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Hidrocacbon qua cc nm thi i hc Nm 2007 Khi A Cu 1: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnhtng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12) A. C2H2 v C4H6. B. C2H2 v C4H8. C. C3H4 v C4H8. D. C2H2 v C3H8. Cu 2: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40) A. 20. B. 40. C. 30. D. 10. Cu 3: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A. C3H6. B. C3H4. C. C2H4. D. C4H8 Cu 4: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1). B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). Cu 5: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l (cho H = 1, C = 12, O = 16) A. C3H8. B. C3H6. C. C4H8. D. C3H4. Nm 2007 khi B Cu 6: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. dung dch NaOH. C. nc brom. D. giy qu tm Cu 7: Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l (cho H = 1, C = 12, Br = 80) A. 3,3-imetylhecxan. B. isopentan. C. 2,2-imetylpropan. D. 2,2,3-trimetylpentan. Nm 2008 khi A Cu 8: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l A. 20,40 gam. B. 18,96 gam. C. 16,80 gam. D. 18,60 gam. Cu 9: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 4. B. 3. C. 2. D. 5. Cu 10: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l A. 1,20 gam. B. 1,04 gam. C. 1,64 gam. D. 1,32 gam Cu 11: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l A. C5H12. B. C3H8. C. C4H10. D. C6H14. Cu 12: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A. 3. B. 2. C. 1. D. 4. Cu 13: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l
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A. 2. B. 4. C. 3. D. 5. Nm 2008 Khi B Cu 14: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A. 3. B. 2. C. 5. D. 4. Cu 15: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. C2H6 v C3H6. B. CH4 v C3H6. C. CH4 v C2H4. D. CH4 v C3H4. Cu 16: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng hn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankan. B. ankin. C. ankaien. D. anken. Cu 17: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H4. B. C2H6. C. C3H8. D. CH4. Nm 2009 Khi A Cu 18: Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. xiclohexan. B. xiclopropan. C. stiren. D. etilen. Cu 19: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,2 mol C2H4 v 0,1 mol C2H2. C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4 Nm 2009 Khi B Cu 20: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l A. 20%. B. 50%. C. 25%. D. 40%. Cu 21: Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH3-CH=CH-CH3. B. CH2=CH2. C. CH2=C(CH3)2. D. CH2=CH-CH2-CH3. Cu 22: Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. stiren; clobenzen; isopren; but-1-en. B. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. C. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. D. buta-1,3-ien; cumen; etilen; trans-but-2-en. Cu 23: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-2-en. B. xiclopropan. C. propilen. D. but-1-en. Nm 2010 Khi A

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Cu 24: un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l A. 0,328. B. 0,205. C. 0,620. D. 0,58 Cu 25: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l A. 2-etylpent-2-en. B. 3-etylpent-2-en. C. 3-etylpent-3-en. D. 3-etylpent-1-en Cu 26: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch Ba(OH) 2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH) 2 ban u. Cng thc phn t ca X l A. C3H8. B. C3H6. C. C3H4. D. C2H6. Nm 2010 Khi B Cu 27: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H 2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C4H8. B. C2H6 v C2H4. C. CH4 v C2H4. D. CH4 v C3H6. Nm 2011 Khi A Cu 28: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm C 2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H 2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 33,6 lt. B. 22,4 lt. C. 26,88 lt. D. 44,8 lt. Cu 29: Cho 13,8 gam cht hu c X c cng thc phn t C 7H8 tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn? A. 5. B. 6. C. 4. D. 2. Cu 30: t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht bng nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO 3 trong NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca C3H4 v C4H4 trong X ln lt l: A. CHC-CH3, CH2=CH-CCH. B. CHC-CH3, CH2=C=C=CH2. C. CH2=C=CH2, CH2=CH-CCH. D. CH2=C=CH2, CH2=C=C=CH2. Cu 31: Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l A. 2. B. 4. C. 1. D. 3. Cu 32: Cho dy chuyn ho sau: Benzen + ( C2H4, xt, to ) > X + ( Br 2 as t l 1:1 ) > Y ( KOH/ C 2H5OH xt, to ) > Z (trong X, Y, Z l sn phm chnh). Tn gi ca Y, Z ln lt l A. 1-brom-1-phenyletan v stiren. B. 1-brom-2-phenyletan v stiren. C. 2-brom-1-phenylbenzen v stiren. D. benzylbromua v toluen. Nm 2011 - Khi B Cu 33: Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5 -COOK + K2CO3 + MnO2 + KOH + H2O. Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l A. 24. B. 34. C. 27. D. 31 Cu 34: Cho cc pht biu sau: (a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O th X l anken. (b) Trong thnh phn hp cht hu c nht thit phi c cacbon. (c) Lin kt ho hc ch yu trong hp cht hu c l lin kt cng ho tr.
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(d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau. (e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh. (g) Hp cht C9H14BrCl c vng benzen trong phn t. S pht biu ng l A. 3. B. 2. C. 5. D. 4. Cu 35: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H 2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH) 2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l A. 6,6. B. 5,85. C. 7,3. D. 3,39. Cu 36: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C 4H10, C4H8, C4H6 v H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l A. 0,48 mol. B. 0,24 mol. C. 0,36 mol. D. 0,60 mol. Cu 37: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l A. 8. B. 7. C. 9. D. 5. Nm 2012 Khi A Cu 38: Hirat ha 5,2 gam axetilen vi xc tc HgSO4 trong mi trng axit, un nng. Cho ton b cc cht hu c sau phn ng vo mt lng d dung dch AgNO 3 trong NH3 thu c 44,16 gam kt ta. Hiu sut phn ng hirat ha axetilen l A. 80%. B. 70%. C. 92%. D. 60%. Cu 39: Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c th c ca X l A. 6. B. 5. C. 7. D. 4. Cu 40: t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 39,4 gam kt ta v khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l A. C3H4 B. CH4. C. C2H4. D. C4H10 Cu 41: t chy hon ton 3 lt hn hp X gm 2 anken kt tip nhau trong dy ng ng cn va 10,5 lt O 2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol bc mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l A. 46,43% B. 31,58%. C. 10,88%. D. 7,89% Cu 42: Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng, thu c hn hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ha l A. 70%. B. 60%. C. 50%. D. 80%. Cu 43: Cho dy cc cht: cumen, stiren, isopren, xiclohexan, axetilen, benzen. S cht trong dy lm mt mu dung dch brom l A. 2. B. 3. C. 4. D. 5. Nm 2012 Khi B Cu 44: Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp X (xc tc Ni) mt thi gian, thu c hn hp Y c t khi so vi H2 bng 10. Dn hn hp Y qua dung dch brom d, sau khi phn ng xy ra hon ton, khi lng brom tham gia phn ng l A. 24 gam. B. 16 gam. C. 0 gam. D. 8 gam. Cu 45: t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c cng thc n gin nht khc nhau, thu c 2,2 gam CO2 v 0,9 gam H2O. Cc cht trong X l A. hai ankaien. B. mt anken v mt ankin. C. hai anken. D. mt ankan v mt ankin. Cu 46: Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm chnh l
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A. 3-metylbutan-2-ol.

B. 3-metylbutan-1-ol

C. 2-metylbutan-2-ol.

D. 2-metylbutan-3-ol.

Chuyn ho hu c n thi i hc 2007 - 2012