S GD & T HNG YN

TRNG THPT NGUYN TRUNG NGN

T Ho - Sinh - Th

THI TH I HC LN I
NM 2012 - 2013
MN: HO HC
Thi gian lm bi: 90 pht.
M : 173

H v tn:..SBD:
Cho bit khi lng nguyn t (theo vC hay theo u) ca cc nguyn t: H=1; C=12; N=14; O=16;
Na=23; K=39; Mg=24; Ca=40; Ba=137; Al=27; Zn=65; Fe=56; Cu=64; Ag=108; Pb=207; Cr=52; P=31;
S=32; Cl=35,5; Br=80; I=127.
Cu 1: A l hn hp kh gm N2 v H2 c t khi so vi oxi bng 0,225. Dn A vo bnh c Ni un nng, phn ng tng
hp amoniac xy ra th thu c hn hp kh B c t khi so vi oxi bng 0,25.
Hiu sut ca qu trnh tng hp NH3 l
A. 30%.
B. 25%
C. 15%.
D. 20%.
Cu 2: Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng ca N trong X l
11,864%. C th iu ch ti a bao nhiu gam hn hp 3 kim loi t 14,16 gam X?
A. 7,68 gam
B. 3,36 gam
C. 6,72 gam
D. 10,56 gam
Cu 3: Cho 2,7 gam Al tan hon ton trong dung dch HNO 3 long, nng thu c kh 0,448 lt X duy nht
(ktc). C cn dung dch thu c 22,7 gam cht rn khan. Vy cng thc ca kh X l:
A. NO
B. NO2
C. N2
D. N2O
Cu 4: Cho cc cht sau : CH CH; CH3 C C CH3; CH2 = CH C CH; CH2 = CH CH = CH2;
CH3 C C CH (CH3)2; HC C C CH; CH3 CH = CH2.
C my cht tc dng vi AgNO3 trong dung dch NH3 to ra kt ta ?
A. 6.
B. 5.
C. 4.
D. 3.
Cu 5: Ch t n-butan (cc dng c thit b, xc tc coi nh y , khng dng thm hp cht hu c khc),
ch thc hin khng qu 4 phn ng trong mi trng hp c th iu ch c nhng polime no ?
A. PE, PVC, cao su buna-S.
B. PE , PP, cao su buna-S.
C. PE, cao su buna, PVA.
D. PE, PVA, cao su isopren.
Cu 6: Cho 5,00 gam hirocacbon X tc dng vi AgNO3 trong dung dch NH3 d th thu c 26,4 gam kt
ta. Cng thc cu to ca X l
A. CH CCH = CH2.
B. HC CCH2C CH.
C. HC CC CH.
D. HC CCH2CH2C CH.
Cu 7: Hp cht 3-metylbut-1-en l sn phm chnh t cht no sau y qua phn ng tch loi nc ?
A. (CH3)2COHCH2CH3
B. (CH3)2CHCHOHCH3
C. (CH3)2CHCH2CH2OH
D. HOCH2CH(CH3)CH2CH3
Cu 8: Cho phng trnh phn ng: Mg + HNO 3 Mg(NO3)2 + NO + N2O + H2O. Nu t khi ca hn hp
NO v N2O i vi H2 l 17,8. T l s phn t b kh v b oxi ha l
A. 14 : 25
B. 11 : 28
C. 25 : 7
D. 28 : 15
Cu 9: C 5 gi bt mu tng t nhau l ca cc cht CuO, FeO, MnO 2, Ag2O, (Fe+FeO). C th dng
dung dch no trong cc dung dch di y phn bit cc cht trn ?
A. Dung dch HNO3 c. B. Dung dch AgNO3
C. Dung dch HCl c.
D. Dung dch Ba(OH)2
Cu 10: Cho cc cht l O2, SO2, H2O2, CO2 ZnS, S, H2SO4, FeCl2. Cc cht va c tnh kh, va c tnh oxi ha l
A. H2O2, S, SO2, CO2. B. FeCl2, S, SO2, H2O2.
C. SO2, ZnS, FeCl2.
D. CO2, Fe2O3, O2, H2SO4.
Cu 11: Cho s : X Y CH3COOH. Vi X l cht hu c c C, H hoc c c O hoc halogen vi s
nguyn t cacbon 2 ; Y l cht hu c. C bao nhiu cch thc hin s trn ?
A. 4
B. 5
C. 6
D. 7
Cu 12: C bao nhiu ng phn c cng CTPT C 5H12O khi oxi ho bng CuO (un nng) to ra sn phm
c phn ng trng bc ?
A. 2.
B. 4.
C. 3.
D. 5.
thi gm 04 trang

M : 173

Cu 13: Cho 8,04 gam hn hp hi gm CH 3CHO v C2H2 tc dng hon ton vi dung dch AgNO3/NH3
thu c 55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam
cht khng tan. Gi tr ca m l:
A. 41,69 gam
B. 55,2 gam
C. 61,78 gam
D. 21,6 gam
Cu 14: Hp cht hu c X c cng thc phn t C 9H16O4 , Khi thy phn trong mi trng kim thu c
mt mui m t mui ny iu ch trc tip c axit dng sn xut t nilon-6,6.
S cng thc cu to tho mn l
A. 1.
B. 2.
C. 3.
D. 4.
Cu 15: Ha tan hon ton 19,2 gam hn hp X gm Fe, FeO, Fe3O4 v Fe2O3 trong 50 ml dung dch
H2SO4 18M (c, d, un nng), thu c dung dch Y v V lt kh SO2 (ktc v l sn phm kh duy nht).
Cho 450 ml dung dch NaOH 2M vo dung dch Y thu c 21,4 gam kt ta. Gi tr ca V l:
A. 3,36 lt.
B. 4,48 lt.
C. 6,72 lt.
D. 5,60 lt.
0
Cu 16: ho tan mt mu km trong dung dch HCl 20 C cn 27 pht. Cng mu km tan ht trong dung
dch axit ni trn 400C trong 3 pht. ho tan ht mu km trong axit ni trn 450C th cn bao nhiu
thi gian?
A. 103,92 giy
B. 60,00 giy
C. 44,36 giy
D. 34,64 giy
Cu 17: t chy ht m gam hn hp X gm hai anehit n chc, mch h (c mt lin kt i C = C trong
phn t) thu c Vlt kh CO2 ktc v a gam H2O. Biu thc lin h gia m; a v V l
4V 7a
4V 9a
5V 9a
5V 7 a

+
+
+ .
A. m =
.
B. m =
.
C. m =
.
D. m =
4
9
5
9
5
7
4
7
Cu 18: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t
visco, t nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l
A. 5.
B. 6.
C. 7.
D. 4.
Cu 19: Aminoaxit Y cha 1 nhm COOH v 2 nhm - NH2 cho 1 mol Y tc dng ht vi dung dch HCl
v c cn th thu c 205g mui khan. Cng thc phn t ca Y l
A. C4H10N2O2.
B. C6H14N2O2.
C. C5H10N2O2.
D. C5H12N2O2.
Cu 20: a mol cht bo X cng hp ti a vi 5a mol Br2. t a mol X c b mol H2O v V lt CO2. Biu
thc gia V vi a, b l
A. V = 22,4.(b + 6a).
B. V = 22,4.(b + 3a). C. V = 22,4.(b + 7a). D. V = 22,4.(4a - b).
Cu 21: Ch ra s cu ng trong cc cu sau:
(1) Phenol, axit axetic, CO2 u phn ng c vi NaOH.
(2) Phenol, ancol etylic khng phn ng vi NaHCO3
(3) CO2, v axit axetic phn ng c vi natriphenolat v dd natri etylat
(4) Phenol, ancol etylic, v CO2 khng phn ng vi dd natri axetat
(5) HCl phn ng vi dd natri axetat, natri p-crezolat
A. 3.
B. 2.
C. 4.
D. 5.
Cu 22: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5);
imetylamin (6). Th t tng dn lc baz ca cc cht l
A. (2) < (3) < (4) < (1) < (5) < (6).
B. (3) < (2) < (4) < (1) < (5) < (6).
C. (2) > (3) > (4) > (1) > (5) > (6).
D. (3) < (1) < (4) < (2) < (5) < (6).
Cu 23: Mt hn hp X gm Na, Al v Fe (vi t l mol Na v Al tng ng l 5:4) tc dng vi H 2O d th
thu c V lt kh, dung dch Y v cht rn Z. Cho Z tc dng vi dung dch H 2SO4 long d th thu c
0,25V lt kh (cc kh o cng iu kin). Thnh phn % theo khi lng ca Fe trong hn hp X l
A. 14,4%
B. 33,43%
C. 20,07%
D. 34,8%.
Cu 24: in phn 200 ml dung dch cha NaCl 0,5M; Fe(NO3)3 0,3M v Cu(NO3)2 0,3M bng in cc
tr c mng ngn xp n khi khi lng dung dch gim 5,63 gam th dng li.
Dung dch sau in phn c cha
A. NaNO3, Fe(NO3)2, Cu(NO3)2 v HNO3.
B. NaNO3 v NaCl..
C. NaNO3 v NaOH.
D. NaNO3, Cu(NO3)2 v HNO3.

thi gm 04 trang

M : 173

Cu 25: Trn 13,6 g phenyl axetat vi 250 ml dung dch NaOH 1M. Sau khi phn ng xy ra hon ton c cn dung
dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l
A. 19,8.
B. 10,2.
C. 21,8.
D. 8,2.
Cu 26: Thy phn ht 1 lng pentapeptit X trong mi trng axit thu c 32,88 gam AlaGlyAlaGly;
10,85 gam AlaGlyAla; 16,24 gam AlaGlyGly; 26,28 gam AlaGly; 8,9 gam Alanin cn li l GlyGly
v Glyxin. T l s mol GlyGly:Gly l 10:1. Tng khi lng GlyGly v Glyxin trong hn hp sn phm l
A. 27,9
B. 29,7
C. 13,95
D. 28,8
Cu 27: Hn hp X gm HCHO( 0,15 mol) v anehit Y. t chy hon ton hn hp X thu c 12,32 lt (
ktc) CO2 v m gam H2O. Mt khc, nu cho hn hp X tc dng vi lng d dung dch AgNO3/NH3 thu
c ti a 1,40 mol Ag. Ga tr ca m l:
A. 9,90
B. 8,10
C. 5,40
D. 6,30
Cu 28: Cho 4 phn ng:
(1) Fe + 2HCl FeCl2 + H2
(2) 2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O
(3) BaCl2 + Na2CO3 BaCO3 + 2NaCl
(4) 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4
Cc phn ng thuc loi phn ng axit - baz l: A. (1), (2).
B. (2), (4).
C. (3), (4).
D. (2), (3).
Cu 29: Nh mt git dung dch H2SO4 2M ln mt mu giy trng. Hin tng s quan st c l
A. Khi h nng, ch giy c git axit H2SO4 s chuyn thnh mu en.
B. Khng c hin tng g xy ra.
C. Khi h nng, ch giy c git axit H2SO4 s bc chy.
D. Ch giy c git axit H2SO4 s chuyn thnh mu en.
Cu 30: Cho 2- metylbuta-1,3- ien tc dng vi dung dch Br2 theo t l mol 1:1 th thu c bao nhiu sn
phm? A. 1.
B. 2.
C. 3.
D. 4.
Cu 31: C cc cht ring bit l benzen, toluen, stiren. C th dng cht no sau y phn bit 3 cht
trn?
A. Dung dch KMnO4. B. Nc brom.
C. Dung dch H2SO4.
D. Dung dch NaOH.
Cu 32: Dy no di y gm cc cht khi tc dng vi H 2O un nng, c xc tc thch hp, mi cht ch
cho 1 sn phm cng?
A. CH2 = CH2 , CH3 CH = CH CH2 CH3
B. CH2 = CH2 ; CH3CH = CH2
C. CH2 = CH2 ; (CH3)2C = C(CH3)2.
D. CH2 = CH2 ; (CH3)2C = CHCH3
Cu 33: Mt hn hp X gm FeO, Fe3O4, Fe2O3. Ly m1 gam hn hp X cho vo ng s chu nhit, nung nng ri thi
mt lung kh CO i qua. Ton b kh sau phn ng c dn t t vo dung dch Ba(OH) 2 d thu c 19,7 gam kt
ta trng. Cht rn cn li trong ng s c khi lng l 19,20 gam gm Fe , FeO v Fe3O4. Gi tr ca m1 l
A. 23,2 gam.
B. 20,8 gam
C. 22,0 gam
D. 23,6 gam
Cu 34: trung ha 500ml dung dch X cha hn hp HCl 0,1M v H2SO4 0,3M cn bao nhiu ml dung dch hn hp
gm NaOH 0,3M v Ba(OH)2 0,2M?
A. 500ml.
B. 750ml.
C. 250ml.
D. 125ml.
Cu 35: Thnh phn chnh ca supepht pht kp l:
A. Ca(H2PO4)2.
B. Ca(H2PO4)2. CaSO4 C. NH4H2PO4
D. Ca3(PO4)2.CaF2
Cu 36: Mt trong cc tc dng ca mui it l c tc dng phng bnh bu c. Thnh phn ca mui it l:
A. NaCl c trn thm mt lng nh KI hoc KIO3
B. NaCl c trn thm mt lng nh I2
C. NaCl c trn thm mt lng nh HI
D. NaCl c trn thm mt lng nh HIO3
Cu 37: Pht biu no sau y l sai?
A. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh.
B. nhit thng, tt c kim loi kim th u tc dng c vi nc.
C. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al2O3 bn vng bo v
D. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn
Cu 38: Sc V lt CO2 (ktc) vo 200 ml dung dch X gm Ba(OH) 2 1M v NaOH 1M. Sau phn ng thu
c 19,7 gam kt ta, gi tr ln nht ca V l:
A. 6,72
B. 8,96
C. 11,2
D. 13,44

thi gm 04 trang

M : 173

Cu 39: Cho propan tc dng vi Cl2 v cho tc dng vi Br2 u theo t l mol 1:1.
Sn phm chnh chim t l cao hn l
A. khi cho clo tc dng vi
B. khi tc dng vi brom cho nhiu hn.
C. trong hai trng hp l nh nhau.
D. khng xc nh c v khng bit t l v s mol.
Cu 40: C bao nhiu cht ng phn cu to ca nhau c cng C3H6ClBr?
A. 2.
B. 3.
C. 4.
D. 5.
Cu 41: Cho cc cht sau : CO2, SO2, H2O2, C6H6, C6H5CH3, CH3CH = CH2, C6H5CH = CH2. C bao
nhiu cht lm mt mu dung dch KMnO4 iu kin thng ?
A. 3.
B. 2.
C. 4.
D. 5.
Cu 42: Thc hin cc th nghim sau:
(a) Nung NH4NO3 rn.
(b) un nng NaCl tinh th vi dung dch H2SO4 (c)
(c) Sc kh Cl2 vo dung dch NaHCO3.
(d) Sc kh CO2 vo dung dch Ca(OH)2 (d).
(e)Sc kh SO2 vo dung dch KMnO4.
(g) Cho dung dch KHSO4 vo dung dch NaHCO3.
(h) Cho PbS vo dung dch HCl (long).
(i) Cho Na2SO3 vo dung dch H2SO4 (d) , un nng.
S th nghim sinh ra cht kh l: A. 2
B. 6
C. 5
D. 4
Cu 43: Cho cc cht: Zn, Cl2, NaOH, NaCl, Cu, HCl, NH3, AgNO3.
S cht tc dng c vi dung dch Fe(NO3)2 l
A. 7
B. 6
C. 5
D. 4
Cu 44: C mt loi qung pirit cha 92% FeS2 cn li l cc tp cht tr. Nu mi ngy nh my sn xut
c 100 tn dung dch H2SO4 98% th cn dng bao nhiu tn qung pirit trn? Bit hiu sut qu trnh iu
ch H2SO4 l 85%.
A. 76,73 tn.
B. 38,36 tn.
C. 56,27 tn.
D. 46,92 tn.
Cu 45: Cho cc cht:C, Cu, ZnS, Fe2O3, CuO, NaCl rn, Mg(OH)2. S cht tc dng vi dung dch H2SO4
c, nng, to kh:
A. 4
B. 2
C. 5
D. 3
Cu 46: un 82,8 gam hn hp 3 ancol n chc ng ng k tip nhau vi H 2SO4 c 140oC (H/s =
100%) thu c 66,6 gam hn hp cc ete c s mol bng nhau. Cng thc ca 3 ancol l
A. C2H6O, C3H8O v C4H10O.
B. C2H4O, C3H6O v C4H8O.
C. C3H6O, C4H8O v C5H10O.
D. CH4O, C2H6O v C3H8O.
Cu 47: C bao nhiu hp cht thm l ng phn ca nhau c CTPT C7H8O lm mt mu dung dch brom ?
A. 5
B. 4
C. 6
D. 7
Cu 48: Cho hn hp gm m gam bt Cu v 27,84 gam Fe3O4 vo dung dch H2SO4 long d thy tan
hon ton thu c dung dch X. oxi ha ht Fe2+ trong dung dch X cn dng 90 ml dung dch KMnO4
0,5M. Gi tr ca m l:
A. 3,36 gam.
B. 5,12 gam.
C. 2,56 gam.
D. 3,20gam.
Cu 49: Cho cc phn ng:
to
(1). O3 + dung dch KI
(6). F2 + H2O

t
(2). MnO2 + HCl c

to
(3). KClO3 + HCl c

(7). H2S + dung dch Cl2 d

(8). HF + SiO2
o

t
(4). NH4HCO3

t
(9). NH4Cl + NaNO2

(10). Cu2S + Cu2O

t
(5). NH3(kh) + CuO

S trng hp to ra n cht l:
A. 5.
B. 6.
C. 7.
D. 8.
Cu 50: Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn ng xy ra hon
ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l
A. 32,50.
B. 48,75.
C. 29,25.
D. 20,80.

.............Ht............
thi gm 04 trang

M : 173