S Gio Dc & o To NGh an

chnh thc

K thi chn hc sinh gii tnh lp 9 THCS nm hc 2010 - 2011

Mn thi: Ha hc - bng a Thi gian: 150 pht (khng k thi gian giao ) Cu I (4,0 im). 1/ Chn 7 cht rn khc nhau m khi cho 7 cht ln lt tc dng vi dung dch HCl c 7 cht kh khc nhau thot ra. Vit cc phng trnh phn ng minh ho. 2/ Cho cc s phn ng ho hc sau y: X1 + X2 Na2CO3 + H2O X3 + H2O X5 + X2 X6 + H2O X6 + CO2 + H2O X7 + X1 Chn cc cht X1, X2, X3, X5, X6, X7, X8 thch hp v hon thnh cc phng trnh ho hc ca cc phn ng trn. 3/ Em hy xut thm 4 phn ng khc nhau trc tip iu ch X 2 Cu II (3,0 im). Cho 26,91 (g) kim loi M vo 700 ml dung dch AlCl 3 0,5M, sau khi phn ng xy ra hon ton thu c V lt H2 (ktc) v 17,94 (g) kt ta. Xc nh kim loi M v gi tr ca V. Cu III (6,0 im): Chia 80 (g) hn hp X gm st v mt oxit ca st thnh hai phn bng nhau: Ho tan ht phn I vo 400 (g) dung dch HCl 16,425% c dung dch A v 6,72 lt kh H 2 (ktc). Thm 60,6 (g) nc vo A c dung dch B, nng % ca HCl d trong B l 2,92%. 1/ Tnh khi lng mi cht trong hn hp X v xc nh cng thc ca oxit st. 2/ Cho phn II tc dng va ht vi H2SO4 c nng ri pha long dung dch sau phn ng bng nc, ta thu c dung dch E ch cha Fe2(SO4)3. Cho 10,8 (g) bt Mg vo 300 ml dung dch E khuy k, sau khi phn ng xy ra hon ton thu c 12,6 (g) cht rn C v dung dch D. Cho dung dch D tc dng vi dung dch Ba(OH)2 d, lc kt ta v nung n khi lng khng i c m (g) cht rn F (trong iu kin th nghim BaSO4 khng b phn hu). Tnh CM ca dung dch E v gi tr m. Cu IV (4,0 im). 1/ Vit phng trnh ha hc ( dng cng thc cu to thu gn) thc hin cc bin ha theo s sau: (1) (2) Axetilen Etilen Etan (7) (5) (8) (3) (4) (6) P.V.C Vinylclorua icloEtan Etylclorua 2/ Cho vo bnh kn hn hp cng s mol C 5H12 v Cl2 to iu kin phn ng xy ra hon ton thu c sn phm hu c m trong mi phn t ch cha mt nguyn t Clo. Vit cc cng thc cu to c th c ca cc sn phm hu c . Cu V (3,0 im). t chy hon ton 1 (g) hn hp X gm C 2H2, C3H6, C2H6. Hp th ton b sn phm chy vo 2 lt dung dch Ca(OH)2 0,02 M thu c 1 (g) kt ta. Mt khc 3,36 lt hn hp X (ktc) lm mt mu ti a 200 ml dung dch Br2 0,5 M. Tnh th tch mi kh c trong 1 (g) hn hp X. Cho: H = 1; Li = 7; C = 12, O = 16; Na = 23; Mg = 24; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Br = 80; Ba= 137. - - - Ht - - in phn nng chy X5 Criolit in phn dung dch c mng ngn

X2 + X4 + H2

X8 + O2

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S Gio Dc & o To NGh an

chnh thc

K thi chn hc sinh gii tnh lp 9 THCS nm hc 2010 - 2011

Mn thi: Ha hc - bng B Thi gian: 150 pht (khng k thi gian giao ) Cu I (5,0 im). 1/ Chn 6 cht rn khc nhau m khi cho 6 cht ln lt tc dng vi dung dch HCl c 6 cht kh khc nhau thot ra. Vit cc phng trnh phn ng minh ho. 2/ Cho cc s phn ng ho hc sau y: X1 + X2 Na2CO3 + H2O X3 + H2O X5 + X2 X6 + H2O X6 + CO2 + H2O X7 + X1 Chn cc cht X1, X2, X3, X5, X6, X7, X8 thch hp v hon thnh cc phng trnh ho hc ca cc phn ng trn. 3/ Em hy xut thm 4 phn ng khc nhau trc tip iu ch X 2 Cu II (3,0 im). Cho 26,91 (g) kim loi M ha tr I vo 700 ml dung dch AlCl 3 0,5M, sau khi phn ng xy ra hon ton thu c V lt H2 (ktc) v 17,94 (g) kt ta. Xc nh kim loi M v gi tr ca V. Cu III (4,0 im): Cho 40 (g) hn hp X gm st v mt oxit ca st tan ht vo 400 (g) dung dch HCl 16,425% c dung dch A v 6,72 lt kh H 2 (ktc). Thm 60,6 (g) nc vo A c dung dch B, nng % ca HCl d trong B l 2,92%. 1/ Vit cc phng trnh ha hc xy ra. 2/ Tnh khi lng mi cht trong X. 3/ Xc nh cng thc ha hc ca oxit st. Cu IV (4,0 im). 1/ Vit phng trnh ha hc ( dng cng thc cu to thu gn) thc hin cc bin ha theo s sau: Axetilen (3) (4) Vinylclorua
in phn nng chy X5 Criolit in phn dung dch c mng ngn

X2 + X4 + H2

X8 + O2

(1)

Etilen

P.V.C

(6)

(5) icloEtan

(2) Etan (7) (8) Etylclorua

2/ Cho vo bnh kn hn hp cng s mol C 5H12 v Cl2 to iu kin phn ng xy ra hon ton thu c sn phm hu c m trong mi phn t ch cha mt nguyn t Clo. Vit cc cng thc cu to c th c ca cc sn phm hu c . Cu V (4,0 im). Chia 1,344 lt hn hp X (ktc) gm C2H2, C3H6, C2H6 thnh 2 phn bng nhau: - t chy hon ton phn 1 ri hp th hon ton sn phm chy vo 2 lt dung dch Ca(OH) 2 0,02 M thu c 1 (g) kt ta. - Phn 2 cho phn ng hon ton vi dung dch Brm d, thy khi lng Brm phn ng l 3,2 (g). Tnh th tch mi kh trong hn hp X. Cho: H = 1; Li = 7; C = 12, O = 16; Na = 23; Mg = 24; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Br = 80; Ba= 137. - - - Ht - - -

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GD&T NGH AN

K THI CHN HC SINH GII TNH LP 9 CP THCS NM HC 2011 2012 Mn thi: HA HC - BNG A Thi gian lm bi: 120 pht

chnh thc

Bi 1: (4,5 im) 1. Vit bn phng trnh ha hc trc tip to ra HCl t Cl2 bng bn cch khc nhau (cc cch khc nhau nu cht tc dng vi Cl2 khc loi). 2. Chn 7 cht rn khc nhau m khi cho mi cht tc dng vi dung dch H 2SO4 c, nng, d u cho sn phm l Fe2(SO4)3, SO2 v H2O. Vit cc phng trnh ha hc. Bi 2: (4,0 im) Mt hn hp rn A gm 0,2 mol Na2CO3; 0,1 mol BaCl2 v 0,1 mol MgCl2. Ch c dng thm nc hy trnh by cch tch mi cht trn ra khi hn hp. Yu cu mi cht sau khi tch ra khng thay i khi lng so vi ban u (Cc dng c, thit b cn thit k c ngun nhit, ngun in cho y ). Bi 3: (2,5 im) T Metan, mui n, (cc cht xc tc, dng c cn thit cho y ) vit cc phng trnh ha hc iu ch ra: iclometan, nha P.V.C, nha P.E, icloetilen, etan, etylclorua. Ghi r iu kin ca phn ng nu c. Bi 4: (4,5 im) Trn u 30,96 gam hn hp bt X gm MgCO 3 v kim loi R c ha tr khng i ri chia lm hai phn bng nhau. - t nng phn I trong khng kh, sau khi cc phn ng xy ra hon ton thu c 15 gam hn hp cc oxit kim loi. - ha tan va ht phn II cn 500ml dung dch cha hn hp HCl 1,2M v H 2SO4 0,24M c dung dch A v c V lt kh B bay ra. 1. Vit cc phng trnh ha hc. 2. Xc nh kim loi R v t khi ca B so vi H2. 3. Cho 61,65 gam Ba kim loi vo dung dch A. Sau khi cc phn ng kt thc, lc c m gam rn F khng tan v 500 ml dung dch E. Tnh gi tr ca m v nng C M ca mi cht tan c trong dung dch E. Bi 5: (4,5 im) Chia 9,84 gam hn hp kh X gm Etilen v 1 hirocacbon mch h A thnh hai phn bng nhau. - Dn phn I qua dung dch Brom d, sau khi phn ng kt thc c V lt kh A thot ra, khi lng Brom tham gia phn ng l 8 gam. - t chy hon ton phn II ri cho ton b sn phm chy vo bnh c cha 500 ml dung dch Ba(OH)2 0,66M. Sau khi phn ng kt thc thu c 63,04 gam kt ta. Dung dch sau khi lc b kt ta b gim i m gam so vi khi lng ca dung dch Ba(OH)2 ban u. 1. Vit cc phng trnh ha hc. 2. Xc nh cng thc phn t ca A. 3. Tnh gi tr ca m v gi tr ca V KTC. Cho H:1; C:12; O:16; Mg:24; Al:27; S:32; Cl:35,5; Ca:40; Fe:56; Cu:64; Zn: 65; Ba:137. .......... Ht ..........

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GD&T NGH AN

K THI CHN HC SINH GII TNH LP 9 CP THCS NM HC 2011 2012 Mn thi: HA HC - BNG B Thi gian lm bi: 120 pht

chnh thc

Bi 1: (5,0 im) 1. Vit bn phng trnh ha hc trc tip to ra HCl t Cl 2 bng bn cch khc nhau (cc cch khc nhau nu cht tc dng vi Cl2 khc loi). 2. Chn 4 cht rn khc nhau m khi cho mi cht tc dng vi dung dch H 2SO4 c, nng, d u cho sn phm l Fe2(SO4)3,SO2 v H2O. Vit cc phng trnh ha hc. Bi 2: (5,0 im) T Metan, mui n, (cc cht xc tc, dng c cn thit cho y ) vit cc phng trnh ha hc iu ch ra: iclometan, nha P.V.C, nha P.E, icloetilen, etan, etylclorua. Ghi r iu kin ca phn ng nu c. Bi 3: (5,0 im) Trn u 30,96 gam hn hp bt X gm MgCO3 v Al ri chia lm hai phn bng nhau. - t nng phn I trong khng kh, sau khi cc phn ng xy ra hon ton thu c 15 gam hn hp cc oxit kim loi. - ha tan va ht phn II cn 500ml dung dch cha hn hp HCl 1,2M v H 2SO4 0,24M c dung dch A v c V lt kh B bay ra. 1. Vit cc phng trnh ha hc. 2. Tnh khi lng mi cht trong hn hp X v t khi ca B so vi H2. 3. Cho dung dch Ba(OH)2 d vo dung dch A. Tnh khi lng kt ta thu c. Bi 4: (5,0 im) Chia 9,84 gam hn hp kh X gm Etilen v 1 hirocacbon mch h A thnh hai phn bng nhau. - Dn phn I qua dung dch Brom d, sau khi phn ng kt thc c V lt kh A thot ra, khi lng Brom tham gia phn ng l 8 gam. - t chy hon ton phn II ri cho ton b sn phm chy vo bnh c cha dung dch Ba(OH) 2 d. Sau khi phn ng kt thc, thu c 63,04 gam kt ta. Dung dch sau khi lc b kt ta b gim i m gam so vi khi lng ca dung dch Ba(OH)2 ban u. 1. Vit cc phng trnh ha hc. 2. Xc nh cng thc phn t ca A. 3. Tnh gi tr ca m v gi tr ca V KTC. Cho H:1; C:12; O:16; Mg:24; Al:27; S:32; Cl:35,5; Ca:40; Fe:56; Cu:64; Zn: 65; Ba:137. .......... Ht ..........

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V O TO GIA LAI CHNH THC Cu 1. (3,0 im) a. Hon thnh chui chuyn ho:

K THI CHN HC SINH GII LP 9 CP TNH Nm hc 2011-2012 MN: HO HC Thi gian: 150 pht (khng k thi gian pht )
+NaOH

A G +B S (lu hunh)
(1)
+ NaOH, , t
o

+ HCl

(3)
+ HCl

B G

(4)
+NaOH

C +NaOH
(5)

A F

+Ba(OH)2

(6)

E kt ta trng J kt ta en

(2)

(7)

(8)

H +NaOH
(9)

+AgNO3

(10)

b. Ch dng thm nc v kh cacbonic hy trnh by phng php nhn bit cc cht rn: Na 2CO3, Na2SO4, NaCl, BaCO3 v BaSO4. Cu 2. (3,0 im) a. Nu hin tng, gii thch, vit phng trnh phn ng xy ra khi p ng nghim cha y Hn hp kh hn hp kh C2H2 v C2H4 vo chu thu tinh cha dung dch nc brom (nh hnh bn). C2H2 v C2H4 b. T nhm cacbua v cc cht v c cn thit hy vit phng trnh phn ng iu ch Dung dch vinyl axetat v hexacloxiclohexan. nc brom Cu 3. (2,0 im) t chy hon ton cht hu c Z (cha C, H v O) thu c CO 2 v H2O c t l khi lng l 88:45. - Tm cng thc phn t ca Z, bit trong phn t Z c mt nguyn t oxi. - Vit cng thc cu to c th c ca Z, bit Z c mt s tnh cht ho hc ging ru etylic. Cu 4. (2,0 im) Y l cht hu c cha cc nguyn t C, H, O v N. t chy hon ton 0,75 gam Y thu c hn hp sn phm gm CO2, H2O v N2, cho hon ton sn phm chy vo dung dch Ca(OH) 2 d thu c 2 gam kt ta v khi lng bnh tng 1,33 gam. Tm cng thc phn t ca Y (bit M Y = 75). Cu 5. (3,0 im) Cho 3,07 gam hn hp bt kim loi X gm Al v Fe vo 150 ml dung dch hn hp gm Fe(NO3)3 1,0 M v AgNO3 0,5 M, khuy u, sau phn ng thu c m gam kim loi v dung dch Y (cha ba mui). Cho t t dung dch NaOH d, ly kt ta nung n khi lng khng i c 16,0 gam cht rn khan. Bit cc phn ng xy ra hon ton. a. Vit phng trnh phn ng c th xy ra. b. Tnh m v phn trm khi lng ca Al v Fe trong X. Cu 6. (3,0 im) a. Cho 14,4 gam hn hp Z gm mui cacbonat v hidrocacbonat ca cng mt kim loi kim (M) phn ng vi dung dch HCl d, phn ng hon ton thu c 2,8 lt kh CO 2 (ktc). Tm M, tnh phn trm khi lng cc mui trong Z. b. X l dung dch HCl 0,3 M, Y l dung dch hn hp Na 2CO3 0,15 M v NaHCO 3 0,1 M. Tnh th tch CO2 sinh ra (ktc) khi: - Cho t t 100 ml dung dch X vo 100 ml dung dch Y v khuy u. - Cho t t 100 ml dung dch Y vo 100 ml dung dch X v khuy u. Cu 7. (2,0 im) Trn 0,2 lt dung dch H 2SO4 x M vi 0,3 lt dung dch NaOH 1,0 M thu c dung dch A. phn ng vi A cn ti a 0,5 lt dung dch Ba(HCO 3)2 0,4 M, sau phn ng thu c m gam kt ta. Tnh gi tr ca x v m. Cu 8. (2,0 im) Ho tan hon ton 5,28 gam hn hp X gm Cu v mt oxit st (Fe xOy) trong H2SO4 c nng (d). Sau khi phn ng xy ra hon ton thu c 448 ml kh SO 2 (ktc) v dung dch. C cn dung dch thu c 13,6 gam hn hp mui khan Y. a. Vit phng trnh phn ng xy ra. b. Tm cng thc phn t ca oxit st, tnh phn trm khi lng cc cht trong Y. Ht Hc sinh c s dng bng h thng tun hon v my tnh b ti.

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V O TO K LK CHNH THC ( thi c 2 trang)

K THI CHN HC SINH GII TNH NM HC 2010-2011 MN HO HC LP 9 THCS Thi gian lm bi: 150 pht (khng k thi gian giao ) Ngy thi: 22/3/2011

Cu 1. (4,0 im) 1. a. Polime X cha 38,4% cacbon; 56,8% clo v cn li l hydro v khi lng. Xc nh cng thc phn t, vit cng thc cu to ca X v gi tn, cho bit trong thc t X dng lm g? b. T metan v cc cht v c cn thit khc. Hy vit cc phng trnh phn ng ho hc (ghi r iu kin) iu ch X ni trn. 2. Trong bn ng nghim c ng ring bit dung dch long trong sut ca bn cht. Bit rng: - Trong cc dung dch ny c mt dung dch l axit khng bay hi; ba dung dch cn li l mui magie, mui bari, mui natri. - C 3 gc axit l clorua, sunfat, cacbonat; mi gc axit trn c trong thnh phn t nht ca mt cht. a. Hy cho bit tn tng cht tan c cha trong mi dung dch trn. b. Ch dng cc ng nghim, khng c cc dng c v ho cht khc, lm th no phn bit cc dung dch trong bn ng nghim trn v vit phng trnh ho hc minh ha. Cu 2. (4,0 im) Hn hp M gm mt hirocacbon mch h A v mt hirocacbon X c cng thc C xH2x - 2 (x 2), c t l s mol l 2:1. T khi ca hn hp so vi hiro bng 25,33. t chy hon ton 3,36 lt (ktc) hn hp M, sau dn ton b sn phm i vo 1000 gam dung dch Ca(OH) 2 7,4% thy c 55 gam kt ta. Lc kt ta, sau nu un si dung dch th khng thy c thm kt ta xut hin. 1. Tm cng thc phn t ca A v X bit chng hn km nhau 1 nguyn t cacbon. 2. Tnh nng phn trm ca dung dch sau khi lc b kt ta. Cu 3. (4,0 im) 1. Ha tan hon ton 24,625 gam hn hp mui gm KCl, MgCl 2 v NaCl vo nc, ri thm vo 300 ml dung dch AgNO3 1,5 M. Sau phn ng thu c dung dch A v kt ta B. Cho 2,4 gam Mg vo dung dch A, khi phn ng kt thc lc tch ring cht rn C v dung dch D. Cho ton b cht rn C vo dung dch HCl long d, sau phn ng thy khi lng ca cht rn C gim i 1,92 gam. Thm dung dch NaOH d vo dung dch D, lc ly kt ta em nung n khi lng khng i c 4 gam cht rn E. Tnh phn trm khi lng cc mui c trong hn hp ban u. 2. Th vin bi st (hnh cu) nng 5,6 gam vo 200 ml dung dch HCl. Sau khi ng knh vin bi ch cn li 1/2 th thy kh ngng thot ra. Xc nh nng mol/l ca dung dch HCl. ( Gi s vin bi Fe b mn u). Cu 4. (3,5 im) Cho 18,6 gam hn hp A gm Zn v Fe vo 500 ml dung dch HCl x M. Khi phn ng xy ra hon ton, c cn dung dch thu c 34,575 gam cht rn. Lp li th nghim trn vi 1 lt dung dch HCl ri c cn th thu c 39,9 gam cht rn. Tnh x v khi lng mi kim loi trong 18,6 gam hn hp A. Cu 5. (4,5 im) 1. Cho cc cht: ru tylic, tilen, benzen, mtan, axtilen. a. Vit cng thc phn t v cng thc cu to mi cht trn b. X v Y l nhng cht trong s cc cht trn, bit rng: - Khi t chy 0,1 mol mi cht thu c th tch kh CO 2 ln lt l 2,24 lt v 4,48 lt ( ktc). - Khi t chy hn hp cha 0,1mol mi cht th thu c 7,2 gam nc. Xc nh X, Y 2. Cho mt lng tinh th mui CuSO 4.5H2O vo mt lng dung dch Na 2SO4 x% thu c dung dch CuSO4 30% v Na2SO4 10%. Tnh x 3. Mt dy hyrocacbon c biu din bi cng thc chung C nH2n+2. Hy cho bit thnh phn % ca Hiro bin i nh th no khi gi tr n thay i. Cho: Ag = 108; Mg = 24; Ca = 40; Cu = 64; Fe = 56; Zn = 65; Na = 23; K = 39; O = 16; Cl = 35,5; S = 32; C = 12; H = 1. ------------HT----------Th sinh khng c s dng ti liu. Gim th khng gii thch g thm.

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V O TO LONG AN CHNH THC

K THI CHN HC SINH GII LP 9 CP TNH MN THI: HA HC NGY THI: 11/ 4/ 2012 THI GIAN:150 PHT (khng k thi gian pht )

Cu 1: (2 im) Hp cht A c cng thc R2X, trong R chim 74,19% v khi lng. Trong ht nhn ca nguyn t R c s ht khng mang in nhiu hn s ht mang in l 1 ht. Trong ht nhn nguyn t X c s ht mang in bng s ht khng mang in. Tng s proton trong phn t R 2X l 30. Tm cng thc phn t ca R2X. Cu 2: (6 im) 2.1/ (3 im) Hn hp A gm cc dung dch: NaCl, Ca(HCO3)2, CaCl2, MgSO4, Na2SO4. Lm th no thu c mui n tinh khit t hn hp trn? 2.2/ (3 im) Ha tan hon ton 13,45g hn hp 2 mui cacbonat axit v cacbonat trung tnh ca 1 kim loi kim bng 300ml dung dch HCl 1M. Sau phn ng phi trung ha HCl d bng 75ml dung dch Ca(OH)2 1M. a. Tm cng thc 2 mui. b. Tnh khi lng mi mui c trong hn hp ban u. Cu 3: (5 im) 3.1/ (2 im) X c nh B, C, D, E, G, M. Bit A l hn hp gm Mg v Cu. Hy vit phng trnh ha hc thc hin s chuyn ha sau: Dung dch D + Na +O2 d + dd HCl A B C Kh E Nung + E, t0 Kt ta G B M 3.2/ (3 im) Cho M l kim loi to ra hai mui MClx, MCly v to ra 2 oxit MO0,5x, M2Oy c thnh phn v khi lng ca Clo trong 2 mui c t l 1 : 1,173 v ca oxi trong 2 oxit c t l 1 : 1,352. a. Xc nh tn kim loi M v cng thc ha hc cc mui, cc oxit ca kim loi M. b. Vit cc phng trnh phn ng khi cho M tc dng ln lt vi MCly; H2SO4 c, nng. Cu 4: ( 3 im) t chy hon ton 2,24 l (ktc) mt hirocacbon A th kh. Sau dn ton b sn phm chy qua bnh ng dung dch Ca(OH)2 c cha 0,2 mol Ca(OH)2 th c 10g kt ta to nn, ng thi thy khi lng bnh tng thm 18,6g. a. Xc nh cng thc phn t ca A. b. Vit cng thc cu to c th c ca A. Cu 5: (4 im) Cho 13,6g hn hp gm Fe v Fe2O3 tc dng hon ton vi 91,25g dung dch HCl 20% va . a. Tnh thnh phn phn trm v khi lng ca mi cht c trong hn hp ban u. b. Tnh nng phn trm ca cht tan c trong dung dch sau phn ng. c. Nu ha tan hon ton 13,6g hn hp ni trn vo H 2SO4 c, nng, khi phn ng kt thc dn ton b kh sinh ra vo 64 ml dung dch NaOH 10% (D = 1,25g/ml) th thu c dung dch A. Tnh nng mol ca cht tan c trong dung dch A.( Bit rng th tch dung dch thay i khng ng k)

---HT--Ch : Hc sinh c php s dng bng tun hon cc nguyn t ha hc.

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

UBND TNH BC NINH S GIO DC V O TO

CHNH THC

( thi c 01 trang)

THI CHN HC SINH GII CP TNH NM HC 2011 2012 MN THI : HA HC-LP 9 Thi gian lm bi: 150 pht (khng k thi gian giao ) Ngy thi: 20 thng 3 nm 2012 ===========

Cu I (2 im): Mt hn hp cha Fe, FeO, Fe2O3. Nu ho tan a gam hn hp trn bng dung dch HCl d th khi lng H2 thot ra bng 1,00% khi lng hn hp em th nghim. Nu kh a gam hn hp trn bng H2 d th thu c khi lng nc bng 21,15% khi lng hn hp em th nghim. Xc nh phn trm v khi lng mi cht c trong a gam hn hp trn. Cu II (2 im): Cho 1 anken A kt hp vi H2 (Ni lm xc tc) ta c ankan B. a/ Xc nh cng thc phn t ca A, B bit rng t chy ht B bng mt lng O 2 va th th tch kh CO2 thu c bng 1/2 tng th tch ca B v O2. b/ Mt hn hp X gm A, B v H 2 c th tch l 22,4 lt. Cho X i qua Ni nung nng xc tc thu c hn hp Y, bit t khi ca X so vi Y bng 0,70. Tnh th tch hn hp Y, s mol H 2 v A phn ng vi nhau. c/ Bit rng hn hp Y khng lm phai mu nc Br 2 v t khi dY/H2= 16. Xc nh thnh phn trm th tch ca cc kh trong hn hp X. Cc th tch kh u o iu kin tiu chun. Cu III (2 im): Cho 316,0 gam dung dch mt mui hirocacbonat (A) 6,25% vo dung dch H 2SO4 long va , sau khi phn ng xy ra hon ton thu c 16,5 gam mui sunfat trung ho. Mt khc cng cho lng dung dch mui hirocacbonat (A) nh trn vo dung dch HNO 3 va , ri c cn t t dung dch sau phn ng th thu c 47,0 gam mui B. Xc nh A, B. Cu IV (2 im): Cho cc ha cht CaCO3, NaCl, H2O v cc dng c cn thit lm th nghim, trnh by phng php iu ch dung dch gm 2 mui Na2CO3 v NaHCO3 c t l s mol l 1:1. Cu V (2 im): Ba cht kh X, Y, Z u gm 2 nguyn t, phn t cht Y v Z u c 3 nguyn t. C 3 cht u c t khi so vi hiro bng 22. Y tc dng c vi dung dch kim, X v Z khng c phn ng vi dung dch kim. X tc dng vi oxi khi t nng sinh ra Y v mt cht khc. Z khng chy trong oxi. a/ Lp lun tm cng thc phn t cc cht X, Y, Z. b/ Trnh by cch phn bit ba bnh ng ring bit ba kh trn b mt nhn. Cu VI (2 im): Vit phng trnh phn ng trong 0,75 mol H2SO4 tham gia phn ng sinh ra a/ 8,4 lt SO2 (ktc). b/ 16,8 lt SO2 (ktc). c/ 25,2 lt SO2 (ktc). d/ 33,6 lt SO2 (ktc). Cu VII (2 im): Dn lung kh CO qua ng s c cha m gam hn hp cht rn X gm CuO v Fe 2O3 nung nng, sau mt thi gian trong ng s cn li n gam hn hp cht rn Y. Kh thot ra c hp th ht vo dung dch Ca(OH)2 d c p gam kt ta. Vit cc phng trnh ha hc ca phn ng v thit lp biu thc lin h gia n, m, p. Cu VIII (2 im): Hai cc thy tinh A, B ng dung dch HCl d t trn hai a cn, thy cn trng thi thng bng. Cho 5,00 gam CaCO 3 vo cc A v 4,79 gam M2CO3 (M l kim loi) vo cc B. Sau khi cc mui ha tan hon ton thy cn tr li v tr thng bng. Hy xc nh M. Cu IX (2 im): Trnh by cc th nghim xc nh thnh phn nh tnh v nh lng ca nc. Cu X (2 im): Nu cch pha ch 500,0 ml dung dch NaCl 0,9% (nc mui sinh l) t mui n nguyn cht v nc ct. Nu tn cc dng c th nghim cn thit v m phng cch tin hnh bng hnh v. ============== Ht ============== Cho bit s khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27; Si = 28; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Cr = 52; Fe = 56; Ni = 58; Cu = 64; Zn = 65; Ag = 108; Ba = 137 Th sinh c s dng bng HTTH v my tnh cm tay thng thng.

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V O TO LNG SN CHNH THC

K THI CHN HC SINH GII CP TNH LP 9 THCS NM HC 2011 - 2012

Mn thi: HA HC Thi gian: 150 pht (Khng k thi gian giao ) Ngy thi: 22/03/2012 ( thi gm 2 trang v c 6 cu) Cu 1. (3,5 im) 1. Trong cng nghip, kh NH3 mi iu ch thng ln hi nc. lm kh kh NH3 ngi ta c th dng ha cht no sau y: H2SO4 c, dung dch HCl c, P2O5, CaO, KOH khan? Gii thch, vit phng trnh ha hc ca phn ng xy ra ( nu c). 2. C mt hn hp kh gm: CO2, CH4, C2H4. Hy trnh by phng php ha hc : a. Thu c kh CH4 tinh khit t hn hp trn. b. Thu c CO2 tinh khit t hn hp trn. Cu 2. ( 3,5 im) Nhng mt thanh st v mt thanh km vo cng mt cc cha 500ml dung dch CuSO4. Sau mt thi gian ly ng thi hai thanh kim loi ra khi cc th mi thanh u c kim loi ng bm vo, khi lng dung dch gim i 0,22 gam so vi ban u. Trong dung dch sau phn ng, nng mol ca ZnSO4 ln gp 2,5 ln nng mol ca FeSO4 ( th tch dung dch coi nh khng i so vi trc phn ng). Thm dung dch NaOH d vo cc, lc ly kt ta ri nung trong khng kh ti khi lng khng i, thu c 14,5 gam cht rn. a. Vit phng trnh ha hc ca phn ng c th xy ra. b. Tnh s gam Cu bm ln mi thanh kim loi v nng mol ca dung dch CuSO4 ban u. Cu 3. (3,5 im) 1. Vit cc phng trnh ha hc hon thnh s phn ng sau (Bit A1, A2, A3, A4, A5 l cc cht v c):

A1 C2 H 2 C2 H 4 C2 H 6
(1) + A4 d (4) (2) +A2 H2SO4 long C2H5OH (5) + A5 C2H2Br4 A3 (6) 2. t chy hon ton 224 ml (ktc) mt hidrocacbon th kh c cng thc tng qut l CnH2n + 2, sn phm chy hp th vo 2 lt dung dch Ba(OH)2 0,01M, sau phn ng hon ton thu c 1,97 gam kt ta. Xc nh cng thc phn t ca hidrocacbon. Cu 4. ( 3 im) 90oC c 540 gam dung dch CuSO4 bo ha. Lm lnh dung dch xung cn 15oC. Hi c bao nhiu gam tinh th CuSO4.5H2O tch ra khi dung dch trong qu trnh lm lnh. Bit tan SCuSO4 (90oC) = 80 gam v SCuSO4 (15oC) = 25 gam. Cu 5 ( 3,5 im) Dung dch A cha hn hp Na2CO3 0,75M v NaHCO3 0,5M. Dung dch B cha H2SO4 1M. Tnh th tch kh CO2 (ktc) thot ra khi: a. rt t t 100 ml dung dch A vo 150 ml dung dch B. b. rt t t 200 ml dung dch A vo 150 ml dung dch B. c. rt t t 150 ml dung dch B vo 200 ml dung dch A.
H v tn th sinh..............S bo danh....

+ A2

+ A3 ti l1:1 ( t o , Pd )

+ A3 til1:1(t o , Ni )

(3)

Gim th 1: Gim th 2: .

Cu 6. ( 3 im) C 7 l ng 7 dung dch mt nhn c nh s t (1) n (7) gm: (NH4)2CO3, BaCl2, MgCl2, H2SO4, Ba(OH)2, NaOH, Na2CO3. Thc hin cc th nghim c kt qu nh sau: - Cht (1) tc dng vi cht (4) hoc (5) u to ra kt ta; tc dng vi cht (2) hoc (7) u to ra kh. - Cht (2) tc dng vi cht (4) hoc (5) u to ra kt ta; tc dng vi cht (3) to ra kh; tc dng vi cht 6 th to ra c kt ta ln kh. - Cht (5) tc dng vi cht (3), (6) hoc (7) u to ra kt ta. - Cht (7) tc dng vi cht (4) hoc (6) u to ra kt ta. Hy bin lun xc nh cc cht t (1) n (7). ( Hc sinh khng cn vit phng trnh ha hc ca cc phn ng xy ra cu ny). HT Hc sinh c s dng bng tun hon

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIAO DUC VA AO TAO HAI DNG THI CHINH THC

K THI CHON HOC SINH GIOI TINH LP 9 THCS NM HOC 2011-2012 Mn: Hoa hoc Thi gian: 150 phut (khng k giao ) Ngay thi: 23/3/2012

Cu I. ( 2,0 im) 1. Nung nong hn hp Cu, Ag trong O2 d, sau phan ng thu c cht rn A. Cho A vao dung dich H2SO4 c nong d thu c dung dich B va khi C. Khi C tac dung vi dung dich KOH thu c dung dich D. Dung dich D va tac dung vi BaCl2, va tac dung vi NaOH. Xac inh thanh phn cac cht co trong A, B, C, D. Vit phng trinh cac phan ng xay ra trong thi nghim trn. 2. Ch dng mt thuc th, trnh by cch nhn bit cac cht bt mau trng ng trong cac lo ring bit mt nhan sau: BaCO3, BaSO4, Na2SO4, Na2CO3, MgCO3, CuSO4 (khan). Vit cac phng trinh phan ng xay ra (nu co). Cu II. ( 1,75 im) 1. Cho hn hp gm ru etylic, axit axetic, nc. Trinh bay phng phap tach ring ru etylic nguyn cht va axit axetic (c th ln nc) t hn hp trn? Vit phng trinh phan ng minh hoa (nu c). 2. Khi thc hin phan ng chuyn hoa metan thanh axetilen thu c hn hp khi X gm metan, axetilen va hidro. t chay hoan toan X cn 6,72 lt O 2 (ktc). San phm chay c hp thu ht vao dung dich cha 0,1 mol Ca(OH)2. a. Tinh khi lng cua hn hp X? b. Hay cho bit dung dich thu c sau khi hp thu san phm chay co khi lng thay i nh th nao so vi dung dich Ca(OH)2 ban u? Cu III. ( 2,0 im) Cho 37,2 gam hn hp X gm: R, FeO, CuO (R la kim loai chi co hoa tri II, hidroxit cua R khng co tinh lng tinh) vao 500 gam dung dich HCl 14,6 % (HCl dung d), sau phan ng thu c dung dich A, cht rn B nng 9,6 gam (chi cha mt kim loai) va 6,72 lt H 2 (ktc). Cho dung dich A tac dung vi dung dich KOH d, thu c kt tua D. Nung kt tua D trong khng khi n khi lng khng i thu c 34 gam cht rn E gm hai oxit. 1. Tim R va % khi lng cua mi cht trong hn hp X . 2. Tinh nng phn trm cua cac cht trong dung dich A. Cu IV. ( 2,0 im) Hn hp X gm (Al va oxit FexOy). Nung m gam X trong iu kin khng co khng khi, khi o xay ra t0 phan ng: Al + FexOy Al2O3 + Fe (phan ng cha c cn bng). Sau phan ng thu c hn hp cht rn Y. Chia Y thanh hai phn: Phn 1: cho tac dung vi dung dich NaOH d, sau phan ng thu c 1,68 lit khi va 12,6 gam cht rn. Phn 2: cho tac dung vi dung dich H2SO4 c nong d, sau phan ng thu c 27,72 lt SO 2 va dung dich Z c cha 263,25 gam mui sunfat. Bit cac phan ng xay ra hoan toan, cac khi o ktc. 1. Vit phng trinh cac phan ng xay ra. 2. Tim m va cng thc phn t cua oxit FexOy Cu V. ( 2,25 im) t chay hoan 6,72 lt hn hp kh gm hai hidrocacbon mach h co cng thc C nH2n+2 (A) va CmH2m (B) thu c 13,44 lit CO2 va 14,4 gam nc. Cc th tch kh o ktc. 1. Tim cng thc phn t cua hai hidrocacbon. 2. T B (mach khng nhanh) vit cac phng trinh phan ng iu ch CH 3COONa khng qua 3 giai oan (khng qua 3 phan ng), cac cht v c va iu kin phan ng xay ra co u. 3. Tim cng thc cu tao co th co cua B thoa man: khi cho B tac dung vi H 2O, xuc tac H2SO4 thi thu c hn hp hai san phm hu c. Vit cac phng trinh phan ng. Cho: Ag = 108; Al = 27; Ba = 137; C=12; Ca = 40; Cl =35,5; Cu = 64; Fe = 56;H = 1; Mg = 24; Mn = 55; Na = 23; O = 16; Pb= 207; S = 32; Zn = 65. Ht

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC & O TO C MAU

CHNH THC

THI HC SINH GII VNG TNH LP 9 THCS NM HC 2011-2012 Mn thi: Ho hc Ngy thi: 22 4 2012 Thi gian: 150 pht (Khng k thi gian giao )

( thi gm c 2 trang)

Cu I (3,5 im) 1. Vit phng trnh ha hc ca cc phn ng thc hin s chuyn i trc tip sau: a. FeS H2S SO2 H2SO4 E b. vi CaO X Y Z T Cho bit E l mui sunfat ca kim loi R c phn t khi l 152 ; X, Y, Z, T u l mui ca canxi vi cc gc axit khc nhau. 2. Vit phng trnh ha hc ca 5 phn ng khc nhau trc tip iu ch FeCl 3. Cu II (3,0 im) 1. Tnh cht ca hp cht hu c ph thuc vo trt t sp xp cc nguyn t trong phn t . Hy ly th d chng minh. 2. Axit lactic c cng thc cu to : CH3 CHOH COOH. Da vo tnh cht cc cht hu c hc, hy vit phng trnh ha hc ca phn ng gia axit lactic vi: a. Mg b. C2H5OH c. Na 3. Cht hu c c cng thc phn t: C 3H9N. Hy vit cc cng thc cu to ng vi cng thc phn t trn. Cu III (3,5 im) 1. C hn hp gm cc cht rn: SiO 2, CuO, BaO. Nu phng php tch ring tng cht ra khi hn hp vi iu kin khng lm thay i khi lng cc cht. Vit phng trnh phn ng xy ra (nu c). 2. C 4 dung dch khng mu b mt nhn: MgSO 4, NaOH, BaCl2, NaCl. Hy nu phng php ha hc nhn ra tng dung dch khi ch c dng thm axit HCl lm thuc th, vit phng trnh ha hc. Du hiu ta nhit trong phn ng trung ha khng c coi l du hiu nhn bit. Cu IV (3,5 im) 1. Nhng cht no sau y c dng lm kh v khng lm kh kh CO 2. Ti sao ? Vit phng trnh phn ng (nu c): P2O5, Fe3O4, H2SO4 (c), Na, CaO. 2. C 2 vt bn trn qun o: vt du nhn v vt du n. Hy chn trong s cc cht sau lm sch vt bn, gii thch: nc, nc x phng, gim n, t-xng, cn 90 o. 3. Dn hn hp kh gm: Hidro v CO ly d qua bnh ng cc oxit: Fe 2O3, Al2O3 v CuO nung nng. Kt thc phn ng thu c cht rn B v hn hp kh C. Ha tan cht rn B vo dung dch HCl thu c dung dch D, kh v rn khng tan. Dn kh C qua dung dch nc vi trong ly d thu c cht kt ta. Cho dung dch NaOH ly d vo dung dch D thu c kt ta c thnh phn mt cht duy nht. Vit cc phng trnh phn ng xy ra. Cu V (2,0 im) Trn a cn 2 cc ng dung dch HCl v H2SO4, cn v tr thng bng. Cho vo cc ng dung dch HCl 25 gam CaCO 3. Cho vo cc ng dung dch H2SO4 a gam Al cn vn v tr thng bng. Tnh a ? Cu VI (2,5 im)
H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

Ly m gam hn hp E gm Al v Cu chia lm 2 phn: - Phn 1 cho vo dung dch H2SO4 long, d thu c 2,688 lt kh. - Phn 2 (nhiu hn phn 1 l 14,16 gam) cho tc dng ht vi H 2SO4 c, nng, ly d thu c 14,336 lt kh. Tnh m v thnh phn phn trm khi lng mi kim loi c trong E. Bit cc phn ng xy ra hon ton v th tch cc kh u o iu kin tiu chun. Cu VII (2,0 im) t chy hon ton cht hu c Y ngi ta thu c 14,336 lt kh CO 2 (ktc) v 5,76 gam H2O. cng iu kin nhit v p sut th tng th tch CO 2 v hi nc thu c bng tng th tch ca Y v O2 tham gia phn ng. 1. Xc nh cng thc phn t ca Y. Bit Y mch h, vit cng thc cu to ca Y. 2. Khi Y tc dng vi dung dch nc Brom theo t l s mol 1:2 thu c cht hu c Z. Vit cng thc cu to c th c ca Z. Cho C = 12; O = 16; H = 1; Ca = 40; S = 32; Al = 27; Cu = 64; Fe = 56; Cl = 35,5. ---------- HT ----------

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V O TO QUNG NAM

K THI CHN HC SINH GII LP 9 THCS NM HC 2011-2012 Mn thi : HO HC

Thi gian : 150 pht (khng k thi gian giao ) Ngy thi : 03/4/2012

CHNH THC

Cu I.(3 im) 1.Cho cc kim loi Mg, Al, Fe ln lt tc dng vi cc dung dch HCl, NaOH, CuSO 4, AgNO3.Vit cc phng trnh phn ng xy ra (nu c). 2.C bn cht sau: KCl, H2O, MnO2, H2SO4 c .T nhng cht trn lm th no c th iu ch :HCl ; Cl 2 ; KClO3. Vit phng trnh phn ng dng. Cu II.(3 im) 1.Hon thnh cc phng trnh phn ng ca s sau. Ghi r iu kin ( nu c): ( 2) (3 ) ( 4) (5 ) (6) (7) (8 ) Saccaroz (1) glucoz ancol etylic axit axetic natriaxetat metan axetilen benzen nitrobenzen. 2.Mt trong nhng cch lm sch tp cht c ln trong nc ma dng sn xut ng phn theo phng php th cng trc y c thc hin bng cch cho bt than xng v mu b vo nc p ma. Sau khuy k un nh ri lc ly phn nc trong. Phn nc trong ny mt hn mu xm v mi ma. C cn nc lc th thu c ng phn. Hy gii thch vic s dng than xng v mu b trong cch lm ny? 3.Butan c ln tp cht l cc kh etilen, cacbonic, axetilen. Nu cch tin hnh v vit cc phng trnh phn ng xy ra trong qu trnh lm sch kh. Cu III.(4 im) 1.Cho 0,1g canxi tc dng vi 25,0cm 3 nc lnh nhit phng. Th tch kh hyro o c trong thi gian 4 pht, mi ln o cch nhau 30 giy. Kt qu thu c nh sau: Thi gian(gy) 0 30 60 90 120 150 180 210 240 Th tch(cm3) 0 20 32 42 50 56 59 60 60 a.Da vo bng s liu cho bit: tc phn ng thay i th no v sau bao nhiu giy phn ng kt thc. b.Tm th tch kh hyro thu c nhit phng v nng phn trm ca dung dch sau khi phn ng kt thc. Bit iu kin nhit phng 1,0 mol kh c th tch 24000cm3 v khi lng ring ca nc l 1,0g/cm3. 2.Cho 400 ml dung dch E gm AlCl 3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. Tm x,y. Cu IV.(3 im) 1.C cc cht lng A, B, C, D, E. Cht no l benzen, ancol etylic, axit axetic, dung dch glucoz, nc. Bit kt qu ca nhng th nghim nh sau: -Cho tc dng vi Na th A, B, C, D c kh bay ra; E khng phn ng - Cho tc dng vi CaCO3 th A, B, C, E khng phn ng; D c kh bay ra -Cho tc dng vi dung dch AgNO3/NH3 th A, C, D, E bc khng xut hin; B c bc xut hin -t trong khng kh th A, E chy d dng; D c chy ; B,C khng chy Xc nh A, B, C, D, E v vit cc phng trnh phn ng ho hc theo cc kt qu th nghim trn. 2.t chy hon ton m(g) cht hu c A ch thu c a(g) CO2 v b(g) H2O. Bit 3a = 11b v 7m = 3(a + b). Xc nh cng thc phn t (A), bit t khi hi ca (A) i vi khng kh : dA/KK < 3 . Cu V.(4 im) Cho V lt(ktc) kh CO i qua ng s ng 5,8g st oxit nung , mt thi gian thu c hn hp kh A v cht rn B. Cho B tc dng ht vi axit HNO3 long d thu c dung dch C v 0,784 lit (ktc) kh NO l sn phm kh duy nht. C cn dung dch C thu c 18,15g mui st III khan. Nu ho tan hon ton B bng axit HCl d thu c 0,672 lit kh (ktc)(xem qu trnh st tc dng vi mui st III v mui st II khng ng k). 1.Tm cng thc st oxit v phn trm khi lng cc cht trong B. 2.Tm V v phn trm th tch cc kh trong hn hp A, bit t khi ca A i vi hyro l 17,2. Cu VI.( 3 im) Mt hn hp kh (A) gm mt hirocacbon (X) mch h v H 2. Cho 17,6g hn hp (A) vo dung dch nc brom , sau khi phn ng hon ton thy dung dch brom nht mu v khi lng brom tham gia phn ng l 96,0g. Khi t chy hon ton 17,6g hn hp (A), dn sn phm chy vo nc vi trong th ton b sn phm chy b hp th ht v to c 20,0g kt ta. Lc b kt ta thy khi lng dung dch nc vi tng thm m(gam) so vi ban u. un si dung dch cn li to thm 50,0g kt ta na. 1.Tm cng thc phn t ca (X) v tnh thnh phn phn trm s mol hn hp (A). 2. Tnh m. H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

Ghi ch : Th sinh c php dng bng tun hon v my tnh b ti.

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V OTO QUNG NINH -------------------- THI CHNH THC

K THI CHN HC SINH GII CP TNH LP 9 THCS NM HC 2011-2012 MN HA HC 9 (BNG B) Ngy thi: 23/03/2012 Thi gian lm bi: 150 pht (Khng k thi gian giao ) ( thi ny c 01 trang)

H v tn, ch k ca gim th s 1

Cu 1 : (3,5 im) Cho s phn ng sau :

(1)
(2) (3 ) FeCl2 B A

(4)

Fe2O3 (5) D (6) C Bit A,B,C,D l cc hp cht khc nhau ca st v khng phi l FeCl 2, Fe2O3. Xc nh cng thc ha hc ca cc hp cht v vit cc phng trnh phn ng minh ha.
(7)

Fe

Cu 2: (5,0 im) 1/ Nhit phn hn hp gm BaCO3, MgCO3, Al2O3 c cht rn A v kh B. Ha tan A vo nc d c dung dch D v cht rn khng tan C. Cho t t n d dung dch HCl vo dung dch HCl vo dung dch D th xut hin kt ta, sau kt ta tan dn. Cht rn C tan mt phn trong dung dch NaOh d, phn cn li tan ht trong dung dch HCl d . Xc nh cc cht trong A,B,C,D v vit phng trnh ha hc xy ra. Bit cc phn ng xu ra hon ton. 2/ Bng phng php ha hc, hy phn bit 4 cht kh ng trong 4 bnh mt nhn sau: CO, CO 2, N2, SO2. Cu 3 (3,5 im) Hn hp X gm Fe, FeO, Fe 3O4 , Fe2O3 c s mol bng nhau. Ly 52 gam hn hp X cho vo dung dch HCl d thu c dung dch A. Cho dung dch NaOH n d vo dung dch A thu c kt ta B. Lc ly kt ta B nung ngoi khng kh n khi lng khng i c m gam cht rn C. Tm gi tr ca m. Bit cc phn ng xy ra hon ton. Cu 4: (3,5 im) Ha tan hon ton a gam oxit ca mt kim loi ha tr (II) trong 48 gam dung dch H 2SO4 long, nng 6,125% thu c dung dch A cha 2 cht tan trong H 2SO4 c nng 0,98%. Mt khc, n 2,8 lt cacsbon (II) oxit kh hon ton a gam oxit trn thnh kim loi thu c kh B duy nht. Nu ly 0,896 lt kh B cho vo dung dch Ca(OH)2 d thu c 0,8 gam kt ta. Tm gi tr ca a v xc nh cng thc ca oxit kim loi . Bit cc th tch kh u o iu kin tiu chun. Cu 5: (4,5 im) t chy hon ton 5,6 lt hn hp gm 2 hidrocacbon (t l th tch l 2:3) c cng s nguyn t cacbon trong phn t thu c 11,2 lt kh cacbonic v 11,2 gam nc. Xc nh cng thc phn t ca 2 hidrocacbon bit cc th tch kh u o iu kin tiu chun.

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V O TO PH TH

THI CHN HC SINH GII CP TNH LP 9 THCS NM HC 2011 2012 Mn: Ha hc Thi gian: 150 pht khng k thi gian giao ( thi c: 01 trang)

chnh thc

Cu I: (2,0 im) Cho ln lt tng cht: Fe, BaO, Al2O3, v KOH vo ln lt cc dung dch: NaHSO4, CuSO4. Hy vit PTHH ca cc phn ng xy ra. Cu II: (3,0 im) 1) C 1 hh gm 5 kim loi: Al, Mg; Fe, Cu, Ag. Hy dng PPHH tch ring tng kim loi vi khi lng khng i. Vit PTHH xy ra trong qu trnh tch. 2) Vit PTP trong mi trng hp sau a. Oxit + Axit 2 mui + oxit b. Mui + kim loi 2 mui c. Mui + baz 2 mui + 1oxit d. Mui + kim loi 1 mui Cu III: (3,0 im) 1) Trn V1 lit dd HCl 0,6M vi V2 lt dd NaOH 0,4M thu c 0,6 lit dd A. Tnh V 1, V2 bit 0,6 lt dd A c th ho tan ht 1,02 gam Al2O3 (coi s pha trn khng lm thay i th tch) 2) Sc t t a mol kh CO2 vo 800 ml dd X gm KOH 0,5M v Ca(OH) 2 0,2M. Tm gi tr ca a thu c khi lng kt ta ln nht. Cu IV: (10,0 im) 1) Ho tan cc cht gm Na2O, NaHCO3, BaCl2, NH4Cl c cng s mol vo nc d c dd A v kt ta B. Hi dd A v kt ta B cha nhng cht g? Vit PTHH ca cc phn ng minh ho. 2) Ho tan ht 3,2 gam oxit M2On trong lng va dd H2SO4 10%, thu c dd mui c nng 12,903%. Sau phn ng em c bt dd v lm lnh thu c 7,868 gam tinh th mui vi hiu sut 70%. Xc nh cng thc ca tinh th mui . 3) Cho x gam mt mui halogenua ca mt kim loi kim tc dng vi 200ml dd H 2SO4 c, nng va . Sau khi phn ng xy ra hon ton, thu c hn hp sn phm A trong c mt kh B (mi trng thi). Cho kh B tc dng vi dd Pb(NO 3)2 (d) thu c 47,8 gam kt ta mu en. Phn sn phm cn li, lm kh thu c 342,4 gam cht rn T. Nung T n khi lng khng i thu c 139,2 gam mui duy nht. a) Tnh nng mol/lit ca dd H2SO4 ban u. b) Xc nh cng thc phn t ca mui halogenua. c) Tnh x. Cu V: (2,0 im) C hn hp kh A gm metan, etilen v axetilen. - Cho 5,6 lt hn hp kh a li qua dd nc brm d th c 52 gam brm tham gia phn ng. - t chy hon ton 2,6 gam hn hp kh A th cn va 30,24 lt khng kh. Xc nh thnh phn trm theo th tch cc kh trong hn hp A, bit cc kh o iu kin tiu chun, trong khng kh oxi chim 20% v th tch cn li l ni t. (Cho NTK: H = 1 ; Li=7; C = 12 ; O = 16 ; F=19; Ca=40; Br=80; I=127; Ba=137; Pb=207; N=14; Na = 23 ; Al = 27 ; S = 32 ; K = 39 ; Cl = 35,5 ; Fe = 56 ; Cu = 64) Ht Cn b coi thi khng gii thch g thm.
H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

K THI CHN HSG LP 9 THCS NM HC 2011 -2012 THI MN: HO HC Thi gian lm bi: 150 pht, khng k thi gian giao . Cu 1 ( 2,0 im). Vit cc phng trnh phn ng theo s sau. 1500oC B A (kh ) CH3COOC2H5 E D C Lm lnh nhanh
CH3COONa
NaOH CaO

S GD & T VNH PHC CHNH THC

X (r n)

Y (kh )

Cu 2 (1,5 im). 1. C 5 dung dch khng c nhn v cng khng c mu: NaCl, HCl, NaOH, Na 2SO4 , H2SO4 . nhn ra tng dung dch, ngi ta a ra cc phng n sau: a/ Dng qu tm v dung dch AgNO3 . b/ Dng qu tm v dung dch BaCl2 . Phng n no ng ? Gii thch ? Vit phng trnh phn ng ? 2. i t cc cht ban u l vi, than v c dng thm cc cht v c cn thit, hy vit cc phng trnh phn ng iu ch ra polivinyl clorua, 1,2- icloetan. Cu 3 (1,5 im). Oxi ha m gam hp cht hu c A bng CuO ri cho sn phm sinh ra gm CO 2 v hi H2O ln lt i qua bnh 1 ng H 2SO4 c v bnh 2 ng 2 lt Ca(OH) 2 0,0225 M. Kt thc cc qu trnh ngi ta thy khi lng bnh 1 tng 1,08 gam, bnh 2 thu c 2 gam kt ta v khi lng CuO gim 3,2 gam. Xc nh cng thc phn t ca A bit MA < 100. Cu 4 (1,5 im) th hnh bn biu din tan S trong nc ca cht rn X. a/ Hy cho bit trong khong nhit t 00C n 700C c nhng khong nhit no ta thu c dung dch bo ha v n nh ca X? b/ Nu 130 gam dung dch bo ha X ang t0(0C) 700C h nhit xung cn 300C. Hi c bao nhiu gam X khan tch ra khi dung dch? Cu 5 (1,0 im). Hn hp kh A gm 2 hirocacbon. t chy hon ton 1 lt A trong kh oxi thu c 1,6 lt kh CO2 v 1,4 lt hi nc. Xc nh cng thc phn t cc hirocacbon c trong hn hp kh A, bit rng th tch cc kh v hi nc o cng iu kin nhit v p sut. Cu 6 (1,5 im). t chy hon ton a gam S ri cho sn phm sc qua 200 ml dung dch NaOH bM thu c dung dch X. Chia X lm hai phn bng nhau. Phn 1 cho tc dng vi dung dch CaCl 2 d thy xut hin c gam kt ta. Phn 2 tc dng vi dung dch nc vi trong d thy xut hin d gam kt ta. Bit d > c. Tm biu thc quan h gia a v b. Cu 7 (1,0 im). Mt hn hp X gm Na, Ca, Na2O v CaO. Ha tan ht 25,65 gam hn hp X vo nc thu c 2,8 lt H2 (ktc) v dung dch Y trong c 14 gam NaOH. Hp th hon ton 16,8 lt CO2(ktc) vo dung dch Y tnh khi lng kt ta thu c. Ht Cho: C = 12; H = 1; O = 16; Na = 23; Mg = 24; Ca = 40; Fe = 56; Br = 80; N = 14; Al = 27; Ba = 137; Cr = 52; Cu = 64; Ag = 108. H v tn th sinh:SBD:.. Cn b coi thi khng gii thch g thm!
H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

Th sinh khng c dng bt c ti liu no k c BTH cc nguyn t ha hc.

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC & O TO QUNG TR

K THI CHON HOC SINH GIOI TINH NM HC 2011 - 2012 MN: HOA HOC LP 9 THCS Thi gian: 150 pht (Khng k thi gian giao ) Kho ngy: 12/4/2012 thi c 01 trang, gm 05 cu

CHNH THC

Cu 1. (4,0 im) 1. Hn hp A gm CaCO3, Cu, FeO, Al. Nung nng A (trong iu kin khng c khng kh) mt thi gian thu ly cht rn B. Cho B vo nc d c dung dch C v cht rn D (khng thay i khi lng khi cho vo dung dch NaOH). Cho D tc dng vi dung dch H 2SO4 c nng, d. Xc nh B, D v vit cc phng trnh phn ng xy ra. 2. Ho tan hon ton 4 gam FexOy cn 52,14 ml dung dch HCl 10% (D = 1,05g/ml). Xc nh cng thc FexOy. 3. Mt hn hp gm Al2(SO4)3 v K2SO4, trong s nguyn t oxi chim 20/31 tng s nguyn t c trong hn hp. Tnh % theo khi lng mi mui trong hn hp. Cu 2. (4,0 im) 1. Vit cc phng trnh phn ng xy ra khi cho ln lt cc cht kh sau: SO 2, Cl2, NO2, H2S, CO2 tc dng vi dung dch Ca(OH)2 d. 2. Hn hp kh A gm a mol SO2 v 5a mol khng kh. Nung nng hn hp A vi V 2O5 xc tc thu c hn hp kh B. Bit rng t khi hi ca A so vi B bng 0,93. Hy tnh hiu sut phn ng gia SO2 v O2. Cho khng kh c cha 80% N2 v 20% O2 theo th tch. 3. Nh t t 3V1 lt dung dch Ba(OH)2 xM (dung dch X) vo V 1 lt dung dch Al2(SO4)3 yM (dung dch Y) th phn ng va v thu c kt ta ln nht l m gam. a) Tnh gi tr x/y. b) Nu trn V2 lt dung dch X vo V1 lt dung dch Y ( trn ) th kt ta thu c c khi lng bng 0,9m gam. Xc nh gi tr V2/V1. Cu 3. (4,0 im) 1. Kh hon ton 24 gam hn hp Fe2O3 v CuO nung nng bng lng CO d, ton b CO2 sinh ra cho hp th hon ton vo dung dch Ca(OH)2 d th thu c 40 gam kt ta. Vit cc phng trnh phn ng xy ra v tnh s mol mi oxit trong hn hp ban u. 2. Vit cc phng trnh phn ng chng minh: a) Tnh axit ca dung dch HCl mnh hn CH3COOH b) hot ng ca O3 mnh hn O2 c) Tnh baz ca dung dch Ba(OH)2 mnh hn NH3 d) hot ng ca Fe mnh hn Cu 3. Cho hn hp A gm 3 kim loi X, Y, Z c ha tr ln lt l III, II, I v t l s mol tng ng l 1:2:3, trong s mol ca X bng x mol. Ha tan hon ton A bng dung dch c cha y (gam) HNO 3 (ly d 25%). Sau phn ng thu c V lt kh NO 2 v NO (ktc, khng c sn phm kh khc). Da vo s phn ng chng minh rng: y = 1,25(10x + V/22,4)63. Cu 4. (4,0 im) 1. Ha tan hon ton 8,7 gam mt hn hp gm kali v mt kim loi M (thuc nhm IIA) trong dung dch HCl d, th thu c 5,6 dm 3 H2 (ktc). Nu ha tan hon ton 9 gam kim loi M trong dung dch HCl d, th th tch kh H2 sinh ra cha n 11 lt (ktc).Hy xc nh kim loi M. (Cho cc kim loi nhm IIA: Be=9, Mg=24, Ca=40, Sr=88, Ba=137) 2. T tinh bt, cc cht v c cn thit v cc iu kin c , hy vit cc phng trnh phn ng iu ch cc cht sau: etyl axetat, etilen, PVC. Cu 5. (4,0 im) Cho 76,2 gam hn hp A gm 1 ancol n chc (ROH) v 1 axit cacboxylic n chc (R /COOH). Chia A thnh 3 phn bng nhau. em phn 1 tc dng ht vi Na, thu c 5,6 lt H 2 (ktc). t chy ht phn 2 th thu c 39,6 gam CO2. em phn 3 thc hin phn ng este ha vi hiu sut 60%, sau phn ng thy c 2,16 gam nc sinh ra. Vit cc phng trnh phn ng xy ra, xc nh cng thc phn t, cng thc cu to ca cc cht trong A. Cho: H=1, O=16, C=12, N=14, Na=23, Mg=24, Al=27, S=32, Cl=35,5; Ca=40, Fe=56, Cu=64. (Th sinh khng c dng bng HTTH v bng Tnh tan)
H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

. HT .

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V OTO LO CAI

K THI CHN HC SINH GII CP TNH LP 9 THCS NM HC 2011-2012

Cu 1. (4,0 im) 1. Nung nng Cu trong khng kh mt thi gian c cht rn A. Ha tan A bng H 2SO4 c nng d c dung dch B v kh C. Kh C tc dng vi dung dch KOH thu c dung dch D. Dung dch D va tc dng vi dung dch BaCl2, va tc dng vi dung dch NaOH. Cho B tc dng vi dung dch KOH. Vit cc phng trnh ha hc xy ra. 2. T pirit st, nc bin, khng kh v cc thit b cn thit khc. Hy vit phng trnh ha hc iu ch cc cht: nc Javen, FeSO4, FeCl3. Cu 2. (4,0 im) 1. Bng phng php ha hc, hy nhn bit cc hn hp sau: (Fe + Fe 2O3), (Fe + FeO), (FeO + Fe2O3). 2. Nu hin tng xy ra trong mi trng hp sau v vit phng trnh ha hc xy ra: a. Cho kh CO2 li chm qua nc vi trong, sau thm tip nc vi trong vo dung dch thu c. b. Cho t t dung dch HCl vo dung dch Na2CO3. Cu 3. (4,0 im) 1. Tm cc cht k hiu bng ch ci trong s sau v hon thnh s bng phng trnh ha hc: 1500oC B A (kh ) CH3COOC2H5 E D C Lm lnh nhanh
CH3COONa
NaOH CaO

X (r n) Y (kh ) 2. T mt loi tinh du ngi ta tch ra c hp cht hu c A. t chy hon ton 2,64 gam A

cn va 4,704 lt kh oxi (ktc) ch thu c CO2 v H2O vi t l khi lng l

mCO2 mH2O

11 . Bit 2

M A < 150. Xc nh cng thc phn t ca A.

Cu 4. (3,0 im) 1. Ha tan 5,72 gam Na2CO3.xH2O trong 44,28 gam nc ta thu c dung dch c nng 4,24%. Xc nh cng thc ca hirat. 2. Kh 3,48 gam oxit mt kim loi M cn dng 1,344 lt H 2 (ktc). Ton b lng kim loi thu c cho tc dng vi dung dch HCl d thu c 1,008 lt H 2 (ktc). Xc nh kim loi M v oxit ca n. Cu 5. (2,0 im) Cho 87 gam dung dch ru etylic tc dng vi Na ly d th thu c 28 lt kh H2 (ktc). a. Tnh khi lng ca ru etylic v nc trong dung dch. b. Tnh ru ca dung dch ru trn (bit khi lng ring ca ru nguyn cht l 0,8 g/ml) Cu 6. (3,0 im) Cho 5,12 gam hn hp X gm 3 kim loi Mg, Fe v Cu dng bt tc dng vi 150 ml dung dch HCl 2M, sau khi phn ng kt thc thy ch thot ra 1,792 lt kh H 2 (ktc). em lc ra thu c 1,92 gam cht rn B. a. Tnh khi lng mi kim loi c trong hn hp X. b. Cho 2,56 gam hn hp X tc dng vi 250 ml dung dch AgNO 3 0,34M. Khuy k hn hp cho phn ng xy ra hon ton, thu c dung dch v cht rn E. Tnh khi lng ca cht rn E. -------------------- Ht -------------------Ch : - Th sinh c s dng bng tun hon cc nguyn t ha hc. - Cn b coi thi khng gii thch g thm.
H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC&O TO THI TUYN SINH LP 10 THPT CHUYN L QU N QUNG TR MN THI: HO HC

CHNH THC

Kho ngy: 07/7/2008 Thi gian lm bi: 150 pht (Khng k thi gian giao )

Cu I (2,0 im) 1. Hy vit cc phng trnh phn ng (c bn cht khc nhau) iu ch mui. 2. Ch dng thm mt cht, hy nhn bit 5 cht rn Al, FeO, BaO, ZnO, Al 4C3 ng trong cc l ring bit. Vit cc phng trnh phn ng xy ra. 3. Cho hai dung dch long FeCl2 v FeCl3 (gn nh khng mu). C th dng cht no sau y: dung dch NaOH; nc brom; Cu; hn hp dung dch (KMnO 4, H2SO4) nhn bit hai dung dch trn? Vit cc phng trnh phn ng xy ra. Cu II (2,5 im) 1.a.Vit cc cng thc cu to c th c ng vi cc cng thc phn t sau: C 5H10, C3H5Cl3. b. un nng glixerol vi hn hp hai axit C 15H31COOH v C17H35COOH (c H2SO4 m c lm cht xc tc) to thnh hn hp cc este. Hy vit cc cng thc cu to c th c ca cc este. 2. Vit cc phng trnh phn ng hon thnh s sau: A
+X, xt

men

C G

+ Y1

D H

+ Z1

E I

+ T1

F F

+ Y2

+ Z2

+ T2

Trong A l hp cht hu c; F l bari sunfat. 3. Ho tan hon ton hn hp X gm a mol Cu 2S ; 0,05 mol FeS2 trong HNO3 long, va u thu c dung dch Y(chi co mui sunfat) v kh NO. Cho dung dch Ba(OH) 2 d vo dung dch Y s thu c bao nhiu gam kt ta? Cu III (2,0 im) 1. Hy gii thch cc trng hp sau v vit cc phng trnh phn ng: a. Kh CO2 dng dp tt a s cc m chy, nhng khng dng dp tt m chy Mg. b. Trong phng th nghim ngi ta ng axit flohiric trong bnh bng nha hay thu tinh? V sao? 2. Khi nung hon ton cht A th thu c cht rn B mu trng v kh C khng mu. Cht B phn ng mnh lit vi nc to thnh dung dch D lm phenolphtalein. Kh C lm vn c dung dch D. Khi cho B tc dng vi cacbon nhit cao th thu c cht E v gii phng kh F. Cho E phn ng vi nc th thu c kh khng mu G. Kh G chy cho nc v kh C. Xc nh cc cht A, B, C, D, E, F, G v vit cc phng trnh phn ng xy ra. 3. Cho 2 bnh kn A, B c cng th tch v u 0 0C. Bnh A cha 1 mol kh clo; bnh B cha 1 mol kh oxi. Cho vo mi bnh 2,4 gam kim loi M c ho tr khng i. Nung nng cc bnh cc phn ng xy ra hon ton ri a v nhit ban u. Sau phn ng thy t l p sut kh trong 2 bnh A v B l rn khng ng k). Hy xc nh kim loi M. Cu IV(1,5 im) 1. Ho tan hon ton mt ming bc kim loi vo mt lng d dung dch HNO 3 15,75% thu c kh NO duy nht v a gam dung dch X; trong nng C% ca AgNO 3 bng nng C% ca HNO 3 d. Thm a gam dung dch HCl 1,46% vo dung dch X. Hy xc nh % AgNO3 tc dng vi HCl. 2. Dn H2 n d i qua 25,6 gam hn hp X gm Fe3O4, MgO, CuO nung nng cho n khi phn ng xy ra hon ton. Sau phn ng thu c 20,8 gam cht rn. Mt khc 0,15 mol hn hp X tc dng va vi 225ml dung dch HCl 2M. Hy vit cc phng trnh phn ng xy ra v tnh % s mol ca mi cht trong hn hp X. Cu V(2,0 im) t chy mt hirocacbon X th kh vi 0,96 gam kh oxi trong bnh kn ri cho cc sn phm sau phn ng ln lt qua bnh (1) cha CaCl2 khan d; bnh (2) cha 1,75 lt Ca(OH) 2 0,01M. Sau th nghim thy bnh (2) thu c 1,5 gam kt ta v cui cng cn 0,112 lt kh duy nht thot ra (o ktc). Xc nh cng thc phn t ca hirocacbon X. Bit cc phn ng xy ra hon ton. Cho C= 12, H=1, O= 16, Ca= 40, Cl=35,5; N= 14 ------------------------------HT-----------------------------H v tn th sinh..............S bo danh....
1,8 (th tch cc cht 1,9

Gim th 1: Gim th 2: .

S GIO DC V O TO TUYN QUANG

K THI TUYN SINH VO LP 10 THPT CHUYN NM HC 2011-2012

chnh thc
Cu 1(3,0 im)

Mn: HO HC Thi gian: 120 pht (khng k thi gian giao )

( ny gm 01 trang)

1. Vit cc phng trnh phn ng thc hin dy bin ha ha hc sau: FeFeCl2FeSO4 Fe2(SO4)3Fe(NO3)3Fe(NO3)2Fe(OH)2Fe(OH)3 Fe2O3 2. Ch c dng thm qu tm v cc ng nghim, hy ch r phng php nhn ra cc dung dch b mt nhn sau: NaHSO 4, Na2CO3, Na2SO3, BaCl2, Na2S. 3. C th tn ti ng thi trong dung dch cc cp cht sau y khng? Gii thch v vit phng trnh phn ng (nu c). a) CaCl2 v Na2CO3 ; b) NaOH v NH4Cl ; c) Na2SO4 v KCl; d) HCl v NaHSO3; e) NaOH v KNO3 Cu 2: (2,5 im) 1.T vi, than v cc cht v c cn thit, hy vit cc phng trnh phn ng iu ch benzen, cao su buna (ghi r iu kin phn ng nu c). 2. t hn hp gm cacbon v lu hunh trong kh oxi d, thu c hn hp kh A. Cho kh A li qua dung dch NaOH thu c dung dch B v kh C. Cho kh C qua hn hp cha CuO v MgO nung nng thu c cht rn D v kh E. Cho kh E li qua dung dch Ca(OH)2 thu c kt ta F v dung dch G. Thm dung dch KOH vo dung dch G li thy kt ta F xut hin, un nng G cng thy xut hin kt ta F. Hy xc nh thnh phn A, B, C, D, E, G, F v vit cc phng trnh phn ng xy ra. Cu 3: (2,5 im) Ho tan hon ton 5,94 gam Al vo dung dch NaOH d c kh th nht. Cho 1,896 gam KMnO4 tc dng ht vi axit HCl c, d c kh th hai. Nhit phn hon ton 12,25 gam KClO3 c xc tc, thu c kh th ba. Cho ton b lng cc kh iu ch trn vo mt bnh kn ri t chy cc phn ng xy ra hon ton. Sau lm lnh bnh cho hi nc ngng t ht v gi thit cc cht tan ht vo nc thu c dung dch E. Vit cc phng trnh phn ng v tnh nng C% ca dung dch E. Cu 4: (2,0 im) Hn hp A gm C2H2 v H2. Cho 10,08 lt A i qua ng ng cht xc tc Ni un nng, thu c 6,944 lt hn hp kh B gm 4 cht. Dn B i chm qua bnh ng nc brom d cho phn ng xy ra hon ton, thu c 4,48 lt hn hp kh C. Bit rng 1mol A c khi lng 10 gam v cc th tch kh u o iu kin tiu chun. Hy vit cc phng trnh phn xy ra v tnh thnh phn phn trm theo th tch ca cc kh trong hn hp A, B, C.
(Cho: H=1; O=16; C=12; S =32; Na=23, Cl=35,5; Ca =40; K=39; Mn=55; Al=27; Fe=56; Cu= 64;)

(Hc sinh c s dng bng HTTH v my tnh theo quy nh ca B GD&T)

Ht

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V O TO TUYN QUANG chnh thc

K THI TUYN SINH VO LP 10 THPT CHUYN NM HC 2010-2011 Mn: Ho hc Thi gian: 120 pht (khng k thi gian giao ) ( thi ny c 1 trang)

Cu 1:(3,0 im) 1. Vit cc phng trnh phn ng thc hin dy bin ha ha hc sau: FeS2 SO2 S SO2 H2SO4 CuSO4 CuS. 2. t chy hon ton 0,1 mol mt hidrocacbon, ri cho ton b sn phm chy hp th vo bnh ng lng d dung dch NaOH thy khi lng ca bnh NaOH tng thm 23 gam. Xc nh cng thc phn t ca hidrocacbon v vit cng thc cu to rt gn dng mch h c th c ca hidrocacbon trn. 3. Xc nh cng thc ha hc ca hp cht XH 3. Bit rng trong hp cht oxit ca X ha tr V c cha 56,34% oxi theo khi lng. Cu 2: (3,0 im) 1. T vi v cc thit b, ha cht cn thit hy vit cc phng trnh phn ng iu ch cc cht sau: cao su buna, polietilen, este etylaxetat (ghi r iu kin phn ng nu c). 2. C 6 dung dch sau ng ring bit trong cc l mt nhn: Ba(OH) 2, BaCl2 , NaCl, HCl, NH4HSO4, H2SO4. Ch dng thm mt thuc th, hy trnh by phng php ha hc nhn bit cc dung dch trn. Vit cc phng trnh phn ng xy ra. Cu 3: (2,0 im) Nhng mt thanh kim loi st v mt thanh kim loi km vo cng mt cc cha 800 ml dung dch CuSO4. Sau mt thi gian ly hai thanh kim loi ra khi cc th thy mi thanh kim loi u c mt lng Cu bm vo, khi lng dung dch trong cc gim mt lng l 0,75 gam. Trong dung dch sau phn ng, nng mol/l ca ZnSO4 gp hai ln nng mol/l ca FeSO4. Thm dung dch NaOH d vo cc, lc ly kt ta em nung ngoi khng kh n khi lng khng i, thu c 20 gam cht rn. 1. Tnh s gam Cu bm trn mi thanh kim loi. 2. Xc nh nng mol/l ca dung dch CuSO4 ban u. Cu 4: (2,0 im) Khi thc hin phn ng crackinh 35 lt butan nhit v p sut thch hp thu c 67 lt hn hp kh X theo 3 phn ng: C4H10 CH4 + C3H6 (1) C4H10 C2H6 + C2H4 (2) C4H10 H2 + C4H8 (3) Chia hn hp X lm 2 phn bng nhau Phn 1: Cho t t qua bnh ng nc brom d, cn li hn hp kh B khng b hp th. Tch hn hp kh B c 3 hidrocacbon B1, B2, B3 theo th t khi lng phn t tng dn. t chy B1, B2 , B3 thu c nhng sn phm c th tch CO2 t l tng ng l 1:3:1. Phn 2: Cho phn ng hp nc nh xc tc c bit thu c hn hp A gm cc ru khc nhau. 1. Tnh t l % th tch butan tham gia phn ng. 2. Tnh t l % th tch mi kh trong hn hp X. 3. Tnh khi lng ca hn hp A. (gi thit cc phn ng vi brom v hp nc xy ra hon ton, cc th tch kh o iu kin tiu chun). (Cho bit: H = 1; O = 16; C = 12; Na = 23; S=32.; Cu =64; Zn= 65, ) Ht
H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GD&T VNH PHC

K THI VO LP 10 THPT CHUYN NM HC 2009-2010

CHNH THC

THI MN: HO HC Dnh cho cc th sinh thi vo lp chuyn Ho Thi gian lm bi: 120 pht, khng k thi gian giao

( thi c 01 trang)

Cu 1.(2,5 im) 1. Mt hn hp X gm cc cht: K2O, KHCO3, NH4Cl, BaCl2 c s mol mi cht bng nhau. Ho tan hn hp X vo nc, ri un nh thu c kh Y, dung dch Z v kt ta M. Xc nh cc cht trong Y, Z, M v vit phng trnh phn ng minh ha. 2. Cho s bin ha :
A A A +X,t0 +Y,t0 +Z,t
0

Fe

+G

+E

Bit rng A + HCl D + G + H2O . Tm cc cht ng vi cc ch ci A, Bv vit cc phng trnh ha hc. Cu 2. (2,0 im) 1. Ha tan 3,38 gam oleum X vo lng nc d ta c dung dch A. trung ha
1 20

lng dung dch A cn dng 40 ml dung dch NaOH 0,1 M . Tm cng thc ca oleum. 2. Ch c dng thm 1 thuc th v cc ng nghim, hy trnh by phng php ha hc nhn ra cc dung dch b mt nhn NaHSO4, Na2CO3, NaCl, BaCl2, Na2S. Cu 3. (1,5 im) 1. Polime X cha 38,4% cacbon; 56,8% clo v cn li l hydro v khi lng. Xc nh cng thc phn t, vit cng thc cu to ca X v gi tn, cho bit trong thc t X dng lm g? 2. T metan v cc cht v c cn thit khc. Hy vit cc phng trnh phn ng ho hc (ghi r iu kin) iu ch X ni trn. Cu 4.(2 im) Cho 6,72 lt hn hp kh gm mt ankan v mt olefin i qua dung dch Brom thy khi lng bnh Brom tng 4,2 gam v thot ra 4,48 lt kh. t chy kh thot ra thu c 8,96 lt kh CO2. Xc nh cng thc phn t ca cc hirocacbon, bit th tch cc kh o ktc. Cu 5. (2 im) Ha tan hon ton 9,18 gam Al nguyn cht cn V lt dung dch axit HNO3, nng 0,25M, thu c mt kh X v mt dung dch mui Y. Bit trong X s nguyn t ca nguyn t c s thay i s oxiha l 0,3612.10 23 (s Avogadro l 6,02.1023). phn ng hon ton vi dung dch Y to ra mt dung dch trong sut cn 290 gam dung dch NaOH 20%. 1. Xc nh kh X v vit cc phng trnh phn ng xy ra? 2. Tnh V? ---------------------------------Ht-----------------------------(cn b coi thi khng gii thch g thm)
H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC & O TO THA THIN HU CHNH THC

K THI TUYN SINH VO LP 10 THPT QUC HC KHA NGY 19.06.2006

MN: HO HC (Chuyn) (Thi gian lm bi: 150 pht )

S bo danh: .........Phng: ...... Cu 1: (2 im) a. T tinh bt v cc cht v c cn thit khc, hy vit cc phng trnh phn ng ha hc iu ch: Etyl axetat, ibrometan. b. t chy 2,7gam hp cht A cha C,H,O cn dng ht 3,696 lt oxi (ktc), thu c CO 2 v H2O =CO hi nc theo t l V :V 5 :2 4. Tm cng thc phn t ca A. Bit t khi hi ca A so vi N2 l 3,215. Cu 2: (1,5 im) C 3 l b mt nhn cha cc dung dch: - L X gm K2CO3 v NaHCO3 - L Y gm KHCO3 v Na2SO4 - L Z gm Na2CO3 v K2SO4 Ch c dng dung dch BaCl2 v dung dch HCl. Nu cch nhn bit cc l v vit cc phng trnh phn ng ha hc minh ha. Cu 3: (2,25 im) 1. C 2 dung dch H2SO4 v NaOH. Bit rng 20ml dung dch H2SO4 tc dng va vi 60ml dung dch NaOH. Mt khc cho 20ml dung dch H 2SO4 trn tc dng vi 5,91gam BaCO 3, trung ha lng H2SO4 d sau phn ng ta cn 10ml dung dch NaOH ni trn. Tnh nng mol/l ca hai dung dch . 2. Ha tan mt mui cacbonat kim loi M bng mt lng va dung dch H 2SO4 9,8% ta thu c dung dch mui c C% = 14,18%. Xc nh cng thc mui cacbonat . Cu 4: (2 im) t chy hon ton 2,24 lt mt hydrocacbon A th kh (ktc). Sn phm chy thu c sau phn ng cho qua bnh ng 400 ml dung dch Ca(OH) 2 0,5M thy khi lng bnh tng 18,6 gam v c 10 gam kt ta. Xc nh cng thc phn t, cng thc cu to c th c ca A. Cu 5: (2,25 im) 1 Hn hp X gm CaCO3, MgCO3 v Al2O3, trong khi lng ca Al2O3 bng 10 khi lng cc mui cacbonat. Nung X nhit cao n khi lng khng i thu c cht rn Y c khi lng bng 56,80% khi lng hn hp X. a. Tnh phn trm khi lng mi cht trong X. b. Ha tan cht rn thu c sau khi nung 22,44 gam X trn bng dung dch HCl 1,6M. Hy xc nh th tch dung dch HCl dng. Cho: Al = 27 ; Mg = 24; Ca = 40 ; Ba = 137 O = 16 ; Cl = 35,5 ; S = 32 ; C = 12 ; H = 1 . Ht Gim th coi thi khng gii thch g thm

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S gio dc v o to chnh thc thi gm c: 02 trang

K thi vo lp 10 THPT CHUYN LAM SN nm hc: 2010 2011

(Dnh cho th sinh thi vo lp chuyn Ha)

Thi gian lm bi: 120 pht (khng k thi gian giao ) Ngy thi: 20 thng 6 nm 2010

Mn: Ha hc

Cu I: (3,0 im) 1. Cho ln lt tng cht: Fe, BaO, Al2O3 v KOH vo ln lt cc dung dch: NaHSO4, CuSO4. Hy vit cc phng trnh phn ng xy ra. 2. Mt hn hp gm Al, Fe, Cu v Ag. Bng phng php ho hc hy tch ri hon ton cc kim loi ra khi hn hp trn. 3. C 5 l mt nhn ng 5 dung dch: NaOH, KCl, MgCl 2, CuCl2, AlCl3. Hy nhn bit tng dung dch trn m khng dng thm ho cht khc. Vit cc phng trnh phn ng xy ra. Cu II: (2,0 im) 1. Hirocacbon X l cht kh ( nhit phng, 250C). Nhit phn hon ton X (trong iu kin khng c oxi) thu c sn phm C v H 2, trong th tch kh H2 thu c gp i th tch kh X (o cng iu kin). Xc nh cc cng thc phn t tha mn X. 2. Ba cht hu c mch h A, B, C c cng thc phn t tng ng l: C 3H6O, C3H4O2, C6H8O2. Chng c nhng tnh cht sau: - Ch A v B tc dng vi Na gii phng kh H2. - Ch B v C tc dng c vi dung dch NaOH. - A tc dng vi B (trong iu kin xc tc, nhit thch hp) thu c sn phm l cht C. Hy cho bit cng thc cu to ca A, B, C. Vit cc phng trnh phn ng xy ra. 3. Metan b ln mt t tp cht l CO2, C2H4, C2H2. Trnh by phng php ho hc loi ht tp cht khi metan. Cu III: (3,0 im) 1. Ha tan hon ton 0,297 gam hn hp Natri v mt kim loi thuc nhm II A trong bng tun hon cc nguyn t ha hc vo nc. Ta c dung dch X v 56 ml kh Y (ktc). Xc nh kim loi thuc nhm IIA v khi lng ca mi kim loi trong hn hp. 2. Hn hp X gm ba kim loi Al, Fe, Cu.

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

Cho m gam hn hp X vo dung dch CuSO 4 (d) sau khi phn ng xy ra hon ton thu c 35,2 gam kim loi. Nu cng ha tan m gam hn hp X vo 500 ml dung dch HCl 2M n khi phn ng xy ra hon ton thu c 8,96 lt kh H2 (ktc), dung dch Y v a gam cht rn. a. Vit cc phng trnh phn ng xy ra v tm gi tr ca a. b. Cho t t dung dch NaOH 2M vo dung dch Y v khuy u n khi thy bt u xut hin kt ta th dng ht V 1 lt dung dch NaOH 2M, tip tc cho tip dung dch NaOH vo n khi lng kt ta khng c s thay i na th lng dung dch NaOH 2M dng ht 600 ml. Tm cc gi tr m v V1. Cu IV: (2,0 im) 1. T tinh bt, cc ha cht v c v iu kin cn thit khc c . Vit phng trnh ha hc iu ch Etyl axetat ( ghi r iu kin nu c). 2. C a gam hn hp X gm mt axit no n chc A v mt este B. B to ra bi mt axit no n chc A1 v mt ru no n chc C (A1 l ng ng k tip ca A). Cho a gam hn hp X tc dng vi lng va NaHCO 3, thu c 1,92 gam mui. Nu cho a gam hn hp X tc dng vi mt lng va NaOH un nng thu c 4,38 gam hn hp hai mui ca 2 axit A, A1 v 1,38 gam ru C, t khi hi ca C so vi hiro l 23. t chy hon ton 4,38 gam hn hp hai mui ca A, A1 bng mt lng oxi d th thu c Na2CO3, hi nc v 2,128 lit CO2 (ktc). Gi thit phn ng xy ra hon ton. a. Tm cng thc phn t, cng thc cu to ca A, A1, C, B. b. Tnh a.
--------------------Ht-----------------Cho bit: H = 1, C = 12, O = 16, S = 32, Na = 23, Fe = 56; Cu = 64; Ca = 40; N = 14; Mg = 24; Al = 27; K = 39; Ca = 40; Cu = 64; Zn = 65; As = 75 ; Br = 80; Rb = 85,5; Ag = 108; Sr = 87,6; Ba = 137

( Gim th khng gii thch g thm, th sinh khng c s dng Bng tun hon )

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

B GIO DC V O TO TRNG I HC S PHM H NI

CNG HA X HI CH NGHA VIT NAM

c lp T do Hnh phc
CHNH THC

THI TUYN SINH VO TRNG TRUNG HC PH THNG CHUYN NM 2010 Mn thi: HA HC (dng cho th sinh thi vo chuyn Ha) Thi gian lm bi : 120 pht
Cu 1. 1. Hy nu hin tng, vit phng trnh phn ng xy ra khi ln lt cho kim loi Ba ti d vo cc dung dch sau: a. CuSO4. b. NaHCO3. c. (NH4)2SO4. d. Al(NO3)3. 2. T vi, mui n, nc v cc iu kin cn thit, hy iu ch: a. Na2CO3. b. NaHCO3. c. CaCl2. d. Nc Gia-ven. Cu 2. 1. Hy nhn bit cc dung dch v cht lng ng trong cc l mt nhn: dung dch Glucoz, cn 100o, dung dch axit axetic, lng trng trng, benzen. 2. Bit axit Lactic c cng thc: CH 3-CH(OH)-COOH. Hy vit phng trnh phn ng xy ra khi cho axit Lactic ln lt tc dng vi cc cht: a. Na d. b. C2H5OH (H2SO4c, un nng nh). c. Dung dch Ba(OH)2. d. Dung dch KHCO3. Cu 3. 1. C mt hn hp rn gm: Al, Fe2O3, Cu, Al2O3. Hy trnh by s tch cc cht trn ra khi nhau m khng lm thay i lng ca mi cht. Vit cc phng trnh phn ng xy ra. 2. Cho cc phn ng : A + 2NaOH 2B + H2O B + HCl D + NaCl H 2 SO4 CH2(OH)COOC2H5 + D + C2H5OH H2O
to

Hy xc nh cng thc cu to ca cc cht A, B, D. Bit A c cng thc phn t l C4H6O5. Cu 4. 1. Ha tan hon ton hn hp X gm Fe v Zn bng mt lng va dung dch H 2SO4 10%, thu c dung dch Y v 22,4 lt H 2 (ktc). Nng ca ZnSO4 trong dung dch Y l 11,6022%. Tnh khi lng ca mi kim loi trong hn hp X. 2. Cho 5,53 gam mt mui hirocacbonat A vo dung dch H 2SO4 long va , sau khi phn ng xy ra hon ton thu c 4,62 gam mui sunphat trung ho. Cho 15,8 gam A vo dung dch HNO 3 va , ri c cn t t dung dch sau phn ng th thu c 37,6 gam mui B. Xc nh cng thc phn t ca B. Cu 5. 1. Thng thng trong cht bo c ln mt lng nh axit bo t do. Bit rng ch s axit ca cht bo l s mg KOH cn thit trung ho axit bo t do c trong 1 gam cht bo. a. Mun trung ho 1,12 kg mt loi cht bo c ch s axit l 6 th cn bao nhiu lt dung dch NaOH 0,2M ? b. x phng ha hon ton 210 kg mt loi cht bo c ch s axit l 8 cn 10,32 kg NaOH . Tnh khi lng x phng thu c? Bit mui ca cc axit bo chim 50% khi lng ca x phng. 2. Cho 32,8 gam hn hp A gm 2 cht hu c X, Y tc dng va vi 0,2 lt dung dch NaOH 1M thu c hn hp 2 ru R1OH, R2OH v 18,8 gam mt mui RCOONa (trong R, R1, R2 ch cha cacbon, hiro v R2 = R1 + 14). Cho ton b 2 ru tc dng vi Na d thu c 6,72 lt H 2 (ktc). Xc nh cng thc cu to ca 2 cht X, Y. Cho: H=1;C=12;O=16;N=14 ; Na=23; Al=27; Si=28 ; S=32; Cl=35,5; K= 39; Cu=64; Zn=65, Fe=56. ..............................................Ht............................................ Ghi ch: Cn b coi thi khng gii thch g thm.
H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

I HC QUC GIA H NI THI TUYN SINH LP 10 TRNG I HC KHOA HC T H THPT CHUYN NM 2008 NHIN MN: HO HC Thi gian lm bi: 150 pht (khng k thi gian pht ) Cu I (1,5 im). 1.C 4 cht kh A, B, C, D. Kh A to nn khi nung nng KMnO 4, kh B bay ra cc m, kh C bay ra cc dng khi in phn dung dch NaCl c mng ngn. Kh D l cht hu c c t khi so vi H2 l 8. Cho bit A, B, C, D l nhng kh g ? Nhng kh no phn ng vi nhau tng i mt ? Vit cc phng trnh phn ng . 2.T cc nguyn liu chnh gm: qung apatit Ca5F(PO4)3, st firit FeS2, khng kh v nc. Hy vit cc phng trnh phn ng iu ch: a) Superphotphat n b) Superphotphat kp Cu II (1,0 im). 1.C hai aminoaxit E v F cng cng thc phn t C 3H7NO2, dng cng thc cu to ca chng vit phng trnh phn ng gia mt phn t E v mt phn t F to ra sn phm mch h. 2.Cho A v B l 2 hp cht hu c n chc (cha C, H, O) u c khi lng mol l 74. A phn ng c vi c Na v NaOH, cn B phn ng vi dung dch NaOH to ra mui c khi lng mol nh hn 74. Hy vit cng thc cu to ng ca A, B v vit cc phng trnh phn ng minh ho. Cu III (2,0 im). Cho 23,22 gam hn hp G gm Cu, Fe, Zn, Al vo cc cha dung dch NaOH d thy cn li 7,52 gam cht rn khng tan v thu c 7,84 lt kh (ktc). Lc ly phn cht rn khng tan ri ho tan ri ho tan ht n vo lng d dung dch HNO3 long, cc phn ng u to ra kh NO, tng th tch NO l 2,688 lt (ktc). Gi thit cc phn ng u t hiu sut 100%, xc nh %m ca mi kim loi trong hn hp G. Cu IV (2,0 im). Chia 156,8 gam hn hp L gm FeO, Fe 3O4, Fe2O3 thnh hai phn tht u nhau. Cho phn th nht tc dng ht vi dung dch HCl d c 155,4 gam mui khan. Phn th hai tc dng va ht vi 500 ml dung dch M l hn hp HCl, H2SO4 long thu c 167,9 gam mui khan. Vit cc phng trnh phn ng xy ra, xc nh %m ca Fe trong L v CM ca dung dch M. Cu V (2,0 im). Hai cht hu c X, Y to nn bi cc nguyn t C, H, O. Trong C chim 40% khi lng mi cht, khi lng mol ca X gp 1,5 ln khi lng mol ca Y. Khi t chy hon ton 0,03 mol hn hp X, Y cn dng va ht 1,68 lt O2 (ktc). Cho 1,2 gam Y tc dng ht vi dung dch NaOH thu c m gam mui khan. Cho 1,8 gam X tc dng ht vi dung dch NaOH thu c 1,647m gam mui khan. Tm cng thc n gin nht, cng thc phn t v cng thc cu to c th c ca X, Y. Cu VI (1,5 im). Hai este P v Q c khi lng mol hn km nhau 28 gam, ph t mi cht u cha C, H v 2 nguyn t O. Cho 32,4 gam hn hp Z gm P v Q tc dng vi dung dch NaOH va , sau c cn dung dch th thu c 32,8 gam cht rn khan. Phn bay hi gm nc v hai ru, trong phn hi ca hai ru chim th tch bng th tch ca 11,2 gam kh N2 o cng iu kin. Khi t chy hon ton mt lng mol nh nhau ca hai ru th s mol CO2 to ra t cc ru hn km nhau 3 ln. Xc nh cng thc cu to cc este v thnh phn %m ca mi cht trong hn hp Z.

Cho bit: H = 1 C = 12 N= 14 O =16 S=32 Cl=35,5 Na= 23 Al=27 Fe=56 Cu = 64 Zn = 65

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

Cn b coi thi khng gii thch g thm

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .

S GIO DC V O TO TNH PH YN CHNH THC

THI TUYN SINH TRUNG HC PH THNG CHUYN NM HC 2008-2009 Mn thi: HA HC Thi gian: 150 pht (khng k thi gian pht )

CU 1:(3,0 im) Cho s bin ho : +X A 1 to Fe(OH)3 B1 +Z

A2 B2

+Y +T

A3 B3

Fe(OH)3

Tm cng thc cc cht A1, A2, A3, B1, B2, B3, X, Y, Z, T . Vit cc phng trnh phn ng . CU 2:(2,5 im) C 5 dung dch: HCl ; NaOH; Na2CO3; BaCl2; NaCl. Cho php dng qu tm hy trnh by cch nhn bit cc dung dch trn, bit rng dung dch Na2CO3 cng lm qu tm ho xanh. CU 3:(2,5 im) Vit phng trnh phn ng xy ra (nu c) khi cho cc cht Al, Fe 3O4, Al2O3 ln lt tc dng vi cc dung dch H2SO4 long, dung dch KOH . CU 4:(2,0 im) t chy hon ton V (lt) m tan (ktc). Cho tt c sn phm chy hp th vo bnh ng 500ml dung dch Ba(OH)2 0,2 M thy to thnh 15,76 gam kt ta . a) Tnh th tch V. b) Khi lng dung dch trong bnh tng hay gim bao nhiu gam? CU 5:(2,0 im) Ho tan ht 4 gam mt kim loi M vo 96,2 gam nc thu c dung dch baz c nng 7,4% v V lt kh (ktc).Xc nh kim loi M. CU 6:(2,0 im) Cho 23,8 gam hn hp X (Cu, Fe, Al) tc dng va 14,56 lt kh Cl 2 ( ktc). Mt khc c 0,25 Mol hn hp tc dng vi dung dch HCl d thu c 0,2 Mol kh ( ktc). Tnh phn trm khi lng mi kim loi trong hn hp X. CU7:(2,0 im) Chia 39,6 gam hn hp ru etylic v ru A c cng thc C nH2n(OH)2 thnh hai phn bng nhau. Ly phn th nht tc dng ht vi Na thu c 5,6 lt H 2 (ktc). t chy ht hon ton phn th hai thu c 17,92 lt CO2 ( ktc). Tm cng thc phn t ru A. CU 8:(2,0 im) Ho tan 4 gam hn hp Fe v mt kim loi ho tr 2 vo dung dch HCl d thu c 2,24 lt kh H2 (ktc). Nu ch dng 2,4 gam kim loi ho tr 2 cho vo dung dch HCl th dng khng ht 500ml dung dch HCl 1M. Tm kim loi ho tr 2 . CU 9:(2,0im) t chy hon ton 0,324 gam hp cht hu c X (C, H, O )sn phm chy dn qua bnh cha 380 ml dung dch Ba (OH)2 0,05 M ta thy kt ta b tan mt phn ng thi khi lng bnh tng 1,14 gam. Cn nu sn phm chy dn qua 220 ml dung dch Ba(OH)2 0,1M th thu kt ta cc i. Tm cng thc phn t ca X, bit MX = 108 . Cho : C = 12, Ba = 137, H = 1, Fe = 56, Cl = 35.5 , Al = 27, Cu = 64 ----------HT---------Th sinh c s dng Bng h thng tun hon khi lm bi.

H v tn th sinh..............S bo danh....

Gim th 1: Gim th 2: .