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B. ha i cng v v c
Phn 1:nguyn t, bng htth, lin kt ho hc ( 2 3 cu )
Cu 1: Trong t nhin ng v 37Cl chim 24,23% s nguyn t clo. Nguyn t khi trung bnh ca clo bng 35,5. Thnh phn phn trm v khi lng ca 37Cl c trong HClO4 (vi hidro l ng v 1H,oxi l ng v 16O) l: A. 8,92%. B. 8,56%. C.9,82%. D. 8,65%. Cu 2: Hai nguyn t A, B hai nhm A lin tip trong bng tun hon. A thuc nhm VA, trng thi n cht A khng tc dng vi B. Tng s proton trong ht nhn A v B bng 23. A, B l: A. O v P. B. F v P. C. N v S. D. Na v Mg. Cu 3: X, Y, Z l cc nguyn t thuc cng chu k ca bng tun hon. Oxit ca X tan trong nc to thnh dung dch lm hng qu xanh, Y phn ng vi nc to dung dch lm xanh qu tm, oxit ca Z tc dng c vi c axit v kim. S hiu nguyn t ca cc nguyn t gim theo trt t: A. X > Y> Z . B. X > Z > Y. C. Z > Y > X . D. Y > X > Z. Cu 4: Cc cht trong dy no sau y c xp theo th t tnh axit tng dn? A. NaOH, Al(OH)3, Mg(OH)2, H2SiO3. B. H2SiO3, Al(OH)3, H3PO4, H2SO4. C. Al(OH)3, H2SiO3, H3PO4, H2SO4. D. H2SiO3, Al(OH)3, Mg(OH)2, H2SO4. Cu 5: Dy gm cc phn t c cng mt kiu lin kt: A. Cl2, Br2, I2, HCl. B. HCl. H2S, NaCl, N2O. C. Na2O, KCl, BaCl2, Al2O3. D. MgO, H2SO4, H3PO4, HCl Cu 6 : Dy sp xp cc cht theo chiu tnh baz tng dn : A. NaOH, Mg(OH)2, Al(OH)3, Si(OH)4. B. Si(OH)4, Al(OH)3, NaOH, Mg(OH)2. C. Mg(OH)2, NaOH, Si(OH)4, Al(OH)3. D. Si(OH)4, Al(OH)3, Mg(OH)2, NaOH. Cu 7 : Dy sp xp cc cht theo chiu tnh axit tng dn : A. H4SiO4, H3PO4, H2SO4, HClO4. B. H2SO4, H3PO4, HClO4, H4SiO4. C. HClO4, H2SO4, H3PO4, H4SiO4. D. H3PO4, HClO4, H4SiO4, H2SO4. Cu 8: Trong hp cht XY ( X l kim loi v Y l phi kim), s electron ca cation bng s electron ca anion v tng s electron trong hp cht l 20. Bit trong mi hp cht Y ch c mt mc OXH duy nht. Cng thc XY l: A. MgO B. AlN. C. NaF D. LiF 3+ 2 6 5 Cu 9: Cho ion M c cu hnh electron [Ne]3S 3p 3d . Nguyn t M thuc A. Nhm VB B. Nhm IIIA C. Nhm VIIIB D. Nhm II 2 + 2+ Cu 10 :X , Y , Z v T l cc ion c cu hnh electron ging cu hnh electron ca Ar. Kt lun no di y l ng 2 + 2+ A. Bn knh ca cc ion X , Y , Z v T l bng nhau. B. Bn knh nguyn t tng dn theo trt t RY < RX < RT < RZ. C. Hydroxit tng ng vi ha tr cao nht ca X c lc axit mnh hn ca Y. D. Hydroxit tng ng vi ha tr cao nht ca T c lc baz mnh hn ca Z. Bin son GV Phm Tun Mobile: 1 0975737845

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Cu 11: Gi thit trong tinh th cc nguyn t st l nhng hnh cu chim 74% th tch tinh th, phn cn li l cc khe rng gia cc qu cu, cho nguyn t khi ca Fe l 55,85 20 0C khi lng ring ca Fe l 7,87g/cm3. Bn knh nguyn t gn ng ca Fe l: A. 1,67 A0. B. 1,28 A0. C. 1,97 A0. D. 1,41A0. Cu 12: Dy gm cc cht trong phn t ch cha mt loi lin kt l A. HF, HClO, KF, H2O. B. NaF, Na2O, CaCl2, KBr. C. NaF, NaCl, NaNO3, KI. D. HF, H2S, HCl, Cu 13: Cu hnh electron cc nguyn t ca cc nguyn t X, Y, Z, T ln lt l : [Ne]3s 23p5; [Ar]3d104s24p4; [He]2s22p5; [Ne]3s23p4. Th t tng dn tnh phi kim ca cc nguyn t tng dn t tri sang phi l : A. Y, T, Z, X B. T, Y, X, Z C. Y , X, T, Z Cu 14. : Dy no sau y xp theo chiu tng dn bn knh ca cc ion? A. Al3+ ; Mg2+; Na+ ; F ; O2. B. Na+; O2; Al3+ ; F; Mg2+. C. O2; F; Na+; Mg2+; Al3+.
Cu 15: Tong so hat proton, ntron, electron trong hai nguyen t X va Y la 92, trong o tong so hat mang ien nhieu hn tong so hat khong mang ien la 28. So hat mang ien cua Y nhieu hn cua X la 8. V tr cua X va Y trong bang tuan hoan cac nguyen to hoa hoc la A. X nam o th 13, chu ky 3 nhom IA; Y nam o th 17 chu ky 3 nhom VIIA. B. X nam o th 13, chu ky 3 nhom IIIA; Y nam o th 17 chu ky 3 nhom VIIA. C. X nam o th 12, chu ky 3 nhom IIA; Y nam o th 17 chu ky 3 nhom VA. D. X nam o th 12, chu ky 3 nhom IIIA; Y nam o th 16 chu ky 3 nhom IVA

Phn 2: phn ng oxihoa khu, tc phn ng ( 2 3 cu )

Cu 1: Cho cc phn ng: 1) SO2 + H2S 2) Na2S2O3 + H2SO4 4) H2S + Cl2 7)Mg + CO2 5) H2O2 + KNO2 8) KClO3 + HCl () 3) HI + FeCl3 6) O3 + Ag 9) NH3 + CuO

S pn ng to ra n cht l: A.6 B.7 C.8 D.9 Cu 2: Cho cc phn ng sau: (1) FeO + 2HNO3 Fe(NO3)2 + H2O (2) 2Fe + 3I2 2FeI3 (3) AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag (4) 2FeCl3 + 3Na2CO3 Fe2(CO3)3 + 6NaCl (5) Zn + 2FeCl3 ZnCl2 + 2FeCl2 (6) 3Fe(d) + 8HNO3l 3Fe(NO3)2 + 2NO + 4H2O (7) NaHCO3 + Ca(OH)2 (d) CaCO3 + NaOH + H2O Nhng phn ng ng l: A. (2), (3), (5), (6), (7). B. (1), (2), (4), (5), (6). C. (2), (4), (5), (7). D. (3), (5), (6), (7). Cu 3: Cho tng cht Mg, FeO, Fe(OH)2, Ca(OH)2, Fe3O4, Al2O3, FeCl2, FeSO4, Fe2(SO4)3, Mg(HCO3)2, Cu2S, FeS2 ln lt phn ng vi dung dch HNO3 c nng. S phn ng thuc loi phn ng oxi ha - kh l: A. 10. B. 9. C. 8. D. 11. Bin son GV Phm Tun 0975737845 Mobile: 2

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Cu 4: Cho dy cc cht v ion: Fe, Cl2, SO2, NO, C, Al3+, Mg2+ Na+, Fe2+, Fe3+. S cht v ion va c tnh oxi ho, va c tnh kh l A. 4. B. 6. C. 8. D. 5. Cu 5; Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2 + KOH + H2O. Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l A. 24. B. 34. C. 27. D. 31 Cu 6. Cho hn hp Na, Al, Fe, FeCO3, Fe3O4 tc dng vi dd NaOH d, lc ly kt ta ri chia lm 2 phn. Phn 1 em tc dng vi dd HNO3 long d. Phn 2 em tc dng vi dd HCl d. S phn ng oxi ha- kh xy ra l A. 8 B. 7 C. 6 D. 5 Cu 7: Trong bnh kn dung tch 2 lt, ngi ta cho vo 11,2 gam kh CO v 10,8 gam hi nc. Phn ng xy ra l:CO + H2O CO2 + H2. 850oC hng s cn bng ca phn ng trn K = 1, nng mol/l ca CO v H2O trng thi cn bng l A. 0.08 M v 0,18M B. 0,2M v 0,3M C. 0,08M v 0,2M D. 0,12M v 0,12M o Cu 8: Khi nhit phn ng tng thm 10 C, tc phn ng tng ln 2 ln. Tc phn ng s tng ln bao nhiu ln khi nng nhit t 25oC ln 75oC ? A. 10 ln B. 16 ln C. 32 ln D. 60 ln 0 Cu 9: Cho phn ng N2(k) + 3H2(k) 2NH3(k) H = -92kJ ( 450 C, 300 atm). cn bng chuyn dch theo chiu nghch, cn A. Tng nhit v gim p sut B. Tng nhit v tng p sut C. Gim nhit v tng p sut D. gim nhit v gim p sut Cu 10: Pht biu lin quan trng thi cn bng ha hc no di y l khng ng? A. trng thi cn bng ha hc cc phn ng thun v nghch vn tip tc xy ra vi vn tc bng nhau. B. trng thi cn bng nng cc cht tham gia phn ng v nng cc cht sn phm u khng i. C. S thay i yu t nhit , nng hoc p sut c th ph v trng thi cn bng ha hc v to ra s chuyn di cn bng. D. T l gia nng cn bng cc cht sn phm v cc cht tham gia (u c s m bng h s t lng) l khng i mi nhit . Cu 11: Xt phn ng : 2SO3 (k) 2SO2 (k) + O2 (k). Trong bnh nh mc 1,00 L, ban u cha 0,777 mol SO 3 (k) ti 1100 K. Ti cn bng c 0,520 mol SO3. Hng s cn bng ca phn ng ny bng: A. 0,0314. B. 0,0635. C. 31,847. D. 0,0628.

Phn 3: in li ( 2 3 cu )
Cu 1: C 500 ml dung dch X cha Na +, NH4+, CO32- v SO42-. Ly 100 ml dung dch X tc dng vi lng d dung dch HCl thu c 2,24 lt kh. Ly 100 ml dd X cho tc dng vi lng d dung dch BaCl 2 thu c 43 gam kt ta. Ly 200 ml dung dch X tc dng vi lng d dung dch NaOH thu c 8,96 lt kh NH3. Cc phn ng hon ton, cc th tch kh u o ktc. Tnh tng khi lng mui c trong 300 ml dung dch X ? A. 23,8 gam. B. 86,2 gam. C. 71,4 gam. D. 119 Cu 2: Dy gm cc cht, ion ch c tnh baz: A. HI, S2-, PO43-, NaOH B. HCO3-, NH3 , NaOH, H2O C. CH3COO-, S2-, NH3, PO43D. HSO 4- , NH4+ , HCO3-, HI Cu 3: Dy gm cc cht no sau y u c tnh lng tnh ? Bin son GV Phm Tun 0975737845 Mobile: 3

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A. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO, H2NCH2COOH, CrO3 B. H2O, Zn(OH)2, HOOC-COONa, H2NCH2COOH, NaHCO3 C. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH, Al2O3 D. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2 Cu 4 : Dung dch X cha 0,025 mol CO 32- ; 0,1 mol Na+ ; 0,25 mol NH4+ v 0,3 mol Cl- . Cho 270ml dung dch Ba(OH)2 0,2M vo v un nng nh (gi s H 2O bay hi khng ng k). Tng khi lng dung dch X v dung dch Ba(OH)2 sau qu trnh phn ng gim i l : A. 4,215 gam. B. 5,296 gam. C. 6,761 gam. D. 7,015 gam Cu 5 : Trn 100ml dung dch A (gm KHCO 3 1M v K2CO3 1M ) vo 100ml dung dch B (gm NaHCO3 1M v Na2CO3 1M ) thu c dung dch C. Nh t t 100ml dung dch D (gm H 2SO4 1M v HCl 1M ) vo dung dch C thu c V lt CO2 (ktc) v dung dch E. Cho dung dch Ba(OH)2 ti d vo dung dch E th thu c m gam kt ta. Gi tr ca m v V ln lt l A. 82,4 gam v 2,24 lt. C. 43 gam v 2,24 lt. B. 4,3 gam v 1,12 lt. D. 3,4 gam v 5,6 lt.

Cu 6 Hn hp gm Na v Ba ha tan vo V lt H2O c dung dch A c pH = 12. Ha tan hn hp gm Al v Fe trong 1,2 lt dung dch B gm HCl v H 2SO4 long thot ra 1344 ml kh H2 ( ktc). Hi phi trn nhiu lt dung dch A v 600 ml dung dch B to c dung dch C. V dung dch C ny c kh nng ha tan c ti a 0,51 gam Al2O3. A. 3 lt hay 5 lt B. 7 lt hay 5 lt C. 12 lt hoc 3 lt D. 7 lt hoc 3 lt.

phn 4: kim loi ( 6 8 cu )

Cu 1: Cho 14,4 gam hn hp Fe, Mg v Cu ( s mol mi kim loi bng nhau) tc dng ht vi dung dch HNO 3 ( ly d 10% so vi lng phn ng) thu c dung dch X v 2,688 lt hn hp 4 kh N 2, NO, NO2, N2O trong 2 kh N2 v NO2 c s mol bng nhau. C cn cn thn dung dch X thu c 58,8 gam mui khan.Tnh s mol HNO3 ban u dng? A. 0,893 B. 0,804 C. 0,4215 D. 0,9823 Cu 2: Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng d dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 8,98 gam mui khan. Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3 oxit th th tch kh O2 (ktc) phn ng l A. 1,008 lt. B. 0,672 lt. C. 2,016 lt. D. 1,344 lt. Cu 3:Cho hn hp bt A gm Fe v Cu vo 500 ml dung dch B gm HNO3 1M v H2SO4 0,5M sau khi phn ng xy ra hon ton thu c dung dch C, cht rn D v kh NO bay ra. Cho D vo dung dch HCl thy c kh bay ra. C cn dung dch C thu c m gam cht rn khan. m c gi tr l A. 62,5 B. 49,8 C. 60,5 D. 44,2 Cu 4: Hn hp A gm Al v Zn. Ha tan hon ton 22,2 gam hn hp A vo dung dch HCl d thu c 10,08 lt kh ( ktc). Mt khc, nu em ha tan 22,2 gam hn hp A trn vo dung dch HNO3 long d thy thot 2,24 lt kh X (ktc) v tng khi lng mui trong dung dch thu c l 79 gam. Kh X l: A. N2O. B. NO. C. N2. D. NO2. Cu 5: Ha tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688 lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4 c t l mol tng ng l 4 : 1. Trung ho dung dch X bi dung Bin son GV Phm Tun 0975737845 Mobile: 4

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dch Y, tng khi lng cc mui c to ra l: A. 13,70 gam. B. 12,78 gam. C. 14,62 gam. D. 18,46 gam Cu 6: em ha tan hon ton m gam Mg trong dd cha ng thi a mol H2SO4 v b mol HCl, sau p hon ton thu c dd cha 2 mui c tng khi lng l 4,1667m. Thit lp biu thc lin h gia s mol ca 2 axit: A. b= 8a B. b= 4a C. b= 7a D. b= 6a Cu 7: Ha tan hon ton 19,2 gam hh X gm Fe, FeO, Fe3O4 v Fe2O3 trong 400 ml dd HNO3 3M (d) un nng, thu c dd Y v V lt kh NO (ktc). NO l sn phm kh duy nht ca NO3-. Cho 350 ml dd NaOH 2M vo dd Y thu c 21,4 gam kt ta. Gi tr ca V l: A. 3,36 lt. B. 5,04 lt. C. 5,60 lt. D. 4,48 lt. Cu 8: Ho tan Fe3O4 trong lng d dung dch H2SO4 long thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al, H2S? A. 8 B. 5 C. 7 D. 6 Cu 9: Nung hn hp gm 11,2g Fe; 6,4g Cu v 26g Zn vi mt lng d lu hunh n hon ton. Sn phm ca phn ng tc dng vi dung dich HCl d thu c kh X. Tnh th tch dung dch CuSO 4 10% (d = 1,1g/ml) ti thiu cn dng hp th ht kh X? A. 872,73ml B. 750,25ml C. 525,25ml D. 1018,18ml Cu 10: Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H 2SO4 0,1M. Sau khi cc phn ng xy ra hon ton thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot ra. Thm tip vo bnh 0,425 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dd l A. 0,224 lt v 3,750 gam. B. 0,112 lt v 3,750 gam. Cu 11: Mt hn hp X gm Na, Al v Fe (vi t l mol Na v Al tng ng l 5:4) tc dng vi H 2O d th thu c V lt kh, dung dch Y v cht rn Z. Cho Z tc dng vi dung dch H 2SO4 long d th thu c 0,25V lt kh (cc kh o cng iu kin). Thnh phn % theo khi lng ca Fe trong hn hp X l A. 14,4% B. 33,43% C. 34,8%. D. 20,07% Cu 12: Ha tan hon ton hn hp X gm Mg, Zn trong bnh ng a mol HNO3 thu c hn hp kh Y (gm b mol NO v c mol N2O) v dung dch Z (khng cha mui amoni). Thm V lt dung dch NaOH 1M vo dung dch Z th thu c lng kt ta ln nht. Biu thc lin h gia V vi a, b v c l A. V = a b 2c B. V = a b c C. V = a + 3b + 8c D. V = a + 4b + 10c Cu 13: Cho 0.87g hh gm Fe, Cu v Al vo bnh ng 300ml dd H2SO4 0.1M. Sau khi cc phn ng xy ra ht thu c 0.32g g cht rn v c 448ml kh(ktc) thot ra. Thm tip vo bnh 0.425g NaNO3 khi cc phn ng kt thc th th tch kh NO(ktc, sp kh duy nht) to thnh v khi lng mui thu c l bao nhiu: A 0.224l v 3.750g B 0.112l v 3.750g C 0.112l v 3.865g D 0.224l v 3.865g Cu 14: Nung m gam hn hp X gm FeS v FeS 2 trong mt bnh kn cha khng kh (gm 20% th tch O 2 v 80% th tch N2) n khi phn ng xy ra hon ton, thu c cht rn v hn hp kh Y c thnh phn th tch: N 2 = 84,77%; SO2 = 10,6% cn li l O2. Thnh phn % theo khi lng ca FeS trong X l A. 68,75% B. 59,46% C. 26,83% D. 42,3% Cu 15: Cho 0,2 mol Zn vo dung dch X gm: 0,2 mol Fe(NO3)3, 0,1mol Cu(NO3)2, 0,1 mol AgNO3. Khi lng cht rn thu c sau khi phn ng kt thc l A. 14 gam. B. 16,4 gam. C. 10,8 gam. D. 17,2 gam. Cu 16: Cho hn hp cha x mol Zn, y mol Fe vo dung dch cha z mol CuSO4, sau khi kt thc phn ng ngi ta thu c cht rn gm hai kim loi. Mi lin h gia x, y v z l: A. x z < x + y. B. x z. C. x < z < y. D. x + y = z.

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Cu 17: Cho 13,6 gam hn hp bt X (gm Fe v Mg) vo 200ml dung dch CuSO4 1M. Sau khi phn ng kt thc thu c cht rn Y v dung dch Z. Cho cht rn Y tc dng vi dung dch HCl (d) thu c 2,24 lt H2 ( ktc). Cho NaOH d vo dung dch Z thu c kt ta hai hiroxit kim loi. % khi lng ca Fe c trong X l A. 66,67%. B. 82,35%. C. 58,82%. D. 17,65%. Cu 18: xc nh hm lng Fe3O4 trong mt mu qung manhetit, ngi ta tin hnh nh sau: Ha tan 10 gam mu qung vo dung dch H2SO4 d c 500 ml dung dch A. Chun 25 ml dung dch A bng dung dch KMnO4 0,01M th thy ht 12,4 ml dung dch chun. Hm lng Fe3O4 trong mu qung l: A. 28,76%. B. 86,30%. C. 57,536%. D. 18,85%. Cu 19: Nhng mt l st nh vo dd cha mt trong nhng cht sau: FeCl3, AlCl3, CuSO4, HCl, HNO3, H2SO4 (c, nng), MgCl2, AlCl3. S trng hp p to mui Fe(II) l: A. 4 B. 6 C. 5 D. 3 Cu 20: C 4 dung dch ring bit: CuSO4, ZnCl2, FeCl3, AgNO3. Nhng vo mi dung dch mt thanh Ni, s trng hp xut hin n mn in ho l: A. 1 B. 2 C. 4 D. 3 Cu 21: Hin tng no sau di y c m t khng ng? A. Thi kh NH3 qua CrO3 un nng thy cht rn chuyn t mu thm sang mu lc thm. B. Nung Cr(OH)2 trong khng kh n khi lng khng i thu c cht rn mu en. C. un nng S vi K2Cr2O7 thy cht rn chuyn t mu da cam sang mu lc thm. D. t CrO trong khng kh thy cht rn chuyn t mu en sang mu lc thm. Cu 22: Cho cc dung dch: Fe(NO3)3 + AgNO3, FeCl3, CuCl2, HCl, CuCl2 + HCl, ZnCl2. Nhng vo mi dung dch mt thanh Fe. S trng hp c th xy ra n mn in ha l A. 3. B. 4. C. 5. D. 2. Cu 23: Ho tan hon ton a gam hn hp : NaI v NaBr vo nc thu c dung dch X. Cho Br 2 d vo X c dung dch Y. C cn Y thu c b gam cht rn khan. Tip tc ho tan b gam cht rn khan trn vo nc c dung dch Z. Cho Cl2 d vo Z c dung dch T. C cn T thu c c gam cht rn khan. Bit cc phn ng xy ra hon ton v 2b = a + c. Phn trm khi lng ca NaBr trong hn hp ban u l: A. 7,3% B. 4,5% C. 3,7% D. 6,7% Cu 24: Thc hin phn ng nhit nhm 53,6 gam hn hp X gm Al v Fe 2O3 trong iu kin khng c khng kh, sau phn ng hon ton thu c hn hp cht rn Y . Ly ton b Y cho tc dng vi dung dch H 2SO4 long, d, thy thot ra 22,4 lt H2 (ktc). Hiu sut cc phn ng l 100%. Thnh phn phn trm khi lng Al trong hn hp X l: A. 20,15% B. 40,3% C. 59,7% D. 79,85% Cu 25: Trn 21,6 gam bt Al vi m gam hn hp X (gm FeO, Fe2O3 v Fe3O4) c hn hp Y. Nung Y nhit cao trong iu kin khng c khng kh n khi phn ng hon ton thu c hn hp cht rn Z. Cho Z tc dng vi dung dch NaOH d thu c 6,72 lt kh. Nu cho Z tc dng vi dung dch HNO3 long, d th thu c 19,04 lt NO (sn phm kh duy nht). Bit cc th tch kh o ktc. Gi tr ca m l A. 50,8. B. 58,6. C. 46,0. D. 62,0. Cu 26: Hn hp X gm Al va Cr 2O3. Nung 21,14 gam X trong iu kin khng co khng khi thu c hn hp Y. Cho toan b Y vao dung dich NaOH loang, d thy co 11,024 gam cht rn khng tan va thu c 1,5456 lit kh (ktc). Hiu sut cua phan ng nhit nhm la: A. 83% B. 87% C. 79,1% D. 90 Cu 27: in phn dung dch hn hp gm CuSO4 v KCl vi in cc tr, mng ngn xp. Khi thy c hai in cc u c bt kh thot ra th dng li. Kt qu anot c 448 ml kh thot ra(ktc), khi lng dung dch sau in phn gim m gam v c th ho tan ti a 0,8 gam MgO. Gi tr ca m l: A. 1,62 B. 2,14 C. 2,95 D. 2,89 Bin son GV Phm Tun 0975737845 Mobile: 6

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Cu 28:in phn 200ml dung dch hn hp gm CuSO4 0,25M v CrCl2 0,6M vi in cc graphit trong thi gian 1 gi 36 pht 30 giy, cng dng in I = 5A. Khi lng kim loi bm vo catot va th tch kh (iu kin tiu chun) thot ra anot ln lt la A. 8,4 gam v 3,024 lit. B. 8,4 gam v 2,688 lit. C. 3,2 gam v 3,024 lit. D. 3,2 gam v 2,688 lit. Cu 29:: in phn dd cha 0,2 mol FeSO4 v 0,06mol HCl vi dng in 1,34 A trong 2 gi (in cc tr, c mng ngn). B qua s ho tan ca clo trong nc v coi hiu sut in phn l 100%. Khi lng kim loi thot ra katot v th tch kh thot ra anot (ktc) ln lt l: A. 1,12 gam Fe v 0,896 lit hh kh Cl2 v O2. B. 1,12 gam Fe v 1,12 lit hh kh Cl2 v O2. C. 11,2 gam Fe v 1,12 lit hh kh Cl2 v O2. D. 1,12 gam Fe v 8,96 lit hh kh Cl2 v O2. Cu 30:: Ha tan 4,5 gam tinh th MSO4.5H2O vo nc c dung dch X. in phn dung dch X vi in cc tr v cng dng in 1,93A. Nu thi gian in phn l t (s) th thu c kim loi M catot v 156,8 ml kh ti anot. Nu thi gian in phn l 2t (s) th thu c 537,6 ml kh . Bit th tch cc kh o ktc. Kim loi M v thi gian t ln lt l: A. Cu v 1400 s B. Cu v 2800 s C. Ni v 2800 s D. Ni v 1400 s Cu 31: in phn 200 ml dung dch gm AgNO 3 0,1M v Cu(NO3)2 0,2 M vi in cc tr, cng dng in I = 5 A, trong thi gian 19 pht 18 giy. Khi lng dung dch sau in phn gim m gam. Tnh m, bit hiu sut in phn 80 % , b qua s bay hi ca nc. A. 3,92g B. 3,056 g C. 6,76g D. 3,44g Cu 32 : Cho 24,3 gam bt Al vo 225 ml dung dch hn hp NaNO3 1M v NaOH 3M khuy u cho n khi kh ngng thot ra th dng li v thu c V lt kh ( ktc).Gi tr ca V l: A. 11,76 lt B. 9,072 lt C. 13,44 lt D. 15,12 lt Cu 33: Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l: A. 17,8 v 4,48 B. 17,8 v 2,24 C. 10,8 v 4,48 D. 10,8 v 2,24

Phn 5: phi kim v bi ton v cht kh ( 2 3 cu )

Cu 1: Cho mt hn hp kh gm N2 v H2 c t khi i vi H2 l 4,9 qua thp tng hp ( c xc tc vi th tch khng ng k) , ngi ta thu c hn hp mi c t khi i vi H 2 l 6,125. Hiu sut phn ng tng hp NH 3 l: A. 40,86% B. 42.86% C. 33,33% D. 37,87%
Cu 2: Hn hp X gm N2 v H2 c M = 7,2. Nung X vi bt Fe phn ng tng hp NH 3 xy ra vi hiu sut 20% c hn hp Y. Cho Y tc dng vi CuO d, nung nng thu c 32,64 g Cu. Hn hp X c th tch l bao nhiu ktc? A. 16,8 lt B. 8,4 lt C. 11,2 lt D. 14,28 lt

Cu 3: Nung hn hp rn gm FeCO 3 v FeS2 (t l mol 1 : 1) trong 1 bnh kn cha khng kh d vi p sut l p 1 atm. Sau khi cc phn ng xy ra hon ton a bnh v nhit ban u thu c cht rn duy nht l Fe 2O3 v p sut kh trong bnh lc ny l p2 atm (th tch cc cht rn khng ng k v sau cc phn ng lu hunh mc oxi ho + 4). Mi lin h gia pl v p2 l: A. pl = p2 B. pl = 2p2 C. 2pl = p2 D. pl = 3p2

Phn 6: tng hp v c ( 6 8 cu )
Cu 1: Ho tan hon ton 33,8 gam hn hp gm FeCl2 v NaF (c cng s mol) vo mt lng nc d, thu c dung dch X. Cho dung dch AgNO3 d vo X, sau khi phn ng xy ra hon ton thu c m gam cht rn. Gi tr ca m l: Bin son GV Phm Tun Mobile: 7 0975737845

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A. 79,0 gam B. 57,4 gam C. 82,8 gam D. 104,5 gam Cu 2: Ho tan ht 12,8 gam hn hp X gm Cu 2S v FeS2 trong dung dch c cha a mol HNO 3 thu c 31,36 lt kh NO2 ( ktc v l sn phm duy nht ca s kh N+5) v dung dch Y.Bit Y phn ng ti a vi 4,48 gam Cu gii phng kh NO.Tnh a? A. 1,8 mol B. 1,44 mol C. 1,92 mol D. 1,42 mol Cu 3: Cho hi nc i qua than nung nng sau khi loi b hi nc d thu c 17,92 lt (ktc) hn hp kh X gm CO2, CO v H2. Hp th X vo dung dch Ba(OH)2 d thu c 35,46 gam kt ta v c V lt kh Y thot ra. Cho Y tc dng vi CuO d nung nng sau phn ng thy khi lng cht rn gim m gam. Gi tr ca m l: A. 2,08 gam B. 9,92 gam C. 2,88 gam D. 12,8 gam Cu 4: C cc nhn xt v kim loi kim: (1)-Cu hnh electron lp ngoi cng ca kim loi kim l ns1 vi n nguyn v 1 < n 7 . (2)-Kim loi kim kh H2O d dng nhit thng gii phng H2. (3)-Kim loi kim c cu trc mng tinh th lp phng tm khi nn chng c nhit nng chy, nhit si thp. (4)-Khi cho kim loi kim vo dung dch HCl th kim loi kim phn ng vi dung mi H2O trc, vi axit sau. (5)-Cc kim loi kim khng y c kim loi yu hn ra khi dung dch mui S nhn xt ng l: A. 4 B. 3 C. 5 D. 2 Cu 5: Cho 13,36 gam hn hp X gm Cu, Fe 3O4 vo dung dch H2SO4 c nng d c V1 lt SO2 v dung dch Y. Cho Y phn ng vi NaOH d c kt ta T, nung kt ta ny n khi lng khng i c 15,2 gam cht rn Q. Nu cng cho lng X nh trn vo 400 ml dung dch P cha HNO 3 v H2SO4 thy c V2 lt NO duy nht thot ra v cn 0,64 gam kim loi cha tan ht. Cc phn ng xy ra hon ton v cc kh o ktc. Gi tr V1 v V2 l A. 2,912 v 0,224 B. 2,576 v 0,672 C. 2,576 v 0,224 D. 2,576 v 0,896 Cu 6: Cho cc cp cht sau: (1). Kh Cl2 v kh O2. (6). Dung dch KMnO4 v kh SO2. (2). Kh H2S v kh SO2. (7). Hg v S. (3). Kh H2S v dung dch Pb(NO3)2. (8). Kh CO2 v dung dch NaClO. (4). Kh Cl2 v dung dch NaOH. (9). CuS v dung dch HCl. (5). Kh NH3 v dung dch AlCl3. (10). Dung dch AgNO3 v dung dch Fe(NO3)2. S cp cht xy ra phn ng ha hc nhit thng l A. 10. B. 8. C. 9. D. 7. Cu 7: t chy hon ton 6,48 gam hn hp cht rn X gm: Cu; CuS; FeS; FeS 2; FeCu2S2; S th cn 2,52 lt O2 v thy thot ra 1,568 lt SO2. Mt khc cho 6,48 gam X tc dng vi dd HNO 3 c nng d thu c V lt NO2 (l sn phm kh duy nht) v dd Y. Cho dd Y tc dng vi dd Ba(OH) 2 d thu c m gam kt ta. Bit th tch cc kh u o ktc. Gi tr ca V v m ln lt la A. 12,316 v 24,34. B. 16,312 v 23,34. C. 13,216 v 23,44. D. 11,216 v 24,44. Cu 8: Cho m gam Ba vo 600ml dung dch cha KOH 0,1M v NaOH 0,1M thu c dung dch X. Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M c kt ta Y. thu c kt ta Y ln nht th gi tr m ti thiu v khi lng kt ta Y ln lt l: A. 8,22 gam v 13,98 gam. B. 0,00 gam v 3,12 gam. C. 8,22 gam v 19,38 gam. D. 2,74 gam v 4,66 gam. Cu 9: Trn 50 gam dung dch KOH 11,2% vi 150 gam dung dch Ba(OH)2 22,8% c dung dch A. Dn 7,84 lt kh CO2 (ktc) vo dung dch A, sau khi phn ng hon ton thu c dung dch B. Khi lng ca dung dch B so khi lng ca dung dch A A. gim 24 gam. B. gim 29,55 gam. C. gim 14,15 gam. D. tng 15,4 gam. Bin son GV Phm Tun 0975737845 Mobile: 8

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Cu 10: Cho cc pht biu sau : (1) Nguyn t cc nguyn t halogen u c 7 electron lp ngoi cng. (2) Cc nguyn t halogen ch c s oxi ha -1 trong mi hp cht. (3) Cc nguyn t halogen c m in gim dn theo th t: F > Cl > Br > I. (4) Cc hidro halogenua u l nhng cht kh, dung dch ca chng trong nc u c tnh axit mnh. (5) Tnh kh ca cc hidro halogenua tng dn theo th t: HF < HCl < HBr < HI. (6) Cc mui bc halogenua u khng tan trong nc. (7) Trong t nhin cc halogen tn ti ch yu dng n cht. Cc pht biu sai l: A. (1), (2), (4), (5). B. (2), (4), (6), (7). C. (2), (3), (5), (6). D. (1), (3), (4), (6).

Cu 11: Cho 84,6 gam hn hp hai mui CaCl2 v BaCl2 tc dng ht vi 1 lt dung dch cha Na2CO3 0,25M v (NH4)2CO3 0,75M sinh ra 79,1 gam kt ta. Thm 600ml Ba(OH)2 1M vo dung dch sau phn ng thu c m gam kt ta v V lt kh ktc . Gi tr ca m v V l: A. 98,5 gam v 2,688 lt. B. 98,5 gam v 26,88 lt. C. 9,85 gam v 26,88 lt. D. 9,85 gam v 2,688 lt. Cu 12: Khi cho 0,03mol CO2 hoc 0,09mol CO2 hp th ht vo 120ml dd Ba(OH)2 th lng kt ta thu c u nh nhau. Nng mol/lt ca dd Ba(OH)2 dng l A. 1,0 M. B. 1,5 M. C. 0,5 M. D. 2,0 M. Cu 13: Ha tan 15,84 gam hn hp gm mt oxit kim loi kim v mt oxit kim loi kim th bng dung dch HCl d c dung dch X. C cn dung dch X, ly mui khan em in phn nng chy hon ton th thu c 6,048 lt kh (o ktc) anot v a (gam) hn hp kim loi catot. Gi tr ca a l: A. 7,2. B. 11,52. C. 3,33. D. 13,68. Cu 14: Ho tan ht 12,8 gam hn hp X gm Cu 2S v FeS2 trong dung dch c cha a mol HNO 3 thu c 31,36 lt kh NO2 ( ktc v l sn phm duy nht ca s kh N +5) v dung dch Y.Bit Y phn ng ti a vi 4,48 gam Cu gii phng kh NO.Tnh a? A. 1,8 mol B. 1,44 mol C. 1,92 mol D. 1,42 mol Cu 15: C cc nhn xt v kim loi kim: (1)-Cu hnh electron lp ngoi cng ca kim loi kim l ns1 vi n nguyn v 1 < n 7 . (2)-Kim loi kim kh H2O d dng nhit thng gii phng H2. (3)-Kim loi kim c cu trc mng tinh th lp phng tm khi nn chng c nhit nng chy, nhit si thp. (4)- Cho kim loi kim vo dung dch HCl th kim loi kim phn ng vi dung mi H2O trc, vi axit sau. (5)-Cc kim loi kim khng y c kim loi yu hn ra khi dung dch mui S nhn xt ng l: A. 4 B. 3 C. 5 D. 2 Cu 15: Cho 13,36 gam hn hp X gm Cu, Fe 3O4 vo dung dch H2SO4 c nng d c V1 lt SO2 v dung dch Y. Cho Y phn ng vi NaOH d c kt ta T, nung kt ta ny n khi lng khng i c 15,2 gam cht rn Q. Nu cng cho lng X nh trn vo 400 ml dung dch P cha HNO 3 v H2SO4 thy c V2 lt NO duy nht thot ra v cn 0,64 gam kim loi cha tan ht. Cc phn ng xy ra hon ton v cc kh o ktc. Gi tr V 1 v V2 l A. 2,912 v 0,224 B. 2,576 v 0,672 C. 2,576 v 0,224 D. 2,576 v 0,896 Cu 16: Ha tan m gam hh X gm CuCl 2 v FeCl3 trong nc c dung dch Y. Chia Y thnh 2 phn bng nhau. Phn 1 : cho kh H2S d vo c 1,28g kt ta. Phn 2 : cho Na2S d vo c 3,04g kt ta. Gi tr ca m l : A. 8,4 g B. 14,6 g C. 9,2 g D. 10,2 g Cu 11: Cho dy cc cht: (NH2)2CO, NH4Cl, (NH4)2SO4, NaHCO3, ZnCl2, FeCl2, KCl. S cht trong dy tc dng vi dung dch Ba(OH)2 d to thnh kt ta sau khi cc phn ng xy ra hon ton l Bin son GV Phm Tun 0975737845 Mobile: 9

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A. 2. B. 5. C. 4. D. 3. Cu 12: Hp th hon ton 10,8 gam hn hp gm CO2 v SO2 c t khi hi so vi H2 bng 27 vo 2 lt dung dch Ba(OH)2 0,075M c kt ta v dung dch Y. Bit khi 2 kh ny to ra kt ta hay ha tan kt ta u c hiu sut phn ng nh nhau. Khi lng dung dch Y so vi khi lng dung dch Ba(OH)2 ban u A. tng 9,9 gam. B. tng 10,8 gam. C. gim 20,7 gam. D. gim 9,9 gam. Cu 13: Nhit phn hon ton hn hp gm Cu(NO3)2 + AgNO3 thu c hn hp kh c t khi so vi H2 bng 21,25. Phn trm khi lng ca Cu(NO3)2 trong hn hp l A. 72,6%. B. 61,5%. C. 52,5%. D. 58,4%. Cu 14: Hn hp kh M gm Cl2 v O2. M phn ng va ht vi mt hn hp Y gm 4,32g Mg v 7,29g Al sau khi phn ng hon ton c 33,345g hn hp cc mui v oxit. Tnh % th tch kh O2 trong hn hp M : A. 33,33% B. 45,87% C. 78,98% D. 44,44% Cu 15. Sc 2,016 lt kh CO2 ( ktc) vo 100 ml dung dch NaOH 1M c dung dch A. Rt thm 200 ml dung dch gm BaCl2 0,15M v Ba(OH)2 xM thu c 5,91 gam kt ta. Tip tc nung nng th thu tip m gam kt ta na. Gi tr ca x v m l: A. 0,1M v 3,94gam B. 0,05M v 1,97 gam C. 0,05M v 3,94 gam D. 0,1M v 1,97 gam.

Bin son GV Phm Tun 0975737845

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