CHUYN AMIN-AMINOAXIT Cu 1. Hy cho bit kt lun no sau y ng nht? A.

. Nguyn nhn gy ra tnh cht baz ca amin l do phn t c cha N c m in ln. B. Do amin c to lin kt hiro vi nc v vi cc axit. C. Do amin c nguyn t Nit lin kt vi cc gc hirocacbon. D. Do nguyn t Nit trong amin cn cp electron cha lin kt linh ng c th to lin kt cho nhn vi H+. Cu 2. Cht no sau y khng c kt ta trng khi cho dung dch Br2 vo dung dch cht ? A. phenyl amoni clorua B. phenol B. anilin D. p-Metylanilin. Cu 3. Khi cho dung dch NaOH vo dung dch phenyl amoni clorua, hy cho bit hin tng no s xy ra? A. thu c dung dch ng nht B. thu c kt ta trng C. ban u thu c dung dch ng nht sau tch thnh 2 lp. D. tch lun thnh 2 lp. Cu 4. Cht X c cha vng benzen v c cng thc phn t l C 7H9N. Khi cho X tc dng vi brom (dd) thu c kt ta Y c cng thc phn t khi l C7H6NBr3. Hy cho bit X c bao nhiu cng thc cu to ? A. 1 B. 2 C. 3 D. 4 Cu 5. Hp cht X c vng benzen v c CTPT l CxHyN. Khi cho X tc dng vi HCl thu c mui Y c cng thc dng RNH2Cl. Trong cc phn t X, % khi lng ca N l 11,57%; Hy cho bit X c bao nhiu cng thc cu to? A. 3 B. 4 C. 5 D. 6 Cu 6. Cho 20 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 31,68 gam hn hp mui. Th tch dung dch HCl dng l bao nhiu mililit? A. 100 ml B. 50 ml C. 200 ml D. 320 ml Cu 7. Cht X c cng thc phn t l C7H9N. Khi cho X tc dng vi dung dch Br 2 thu c kt ta trng. Hy cho bit X c bao nhiu cng thc cu to ? A. 2 B. 3 C. 4 D. 5 Cu 8. tch ring tng cht t hh benzen, anilin v phenol ta ch cn dng cc ho cht (dng c, iu kin th nghim y ) l: A. dung dch NaOH, dung dch HCl v kh CO2 B. dung dch NaOH, dung dch NaCl v kh CO2 . C. dung dch NaOH, dung dch Br2 v kh CO2 . D. dung dch HCl, dung dch Br2 v kh CO2 . Cu 9. Cho cht X c cng thc phn t l C3H7O2N. un nng X vi NaOH thu c mui cacboxylat, H2O v cht hu c Y. Hy cho bit X c bao nhiu cng thc cu to tha mn. A. 2 B. 3 C. 4 D. 5 Cu 10. C cc dung dch : natriphenolat, anilin, phenol, phenyl amoni clorua. Ha cht no c th s dng nhn bit cc dung dch (Nu gi thit rng chng c t trong cc bnh mt nhn). Cc dng c v thit b c . A. dd NaOH, dd Br2, qu tm B. qu tm, dung dch HCl v dung dch NaOH C. qu tm, dung dch HCl v dung dch Br2. D. phenolphtalein, dung dch HCl v dung dch NaOH. Cu 11. Mt l ha cht m c nghi l phenyl amoni clorua. Ha cht no c th s dng kim tra l ha cht . A. dd NaOH , dd HCl B. dd NaOH, dd AgNO3 C. dd NaOH, dd NH3 D. dd AgNO3, dd HCl Cu 12. Dng tn ti ch yu ca glyxin l dng no sau y: A. H2N-CH2-COOH B. H3N+-CH2-COO -, C. H3N+-CH2-COOH. D. H2N-CH2-COO-. Cu 13. Trng hp no sau y lm hng qu tm tm H2O: A. CH3-CH(NH2)-COOH B. H2N-CH2-COONa C. H2N-CH2-CH(NH2)-COOH. D.ClH3N-CH2-CH2-COOH Cu 14. Cho cc cht sau: Glyxin (I); axit glutamic (II) ; HOOC-CH 2-CH2-CH(NH3Cl)-COOH (III) ; H2NCH2-CH(NH2)-COOH (IV) Sp xp cc cht trn theo th t tng dn v pH (gi s chng c cng nng mol/l). A. (I) < (II) < (III) < (IV) B. (III) < (I) < (II) < (IV) C. (III) < (II) < (I) < (IV) D. (III)<(IV) < (I) <(II) Cu 15. Cho dung dch phenolphtalein vo cc dung dch sau: H 2N-CH2-CH(NH2)-COOH (1); H2N-CH2COONa (2); ClH3N-CH2COOH (3) ; HOOC-CH2-CH2-CH(NH2)-COOH (4) ; NaOOC-CH2-CH2-CH(NH2)-COONa (5).

Hy cho bit dung dch no chuyn sang mu hng? A. (1) (2) (4) (5) B. (1) (2) (5) C. (1) (3) (5) D. (2) (3) (4) (5) Cu 16. Cht X c cng thc phn t C8H15O4N. T X, thc hin bin ha sau: C8H15O4N + dung dch NaOH d ,t0 Natri glutamat + CH4O + C2H6O Hy cho bit, X c th c bao nhiu cng thc cu to? A. 1 B. 2 C. 3 D. 4 + NaOH ,t 0 + HCl du ,t 0 Cu 17. Cho s sau: C4H9O2N C3H6O2NNa X. Hy cho bit X c cng thc phn t l g? A. C3H7O2N B. C3H7O2NaCl C. C3H8O2NCl D. C3H9O2NCl. Cu 18. Cho axit glutamic tc dng vi hn hp ru etylic v metylic trong mi trng HCl khan, hy cho bit c th thu c bao nhiu loi este? A. 5 B. 6 C. 7 D. 8 Cu 19. Cht no sau y c nhit nng chy cao nht? A. CH3CH2CH(NH2)-COOH B. CH3CH(NH2)-COOCH3 C. H2N-CH2-COOC2H5 D. CH3COOCH2CH2NH2 Cu 20. Mt hn hp gm alanin v glixin. Hy cho bit t hn hp d c th to nn bao nhiu loi ipeptit mch h. A. 1 B. 2 C. 3 D. 4 Cu 21. Trong mi trng HCl khan, khi thc hin P este ha gia glyxin vi ru metylic, sn phm hu c cui cng thu c l: A. H2N-CH2-COOCH3 B. ClH3N-CH2-COOCH3 C. ClH3N-CH2COOH D. ClH3NCH(CH3)COOCH3 Cu 22. Hy cho bit, trong cc dng tn ti sau, dng tn ti no l ch yu ca axit glutamic trong dung dch ca n ? A. HOOC-CH2-CH2-CH(NH+3)-COOB. - OOC-CH2-CH2-CH(NH+3)-COOH + C. HOOC-CH2-CH2-CH(NH 3)-COOH D. - OOC-CH2-CH2-CH(NH2)-COO Cu 23. Cho s sau: dd NaOH, t0
X -NH3, -H2O X1 H2SO4 -Na2SO4 X2 C2H5OH/ H2SO4 c, t0 CH3-CH-COOC2H5 -H2O NH3HSO4

Hy cho bit cht X l A. CH3-CH(NH2)-COONH4 B. CH3-CH(NH3Cl)-COOH C. CH3-CH(NH2)-COONH2 D. H2N-CH2-COONH4 Cu 24. Hy cho bit dng qu tm c th phn bit c dy cc dung dch no sau y ? A. glyxin ; H2N-CH2COOCH3 ; H2N-CH2COONa. B. glyxin ; H2N-CH2COONa ; H2N-CH2-CH2COONa. C. glyxin ; H2N-CH2-COONa ; axit glutamic. D. ClH3N-CH2COOH, axit glutamic, glyxin. Cu 25. Cht X c cng thc phn t l C 3H9O2N. un nng X trong NaOH thu c mui cacboxylat Y, H2O v cht hu c Z. T khi ca Z i vi H2 > 15. Hy cho bit c bao nhiu cht hu c X tha mn. A. 1 B. 2 C. 3 D. 4 Cu 26. Cht X c cng thc phn t l C4H9O2N. X tc dng vi NaOH v HCl. un nng X trong NaOH thu c mui X1 c cng thc l C3H3O2Na. Hy cho bit tn gi ca X. A. metyl amoni axetat B. metyl amoni acrylat C. amoni metacrrylat D. mety amoni propionat. Cu 27. Cht X c CTPT l C 4H9O2N. Khi cho X tc dng vi NaOH un nng thu c mui X 1 c cng thc l C2H4O2NNa. Hy cho bit cng thc cu to ca X. A. H2N-CH2-COOCH3 B. H2N-CH2-CH2-COOCH3 C. H2N-CH2-COOCH2-CH3 D. CH3-CH(NH2)-COOCH3 Cu 28. Mt aminoaxit no X tn ti trong t nhin (ch cha mt nhm - NH 2 v mt nhm - COOH). Cho 0,89g X phn ng va vi HCl to ra 1,255g mui. Cng thc cu to ca X l: A. H2N-CH2-COOH. B. CH3-CH(NH2)-COOH C. H2N-CH2-CH2-COOH. D. B, C u ng. Cu 29. Este X c iu ch t aminoaxit X1 v ru etylic. X khng tc dng vi Na. t chy hon ton 2,03 gam cht X thu c 3,96 gam CO2; 1,53gam nc v 112 ml N2 (ktc).

a/ X c cng thc phn t trng vi cng thc n gin nht. Cng thc phn t ca X l: A. C5H11O2N B. C7H13O2N C. C9H17O4N D. C10H17O4N b/ un nng 0,1 mol X vi 200 ml NaOH 1,5M; sau khi phn ng hon ton, em c cn cn thn dung dch sau phn ng, thu c cht rn G c khi lng l: A. 19,1 gam B. 23,1 gam C. 27,7 gam D. 32,3 gam. c/ Cho ton b cht rn G vo dd HCl d, sau em c cn cn thn dung dch sau phn ng thu c cht rn E c khi lng l: A. 54,25 gam B. 48,4 gam C. 42,55 gam D. 35,9 gam Cu 30. X l cht hu c c dng: ROOC-(CH2)n-CH(NH2)-COOR. un nng 0,1 mol X trong 200 ml dung dch NaOH 1,5M, sau khi phn ng xy ra hon ton, c cn cn thn dung dch sau phn ng thu c 9,2 gam ru v dung dch Y. a/ Cng thc ca ru l : A. CH3OH B. C2H5OH C. CH3CH2CH2OH D. CH2=CH-CH2OH b/ C cn dung dch Y thu c cht rn Z c khi lng l 23,1 gam. Xc nh n. A. n = 0 B. n = 1 C. n = 2 D. n = 3 c/ Cho ton b cht rn Z vo dung dch HCl d, sau em c cn cn thn thu c bao nhiu gam cht rn khan. A. 35,9 gam B. 30,05 gam C. 24,2 gam D. 18,35 gam. Cu 31. Cht no sau y lm i mu qu tm: H2N-CH2-CH(NH2)-COOH (I) ; HOOC-CH(NH2)-CH2COOH (II) ; H2N-CH2-COOH (III) ; CH3CH(NH2)COOH (IV); ClH3N-CH2COOH (V); ClH3N-CH2-COOCH3 (VI) v H2N-CH2COONa (VII). A. (I) (II) (V) (VI) v (VII) B. (I) (II) (III) (IV) v (VII) C. (I) (II) v (VII) D. (I) v (II) Cu 32. Cho 0,1 mol -amino axit X tc dng va vi 0,1 mol HCl. Trong mt th nghim khc, cho 26,7 gam X vo dung dch HCl d, sau c cn cn thn thu c 37,65 gam mui khan. Vy X l: A. glixin B. alanin C. glutamic D. -amino butiric. Cu 33. Thc hin phn ng este ha gia alanin vi ru metylic trong mi trng HCl khan, thu c cht hu c X. Dung dch cht X c mi trng axit. Vy X l: A. H2NCH(CH3)-COOCH3 B. ClH3N-CH(CH3)-COOCH3 C. H2NCH2COOCH3 D. ClH3NCH2COOCH3 Cu 34. Cho 0,1 mol -amino axit X (X c mch cacbon khng phn nhnh) tc dng va vi 0,2 mol NaOH thu c 17,7 gam mui. Mt khc, 2,66 gam X tc dng vi HCl (va ) cho 3,39 gam mui Y. a/ Vy X l: A. HOOC-CH(NH2)-COOH B. HOOC-CH2-CH(NH2)-COOH C. HOOC-(CH2)2-CH(NH2)-COOH D. HOOC-(CH2)3-CH(NH2)-COOH b/ Nu cho 3,39 gam mui Y tc dng vi 200 ml dung dch NaOH (ly d) , sau phn ng hon ton, c cn cn thn dung dch thu c 5,91 gam cht rn khan. Xc nh nng mol/l ca dung dch NaOH? A. 0,3M B. 0,35M C. 0,4M D. 0,45M Cu 35. Cho aminoaxit X (cha 1 nhm amino v 1 nhm cacboxyl). Cho m gam X tc dng va vi NaOH, thu c 8,88 gam mui Y. Mt khc, cho m gam X tc dng vi dung dch HCl d, c cn cn thn dung dch thu c 10,04 gam hn hp mui Z. a/ Xc nh m. A. 7,12 gam B. 7,18 gam C. 8,04 gam D. 8,16 gam b/ Xc nh s cng thc cu to c th c ca X. A. 1 B. 2 C. 3 D. 4 Cu 36. Cho cc cht v ion no sau: H3N+-CH2COOH; H2N-CH2-CH(NH2)-COONa; HOOC-CH2-CH2CH(NH2)-COOH; H2N-CH2COOH; CH2=CH-COONH3CH3; CH3-CH(NH2)-COOH. Hy cho bit c bao nhiu cht hoc ion c tnh cht lng tnh. A. 1 B. 2 C. 3 D. 4 Cu 37. Cho s sau: X(C3H7O2N) X1(C3H8O2NCl) X2 (C2H4O2NNa) X3 (C2H6O2NCl) a/ Hy cho bit cht no trong s cc cht trong s c nhit nng chy thp nht.

A. cht X B. cht X1 C. cht X2 D. cht X3 b/ Hy cho bit c bao nhiu cht c kh nng i mu qu tm? A. 1 B. 2 C. 3 D. 4 Cu 38. Hp cht X, Y l ng phn ca nhau c cng thc phn t l C 4H11O2N. Khi cho 0,15 mol hn hp G gm X, Y tc dng vi dung dch NaOH va th thu c 13,7 gam hn hp mui natri ca 2 axit cacboxylic n chc v hn hp hi gm 2 amin l ng ng k tip nhau. a/ Cng thc cu to ca X, Y l: A.CH3COOH3NCH2CH3vHCOOH3NCH2CH2CH3 B.CH3COOH2N(CH3)2vHCOOH2N(CH3)CH2CH3 C. CH3COOH3NCH2CH3 v CH3CH2COOH3NCH3 D.CH3COOH2N(CH3)2 v HCOOHN(CH3)3 b/ Hp th hon ton lng amin thu c bi dung dch HCl, sao em c cn cn thn dung dch sau phn ng thu c cht rn c khi lng l: A. 10,675 gam B. 10,825 gam C. 11,19 gam D. 12,125 gam c/ chng minh tnh lng tnh ca X hoc Y cn cho X hoc Y tc dng vi cht no sau y? A. dung dch NaOH v dung dch NH4Cl B. dung dch HCl v dung dch NH3 C. dung dch HCl v dung dch NaOH D. dung dch NH4Cl v dung dch NH3 Cu 39. Mt aminoaxit no X tn ti trong t nhin (ch cha mt nhm - NH 2 v mt nhm - COOH). Cho 0,89g X phn ng va vi HCl to ra 1,255g mui. Cng thc cu to ca X l: A. H2N CH2 COOH. B. CH3-CH(NH2)-COOH C. H2N-CH2-CH2-COOH. D. B, C u ng. Cu 40. Cho X l mt aminoaxit. Khi cho 0,01mol X tc dng vi HCl th dng ht 80ml dd HCl 0,125M v thu c 1,835g mui khan. Cn khi cho 0,01mol X tc dng vi dung dch NaOH th cn dng 25gam dd NaOH 3,2%. Cng thc cu to ca X l: A. C3H6(NH2)-COOH B. C2H4(NH2)COOH C. H2N-C3H5(COOH)2 D. (H2N)2C3H5 COOH Cu 41. t chy hon ton 6,52 gam cht X (cha C, H, O, N) thu c 10,56 gam CO 2, 4,68 gam H2O v 0,448 lt N2 (ktc). a/ Xc nh CTPT ca X, bit n trng vi cng thc n gin. A. C6H7O2N B. C6H7O4N C. C6H13O2N D. C6H13O4N o b/ T X, ngi ta thc hin dy bin ha sau: X + NaOH d, t X1 + CH4O + C2H6O Bit rng X1 c nhm NH2 v tr - v X1 c mch cacbon khng phn nhnh. Hy cho bit X c bao nhiu cng thc cu to ? A. 1 B. 2 C. 3 D. 4 c/ Hy cho bit 0,1 mol X1 tc dng ti a bao nhiu mol HCl. A. 0,1 mol B. 0,2 mol C. 0,3 mol D. 0,4 mol. Cu 42. X l -aminoaxit c mch cacbon no khng phn nhnh cha 2 nhm amino 2 cacbon khng cnh nhau v 1 nhm cacboxyl. a/ Cng thc chung ca dy ng ng cha X l: A. CnH2n(NH2)2COOH (n 2) B. CnH2n-1(NH2)2COOH (n 2) C. CnH2n-1(NH2)2COOH (n 3) D.CnH2n(NH2)2COOH(n3) b/ Cho 1,18 gam X vo dung dch HCl d, c cn cn thn dung dch sau phn ng thu c 1,91 gam cht rn E. Mt khc, cho 1,18 gam cht rn E vo 200 ml dung dch KOH (d) , un nng cc phn ng xy ra hon ton. C cn cn thn dung dch sau phn ng thu c 3,8 gam cht rn khan. Xc nh nng mol/l ca dung dch KOH. A. 0,2M B. 0,25M C. 0,3M D. 0,35M Cu 43. E, F l ng phn ca nhau v c cng thc phn t l C4H9O2N. Khi cho E, F cng tc dng vi dung dch NaOH un nng th t E thu c mui E 1 c cng thc phn t C4H8O2NNa cn F thu c mui F1 c cng thc phn t l C3H6O2NNa. C E1 v F1 u c nhm NH2. a/ Xc nh s lng ng phn ca E v ca F. A. E-3 ; F -2 B. E -4 ; F -3 C. E - 5 ; F -2 D. E - 5 ; F -3 b/ S sp xp no sau y ng vi chiu tng dn v pH ca 2 dung dch E, F nu chng c cng nng mol/l ? A. E > F B. E < F C. E = F D. khng xc nh.

Cu 44. X l amino axit no ch cha mt nhm -COOH v mt nhm -NH 2 v tr -. Cho X tc dng va vi 16,6 ml dung dch HCl 20% ( d = 1,1 g/ml) thu c dung dch G. Cho dung dch G tc dng hon ton v va vi V ml dung dch NaOH 0,5M thu c dung dch F. a/ Xc nh V. A. 200 ml B. 300 ml C. 400 ml D. 250 ml b/ C cn cn thn dung dch F thu c 15,55 gam mui khan. Cng thc ca X l: A. H2N-CH2-COOH B. H2N-CH(CH3)-COOH C. CH3CH2CH(NH2)COOH D.(CH3)2C(NH2)-COOH Cu 45. Cht hu c X cng thc phn t l C 3H9O2N. un nng cc cht vi NaOH u thu c mui cacboxylat v amin. Hy cho bit c bao nhiu cng thc cu to ph hp vi X. A. 1 B. 2 C. 3 D. 4 Cu 46. Cht no sau y l cht rn : A. C3H5(OH)3 ; B. CH2Cl-CHCl-CH2Cl C. H2N-CH2-COOH ; D. C6H6 Cu 47. Cho 0,1 mol X tc dng va vi 0,1 mol axit H2SO4; 0,1 mol X tc dng va vi 0,1 mol NaOH. Hy cho bit cng thc chung no ng vi axit X. A. R(NH2)COOH B. R(NH2)2COOH C. R(NH2)(COOH)2 D. R(NH2)2(COOH)2 Cu 48. Cho s sau: X(C3H7O2N) X1(C3H8O2NCl) X2 (C2H4O2NNa) X3 (C2H6O2NCl) X4 (C2H6O5N2) a/ Hy cho bit cht no trong s cc cht trong s c nhit nng chy thp nht. A. cht X B. cht X1 C. cht X2 D. cht X3 b/ Nhng cht no lm qu tm i sang mu ? A. cht Cu 49. Thc hin phn ng ca glixin vi CH3OH trong mi trng HCl khan, ngi ta thu c cht X c cng thc l: ClH3N-CH2-COOCH3. Hy cho bit c th ch ha X vi cht no sau y c th thu c cht Y c cng thc H2N-CH2COOCH3 vi hiu sut cao nht: A. NaOH B. AgNO3 C. NH3 D. Ba(OH)2