Trng THPT Hong Vn Th-V Bn-Nam nh

Bi tp V HNO3 v mui NO3-

Dng1: Tnh khi lng kim loi lng axit v lng sn phm kh to thnh
Cu1: Ha tan ht m(g) Al trong dd HNO3, thu c hn hp kh (ktc) gm NO v NO2 c th tch l 8.96 lit v c t khi i vi hir l 16.75. gi tr ca m l: A. 9.1125 B. 2.7g C. 8.1g D. 9.225g Cu2: Cho 11g hn hp Al v Fe vo dd HNO3 long d, th c 6.72lit (ktc) kh NO bay ra. Khi lng cc kim loi Al v Fe trong hn hp u ln lt l: A.2.7g, 11.2g B.5.4g, 5.6g C. 0.54g, 0.56g D. kt qu khc Cu3: Ha tan hon ton 12g hn hp Fe v Cu( t l mol 1:1) bng axit HNO3, thu c V lit( ktc) hn hp kh X (gm NO v NO2), v dd Y( ch cha 2 mui v axit d). t khi ca X i vi H2 bng 19. Gi tr ca V(lit) l: A. 2.24 B.5.6 C.3.36 D.4.48 Cu4: Cho m(g) Al tan hon ton trong dd HNO3 thy to ra 11.2lit(ktc) hn hp 3 kh NO, N2O, N2 vi t l mol tng ng l 1:2:2. Gi tr ca m l: A. 16.47g B. 23g C. 35.1g D. 12.73g Cu5: Cho 0.28mol Al vo dd HNO3 d thu c kh NO v dd cha 62.04g mui. S mol kh NO thu c l: A. 0.2 B. 0.28 C. 0.1 D. 0.14 Cu6: Cho m(g) Al tc dng va vi dd HNO3 to ra hn hp kh A gm 0.15mol NO v 0.05mol N2O. Gi tr ca m l: A. 7.76g B. 7.65g C. 7.85g D. 8.85 Cu7: Cho 18.5g hn hp Fe v Fe3O4 vo 200ml dd HNO3 un nng, khuy k thu c 2.24lit kh NO(ktc), dd Y v 1.46g kim loi . Nng HNO3 dng l: A. 1.2M B. 2.4M C. 3.2M D. 2M Cu8: Cho 0.9mol Cu vo 400ml dd H2SO4 1M v NaNO3 1M. S mol kh NO thu oc l: A. 0.2 B. 0.4 C. 0.6 D. 0.8 Cu9: Ha tan 5g Cu trong 100ml dd cha ng thi 2 axit HNO3 1M v H2SO4 0.5M th gii phng kh NO duy nht. Th tch kh o ktc bng: A. 0.56lit B. 1.12lit C. 1.17lit D. 2.24lit Cu10: Mt hn hp bt gm 2 kim loi Mg v Al c chia thnh 2 phn bng nhau Phn1: cho tc dng vi dd HCl d thu c 3.36 lit kh H2 Phn2: ha tan ht trong dd HNO3 long d thu c mt kh khng mu ha nu trong khng kh ( th tch cc kh o ktc). Gi tr ca V l: A. 2.24lit B. 3.36lit C. 4.48lit D. 5.6lit Cu11: Cho ag Al tc dng va vi dd HNO3 long, thu c dd A v 0.1792lit hn hp kh X gm N2 v NO c dX/H2 = 14.25. Tnh a Cu12: Cho 28g hhA gm Cu v Ag vo dd HNO3 c, d, sau p kt thc thu c ddB v 10 lit NO2 ( 0 0C; 0,896atm). Xc nh % khi lng mi KL trong hh u Cu13: Ho tan hon ton 9.41g hh 2Kl Al v Zn vo 530ml dd HNO3 2M, sau p thu c dd A v 2,464lit hh kh gm N2O v NO(ktc) c khi lng bng 4,28g. a) Tnh % khi lng mi KL trong hh u b) Tnh Vdd HNO3 tham gia p. Cu14 : Cho 1,86 g hn hp Mg v Al vo dung dch HNO3 long d sau phn ng thu c 560 ml N2O ( ktc) l sn phm kh duy nht . Tnh % v khi lng ca mi kim loi trong hn hp ban u. Cu15: Cho 3,84 gam Cu tc dng vi 80 ml dung dch hn hp gm HNO3 1M v HCl 1M s thu c ti a bao nhiu lit NO (ktc) 1

Trng THPT Hong Vn Th-V Bn-Nam nh Bi tp V HNO3 v mui NO3Cu16: cho 7,68 gam Cu vo 120 ml dung dch hn hp gm HNO3 1M v H2SO4 1M, sau khi phn ng hon ton thu c bao nhiu lt NO (ktc) l spk duy nht. C cn dung dch thu c bao nhiu gam mui khan. Cu17: Cho 1,92 gam Cu vo 100 ml dung dch cha KNO3 0,16M v H2SO4 0,4M thy sinh ra mt cht kh c t khi so vi H2 l 15 v dung dch A a) Tnh th tch kh sinh ra ktc b) Tnh th tch dung dch NaOH 0,5M ti thiu cn cho vo dung dch A kt ta ton b ion Cu2+ c trong dung dch A Cu18: cho m gam st tc dng vi dung dch HNO3 sau phn ng thu c dung dch Y; 0,1mol NO (spk duy nht ) v 2 gam kim loi. Tnh m Cu19: ho tan hon ton 0,368 gam hn hp nhm v km cn va 2,5 lit dung dch HNO3 0,01M th khng thy c kh thot ln, sau phn ng ta thu c 3 mui. Tnh % v khi lng ca mi kim loi c trong hn hp. Cu20: Cho 4,86g Al tan va trong 660ml dung dch HNO3 1M thu c V lt hn hp kh(ktc) gm N2 v N2O. Tnh V? A. 0,112lt B. 0,448lt C. 1,344lt D. 1,568lt Cu21: Cho 13,5g hn hp gm Al v Ag tan trong HNO3 d thu c dung dch A v 4,48 lt hn hp kh gm (NO,NO2) c khi lng 7,6gam. Tnh % khi lng mi kim loi. A. 30 v 70 B. 44 v 56 C. 20 v 80 D. 60 v 40

Dng2: Xc nh tn kim loi

Cu22: Cu23: Ho tan hton 62.1g kim loi M bng dd HNO3 long sau p thu c 16.3lit hh kh X gm 2kh khng mu, khng ho nu trong kk(kc).(dX/H2O=17.2) Xc nh M. Cu24: Ho tan hon ton 1,35 gam mt kim loi M bng dung dch HNO3 d un nng thu c 2,24 lit NO v NO2 (ktc) c t khi so vi H2 bng 21 ( khng cn sn phm kh khc). Tm kim loi M Cu25: Ha tan 13g mt kim loi c ha tr khng i vo HNO3. Sau phn ng thm vo NaOH d thy bay ra 1,12 lt kh c mi khai. Xc nh kim loi dng? Cu 26: Cu 27: Ha tan hon ton 2,7g mt kim loi M bng HNO3 thu c 1,12lt kh(ktc) hn hp X gm X 2 kh khng mu trong c 1 kh ha nu ngoi khng kh. Bit d H 2 =19,2. M l? A. Fe B. Al C. Cu D.Zn Cu 28: Cu 29: Cu30: Ho tan 16.2 g mt kloi cha r ho tr bng HNO3 long, d, sau p thu c 4.48 lit hn hp kh X gm N2 v NO2 (ktc), dX/H2=18. Xc nh kim loi. Bit rng sau p khng c mui NH4NO3

Dng3: Tm sn phm kh
Cu31: Cu 32: Cho 3,6 gam Mg tc dng ht vi dung dch HNO 3 (d), sinh ra 2,24 lt kh X (sn phm kh 2

Trng THPT Hong Vn Th-V Bn-Nam nh duy nht, ktc). Xc nh kh X. Cu 33: Cu 34:

Bi tp V HNO3 v mui NO3-

Cu35: Ho tan 0.2 mol Fe v 0.3 mol Mg vo HNO3 d thu c 0.4mol mt sn phm kh cha N duy nht. Xc nh spk.

Dng4: Tnh khi lng mui NO3Cu36: Ha tan hon ton 15.9g hn hp 3 kim loi Al, Mg, Cu bng dd HNO3 thu c 6.72 lit kh NO v dd X. em c cn dd X th thu c khi lng mui khan l: A. 77.1g B. 71.7g C. 17.7g D. 53.1 Cu37: Ho tan hton 8.3g hh 2 kim loi A, B( ho tr III) trong dd HNO3, thu c 4,48l NO(ktc). a> Tnh m mui khan thu c b> Tm A, B S : a. 45,5 b. Al,Fe Cu38: Cho 8,4 gam Fe tc dng vi 400ml dung dch HNO3 1M , sau phn ng thu c dung dch X v sn phm kh duy nht l NO. C cn dung dch X th thu c bao nhiu gam mui khan. Cu39: cho 11,2 gam Fe vo 1lit dung dch HNO3 0,6M thu c dung dch X v NO l spk duy nht . sau phn ng c cn dung dch X th thu c bao nhiu gam mui khan. Cu40: cho 25,6 gam Cu vo dung dch HNO3 sau phn ng thu c hn hp X v 4,48lt (ktc) kh NO duy nht . Cho tip 100ml dung dch HCl 0,8 M vo X th c thu c kh na khng, bao nhiu lit(ktc) Cu41: Cho 2,16 gam Mg tc dng vi dung dch HNO 3 (d). Sau khi phn ng xy ra hon ton thu c 0,896 lt kh NO ( ktc) v dung dch X. Tnh khi lng mui khan thu c khi lm bay hi dung dch X. Cu42: Khi cho 1,92g hn hp X gm Mg v Fe c t l mol 1:3 tc dng hon ton vi HNO3 to ra hn hp kh gm NO v NO2 c th tch 1,736 lt (ktc). Tnh khi lng mui to thnh v s mol HNO3 phn ng. A. 8,074gam v 0,018mol B. 8,4gam v 0,8mol C. 8,7gam v 0,1mol D. 8,74gam v 0,1875mol

Dng5: Tnh lng HNO3 phn ng

Cu43: Cho 8,32 gam Cu tc dng va vi 120 ml dung dch HNO3 sau phn ng thu c 4,928 lit (ktc) hn hp NO v NO2 . tnh nng mol ca dung dch HNO3 ban u. Cu44: Ho tan hon ton m gam hn hp 2 kim loi X, Y (c ho tr duy nht) trong dung dch axit HNO3 thu c hn hp kh B gm 0,03 mol NO2 v 0,02 mol NO. S mol HNO3 tham gia phn ng Cu45: ho tan ht 0,06 mol Fe th cn s mol HNO3 ti thiu l (sn phm kh duy nht l NO): Cu46: Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H2SO4 0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l Cu47: Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp 3

Trng THPT Hong Vn Th-V Bn-Nam nh Bi tp V HNO3 v mui NO3gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) Cu48: Ho tan hon ton 31,2g hn hp Al, Mg bng dung dch HNO3 long, d thu c dung dch A v 8,96 lit hn hp kh B (ktc) gm N2, N2O (khng cn spk khc), dB/H2 =20. Tnh s mol HNO3 phn ng v khi lng mui khan thu c khi c cn A Cu49: Ho tan hon ton 23,1g hn hp Al, Mg, Zn , Cu bng dung dch HNO3 long, d thu c dung dch A v hn hp kh B gm 0,2 mol NO, 0,1 mol N2O (khng cn sp kh khc). Tnh s mol HNO3 phn ng v khi lng mui khan thu c khi c cn A. Cu50: Khi cho 19,2g Cu tc dng vi HNO3 long va th th tch acid cn dng l? A. 0.8lt B. 0,4lt C. 0,6lt D. 0,3lt

Dng6: Phn ng ca NO3- trong mi trng axit

Cu51: Cu52:

Dng7: Nhit phn mui NO3Cu53: nung 67.2g hn hp Fe(NO3)3, Cu(NO3)2 sau p thu c 4.48lit kh oxi(ktc). Cht rn sau khi nung c khi lng l: A. 64g B. 24g C. 34g D. 46g Cu54: Cho 17,7 gam hn hp Cu, Zn, Mg tc dng vi dung dch HNO3 d thu c dung dch X, c cn dung dch X thu c 67,3gam mui khan( khng c NH4NO3 ).Nung hn hp mui khan ny n khi lng khng i th thu c bao nhiu gam cht rn.