32

P N

1.C 2.C 3.D 4.B 5.C 6.B 7.B 8.B
9.D 10.C 11.C 12.B 13.D 14.A 15.D 16.A
17.C 18.C 19.B 20.B 21.D 22.C 23.B 24.B
25.D 26.D 27.B 28.B 29.A 30.A 31.A 32.B
33.D 34.B 35.A 36.C 37.A 38.C 39.C 40.A
41.B 42.D 43.B 44.A 45.A 46.A 47.B 48.D
49.B 50.A 51.A 52.A 53.A 54.C 55.B 56.C
57.A 58.B 59.C 60.B 61.A 62.D 63.A 64.C
65.A 66.D 67.D 68.A 69.A 70.A 71.D 72.A
73.A 74.C 75.A 76.D 77.A 78.A 79. 80.C
81.D 82.A 83.D 84.B 85. 86.C 87.A 88.D
89.A 90.C 91.D 92.A 93.A 94.D 95.C 96.C
97.A 98.A 99.A 100.D 101.A 102.B 103.B 104.D
105.A 106.C 107.B 108.D 109.C 110.A 111.B 112.D
113.B 114.B 115.A 116.B 117.B 118.D 119.B 120.A
121.C 122.D 123.C 124.C 125.C 126.D 127.C 128.D
129.C 130.B 131.B 132.D 133. 134.D 135.C 136.A
137.C 138.B 139.D 140.B 141.A 142.B 143. 144.C
145.D 146.D 147.B 148.B 149.B 150.C 151.A 152.D
153.C 154.C 155.B 156.B 157.A 158.C 159.D 160.C
161.A 162.D 163.B 164.B 165.D 166.A 167.B 168.C
169.D 170.D 171.D 172.A 173.B 174.D 175.D 176.A
177.D 178.D 179.A 180.B 181.D 182.B 183.A 184.C
185.D 186.C 187.C 188.B 189.A 190.D 191.C 192.A
193.C 194.A 195.D 196.B 197.D 198.B 199.D 200.B
201.B 202.C 203.D 204.A 205.A 206.C 207.A 208.D
209.A 210.D 211.A 212.C 213.C 214.C 215.B 216.D
217.A 218.D 219.D 220.A 221.D 222.B


1
Chuyn : Amin Axit amin - Peptit

I. nh ngha Cng thc tng qut Tn gi:
1. Khi nim : Khi thay th mt hay nhiu nguyn t hidro trong phn t
NH3 bng 1 hay nhiu gchidrocacbon ta c amin .
VD: CH
3
NH
2
; CH
3
NH CH
3
.
2. Cng thc .
R-NH
2
(Amin) ; R-CH-COOH(Amino axit);
H
2
N-CH-CO--NH-CH-COOH(Peptit)
Nng cao : n li CT tng qut : C
n
H
2n+2 2a x
(Chc)
x

CT tng qut ca amino axit : CnH2n+2 2a x (NH2)x vi a l s lin kt t v x
l s nhm chc.
T CT trn =>CT amin n chc : CnH2n + 1 2a (NH2)
=> amin n chc no => a = 0: CnH
2n+1
NH
2
, c 1 lk t =>a =1: C
n
H
2n 1
NH
2

Thay a vo => CT tng ng.
CT tng qut ca amino Axit : (H
2
N)
n
R (COOH)
n
: n , n 1 : R l gc
hidrocacbon ha tr (n + n)
Hoc ( H
2
N)
n
C
x
H
y
(COOH)
n
: n , n 1 , x 1 , y + n + n 2x + 2
Amino axit thng gp :
Amino axit cha 1 nhm amino (NH
2
) v mt nhm chc axit (COOH) no
mch h : H
2
N-R-COOH
* Bc ca amin bng s nguyn t H trong amin b thay th bi gc
hidrocabon
Vd: CH3 NH2 (Bc 1), CH3 NH CH3(Bc 2), (CH3)3N (Bc 3)
1/ Tn gi :
Tn gc hidrocacbon + amin

Vd: CH
3
NH CH
3
: imetyl amin.
2/ Tnh cht
a) Tnh cht ca nhm NH
2

* Tnh baz: R-NH
2
+H
2
O =>[R-NH
3
]
+
OH
-

Tc dng vi axit cho mui: R-NH
2
+HCl =>[R-NH
3
]
+
Cl
-
* Tc dng vi HNO2
Amin bo bc I to thnh ancol v kh N
2
:
R-NH2 +HONO =>R-OH +N2 +H2O
Amin thm bc I:
ArNH2 +HNO2 +HCl =>ArN2+Cl hay ArN2Cl
Tc dng vi dn xut Halogen
R-NH
2
+CH
3
I =>R-NHCH
3
+HI

2
b) Amino axit c tnh cht ca nhm COOH
* Tnh axit: RCH(NH
2
)COOH +NaOH =>RCH(NH2)COONa +H
2
O
* Phn ng este ho:
RCH(NH2)COOH +ROH => RCH(NH2)COOR +H2O
c) Amino axit c phn ng gia nhm COOH v nhm NH
2

To mui ni H2N-CH-COOH =>H3N+-CH-COO
Phn ng trng ngng ca cc v amino axit to poliamit:
nH2N-[CH2]5-COOH => ( NH-[CH2]5-CO )n +nH2O
axit - aminocaproic policaproamit
d) Protein c phn ng ca nhm peptit CO-NH
* Phn ng thu phn:
* Phn ng mu: Tc dng vi Cu(OH)2 cho dung dch mu xanh tm.
e) Anilin: c phn ng th d dng 3 nguyn t H ca vng benzen(o , p) =>
kt ta trng (dng nhn bit anilin)
Ch cc cht sau : anilin (C6H5NH2) v amino axit thng dng.
II) Cc dng bi tp thng gp
Dng 1: S ng phn ca amin n :

CTPT Tng s ng
phn
Bc 1 Bc 2 Bc3
C
3
H
9
N 4 2 1 1
C4H11N 8 4 3 1
C
5
H
13
N 17 8 6 3
C6H15N 7
C
7
H
9
N 5 4 1 0
Vd
1
: Cho amin no n chc c %N = 23,72%. Tms ng phn bc 3 ca
amin
A. 1 B.2 C.3 D.4
PP: amin no n chc =>CT : C
n
H
2n+1
NH
2

%N =
N
amin
M .100% 14.100%
23,72%
M 14n 17
= =
+
Gii ra c n = 3
CT : C
3
H
7
N
2
=> C ng phn bc 3 l 1 ( Bng trn C
3
H
9
N)
Dng 2: So snh tnh baz ca cc amin
Nguyn tc :
Amin cn d i e cha lin kt trn nguyn t Nit nn th hin tnh baz
=> c trng cho kh nng nhn proton H
+

Nhmankyl c nh hng lm tng mt e nguyn t Nit =>lm tng
tnh baz. >NH
3

Nhmphenyl (C
6
H
5
-
) lmgim mt e trn nguyn t Nit =>lm gim
tnh baz.<NH3

31
Cu 216: Nhng cht no sau y lng tnh :
A. NaHCO3 B. H2N-CH2-COOH
C. CH
3
COONH
4
D. C A, B, C
Cu 217: Ngi ta iu ch anilin bng cch nitro ho 500 g benzen ri kh hp
cht nitro sinh ra. Khi lng anilin thu c l bao nhiu bit rng hiu sut
mi giai on u t 78%.
A. 362,7 g B. 463,4 g C. 358,7 g D. 346,7 g
Cu 218: 9,3 g mt ankylamin cho tc dng vi dung dch FeCl
3
d thu c
10,7 g kt ta. CTCT l :
A. C2H5NH2 B. C3H7NH2 C. C4H9NH2 D. CH3NH2
Bi 219: (A) l mt hp cht hu c c CTPT C
5
H
11
O
2
N. un (A) vi dung
dch NaOH thu c mt hp cht c CTPT C2H4O2NNa v cht hu c (B).
Cho hi qua CuO/t
0
thu c cht hu c (D) c kh nng cho phn ng trng
gng. CTCT ca A l :
A. CH
2
=CH - COONH
3
- C
2
H
5
B. CH
3
(CH
2
)
4
NO
2

C. H2N- CH2 - CH2 - COOC2H5 D. NH2 - CH2COO - CH2- CH2 - CH3
Bi 220: Dung dch etylamin c tc dng vi d ca mui no di y :
A. FeCl
3
B. NaCl
C. Hai mui FeCl
3
v NaCl D. AgNO
3

Bi 221: Sp xp cc hp cht sau y theo th t gim dn tnh baz :
(1) C6H5NH2 (2) C2H5NH2 (3) (C6H5)2NH (4) (C2H5)2NH
(5) NaOH (6) NH
3

A. (5) >(4) >(2) >(1) >( 3) >(6) B. (1) >(3) >(5) >(4) >(2) >(6)
C. (4) >(5) >( 2) >(6) >( 1) >(3) D. (5) >(4) >(2) >(6) >(1) >(3)
Bi 222: Nhit si ca C4H10 (1), C2H5NH2 (2), C2H5OH (3) tng dn theo
th t:
A. (1) <(2) <(3) B. (1) <(3) <(2) C. (2) <( 3) <(1) D. (2)<(1)<(3)














30
Cu 207: Cho 22,15 g mui gm CH
2
NH
2
COONa v CH
2
NH
2
CH
2
COONa tc
dng va vi 250 ml dung dch H2SO4 1M. Sau phn ng c cn dung dch
th lng cht rn thu c l :
A. 46,65 g B. 45,66 g C. 65,46 g D. Kt qu khc
Cu 208: Cho 13,35 g hh X gm CH
2
NH
2
CH
2
COOH v CH
3
CHNH
2
COOH tc
dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y
tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V l :
A. 100 ml B. 150 ml C. 200 ml D. 250 ml
Cu 209: Cho 20,15 g hn hp X gm (CH
2
NH
2
COOH v CH
3
CHNH
2
COOH)
tc dng vi 200 ml dung dch HCl 1M thu c dung dch Y. Y tc dng va
vi 450 ml dung dch NaOH 1M . Phn trm khi lng ca mi cht trong
X l:
A. 55,83 % v 44,17 % B. 58,53 % v 41,47 %
C. 53,58 % v 46,42 % D. 52,59 % v 47,41%
Cu 210: Cho 4,41 g mt aminoaxit X tc dng vi dung dch NaOH d cho ra
5,73 g mui. Mt khc cng lng X nh trn nu cho tc dng vi dung dch
HCl d thu c 5,505 g mui clorua. Xc nh CTCT ca X.
A. HOOC-CH
2
CH
2
CH(NH
2
)COOH B. CH
3
CH(NH
2
)COOH
C. HOOCCH2CH(NH2)CH2COOH D. C A v B
Cu 211: Mt amino axit (X) c cng thc tng qut NH
2
RCOOH. t chy
hon ton a mol X thu c 6,72 (l) CO2 (ktc) v 6,75 g H2O. CTCT ca X l:
A. CH
2
NH
2
COOH B. CH
2
NH
2
CH
2
COOH
C. CH
3
CH(NH
2
)COOH D. C B v C
Cu 212: Cht no sau y c tnh baz mnh nht ?
A. NH
3
B. C
6
H
5
NH
2

C. CH
3
-CH
2
-CH
2
-NH
2
D. CH
3
-CH(CH
3
)-NH
2

Cu 213: Mt amino axit no X ch cha mt nhm -NH2 v mt nhm -COOH.
Cho 0,89 g X phn ng va vi HCl to ra 1,255 g mui. CTCT ca X l:
A. H
2
N-CH
2
-COOH B. CH
3
-CH(NH
2
)-CH
2
-COOH
C. H2N-CH2-CH2-COOH D. B, C, u ng.
Cu 214: A +HCl =>RNH
3
Cl. Trong (A) (C
x
H
y
N
t
) c % N =31,11%
CTCT ca A l :
A. CH3 - CH2 - CH2 - NH2 B. CH3 - NH - CH3
C. C
2
H
5
NH
2
D. C
2
H
5
NH
2
v CH
3
- NH - CH
3

Cu 215: L do no sau gii thch tnh baz ca monoetylamin mnh hn
amoniac:
A. Nguyn t N cn i electron cha to lin kt
B. nh hng y electron ca nhm -C
2
H
5

C. Nguyn t N c m in ln
D. Nguyn t nit trng thi lai ho


3
Lc baz : C
n
H
2n+1
NH
2
>NH
3
>C
6
H
5
-NH
2

Amin bc 2 > Amin bc 1
Gii thch: Do amin bc 2 (R-NH-R) c hai gc HC nn mt y e vo
nguyn t N trung
tm ln hn amin bc 1 (R-NH
2
).
Amin cng c nhiu gc ankyl, gc ankyl cng ln =>tnh baz cng mnh.

gc phenyl => tnh baz cng yu.
* V d: So snh tnh baz ca cc hp cht hu c sau: NH
3
, C
2
H
5
NH
2
,
CH
3
NH
2
, C
6
H
5
NH
2
, (C
6
H
5
)
2
NH, (C
2
H
5
)
2
NH, C
6
H
5
- CH
2
NH
2
?
(C
2
H
5
)
2
NH>C
2
H
5
NH
2
>CH
3
NH
2
>NH
3
>C
6
H
5
>CH
2
NH
2
>C
6
H
5
NH
2
>(C
6
H
5
)
2
NH
Vd
1
: Cho cc cht: (1)amoniac, (2)metylamin, (3)anilin, (4)imetylamin.
Tnh baz tng dn theo th t no sau y?
A. (1) <(3) <(2) <(4). B. (3) <(1) <(2) <(4).
C. (1) <(2) <(3) <(4). D. (3) <(1) <(4) <(2).
Amoniac : NH3 ; metyamin : CH3NH2 ; anilin : C6H5NH2;
imetyl amin : CH
3
NH CH
3

Da vo tnh cht trn: anilin c vng benzen(gc phenyl) => Tnh baz yu
nht, NH
3
mc trung gian > C
6
H
5
NH
2

Amin bc I (CH
3
NH
2
) <Amin bc 2 (NH
3
NH NH
3
)
=> Th t : C
6
H
5
NH
2
<CH
3
<CH
3
NH
2
<(CH
3
)NH
Dng 3: Xc nh s nhm chc :
Nu bi cho s mol amin v s mol axit (H
+
) lp t s :
S nhm chc =
H
amin
n
n
+

Nu amin ch c 1 N =>s chc = 1
Vd: trung ha 50 ml dd amin no,(trong amin c 2 nguyn t Nit)cn 40
ml dd HCl 0,1 M . Tnh CM ca imetyl amin dng l :
A.0,08M B.0,04M C.0,02M D.0,06M
Amin c 2 N =>amin c s chc = 2 ADCT :
HCl
amin
n
n
2
= =0,002 mol
=>C
M
amin =0,04 M
Dng 4 : Xc inh s mol ca ca amin nu bit s mol ca CO2 & H2O :
Nu bi cha cho amin no, n chc th ta c gi s l amin no, n.
Khi t chy
2 2
H O CO
n n > , ta ly :
2 2
H O CO amin
n - n = 1, 5n
Cch chng minh nh phn hidrocacbon CT amin no n chc : C
n
H
2n+1
NH
2

PT : CnH2n+3N2 +O2 =>nCO2 +(n+3/2)H2O +N2
x mol n.x mol (n+3/2).x mol

4
Ta ly
2 2
H O CO amin
n n 1,5x 1,5n = =
T => n (s C trong amin) hoc n =
2 2
2 2
CO CO
amin H O CO
n 1,5.n
n n n
=

Tng t c CT i vi amin khng no , n chc
+C 1 lk t , C 2 lk t , Chng minh tng t
Nu bi cho amin n chc, m khi t chy to ra bit
2
CO
n v
2
N
n .
th ta c CT sau
V amin n chc =>c 1 N . p dng LBT nguyn t N =>
2
amin N
n 2n =
M n hoc n =
2 2
2
CO CO
amin N
n n
n(n)
n 2n
=
Vd
1
: t chy hon ton a mol hh X gm 2 amin no n chc lin tip nhau
thu c 5,6 lt CO2 (ktc) v 7,2 g H2O . Gi tr ca a l :
A. 0,05 mol B. 0,1 mol C. 0,15 mol D. 0,2 mol
TmCT 2 amin ?
p dng CT:
2 2
H O CO
amin
(n n )
n
1,5

= ( i vi amin no n chc)
=(0,4 0,25)/1,5 =0,1 mol
CT amin : n =
2
CO
amin
n
0,25
2,5
n 0,1
= = =>Amin c CT : CnH2n+1NH2
n =2 v n =3 : C
2
H
5
NH
2
v C
3
H
7
NH
2

Vd2: Aminoaxit X cha mt nhmchc amin bc nht trong phn t. t
chy hon ton mt lng X thu c CO
2
v N
2
theo t l th tch l 4 : 1. X
c cng thc cu to l:
A. H
2
N CH
2
CH
2
COOH B. H
2
N (CH
2
)
3
COOH
C. H2N CH2 COOH D. H2N (CH2)4 COOH
Da vo p n => amin X ch c 1 N =>2nN2 =namin (BT NT Nito)
M
2 2
2
CO CO
amin N
n n
4
n n 2
n 2n 2
= = = = =>X Ch c 2 C => C
Dng 5: tm CTPT ca amin n, nu bit % khi lng N hoc %H hay
%C cng c:
Gi R l gc hidrocacbon ca amin cn tm.
Vd: amin n chc CT : R-NH
2

Mt s gc hidrocacbon thng gp :
15 : CH
3
- ; 27 : CH
2
=CH- ; 29 : C
2
H
5
- ; 43 :C
3
H
7
- ; 57 : C
4
H
9
-
Vd 1: Cho amin no, n chc bc 1 c %N = 31,11% . Tm CT ca amin

29
Cu 197: Phn ng no sau y sai ?
C
6
H
5
NH
2
+H
2
O =>C
6
H
5
NH
3
OH (1)
(CH
3
)
2
NH +HNO
2
=> 2CH
3
OH +N
2
(2)
C6H5NO2 +3Fe +7 HCl =>C6H5NH3Cl +3FeCl2 +2H2O. (3)
(4)
A. (1) (2) (4) B. (2) (3) (4) C. (2) (4) D. (1) (3)
Cu 198: ti to li anilint ddphenyl amonicloruaphi dngddcht no sau
y:
A. dd HCl B. dd NaOH C. dd Br
2
D. C A, B, C
Cu 199: t chy mt amin no n chc mch thng ta thu cCO2 v H2O
c t l mol 8 : 11 .CTCT ca X l
A. (C
2
H
5
)
2
NH B. CH
3
(CH
2
)
3
NH
2

C. CH3(NHCH2CH2CH3 D. C A, B, C
Cu 200: Cho 11,8 g hn hp X gm 3 amin : n-propyl amin, etylmetylamin,
trimetyl amin. Tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l :
A. 100ml B. 150 ml C. 200 ml D. Kt qu khc
Cu 201: t chy hon ton a mol hn hp X gm 2 amin no n chc thu
c 5,6 (l) CO2 (ktc) v 7,2 g H2O. Gi tr ca a l :
A. 0 ,05 mol B. 0,1 mol C. 0,15 mol D. 0,2 mol
Cu 202: t chy hon ton hn hp X gm 2 amin no n chc k tip nhau
trong dy ng ng, thu c 22 g CO
2
v 14,4 g H
2
O. CTPT ca hai amin l :
A. CH
3
NH
2
v C
2
H
7
N B. C
3
H
9
N v C
4
H
11
N
C. C2H7N v C3H9N D. C4H11N v C5H13 N
Cu 203: Cht no sau y ng thi tc dng c vi dd HCl v dd NaOH.
A. C
2
H
3
COOC
2
H
5
B. CH
3
COONH
4

C. CH3CHNH2COOH D. C A, B, C
Cu 204: Mt hp cht hu c X c CTPT C
2
H
7
O
2
N. X d dng phn ng vi
dung dch NaOH v dung dch HCl. CTCT ph hp ca X l :
A. CH
2
NH
2
COOH B. CH
3
COONH
4

C. HCOONH
3
CH
3
D. C A, B v C
Cu 205: Tng ng vi CTPT C3H9O2N c bao nhiu ng phn cu to va
tc dng c vi dung dch NaOH va tc dng vi dung dch HCl.
A. 3 B. 9 C. 12 D. 15
Cu 206: Cho 12,55 gam mui CH3CH(NH3Cl)COOH tc dng vi 150 ml dd
Ba(OH)
2
1M. C cn dd sau p/ng thu c m gam cht rn. Gi tr ca m l:
A. 15,65 g B. 26,05 g C. 34,6 g D. Kt qu khc

28
Cu 187: Cho cc cht sau: CH
3
CH
2
NHCH
3
(1), CH
3
CH
2
CH
2
NH
2
(2), (CH
3
)
3
N
(3).
Tnh baz tng dn theo dy :
A. (1) <(2) <(3) B. (2) <(3) <(1) C. (3) <(2) <(1) D. (3) < (1) <
(2)
Cu 188: Cho cc cht sau: p-CH3C6H5NH2(1) m-CH3C6H5NH2 (2),
C
6
H
5
NHCH
3
(3) C
6
H
5
NH
2
(4).
Tnh baz tng dn theo dy :
A. (1) <(2) <(4) <(3) B. (4) <(2) <(1) <(3)
C. (4) <(3) <(2) <(1) D. (4) <(3) <(1) <(2)
Cu 189: Cho cc cht sau: p-NO2C6H4NH2 (1), p-ClC6H5NH2 (2),
p-CH
3
C
6
H
5
NH
2
(3).
Tnh baz tng dn theo dy :
A. (1) <(2) <(3) B. (2) <(1) <(3) C. (1) <(3) <(2) D. (3) < (2) <
(1)
Cu 190: C bao nhiu ng phn amin ng vi CTPT C4H11N ?
A. 5 B. 6 C. 7 D. 8
Cu 191: Chocccht sau:Ru etylic(1) etylamin(2)
metylamin(3) axit axetic(4)
Sp sp theo chiu c nhit si tng dn :
A. (2) <(3) <(4) <(1) B. (2) <(3) <(4) <(1)
C. (3) <(2) <(1) <(4) D. (1) <(3) <(2) <(4)
Cu 192: Cho cc dung dch :
1) HNO
2
2) FeCl
2
3) CH
3
COOH 4) Br
2

Cc dung dch tc dng c vi anilin l :
A. (1), (4) B. (1), (3) C. (1), (3), (4) D. C 4 cht
Cu 193: Cho phn ng : X +Y =>C
6
H
5
NH
3
Cl. X +Y c th l :
A. C6H5NH2 +Cl2. B. (C6H5)2NH +HCl.
C. C
6
H
5
NH
2
+HCl D. C A, B, C
Cu 194: Cho s : (X) =>(Y) => (Z) => M (trng).
Cc cht X, Y, Z ph hp s trn l :
A. X (C6H6), Y (C6H5NO2), Z (C6H5NH2)
B. X (C
6
H
5
CH(CH
3
)
2
), Y (C
6
H
5
OH), Z (C
6
H
5
NH
2
)
C. X (C
6
H
5
NO
2
), Y (C
6
H
5
NH
2
), Z (C
6
H
5
OH)
D. C A v C
Cu 195: Hy chn thuc th thch hp phn bit 3 cht kh sau :
imetyl amin, metylamin, trimetyl amin.
A. dd HCl B. dd FeCl
3
C. dd HNO
2
D. C B v C
Cu 196: Thuc th thch hp phn bit 3 cht lng: phenol, anilin,benzen l:
A. dd HNO
2
B. dd FeCl
3
C. dd H
2
SO
4
D. Nc Br
2


5
Nh li CT tng qut : C
n
H
2n+2 2a m
(Chc)
m
( a l tng pi tnh phn trn)
y v amin n chc => m = 1 , V amin no =>a =0
=>CT: C
n
H
2n+2 1
NH
2
=C
n
H
2n+1
NH
2

=>%N = =
+
% 11 , 31
17 14
% 100 . 14
n
Gii ra c n = 2 => CT: C2H5NH2
Dng 6: Cho amin tc dng vi dd FeCl3, Cu(NO3)2 to kt ta :
Amin c kh nng tc dng vi dd FeCl
3
, Cu(NO
3
)
2
xy ra theo p/trnh :
3RNH2 +FeCl3 +3H2O => Fe(OH)3 +3RNH3Cl
2RNH
2
+Cu(NO
3
)
2
+2H
2
O => Cu(OH)
2
+2RNH
2
NO
3

Thng th bi hay cho mkt ta : Fe(OH)
3
hoc Cu(OH)
2

Dng 7: tm CTPT ca amin da theo phn ng chy
- Cng thc : AD CT : TmCT bt k : C
n
H
2n+2 2a m
(Chc)
m
Ta c
Amin bt k : CxHyNz vi y 2x + 2 +z y chn th z chn, y l th z l
Amin n chc : C
x
H
y
N
Amin n chc no : CnH2n+1NH2 , CnH2n+3NH2
Amin a chc no : C
n
H
2n+2-z
(NH
2
)
z
, C
n
H
2n+2+z
N
z

Nu cho phn trm khi lng tng nguyn t th lp CT n gin nht,
da vo gi thuyt bin lun. Theo T l : x : y : z
Nu bi cho s mol sn phm th lm tng t dng 3, tm c s ngt
C trung bnh, da vo yu cu a ra CT ng
Nu bi cho m gamin n chc t chy hon ton trong khng kh va
(cha 20% oxi, 80% nit) thu c ch k mol CO2 hoc c k mol CO2
ln x mol nit , ta c th lm nh v d:
Vd1: t chy hon ton 1,18 g amin n chc B bng mt lng oxi va .
Dn ton b sn phm qua bnh ng nc vi trong d thu c 6gam kt ta.
CTPT ca B l :
Gi cng thc l C
x
H
y
N
CxHyN +O2 =>x CO2
Ta c t l :
2
amin CO
x.n n =

06 , 0
84 , 0 46 , 0
06 , 0
14 12
18 , 1
.

= => =
+ +
x
y
y x
x 2x +2+1 x 3
Cho x chy t 1=>3 : ch c gi tr x=3 v y=9 l tho k . Vy CTPT l C
3
H
9
N
Vd
2
: t chy hon ton 1,18g amin n chc B bng mt lng khng kh
va (cha 20% oxi, 80% nit). Dn ton b sn phm qua bnh ng nc
vi trong d thu c 6 gam kt ta v c 9,632 lt kh duy nht thot ra. Cng
thc phn t ca B l :
Gi cng thc l C
x
H
y
N. Theo
3 2
CaCO CO
n n = =0,06 mol
C
x
H
y
N +(x +y/4) O
2
=> x CO
2
+y/2 H
2
O +N
2


6
Theo pt :
2 2
2 2
O N kk
N N
y y
0,06(x ) 0,06(x )
4 4
n n 4.
x x
y
0,06(x )
0,03 0,03
4
n n 4. 0,43 0,19x 0,06y 0,03(1)
x x x
1,18 0,06
0,46x 0,06y 0,84(2)
12x y 14 x
+ +
= =
+
= = + = =
= =
+ +

Gii (1) & (2) x =3, y =9. Vy CTPT l C
3
H
9
N
Nu bi ton cho t chy mt amin bng khng kh, ri thu a mol CO
2
; b
mol H
2
O; c mol N
2
.Ta lm nh sau :
Tmkhi lng O trong CO2; H2O =khi lng Oxi tham gia phn ng ( BT
Nguyn t O)
=>s mol oxi =>s mol Nit trong kk =
2
O
4n
(Nu bi tp cho t trong
khng kh cn Nu t trong O
2
th khng phi tnh)
=>s mol Nit sinh ra trong phn ng chy. T ta s c s mol C, H, N
trong amin =>TmCTGN => CTPT
Vd1: Mt amino axit cha 46,6% C, 8,74% H, 13,59% N,cn li l oxi. Cng
thc n gin nht trng vi cng thc phn t. CTPT ng ca amino axit l
A.C3H7O2N B.C4H9O2N C.C5H9O2N D.C6H10O2N
Bi gii:
Ta c: % O =100 - (46,6 +8,74 +13,59) =31,07 %
C : H : O : N =
14
59 , 13
:
16
07 , 31
:
1
74 , 8
:
12
6 , 46
14
%
:
16
%
:
1
%
:
12
%
=
N O H C

=3,88 : 8,74 : 1,94 : 0,97 =4 : 9 : 2 : 1
=>CTG : C
4
H
9
O
2
N =>Chn B
* Nu lm trc nghim nh th th hi lu.
Mo p n: S C u khc nhau v s N ging nhau ( bi hay cho kiu
ny)
Ch cn xt t l gia C v N thi khng cn O v H
Xt t l ta c C : O = 4 : 1 => B
Vd
2
: Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO
2
,
1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn
t ca X l (cho H =1, O =16)Chn mt p n di y
A. C3H7N B. C3H9N C. C4H9N D. C2H7N
Cu ny khc xt t l C : H hay hn Tm c t l 1 : 3 => B
V p n A v B t l C : N = 3: 1

27
Cu 180: Nhiu phn t amino axit kt hp c vi nhau bng cch tch -OH
ca nhm - COOH v -H ca nhm -NH
2
to ra cht polime (gi l phn ng
trng ngng). Polime c cu to mch :
(- HN - CH2 - CH2 - COO - HN - CH2 - CH2 - COO - )n
Monome to ra polime trn l :
A. H2N - CH2 - COOH B. H2N - CH2 - CH2COOH
C. H
2
N - CH
2
- CH
2
- CH
2
- COOH D. Khng xc nh c
Cu 181: S ng phn ca amino axit, phn t cha 3 nguyn t C l :
A. 1 B. 2 C. 3 D. 4
Cu 182: X l mt aminoaxit no ch cha mt nhm -NH2 v mt nhm-COOH.
Cho 0,89 gam X phn ng va vi HCl to ra 1,255g mui. CTCT ca X l :
A. NH
2
CH
2
COOH B.
3
2
CH CH COOH
|
NH


C.
3 2
2
CH CH CH COOH
|
NH

D.
3 2 2
2
CH CH CH CH COOH
|
NH


Cu 183: T l sinh ra khi t chy hon ton mt ng ng X ca glixin l 6 :
7 (phn ng sinh ra kh N
2
). X t/dng vi glixin cho sn phm l ipeptit. X l :
A.
3
2
CH CH COOH
|
NH
B. NH
2
-CH
2
-CH
2
-COOH
C.
3 2
2
CH CH CH COOH
|
NH

D. Kt qu khc
Cu 184: Gi tn hp cht c CTCT nh sau theo danh php thng thng.

3 2 2 2 2 3
3
CH CH CH CH N CH CH
|
CH


A. Etylmetyl amino butan C. n-butyletyl metyl amin
B. Metyletyl amino butan D. metyletylbutylamin
Cu 185: Gi tn hp cht c CTCT nh sau theo danh php thng thng :

A. 1-amino-3-metyl benzen. C. m-toludin.
B. m-metylanilin. D. C B, C.
Cu 186: Amin no sau y c tnh baz ln nht :
A. CH
3
CH=CH-NH
2
B.CH
3
C C-NH
2
C. CH3CH2CH2NH2 D. CH3CH2NH2

26
Cu 172: Phng php no thng dng iu ch amin ?
A. Cho dn xut halogen tc dng vi NH3
B. Cho ru tc dng vi NH
3

C. Hiro ho hp cht nitrin
D. Kh hp cht nitro bng hiro nguyn t .
Cu 173: Ru v amin no sau y cng bc ?
A. (CH3)3COH v (CH3)3CNH2 B. C6H5NHCH3 v C6H5CHOHCH3
C. (CH
3
)
2
CHOH v (CH
3
)
2
CHNH
2
D.(CH
3
)
2
CHOH v(CH
3
)
2
CHCH
2
NH
2

Cu 174: Tmpht biu sai trong cc pht biu sau ?
A. Etylamin d tan trong H2O do c to lin kt H vi nc
B. Nhit si ca ru cao hn so vi hirocacbon c phn t khi tng
ng do c lin kt H gia cc phn t ru.
C. Phenol tan trong H
2
O v c to lin kt H vi nc.
D. Metylamin l cht lng c mi khai, tng t nh amoniac.
Cu 175: Trong s cc cht sau :
C
2
H
6
; C
2
H
5
Cl; C
2
H
5
NH
2
; CH
3
COOC
2
H
5
; CH
3
COOH; CH
3
CHO; CH
3
OCH
3.
Cht no to c lin kt H lin phn t ?
A. C2H6 B. CH3COOCH3
C. CH
3
CHO; C
2
H
5
Cl D. CH
3
COOH ; C
2
H
5
NH
2

Cu 176: Metylamin d tan trong H2O do nguyn nhn no sau y ?
A. Do nguyn t N cn cp electron t do d nhn H
+
ca H
2
O.
B. Do metylamin c lin kt H lin phn t.
C. Do phn t metylamin phn cc mnh.
D. Do phn t metylamin to c lin kt H vi H
2
O.
Cu 177: Nguyn nhn gy nn tnh baz ca amin l :
A. Do amin tan nhiu trong H2O.
B. Do phn t amin b phn cc mnh.
C. Do nguyn t N c m in ln nn cp e chung ca nguyn t N v H
b ht v pha N.
D. Do nguyn t N cn cp eletron t do nn p/t amin c th nhn proton.
Cu 178: Dy sp xp ng theo th t gim dn tnh baz l dy no ?
(1)C
6
H
5
NH
2
, (2)C
2
H
5
NH
2
, (3)(C
6
H
5
)
2
NH, (4)(C
2
H
5
)
2
NH, (5)NaOH, (6)NH
3

A. (1) >(3) >(5) >(4) >(2) >(6) B. (5) >(6) >(2) >(1) >(2) >(4)
C. (5) >(4) >(3) >(5) >(1) >(2) D. (5) >(4) >(2) >(6) >(1) >(3)
Cu 179: Trong bnh kn cha 35 ml hn hp gm H
2
, mt amin n chc v 40
ml O2. Bt tia la in phn ng chy xy ra hon ton ri a hn hp v
iu kin ban u, th tch cc cht to thnh bng 20 ml gm 50% l CO
2
,
25% l N
2
v 25% l O
2
. CTPT no sau y l ca amin cho ?
A. CH5N B. C2H7N C. C3H6N D. C3H5N

7
Dng 8: Cho amin tc dng vi HCl: (PP Gii bi tp dng tng gim khi
lng)
Vd amin bc 1:
Aminno axit : NH2 R COOH +HCl =>ClNH3-R-COOH
Gi s 1mol 1mol => 1mol
=>m
|
=m
mui
m
amin
=36,5 g (v P cng HCl)
Vi xmol => xmol => xmol => m Tng = 36,5x g
m mui =mamin +namin (HCl hoc mui).36,5
Hoc dng BT Khi lng : m
amin
+m
HCl
=m
mui
(Chnh l CT trn)
Cn nu amino axit tc dng vi NaOH(Kim) (Hoc Na,K) Th xemli phn
Axit nh.
CT: mmui = mamino axit +m.nNaOH.22 ( m l s chc COOH)
i vi Amino Axit c 1 nhm COOH => n
NaOH
=n
amino axit
=n
mui

Vd1: Cho 0,01 mol amino axit A tc dng va vi 80 ml dung dch HCl
0,125 M. C cn dung dch thu c1,835 gammui. Khi lng phn t ca
A (Tc l M ca A)l
A. 97 B. 120 C. 147 D. 150
ADCT: m
mui
=m
amin
+n
HCl
.36,5
1,835 =M
amoni
. 0, 01 +0,01.36,5 M
amino
=147
Vd
2
: Cho 0,01 mol aminoaxit X phn ng ht vi 40ml dung dch HCl 0,25M
to thnh 1,115g mui khan. X c cng thc cu to no sau y:
A. NH
2
CH
2
COOH B. NH
2
(CH
2
)
2
COOH
C. CH3COONH4 D. NH2 (CH2)3 COOH
Da vo p n hoc Xt t l : n
HCl
/ n
amin
=1 =amino axit c 1 gc chc.
p t l 1 :1 => Loi p n C.
p dng CT : m
mui
=M
amino axit
. 0,01 +n
HCl
. 36,5
1,115 =M
X
.0,01 +0,01.36,5 M
X
=75
CT : amino axit : NH2 CnH2n COOH =>MR =14n +61 =75 =>n =1
CT : NH
2
CH
2
COOH. Chn p n A
Vd3: A l mt -amino axit no ch cha mt nhm -NH2 v mt nhm
COOH. Cho 3 gam A tc dng vi NaOH d thu c 3,88 gam mui. Cng
thc phn t ca A l
A.CH
3
-CH
2
-CHNH
2
-COOH B.CH
2
NH
2
-CH
2
-COOH
C.CH
3
-CHNH
2
-COOH D.H
2
N-CH
2
-COOH
Cch gii bnh thng :
Theo bi ta c gc hirocacbono l C
n
H
2n

H2NCnH2nCOOH +NaOH =>H2NCnH2nCOONa +H2O
bi 3 gam 3,88 gam
Theo ptrnh =>
2 n 2n 2 n 2n
H N C H COOH H N C H COONa
n n

=

8

83 14
88 , 3
61 14
3
+
=
+ n n
Gii ra c : n = 1 => CTCT ca A l H
2
N-CH
2
-
COOH Chn D
ADCT trn =>
2 n 2n
H N C H COOH
n

=
mui amino
m m 3,88 3
0,04mol
22 22

= =

2 n 2n
H N C H COOH
M

=14n +61 = 1 75
04 , 0
3
= = n
Dang 9: Trn hn hp gm amin v hirocacbon ri em t chy
Xt v d sau :
Vd: t chy hon ton hn hp gm 100ml hh gm imetylamin v hai
hirocacbon ng ng k tip thu c 140ml CO2 v 250ml nc (cc V
cng iu kin). CTPT ca hai hirocacbon?
Ta thy :
Hn hp gm (C
2
H
5
)
2
NH v C
x
H
y
(x l s ngt C trung bnh ca hai HC).
Gi n l s nguyn t C trung bnh => 4 , 1
100
140
= = n
Vy mt trong hai cht phi c 1 cht c s ngt C > 1,4 , l (C
2
H
5
)
2
NH.
Cht cn li c s ngt C nh hn 1,4 => x <1,4 => hai hirocacbon ng
ng k tip trn phi thuc dy ng ng ca ankan. Vy 2 hirocacbon cn
tml CH4 v C2H6
Bi tp vn dng :
Cu 1: Anilin v phenol u p vi:
A. dd HCl B. dd NaOH C. dd Br
2
D. dd NaCl

Cu 2: Cho s : NH
3
Y Z

Bit Z c kh nng tham gia p trng gng. Y v Z ln lt l
A.C
2
H
5
OH, HCHO B.C
2
H
5
OH, CH
3
CHO
C.CH3OH, HCHO D.CH3OH, HCOOH
Cu 3: Dy gm cc cht u lmqu tm m chuyn sang mu xanh l
A. anilin, metyl amin, amoniac
B. amoni clorua, metyl amin, natri hidroxit
C. anilin, aminiac, natri hidroxit
D. metyl amin , amoniac, natri axetat.
Cu 4: C 3 cht lng: benzen,anilin,stiren ng ring bit trong 3 l mt nhn.
Thuc th phn bit 3 cht lng trn l :
A. dd phenolphtalein B. dd Br
2

C. dd NaOH D. Qu tm
CH3I HNO2 CuO
1:1 t
o

25
A. CH(NH
2
)=CHCOOH B. CH
2
=C(NH
2
)COOH
C. CH2=CHCOONH4 D. C A, B, C
Cu 163: Cho cc cht: (1) amoniac, (2) metylamin, (3) anilin, (4) dimetylamin.
Tnh baz tng dn theo th t no sau y?
A. (1) <(3) <(2) <(4). B. (3) <(1) <(2) <(4).
C. (1) <(2) <(3) <(4). D. (3) <(1) <(4) <(2).
Cu 164: Cho 0,76 gam hn hp gmamin ng ng lin tip t/d va vi
Vml dd HNO3 0,5M th thu c 2,02 g hn hp mui khan. Hai amin trn l
A. Etylamin v propylamin B. Metylamin v etylamin
C. Anilin v benzylamin D. Anilinv metametylanilin
Cu 165: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gamX tc dng vi
axit HCl (d), thu c 13,95 gam mui khan. CTCT thu gn ca X l
A. NH2CH2CH2COOH B. CH3CH(NH2)COOH
C. NH
2
CH
2
COOH D. CH
3
CH
2
CH(NH
2
)COOH
Cu 166: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l
A. metyl amin, amoniac, natri axetat
B. anilin, metyl amin, amoniac
C. anilin, amoniac, natri hiroxit
D. amoni clorua, metyl amin, natri hiroxit
Cu 167: Amin ng vi cng thc phn t C
4
H
11
N c my ng phn mch
khng phn nhnh ?
A. 4 B. 5 C. 6 D.7
Cu 168: Amin thm ng vi cng thc phn t C
7
H
9
N c my ng phn ?
A. 3 B. 4 C. 5 D. 6
Cu 169: Cho cc cht c cu to nh sau :
(1) CH
3
- CH
2
- NH
2
(2) CH
3
- NH - CH
3
(3) CH
3
- CO - NH
2
(4) NH
2
- CO - NH
2
(5) NH
2
- CH
2
- COOH (6) C
6
H
5
- NH
2


(7) C6H5NH3Cl (8) C6H5 - NH - CH3 (9) CH2 =CH - NH2.
Cht no l amin ?
A. (1); (2); (6); (7); (8) B. (1); (3); (4); (5); (6); (9)
C. (3); (4); (5) D. (1); (2); (6); (8); (9).
Cu 170: Anilin tc dng c vi nhng cht no sau y ?
(1) dd HCl (2) dd H2SO4 (3) dd NaOH (4) dd brom
(5) dd CH
3
- CH
2
- OH (6) dd CH
3
COOC
2
H
5

A. (1), (2), (3) B. (4), (5), (6) C. (3), (4), (5) D. (1), (2), (4)
Cu 171: Pht biu no sau y sai ?
A. Anilin l baz yu hn NH
3
v nh hng ht electron ca nhn benzen
ln nhm- NH
2
bng hiu ng lin hp.
B. Anilin khng lm thay i mu giy qu tm m.
C. Anilin t tan trong H
2
O v gc C
6
H
5
- k nc.
D. Nh c tnh baz , anilin tc dng c vi dung dch brom.

24
Dung dch no lm qu tm ha xanh ?
A. X
1
, X
2
, X
5
B. X
2
, X
3
, X
4
C. X
2
, X
5
D. X
1
, X
3
, X
5

Cu 154: Hp cht C
3
H
7
O
2
N tc dng c vi NaOH, H
2
SO
4
v lm mt mu
dd brom, CTCT ca n l
A. CH
3
-CHNH
2
-COOH B. H
2
N-CH
2
- CH
2
COOH
C. CH2 =CH - COONH4 D. A v B ng.
Cu 155: X l mt aminoaxit no ch cha mt nhm -NH
2
v mt nhm-COOH.
Cho 0,89 gamX p/ va vi HCl to ra 1,255 gam mui. CTCT ca X l :
A. NH
2
-CH
2
-COOH B. CH
3
-CH(NH
2
)COOH
C. CH3-CH(NH2)-CH2- COOH D. CH3-CH2-CH2-CH(NH2)COOH
Cu 156: T l
2 2
CO H O
V : V sinh ra khi t chy hon ton mt ng ng X ca
glixinl6: 7(phn ng sinhrakh N2). X t/d vi glixin cho s/p l ipeptit. X l :
A. NH
2
-CH
2
-COOH B. NH
2
-CH
2
-CH
2
-COOH
C. CH3-CH2-CH2-CH(NH2)COOH D. Kt qu khc
Cu 157: Dung dch ca cht no sau y khng lm i mu qu tm :
A. Glixin (CH2NH2-COOH)
B. Lizin (H
2
NCH
2
-[CH
2
]
3
CH(NH
2
)-COOH)
C. Axit glutamic (HOOCCH
2
CHNH
2
COOH)
D. Natriphenolat (C
6
H
5
ONa)
Cu 158: Cht no sau y ng thi tc dng c vi dd HCl v dd NaOH.
A. C2H3COOC2H5 B. CH3COONH4
C. CH
3
CH(NH
2
)COOH D. C A, B, C
Cu 159: Cc cht X, Y, Z c cng CTPT C2H5O2N. X tc dng c c vi
HCl v Na
2
O. Y tc dng c vi H mi sinh to ra Y
1
. Y
1
tc dng vi
H2SO4 to ra mui Y2. Y2 tc dng vi NaOH ti to li Y1. Z tc dng vi
NaOH to ra mt mui v kh NH
3
. CTCT ng ca X, Y, Z l :
A. X (HCOOCH2NH2), Y (CH3COONH4), Z (CH2NH2COOH)
B. X(CH
3
COONH
4
), Y (HCOOCH
2
NH
2
), Z (CH
2
NH
2
COOH)
C. X (CH
3
COONH
4
), Y (CH
2
NH
2
COOH), Z (HCOOCH
2
NH
2
)
D. X (CH2NH2COOH), Y (CH3CH2NO2), Z (CH3COONH4)
Cu 160: Mt cht hu c X c CTPT C
3
H
9
O
2
N. Cho tc dng vi dung dch
NaOH un nh, thu c mui Y v kh lm xanh giy qu tm t. Nung Y
vi vi ti xt thu c kh etan. Cho bit CTCT ph hp ca X ?
A. CH3COOCH2NH2 B. C2H5COONH4.
C. CH
3
COONH
3
CH
3
D. C A, B, C
Cu 161: Tng ng vi CTPT C2H5O2N cbaonhiu/phnccha 3nhmchc:
A. 1 B. 2 C. 3 D. 4
Cu 162: Mt hp cht hu c X c CTPT C
3
H
7
O
2
N. X phn ng c vi
dung dch Br2, X tc dng c vi NaOH v HCl. CTCT ng ca X l :

9
Cu 5: Cho cc cht: etyl axetat,etanol,axit acrylic,phenol, anilin, phenyl amoni
clorua, ancol benzylic, p crezol. Trong cc cht trn, s cht p vi NaOH l:
A. 3 B. 4 C. 5. D. 6
Cu 6: Nhn nh no sau y ko ng ?
A. cc amin u c kh nng nhn proton.
B. Tnh bazo ca cc amin u mnh hn NH3.
C. Metyl amin c tnh bazo mnh hn anilin
D. CTTQ ca amino , mnh h l : CnH2n+2+2kNk
Cu 7: dd metyl amin khng tc dng vi cht no sau y?
A. dd HCl B. dd Br2/CCl4 C. dd FeCl3 D. HNO2
Cu 8: tch ring hh kh CH
4
v CH
3
NH
2
ta dng :
A. HCl B. HCl, NaOH C. NaOH, HCl D. HNO
2

Cu 9: phn bit cc dd : CH
3
NH
2
, C
6
H
5
OH , CH
3
COOH , CH
3
CHO khng
th dng
A. qu tm , dd Br2 B. Qu tm , AgNO3/NH3
C. dd Br
2
, phenolphtalein D. Qu tm, Na kim loi
Cu 10: Cho anilin tc dng vi cc cht sau: dd Br2 , H2, CH3I, dd HCl, dd
NaOH, HNO
2
. S p xy ra l :
A. 3 B. 4 C. 5 D. 6
Cu 11: Cho cc cht sau: (1) NH
3
; (2) CH
3
NH
2
; (3) (CH
3
)
2
NH ; (4) C
6
H
5
NH
2

; (5) (C
6
H
5
)
2
NH . Th t tng dn tnh bazo ca cc cht trn l :
A. (4) <(5) <(1) <(2) <(3) B. (1) <(4) <(5) <(2) <(3)
C. (5) <(4) <(1) <(2) <(3) D. (1) <(5) <(2) <(3) <(4)
Cu 12: Cho s chuyn ha sau :

Alanin X Y Z. Cht Y l :
A. CH
3
CH(OH) COOH B. H
2
N CH
2
COOCH
3

C. CH3 CH(OH) COOCH3 D. H2N CH(CH3) COOCH3
Cu 13: chng minh glyxin C
2
H
5
O
2
N l mt amino axit , ch cn cho p vi
A. NaOH B. HCl C. CH3OH/HCl D. HCl v NaOH
Cu 14: ng vi CT C
3
H
7
O
2
N c bao nhiu ng phn amino axit ?
A. 2 B. 3 C. 4 D. 5
Cu 15: Hp cht khng lm i mu giy qu m l :
A. CH
3
NH
2
B. C
6
H
5
ONa
C. H2N CH2 CH(NH2) COOH D. H2NCH2 COOH
Cu 16: Cht X c CT l C
3
H
7
O
2
N . X c th tc dng vi NaOH , HCl v lm
mt mu dd Br. CT ca X l:
A. CH
2
=CH COONH
4
B. CH
3
CH(NH
2
)COOH
C. H2NCH2CH2COOH D. CH3CH2CH2NO2
+CH3OH/HCl +NH3 +HNO2

10
Cu 17: dd cht no sau y khng lmchuyn mu qu tm. ?
A. H2N(CH2)2CH(NH2)COOH. B. CH3CH(OH)COOH
C. H
2
NCH
2
COOH D. C
6
H
5
NH
3
Cl
Cu 18: Axit glutamic (HCOO(CH2)2CH(NH2)COOH) l cht
A. Ch c tnh axit B. Ch c tnh baz C. Lng tnh D. Trung tnh.
Cu 19: Cho cc loi hp cht: amino axit(X), mui amoni ca axit
cacboxylic(Y), amin(Z) este ca amino axit(T), dy gm cc hp cht u p
vi NaOH v dd HCl l :
A. X, Y,Z , T B. X,Y,T C. X,Y,Z D. Y,Z,T
Cu 20: Trong cc cht sau cht no c lin kt peptit?
A. alanin B. Protein C. Xenlulozo D. Glucozo
Cu 21: Cho 0,1 mol A ( amino axit H2N-R-COOH) phn ng ht vi HCl
to 11,15 gam mui. A l
A. Valin B. Phenylalani C. Alanin D. Glyxin
Cu 22: Amino axit X cha mt nhm COOH v 2 nhm NH2.Cho 1 mol X
tc dng ht vi dung dch NaOH, thu c 154 gam mui. CTPT ca X l:
A. C
4
H
10
N
2
O
2
B. C
5
H
10
N
2
O
2
C. C
5
H
12
N
2
O
2
D. C
6
H
14
N
2
O
2

Cu 23: Hp cht no sau y khng phi l Amino axit
A. H
2
NCH
2
COOH B. CH
3
CH
2
CONH
2

C. CH3NHCH2COOH D. HCOOCCH2CH(NH2)COOH
Cu 24: C 3 cht: butylamin, anilin v amoniac. Th t tng dn lc baz l
A. NH
3
<C
6
H
5
NH
2
<C
4
H
9
NH
2
B. C
6
H
5
NH
2
<NH
3
<C
4
H
9
NH
2

C. C4H9NH2 <NH3 <C6H5NH2 D. C4H9NH2 <C6H5NH2 <NH3
Cu 25: Hp cht hu c X c mch cacbon khng phn nhnh, bc nht (cha
C, H, N), trong nit chim 23,73% v khi lng. Bit X tc dng c vi
HCl vi t l s mol
X HCl
n : n 1:1 = . Cng thc phn t ca X l
A. CH
3
NH
2
B. CH
3
CH
2
NH CH
3

C. CH3 CH(CH3) NH2 D. CH3 CH2 CH2 NH2
Cu 26: Cho 20 gamhn hp gm 3 amin no, n chc l ng ng k tip
nhau tc dng va vi dung dch HCl 1M, c cn dung dch thu c 31,68
gammui. Th tch dung dch HCl dng l
A. 16ml B. 32ml C. 160ml D. 320ml
Cu 27: t chy hon ton 1 amin no n chc, bc 2, mch h X thu c
CO2 v hi nc theo t l s mol tng ng l 2 : 3. CTCTca X l
A. CH
3
NH CH
3
B. CH
3
NH C
2
H
5

C. CH
3
CH
2
CH
2
NH
2
D. C
2
H
5
NH C
2
H
5

Cu 28: t chy hon ton hn hp 2 amin no n chc ng ng lin tip,
thu c
2 2
H O CO
n : n 2:1 = . Hai amin c cng thc phn t l:
A. C
2
H
5
NH
2
v C
3
H
7
NH
2
B. CH
3
NH
2
v C
2
H
5
NH
2

C. C
3
H
7
NH
2
v C
4
H
9
NH
2
D. C
4
H
9
NH
2
v C
5
H
11
NH
2


23
Cu 145: -aminoaxit X cha mt nhm -NH
2
. Cho 10,3 gamX tc dng vi
axit HCl (d), thu c 13,95 gam mui khan. CTCT thu gn ca X l
A. H
2
NCH
2
CH
2
COOH. B. H
2
NCH
2
COOH.
C. CH3CH(NH2)COOH. D. CH3CH2CH(NH2)COOH.
Cu 146: Cho hn hp X gm hai cht hu c c cng cng thc phn t
C2H7NO2 tc dng va vi dd NaOH v un nng, thu c dd Y v 4,48 lt
hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z
i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l :
A. 8,9 gam. B. 15,7 gam. C. 16,5 gam. D. 14,3 gam.
Cu 147: t chy hon ton mt lng cht hu c X thu c 3,36 lt kh
CO
2
, 0,56 lt kh N
2
(cc kh o ktc) v 3,15 gam H
2
O. Khi X tc dng vi
dd NaOH thu c s/p c mui H
2
N-CH
2
-COONa. CTCT thu gn ca X l
A. H
2
N-CH
2
-COO-C
3
H
7
. B. H
2
N-CH
2
-COO-CH
3
.
C. H
2
N-CH
2
-COO-C
2
H
5
. D. H
2
N-CH
2
-CH
2
-COOH.
Cu 148: Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l
A. protit lun cha chc hiroxyl. B. protit lun cha nit.
C. protit lun l cht hu c no. D. protit c khi lng phnt ln hn.
Cu 149: Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic
(Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng
c vi dung dch NaOH v u tc dng c vi dung dch HCl l
A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T.
Cu 150: Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l
A.. dd NaCl. B. dd HCl. C. Cu(OH)
2
/OH
-
. D. dd NaOH.
Cu 151: Este A c iu ch t amino axit B v ru metylic. T khi hi
ca A so vi hiro l 44,5. t chy hon ton 8,9gam este A thu c
13,2gamkh CO2, 6,3gamH2O v 1,12 lit N2(ktc). CTCT ca A v B l
A. NH
2
-CH
2
-COOCH
3
v NH
2
-CH
2
-COOH.
B. NH2-CH2-CH2-COOCH3 v NH2-CH2-COOH
C. CH
3
COOCH
3
v NH
2
-CH
2
-COOH.
D. NH2-CH2-COOH v NH2-CH2-CH2-COOH
Cu 152: Cho qu tm vo mi dung dch hn hp di y, dung dch no lm
qu tm ha ?
(1) H
2
N - CH
2
- COOH (2) Cl - NH
3
+
- CH
2
- COOH
(3) NH
2
- CH
2
- COONa (4) H
2
N- CH
2
-CH
2
-CH(NH
2
)- COOH
(5) HOOC- CH2-CH2-CHNH2- COOH
A. (2), (4) B. (3), (1) C. (1), (5) D. (2), (5).
Cu 153: Cho dung dch cha cc cht sau: X1 : C6H5 - NH2; X2 : CH3 - NH2;
X
3
: NH
2
- CH
2
COOH; X
4
: HOOC-CH
2
-CH
2
-CHNH
2
COOH;
X5 : H2N- CH2-CH2-CH2-CHNH2COOH.

22
Cu 137: Hp cht X cha cc nguyn t C, H, O, N v c phn t khi l 89.
Khi t chy honton 1 mol X thu c hi nc, 3mol CO
2
v 0,5mol N
2
.
Bit rng X l hp cht lng tnh v t/dng c vi nc Br
2
. X c CTCT l
A. H2N-CH=CH-COOH. B. CH2=CH(NH2)COOH.
C. CH
2
=CH-COONH
4
. D. CH
3
-CH(NH
2
)-COOH.
Cu 138: Hai hp cht hu c X v Y c cng CTPT l C2H7NO2. Bit
X +NaOH =>A +NH
3
+H
2
O Y +NaOH =>B +CH
3
-NH
2
+H
2
O.
A v B c th l:
A. HCOONa v CH
3
COONa. B. CH
3
COONa v HCOONa.
C. CH3NH2 v HCOONa. D. CH3COONa v NH3.
Cu 139: X l mt -aminoaxit no ch cha mt nhm-NH
2
v mt nhm-
COOH. Cho 14,5gamX tc dng vi dung dch HCl d thu c 18,15gam
mui clorua ca X. CTCT ca X c th l
A. CH
3
CH(NH
2
)COOH. B. H
2
NCH
2
COOH.
C.CH3CH2CH(NH2)COOH. D. CH3[CH2]4CH(NH2)COOH.
Cu 140: X l mt -aminoaxit. Cho 0,01mol X tc dng va vi 80ml dd
HCl 0,125M, sau em c cn dd thu c 1,835gam mui. Phn t khi ca
X l
A. 174. B. 147. C. 197. D. 187.
Cu 141: Cho cc cht : (1)C
6
H
5
-NH
2
; (2) C
2
H
5
NH
2
; (3) (C
2
H
5
)
2
NH; (4) NaOH;
(5): NH
3
. Dy c sp xp theo chiu tng ca lc baz l
A. (1)<(5)<(2)<(3)<(4). B. (1)<(2)<(5)<(3)<(4).
C. (1)<(5)<(3)<(2)<(4). D. (2)<(1)<(3)<(5)<(4).
Cu 142: trung ha 200ml dung dch amino axit X cn 100g dung dch
NaOH 8%, c cn dung dch c 16,3g mui khan. X c CTCT l
A. NH
2
CH
2
CH
2
COOH. B. H
2
NCH(COOH)
2
.
C. (H2N)2CHCOOH. D. H2NCH2CH(COOH)2.
Cu 143: Cho cht hu c X c cng thc phn t C
2
H
8
O
3
N
2
tc dng vi dung
dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng
phn t (theo vC) ca Y l
A. 85 B. 68 C. 45 D. 46
Cu 144: Hp cht X c cng thc phn t trng vi cng thc n gin nht,
va tc dng c vi axit va tc dng c vi kim trong iu kin thch
hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C,
H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45
gamX phn ng hon ton vi mt lng va dung dch NaOH (un nng)
thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l
A. CH
2
=CHCOONH
4
. B. H
2
NCOO-CH
2
CH
3
.
C. H2NCH2COO-CH3. D. H2NC2H4COOH.

11
Cu 29: T l th tch ca CO
2
: H
2
O khi t chy hon ton mt ng ng X
ca glixin l 6 : 7 (phn ng chy sinh ra N
2
). X tc dng vi glixin cho sn
phm ipeptit. Cng thc cu to ca X l:
A. CH3CH(NH2)COOH B. NH2CH2CH2COOH
C. C
2
H
5
CH(NH
2
)COOH D. A v B ng
Cu 30: Hy chn trnh t tin hnh no trong cc trnh t sau phn bit
dung dch cc cht: CH
3
NH
2
, H
2
NCOOH, CH
3
COONH
4
, anbumin.
A. Dng qu tm, dng dd HNO3 c , dng dd NaOH
B. Dng qu tm, dng Ca(OH)
2

C. Dng Cu(OH)2 , dng phenolphtalein, dng dd NaOH
D. Dng qu tm, dng dd CuSO
4
, dng dd NaOH
Cu 31: X l mt o amino axit no ch cha mt nhm - NH2 v mt nhm
COOH. Cho 13,1g X tc dng vi dung dch HCl d, ta thu c 16,75g mui
clohirat ca X. X c cng thc cu to no sau y?
A. CH
3
CH
2
(NH
2
)COOH B. H
2
N(CH
2
)
3
COOH
C. CH
3
(CH
2
)
4
(NH
2
)COOH D. H
2
N(CH
2
)
5
COOH
Cu 32: Mt hp cht hu c X c cng thc C
3
H
7
O
2
N. X phn ng vi dd
brom, X tc dng vi dung dch NaOH v HCl. Cht hu c X c CTCT l:
A. H2N CH =CH COOH B. CH2 =CH COONH4
C. H
2
N CH
2
CH
2
COOH D. A v B ng
Cu 33: Hp cht hu c X c phn t khi nh hn phn t khi ca benzen,
ch cha C, H, O, N trong H chim 9,09%, N chim 18,18%. t chy 7,7g
X, thu c 4,928 lt kh CO2 o 27,3
0
C, 1 atm. X tc dng vi dung dch
NaOH cho mui ca axit hu c. X c cng thc cu to no sau y?
A. CH3COONH4 B. HCOONH3CH3
C. H
2
NCH
2
CH
2
COOH D. A v B ng
Cu 34: Hy sp xp cc cht sau y theo trnh t tnh baz tng dn t tri
sang phi: amoniac,anilin, p-nitroanilin, p-nitrotoluen, metylamin, imetylamin.
A. C
6
H
5
NH
2
<O
2
NC
6
H
4
NH
2
<H
3
CC
6
H
4
NH
2
<NH
3
<CH
3
NH
2
<(CH
3
)
2
NH
B. O2NC6H4NH2 <C6H5NH2 <H3CC6H4NH2 <NH3 <CH3NH2 <(CH3)2NH
C. O
2
NC
6
H
4
NH
2
<H
3
CC
6
H
4
NH
2
<C
6
H
5
NH
2
<NH
3
<CH
3
NH
2
<(CH
3
)
2
NH
D. Tt c u sai
Cu 35: t chy ht a mol mt aminoaxit c 2a mol CO
2
v a/2mol N
2
.
Aminoaxit trn c cng thc cu to l:
A. H
2
NCH
2
COOH B. H
2
N(CH
2
)
2
COOH
C. H
2
N(CH
2
)
3
COOH D. H
2
NCH(COOH)
2

Cu 36: t chy mt amin X n chc no, thu c CO
2
v H
2
O c t l s
mol
2 2
CO H O
n : n 2:3 = . Amin X c tn gi l:
A. Etyl amin B. Metyl etyl amin C. Trimetyl amin D. Kt qu khc

12
Cu 37: C hai amin bc mt: X (ng ng ca anilin) v Y (ng ng ca
metylamin). t chy hon ton 3,21g amin X sinh ra kh CO
2
v hi nc v
336 cm
3
kh nit (ktc). Khi t chy hon ton amin Y cho
2 2
CO H O
n : n 2:3 = .
Cng thc phn t ca amin l:
A. CH3C6H4NH2, CH3CH2CH2NH2 B. C2H5C6H4NH2 , CH3CH2CH2NH2
C. CH
3
C
6
H
4
NH
2
, CH
3
(CH
2
)
4
NH
2
D. A v B ng
Cu 38: t chy hon ton mt aminthm X thu c 3,08g CO2 v 0,9g H2O
v 336ml N
2
(o ktc). trung ho 0,1 mol X cn dng 600ml HCl 0,5M.
Cng thc phn t ca X l cng thc no sau y:
A. C7H11N B. C7H8NH2 C. C7H11N3 D. C8H9NH2
Cu 39: t chy hon ton 6,2g mt aminno n chc cn dng 10,08 lt kh
oxi (ktc). Cng thc phn t ca amin l:
A. C
2
H
5
NH
2
B. C
3
H
7
NH
2
C. CH
3
NH
2
D. C
4
H
9
NH
2

Cu 40: t chy hon ton mgammt amin X bng lng khng kh va
thu c 17,6g CO
2
v 12,6g H
2
O v 69,44 lt nit. Gi thit khng kh ch gm
nit v xi, trong oxi chim 20% th tch. Cc th tch o ktc. Amin X c
cng thc phn t l:
A. C
2
H
5
NH
2
B. C
3
H
7
NH
2
C. CH
3
NH
2
D. C
4
H
9
NH
2

Cu 41: Cho 20 gam hn hp 3 aminno, n chc, ng ng k tip, tc dng
vi dung dch HCl va , sau c cn thu c 31,68 hn hp mui. Nu 3
amin trn trn theo th t khi lng mol tng dn vi s mol c t l 1: 10: 5
th amin c khi lng phn t nh nht c cng thc phn t l:
A. CH3NH2 B. C2H5NH2 C. C3H7NH2 D. C4H11NH2
Cu 42: Cng thc phn t ca amin cha 23,73% khi lng nit?
A. C2H5NH2 B. C6H5NH2 C. (CH3)2NH D. (CH3)3N
Cu 43: Cho 9,85 gam hn hp 2 amin, n chc, bc 1 tc dng va vi
dung dch HCl thu c 18,975 gam mui. Khi lng HCl phi dng l
A. 9,521 B. 9,125 C. 9,215 D. 9,512
Cu 44: X l hp cht hu c mch h, cha cc nguyn t C, H, N, trong N
chim 31,11%% v khi lng. X tc dng vi dung dch HCl theo t l 1:1. X
c s ng phn l:
A. 2 B. 3 C. 4 D. 5
Cu 45: trung ha 200ml dung dch aminoaxit X 0,5M cn 100g dung dch
NaOH 8%. C cn dd thu c 16,3g mui khan. X c cng thc cu to l:
A. H
2
NCH(COOH)
2
B. H
2
NCH
2
CH(COOH)
2

C. (H2N)2CHCH2(COOH)2 D. Av B ng
Cu 46: Hp cht X gm cc nguyn t C, H, O, N vi t l khi lng tng
ng l 3:1:4:7. Bit phn t ch c 2 nguyn t nit. X c cng thc phn t l:
A. CH4ON2 B. C3H8ON2 C. C3H10O2N2 D. C4H12O2N2

21
Cu 127: S ng phn cu to ca amin bc mt c cng CTPT C
4
H
11
N l
A. 2 B. 5 C. 4 D. 3
Cu 128: Cht X c cng thc phn t C
3
H
7
O
2
N v lm mt mu dung dch
brom. Tn gi ca X l
A. axit -aminopropionic B. mety aminoaxetat
C. axit - aminopropionic D. amoni acrylat
Cu 129: Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t
khi ca X bng 100.000 vc th s mt xch alanin c trong phn t X l
A. 453 B. 382 C. 328 D. 479
Cu 130: Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc
phn t C3H9O2N tc dng va vi dd NaOH, un nng thu c kh Y v
dung dch Z. C cn Z thu c 1,64 gam mui khan. CTCT thu gn ca X l
A. CH3CH2COONH4. B. CH3COONH3CH3.
C. HCOONH
2
(CH
3
)
2
. D. HCOONH
3
CH
2
CH
3
.
Cu 131: Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl,
sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dd Y
c 9,55 gam mui khan. S cng thc cu to ng vi CTPT ca X l
A. 2. B. 4. C. 5. D. 3.
Cu 132: Trong phn t aminoaxit X c mt nhm amino v mt nhm
cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung
dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l
A. H2NC3H6COOH. B. H2NC2H4COOH.
C. H
2
NC
4
H
8
COOH. D. H
2
NCH
2
COOH.
Cu 133: un nng cht H
2
N-CH
2
-CONH-CH(CH
3
)-CONH-CH
2
-COOH trong
dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l :
A. H
2
N-CH
2
-COOH, H
2
H-CH
2
-CH
2
-COOH
B. H
3
N
+
-CH
2
-C, H
3
N
+
-CH
2
-CH
2
-COOHClOOHCl
C. H3N
+
-CH2-C, H3N
+
-CH(CH3)-COOOHClOHCl
D. H
2
N-CH
2
-COOH, H
2
N-CH(CH
3
)-COOH
Cu 134: Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N
phn ng vi 100 ml dd NaOH 1,5M. Sau khi phn ng xy ra hon ton, c
cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l :
A. HCOOH3NCH=CH2 B. H2NCH2CH2COOH
C. CH
2
=CHCOONH
4
D. H
2
NCH
2
COOCH
3

Cu 135: Khi t chy cc ng ng ca metylamin, t l s mol a = nCO
2
/
nH2O bin i trong khong no
A. 0,4 <a<1,2. B. 1 <a<2,5. C. 0,4 <a <1. D. 0,75 <a <1.
Cu 136: Amino axit X cha mt nhmchc amino trong phn t. t chy
hon ton mt lngX thu c CO2 v N2 theo t l th tch 4:1.X c tn gi l
A. Axit aminoetanonic. B. Axit 3-amino propanoic.
C. Axit 2,2-iaminoetanoic. D. Axit -4-aminobutanoic.

20
Cc trng hp c kh nng tham gia phn ng trng ngng?
A. 1, 2 B. 3, 5 C. 3, 4 D. 1, 2, 3, 4, 5.
Cu 119: Poli peptit l hp cht cao phn t c hnh thnh t cc :
A. Phn t axit v ru . B. Phn t amino axit .
C. Phn t axit v andehit . D. Phn t ru v amin .
Cu 120: t chy hon ton hn hp 2 amin no n chc l ng ng k tip
thu c 2,24lit kh CO
2
(ktc) v 3,6gam H
2
O. Cng thc ca hai amin l
A. CH3NH2 v C2H5NH2. B. C2H5NH2 v C3H7NH2.
C. C
3
H
7
NH
2
v C
4
H
9
NH
2
. D. C
5
H
11
NH
2
v C
6
H
13
NH
2
.
Cu 121: Khi t chy hon ton mt amin n chc X thu c 10,125gam
H
2
O, 8,4lt CO
2
(kc) v 1,4lt N
2
. S ng phn ng vi CTPT ca X l
A. 2. B. 3. C. 4. D. 5.
Cu 122: Dung dch X gm HCl v H
2
SO
4
c pH = 2. trung ho hon ton
0,59gam hn hp hai amin no n chc, bc 1 ( c s nguyn t C nh hn
hoc bng 4 th phi dng 1 lt dung dch X. Cng thc phn t ca 2 amin l
A. CH
3
NH
2
v C
4
H
9
NH
2
. B. C
3
H
7
NH
2
v C
4
H
9
NH
2
.
C. C2H5NH2 v C4H9NH2. D. A v C.
Cu 123: Hp cht X mch h c CTPT l C
4
H
9
NO
2
. Cho 10,3 gam X p/ng
va vi dd NaOH sinh ra mt cht kh Y v dd Z. Kh Y nng hn khng
kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt
mu nc brom. C cn dd Z thu c m gam mui khan. Gi tr ca m l
A.8,2. B. 10,8. C. 9,4. D. 9,6.
CH
2
=CHCOONH
3
CH
3
+NaOH =>CH
2
=CHCOO Na +CH
3
NH
2
+H
2
O
Cu 124: Pht biu no sau y l ng?
A. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni.
B. Benzen lmmt mu nc brom nhit thng.
C. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh.
D. Cc ancol a chc u phn ng vi Cu(OH)2 to dd mu xanh lam.
Cu 125: Cho hai hp cht hu c X, Y c cng cng thc phn t l C
3
H
7
NO
2

. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c
Z ; cn Y to ra CH
2
=CHCOONa v kh T. Cc cht Z v T ln lt l
A. CH
3
OH v CH
3
NH
2
B. C
2
H
5
OH v N
2

C. CH3OH v NH3 D. CH3NH2 v NH3
Cu 126: : Cht X c cng thc phn t C
4
H
9
O
2
N . Bit :
X +NaOH Y + CH
4
O; Y + HCl (d) Z + NaCl
Cng thc cu to ca X v Z ln lt l
A. H
2
NCH
2
CH
2
COOCH
3
v CH
3
CH(NH
3
Cl)COOH
B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH
C. H
2
NCH
2
COOC
2
H
5
v ClH
3
NCH
2
COOH
D. CH
3
CH(NH
2
)COOCH
3
v CH
3
CH(NH
2
)COOH

13
Cu 47: A l -amioaxit (c cha 1 nhm NH
2
). t chy 8,9g A bng O
2

va c 13,2g CO
2
; 6,3g H
2
Ov 1,12 lt N
2
(ktc). A c CTPT l :
A. C
2
H
5
NO
2
B. C
3
H
7
NO
2
C. C
4
H
9
NO
2
D. C
6
H
9
NO
4

Cu 48: -aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi
axit HCl (d), thu c 13,95 gam mui khan. CTCT thu gn ca X l
A. H2NCH2CH2COOOH B. CH3CH(NH2)COOH
C. H
2
NCH
2
COOH D. CH
3
CH
2
CH(NH
2
)COOH
Cu 49: C7H9N c s ng phn cha nhn thm l.
A. 6. B. 5. C. 4. D. 3.
Cu 50: Hp cht Y l mt amin n chc cha 20,89% N theo khi lng. Y
c cng thc phn t l
A. C4H5N B. C4H7N C. C4H9N D. C4H11N
Cu 51: A l hp cht hu c cha C,H,O,N. t chy 1 mol A c 2 mol
CO2; 2,5mol H2O; 0,5mol N2. ng thi phi dng 2,25mol O2. A c CTPT l:
A. C
2
H
5
NO
2
B. C
3
H
5
NO
2
C. C
6
H
5
NO
2
D. C
3
H
7
NO
2

Cu 52: t chy hon ton mt amin thm X thu c 0,07 mol CO2 , 0,99g
H
2
O v 336 ml N
2
(ktc). trung ha 0,1 mol X cn 600 ml dd HCl 0,5M.
Bit X l amin bc 1 . X c cng thc l,
A. CH
3
-C
6
H
2
(NH
2
)
3
B. C
6
H
3
(NH
2
)
3

C. CH
3
NH C
6
H
3
(NH
2
) D. NH
2
C
6
H
2
(NH
2
)
2

Cu 53: trung ha ht 3,1 g mt amin n chc cn dng 100ml dd HCl
1M. amin l;
A. CH5N B. C2H7N C. C3H3N D. C3H9N
Cu 54: C 3 dd sau: H
2
N CH
2
CH
2
COOH ; CH
3
CH
2
COOH ;
CH
3
(CH
2
)
3
NH
2
. phn bit cc dd trn ch cn dng thuc th l:
A. dd NaOH B. dd HCl C. Qu tm D. phenolphtalein
Cu 55: Mt este c CT C
3
H
7
O
2
N, bit este c iu ch t amino axit X
v ru metylic. Cng thc cu to ca amino axit X l:
A. CH
3
CH
2
COOH B. H
2
N CH
2
COOH
C. NH
2
CH
2
CH
2
COOH D. CH
3
CH(NH
2
) COOH
Cu 56: Amin c cha 15,05% N v khi lng c CT l :
A. C
2
H
5
NH
2
B. C
3
H
7
NH
2
C. C
6
H
5
NH
2
D. (CH
3
)
3
N
Cu 57: Cho 9,3 g mt ankyl amin X tc dng vi dd FeCl
3
d thu c 10,7g
kt ta. Cng thc cu to ca X l:
A. CH
3
NH
2
B. C
2
H
5
NH
2
C. C
3
H
7
NH
2
D. C
4
H
9
NH
2

Cu 58: Ba cht A, B, C (CxHyNz) c thnh phn % theo khi lng N trong A,
B, C ln lt l 45,16%; 23,73%; 15,05%; A , B, C tc dng vi axit cho
mui amoni R NH
3
Cl CT ca A, B, C ln lt l:
A. CH3NH2, C3H7NH2, C4H9NH2 B. CH3NH2, C3H7NH2, C6H5NH2
C. CH
3
NH
2
, C
4
H
9
NH
2
, C
6
H
5
NH
2
D. CH
3
NH
2
, C
6
H
5
NH
2
, C
2
H
5
NH
2


14
Cu 59: Hp cht C
3
H
7
O
2
N tc dng vi NaOH , H
2
SO
4
v lmmt mu dd
Br
2
nn CTCT hp l ca hp cht l:
A. CH
3
CH(NH
2
) COOH B. CH
2
(NH
2
) CH
2
COOH
C. CH2 =CH COONH4 D. CH3 CH2 COONH4
Cu 60: Cht X c %C =40,45%; %H =7,86%; %N =15,73% cn li Oxi. M
X

<100. Khi X p vi NaOH cho mui C3H6O2Na. Cng thc phn t ca X l
A. C
4
H
9
O
2
N B. C
3
H
7
O
2
N C. C
2
H
5
O
2
N D. CH
3
O
2
N
Cu 61: Cho 1 este A c iu ch t aminoaxit B v ancol Metylic. T khi
hi ca A so vi H
2
= 44,5. t chy hon ton 8,9 g este A thu c 13,2g
CO2, 6,3 g H2O, 1,12 lt N2 (ktc).Cng thc cu to ln lt ca A v B l :
A. H
2
N CH
2
COO CH
3
v H
2
N CH
2
COOH
B. H
2
N CH
2
CH
2
COOCH
3
v H
2
N CH
2
COOH
C. H
2
N CH
2
COO CH
3
v CH
3
CH
2
COOH
D. H
2
N CH(CH
3
) COO CH
3
V H
2
N CH
2
COOH
Cu 62: Mt aminoaxit no X tn ti trong t nhin gm ( ch cha 1 nhm
NH
2
v mt nhm COOH). Cho 0,89 g X p va vi HCl to ra 1,255 g
mui . Cng thc cu to ca X l:
A. H
2
N CH
2
COOH B. CH
3
CH(NH
2
)- COOH
C. H2N-CH2-CH2-COOH D. B,C ng
Cu 63: trung ha 50 ml dd metyl amin cn 40 ml dd HCl 0,1 M. Tnh C
M

ca metyl amin dng l :
A. 0,08M B. 0,04M C. 0,02M D. 0,06M
Cu 64: Hp cht X cha cc nguyn t C,H,O,N v c MX = 89. Khi t chy
1 mol X thu c 3 mol CO2 v 0,5 mol N2. Bit hp cht lng tnh v tc
dng vi nc Br
2
. X l
A. H
2
N CH =CH COOH B. CH
2
=CH(NH
2
) COOH
C. CH2 =CH COONH4 D. CH2 =CH CH2 NO2
Cu 65: Cho mg anilin tc dng vi dd HCl c d, c cn dung dch sau p
thu c 15,54 g mui khan. Hiu sut p t 80% . m c gi tr l :
A. 13,95g B. 8,928g C. 11,16g D. 12,5g
Cu 66: Cho 20g hh 3 amin: metyl amin, etyl amin, anlyl amin t/d va vi V
ml dd HCl 1M . Sau p c cn dd thu c 31,68 g mui khan. Gi tr ca V l:
A. 120ml B. 160ml C. 240ml D. 320 ml
Cu 67: Cho 4,41 g mt amino axit X tc dng vi dd NaOH d thu c 5,73
g mui . Mt khc cng lng X trn nu cho tc dng vi HCl d thu c
5,505 g mui clorua . Cng thc cu to ca X l:
A. HCOOC CH
2
CH
2
CH(NH
2
) COOH
B. CH3 CH(NH2) COOH
C. HOOC CH
2
CH(NH
2
)CH
2
COOH
D. C A v C

19
Cu 108: Khi thy phn n cng protein thu c cc cht :
A. o -Gucoz v | -Glucoz B. Axit
C. Amin D. Aminoaxit
Cu 109: Trong cc cht sau :
X
1
: H
2
N CH
2
COOH X
2
: CH
3
NH
2

X
3
: C
2
H
5
OH X
4
: C
6
H
5
NH
2

Nhng cht c kh nng th hin tnh baz l :
A. X
1
,X
3
B. X
1
,X
2
C. X
2
,X
4
D. X
1
,X
2
,X
3

Cu 110: Khi un nng dd protein xy ra h/tng no trong s cc h/tng sau?
A. ng t B. Bin i mu ca dung dch
C. Tan tt hn D. C kh khng mu bay ra
Cu 111: nhn bit dung dch glixin, h tinh bt, lng trng trng, ta c th
tin hnh theo th t no sau y :
A. Dng qu tm, dng dung dch iot B. Dng dd iot , dng dd HNO
3

C. Dng qu tm, dng dng dd HNO3 D. Dng Cu(OH)2, dng dd HNO3
Cu 112: Mt amino axit A c 40,4% C ; 7,9% H ; 15,7 % N; 36%O v M
A
=
89. Cng thc phn t ca A l :
A. C4H9O2N B. C3H5O2N C. C2H5O2N D. C3H7O2N
Cu 113: Cho 0,01 mol amino axit A tc dng va 80 ml dung dch HCl
0,125 M.C cn dung dch thu c 1,835 gam mui . Khi lng ca A l :
A. 9,7 B. 1,47 C. 1,2 D. 1,5
Cu 114: Cho 0,1 mol A (aminoaxit dng H
2
NRCOOH) phn ng ht vi
HCl to 11,15 gam mui. A l cht no di y?
A. Valin B. Glixin C. Alanin D. Phenylalanin
Cu 115: Cho 0,01 mol amino axit X phn ng ht vi 40 ml dung dch HCl
0,25M to thnh 1,115gammui khan. X c CTCT no sau :
A. NH2-CH2-COOH B. NH2-(CH2)2-COOH
C. CH
3
COONH
4
D. NH
2
-(CH
2
)
3
-COOH
Cu 116: Cho 0,01 mol aminoaxit A phn ng va vi 0,02 mol HCl hoc
0,01 mol NaOH. Cng thc ca A c dng nh th no?
A. (H
2
N)
2
R(COOH)
2
B. (H
2
N)
2
RCOOH
C. H2NRCOOH D. H2NR(COOH)2
Cu 117: Tn gi no sai so vi CT tng ng:
A. H
2
N-CH
2
-COOH : glixin
B. CH3-CH(NH2)-COOH : -Alanin
C. HOOC - CH
2
- CH
2
- CH(NH
2
) - COOH : axit glutamic
D. H
2
N - (CH
2
)
4
- CH(NH
2
) - COOH: Lisin
Cu 118: Cho cc cht sau y:
(1) CH
3
-CH(NH
2
)-COOH (2) OH-CH
2
-COOH
(3) CH
2
O v C
6
H
5
OH (4) C
2
H
4
(OH)
2
v p - C
6
H
4
(COOH)
2

(5) (CH2)6(NH2)2 v (CH2)4(COOH)2

18
Cu 96: Cht no l amin bc 2 ?
A. H
2
N CH
2
NH
2
. B. (CH
3
)
2
CH NH
2
.
C. CH
3
NH CH
3
. D. (CH
3
)
3
N.
Cu 97: Cho 4,5 gametylamin (C2H5NH2) tc dng va vi axit HCl. Khi
lng mui thu c l
A. 8,15 gam B. 0,85 gam C. 7,65 gam D. 8,10 gam
Cu 98: Th tch nc brom 3% (d = 1,3g/ml) cn dng iu ch 4,4g
tribromanilin l
A. 164,1ml. B. 49,23ml. C. 146,1ml. D. 16,41ml.
Cu 99: Khi lng anilin cn dng tc dng vi nc brom thu c 6,6g
kt ta trng l
A. 1,86g. B. 18,6g. C. 8,61g. D. 6,81g.
Cu 100: Mt amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl .
Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. X c th l :
A. axit glutami B. valin. C. glixin D. alanin.
Cu 101: chng minh tnh lng tnh ca NH
2
-CH
2
-COOH(X),ta cho X t/d vi
A. HCl, NaOH. B. Na2CO3, HCl.
C. HNO
3
, CH
3
COOH. D. NaOH, NH
3
.
Cu 102: Cho cc phn ng :
H2N CH2 COOH +HCl Cl
-
H3N
+
CH2 COOH.
H2N CH2 COOH +NaOH H2N CH2 COONa +H2O.
Hai phn ng trn chng t axit amino AxetiC.
A. C tnh axit B. C tnh cht lng tnh
C. C tnh baz D. C tnh oxi ha v tnh kh
Cu 103: Cho cc cht: (1) amoniac; (2) metylamin; (3) anilin; (4) imetylamin.
Tnh baz tng dn theo th t no sau y?
A. (1) <(3) <(2) <(4). B. (3) <(1) <(2) <(4).
C. (1) <(2) <(3) <(4). D. (3) <(1) <(4) <(2)
Cu 104: Mt amin A thuc cng dy ng ng vi metylamin c hm lng
cacbon trong phn t bng 68,97%. Cng thc phn t ca A l.:
A. C
2
H
7
N. B. C
3
H
9
N. C. C
4
H
11
N. D. C
5
H
13
N.
Cu 105: Hp cht no sau y khng phi l amino axit :
A. CH
3
CONH
2
B. CH
3
CH(NH
2
)CH(NH
2
)COOH
C. HOOC-CH(NH2)CH2COOH D. CH3CH(NH2)COOH
Cu 106: Axit amino axetic khng tc dng vi cht :
A. CaCO
3
B. H
2
SO
4
long C. KCl D. CH
3
OH
Cu 107: Aminoaxit c kh nng tham gia phn ng este ha v :
A. Aminoaxit l cht lng tnh B. Aminoaxit c nhmchc -COOH
C. Aminoaxit chc nhm chc NH2 D. Tt c u sai

15
Cu 68: S ng phn amin c cng thc phn t C
2
H
7
N l
A. 2. B. 4. C. 5. D. 3.
Cu 69: Cho cc phn ng:
H2N - CH2 - COOH +HCl =>H3N
+
- CH2 - COOH Cl
-
.
H
2
N - CH
2
- COOH +NaOH =>H
2
N - CH
2
- COONa +H
2
O.
Hai phn ng trn chng t axit aminoaxetic
A. c tnh cht lng tnh. B. ch c tnh axit.
C. ch c tnh baz. D. va c tnh oxi ho, va c tnh kh.
Cu 70: Anilin (C
6
H
5
NH
2
) c phn ng vi dung dch
A. NaOH. B. Na
2
CO
3
. C. NaCl. D. HCl.
Cu 71: Cho 8,9 gammt hp cht hu c X c cng thc phn t C3H7O2N
phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon
ton, c cn dung dch thu c 11,7 gam cht rn. CTCT thu gn ca X l
A. HCOOH
3
NCH=CH
2
. B. H
2
NCH
2
CH
2
COOH.
C. CH
2
=CHCOONH
4
. D. H
2
NCH
2
COOCH
3
.
Cu 72: Cho dy cc cht: C6H5OH(phenol), C6H5NH2(anilin), H2NCH2COOH,
CH
3
CH
2
COOH, CH
3
CH
2
CH
2
NH
2
. S cht trong dy t/d c vi dd HCl l
A.4. B. 2. C. 3. D. 5.
Cu 73: Cht no sau y khng kh nng tham gia phn ng trng ngng :
A. CH3CH(NH2)COOH B. HCOOCH2CH2CH2NH2
C. CH
3
CH(OH)COOH D. HOCH
2
- CH
2
OH
Cu 74: Cho 12,55g mui CH
3
CH(NH
3
Cl)COOH t/d vi 150ml dd Ba(OH)
2

1M. C cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l :
A. 15,65 g B. 26,05 g C. 34,6 g D. Kt qu khc
CH3CH(NH3Cl)COOH +Ba(OH)2 =>(CH3CH(NH3)COO)2Ba +BaCl2 +H2O
Cu 75: Cho 22,15 g mui gm CH
2
NH
2
COONa v CH
2
NH
2
CH
2
COONa tc
dng va vi 250 ml dung dch H
2
SO
4
1M. Sau phn ng c cn dung dch
th lng cht rn thu c l :
A. 46,65 g B. 45,66 g C. 65,46 g D. Kt qu khc
Cu 76: Cho 13,35g hh X gm H2NCH2CH2COOH v CH3CH(NH2)COOH tc
dng vi V ml dung dch NaOH 1M thu c dung dch Y. Bit dung dch Y
tc dng va vi 250 ml dung dch HCl 1M. Gi tr ca V l
A. 100 ml B. 150 ml C. 200 ml D. 250 ml
Cu 77: Cho 20,15 g hn hp X gm (CH
2
NH
2
COOH v CH
3
CHNH
2
COOH)
tc dng vi 450 ml dung dch HCl 1M thu c dung dch Y. Y tc dng va
vi 200 ml dung dch NaOH. Phn trm khi lng ca mi cht trong X l:
A. 55,83 % v 44,17 % B. 53,58 % v 46,42 %
C. 58,53 % v 41,47 % D. 52,59 % v 47,41%
Cu 78: Mt amino axit (X) c cng thc tng qut NH2RCOOH. t chy
hon ton a mol X thu c 6,72 (l) CO
2
(ktc) v 6,75g H
2
O. CTCT ca X l:

16
A. CH
2
NH
2
COOH B. CH
2
NH
2
CH
2
COOH
C. CH
3
CH(NH
2
)COOH D. C B v C
Cu 79: Xc nh th tch O
2
(ktc) cn t chy ht 22,455 g hn hp X
gm (CH3CH(NH2)COOH v CH3COOCH(NH2)CH3. Bit sn phm chy
c hp th ht vo bnh ng dd NaOH th khi lng bnh tng 85,655 g.
A. 44,24 (l) B. 42,8275 (l) C. 128,4825 (l) D. Kt qu khc
Cu 80: Mt amino axit no X ch cha mt nhm -NH
2
v mt nhm -COOH.
Cho 0,89 g X phn ng va vi HCl to ra 1,255 g mui. CTCT ca X l:
A. H
2
N-CH
2
-COOH B. CH
3
-CH(NH
2
)-CH
2
-COOH
C. H
2
N-CH
2
-CH
2
-COOH D. B, C, u ng.
Cu 81: Nhng cht no sau y lng tnh :
A. NaHCO
3
B. H
2
N CH
2
COOH
C. CH3COONH4 D. C A, B, C
Cu 82: Cho qu tm vo dung dch mi hp cht di y, dung dch no s
lm qu tm ho : (1) H2N CH2 COOH; (2) Cl-NH3
+
- CH2COOH;
(3) H
2
N - CH
2
- COONa (4) H
2
N(CH
2
)
2
CH(NH
2
)-COOH;
(5) HOOC(CH2)2CH(NH2) COOH;
A. (2), (5) B. (1), (4) C. (1), (5) D. (2)
Cu 83: l mt hp cht hu c c CTPT C5H11O2N. un (A) vi dD NaOH
thu c mt hp cht c CTPT C
2
H
4
O
2
NNa v cht hu c (B). Cho hi qua
CuO/t
0
thu c cht hu c (D) c kh nng cho phn ng trng gng. Cng
thc cu to ca A l :
A. CH
2
=CH-COONH
3
-C
2
H
5
B. CH
3
(CH
2
)
4
NO
2

C. H2NCH2-CH2-COOC2H5 D. NH2CH2COO-CH2- CH2-CH3
Cu 84: Bit rng khi t chy hon ton 0,1 mol X thu c 1,12 lt N
2
; 6,72
lt CO2 v 6,3 gam H2O. CTPT ca X
A. C
3
H
5
O
2
N B. C
3
H
7
O
2
N C. C
3
H
5
O
2
N D. C
4
H
9
O
2
N
Cu 85: cho 0,1 mol cht X (C2H8O3N2) tc dng vi dd cha 0,2 mol NaOH
un nng thu c cht kh lmxanh giy qu tm m t v dd Y. C cn dd
Y thu c m gam cht rn khan. Gi tr ca m l
A. 5,7 B. 12,5 C. 15 D. 21,8
Cu 86: aminoaxit X cha 1 nhm COOH v 2 nhmNH
2
. cho 1 mol X tc
dng ht vi dd NaOH thu c 154 gam mui. CTCT ca X l
A. H
2
NCH
2
CH(NH
2
)CH
2
COOH B. H
2
NCH
2
CH
2
CH
2
(NH
2
)COOH
C. H2N(CH2)3CH(NH2)COOH D. H2NCH=CHCH(NH2)COOH
Cu 87: t chy ht a mol mt aminoaxit c 2a mol CO
2
v a/2 mol N
2
.
amonoaxit trn c CTPT l
A. H
2
NCH
2
COOH B. H
2
N(CH
2
)
2
COOH
C. H2N[CH2]3COOH D. H2NCH[COOOH]2

17
Cu 88: A l mt o-aminoaxit no, c mch cacbon khng phn nhnh, cha
mt nhm -NH
2
v 2 nhm COOH. Khi t chy hon ton 1 mol A th thu
c hh kh trong c 4,5 mol <
2
CO
n <6 mol. CTCT ca A l
A. H
2
NCH(COOH)-CH(COOH)-CH
3
B. H
2
NCH(COOH)-CH
2
-CH
2
COOH
C. HOOC-CH(NH2)-CH2COOH D. HOOCCH2-CH(NH2)-CH2COOH
Cu 89: cho 100 ml dd aminoaxit A 0,2M tc dng va vi 80 ml dd NaOH
0,25M. mt khc 100 ml dd A trn tc dng vag vi 80 ml dd HCl 0,5M.
Bit d A/H
2
=52 . CTPT ca A l
A. (H2N)2C2H3COOH B. H2NC2H3(COOH)2
C. (H
2
N)
2
C
2
H
2
(COOH)
2
D. H
2
NC
3
H
5
(COOH)
2

Cu 90: Cho X l mt aminoaxit. Khi cho 0,01 mol X t/d vi HCl th dng ht
80 ml dd HCl 0,125M v thu c 1,835 gam mui khan. Cn cho 0,01 mol X
tc dng vi dd NaOH th cn dng 25 gam dd NaOH 3,2%. CTCT ca X l
A. H
2
NC
3
H
6
COOH B. H
2
NC
2
H
4
COOH
C. H
2
NC
3
H
5
(COOH)
2
D. (H
2
N)
2
C
3
H
4
(COOH)
2

Cu 91: t chy hon hon ton cht hu c X thu c 3,36 lt kh CO2 v
0,56 lt N
2
(u o ktc) v 3,15 gam H
2
O. khi cho X tc dng vi dd NaOH
thu c sn phm c mui H2NCH2COONa. CTCT thu gn ca X l
A. H
2
NCH
2
CH
2
COOH B. H
2
NCH
2
COOC
3
H
7

C. H2NCH2COOC2H5 D. H2NCH2COOCH3
Cu 92: Este A c iu ch t aminoaxit B v CH
3
OH, dA/H
2
= 44,5. t
chy hon ton 8,9 gam A thu c 13,2gam CO
2
; 6,3gamH
2
O v 1,12 lt N
2

(ktc). CTCT ca A l
A. H
2
NCH
2
COOCH
3
B. H
2
NC
2
H
4
COOCH
3

C. H2NC3H6COOCH3 D. H2NC2H2COOCH3
Cu 93: Hp cht X mch h c CT: C
x
H
y
O
z
N
t
.

trong X c 15,7303%N v
35,955%O. bit X tc dng vi dd HCl ch to ra mui ROzNH3Cl (HS rn k
nng: l gc hirocacbon) v tham gia phn ng trng ngng. CTCT ca X l
A. H2NC2H4COOH B. H2NCH2COOH
C. H
2
NC
2
H
2
COOH D. H
2
NC
3
H
6
COOH
Cu 94: Hp cht X c CTPT trng vi CTGN va tc dng vi dd NaOH
va tc dng vi dd HCl. trong X c thnh phan cc nguyn t C, H, N ln lt
l 40,449%; 7,865%; 15,73% v cn li l oxi. Cn khi cho 4,45 gamX phn
ng vi dd NaOH (va ) thu c 4,85 gam mui khan. CTCT ca X l
A. CH
2
=CH COONH
4
B. H
2
NC
2
H
4
COOH
C. H2NCOOCH2CH3 D. H2NCH2COOCH3
Cu 95: Hp cht CH
3
NH CH
2
CH
3
c tn ng l
A. imetylamin. B. EtylMetylamin.
C. N-Etylmetanamin. D. imetylmetanamin.