Phng php chun kt ta

Ging vin hng dn: Dng Th Lan

Nhm sinh vin thc hin:

Phng php mohr

Nguyn Th Tuyt Nguyn Th Thy {o Th Bch Nguyn Th Hnh Trn Vn Tuyn Nguyn Th Hng Lan

Lp C9KM2

Phng php xc nh im dng trong chun o bc

Nguyn tc:

Chun kt ta l phng php th tchda trn c s ca cc phn ng to cht kt ta t tan

Phng php xc nh im dng trong chun o bc

Yu cu ca phn ng chun : + Phn ng xy ra ng phng trnh, khng c phn ng ph. + Phn ng xy ra nhanh, nhy, chn lc.
+ To kt ta khng tan.

+ Chn c ch th thch hp

Phng php Mohr

Mc ch :

- X|c nh im dng trong chun o bc. -X|c nh Cl- ; Br - ;khng x|c nh c I- , SCN Nguyn tc :

X|c nh c|c halogenua bng dung dch Ag+ vi cht ch th l{ CrO42-

Phng php Mohr

Ch th :

CrO4 2 Phng trnh phn ng chun : Ag+ + X - AgX Ti s|t im tng ng c phn ng : 2 Ag+ + CrO4 2- Ag2CrO4 ( gch)

Phng php Mohr

iu kin chun :

- Phi tin hnh trong mi trng trung tnh hoc baz yu V : + pH thp, ion CrO42- gim nng do tc dng vi ion H+ nn kt ta gch khng xut hin st im tng ng 2CrO42- + 2H+ 2CrO72- + H2O + pH cao, Ag+ b thy phn, s xut hin Ag2O kt ta en 2AgOH Ag2O + H2O (rn) (rn, en) -Nng ca cht ch th phi m bo cho kt ta ca ch th vi bc xut hin st im tng ng 2Ag+ + 2OH-

Phng php Mohr

Dng c: pipet, buret, bnh nh mc, bnh tam gic sch, cn k thut

S chun :
Cht chun, nng

V(ml) dung dch cht nh phn Ch th

(

mu a

mu b)

Phng php Mohr

tin hnh
B1: Dng pipet ly chnh xc V(ml) dung dch halogenua cn xc nh vo bnh nn sch
B2: cho thm cht ch th

sch, lc u

CrO42- vo bnh nn

B3: Thm t t dung dch chun Ag+ t buret vo dung dch cn chun cho n khi dd chuyn t mu vng nht sang mu gch, n nh trong 30s th dng chun

B4: Ghi th tch dung dch Ag+ tiu tn

B5: chun 3 ln ri ly kt qu trung bnh

Phng php Mohr

c, kt qu: CX- = (CAg+ . VAg+) / VX Gii thch lng dng ca ch th:

2Ag+

CrO42- Ag2CrO4 ( gch)

Phng php Mohr

V mt l thuyt, sai s bng khng,

kt ta gch phi xut hin ti thi im tng ng, khi ; Ks(AgCl) = 10-10 (M) V dung dch b~o ha: [Ag+][Cl-] = 10-10 (M) [Ag+] = [Cl-] = 10-5 (M) Gi tan ca CrO42- l s

Phng php Mohr

s= =2. = 0,02 (M)
= 0.02M th lm cho Ag+ s b thy ph}n xut hin kt ta en Ag2O cn gim nng ca ch th xung + ) c ch th s|t im tng [CrO42-]= 0.005(M) [Ag+]= = = 2.10-5 pAg = =4,7 Lc sai s mc phi l{: +o,1 % nn chp nhn c.

Phng php Mohr

Xt trng hp c th :

chun clorua bng phng php mohr

1. Nguyn tc: -phn ng chun :

Ag+ + Cl-

St im tng ng : 2Ag+
-pH tng ng:

AgCl (trng)

CrO42- Ag2CrO4 ( gch)

CrO42-

- Cht ch th :

Phng php Mohr

2. Ha cht- dng c:
* Ha cht: - Cht chun : Ag + (AgNO3)

- Cht nh ph}n : Cl (NaCl) - Ch th : CrO42- 5% (K2CrO4)

Phng php Mohr

- Tnh to|n pha cht nh ph}n v{ cht chun: 100 ml , 0,1N mAgNO3 = V.C.M = 0,1.0,1.170 = 1,7(g) mNaCl =V.C.M = 0,1.0,1.58,5 = o,585(g) + Cn chnh xc 1,7 g AgNO3 ha tan trong 100ml nc ct + Cn chnh xc 0,585 g NaCl ha tan trong 100ml nc ct + Dng pipet ly chnh x|c 5 g K2CrO4 ha tan trong 100ml nc ct

Phng php Mohr

Dng c:

pipet, buret bnh nh mc, bnh tam gi|c, c}n k thut

3. Tin h{nh th nghim: + S chun

dd Ag+ 0.1N

25(ml) dd Cl1 ml ch th CrO42- 5% Vng nht

Phng php Mohr

tin hnh:
B1

Dng pipet ly chnh xc 25ml dd Clcho vo bnh tam gic sch

Cho 1 ml ch th CrO42- vo bnh tam gic sch, lc u
Thm t t dd Ag+ t buret vo dd cn chun cho n khi dd chuyn t vng nht sang gch, n nh trong 30s ri dng chun

B2

B3

B4

Ghi th tch dd Ag+ tiu tn Chun 3 ln ri ly kt qu trung bnh

B5

Phng php Mohr

4. Kt qu:

CN(Cl-) = (CN(Ag+).VAg+) / VClCM(Cl-)

=

CN(Cl-)

The end.