HA HC 11

Bin son : Thy Ti 0966.293.727

CHNG I : S IN LI
DNG 1: VIT PHNG TRNH IN LI
Phng php : Khi vit pt in li phi ch cc yu t sau : u tin phi xem cht in li l cht in li mnh hay yu - Nu mnh th dng du mi tn mt chiu. VD : HCl H+ + Cl-. - Nu yu th dng du mi tn hai chiu. VD : CH3COOH CH3COO- + H+ Nu Axit yu, bazo yu th vit pt in li tng nc VD: H3PO4 H+ +H2PO4- ; H2PO4 - H+ + HPO42- ; HPO42- H+ + PO43 Nu l mui Axit th vit pt in li qua 2 giai on ( ch gc axit mnh, yu vit ng du mi tn 1 chiu hay 2 chiu ) VD : NaHCO3 Na+ + HCO3- ; HCO3- CO32- + H+ Ch mt s mui : Na2HPO3, NaH2PO2 khng phi l mui Axit nn pt in li nh sau : Na2HPO3 2Na+ + HPO32: NaH2PO2 Na+ + H2PO2 Hidroxit lng tnh th vit 2 kiu phn li ( theo kiu axit v bazo) VD: Kiu bazo : Al(OH)3 Al3+ + 3OHKiu axit : Al(OH)3 AlO2- + H2O + H+ Ch mui HgCl2, Hg(CN)2 l cht in li yu nn dng du 2 chiu vit pt in li Bi tp p dng : Bi 1: Vit phng trnh in li cc cht sau : H2S, H2SO4 , H2SO3 , H2MnO4 ,HNO3 , KOH, Ba(OH)2 , FeCl3 , CuSO4 , Al2(SO4)3 , Mg(NO3)2 , Pb(NO3)2, Na3PO4 , NH4H2PO4, KClO3 , (NH4)2SO4 , NaHCO3 , K2SO3 , (CH3COO)2Cu , K2CrO4, NaHCO3, HClO, HNO2, HCN, HBrO, Sn(OH)2, Na2HPO4, Na2HPO3, KHSO4,Zn(OH)2 Bi 2 : Vit cng thc ho hc cho nhng cht m s in li cho cc ion sau: a/ Fe3+ v SO42b/ Ca2+ v Clc/ Al3+ v NO3- d/ K+ v PO43-

DNG 2: TNH NNG ION C TRONG DUNG DCH CHT IN LI, IN LI

Phng php : + Nng mol : CM = + Nng phn trm : C% + mdd = V.D V: th tch dung dch (lit) . 100% D: khi lng ring (g/ml)

+ V dung dch trung ha in nn vn dng nguyn tc bo ton in tch tm ion cui cng khi bit ht cc ion kia ncation.in tch ca cation = nanion.in tch ca anion Lu : Cc em phi phn bit k hiu :[ ] nng ca cc ion hoc phn t trng thi cn bng C : nng ca cc ion hoc phn t trng thi ban u + Cng thc tnh in li : Bi tp p dng : Bi 1: Tnh nng mol/l ca cc ion c trong dung dch : CaCl2 0,02M, Na3PO4 0,05M, NH4NO3 0,002M, KOH 0,01M Bi 2 : Tnh nng mol/l ca cc ion K+ v SO42- c trong 2 lt dung dch cha 17,4g K2SO4 tan trong nc. Bi 3: Tnh nng mol/l ca cc ion H+ trong dung dch HNO310% (Bit D=1,054g/ml). Bi 4: Tnh th tch dung dch HCl 0,5M c cha s mol H+ bng s mol H+ c trong 0,3 lt dung dch HNO3 0,2M. Bi 5 : Trn ln 80ml dung dch KOH 0,45M vi 35ml dung dch H2SO4 0,8M th thu c dung dch D. a/ Tnh nng mol/l cc ion c trong dung dch D.(bit phn ng xy ra hon ton) b/ Tnh th tch dung dch Ba(OH)2 1,2M cn trung ho dung dch D. Bi 6: Cho 60ml dung dch NaOH 8% (D = 1,109 g/ml) vo 50ml dung dch HCl 10% (D=1,047 g/ml). 1 . Khi pha long dung dch th in li tng

HA HC 11

Bin son : Thy Ti 0966.293.727

a/ Tnh nng % dung dch thu c. b/ Tnh nng mol/l cc ion trong dung dch thu c (cho rng th tch dung dch thay i khng ng k). Bi 7: Ho tan 12,5gam CuSO4.5H2O vo mt lng nc va to thnh 200ml dung dch. Tnh nng mol/l cc ion c trong dung dch.(B qua s in ly ca H2O) Bi 8 : Mt dung dch A gm : 0,1 mol Mg2+, 0,3 mol K+; 0,4 mol Na+ v x mol SO42a. Tnh x ? b. Nu c cn dung dch A thu c bao nhiu gam mui khan ? Bi 9: nng cu ion H+ trong dung dch CH3COOH 0,1 M l 0,0013M. Tnh in li ?

DNG 3 : TNH pH
Phng php : 1. Cng thc : [H+] . [OH-] = 10-14 Trong dung dch m c [H+] th c th [OH-] v ngc li pH l mt i lng dng ch mnh ca axit, bazo : pH = -lg[H+] [H+] = 10-pH Gi tr pH c trng cho mi trng : + pH = 7 mi trng trung tnh + pH > 7 mi trng bazo + pH < 7 mi trng axit 2. Cch tnh pH ca dung dch : Nh mun tnh pH th phi c [H+] Nu dung dch c mi trng axit th tnh [H+] ri suy ra pH Nu dung dch c mi trng bazo th tnh [OH-] ri suy ra [H+] sau tnh pH Nu trn ln hn hp axit vi bazo th lm theo cc bc sau : - Bc 1: Tnh s mol axit (nH+) v s mol bazo (nOH-) - Bc 2: Vit ptr : H+ + OH- H2O . Sau so snh s mol xem H+ d hay OH- d - Bc 3: Tnh nng ca lng d ny ( chnh lng d ny quyt nh n pH ca dung dch sau p/u), nh l V dd sau p/ bng tng cc V ban u ( Vdd sau = Vaxit + V bazo) Lu : + Ngoi CT tnh pH cn c CT tnh gi tr pOH = -lg[OH-] v pOH + pH =14 + H2O l cht in li rt yu nn b qua lng H+ do H2O phn li ra Bi tp p dng : Bi 1 : Tnh pH ca dung dch sau: a. Dung dch NaCl 0,1M ; b. dung dch H2SO4 0,005M c. dung dch Ba(OH)2 0,05M d. hn hp gm HCl 0,05M v H2SO4 0,005M e. hn hp gm KOH 0,005M v Ba(OH)2 0,0025M

Bi 2: Tnh pH ca dung dch cha 1,46 gam HCl trong 400 ml dung dch HCl ? Bi 3: a) Trn 40 ml dung dch H2SO4 0,25M vi 60 ml dung dch NaOH 0,5M. Tnh pH ca dung dch to thnh ? b) Trn 50 ml dung dch HCl 0,12M vi 50 ml dung dch NaOH 0,1M. Tnh pH ca dung dch thu c ? Bi 4: Cho 40 ml dung dch HCl 0,75M vo 160 ml dung dch hn hp Ba(OH) 2 0,08M v KOH 0,04M. Tnh pH ca dung dch thu c sau phn ng ? Bi 5: Trn 100 ml dung dch gm Ba(OH) 2 0,1M v NaOH 0,1M vi 400 ml dung dch H 2SO4 0,0375M v HCl 0,0125M c dung dch X. Tnh pH ca dung dch X ? Ch : Cc bi ton ngc cho pH tnh nng hay th tch cc cht ban u ta lm theo cc bc sau : Bc 1: Tnh nH+ v nOH- ( lu : 1 trong 2 s mol s cha n l nng a hoc l th tch V ) Bc 2: Vit pt : H+ + OH- H2O. Xem gi tr pH,pOH ca dd sau p/ bi cho xc nh mi trng dd sau p/ Bc 3: Da vo Ct : n d = n ban u n p/ tm ra gi tr a hoc V

Bi 6: Trn ln 300ml dung dch HCl 0,05M vi 200ml dung dch Ba(OH) 2 nng a (M) thu c dung dch c pH = 12. Gi tr ca a ? Bi 7: Thm 1 lit dung dch HCl c pH = 3 vo V lit dung dch X cha NaOH 0,02M v Ba(OH) 2 0,01M sau phn ng thu c dung dch Y c pH = 4. Tnh gi tr V ? 2

HA HC 11

Bin son : Thy Ti 0966.293.727

Bi 8: Trn 100 ml dung dch c pH = 1 gm HCl v HNO 3 vi 100 ml dung dch NaOH c nng a mol/l thu c 200 ml dung dch c pH = 12. Tnh a ? Bi 9* : Trn 200 ml dung dch HCl 0,1M v H 2SO4 0,05M vi 300 ml dung dch Ba(OH) 2 a mol/lit thu c m gam kt ta v 500 ml dung dch c pH = 13. Tnh gi tr a, m ?

DNG 4: S THY PHN CA MUI

Phng php : n li bazo mnh, yu, Axit mnh, yu + Bazo mnh : NaOH, KOH, Ba(OH)2, Ca(OH)2,... + Bazo yu : Bazo khng tan nh : Cu(OH)2, Mg(OH)2,... dung dch NH3 + Axit mnh : H2SO4,HCl, HNO3, HClO4, HBr,HI, HclO3 + Axit yu : H3PO4, H2SO3, H2CO3, H2S, HClO, HClO2, HF,HNO2, axit hu c S thy phn ca Mui : + Mui to bi Axit mnh v bazo yu s b thy phn mi trng axit, pH < 7 + Mui to bi Axit yu v bazo yu s b thy phn mi trng bazo, pH> 7 + Mui to bi Axit mnh v bazo mnh khng b thy phn mi trng trung tnh, pH=7 + Mui to bi Axit yu v bazo yu s b thy phn mi trng ph thuc vo qu trnh no thy phn mnh hn V d : Cho bit mi trng ca cc dd mui sau v gii thch bng pp thy phn : Fe(NO3)3, K2S,NaCl Fe(NO3)3 Fe3+ + 3NO3- ; Fe3+ +3 H2O Fe(OH)3 + 3H+ mi trng Axit K2S 2K+ + S2- ; S2- + H2O HS- + OH- mi trng bazo + NaCl Na + Cl ; 2 ion ny khng b thy phn mi trng trung tnh Lu : Gc axit mnh, bazo mnh khng b thy phn. Mi trng trung tnh Gc bazo yu b thy phn cho mi trng bazo Gc axit yu b thy phn cho mi trng axit Mui NaHSO3 mi trng bazo ,pH>7 cn NaHSO4 mi trng axit,pH<7 Bi tp p dng : Bi 1: Hy cho bit mi trng ca cc dung dch mui sau ? gii thch bng phng php thy phn : a. CH3COONa b.K2SO4 c. NH4NO3 d.CuSO4 Bi 2: Hy cho bit mu ca qu tm thay i nh th no (gi s nng ln lm i mu qu tm) khi cho vo cc dung dch sau: CH3COOH, CaBr2, MgSO4, K2S. Gii thch ? Bi 3 : Cc dung dch sau c pH nh th no ? gii thch:Na 2CO3, NH4Cl, Na2SO3, Fe(NO3)3, KI, NaHSO4 , NaHCO3

DNG 5: PHN NG TRAO I ION

Phng php : iu kin xy ra phn ng : sn phm to thnh phi c cht kt ta, cht kh hoc l cht in li yu Cch vit pt ion thu gn : - Cht tan, cht in li mnh vit di dng ion - Cht kt ta, cht kh v cht in li yu gi nguyn - Rt gn cc ion ging nhau 2 v Bi tp p dng : Bi 1 : Vit phng trnh phn t v ion rt gn ca cc phn ng sau (nu c) xy ra trong dung dch: a, KNO3 + NaCl b, NaOH + HNO3 c,Mg(OH)2 + HCl d, NaF + AgNO3 e, Fe2(SO4)3 + KOH g, FeS + HCl h, NaHCO3 + HCl i, NaHCO3 + NaOH k, K2CO3 + NaCl l, Al(OH)3 + HNO3 m, Al(OH)3 + NaOH n, CuSO4 + Na2S o, NH4HCO3 + NaOH Bi 2: Hy vit pt phn t t cc pt ion thu gn sau : a. H+ + OH- H2O c. Ba2+ + CO32- BaCO3 d. CO32- + 2H+ CO2 + H2O 23+ b. Zn(OH)2 + 2OH ZnO2 + 2H2O e. Al + 3OH Al(OH)3 Bi 3:Trong dung dch c th tn ti ng thi cc ion sau y c khng? Gii thch a, Na+, Cu2+, Cl-, OHb, K+, Ba2+, Cl-, SO4 2-. + 2+ 2c, K , Fe , Cl , SO4 . d, HCO3-, OH-, Na+, Cl3

HA HC 11

Bin son : Thy Ti 0966.293.727

H2O

Bi 4: Vit PT dng phn t v ion rt gn ca cc phn ng trong dd theo s sau: a. Pb(NO3)2 + ? PbCl2 + ? b. FeCl3 + ? Fe(OH)3 + ? c. BaCl2 + ? BaSO4 + ? d. HCl + ? ? + CO2 + e. NH4NO3 + ? ? + NH3 + H2O f. H2SO4 + ? ? + H 2O

DNG 6: BI TON PHA TRN DUNG DCH

Phng php : Trn ln hai dung dch: Dung dch 1: c khi lng m1, th tch V1, nng C1 (nng phn trm hoc nng mol), khi lng ring d1. Dung dch 2: c khi lng m2, th tch V2, nng C2 (C2 > C1 ), khi lng ring d2. Dung dch thu c: c khi lng m = m1 + m2, th tch V = V1 + V2, nng C (C1 < C < C2) v khi lng ring d. S ng cho v cng thc tng ng vi mi trng hp l: a. i vi nng % v khi lng:

C1 C2

| C2 - C | | C1 - C |

m1 C 2 C = m 2 C1 C

(1)

b. i vi nng mol/lt:

CM1 CM2
d1 d2 d

` | C2 - C | | C1 - C |
| d2 - d | | d1 - d |

V1 C2 C = V2 C1 C

(2)

c. i vi khi lng ring:

V1 C2 C = V2 C1 C

(3)

Khi s dng s ng cho cn ch : - Cht rn coi nh dung dch c C = 100% - Dung mi coi nh dung dch c C = 0% - Khi lng ring ca H2O l d = 1g/ml. Bi tp p dng : Bi 1: Phi thm bao nhiu gam nc vo 200 gam dung dch KOH 20% c dung dch KOH 16% ?

Bi 2:Ha tan 100 ml dung dch HNO3 0,5M vi 200 ml dung dch HNO3 0,1M. Tnh nng mol/lit dung dch to thnh ? Bi 3: Cn pha trn bao nhiu gam dd NaOH 15% vo 200 g dung dch NaOH 45% c dung dich NaOH 20% ?

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Bin son : Thy Ti 0966.293.727

Cu 1. cc dd axit, baz, mui dn in c l do trong dd ca chng c: A. ion tri du B. cation C. anion D. cht Cu 2. Cho cc cht sau: K3PO4, H2SO4, HClO, HNO2, NH4Cl, HgCl2, Sn(OH)2. dy cc cht in li yu l: A.HClO, HNO2, HgCl2, Sn(OH)2. B.HClO, HNO2, K3PO4, H2SO4. C.HgCl2, Sn(OH)2, NH4Cl, HNO2. D.HgCl2, Sn(OH)2, HNO2, H2SO4. Cu 3. Cho cc cht: H2O, NaCl, HCl, NaOH,CH3COOH, CuSO4. Cc cht in li yu l: A. H2O, CH3COOH, CuSO4 B. CH 3COOH, CuSO4 C. CH3COOH, H2O D. H2O, NaCl, CH3COOH, NaOH Cu 4. Cho cc cht: HNO3, NaOH, Ag2SO4, NaCl, H2SO3, CuSO4, Cu(OH)2. Cc cht in li mnh l: A. NaOH, Ag2SO4, NaCl, H2SO3 B. HNO3, NaOH, NaCl, CuSO4 C. NaCl, H2SO3, CuSO4 D. Ag2SO4, NaCl, NaOH, Cu(OH)2 Cu 5. Da vo nh lut bo ton in tch hy cho bit dd no sau y khng tn ti. A. dd cha Na + 0,1M, Ba 2 + 0,1M, K + 0,15M, Cl 0,25M, NO 3 0,1M. B. dd cha Ca 2+ 0,2M, K + 0,25M, Cl 0,25M, NO 3 0,4M. C. dd cha K + 0,1M, Na + 0,2M, NO 3 0,05M, CH 3 COO 0,05M, Cl 0,2M.
2 D. dd cha Mg 2 + 0,2M, K + 0,1M, NH 4 0,1M, 0, SO 4 0,25M, Cl 0,05M, NO 3 , 0,05M. Cu 6. Theo Areniut nhng cht no sau y l hiroxit lng tnh? A. Al(OH)3. B. Fe(OH)2. C. Cr(OH)2 D. Mg(OH)2.

MT S BI TP TRC NGHIM

Cu 7. Theo Areniut pht biu no sau y l ng? A. Hp cht c kh nng phn li ra ion H + l axit. B. Hp cht c cha nhm OH l hidroxit. C. Hp cht c cha hiro trong phn t l axit. D. Hp cht c cha 2 nhm OH l hiroxit lng tnh. Cu 8. Gi tr tch s ion ca nc ph thuc vo: A. Nhit . B. p sut C. Cht ho tan D. ion ho tan Cu 9. Cho 2 dd axit l: HNO 3 v HClO c cng nng . S so snh no sau y l ng? A.[HNO3] < [ HClO].

C. NO 3 > ClO . D. H HNO3 = H HClO . Cu 10. Theo Areniut hiroxit no sau y c tnh lng tnh ? A. Zn(OH)2. B. Pb(OH)2. C. Al(OH)3. D. tt c. Cu 11. Mui axit l: A. mui c kh nng p vi baz. B. mui vn cn hiro trong phn t. C. mui to bi baz yu v axit mnh D. mui vn cn kh nng phn li ra cation H+. Cu 12. Mui trung ho l : A.mui m dd c pH = 7. B. mui khng cn hiro trong phn t. C. mui c kh nng p vi axit hoc baz. D. mui khng cn hiro c th b thay th bng kim loi Cu 13. trong cc cht sau, cht no l cht in li yu ? A. H2O. B. HCl. C. NaOH. D. NaCl. Cu 14. nc ng vai tr g trong qu trnh in li ca cc cht trong nc ? A. Mi trng in li. B. Dung mi khng phn cc. C. Dung mi phn cc. D. to lin kt hiro vi cc cht tan. Cu 15. chn pht biu ng trong s cc pht biu sau y ? A. gi tr pH tng th axit gim. B. gi tr pH tng th axit tng.
+

[ ]
+

B.

[H ]
+

HNO3

+ > H

HClO

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C. dd c pH < 7 lm qu tm ho xanh. D. dd c pH >7 lm qu tm ho . Cu 16. Cho cc dd c nh s th t nh sau: 1. KCl. 2. Na2CO3. 3. CuSO4. 4. CH3COOH. 5. Al2(SO4)3 6. NH4Cl. 7. NaBr. 8. K2S. chn phng n trong dd c pH < 7. A. 1, 2, 3. B. 3, 4, 5, 6. C. 6, 7, 8. D. 2, 4, 6. Cu 17. Trong cc dd sau y : K 2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, Na2S. C bao nhiu dd c pH > 7 ? A. 1. B. 2. C. 3. D. 4. Cu 18. in li ca cht in li ph thuc vo nhng yu t no di y? A. Bn cht ca cht in li. B. Bn cht ca dung mi. C. Nhit v nng ca cht tan. D. Tt c cc trn Cu 19. dd mui no sau y c pH = 7 ? A. Al2(SO4)3. B. NH4NO3. C. KNO3. D. tt c cc dd trn. Cu 20. mui no sau y khi thu phn to dd c pH < 7 ? A. CaCl2. B. CH3COONa. C. NaCl. D. NH4Cl. Cu 21. S thu phn ca Na2CO3 to ra : A. mi trng axit. B. mi trng baz. C. mi trng trung tnh D. khng xc nh c. Cu 22. cht no sau y khng dn c in? A. KCl rn, khan B. CaCl2 nng chy C. NaOH nng chy D. HBr/H2O Cu 23. Cht no sau y khng phn li thnh ion khi tan trong nc A. MgCl2 B. HClO3 C. C6H12O6 D. Ca(OH)2 Cu 24. Nng ion H+ trong dd CH3COOH 0,1M l 0,0013 mol.l. in li ca axit trn l: A. 2,3% B. 1,3% C. 1,2% D. 1,32% Cu 25. Mt dd c nng ion H+ l 0,004M, pH ca dd trn l: A. 2,4 B. 4,2 C. 2,3 D. 2,2 -5 Cu 26. mt dd c [OH ] = 1,8 .10 . pH ca dd ny l: A. 9,52 B. 9,25 C. 9,35 D. 9,26 Cu 27. ho tan 4,9g H2SO4 vo nc c 1 lt dd. pH ca dd ny l: A.1 B. 2 C. 1,5 D. kt qu khc Cu 28. Ho tan 0,1g NaOH vo nc c 1 lt dd. pH ca dd ny l: A. 10,4 B. 12,4 C. 11,4 D. 13,4 Cu 29. c 3 dd Ba(OH)2, NaOH, NH3 c cng nng mol. nu sp xp theo chiu pH tng dn th s sp xp no sau y l ng? A. NaOH, Ba(OH)2, NH3 B. NaOH, NH3, Ba(OH)2 C. NH3, NaOH, Ba(OH)2 D. Ba(OH)2, NaOH, NH3 Cu 30. Tnh pH thu c khi trn 10ml dd NaOH c pH = 13 vi 10ml dd HCl 0,3M A. 8 B. 1 C. 7 D. 2 Cu 31. Dung dch A c a mol NH4+ , b mol Mg2+ , c mol SO42- v d mol HCO3-. Biu thc no biu th s lin quan gia a, b, c, d sau y l ng ? A. a + 2b = c + d B. a + 2b = 2c + d
+ -

Bin son : Thy Ti 0966.293.727

C. a + b = 2c + d

D. a + b = c + d

Cu 32. Phng trnh ion thu gn H + OH H2O biu din bn cht ca cc phn ng ha hc no sau y? A. HCl + NaOH H2O + NaCl C. H2SO4 + BaCl2 2 HCl + BaSO4 A. Mg2+ , SO42- , Cl- , Ag+ C. S2- , Fe2+ , Cu2+ , ClA. [H+] < [OH] B. NaOH + NaHCO3 H2O + Na2CO3 D. A v B ng B. H+ , Cl- , Na+ , Al3+ D. OH- , Na+ , Ba2+ , Fe3+ B. [H+] = [OH] 6

Cu 33. Nhng ion no sau y cng c mt trong dung dch?

Cu 34. Ha tan mt axit vo nc, kt qu l

HA HC 11
C. [H+] > [OH] Cu 35. Dung dch ca mt baz 250C c

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D. khng xc nh c v khng bit nng axit

A. [H+] = 107 M B. [H+] < 107 M C. [H+] > 107M D. [H+][OH] > 1014 Cu 36. Phn ng no to thnh PbSO4 di y khng phi l phn ng trao i ion ? A. Pb(NO3)2 + Na2SO4 PbSO4 + 2NaNO3 B. Pb(OH)2 + H2SO4 PbSO4 + 2H2O C. PbS + 4H2O2 PbSO4 + 4H2O D. (CH3COO)2Pb + H2SO4 PbSO4 + 2CH3COOH Cu 37: Dy cht no di y gm cc cht khi phn li trong nc u tham gia phn ng thy phn? A. Na3PO4, Ba(NO3)2, KCl. C. AlCl3, Na3PO4, K2SO3. trng : A. axit B. trung tnh B. Mg(NO3)2, Ba(NO3)2, NaNO3. D. KI, K2SO4, K3PO4. C. baz D. khng xc nh

Cu 38: Cho dung dich cha x (g) Ba(OH)2 vo dung dch cha x (g) HCl. Dung dich thu c sau phn ng c mi Cu 39: Cho cc dung dch sau: Na3PO4, Ba(OH)2 v NaOH c cng gi tr pH. Hy cho bit s sp xp no ng vi gi tr CM ca cc dung dch A. Ba(OH)2 < NaOH < Na3PO4 C. Ba(OH)2 < Na3PO4 < NaOH A. NH4+, K+, Na+. C. Ca2+, Mg2+, Na+. Cu 41: Dy gm cc ion cng tn ti trong mt dung dch l A. Na+, NH4+, Al3+, SO42-, OH-, Cl-. C. Ag+, Fe3+, H+, Br-, CO32-, NO3-. ca dung dch X l A. 3. B. 4. C. 8. D. 10. Cu 43: Trn 200ml dung dch gm HCl 0,1M v H2SO4 0,05M vi 300 ml dung dch Ba(OH)2 a mol/lt thu c m gam kt ta v 500ml dung dch c pH = 13. Gi tr ca a v m tng ng l A. 0,1; 2,33. B. 0,15; 2,33. C. 0,2; 10,48. D.0,25; 10,48. Cu 44: Trn 100 ml dung dch gm Ba(OH) 2 0,1M v NaOH 0,1M vi 400 ml dung dch gm H 2SO4 0,0375M v HCl 0,0125M, thu c dung dch X. Gi tr pH ca dung dch X l A. 7. A. 4V. B. 6. B. 7V. C. 1. C. 9V. D. 2. D. 10V. Cu 45: Lng nc cn thm vo V lt dung dch NaOH c pH = 12 thu c dung dch NaOH c pH = 11 l Cu 46: Trn ln 100 ml dung dch Ba(OH) 2 0,5M vi 100 ml dung dch HCl 0,5 M c dung dch X. Th tch (ml) dung dch H2SO4 1M va trung ho dung dch X l A. 250. khi lng l 7 B.50. C. 25. D. 150. Cu 47: Mt dung dch c cha Ca2+ (0,1 mol), Na+ (0,2 mol), Cl- (0,4 mol). C cn dung dch ny thu c mui khan c B. Ca2+, K+, Cu2+, NO3-, OH-, Cl-. D. Na+, Mg2+, NH4+, SO42-, Cl-, NO3-. B. Na3PO4 < NaOH < Ba(OH)2 D. NaOH < Ba(OH) 2 < Na3PO4 B. H+, NH4+, K+, Na+. D. Ba2+, Cu2+, NH4+, K+.

Cu 40: Dy gm tt c cc ion u khng tc dng vi CO32- l

Cu 42: Trn 100ml dung dch KOH c pH = 12 vi 100 ml dung dch HCl 0,012M, thu c dung dch X. Gi tr pH

HA HC 11
A. 28,8 gam trong cc iu kin sau: A. A.to thnh cht kt ta. C. to thnh cht in li yu. B.to thnh cht kh . B. 22,8 gam C. 2,28 gam

Bin son : Thy Ti 0966.293.727

D. 23,2 gam

Cu 48.Hy chn cu tr li ng: Phn ng trao i trong dung dch cc cht in li ch c th xy ra khi c t nht mt

D. hoc A, hoc B, hoc C.

E. c A, B v C

Cu 49. Cu no sau y ng khi ni v s in ly? A. S in ly l s ho tan mt cht vo nc thnh dung dch. B. S in ly l s phn ly mt cht di tc dng ca dng in. C. S in ly l s phn ly mt cht thnh ion dng v ion m khi cht tan trong nc D. S in ly thc cht l qu trnh oxi ho kh. Cu 50. Cho 10,6g Na2CO3 vo 12g dung dch H2SO4 98%, s thu c bao nhiu gam dung dch? Nu c cn dung dch sau phn ng s thu c bao nhiu gam cht rn? A. 18,2g v 14,2g B. 18,2g v 16,16g C. 22,6g v 16,16g D. 7,1g v 9,1g Cu 51. Trong dung dch Al2(SO4)3 long c cha 0,6 mol SO42-, th trong dung dch c cha: A. 0,2 mol Al2(SO4)3. B. 0,4 mol Al3+. C. 1,8 mol Al2(SO4)3. D. C A v B u ng. Cu 52. Trong cc cp cht sau y, cp cht no cng tn ti trong dung dch? A. AlCl3 v Na2CO3. B. HNO3 v NaHCO3. C. NaAlO2 v KOH. D. NaCl v AgNO3. Cu 53. C bn l ng bn dung dch mt nhn l: AlCl 3, NaNO3, K2CO3, NH4NO3. Nu ch c php dng mt cht lm thuc th th c th chn cht no trong cc cht sau? A. Dung dch NaOH B. Dung dch H2SO4 C. Dung dch Ba(OH)2 D. Dung dch AgNO3 Cu 54. Cc cht no trong dy sau y va tc dng vi dung dch kim mnh, va tc dng vi dung dch axit mnh? A. Al(OH)3, (NH2)2CO, NH4Cl. B. NaHCO3, Zn(OH)2, CH3COONH4. C. Ba(OH)2, AlCl3, ZnO. D. Mg(HCO3)2, FeO, KOH. Cu 55: Cho 10 ml dung dch hn hp HCl 1M v H 2SO4 0,5M. Th tch dung dch NaOH 1M cn trung ho dung dch axit cho l: A. 10ml. B. 15ml. C. 20ml. D. 25ml. Cu 56 : Trn 200ml dung dch HCl 1M vi 300 ml dung dch HCl 2M. Nu s pha trn khng lm co gin th tch th dung dch mi c nng mol l: A. 1,5M B. 1,2M C. 1,6M D. 0,15M + 2+ 2Cu 57: Dung dch A c a mol NH4 , b mol Mg , c mol SO4 v d mol HCO3 . Biu thc no biu th s lin quan gia a, b, c, d sau y l ng? A. a + 2b = c + d B. a + 2b = 2c + d C. a + b = 2c + d D. a + b = c + d Cu 58: Cho phng trnh ion thu gn: H + + OH- H2O. Phng trnh ion thu gn cho biu din bn cht ca cc phn ng ho hc no sau y? A. HCl + NaOH C. H2SO4 + BaCl2 H2O + NaCl 2HCl + BaSO4 B. NaOH + NaHCO 3 H2O + Na2CO3 D. A v B ng.

Cu 59. Khi pha long dung dch, in li ca cc cht in li : A.u tng. B.u gim. B.khng thay i. D.tng hay gim ph thuc vo tng cht in li. 8

HA HC 11

Cu 60: Cht in li yu c in li nm trong khong :

Bin son : Thy Ti 0966.293.727

A.0 1. B.0 < 1. C.0 < 1. D.0 < < 1. Cu 61 : Thm 10 ml dung dch NaOH 0,1M vo 10 ml dung dch NH 4Cl 0,1M v vi git qu tm sau un si. Dung dch s c mu g trc v sau khi un si ? A. Xanh thnh B. thnh tm C. Xanh thnh tm D.Ch mt mu xanh Cu 62: Cho nhng ion c th ng thi tn ti trong dung dch : A. S2-, Fe2+,Cu2+ v ClC.H+,Cl-, Na+ v Al3+ B. Mg2+, SO42-,Cl- v Ba2+ D.Fe3+,Cl-, OH- v Ba2+ 2+ Cu 63: Phng trnh : S +2H H2S, phng trnh ion thu gn ca phn ng : A. NaHSO4 + Na2S 2Na2SO4 + H2S C.BaS + H2SO4 BaSO4 + H2S B. FeS + 2HCl FeCl2 + H2S D.2CH 3COOH + K2S 2CH3COOK + H2S