De Thi Huu Ich Cho SVHoaHoc

thi hu ch dnh cho sinh vin Ha hc - 1
2009
1
Vn Hip Lp K52A-Ha hc.Trng i hc khoa hc T Nhin-HQGHN
Li gii thiu
Kin thc l kho bu khng phi ca ring ai. V vy, bn ng ngn ngi khi chia s cho mi
ngi .
Cc bn thn mn!
Ban u t khng nh lm ci tng hp thi ny u nhng m thy tnh trng thiu ti
liu hc tp nht l nhng thi cc nm trc vn c cnh SV chng ta coi nh l bo
bi v c th luyn tp qua cc dng thi cc kha trc v bit u trong chng ta li c
ngi no on c thi cho kha mnh th sao nh?
Thi ni v ni dung chnh no.T tng hp cc thi ca cc kha trc dnh cho SV
khoa Ha hc Trng H Khoa hc t nhin HQGHN.y l nhng bi rt hu ch
cho nhng SV kha sau ca khoa Ha hc Trng HKHTN nhng t ngh n cng l 1
ngun tham kho hu ch cho nhng bn ang hc Ha hoc yu thch ngnh Ha.Nhn
y t cng rt cm n CLB Ha hc trng HKHTN cung cp thi v t da trn
chnh sa v b sung li cho y .Hin ti do cng vic hc tp trn lp kh bn nn
t cha nh my c nhng thi gn y nht dnh cho SV K51-K52 .Nn y mi ch
l phn u ti liu t mun gii thiu cho tt c cc bn thi.Khi no c thi gian rnh th
t s vit tip , b sung vo ti liu trong ngn sch hc tp ca cc bn.Nu cc bn mun
ly cc ti liu khc m t cha kp nh my v chuyn sang dng PDF th hy lin lc vi
t nh.V y l ln u tin nn cn non kinh nghim ,chc chc s cn rt nhiu li cn
phi sa do t mong s nhn c nhng phn hi cng nh nh gi ,gp ,ph bnh
t cc bn.Hoan nghnh!Hoan nghnh!
H tn : Vn Hip
a ch : Lp K52A-Ha hc.Trng HKHTN-HQGHN
19 L Thnh Tng ,Hon Kim,H Ni
in thoi : 0973.616.852 (Cng p ch nh??)
Email : dovanhiep@hus.edu.vn hay vanhiepk52a@gmail.com
Mong rng ti liu m t gii thiu cho cc bn s phn no c ch cho cng vic hc tp
hay nghin cu ca cc bn.Chc cc bn hc gii v thnh cng s n vi cc bn.
Tm bit !
2009
2
Mn thi: Vt l in - Quang.
S vht: 05
Dnh cho :K47 khoa Ha
Thi gian lm bi: 120 pht.
Cu 1
a) Xy dng cng thc v mi lin h gia in th v in trng.
b) Cho qu cu c lp bng cht dn in, c tch in Q = 2,5 nC phn b u trn mt
qu cu; c bn knh R = 6,85cm. Hy tnh:
- Nng lng ca qu cu.
- Tnh in trng v in th ti im cch tm qu cu l 5 cm v 13,7 cm.
Cho bit: c =1;
0
c = 8,85.10-12 C
2
/N.m
2
; k = 9.109 N.m
2
/C
2
Cu 2
a) Vit cng thc ca nh lut Bio - Savart - Laplace cho mt nguyn t dng.
b) Vit cng thc tnh cm ng t do mt dng in thng gy ra.
c) Cho dy dn c dng in I = 1A chy qua, trong khng kh; c gp li thnh mt tam
gic vung nh hnh v. Bit
.
A = 900,
.
B = 300 v BC = 10 cm.
Tnh cm ng t ti cc nh ca tam gic.
Cho bit: =1;
0
= 4t .10
-7
T.m/A
2009
3
Cu 3
- Pht biu thuyt lng t nh sng ca Einstein.
- Vn dng thuyt lng t nh sng gii thch cc quy lut v dng quang in.
- Nu mt lp lun chng t thuyt sng v nh sng khng th gii thch c hiu ng
quang in.
Cu 4
Mt cch t c s vch trn mt cm l 2000 vch/cm, c chiu vung gc bi mt chm
sng n sc c bc sng 500 nm. Mn quan st c t trn tiu din ca mt thu
knh hi t c tiu c f = 1m, t sau thu knh v song song vi cch t.
a) Tm khong cch t cc i nhiu x trung tm n cc i nhiu x chnh th nht.
b) Tnh s cc i nhiu x chnh ti a cho bi cch t.
C
B
2009
4
S vht: 05
i tng d thi: K48 ngnh Ha
Cu 1
1. p dng nh lut Ostrogradsky Gauus xc nh: in trng do qu cu kim loi
bn knh R tch in Q gy ra ti im M cch tm qu cu mt on r > R. T kt qu thu
c c nhn xt g?
2. Mt qu cu kim loi, bn knh 10 cm c tch in n in tch 1,6.10
-8
C. Hy xc
nh:
a) in trng, in th ti im M
1
cch tm qu cu mt on 5 cm.
b) in trng, in th ti im M
2
cch tm qu cu mt on 20 cm.
c) Nng lng (tnh in) ca qu cu. Mt nng lng in trng ti im M
2
.
Cho hng s in mi ca kim loi v khng kh c =1, ly = 8,86.10
-12
C
2
/N.m
2
.
Cu 2
1. Mt dy dn c un thnh ng trn bn knh R tm O, c dng in mt chiu
cng I chy qua. Chiu ca dng in cng chiu kim ng h. T nh lut Bio
Savart Laplace Hy suy ra chiu v ln ca ttrng ti tm O do dng in gy ra.
2. Cho C l mt vng dy kim loi, t trong t trng c vect cm ng t nh hnh v.
Mi tn trn ng cong C ch chiu dng cm ng. Cho bit t trng tng hay gim? Gii
thch ti sao?
2009
5
C
Cu 3
Trnh by hin tng phn cc quay v nu mt s ng dng.
Cu 4
kh phn x i vi tia sng laser He Ne bc sng 632,8 nm ri theo phng vung
gc vi thu knh, ngi ta trng ln b mt thu knh mt lp vt liu trong sut chit sut
1,3. Bit thu knh thy tinh chit sut 1,5. Tnh dy ti thiu ca lp kh phn x trn.
Cu 5
Mt cch t nhiu x gm nhng khe rng l 300 nm v cch nhau 900nm. Ngi ta
chiu vo cch t mt nh sng n sc bc sng 600 nm theo phng vung gc vi
cch t.
a) Hi nh sng nhiu x ton phn c bao nhiu cc i nhiu x.
b) Gi s rng cch t c s dng l 1,2 cm.
- Tnh bn rng gc ca vch ph quan st c ph nhiu x bc mt.
- Tnh gii hn phn ly ca cch t trong vng ph gn 600 nm.
B
+

2009
6
S vht: 05
Cu 1 (2,5 ) Mt a trn bn knh R, tch in u vi mt o .
a) Xy dng cng thc tnh cng in trng ti mt im nm trn trc a v cch
tm a mt on l h.
b) Chng minh rng nu h0 th biu thc thu c chuyn thnh biu thc tnh cng
in trng gy ra bi mt phng v hn tch in.
c) Chng minh rng nu h >> R th biu thc thu c chuyn thnh biu thc tnh cng
in trng gy bi in tch im.
Cu 2 (2,5 )
a) Nng lng t trng ca dng in. Mt nng lng t trng.
b) Mt dy dn di v hn c dng in 5A chy qua c un thnh mt gc vung. Tm
cng t trng ti 1 im nm trn phn gic ca gc vung v cch nh 10 cm.
Cu 3 (2 )
a) Trnh by hin tng phn cc qua bn Tourmaline v gii thch.
b) Th no l hin tng phn cc quay, nu mt ng dng ca hin tng phn cc quay.
2009
7
Cu 4 (2 )
Mt cch t nhiu x c 2000 vch/mm c chiu bi nh sng n sc c bc sng
500 nm di gc ti l 300.
a) Tnh s cc i nhiu x c th quan st c v gc tng ng quan st thy cc
cc i .
b) Nu chiu theo phng vung gc vi cch t th s cc i nhiu x quan st c l
bao nhiu? Khi cch t c kh nng tn sc hay khng?
Cu 5 (1 )
kh phn x i vi tia sng laser He - Ne bc sng 632,8 nm ri theo phng vung
gc vi thu knh, ngi ta trng ln b mt thu knh mt lp vt liu trong sut chit sut
1,3. Bit thu knh thy tinh chit sut 1,5. Tnh b dy ti thiu ca lp kh phn x trn.
2009
8
Mn thi: Nh nc v php lut i cng
S vht: 02
Cu 1
Trnh by v tr php l, chc nng c bn ca cc c quan nh nc Trung ng Vit
Nam. ( C v s ).
Cu 2
Nu nh ngha thc php lut, cc bin php gio dc v nng cao thc php lut trong
sinh vin nc ta hin nay.
S vht: 02
2009
9
Cu 1
Trnh by ni dung c bn chc nng kinh t ca nh nc ta hin nay?
Cu 2
Phn tch v cho v d v cc du hiu ca vi phm php lut. Sinh vin cn lm g gp
phn vo vic u tranh phng v chng cc vi phm php lut trong hc ng.
S vht: 02
Cu 1
Phn tch v tr php l, chc nng c bn ca Quc hi nc Cng ha x hi ch ngha
Vit Nam.
Cu 2
thc php lut l g? Theo anh (ch), lm th no nng cao thc php lut trong sinh
vin?
2009
10
Mn thi: Ha hc hu c I
S vht: 04
i tng d thi: K46 A, S ngnh Ha
Cu 1
Hy vit cng thc cu to v tn gi cc ng phn ca ankan c cng thc phn t
C
6
H
14
.
Cu 2
Cho propen tc dng vi HBr. Hy ch r sn phm chnh, sn phm ph khi khng c v
khi c xc tc peoxit. Vit c ch phn ng gii thch s to thnh cc sn phm .
Cu 3
Vit s phn ng v c ch cc phn ng sau:
a) Alkyl ha benzen c mt AlCl
3
khan.
b) Axyl ha benzen c mt AlCl
3
khan.
Phn ng no thu c sn phm th mono - , i - , tri - ,...Ti sao?
Cu 4
2009
11
Hon thnh cc phn ng sau v cho bit phn ng chy theo c ch no (thuc loi phn
ng no) ?
a.
- HBr
b.

Zn
c.
NaOH
d.
HCl c

e.
H
H
H
CH
3
Br
CH
3
Br
Br
H
H
CH
3
CH
3
C H
3
C H
2
C CH
3
CH
3
Br
C H
3
C
CH
3
CH
3
OH
N
+
O
-
O
N
+
O
-
O Cl
2009
12
NaOH
f.
Br
2
CCl
4
S vht: 04
Cu 1 (3 )
Trnh by phn ng cng electrophil vo anken.
Cu 2 (3 )
Trnh by phn ng th electrophil vo nhn thm.
Cu 3 (2 )
a) Hy vit cc phng trnh v c ch to thnh tt c cc sn phm trong phn ng ca
sec- butylclorua vi dung dch KOH trong etanol.
b) Hy gii thch ti sao khi c mt ion bromua, sec- butylbromua quang hot li to thnh
hn hp raxemic.
Cu 4 (1 )
Hy vit sn phm cc phn ng sau:
a) CH
3
MgI + HCO
2
C
2
H
5
= ?
b) CH
3
CH
2
MgBr + CS
2
= ?
CH
2
2009
13
c) CH
3
CH
2
MgBr + NH
3
= ?
d) (CH
3
)CMgCl + CO
2
= ?
e) CH
3
MgI + CH
3
COCH
2
CH
2
COC
2
H
5
= ?
Cu 5 (1 )
Hy vit cc phn ng iu ch cc hp cht theo s sau (c th dng thm cc tc
nhn khc nu cn thit):
C
6
H
6
C
6
H
5
CH(CH
3
)
2
C
6
H
5
OCH
3
2-(Br), 4-(NO
2
)C
6
H
4
OCH
3
S vht: 03
i tng d thi: K48B CN Ha
Cu 1
1. Hy vit cng thc cu to ca cc hp cht sau v ch ra nguyn t cacbon bt i (vt
khng trng nh) mi hp cht (nu c):
a) 3- Clo- 2- metylhexan
b) 2, 3, 4- Tri metylpentan
c) 1, 4- ibrom- 2- metylbutan
d) 2, 2- imetyl pentan
2. Hy vit cng thc cu trc ca cc ng phn c cng thc phn t l C
4
H
8
. Gi tn
chng theo IUPAC. ng phn no c th xut hin dng cis v trans.
Cu 2
Hirocacbon C
6
H
12
c nhng c tnh sau:
2009
14
1. Lm mt mu dung dch brom
2. Tan trong H
2
SO
4
3. Khi hiro ha chuyn thnh n-hexan
4. Khi oxi ha bng KMnO
4
cho mt axit kiu RCOOH.
Hy vit cc phn ng xy ra trn; gi tn hirocacbon ny v cho bit c th xut hin
dng cis v trans hay khng?
Cu 3
T cc anken thch hp hy vit phng trnh iu ch:
a) 2- Iot- 2- metyl pentan
b) 1- Brom- 3- metyl butan
c) 1- Clo- 1- metyl xiclohexan.
Cu 4
Hirocacbon thm C
9
H
8
c nhng c tnh sau:
1. Cng hp 2 phn t brom
2. Khi b oxi ha cho axit benzoic
3. Vi bc nitrat trong amoniac cho kt ta c trng.
Hy vit cc phng trnh phn ng xy ra trn v gi tn cc hirocacbon ny.
2009
15
S vht: 04
Cu 1 (2,5 )
Vit cng thc, tn sn phm v gii thch c ch cc phn ng sau:
a) t- Butylbromua + - OC
2
H
5
A + C
2
H
5
OH + Br
-
b) t- Butylclorua + OH
-
B + Cl
-
c) 2, 4- initroclobenzen + OH
-
C + Cl
-
d) trans- 2- Clometylxiclopentan + C
2
H
5
O
-
D + C
2
H
5
OH + Cl
-
e) Isopentan + Cl
2
( h ) E (sn phm chnh, th mono)
Cu 2 (2,5 )
Gii thch c ch phn ng v quy lut th vng benzen. So snh tc phn ng nitro
ha benzen, toluen, nitrobenzen v triflobenzen.
Cu 3 (2,5 )
Hon thnh cc phn ng sau: (vit cng thc sn phm di dng lp th v gi tn)
a) CH
3
-CH=CH-C
2
H
5
+ Br
2
/ CCl
4
A
1
+ A
2
cis- pent- 2- en
2009
16
b) CH
3
-CH=CH-C
2
H
5
+ CH
3
COOH/ CH
2
Cl
2
B
1
+ B
2
cis- pent- 2- en
c)
CH
2
C H
3
C H
3
C H
3
A + B
4-t-butyl(metylen)-xiclohexan
d) P- Bromtoluen + HNO
3
/ H
2
SO
4
C
as Cl /
2
D
e) CH
3
-CO-CH
2
CH
3
+ C
6
H
5
MgBr E F G H
Cu 4 (2,5 )
Gii thch cu dng ca n- butan. (vit cng thc phi cnh v hnh chiu Niumen)
2009
17
S vht: 04
Cu 1
Hy gii thch nguyn nhn gy ra cc tnh cht sau:
1. Tnh axit ca: FCH
2
COOH > ClCH
2
COOH > BrCH
2
COOH
2. Tnh axit ca: HCCH> CH
2
=CH
2
> CH
3
-CH
3
3. Tnh baz ca: Anilin > p- Cloanilin > p-nitroanilin
Cu 2
1.Vit cng thc phi cnh, cng thc chiu Fis v gi tn cc ng phn quang hc ca
CH
2
OH-CHOH-CHO.
2. Hy vit cng thc Niumen 2 cu hnh R v S ca metyletylbutylcacbinol.
3. Hp cht sau y c nhng loi ng phn no? Hy vit cng thc cu to v gi tn
ng phn : CH
3
-CBr=CH-CH
2
OH
4 .Hp cht c vit di y c cu hnh R hay S:
2009
18
H
H
H
C
2
H
5
H
Cl
Cu 3
Hy hon thnh, gi tn v gii thch c ch cc phn ng sau:
1. C
6
H
6
+ HNO
3
/ H
2
SO
4
(c)
2. CH
3
-CH=CH
2
+ HBr (peoxit)
3. CH
3
CH
2
Br + NaOH/H
2
O
4. (CH
3
)
3
CBr + C
2
H
5
OK/C
2
H
5
OH
5. (CH
3
)
3
CH + Cl
2
Cu 4
T benzen Hy iu ch:
1. Etylbenzen
2. Axit 3-nitrobenzoic
3. 3- clobrombenzen
Gi tn v gii thch c ch ca mt trong 3 phn ng.
2009
19
Mn thi : Nhit ng hc
S vht: 03
Cu 1
a) Pht biu nh Clausius v nh Thomson.
Chng minh hai nh ny l tng ng.
b) Gii thch v sao c th s dng entropi m khng th s dng ni nng xt chiu
hng v gii hn qu trnh trong h c lp.
Cu 2
a) Vit phng trnh ng nhit, phng trnh ng p ca phn ng ha hc, phng
trnh biu th s ph thuc ca hng s cn bng phn ng vo p sut.
b) Chng minh rng cc phng trnh l cc biu thc nh lng ca nguyn l chuyn
dch cn bng Lsatli.
Cu 3
a) Phng trnh
2
ln
RT
H
dT
P d A
= p dng cho trng hp no? Gii thch.
b) i vi benzen nguyn cht, nhit nng chy tnc = 5,530 C p sut P= 1atm, nhit
nong chy
nc
H A = 30,6 cal/g; th tch ring ca n th lng v th rn l V
1
= 1,11
2009
20
cm
3
/g v V
r
= 1,106 cm
3
/g. Hi khi p sut ngoi tng ln 10 atm th nhit nng chy ca
benzen l bao nhiu? (Cho 1 cal = 41,4 cm
3
.atm)
Cu 4
a) Thit lp quy tc pha ca Gibbs
b) S dng quy tc pha xc nh s bc t do f ca h:
- Ti im ba ca h 1 cu t.
- Ti im ng ph ca h 2 cu t.
- Ti im tecti ca h 2 cu t.
Mn thi : Nhit ng hc
S vht: 03
Cu 1
Vit phng trnh biu din s ph thuc vo nhit ca:
a) Hiu ng nhit ( H A ) ca phn ng.
b) Hng s cn bng ( K
p
) ca phn ng.
c) p sut hi bo ha ( P ) ca cht lng.
d) tan ( x
2
) ca cht trong dung dch l tng
Nu ngha v ng dng ca cc phng trnh .
Cu 2
250 C entropi ca lu hunh rombic v lu hunh n t bng 31,88 v 32,55 J/mol.K.
Nhit hnh thnh ca 2 dng tng ng bng 0,00 v 0,30 kJ/mol.
a) Tnh G A i vi qu trnh chuyn S
rombic
S
n t
250
0
C. T kt qu thu c c th
rt ra kt lun g?
2009
21
b) Xc nh nhit ti cn bng gia 2 dng chuyn ha c thit lp. Chp nhn
H A v S khng ph thuc nhit .
Cu 3
a) Dung dch l tng l g? Cho v d.
b) Chng minh rng p sut hi chung ca cc cu t A, B trong dung dch v cng long l
mt hm tuyn tnh ca thnh phn dung dch.
c) Dung dch Axeton Clorofooc l mt dung dch sai lch dng
i i i
x P P
0 0
> hay sai lch
m? Vit phng trnh biu th s ph thuc ca p sut hi chung ca dung dch vo
thnh phn dung dch.
Mn thi : Nhit ng hc
S vht: 03
Cu 1
1. Trnh by phng php xc nh nhit ha hi ca H
2
O.
a) Da vo nh lut Hess.
b) Da vo phng trnh Clapeyron - Clausius.
2. Vit phng trnh biu th s ph thuc ca nhit ha hi ca H
2
O vo nhit .
3. Cho bin thin entropi trong qu trnh chuyn ng p 1 mol nc 0
0
C thnh hi
nc 100
0
C l S = 154,54 J/K.mol. Nhit nng chy ca nc 0
0
C l H
nc
= 6,009
kJ/mol. Chp nhn nhit dung ng p ca nc lng trong khong t 0
0
C n 100
0
C
khng i v bng 75,31 J/K.mol
a) Tnh bin thin entropi trong qu trnh chuyn ng p, ng nhit 1 mol nc lng
100
0
C thnh hi nc.
b) Tnh nhit ha hi mol ca nc 100
0
C.
2009
22
Cu 2
Vit phng trnh ng nhit ca phn ng ha hc:
aA + bB = cC + dD (khi P, T= const)
Nu ngha v cc ng dng ca phng trnh .
Cu 3
1. V gin trng thi ca h Pb - Sn trong h ta nhit - thnh phn (khi P =const)
Gii thch v cc ng cong trn gin .
2. Ti nhng v tr no trn gin h gm 2 pha cn bng? Hy xc nh s bc t do f
ca h ti cc v tr .
Mn thi : Thy kh
S vht: 02
Cu 1 ( 4 )
Thit lp phng trnh mt ng p v phn b p sut cho trng hp bnh cha cht lng
chuyn ng ngang vi gia tc a khng i.
Cu 2 (3 )
Hy trnh by nguyn l ca ng venturi.
Cu 3 (3 )
Trong ng nm ngang c ng knh 60 mm v c nhm tng i n = 10
-4
c nc
chy ( nhit 15
0
C) vi lu lng 10 m
3
/h.
Hy cho bit tn tht p sut do ma st thay i nh th no nu lu lng th tch ca
dng chy cng nh ng knh ng tng gp i.Cho bit: khilngring ca nc
150
0
C l 999 kg/m
3
; nht = 1,1404.10
-3
N.s/m
2
. H s ma st c tnh theo cng
thc:
25 , 0
Re
3164 , 0
=
2009
23
Mn thi : Thy kh
S vht: 02
Cu 1
nht l g? Trnh by cng thc tnh nht v gii thch cc i lng, ghi r cc n
v.
Cu 2
Hy trnh by cng thc tnh chiu cao ht v chiu cao y ca bm. cao ht ti a ca
bm ph thuc vo nhng yu t no?
Cu 3
Trong ng nm ngang c ng knh 30 mm nc chy ( nhit 150
0
C) vi lu lng
5660 l/h. Ti mt im bt k trn ng ng khi ngi ta ni mt ng h theo phng
thng ng thy ct nc dng ln cao 2,5 m. Ti chnh im pha di s cni
vi mt u ca p k thy ngn hnh ch U. u th hai ca p k ch U c ni vi
mt im cch im u tin 5 m.
Hy tnh:
- p sut ti im th hai nu nhm tng i ca ng l n = 0,002.
- S chnh lch thy ngn trong p k.
- ng knh tng i ca ng s phi l bao nhiu lu lng tng t chnh lch
mc thy ngn trong p k s bng 7,5 cm?
2009
24
Cho bit: khi lng ring ca nc 200
0
C l 998,2 kg/m
3
; khi lng ring ca thy
ngn l 13600 kg/m
3
; nht = 1,1005.10
-3
N.s/
m2
. H s ma st c tnh theo cng
thc:
5 , 6 ) . (Re 135 , 0
Re
log 8 , 1
1
+
=
n
Mn thi : Lch s ng Cng sn Vit Nam
S vht: 04
Cu 1
Trnh by hon cnh ra i, ni dung, ngha ca bn ch th Nht Php bn nhau v hnh
ng ca chng ta do thng v Trung ng ng nu ra ngy 12/3/1945?
Cu 2
Trnh by ngha lch s ca cuc khng chin chng M cu nc.
Mn thi : Lch s ng Cng sn Vit Nam
S vht: 04
Cu 1
Trnh by ngha lch s ca cch mng thng Tm nm 1945.
Cu 2
2009
25
Trnh by nhng thun li, kh khn ca nc Vit Nam dn ch cng ha sau thng Tm
nm 1945 v nhng ni dung c bn ca ch th Khng chin kin quc do Ban Thng v
Trung ng ng nu ra ngy 25/11/1945.
Mn thi : Vn ha i cng
S vht: 03
Cu 1
L sn phm ca li t duy tng hp, lch m dng c xy dng gm my giai on?
Cu 2
Chng minh nguyn l hi ha m dng ca vn ha gc nng nghip qua bng gii m
Lc Th.
Mn thi : Ha hc phn tch
S vht: 05
i tng d thi: K45A, S ngnh Ha
Cu 1
Cn chnh xc 2,75325 gam axit yu HA, ha tan ht vo nc thnh 250,00 ml dung dch
A. Ly ra 50,00 ml A chun n bng dung dch chun NaOH 0,10M. Bit rng khi thm
vo 37,64 ml dung dch NaOH trn th pH hn hp nhn c bng 5,00. Khi thm vo
62,50 ml dung dch NaOH trn th t ti im tng ng.
1. Tnh khi lng mol v hng s axit K
a
ca axit HA.
2. Tnh pH ca dung dch ti im tng ng trong php chun trn.
Cu 2
Cho dung dch B cha Fe
3+
v Al
3+
. Ly 25,00 ml dung dch B, iu chnh pH bng 2 ri
thm cht ch th axit sunfosalixylic vo, un nng n 850C, chun bng dung dch
EDTA 0,0105M. Khi thm vo 24,63 ml EDTA th cht ch th i mu.
2009
26
Li ly 25,00 ml dung dch B na, iu chnh v gi khng i pH ca n bng 5,0 ; thm
vo 50,00 ml dung dch EDTA 0,0105M (d), cht ch th xilenol da cam, un nng n
850C ri chun lng EDTA cn d bng dung dch chun Zn
2+
0,0100M dng ht 8,74
ml dung dch chun th cht ch th chuyn mu.
1. Gii thch vn tt nguyn tc ca php xc nh trn.
2. Tnh nng mol ca Fe
3+
v Al
3+
trong dung dch B.
Bit:
FeY
-
= 10
25.1
;
AlY
-
= 10
16.13
;
ZnY
-
= 10
16.10
.
Khi pH = 2,0 gi tr =10
13.43
; khi pH = 5,0 gi tr
Y(H)
= 10
6.45
.
Cu 3
xc nh hm lng ca CO trong khng kh ca l luyn cc, ngi ta ly 24,70 lit
mu khng kh, cho mu i qua thit b cha lng d I
2
O
5
nung nng oxi ha ton
b CO thnh CO
2
v to thnh I
2
theo PTP:
I
2
O
5
+ 5CO = 5CO
2
+ I
2
Lng I
2
to thnh c ct v cho hp th ht vo dung dch KI d ri c chun
bng 7,75 ml dung dch Na
2
S
2
O
3
0,00221M.
Hy tnh hm lng ca CO trong mu khng kh theo ppm. Bit khi lngring ca mu
khng kh l 1,20 g/lit (CO = 28).
Cu 4
Chun dung dch Fe
2+
0,1000M bng dung dch KMnO
4
trong mi trng axit c pH
khng i bng 0.
a) Tnh th oxi ha - kh ti im tng ng.
b) Tnh sai s chun nu kt thc th +1,00V. Bit th oxi ha tiu chun ca h
MnO
4
-
,
H
+
/ Mn
2+
, H
2
O bng 1,51V v ca h Fe
3+
/Fe
2+
bng + 0,68V.
2009
27
Mn thi: Ha hc phn tch
S vht: 05
i tng d thi: K46A ngnh Ha
Cu 1
1. Dung dch m pH l g? Cho th d. Kh nng m ca cc dung dch m ph thuc
vo nhng yu t no?
2. Axit glicolic (vit tt l HA) c hng s axit K
a
= 1,48.10-4. Cn phi trn bao nhiu ml
dung dch HA 0,200M vi bao nhiu ml dung dch NaOH 0,200M thu c dung dch
m c pH = 4,50.
3. Tnh sai s chun khi chun dung dch HA 0,100M bng dung dch NaOH 0,100M
dng cht ch th i mu ti pH = 9,5.
Cu 2
xc nh cng ca mt loi nc ngi ta lm nh sau:
1. Ly 100,00 ml mu nc, chun bng dung dch chun HCl 0,1250M theo metyl da
cam, dng ht 5,20 ml dung dch HCl .
2. Li ly 100,00 ml mu nc na, un si, ngui ri lc b kt ta, thu ly nc lc.
Thm 15,00 ml dung dch hn hp NaOH + Na
2
CO
3
vo nc lc . Lc, ra kt ta mi
2009
28
to thnh, thu ly nc lc v nc ra c dung dch A. Chun dung dch A bng
dung dch chun HCl 0,1250 theo metyl da cam, dng ht 43,60 ml dung dch HCl .
a) Hy vit cc PTP xy ra.
b) Tnh cng tm thi, cng vnh cu v cng chung theo tng s milimol ca cc
mui Ca, Mg trong loi nc .
Cu 3
Thm 25,00 ml dung dch EDTA 0,0200M vo 25,00 ml dung dch Ni
2+
0,0200M c m
bng dung dch m NH
3
+ NH
4
Cl c pH = 9,0 v khi
Y(H)
= 10
1.28
;
) (
3
NH Ni
o = 10
8.2
. Phc
ca Ni
2+
vi EDTA c hng s bn l =10
18.62
.
Hi khi bao nhiu % lng ion Ni to phc vi EDTA.
Cu 4
Chun dung dch Fe
2+
0,2000M bng dung dch chun KmnO
4
0,0400M c nng cn
bng ca ion H
+
khng i bng 1 mol/lit.
a) Tnh hng s cn bng ca phn ng.
b) Tnh nng cn bng ca ion Fe
2+
ti im tng ng.
c) Nu trong php chun ny kt thc khi th oxi ha kh ca dung dch bng
+1,00V th sai s l bao nhiu?
Cho bit cc th oxi ha kh tiu chun ca cc h lin hp l:
MnO
4
, H
+
/ Mn
2+
, E
0
= +1,51V
Fe
3+
/Fe
2+
, E
0
= +0,77V.
2009
29
S vht: 05
Cu 1
Tnh nng cn bng ca cc ion v phn t trong dung dch H
3
PO
4
c nng 5.10
-3
M.
Bit H
3
PO
4
c: K
1
= 7,6.10
-2
; K
2
= 6,2.10
-8
v K
3
= 4,2.10
-13
.
Cu 2
Cn thm bao nhiu ml dd NaOH 0,1 M vo 50 ml dd CH
3
COOH 0,2 M
(K = 10
-4.75
) c dd hn hp c pH bng:
a) 4,00 b) 5,50
c) 7,00 d) 9,00
php chun trn c sai s khng vt qu 0,2% th phi dng cc cht ch th c pT
nm trong khong pH no?
Cu 3
2009
30
Chun 100 ml dd MgCl
2
bng dd EDTA c cng nng l 10
-2
M; dng dd m NH
3
+
NH
4
Cl c pH = 10 gi cho pH ca dung dch khng i trong qu trnh chun .
1. Tnh pMg sau khi thm vo 50 ; 90 ; 99,9 ; 100 ; 100,1 ; 101 ; 110 ml dd EDTA.
2. Tnh sai s chun nu kt thc chun khi pMg = 4 v pMg = 5,3.
Bit:
MgY
-
= 10
8.7
; H
4
Y c pK
1
= 2; pK
2
= 2,7; pK
3
= 7,2; pK
4
= 10,3.
Cu 4
Chun 20 ml dd FeSO
4
0,09N bng dd K
2
Cr
2
O
7
0,015M trong mi trng c pH = 0.
1. Tnh hng s cn bng ca phn ng.
2. Tnh th ca dung dch sau khi thm 10 ; 18 ; 19,8 ; 19,98 ; 20 ; 20,02 ; 20,2 v 22,0
ml dd K
2
Cr
2
O
7
.
3. Tnh sai s chun nu kt thc chun khi E
c
= 0,94V v E
c
= 1,35V.
Bit:
0
/
2 3 + +
Fe Fe
E = 0,68V v
0
/ ,
3
7 2
+ +
Cr H O Cr
E = 1,36V
S vht: 04
Cu 1
1. chun cc dung dch HCl c nng sau: 1M ; 0,1M ; 0,01M ; 0,001M bng dd
NaOH c cng nng vi sai s khng vt qu 0,2% th cn chn nhng cht no trong
nhng cht ch th sau y:
- Metyl da cam (pT = 4)
- Metyl (pT = 5)
- Brom phenol (pT = 6,5)
- trung tnh (pT = 7)
- Phenolphtalein (pT=9).
2. Mt cht ch th axit - baz l mt axit hu c yu HInd c hng s axit K
a
=10
-7.3
. Dng
axit mu vng, dng baz mu xanh. Mt Ngi nhn c mu dng axit khi nng ca
2009
31
n ln hn nng dng baz 10 ln v nhn c mu dng baz khi nng ca
n ln hn dng axit 2 ln. Tnh khong i mu ca ch th .
Cu 2
1. Chun dd Mg
2+
0,01M bng dd EDTA cng nng , c pH = 10 v dng ch th i
mu khi t s cc nng
] [
] [
2
Ind
MgInd
= 1. cht ch th i mu ng im tng ng th
hng s bn iu kin bng bao nhiu? Bit
MgY
2-
= 5.10
8
.
2. Tnh th tch dd EDTA 0,05M cn chun:
a) Ca c trong 0,4397g mu khong cht c cha 81,4% CaHPO
4
.2H
2
O (172,09 g/mol).
b) Ca v Mg c trong 0,1557g mu cha 92,5% olomit CaCO
3
.MgCO
3
(184,4 g/mol).
Bit axit H
4
Y c K
1
= 10
-2
; K
2
= 10
-3
; K
3
= 10
-6
; K
4
=10
-11
.

Cu 3
Gii thch ti sao bc kim loi khng tc dng vi HCl m tc dng vi HI gii phng H
2
bit:

0
/ Ag Ag
E
+
= +0,8V ; T
AgCl
= 10
-10
; T
AgI
= 10
-16
.
Cu 4
Ha tan 0,125g hn hp K
2
CO
3
, Na
2
CO
3
v SiO
2
bng dd HCl. Lc b b khng tan, lm
bay hi nc lc thu c 0,1282g hn hp NaCl v KCl. Ha tan hn hp ny vo nc
ri chun bng dd AgNO
3
0,1003M th ht 19,7 ml.
Tnh hm lng % cc cht trong hn hp phn tch.
(Ag = 108; Si = 28; K =39; Na = 23; C = 12; Cl = 35,5; H = 1; O = 16).
2009
32
S vht: 04
Cu 1
chun cc dd NaOH c nng sau: 1M ; 0,1M ; 0,01M ; 0,001M bng dd HCl c
cng nng vi sai s khng vt qu 0,2% th cn chn nhng cht no trong nhng
cht ch th sau y:
- Metyl da cam (pT = 4)
- Metyl (pT = 5)
- Brom phenol (pT = 6,5)
- trung tnh (pT = 7)
- Phenolphtalein (pT=9).
Cu 2
Tnh hng s bn iu kin ca phc CaY
2-
v ZnY
2-
trong dung dch NH
3
5M c pH = 12.
Bit rng nng ban u ca Ca
2+
v ZnY
2-
khng ng k so vi nng NH
3
.
2009
33
Bit CaY
2-
c = 10
10.6
; ZnY
2-
c = 10
16.5
. Cc phc Zn
2+
vi OH
-
c logarit hng s bn
tng cng ln lt l 4,4 ; 11,3 ; 13,1 ; 14,7. Axit H
4
Y c pK
1
=2 ; pK
2
= 2,67 ; pK
3
= 6,27 ;
pK
4
=10,95. Cc phc Zn
2+
vi NH
3
c
11
= 2 ;
12
= 4,4 ;
13
= 6,7 ;
14
= 8,7.
Cu 3
Bao nhiu mg BaSO
4
tan ra khi ra n bng:
1. 250 ml nc ct.
2. 250 ml nc c cha 0,83g (NH
4
)
2
SO
4.
Bit T
4
BaSO = 10
-10
Cu 4
C mt mu mui clorua, ly 0,74 g ha tan thnh 250 ml, thm 40 ml dd AgNO
3
1M vo 50
ml dd trn kt ta ht Cl
-
. Sau chun lng d AgNO
3
th tn ht 19,35 ml dd
NH
4
SCN 1,05M.
Tnh hm lng % clo c trong mui clorua.
Cu 5
Tnh th oxi ha - kh tiu chun iu kin ca cp
0
Cu
Cu
+
khi c d CN
-
to phc
[Cu(CN)
4
]
3-
c = 10
30.3
.
Bit th oxi ha - kh tiu chun ca cp
0
Cu
Cu
+
= 0,52V
2009
34
Mn thi : Ha hu c II
S vht: 04
i tng d thi: K46 A,S ngnh Ha
Cu 1
Vit cc phng trnh phn ng sau y ca anhit hoc xton:
- Kh thnh ancol.
- Kh thnh hirocacbon.
- Phn ng vi hirazin.
- Phn ng vi iofom.
- Phn ng vi hp cht ilit.
- Phn ng Canizaro.
- Phn ng anol ha.
- Phn ng vi hp cht c magi.
2009
35
- Phn ng cng vi bisunfit.
- Phn ng vi HCN.
Cu 2
T n- propanol v cc ha cht cn thit khc Hy vit phng trnh v c ch phn ng
iu ch axit butyric (CH
3
CH
2
CH
2
COOH) bng cc phng php khc nhau.
Cu 3
Hp cht C
7
H
8
O khng cho phn ng nhum mu vi FeCl
3
, khng tan trong dung dch
kim nhng khi b oxi ha s cho axit benzoic.
Hy xc nh cu to ca hp cht .
Cu 4
Trnh by cc phng php xc nh C, H.
Mn thi : Ha hu c II
S vht: 03
Cu 1
Nu cc phng php iu ch amin.
Cu 2
Hy ngh s tng hp sau y:
1. CH
3
CH
2
CH
2
Cl CH
3
CH
2
CH
2
COOH (bng 2 cch)
2. CH
3
CH
2
CH
2
OH CH
3
CH
2
CH(OH)- COOH
3. CH
3
(CO)CH
3
CH
3
CH(CH
3
)- COOH
Vit phng trnh phn ng v iu kin cn thit thc hin cc chuyn ha trn.
2009
36
Cu 3
un nng toluen vi dd KMnO
4
. Sau phn ng lc b kt ta thu dung dch khng mu, axit
ha dung dch ny c cht A kt ta. Cho A tc dng vi thionyl clorua (SOCl
2
) c cht
B. Hiro ha B vi xc tc Pd c cht C. Cho C chuyn ha tip tc theo s :
C

OH HCN,
D
O H
2
2
E
0
2
,t O H
F
Hy cho bit cng thc cu to ca C, D, E, F v vit phng trnh phn ng cc chuyn
ha t toluen ti C v t C n F.
thi mn: Ha hu c II
S vht: 03
Cu 1
Cc phng php tng hp ancol.
Cu 2
Dng cc cng thc cu to ca cc hp cht hu c c tn hoc ng vi cc ch ci
trong s di y, vit y phng trnh chuyn ha:
1. Bezen
3 2 2
, ) ( AlCl O CO CH
A
CHl Hg Zn ,
B
3 2
. 2 , . 1 AlCl SOCl
C
2
HONH
D

4 2
SO H
(E, F).
Et3N
2. Benzandehit

0
3 2 3
, , ) .( 1 t COONa CH O CO CH
G

4
LiAlH
H
2009
37
Cu 3
Hp cht L c cng thc phn t C
10
H
10
O, khng to mu vi FeCl
3
nhng to sn phm
cng vi NaHSO
3
. Cho L tc dng vi I
2
/NaOH khng to ra kt ta, nhng axit ha hn
hp sau phn ng nhn c M (c cng thc C
10
H
10
O
2
) khng lm mt mu dd KmnO
4
.
Cho M tc dng vi lng d Br
2
trong s c mt ca lng d HgO trong dung mi
CCl
4
th thu c cht N l 1, 2, 3- tri- brom- 2- phenylpropan (hu nh khng c sn
phm hu c khc).
Mt khc, L tc dng vi NaBH
4
to ra X c cng thc C
10
H
12
O. un nng nh X vi H
2
SO
4
c Y c cng thc C
10
H
10
.
Xc nh cng thc cu to ca L, M, N, X v Y. Vit cc phng trnh phn ng.
Mn thi : Ha hu c II
S vht: 03
Cu 1
Aspirin l mt loi thuc cha nhiu bnh v dng ph bin. N c tn ha hc l axit
axetylsalisylic. Anh (ch) Hy vit cc phng trnh phn ng tng hp thuc ny t Etan ly
t kh ng hnh v cc ha cht cn thit khc ty chn.
Cu 2
Thc nghim cho thy pyrol tham gia phn ng th i in t mnh hn piriin nhiu. Anh
(ch) Hy gii thch iu v cho v d.
Cu 3 Hy so snh tnh axit ca cc hp cht sau:

K
SOCl2
2009
38
1. H
2
O 2. R
2
CHOH 3. RCH
2
OH 4. CH
3
COOH
5. H
2
CO
6
6. C
6
H
5
COOH 7. C
6
H
5
OH
Cu 4
Hon thnh s phn ng sau: CH
3
MgBr
C
2
H
5
OH A B C
Cu 5
Hon thnh cc phn ng sau:
1. RCHO + H
2
N NH Ar
2. RCH
2
OH + HCl/ZnCl
2
(kh)
3. RCH
2
CH(OH)CH
3
H
2
SO
4
,t
0
cao
4. RNH
2
+ R
1
Cl
5. ROH +
O
6. R
2
CO + R
1
MgX
7. ArNH
2
+ HNO
2
5
o
C
8. RCOR + NaHSO
3
9. ArCHR + KmnO
4
H
2
O
10. C
2
H
5
OH + RCOOH H
+
D E E
CH
3
CH
2
CH
2
OH
CH2O
2009
39
Mn thi : in ha hc
S vht: 02
Cu 1
1. Nguyn nhn sinh ra th in cc? Thit lp phng trnh Necx tnh gi tr th in
cc.
2. Thit lp quan h i, igh v A ; v th i- A v cho nhn xt.
Cu 2
2009
40
1.Dung dch cht in ly yu MA (nng 0,01m) c nhit ng c bng - 0,019
0
C.
Tnh in ly ; hng s K
l
v nng cc cht khi cn bng.
Bit rng hng s ng c K

ca nc bng K

(H20) = 1,86.
2. Phn ng tng cng xy ra trong mt pin in l:
H
2
+ Hg
2
Cl
2
2Hg + 2H
+
+ 2Cl
-
a) Thit lp pin in, vit cc phn ng in cc.
b) Lp phng trnh th hin sc in ng E ca pin in ph thuc vo (hot
trung bnh cht phn ng).
Mn thi : in ha hc
S vht: 02
Cu 1
1. dn in ring v dn in ng lng.
Cng thc tnh

m a , , i vi dung dch cht in ly
+
A M c nng m v hot
a. ngha ca h s hot .
2. in phn dung dch AgNO
3
vi cc in cc Ag.Lng AgNO
3
ti khu ant trc v
sau in phn tng ng bng 0,2470g v 0,3018g.
2009
41
Tnh s vn ti v t
Ag
+
;
3
NO
t bit rng kt thc in phn trn catt ng ca Culng k
ng c lng ng tng ln l 0,0191g.
Cu 2
1. Thit lp phng tnh tnh S ca pin nng khi khng tnh n s vn ti v tnh
n s vn ti, cho nhn xt.
2. Trong pin in xy ra phn ng:
Cd + Cu
2+
Cd
2+
+ Cu (1) 250
0
C
Thit lp pin in. Tnh hng s cn bng ca phn ng (1) v cho nhn xt; bit rng
0
/
2
Cd Cd
+
= -0,402V v
0
/
_ 2
Cu Cu
+
= +0,34V
thi mn: in ha hc
S vht: 02
Cu 1
1. Cho pin in Danien Jacobi. Thit lp phong trnh tnh S E ca pin vo nng
cht phn ng.
Tnh hng s cn bng ca phn ng xy ra trong pin cho bit:
0
/
2
Cu Cu
E
+
= 0,34V v
0
/
2
Zn Zn
E
+
= -0,76V 25
0
C
2. V ng phn cc dng i = f(E) v E lgi ca h : Cu
2+
+ 2e Cu ca in cc
ng Cu
2+
/Cu. Th no l trng thi cn bng?
2009
42
Cu 2
1. Nu cng thc tnh

m a , , i vi dung dch cht in ly
+
A M c nng m .
ngha ca h s hot .
2. nh ngha v cng thc tnh dn in ring, dn in ng lng.
Cu 3
Cho dung dch BaCl
2
0,003m. Da vo cng thc Debye-Huckel cho h s A= 0,509; Hy
tnh h s hot tng ion.
Tnh :

m a , ,
Mn thi : ng hc - xc tc
S vht: 02
Cu 1 (3 )
Cho 3 phn ng song song:
A B
k

1
A C
k

2
A D
k

3
1. Cho nng B, C, D t = 0 bng 0.
Dn biu thc tc tiu th A v biu thc m t din bin ca A theo thi gian.
2. Cho k
1
= 1s
-1
; k
2
= 10s
-1
; k
3
= 100s
-1
. Hy tnh
2 / 1
t ca A.
Cu 2 (3 )
2009
43
Cht tan nh hng ti vn tc phn ng thng qua nhng hiu ng no? (ch lit k tn
hiu ng).
Hy trnh by hiu ng mui s cp v ni r trng hp no nh hng m vtrng
hp no nh hng dng.
Cu 3 (2 )
Trong mt phn ng Ngi ta xc nh c nng N
2
O
5
trong Br
2
lng thay i theo thi
gian nh sau:
T, s 0 200 400 600 1000
[N2O5], mol.L
-1
0,110 0,073 0,048 0,032 0,014
Xc nh n v k.
Cu 4 (2 )
Cho phn ng phn hy CH
4
nh sau:

4
CH
.
3
.
H CH + ; k
1

3
.
4
CH CH +

.
6 2
H H C + ; k
2

.
4
H CH +

2 3
.
H CH + ; k
3

M H CH + +
.
3
.
M CH +
4
; k
4
p dng nguyn l nng n nh i vi H
.
v
.
CH
3
. Hy tm tc phn ng :
dt
H C d ] [
6 2
2009
44
S vht: 02
Cu 1 (2 )
Vn tc u ca phn ng ph thuc vo nng u ca cht phn ng J nh sau:
[J]
o
, x 103 mol.L
-1
5,0 8,2 17,0 30,0
W
o
, x 107 mol.L
-1 .
s
-1
3,6 9,6 41,0 130,0
Xc nh bc ca phn ng theo J
o
v tnh hng s tc .
Cu 2 (3 )
S khc bit gia n nhit v n dy chuyn l g?
C my loi gii hn n nhit. Hy chng minh.
2009
45
Cu 3 (2 )
(a)
2
Br
.
2Br ; w = k
a
[Br
2
]
(b)
2
.
H Br +
.
H HBr + ; w = k
b
[Br
.
][H
2
]
(b
)
2
.
Br H +
.
Br HBr + ; w = k
b
[H
.
][Br
2
]
(c) HBr H +
.
.
2
Br H + ; w = k
c
[H
.
][HBr]
(d) M Br Br + +
. .
M Br +
2
; w = k
d
[Br
.
]
2
1. p dng nguyn l nng n nh, Hy dn phng trnh tc ca phn ng.
2. Nu r loi ca tng phn ng trong phn ng dy chuyn.
3. Vi kt qu nhn c Hy tm iu kin phn ng c bc 3/2 theo Br
2
v chng
minh HBr l cht lm chm.
Cu 4 (2 )
Hy lit k (khng cn dn) nhng yu t nh hng ti vn tc phn ng v nhng
phng trnh (hoc l thuyt) chng minh iu (t nht 4 yu t).
S vht: 02
Cu 1 (4 )
1. Hy nu khi nim vn tc phn ng v hng s tc phn ng v bc phn ng.
2. So snh ( ngha, n v, cc yu t nh hng hc (vit cc phng trnh minh
ha yu t nh hng c th c khng dn phng trnh).
3. Nu nguyn l xc nh w, k t thc nghim (t ng cong ng hc cho).
Cu 2 (3 )
Cho phn ng phn hy NO
2
:
NO
2
= 2NO + O
2
2009
46
p sut thp v nhit cao y l phn ng mt chiu. Hy xc nh bc phn ng v
hng s tc da vo cc d kin thc nghim sau y:
t, s 0 20 26 40 60 80 100
[NO
2
].1011mol/L 17,8 10,6 9,0 7,1 5,4 4,6 4,0
Cu 3 (3 )
Cho c ch phn ng: H
2
+ Br
2
2HBr nh sau
(a)
2
Br
.
2Br ; w
a
= k
a
[Br
2
]
(b)
2
.
H Br +
.
H HBr + ; w
b
= k
b
[Br
.
][H
2
]
(b
)
2
.
Br H +
.
Br HBr + ; w
b
= k
b
[H
.
][Br
2
]
(c) HBr H +
.
.
2
Br H + ; w
c
= k
c
[H
.
][HBr]
(d) M Br Br + +
. .
M Br +
2
; w
d
= k
d
[Br
.
]
Hy dn biu thc vn tc phn ng, chng minh HBr l cht c ch (b qua yu t M)
Khi no th phn ng c bc 1/2 theo Brm?
S vht: 02
Cu 1 (2 )
Tc phn ng: 2A + B 2C + 3D bng 1,0 mol.L
-1
.s
-1
Hy xc nh tc chuyn ha hoc hnh thnh ca A, B, C v D.
Cu 2 (3 )
Cho phn ng: A + B = C vi nng u [A]
o
= [B]
o
= 1 mol/L sau 1 gi A phn ng ht
75%. Hi sau 2 gi A cn li bao nhiu nu phn ng trn l:
a) Bc 1 i vi A, bc 0 i vi B.
b) Bc 1 i vi A, bc 1 i vi B.
c) Bc 0 i vi A, bc 0 i vi B.
2009
47
Cu 3 (3 )
Cho phn ng phn hy N
2
O
5
nh sau:

5 2
O N
1
k
3 2
NO NO +
3 2
NO NO +
' 1
k
5 2
O N
3 2
NO NO +
2
k
2 2
O NO NO + +
5 2
O N NO+
3
k
2
3NO
p dng nguyn l nng n nh i vi NO
3
v NO Hy tm
dt
O N d ] [
5 2
v vn tc phn
ng.
Cu 4 (2 )
T phng trnh Michaelis - Menten Hy nu hai phng php xc nh K
S
(K
M
) v Wm .So
snh hai phng php.
Nu ngha hai i lng trn.
Nu u nhc im ca xc tc men, cch khc phc nhc im.
Mn thi : Cao phn t
S vht: 02
Cu 1
Gii phng trnh ng hc phn ng trng hp gc.
2009
48
Cu 2
Nu nh hng ca cu to monome n phn ng trng hp v ng trng hp.
Cu 3
Cho 2 monome:
C H
2
C CH CH
2
CH
3
C H
2
C H CH CH
2
Monome no trng hp theo c ch gc tt hn?
Mn thi : Cao phn t
S vht: 02
Cu 1
Hy chng minh phng trnh ng hc ca phn ng trng hp gc.
Cu 2
2009
49
Nu c ch v so snh 2 phng php trng hp huyn ph v trng hp nh tng. Ni
nhng u im ca 2 phng php ny.
Cu 3
Cho 2 monome:
C H
2
C CH CH
2
CH
3
C H
2
C H CH CH
2
Monome no trng hp theo c ch gc tt hn? Ti sao?
Mn thi : Cao phn t
S vht: 02
Cu 1
Hy chng minh phng trnh thnh phn vi phn ca phn ng ng trng hp gc.
Cu 2
2009
50
Nu nh hng ca cu to monome n phn ng trng hp v ng trng hp.
Cu 3
C 3 monome:
PVC (polyvinylclorua)
PS (polystiren)
PE (polyetilen)
Khng bng phng php ha hc lm th no xc nh c?
Mn thi : Ha keo
S vht: 02
i tng d thi: K45A,S ngnh Ha
Cu 1
Trnh by m hnh Gouy - Chapman v lp in kp. T a ra nh ngha th . Th
ph thuc vo nhng yu t no?
2009
51
Cu 2
Gc tip xc l g? Hy chng minh gc tip xc l mt hng s vt l.
Cu 3
Hy a ra mt s l thuyt v s keo t bng cht in ly.
Cu 4
Tnh cao cho nng cc ht keo vng c ng knh 9.10
-7
cm trong dung dch
gim i 3 ln.
Cho bit: vng c khi lng ring l 19,3 g/cm
3
; k = 1,38.10
-16
ec.K
-1
; g = 980 cm.s
-2
;
t
o
dd keo
= 250
0
C.
Mn thi : Ha keo
S vht: 02
Cu 1
Thit lp phng trnh Gibbs m t s hp ph trn b mt dung dch kh. T , phn
bit cht hot ng b mt v khng hot ng b mt.
2009
52
Cu 2
Trnh by m hnh Gouy - Chapman v lp in kp v nu cc yu t nh hng n th
in ng hc (th).
Cu 3
Gii thch vai tr ca cht in ly i vi s keo t.
Cu 4
Tnh h s khuch tn ca cc ht keo c ng knh 10
-5
cm trong mi trng nc
nhit 270
0
C.
Cho bit:
O H
2
q = 10
-2
P ; k = 1,38.10
-16
ec.K
-1
Mn thi : Ha keo
S vht: 02
i tng d thi: K46S ngnh Ha
Cu 1
Thit lp phng trnh Langmuir biu din s hp ph mt lp n phn t.
Cu 2
2009
53
Hy trnh by l thuyt v s keo t bng cht in ly.
Cu 3
Gii thch vai tr ca cht nh ha, th no l mt cht nh ha tt.
Cu4
-7
cm trong dung dch
gim i 3 ln.
3
; k = 1,38.10
-16
ec.K
--1
;
g = 980 cm.s
-2
; t
0
dd keo
= 250
0
C.
Mn thi : Ha keo
S vht: 02
i tng d thi: K4CNTN ngnh Ha
Cu 1
Thit lp phng trnh Laplace v gii thch hin tng mao dn.
Cu 2
Trnh by m hnh Gouy Chapman v lp in kp. Th ph thucvo nhng yu t no?
Gii thch?
2009
54
Cu 3
Th no l s o pha ca nh tng? Cho v d.
Cu 4
-7
cm trong dung dch
gim i 3 ln.
3
; k = 1,38.10
-16
ec.K
-1
;
g = 980 cm.s
-2
; t
0
dd keo
= 250
0
C.
Mn thi : Ha keo
S vht: 02
i tng d thi: K47A,S ngnh Ha
Cu 1
Thit lp phng trnh Laplace v gii thch hin tng mao dn.
Cu 2
2009
55
Gc tip xc l g? Hy chng minh gc tip xc l mt hng s vt l. Nu nh ngha v
gii thch tc dng ca cht thm t.
Cu 3
Gii thch hin tng phn tn v hp th nh sng ca h keo. Hin tng in di l g?
Gii thch.
Cu 4
-7
cm trong dung dch
gim i 3 ln.
Cho bit: vng c khilngring l 19,3 g/cm
3
; k = 1,38.10
-16
ec.K
-1
;
g = 980 cm.s
-2
; t
0
dd keo
= 250
0
C.
Mn thi : Ha keo v cao phn t
S vht: 03
Cu 1
Hy chng minh phng trnh thnh phn vi phn ca phn ng ng trng hp gc.
2009
56
Cu 2
Nu nh hng cu to monome n phn ng trng hp.
Cu 3
Xc nh b mt ring, b mt tng ca ht keo v phn tn ca h khi nghin 1 gam lu
hunh thnh ht c dng hnh lp phng vi di cnh bng 10
-3
cm. Cho bit khi
lng ring ca lu hunh l 2,07.10
3
kg.m
-3
.
Cu 4
Vit cng thc v s cu to ca mixen keo c to thnh theo 3 cch khc nhau khi
cho Na
2
SO
4
tc dng vi BaCl
2
vi gi thit mt lng d BaCl
2
.
Mn thi : Ch ngha x hi khoa hc
S vht: 04
Cu 1 (5 )
Anh (ch) trnh by quan im ca ch ngha Mac - Lnin trong vic gii quyt vn tn
gio di ch ngha x hi? ng cng sn Vit Nam vn dng quan im ny gii
quyt vn tn gio Vit Nam nh th no?
Cu 2 (5 )
2009
57
Anh (ch) Hy trnh by c s l lun v thc tin Lnin a ra cng lnh dn tc? Ni
dung ca cng lnh dn tc do Lnin a ra c ngha l lun v thc tin g i vi thi
i hin nay?
S vht: 04
Cu 1 (6 )
Ti sao ni ng cng sn l nhn t quyt nh thc hin thnh cng s mnh lch s ca
giai cp cng nhn?
Lin h vai tr ca ng cng sn Vit Nam i vi vic thc hin s mnh lch s ca giai
cp cng nhn nc ta hin nay?
Cu 2 (4 )
Hy nu khi nim v bn cht ca dn ch x hi ch ngha? Theo anh (ch) lm th no
pht huy dn ch nc ta hin nay.
S vht: 04
Cu 1 (6 )
Trnh by quan im ca ch ngha Mac - Lnin trong vic gii quyt vn tn gio di
ch ngha x hi? ng cng sn Vit Nam vn dng quan im ny gii quyt vn
tn gio Vit Nam nh th no?
Cu 2 (4 )
2009
58
Ch ngha x hi khng tng l g? Anh (ch) Hy nu nhng gi tr tch cc v nhng hn
ch, nguyn nhn ca nhng hn ch ca ch ngha x hi khng tng? Ti sao chng ta
phi nghin cu ch ngha x hi khng tng?
S vht: 04
Cu 1
Khi nim giai cp cng nhn? Nhng iu kin khch quan quy nh s mnh lch s ca
giai cp cng nhn? Lin h vi giai cp cng nhn Vit Nam?
Cu 2
Phn tch nhng mu thun c bn ca thi i ngy nay?
Mn thi : Phn tch cng c
S vht: 04
Cu 1
1. V s ca thit b cc ph c in. V sng cc ph khuch tn v nu 2 tnh cht
c bn ca sng cc ph .
2. Phng trnh dng gii hn khuch tn ti in cc git thy ngn: phng trnh
Ilkovic. Nu cc iu kin cn thc hin p dng phng trnh vo ph-ng php cc
ph nh lng.
Cu 2
2009
59
1. Phng trnh ca nh lut c bn v s hp th nh sng: nh lut Bugher - Lambert
- Beer. Vit phng trnh . Nu ngha cc i lng trong phng trnh.
2. Mt cht ch th pH l n axit yu, vit tt l HInd. Dng axit (HInd) v dng baz (Ind
-
)
u c mu. Di y l h s hp th mol ca cc dng hai bc sng 430nm v
570nm:
Dng ca ch th
HInd 6,3.102 7,12.103
Ind
-
2,06.104 9,61.102
Chun b mt dung dch nc ca cht ch th v o hp th nh sng ca n hai bc
sng trn, dung cuvet c b dy 1 cm, thu c cc kt qu sau:
A
430
= 0,236 ; A
570
= 0,073
Hy tnh:
a) Nng dung dch cht ch th
b) pH ca dung dch cht ch th
c) Hng s axit Ka ca cht ch th.
Cu 3
1. Nu nguyn tc chung ca phng php phn tch sc k.
2. Nu nguyn tc ca sc k trao i ion. Cho v d minh ha.
Mn thi : Ha lng t
S vht: 03
Cu 1
Kt qu kho st phn t BeH
2
bng phng php MO cho 2 MO to lin kt:
) (
S
o = c
1
2s + c2(1s
a
+ 1s
b
)
) (
Z
o = c
3
2p
z
+ c4(1s
a
1s
b
)
Gi thit rng mt in tch ca m my electron c phn b trn cc MO nh
sau:
S
o : Be = 30% ; 2H = 70%
2009
60
Z
o : Be = 20% ; 2H = 80%
Hy xc nh cc MO -
S
o ; MO -
Z
o v s phn b in tch trong BeH
2
.
Cu 2
Cho hm R(r) ca obitan 2s l :
0
2 /
0
2 / 3
0
2
1
2
1
a r
e
a
r
a

|
|
.
|
\
|
1. Hy tnh mt xc sut theo r.

2. Biu din kt qu thu c trn th.
Cu 3
Da vo l thuyt HMO:
1. Vit nh thc th k cho phn t benzen. Sau khi m nh thc ta thu c phng
trnh: x
6
- 6x
4
+ 9x
2
- 4 = 0. T phng trnh ny Hy xc nh cc mc nng lng electron
t tng ng v biu din cc gi tr thu c trn gin nng lng, bit
|
o E
x

= ;
0 , < | o ; | o > .
2. Tnh nng lng tng cng electron t cho phn t benzen, cation v anion benzen.
Cho bit 3 hp cht ni trn th hp cht no bn vng nht?
Mn thi : Ha lng t
S vht: 03
Cu 1
Bit f(x) = l hm ring ca ton t =
(
.
2
2 2
dx
d
X
Hy xc nh tr ring ca khi thc hin php f(x).
2009
61
Cu 2
Phng trnh Strding p dng cho h vo mt trng th khng ph thuc vo thi
gian U = U(x) c dng:
t
t x
i
c
c ) , (
= ) , ( ) ( t x x H
.
(1)
Nghim tng qut ca phng trnh (1):

/
). ( ) , (
iEt
e x t x

= (2)
1. Cho bit trng thi no l trng thi dng v Hy vit phng trnh Strding cho
trng thi dng.
2. Chng minh rng nhng trng thi dng, mt xc sut khng ph thuc vo
thi gian.
Cu 3
Trn c s phng php MO - Hukel Hy xc nh gi tr nng lng electron t ) (
t
E v
hm sng tng ng i vi phn t fomanehit bit rng phn t ny c 2 electron t
trng thi c bn.
Cho : | o o 2 , 0 + =
C
; | o o 7 , 0 + =
O
; | | 1 , 1 =
CO
Mn thi : Cc phng php ph
S vht: 04
Cu 1
2009
62
Xt ph quay tn x Raman ca phn t hai nguyn t trn c s ca m hnh quay t
cng (r = const).
a) Hy vit biu thc tnh nng lng quay (gii thch cc k t trong biu thc) v Hy
v gin nng lng cc mc quay.
b) Hy cho bit quy tc la chn i vi ph quay Raman v s dng cc mi tn biu
din cc bc chuyn di c php ng vi cc vch Stokes v phn Stokes.
c) Vit biu thc tnh s sng u ca cc vch Stockes.
d) Khi s dng bc x kch thch
0
u = 29697,2 cm
-1
th trn ph ca HCl vch Stokes
u tin (gn vch
0
u nht) c s sng
1
u =29637,2 cm
-1
. Hy tnh momen qun tnh I ca
phn t v khong cch r gia hai ht nhn.
(h = 6,625.10
-34
J.s ; c = 3.10
-8
m/s ; N
A
= 6,022.10
23
; H = 1 ; Cl =35)
Cu 2
Hy v s ph cng hng t proton ca phn t CH
3
CH
2
Cl , trong c ch
n v tr tng i ca cc tn hiu, s v cng tng i ca cc vch trong mi tn
hiu.
Cu 3
Clo c 2 ng v: ) 324 , 0 ( ), 1 (
37 35
Cl Cl ; Brom c 2 ng v : ) 981 , 0 ( ), 1 (
81 79
Br Br ; hm lng
ghi trong ngoc.
Hy tnh t s cng tng i ca cc pic ng v trn ph khi lng trong cc trng
hp sau:
a) Phn t c 1 nguyn t Br.
b) Phn t c 2 nguyn t Br.
c) Phn t c 1 nguyn t Cl v 2 nguyn t Br.
(Biu din cng cc pic bng cc vch c chiu cao tng ng).
Cu 4
Trong phng php tinh th quay Ngi ta s dng ng phim bn knh R = 28,7 mm v tia
X n sc = 1,537 A
0
.
2009
63
Mt tinh th kt tinh dng lp phng. Khi cho tinh th quay chung quanh mt trc song
song vi cnh ca t bo s ng th trn ph nhiu x, ng lp th nht (n = 1) cch
ng xch o mt on e
1
= 16,57 mm.
Hy tnh cnh a ca t bo s ng.
Mn thi : Cc phng php ph
S vht: 04
Cu 1
2009
64
Xt ph hp th quay thun ty ca phn t hai nguyn t trn c s ca m hnh quay t
cng.
a) Hy vit biu thc tnh nng lng quay v biu thc tnh s sng u ca cc vch
ph hp th.
b) Trn ph ca HCl, hai vch ph ng cnh nhau c hiu s sng u A = 20,60 cm
-1
.
Hy tnh hng s quay B, momen qun tnh I ca phn t v khong cch r gia cc ht
nhn.
(h = 6,625.10
-34
J.s ; c = 3.10
8
m/s ; N
A
= 6,022.10
23
; H = 1 ; Cl =35)
Cu 2
1. Hnh 1 l ph cng hng t proton ca mt trong s cc ng phn ca
imetylpiriin:

N N
N
CH
3
CH
3
CH
3
CH
3 C H
3
CH
3
a b c

Hy cho bit l ph ca ng phn no? Ti sao?
2. Hnh 2 l ph cng hng t proton ca hp cht c cng thc nguyn l C9H12.
Hy xc nh cng thc cu trc ca hp cht .
2009
65
Cu 3
Clo c 2 ng v: ) 324 , 0 ( ), 1 (
37 35
Cl Cl ; Brom c 2 ng v : ) 981 , 0 ( ), 1 (
81 79
Br Br ; hm lng
tng i ghi trong ngoc.
Hy tnh t s cng tng i ca cc pic ng v trn ph khi lng trong cc trng
hp sau:
a) Phn t c 2 nguyn t Cl.
b) Phn t c 1 nguyn t Cl.
c) Phn t c 1 nguyn t Cl v 2 nguyn t Br.
(Biu din cng tng i ca cc pic bng cc vch c chiu cao tng ng).
Cu 4
Trong phng php tinh th quay Ngi ta s dng ng phim bn knh R = 28,7 mm v tia
X n sc = 1,537 A
0
.
Mt tinh th kt tinh dng lp phng. Khi cho tinh th quay chung quanh mt trc song
song vi cnh ca t bo s ng th trn ph nhiu x, ng lp th nht (n = 1) cch
ng xch o mt on e
1
= 16,57 mm.
Hy tnh cnh a
0
ca t bo s ng.
Mn thi : Ha vt liu
2
1
8 7 6 5 4 3 2 1 0
Hnh 1
8 7 6 5 4 3 2 1
1
3
Hnh 2
2009
66
S vht: 02
Cu 1
St kim loi di 768
0
C c mng li lp phng tm khi v hng s mng a = 2,9 , trn
910
0
C c mng li lp phng tm mt vi hng s mng a = 3,6 A
0
.
Hy m t t bo mng li ca hai dng th hnh ca st v tnh t trng theo l thuyt
(g/cm
3
) ca chng.
Xc nh s phi tr, chc c, s hc trng t din, bt din ca tng loi. Cho bit
nguyn t lng ca Fe bng 55,85.
Cu 2
Trnh by nhng tng tc gia FeO v Al
2
O
3
da vo gin sau y. Xt qu trnh xy
ra khi lm ngui lnh khi nng chy c thnh phn 20% khi lngAl
2
O
3
. Xc nh nh
tnh v nh lng thnh phn pha ca gm thu c khi lm lnh n nhit phng.
Cu 3
Trnh by phng php tng hp gm theo k thut ng kt ta. Ly v d tng hp gm
ferit km ZnFe
2
O
4
.
Nhng iu cn lu khi thc hin k thut ny.
H
E
1
K
M
E
2
N
0
C
2100
1900
FeO Al
2
O
3
% khi lng
20 40 60 80
(FeAl
2
O
4
)
2009
67
Mn thi : Ha vt liu
S vht: 03
Cu 1
CeO
2
c cu trc tinh th kiu florite. M t t bo mng li tinh th ca n. Tnh khi
lng ring (g/cm
3
); tnh di lin kt Ce O; khong cch Ce Ce; khong cch O O;
trong t bo mng. Cho bit hng s mng ca CeO
2
l a= 5,411 A
0
; nguyn t lng ca
Ce bng 140,13 ; ca O bng 16.
Cng cu hi tnh ton vi t bo mng ca antiflorite Na
2
O; cho bit hng s t bo
mng ca Na
2
O l a = 5,55 A
0
; nguyn t lng ca Na l 22,991.
Cu 2
Trnh by cc c ch c th xy ra khi thay th cation c in tch ln vo v tr ca cation
c in tch b (ly v d thay th Y
3+
vo v tr ca Ca
2+
trong tinh th CaF
2-
).
Khi thay th 3% v tr nt mng ca Ca
2+
bng Y
3+
thu c dung dch rn c d = 3,2634
g/cm
3
. Gii thch c ch ca s hnh thnh dung dch rn .
Cho bit hng s mng ca CaF
2-
l a = 5,462 A
0
; nguyn t lng ca Ca bng 40; ca Y
bng 88,9 v ca F bng 19.
Cu 3
Nghin trn tht k 0,4 mol ZrO
2
v 0,6 mol CaO; un nng chy ( nhit no) ri lm
ngui lnh n nhit phng.
Xc nh thnh phn pha nh tnh v nh lng ca gm thu c, m t cu to b mt
ca gm :
2009
68
Cu 4
Bin php lm tng tc phn ng gia cc pha rn.
CaZrO
3
CaO
ZrO
2
20 60
% mol

2600
2400
2009
69
Mn thi : Ha k thut
S vht: 06
Cu 1
Hnh v di y l ng cn bng lng hi ca h CS
2
CCl
4
.
a) Hi khi chng ct vi t s hi lu u = 5 t c sn phm u ct (phn ct)
c phn s mol ca cu t nh (CS
2
) l 0,90 v cui ct c phn s mol 0,23 ngi ta cn
s a l thuyt (LT) ca ct ct l bao nhiu?
b) Nu chng ct t hn hp c phn s mol ca cu t nh trong pha lng l 0,30
cho n khi t c sn phm ct ra c phn s mol ca cu t nh l 0,95 th gi tr t s
hi lu phi l bao nhiu?
Cu 2
0 0,1 0,2 0,3 0,4 0,5 0,6 0,7 0,8 0,9 1,0 x
y
1,0
0.9
0.8
2009
70
Phn ng c bn, ng th pha kh: A 2R + S xy ra iu kin ng nhit, ng p,
trong thit b khuy l tng gin on. Hn hp phn ng ban u cha 50% cht A v
50% cht tr I. Th tch ca khi phn ng tng ln gp ri sau 30 pht tin hnh phn
ng.
Hy xc nh:
a) chuyn ha ng vi thi im nu trn
b) Th tch thit b ng dng PFR v khuy l tng lin tc IMR cn thit t c
chuyn ha trn, trong iu kin tc dng th tch nguyn liu l 120 lt/gi.
Cu3
V s khi, trnh by s lc cc cng on trong sn xut axit sunphuric bng phng
php tip xc; vit cc phng trnh phn ng minh ha.
Cu 4
Phng php sn xut metanol cng nghip v cc sn phm t metanol.
2009
71
thi mn: Ha k thut
S vht: 06
Cu 1
T mt hn hp cha 50% khi lng axeton trong nc cn phi chit axeton trong dng
ngc chiu bng clobenzen nguyn cht. Dch b cho php cn cha ti a 2% khi
lng axeton. Lu lng cc dng vo ca nguyn liu v dung mi l bng nhau. Lu
lng dng vo ca nguyn liu l 1000 kg/gi.
Hy xc nh s bc tch l thuyt v lu lng dng ra ca dch chit.
S liu cn bng pha tnh theo nng % khi lng cho bng sau:
Pha nc (dch b) Pha hu c (dch chit)
Nc Axeton Nc Axeton
99,89 0,00 0,18 0,00
89,79 10,00 0,49 10,79
49,69 20,00 0,79 22,23
69,42 30,00 1,72 37,48
58,64 40,00 3,05 49,44
46,28 50,00 7,24 59,19
27,41 60,00 22,85 61,07
Cu 2
Phn ng pha ng th: A + B 2R c tin hnh iu kin ng nhit trong thit b
gm hai bnh khuy l tng mc ni tip. Th tch cc bnh V
1
= 0,3 m
3
; V
2
= 0,6 m
3
. Cht
A vi nng ban u C
AO
= 0,18 mol/l c a vo vi tc
.
A
V = 3600 l/h. Cht B vi
2009
72
nng ban u C
BO
= 0,3 mol/l c a vo vi tc
.
B
V = 1800 l/h. Hng s tc
phn ng k = 5.10
-2
.s
-1
.mol
-1
l.
a) Hy xc nh tc thu sn phm F
R
=
.
V C
R2
b) Trong trng hp h thng phn ng ni trn c thay th bng mt thit b ng
dng c th tch V = V
1
+V
2
th tc thu sn phm trong trng hp ny F
R
s bng bao
nhiu? So snh F
R
v F
R
v rt ra nhn xt. Cho bit cc iu kin phn ng khc vn
c gi nguyn.
Cu 3
a) V s khi cng ngh sn xut axit sunphuric theo phng php tip xc. Trnh
by tm tt nhng cng on chnh v minh ha bng cc phng trnh phn ng.
b) Trnh by cc phng php sn xut vinylclorua t etylen v ng dng ca PVC.
2009
73
thi mn: Ha k thut
S vht: 06
Cu 1
Phn ng pha lng ng th: A + B 2R c tin hnh iu kin ng nhit trong
thit b gm hai bnh khuy l tng mc ni tip. Th tch cc bnh V
1
= 0,24 m
3
; V
2
= 0,48
m
3
. Cht A vi nng ban u C
AO
= 0,24 kmol/m
3
c a vo vi tc
.
A
V =48
l/pht. Cht B vi nng ban u C
BO
= 0,36 kmol/m
3
c a vo vi tc
.
B
V = 24
l/pht. Hng s tc phn ng k = 5.10
-2
s
-1
mol
-1
l.
a) Hy xc nh tc thu sn phm F
R
=
.
V C
R2
b) Trong trng hp h thng phn ng ni trn c thay th bng mt thit b ng
dng c th tch V = V
1
+V
2
th tc thu sn phm trong trng hp ny F
R
s bng bao
nhiu? So snh F
R
v F
R
v rt ra nhn xt. Cho bit cc iu kin phn ng khc vn
c gi nguyn.
Cu 2
Tch cht k thut
a) Trong mt th nghim c in tch mng lc l 0,4
m2
, p sut lc l 50000 N/
m2
,
nhng khong thi gian khc nhau Ngi ta o c nhng th tch sau y ca dch lc:
t[s] 96,5 258,0 484,5 776,0
V[m
3
] 5.10-3 10.10-3 15.10-3 20.10-3
Lng cht rn ca huyn ph l 50 kg/m3 ; nht ca cht lng nguyn cht l 1,14.10
-3
Pa.s
Hy tnh:
- Thng s o v | ca phng trnh lc.
- in tch mng lc cn thit lc 20 m
3
huyn ph trong 1 gi.
2009
74
b) Cn bng lng - hi ca h bc 2 no c biu din bi gin y/x nh hnh v.
Theo anh (ch) c th tch hon ton cc cu t nhau trong h ra khi nhau bng cc
phng php no trong cc phng php di y:
- Chng ct p sut thng y
- Tng s a l thuyt ca ct
- Chng ct vi s thay i p sut
- Tng ng knh ca ct
- Tng nhit ca ngun nng O
- Chng ct c thm cu t th 3 chn lc x
Hy gii thch cho s la chn .
Cu 3
Nu v phn tch qu trnh cng ngh sn xut kaliclorua t qung sylvinite. V s khi
minh ha qu trnh.
Cu 4
Trnh by phng php cng ngh sn xut Vinylacetat.
2009
75
Mn thi : Ha k thut I
S vht: 02
Thi gian lm bi: 60pht.
Cu 1
Trnh by c s l thuyt ca qu trnh chng ct, phng php xc nh chiu cao v
ng knh ct chng ct cho mt nhim v tch cht.
Cu 2
Phn ng c bn, ng th pha kh: A 2R + S xy ra iu kin ng nhit, ng p,
trong thit b khuy l tng gin on BR. Hn hp phn ng ban u cha 90% cht A v
10% cht tr I (tnh theo th tch). Th tch ca khi phn ng tng ln gp 2 ln sau 30
pht tin hnh phn ng.
Hy xc nh:
a) chuyn ha ng vi thi im nu trn
b) Th tch thit b ng dng PFR v khuy l tng lin tc IMR cn thit t c
chuyn ha trn, trong iu kin tc dng th tch nguyn liu l 150 lt/gi.
c) Nng ban u ca cht phn ng C
AO
c nh hng nh th no n
chuyn ha thu c trong cc trng hp nu trn.
2009
76
Mn thi : Ha k thut II
S vht: 02
Thi gian lm bi: 60pht.
Cu 1 (5 )
Anh (ch) hy trnh by cng ngh sn xut metanol v cc ng dng ca chng.
Cu 2 (5 )
nh ngha v phn loi nguyn liu cho cng nghip ha cht. M t tm tt cc phng
php lm giu c hc thng c s dng i vi nhin liu qung t nhin.
2009
77
Mn thi : T tng H Ch Minh
S vht: 03
thi
Anh (ch) hy trnh by:
Nhng quan im c bn ca H Ch Minh v i on kt dn tc.
Mn thi: T tng H Ch Minh
S vht: 03
thi
Anh (ch) hy trnh by:
Quan nim ca H Ch Minh v c trng bn cht v mc tiu, ng lc ca ch ngha x
hi.
2009
78
Mn thi : Ha hc du m
S vht: 03
Cu 1
a) Th no l bitum? Thnh phn ca bitum.
b) Cho bit mt s tnh cht ha hc ca bitum v ng dng va bitum.
Cu 2
a) Hy cho bit cc c trng ca cc hp phn chnh ca xc tc crackinh hin i?
b) Nu cc nguyn tc lm th no thu c xc tc crackinh nh hng to xng
c ch s octan cao (FCC - Octan).
Cu 3
a) Mc ch v ngha ca qu trnh thm ha LPG (kh ha lng).
b) Hy phn tch cc phn ng c th din ra khi chuyn ha ring bit v hn hp
propan v n butan trn xc tc lng chc nng (v d Pt/ HZSM - 5). T cho thy
y l mt trong nhng qu trnh cung cp nhin liu cho cng ngh tng hp hu c.
Cu 4
a) M bi trn l g?
b) Cc giai on iu ch m bi trn. ngha ha hc ca cc giai on .
c) ng dng ca m bi trn.
2009
79
Mn thi : Ha hc du m
S vht: 03
i tng d thi: K47A + CNTN K6
Cu 1
a) Xng b gm ha l nh th no? Cch hn ch hin tng gm ha xng.
b) Cc phng php lm tng ch s octan ca phn on xng.
Cu 2
a) Th no l crackinh vi hi nc v cng crackinh KSF?
b) Crackinh n - octan trn nhm silicat c lc axit Bronsted rt mnh, ngi ta thu c
cc sn phm kh ch yu l (CH
3
)
3
CH, (CH
3
)
2
C=CH
2
. Hy vit c ch phn ng trn.
Cu 3
a) M bi trn l g?
b) ng dng ca m bi trn.
c) Trnh by bn cht ha hc ca cc giai on iu ch m bi trn.
Cu 4
Hy phn tch hai qu trnh cng ngh c kh nng sinh ra BTX (Benzen, Toluen, Xilen).
- Phn tch cc phn ng c bn v s c ch.
- H xc tc s dng.
- Phn tch mt s iu kin cng ngh cn thit.
- Nu mt s ng dng ca benzen trong cng nghip tng hp hu c.
2009
80
Mn thi : Ha hc mi trng
S vht: 03
Cu 1
S nhim kh quyn bi kh CO:
- S hnh thnh kh CO.
- Ngun thi kh CO vo kh quyn.
- C ch gy c hi ca kh CO. Cch cp cu khi b nhim c CO.
- Cch hn ch lng CO thi vo kh quyn.
Cu 2
Trnh by c ch gy c hi ca thy ngn:
- Ngun thi thy ngn vo mitrng.
- Thy ngn kim loi v cc dng thy ngn c tc dng gy c.
- C ch gy c hi ca thy ngn.
- S lan truyn thy ngn trong dy chuyn thc phm.
Cu 3
Tng zn. Vai tr ca tng zn i vi s sng trn tri t. S hnh thnh v s ph hy
tng zn. Trnh by cc tc nhn v c ch ph hy tng zn, vit cc phng trnh phn
ng.
Cu 4
Trnh by nguyn tc v vit cc phng trnh phn ng khi dng phng php Winkler
xc nh lng oxi ha tan trong nc(DO).
Ly 50ml nc phn tch theo quy trnh phn tch ca Winkler, dng ht 18 ml dung dch
Na
2
S
2
O
3
5.10
-3
mol/l.
Tnh s miligam oxi ha tan trong 1 lt nc.
2009
81
S vht: 03
Cu 1
Trnh by s nhim c thy ngn:
- Ngun thi thy ngn vo mi trng.
- Chu trnh chuyn ha thy ngn t mi trng vo c th.
- C ch gy c ca cc dng thy ngn.
Cu 2
Trong nc bin c i lng pE c tnh n nh ton cu. Hy gii thch v chng minh
iu ny.
Cu 3
Hiu ng nh knh:
- Hiu ng nh knh l g?
- Cc kh nh knh.
- Trnh by mt li v mt hi ca hiu ng nh knh.
Cu 4
Trnh by nguyn tc v vit cc phng trnh phn ng khi dng phng php Winkler
xc nh lng oxi ha tan trong nc(DO).
Ly 100ml nc em xc nh lng DO bng phng php Winkler, Ngi ta dng ht 28
ml dung dch Na
2
S
2
O
3
3.10
-3
mol/l. Tnh s miligam oxi ha tan trong 1 lit nc.
2009
82
Mn thi: Ha hc mi trng
S vht: 02
Cu 1
Tc dng c hi ca xianua:
- Cc ngun pht thi xianua gy nhim mitrng.
- Xianua c trong mt s thc vt no, chng tn ti dng no? V chuyn ha
xianua ra sao?
- C ch x l khi b nhim c bi xianua.
Cu 2
Hiu ng nh knh tc ng n mi trng:
- Hiu ng nh knh?
- Hiu ng kh nh knh? Cc kh nh knh v vai tr ca kh nh knh i vi kh hu
tri t.
- S gia tng kh CO
2
trong kh quyn
- Hu qu ca s gia tng kh nh knh n kh hu ton cu. Tc hi.
- Lm th no m bo lng kh nh knh trong kh quyn nm trong gii hn c
li cho kh hu trn tri t.
Cu 3
Trong nc bin c hai i lng pH v pE l gn nh khng i v n nh trn ton cu.
Hy gii thch v chng minh iu .
2009
83
S vht: 03
Cu 1
Cc cht gy nhim mi trng thm nhp vo c th con ngi bng nhng cch no?
Trnh by c ch gy c hi ca cc loi thuc bo v thc vt khi n thm nhp vo c
th con ngi.
Cu 2
Hiu ng nh knh:
- Hin tng hiu ng nh knh.
- Cc kh gy hiu ng nh knh.
- Nhng im c li v c hi ca kh nh knh.
- Bin php gim thiu a hiu ng nh knh vo kh quyn.
Cu 3
Oxi ha tan trong nc(DO), nhu cu oxi sinh hc(BOD), nhu cu oxi ha hc(COD).
1. Trinh by nh ngha, nguyn tc, quy trnh th nghim, vit cc phng trnh phn
ng, lp cng thc tnh cc ch tiu trn.
2. Ly 50 ml nc thi, xc nh DO theo phng php Winkler, chun ht 18,75 ml
dung dch Na
2
S
2
O
3
3.10
-3
M. Tnh gi tr DO.
3. Tnh gi tr COD ca mu nc thi , bit rng ly 20 ml nc thi em th nghim
dng cht oxi ha l K
2
Cr
2
O
7
, sau th nghim chun lng K
2
Cr
2
O
7
d ht 9,55 ml dung
dch Fe
2+
0,1M. Lm th nghim vi mu trng th chun ht 14,30 ml dung dch Fe
2+
0,1M.
4. Tnh gi tr BOD
5
ca mu nc thi trn bit rng gi tr DO ca mu nc thi xc
nh c (2), cn gi tr DO xc nh sau 5 ngy 20
0
C l 4 mg/l.
So snh 2 gi tr COD v BOD
5
ca mu nc thi. Cho nhn xt v gii thch v sao chng
khc nhau? (Cho O = 16)
(Cn na)

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1. Hy tnh mt xc sut theo r.

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