Bi tp theo cu trc thi i hc mn Ho hc 2012 cp tc

n luyn

Phn 1: ng phn ( 1 2 cu)

Cu 1: S ng phn apha amino axit ca C5H11O2N l: A. 3 B4 C. 5 D. 6 Cu 2: C8H11N c bao nhiu ng phn thm tc dng vi brom cho kt ta trng: A. 4 B. 5 C. 3 D. 6 Cu 3: C4H6O2 c bao nhiu ng phn n chc mch h tc dng vi NaOH thu c sn phm c kh nng trng gng: A. 2 B. 3 C. 4 D.5 Cu 4: Cho cc ng phn mch h ca C2H4O2 tc dng ln lt vi Na, NaOH, CH3OH, AgNO3/NH3. Sphn ng xy ra l: A. 4 B. 5 C. 6 D.7 Cu 5: C8H10O: - C bao nhiu ng phn cha vng benzen tc dng vi dd brom c kt ta trng A. 6 B. 3 C. 4 D.5 - C bao nhiu ng phn tc dng vi NaOH: A. 6 B. 7 C. 8 D. 9 Cu 6: S ng phn thm ca C7H8O2 tho mn tnh cht sau: - Tc dng vi Na: A. 7 B. 8 C. 9 D. 10 - Tc dng vi NaOH theo t l 1:2 A. 4 B. 5 B. 6 D. 7 Cu 7: C8H8O2 c bao nhiu ng phn thm tc dng vi NaOH theo t l 1:2 A. 3 B. 4 C. 5 D. 6 Cu 8: C3H6O2 - c bao nhiu pct mch h tc dng vi Na: A.1 B. 2 C. 3 D. 4 - Cho cc pct n chc mch h tc dng vi Na, NaOH, NaHCO3, AgNO3/NH3 A. 5 B. 6 C. 7 D. 3 Cu 9: C3H6O c bao nhiu pct: A. 2 B. 4 C. 5 D. 7 Cu 10: C5H13N c s p amin bc mt l x, C5H12O c s p acol bc mt la y. x v y ln lt l: A.8 v 4 B. 16 v 8 C. 8 v 4 D.16 v 6

Phn 2: Hirocacbon ( 2 3 cu)

Cu 1: Cho cc cht: eten, axetylen, bezen, propylen, toluen, stien, xiclopropan, metylxiclobutan, naphtalen, isopren, isopentan, p- xilen, cumen, phenylaxetylen, tetrafloeten, anlen, butadien, caosubuna. S cht lm mt mu brom l: A. 9 B. 10 C. 11 D. 8 Cu 2: X v Y c cng CTPT la C5H10. X lm mt mu dd brom nhit thng to sp 1,3 dibrom 2- metylbutan. Y p vi brom khi c askt thu c 1 dn xut mono duy nht. X v Y ln lt l: A.3- metylbut-1-en v xiclopentan B. 2-metylbut-2-en v metylxiclobutan C. 1,1-dimetylxiclopropan va xiclopentan D. 1,2-dimetylxiclopropan v xiclopentan Cu 3: Dn 0,336 lt C2H2 (dktc) vo dd KMnO4 0,2M thy to thnh cht rn mu en. Th tch dd KMnO4 ti thiu hp th ht kh trn: A. 400 ml B. 40 ml C. 20 ml D. 200 ml Bin son GV Phm Tun 1

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc Cu 4: Mt hn hp X gm ankan A v anken B, A c nhiu hn B mt nguyn t cacbon, A v B u th kh ( ktc). Khi cho 6,72 lt kh X (ktc) i qua nc brom d, khi lng bnh brom tng ln 2,8 gam; th tch kh cn li ch bng 2/3 th tch hn hp X ban u. CTPT ca A, B v khi lng ca hn hp X l: A. C4H10, C3H6 ; 5,8 gam. B. C3H8, C2H4 ; 5,8 gam. C. C4H10, C3H6 ; 12,8 gam. D. C3H8, C2H4 ; 11,6 gam. Cu 5: un nng hn hp X gm 0,1 mol C3H4 ; 0,2 mol C2H4 ; 0,35 mol H2 vi bt Ni xc tc c hn hp Y. Dn ton b Y qua bnh ng dung dch KMnO4 d, thy thot ra 6,72 l hn hp kh Z (ktc) c t khi so vi H 2 l 12. Bnh ng dung dch KMnO4 tng s gam l: A. 17,2. B. 9,6. C. 7,2. D. 3,1. Cu 6: Tin hanh trung hp 10,4 gam stiren c hn hp X gm polistiren va stiren (d). Cho X tac dung vi 200 ml dung dich Br2 0,15M, sau o cho dung KI d vao thy xut hin 1,27 gam iot. Hiu sut trung hp stiren l A. 60%. B. 75%. C. 80%. D. 83,33%. Cu 7: hiro ho etylbenzen ta c stiren; trng hp stiren ta c polistiren vi hiu sut chung 80%. Khi lng etylbenzen cn dng sn xut 10,4 tn polisitren l: A.13,52 tn. B. 10,6 tn. C. 13,25 tn. D. 8,48 tn. Cu 8: A, B, C la ba cht hu c co %C, %H (theo khi lng) ln lt la 92,3% va 7,7%, ti l khi lng mol tng ng la 1: 2 : 3. T A co th iu ch B hoc C bng mt phan ng. C khng lam mt mau nc brom. t 0,1 mol B ri dn toan b san phm chay qua binh ng dung dich nc vi trong d. a. Khi lng binh tng hoc giam bao nhiu gam ? A. Tng 21,2 gam. B. Tng 40 gam. C. Giam 18,8 gam. D. Giam 21,2 gam. b. Khi lng dung dch tng hoc giam bao nhiu gam ? A. Tng 21,2 gam. B. tng 40 gam. C. giam 18,8 gam. D. giam 21,2 gam. XC Dy cc cht u lm mt mu dung dch thuc tm l A. Xiclobutan, but-1-in, m-xilen, axit axetic B. Benzen, but-1-en, axit fomic, p-xilen C. Etilen, axetilen, anehit fomic, toluen D. Axeton, etilen, anehit axetic, cumen Cu 10: Hn hp X gm 1 hirocacbon th kh v H2 c t khi so vi H2 bng 4,8. Cho X i qua Ni nung nng n khi phn ng xy ra hon ton thu c hn Y c t khi so vi CH4 bng 1. Cng thc phn t ca hirocacbon trong hn hp X l? A. C3H6. B. C2H2. C. C3H4. D. C2H4. Cu 11: t chy hon ton hn hp Q gm 2 ankin X, Y. Hp th ton b sn phm chy vo 4,5 lt dung dch Ca(OH)2 0,02M thu c kt kt ta v khi lng dung dch tng 3,78 gam so vi ban u. Cho dung dch Ba(OH)2 va vo dung dch thu thm kt ta. Tng kt ta 2 ln l 18,85 gam. Bit rng s mol ca X bng 60% tng s mol ca X v Y c trong hn hp Q. Cc phn ng xy ra hon ton. Cng thc ca X, Y ln lt l: A. C2H2 v C4H6 B. C4H6 v C2H2 C. C2H2 v C3H4 D. C3H4 v C2H6 Cu 12: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 19 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H2 l 8,5. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 22,4 lt. B. 26,88 lt. C. 58,24 lt. D. 53,76 lt. Cu 13: t chy hon ton 0,336 lt kh ( ktc) mt ankaien X. Sn phm chy c hp th hon ton vo 400 ml dung dch Ba(OH)2 0,15M thu c 8,865 gam kt ta. Cng thc phn t ca X l A. C3H4. B. C3H4 hoc C5H8 C. C4H6. D. C5H8. Cu 14: Crackinh hoan toan mt th tich ankan X thu c 3 th tich hn hp Y. Ly 6,72 lit Y(kc) lam mt mau va u dung dich cha a mol Br2. Gia tri cua a la: A. 0,6 B. 0,2 C. 0,3 D. 0,1 Cu 15: Hn hp X gm eten v propen c t l mol l 3:2. Hirat ha hon ton X thu c hn hp ancol Y trong t l khi lng ancol bc 1 so vi ancol bc 2 l 28:15. Thanh phn phn trm v khi lng ca ancol isopropylic trong Y l: A. 45,36% B. 11,63% C. 34,88% D. 30,00% Bin son GV Phm Tun 2

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc Cu 16: Crckinh V lt propan thu c 35 lt hn hp X gm H2,C3H6 ,CH4, C2H4,C3H8. Dn ton b X vo bnh ng dung dch Br2 d th cn li 20 lt hn hp kh ( Cc th tch kh o cng iu kin nhit p sut) . Tnh hiu sut ca qu trnh crckinh . A. 57,14 % B. 75% C. 80 % D. 42,85 % Cu 17: Mt hidrocacbon E c cng thc nguyn l (CH)n vi n < 7. E tc dng vi dung dch AgNO3/NH3 d c kt ta F. Khi lng phn t ca E v F khc nhau 214 vC. S CTCT ph hp ca E: A. 1 B. 2 C. 3 D.4 Cu 18: Crac kinh V lt n- butan c 36 lt hn hp kh X gom 7 cht C4H8, H2, C3H6,CH4, C2H4, C2H6, C4H10 . Bit hiu sut phn ng l 80 % . Dan hon hp X vao bnh ng dung dch Br2 d th con lai hon hp kh Y (th tch o cung ieu kien to, p). Th tch ca hon hp kh Y l A. 22,5 lt B. 20 lit C.15 lt D.32 lt Cu 19: Cho 140cm3 hn hp A (kc) gm C2H6 v C2H2 li t t qua bnh ng dung dch HgSO4 80oC. Ton b cc cht kh v hi i ra khi bnh phn ng c dn vo bnh cha dung dch AgNO3 trong NH3 v un nng, thu c 0,54 gam Ag. Gi s cc phn ng u xy ra hon ton. Thnh phn % th tch C2H6 v C2H2 trong hn hp A l : A. 45% v 55% B. 50% v 50% C. 60% va 40% D. 30% v 70% Cu 20: Mt bnh kn ng hn hp hiro vi axetilen v mt t bt niken. Nung nng bnh mt thi gian sau a v nhit ban u thu c hn hp kh X. Nu cho mt na hn hp X i qua dung dch AgNO3 trong NH3 th c 1,20 gam kt ta mu vng nht. Nu cho na cn li qua bnh ng nc brom d thy khi lng bnh tng 0,41 gam. Khi lng etilen sinh ra trong X bng : A. 0,14 gam B. 0,28 gam C. 0,42 gam D. 0,56 gam

Phn 3: ancol, phenol ( 2 3 cu )

Cu 1: Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d dd AgNO 3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l A. 83,7%. B. 48,9%. C. 65,2%. D. 16,3%. Cu 2: Chia m gam hn hp 2 anehit n chc mach h thanh 2 phn bng nhau Phn 1 tac dung vi lng d AgNO3 trong NH3 thu c 86,4 gam Ag kt tua Phn 2 tac dung va u vi 1 gam hiro co xuc tac Niken nung nong thu c hn hp ancol Y. Ngng tu Y ri cho toan b vao binh cha Na thy khi lng binh tng (0,5m+0,7) gam. Cng thc cua 2 anehit la: A. HCHO va C2H5CHO B. CH2CHCHO va HCHO C. CH2CHCHO va CH3CHO D. HCHO va CH3CHO Cu 3: Hn hp X gm metanol, etanol, propan-1- ol, v H 2O. Cho m gam X + Na d thu c 15,68 lit H 2(ktc). Mt khc t chy hon ton X thu c Vlit CO2(ktc) v 46,8 gam H2O. Gi tr m v V l. A. 19,6 v 26,88 B. 42 v 26,88 C. 42 v 42,56 D. 61,2 v 26,88 Cu 4: Chia m gam hn hp M gm hai ancol n chc k tip trong dy ng ng thnh 2 phn bng nhau. Cho phn mt tc dng vi Na (d), c 3,36 lt kh hiro (ktc). Cho phn hai phn ng hon ton vi CuO nhit cao, c hn hp M1 cha hai anehit (ancol ch bin thnh anehit). Ton b lng M 1 phn ng ht vi AgNO3 trong NH3, thu c 86,4 gam Ag. Gi tr ca m l A. 24,8 gam B. 30,4 gam C. 15,2 gam D. 45,6 gam Cu 5: ng vi cng thc phn t C3H8On co x ng phn ancol bn, trong s nay co y ng phn hoa tan c Cu(OH)2 tao dung dich xanh m. x, y la: A. 4 va 2 B. 4 va 3 C. 5 va 2 D. 5 va 3

Bin son GV Phm Tun

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc Cu 6: un nong hn hp X gm 2 ancol no n chc k tip nhau vi H2SO4 c 180oC thu c hn hp 2 cht hu c Y co dY/X = 0,66. X la: A. CH3OH va C2H7OH B. C2H5OH va C3H7OH C. C3H7OH va C4H9OH D. C4H9OH va C5H11OH Cu 7: Oxi ha 78 gam mt ancol n chc X c hn hp Y gm ancol d, anehit, axit v nc. Cho ton b Y tc dng vi Na d c 0,85 mol H2. Hn hp Y tc dng vi NaHCO3 d c 0,4 mol CO2. Cng thc ca ancol X l: A. C3H5OH B. C2H5OH C. C3H7OH D. C4H9OH Cu 8: Chia hon hp X gom phenol, axit acrylic va glixerol thanh hai phan. Phan mot co khoi lng 7 gam phan ng va u vi 2,94 gam Cu(OH)2 nhiet o thng. Phan co so mol la 0,16 mol lam mat mau va ung 80 ml dung dch Br2 2M. Cac phan ng xay ra hoan toan. Thanh phan phan tram khoi lng phenol trong hon hp X la A. 26,86%. B. 13,43%. C. 40,29%. D. 20,14%. Cu 9: trung ha 28,8 gam hn hp gm axit axetic, ru n-propilic v p-cresol cn 150 mL dung dch NaOH 2 M. Ha tan 28,8 gam hn hp trn trong n-hexan ri cho Na d vo th thu c 4,48 L kh hiro (ktc). Lng axit axetic trong hn hp bng : A. 0,1 mol. B. 0,2 mol. C. 0,3 mol. D. 0,4 mol. Cu 10: Mt hh X gm CH3OH; CH2=CH-CH2OH; CH3CH2OH; C3H5(OH)3. Cho 25,4 gam hh X t/d vi Na d thu c 5,6 lt H2 (ktc). Mt khc, em t chy hon ton 25,4 gam hh X thu c a mol CO2 v 27 gam H2O. Gi tr ca a l A. 1,25 B. 1 C. 1,4 D. 1,2 Cu 11:. Hn hp gm cc ancol u no n chc v phn t khi u 60. Khi tch nc 170oC vi xc tc H2SO4 c th trong sn phm c hai anken l ng ng lin tip nhau: Vy trong hn hp u c th cha ti a bao nhiu ancol A. 2 B. 3 C. 4 D. 5 Cu 12:. Tm nhn xt ng: A. Trong cng nghip, sn xut phnol ngi ta oxi ha Cumen vi O2 khng kh, vi xc tc thch hp. B. Do nh hng ca nhm OH, nn phnol c kh nng th hin tnh axit yu, d dng phn ng vi dung dch NaOH. C. Nha Bkalit ( Phenolfomandehit) l hp cht cao phn t, l sn phm ca phn ng trng hp gia phnol v anhit fomic. D. Khng th nhn bit c phnol v anilin bng dung dch HCl, hoc NaOH. Cu 13:. Oxi ha 4,64 gam mt ancol n chc A bng CuO thy khi lng cht rn gim i 1,12 gam v thu c hn hp gm mt anhit, ancol d ,nc . ( Bit ancol A c t khi hi so vi hidro ln hn 23,1). Hiu sut ca phn ng l: A. 48,28% B. 70% C. 89,74% D. 87,5%. Cu 14: t chy hon ton 80,08 gam hn hp X gm C3H7OH, C2H5OH v CH3OC3H7 thu c 95,76 gam H2O v V lt kh CO2 (ktc). Gi tr ca V l: A. 129,6 lt B. 87,808 lt C. 119,168 lt D. 112 lt Cu 15: Hn hp X gm ancol metylic v 1 ru no n chc A. Cho 4,6 gam X tc dng vi Na d thu c 1,12 lt H2(ktc) . Mt khc oxi ha hon ton 4,6 gam X bng CuO , to ri cho ton b sn phm thu c tc dng vi dung dch Ag2Od/NH3 thu c 0,2 mol Ag . CTCT ca A l: A. C2H5OH B. CH3CHOHCH3 C. CH3CH2CH2OH D.CH3CH2CHOHCH3 Cu 16: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l A. 15,3. B. 13,5. C. 8,1. D. 8,5 Cu 17: Chia 30,4 gam hn hp hai ancol n chc thnh hai phn bng nhau phn 1 cho tc dng ht vi Na to ra 0,15 mol H2 phn 2 em oxi ho hon ton bng CuO, to thu c hn hp 2 andehit, cho ton b hn hp 2 andehit tc dng ht vi Ag2O/NH3 d (dung dch AgNO3/NH3 d) thu c 86,4 gam Ag. Hai ancol l Bin son GV Phm Tun 4

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc A. CH3OH v C2H5OH B. C2H5OH v C2H5CH2OH C. CH3OH va C2H5CH2OH D. CH3OH v C2H3CH2OH Cu 18: Cho m gam hi ancol metylic i qua mt ng s cha CuO t nng, lm lnh ton b phn hi i ra khi ng s ri chia thnh 2 phn u nhau. Phn 1 cho phn ng ht vi Na thu c 3,36 lt kh H2(ktc). Phn 2 cho phn ng ht vi dung dch AgNO3 trong NH3 thu c 86,4 gam Ag. Hi u sut ca phn ng oxi ho ancol metylic l : A: 40% B: 33,3% C: 66,67% D: 50%

Phn 3: andehit ( 2- 3 cu )
Cu 1: Hn hp A gm 0,1 mol anehit metacrylic v 0,3 mol kh hiro. Nung nng hn hp A mt thi gian, c mt cht xc tc Ni, thu c hn hp hi B gm hn hp cc ancol, cc anehit v hiro. T khi hi ca B so vi He bng 95/12. Hiu sut ca phn ng hiro ha anehit metacrylic l: A. 100% B. 70% C. 65% D. 80% Cu 2 : Hn hp A gm hai anehit X, Y. Trong X c iu ch bng cch cho ankin hp H 2O khi c mt HgSO4 80oC, Y c iu ch bng cch oxi ho ancol anlylic. Cho 20,48 gam hn hp A (trong anehit c phn t khi nh chim 40% v s mol) tc dng vi AgNO3 trong NH3 d. Khi lng Ag thu c khi phn ng xy ra hon ton l: A. 86,4 g B. 43,2 g C. 64,8 g D. 32,4 g Cu 3: Hn hp X gm 2 anehit cacboxylic u no, mch h. Cho 0,1 mol X phn ng trng gng hon ton thu c 0,3 mol Ag. Khi t chy hon ton 0,3 mol X thu c 16,8 lt CO2 ( ktc). Cng thc ca 2 anehit l: A. CH3CHO ; CH2(CHO)2 B. CH3CHO; (CHO)2. C. HCHO; CH3CHO. D. CH3CHO; C2H5CHO. Cu 4:Anehit mach h A tac dung vi H2 theo t le mol n A : n H = 1:2 va trang gng theo t le mol n A : n Ag = 1:4.ot chay hoan toan m gam A can va ung V lt O2 ( ktc). Hap thu toan bo san pham chay vao dung dch nc voi trong d thu c a gam ket tua. Moi lien he gia m vi V va a la
2

A. m =

Cu 5: Chia 0,16 mol hon hp X gom hai anehit n chc A va nh chc B (M A < MB) thanh hai phan bang nhau. Hiro hoa phan mot can va ung 3,584 lt H2 (ktc). Cho phan hai tac dung vi mot lng d dung dch AgNO3/NH3 thu c 25,92 gam Ag va 8,52 gam hon hp hai muoi amoni cua hai axit hu c. Cac phan ng xay ra hoan toan. Thanh phan phan tram khoi lng cua A trong hon hp X la A. 49,12%. B. 50,88%. C. 34,09%. D. 65,91%. Cu 6: Chia m gam hn hp 2 anehit n chc mach h thanh 2 phn bng nhau Phn 1 tac dung vi lng d AgNO3 trong NH3 thu c 86,4 gam Ag kt tua Phn 2 tac dung va u vi 1 gam hiro co xuc tac Niken nung nong thu c hn hp ancol Y. Ngng tu Y ri cho toan b vao binh cha Na thy khi lng binh tng (0,5m+0,7) gam. Cng thc cua 2 anehit la: A. HCHO va C2H5CHO B. CH2CHCHO va HCHO C. CH2CHCHO va CH3CHO D. HCHO va CH3CHO Cu 7: Hn hp A gm 2 anehit no n chc mach h Y,Z (MY <MZ). Chia A thanh 2 phn bng nhau. Phn 1. tac dung vi dung dich AgNO3 trong NH3 d thu c 64,8 gam Ag Phn 2. oxi hoa hoan toan thanh hn hp axit B. Trung hoa C cn 200ml dung dich NaOH 1M thu c dung dich D. C can D, t chay hoan toan cht rn sinh ra thu c 8,96 lit CO2 (ktc). Cng thc phn t cua Z la: Bin son GV Phm Tun 5

11a 25V . 25 28

B. m =

11a 25V + . 25 28

C. m =

11a 5V . 25 8

D. m =

11a 5V + . 25 8

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc A. C2H5CHO B. C3H7CHO C. C4H9CHO D. CH3CHO Cu 8:. Cho s chuyn ha sau y: C2H6O2 C2H2O2 (X): C2H4O2. Cht X khng c tnh cht no sau y: A. Tc dng c vi Na, B. Tc dng c vi dung dch AgNO3/NH3. C. Tc dng c vi dung dch CH3COOH. D. Tc dng c vi Na2CO3 v NaOH. Cu 9 :. Hn hp gm hai anhit n chc A v B c chia thnh hai phn bng nhau: - Phn mt un nng vi dung dch AgNO3/NH3 d th to ra 10,8 gam Ag. - Phn hai oxi ha to thnh hai axit tng ng, sau cho hai axit ny phn ng vi 250 ml dung dch NaOH 0,26M c dung dch A. trung ha lng NaOH d trong dung dch A cn dng ng 100 ml dung dch HCl 0,25M. C cn dung dch A, em t chy cht rn c cn to c 3,52 gam CO 2 v 0,9 gam H2O. Cng thc phn t ca hai anhit A v B l: A. HCHO v C2H5CHO. B. HCHO v C2H3CHO C. HCHO v CH3CHO D. CH3CHO v C2H5CHO Cu 10: Trng bc hon ton 5,72g mt anehit X no n chc, mch h. Ton b lng bc thu c em ho tan ht vo dung dch HNO3 c nng gii phng V lt kh NO2 (sn phm kh duy nht). Sau phn ng khi lng dung dch thay i 16,12g (gi s hi nc bay hi khng ng k). Cng thc cu to thu gn ca X l: A. CH3CHO B. HCHO C. C2H5CHO D. C3H7CHO Cu 11: Khi cho 1 mol andehit A mach h tac dung va u vi a mol H2 thu c 1 mol ancol B. Cho 1 mol ancol B tac dung vi Na d thu c b mol H2 . Biet a = 4 b. A thuc dy ng ng no trong s cc ng ng sau: A. andehit 1ni i C = C ,n chc B. Andehit no, n chc . C. Andehit no, hai chc . D. andehit 1ni i C = C , hai chc. Cu 12: Oxi ha 3,75 gam mt anehit n chc X bng oxi c xc tc thu c 5,35 gam hn hp Y gm axit, anehit d. t chy hon ton X ri cho sn phm chy hp th vo dung dch Ca(OH)2 d th khi lng kt ta thu c l A. 12,5 gam B. 17,05 gam. C. 19,4 gam. D. 25 gam Cu 13: Cho hn hp kh X gm HCHO v H 2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c x mol CO 2 v (x+0,3) mol H2O ( ktc). Cho Y tcdng vi lng d AgNO 3/NH3, sinh ra 21,6 gam Ag. Phn trm theo th tch ca H 2 trong X l A. 65,00%. B. 46,15 % C. 35,00% D. 53,85%. Cu 14: Cho 0,25 mol hn hp X gm 2 anhit no n chc tc dng vi dung dch AgNO3d /NH3 sinh ra 0,7 mol Ag. Mt khc khi t chy hon ton X thu c 24,2 gam CO. Cng thc 2 anhit l A. CH3CHO v C2H5CHO B. HCHO v CHCHO C. HCHO v C3H7CHO D. HCHO v C2H5CHO. Cu 15: Ho hi 2,28 gam hn hp 2 andehit c th tch ng bng th tch ca 1,6 gam oxi cng iu kin, mt khc cho 2,28 gam hn hp 2 andehit trn tc dng vi AgNO3 trong NH3 d thu c 15,12 gam Ag. Cng thc phn t 2 andehit l A. CH2O v C2H4O B. CH2O v C2H2O2 C. C2H4O v C2H2O2 D. CH2O v C3H4O

Phn 4: axit cacboxylic ( 2 3 cu )

Cu 1: Hn hp X gm HCOOH v CH 3COOH ( t l mol 1:1); hn hp Y gm CH 3OH v C2H5OH ( t l mol 3 : 2). Ly 11,13 gam hn hp X tc dng vi 7,52 gam hn hp Y c xc tc H 2SO4 c, un nng. Khi lng ca este thu c l ( bit hiu sut cc phn ng este u 75%) A. 10,89 gam B. 11,4345 gam C. 14,52 gam D. 11,616 gam Cu 2: Sp xp cc cht sau y theo trnh t gim dn nhit si: CH3COOH (1), HCOOCH3 (2), CH3CH2COOH (3),CH3COOCH3 (4), CH3CH2CH2OH (5). A. (3) > (1) > (4) > (5) > (2). B. (1) > (3) > (4) > (5) > (2). Bin son GV Phm Tun 6

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc C. (3) > (1) > (5) > (4) > (2). D. (3) > (5) > (1) > (2) > (4). Cu 3: Cho cc cht sau y: 1)CH 3COOH, 2)C2H5OH, 3)C2H2, 4)CH3COONa, 5)HCOOCH=CH2, 6)CH3COONH4. Dy gm cc cht no sau y u c to ra t CH3CHO bng mt phng trnh phn ng l: A. 1, 2, 3, 4, 5, 6. B. 1, 2, 6. C. 1, 2. D. 1, 2, 4, 6. Cu 4: Cho 0,7 mol hn hp gm 2 axit hu c ( mi axit cha khng qu 2 nhm -COOH ) phn ng va dd Na2CO3 thu c lng mui hu c nhiu hn khi lng axit l 26,4 g. Cng thc ca 2 axit l: A: CH2(COOH)2 v C6H5COOH B: HCOOH v CH3COOH C: HOOC - COOH v CH2(COOH)2 D: CH3COOH v CH2=CH- COOH Cu 5: Sp xp theo th t tnh axit tng dn ca cc cht sau: CH3OH (1) , C2H5OH (2) , H2O (3) , C6H5OH (4) , ClCH2-CH2-COOH (5) , CH3COOH (6) , ClCH2COOH (7) ? A. (2)<(1)<(3)<(4)<(6)<(5)<(7) B. (3)<(2)<(1)<(4)<(6)<(5)<(7). C. (1)<(2)<(3)<(4)<(6)<(5)<(7) D. (1)<(2)<(3)<(4)<(5)<(6)<(7). Cu 6: Cho 20,15 gam hn hp 2 axit no n chc tc dng va vi dung dch Na 2CO3, thu c V(lit) kh CO2 (ktc)v dung dch, c cn dung dch thu c 28,96 gam mui . Gi tr ca V l: A.4,84lt B.4,48lit C.2,24lit D.2,42lt. Cu 7: Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc l ng ng k tip. t chy hn hp X v cho sn phm (CO 2, H2O)ln lt qua bnh 1 ng H 2SO4c, bnh 2 ng KOH d, thy khi lng bnh 2 tng nhiu hn bnh 1 nhiu hn bnh mt l 3,51 gam. Phn cht rn Y cn li sau khi t l Na2CO3 cn nng 2,65 gam. Cng thc phn t ca hai mui natri l A.CH3COONa,C2H5COONa. B.C3H7COONa,C4H9COONa. C.C2H5COONa,C3H7COONa. D.ktqukhc. Cu 8: trung ho 8,3 gam hn hp 2 axit n chc X, Y cn dng 150 gam dung dch NaOH 4%. Mt khc cng cho khi lng trn tc dng vi lng d dung dch AgNO3 trong NH3 cho 21,6 gam bc. X v Y c cng thc phn t l: A. CH3COOH v C2H5COOH B. HCOOH v CH3COOH C. C2H5COOH v C3H7COOH D. HCOOH v C2H5COOH Cu 9: Hn hp A gm 1 axit no n chc & 2 axit khng no, n chc cha 1 lin kt i k tip nhau trong dy ng ng. Cho A tc dng hon ton vi 150 ml dung dch NaOH 2M. trung ha va ht lng NaOH cn thm vo 100 ml dung dch HCl 1M c dung dch D. C cn cn thn D c 22,89 g rn khan. Mt khc, t chy hon ton hn hp A ri cho ton b sn phm chy hp th vo bnh NaOH c (d), khi lng bnh tng thm 26,72 (g). CTPT 3 axit : A. HCOOH, C2H3COOH, C3H5COOH B. CH3COOH, C2H3COOH, C3H5COOH C. HCOOH, C3H5COOH, C4H7COOH D. HCOOH, C5H9COOH, C4H7COOH Cu 10: t chy hon ton hn hp X gm: HCOOH, CH 3COOH, CH2=CH-COOH. Cho ton sn phm chy vo dung dch nc vi trong d thy thu c 60 gam kt ta v khi lng dung dch gim 24,6 gam. S mol ca CH2=CH-COOH trong hn hp X l A. 0,20. B. 0,15. C. 0,05. D. 0,10. Cu 11: t chy hon ton 29,6 gam hn hp X gm CH3COOH,CxHyCOOH,v (COOH)2 thu c 14,4 gam H2O v m gam CO2. Mt khc, 29,6 gam hn hp X phn ng hon ton vi NaHCO3 d thu c 11,2 lt (ktc) kh CO2.Tnh m: A. 52,8 gam B. 48,4 gam C. 44 gam D. 33 gam Cau 12:. Hon hp X gom axit CH3COOH va axit CH2=CH-COOH t le mol 2:1. Lay 12.8 gam hon hp X cho tac dung vi 18 gam C 3H7OH co xuc tac H2SO4 ac thu c m gam hon hp este ( hieu suat cac phan ng este hoa eu bang 60%). Gia tr cua m la: ( Cho C =12, H =1, O =16). A. 12,72 B. 18,36 C. 19,08 D. 21,2 Cu 13: Axit Malic (2-hiroxi butanioic) c trong qu to. Cho m gam axit Malic t/d vi Na d thu c V1 lt kh H2. Mt khc, cho m gam axit Malic t/d vi NaHCO3 d thu c V2 lt kh CO2 (Th tch cc kh o cng iu kin). Mi quan h gia V1 v V2 l: Bin son GV Phm Tun 7

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc A. V1 = 0,5V2. B. V1 = V2. C. V1 = 0,75V2. D. V1 = 1,5V2. Cau 14:. Hon hp X gom mot axit no n chc mach h va mot ru ( ancol ) no n chc mach h co phan t khoi bang nhau. Chia m gam X thanh hai phan bang nhau: - ot chay het phan 1 roi cho san pham chay hap thu qua dung dch Ba(OH)2 co d thu c 7,88 gam ket tua. - Cho phan 2 tac dung het vi Na thu c 168 ml H2 (ktc). Cong thc cau tao cua A va B co the la: ( Cho C =12, H = 1, O =16, Ba = 137) A. HCOOH va C2H5OH. B. CH3COOH va C3H7OH. C. C2H5COOH va C4H9OH. D. CH3COOH va C2H5OH. Cu 15: Cho hn hp X gm ancol etylic v hai axit cacboxylic no, n chc k tip nhau trong dy ng ng tc dng ht vi Na gii phng ra 8,96 lt H 2 (ktc). Nu un nng hn hp X (c H 2SO4 c xt) th cc cht trong hn hp phn ng va vi nhau to thnh 34,88 gam este (gi thit cc phn ng este ho xy ra nh nhau v t hiu sut 80%). Hai axit cacboxylic trong hn hp l A. C3H7COOH & C4H9COOH. B. CH3COOH & C2H5COOH C. C2H5COOH & C3H7COOH. D. HCOOH & CH3COOH. Cu 16:. Cho cc s chuyn ha sau y: +Br +NaOH (1). Xiclopropan A1
2

A2 B3
+Cl2 , 500oC

+CuO +CH3COOH, H+, to

A3

+AgNO3/NH3

A4

+NaOH

A5

+NaOH CaO, to

CH4

(2). Isopren

+HBr

B1

+NaOH

B2

+H2

CH3COO(CH2)2CH(CH3)2. C3
+NaOH

(3). Prpan -1-ol

+H2SO4 c 170oC
o

C1
+Br2/as

C2

+Cl2 + H2O

C4

+HNO3 c

Glixerin trinitrat.

+HCl (4) CaC2 +HCl D1 +600 C D2 D3 +NaOH D4 Phenol. Cc s no sau y biu din ng: A. (1), (2), (3) B. (1), (2), (3), (4) C. (2), (4) D. (2), (3). Cu 17: Hn hp X gm 2 cht hu c A, B ch cha mt loi nhm chc. Cho m gam X tc dng ht vi NaOH thu c mt mui ca axit hu c n chc v hn hp 2 ancol, tch nc hon ton hai ancol ny iu kin thch hp ch thu c mt anken lm mt mu va 24 gam Br 2. Bit A, B cha khng qu 4 nguyn t cacbon trong phn t. Gi tr ca m l : A. 22,2 g B. 11,1 g C. 13,2 g D. 26,4 g Cu 18: Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO 3 d th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O 2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l A. 0,8. B. 0,3. C. 0,6. D. 0,2.

Phn 5: este , lipit ( 2 3 cu )

Cu 1: t chy hon ton mt lng hn hp hai este n chc no, mch h cn 3,976 lt oxi (ktc) thu c 6,38 gam CO2. Cho lng este ny tc dng va vi KOH thu c hn hp hai ancol k tip v 3,92 gam mui ca mt axit hu c. Cng thc ca hai cht hu c trong hn hp u l: A. HCOOC3H7 v HCOOC2H5 B. CH3COOCH3 v CH3COOC2H5 C. C2H5COOC2H5 v C2H5COOCH3 D. CH3COOC2H5 v CH3COOC3H7 Cu 2: t chy 1,7 gam este X cn 2,52 lt oxi (ktc), ch sinh ra CO 2 v H2O vi t l s mol nCO2 : nH2O = 2. un nng 0,01 mol X vi dung dch NaOH thy 0,02 mol NaOH tham gia phn ng. X khng c chc ete, khng phn ng vi Na trong iu kin bnh thng v khng kh c AgNO 3, trong amoniac ngay c khi un nng. Bit Mx < 140. Cng thc cu to ca X l A. CH3COOC6H5 B. C2H3COOC6H5 C. HCOOC6H5 D. C2H5COOC6H5 Bin son GV Phm Tun 8

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc Cu 3: Mt este c cng thc phn t C4H6O2. Thu phn ht X thnh hn hp Y. X c cng thc cu to no Y cho phn ng trng gng to ra lng Ag ln nht? A. CH3COOCH = CH2 B. HCOOCH2CH = CH2 C. HCOOCH = CHCH3 D. CH2 = CHCOOCH3 Cu 4: Thu phn hon ton glixerol trifomiat trong 200 gam dung dch NaOH c cn dung dch hn hp sau phn ng thu c 28,4 gam cht rn khan v 9,2 gam ankol. Xc nh nng % ca dung dch NaOH? A. 8% B. 10% C. 12% D. 14% Cu 5: Hp cht hu c A cha mt loi nhm chc c cng thc phn t C 8H14O4. Khi thu phn A trong dung dch NaOH c mt mui v hn hp hai ancol X, Y. Phn t ancol Y c s nguyn t cacbon nhiu gp i s nguyn t cacbon trong phn t ancol X. Khi un nng vi H 2SO4 c, X cho mt olefin, Y cho hai olefin ng phn. Cng thc cu to ca A l: A. CH3OOCCH2CH2COOC3H7 B. C2H5 OOC- COO[CH2]3CH3 C. C2H5OOCCH2COOCH(CH3)2 D. C2H5OOC- COOCH(CH3)C2H5 Cu 6: Cho 0,0 1 mol mt este X phn ng va ht vi 100 ml dung dch NaOH 0,2M, sn phm to ra ch gm mt mui v mt ancol u c s mol b?ng s mol este, u c cu to mch cacbon khng phn nhnh. Mt khc x phng ho hon ton mt lng este X bng dung dch KOH va , th va ht 200 ml KOH 0,15M v thu c 3,33 gam mui. X l: A. imetyl aipat. B. Etylenglycol oxalat. C. ietyl oxalat D. Etylenglicol aipat Cu 7: t chy hon ton 0,25 mol hn hp hai este no, mch h, n chc l ng ng lin tip thu c 19,712 lit kh CO2 (ktc). X phng ha cng lng este trn bng dung dch NaOH to ra 17 gam mt mui duy nht. Cng thc ca hai este l : A. HCOOC2H5 v HCOOC3H7 B. CH3COOCH3 v CH3COOC2H5 C. HCOOC3H7 v HCOOC4H9 D. CH3COOC2H5 v HCOOC2H5 Cu 8: Pht biu ng l: A. Phn ng thy phn este trong mi trng axit l phn ng thun nghch. B. Khi thy phn cht bo lun thu c C2H4(OH)2. C. Phn ng gia axit v ancol khi c H2SO4 c l phn ng mt chiu. D. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ancol. Cau 9: Thuy phan hoan hon hp X gom hai este hai chc, mach h co cung cong thc phan t C4H6O4 can va ung 100 ml dung dch NaOH 1M, roi co can thu c 6,76 gam hon hp muoi va a gam hon hp ancol. Oxi hoa toan bo lng ancol sinh ra bang CuO roi cho toan bo san pham tao thanh tac dung vi mot lng d dung dch AgNO3/NH3 thu c m gam ket tua. Cac phan ng xay ra hoan toan. Gia tr cua m la A. 34,56. B. 43,20. C. 51,84. D. 30,24. Cau 10: ot chay hoan toan a mol chat beo A thu c b mol CO2 va c mol H2O. Biet b c = 5a, va hiro hoa hoan toan m gam A can va ung 2,688 lt H 2 ( ktc) thu c 35,6 gam san pham B. Mat khac thuy phan hoan toan m gam A trung tnh bang mot lng dung dch NaOH va u, roi co can thu c x gam xa phong. Gia tr cua x la A. 36,48. B. 12,16. C. 36,24. D. 12,08. Cu 11: Thc hin phn ng este ho gia axit axetic v hn hp gm 8,4 gam 3 ancol l ng ng ca ancol etylic. Sau phn ng thu c 16,8 gam 3 este. Ly sn phm ca phn ng este ho trn thc hin phn ng x phng ho vi dung dch NaOH 4 M th thu c m gam mui: (Gi s hiu sut phn ng este ho l 100%). Gi tr ca m l A. 10,0gam B. 16,4gam C. 20,0gam D. 8,0gam Cu 12: t chy hon ton gam hh X gm hai este ng phn ca nhau cn dng 0,525 mol O2 v thu c 0,45 mol CO2, 0,45 mol H2O. Nu cho m gam X t/d ht vi 0,2 mol NaOH, ri kh cn dd to thnh cn li 12,9 gam cht rn khan. Phn trm khi lng ca este c gc axit nh hn trong X l. Bin son GV Phm Tun 9

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc A. 60 B. 33,33 C. 66,67 D. 50 Cu 13: Este X tc dng vi NaOH theo t l mol 1:2 thu c mt mui ca axit hu c Y v mt ancol Z c s mol bng nhau v bng s mol X phn ng. Cho 11,6 gam X phn ng va vi 200 ml dung dch NaOH 1M thu c 6,2 gam ancol Z. Cng thc phn t ca axit Y l A. C3H4O4. B. C2H2O4. C. C4H4O4. D. C2H4O2 Cu 14: Hp cht X l ancol no, a chc. t chy ht 0,1 mol X cn 0,25 mol O 2. Cho 100 gam X tc dng vi 150 gam axit axetic (xc tc H2SO4 c, t0) thu c 109,5 gam cht Z (a chc). Tnh hiu sut ca phn ng to Z. A. 50%. B. 65%. C. 60%. D. 75%. Cu 15: X phng ho hon ton 20,4 gam cht hu c X n chc bng dung dch NaOH thu c mui Y v cht hu c Z. Nung Y vi NaOH rn cho kh R.Bit dR/O2 = 0,5. Cho Z tc dng vi Na thu c 2,24 lt H2 ktc. Z tc dng vi CuO nng cho sn phm tham gia phn ng trng bc. Vy X l: A. etyl axetat B. Isopropyl axetat C. etyl propyonat D. propyl axetat Cu 16: Cho hn hp X gm ancol etylic v hai axit cacboxylic no, n chc k tip nhau trong dy ng ng tc dng ht vi Na gii phng ra 8,96 lt H 2 (ktc). Nu un nng hn hp X (c H 2SO4 c xt) th cc cht trong hn hp phn ng va vi nhau to thnh 34,88 gam este (gi thit cc phn ng este ho xy ra nh nhau v t hiu sut 80%). Hai axit cacboxylic trong hn hp l A. C3H7COOH & C4H9COOH. B. CH3COOH & C2H5COOH C. C2H5COOH & C3H7COOH. D. HCOOH & CH3COOH. Cu 17: Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. CH3COOH v CH3COOC2H5 B. C2H5COOH v C2H5COOCH3. C. HCOOH v HCOOC2H5. D. HCOOH v HCOOC3H7 Cu 18: un nng 0,01 mol cht Y vi dung dch NaOH d thu c 1,34 g mui ca mt axit hu c Z v 0,92 g ancol n chc. Nu cho ancol bay hi th chim th tch l 0,448 lt kc. CT ca Y: A.(COOC2H5)2 B.C2H5(COOCH3)2. C. CH3COOC2H5 D. CH2(COOC2H5)2

Phn 6: gluxit ( 1 -2 cu )
Cu 1: Thy phn hon ton mt lng mantoz, sau cho ton b lng glucoz thu c ln men thnh ancol etylic th thu c 100 ml ru 460. Khi lng ring ca ancol l 0,8gam/ml. Hp th ton b kh CO 2 vo dung dch NaOH d thu c mui c khi lng l: A. 84,8 gam. B. 42,4 gam. C. 212 gam. D. 169,6 gam. Cu 2: Mt loi mn ca cha 60% xenluloz c dng lm nguyn liu iu ch ancol etylic. Bit hiu sut ca qu trnh l 70%. Khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml. T 1 tn mn ca trn iu ch c th tch cn 70o l: A. 310,6 lt B. 306,5 lt C. 425,9 lt D. 305,7 lt Cu 3: Pht biu no di y l ng ? A. Trong dung dch, glucozo, saccarozo, fructozo, tinh bt u tc dng vi Cu(OH)2 cho dd mu xanh lam. B. Fructzo c phn ng trng bc, chng t phn t fructozo c nhm chc CHO. C. Trong mi trng kim, un nng mantozo cho kt ta gch D. Khi thu phn n cng saccarozo, tinh bt v xenlolozo u cho mt monosaccarit Cu 4: Cho xenlulozo phn ng vi anhidrit axetic (H2SO4 xc tc) thu c 4,2 g CH3COOH v 7,8 g hn hp X gm : xenlulozo triaxetat v xenlulozo iaxetat. Thnh phn % theo khi lng ca cc cht trong hn hp X l: A. 36,92% & 63,08% B. 39,87% & 60,13% Bin son GV Phm Tun 10

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc C. 65.94% & 34,06% D. 47.92% & 52.08% Cu 5: Hon hp X gom mantoz va saccaroz c chia thanh hai phan bang nhau. Phan mot phan ng va u vi 4,9 gam Cu(OH)2. Thuy phan phan hai, trung hoa dung dch sau phan ng va bang phng phap thch hp, tach thu c m gam hon hp Y, toan bo hon hp Y lam mat mau va ung 160 ml dung dch Br2 1M. Cac phan ng xay ra hoan toan. Khoi lng hon hp X la A. 34,20. B. 68,40. C. 54,72. D. 109,44. men + H 2O / H + Cu 6: S iu ch ancol etylic t tinh bt: Tinh bt glucoz ancol etylic. Ln men 162 gam tinh bt vi hiu sut cc giai on ln lt l 80% v 90%. Th tch dung dch ancol etylic 40 0 thu c l (Bit khi lng ring ca C2H5OH nguyn cht l 0,8 g/ml) A. 230 ml B. 207 ml C. 115 ml D. 82,8 ml Cu 7: Ln men m gam glucozo vi hiu sut 70% ri hp th ton b kh thot ra vo 4 lt dung dch NaOH 0,5M ( D=1,05g/ml ) thu c dung dch cha 2 mui c tng nng l 3,211%. Gi tr ca m l: A. 384,7 B. 135,0 C. 270,0 D. 192,9 Cu 8. 10 kg glucoz co lan tap chat ( 2%) len men thanh ancol etylic. Neu qua trnh len men ancol b hao hut 10% th lng ancol thu c la: A. 9,00 kg. B. 1,8 kg C. 4,50kg D. 3,6 kg. Cu 9:.Saccarozo co the tac dung vi hoa chat nao cho di ay? (1). Cu(OH)2 (2). AgNO3/NH3 (3). H2/Ni, to (4). H2SO4 loang, nong. A. (1), (4) B. (2), (3) C. (1), (2) D. (3), (4). Cu 10: Thy phn 68,4 gam saccaroz vi hiu sut 60%. Dung dnh sau phn ng chia thnh hai phn bng nhau. Phn I tc dng vi dung dch AgNO3 trong NH3 d thu c x mol Ag. Phn II lm mt mu va dung dch cha y mol brom. Gi tr ca x, y ln lt l:A. 0,24; 0,06. B. 0,12; 0,06. C. 0,32; 0,1. D. 0,48; 0,12. Cu 11: Ch dng Cu(OH)2/OH c th nhn bit c cc dung dch ng ring bit tng cht trong nhm no sau y? A. Glucoz, sobitol, axit axetic, etanal, anbumin. B. Glucoz, fructoz, glixerol, axit axetic, metanol. C. Anbumin, axit acrylic, axit axetic, etanal, glucoz. D. Sobitol, glucoz, tripeptit, ancol etylic, glixerol. Cu 12: Ln men a gam glucoz vi hiu sut 90%, lng CO2 sinh ra hp th ht vo nc vi trong thu c 10 gam kt ta v khi lng dung dch gim 3,4 gam. Khi lng a bng : A. 13,5 gam. B. 15,0 gam. C. 20,0 gam. D. 30,0 gam. Cu 13: Th tch dung dch HNO3 96% (D = 1,52 g/mL) cn dng tc dng hon ton vi lng d xenluloz to 29,7 gam xenluloz trinitrat l : A. 12,95 ml. B. 29,50 ml. C. 2,950 ml. D. 1,295 ml. Cu 14: C th tng hp ancol etylic t CO 2 theo s sau: CO2 Tinh bt Glucoz Ancol etylic. Tnh th tch CO2 sinh ra km theo s to thnh ancol etylic nu CO2 lc u dng l 1120 lt (ktc) v hiu sut ca mi qu trnh ln lt l 50%, 75%, 80%. A. 373,3 lt B. 280,0 lt C. 149,3 lt D. 112,0 lt Cu 15: Ln men m g glucoz vi hiu sut 72%. Lng CO 2 sinh ra c hp th hon ton vo 500 ml dung dch hn hp gm NaOH 0,1M v Ba(OH)2 0,2M, sinh ra 9,85 g kt ta. Gi tr ca ln nht ca m l A. 25,00. B. 12,96. C. 6,25. D. 13,00.

Phn 7: amin ( 1 - 2 cu )
Cu 1: t chy hon ton m gam hn hp X gm cc amin ng ng ca vinylamin thu c 41,8 gam CO 2 v 18,9 gam H2O . Gi tr ca m l: A. 16,7 gam B. 17,1 gam C. 16,3 gam D. 15,9 gam Bin son GV Phm Tun 11

Bi tp theo cu trc thi i hc mn Ho hc 2012 cp tc

HNO 3 + HCl , Fe + H = 70% ddNaOH H = 100% C6H5NH2

n luyn

Cu 2. Cho s : C6H6 H = 60% C6H5NO2 C6H6NH3Cl 1 tn nha than tch ra c 20kg anilin v 1,6kg C6H6 . Lng anilin thu c t 10 tn nha than l : A.20,081 kg B. 21,6kg C. 208,01 kg D. 219,7 kg Cu 3: t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6 gam CO2, 12,6 gam H2O v 69,44 lt N2 (ktc). Gi thit khng kh ch gm N2 v O2 trong oxi chim 20% th tch khng kh. X c cng thc l A. C2H5NH2. B. C3H7NH2. C. CH3NH2. D. C4H9NH2. Cu 4: Cho cc cht sau NH3 (1), anilin (2), p-nitro anilin (3), p-metyl anilin (4), metyl amin (5), imetyl amin (6) . Th t tng dn lc bazo l: A. 3<2<4<1<5<6 B. 2<3<4<1<5<6 C. 3<1<4<2<5<6 D. 2<3<1<4<5<6 Cu 5: Hon hp X gom amin no, n chc, mach h A va O2 (lng O2 trong X gap 3 lan lng O2 can dung e ot chay hoan toan A). Bat tia la ien ot chay hoan toan hon hp X, thu c hon hp kh Y. Dan hon hp Y i qua bnh ng dung dch H2SO4 ac thu c hon hp kh Z co t khoi hi oi vi H2 la 17,1. Cong thc phan t cua A la A. CH5N. B. C2H7N. C. C3H9N. D. C4H11N Cau 6: ot chay mot amin, no n chc, mach h A trong mot bnh kn bang mot lng khong kh va u 136,50C va ap suat P1 . Sau khi phan ng xay ra hoan toan van gi nhiet o bnh khong thay oi va ap suat luc bay gi la P2. Biet 52P1 = 49P2. Biet khong kh gom co 20% O2 va 80% N2 theo the tch. Cong thc phan t cua A la A. CH5N. B. C2H7N. C. C3H9N. D. C4H11N. Cu 7:. Cc dung dch sau y c cng nng mol (vi dung mi l nc v xt cng iu kin v nhit , p sut): natri hiroxit (1); anilin (2); amoniac (3); metylamin (4); iphenylamin (5); etylamin (6). Dy cc cht c sp xp theo chiu tng dn pH l A. (5); (4); (2); (6); (1); (3) B. (1); (6); (3); (4); (2); (5) C. (1); (4); (2); (5); (3); (6) D. (5); (2); (3); (4); (6); (1) Cu 8: Amin X cha vng benzen v c cng thc phn t C 8H11N. X tc dng vi HNO2 nhit thng gii phng kh nit. Mt khc, nu cho X tc dng vi nc brom th thu c cht kt ta c cng thc C 8H10NBr3. S cng thc cu to ca X l: A. 2 B. 3 C. 5 D. 6 Cu 9 : 42.8g mt hn hp X gm 2 amin no A, B, n chc ng ng k tip. Chia X lm 2 phn bng nhau P1: tc dng va vi 0.3 lit dd H2SO4 1 M. P2: t chy cho ra V lt N2 Xc nh CTPT, s mol mi amin v V A. 0.4 mol CH3-NH2, 0.2 mol C2H5-NH2, 3.36l N2 B. 0.8 mol C2H5-NH2, 0.4 mol C3H7- NH2, 11.2 l N2 C. 0.6 mol C2H5-NH2. 0.3 mol C3H7-NH2, 8.96 l N2 D. 0.8 mol CH3-NH2, 0.4 mol C2H5-NH2, 6,72 l N2 Cu 10: Hn hp X gm 3 amin n chc no l ng ng k tip nhau c theo th t khi lng mol phn t tng dn vi t l s mol tng ng 1:10:5. Cho 20 gam X tc dng vi dung dch HCl va . C cn dung dch thu c sau phn ng thu c 31,68 gam hn hp mui. CT ca 3 amin l: A. CH3NH2, C2H5NH2, C3H7NH2 B. C2H5NH2, C3H7NH2, C4H9NH2 C. C3H7NH2, C4H9NH2, C5H11NH2 D. C4H9NH2, C5H11NH2, C6H13NH2

Phn 8: aminoaxit ( 2 3 cu )
Bin son GV Phm Tun 12

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc Cu 1: Tripeptit mch h X v tetrapeptit mch h Y u c to nn t mt -aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,2 mol Y thu c tng khi lng CO2 v H2O bng 95,6 gam. t chy hon ton 0,1 mol X, sn phm thu c cho hp th vo dung dch Ba(OH)2 d, sau phn ng khi lng dung dch ny A. gim 81,9 gam B. Gim 89 gam C. Gim 91,9 gam D. gim 89,1 gam Cu 2: t chy hon ton 4,45 gam mt amino axit no, phn t ch cha mt nhm amino v 1 nhm cacboxyl. Dn ton b sn phm chy vo bnh ng dung dch NaOH d th c 0,56 lt kh bay ra(ktc). Cng thc phn t v s ng phn cu to amino axit tho mn c im X l: A: C3H7O2N; 2 p B: C3H7O2N; 3 p C: C2H5O2N; 1 p D: C4H9O2N; 5 p Cu 3: Thy phn mt tripeptit X sn phm thu c ch c alanin. t chy m gam X c 1,05 gam nit. Gi tr ca m l: A. 4,725 g B. 5,775 g C. 5,125 g D. 5,725 g Cu 4: Mt mui X c cng thc C3H10O3N2. Ly 14,64 gam X cho phn ng ht vi 150 ml KOH 1M. C cn dung dch sau phn ng thu c phn hi v cht rn. Trong phn hi c mt cht hu c Y bc 1. Trong cht rn ch l mt hp cht v c. Cng thc phn t ca Y l: A. C3H7NH2 B. C2H5NH2 C. CH3NH2 D. C3H7OH Cu 5: X l mt amino axit. Khi cho 0,2 mol X tc dng va vi HCl thu c 33,9 gam mui. Mt khc cho 0,2 mol X tc dng va vi NaOH thu c 35,4 gam mui. Cng thc phn t ca X l: A. C3H7NO2 B. C4H7NO4 C. C4H6N2O2 D. C5H7NO2 Cu 6: Cho m gam hn hp hai amino axit (trong phn t ch cha 1 nhm amino v 1 nhm cacboxyl) tc dng vi 110 ml dung dch HCl 2M c dung dch X. phn ng ht vi cc cht trong X cn dng 200 gam dung dch NaOH 8,4% c dung dch Y. C cn Y c 34,37 gam cht rn khan. Gi tr ca m l A. 15,1 gam. B. 16,1 gam. C. 17,1 gam. D. 18,1 gam. Cu 7: ng dng no ca amino axit di y c pht biu KHNG ng ? A. Amino axit thin nhin (hu ht l -amino axit) l c s kin to protein ca c th sng. B. Mui inatri glutamat l gia v thc n (gi l bt ngt hay m chnh). C. Axit glutamic l thuc b thn kinh, methionin l thuc b gan. D. Cc amino axit (nhm amin v tr s 6, 7, ...) l nguyn liu sn xut t nilon. Cu 8: t chy hon ton 18,3 g hp cht hu c A cn 13,44 (l) O 2 to ra 13,5 g H2O, 13,44 (l) hn hp CO2 & N2 . un nng 0.15 mol A vi 200 ml dung dch KOH 1M to dung dch Y ch c cc cht v c. C cn dung dch Y thu c bao nhiu gam rn. Bit CTPT trng vi CTG. A. 18,25 gam B. 17,95 gam C. 38,61 gam D. 35,4 gam Cu 9: Cho 0,15 mol hn hp X gm H 2NC3H5(COOH)2 (axit glutamic) v (H2N)2C5H9COOH (lysin) vo 200ml dung dch HCl 1M, thu c dung dch Y. Y phn ng va ht vi 400ml dung dch NaOH 1M. S mol axit glutamic trong 0,15 mol hn hp X l A. 0,075. B. 0,125. C. 0,050. D. 0,100. Cu 10: Thuy phan hoan toan 0,1 mol mot peptit X c cau tao bi glyxin va alanin bang dung dch NaOH roi co can thu c 57,6 gam chat ran. Biet so mol NaOH a dung gap oi so vi lng can thiet va khoi lng chat ran thu c sau phan ng tang hn so vi ban au la 30,2 gam. So cong thc cau tao cua X trong trng hp nay la A. 4. B. 6. C. 8. D. 10. Cu 11. Cht (Y) c cng thc phn t C3H9NO2, d phn ng vi axit ln baz. Trn 1,365 gam (Y) vi 100ml dung dch NaOH 0,2M ri un nng nh, c kh thot ra lm xanh giy qu tm m v dung dch (A), c cn dng dch (A) thu c a gam cht rn. Gi tr ca a l: A. 1, 25 gam B. 2,30 gam C. 1,66 gam D. 1,43 gam

Bin son GV Phm Tun

13

Bi tp theo cu trc thi i hc mn Ho hc 2012 n luyn cp tc Cu 12. Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l A. Gly, Gly. B. Ala, Gly. C. Ala, Val. D. Gly, Val. Cu 13: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hh X v Y c t l s mol nX : nY = 1 : 3 vi 780 ml dd NaOH 1M (va ), sau khi p kt thc thu c dd Z. C cn dd thu c 94,98 gam mui. m c gi tr l A. 68,10 gam. B. 64,86 gam. C. 77,04 gam. D. 65,13 gam Cu 14: Cho m gam hh X gm axit glutamic v alanin t/d vi dd HCl d. Sau p lm bay hi cn thn dd thu c (m + 11,68) gam mui khan. Nu cho m gam hh X t/d vi dd KOH va , sau p lm bay hi cn thn dd thu c (m + 19) gam mui khan. Gi tr ca m l: A. 36,6 gam B. 38,92 gam C. 38,61 gam D. 35,4 gam Cu 15: (X) l hp cht hu c c cng thc phn t C 5H11O2N. un X vi dd NaOH thu c mt hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t o thu c cht hu c (Z) khng c kh nng phn ng trng bc. Cng thc cu to ca (X) l: A. CH3(CH2)4NO2 B. NH2 - CH2 - COO - CH(CH3)2 C. NH2 - CH2COO - CH2 - CH2 - CH3 D. H2N - CH2 - CH2 - COOC2H5 Cu 16: Cho 0,15 mol Lysin tc dng vi 200ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l: A. 0,45 B. 0,55 C. 0,35 D. 0,25 Cu 17: Tripeptit mch h X v tetrapeptit mch h Y u c to ra t mt amino axit no, mch h c 1 nhm COOH v 1 nhm NH2. t chy hon ton 0,2 mol X thu c sn phm gm CO 2, H2O, N2 trong tng khi lng CO2, H2O l 109,8 gam. Nu t chy hon ton 0,3 mol Y cn s mol O2 l: A. 4,5 B. 9 C. 6,75 D. 3,375 Cu 18: Thuy phn hoan toan 1 tetrapeptit X thu c 2 mol glyxin,1 mol alanin,1 mol valin. S ng phn cu tao cua peptit X la: A. 10 B. 24 C. 18 D. 12 Cu 19: Hon hp gom hai hp chat hu c A va B co cung cong thc phan t C4H11O2N. Cho hon hp tac dung vi 600 ml dung dch NaOH 0,1M thoat ra hon hp hai kh eu lam xanh mau giay quy co the tch 1,12 lt va co t khoi hi oi vi H2 la: 19,7 va dung dch A. Co can dung dch A thu c m gam ran khan. Gia tr cua m la: A. 4,78 B. 7,48 C. 8,56 D. 5,68 Cu 20: X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h, c mt nhm -COOH v mt nhm -NH2. t chy hon ton 0,1 mol Y thu c sn phm gm CO 2, H2O, N2, trong tng khi lng ca CO2 v H2O l 47,8 gam. Nu t chy hon ton 0,3 mol X cn bao nhiu mol O2? A. 2,8 mol B. 2,025 mol C. 3,375 mol D. 1,875 mo Cu 21: Hp cht thm X c cng thc phn t C6H8N2O3. Cho 28,08 gam X tc dng vi 200 ml dung dch KOH 2M sau phn ng thu c dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi tr ca m l: A. 18,1 gam B. 21,5 gam C. 38,8 gam D. 30,5 gam Cu 22: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp X v Y c t l s mol nX : nY = 1 : 3 vi 780 ml dung dch NaOH 1M (va ), sau khi phn ng kt thc thu c dung dch Z. C cn dung dch thu c 94,98 gam mui. m c gi tr l A. 68,10 gam. B. 64,86 gam. C. 77,04 gam. D. 65 gam Cu 23 X l mt - aminoaxit mch h, khng phn nhnh. C 1 mol X tc dng ht vi dung dch cha 1 mol HCl to ra 183,5 gam mui. C 147 gam X tc dng ht vi dung dch NaOH thu c 191 gam mui. Ch ra pht biu ng v X : A. t chy hon ton 0,1mol X thu c 0,5 mol CO2 Bin son GV Phm Tun 14

Bi tp theo cu trc thi i hc mn Ho hc 2012 cp tc B. Dung dch X lm qu tm ha xanh. C. Dung dch X khng i mu giy qu. D. t chy hon ton 0,1mol X thu c 0,1 mol N2.

n luyn

Phn 9: polime ( 1 -2 cu )
Cu 1: Mun tng hp 120kg poli ( metylmetacrylat) th khi lng ca 2 axit v ancol tng ng cn dng l bao nhiu Bit hiu sut qu trnh este ho v trng hp ln lt l 60% v 80% . A. 171 kg v 82kg B. 65kg v 40kg C. 215kg v 80kg D. 175kg v 70kg Cu 2: Thy phn hon ton 200 gam hn hp t tm v lng cu th thu c 31,7 gam glyxin. Bit phn trm khi lng glyxin trong t tm l 43,6%, trong lng cu l 6,6 %. T l % khi lng t tm v lng cu ln lt l: A. 25% v 75% B. 50% v 50% C. 43,6% v 56,4% D. Kt qu khc Cu 3: Cao su buna-N c to ra do phn ng ng trng hp gia buta-1,3-ien vi acrylonitrin (CH2=CHCN). t chy hon ton cao su buna-N vi khng kh va , sau a hn hp sau phn ng v 136,5o thu c hn hp kh Y ch 14,41% CO2 v th tch. T l mc xch gia buta-1,3-ien v acrylonitrin: A. 3:2 B. 2:1 C. 2:3 D. 1:2 Cu 4: Cao su lu hoa co cha 3,14% lu huynh. Gia thiet rang S a thay the cho H cau metylen trong mach cao su. So mat xch isopren co mot cau isunfua S S la A. 34. B. 36. C. 32. D. 30. Cu 5: Pht biu no sau y l ng: A. T nilon-6,6 thuc loi t poliamit, c iu ch bng phn ng ng trng hp cc monome tng ng. B. Ancol o-hiroxibenzylic l sn phm trung gian trong qu trnh iu ch nha novolac t phenol v fomanehit. C. T visco, t xenluloz axetat, t nitron cng thuc loi t nhn to. D. Cao su buna-S thu c khi cho cao su buna tc dng vi lu hunh

Bin son GV Phm Tun

15