K hoch hc Hysys

3.1. Bt u vi Hysys 3.1.1. Simulation Basis Manager La chn cu t Chn gi cht lu Thit lp cu t gi Thit lp phn ng 3.1.2. Simulation Enviroment: Thit lp dng vt cht 3.2. S dng cc tin ch trong Hysys 3.2.1. Tnh ton Flash 3.2.2. Envelope 3.2.3. Property Table 3.3. Unit Operation 3.3.1. Bm 3.3.2. Compressor/Expander 3.3.3. Heater and Cooler 3.3.4. Shortcut Distillation 3.3. Hng dn thc hnh 3.3.1. Chu trnh lm lnh bng Propan 3.3.2. Phn xng lm lnh kh 3.3.3. Lm ngt kh chua bng DEA 3.3.4. S c trng du m
We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Session 3.1.

Bt u vi Aspen Hysys

Revise
(Yu cu xem li Session 1 hiu cc bc tin hnh qu trnh m phng) xy dng mt m hnh m phng hiu qu, chng ta phi xc nh ng mc tiu. Bc u tin trong bt c mt qu trnh m phng no cng l lng ha cc mc tiu cng nhiu cng tt. Cc kt qu t c thng ph thuc vo cc yu cu t ra. Nh vy, trc khi m phng nn t ra cc cu hi sau: Mc ch s dng cng c m phng trong trng hp ny lm g? Qu trnh m phng s thc hin nhng vic g? S phc tp c cn thit khng? Cn thit phi tm ra cc kt qu no t qu trnh m phng?

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Bt u vi Hysys
Simulation Basis Manager (thit lp ban u cho qu trnh m phng)

La chn cu t Chn gi cht lu Thit lp cu t gi Thit lp phn ng c trng du m

Simulation Enviroment (vo mi trng m phng)

t cc dng: thnh phn, lu lng, t, P. Tnh ton cc tnh cht ca dng t cc thit b Chy v in kt qu

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Simulation Basis Manager

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

La chn cu t
Nt View Miu t Cho php chng ta xem hoc sa i thng tin trong ca s hin th tnh cht ca danh sch hp phn c la chn. Cho php chng ta to mt danh sch hp phn. Ch : Cc danh sch hp phn c th c tao thm thng qua ca s hin th tnh cht ca gi cht lu Loi b danh sch hp phn c la chn khi m phng To mt bn sao ca danh sch hp phn c la chn. Cho php chng ta nhp mt mt danh sch hp phn c nh ngha trc t a. Cc cc danh sch hp phn l cc file c phn m rng l .cml. Cho php chng ta xut danh sch hp phn c la chn ra mt a. Cc danh sch hp phn c th c ly li vo cc m phng khc bng vic s dng chc nng Import.
We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Add

Delete Copy Import

Export

H nhit ng

Thit lp h nhit ng

Xut nhp file lu h nhit ng

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

H nhit ng

La chn m hnh nhit ng ph hp ng vai tr quan trng ti chnh xc kt qu m phng Cc thng s xc nh t h nhit ng

Hng s cn bng pha K Enthanpie ca pha lng v pha hi Entropy ca pha lng v pha hi T trng ca pha lng v pha hi

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

La chn phng php nhit ng hc

Cc m hnh nhit ng Dng theo phng php hiu chnh ( Generalized Correlation Methods): GS, CS,IGS, Dng phng trnh trng thi (Equation of State Methods): SRK, PR, SRKS, BWRS,... Dng theo hot (Liquid Activity Methods): NRTL, UNIQUAC, Dng c bit (Special Packages): AMINE, ALCOHOL, SOUR,

C s la chn h nhit ng:

c trng nhit ng ca h (h s K)
Thnh phn hn hp Phm vi nhit p sut Tnh sn c ca cc thng s ca h

PR: Peng Robonson PRSV: Peng Robinson Stryjek-Vera GS: Grayson-Streed ZJ: Zudkevitch Joffee CS: Chao Seader NRTL: Non-Random-Two-Liquid MBWR: Modified Benedict Webb Rubin

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

La chn phng php nhit ng hc

H tiu biu Sy kh bng TEG Nc chua X l kh nhit thp Tch khng kh Thp chng ct du th p sut kh quyn Thp chng ct chn khng Thp Ethylene H H2 p sut cao Cc thng cha c ch to hydrate H nhit ng ph hp c ngh s dng PR PR, Sour PR PR, PRSV PR, PRSV PR, PR Options, GS PR, PR Options, GS (<10mmHg), Braun K10, Esso K Lee Kesler Plocker PR, ZJ hoc GS Steam Package, CS hoc GS PR

Cc h ha hc
Alkyl ha xc tc HF Sy bng TEG c mt cc hp cht thm Cc h hydrocacbon trong tan ca nc trong cc hydrocacbon l quan trng Cc h c mt vi kh v cc hydrocacbon nh

Activity Models, PRSV

PRSV, NRTL PR Kabadi Danner MBWR

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Qu trnh ch bin kh
Vi kh cha 5% N2, CO2 v H2S v khng c phn t phn cc no khc SRK, PR hoc BWRS

Vi kh cha 5% N2, CO2 v H2S v khng c phn t phn cc no khc

Tch cc hydrocacbon nh Tch kh t khng kh bng lm lnh su

SRK, PR, (ngi s dng nn a vo cc thng s tng tc thu c kt qu chnh xc hn)

PR-BM, RKS-BM, PR, SRK. PR-BM, RKS-BM, PR, SRK

Tch nc bng Glycol

Hp th kh axit bng metanol (RECTISOL) NMP (PURISOL) Hp th kh axit bng amin (AMISOL) kim xoda nng Qu trnh Claus X l kh t nhin c ln nc lm vic p sut cao ( ha tan ca hydrocacbon trong nc s tng ln)

PRWS, RKSWS, PRMHV2, RKSMHV2, PSRK, SR-POLAR, SAFT

PRWS, RKSWS, PRMHV2, RKSMHV2, PSRK ,SR-POLAR, PHSCT, SAFT ELECNRTL PRWS, RKSWS, PRMHV2, RKSMHV2, PSRK, SRPOLAR SRKM, PRM, SRKS, SRKKD (EOS SRK c bin i bi Kabadi-Danner)

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Qu trnh ch bin du
H thng p sut thp (thp chng ct p sut kh quyn v chn khng) Trong nguyn liu ca cc h thng ny c khong trn 3% th tch phn nh
Khi hm lng phn nh ln (nht l thnh phn C1)

BK10 hoc GS v cc dng bin i ca n

SRK,PR.

H thng p sut cao (thp chng ct phn on sn phm ca phn xng cracking, cc ha,) hm lng phn nh ni chung ln

GS, SRK, PR

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Qu trnh ha du
Qu trnh tch cc hydrocacbon nh
p sut thp SRK,PK

p sut cao

SRKKD

Tch BTX

P<2 bars
P>2 bars

IDEAL
GS,SRK,PK WILSON, NRTL, UNIQUAC PR, SRK, WILSON, NRTL WILSON, NRTL, UNIQUAC WILSON, NRTL, UNIQUAC

Cc sn phm khc MTBE, ETBE, TAME Tch ethylbenzen,styren Axit Terephthalic Chng tch ru ng ph

Axit Cacboxylic
Sn xut phenol Sn xut amonia Sn xut kh tng hp

WILS-HOC, UNIQ-HOC
WILSON, NRTL, UNIQUAC PR, SRK PR-BM, RKS-BM

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Cu t gi (Hypothetical)
Mt hp phn gi nh c th c s dng to m hnh cc cu t khng c trong th vin, cc hn hp xc nh, cc hn hp khng xc nh, hay cc cht rn.

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Cu t gi (Hypothetical)
Structure Builder: Xy dng cu trc Critical: Nhp thng tin ti thiu Estimate Unknown Props: Hysys s t ng tnh ton tt c cc tnh cht khc cng nh nh ngha y hp phn gi nh. Add Hypo: Nhp hp phn gi nh vo danh sch cc hp phn c la chn (C th s dng nt Sort list gi danh sch cc hp phn (Thng tin ti thiu phi bit nh ngha mt hp phn gi nh l nhit si iu kin chun Pt hay l t trng ca cht lu l tng (cht lu c dng chy l tng) v khi lng phn t. VD: nhit si ca C7+ = 1100C
We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Thit lp cc phn ng

Thit lp phn ng

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Cc dng phn ng

Conversion : phn ng tnh ton da vo chuyn ha Equilibium: phn ng tnh ton da trn hng s cn bng K Heterogeneous Catalytic Kinetic: phn ng tnh ton da trn hng s tc phn ng Simple Rate

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Thit lp phn ng

Cc h s t lng ca phn ng
We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

 chuyn ha

chuyn ha

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

S c trng du m
c trng du m trong Hysys chp nhn cc dng thng tin khc nhau v dng du m. Chng ta cng cung cp nhiu thng tin cho mu ca chng ta, th s miu t cng chnh xc. (Lng thng tin ti thiu m Hysys yu cu c trng mt du m l: 1. Mt ng cong chng ct trong phng TN 2. Hai trong s cc tnh cht sau: Khi lng phn t, t trng, hoc h s K Waston.)

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Cc dng php th
Vic c trng ng tnh d bay hi l quan trng khi miu t mt cht lu du m trong qu trnh m phng ca chng ta. Hysys chp nhn cc c trng tiu chun nh gi kh nng bay hi sau: im si thc (TBP). c thc hin cc my phn tch gin on c nhiu a hot ng cc t s hi lu cao. ASTM D86. S chng ct dng phn tch gin on nhng s dng cc bnh Engler khng c hi lu (bnh tht c). Ni chung s dng cho cc phn on du m nh v trung bnh. (Vi tt c cc ng cong chng ct, chng ta c yu cu l phi nhp t nht 5 im d liu) D1160 distillation. S chng ct dng phn tch gin on nhng s dng cc bnh Engler khng c hi lu (bnh tht c). Ni chung s dng cho cc phn on du m nng. D86_D1180. y l mt s kt hp ca cc dng d liu chng ct D86/D1180. ASTM D2887. M phng chng ct phn tch t d liu sc k. Equilibrium Flash Vaporization (EFV). Bao gm mt chui cc thc nghim p sut kh quyn khng i, ton b hi nm cn bng vi lng cha bay hi. Chromatographic Analysis. Mt phn tch sc k kh ca mt mu nh du bay hi hon ton, c phn tch cho cc nhm hydrocacbon paraffin, aromatic, naphten t C6 n C30. Cc phn tch sc k c th c nhp trn c s mole, khi lng, hay th tch lng.

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Phn on nh
Cc phn on nh c nh ngha bng cc hp phn nguyn cht vi cc im si thp. Cc thnh phn trong khong nhit si ca C2 n n-C5 thng c quan tm nht. Hysys cung cp ba tu chn tnh ton cho phn on nh: Ignore. Hysys c trng phn on nh ca mu ca chng ta bng cc cu t gi. y l phng php t chnh xc nht v do vy n khng c khuyn co s dng. Auto Calculate. La chn ci ny khi chng ta khng c mt phn tch ring r cc hp phn nh nhng chng ta mun phn c nhit si thp c miu t bng cc cu t nguyn cht. Hysys s ch s dng cc cu t nguyn cht m chng ta la chn trong gi cht lu. Input Composition. La chn ci ny khi chng ta c phn on nh c phn tch ring r v du m ca chng ta c pha ch vi phn on nh trong mu. Hysys cung cp mt danh sch cc cu t nguyn cht m chng ta la chn trong gi cht lu. y l mt phng php chnh xc nht miu t.

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Cc tnh cht khi

Cc tnh cht khi cho mu cng c th c cung cp. Cc tnh cht khi l tu y nu mt ng cong chng ct hay cc d liu sc k cc c cung cp. Khi lng phn t. y l khi lng phn t ca mu th tch (bulk sample). N phi ln hn 16. T khi. T khi phi nm gia 250 v 2000 kg/m3. (Cc n v cho t trng c th l t khi, API hay trng lng ring, c chn t danh sch s xung trong thanh Edit) H s K Waston (UOP). Phi nm gia 8 v 15 (H s K Waston l mt ch s parafin gn ng. K = (Mean Avg BP)1/3/(sp gr 60F/60F) Bulk Viscosities. Cho hai nhit no , mc nh 37.780C v 98.890C (1000F v 2100F).
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Nhp cc d liu du m
La chn mc Assay>Add Mc Input Data nhp cc thng tin sau: Name: Res-Fluid. Bulk Props: Used Assay Data Type: Chromatograph Light Ends: Input Composition Input Data : Light Ends Assay Basis: phn trm mole. Nhp cc d liu nh bng di:

Thnh phn N2 H2S CO2 C1 C2 C3 i-C4 n-C4 i-C5 n-C5

Phn mole 0.48 0.00 0.87 41.83 8.87 7.11 1.47 3.75 1.25 1.63

C6 H2O

0.00 0.00

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Nhp cc d liu du m

La chn tu chn Paraffinic v ch r n v l mole. Nhp cc d liu sau:

Thnh phn Hexane (C6) Heptane (C7) Octane (C8) Nonane (C9) Decane (C10) Undecane (C11) Dodecane (C12) Phn mole 0.0286 0.0371 0.0348 0.0231 0.0240 0.0183 0.0142 Octadecane (C18) Nonadecane (C19) Eicosane (C20) Heneicosane (C21) Docosane (C22) Tricosane (C23) Tetracosane (C24) Pentacosane (C25) 0.0062 0.0049 0.0046 0.0039 0.0036 0.0032 0.0027 0.0024

Tridecane (C13)
Tetradecane (C14) Pentadecane (C15) Hexadecane (C16) Heptadecane (C17)

0.0141
0.0113 0.0099 0.0074 0.0082

Hexacosane (C26)
Heptacosane (C27) Octacosane (C28) Nonacosane (C29) Triconane Plus

0.0021
0.0020 0.0018 0.0016 0.0133

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Nhp cc d liu du m
La chn tu chn Aromatic v la chn cc d liu phn mole sau:
Thnh phn Benzene (C6H6) Phn mole 0.0004

Toluene (C7H8)
EBZ, p+m-Xylene (C8H10) o-xylene (C8H10) 1,2,4-TrimethylBenzene (C9H12)

0.0015
0.0070 0.0028 0.0028

Nhp cc d liu sau cho cc thnh phn naphten:

Thnh phn Cyclopentane (C5H10) Methylcyclopentan (C6H12) Cyclohexane (C6H12) Phn mole 0.0002 0.0106 0.0050

Methylcyclohexan (C7H14)

0.0156

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Nhp cc d liu du m

La chn mc Bulk Props nhp cc tnh cht khi: Khi lng phn t l 79.6 v t trng tiu chun l 0.6659 SG_60/60api. Calculate -> Assay was Calculated. Ngay khi du m c tnh ton, cc ng cong lm vic s c hin th trn mc Working Curves. Cc ng cong lm vic c chuyn ngc t d liu u vo ca du m. Vic tnh ton cho s pha trn da trn cc ng cong lm vic ny. ng ca s ny li quay tr li ca s Oil Characterization. Chng ta s vn trong mc Assay ca ca s. Ch y l tt c cc nt trn ca s by gi c th s dng c. (Vi cc gi cht lng, cc du m c th c nhp v xut c s dng trong cc bi tp khc)

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Cc khong phn ct
Chng ta c ba la chn cho Cut option selection: Auto cut: Hysys s chia du m da trn cc gi tr bn trong Khong 37.78-4250C (100-8000F) 425-6500C (800-12000F) 650-7800C (1200-16000F) S phn on 28 (4 phn on trn mi khong 37.780C/1000F) 8 (2 phn on trn mi khong 37.780C/1000F) 4 (1 phn on trn mi khong 37.780C/1000F)

User Points: chng ta ch r s lng cc cu t gi yu cu. Hysys cn i cc phn on theo s khi bn trong.

Khong gia cc im ct IBP-4250C (IBP-8000C) 425-6500C (800-12000F) 6500C-FBP (12000F-FBP)

Phn on 4 phn on trn mi khong 37.780C/1000F 2 phn on trn mi khong 37.780C/1000F 1 phn on trn mi khong 37.780C/1000F

User Ranges: Chng ta ch r cc khong theo im si v s lng cc phn on trn mi khong.

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Chia ct du m
Ngay khi phn on du m c tnh ton, chng ta c th ct du m thnh cc cu t gi ring bit. Di chuyn n mc Cut/Blend ca ca s Oil Characterization. Kch vo nt Add to mt hn hp pha trn mi. Trong Name, thay i dng tn mc nh t Bend -1 thnh Res-Fluid. T danh sch cc du m c hiu lc (ch nn c mt), la chn Res Fluid v kch vo nt Add. Ci ny s thm du m vo bng cc tnh cht ca dng v mt hn hp trn ln s c tnh ton t ng. Hn hp trn ln c tnh ton s dng tu chn chia ct mc nh, t ng chia ct. Thay v vic s dng tu chn chia ct t ng mc nh, thay i la chn chia ct s dng cc im do ngi s dng nhp vo v thay i s on chia ct l 5. (Ch rng vic gim s on chia ct s lm tng tc m phng, nhng n c th c mt nh hng xu n chnh xc ca m phng) Kt qu tnh ton c th c hin th trong mc Tables ca ca s Blend.
We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Phn tch kt qu
Ngay khi chng ta tnh ton mt hn hp trn ln, chng ta c th kim tra cc tnh cht khc v cc tm tt cho dng ca cc cu t gi c to ra miu t mt du m c tnh ton. Quay li mi trng du m v m ca s ca hn hp trn ln, Res-Fluid. Oil Characterization>Cut/Blend>View Mc Tables Mc Property Plot Mc Composite Plot
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Thit lp n v tnh
Tools/Preferences/Variable tab

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Simulation Enviroment

Menu Bar Toolbar Object Pallette

Status Bar

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Object Status Window

Trace Window

Performance Slider

Stream
Material streams Flow rates (F): Stream and components (mass, mol, etc.) Composition (x): Components and their mass/mol fractions Phase (f): Solid, liquid, gas, 2phase, 3-phase, etc. Temperature (T) Pressure (P) Form (): Particle size distribution, shape, etc. Energy streams Flow (e): Energy flow kJ/h Form: Power (work) or heat

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Stream
C 3 cch nhp cc dng trong Hysys Phng php S dng Menu Bar Cch thc hin

La chn Add Stream t mc Flowsheet trn thanh menu, hoc n vo phm nng F11

S dng Workbook S dng bng ni

M Workbook di chuyn n mc Material Streams. Nhp tn dng vo trong New. T mc Flowsheet trn thanh menu, la chn Open Object Palette hoc n F4 m bng ni. Nhp p vo biu tng dng

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Stream
Nhp cc thnh phn ca dng C hai mc khc nhau nhp thnh phn dng: Mc iu kin Thc hin p vo Molar Flow phn mole. Hoc kch p vo Mass Flow nhp phn khi lng. Hoc * Kch p vo Std Ideal Liquid Volume Flow nhp phn th tch.
Kch

Thnh phn

Kch vo nt Edit, ca s nhp thnh phn dng s xut hin.

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Extra Cc phm nng trong Hysys

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Extra Cc phm nng trong Hysys

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others

Homework
Dng 3 cch khc nhau nhp cc dng vt cht sau: Gaswell 1 Gaswell 2
Cu t N2 H2S CO2 C1 C2 C3 i-C4 n-C4 i-C5 n-C5 C6 C7+ Phn mole 0.0002 0.0405 0.0151 0.7250 0.0815 0.0455 0.0150 0.0180 0.0120 0.0130 0.0090 0.0252 Cu t Phn mole

Gaswell 3
Cu t N2 Phn mole 0.0050

N2
H2S CO2 C1 C2 C3 i-C4 n-C4 i-C5 n-C5 C6 C7+

0.025
0.0237 0.0048 0.6800 0.1920 0.0710 0.0115 0.0085 0.0036 0.0021 0.0003 0.0000

H2S
CO2 C1 C2

0.0141
0.0205 0.5664 0.2545

C3
i-C4 n-C4 i-C5

0.0145
0.0041 0.0075 0.0038

n-C5
C6 C7+

0.0037
0.0060 0.0090

We learn 10% of what we read; 20% of what we hear; 30% of what we see; 50% of what we see and hear; 70% of what we discuss; 80% of what we experience; 95% of what we teach others