ng l 1 : 10 : 5, tc dng va vi dung dch HCl thu c 31,68g hn hp mui. CTPT ca amin nh nht l? A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D.C4H9NH2 DNG 3: GII TON AMINOAXIT - Cng thc chung ca amino axit: (H2N)a R (COOH)b - Da vo phn ng trung ho vi dung dch kim xc nh b PTPU: (H2N)a R (COOH)b +bNaOH (H2N)a R (COONa)b + bH2O

nNaOH = b = s nhm chc axit COOH na min

- Da vo phn ng vi dd axit xc nh a PTPT: (H2N)a R (COOH)b + aHCl (ClH3N)a R (COOH)b

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Bi tp chng 3: Amin-Aminoaxit. nHCl = a = s nhm chc bazo NH2 na min

Phm Huy Quang

CC V D: Cu 1: Cho 0,1 mol -aminoaxit phn ng va vi 200ml dung dch HCl 0,5M thu c dung dch A. Cho dung dch NaOH 0,5M vo dung dch A th thy cn va ht 600ml. S nhm NH 2 v COOH ca axitamin ln lt l? A. 1 v 1 B. 1 v 3 C. 1 v 2 D. 2 v 1 Cu 2: Cho 0,01 mol amino axit A tc dng va vi 80ml dung dch HCl 0,125M. C cn dung dch c 1,835g mui. Khi lng phn t ca A l? A. 97 B. 120 C. 147 D. 157 Cu 3 (C 2008): Trong phn t amino axit X c mt nhm amino v mt nhm cacboxyl. Cho 15g X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4g mui khan. Cng thc ca X l? A. H2NC3H6COOH B. H2NCH2COOH C. H2NC2H4COOH D. H2NC4H8COOH Cu 4 (HKB 2009): Cho 0,02 mol amino axit X tc dng va vi 200ml dung dch HCl 0,1M thu c 3,67g mui khan. Mt khc, 0,02 mol X tc dng va vi 40g dung dch NaOH 4%. Cng thc ca X l? A. (H2N)2C3H5COOH B. H2NC2H3(COOH)2 C. H2NC3H6COOH D. H2NC3H5(COOH)2 Cu 5: Hp cht Y l mt aminoaxit. Cho 0,02 mol Y tc dng va vi 80ml dd HCl 0,25M. Sau c cn c 3,67g mui. Mt khc, trung ha 1,47g Y bng mt lng va dung dch NaOH,c cn dung dch thu c 1,91g mui. Bit Y c cu to mch khng nhnh. CTCT ca Y l ? A. H2NCH2CH2COOH B. CH3CH(NH2)COOH C. HOOCCH2CH2CH(NH2)COOH D. HOOCCH2CH(NH2)COOH Cu 6: Cho 0,2 mol amino axit X phn ng va vi 100ml dd HCl 2M thu c dung dch A. Cho dung dch A phn ng va vi dd NaOH, sau phn ng, c cn sn phm thu c 33,9g mui. X c tn gi l? A. Glyxin B. Alanin C. Valin D. Axit glutamic Cu 7 (HKA 2009): Cho 1 mol amino axit X phn ng vi dung dch HCl d thu c m 1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH d, thu c m2 gam mui Z. Bit m2 m1 = 7,5. Cng thc phn t ca x l? A. C4H10O2N2 B. C5H9O4N C. C4H8O4N2 D. C5H11O2N Cu 8 (HKB 2010): Hn hp X gm Alanin v axit glutamic. Cho m g X tc dng hon ton vi dd NaOH d, thu c dd Y cha ( m + 30,8) g mui. Mt khc, nu cho m g X tc dng hon ton vi dung dch HCl, thu c dd Z cha ( m + 36,5)g mui. Gi tr ca m l? A. 112,2 B. 165,6 C. 123,8 D. 171,0 Cu 9 (HKA 2010): Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175ml dd HCl 2M thu c dd X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l? A. 0,50 B. 0,65 C. 0,70 D. 0,55 Cu 10: X l mt amino axit c cng thc tng qut dng H 2N R COOH. Cho 8,9g X tc dng vi 200ml dung dch HCl 1M , thu c dung dch Y. phn ng vi ht vi cc cht trong dd Y cn dng 300ml dd NaOH 1M. Cng thc cu to ng ca X l ? A. H2N-CH2-COOH B. H2N-CH2-CH2-COOH C. CH3CH(NH2)COOH D. CH3CH2CH(NH2)COOH DANG 4: GII TON MUI AMONI, ESTE CA AMINO AXIT - Cng thc chung ca mui amoni: H2N R COONH4 hoc H2N R COOH3NR - Cng thc chung este ca amino axit: H2N R COOR - Mui amoni, este ca amino axit l hp cht lng tnh: H2N R COONH3R + HCl ClH3N R COONH3R H2N R COONH3R + NaOH H2N R COONa + RNH2 + H2O * CH : Thng s dng nh lut bo ton khi lng gii cc bi ton dng ny. CC V D: Cu 1 (C-2010): ng vi CTPT C2H7O2N c bao nhiu cht va phn ng c vi dung dch NaOH va phn ng c vi HCl? A. 2 B. 3 C. 1 D. 4 Cu 2 (C-2009): Cht X c CTPT C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. Axit -aminopropionic B. Mety aminoaxetat C. Axit -aminopropionic D. Amoni acrylat Cu 3: Cho 2 hp cht hu c X, Y c cng cng thc phn t l C 3H7NO2. Khi phn ng vi NaOH, X to ra H2NCH2COONa v hp cht hu c Z; cn Y to ra CH2=CH COONa v kh T. Cc cht Z v T ln lt l A. CH3OH v CH3NH2 B. C2H5OH v N2 C. CH3OH v NH3 D. CH3NH2 v NH3 Cu 4 (C-2009): Cht X c CTPT C4H9O2N. Bit:

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Bi tp chng 3: Amin-Aminoaxit.

Phm Huy Quang

X + NaOH Y + CH4O Y + HCl (d) Z + NaOH CTCT ca X v Z ln lt l: A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH C. H2NCH2COOC2H5 v ClH3NCH2COOH D. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH Cu 5 (HKA- 2009): Hp cht X mch h c CTPT C4H9NO2. Cho 10,3 g X phn ng va vi dung dch NaOH sinh ra mt kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l: A. 8,2 B. 10,8 C. 9,4 D. 9,6 Cu 6 (HKB-2009): Este X (c KLPT=103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi >1) v mt amino axit. Cho 25,75 g X phn ng ht vi 300ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr ca m l A. 29,75 B. 27,75 C. 26,25 D. 24,25 Cu 7 (C-2009): Cho 1,82 gam hp cht hu c n chc, mch h X c CTPT C 3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. CTCT thu gn ca X l A. CH3CH2COONH4 B. CH3COONH3CH3 c. HCOONH2(CH3)2 D. HCOONH3CH2CH3 Cu 8 (HKA-2007): Cho hn hp X gm 2 cht hu c c cng CTPT C 2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48l hn hp Z (kc) gm 2 kh (u lm xanh giy qu m). t khi hi ca Z i vi H2 = 13,75. c cn dung dch Y thu c khi lng mui khan l A. 16,5 gam B. 14,3 gam C. 8,9 gam D. 15,7 gam Cu 9 (CKA,B-2007): Hp cht X c CTPT trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73% cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. CTCT thu gn ca X l: A. CH2=CHCOONH4 B. H2N-COOCH2-CH3 C. H2N-CH2-COOCH3 D. H2NC2H4COOH Cu 10 (HKB-2008): Cho cht hu c X c CTPT C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l: A. 85 B. 68 C. 45 D. 46 - Peptit c cu to t cc gc -aminoaxit - T n phn t -aminoaxit khc nhau th c n! ng phn peptit (s peptit cha cc gc -aminoaxit khc nhau) - T n phn t -aminoaxit khc nhau th c n2 s peptit c to thnh - Phn ng thy phn khng hon ton peptit cho sn phm c th l -aminoaxit, hoc ipeptit, hoc tripeptit ... - Phn ng thy phn hon ton peptit cho sn phm l cc gc -aminoaxit.
CC V D: Cu 1 (HKB-2009): S ipeptit ti a c th to ra t 1 hn hp gm alanin v glyxin l: A. 2 B. 3 C. 4 D. 1 Cu 2 (HKA-2010): C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin? A. 3 B.9 C. 4 D. 6 Cu 3(HKA-2009): Thuc th c dng phn bit gly-ala-gly vi gly-ala l: A. Cu(OH)2 trong mi trng kim B. Dung dch NaCl C. Dung dch HCl D. Dung dch NaOH Cu 4 (HKB-2008): un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl d, sau khi cc phn ng kt thc thu c sn phm l: A. H2N-CH2-COOH, H2N-CH2-CH2-COOH B. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl+ + C. H3N -CH2-COOHCl , H3N -CH(CH3)-COOHCl D. H2N-CH2-COOH, H2N-CH(CH3)-COOH Cu 5 (C-2010): Nu thy phn khng hon ton pentapeptit gly-ala-gly-ala-gly th thu c ti a bao nhiu ipeptit khc nhau? A. 3 B. 1 C. 2 D. 4 Cu 6 (HKB-2010): Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (gly), 1 mol alanin (ala), 1mol valin (val) v 1 mol phenylalanin (phe). Thy phn khng hon ton X thu c ipeptit val-phe v tripeptit gly-ala-val nhng khng thu c ipptit gly-gly. Cht X c cng thc l: A. gly-phe-gly-ala-val B. gly- ala-val- val-phe C. gly- ala-val-phe-gly D. val-phe-gly-ala-gly Cu 7(C-2009): Thy phn 1250gam protein X thu c 425gam alanin. Nu phn t khi ca X bng 100000 vC th s mt xch alanin c trong phn t X l A. 453 B. 382 C. 328 D. 479

DNG 5: BI TON PROTEIN PEPTIT

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Bi tp chng 3: Amin-Aminoaxit.

Phm Huy Quang

Cu 8 (HKB-2010): ipeptit mch h X v tripeptit mch h Y u c to nn t 1 aminoaxit (no, mch h, trong phn t cha 1 nhm NH2 v 1 nhm COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr m l: A. 120 B. 60 C. 30 D. 45

BI TP TNG HP
Cu 47 : Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 8,15 gam B. 0,85 gam C. 7,65 gam D. 8,10 gam Cau 48 : The tch nc brom 3% (d = 1,3g/ml) can dung e ieu che 4,4g tribormanilin la A. 164,1ml. B. 49,23ml. C 146,1ml. D. 16,41ml. Cau 49 : Khoi lng anilin can dung e tac dung vi nc brom thu c 6,6g ket tua trang la A. 1,86g. B. 18,6g. C. 8,61g. D. 6,81g. Cu 50 : Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. X c th l : A. axit glutamic. B. valin. C. glixin D. alanin. Cau 51 : 1 mol -aminoaxit X tac dung va het vi 1 mol HCl tao ra muoi Y co ham lng clo la 28,287%. CTCT cua X la A. CH3 CH(NH2) COOH. B. H2N CH2 CH2 COOH. C. NH2 CH2 COOH. D. H2N CH2 CH(NH2) COOH. Cau 52 : Khi trung ngng 13,1g axit -aminocaproic vi hieu suat 80%, ngoai aminoaxit con d ngi ta thu c m gam polime va 1,44g nc. Gia tr m la A. 10,41g. B. 9,04g. C. 11,02g. D. 8,43g. Cau 53 : Mot amin n chc cha 19,718% nit ve khoi lng. CTPT cua amin la A. C4H5N. B. C4H7N. C. C4H9N. D. C4H11N. Cau 54 : ot chay hoan toan mot amin no n chc thu c V H2O = 1,5VCO2. CTPT cua amin la A. C2H7N. B. C3H9N. C. C4H11N. D. C5H13N. Cau 55 : Cho 3,04g hon hp A gom 2 amin no n chc tac dung va u vi 400ml dd HCl 0,2M c 5,96g muoi. Tm the tch N2 (ktc) sinh ra khi ot het hon hp A tren ? A. 0,224 lt. B. 0,448 lt. C. 0,672 lt. D. 0,896 lt. Cau 56 : Cho 17,7g mot ankylamin tac dung vi dd FeCl3 d thu c 10,7g ket tua. CTPT cua ankylamin la A. C2H7N. B. C3H9N. C. C4H11N. D. CH5N. Cu 57. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit? A. 100ml B. 50ml C. 200ml D. 320ml Cau 58 : Cho 0,01 mol aminoaxit X tac dung va u vi 80ml dd HCl 0,125M, sau o co can dd thu c 1,835g muoi. Phan t khoi cua X la A. 174. B. 147. C. 197. D. 187 Cu 59. Cho 10 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 15,84 gam hn hp mui. Nu trn 3 amin trn theo t l mol 1 : 10 : 5 theo th t phn t khi tng dn th cng thc phn t ca 3 amin l p n no sau y? A. CH5N, C2H7N, C3H7NH2 B. C2H7N, C3H9N, C4H11N C. C3H9N, C4H11N, C5H11N D. C3H7N, C4H9N, C5H11N Cu 60. t chy hon ton 6,2 gam mt amin no, n chc phi dng ht 10,08 lt kh oxi (ktc). Cng thc ca amin l cng thc no sau y? A. C2H5NH2 B. CH3NH2 C. C4H9NH2 D. C3H7NH2 Cu 61. Hp cht hu c to bi cc nguyn t C, H, N l cht lng, khng mu, rt c, t tan trong nc, d tc dng vi cc axit HCl, HNO 2 v c th tc dng vi nc brom to kt ta. Hp cht o c cng thc phn t nh th no? A. C2H7N B. C6H13N C. C6H7N D. C4H12N2 Cu 62. t chy hon ton 100ml hn hp gm imetylamin v hai hirocacbon ng ng k tip thu c 140ml CO 2 v 250ml hi nc (cc th tch o cng iu kin). Cng thc phn t ca hai hirocacbon l p n no? A. C2H4 v C3H6 B. C2H2 v C3H4 C. CH4 v C2H6 D. C2H6 v C3H8 Cu 63. Trung ha 3,1 gam mt amin n chc X cn 100ml dung dch HCl 1M. Cng thc phn t ca X l p n no? A. C2H5N B. CH5N C. C3H9N D. C3H7N Cu 64. t chy hon ton hn hp hai amin no n chc ng ng lin tip, ta thu c hn hp sn phm kh vi t l nCO2: nH 2O = 8 : 17. Cng thc ca hai amin l p n no? A. C2H5NH2, C3H7NH2 B. C3H7NH2, C4H9NH2 C. CH3NH2, C2H5NH2 D. C4H9NH2, C5H11NH2 Cu 65. t chy hon ton mt amin n chc cha no c mt lin kt i mch cacbon ta thu c CO 2 v H2O theo t l mol = 8:9. Vy cng thc phn t ca amin l cng thc no? A. C3H6N B. C4H9N C. C4H8N D. C3H7N Cu 66. Cho 1,52 gam hn hp hai amin no n chc (c trn vi s mol bng nhau) tc dng va vi 200ml dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc. A. Nng mol ca dung dch HCl bng 0,2M. B. S mol ca mi cht l 0,02mol C. Cng thc thc ca hai amin l CH5N v C2H7N D. Tn gi hai amin l metylamin v etylamin Cu 67. Ngi ta iu ch anilin bng cch nitro ha 500g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu, bit hiu sut mi giai on 78%? A. 346,7gam B. 362,7gam C. 463,4gam D. 358,7 gam Cu 68. Cho lng d anilin phn ng hon ton vi dung dch cha 0,05mol H2SO4 long. Khi lng mui thu c bng bao nhiu gam? A. 7,1gam B. 14,2gam C. 19,1gam D. 28,4 gam Cu 69. Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng vi vi 0,075 mol Br2 to kt ta. Lng cc cht NH3, C6H5NH2 v C6H5OH ln lt bng bao nhiu? A. 0,01 mol; 0,005mol v 0,02mol B. 0,005 mol; 0,005mol v 0,02mol C. 0,05 mol; 0,002mol v 0,05mol. D. 0,01 mol; 0,005mol v 0,02mol Cu 70. t chy hon ton 100ml hn hp gm imetylamin v 2 hirocacbon ng ng k tip thu c 140ml CO2 v 250ml hi nc (cc th tch o cng iu kin). Thnh phn % th tch ca ba cht trong hn hp theo tng phn t khi ln lt bng bao nhiu? A. 20%; 20% v 60% B. 25%; 25% v 50% C. 30%; 30% v 40% D. 60%; 20% v 20% Cu 71. Este X c iu ch t aminoaxit v ru etylic. T khi hi ca X so vi hiro 51,5 . t chy hon ton 10,3 gam X thu c 17,6gam kh CO 2, 8,1gam nc v 1,12 lt nit (ktc). Cng thc cu to thu gn ca X l cng thc no sau y? A. H2N- CH2 - COO-C2H5. B. H2N- CH(CH3) - COO- C. H2N- CH2 CH(CH3) - COOH D. H2N-CH2 -COO-CH3 Cu 72. X l mt aminoaxit no ch cha 1 nhm - NH 2 v 1 nhm COOH. Cho 0,89 gam X tc dng vi HCl va to r a 1,255 gam mui. Cng thc cu to ca X l cng thc no sau y? A. H2N- CH2-COOH B. CH3- CH(NH2)-COOH. C. CH3-CH(NH2)-CH2-COOH. D. C3H7-CH(NH2)-COOH Cu 73. X l mt - amioaxit no ch cha 1 nhm -NH 2 v 1 nhm -COOH. Cho 15,1 gam X tc dng vi HCl d thu c 18,75 gam mui. Cng thc cu to ca X l cng thc no? A. C6H5- CH(NH2)-COOH B. CH3- CH(NH2)-COO C. CH3-CH(NH2)-CH2-COOH D. C3H7CH(NH2)CH2COOH

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Bi tp chng 3: Amin-Aminoaxit.

Phm Huy Quang

Cu 74. X l mt - amioaxit no ch cha 1 nhm -NH2 v 1 nhm -COOH. Cho 23 gam X tc dng vi HCl d thu c 30,3 gam mui. Cng thc cu to thu gn ca X l cng thc no? A. CH3-CH(NH2)-COOH B. H2N-CH2-COOH C. H2N-CH2CH2 -COOH D.CH2=C(CH3)CH(NH2)COOH Cu 75. Cht A c % khi lng cc nguyn t C, H, O, N ln lt l 32%, 6,67% 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng NaOH va tc dng dd HCl, A c cng thc cu to nh th no? A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cu 76 Cht A c thnh phn % cc nguyn t C, H, N ln lt l 40,45%, 7,86%, 15,73% cn li l oxi. Khi lng mol phn t ca A <100 g/mol. A tc dng c vi NaOH v vi HCl, c ngun gc t thin nhin, A c CTCT nh th no. A. CH3-CH(NH2)-COOH B. H2N-(CH2)2-COOH C. H2N-CH2-COOH D. H2N-(CH2)3-COOH Cau 77 : Este A c ieu che t aminoaxit B (ch cha C, H, O, N) va ancol metylic. T khoi hi cua A so vi H 2 la 44,5. CTCT cua A la A. H2N CH2 CH2 COOCH3. B. H2N CH2 COOCH3. C. H2N CH2 CH(NH2) COOCH3. D. CH3 CH(NH2) COOCH3. Cau 78 : DD X gom HCl va H 2SO4 co pH=2. e trung hoa hoan toan 0,58g hon hp 2 amin no n chc bac 1 (co so ngt C nho hn hoac bang 4) phai dung 1 lt dd X. Cong thc cua 2 amin co the la A. CH3NH2 va C4H9NH2. B. C2H5NH2 va C4H9NH2. C. C3H7NH2 va C4H9NH2. D. Ca A va B. Cau 79: ot chay hoan toan ong ang X cua axit aminoaxetic, thu c t le so mol CO 2 : H2O la 6 : 7. Cac CTCT co the co cua X la A. CH3CH(NH2)COOH ; H2NCH2CH2COOH. B. CH3CH2CH(NH2)COOH ; H2NCH2CH2CH2COOH. C. CH3CH2CH2CH(NH2)COOH ; H2N[CH2]4COOH. D. CH3[CH2]3CH(NH2)COOH ; H2N[CH2]5COOH. Cau 80 : ot chay hoan toan a mol aminoaxit A thu c 2a mol CO 2 va a/2 mol N2. Aminoaxit A la A. H2NCH2COOH. B. H2N[CH2]2COOH. C. H2N[CH2]3COOH. D. H2NCH(COOH)2.

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