GV:L Vn Thnh

Lp: 10A3

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT A- HIROSUNFUA NI DUNG BI HC

I- CU TO PHN T . II- TNH CHT VT L. III-TNH CHT HA HC . IV- TRNG THI T NHIN V IU CH. V- TNH CHT CA MUI SUNFUA .

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT

I- CU TO PHN T: Cng thc phn t: H2S

Hy

vit cng thc electron, cng thc cu to ca phn t H2S v xc nh s oxi ho ca S trong hp cht ny.

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT .. Phn t H2S c cng thc electron: H :S: .. H Cng thc cu to: H-S-H S oxi ho ca S l -2

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT

II- TNH CHT VT L:

Hirosunfua c nhng tnh cht vt l nh th no?

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT

II- TNH CHT VT L:

L

cht kh, khng mu, mi trng thi v rt c Ho lng -600C, ho rn 860C Nng hn khng kh, t tan trong nc.

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT

III- TNH CHT HA HC: Hiro sunfua c nhng tnh cht

ha hc g ?

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT 1-Tnh axit yu: Hirosunfua tan trong nc to thnh dung dch axit rt yu (yu hn axit cacbonic), c tn l axit sunfuhiric.
H2S + NaOH NaHS + H2O

(Natri hirosunfua)
(Natri sunfua)

H2S + 2NaOH Na2S +2 H2O

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT

Hy vit phng trnh phn ng ha hc khi cho axit sunfuhiric tc dng vi dung dch NaOH?

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT 2. Tnh kh mnh V sao hiro sunfua c tnh kh mnh? 2H2S + 3O2 2SO2 +2H2O ( oxi) 2H2S + O2 2S + 2H2O (thiu oxi) Clo c th oxi ho H2S thnh H2SO4
-2 0 -2 t0

+4

H2S +4Cl2 +4H2O H2SO4 +8HCl

-2

+6

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT IV- TRNG THI T nhin V IU CH 1- Trng thi t nhin

Trong t nhin,hiro sunfua c trong mt s nc sui,trong kh ni la v bc ra t xc cht ca ngi v ng vt

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT IV- TRNG THI T nhin V IU CH

2- iu ch: Trong cng nghip: Khng iu ch . Trong phng th nghim:

FeS +2HCl FeCl2 + H2S

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT V- TNH CHT CA MUI SUNFUA:

Mui sunfua ca kim loi nhm IA, IIA (tr Be) nh Na2S, K2S tan trong nc v tc dng vi dung dch HCl, H2SO4 long sinh ra kh H2S.

Mui sunfua ca mt s kim loi nng nh PbS,CuSkhng tan trong nc, khng tc dng vi dung dch HCl, H2SO4 long. Mui sunfua ca nhng kim loi cn li nh ZnS, FeS
khng tan trong nc , nhng tc dng vi dung dch HCl, H2SO4 long sinh ra kh H2S. Mt s mui c mu c trng: CdS:mu vng, PbS,CuS,FeS, Ag2S : mu en , MnS: Mu hng, SnS: mu gch

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT

Mui sunfua

(FeS, ZnS)
+ HCl H2SO4 long NaHS Na2S

+ NaOH

Hiro sunfua (H2S)

+X2 +H2O

H2SO4
+ HX

Thiu
S + H2O

+ O2

D SO2 + H2O

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT V sao trong t nhin c nhiu ngun phng thi ra kh H2S nhng li khng c s tch t kh trong khng kh? Do H2S c tnh kh mnh nn n b oxi ca khng kh oxi ho n S. 2H2S + O2 2S + 2H2O

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT V sao cc vt bng bc, ng lu ngy trong khng kh b xm en? Do Ag,Cu tc dng vi kh H2S v O2 trong khng kh to ra Ag2S, CuS mu en. 4 Ag + 2H2S + O2 2Ag2S + 2H2O

2Cu + 2H2S + O2 2 CuS + 2H2O

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT BI TP TRC NGHIM CNG C Cu1: Cho s chuyn ha sau: X
+ Fe
t0

+HCl

+NaOH 1mol:2mol

+ Pb(NO3)2

PbS

Cc cht X, Y, Z, M ln lt l: Sai A. S, FeS2, H2S, Na2S. ng B. S, FeS, H2S, Na2S. C. S, FeS2, H2S, NaHS. Sai Sai D. S, FeS, H2S, NaHS.

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT Cu2: T bt Fe, S, dung dch HCl c th c my cch iu ch c H2S ?

A. 1 B. 2
C. 3

Sai

ng Sai
Sai

D. 4

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT

Cu3: Cho hn hp gm Fe v FeS ho tan vo dung dch HCl d thu c 6,72 lt hn hp kh(ktc). Dn hn hp kh ny qua dung dch Pb(NO3)2 d thu c 47,8 g kt ta en. Thnh phn phn trm theo khi lng ca Fe v FeS trong hn hp ban u l: A. 25,2% v 74,8%. B. 32% v 68%. C. 24,14% v 75,86%. D. 60% v 40%.

Sai Sai ng Sai

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT Cu4: t chy hon ton 3,4 g mt cht X thu c 6,4 g SO2 v 1,8 g H2O. X c cng thc phn t l: A. H2S B. H2SO3 C. H2SO4 D. H2S2O7 ng Sai Sai Sai

BI TP V NH
Cu1: Vit cc phng trnh phn ng thc hin dy bin ha sau. Ghi r iu kin phn ng (nu c)

H2 S

ZnS

H2S

K2S

CuS

SO2 Cu2: Nung 5,6 g Fe vi 1,6 g S trong mi trng khng c khng kh.Sn phm phn ng cho tc dng vi dung dch HCl d. Kh sinh ra c dn vo dung dch CuSO4.Tnh th tch dung dch CuSO4 10% (D =1,1 g/ml) cn phi ly hp th ht kh sinh ra v

khi lng kt ta thu c.

Lm cc bi tp: 3,8,9 trang 138,139 (SGK)

Tit: 53

HIRO SUNFUA

LU HUNH IOXIT- LU HUNH TRIOXIT HNG DN CHUN B BI MI

Tnh cht vt l, tnh cht ha hc , ng dng v iu ch ca Lu hunh ioxit v Lu hunh trioxit.

Fe + 2HCl FeCl2 + H2 0,1 0,1 FeS + 2HCl FeCl2 + H2S 0,2 0,2

(1)
(2)

H2S + Pb(NO3)2 PbS + 2HNO3 (3) 0,2 0,2 6,72 47,8 n n = = = 0,2 PbS hh kh 22,4 293 m Fe = 0,1. 56 = 5,6 g 5,6 .100 23,2 m FeS

= 0,3

= 0,2 . 88 = 17,6 g
% FeS = 75,86%

% Fe =

= 24,14%

SO2 = 0,1 mol

H2O

= 0,1 mol m = 0,1 .2 = 0,2 g

m = 0,1 . 32 = 3,2 g S

m + m = 3,4 g X ch c 2 nguyn t H v S S H

S = 0,2 : 0,1 = 2 : 1

Cng thc phn t ca X l: H2S

CM N QU THY C N D! CHC CC EM HC TT!

Mui sunfua

(FeS, ZnS)
+ HCl H2SO4 long NaHS Na2S

+ NaOH

Hiro sunfua (H2S)

+X2 +H2O

H2SO4
+ HX

Thiu
S + H2O

+ O2

D SO2 + H2O