LI M U

Cc em hc sinh thn mn! K thi tuyn sinh i hc cao ng nm 2013 sp n. Trong thi gian ny, cc em cn phi n luyn nhiu hn na. Cun sch ny hi vng s gip cc em c phng php hc tp tt v tip cn thi cc nm. Ni dung cun sch gm c ba phn. Phn 1: gip cc em nm vng phng php gii ton Ha hc. Phn 2: gm thi cc nm 2007 n 2011 c phn thnh tng chng t lp 10 n lp 12. Phn 3: B thi gip cc em luyn tp trong thi gian 90 pht rn k nng khi i thi. Cc thi u c p n gip cc em kim tra li sc hc ca mnh. Do thi gian c hn, chc chn cun sch ny s c mt vi sai st. Mi gp xin lin h a ch thom_bv@yahoo.com.vn Chc cc em t kt qu tt trong k thi. Tc gi

CCH HC MN HA HC C HIU QU. c th ring mn Ha hc:C rt nhiu phng trnh phn ng t lp 10 n lp 12. Hc sinh phi hc bi kh vt v. d dng hc bi v nh lu, cc em cn phi tng hp cc kin thc theo tng nhm cht trong ha v c (nhm VIIA, VIA,VA...) hoc phn loi theo kiu phn ng trong ha hu c (phn ng th, cng, oxi ha, trng hp...) trong t giy ln d dng thy mi quan h gia chng, so snh cc tnh cht (ging v khc nhau),v gii thch. Nh vy, cc em c th tr li nhanh cc cu hi l thuyt dng tng hp hoc nhn nh nhanh cc phng trnh phn ng xy ra trong cc bi ton. Cc em c th t kim tra s lng phng trnh phn ng m mnh nh hoc hc ln nhau bng cch t chc cc tr chi cng bn b nh ni tip nhau vit cc phng trnh phn ng: cht to thnh ca ngi ny l cht tham gia ca ngi k tip (vit chui phn ng). Chui phn ng c vit cng di, chng t cc em nh cng nhiu phn ng. gii tt cc bi ton ha hc, cc em phi bit nhn nh nhanh cc phng trnh phn ng xy ra trong cc bi ton v nhn nh dng bi gii theo phng trnh phn ng ha hc hay gii theo cc nh lut (nh lut thnh phn khng i, nh lut bo ton khi lng, bo ton mol nguyn t,bo ton mol elctron,...).C mt s dng ton c th dng cc cng thc tnh nhanh. Cc em c th dng cc cng thc tit kim thi gian. Nhng mun nh cc cng thc tnh nhanh, cc em phi hiu ngun gc xy dng cng thc . Cc dng ton trong ha hc thng khng nhiu so vi mn ton, vt l. Tuy nhin, hc sinh thng b sai do khng bit cc phn ng xy ra. Tm li, hc sinh cn c gng thuc nhiu phng trnh phn ng ha hc trong chng trnh. CU TRC THI I HC thi mn Ha hc gm 50 cu trc nghim chia lm hai phn: phn chung 40 cu dnh cho tt c th sinh; phn ring (10 cu) gm 2 phn theo chng trnh chun v chng trnh nng cao. Cu trc v gii hn ni dung kin thc nh sau I. Phn chung cho tt c th sinh (40 cu): _ Nguyn t, bng tun hon cc nguyn t ha hc, lin kt ha hc ( 2 cu) _ Phn ng oxi ha kh, tc phn ng v cn bng ha hc (2 cu) _ S in li (2 cu) _ Phi kim (cacbon, silic, nit, photpho, oxi, lu hunh, halogen) (2 cu) _ i cng v kim loi (2 cu) _ Kim loi kim, kim loi kim th, nhm, st (5 cu) _Tng hp ni dung cc kin thc ha v c thuc chng trnh ph thng (6 cu) _ i cng ha hu c, hidrcacbon (2 cu) _ Dn xut Halogen, ancol, phenol (2 cu) _ Andehyt, xeton, axit cacboxylic (2 cu) _ Este, lipit (2 cu) _ Amin, amino axit v protein (3 cu) _ Cacbohidrat (1 cu) _ Polime v vt liu polime (1 cu) _ Tng hp ni dung kin thc ha hu c thuc chng trnh ph thng (6 cu) II. Phn ring (10 cu) Th sinh ch c lm mt trong hai phn A. Phn theo chng trnh chun: _ Tc phn ng, cn bng ha hc, s in li (1 cu) _ andehyt, xeton, axit caboxylic (2 cu)
2

_ dy in th cc chun (1 cu) _ Crom, ng, km, niken, ch, bc, vng, thic (2 cu) _ Phn bit mt s cht v c, ha hc v vn pht trin kinh t, x hi, mi trng (1 cu) _ Dn xut halogen, ancol, phenol (1 cu) _ Amin, amino, axit v protein (1 cu) B. Phn theo chng trnh nng cao: _ Tc phn ng, cn bng ha hc, s in li (1 cu) _ Andehyt, xeton, axit caboxylic (2 cu) _ Dy in th cc chun (1 cu) _ Crom, ng, km, niken, ch, bc, vng, thit (2 cu) _ Phn bit mt s cht v c, ha hc v vn pht trin kinh t, x hi, mi trng (1 cu) _ Dn xut halogen, ancol, phenol (1 cu) _ Amin, amino, axit v protein (1 cu) PHN 1: M T S PHNG PHP GII TON A.QUI I HN HP NHIU CHT THNH S LNG CHT T HN GIM N S V PHNG TRNH PHN NG TRONG CC BI TON HA V C 1.Cho 4,4 gam hn hp hai kim loi nhm IA hai chu k lin tip tc dng vi dung dch HCl d thu c 4,48 lt H (ktc) v dung dch cha m gam mui tan. Tn hai kim loi v khi lng
2

m l A. 11 gam; Li v Na. B. 18,6 gam; Li v Na. C. 18,6 gam; Na v K.D. 12,7 gam; Na v K. 2M + 2HCl 2MCl + H 0,4 0,2
2

M = 44/0,4 = 11 Li v Na m = 0,4(11+35,5)=18,6 2.Ha tan hon ton 2,84 gam hn hp hai mui cacbonat ca hai kim loi phn nhm IIA v thuc hai chu k lin tip trong bng tun hon bng dung dch HCl ta thu c dung dch X v 672 ml CO ( ktc).Hy xc nh tn cc kim loi.
2

A. Be, Mg.
3

B. Mg, Ca.
2

C. Ca, Ba.
2 2

D. Ca, Sr.

MCO + 2HCl 2MCl + CO + H O 0,03 Mg, Ca 3.Tnh th tch dung dch HCl 1M cn dng ha tan 23,2 gam hn hp gm FeO, Fe O v
3 4

0,03

M = (2,84/0,03 ) 60 = 34,67

Fe O ,trong FeO v Fe O c s mol bng nhau.

2 3 2 3

A.0,4 lt

B.0,6 lt

C.0,8 lt

D.1,0 lt
3

Fe O
3

0,1 mol n = 0,4 mol

O

n = 0,8 = n
H

HCl

HCl

= 0,8 lt
3 4 2 3

4.Cho 9,12 gam hn hp gm FeO, Fe O v Fe O tc dng vi dung dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl v m gam
2

FeCl . Gi tr ca m l
3

A. 8,75.
2 3

B. 9,75.

C. 6,50.

D. 7,80.

FeO x mol v Fe O y mol 72x + 160y = 9,12 127x = 7,62 x=0,06; y = 0,03 m= 0,03.2(56+35,5.3)=9,75 5.Hn hp X gm Fe O (0,1 mol), Fe O (0,1 mol), FeO (0,2 mol) v Fe (0,1 mol). Cho X tc
2 3 3 4

dng vi dung dch HNO long (d), ch sinh ra sn phm kh duy nht l kh NO. S mol HNO
3

tham gia phn ng l A.2,6.

0 +3

B. 2,0.

C. 2,3.

D. 2,4.

Gii Fe: 0,8 mol O: 0,9 mol Fe

0 0

Fe

+3e (1)
-2 + 2

O +2e O hay O +2e + 2H H O(2)

+5 3 +2 + 2

N + 3e N hayNO +3e + 4H NO + 2H O(3) n (3)=0,8.3-0,9.2=0,6

e

nHNO =0,9.2+0,6.4:3=2,6
3

6.Cho 20,88g Fe O tc dng vi HNO (ly d 25% so vi lng phn ng) thu c 0,672 lt
3 4 3

kh N O (kc),sn phm kh duy nht. Tnh khi lng vi HNO dng.

x y 3

A.66,15g
3 4

B.70,12

C.50,25

D.60,72

Gii: Fe O :0,09 mol. Fe: 0,27 mol;O: 0,36 mol

4

+3

Fe
0

Fe +3e
-2 0 + 2

O +2e O hay O +2e+ 2H H O

+5

N + ke X 0,03k=0,27.3-0,36.2=0,09 k=3 NO
+

hay NO

+3e +4H NO+2H O

2

n HNO =(0,36.2+0,03.4)63.125/100=66,15
3

7.Cho 30,8 gam hn hp X gm Cu v Fe O tc dng vi dung dch cha a mol HNO long
3 4 3

khuy u. Sau khi cc phn ng xy ra hon ton, thu c 2,24 lt kh X (sn phm kh duy nht, ktc), dung dch Y cha 64,6gam mui nitrat v cn li 6,4 gam kim loi. Cng thc phn t X v gi tr ca a l A. NO 0,2. B. NO 0,7.
2

C. NO 0,8.

D. N O 1,0.
2

Gii: Cu x mol Fe 3y mol O 4y mol 64x+56.3y+16.4y=30,8 - 6,4(1) 188x+180.3y= 64,6(2) x=0,2; y=0,05
0 0 +2 -2 +5 0 +2

Cu Cu

+2e; Fe

Fe

+2e

O +2e O ; N +ke X 0,1k=0,2.2+0,05.3.2-0.05.4.2=0,3 k=3 (NO)

0 + 2

O +2e +2H H O
3 + 2

NO +3e +4H NO +2H O n HNO =a=(0,05.4.2+0,1.4)=0,8

3

8.Cho 61,2 gam hn hp X gm Cu v Fe O tc dng vi dung dch HNO long, un nng v

3 4 3

khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l ( thi TSH khi B 2009) A. 151,5.
0 0 +2

B. 137,1.

C. 97,5.

D. 108,9.

Gii: Cu x mol Fe 3y mol O 4y mol Cu Cu

+2

+2e; +2e
-2 +2

Fe
0 +5

Fe

O +2e O ; N +3e N
5

64x+56.3y+16.4y=61,2 - 2,4(1) 2x+2.3y= 2.4y+0,15.3(2) x=0,375; y=0,15 m=0,375.188+0,15.3.180=151,5 9.Cho 20,88g Fe O tc dng vi H SO c, nng thu c 3,248 lt kh SO (kc),sn phm kh
x y 2 4 2

duy nht v dung dch X. C cn dung dch X th thu c bao nhiu gam mui. A.52,2g Gii: Fe O
x 0 y

B.48,8g

C.54,0g

D.58,0g

Fe x mol O y mol +3e

-2

+3

Fe Fe
0

O +2e O
+6 +4

S + 2e S 56x + 16y = 20,88 3x = 2y + 0,145.2 x=0,29; y=0,29 m=0,29.400/2= 58. 10.Ho tan hon ton 2,44 gam hn hp bt X gm FexOy v Cu bng dung dch H SO c nng
2 4

(d). Sau phn ng thu c 0,504 lt kh SO (sn phm kh duy nht, ktc) v dung dch cha
2

6,6 gam hn hp mui sunfat. Phn trm khi lng ca Cu trong X l A. 39,34%.
0 0 +3 -2

B. 65,57%.
0 +6

C. 26,23%.
+2 +4

D. 13,11%. (B-2010)

Fe: a mol; Cu: b mol; O: c mol Fe Fe +3e ; Cu Cu +2e ; S + 2e S

O +2e O 200a+160b=6,6

56a +64b +16c = 2,44 3a+2b = 2c + 0,0225.2 a=0,025; b=0,01; c=0,025 %m =0,01.64.100/2,44=26,23
Cu

11.Cho 18,4 gam hn hp X gm Cu S, CuS, FeS v FeS tc dng ht vi HNO (c nng d)

2 2 3

thu c V lt kh ch c NO ( ktc, sn phm kh duy nht) v dung dch Y. Cho ton b Y vo

2

mt lng d dung dch BaCl , thu c 46,6 gam kt ta, cn khi cho ton b Y tc dng vi
2

dung dch NH d thu c 10,7 gam kt ta. Gi tr ca V l

3

A. 38,08

B. 11,2 C. 24,64

D. 16,8 (A-2012)

Cu x mol Fe y mol S z mol

6

0 0

+2 +3 3+

Cu Cu +2e; Fe
0

Fe
+6

+3e; Fe Fe(OH)
24

S S + 6e ; SO
+5 +4

BaSO

N + 1e N 64x+56y+32z=18,4(1) z=46,6/233=0,2 (2) y=10,7/107=0,1 (3) x=0,1 V( NO )=(0,1.2+0,1.3+0,2.6)22,4=38,08.

2

12.Hn hp X gm Na, Ba, Na O, BaO, trong oxi chim 8,897% khi lng. Ha tan ht 107,9
2

gam hn hp X vo nc thu c 7,84 lt kh H (ktc) v 2 lt dung dch kim Y . Nng ca

2

NaOH v Ba(OH) trong dung dch Y ln lt l:

2

A.0,35M v 0,3M C. 0,3M v 0,45M

0 +

B. 0,4M v 0,35M D.0,4M v 0,5M

Na:xmol Ba:y mol O:8,897.107,9/100=9,6g (hay0,6 mol) Na

0

Na +1e ;
+2

Ba
2 0

Ba

+2e
2

H O + 2e H + 2OH ;
2

O +2e + H O 2OH 23x+137y=107,9-9,6(1) x+2y=0,35.2+2.0,6 (2) x=0,7; y= 0,6 C NaOH =0,35M v C Ba(OH) =0,3M
M M 2

13.Nung 2,23gam hn hp X gm cc kim loi Al, Fe, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn hp Y. Ha tan hn hp Y vo dung dch HNO (d) thu c 0,672 lt kh NO
3

(sn phm kh duy nht, ktc). S mol HNO phn ng l. (H B10)

3

A.0,12
0 + 2

B.0,14

C.0,16

D.0,18

O +2e + 2H H O
3 + 2

NO +3e + 4H NO + 2H O n = (2,71-2,23): 16=0,03

O

nHNO = 0,03.2+0,03.4=0,18
3

14.Nung 4,46gam hn hp X gm cc kim loi Fe,Al, Zn, Mg trong oxi, sau mt thi gian thu c 5,42gam hn hp Y. Ha tan hn hp Y vo dung dch HNO (d) th s mol HNO phn
3 3

ng l 0,36 mol. Sau phn ng thu c V lt kh NO( sn phm kh duy nht, ktc). Tnh V lt kh NO A.0,12
0

B.0,896 C.1,344
+ 2

D.0,672

O +2e + 2H H O
+

NO
O

+3e + 4H NO + 2H O
2

n = (5,42-4,46): 16=0,06 n
NO NO

= (0,36-0,06.2):4=0,06 =0,06.22,4=1,344 lt

B.QUI I HN HP NHIU CHT THNH S LNG CHT T HN GIM N S V PHNG TRNH PHN NG TRONG CC BI TON HA HU C 1.t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO v 0,425 mol H O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d),
2 2

thu c cha n 0,15 mol H . Cng thc phn t ca X, Y l:

2

( thi TSC 2008)

A. C H O , C H O . B. C H O v CH O.
2 6 2 3 8 2 2 6 4

C.C H OvC H O. D.C H OvC H O.

3 6 4 8 2 6 3 8

nH O > nCO ancol no

2 2

nM = nH O nCO = 0,125
2 2

n = nCO / nM=0,3/0,125=2,4
c 2

nM=0,25; nH < 0,15 n chc

2

C H O v C H O.
2 6 3 8

2.t chy hon ton m gam hn hp X gm 3 ancol n chc, thuc cng dy ng ng, thu c 3,808 lt kh CO (ktc) v 5,4 gam H O. Gi tr ca m l
2 2

A. 5,42.

B. 4,72. O

C. 7,42.

D. 5,72.

thi TSH khi A 2010 nH O>nCO C H

2 2 n 2 2 2n+2

nX = nH OnCO = 0,3-0,17=0,13 n = nCO / nX = 0,17/0,13= 1,307

2

(14n+18)0,13= 4,72
8

3.t chy hon ton 10,8g hh X gm metanol,etanol, propanol ri cho sn phm i qua bnh ng 1dd axit sunfuric c sau qua bnh 2 ng dd Ca(OH) d. Kt thc p thy bnh 1 tng
2

12,6g v bnh 2 to mg kt ta. Tnh m. A.45. CH

n n 2n+2 2n+2

B.50 O ;x mol

C.60

D.75

CH

O nCO + (n+1)H O
2 2

(14n + 18)x = 10,8; (n+1)x = 0,7 nx=0,45 ; x=0,25 mCaCO =0,45x100=45g

3

4. t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH) (d). Sau phn ng thu c 18
2

gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH) ban u thay
2

i nh th no? (A-2011) A.Tng 2,70 gam. C. Tng 7,92 gam. CH

n 2n-2 2 2

B. Gim 7,74 gam. D.Gim7,38 gam.

2

O nCO + (n-1)H O

(14n + 18)x = 3,24; nx = 0,18 x = 0,03 nH O =nx-x= 0,15

2

mCaCO >( mCO + mH O ) m gim

3 2 2 dd

= 18-(0,18x44 + 0,15x 18) = 7,38 5.Hn hp X c t khi so vi H l 21,2 gm propan, propen v propin. Khi t chy hon ton
2

0,1 mol X, tng khi lng ca CO v H O thu c l

2 2

A. 20,40 gam.B. 18,96 gam.C. 16,80 gam.D. 18,60 gam. thi TSH khi A 2008 CH
3 n

12 . 3 + n = 21,2. 2 n= 6,4 CH
3 n

3CO + n/2 H O
2 2

0,1

0,3 0,32

m=0,3.44 + 0,32. 18 = 18,96. 6.t chy hon ton hn hp X ( glucozo, fructozo, metanal v axit etanoic) cn 3,36 lt O (kc)
2

. Dn sn phm chy vo bnh ng dd nc vi trong d, sau khi phn ng xy ra hon ton thu c m gam kt ta. Gi tr ca m l: A. 10,0 B. 12,0 C. 15,0
9

D. 20,5

C H O ; C H O ; CH O ; C H O C H O .
6 12 6 6 12 6 2 2 4 2 n 2n n

C H O + n O nCO + nH O
n 2n n 2 2 2

nCO = nO = 0,15
2 2

nCaCO = 0,15.100=15
3

7.t chy hon ton m gam hn hp Y gm C H , C H v C H th thu c 12,98 gam CO

2 6 3 4 4 8

v5,76 gam H O. Vy m c gi tr l
2

A. 1,48 gam. B. 8,14 gam. C. 4,18 gam. D. 16,04 gam. Y: C ; H nCO = 0,295 nC= 0,295
2

n H O= 0,32 nH = 0,64
2

mY = mC + mH m = 0,295. 12 + 0, 64 = 4,18 t chy hon ton 4,872g mt hidrocacbon X, dn sn phm chy qua bnh ng nc vi trong. Sau phn ng thu c 27,93g kt ta v thy khi lng dung dch gim 5,586g. CTPT ca X l: A.CH
4

B.C H
4

C.C H
4

10

D.C H
3

C: x mol ; H: y mol 12x+y = 4,872 27,93-(44x + 9y)=5,586 x= ; y= x/y= = 2/5 C H

4 10 3 3

8.t chy hon ton 2,76 gam hn hp X gm CxHyCOOH, CxHyCOOCH , CH OH thu c 2,688 lt CO
2

(ktc) v 1,8 gam H O. Mt khc, cho 2,76 gam X phn ng va vi 30 ml

2 3 3

dung dch NaOH 1M, thu c 0,96 gam CH OH. Cng thc ca CxHyCOOH l A. C H COOH.
2 5

B. C H COOH. C. C H COOH. D. CH COOH.

3 5 2 3

CA-20109. C;H;O. CO : 0,12 mol nC=0,12

2

H O : 0,1 mol nH = 0,2

2

mO = 2,76 - ( 0,12 . 12 + 0,2 ) = 1,12 nO = 1,12 : 16 = 0,07 CxHyCOOH (a mol), CxHyCOOCH (b mol), CH OH (c mol)
3 3

2a+2b+c= 0,07 a+b b+c = 0,03 = 0,03

a=0,01 ; b=0,02 ; c=0,01 (R + 45).0,01 + (R + 44 +15 ). 0,02 + 32.0,01= 2,76

10

 R= 27 C H COOH
2 3

9. Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X thu c 6,72 lt kh CO (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh
2

H (ktc). Gi tr ca V l
2

A. 3,36

B. 11,20

C. 5,60

D. 6,72

B-2012 CH O ; C H O ; C H O
4 2 6 2 3 8 C O 3

C; H; O n = n =0,3 n =n
O OH

,n

H2

= nOH = 0,15

H2

= 0,15. 22,4 = 3,36

10.t chy hon ton 0,1 mol hn hp A gm etylpropionat, axit axetic v metylacrylat cn dng V lt O (kc) thu c 17,6g CO v 5,4g H O. Tr s ca V l:
2 2 2

A.10,08 lt
5 10 2 2

B.8,96
4 2 4 6 2

C13,44

D.20,16

C H O ;C H O ; C H O
X O

C; H; O 2n = n =0,1.2 = 0,2 0,2 + n n n

O(O2)

= 0,4x2 + 0,3

O(O2) O2

= 0,9

= 0,45 x 22,4 = 10,08

11.t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc, mch h, c cng s nhm -OH) cn va V lt kh O2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc th tch kh o ktc). Gi tr ca V l A. 14,56. B. 15,68. C. 11,20. B-2010 nX = nH O nCO = 0,7-0,5= 0,2;
2 2

D. 4,48.

C = nCO / nX=0,5/0,2=2,5
2

ancol c 2 chc C H
n

2n+2

2n = n
X

O O(O2)

0,2.2 + n n n
O(O2) O2

= 0,5.2 + 0,7

= 1,3

= 0,65 . 22,4 = 14,56

11

12.Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m gam X phn ng ht vi dung dch NaHCO thu c 1,344 lt CO (ktc). t chy hon ton m gam X cn 2,016 lt
3 2

O (ktc), thu c 4,84 gam CO v a gam H O. Gi tr ca a l

2 2 2

A. 1,62.

B. 1,80.

C. 3,60.

D. 1,44.

A-2012 CH O ; C H O ; C H O ; C H O
2 2 3 4 2 2 4 2 2 2 4

C; H; O ; nO = 2 nCOOH nCO =0,06 nCOOH = 0,06

2

n = 0,12
O

0,12 + 0,18 = 0,22 + nO(H O)

2

nO(H O) = 0,08 = nH O
2 2

a= 0,08. 18 = 1,44. 13.t chy hon ton 54g hn hpX gm axit fomic, axit acrylic, axit axetic, axit oxalic v axit adipic thu c 39,2 lt CO (ktc)v m gam H O. Cho 54g gam X phn ng ht vi dung dch
2 2

NaHCO thu c 21,28 lt CO (ktc). Gi tr ca m l

3 2

A. 46,8.
2 2 3 4 2 2

B. 43,2.
4 2 2 2 4

C. 23,4.
6 10 4

D. 21,6.

CH O ; C H O ; C H O ; C H O ; C H O C; H; O
2

nO = 2 nCOOH

nCO =0,95 nCOOH = 0,95 n = 1,9.

O

nO : x mol; nH O: y mol; nCO =1,75.

2 2 2

54 + 32x = 77 +18y 1,9 + 2x = 3,5 + y x=1,45 ; y = 1,3 m= 1,3. 18 = 23,4. 14.Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH trong phn t), trong
2

t l m : m = 80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch HCl 1M.

O N

Mt khc, t chy hon ton 3,83 gam hn hp X cn 3,192 lt O (ktc). Dn ton b sn phm
2

chy (CO , H O v N ) vo nc vi trong d th khi lng kt ta thu c l

2 2 2

A. 20 gam.

B. 13 gam.

C. 10 gam.

D. 15 gam. A-2012

m : m = 80 : 21 n : n = 10 : 5
O N O N

COOH

:n

NH2

=5:3
12

HCl

= 0,03 n
2 2

NH2

= 0,03 n
2

COOH

=0,05

(CO x mol; H O y mol v N 0,015 mol) 3,83 + 0,1425. 32 = 44x +18y + 0,015. 28 0,05.2 + 0,1425. 2 = 2x +y x = 0,13 mCaCO =0,13.100=13g
3

PHN 2:GII THI I HC-CAO NG THEO CHNG TRNH CC LP 10, 11, 12

1.Nguyn t, bng tun hon cc nguyn t ha hc lin kt ha hc: 2

1. Khi lng ring ca canxi kim loi l 1,55 g/cm3. Gi thit rng, trong tinh th canxi cc nguyn t l nhng hnh cu chim 74% th tch tinh th, phn cn li l khe rng. Bn knh nguyn t canxi tnh theo l thuyt l A. 0,155nm. B. 0,185 nm. C. 0,196 nm. D. 0,168 nm. H A 2011 Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng s electron ca anion v tng s electron trong XY l 20. Bit trong mi hp cht, Y ch c mt mc oxi ha duy nht. Cng thc XY l A. MgO B. AlN C. NaF D. LiF H B 2007 Mt nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52 v c s khi l 35. S hiu nguyn t ca nguyn t X l A. 18. B. 23. C. 17. D. 15. C 2009 Nguyn t ca nguyn t X c tng s ht electron trong cc phn lp p l 7. S ht mang in ca mt nguyn t Y nhiu hn s ht mang in ca mt nguyn t X l 8 ht. Cc nguyn t X v Y ln lt l (bit s hiu nguyn t ca nguyn t: Na = 11; Al = 13; P = 15; Cl = 17; Fe = 26) A. Fe v Cl. B. Na v Cl. C. Al v Cl. D. Al v P. C 2008 2 2 6 1 2 2 6 2 Cc kim loi X, Y, Z c cu hnh electron nguyn t ln lt l: 1s 2s 2p 3s ; 1s 2s 2p 3s ; 2 2 6 2 1 1s 2s 2p 3s 3p . Dy gm cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l: A. Y, Z, X. B. Z, X, Y. C. X, Y, Z. D. Z, Y, X. C 2010 Trong t nhin, nguyn t ng c hai ng v l
63 29

2.

3.

4.

5.

6.

Cu v

65 29

Cu . Nguyn t khi trung bnh ca ng l

65 29

63,54. Thnh phn phn trm tng s nguyn t ca ng v A. 27% 7. B. 50

37 17

Cu l
D. 73%. C 2007
35 17

C. 54%

: Trong t nhin clo c hai ng v bn: phn trm theo khi lng ca A. 8,43%.
37 17

Cl chim 24,23% tng s nguyn t, cn li l

C. 8,92%.

Cl. Thnh phn

Cl trong HClO4 l
B. 8,79%. D. 8,56%.

8.

3+ Mt ion M c tng s ht proton, ntron, electron l 79, trong s ht mang in nhiu hn s ht khng mang in l 19. Cu hnh electron ca nguyn t M l 5 1 6 2 6 1 3 2 A. [Ar]3d 4s . B. [Ar]3d 4s . C. [Ar]3d 4s . D. [Ar]3d 4s . H B 2010 13

9.

+ 2 2 6 Dy gm cc ion X , Y v nguyn t Z u c cu hnh electron 1s 2s 2p l: + + + A. Na , Cl , Ar. B. Li , F , Ne. C. Na , F , Ne. 10. Cu hnh electron ca ion Cu2+ v Cr3+ ln lt l : A. [Ar]3d9 v [Ar]3d3 . C. [Ar]3d9 v [Ar]3d14s2. B. [Ar]3d74s2 v [Ar]3d14s2. D. [Ar]3d74s2 v [Ar]3d3.

+ D. K , Cl , Ar. HC A 2007

H A 2011 11. 2+ 2 6 u c cu hnh electron lp ngoi cng l 3s 3p . V tr ca cc nguyn t Anion X v cation Y trong bng tun hon cc nguyn t ha hc l: A.X c s th t 17, chu k 4, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). B. X c s th t 18, chu k 3, nhm VIA (phn nhm chnh nhm VI); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). C. X c s th t 17, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 4, nhm IIA (phn nhm chnh nhm II). D.X c s th t 18, chu k 3, nhm VIIA (phn nhm chnh nhm VII); Y c s th t 20, chu k 3, nhm IIA (phn nhm chnh nhm II). H A 2007 Cc nguyn t t Li n F, theo chiu tng ca in tch ht nhn th A. bn knh nguyn t v m in u gim. B. bn knh nguyn t v m in u tng. C. bn knh nguyn t gim, m in tng. D. bn knh nguyn t tng, m in gim. H A 2010 2+ 2 2 6 2 6 6 l 1s 2s 2p 3s 3p 3d . Trong bng tun hon cc nguyn t ho hc, Cu hnh electron ca ion X nguyn t X thuc A. chu k 4, nhm VIIIA. B. chu k 4, nhm IIA. C. chu k 3, nhm VIB. D. chu k 4, nhm VIIIB. H A 2009 Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y cng c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y c s electron hn km nhau l 2. Nguyn t X, Y ln lt l A. kim loi v kim loi. B. phi kim v kim loi. C. kim loi v kh him. D. kh him v kim loi. C 2009 Trong mt nhm A (phn nhm chnh), tr nhm VIIIA (phn nhm chnh nhm VIII), theo chiu tng ca in tch ht nhn nguyn t th A. m in gim dn, tnh phi kim tng dn. B. tnh phi kim gim dn, bn knh nguyn t tng dn. C. tnh kim loi tng dn, m in tng dn. D. tnh kim loi tng dn, bn knh nguyn t gim dn. H B 2007 Cho cc nguyn t M (Z = 11), X (Z = 17), Y (Z = 9) v R (Z = 19). m in ca cc nguyn t tng dn theo th t A. Y < M < X < R. B. R < M < X < Y. C. M < X < Y < R. D. M < X < R < Y. C 2007 Bn knh nguyn t ca cc nguyn t: 3Li, 8O, 9F, 11Na c xp theo th t tng dn t tri sang phi l A. F, Na, O, Li. B. F, Li, O, Na. C. F, O, Li, Na. D. Li, Na, O, F. H A 2008 Cho cc nguyn t: K (Z = 19), N (Z = 7), Si (Z = 14), Mg (Z = 12). Dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l: A. N, Si, Mg, K. B. K, Mg, Si, N. C. K, Mg, N, Si. D. Mg, K, Si, N. H B 2009 Dy cc nguyn t sp xp theo chiu tng dn tnh phi kim t tri sang phi l: A. P, N, O, F. B. P, N, F, O. C. N, P, O, F. D. N, P, F, O. 14

12.

13.

14.

15.

16.

17.

18.

19.

H B 2008 20. Cng thc phn t ca hp cht kh to bi nguyn t R v hiro l RH3. Trong oxit m R c ho tr cao nht th oxi chim 74,07% v khi lng. Nguyn t R l A. As. B. N. C. S. D. P. H B 2008 2 4 Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns np . Trong hp cht kh ca nguyn t X vi hiro, X chim 94,12% khi lng. Phn trm khi lng ca nguyn t X trong oxit cao nht l A. 50,00%. B. 27,27%. C. 60,00%. D. 40,00%. H A 2009 Hp cht trong phn t c lin kt ion l A. NH4Cl. B. HCl. 23.

21.

22. C. H2O. D. NH3. H A 2008 Dy gm cc cht trong phn t ch c lin kt cng ho tr phn cc l: A. O2, H2O, NH3. B. H2O, HF, H2S. C. HCl, O3, H2S. D. HF, Cl2, H2O. C 2009

24.

S lin kt (xich ma) c trong mi phn t: etilen; axetilen; buta-1,3-ien ln lt l: A. 5; 3; 9. B. 3; 5; 9. C. 4; 3; 6. D. 4; 2; 6. C 2010 Nguyn t ca nguyn t X c cu hnh electron 1s22s22p63s23p64s1, nguyn t ca nguyn t Y c cu hnh electron 1s22s22p5. Lin kt ho hc gia nguyn t X v nguyn t Y thuc loi lin kt B. cng ho tr. C. ion. D. cho nhn. A. kim loi. C 2008 Cc cht m phn t khng phn cc l: A. HBr, CO2, CH4. B. Cl2, CO2, C2H2. C. NH3, Br2, C2H4. D. HCl, C2H2, Br2. H B 2010 Dy gm cc kim loi c cu to mng tinh th lp phng tm khi l: A. Li, Na, K. B. Be, Mg, Ca. C. Li, Na, Ca. : Pht biu no sau y l sai? A. Bn knh nguyn t ca clo ln hn bn knh nguyn t ca flo. B. m in ca brom ln hn m in ca iot. C. Tnh axit ca HF mnh hn tnh axit ca HCl. D. Tnh kh ca ion Br- ln hn tnh kh ca ion Cl-. H A 2011 Lin kt ho hc gia cc nguyn t trong phn t H2O l lin kt A. cng ho tr khng phn cc. B. hiro. C. cng ho tr phn cc. D. ion. C 2010 Pht biu no sau y l ng ? Photpho trng c cu trc tinh th nguyn t. th rn, NaCl tn ti di dng tinh th phn t. Nc thuc loi tinh th phn t. Kim cng c cu trc tinh th phn t. H B 2009

25.

26.

27.

D. Na, K, Mg. C 2010

28.

29.

30.

31.

2.Phn ng oxi ha kh, tc phn ng v cn bng ha hc: 2 + 0,5

Cho cc phn ng sau: a) FeO + HNO3 (c, nng) b) FeS + H2SO4 (c, nng) c) Al2O3 + HNO3 (c, nng) d) Cu + dung dch FeCl3 e) CH3CHO + H2 f) glucoz + AgNO3 trong dung dch NH3 g) C2H4 + Br2 h) glixerol (glixerin) + Cu(OH)2 Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l: A. a, b, d, e, f, h. B. a, b, d, e, f, g. C. a, b, c, d, e, h. D. a, b, c, d, e, g. H A 2007 15

32.

Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l A. 8. B. 5. C. 7. D. 6. H A 2007 Trong phn ng: K2Cr2O7 + HCl CrCl3 + Cl2 + KCl + H2O S phn t HCl ng vai tr cht kh bng k ln tng s phn t HCl tham gia phn ng. Gi tr ca k l A. 4/7. B. 3/7. C. 3/14. D. 1/7. H A 2010 Cho cc phn ng: Ca(OH)2 + Cl2

33.

34.

CaOCl2

2H2S +

SO2

3S + 2H2O 3S + 2H2O

2NO2 + 2NaOH NaNO3 + NaNO2 + H2O O3 O2 + O S phn ng oxi ho kh l A. 5. 35.

4KClO3 + SO2

B. 4.

C. 2.

D. 3.

H B 2008 Tng h s (cc s nguyn, ti gin) ca tt c cc cht trong phng trnh phn ng gia Cu vi dung dch HNO3 c, nng l A. 10. B. 11. C. 8. D. 9. H A 2007 Cho phng trnh ho hc: Fe3O4 + HNO3 Fe(NO3)3 + NxOy + H2O Sau khi cn bng phng trnh ho hc trn vi h s ca cc cht l nhng s nguyn, ti gin th h s ca HNO3 l A. 13x - 9y. B. 46x - 18y. C. 45x - 18y. D. 23x - 9y. H A 2009 Trong phn ng t chy CuFeS2 to ra sn phm CuO, Fe2O3 v SO2 th mt phn t CuFeS2 s A. nhn 12 electron. B. nhn 13 electron. C. nhng 12 electron. D. nhng 13 electron. H B 2007 Cho bit cc phn ng xy ra sau: 2FeBr2 + Br2 2FeBr3 2NaBr + Cl2 2NaCl + Br2 3+ B. Tnh oxi ha ca Cl2 mnh hn ca Fe . D. Tnh oxi ha ca Br2 mnh hn ca Cl2. H B 2008 2+ Cho dy cc cht v ion: Zn, S, FeO, SO2, N2, HCl, Cu , Cl . S cht v ion c c tnh oxi ha v tnh kh l A. 7. B. 5. C. 4. D. 6. H A 2009 + 2+ 2+ 3+ 2+ 2Cho dy cc cht v ion: Cl2, F2, SO2, Na , Ca , Fe , Al , Mn , S , Cl . S cht v ion trong dy u c tnh oxi ho v tnh kh l A. 5. B. 4. C. 3. D. 6. H B 2008 Cho cht xc tc MnO2 vo 100 ml dung dch H2O2, sau 60 giy thu c 33,6 ml kh O2 ( ktc). Tc trung bnh ca phn ng (tnh theo H2O2) trong 60 giy trn l A. 5, 0.10 4 mol/(l.s). B. 5, 0.10 5 mol/(l.s). C. , 0.10 3 mol/(l.s). D. 2, 5.10 4 mol/(l.s). H B 2009 Cho phng trnh ha hc ca phn ng tng hp amoniac
t 2NH3 (k) N 2 (k) + 3H 2 (k)
o

36.

37.

38.

Pht biu ng l: 2+ A. Tnh kh ca Br mnh hn ca Fe . C. Tnh kh ca Cl mnh hn ca Br .

39.

40.

41.

42.

xt

Khi tng nng ca hiro ln 2 ln, tc phn ng thun: 16

A. tng ln 8 ln. 43.

B. tng ln 2 ln.

C. tng ln 6 ln.

D. gim i 2 ln. C 2007

Cho phn ng: Br2 + HCOOH 2HBr+ CO2. Nng ban u ca Br2 l a mol/lt, sau 50 giy nng Br2 cn li l 0,01 mol/lt. Tc trung bnh -5 ca phn ng trn tnh theo Br2 l 4.10 mol/(l.s). Gi tr ca a l A. 0,018. B. 0,014. C. 0,012. D. 0,016. C 2010

44. Mt bnh phn ng c dung tch khng i, cha hn hp kh N2 v H2 vi nng tng ng l o 0,3M v 0,7M. Sau khi phn ng tng hp NH3 t trng thi cn bng t C, H2 chim 50% th tch o hn hp thu c. Hng s cn bng KC t C ca phn ng c gi tr l A. 2,500. B. 3,125. C. 0,609. D. 0,500. HA 2009 Cho cc cn bng sau:

45.

2HI (k) (1) H 2 (k) + I 2 (k) 1 H 2 (k) + 1 I 2 (k) (3) HI (k) 2 2 2HI (k) (5) H 2 (k) + I 2 (r)

1 1 HI (k) (2) H 2 (k) + I 2 (k) 2 2 H 2 (k) + I 2 (k) (4) 2HI (k)

nhit xc nh, nu KC ca cn bng (1) bng 64 th KC bng 0,125 l ca cn bng A. (4). B. (2). C. (3). D. (5). C 2009 46. Cho cn bng ha hc: 2SO2 (k) + O2 (k)

2SO3 (k); phn ng thun l phn ng ta nhit. Pht

biu ng l: Cn bng chuyn dch theo chiu thun khi tng nhit . Cn bng chuyn dch theo chiu nghch khi gim nng O2. Cn bng chuyn dch theo chiu thun khi gim p sut h phn ng. Cn bng chuyn dch theo chiu nghch khi gim nng SO3. H A 2008 47. Cho cn bng (trong bnh kn) sau: CO (k) + H2O (k)

CO2 (k) + H2 (k)

H < 0

Trong cc yu t: (1) tng nhit ; (2) thm mt lng hi nc; (3) thm mt lng H2; (4) tng p sut chung ca h; (5) dng cht xc tc. Dy gm cc yu t u lm thay i cn bng ca h l: A. (1), (4), (5). B. (1), (2), (3). C. (2), (3), (4). D. (1), (2), (4). C 2009 48. Cho cn bng ho hc: N2 (k) + 3H2 (k) bng ho hc khng b chuyn dch khi A. thay i nng N2. C. thay i nhit . 49. Cho cc cn bng ho hc: N2 (k) + 3H2 (k) 2NH3 (k)(1) H2 (k) + I2 (k)

2NH3 (k); phn ng thun l phn ng to nhit. Cn

B. thm cht xc tc Fe. D. thay i p sut ca h. H B 2008

2SO2 (k) + O2 (k) 2SO3 (k)(3) 2NO2 (k) N2O4 (k)(4) Khi thay i p sut nhng cn bng ha hc b chuyn dch l: A. (1), (2), (3). B. (2), (3), (4). C. (1), (3), (4). 50. Cho cc cn bng sau:

2HI (k)(2)
D. (1), (2), (4). C 2008

17

(1) 2SO2(k) + O2(k) (3) CO2(k) + H2(k)

2SO3(k)

(2) N2 (k) + 3H2 (k) (4) 2HI (k)

2NH3 (k)

CO(k) + H2O(k)

H2 (k) + I2 (k)
D. (2) v (4). C 2009

Khi thay i p sut, nhm gm cc cn bng ho hc u khng b chuyn dch l A. (1) v (2). B. (1) v (3). C. (3) v (4). 51.

Cho cn bng sau trong bnh kn: 2NO2

N2O4

(mu nu ) (khng mu) Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c: A. H < 0, phn ng to nhit B. H > 0, phn ng to nhit C. H < 0, phn ng thu nhit D. H > 0, phn ng thu nhit H A 2009 52. Cho 5,6 gam CO v 5,4 gam H2O vo mt bnh kn dung tch khng i 10 lt. Nung nng o bnh mt thi gian 830 C h t n trng thi cn bng: CO (k) + H2O (k) CO2 (k) + H2 (k) (hng s cn bng KC = 1). Nng cn bng ca CO, H2O l n lt l A. 0,08M v 0,18M. B. 0,018M v 0,008M. C. 0,012M v 0,024M. D. 0,008M v 0,018M. H B 2011 53. Xt cn bng: N2O4 (k) 2NO2 (k) 25 C. Khi chuyn dch sang mt trng thi cn bng mi nu nng ca N2O4 tng ln 9 ln th nng ca NO2 A. tng 9 ln. B. gim 3 ln. C. tng 4,5 ln. D. tng 3 ln. H A 2010 Hng s cn bng ca phn ng xc nh ch ph thuc vo A. nhit . B. p sut. C. cht xc tc. D. nng . C 2008 2HI (k) ; H > 0. Cho cn bng ha hc: H2 (k) + I2 (k) Cn bng khng b chuyn dch khi A. gim p sut chung ca h. B. gim nng HI. C. tng nhit ca h. D. tng nng H2. H A 2011 Cho cn bng ho hc sau: 2SO2 (k) + O2 (k) 2SO3 (k); H < 0. Cho cc bin php: (1) tng nhit , (2) tng p sut chung ca h phn ng, (3) h nhit , (4) dng thm cht xc tc V2O5, (5) gim nng SO3, (6) gim p sut chung ca h phn ng. Nhng bin php no lm cn bng trn chuyn dch theo chiu thun? A. (1), (2), (4), (5). B. (2), (3), (5). C. (2), (3), (4), (6). D. (1), (2), (4). H B 2011 Cho cc cn bng sau: (I) 2HI (k) H2 (k) + I2(k); (II) CaCO3 (r) CaO (r) + CO2 (k); (III) FeO (r) + CO (k) Fe (r) + CO2 (k); (IV) 2SO2 (k) + O2 (k) 2SO3 (k). Khi gim p sut ca h, s cn bng b chuyn dch theo chiu nghch l A. 4. B. 3. C. 2. 58. o

54.

55.

56.

57.

D. 1. H B 2010

3.S in li: 2 + 0,5

Dung dch HCl v dung dch CH3COOH c cng nng mol/l, pH ca hai dung dch tng ng l x v y. Quan h gia x v y l (gi thit, c 100 phn t CH3COOH th c 1 phn t in li) A. y = 100x. B. y = 2x. C. y = x - 2. D. y = x + 2. H A 2007 18

59.

+ 2+ Cho dung dch X gm: 0,007 mol Na ; 0,003 mol Ca ; 0,006 mol Cl ; 0,006 mol HCO3 v 2+ 0,001 mol NO3 . loi b ht Ca trong X cn mt lng va dung dch cha a gam Ca(OH)2. Gi tr ca a l A. 0,222. B. 0,444. C. 0,120. D. 0,180. H A 2010 Cho ba dung dch c cng nng mol: (1) H2NCH2COOH, (2) CH3COOH, (3) CH3CH2NH2. Dy xp theo th t pH tng dn l: A. (2), (1), (3). B. (3), (1), (2). C. (1), (2), (3). D. (2), (3), (1). H B 2011 o Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 25 C, Ka ca -5 o CH3COOH l 1,75.10 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25 C l A. 1,00. B. 4,24. C. 2,88. D. 4,76. H B 2009 2+ + Dung dch X cha cc ion: Ca , Na , HCO3 v Cl , trong s mol ca ion Cl l 0,1. Cho 1/2 dung dch X phn ng vi dung dch NaOH (d), thu c 2 gam kt ta. Cho 1/2 dung dch X cn li phn ng vi dung dch Ca(OH)2 (d), thu c 3 gam kt ta. Mt khc, nu un si n cn dung dch X th thu c m gam cht rn khan. Gi tr ca m l A. 9,21. B. 9,26. C. 8,79. D. 7,47. H B 2010 Cho dy cc cht: KAl(SO4)2.12H2O, Ca(OH)2, CH3COONH4. S cht in li l A. 2. B. 4. C2H5OH, C12H22O11 (saccaroz), D. 3. CH3COOH,

60.

61.

62.

63.

C. 5.

64.

65.

66.

67.

68.

69.

70.

H B 2008 Cho dy cc cht: Ca(HCO3)2, NH4Cl, (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l A. 3. B. 5. C. 2. D. 4. H A 2007 Cho dy cc cht: Cr(OH)3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, MgO, CrO3. S cht trong dyc tnh cht lng tnh l A. 5. B. 2. C. 3. D. 4. C 2008 Cc hp cht trong dy cht no di y u c tnh lng tnh? A. Cr(OH)3, Zn(OH)2, Pb(OH)2` B. Cr(OH)3, Zn(OH)2, Mg(OH)2 D. Cr(OH)3, Fe(OH)2, Mg(OH)2 C. Cr(OH)3, Pb(OH)2, Mg(OH)2 C 2007 Cho cc cht: Al, Al2O3, Al2(SO4)3, Zn(OH)2, NaHS, K2SO3, (NH4)2CO3. S cht u phn ng c vi dung dch HCl, dung dch NaOH l A. 6. B. 4. C. 5. D. 7. H A 2008 Dy gm cc cht va tan trong dung dch HCl, va tan trong dung dch NaOH l: A. NaHCO3, MgO, Ca(HCO3)2. B. NaHCO3, ZnO, Mg(OH)2. C. NaHCO3, Ca(HCO3)2, Al 2O3. D. Mg(OH)2, Al2O3, Ca(HCO3)2. C 2009 Trong s cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa, nhng dung dch c pH > 7 l A. Na2CO3, C6H5ONa, CH3COONa. B. Na2CO3, NH4Cl, KCl. C. NH4Cl, CH3COONa, NaHSO4. D. KCl, C6H5ONa, CH3COONa. C 2007 Cho cc dung dch c cng nng : Na2CO3 (1), H2SO4 (2), HCl (3), KNO3 (4). Gi tr pH ca cc dung dch c sp xp theo chiu tng t tri sang phi l: A. (3), (2), (4), (1). B. (4), (1), (2), (3). C. (1), (2), (3), (4). D. (2), (3), (4), (1). 19

C 2008 71. Cho 4 phn ng: Fe + 2HCl FeCl2 + H2

2NaOH + (NH4)2SO4 Na2SO4 + 2NH3 + 2H2O BaCl2 + Na2CO3 BaCO3 + 2NaCl 2NH3 + 2H2O + FeSO4 Fe(OH)2 + (NH4)2SO4 Cc phn ng thuc loi phn ng axit - baz l A. (1), (2). B. (2), (4). C. (3), (4). 72. Cho cc phn ng ha hc sau: (1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2 (4) H2SO4 + BaSO3 (3) Na2SO4 + BaCl2 (6) Fe2(SO4)3 + Ba(NO3)2 (5) (NH4)2SO4 + Ba(OH)2 Cc phn ng u c cng mt phng trnh ion rt gn l: A. (1), (2), (3), (6). B. (1), (3), (5), (6). C. (2), (3), (4), (6). Dung dch axit fomic 0,007M c pH = 3. Kt lun no sau y khng ng? A. Khi pha long 10 ln dung dch trn th thu c dung dch c pH = 4. B. in li ca axit fomic s gim khi thm dung dch HCl. C. Khi pha long dung dch trn th in li ca axit fomic tng. D. in li ca axit fomic trong dung dch trn l 14,29%.

D. (2), (3). H B 2007

D. (3), (4), (5), (6). H B 2009

73.

74.

75.

76.

77.

78.

79.

H B 2010 Trn ln V ml dung dch NaOH 0,01M vi V ml dung dch HCl 0,03 M c 2V ml dung dch Y. Dung dch Y c pH l A. 2. B. 3. C. 1. D. 4. H A 2008 Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dung dch (gm H2SO4 0,0375M v HCl 0,0125M), thu c dung dch X. Gi tr pH ca dung dch X l A. 1. B. 2. C. 7. D. 6. H B 2007 Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm NaOH 0,2M v Ba(OH)2 0,1M, thu c dung dch X. Dung dch X c pH l A. 13,0. B. 1,2. C. 1,0. D. 12,8. H B 2009 Trn 100 ml dung dch c pH = 1 gm HCl v HNO3 vi 100 ml dung dch NaOH nng a (mol/l) thu c 200 ml dung dch c pH = 12. Gi tr ca a l A. 0,30. B. 0,12. C. 0,15. D. 0,03. H B 2008 Dung dch X gm CH3COOH 1M (Ka = 1,75.10-5) v HCl 0,001M . Gi tr pH ca dung dch X l: A. 2,43 B. 2,33 C. 1,77 D. 2,55 H A 2011 Cho dung dch cha 0,1 mol (NH4)2CO3 tc dng vi dung dch cha 34,2 gam Ba(OH)2. Sau phn ng thu c m gam kt ta. Gi tr ca m l A. 19,7. B. 39,4. C. 17,1. D. 15,5. C 2009 Mt dung dch cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl- v y mol SO 4 . Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l: A. 0,01 v 0,03. B. 0,05 v 0,01. C. 0,03 v 0,02. D. 0,02 v 0,05. C 2007 Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 (va ), thu c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l A. 0,04. B. 0,075. C. 0,12. D. 0,06. H A 2007 20
2-

80.

81.

82.

Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O (d), un nng, dung dch thu c cha A. NaCl. C. NaCl, NaOH. B. NaCl, NaOH, BaCl2. D. NaCl, NaHCO3, NH4Cl, BaCl2.

83.

84.

H B 2007 Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2, dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l: B. NaCl, Na2SO4, Ca(OH)2. A. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. D. HNO3, NaCl, Na2SO4. C. HNO3, Ca(OH)2, KHSO4, Na2SO4. H B 2007 3+ 2+ Dung dch X cha cc ion: Fe , SO4 , NH4 , Cl . Chia dung dch X thnh hai phn bng nhau: Phn mt tc dng vi lng d dung dch NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt ta; Phn hai tc dng vi lng d dung dch BaCl2, thu c 4,66 gam kt ta.Tng khi lng cc mui khan thu c khi c cn dung dch X l (qu trnh c cn ch c nc bay hi) A. 3,73 gam. B. 7,04 gam. C. 7,46 gam. D. 3,52 gam. C 2008 Khi ha tan hiroxit kim loi M(OH)2 bng mt lng va dung dch H2SO4 20% thu c dung dch mui trung ho c nng 27,21%. Kim loi M l A. Cu. B. Zn. C. Mg. D. Fe. C 2007 Ho tan hon ton m gam ZnSO4 vo nc c dung dch X. Nu cho 110 ml dung dch KOH 2M vo X th thu c 3a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th thu c 2a gam kt ta. Gi tr ca m l A. 32,20. B. 24,15. C. 17,71. D. 16,10. H A 2010

85.

86.

87.

HA HC V C 4. Phi kim (halogen oxi, lu hunh cacbon, silic nit, photpho): 2

Trong phng th nghim, ngi ta thng iu ch clo bng cch in phn nng chy NaCl. cho dung dch HCl c tc dng vi MnO2, un nng. in phn dung dch NaCl c mng ngn. cho F2 y Cl2 ra khi dung dch NaCl. H A 2007

88.

Trong phng th nghim, ngi ta iu ch oxi bng cch A. in phn nc. B. nhit phn Cu(NO3)2. C. nhit phn KClO3 c xc tc MnO2. D. chng ct phn on khng kh lng. H A 2008

89.

ng dng no sau y khng phi ca ozon? A. Ty trng tinh bt, du n. C. iu ch oxi trong phng th nghim.

B. Cha su rng. D. St trng nc sinh hot.

90.

H B 2009 Trong phng th nghim, iu ch mt lng nh kh X tinh khit, ngi ta un nng dung dch amoni nitrit bo ho. Kh X l A. NO. B. NO2. C. N2O. D. N2. H A 2007 Trong phng th nghim, ngi ta thng iu ch HNO3 t A. NaNO3 v H 2 SO 4 c. B. NaNO2 v H 2 SO 4 c. C. NH3 v O2. D. NaNO3 v HCl c. H B 2007 21

91.

92.

Cho 0,448 lt kh NH3 (ktc) i qua ng s ng 16 gam CuO nung nng, thu c cht rn X (gi s phn ng xy ra hon ton). Phn trm khi lng ca Cu trong X l A. 14,12%. B. 87,63%. C. 12,37%. D. 85,88%. H A 2010 Cc cht va tc dng c vi dung dch HCl va tc dng c vi dung dch AgNO3 l: A. Zn, Cu, Fe. B. MgO, Na, Ba. C. Zn, Ni, Sn. D. CuO, Al, Mg. H A 2010 Cho Cu v dung dch H 2 SO 4 long tc dng vi cht X (mt loi phn bn ha hc), thy thot ra kh khng mu ha nu trong khng kh. Mt khc, khi X tc dng vi dung dch NaOH th c kh mi khai thot ra. Cht X l A. amophot. B. ure. C. natri nitrat. D. amoni nitrat. H A 2008 Phn bn no sau y lm tng chua ca t? A. KCl. B. NH4NO3. C. NaNO3. D. K2CO3. H B 2009 Thnh phn chnh ca qung photphorit l A. CaHPO4. B. Ca3(PO4)2.

93.

94.

95.

96.

97.

98.

99.

100.

101.

D. NH4H2PO4. H B 2008 Mt loi phn supephotphat kp c cha 69,62% mui canxi ihirophotphat, cn li gm cc cht khng cha photpho. dinh dng ca loi phn ln ny l A. 48,52%. B. 42,25%. C. 39,76%. D. 45,75%. H B 2010 Pht biu no sau y l ng? + A .Phn ln cung cp nit ho hp cho cy di dng ion nitrat (NO3 ) v ion amoni(NH4 ). B. Amophot l hn hp cc mui (NH4)2HPO4 v KNO3. C. Phn hn hp cha nit, photpho, kali c gi chung l phn NPK. D. Phn ur c cng thc l (NH4)2CO3. H A 2009 Pht biu no sau y khng ng? A. Dung dch m c ca Na2SiO3 v K2SiO3 c gi l thy tinh lng. B. m chy magie c th c dp tt bng ct kh. C. CF2Cl2 b cm s dng do khi thi ra kh quyn th ph hy tng ozon. D. Trong phng th nghim, N2 c iu ch bng cch un nng dung dch NH4NO2 bo ho. H B 2010 Phn bn nitrophotka (NPK) l hn hp ca A. (NH4)2HPO4 v KNO3. B. NH4H2PO4 v KNO3. C. (NH4)3PO4 v KNO3. D. (NH4)2HPO4 v NaNO3. C 2009 Cho cc phn ng sau: (1) Cu(NO3 )2 (3) NH3 + O 2
t0 8500 C,Pt t0

C. Ca(H2PO4)2.

(2) NH 4 NO 2 (4) NH 3 + Cl2 (6) NH3 + CuO C. (2), (4), (6). D. (3), (5), (6). H A 2008
t0 t0

t0

(5) NH 4 Cl Cc phn ng u to kh N2 l: A. (1), (3), (4). B. (1), (2), (5). 102. Cho cc phn ng sau:

t 4HCl + MnO2 MnCl2 + Cl2 + 2H2O. 2HCl + Fe FeCl2 + H2. to 14HCl + K2Cr2O7 2KCl + 2CrCl3 + 3Cl2 + 7H2O.
o

22

6HCl + 2Al 2AlCl3 + 3H2. 16HCl + 2KMnO4 2KCl + 2MnCl2 + 5Cl2 + 8H2O. S phn ng trong HCl th hin tnh oxi ha l A. 3. B. 4.

C. 2.

D. 1. H A 2008

103.

Cho cc phn ng sau: 4HCl + PbO2 PbCl2 + Cl2 + 2H2O. HCl + NH4HCO3 NH4Cl + CO2 + H2O. 2HCl + 2HNO3 2NO2 + Cl2 + 2H2O. 2HCl + Zn ZnCl2 + H2. S phn ng trong HCl th hin tnh kh l A. 2. B. 3. C. 1.

D. 4. H B 2009

104.

Cho cc phn ng : (1) O3 + dung dch KI

t0

(2) F2 + H2O

t
0

(3) MnO2 + HCl c (4) Cl2 + dung dch H2S Cc phn ng to ra n cht l : A. (1), 2), (3) B. (1), (3), (4) C (2), (3), (4) 105. Phn ng nhit phn khng ng l : A. 2KNO3 C. NH4Cl 106.
t 2KNO2 + O2
0

D. (1), (2 , (4) H B 2008

B. NH4NO2

t N2 + 2H2O
0

t NH3 + HCl
0

D. NaHCO3

t NaOH + CO2
0

H B 2008 Trng hp khng xy ra phn ng ha hc l B. FeCl2 + H2S FeS + 2HCl D. Cl2 + 2NaOH NaCl + NaClO + H2O C 2008 Dy gm cc cht u tc dng c vi dung dch HCl long l: A. KNO3, CaCO3, Fe(OH)3. B. FeS, BaSO4, KOH. D. Mg(HCO3)2, HCOONa, CuO. C. AgNO3, (NH4)2CO3, CuS. H A 2009 Nu cho 1 mol mi cht: CaOCl2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l A. KMnO4. B. MnO2. C. CaOCl2. D. K2Cr2O7. H A 2009 Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 ln nht l B. KMnO4. C. KNO3. D. AgNO3. A. KClO3. H B 2009 Cht kh X tan trong nc to ra mt dung dch lm chuyn mu qu tm thnh v c th c dng lm cht ty mu. Kh X l A. NH3. B. CO2. C. SO2. D. O3. C 2009 SO2 lun th hin tnh kh trong cc phn ng vi A. H2S, O2, nc Br2. B. dung dch NaOH, O2, dung dch KMnO4. C. O2, nc Br2, dung dch KMnO4. D. dung dch KOH, CaO, nc Br2. C 2007 Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (ktc). Gi tr ca 23 A. 3O2 + 2H2S 2SO2 + 2H2O C. O3 + 2KI + H2O O2 + 2KOH + I2
to

107.

108.

109.

110.

111.

112.

V l A. 2,80. 113.

B. 3,36.

C. 3,08. o

D. 4,48. C 2008

114.

Cho 13,44 lt kh clo ( ktc) i qua 2,5 lt dung dch KOH 100 C. Sau khi phn ng xy ra hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c nng l A. 0,24M. B. 0,2M. C. 0,4M. D. 0,48M. H B 2007 Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3 (d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l A. 58,2%. B. 41,8%. C. 52,8%. D. 47,2%. H B 2009

115.

t chy hon ton m gam FeS2 bng mt lng O2 va , thu c kh X. Hp th ht X vo 1 lt dung dch cha Ba(OH)2 0,15M v KOH 0,1M, thu c dung dch Y v 21,7 gam kt ta. Cho Y vo dung dch NaOH, thy xut hin thm kt ta. Gi tr ca m l A. 23,2. B. 12,6. C. 18,0. D. 24,0. H B 2010 Hn hp kh X gm N2 v H2 c t khi so vi He bng 1,8. un nng X mt thi gian trong bnh kn (c bt Fe lm xc tc), thu c hn hp kh Y c t khi so vi He bng 2. Hiu sut ca phn ng tng hp NH3 l A. 50%. B. 40%. C. 36%. D. 25%. H A 2010 Cho 0,015 mol mt loi hp cht oleum vo nc thu c 200 ml dung dch X. trung ho 100 ml dung dch X cn dng 200 ml dung dch NaOH 0,15M. Phn trm v khi lng ca nguyn t lu hunh trong oleum trn l A. 32,65%. B. 23,97%. C. 35,95%. D. 37,86%. C 2010 Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v 80% th tch N2) n khi cc phn ng xy ra hon ton, thu c mt cht rn duy nht v hn hp kh Y c thnh phn th tch: 84,8% N2, 14% SO2, cn li l O2. Phn trm khi lng ca FeS trong hn hp X l A. 42,31%. B. 59,46%. C. 19,64%. D. 26,83%. H A 2011 Cht rn X phn ng vi dung dch HCl c dung dch Y. Cho t t dung dch NH3 n d vo dung dch Y, ban u xut hin kt ta xanh, sau kt ta tan, thu c dung dch mu xanh thm. Cht X l A. CuO. B. Fe. C. FeO. D. Cu C 2010 Thuc th dng phn bit dung dch NH4NO3 vi dung dch (NH4)2SO4 l A. ng(II) oxit v dung dch HCl. B. kim loi Cu v dung dch HCl. C. dung dch NaOH v dung dch HCl. D. ng(II) oxit v dung dch NaOH. C 2010 Kim loi M c th c iu ch bng cch kh ion ca n trong oxit bi kh H2 nhit cao. Mt khc, + kim loi M kh c ion H trong dung dch axit long thnh H2. Kim loi M l A. Cu. B. Fe. C. Al. D. Mg. C 2010 Khi cho Cu tc dng vi dung dch cha H 2 SO 4 long v NaNO3, vai tr ca NaNO3 trong phn ng l A. cht oxi ho. B. mi trng. C. cht kh. D. cht xc tc. H B 2007 Thc hin hai th nghim: -Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO. - Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO3 1M v H 2 SO 4 0,5 M thot ra V2 lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1 v V2 l A. V2 = 1,5V1. B. V2 = 2V1. C. V2 = 2,5V1. D. V2 = V1. H B 2007 Cho 7,68 gam Cu vo 200 ml dung dch gm HNO3 0,6M v H2SO4 0,5M. Sau khi cc phn ng x y ra hon ton 24

116.

117.

118.

119.

120.

121.

122.

123.

124.

125.

126.

127.

128.

129.

(sn phm kh duy nht l NO), c cn cn thn ton b dung dch sau phn ng th khi lng mui khan thu c l A. 20,16 gam. B. 19,76 gam. C. 19,20 gam. D. 22,56 gam. H A 2011 Cho 3,2 gam bt Cu tc dng vi 100 ml dung dch hn hp gm HNO3 0,8M v H 2 SO 4 0,2M. Sau khi cc phn ng xy ra hon ton, sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 0,746. B. 0,672. C. 0,448. D. 1,792. H A 2008 Cho m gam bt Fe vo 800 ml dung dch hn hp gm Cu(NO3)2 0,2M v H2SO4 0,25M. Sau khi cc phn ng xy ra hon ton, thu c 0,6m gam hn hp bt kim loi v V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l A. 10,8 v 4,48. B. 10,8 v 2,24. C. 17,8 v 2,24. D. 17,8 v 4,48. H B 2009 Cho hn hp gm 1,12 gam Fe v 1,92 gam Cu vo 400 ml dung dch cha hn hp gm H2SO4 0,5M v NaNO3 0,2M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v kh NO (sn phm kh duy nht). Cho V ml dung dch NaOH 1M vo dung dch X th lng kt ta thu c l ln nht. Gi tr ti thiu ca V l A. 360. B. 240. C. 400. D. 120. H A 2009 Nung 6,58 gam Cu(NO3)2 trong bnh kn khng cha khng kh, sau mt thi gian thu c 4,96 gam cht rn v hn hp kh X. Hp th hon ton X vo nc c 300 ml dung dch Y. Dung dch Y c pH bng A. 4. B. 2. C. 1. D. 3. H A 2009 (t kh i ca Nhit phn hon ton 34,65 gam hn hp gm KNO3 v Cu(NO3)2, thu c hn hp kh X X so vi kh hiro bng 18,8). Khi lng Cu(NO3)2 trong hn hp ban u l A. 8,60 gam. B. 20,50 gam. C. 11,28 gam. D. 9,40 gam. C 2008 Ho tan hon ton mt lng bt Zn vo mt dung dch axit X. Sau phn ng thu c dung dch Y v kh Z. Nh t t dung dch NaOH (d) vo Y, un nng thu c kh khng mu T. Axit X l A. H2SO4 c. B. HNO3. C. H3PO4. D. H2SO4 long. C 2009 Cho 2,16 gam Mg tc dng vi dung dch HNO3 (d). Sau khi phn ng xy ra hon ton thu c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l A. 13,32 gam. B. 6,52 gam. C. 8,88 gam. D. 13,92 gam. H B 2008 Ho tan hon ton 12,42 gam Al bng dung dch HNO3 long (d), thu c dung dch X v 1,344 lt ( ktc) hn hp kh Y gm hai kh l N2O v N2. T khi ca hn hp kh Y so vi kh H2 l 18. C cn dung dch X, thu c m gam cht rn khan. Gi tr ca m l A. 38,34. B. 34,08. C. 106,38. D. 97,98. H A 2009

130.

131.

132.

133.

5. i cng v kim loi: 2 Dy th in cc chun: 1

Dy cc ion xp theo chiu gim dn tnh oxi ho l (bit trong dy in ha, cp Fe 3 + /Fe 2 + ng tr c c p Ag + /Ag): A. Ag + , Cu 2 + , Fe 3 + , Fe 2 + B. Fe 3 + , Fe 2 + , Cu 2 + , Ag + + 3+ 2+ 2+ C. Ag , Fe , Cu , Fe D. Fe 3 + , Ag +, Cu2+, Fe 2 + H A 2007 Cho cc phn ng xy ra sau y: AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag Mn + 2HCl MnCl2 + H2 Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l A. Ag + , Mn2+, H+, Fe 3 + . B. Mn2+, H+, Ag + , Fe 3 + . 25

134.

C. Ag + , Fe 3 + , H+, Mn2+. 135.

2+ 2+ 2+ 2+ 2+

D. Mn2+, H+, Fe 3 + , Ag + . H B 2007

Cho cc ion kim loi: Zn , Sn , Ni , Fe , Pb . Th t tnh oxi ho gim dn l A. Pb2+ > Sn2+ > Fe 2 + > Ni2+ > Zn2+. B. Pb2+ > Sn2+ > Ni2+ > Fe 2 + > Zn2+. 2+ 2+ 2+ 2+ 2+ 2+ D. Zn >Sn2+ > Ni2+ > Fe 2 + > Pb2+. C. Sn > Ni > Zn > Pb > Fe . C 2007 Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu. Trong phn ng trn xy ra A. s kh Fe 2 + v s oxi ha Cu. C. s oxi ha Fe v s oxi ha Cu. B. s kh Fe 2 + v s kh Cu2+. D. s oxi ha Fe v s kh Cu2+. C 2008

136.

137.

Hai kim loi X, Y v cc dung dch mui clorua ca chng c cc phn ng ha hc sau: X + 2YCl3 XCl2 + 2YCl2; Y + XCl2 YCl2 + X. Pht biu ng l: A.Ion Y2+ c tnh oxi ha mnh hn ion X2+. B. Kim loi X kh c ion Y2+. C. Kim loi X c tnh kh mnh hn kim loi Y. D. Ion Y3+ c tnh oxi ha mnh hn ion X2+. C 2008

138.

Th t mt s cp oxi ho - kh trong dy in ho nh sau: Fe Fe; Cu /Cu; Fe /Fe . Cp cht khng phn ng vi nhau l B. dung dch FeCl2 v dung dch CuCl2. A. Cu v dung dch FeCl3. C. Fe v dung dch CuCl2. D. Fe v dung dch FeCl3. C 2007 Cp cht khng xy ra phn ng ho hc l A. Cu + dung dch FeCl3. C. Fe + dung dch FeCl3.

2+

2+

3+

2+

139.

B. Fe + dung dch HCl. D. Cu + dung dch FeCl2.

140.

141.

142.

143.

C 2008 Cho bit th t t tri sang phi ca cc cp oxi ho - kh trong dy in ho (dy th in cc chun) 2+ 2+ 2+ 3+ 2+ + nh sau: Zn /Zn; Fe /Fe; Cu /Cu; Fe /Fe ; Ag /Ag. 2+ Cc kim loi v ion u phn ng c vi ion Fe trong dung dch l: + 2+ 3+ 2+ A. Zn, Ag . B. Zn, Cu . C. Ag, Fe . D. Ag, Cu . C 2010 3+ 2+ kh ion Fe trong dung dch thnh ion Fe c th dng mt lng d A. kim loi Cu. B. kim loi Ag. C. kim loi Ba. D. kim loi Mg. C 2007 Mnh khng ng l: A. Fe 2 + oxi ho c Cu. B. Fe kh c Cu2+ trong dung dch. C. Fe 3 + c tnh oxi ha mnh hn Cu2+. D. Tnh oxi ha ca cc ion tng theo th t: Fe 2 + , H+, Cu2+, Ag +. H A 2007 2+ kh ion Cu trong dung dch CuSO4 c th dng kim loi A. K. B. Na. C. Fe. D. Ba. C 2007 X l kim loi phn ng c vi dung dch H 2 SO 4 long, Y l kim loi tc dng c vi dung dch Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy th in ho: Fe 3 + /Fe 2 + ng trc + Ag /Ag) A. Ag, Mg. B. Cu, Fe C. Fe, Cu. D. Mg, Ag. H A 2008 26

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145.

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Th t mt s cp oxi ho - kh trong dy in ho nh sau: Mg2+/Mg; Fe2+/Fe; Cu2+/Cu; 2+ + Fe3+/Fe ; Ag /Ag. Dy ch gm cc cht, ion tc dng c vi ion Fe3+ trong dung dch l: + 2+ 2+ B. Mg, Fe , Ag. C. Mg, Cu, Cu . D. Mg, Fe, Cu. A. Fe, Cu, Ag . C 2009 Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c vi dung dch AgNO3? A. Fe, Ni, Sn. B. Al, Fe, CuO. C. Zn, Cu, Mg. D. Hg, Na, Ca. C 2009 Kim loi M phn ng c vi: dung dch HCl, dung dch Cu(NO3)2, dung dch HNO3 (c, ngui). Kim loi M l A. Al. B. Zn. C. Fe. D. Ag. C 2008 Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau: Fe v Pb; Fe v Zn; Fe v Sn; Fe v Ni. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim loi trong Fe b ph hu trc l A. 1. B. 2. C. 4. D. 3. C 2007 Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch cht in li th cc hp kim m trong Fe u b n mn trc l: A. I, II v IV. B. I, II v III. C. I, III v IV. D. II, III v IV. H A 2009 Bit rng ion Pb2+ trong dung dch oxi ha c Sn. Khi nhng hai thanh kim loi Pb v Sn c ni vi nhau bng dy dn in vo mt dung dch cht in li th A. ch c Pb b n mn in ho. B. ch c Sn b n mn in ho. C. c Pb v Sn u khng b n mn in ho.D. c Pb v Sn u b n mn in ho. H A 2008 : Cho cc phn ng sau: Fe + 2Fe(NO3)3 3Fe(NO3)2 AgNO3 + Fe(NO3)2 Fe(NO3)3 + Ag Dy sp xp theo th t tng dn tnh oxi ha cc ion kim loi l: A. Ag+, Fe2+, Fe3+ B. Fe2+, Fe3+, Ag+ C. Fe2+, Ag+, Fe3+ D. Ag+, Fe3+, Fe2+. H A 2011 C 4 dung dch ring bit: a) HCl, b) CuCl2 , c) FeCl3, d) HCl c ln CuCl2. Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ho l A. 1. B. 2. C. 0. D. 3. H B 2007 Tin hnh bn th nghim sau: Th nghim 1: Nhng thanh Fe vo dung dch FeCl3; Th nghim 2: Nhng thanh Fe vo dung dch CuSO4 ; Th nghim 3: Nhng thanh Cu vo dung dch FeCl3; Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl. S trng hp xut hin n mn in ho l A. 3. B. 4. C. 1. D. 2. H B 2008 Trong pin in ha Zn-Cu, qu trnh kh trong pin l + A. Cu Cu2+ + 2e. B. Zn Zn2 + 2e. 2 2+ C. Zn + 2e Zn. D. Cu + 2e Cu. H B 2007 Cho bit phn ng oxi ho - kh xy ra trong pin in ho Fe Cu l: 0 0 Fe + Cu2+ Fe 2 + + Cu ; E (Fe 2 + /Fe) = 0,44 V, E (Cu2+/Cu) = + 0,34 V. Sut in ng chun ca pin in ho Fe - Cu l A. 1,66 V. B. 0,10 V. C. 0,78 V. D. 0,92 V. C 2008 27

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o o o o Cho sut in ng chun E ca cc pin in ho: E (Cu-X) = 0,46V; E (Y-Cu) = 1,1V; E (Z-Cu) = 0,47V (X, Y, Z l ba kim loi). Dy cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l A. Y, Z, Cu, X. B. Z, Y, Cu, X. C. X, Cu, Z, Y. D. X, Cu, Y, Z. H B 2008

157.

Cho cc th in cc chun:

o Al3+ /Al

= -1,66V;

o = Zn 2+ / Zn

-0,76V;

o = Pb 2+ /Pb

-0,13V;

o Cu 2+ /Cu

= +0,34V.

158.

D. Pin Pb Cu. H B 2009 Cho sut in ng chun ca cc pin in ho: Zn-Cu l 1,1V; Cu-Ag l 0,46 V. Bit th in cc chun
o Eo v E Cu 2+ /Cu c gi tr ln lt l: Zn 2+ / Zn

Trong cc pin sau y, pin no c sut in ng ln nht: A. Pin Zn Cu. B. Pin Zn Pb.

C. Pin Al Zn.

A. -0,76V v +0,34V. C. +1,56V v +0,64V. 159.

B. -1,46V v -0,34V. D. -1,56V v +0,64V.

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H A 2009 Mt pin in ho c in cc Zn nhng trong dung dch ZnSO4 v in cc Cu nhng trong dung dch CuSO4. Sau mt thi gian pin phng in th khi lng A. in cc Zn gim cn khi lng in cc Cu tng. B. c hai in cc Zn v Cu u tng. C. in cc Zn tng cn khi lng in cc Cu gim. D. c hai in cc Zn v Cu u gim. H A 2008 Nguyn tc chung c dng iu ch kim loi l A. cho hp cht cha ion kim loi tc dng vi cht kh. B. oxi ho ion kim loi trong hp cht thnh nguyn t kim loi. C. kh ion kim loi trong hp cht thnh nguyn t kim loi. D. cho hp cht cha ion kim loi tc dng vi cht oxi ho. C 2009 Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp cht nng chy ca chng, l: A. Na, Ca, Al. B. Na, Ca, Zn. C. Na, Cu, Al. D. Fe, Ca, Al. H A 2007 Hai kim loi c th c iu ch bng phng php in phn dung dch l A. Al v Mg. B. Na v Fe. C. Cu v Ag. D. Mg v Zn. C 2008 Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui ca chng l: A. Fe, Cu, Ag. B. Mg, Zn, Cu. C. Al, Fe, Cr. D. Ba, Ag, Au. H A2009 Khi in phn NaCl nng chy (in cc tr), ti catt xy ra A. s oxi ho ion ClB. s oxi ho ion Na+. C. s kh ion Cl-. D. s kh ion Na+. H A 2008 Khi in phn dung dch NaCl (cc m bng st, cc dng bng than ch, c mng ngn xp) th: A. cc dng xy ra qu trinh oxi ha ion Na+ v cc m xy ra qu trnh kh ion Cl-. B. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ha Cl-. C. cc m xy ra qu trnh oxi ha H2O v cc dng x ra qu trnh kh ion Cl-. D. cc m xy ra qu trnh kh ion Na+ v cc dng xy ra qu trnh oxi ha ion Cl-. H A 2011 in phn nng chy Al 2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al catot v 3 67,2 m ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp kh X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l A. 108,0. B. 75,6. C. 54,0. D. 67,5. H B 2009 in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn). dung dch sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l A. b < 2a. B. b = 2a. C. b > 2a. D. 2b = a. H B 2007 28

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in phn dung dch CuCl2 vi in cc tr, sau mt thi gian thu c 0,32 gam Cu catt v mt lng kh X ant. Hp th hon ton lng kh X trn vo 200 ml dung dch NaOH ( nhit thng). Sau phn ng, nng NaOH cn li l 0,05M (gi thit th tch dung dch khng thay i). Nng ban u ca dung dch NaOH l (cho Cu = 64) A. 0,15M. B. 0,2M. C. 0,1M. D. 0,05M. H A 2007 in phn (in cc tr) dung dch X cha 0,2 mol CuSO4 v 0,12 mol NaCl bng dng in c cng 2A. Th tch kh (ktc) thot ra anot sau 9650 giy in phn l A. 1,792 lt. B. 2,240 lt. C. 2,912 lt. D. 1,344 lt. H A 2010 in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2 (in cc tr, mng ngn xp) n kh khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit lng nc bay hi khng ng k). Tt c cc cht tan trong dung dch sau in phn l A. KNO3 v KOH. B. KNO3, KCl v KOH. D. KNO3, HNO3 v Cu(NO3)2. C. KNO3 v Cu(NO3)2. H A 2011 in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M (in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l A. 4,05. B. 2,70. C. 1,35. D. 5,40. H B 2009 in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu c dung dch Y vn cn mu xanh, c khi lng gim 8 gam so vi dung dch ban u. Cho 16,8 gam bt st vo Y, sau khi cc phn ng xy ra hon ton, thu c 12,4 gam kim loi. Gi tr ca x l A. 2,25. B. 1,50. C. 1,25. D. 3,25. H B 2010 Ha tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi in cc tr, cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi tr ca y l A. 4,480. B. 3,920. C. 1,680. D. 4,788. H A 2011 in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l A. kh Cl2 v H2. B. kh Cl2 v O2. C. kh H2 v O2. D. ch c kh Cl2. H A 2010 Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n mn in ho xy ra khi nhng hp kim Zn-Cu vo dung dch HCl c c im l: A. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi. B. Phn ng xy ra lun km theo s pht sinh dng in. C. u sinh ra Cu cc m. D. Phn ng cc dng u l s oxi ho Cl . H A 2010 Ha tan hon ton 3,22 gam hn hp X gm Fe, Mg v Zn bng mt lng va dung dch H 2 SO 4 long, thu c 1,344 lt hiro (ktc) v dung dch cha m gam mui. Gi tr ca m l A. 10,27. B. 9,52. C. 8,98. D. 7,25. C 2007 Cho 3,68 gam hn hp gm Al v Zn tc dng vi mt lng va dung dch H2SO4 10%, thu c 2,24 lt kh H2 ( ktc). Khi lng dung dch thu c sau phn ng l A. 101,68 gam. B. 88,20 gam. C. 101,48 gam. D. 97,80 gam. H A 2009 Ho tan ht 7,74 gam hn hp bt Mg, Al bng 500 ml dung dch hn hp HCl 1M v H 2 SO 4 0,28M thu c dung dch X v 8,736 lt kh H2 (ktc). C cn dung dch X thu c lng mui khan l A. 38,93 gam. B. 103,85 gam. C. 25,95 gam. D. 77,86 gam. C 2008 29

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Cho 13,5 gam hn hp cc kim loi Al, Cr, Fe tc dng vi lng d dung dch H2SO4 long nng (trong iu kin khng c khng kh), thu c dung dch X v 7,84 lt kh H2 ( ktc).C cn dung dch X (trong iu kin khng c khng kh) c m gam mui khan. Gi tr ca m l A. 42,6 B. 45,5 C. 48,8 D. 47,1 C 2008 Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H 2 SO 4 0,5M, thu c 5,32 lt H2 ( ktc) v dung dch Y (coi th tch dung dch khng i). Dung dch Y c pH l A. 1. B. 6. C. 7. D. 2. H A 2007 Pht biu no sau y ng? A. Cc kim loi: natri, bari, beri u tc dng vi nc nhit thng. B. Kim loi xesi c dng ch to t bo quang in. C. Theo chiu tng dn ca in tch ht nhn, cc kim loi kim th (t beri n bari) c nhit nng chy gim dn. D. Kim loi magie c kiu mng tinh th lp phng tm din. H A 2010 Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc nhm IIA tc dng ht vi dung dch HCl (d), thot ra 0,672 lt kh H2 ( ktc). Hai kim loi l A. Be v Mg. B. Ca v Sr. C. Sr v Ba. D. Mg v Ca. H B 2007 Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l A. 12,3. B. 15,6. C. 10,5. D. 11,5. H B 2008 X l kim loi thuc phn nhm chnh nhm II (hay nhm IIA). Cho 1,7 gam hn hp gm kim loi X v Zn tc dng vi lng d dung dch HCl, sinh ra 0,672 lt kh H2 ( ktc). Mt khc, khi cho 1,9 gam X tc dng vi lng d dung dch H 2 SO 4 long, th th tch kh hiro sinh ra cha n 1,12 lt ( ktc). Kim loi X l A. Ba. B. Ca. C. Sr. D. Mg. C 2008 Ho tan hon ton hn hp X gm Fe v Mg bng mt lng va dung dch HCl 20%, thu c dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76%. Nng phn trm ca MgCl2 trong dung dch Y l A. 24,24%. B. 15,76%. C. 28,21%. D. 11,79%. C 2007 Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu c dung dch ch cha mt cht tan v kim loi d. Cht tan l A. Fe(NO3)3. B. Fe(NO3)2. C. HNO3. D. Cu(NO3)2. H B 2007 Cho hn hp X gm Mg v Fe vo dung dch axit H 2 SO 4 c, nng n khi cc phn ng xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l A. MgSO4 v Fe2(SO4)3. B. MgSO4, Fe2(SO4)3 v FeSO4. C. MgSO4 v FeSO4. D. MgSO4. C 2007 Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) A. 0,8 lt. B. 1,0 lt. C. 0,6 lt. D. 1,2 lt. H B 2008 Kh hon ton m gam oxit MxO y cn va 17,92 lt kh CO (ktc), thu c a gam kim loi M. Ho tan ht a gam M bng dung dch H2SO4 c nng (d), thu c 20,16 lt kh SO2 (sn phm kh duy nht, ktc). Oxit MxOy l A. Cr2O3. B. FeO. C. Fe3O4. D. CrO. H B 2010 30

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Cho 3,6 gam Mg tc dng ht vi dung dch HNO3 (d), sinh ra 2,24 lt kh X (sn phm kh duy nht, ktc). Kh X l A. N2O. B. NO2. C. N2. D. NO. C 2008 un nng m gam hn hp Cu v Fe c t l khi lng tng ng 7 : 3 vi mt lng dung dch HNO3. Khi cc phn ng kt thc, thu c 0,75m gam cht rn, dung dch X v 5,6 lt hn hp kh (ktc) gm NO v NO2 (khng c sn phm kh khc ca N+5). Bit lng HNO3 phn ng l 44,1 gam. Gi tr ca m l A. 44,8. B. 40,5. C. 33,6. D. 50,4. H A 2011 Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 2,71 gam hn hp Y. Ho tan hon ton Y vo dung dch HNO3 (d), thu c 0,672 lt kh NO (sn phm kh duy nht, ktc). S mol HNO3 phn ng l A. 0,12. B. 0,14. C. 0,16. D. 0,18. H B 2010 Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt (ktc) hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l A. 2,24. B. 4,48. C. 5,60. D. 3,36. H A 2007 Cho 0,87 gam hn hp gm Fe, Cu v Al vo bnh ng 300 ml dung dch H2SO4 0,1M. Sau khi cc phn ng xy ra hon ton, thu c 0,32 gam cht rn v c 448 ml kh (ktc) thot ra. Thm tip vo bnh 0,425 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l A. 0,224 lt v 3,750 gam. B. 0,112 lt v 3,750 gam. C. 0,112 lt v 3,865 gam. D. 0,224 lt v 3,865 gam. H A 2011 Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO3 long, thu c dung dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt kh ha nu trong khng kh. Khi lng ca Y l 5,18 gam. Cho dung dch NaOH (d) vo X v un nng, khng c kh mi khai thot ra. Phn trm khi lng ca Al trong hn hp ban u l A. 19,53%. B. 12,80%. C. 10,52%. D. 15,25%. C 2009 Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M +5 v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht ca N ). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l A. 2. B. 4. C. 3. D. 1. H B 2011 Cho 6,72 gam Fe vo dung dch cha 0,3 mol H 2 SO 4 c, nng (gi thit SO2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton, thu c A. 0,12 mol FeSO4. B. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4. C. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d. D. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4. H B 2007 Cho hn hp gm 6,72 gam Mg v 0,8 gam MgO tc dng ht vi lng d dung dch HNO3. Sau khi cc phn ng xy ra hon ton, thu c 0,896 lt mt kh X (ktc) v dung dch Y. Lm bay hi dung dch Y thu c 46 gam mui khan. Kh X l A. N2O. B. NO. C. N2. D. NO2. C 2010 Cho 3,024 gam mt kim loi M tan ht trong dung dch HNO3 long, thu c 940,8 ml khNxOy (sn phm kh duy nht, ktc) c t khi i vi H2 bng 22. Kh NxOy v kim loi M l A. NO v Mg. B. NO2 v Al. C. N2O v Al. D. N2O v Fe. H A 2009 Cho hn hp bt Al, Fe vo dung dch cha Cu(NO3)2 v AgNO3. Sau khi cc phn ng xy ra hon ton, thu c hn hp rn gm ba kim loi l: A. Fe, Cu, Ag. B. Al, Cu, Ag. C. Al, Fe, Cu. D. Al, Fe, Ag. 31

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C 2008 Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l B. Zn(NO3)2 v Fe(NO3)2. A. Fe(NO3)3 v Zn(NO3)2. C. AgNO3 v Zn(NO3)2. D. Fe(NO3)2 v AgNO3. H A 2009 Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO3 1M. Sau khi cc phn ng xy ra hon ton, thu c m gam cht rn. Gi tr ca m l (bit th t trong dy th in ho: + Fe 3 + /Fe 2 + ng trc Ag /Ag) A. 32,4. B. 64,8. C. 59,4. D. 54,0. H A 2008 Cho 2,7 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO4. Sau mt thi gian, thu c dung dch Y v 2,84 gam cht rn Z. Cho ton b Z vo dung dch H2SO4 (long, d). sau khi cc phn ng kt thc th khi lng cht rn gim 0,28 gam v dung dch thu c ch cha mt mui duy nht. Phn trm khi lng ca Fe trong X l: A. 58,52% B. 51,85% C. 48,15% D. 41,48% H A 2011 Cho 29,8 gam hn hp bt gm Zn v Fe vo 600 ml dung dch CuSO4 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v 30,4 gam hn hp kim loi. Phn trm v khi lng ca Fe trong hn hp ban u l A. 37,58%. B. 64,42%. C. 43,62%. D. 56,37%. C 2010 Cho m1 gam Al vo 100 ml dung dch gm Cu(NO3)2 0,3M v AgNO3 0,3M. Sau khi cc phn ng x y ra hon ton th thu c m2 gam cht rn X. Nu cho m2 gam X tc dng vi lng d dung dch HCl th thu c 0,336 lt kh ( ktc). Gi tr ca m1 v m2 ln lt l A. 8,10 v 5,43. B. 1,08 v 5,43. C. 0,54 v 5,16. D. 1,08 v 5,16. C 2009 Tin hnh hai th nghim sau: Th nghim 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M; Th nghim 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M. Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr ca V1 so vi V2 l A. V1 = 10 V2. B. V1 = 5V2. C. V1 = 2 V2. D. V1 = V2. H B 2008 Cho mt lng bt Zn vo dung dch X gm FeCl2 v CuCl2. Khi lng cht rn sau khi cc phn ng xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn phn dung dch sau phn ng thu c 13,6 gam mui khan. Tng khi lng cc mui trong X l B. 14,1 gam. C. 17,0 gam. D. 19,5 gam. A. 13,1 gam. H B 2008 Cho m gam bt Zn vo 500 ml dung dch Fe2(SO4)3 0,24M. Sau khi cc phn ng xy ra hon ton, khi lng dung dch tng thm 9,6 gam so vi khi lng dung dch ban u. Gi tr ca m l A. 20,80. B. 29,25. C. 48,75. D. 32,50. H B 2011 2+ + Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu v 1 mol Ag n khi cc phn ng xy ra hon ton, thu c mt dung dch cha ba ion kim loi. Trong cc gi tr sau y, gi tr no ca x tho mn trng hp trn? A. 1,8. B. 1,5. C. 1,2. D. 2,0. H A 2009 Cho m gam hn hp bt Zn v Fe vo lng d dung dch CuSO4. Sau khi kt thc cc phn ng, lc b phn dung dch thu c m gam bt rn. Thnh phn phn trm theo khi lng ca Zn trong hn hp bt ban u l A. 90,27%. B. 12,67%. C. 85,30%. D. 82,20%. H B 2007 Nhng mt thanh st nng 100 gam vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc 32

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D. 1,72 gam. H B 2009 Ha tan hn hp bt gm m gam Cu v 4,64 gam Fe3O4 vo dung dch H2SO4 (long, rt d) sau khi cc phn ng kt thc ch thu c dung dch X. Dung dch X lm mt mu va 100 ml dung dch KMnO4 0,1M. Gi tr ca m l: A. 1,24 B. 3,2 C. 0,64 D.0,96 H A 2011 Nhng mt l kim loi M (ch c ho tr hai trong hp cht) c khi lng 50 gam vo 200 ml dung dch AgNO3 1M cho n khi phn ng xy ra hon ton. Lc dung dch, em c cn thu c 18,8 gam mui khan. Kim loi M l A. Fe. B. Cu. C. Mg. D. Zn. C 2009 Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H 2 SO 4 0,1M (va ). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l A. 6,81 gam. B. 4,81 gam. C. 3,81 gam. D. 5,81 gam. H A 2007 Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va phn ng ht vi Y l A. 50 ml. B. 57 ml. C. 75 ml. D. 90 ml. H A 2008 Nung nng 16,8 gam hn hp gm Au, Ag, Cu, Fe, Zn vi mt lng d kh O2, n khi cc phn ng xy ra hon ton, thu c 23,2 gam cht rn X. Th tch dung dch HCl 2M va phn ng vi cht rn X l A. 400 ml. B. 200 ml. C. 800 ml. D. 600 ml. C 2009 ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l A. 0,16. B. 0,18. C. 0,23. D. 0,08. H A 2008 Cho 9,12 gam hn hp gm FeO, Fe2O3, Fe3O4 tc dng vi dung dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l A. 8,75. B. 9,75. C. 6,50. D. 7,80. H B 2008 Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 35,50. B. 34,36. C. 49,09. D. 38,72. H A 2008 t chy hon ton 7,2 gam kim loi M (c ho tr hai khng i trong hp cht) trong hn hp kh Cl2 v O2. Sau phn ng thu c 23,0 gam cht rn v th tch hn hp kh phn ng l 5,6 lt ( ktc). Kim loi M l 4 4 A. Mg. B. Ca. C. Be. D. Cu. C 2009 Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 (ktc). Gi tr ca V l A. 2,80. B. 3,36. C. 3,08. D. 4,48. C 2008 Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao. Sau phn ng hn hp rn cn li l: A. Cu, Fe, Zn, MgO. B. Cu, Fe, ZnO, MgO. C. Cu, Fe, Zn, Mg. D. Cu, FeO, ZnO, MgO. 33

kim loi to thnh u bm ht vo thanh st). Khi lng st phn ng l A. 1,40 gam. B. 2,16 gam. C. 0,84 gam.

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224.

H A 2007 Cho kh CO (d) i vo ng s nung nng ng hn hp X gm Al2O3, MgO, Fe3O4, CuO thu c cht rn Y. Cho Y vo dung dch NaOH (d), khuy k, thy cn li phn khng tan Z. Gi s cc phn ng xy ra hon ton. Phn khng tan Z gm C. MgO, Fe, Cu. D. Mg, Al, Fe, Cu. A. Mg, Fe, Cu. B. MgO, Fe3O4, Cu. C 2007 Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l A. 1,120. B. 0,896. C. 0,448. D. 0,224. C 2008 Trn 10,8 gam bt Al vi 34,8 gam bt Fe3O4 ri tin hnh phn ng nhit nhm trong iu kin khng c khng kh. Ho tan hon ton hn hp rn sau phn ng bng dung dch H2SO4 long (d), thu c 10,752 lt kh H2 (ktc). Hiu sut ca phn ng nhit nhm l A. 80%. B. 90%. C. 70%. D. 60%. H B 2010 Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l A. 0,112. B. 0,560. C. 0,224. D. 0,448. H A 2008 Cho m gam bt Cu vo 400 ml dung dch AgNO3 0,2M, sau mt thi gian phn ng thu c 7,76 gam hn hp cht rn X v dung dch Y. Lc tch X, ri thm 5,85 gam bt Zn vo Y, sau khi phn ng xy ra hon ton thu c 10,53 gam cht rn Z. Gi tr ca m l A. 5,12. B. 3,84. C. 5,76. D. 6,40. H B 2011 Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al2O3 nung nng n khi phn ng hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l A. 0,8 gam. B. 8,3 gam. C. 2,0 gam. D. 4,0 gam. H A 2009 Cho hi nc i qua than nng , thu c 15,68 lt hn hp kh X (ktc) gm CO, CO2 v H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ho tan ton b Y bng dung dch HNO3 (long, d) c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l A. 57,15%. B. 14,28%. C. 28,57%. D. 18,42%. H B 2011 Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng A. Fe3O4; 75%. B. Fe2O3; 75%. C. Fe2O3; 65%. D. FeO; 75%. C 2007

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6. Kim loi kim, kim loi kim th, nhm, st, crom, ng. Ha hc vi vn pht trin kinh t, x hi v mi trng: 5
Trong cng nghip, natri hiroxit c sn xut bng phng php A. in phn dung dch NaNO3, khng c mng ngn in cc. B. in phn dung dch NaCl, c mng ngn in cc. C. in phn dung dch NaCl, khng c mng ngn in cc. D. in phn NaCl nng chy.

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C 2007 Ho tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688 lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4, t l mol tng ng l 4 : 1. Trung ho dung dch X bi dung dch Y, tng khi lng cc mui c to ra l A. 18,46 gam. B. 12,78 gam. C. 14,62 gam. D. 13,70 gam. H A 2010 Thc hin cc th nghim sau: 34

I.Cho dung dch NaCl vo dung dch KOH. II.Cho dung dch Na2CO3 vo dung dch Ca(OH)2. III.in phn dung dch NaCl vi in cc tr, c mng ngn. IV.Cho Cu(OH)2 vo dung dch NaNO3. (V) Sc kh NH3 vo dung dchNa2CO3. VI. Cho dung dch Na2SO4 vo dung dch Ba(OH)2. Cc th nghim u iu ch c NaOH l: A. II, III v VI. B. I, II v III. C. I, IV v V. 234.

D. II, V v VI. H B 2009 Phn ng ho hc xy ra trong trng hp no di y khng thuc loi phn ng nhit nhm? B. Al tc dng vi axit H 2 SO 4 c, nng. A. Al tc dng vi Fe3O4 nung nng. C. Al tc dng vi CuO nung nng. D. Al tc dng vi Fe2O3 nung nng. C 2007

235.

thu c Al2O3 t hn hp Al2O3 v Fe2O3, ngi ta ln lt: A.dng dung dch NaOH (d), kh CO2 (d), ri nung nng. B.dng kh H2 nhit cao, dung dch NaOH (d). C. dng kh CO nhit cao, dung dch HCl (d). D.dng dung dch NaOH (d), dung dch HCl (d), ri nung nng. H B 2007 Nguyn tc luyn thp t gang l: A. Dng CaO hoc CaCO3 kh tp cht Si, P, S, Mn, trong gang thu c thp. B. Dng cht kh CO kh oxit st thnh st nhit cao. C. Dng O2 oxi ho cc tp cht Si, P, S, Mn, trong gang thu c thp. D. Tng thm hm lng cacbon trong gang thu c thp. H B 2008 Cho 1,56 gam hn hp gm Al v Al2O3 phn ng ht vi dung dch HCl (d), thu c V lt kh H2 (ktc) v dung dch X. Nh t t dung dch NH3 n d vo dung dch X thu c kt ta, lc ht lng kt ta, nung n khi lng khng i thu c 2,04 gam cht rn. Gi tr ca V l A. 0,224. B. 1,344. C. 0,672. D. 0,448. C 2010 Ha tan hon ton 2,45 gam hn hp X gm hai kim loi kim th vo 200 ml dung dch HCl 1,25M, thu c dung dch Y cha cc cht tan c nng mol bng nhau. Hai kim loi trong X l A. Mg v Ca. B. Be v Mg. C. Mg v Sr. D. Be v Ca. H B 2010 Cho 150 ml dung dch KOH 1,2M tc dng vi 100 ml dung dch AlCl3 nng x mol/l, thu c dung dch Y v 4,68 gam kt ta. Loi b kt ta, thm tip 175 ml dung dch KOH 1,2M vo Y, thu c 2,34 gam kt ta. Gi tr ca x l A. 1,2. B. 0,8. C. 0,9. D. 1,0. H B 2010 Cho dy cc cht: NH4Cl, (NH4)2SO4, NaCl, MgCl2, FeCl2, AlCl3. S cht trong dy tc dng vi lng d dung dch Ba(OH)2 to thnh kt ta l A. 5. B. 4. C. 1. D. 3. C 2008 Dy gm cc cht (hoc dung dch) u phn ng c vi dung dch FeCl2 l: A. Bt Mg, dung dch BaCl2, dung dch HNO3. B. Kh Cl2, dung dch Na2CO3, dung dch HCl. C. Bt Mg, dung dch NaNO3, dung dch HCl. D. Kh Cl2, dung dch Na2S, dung dch HNO3 Cho s phn ng: NaCl (X) NaHCO3 (Y) NaNO3. X v Y c th l A. NaOH v NaClO. B. NaOH v Na2CO3. C. Na2CO3 v NaClO. D. NaClO3 v Na2CO3. C 2007 Cho cc phn ng: (a) Sn + HCl (long) (c) MnO2 + HCl (c) (e) Al + H2SO4 (long) 35

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(b) FeS + H2SO4 (long) (d) Cu + H2SO4 (c) (g) FeSO4 + KMnO4 + H2SO4

+ S phn ng m H ca axit ng vai tr cht oxi ho l A. 3. B. 5. 244. T hai mui X v Y thc hin cc phn ng sau:

C. 2.

D. 6. H B 2011

X X1 + CO2 X1 + H2O X2 X2 + Y X + Y1 + H2O X2 + 2Y X + Y2 + 2H2O Hai mui X, Y tng ng l A. BaCO3, Na2CO3 B. CaCO3, NaHSO4 C. MgCO3, NaHCO3 D. CaCO3, NaHCO3 H A 2008
to

245.

Mt mu nc cng cha cc ion: Ca2+, M g 2 + , nc cng trn l A. HCl. B. H 2 SO 4 . C. Na2CO3.

2HCO3 , Cl-, SO 4 . Cht c dng lm mm mu

D. NaHCO3. H B 2008

246.

Dy gm cc cht u c th lm mt tnh cng tm thi ca nc l: A. HCl, NaOH, Na2CO3. B. NaOH, Na3PO4, Na2CO3. C. KCl, Ca(OH)2, Na2CO3. D. HCl, Ca(OH)2, Na2CO3. H A 2011 Hai cht c dng lm mm nc cng vnh cu l A. Na2CO3 v HCl. C. Na2CO3 v Ca(OH)2.

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B. Na2CO3 v Na3PO4. D. NaCl v Ca(OH)2.

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C 2008 Cho mt mu hp kim Na-Ba tc dng vi nc (d), thu c dung dch X v 3,36 lt H2 (ktc). Th tch dung dch axit H 2 SO 4 2M cn dng trung ho dung dch X l A. 60ml. B. 150ml. C. 30ml. D. 75ml. C 2007 Khi cho 100ml dung dch KOH 1M vo 100ml dung dch HCl thu c dung dch c cha 6,525 gam cht tan. Nng mol (hoc mol/l) ca HCl trong dung dch dng l A. 0,75M. B. 1M. C. 0,5M. D. 0,25M. C 2007 Chia m gam Al thnh hai phn bng nhau: Phn mt tc dng vi lng d dung dch NaOH, sinh ra x mol kh H2; Phn hai tc dng vi lng d dung dch HNO3 long, sinh ra y mol kh N2O (sn phm kh duy nht). Quan h gia x v y l A. x = 2y. B. y = 2x. C. x = 4y. D. x = y. C 2008 Cho hn hp gm Na v Al c t l s mol tng ng l 1 : 2 vo nc (d). Sau khi cc phn ng xy ra hon ton, thu c 8,96 lt kh H2 ( ktc) v m gam cht rn khng tan. Gi tr ca m l A. 5,4. B. 7,8. C. 10,8. D. 43,2. H A 2008 Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th thot ra V lt kh. Nu cng cho m gam X vo dung dch NaOH (d) th c 1,75V lt kh. Thnh phn phn trm theo khi lng ca Na trong X l (bi t cc th tch kh o trong cng iu kin) A. 77,31%. B. 39,87%. C. 49,87%. D. 29,87%. HB 2007 Chia hn hp X gm K, Al v Fe thnh hai phn bng nhau. - Cho phn 1 vo dung dch KOH (d) thu c 0,784 lt kh H2 (ktc). - Cho phn 2 vo mt lng d H2O, thu c 0,448 lt kh H2 (ktc) v m gam hn hp kim loi Y. Ha tan hon ton Y vo dung dch HCl (d) thu c 0,56 lt kh H2 (ktc). Khi lng (tnh theo gam) ca K, Al, Fe trong mi phn hn hp X ln lt l: A. 0,39; 0,54; 1,40. B. 0,78; 0,54; 1,12. C. 0,39; 0,54; 0,56. D. 0,78; 1,08; 0,56. H A 2011 Ho tan hon ton 2,9 gam hn hp gm kim loi M v oxit ca n vo nc, thu c 500 ml dung dch cha mt cht tan c nng 0,04M v 0,224 lt kh H2 ( ktc). Kim loi M l A. Na. B. Ca. C. Ba. D. K. H B 2009 Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp 36

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kh v dung dch X. Sc kh CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l A. 0,55. B. 0,60. C. 0,45. D. 0,40. H A 2008 Nung 13,4 gam hn hp 2 mui cacbonat ca 2 kim loi ha tr 2, thu c 6,8 gam cht rn v kh X. Lng kh X sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan thu c sau phn ng l A. 5,8 gam. B. 4,2 gam. C. 6,3 gam. D. 6,5 gam. H B 2007 Hp th hon ton 4,48 lt kh CO2 (ktc) vo 500 ml dung dch hn hp gm NaOH 0,1M v Ba(OH)2 0,2M, sinh ra m gam kt ta. Gi tr ca m l A. 9,85. B. 11,82. C. 19,70. D. 17,73. H A 2008 Hp th hon ton 3,36 lt kh CO2 (ktc) vo 125 ml dung dch Ba(OH)2 1M, thu c dung dch X. Coi th tch dung dch khng thay i, nng mol ca cht tan trong dung dch X l A. 0,6M. B. 0,4M. C. 0,2M. D. 0,1M. C 2010 H p th hon ton 2,24 lt CO2 ( ktc) vo 100 ml dung d ch g m K2 CO 3 0,2M v KOH x mol/lt, sau khi cc phn ng x y ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch BaCl2 (d), thu c 11,82 gam kt ta. Gi tr ca x l A. 1,6. B. 1,2. C. 1,0. D. 1,4. H B 2011 Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v Ba(OH)2 0,12M, thu c m gam kt ta. Gi tr ca m l B. 3,940. C. 1,970. D. 2,364. A. 1,182. H A 2009 Hp th hon ton 0,672 lt kh CO2 (ktc) vo 1 lt dung dch gm NaOH 0,025M v Ca(OH)2 0,0125M, thu c x gam kt ta. Gi tr ca x l A. 2,00. B. 0,75. C. 1,00. D. 1,25. H A 2011 Hp th hon ton 2,688 lt kh CO2(ktc) vo 2,5 lt dung dch Ba(OH)2 nng a mol/l, thu c 15,76 gam kt ta. Gi tr ca a l B. 0,048. C. 0,06. D. 0,04. A. 0,032. H A 2007 Cho 100 ml dung dch KOH 1,5M vo 200 ml dung dch H3PO4 0,5M, thu c dung dch X. C cn dung dch X, thu c hn hp gm cc cht l A. KH2PO4 v K3PO4. B. KH2PO4 v K2HPO4. C. KH2PO4 v H3PO4. D. K3PO4 v KOH. H B 2009 Cho 0,1 mol P2O5 vo dung dch cha 0,35 mol KOH. Dung dch thu c c cc cht: A. K2HPO4, KH2PO4. B. K3PO4, KOH. C. H3PO4, KH2PO4. D. K3PO4, K2HPO4. H B 2008 Cho t t dung dch cha a mol HCl vo dung dch cha b mol Na2CO3 ng thi khuy u, thu c V lt kh ( ktc) v dung dch X. Khi cho d nc vi trong vo dung dch X thy c xut hin kt ta. Biu thc lin h gia V vi a, b l: A. V = 22,4(a - b). B. V = 11,2(a - b). C. V = 11,2(a + b). D. V = 22,4(a + b). H A 2007 Dung dch X cha hn hp gm Na2CO3 1,5M v KHCO3 1M. Nh t t tng git cho n ht 200 ml dung dch HCl 1M vo 100 ml dung dch X, sinh ra V lt kh ( ktc). Gi tr ca V l A. 4,48. B. 3,36. C. 2,24. D. 1,12. H A 2009 Nh t t tng git n ht 30 ml dung dch HCl 1M vo 100 ml dung d ch cha Na2CO30,2M v NaHCO3 0,2M, sau phn ng thu c s mol CO2 l A. 0,015. B. 0,010. C. 0,020. D. 0,030. H A 2010 Cho 9,125 gam mui hirocacbonat phn ng ht vi dung dch H2SO4 (d), thu c dung dch cha 7,5 37

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gam mui sunfat trung ho. Cng thc ca mui hirocacbonat l A. Mg(HCO3)2. B. NaHCO3. C. Ca(HCO3)2. 269.

D. Ba(HCO3)2. C 2010

270.

Cho dung dch Ba(HCO3)2 ln lt vo cc dung dch: CaCl2, Ca(NO3)2, NaOH, Na2CO3, KHSO4, Na2SO4, Ca(OH)2, H2SO4, HCl. S trng hp c to ra kt ta l A. 4. B. 7. C. 5. D. 6. H B 2010 Cho 1,9 gam hn hp mui cacbonat v hirocacbonat ca kim loi kim M tc dng ht vi dung dch HCl (d), sinh ra 0,448 lt kh ( ktc). Kim loi M l A. Na. B. Li. C. K. D. Rb. H B 2008 Cho m gam NaOH vo 2 lt dung dch NaHCO3 nng a mol/l, thu c 2 lt dung dch X. Ly 1 lt dung dch X tc dng vi dung dch BaCl2 (d) thu c 11,82 gam kt ta. Mt khc, cho 1 lt dung dch X vo dung dch CaCl2 (d) ri un nng, sau khi kt thc cc phn ng thu c 7,0 gam kt ta. Gi tr ca a, m tng ng l A. 0,04 v 4,8. B. 0,07 v 3,2. C. 0,08 v 4,8. D. 0,14 v 2,4. H A 2010 Nhit phn hon ton 40 gam mt loi qung lmit c ln tp cht tr sinh ra 8,96 lt kh CO2(ktc). Thnh phn phn trm v khi lng ca CaCO3.MgCO3 trong loi qung nu trn l B. 84%. C. 40%. D. 92%. A. 50%. H B 2008 AlCl Nh t t cho n d dung dch NaOH vo dung dch 3 . Hin tng xy ra l B. ch c kt ta keo trng. A. c kt ta keo trng, sau kt ta tan. C. c kt ta keo trng v c kh bay ln. D. khng c kt ta, c kh bay ln. H A 2007 + 3+ Dung dch X gm 0,1 mol H , z mol Al , t mol NO3 v 0,02 mol SO42. Cho 120 ml dch Y gm KOH 1,2M v Ba(OH)2 0,1M vo X, sau khi cc phn ng kt thc, thu c 3,732 gam kt ta. Gi tr ca z, t ln lt l A. 0,020 v 0,012. B. 0,012 v 0,096. C. 0,020 v 0,120. D. 0,120 v 0,020. H B 2011 Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl3; 0,016 mol Al2(SO4)3 v 0,04 mol H2SO4 thu c m gam kt ta. Gi tr ca m l A. 2,568. B. 1,560. C. 4,128. D. 5,064. C 2009 Ho tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu c dung dch X. Cho ton b X tc dng vi 200 ml dung dch Ba(OH)2 1M, sau phn ng thu c m gam kt ta. Gi tr ca m l B. 46,6. C. 54,4. D. 62,2. A. 7,8. C 2009 Trn dung dch cha a mol AlCl3 vi dung dch cha b mol NaOH. thu c kt ta th cn c t l A. a : b = 1 : 4. B. a : b < 1 : 4. C. a : b = 1 : 5. D. a : b > 1 : 4. H A 2007 Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. T l x : y l A. 3 : 4. B. 3 : 2. C. 4 : 3. D. 7 : 4. H B 2011 Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6 gam. Gi tr ln nht ca V l A. 1,2. B. 1,8. C. 2,4. D. 2. H B 2007 Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol H 2 SO 4 n khi phn ng hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l A. 0,35. B. 0,45. C. 0,25. D. 0,05. H A 2008 Thm m gam kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X. 38

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Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln nht th gi tr ca m l A. 1,59. B. 1,17. C. 1,95. D. 1,71. C 2007 Cho 7,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th Y tc dng ht vi lng d dung dch HCl long, thu c 5,6 lt kh (ktc). Kim loi X, Y l A. kali v bari. B. kali v canxi. C. natri v magie. D. liti v beri. H A 2010 Ho tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110 ml dung dch KOH 2M vo X, thu c a gam kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi tr ca m l A. 20,125. B. 22,540. C. 12,375. D. 17,710. H A 2009 Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch Y ch cha cht tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta. Gi tr ca m v a ln lt l A. 8,3 v 7,2. B. 11,3 v 7,8. C. 13,3 v 3,9. D. 8,2 v 7,8. C 2009 iu ch c 78 gam Cr t Cr2O3 (d) bng phng php nhit nhm vi hiu sut ca phn ng l 90% th khi lng bt nhm cn dng ti thiu l A. 81,0 gam. B. 54,0 gam. C. 40,5 gam. D. 45,0 gam. C 2009 Nung hn hp bt gm 15,2 gam Cr2 O3 v m gam Al nhit cao. Sau khi phn ng hon ton, thu c 23,3 gam hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl (d) thot ra V lt kh H2 (ktc). Gi tr ca V l A. 4,48. B. 3,36. C. 7,84. D. 10,08. H B 2007 Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2O3 trong hn hp X l A. 20,33%. B. 50,67%. C. 36,71%. D. 66,67%. C 2007 Thc hin phn ng nhit nhm hn hp gm m gam Al v 4,56 gam Cr2O3 (trong iu kin khng c O2), sau khi phn ng kt thc, thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl (long, nng), sau khi cc phn ng xy ra hon ton, thu c 2,016 lt H2 (ktc). Cn nu cho ton b X vo mt lng d dung dch NaOH (c, nng), sau khi cc phn ng kt thc th s mol NaOH phn ng l A. 0,14 mol. B. 0,08 mol. C. 0,16 mol. D. 0,06 mol. H B 2011 Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn Y. Chia Y thnh hai phn bng nhau: Phn 1 tc dng vi dung dch H 2 SO 4 long (d), sinh ra 3,08 lt kh H2 (ktc); Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H2 (ktc). Gi tr ca m l A. 22,75 B. 29,43. C. 29,40. D. 21,40. H A 2008 Nung nng m gam hn hp gm Al v Fe3O4 trong iu kin khng c khng kh. Sau khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng vi dung dch NaOH (d) thu c dung dch Y, cht rn Z v 3,36 lt kh H2 ( ktc). Sc kh CO2 (d) vo dung dch Y, thu c 39 gam kt ta. Gi tr ca m l A. 45,6. B. 48,3. C. 36,7. D. 36,7. H B 2009 t nng mt hn hp gm Al v 16 gam Fe2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c hn hp rn X. Cho X tc dng va vi V ml dung dch NaOH 1M sinh ra 3,36 lt H2 (ktc). Gi tr ca V l A. 150. B. 100. C. 200. D. 300. C 2008 39

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luyn c 800 tn gang c hm lng st 95%, cn dng x tn qung manhetit cha 80% Fe3O4 (cn li l tp cht khng cha st). Bit rng lng st b hao ht trong qu trnh sn xut l 1%. Gi tr ca x l A. 1394,90. B. 1325,16. C. 1311,90. D. 959,59. H B 2011 Hn hp bt X gm Cu, Zn. t chy hon ton m gam X trong oxi (d), thu c 40,3 gam hn hp gm CuO v ZnO. Mt khc, nu cho 0,25 mol X phn ng vi mt lng d dung dch KOH long nng, th thu c 3,36 lt kh H2 (ktc). Phn trm khi lng ca Cu trong X l A. 19,81%. B. 29,72%. C. 39,63%. D. 59,44%. H B 2010 Nung m gam bt st trong oxi, thu c 3 gam hn hp cht rn X. Ha tan ht hn hp X trong dung dch HNO3(d), thot ra 0,56 lt (ktc) NO (l sn phm kh duy nht). Gi tr ca m l A. 2,52. B. 2,22. C. 2,32. D. 2,62. H B 2007 Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 35,50. B. 34,36. C. 49,09. D. 38,72. H A 2008 Cho hn hp Fe, Cu phn ng vi dung dch HNO3 long. Sau khi phn ng hon ton, thu c dung dch ch cha mt cht tan v kim loi d. Cht tan l A. Fe(NO3)3 B. Fe(NO3)2 C. HNO3. D. Cu(NO3)2. H B 2007 Cho hn hp X gm Mg v Fe vo dung dch axit H2SO4 c, nng n khi cc phn ng xy ra hon ton, thu c dung dch Y v mt phn Fe khng tan. Cht tan c trong dung dch Y l A. MgSO4 v Fe2(SO4)3. B. MgSO4, Fe2(SO4)3 v FeSO4. C. MgSO4 v FeSO4. D. MgSO4. C 2007 Cho 6,72 gam Fe vo dung dch cha 0,3 mol H 2 SO 4 c, nng (gi thit SO2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton, thu c A. 0,12 mol FeSO4. B. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4. C. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d. D. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4. H B 2007 Th tch dung dch HNO3 1M (long) t nht cn dng ho tan hon ton mt hn hp gm 0,15 mol Fe v 0,15 mol Cu l (bit phn ng to cht kh duy nht l NO) A. 0,8 lt. B. 1,0 lt. C. 0,6 lt. D. 1,2 lt. H B 2008 Ha tan hon ton 12 gam hn hp Fe, Cu (t l mol 1:1) bng axit HNO3, thu c V lt (ktc) hn hp kh X (gm NO v NO2) v dung dch Y (ch cha hai mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V l A. 2,24. B. 4,48. C. 5,60. D. 3,36. H A 2007 Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c kh NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l A. 1,92. B. 3,20. C. 0,64. D. 3,84. H A 2009 Cho a gam Fe vo 100 ml dung dch hn hp gm HNO3 0,8M v Cu(NO3)2 1M. Sau khi cc phn ng xy ra hon ton, thu c 0,92a gam hn hp kim loi v kh NO (sn phm kh duy nht ca N ). Gi tr ca a l A. 11,2. B. 11,0. C. 5,6. D. 8,4. C 2010 Cho 61,2 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 3,36 lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 2,4 gam kim loi. C cn dung dch Y, thu c m gam mui khan. Gi tr ca m l 40

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A. 151,5. 304.

B. 137,1.

C. 97,5.

D. 108,9. H B 2009

305.

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D. manhetit. H A 2008 Khi nung hn hp cc cht Fe(NO3)2, Fe(OH)3 v Fe CO 3 trong khng kh n khi lng khng i, thu c mt cht rn l A. Fe3O4. B. FeO. C. Fe. D. Fe2O3. H A 2007 Ha tan hon ton Fe3O4 trong dung dch H 2 SO 4 long (d) c dung dch X1. Cho lng d bt Fe vo dung dch X1 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton, thu c dung dch X2 cha cht tan l A. Fe2(SO4)3 v H 2 SO 4 . B. FeSO4. C. Fe2(SO4)3. D. FeSO4 v H 2 SO 4 . C 2008 Cho dy cc cht: FeO, Fe(OH)2, FeSO4, Fe3O4, Fe2(SO4)3, Fe2O3. S cht trong dy b oxi ha khi tc dng vi dung dch HNO3 c, nng l A. 3. B. 5. C. 4 D. 6. C 2008 Trong cc cht: FeCl2, FeCl3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3. S cht c c tnh oxi ho v tnh kh l A. 2. B. 3. C. 5. D. 4. C 2009 Cho dung dch X cha KMnO4 v H2SO4 (long) ln lt vo cc dung dch: FeCl2, FeSO4, CuSO4, MgSO4, H2S, HCl (c). S trng hp c xy ra phn ng oxi ho - kh l A. 3. B. 5. C. 4. D. 6. H B 2010 Cho s chuyn ho: Fe3O4 + dung dch HI (d) X + Y + H2O Bit X v Y l sn phm cui cng ca qu trnh chuyn ho. Cc cht X v Y l A. Fe v I2. B. FeI3 v FeI2. C. FeI2 v I2.

Trong cc loi qung st, qung c hm lng st cao nht l A. hematit . B. xierit. C. hematit nu.

307.

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D. FeI3 v I2. H B 2010

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Cho tng cht: Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3 , FeCO3 ln lt phn ng vi HNO3 c, nng. S phn ng thuc loi phn ng oxi ho - kh l A. 8. B. 5. C. 7. D. 6. H A 2007 Cho hn hp X gm Fe2O3, ZnO v Cu tc dng vi dung dch HCl (d) thu c dung dch Y v phn khng tan Z. Cho Y tc dng vi dung dch NaOH (long, d) thu c kt ta: A. Fe(OH)3 v Zn(OH)2 B. Fe(OH)2, Cu(OH)2 v Zn(OH)2 D. Fe(OH)2 v Cu(OH)2 C. Fe(OH)3 H A 2011 Ho tan 5,6 gam Fe bng dung dch H 2 SO 4 long (d), thu c dung dch X. Dung dch X phn ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V l A. 80. B. 40. C. 20. D. 60. H A 2007 Cho 0,3 mol bt Cu v 0,6 mol Fe(NO3)2 vo dung dch cha 0,9 mol H2SO4 (long). Sau khi cc phn ng xy ra hon ton, thu c V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 6,72. B. 8,96. C. 4,48. D. 10,08. H B 2010 ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l A. 0,16. B. 0,18. C. 0,23. D. 0,08. H A 2008 41

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Cho 9,12 gam hn hp gm FeO, Fe3O4 v Fe2O3 tc dng vi dung dch HCl (d). Sau khi cc phn ng xy ra hon ton, c dung dch Y; c cn Y thu c 7,62 gam FeCl2 v m gam FeCl3. Gi tr ca m l A. 8,75. B. 9,75. C. 6,50. D. 7,80. H B 2008 Cho m gam hn hp X gm FeO, Fe2O3, Fe3O4 vo mt lng va dung dch HCl 2M, thu c dung dch Y c t l s mol Fe2+ v Fe3+ l 1 : 2. Chia Y thnh hai phn bng nhau. C cn phn mt thu c m1 gam mui khan. Sc kh clo (d) vo phn hai, c cn dung dch sau phn ng thu c m2 gam mui khan. Bit m2 m1 = 0,71. Th tch dung dch HCl dng l A. 240 ml. B. 80 ml. C. 320 ml. D. 160 ml. C 2009 Cho x mol Fe tan hon ton trong dung dch cha y mol H2SO4 (t l x : y = 2 : 5), thu c mt sn phm kh duy nht v dung dch ch cha mui sunfat. S mol electron do lng Fe trn nhng khi b ho tan l A. 2x. B. 3x. C. y. D. 2y. H A 2010 Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3 long (d), thu c 1,344 lt kh NO (sn phm kh duy nht, ktc) v dung dch X. C cn dung dch X thu c m gam mui khan. Gi tr ca m l A. 35,50. B. 34,36. C. 49,09. D. 38,72. H A 2008 Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch X v 3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat khan. Gi tr ca m l A. 52,2. B. 54,0. C. 58,0. D. 48,4. H B 2009 Cho 0,01 mol mt hp cht ca st tc dng ht vi H 2 SO 4 c nng (d), thot ra 0,112 lt (ktc) kh SO2 l sn phm kh duy nht). Cng thc ca hp cht st l A. FeS. B. FeS2. C. FeO D. F e CO 3 . H B 2007 Kh hon ton mt oxit st X nhit cao cn va V lt kh CO ( ktc), sau phn ng thu c 0,84 gam Fe v 0,02 mol kh CO2. Cng thc ca X v gi tr V ln lt l A. Fe3O4 v 0,224. B. Fe3O4 v 0,448. C. FeO v 0,224. D. Fe2O3 v 0,448. C 2009 : Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng ca nit trong X l 11,864%. C th iu ch c ti a bao nhiu gam hn hp ba kim loi t 14,16 gam X? A. 10,56 gam. B. 3,36 gam. C. 7,68 gam. D. 6,72 gam. H B 2011 Cho 4,48 lt kh CO ( ktc) t t i qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi hiro bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp kh sau phn ng l A. Fe3O4; 75%. B. Fe2O3; 75%. C. Fe2O3; 65%. D. FeO; 75%. C 2007 Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c 3,36 gam cht rn. Gi tr ca m l A. 2,16. B. 5,04. C. 4,32. D. 2,88. C 2009 Nhit phn mt lng AgNO3 c cht rn X v hn hp kh Y. Dn ton b Y vo mt lng d H2O, thu c dung dch Z. Cho ton b X vo Z, X ch tan mt phn v thot ra kh NO (sn phm kh duy nht). Bit cc phn ng xy ra hon ton. Phn trm khi lng ca X phn ng l A. 70%. B. 25%. C. 60%. D. 75%. H B 2011 Cho 100 ml dung dch FeCl2 1,2M tc dng vi 200 ml dung dch AgNO3 2M, thu c m gam kt ta. Gi tr ca m l A. 34,44. B. 47,4. C. 30,18. D. 12,96. 42

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C 2009 Ho tan hon ton 24,4 gam hn hp gm FeCl2 v NaCl (c t l s mol tng ng l 1 : 2) vo mt lng nc (d), thu c dung dch X. Cho dung dch AgNO3 (d) vo dung dch X, sau khi phn ng xy ra hon ton sinh ra m gam cht rn. Gi tr ca m l A. 57,4. B. 28,7. C. 10,8. D. 68,2. H B 2009 Nung mt hn hp rn gm a mol Fe C O 3 v b mol FeS2 trong bnh kn cha khng kh (d). Sau khi cc phn ng xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe2O3 v hn hp kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia a v b l (bit sau cc phn ng, lu hunh mc oxi ho +4) A. a = 4b. B. a = 2b. C. a = b. D. a = 0,5b. H B 2008 Ho tan 25 gam hn hp X gm FeSO4 v Fe2(SO4)3 vo nc, thu c 150 ml dung dch Y. Thm H2SO4 (d) vo 20 ml dung dch Y ri chun ton b dung dch ny bng dung dch KMnO4 0,1M th dng ht 30 ml dung dch chun. Phn trm khi lng FeSO4 trong hn hp X l A. 68,4%. B. 9,12%. C. 31,6%. D. 13,68%. H B 2011 Trn 5,6 gam bt st vi 2,4 gam bt lu hunh ri nung nng (trong iu kin khng c khng kh), thu c hn hp rn M. Cho M tc dng vi lng d dung dch HCl, gii phng hn hp kh X v cn li mt phn khng tan G. t chy hon ton X v G cn va V lt kh O2 ( ktc). Gi tr ca V l A. 2,80. B. 3,36. C. 3,08. D. 4,48. C 2008 Pht biu khng ng l: A.Hp cht Cr(II) c tnh kh c trng cn hp cht Cr(VI) c tnh oxi ho mnh. B. Cc hp cht Cr2O3, Cr(OH)3, CrO, Cr(OH)2 u c tnh cht lng tnh. C. Cc hp cht CrO, Cr(OH)2 tc dng c vi dung dch HCl cn CrO3 tc dng c vi dung dch NaOH. D. Thm dung dch kim vo mui icromat, mui ny chuyn thnh mui cromat. H A 2007 NH Cho cc dung dch: HCl, NaOH c, 3, KCl. S dung dch phn ng c vi Cu(OH)2 l A. 2. B. 1. C. 3. D. 4. H B 2008 Cho s chuyn ho gia cc hp cht ca crom:
+ (Cl2 + KOH) + H 2SO4 + FeSO4 + H 2SO4 + KOH Cr(OH)3 X Y Z T

330.

331.

332.

333.

334.

Cc cht X, Y, Z, T theo th t ln lt l: A. K2CrO4; KCrO2; K2Cr2O7; Cr2(SO4)3. C. KCrO2; K2Cr2O7; K2CrO4; CrSO4.

B. KCrO2; K2Cr2O7; K2CrO4; Cr2(SO4)3. D. KCrO2; K2CrO4; K2Cr2O7; Cr2(SO4)3.

335.

Cho cc phn ng: (1) Cu2O + Cu2S

t
o

(2) Cu(NO3)2

t
o

(3) CuO + CO S phn ng to ra kim loi Cu l : A. 1 B. 2

to

(4) CuO + NH3 C. 3

t
o

D. 4 H B 2007

336.

Cho dy cc cht: SiO2, Cr(OH)3, CrO3, Zn(OH)2, NaHCO3, Al2O3. S cht trong dy tc dng c vi dung dch NaOH (c, nng) l A. 4. B. 6. C. 3. D. 5. H B 2011 Pht biu no sau y khng ng? A. Ancol etylic bc chy khi tip xc vi CrO3. B. Khi phn ng vi dung dch HCl, kim loi Cr b oxi ho thnh ion Cr2+. C. Crom(VI) oxit l oxit baz . 43

337.

D. Crom(III) oxit v crom(III) hiroxit u l cht c tnh lng tnh. 338. C 2010 : Nhm nhng cht kh (hoc hi) no di y u gy hiu ng nh knh khi nng ca chng trong kh quyn vt qu tiu chun cho php? A. N2 v CO B. CO2 v O2 C. CH4 v H2O D.CO2 v CH4 H A 2011 : Thc hin cc th nghim sau: (a) Nung NH4NO3 rn. (b) un nng NaCl tinh th vi dung dch H2SO4 (c). (d) Sc kh CO2 vo dung dch Ca(OH)2 (d). (c) Sc kh Cl2 vo dung dch NaHCO3. (g) Cho dung dch KHSO4 vo dung dch NaHCO3. (e) Sc kh SO2 vo dung dch KMnO4. h) Cho PbS vo dung dch HCl (long). (i) Cho Na2SO3 vo dung dch H2SO4 (d), un nng. S th nghim sinh ra cht kh l A. 4. B. 6. C. 5. D. 2. H B 2011 Pht biu no sau y khng ng khi so snh tnh cht ha hc ca nhm v crom? A. Nhm v crom u b th ng ha trong dung dch H2SO4 c ngui. B. Nhm c tnh kh mnh hn crom. C. Nhm v crom u phn ng vi dung dch HCl theo cng t l v s mol. D. Nhm v crom u b n trong khng kh v trong nc. H B 2010 Pht biu no sau y l sai? A. Trong tinh th NaCl, xung quanh mi ion u c 6 ion ngc du gn nht. B. Tt c cc tinh th phn t u kh nng chy v kh bay hi. C. Tinh th nc , tinh th iot u thuc loi tinh th phn t. D. Trong tinh th nguyn t, cc nguyn t lin kt vi nhau bng lin kt cng ho tr. H B 2011 Trng hp xy ra phn ng l A. Cu + Pb(NO3)2 (long) B. Cu + HCl (long) C. Cu + H2SO4 (long) 343. Cho s chuyn ha qung ng thnh ng :
2 X 2 Y Cu CuFeS2 + O ,t 0 + O ,t 0 + X,t 0

339.

340.

341.

342.

D. Cu + HCl (long) + O2 H A 2009

Hai cht X, Y ln lt l A. Cu2O, CuO 344.

B. CuS, CuO

C. Cu2S, CuO

D. Cu2S, Cu2O H A 2008

Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l: A. Na, K, Ca. B. Na, K, Ba. C. Li, Na, Mg.

345.

346.

347.

D. Mg, Ca, Ba. H B 2011 iu ch c 78 gam Cr t Cr2O3 (d) bng phng php nhit nhm vi hiu sut ca phn ng l 90% th khi lng bt nhm cn dng ti thiu l A. 81,0 gam. B. 54,0 gam. C. 40,5 gam. D. 45,0 gam. C 2009 Nung hn hp bt gm 15,2 gam Cr2O3 v m gam Al nhit cao. Sau khi phn ng hon ton, thu c 23,3 gam hn hp rn X. Cho ton b hn hp X phn ng vi axit HCl (d) thot ra V lt kh H2 (ktc). Gi tr ca V l A. 4,48. B. 3,36. C. 7,84. D. 10,08. H B 2007 Khi cho 41,4 gam hn hp X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch NaOH c (d), sau phn ng thu c cht rn c khi lng 16 gam. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Thnh phn phn trm theo khi lng ca Cr2 O3 trong hn hp X l A. 20,33%. B. 50,67%. C. 36,71%. D. 66,67%. C 2007

348.

Hn hp X gm CuO v Fe2O3. Ho tan hon ton 44 gam X bng dung dch HCl (d), sau phn ng thu c dung dch cha 85,25 gam mui. Mt khc, nu kh hon ton 22 gam X bng CO (d), cho hn hp kh thu c sau phn ng li t t qua dung dch Ba(OH)2 (d) th thu c m gam kt ta. Gi tr ca m l 44

A. 76,755. 349.

B. 73,875.

C. 147,750.

D. 78,875.

350.

351.

352.

353.

354.

355.

356.

H B 2010 Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng d dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 8,98 gam mui khan. Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3oxit th th tch kh O2 (ktc) phn ng l A. 1,008 lt. B. 0,672 lt. C. 2,016 lt. D. 1,344 lt. H A 2010 Ho tan hon ton 2,44 gam hn hp bt X gm FexOy v Cu bng dung dch H2SO4 c nng (d). Sau phn ng thu c 0,504 lt kh SO2 (sn phm kh duy nht, ktc) v dung dch cha 6,6 gam hn hp mui sunfat. Phn trm khi lng ca Cu trong X l A. 39,34%. B. 65,57%. C. 26,23%. D. 13,11%. H B 2010 oxi ha hon ton 0,01 mol CrCl3 thnh K2CrO4 bng Cl2 khi c mt KOH, lng ti thiu Cl2 v KOH tng ng l A. 0,03 mol v 0,08 mol. B. 0,015 mol v 0,08 mol. C. 0,015 mol v 0,04 mol. D. 0,03 mol v 0,04 mol. H A 2008 Ha tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh NO2 (sn phm kh duy nht, ktc) v dung dch Y. Sc t t kh NH3 (d) vo dung dch Y, sau khi phn ng xy ra hon ton thu c m gam kt ta. Phn trm v khi lng ca Cu trong hn hp X v gi tr ca m ln lt l A. 21,95% v 2,25. B. 78,05% v 2,25. C. 21,95% v 0,78. D. 78,05% v 0,78. H B 2009 Cho 19,3 gam hn hp bt gm Zn v Cu c t l mol tng ng l 1 : 2 vo dung dch cha0,2 mol Fe2(SO4)3. Sau khi cc phn ng xy ra hon ton, thu c m gam kim loi. Gi tr ca m l A. 12,00. B. 16,53. C. 6,40. D. 12,80. H A 2010 Ho tan hon ton 14,6 gam hn hp X gm Al v Sn bng dung dch HCl (d), thu c 5,6 lt kh H2 ( ktc). Th tch kh O2 ( ktc) cn phn ng hon ton vi 14,6 gam hn hp X l A. 2,80 lt. B. 1,68 lt. C. 4,48 lt. D. 3,92 lt. H A 2009 Khi ho tan hon ton 0,02 mol Au bng nc cng toan th s mol HCl phn ng v s mol NO (sn phm kh duy nht) to thnh ln lt l A. 0,03 v 0,02. B. 0,06 v 0,01. C. 0,03 v 0,01. D. 0,06 v 0,02. H B 2009 Nung nng m gam PbS ngoi khng kh sau mt thi gian, thu c hn hp rn (c cha mt oxit) nng 0,95m gam. Phn trm khi lng PbS b t chy l A. 95,00%. B. 25,31%. C. 74,69%. D. 64,68%. H A 2009

357.

8. Tng hp ni dung cc kin thc ha v c thuc chng trnh ph thng: 6

B. NH3, SO2, CO, Cl2. D. NH3, O2, N2, CH4, H2. C 2007 Khng kh trong phng th nghim b nhim bi kh clo. kh c, c th xt vo khng kh dung dch no sau y? A. Dung dch NH3 B. Dung dch NaCl C.Dung dch NaOH D. Dung dch H2SO4 long H A 2011 C 4 dung dch ring bit: CuSO4, ZnCl2, FeCl3, AgNO3. Nhng vo mi dung dch mt thanh Ni. S trng hp xut hin n mn in ho l A. 1. B. 4. C. 3. D. 2. H B 2010 Thc hin cc th nghim vi hn hp bt gm Ag v Cu (hn hp X): 45 C th dng NaOH ( th rn) lm kh cc cht kh A. N2, NO2, CO2, CH4, H2. C. N2, Cl2, O2, CO2, H2.

358.

359.

360.

(a) Cho X vo bnh cha mt lng d kh O3 ( iu kin thng). (b) Cho X vo mt lng d dung dch HNO3 (c). (c) Cho X vo mt lng d dung dch HCl (khng c mt O2). (d) Cho X vo mt lng d dung dch FeCl3. Th nghim m Cu b oxi ho cn Ag khng b oxi ho l A. (d). B. (a). C. (b). 361. Cht dng lm kh kh Cl2 m l A. nc brom. C. dung dch Ba(OH)2

D. (c). H B 2011

B. CaO D. dung dch NaOH

362.

C 2009 thu ly Ag tinh khit t hn hp X (gm a mol Al2O3, b mol CuO, c mol Ag2O), ngi ta ho tan X bi dung dch cha (6a + 2b + 2c) mol HNO3 c dung dch Y, sau thm (gi thit hiu sut cc phn ng u l 100%) A. c mol bt Al vo Y. B. c mol bt Cu vo Y. C. 2c mol bt Al vo Y. D. 2c mol bt Cu vo Y. H A 2007 Cho dy cc cht sau: Al, NaHCO3, (NH4)2CO3, NH4Cl, Al2O3, Zn, K2CO3, K2SO4. C bao nhiu cht trong dy va tc dng c vi dung dch HCl, va tc dng c vi dung dch NaOH? A. 3. B. 5. C. 4. D. 2. H B 2011 phn bit CO2 v SO2 ch cn dng thuc th l A. nc brom. B. CaO. C. dung dch Ba(OH)2. D. dung dch NaOH. C 2009 Nung nng tng cp cht sau trong bnh kn: (1) Fe + S (r), (2) Fe2O3 + CO (k), (3) Au + O2 (k), (4) Cu + Cu(NO3)2 (r), (5) Cu + KNO3 (r), (6) Al + NaCl (r). Cc trng hp xy ra phn ng oxi ho kim loi l: A. (1), (4), (5). B. (2), (3), (4). C. (2), (5), (6). D. (1), (3), (6). H A 2010 Pht biu no sau y l sai? A. Ch (Pb) c ng dng ch to thit b ngn cn tia phng x. B. Thic c th dng ph ln b mt ca st chng g. C. Trong y hc, ZnO c dng lm thuc gim au dy thn kinh, cha bnh eczema, bnh nga. D. Nhm l kim loi dn in tt hn vng. H B 2011 Ho tan hn hp gm: K2O, BaO, Al2O3, Fe3O4 vo nc (d), thu c dung dch X v cht rn Y. Sc kh CO2 n d vo dung dch X, sau khi cc phn ng xy ra hon ton thu c kt ta l A. K2CO3. B. BaCO3. C. Fe(OH)3. D. Al(OH)3. C 2010 nhn bit ba axit c, ngui: HCl, H 2 SO 4 , HNO3 ng ring bit trong ba l b mt nhn, ta dng thuc th l B. CuO. C. Al. D. Cu. A. Fe. H A 2007 Phn chua c dng trong ngnh cng nghip thuc da, cng nghip giy, cht cm mu trong ngnh nhum vi, cht lm trong nc. Cng thc ha hc ca phn chua l A. Li2SO4.Al2(SO4)3.24H2O. B. K2SO4.Al2(SO4)3.24H2O. C. (NH4)2SO4.Al2(SO4)3.24H2O. D. Na2SO4.Al2(SO4)3.24H2O. H A 2011 Pht biu no sau y khng ng? A. Trong mi trng kim, mui Cr(III) c tnh kh v b cc cht oxi ho mnh chuyn thnh mui Cr(VI). 2+ + B. Do Pb /Pb ng trc 2H /H2 trong dy in ho nn Pb d dng phn ng vi dung dch HCl long ngui, gii phng kh H2. C. CuO nung nng khi tc dng vi NH3 hoc CO, u thu c Cu. D. Ag khng phn ng vi dung dch H2SO4 long nhng phn ng vi dung dch H2SO4 cng. 46

363.

364.

365.

366.

367.

368.

369.

370.

371.

372.

373.

374.

H B 2010 Thc hin cc th nghim sau: (a) Nhit phn AgNO3. (b) Nung FeS2 trong khng kh. (c) Nhit phn KNO3. (d) Cho dung dch CuSO4 vo dung dch NH3 (d). (e) Cho Fe vo dung dch CuSO4. (g) Cho Zn vo dung dch FeCl3 (d). (h) Nung Ag2S trong khng kh. (i) Cho Ba vo dung dch CuSO4 (d). S th nghim thu c kim loi sau khi cc phn ng kt thc l A. 3. B. 5. C. 2. D. 4. H B 2011 C th phn bit 3 dung dch: KOH, HCl, H 2 SO 4 (long) bng mt thuc th l A. Zn. B. Al. C. giy qu tm. D. BaCO3. H B 2007 Trong c th nghim sau : (1) Cho SiO2 tc dng vi axit HF. (2) Cho kh SO2 tc dng vi kh H2S. (3) Cho kh NH3 tc dng vi CuO un nng. (4) Cho CaOCl2 tc dng vi dung dch HCl c. (5) Cho Si n cht tc dng vi dung dch NaOH. (6) Cho kh O3 tc dng vi Ag. (7) Cho dung dch NH4Cl tc dng vi dung dch NaNO2 un nng. S th nghim to ra n cht l: A. 4 B. 7 C. 6 D. 5 H A 2011 Ch dng dung dch KOH phn bit c cc cht ring bit trong nhm no sau y? B. Mg, K, Na C. Zn, Al2O3, Al D. Fe, Al2O3, Mg A. Mg, Al2O3, Al. C 2009 Trong qu trnh hot ng ca pin in ho Zn Cu th 2+ A. nng ca ion Zn trong dung dch tng. B. khi lng ca in cc Cu gim. 2+ C. nng ca ion Cu trong dung dch tng. D. khi lng ca in cc Zn tng. H B 2011 Hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl 2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O (d), un nng, dung dch thu c cha A. NaCl. C. NaCl, NaOH. B. NaCl, NaOH, BaCl 2 . D. NaCl, NaHCO3, NH4Cl, BaCl 2 . H B 2007

375.

376.

377.

Pht biu no sau y l sai? A. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn. B. nhit thng, tt c cc kim loi kim th u tc dng c vi nc. C. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thu tinh. D. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al2O3 bn vng bo v. H B 2011 C cc pht biu sau: (1) Lu hunh, photpho u bc chy khi tip xc vi CrO3. (2) 3+ 5 Ion Fe c cu hnh electron vit gn l [Ar]3d . (3) Bt nhm t bc chy khi tip xc vi kh clo. (4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O. Cc pht biu ng l: A. (1), (3), (4). B. (2), (3), (4). C. (1), (2), (3).

378.

D. (1), (2), (4). H A 2010

379.

380.

: Phng php loi b tp cht HCl c ln trong kh H2S l: Cho hn hp kh li t t qua mt lng d dung dch A. Pb(NO3)2. B. NaHS. C. AgNO3. D. NaOH. H B 2010 Khi so snh NH3 vi NH4+, pht biu khng ng l: A. Trong NH3 v NH4+, nit u c s oxi ha -3. 47

B. NH3 c tnh baz, NH4+ c tnh axit. C. Trong NH3 v NH4+, nit u c cng ha tr 3. D. Phn t NH3 v ion NH4+ u cha lin kt cng ha tr. 381. H A 2011 Cho bn hn hp, mi hn hp gm hai cht rn c s mol bng nhau: Na2O v Al2O3; Cu v FeCl 3; BaCl2 v CuSO4; Ba v NaHCO3. S hn hp c th tan hon ton trong nc (d) ch to ra dung dch l A. 3. B. 2. C. 1. D. 4. H A 2009 : Cho dy cc oxit sau: SO2, NO2, NO, SO3, CrO3, P2O5, CO, N2O5, N2O. S oxit trong dy tc dng c vi H2O iu kin thng l A. 7. B. 5. C. 6. D. 8. H B 2011 Cho cc cht: NaHCO3, CO, Al(OH)3, Fe(OH)3, HF, Cl2, NH4Cl. S cht tc dng c vi dung dch NaOH long nhit thng l A. 3. B. 5. C. 6. D. 4. H A 2010 Cho dy cc cht v ion : Fe, Cl2, SO2, NO2, C, Al, Mg2+, Na+, Fe2+, Fe3+. S cht v ion va c tnh oxi ha, va c tnh kh l: A. 4 B. 5 C. 6 D. 8 H A 2011 C 4 dung dch mui ring bit: CuCl2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) ri thm tip dung dch NH3 (d) vo 4 dung dch trn th s cht kt ta thu c l A. 4. B. 1. C. 3. D. 2. H A 2007 Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4, Mg(NO3)2 dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l: A. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. B. NaCl, Na2SO4, Ca(OH)2. C. HNO3, Ca(OH)2, KHSO4, Na2SO4. D. HNO3, NaCl, Na2SO4. H B 2007 Cho cc cp cht vi t l s mol tng ng nh sau: (a) Fe3O4 v Cu ( :1); (b) Sn v Zn (2:1); (c) Zn v Cu (1:1); (d) Fe2(SO4)3 v Cu (1:1); (e) FeCl2 v Cu (2:1); (g) FeCl3 v Cu (1:1). S cp cht tan hon ton trong mt lng d dung dch HCl long nng l A. 4. B. 2. C. 3. 388. D. 5. H B 2010 Cho cc dung dch: HCl, NaOH c, NH3, KCl. S dung dch phn ng c vi Cu(OH)2 l A. 2. B. 1. C. 3. D. 4. H B 2008 389. Thc hin cc th nghim sau: (1) t dy st trong kh clo. (2) t nng hn hp bt Fe v S (trong iu kin khng c oxi). (3) Cho FeO vo dung dch HNO3 (long, d). (4) Cho Fe vo dung dch Fe2(SO4)3. (5) Cho Fe vo dung dch H2SO4 (long, d). C bao nhiu th nghim to ra mui st (II) ? A. 4 B. 2 C. 3

382.

383.

384.

385.

386.

387.

D. 1

390.

H A 2011 Hn hp rn X gm Al, Fe2O3 v Cu c s mol bng nhau. Hn hp X tan hon ton trong dung dch A. NH3 (d). B. NaOH (d). C. AgNO3 (d). D. HCl (d). H B 2008 Cho cc dung dch long: (1) FeCl3, (2) FeCl2, (3) H2SO4, (4) HNO3, (5) hn hp gm HCl v NaNO3. Nhng dung dch phn ng c vi kim loi Cu l: A. (1), (3), (4). B. (1), (4), (5). C. (1), (2), (3). D. (1), (3), (5). C 2010 48

391.

392.

393.

394.

395.

396.

397.

398.

399.

400.

401.

Cho dy cc cht: KOH, Ca(NO3)2, SO3, NaHSO4, Na2SO3, K2SO4. S cht trong dy to thnh kt ta khi phn ng vi dung dch BaCl 2 l A. 4. B. 6. C. 3. D. 2. C 2008 Nh t t dung dch NaOH n d vo dung dch X. Sau khi cc phn ng xy ra hon ton ch thu c dung dch trong sut. Cht tan trong dung dch X l A. CuSO4. B. AlCl3. C. Fe(NO3)3. D. Ca(HCO3)2. C 2010 C nm dung dch ng ring bit trong nm ng nghim: (NH4)2SO4, FeCl 2, Cr(NO3)3, K2CO3, Al(NO3)3. Cho dung dch Ba(OH)2 n d vo nm dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l A. 4. B. 2. C. 5. D. 3. H A 2009 Th nghim no sau y c kt ta sau phn ng? A. Cho dung dch NaOH n d vo dung dch Cr(NO3)3. B. Cho dung dch NH3 n d vo dung dch AlCl3 C. Cho dung dch HCl n d vo dung dch NaAlO2 (hoc Na[Al(OH)4]) D. Thi CO2 n d vo dung dch Ca(OH)2. H B 2009 Cc kh c th cng tn ti trong mt hn hp l A. Cl2 v O2. B. H2S v Cl2. C. NH3 v HCl. D. HI v O3. C 2007 Dy gm cc ion (khng k n s phn li ca nc) cng tn ti trong mt dung dch l: + 23A. Al3+, NH 4 , Br-, OH-. B. M g 2 + , K+, SO 4 , PO 4 2D. Ag + , Na + , NO3 , Cl - . C. H+, Fe 3 + , NO3 , SO 4 C 2009 Hp cht no ca canxi c dng c tng, b bt khi gy xng? A. Vi sng (CaO). B. Thch cao sng (CaSO4.2H2O). D. Thch cao nung (CaSO4.H2O). C. vi (CaCO3). H A 2011 Trng hp no sau y khng xy ra phn ng ho hc? A. Sc kh Cl2 vo dung dch FeCl2. B. Sc kh H2S vo dung dch CuCl2. C. Sc kh H2S vo dung dch FeCl2. D. Cho Fe vo dung dch H2SO4 long, ngui. H A 2009 Hin tng xy ra khi nh vi git dung dch H2SO4 vo dung dch Na2CrO4 l: A. Dung dch chuyn t mu vng sau khng mu. B. Dung dch chuyn t mu da cam sang mu vng. C. Dung dch chuyn t mu vng sang mu da cam. D. Dung dch chuyn t khng mu sang mu da cam H A 2011 C cc th nghim sau: I. Nhng thanh st vo dung dch H2SO4 long,ngui. (II) Sc kh SO2 vo nc brom. III.Sc kh CO2 vo nc Gia-ven.IV.Nhng l nhm vo dung dch H2SO4 c, ngui. S th nghim xy ra phn ng ho hc l A. 2. B. 1. C. 3. D. 4. H B 2009 Pht biu no sau y khng ng? A. Trong cc dung dch: HCl, H2SO4, H2S c cng nng 0,01M, dung dch H2S c pH ln nht. B. Nh dung dch NH3 t t ti d vo dung dch CuSO4, thu c kt ta xanh. C. Dung dch Na2CO3 lm phenolphtalein khng mu chuyn sang mu hng. D. Nh dung dch NH3 t t ti d vo dung dch AlCl3, thu c kt ta trng. H B 2010 Cho dy cc cht: NaOH, Sn(OH)2, Pb(OH)2, Al(OH)3, Cr(OH)3. S cht trong dy c tnh cht lng tnh l A. 4. B. 1. C. 3. D. 2. H A 2011 49

402.

403.

404.

405.

Ho tan m gam hn hp gm Al, Fe vo dung dch H2SO4 long (d). Sau khi cc phn ng xy ra hon ton, thu c dung dch X. Cho dung dch Ba(OH)2 (d) vo dung dch X, thu c kt ta Y. Nung Y trong khng kh n khi lng khng i, thu c cht rn Z l A. hn hp gm BaSO4 v FeO. B. hn hp gm Al2O3 v Fe2O3. C. hn hp gm BaSO4 v Fe2O3. D. Fe2O3. H B 2009 Cho cc phn ng sau : H2S + O2 (d)
t Kh X + H2O
0

NH3 + O2 Kh Y + H2O NH4HCO3 + HCl long Kh Z + NH4Cl + H2O Cc kh X, Y, Z thu c ln lt l B. SO2, N2, NH3 A. SO3, NO, NH3
8500 C,Pt

C. SO2, NO, CO2

D. SO3, N2, CO2 H B 2008

406.

Cho s chuyn ho (mi mi tn l mt phng trnh phn ng):

+ dd X + dd Y + dd Z NaOH Fe(OH)2 Fe 2 (SO 4 )3 BaSO 4

Cc dd (dung dch) X, Y, Z ln lt l: A. FeCl3, H 2 SO 4 (c, nng), Ba(NO3)2. C. FeCl2, H 2 SO 4 c nng, BaCl 2 . 407.

B. FeCl3, H 2 SO 4 c nng, BaCl 2 . D. FeCl3, H 2 SO 4 c nng, Ba(NO 3 ) 2 .

C 2008 Khi nhit phn hon ton tng mui X, Y th u to ra s mol kh nh hn s mol mui tng ng. t mt lng nh tinh th Y trn n kh khng mu, thy ngn la c mu vng. Hai mui X, Y ln lt l: A. KMnO4, NaNO3. B. Cu(NO3)2, NaNO3.C. CaCO3, NaNO3. D. NaNO3, KNO3. H B 2009 Nhit phn 4,385 gam hn hp X gm KClO3 v KMnO4, thu c O2 v m gam cht rn gm K2MnO4, MnO2 v KCl. Ton b lng O2 tc dng ht vi cacbon nng , thu c 0,896 lt hn hp kh Y (ktc) c t khi so vi H2 l 16. Thnh phn % theo khi lng ca KMnO4 trong X l A. 74,92%. B. 72,06%. C. 27,94%. D. 62,76%. H B 2011 Cho kim loi M tc dng vi Cl2 c mui X; cho kim loi M tc dng vi dung dch HCl c mui Y. Nu cho kim loi M tc dng vi dung dch mui X ta cng c mui Y. Kim loi M c th l A. Mg. B. Al. C. Zn. D. Fe. C 2007 Pht biu khng ng l: A. Kim cng, than ch, fuleren l cc dng th hnh ca cacbon. B. Hiro sunfua b oxi ho bi nc clo nhit thng. C. Tt c cc nguyn t halogen u c cc s oxi ho: -1, +1, +3, +5 v +7 trong cc hp cht. D. Trong cng nghip, photpho c sn xut bng cch nung hn hp qung photphorit, ct v than cc o 1200 C trong l in. H A 2010 Cho 4 dung dch: H2SO4 long, AgNO3, CuSO4, AgF. Cht khng tc dng c vi c 4 dung dch trn l A. BaCl2. B. NaNO3. C. NH3. D. KOH. H A 2010 Qung st manhetit c thnh phn chnh l A. FeS2. B. Fe3O4. C. Fe2O3. D. FeCO3. H A 2011 Thc hin cc th nghim sau: (I) Sc kh SO2 vo dung dch KMnO4. (II) Sc kh SO2 vo dung dch H2S. (III) Sc hn hp kh NO2 v O2 vo nc. (IV) Cho MnO2 vo dung dch HCl c, nng. (V) Cho Fe2O3 vo dung dch H2SO4 c, nng. (VI) Cho SiO2 vo dung dch HF. 50

408.

409.

410.

411.

412.

413.

S th nghim c phn ng oxi ho - kh xy ra l A. 4. B. 3. 414.

C. 6.

D. 5. H A 2010

Tin hnh cc th nghim sau: (1) Cho dung dch NaOH vo dung dch Ca(HCO3)2. (2) Cho dung dch HCl ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (3) Sc kh H2S vo dung dch FeCl2. (4) Sc kh NH3 ti d vo dung dch AlCl3. (5) Sc kh CO2 ti d vo dung dch NaAlO2 (hoc Na[Al(OH)4]). (6) Sc kh etilen vo dung dch KMnO4. Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta? A. 3. B. 4. C. 6. Pht biu no sau yng? A. Dung dch NaF phn ng vi dung dch AgNO3 sinh ra AgF kt ta. B. Axit HBr c tnh axit yu hn axit HCl. C. Iot c bn knh nguyn t ln hn brom. D. Flo c tnh oxi ho yu hn clo.

D. 5. H A 2011

415.

416.

417.

418.

419.

420.

421.

C 2010 T l s ngi cht v bnh phi do ht thuc l gp hng chc ln s ngi khng ht thuc l. Cht gy nghin v gy ung th c trong thuc l l A. aspirin. B. cafein. C. moocphin. D. nicotin. C 2007 Trong s cc ngun nng lng: (1) thy in, (2) gi, (3) mt tri, (4) ho thch; nhng ngun nng lng sch l: A. (1), (3), (4). B. (2), (3), (4). C. (1), (2), (4). D. (1), (2), (3). H A 2010 Cht c dng ty trng giy v bt giy trong cng nghip l A. CO2. B. N2O. C. NO2. D. SO2. H A 2010 Dy gm cc cht v thuc u c th gy nghin cho con ngi l A. cocain, seduxen, cafein. B. heroin, seduxen, erythromixin. C. ampixilin, erythromixin, cafein. D. penixilin, paradol, cocain. H A 2009 Cho mt s nhn nh v nguyn nhn gy nhim mi trng khng kh nh sau: (1) Do hot ng ca ni la. (2) Do kh thi cng nghip, kh thi sinh hot. (3) Do kh thi t cc phng tin giao thng. (4) Do kh sinh ra t qu trnh quang hp ca cy xanh. 2+ 2+ 2+ 2+ (5) Do nng cao ca cc ion kim loi: Pb , Hg , Mn , Cu trong cc ngun nc. Nhng nhn nh ng l: A. (1), (2), (3). B. (2), (3), (5). C. (1), (2), (4). D. (2), (3), (4). H B 2010 Tc nhn ch yu gy ma axit l A. SO2 v NO2. B. CH4 v NH3. C. CO v CH4. D. CO v CO2. H A 2008 nh gi s nhim kim loi nng trong nc thi ca mt nh my, ngi ta ly mt t nc, c c ri thm dung dch Na2S vo thy xut hin kt ta mu vng. Hin tng trn chng t nc thi b nhim bi ion 2+ 2+ 2+ 2+ A. Fe . B. Cu . C. Pb . D. Cd . H B 2010 Hi thu ngn rt c, bi vy khi lm v nhit k thu ngn th cht bt c dng rc ln thu ngn ri gom li l A. mui n. B. ct. C. vi sng. D. lu hunh. H B 2008

422.

423.

424.

HA HC HU C 8. i cng ha hc hu c, hirocacbon: 2
51

S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 4. B. 3. C. 2. 425.

D. 5.

426.

427.

428.

429.

430.

431.

H A 2008 Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3, CH2=CH-CH2-CH=CH2. S cht c ng phn hnh hc l A. 3. B. 2. C. 1. D. 4. H A 2008 : Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2 + KOH + H2O. Tng h s (nguyn, ti gin) tt c cc cht trong phng trnh ho hc ca phn ng trn l A. 27. B. 24. C. 34. D. 31. H B 2011 Cho cc cht sau: CH2=CH-CH=CH2; CH3-CH2-CH=C(CH3)2; CH3-CH=CH-CH=CH2; CH3-CH=CH2; CH3-CH=CH-COOH. S cht c ng phn hnh hc l A. 4. B. 3. C. 2. D. 1. C 2009 Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankaien. B. ankin. C. anken. D. ankan. H B 2008 S ng phn cu to ca C5H10 phn ng c vi dung dch brom l A. 8. B. 7. C. 9. D. 5. H B 2011 Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca A. ankan. B. ankin. C. ankaien. D. anken. C 2008 Cho cc pht biu sau: (a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O th X l anken. (b) Trong thnh phn hp cht hu c nht thit phi c cacbon. (c) Lin kt ho hc ch yu trong hp cht hu c l lin kt cng ho tr. (d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau. (e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh. (g) Hp cht C9H14BrCl c vng benzen trong phn t. A. 2. S pht biu ng l B. 5. C. 4. D. 3.

432.

433.

H B 2011 Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau o khi phn ng vi H2 (d, xc tc Ni, t ), cho cng mt sn phm l: A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis-but-2-en v xiclobutan. C 2009 Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l B. 0,2 mol C2H4 v 0,1 mol C2H2. A. 0,1 mol C2H4 v 0,2 mol C2H2. C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4. H A 2009 Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l A. 7,3. B. 6,6. C. 3,39. D. 5,85. H B 2011 kh hon ton 200 ml dung dch KMnO4 0,2M to thnh cht rn mu nu en cn V lt kh C2H4 ( ktc). Gi tr ti thiu ca V l A. 2,240. B. 2,688. C. 4,480. D. 1,344. 52

434.

435.

436.

437.

C 2009 Cho buta-1,3 - ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l: A. 3 B. 1 C. 2 D. 4 H A 2011 Trong s cc cht: C3H8, C3H7Cl, C3H8O v C3H9N; cht c nhiu ng phn cu to nht l A. C3H8. B. C3H8O. C. C3H9N. D. C3H7Cl. H A 2010 un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni), thu c hn hp kh Y. Cho Y li t t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l A. 0,328. B. 0,620. C. 0,585. D. 0,205. H A 2010 Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6 v H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l A. 0,24 mol. B. 0,36 mol. C. 0,60 mol. D. 0,48 mol. H B 2011 Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l A. 3-etylpent-1-en. B. 2-etylpent-2-en. C. 3-etylpent-3-en. D. 3-etylpent-2-en. H A 2010 Cht no sau y c ng phn hnh hc? A. But-2-in. B. 1,2-icloetan. C. 2-clopropen. D. But-2-en. C 2010 Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l A. 20. B. 40. C. 30. D. 10. H A 2007 Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l A. 22,4 lt. B. 44,8 lt. C. 26,88 lt. D. 33,6 lt. H A 2011 t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-Metylbutan. B. etan.C. 2,2-imetylpropan. D. 2-Metylpropan. C 2008 t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh (ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l A. 56,0 lt. B. 78,4 lt. C. 70,0 lt. D. 84,0 lt. C 2007 t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l A. C2H6. B. C3H6. C. C3H8. D. C3H4. H A 2010 t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht bng nhau) thu c 0,09 mol CO2. Nu ly cng mt lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO3 trong NH3, th khi lng kt ta thu c ln hn 4 gam. Cng thc cu to ca C3H4 v C4H4 trong X ln lt l: A. CHC-CH3, CH2=CH-CCH. B. CHC-CH3, CH2=C=C=CH2. C. CH2=C=CH2, CH2=C=C=CH2. D. CH2=C=CH2, CH2=CH-CCH. H A 2011 Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca CO2 v H2O thu c l 53

438.

439.

440.

441.

442.

443.

444.

445.

446.

447.

448.

449.

450.

451.

452.

453.

454.

455.

456.

457.

458.

459.

460.

461.

D. 18,60 gam. H A 2008 t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C2H4. B. C3H8. C. C2H6. D. CH4. H B 2008 t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn phn trm v s mol ca X v Y trong hn hp M ln lt l A. 75% v 25%. B. 20% v 80%. C. 35% v 65%. D. 50% v 50%. C 2008 Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H 2 SO 4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l A. C3H8. B. C3H6. C. C4H8. D. C3H4. H A 2007 t chy hon ton 6,72 lt (ktc) hn hp gm hai hirocacbon X v Y (MY > MX), thuc 11,2 lt kh CO2 (ktc) v 10,8 gam H2O. Cng thc ca X l A. C2H6. B. CH4. C. C2H4. D. C2H2. C 2010 t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l A. 12,9. B. 25,8. C. 22,2. D. 11,1. C 2008 Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol cn cho phn ng chy) 139,9oC, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l B. C3H6O2. C. C4H8O2. D. CH2O2. A. C2H4 O2. H B 2007 Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l B. xiclopropan. C. stiren. D. etilen. A. xiclohexan. H A 2009 Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en (hoc buten-1).B. propen v but-2-en (hoc buten-2). C. eten v but-2-en (hoc buten-2). D. eten v but-1-en (hoc buten-1). H A 2007 o Cho 3,12 gam ankin X phn ng vi 0,1 mol H2 (xc tc Pd/PbCO3, t ), thu c hn hp Ych c hai hirocacbon. Cng thc phn t ca X l A. C2H2. B. C5H8. C. C3H4. D. C4H6. C 2010 Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l A. C3H6. B. C3H4. C. C2H4. D. C4H8. H A 2007 Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en. B. xiclopropan. C. but-2-en. D. propilen. H B 2009 un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi lng bnh dung dch brom tng l A. 1,20 gam. B. 1,04 gam. C. 1,64 gam. D. 1,32 gam. H A 2008 Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l 54

A. 20,40 gam.

B. 18,96 gam.

C. 16,80 gam.

A. 20%. 462.

B. 25%.

C. 50%.

D. 40%.

463.

464.

465.

466.

467.

468.

469.

C 2009 Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l B. CH2=CH2. A. CH2=C(CH3)2. C. CH2=CH-CH2-CH3. D. CH3-CH=CH-CH3. H B 2009 Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l A. 16,0. B. 3,2. C. 8,0. D. 32,0. C 2009 Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. C2H6 v C3H6. B. CH4 v C3H6. C. CH4 v C3H4. D. CH4 v C2H4. H B 2008 Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l B. C2H2 v C4H8. C. C3H4 v C4H8. D. C2H2 v C3H8. A. C2H2 v C4H6. H A 2007 Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d AgNO3 trong dung dch NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng A. 11,2. B. 13,44. C. 8,96. D. 5,60. C 2007 Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l A. C5H12. B. C3H8. C. C4H10. D. C6H14. H A 2008 Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l A. 20%. B. 50%. C. 25%. D. 40%. H B 2009 Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l A. 2. B. 4. C. 3. D. 5. H A 2008 Khi brom ha mt ankan ch thu c mt dn xut monobrom duy nht c t khi hi i vi hiro l 75,5. Tn ca ankan l A. 3,3-imetylhecxan. B. isopentan. C. 2,2-imetylpropan. D. 2,2,3-trimetylpentan. H B 2007 Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l A. 2,3-imetylbutan. B. butan. C. 3-metylpentan. D. 2-metylpropan. C 2007 Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l 55

470.

471.

472.

A. CH4 v C2H4. 473.

B. C2H6 v C2H4.

C. CH4 v C3H6.

D. CH4 v C4H8. H B 2010

Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut monoclo ti a sinh ra l A. 3. B. 4. C. 5. D. 2. H B 2008

474.

9. Dn xut halogen, ancol, phenol: 2 + 1

Cho cc cht c cng thc cu to nh sau: HOCH2-CH2OH (X); CH2-CH2-CH2OH (Y); HOCH2-CHOHCH2OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CHOH-CH2OH (T). Nhng cht tc dng c vi Cu(OH)2 to thnh dung dch mu xanh lam l A. X, Y, R, T. B. X, Z, T. C. Z, R, T. D. X, Y, Z, T. C 2007 Kh nng phn ng th nguyn t clo bng nhm -OH ca cc cht c xp theo chiu tng dn t tri sang phi l: A. phenyl clorua, propyl clorua, anlyl clorua.B. anlyl clorua, phenyl clorua, propyl clorua. C. phenyl clorua, anlyl clorua, propyl clorua. D. anlyl clorua, propyl clorua, phenyl clorua. C 2010 Cho cc hp cht sau: Cho cc hp cht sau: (a) HOCH2-CH2OH. (b)HOCH2CH2CH2OH. (c)HOCH2-CH(OH)-CH2OH. (d)CH3CH(OH)CH2OH (e) CH3-CH2OH. (f) CH3-O-CH2CH3. Cc cht u tc dng c vi Na, Cu(OH)2 l: A. (a), (b), (c). B. (c), (d), (f). C. (a), (c), (d). D. (c), (d), (e). H B 2009 Pht biu no sau y ng? A. Khi un C2H5Br vi dung dch KOH ch thu c etilen. B. Dung dch phenol lm phenolphtalein khng mu chuyn thnh mu hng. C. Dy cc cht: C2H5Cl, C2H5Br, C2H5I c nhit si tng dn t tri sang phi. o D. un ancol etylic 140 C (xc tc H2SO4 c) thu c imetyl ete. H B 2010 C bao nhiu ru (ancol) bc 2, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18%? A. 2. B. 5. C. 3. D. 4. C 2007 C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H2 (xc tc Ni, o t )? A. 3. B. 5. C. 2. D. 4. H B 2010 o Cho 10 ml dung dch ancol etylic 46 phn ng ht vi kim loi Na (d), thu c V lt khH2 (ktc). Bit khi lng ring ca ancol etylic nguyn cht bng 0,8 g/ml. Gi tr ca V l A. 0,896. B. 4,256. C. 3,360. D. 2,128. C 2010 Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 3. B. 6. C. 4. D. 5. H A 2009 Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. anilin. B. phenol. C. axit acrylic. D. metyl axetat. H A 2009 56

475.

476.

477.

478.

479.

480.

481.

482.

483.

484.

485.

486.

487.

488.

489.

Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc phn t ca X l A. 2. B. 3. C. 4. D. 1. H A 2008 Dy gm cc cht u tc dng vi ancol etylic l: o o A. HBr (t ), Na, CuO (t ), CH3COOH (xc tc). o B. Ca, CuO (t ), C6H5OH (phenol), HOCH2CH2OH. C. NaOH, K, MgO, HCOOH (xc tc). o D. Na2CO3, CuO (t ), CH3COOH (xc tc), (CH3CO)2O. C 2009 Trong thc t, phenol c dng sn xut A. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D. B. nha rezol, nha rezit v thuc tr su 666. C. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric. D. nha rezit, cht dit c 2,4-D v thuc n TNT. C 2009 Cho cc cht: (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4-metylbenzen; (5) 4-metylphenol; (6) -naphtol. Cc cht thuc loi phenol l: A. (1), (3), (5), (6). B. (1), (2), (4), (6). C. (1), (2), (4), (5). D. (1), (4), (5), (6). H B 2010 Trong s cc pht biu sau v phenol (C6H5OH): (1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl. (2) Phenol c tnh axit, dung dch phenol khng lm i mu qu tm. (3) Phenol dng sn xut keo dn, cht dit nm mc. (4) Phenol tham gia phn ng th brom v th nitro d hn benzen. Cc pht biu ng l: A. (1), (3), (4). B. (1), (2), (4). C. (1), (2), (3). D. (2), (3), (4). H A 2010 Dy gm cc cht u phn ng vi phenol l: A. nc brom, anehit axetic, dung dch NaOH. B. dung dch NaCl, dung dch NaOH, kim loi Na. C. nc brom, axit axetic, dung dch NaOH. D. nc brom, anhirit axetic, dung dch NaOH. H B 2007 nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH B. Na kim loi. C. . nc Br2. D. H2 (Ni, nung nng). H B 2008 Cho s
+ Cl 2 (1:1) + NaOH, du + HCl C 6 H 6 X Y Z o o Fe, t t cao,P cao

490.

Hai cht hu c Y, Z ln lt l: A. C6H6(OH)6, C6H6Cl6. C. C6H5OH, C6H5Cl. 491. Cho cc phn ng : HBr + C2H5OH
t
0

B. C6H4(OH)2, C6H4Cl2. D. C6H5ONa, C6H5OH. H A 2007 C2H4 + Br2 C2H6 + Br2

askt(1:1mol)

C2H4 + HBr S phn ng to ra C2H5Br l : A. 1 B.2 492. Cho s chuyn ho:

C. 3

D. H B 2008

H 2SO4 c + HBr + Mg, etekhan Butan - 2 - ol X(anken) Y Z to

Trong X, Y, Z l sn phm chnh. Cng thc ca Z l 57

A. (CH3)3C-MgBr. C. CH3-CH(MgBr)-CH2-CH3. 493. Cho s chuyn ho sau :

B. CH3-CH2-CH2 -CH2-MgBr. D. (CH3)2CH-CH2-MgBr. H B 2009

+ Br2 (1:1mol),Fe,t + NaOH (d ),t ,p + HCl(d ) Toluen X Y Z

0 0

494.

495.

496.

497.

498.

Trong X, Y, Z u l hn hp ca cc cht hu c, Z c thnh phn chnh gm : A. m-metylphenol v o-metylphenol B. benzyl bromua v o-bromtoluen C. o-bromtoluen v p-bromtoluen D. o-metylphenol v p-metylphenol H B 2008 t chy hon ton mt ancol a chc, mch h X, thu c H2O v CO2 vi t l s mol tng ng l 3:2. Cng thc phn t ca X l A. C2H6O2. B. C2H6O. C. C3H8O2. D. C4H10O2. C 2008 Khi thc hin phn ng tch nc i vi ancol X, ch thu c mt anken duy nht. Oxi ho hon ton mt lng cht X thu c 5,6 lt CO2 ( ktc) v 5,4 gam nc. C bao nhiu cng thc cu to ph hp vi X? A. 2. B. 4. C. 3. D. 5. C 2007 Cho 13,8 gam cht hu c X c cng thc phn t C7H8 tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn? A. 5. B. 4. C. 6. D. 2. H A 2011 t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l: A. C2H6O2, C3H8O2. B. C2H6O v CH4O. C.C3H6OvC4H8O. D.C2H6OvC3H8O. C 2008 t chy hon ton mt ru (ancol) X thu c CO2 v H2O c t l s mol tng ng l 3 : 4. Th tch kh oxi cn dng t chy X bng 1,5 ln th tch kh CO2 thu c ( cng iu kin). Cng thc phn t ca X l B. C3H8O3. C. C3H4O. D. C3H8O2. A. C3H8O. C 2007 Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi hi ca X so vi hiro bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi cc phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d dung dch AgNO3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l A. 65,2%. B. 16,3%. C. 48,9%. D. 83,7%. H B 2010 t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l A. 9,8 v propan-1,2-iol. B. 4,9 v propan-1,2-iol. C. 4,9 v propan-1,3-iol. D. 4,9 v glixerol. H A 2009 t chy hon ton mt lng hn hp X gm 2 ancol (u no, a chc, mch h, c cng s nhm -OH) cn va V lt kh O2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc th tch kh o ktc). Gi tr ca V l A. 14,56. B. 15,68. C. 11,20. D. 4,48. H B 2010 X l mt ancol (ru) no, mch h. t chy hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l A. C3H7OH. B. C3H6(OH)2. C. C3H5(OH)3. D. C2H4(OH)2. H B 2007

499.

500.

501.

502.

58

503.

Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l: A. m = 2a V/22,4 B m = 2a + V/11,2 C. m = a + V/5,6 D. m = a V/5,6 H A 2009 Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l A. C3H5(OH)3 v C4H7(OH)3. B. C2H5OH v C4H9OH. D. C2H4(OH)2 v C3H6(OH)2. C. C2H4(OH)2 v C4H8(OH)2. H A 2009 Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H 2 SO 4 lm xc tc) thu c hn hp Z gm hai ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu gn ca X v Y l (th tch dung dch thay i khng ng k) A. C4H9OH v C5H11OH. B. C2H5OH v C4H9OH. C. C3H7OH v C4H9OH. D. C2H5OH v C3H7OH. C 2007 Khi t 0,1 mol mt cht X (dn xut ca benzen), khi lng CO2 thu c nh hn 35,2 gam. Bit rng, 1 mol X ch tc dng c vi 1 mol NaOH. Cng thc cu to thu gn ca X l A. HOCH2C6H4COOH. B. C6H4 (OH)2. C. HO C6H4CH2OH. D. C2H5C6H4OH. H B 2007 S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l A. 3. B. 1. C. 4. D. 2. H B 2007 Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S l ng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l A. 2. B. 4. C. 1. D. 3. H B 2007 Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l A. HOC6H4CH2OH. B. CH3C6H3(OH)2. D.C6H5CH(OH)2. C. CH3OC6H4OH. C 2007 Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HO-C6H4-COOCH3. B. CH3-C6H3(OH)2. C. HO-CH2-C6H4-OH. D. HO-C6H4-COOH. H B 2009 Khi un nng hn hp ru (ancol) gm CH3OH v C2H5OH (xc tc H2SO4 c, 140oC) th s ete thu c ti a l A. 4. B. 2. C. 1. D. 3. C 2008 Khi tch nc t ru (ancol) 3-metylbutanol-2 (hay 3-metylbutan-2-ol), sn phm chnh thu c l A. 2-metylbuten-3 (hay 2-metylbut-3-en).B. 2-metylbuten-2 (hay 2-metylbut-2-en). C. 3-metylbuten-2 (hay 3-metylbut-2-en).D. 3-metylbuten-1 (hay 3-metylbut-1-en). H A 2008 Khi tch n c t m t ch t X c cng th c phn t C4H10O t o thnh ba anken l ng phn c a nhau (tnh c ng phn hnh h c). Cng th c c u t o thu g n c a X l A. (CH3)3COH. B. CH3OCH2CH2CH3. 59

504.

505.

506.

507.

508.

509.

510.

511.

512.

513.

C. CH3CH(OH)CH2CH3. 514.

D. CH3CH(CH3)CH2OH.

H A 2007 Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol mi ancol th lng nc sinh ra t ancol ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y l A. CH3-CH2-CH(OH)-CH3. B. CH3-CH2-CH2-CH2-OH. C. CH3-CH2-CH2-OH. D. CH3-CH(OH)-CH3. H A 2010 un nng h n h p g m hai r u (ancol) n ch c, m ch h , k ti p nhau trong dy ng ng vi H2SO4 c 140 o C. Sau khi cc ph n ng k t thc, thu c 6 gam h n h p g m ba ete v 1,8 gam n c. Cng th c phn t c a hai ancol trn l B. CH3OH v C2H5OH. A. C3H5OH v C4H7OH. C. C2H5OH v C3H7OH. D. C3H7OH v C4H9OH. H B 2008 t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy ng ng, thu c3,808 lt kh CO2 (ktc) v 5,4 gam H2O. Gi tr ca m l A. 5,42. B. 4,72. C. 7,42. D. 5,72. H A 2010 X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung dch o NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 140 C, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 4,05. B. 8,10. C. 18,00. D. 16,20. H A 2009 un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y l A. C4H8O. B. C3H8O. C. CH4O. D. C2H6O. H 2008 un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l A. C2H5OH v CH2=CH-CH2-OH. B. C2H5OH v CH3OH. C. CH3OH v C3H7OH. D. CH3OH v CH2=CH-CH2-OH. H A 2009 Oxi ho ancol n chc X bng CuO (un nng), sinh ra mt sn phm hu c duy nht l xeton Y (t khi hi ca Y so vi kh hiro bng 29). Cng thc cu to ca X l B. CH3-CH2-CHOH-CH3. A. CH3-CHOH-CH3. C. CH3-CO-CH3. D. CH3-CH2-CH2-OH. C 2008 Cho 4,6 gam mt ancol no, n chc phn ng vi CuO nung nng, thu c 6,2 gam hn hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi lng d dung dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l A. 21,6. B. 10,8. C. 43,2. D. 16,2. C 2010 Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hpsn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l A. 15,3. B. 13,5. C. 8,1. D. 8,5. H B 2009 Cho m gam mt ancol (ru) no, n chc X qua bnh ng CuO (d), nung nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l A. 0,64. B. 0,46. C. 0,32. D. 0,92. H B 2007 Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 60

515.

516.

517.

518.

519.

520.

521.

522.

523.

524.

525.

526.

527.

528.

l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 9,2. B. 7,8. C. 7,4. D. 8,8. H A 2008 Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO3 (d), thu c 0,56 lt kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l A. 1,15 gam. B. 4,60 gam. C. 2,30 gam. D. 5,75 gam. C 2009 Hiro ho cht hu c X thu c (CH3)2CHCH(OH)CH3. Cht X c tn thay th l A. metyl isopropyl xeton. B. 3-metylbutan-2-on. C. 2-metylbutan-3-on. D. 3-metylbutan-2-ol. H A 2010 Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l A. 65,5%. B. 80,0%. C. 76,6%. D. 70,4%. H B 2008 Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi ph ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l A. 0,60. B. 0,36. C. 0,54. D. 0,45. H B 2010

529.

10. Anehit, xeton, axit cacboxylic: 2 + 2

Cho cc cht: HCN, H2, dung dch KMnO4, dung dch Br2. S cht phn ng c vi (CH3)2CO l A. 2. B. 4. C. 1. D. 3. H A 2007 Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l: B. C2H5OH, C2H4, C2H2. A. CH3COOH, C2H2, C2H4. C. C2H5OH, C2H2, CH3COOC2H5. D. HCOOC2H3, C2H2, CH3COOH. H A 2009 Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l: A. CH3CHO, C2H5OH, C2H5COOCH3. B. CH3CHO, C6H12O6 (glucoz), CH3OH. C. CH3OH, C2H5OH, CH3CHO. D. C2H4(OH)2, CH3OH, CH3CHO. C 2009 Qu trnh no sau y khng to ra anehit axetic? o o B. CH2=CH2 + O2 (t , xc tc). A. CH2=CH2 + H2O (t , xc tc HgSO4). o o CH3COOCH=CH2 + dung dch NaOH (t ). D. CH3CH2OH + CuO (t ). C 2009 Trong cng nghip, axeton c iu ch t A. cumen. B. propan-1-ol.

530.

531.

532.

533.

C. xiclopropan.

D. propan-2-ol. C 2007

534.

S ng phn xeton ng vi cng thc phn t C5H10O l A. 3. B. 5. C. 6. D. 4. H A 2008 Anehit no mch h X c cng thc n gin nht C2H3O. Cng thc phn t ca X l A. C2H3O. B. C6H9O3. C. C4H6O2. D. C8H12O4. C 2010 Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 43,2 gam kt ta v dung dch cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca m l A. 10,2. B. 10,9. C. 9,5. D. 14,3. H A 2010 61

535.

536.

537.

: Cho phn ng: 2C6H5-CHO + KOH C6H5-COOK + C6H5-CH2OH Phn ng ny chng t C6H5-CHO A. va th hin tnh oxi ho, va th hin tnh kh. B. ch th hin tnh oxi ho. C. ch th hin tnh kh. D. khng th hin tnh kh v tnh oxi ho. H B 2010

538.

539.

540.

541.

542.

Axeton c iu ch bng cch oxi ho cumen nh oxi, sau thu phn trong dung dch H2SO4 long. thu c 145 gam axeton th lng cumen cn dng (gi s hiu sut qu trnh iu ch t 75%) l A. 400 gam. B. 600 gam. C. 500 gam. D. 300 gam. H A 2010 Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t ca X l A. C9H12O9. B. C12H16O12. C. C6H8O6. D. C3H4O3. H B 2008 Oxi ho 4,48 lt C2H4 ( ktc) bng O2 (xc tc PdCl2, CuCl2), thu c cht X n chc. Ton b lng cht X trn cho tc dng vi HCN (d) th c 7,1 gam CH3CH(CN)OH (xianohirin). Hiu sut qu trnh to CH3CH(CN)OH t C2H4 l A. 50%. B. 60%. C. 70%. D. 80%. H B 2007 Tng s cht hu c mch h, c cng cng thc phn t C2H4O2 l A. 2. B. 4. C. 1. D. 3. H A 2010 un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. khng no (cha mt ni i C=C), hai chc. B. no, hai chc. C. khng no (cha mt ni i C=C), n chc. D. no, n chc. H A 2008 Hn hp X gm hai axit cacboxylic no, mch h Y v Z (phn t khi ca Y nh hn ca Z). t chy hon ton a mol X, sau phn ng thu c a mol H2O. Mt khc, nu cho a mol X tc dng vi lng d dung dch NaHCO3, th thu c 1,6a mol CO2. Thnh phn % theo khi lng ca Y trong X l A. 46,67%. B. 40,00%. C. 25,41%. D. 74,59%. H B 2011 Cho hn hp X gm ancol metylic v hai axit cacboxylic (no, n chc, k tip nhau trong dy ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H2 (ktc). Nu un nng hn hp X (c H2SO4 c lm xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este (gi thit phn ng este ho t hiu sut 100%). Hai axit trong hn hp X l A. CH3COOH v C2H5COOH. B. HCOOH v CH3COOH. C. C3H7COOH v C4H9COOH. D. C2H5COOH v C3H7COOH. H A 2010 Hai hp cht hu c X, Y c cng cng thc phn t C3H6O2. C X v Y u tc dng vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v HCOOC2H5. B. HCOOC2H5 v HOCH2COCH3. C. HCOOC2H5 v HOCH2CH2CHO. D. C2H5COOH v CH3CH(OH)CHO. C 2009 Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HOCH2CHO v HOCH2CH2CHO. B. HOCH2CH2CHO v HOCH2CH2CH2CHO. C. HOCH(CH3)CHO v HOOCCH2CHO. 62

543.

544.

545.

546.

D. HCOOCH3 v HCOOCH2CH3. H B 2009 547. Cho cc hp cht hu c: (1) ankan; (2) ancol no, n chc, mch h; (3) xicloankan; (4) ete no, n chc, mch h (5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h; (7) ankin; (8) anehit no, n chc, mch h; (9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (1), (3), (5), (6), (8). B. (3), (4), (6), (7), (10). C. (3), (5), (6), (8), (9). D. (2), (3), (5), (7), (9). H B 2009 t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit A. khng no c mt ni i, n chc. B. no, n chc. C. khng no c hai ni i, n chc. D. no, hai chc. H B 2007 Chia hn hp gm hai ancol n chc X v Y (phn t khi ca X nh hn ca Y) l ng ng k tip thnh hai phn bng nhau: - t chy hon ton phn 1 thu c 5,6 lt CO2 (ktc) v 6,3 gam H2O. o - un nng phn 2 vi H2SO4 c 140 C to thnh 1,25 gam hn hp ba ete. Ho hi hon ton hn hp ba ete trn, thu c th tch hi bng th tch ca 0,42 gam N2 (trong cng iu kin nhit , p sut).Hiu sut phn ng to ete ca X, Y ln lt l A. 25% v 35%. B. 20% v 40%. C. 40% v 20%. D. 30% v 30%. H B 2011 Oxi ho ht 2,2 gam hn hp hai ancol n chc thnh anehit cn va 4,8 gam CuO. Cho ton b lng anehit trn tc dng vi lng d dung dch AgNO3 trong NH3, thu c 23,76 gam Ag. Hai ancol l: A. C2H5OH, C2H5CH2OH. B. C2H5OH, C3H7CH2OH. C. CH3OH, C2H5CH2OH. D. CH3OH, C2H5OH. H A 2010 t chy hon ton m gam hn hp X gm ba ancol (n chc, thuc cng dy ng ng), thu c 8,96 lt kh CO2 (ktc) v 11,7 gam H2O. Mt khc, nu un nng m gam X vi H2SO4 c th tng khi lng ete ti a thu c l A. 7,85 gam. B. 7,40 gam. C. 6,50 gam. D. 5,60 gam. H B 2010 ng vi cng thc phn t C3H6O c bao nhiu hp cht mch h bn khi tc dng vi khH2 (xc tc Ni, o t ) sinh ra ancol? A. 3. B. 4. C. 2. D. 1. C 2010 t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l A. HO-CH2-CH2-CH=CH-CHO. B. HOOC-CH=CH-COOH. C. HO-CH2-CH=CH-CHO. D. HO-CH2-CH2-CH2-CHO. H B 2009 Hn hp M gm axit cacboxylic X, ancol Y (u n chc, s mol X gp hai ln s mol Y) v este Z c to ra t X v Y. Cho mt lng M tc dng va vi dung dch cha 0,2 mol NaOH, to ra 16,4 gam mui v 8,05 gam ancol. Cng thc ca X v Y l A. HCOOH v CH3OH. B. CH3COOH v CH3OH. C. HCOOH v C3H7OH. D. CH3COOH v C2H5OH. H B 2010 t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O2 ( ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l A. 8,96. B. 6,72. C. 4,48. D. 11,2. H B 2007 63

548.

549.

550.

551.

552.

553.

554.

555.

556.

557.

558.

559.

560.

561.

562.

563.

564.

565.

566.

t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 ( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l A. O=CH-CH=O. B. CH2=CH-CH2-OH. C. CH3COCH3. D. C2H5CHO. H B 2009 Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau trong dy ng ng (MX < MY), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln lt l A. HCHO v 50,56%. B. CH3CHO v 67,16%. D. HCHO v 32,44%. C. CH3CHO v 49,44%. C 2009 Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 17,8. B. 24,8. C. 10,5. D. 8,8. H B 2009 Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l A. 46,15%. B. 35,00%. C. 53,85%. D. 65,00%. A 2009 Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l A. 3. B. 6. C. 4. D. 5. C 2008 t chy hon ton anehit X, thu c th tch kh CO2 bng th tch hi nc (trong cng iu kin nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dung dch AgNO3 trong NH3 th thu c 0,04 mol Ag. X l A. anehit fomic. B. anehit no, mch h, hai chc. C. anehit axetic. D. anehit khng no, mch h, hai chc. H A 2011 Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l A. 43,2 gam. B. 10,8 gam. C. 64,8 gam. D. 21,6 gam. C 2008 t chy hon ton mt anehit X, thu c s mol CO2 bng s mol H2O. Nu cho X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, sinh ra s mol Ag gp bn ln s mol X phn ng. Cng thc ca X l A. HCHO. B. CH3CHO. C. (CHO)2. D. C2H5CHO. C 2008 X, Y ,Z l cc hp cht mch h, bn c cng cng thc phn t C3H6O . X tc dng c vi Na v khng c phn ng trng bc. Y khng tc dng vi Na nhng c phn ng trng bc, Z khng tc dng c vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l: A. CH2=CH-CH2-OH, CH3-CH2-CHO, CH3-CO-CH3. B. CH2=CH-CH2-OH, CH3-CO-CH3, CH3-CH2-CHO. C. CH3-CH2-CHO, CH3-CO-CH3, CH2=CH-CH2-OH. D. CH3-CO-CH3, CH3-CH2-CHO, CH2=CH-CH2-OH. H A 2011 Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l A. HCHO. B. CH3CHO. C. OHC-CHO. D. CH3CH(OH)CHO. H A 2007 Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3, thu c o 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, t ) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l A. CnH2n(CHO)2 (n 0). B. CnH2n+1CHO (n 0). 64

C. CnH2n-1CHO (n 2). 567.

D. CnH2n-3CHO (n 2).

568.

H A 2009 Cho 2,9 gam mt anehit phn ng hon ton vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 21,6 gam Ag. Cng thc cu to thu gn ca anehit l B. OHC-CHO. C. HCHO. D. CH3CHO. A. CH2=CH-CHO. C 2007 : hiro ho hon ton 0,025 mol hn hp X gm hai anehit c khi lng 1,64 gam, cn 1,12 lt H2 (ktc). Mt khc, khi cho cng lng X trn phn ng vi mt lng d dung dch AgNO3 trong NH3 th thu c 8,64 gam Ag. Cng thc cu to ca hai anehit trong X l A. CH2=C(CH3)-CHO v OHC-CHO. B. OHC-CH2-CHO v OHC-CHO. C. H-CHO v OHC-CH2-CHO. D. CH2=CH-CHO v OHC-CH2-CHO. H B 2011 Cho hn hp M gm anehit X (no, n chc, mch h) v hirocacbon Y, c tng s mol l 0,2 (s mol ca X nh hn ca Y). t chy hon ton M, thu c 8,96 lt kh CO2 (ktc) v 7,2 gam H2O. Hirocacbon Y l A. CH4. B. C2H2. C. C3H6. D. C2H4. H B 2010 Hn hp X gm hai anehit n chc Y v Z (bit phn t khi ca Y nh hn ca Z). Cho 1,89 gam X tc dng vi mt lng d dung dch AgNO3 trong NH3, sau khi cc phn ng kt thc, thu c 18,36 gam Ag v dung dch E. Cho ton b E tc dng vi dung dch HCl (d), thu c 0,784 lt CO2 (ktc). Tn ca Z l A. anehit acrylic. B. anehit butiric. C. anehit propionic. D. anehit axetic. H B 2011 Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho phn ng ht vi axit HNO3 long, thot ra 2,24 lt kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l A. CH3CHO. B. HCHO.C. CH3CH2CHO.D. CH2 = CHCHO. H A 2007 Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. C4H9CHO. C. HCHO. D. C2H5CHO. H A 2008 Hn hp M gm mt anehit v mt ankin (c cng s nguyn t cacbon). t chy hon ton x mol hn hp M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca anehit trong hn hp M l A. 30%. B. 40%. C. 50%. D. 20%. H B 2011 X l hn hp gm H2 v hi ca hai anehit (no, n chc, mch h, phn t u c s nguyn t C nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y c t khi hi so vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V lt H2 (ktc). Gi tr ln nht ca V l A. 22,4. B. 13,44. C. 5,6. D. 11,2. H B 2011 Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X l A. HCHO v C2H5CHO. B. HCHO v CH3CHO. C. C2H3CHO v C3H5CHO. D. CH3CHO v C2H5CHO. C 2009 Khi oxi ha hon ton 2,2 gam mt anehit n chc thu c 3 gam axit tng ng. Cng thc ca anehit l B. CH3CHO. C. HCHO. D. C2H3CHO. A. C2H5CHO. H B 2007 Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. etylen glicol. B. axit aipic. C. ancol o-hiroxibenzylic. D. axit 3-hiroxipropanoic. 65

569.

570.

571.

572.

573.

574.

575.

576.

577.

H B 2009 578. Cho s phn ng:

axit cacboxylic Y1. (1) X + O2

xt, to

xt, t ancol Y2. xt, to 3) Y1 + Y2 Y3 (thun nghch)

(2) X + H2

Bit Y3 c cng thc phn t C6H10O2. Tn gi ca X l A. anehit acrylic. B. anehit propionic. 579.

580.

C. anehit metacrylic. D. anehit axetic. H B 2011 t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ha a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l A. HOOC-CH2-CH2-COOH. B. C2H5-COOH. D. HOOC-COOH. C. CH3-COOH. H A 2007 o Dy gm cc cht u tc dng vi H2 (xc tc Ni, t ), to ra sn phm c kh nng phn ng vi Na l: A. C2H3CH2OH, CH3COCH3, C2H3COOH. B. C2H3CHO, CH3COOC2H3, C6H5COOH. C. C2H3CH2OH, CH3CHO, CH3COOH. D. CH3OC2H5, CH3CHO, C2H3COOH. H B 2010

581.

582.

583.

584.

Axit cacboxylic X c cng thc n gin nht l C3H5O2. Khi cho 100 ml dung dch axit X nng 0,1M phn ng ht vi dung dch NaHCO3 (d), thu c V ml kh CO2 (ktc). Gi tr ca V l A. 112. B. 448. C. 336. D. 224. C 2010 Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3 mol hn hp X, thu c 11,2 lt kh CO2 ( ktc). Nu trung ha 0,3 mol X th cn dng 500 ml dung dch NaOH 1M. Hai axit l: B. HCOOH, HOOC-CH2-COOH. A. HCOOH, HOOC-COOH. C. HCOOH, C2H5COOH. D. HCOOH, CH3COOH. H A 2009 Hn hp gm 0,1 mol mt axit cacboxylic n chc v 0,1 mol mui ca axit vi kim loi kim c tng khi lng l 15,8 gam. Tn ca axit trn l A. axit etanoic. B. axit propanoic. C. axit butanoic. D. axit metanoic. H A 2010 Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l A. 4,90 gam. B. 6,84 gam. C. 8,64 gam. D. 6,80 gam. H A 2008 Hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn s mol ca X). Nu t chy hon ton M th thu c 33,6 lt kh CO2 (ktc) v 25,2 gam H2O. Mt khc, nu un nng M vi H2SO4 c thc hin phn ng este ho (hiu sut l 80%) th s gam este thu c l A. 22,80. B. 18,24. C. 27,36. D. 34,20. H A 2010 t chy hon ton 0,11 gam mt este X ( to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l: A. 2 B. 5 C. 6 D.4 H A 2011 trung ha 6,72 gam mt axit cacboxylic Y (no, n chc), cn dng 200 gam dung dch NaOH 2,24%. Cng thc ca Y l B. C3H7COOH. C. C2H5COOH. D. HCOOH. A. CH3COOH. H B 2007 Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l A. CH2=CH-COOH. B. HCC-COOH. C. CH3-CH2-COOH. D. CH3COOH. 66

585.

586.

587.

588.

C 2007 589. Hn hp Z gm hai axit cacboxylic n chc X v Y (MX > MY) c tng khi lng l 8,2 gam. Cho Z tc dng va vi dung dch NaOH, thu c dung dch cha 11,5 gam mui. Mt khc, nu cho Z tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 21,6 gam Ag. Cng thc v phn trm khi lng ca X trong Z l A. C3H5COOH v 54,88%. B. C2H3COOH v 43,90%. C. C2H5COOH v 56,10%. D. HCOOH v 45,12% H B 2010 Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l A. C2H5COOH. B. HCOOH. C. CH3COOH. D. C3H7COOH. H B 2008 : Ha hi 15,52 gam hn hp gm mt axit no n chc X v mt axit no a chc Y (s mol X ln hn s mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N2 (o cng trong iu kin nhit , p sut). Nu t chy ton b hn hp hai axit trn th thu c 10,752 lt CO2 (ktc) . Cng thc cu to ca X, Y ln lt l: A. CH3-CH2-COOH v HOOC-COOH B. CH3-COOH v HOOC-CH2-CH2-COOH C. H-COOH v HOOC-COOH D. CH3-COOH v HOOC-CH2-COOH H A 2011 Trung ha 3,88 gam hn hp X gm hai axit cacboxylic no, n chc, mch h bng dung dch NaOH, c cn ton b dung dch sau phn ng thu c 5,2 gam mui khan. Nu t chy hon ton 3,88 gam X th th tch oxi (ktc) cn dng l A. 4,48 lt. B. 3,36 lt. C. 2,24 lt. D. 1,12 lt. H A 2011 Cho 16,4 gam hn hp X gm 2 axit cacboxylic l ng ng k tip nhau phn ng hon ton vi 200 ml dung dch NaOH 1M v KOH 1M, thu c dung dch Y. C cn dung dch Y, thu c 31,1 gam hn hp cht rn khan. Cng thc ca 2 axit trong X l A. C3H4O2 v C4H6O2. B. C2H4O2 v C3H4O 2. C. C2H4O2 v C3H6O2. D. C3H6O2 v C4H8O 2. C 2010 Cho 0,04 mol mt hn hp X gm CH2=CH-COOH, CH3COOH v CH2=CH-CHO phn ng va vi dung dch cha 6,4 gam brom. Mt khc, trung ho 0,04 mol X cn dng va 40 ml dung dch NaOH 0,75 M. Khi lng ca CH2=CH-COOH trong X l A. 0,56 gam. B. 1,44 gam. C. 0,72 gam. D. 2,88 gam. H B 2009 Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO3 (d) th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l A. 0,3. B. 0,8. C. 0,2. D. 0,6. H A 2011 Trung ho 8,2 gam hn hp gm axit fomic v mt axit n chc X cn 100 ml dung dch NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi mt lng d dung dch AgNO3 trong NH3, un nng th thu c 21,6 gam Ag. Tn gi ca X l A. axit acrylic. B. axit propanoic. C. axit etanoic. D. axit metacrylic. C 2009 t chy hon ton x gam hn hp gm hai axit cacboxylic hai chc, mch h v u c mt lin kt i C=C trong phn t, thu c V lt kh CO2 (ktc) v y mol H2O. Biu thc lin h gia cc gi tr x, y v V l A. V =

590.

591.

592.

593.

594.

595.

596.

597.

28 ( x 30 y ) . 55

B. V =

28 ( x 62 y ) 95

C. V =

28 ( x + 30 y ) . 55

D.V =

28 ( x + 62 y ) . 95

598.

Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ho m gam X cn 40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2 (ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l A. 0,015. B. 0,010. C. 0,020. D. 0,005. H B 2010 67

599.

Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc).t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOC-CH2-COOH v 70,87%. B. HOOC-CH2-COOH v 54,88%. C. HOOC-COOH v 60,00%. D. HOOC-COOH v 42,86%. H B 2009 Cho 45 gam axit axetic phn ng vi 69 gam ancol etylic (xc tc H2SO4 c), un nng, thu c 41,25 gam etyl axetat. Hiu sut ca phn ng este ho l A. 31,25%. B. 62,50%. C. 40,00%. D. 50,00%. C 2010

600.

601.

11. Este, lipit: 1 + 1

Mnh khng ng l: A. CH3CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3. B. CH3CH2COOCH=CH2 tc dng vi dung dch NaOH thu c anehit v mui. C. CH3CH2COOCH=CH2 tc dng c vi dung dch Br2. D. CH3CH2COOCH=CH2 c th trng hp to polime. H A 2007

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S ng phn este ng vi cng thc phn t C4H8O2 l A. 6. B. 5. C. 2.

D. 4.

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H A 2008 C bao nhiu tripeptit (mch h) khc loi m khi thy phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin? A. 3. B. 4. C. 9. D. 6. H A 2010 S hp cht l ng phn cu to, c cng cng thc phn t C4H8O2, tc dng c vi dung dch NaOH nhng khng tc dng c vi Na l A. 3. B. 2. C. 4. D. 1. C 2009 Pht biu ng l: A.Phn ng thy phn este trong mi trng axit l phn ng thun nghch. B. Phn ng gia axit v ru khi c H2SO4 c l phn ng mt chiu. C.Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v (ancol). D. Khi thy phn cht bo lun thu c C2H4(OH)2. H A 2008 Pht biu no sau y sai? Nhit si ca este thp hn hn so vi ancol c cng phn t khi. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn. S nguyn t hiro trong phn t este n v a chc lun l mt s chn. Sn phm ca phn ng x phng ho cht bo l axit bo v glixerol. C 2009 Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na, Cu(OH)2, CH3OH, dung dch Br2, dung dch NaOH. Trong iu kin thch hp, s phn ng xy ra l A. 4. B. 2. C. 3. D. 5. H A 2008 Thy phn este Z trong mi trng axit thu c hai cht hu c X v Y (MX < MY). Bng mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l A. metyl propionat. B. metyl axetat. C. etyl axetat. D. vinyl axetat. H B 2010 Tng s hp cht hu c no, n chc, mch h, c cng cng thc phn t C5H10O2, phnng c vi dung dch NaOH nhng khng c phn ng trng bc l A. 4. B. 5. C. 8. D. 9. H B 2010 Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO 3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi 68

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t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l B. HOOC-CHO. A. O=CH-CH2-CH2OH. C. CH3COOCH3. D. HCOOC2H5. H B 2009 Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l B. HCOOC2H5 v CH3COOCH3. A. C2H5COOCH3 v HCOOCH(CH3)2. C. C2H3COOC2H5 v C2H5COOC2H3. D. HCOOCH2CH2CH3 v CH3COOC2H5. H B 2007 Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l A. C2H4O2 v C5H10O2. B. C2H4O2 v C3H6O2. C. C3H4O2 v C4H6O2. D. C3H6O2 v C4H8O2. H B 2009 Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. metyl fomiat. B. etyl axetat. C. metyl axetat. D. n-propyl axetat. H B 2008 Este X c cc c im sau: t chy hon ton X to thnh CO2 v H2O c s mol bng nhau;Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X). Pht biu khng ng l: A. Cht X thuc loi este no, n chc. B. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O. C. Cht Y tan v hn trong nc. D.un Z vi dung dch H2SO4 c 170oC thu c anken. H A 2008 Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca este l A. CH2=CH-COO-CH3. B. HCOO-C(CH3)=CH2. C. HCOO-CH=CH-CH3. D. CH3COO-CH=CH2. H A 2007 Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. ru metylic. B. etyl axetat. C. axit fomic. D. ru etylic. H B 2007 Hp cht hu c mch h X c cng thc phn t C6H10O4. Thu phn X to ra hai ancol n chc c s nguyn t cacbon trong phn t gp i nhau. Cng thc ca X l A. CH3OCO-CH2-COOC2H5. B. C2H5OCO-COOCH3. C. CH3OCO-COOC3H7. D. CH3OCO-CH2-CH2-COOC2H5. H B 2010 X phng ho mt hp cht c cng thc phn t C10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l: A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa. B. HCOONa, CHC-COONa v CH3-CH2-COONa. C. CH2=CH-COONa, HCOONa v CHC-COONa. D. CH3-COONa, HCOONa v CH3-CH=CH-COONa. H A 2009 Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X? A. 5. B. 4. C. 3. D. 2. 69

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621.

C 2007 Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3 thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. HCOOCH3. B. HCOOCH=CH2. C. CH3COOCH=CH-CH3. D. CH3COOCH=CH2. C 2007 Cht hu c X c cng thc phn t C5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l A. HCOOC(CH3)=CHCH3. B. CH3COOC(CH3)=CH2. C. HCOOCH2CH=CHCH3. D. HCOOCH=CHCH2CH3. H A 2009 Hai cht X v Y c cng cng thc phn t C2H4O2. Cht X phn ng c vi kim loi Na v tham gia phn ng trng bc. Cht Y phn ng c vi kim loi Na v ho tan c CaCO 3. Cng thc ca X, Y ln lt l: A. HCOOCH3, HOCH2CHO. B. HCOOCH3, CH3COOH. C. HOCH2CHO, CH3COOH. D. CH3COOH, HOCH2CHO. C 2010 Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l: A. CH3-COOH, CH3-COO-CH3. B. (CH3)2CH-OH, H-COO-CH3. C. H-COO-CH3, CH3-COOH. D. CH3-COOH, H-COO-CH3. C 2008 Pht biu no sau y ng? A. Trong phn ng este ho gia CH3COOH vi CH3OH, H2O to nn t OH trong nhm COOH ca axit v H trong nhm OH ca ancol. B. Phn ng gia axit axetic vi ancol benzylic ( iu kin thch hp), to thnh benzyl axetat c mi thm ca chui chn. C. phn bit benzen, toluen v stiren ( iu kin thng) bng phng php ho hc, ch cn dng thuc th l nc brom. D. Tt c cc este u tan tt trong nc, khng c, c dng lm cht to hng trong cng nghip thc phm, m phm. H B 2011 Cht hu c X c cng thc phn t C4H6O4 tc dng vi dung dch NaOH (un nng) theo phng trnh phn ng: C4H6O4 + 2NaOH 2Z + Y. oxi ho ht a mol Y th cn va 2a mol CuO (un nng), sau phn ng to thnh a mol cht T (bit Y, Z, T l cc hp cht hu c). Khi lng phn t ca T l A. 44 vC. B. 58 vC. C. 82 vC. D. 118 vC. C 2008 Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O2 (ktc), thu c 5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l A. (HCOO)2C2H4 v 6,6. B. HCOOC2H5 v 9,5. C. CH3COOCH3 v 6,7. D. HCOOCH3 v 6,7. C 2010 Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi dung dch cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng ht vi Na thu c 3,36 lt kh H2 ( ktc). Hai cht hu c l A. mt este v mt axit. B. hai axit. C. hai este. D. mt este v mt ancol. C 2009 Mt hn hp X gm hai cht hu c n chc. Cho X phn ng va vi 500 ml dung dch KOH 1M. Sau phn ng, thu c hn hp Y gm hai mui ca hai axit cacboxylic v mt ru (ancol). Cho ton b lng ru thu c trn tc dng vi Na (d), sinh ra 3,36 lt H2 ( ktc). Hn hp X 70

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gm A. mt axit v mt este. C. hai este. 629.

B. mt este v mt ru. D. mt axit v mt ru.

630.

C 2008 Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tho mn cc tnh cht trn l A. 5. B. 2. C. 4. D. 6. H B 2011 Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. CH3COOH v CH3COOC2H5. B. C2H5COOH v C2H5COOCH3. C. HCOOH v HCOOC2H5. D. HCOOH v HCOOC3H7. H B 2009 t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO2 bng 6/7 th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l A. 6,66. B. 7,20. C. 10,56. D. 8,88. H A 2010 X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l A. 400 ml. B. 300 ml. C. 150 ml. D. 200 ml. C 2008 X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam. H A 2007 Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 27,75. B. 24,25. C. 26,25. D. 29,75. H B 2009 X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l A. HCOOCH2CH2CH3. B. HCOOCH(CH3)2. C. C2H5COOCH3. D. CH3COOC2H5. H B 2007 Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l A. etyl axetat. B. metyl propionat. C. isopropyl axetat. D. etyl propionat. C 2007 Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l A. CH2=CH-CH2-COO-CH3. B. CH2=CH-COO-CH2-CH3. C. CH3 -COO-CH=CH-CH3. D. CH3-CH2-COO-CH=CH2. C 2008 Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l A. CH2=CHCH2COOCH3. B. CH3COOCH=CHCH3. C. C2H5COOCH=CH2. D. CH2=CHCOOC2H5. C 2009 71

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Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l A. CH3OOC(CH2)2COOC2H5. B. CH3OOCCH2COOC3H7. C. CH3COO(CH2)2OOCC2H5. D. CH3COO(CH2)2COOC2H5. H B 2008 X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l A. 18,24 gam. B. 16,68 gam. C. 18,38 gam. D. 17,80 gam. H B 2008 X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l B. C2H5COOCH3 v C2H5COOC2H5. A. CH3COOCH3 v CH3COOC2H5. C. CH3COOC2H5 v CH3COOC3H7. D. HCOOCH3 v HCOOC2H5. H A 2009 Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo. Hai loi axit bo l A. C15H31COOH v C17H35COOH. B. C17H33COOH v C15H31COOH. C. C17H31COOH v C17H33COOH. D. C17H33COOH v C17H35COOH. H A 2007 Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste c to ra ti a l A. 6. B. 5. C. 3. D. 4. H B 2007 un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l A. 6,0 gam. B. 4,4 gam. C. 8,8 gam. D. 5,2 gam. C 2008 t chy hon ton x mol axit cacboxylic E, thu c y mol CO2 v z mol H2O (vi z=yx). Cho x mol E tc dng vi NaHCO3 (d) thu c y mol CO2. Tn ca E l A. axit acrylic. B. axit oxalic. C. axit aipic. D. axit fomic. H A 2011 Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l A. 10,12. B. 6,48. C. 8,10. D. 16,20. H A 2007 t chy hon ton 2,76 gam hn hp X gm CxH yCOOH, CxHyCOOCH3, CH3OH thu c 2,688 lt CO2 (ktc) v 1,8 gam H2O. Mt khc, cho 2,76 gam X phn ng va vi 30 ml dung dch NaOH 1M, thu c 0,96 gam CH3OH. Cng thc ca CxHyCOOH l A. C2H5COOH. B. C3H5COOH. C. C2H3COOH. D. CH3COOH. C 2010 Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l A. HCOOH v C2H5COOH. B. HCOOH v CH3COOH. C. CH3COOH v C2H5COOH. D. C2H5COOH v C3H7COOH. H A 2010 un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l A. 55%. B. 50%. C. 62,5%. D. 75%. C 2007 t chy hon ton 3,42 gam hn hp gm axit acrylic, vinyl axetat, metyl acrylat v axit oleic, ri hp th ton b sn phm chy vo dung dch Ca(OH)2 (d). Sau phn ng thu c 18 gam kt ta v dung dch X. Khi lng X so vi khi lng dung dch Ca(OH)2 ban u thay i nh th no? A. Tng 2,70 gam. B. Gim 7,74 gam. C. Tng 7,92 gam. D. Gim 7,38 gam. H A 2011 Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit axetylsalixylic (o-CH3COO72

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C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l A. 0,72. B. 0,48. C. 0,96. D. 0,24. H A 2011 Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 14,5. B. 17,5. C. 15,5. D. 16,5. H A 2011 Hn hp X gm vinyl axetat, metyl axetat v etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam H2O. Phn trm s mol ca vinyl axetat trong X l A. 75%. B. 72,08%. C. 27,92%. D. 25%. H B 2011 Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit ) A. 0,342. B. 2,925. C. 2,412. D. 0,456. H A 2007 trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH 0,1M. Ch s axit ca mu cht bo trn l A. 5,5. B. 4,8. C. 6,0. D. 7,2. C 2007 Triolein khng tc dng vi cht (hoc dung dch) no sau y? A. H2O (xc tc H2SO4 long, un nng). B. Cu(OH)2 ( iu kin thng). C. Dung dch NaOH (un nng). D. H2 (xc tc Ni, un nng). H B 2011 Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l A. 31,45 gam. B. 31 gam. C. 32,36 gam. D. 30 gam. H B 2011 trung ho 15 gam mt loi cht bo c ch s axit bng 7, cn dng dung dch cha a gamNaOH. Gi tr ca a l A. 0,075. B. 0,280. C. 0,150. D. 0,200. C 2010 12. Amin, amino axit v protein: 3 + 1 Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. protit lun l cht hu c no. B. protit lun cha chc hiroxyl. C. protit c khi lng phn t ln hn. D. protit lun cha nit. H B 2007 Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 2. B. 3. C. 4. D. 1. H A 2011 Ancol v amin no sau y cng bc? A. (CH3)3COH v (CH3)3CNH2. B. (C6H5)2NH v C6H5CH2OH. C. (CH3)2CHOH v (CH3)2CHNH2. D. C6H5NHCH3 v C6H5CH(OH)CH3. H B 2011 Pht biu khng ng l: A.Trong dung dch, H2N-CH2-COOH cn tn ti dng ion lng cc H3N+-CH2-COO-. B. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl. C. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin). D.Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt. H A 2008 S ng phn amino axit c cng thc phn t C3H7O2N l A. 2. B. 4. C. 3. D. 1. H A 2011 C cc dung dch ring bit sau: C6H5NH3Cl (phenylamoni clorua), NH2 CH2 CH2 CH(NH2) COOH, ClNH3 CH2 COOH, HOOC 73

665.

CH2 CH2 CH(NH2) COOH, NH2 CH2 COONa S lng cc dung dch c pH < 7 l A. 2. B. 4. C. 5. D. 3. H A 2008 Dung dch no sau y lm qu tm i thnh mu xanh? A. Dung dch alanin B. Dung dch glyxin C. Dung dch lysin D. Dung dch valin H A 2011 Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 28,48 gam Ala, 32 gam AlaAla v 27,72 gam Ala-Ala-Ala. Gi tr ca m l A. 90,6. B. 111,74. C. 81,54. D. 66,44. H A 2011 un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi cc phn ng kt thc thu c sn phm l: H2N-CH2-COOH, H2N-CH(CH3)-COOH. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. H2N-CH2-COOH, H2N-CH2-CH2-COOH. H B 2008 t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l A. CH2=CH-NH-CH3. B. CH2=CH-CH2-NH2. C. CH3-CH2-CH2-NH2. D. CH3-CH2-NH-CH3. H A 2010 S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l A. 4. B. 2. C. 5. D. 3. C 2009 S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 3. B. 1. C. 2. D. 4. H B 2009 Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaOH. B. dung dch NaCl. C. Cu(OH)2 trong mi trng kim. D. dung dch HCl. H A 2009 Hn hp kh X gm O2 v O3 c t khi so vi H2 l 22. Hn hp kh Y gm metylamin v etylamin c t khi so vi H2 l 17,833. t hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2, H2O v N2, cc cht kh o cng iu kin nhit , p sut). T l V1 : V2 l A. 2 : 1. B. 1 : 2. C. 3 : 5. D. 5 : 3. H B 2011 Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l A. C2H5NH2 v C3H7NH2. B. CH3NH2 v (CH3)3N. C. C3H7NH2 v C4H9NH2. D. CH3NH2 v C2H 5NH2. C 2010 Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Phe-Gly-Ala-Val. B. Gly-Ala-Val-Val-Phe. C. Gly-Ala-Val-Phe-Gly. D. Val-Phe-Gly-Ala-Gly. H B 2010 Nu thu phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau? A. 1. B. 4. C. 2. D. 3. C 2010 74

666.

667.

668.

669.

670.

671.

672.

673.

674.

675.

676.

Thy phn hon ton 60 gam hn hp hai ipetit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho

1 hn hp X tc dng vi dung dch HCl 10

D. 7,82 gam. H A 2011

(d), c cn cn thn dung dch, th lng mui khan thu c l : A. 7,09 gam. B. 16,30 gam C. 8,15 gam 677.

Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l A. metyl aminoaxetat. C. axit -aminopropionic. B. axit -aminopropionic. D. amoni acrylat. C 2009

678.

Cht X c cng thc phn t C4H9O2N. Bit: X + NaOH Y + CH4O Y + HCl (d) Z + NaCl Cng thc cu to ca X v Z ln lt l A.H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH. C. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH. D. H2NCH2COOC2H5 v ClH3NCH2COOH. C 2009 Cho s phn ng: NH 3

679.

X Y Z
+ CH3I (1:1) + HONO + CuO to

Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l: B. C2H5OH, HCHO. A. C2H5OH, CH3CHO. C. CH3OH, HCHO. D. CH3OH, HCOOH. 680. H B 2007 Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l A. C3H7N. B. C2H7N. C. C3H9N. D. C4H9N. H A 2007 t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2, 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2COONa. Cng thc cu to thu gn ca X l B. H2N-CH2-COO-CH3. A. H2N-CH2-COO-C3H7. C. H2N-CH2-CH2-COOH. D. H2N-CH2-COO-C2H5. H A 2007 Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este caaminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T. H B 2007 Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. vinylamoni fomat v amoni acrylat. B. amoni acrylat v axit 2-aminopropionic. C. axit 2-aminopropionic v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic. H B 2010 Pht biu khng ng l: A. ipeptit glyxylalanin (mch h) c 2 lin kt peptit. B. Etylamin tc dng vi axit nitr nhit thng to ra etanol. C. Protein l nhng polipeptit cao phn t c phn t khi t vi chc nghn n vi triu. D. Metylamin tan trong nc cho dung dch c mi trng baz. H B 2011 Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 75

681.

682.

683.

684.

685.

17,64 gam mui. Amin c cng thc l A. H2NCH2CH2CH2CH2NH2. C. H2NCH2CH2NH2. 686.

B. CH3CH2CH2NH2. D. H2NCH2CH2CH2NH2. H B 2010

-aminoaxit X cha mt nhm -NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l B. H2NCH2CH2COOH. A. H2NCH2COOH. C. CH3CH2CH(NH2)COOH. D. CH3CH(NH2)COOH. H A 2007 Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l A. 8 v 1,0. B. 8 v 1,5. C. 7 v 1,0. D. 7 v 1,5. H A 2010 Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 4. B. 8. C. 5. D. 7. H A 2009 Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5. B. 4. C. 2. D. 3. C 2008 Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l A. 2. B. 4. C. 5. D. 3. H B 2011 Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C5H9O4N. B. C4H10O2N2. C. C5H11O2N. D. C4H8O4N2. H A 2009 t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l A. 0,1. B. 0,4. C. 0,3. D. 0,2. H B 2010 trung ha 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H7N. B. C3H7N. C. C3H5N. D. CH5N. C 2007 Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l A. C2H4 v C3H6. B. CH4 v C2H6. C. C3H6 v C4H8. D. C2H6 v C3H8. H A 2010 Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC3H6COOH. B. H2NCH2COOH. C. H2NC2H4COOH. D. H2NC4H8COOH. C 2008 Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. 76

687.

688.

689.

690.

691.

692.

693.

694.

695.

696.

C. (H2N)2C3H5COOH. D. H2NC3H6COOH. 697. H B 2009 Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l A. 112,2. B. 165,6. C. 123,8. D. 171,0. H B 2010 Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l A. 3,56. B. 5,34. C. 2,67. D. 4,45. H B 2011 Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l A. CH2=CHCOONH4. B. H2NC2H4COOH. D. H2NCH2COO-CH3. C. H2NCOO-CH2CH3. C 2007 Cho 8,9 gam mt hp cht hu c X c cng thc phn t C3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. CH2=CHCOONH4. B. H2NCH2CH2COOH. C. HCOOH3NCH=CH2. D. H2NCH2COOCH3. H B 2008 Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 175 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,50. B. 0,65. C. 0,55. D. 0,70. H A 2010 Cho 1,82 gam hp cht hu c n chc, mch h X c cng thc phn t C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. Cng thc cu to thu gn ca X l A. HCOONH3CH2CH3. B. CH3COONH3CH3. C. CH3CH2COONH4. D. HCOONH2(CH3)2. thi TSC 2009 ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 120. B. 60. C. 30. D. 45. H B 2010 Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l A. 16,5 gam. B. 14,3 gam. C. 8,9 gam. D. 15,7 gam. H A 2007 Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 10,8. B. 9,4. C. 8,2. D. 9,6. 77

698.

699.

700.

701.

702.

703.

704.

705.

706.

707.

708.

H A 2009 Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 46. B. 85. C. 68. D. 45. H B 2008 Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l B. CH3OH v CH3NH2. A. CH3OH v NH3. C. CH3NH2 v NH3. D. C2H5OH v N2. H B 2009 Ngi ta iu ch anilin bng s sau:
+ HNO3 c Fe + HCl Benzen Nitrobenzen Anilin H 2SO4 c to

709.

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 186,0 gam. B. 55,8 gam. C. 93,0 gam. D. 111,6 gam. H B 2009 Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l 0,1 mol v 0,4 mol. B. 0,1 mol v 0,3 mol. C. 0,1 mol v 0,1 mol. D. 0,1 mol v 0,2 mol H B 2008

710.

13. Cacbohirat: 1 + 1
chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch glucoz phn ng vi A. kim loi Na. B. AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. C. Cu(OH)2 trong NaOH, un nng. D. Cu(OH)2 nhit thng. H A 2007 Cacbohirat nht thit phi cha nhm chc ca A. ancol. B. xeton. C. amin. D. anehit. H A 2009 Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong dung dch axit un nng (6). Cc tnh cht ca xenluloz l: A. (2), (3), (4) v (5). B. (3), (4), (5) v (6). C. (1), (2), (3) v (4). D. (1), (3), (4) v (6). H B 2009 Pht biu khng ng l A. Dung dch mantoz tc dng vi Cu(OH)2 khi un nng cho kt ta Cu2O. B.Sn phm thy phn xenluloz (xc tc H+, to) c th tham gia phn ng trng gng. C. Thy phn (xc tc H+, to) saccaroz cng nh mantoz u cho cng mt monosaccarit. D. Dung dch fructoz ho tan c Cu(OH)2. H B 2007 Pht biu no sau y khng ng? A. Glucoz tc dng c vi nc brom. B Khi glucoz dng vng th tt c cc nhm OH u to ete vi CH3OH. C. Glucoz tn ti dng mch h v dng mch vng. D. dng mch h, glucoz c 5 nhm OH k nhau. H B 2009 Cht X c cc c im sau: phn t c nhiu nhm -OH, c v ngt, ho tan Cu(OH)2 nhit thng, phn t c lin kt glicozit, lm mt mu nc brom. Cht X l A. xenluloz. B. mantoz. C. glucoz .D. saccaroz H B 2010 78

711.

712.

713.

714.

715.

716.

Pht biu no sau y l ng? A.Saccaroz lm mt mu nc brom. B. Xenluloz c cu trc mch phn nhnh. C. Amilopectin c cu trc mch phn nhnh. D.Glucoz b kh bi dung dch AgNO3 trong NH3. H B 2009 Cho cc pht biu sau: (a) C th dng nc brom phn bit glucoz v fructoz. (b) Trong mi trng axit, glucoz v fructoz c th chuyn ho ln nhau. (c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO3 trong NH3. (d) Trong dung dch, glucoz v fructoz u ho tan Cu(OH)2 nhit thng cho dung dch mu xanh lam. (e) Trong dung dch, fructoz tn ti ch yu dng mch h (g) Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh (dng v ). S pht biu ng l A. 4. B. 5. C. 3. D. 2 H B 2011 Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng A. thy phn. B. trng gng. C. trng ngng.D. ho tan Cu(OH)2. H A 2008 Mt phn t saccaroz c A. mt gc -glucoz v mt gc -fructoz. B. hai gc -glucoz. C. mt gc -glucoz v mt gc -fructoz. D. mt gc -glucoz v mt gc -fructoz H A 2010

717.

718.

719.

720.

Gluxit (cacbohirat) ch cha hai gc glucoz trong phn t l A. tinh bt. B. mantoz. C. xenluloz. Pht biu ng l: A. Enzim amilaza xc tc cho phn ng thy phn xenluloz thnh mantoz. B. Khi cho dung dch lng trng trng vo Cu(OH)2 thy xut hin phc mu xanh m. C. Axit nucleic l polieste ca axit photphoric v glucoz. D. Khi thy phn n cng cc protein n gin s cho hn hp cc -aminoaxit

D. saccaroz. H A 2008

721.

722.

H A 2010 Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, mantoz. S cht trong dy tham gia phn ng trng gng l A. 3. B. 4. C. 2. D. 5. C 2008 Thu phn hon ton tinh bt trong dung dch axit v c long, thu c cht hu c X. ChoX phn ng vi o kh H2 (xc tc Ni, t ), thu c cht hu c Y. Cc cht X, Y ln lt l: A. glucoz, fructoz. B. glucoz, etanol. C. glucoz, saccaroz. D. glucoz, sobitol. C 2010 Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO3 trong dung dch NH3 thu c 2,16 gam Ag kt ta. Nng mol/l ca dung dch glucoz dng l A. 0,01M. B. 0,02M. C. 0,20M. D. 0,10M. C 2007 Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l A. 1,44 gam. B. 2,25 gam. C. 1,80 gam. D. 1,82 gam. H A 2008 Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l A. CH3CH2OH v CH2=CH2. B. CH3CHO v CH3CH2OH. C. CH3CH(OH)COOH v CH3CHO. D. CH3CH2OH v CH3CHO. 79

723.

724.

725.

726.

727.

728.

729.

730.

731.

732.

733.

734.

735.

736.

737.

738.

C 2007 Thu phn hon ton 3,42 gam saccaroz trong mi trng axit, thu c dung dch X. Cho ton b dung dch X phn ng ht vi lng d dung dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l A. 2,16. B. 43,20. C. 21,60. D. 4,32. C 2010 Thu phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l A. 0,090 mol. B. 0,12 mol. C. 0,095 mol. D. 0,06 mol. H B 2011 T 180 gam glucoz, bng phng php ln men ru, thu c a gam ancol etylic (hiu sut 80%). Oxi ho 0,1a gam ancol etylic bng phng php ln men gim, thu c hn hp X. trung ho hn hp X cn 720 ml dung dch NaOH 0,2M. Hiu sut qu trnh ln men gim l A. 80%. B. 90%. C. 10%. D. 20%. H A 2010 Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 5,0 kg.B. 5,4 kg. C. 6,0 kg. D. 4,5 kg. H B 2008 Ln men hon ton m gam glucoz thnh ancol etylic. Ton b kh CO2 sinh ra trong qu trnh ny c hp th ht vo dung dch Ca(OH)2 (d) to ra 40 gam kt ta. Nu hiu sut ca qu trnh ln men l 75% th gi tr ca m l A. 60. B. 58. C. 30. D. 48. C 2009 Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 90%, Hp th ton b lng CO2, sinh ra khi ln men m gam tinh bt vo nc vi trong , thu c 330 gam kt ta v dung dch X. Bit khi lng X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m l: A. 405 B. 324 C. 486 D.297 H A 2011 Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81%. Ton b lng CO2 sinh ra c hp th hon ton vo dung dch Ca(OH)2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 100 gam kt ta. Gi tr ca m l A. 550. B. 810. C. 650. D. 750. H A 2007 Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l B. 30,0. C. 13,5. D. 15,0. A. 20,0. H A 2009 T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit hiu sut phn ng tnh theo xenluloz l 90%). Gi tr ca m l A. 26,73. B. 33,00. C. 25,46. D. 29,70. C 2008 Th tch ca dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut c 59,4 kg xenluloz trinitrat (hiu sut 80%) l A. 42,34 lt. B. 42,86 lt. C. 34,29 lt. D. 53,57 lt. C 2009 Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l A. 30 kg. B. 42 kg. C. 21 kg. D. 10 kg. H B 2007 Xenluloz trinitrat c iu ch t phn ng gia axit nictric vi xenluloz (hiu sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l A. 2,97 tn. B. 3,67 tn. C. 2,20 tn. D. 1,10 tn. H A 2011 80

739.

Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %) A. 81 lt. B. 55 lt. C. 49 lt. D. 70 lt. H B 2008

740.

14. Polime v vt liu polime: 1

Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. stiren; clobenzen; isopren; but-1-en. B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. C. buta-1,3-ien; cumen; etilen; trans-but-2-en. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. H B 2009

741.

Pht biu no sau y l ng? A.T visco l t tng hp. B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N. C. Trng hp stiren thu c poli(phenol-fomanehit). D. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng. H B 2009 Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao nhiu t thuc loi t poliamit? A. 1. B. 2. C. 3. D. 4. H B 2011 Nilon6,6 l mt loi A. t axetat.

742.

743.

B. t poliamit.

C. polieste.

D. t visco. H A 2007

744.

Polime no sau y c tng hp bng phn ng trng ngng? A. poliacrilonitrin. B. poli(metyl metacrylat). C. polistiren. D. poli(etylen terephtalat). C 2010 Dy gm cc cht c dng tng hp cao su Buna-S l: A. CH2=CH-CH=CH2, C6H5CH=CH2.B. CH2=C(CH3)-CH=CH2, C6H5CH=CH2. C. CH2=CH-CH=CH2, lu hunh. D. CH2=CH-CH=CH2, CH3-CH=CH2. H B 2007 Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp B. CH2=CH-COO-CH3. A. CH2=CH-COO-C2H5. C. C2H5COO-CH=CH2. D. CH3COO-CH=CH2. C 2007 Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp A. CH2=C(CH3)COOCH3. B. C6H5CH=CH2. C. CH3COOCH=CH2. D. CH2 =CHCOOCH3. C 2007 Trong s cc loi t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t enang, nhng loi t no thuc loi t nhn to? A. T visco v t axetat. B. T tm v t enang. C. T nilon-6,6 v t capron. D. T visco v t nilon-6,6. C 2007 Polime c cu trc mng khng gian (mng li) l A. nha bakelit. B. PVC. C. PE. D. amilopectin. H B 2008 Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l CH2=CH-COOCH3 v H2N-[CH2]6-COOH. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH. H A 2009 T nilon - 6,6 c iu ch bng phn ng trng ngng A. HOOC-(CH2)2-CH(NH2)-COOH. B. HOOC-(CH2)4-COOH v HO-(CH2)2-OH. 81

745.

746.

747.

748.

749.

750.

751.

C. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2. D. H2N-(CH2)5-COOH. 752. C 2008 Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t X l A. 453. B. 382. C. 328. D. 479. C 2009 Clo ho PVC thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l A. 3. B. 6. C. 4. D. 5. H A 2007 Cho cc loi t: bng, t capron, t xenluloz axetat, t tm, t nitron, nilon-6,6. S t tng hp l A. 3. B. 2. C. 4. D. 5. H A 2010 Cc cht u khng b thu phn trong dung dch H2SO4 long nng l: A. t capron; nilon-6,6; polietilen. B. poli(vinyl axetat); polietilen; cao su buna. C. nilon-6,6; poli(etylen-terephtalat); polistiren. D. polietilen; cao su buna; polistiren. H B 2010 Trong cc polime sau: (1) poli(metyl metacrylat); (2) polistiren; (3) nilon-7; (4) poli(etylen- terephtalat); (5) nilon-6,6; (6) poli(vinyl axetat), cc polime l sn phm ca phn ng trng ngng l: A. (1), (3), (5). B. (1), (3), (6). C. (1), (2), (3). D. (3), (4), (5). H A 2010 Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l A. 121 v 114. B. 121 v 152. C. 113 v 152. D. 113 v 114. H A 2008 Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) A. 224,0. B. 286,7. C. 358,4. D. 448,0. H A 2008

753.

754.

755.

756.

757.

758.

759.

15. Tng hp ni dung cc kin thc ha hu c thuc chng trnh ph thng: 6

Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l: A. anehit axetic, butin-1, etilen. B. anehit axetic, axetilen, butin-2. C. axit fomic, vinylaxetilen, propin. D. anehit fomic, axetilen, etilen.

760.

761.

762.

763.

H A 2007 Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht c kh nng lm mt mu nc brom l A. 5. B. 4. C. 6. D. 3. H B 2010 Dy gm cc dung dch u tham gia phn ng trng bc l: A. Glucoz, mantoz, axit fomic, anehit axetic. B. Fructoz, mantoz, glixerol, anehit axetic. C. Glucoz, glixerol, mantoz, axit fomic. D. Glucoz, fructoz, mantoz, saccaroz. H A 2009 Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l A. 2. B. 3. C. 5. D. 4. H B 2007 Cho s phn ng: (1) CH3CHO X1
+ HCN

+ HCN X2 . +H+, to
+ CO + HCl

2 Y (2) C2H5Br Y1 Y3. 2 + ete

+ Mg

82

Cc cht hu c X1, X2, Y1, Y2, Y3 l cc sn phm chnh. Hai cht X2, Y3 ln lt l A. axit 2-hiroxipropanoic v axit propanoic. C. axit axetic v axit propanoic. B. axit 3-hiroxipropanoic v ancol propylic. D. axit axetic v ancol propylic. H B 2011

764.

765.

766.

767.

768.

769.

770.

771.

772.

773.

774.

775.

Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi NaOH (trong dung dch) l A. 3. B. 2. C. 1. D. 4. C 2008 Ho tan cht X vo nc thu c dung dch trong sut, ri thm tip dung dch cht Y th thu c cht Z (lm vn c dung dch). Cc cht X, Y, Z ln lt l: A. phenol, natri hiroxit, natri phenolat. B. phenylamoni clorua, axit clohiric, anilin. C. anilin, axit clohiric, phenylamoni clorua. D. natri phenolat, axit clohiric, phenol. H B 2011 Khi ni v peptit v protein, pht biu no sau y l sai? A. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit. B. Tt c cc protein u tan trong nc to thnh dung dch keo. C. Protein c phn ng mu biure vi Cu(OH)2. D. Thy phn hon ton protein n gin thu c cc -amino axit. H A 2011 Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A. 4. B. 2. C. 3. D. 5. C 2008 Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l A. 4. B. 5. C. 3. D. 6. H B 2008 Pht biu no sau y v anehit v xeton l sai? A. Hiro xianua cng vo nhm cacbonyl to thnh sn phm khng bn. B. Axeton khng phn ng c vi nc brom. C. Axetanehit phn ng c vi nc brom. D. Anehit fomic tc dng vi H2O to thnh sn phm khng bn. H A 2011 Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 5. B. 6. C. 8. D. 7. H B 2008 Cho cc cht: ru (ancol) etylic, glixerin (glixerol), glucoz, imetyl ete v axit fomic. S cht tc dng c vi Cu(OH)2 l A. 2. B. 1. C. 4. D. 3. H B 2008 Cht phn ng vi dung dch FeCl3 cho kt ta l A. CH3COOH. B. CH3OH. C. CH3NH2.D. CH3COOCH3. H B 2008 S hp cht n chc, ng phn cu to ca nhau c cng cng thc phn t C4H8O2, u tc dng c vi dung dch NaOH l A. 4. B. 3. C. 5. D. 6. C 2007 Sn phm hu c ca phn ng no sau y khng dng ch to t tng hp? A. Trng hp vinyl xianua. B. Trng ngng axit -aminocaproic. C. Trng hp metyl metacrylat. D. Trng ngng hexametyleniamin vi axit aipic. H A 2011 Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). 83

Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3 to ra kt ta l A. 3. 776. B. 4. C. 5. D. 2. H A 2009 Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 3. B. 1. C. 4. D. 2. C 2007 Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 6. B. 4. C. 5. D. 3. H B 2007 Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 4. B. 3. C. 6. D. 5. H A 2011 Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht. Trong X, t l khi lng cc nguyn t l mC : mH : mO = 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hir bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn? A. 9. B. 3. C. 7. D. 10 H A 2011 Cho tng cht H2NCH2COOH, CH3COOH, CH3COOCH3 ln lt tc dng vi dung dch o o NaOH (t ) v vi dung dch HCl (t ). S phn ng xy ra l A. 3. B. 6. C. 4. D. 5. C 2009 Cho cc pht biu sau v cacbohirat: (a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit. (c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam. (d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag. (g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol. S pht biu ng l A. 5. B. 6. C. 4. D. 3. H B 2011 Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3), CH2=CH-CH2-OH (4). Nhng cht phn ng hon ton vi lng d H2 (Ni, to) cng to ra mt sn phm l: A. (2), (3), (4). B. (1), (2), (4). C. (1), (2), (3). D. (1), (3), (4). C 2008 Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc cht c sp xp theo tnh axit tng dn (t tri sang phi) l: A. (T), (Y), (X), (Z). B. (X), (Z), (T), (Y). C. (Y), (T), (Z), (X). D. (Y), (T), (X), (Z). C 2009 Cho cc cht: axit propionic (X), axit axetic (Y), ancol (ru) etylic (Z) v imetyl ete (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l A. T, X, Y, Z. B. T, Z, Y, X. C. Z, T, Y, X. D. Y, T, X, Z. H B 2007 Cc dung dch phn ng c vi Cu(OH)2 nhit thng l: A. glixerol, axit axetic, glucoz. B. lng trng trng, fructoz, axeton. C. anehit axetic, saccaroz, axit axetic. D. fructoz, axit acrylic, ancol etylic. H B 2010 Cho s phn ng: CHCH
+HCN trng hp

777.

778.

779.

780.

781.

782.

783.

784.

785.

786.

X; X

polime Y; X + CH2=CH-CH=CH2 84

ng trng hp

polime Z

Y v Z ln lt dng ch to vt liu polime no sau y? A.T capron v cao su buna. B. T nilon-6,6 v cao su cloropren. C. T olon v cao su buna-N. D. T nitron v cao su buna-S. H A 2011 787. Dy gm cc cht c xp theo chiu nhit si tng dn t tri sang phi l: A. CH3CHO, C2H5OH, C2H6, CH3COOH. B. CH3COOH, C2H6, CH3CHO, C2H5OH. C. C2H6, C2H5OH, CH3CHO, CH3COOH. D. C2H6, CH3CHO, C2H5OH, CH3COOH. H A 2008 788. : Cho dy chuyn ha sau Benzen
+C2H4

xt.t

+Br2, as

KOH/C2H5OH t0

Z (trong X, Y, Z l sn phm chnh)

t l mol 1:1

Tn gi ca Y, Z ln lt l A. benzylbromua v toluen B. 1-brom-1-phenyletan v stiren C. 2-brom-1pheny1benzen v stiren D. 1-brom-2-phenyletan v stiren. H A 2011 789. Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l: A. CH3COOH, C2H5OH, HCOOH, CH3CHO. B. CH3CHO, C2H5OH, HCOOH, CH3COOH. C. CH3COOH, HCOOH, C2H5OH, CH3CHO. D. HCOOH, CH3COOH, C2H5OH, CH3CHO. H B 2009 790. Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac.B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit.D. metyl amin, amoniac, natri axetat. H B 2007 791. Cho cc pht biu sau: (a) Anehit va c tnh oxi ho va c tnh kh. (b) Phenol tham gia phn ng th brom kh hn benzen. (c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt. (d) Dung dch axit axetic tc dng c vi Cu(OH)2. (e) Dung dch phenol trong nc lm qu tm ho . (g) Trong cng nghip, axeton c sn xut t cumen. S pht biu ng l A. 4. B. 2. C. 5.

D. 3.

792.

793.

794.

795.

H B 2011 C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. dung dch NaOH. C. nc brom. D. giy qu tm. H B 2007 Ch dng Cu(OH)2 c th phn bit c tt c cc dung dch ring bit sau: A. saccaroz, glixerin (glixerol), anehit axetic, ru (ancol) etylic. B. glucoz, lng trng trng, glixerin (glixerol), ru (ancol) etylic. C. lng trng trng, glucoz, fructoz, glixerin (glixerol). D. glucoz, mantoz, glixerin (glixerol), anehit axetic. C 2007 C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? A. 5. B. 6. C. 3. D. 4. H A 2009 Pht biu ng l: A. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp. B. Tnh baz ca anilin mnh hn ca amoniac. 85

C. Cao su thin nhin l sn phm trng hp ca isopren. D. Tnh axit ca phenol yu hn ca ru (ancol). H A 2008 796. Pht biu khng ng l: A. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c phenol. C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin. D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu c natri phenolat. H A 2007 Trong qu gc chn rt giu hm lng A. vitamin A. B. ete ca vitamin A. B. este ca vitamin A. H B 2011 ng vi cng thc phn t C2H7O2N c bao nhiu cht va phn ng c vi dung dchNaOH, va phn ng c vi dung dch HCl? A. 3. B. 1. C. 4. D. 2. C 2010 Cp cht no sau y khng phi l ng phn ca nhau? A. Saccaroz v xenluloz. B. Glucoz v fructoz. C. Ancol etylic v imetyl ete. D. 2-metylpropan-1-ol v butan-2-ol. C 2010 Thu phn cht hu c X trong dung dch NaOH (d), un nng, thu c sn phm gm 2 mui v ancol etylic. Cht X l A. CH3COOCH2CH3. B. CH3COOCH2CH2Cl. C. CH3COOCH(Cl)CH3. D. ClCH2COOC2H5. C 2010 Pht biu no sau y l ng? A. Cc ancol a chc u phn ng vi Cu(OH)2 to dung dch mu xanh lam. B. Etylamin phn ng vi axit nitr nhit thng, sinh ra bt kh. C. Benzen lm mt mu nc brom nhit thng. B. Anilin tc dng vi axit nitr khi un nng, thu c mui iazoni. H A 2009 Cho s chuyn ho sau: C3H4O2 + NaOH X + Y X + H2SO4 long Z + T Bit Y v Z u c phn ng trng gng. Hai cht Y, Z tng ng l: A. CH3CHO, HCOOH. B. HCOONa, CH3CHO. C. HCHO, CH3CHO. D. HCHO, HCOOH. H A 2008 Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng): Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l: A. C2H5OH, CH3COOH. B. CH3COOH, CH3OH. C. CH3COOH, C2H5OH. D. C2H4, CH3COOH. C 2008 Cho s chuyn ho sau:
+X + NaOH dPhenol phenyl axetat Y (h p cht thm) to

797.

C. -caroten.

798.

799.

800.

801.

802.

803.

804.

Hai cht X, Y trong s trn ln lt l: A. axit axetic, phenol. C. anhirit axetic, natri phenolat.
805.

B. anhirit axetic, phenol. D. axit axetic, natri phenolat. H A 2009

Cho cc chuyn ho sau:

86

xt, t Y X + H 2 O
o

Ni Sobitol Y + H 2 to

Amoni gluconat + 2Ag + NH 4 NO3 Y + 2AgNO3 + 3NH 3 + H 2 O

xt Y E + G
di p lc Z + H 2 O X + G nh sng

X, Y v Z ln lt l: A. xenluloz, fructoz v kh cacbonic. C. xenluloz, glucoz v kh cacbon oxit. 806. Cho s phn ng:
+CH3I (1:1) +HNNO

B. tinh bt, glucoz v ancol etylic. D. tinh bt, glucoz v kh cacbonic. C 2009
+CuO to

NH3 X Y Z

Bit Z c kh nng tham gia phn ng trng gng. Hai cht Y v Z ln lt l: A. C2H5OH, CH3CHO. B. C2H5OH, HCHO. C. CH3OH, HCHO. D. CH3OH, HCOOH. H B 2007 807. Cho s chuyn ha:
+ H 3O + KCN CH 3CH 2 Cl X Y to
+

Cng thc cu to ca X, Y ln lt l: A. CH3CH2NH2, CH3CH2COOH. C. CH3CH2CN, CH3CH2CHO. 808.

B. CH3CH2CN, CH3CH2COOH. D. CH3CH2CN, CH3CH2COONH4.

809.

H A 2009 Ba cht hu c mch h X, Y, Z c cng cng thc phn t C3H6O v c cc tnh cht: X, Z u phn ng vi nc brom; X, Y, Z u phn ng vi H2 nhng ch c Z khng b thay i nhm chc; cht Y ch tc dng vi brom khi c mt CH3COOH. Cc cht X, Y, Z ln lt l: A. C2H5CHO, (CH3)2CO, CH2=CH-CH2OH. B. C2H5CHO, CH2=CH-O-CH3, (CH3)2CO. C. (CH3)2CO, C2H5CHO, CH2=CH-CH2OH. D.CH2=CH-CH2OH, C2H5CHO, (CH3)2CO. H B 2008 iu kin thch hp: cht X phn ng vi cht Y to ra anehit axetic; cht X phn ng vi cht Z to ra ancol etylic. Cc cht X, Y, Z ln lt l: A. C2H4, O2, H2O. B. C2H2, H2O, H2. C. C2H2, O2, H2O. D. C2H4, H2O, CO. C 2010

PHN 3 :TP GII TRN VN THI TRONG 90 PHT 1

I. PHN CHUNG CHO TT C TH SINH (40 cu , t cu 1 n cu 40) Cu 1: Cho hn hp X gm hai kim loi kim tan ht trong 200ml dung dch cha BaCl2 0,3M v Ba(HCO3)2 0,8M thu c 2,8 lt H2 ( ktc) v m gam kt ta. Gi tr ca m l: A. 43,34 B. 49,25 C. 31,52 D. 39,4 Cu 2: Hn hp X gm hiro, propen, propanal, ancol alylic (CH2=CH-CH2OH). t 1 mol hn hp X thu c 40,32 lt CO2 (ktc). un X vi bt Ni mt thi gian thu c hn hp Y c dY = 1,25. Nu ly 0,1 mol hn hp Y
X

th tc dng va vi V lt dung dch Br2 0,2M. Gi tr ca V l: A. 0,1 lt B. 0,2 lt C. 0,25 lit Cu 3: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l: A. Ca, Sr, Ba B. Na, K, Ba C. Na, K, Mg 87

D. 0,3 mol D. Mg, Ca, Ba

Cu 4: Dy no sau y gm cc ion X+, Y2+ ,Z- ,T2- v nguyn t M u c cu hnh e l 1s22s22p63s23p6 ? A. K+, Ca2+, Cl-, S2-, Ar. B. K+, Ca2+, F-, O2-, Ne. + 2+ 2D. K+, Mg2+, Br-, S2-, Ar. C. Na , Ca , Cl , O , Ar. Cu 5: Nhng mt l st nh vo dung dch cha lng d mt trong nhng cht sau: FeCl3, AlCl3, CuSO4, Pb(NO3)2, NaCl, HCl, HNO3 long, H2SO4 c nng, NH4NO3. S trng hp phn ng to mui Fe(II) l: A. 4 B. 3 C. 6 D. 5 Cu 6: phn ng ht a mol kim loi M cn 1,25a mol H2SO4 v sinh ra kh X (sn phm kh duy nht). Ha tan ht 19,2 gam kim loi M vo dung dch H2SO4 to ra 4,48 lt kh X (sn phm kh duy nht, ktc). Kim loi M l: A. Fe. B. Cu. C. Mg. D. Al. Cu 7: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung dch HNO3 th thu c 0,448 lt mt kh duy nht (o ktc) v dung dch Y. C cn cn thn dung dch Y thu c 23 gam cht rn khan T. Xc nh s mol HNO3 phn ng. A. 0,28 B. 0,36 C. 0,32 D. 0,34 Cu 8: t chy hon ton 4,872 gam mt hirocacbon X, dn sn phm chy qua bnh ng dung dch nc vi trong. Sau phn ng thu c 27,93 gam kt ta v thy khi lng dung dch gim 5,586 gam. Cng thc phn t ca X l: A. CH4 B. C4H8 C. C4H10 D. C3H6 Cu 9: Hn hp X cha K2O, NH4Cl, KHCO3 v BaCl2 c s mol bng nhau. Cho X vo nc d, un nng, dung dch thu c cha cht tan l: B. KCl, KOH C. KCl, KHCO3, BaCl2 D. KCl A. KCl, BaCl2 Cu 10: un nng 10,71 gam hn hp X gm propyl clorua v phenyl clorua vi dung dch NaOH long, va v un nng, sau thm tip dung dch AgNO3 n d vo hn hp sau phn ng thu c 8,61 gam kt ta, cc phn ng xy ra hon ton. Khi lng phenyl clorua c trong hn hp X l: A. 4,0 gam. B. 2,71 gam. C. 4,71 gam D. 6,0 gam. Cu 11: Nung nng hon ton 27,3 gam hn hp NaNO3, Cu(NO3)2. Hn hp kh thot ra c dn vo nc d th thy c 1,12 lt kh (ktc) khng b hp th (lng O2 ha tan khng ng k). Khi lng Cu(NO3)2 trong hn hp ban u l: A. 4,4 gam. B. 18,8 gam. C. 28,2 gam. D. 8,6 gam. Cu 12: Trn 3 dung dch Ba(OH)2 0,1M, NaOH 0,2M, KOH 0,3 M vi nhng th tch bng nhau thu c dung dch A . Ly 300ml dung dch A cho phn ng vi V lt dung dch B gm HCl 0,2M v HNO3 0,29M, thu c dung dch C c pH =12. Gi tr ca V l: A. 0,134 lt B. 0,414 lt C. 0,424 lt D. 0,214 lt Cu 13: Ha tan mt lng ancol X vo nc thu c 6,4 gam dung dch Y, nng ca X trong Y l 71,875%. Cho 6,4 gam dung dch Y tc dng vi lng d Na thu c 2,8 lt H2 (ktc). S nguyn t H c trong cng thc phn t ancol X l: A. 10 B. 6 C. 8 D. 4 Cu 14: Dung dch X cha 14,6 gam HCl v 22,56 gam Cu(NO3)2. Thm m (gam) bt st vo dung dch X, sau khi phn ng xy ra hon ton thu c hn hp kim loi c khi lng l 0,628m (gam) v ch to kh NO (sn phm kh duy nht ca N+5). Gi tr ca m l: A. 1,92. B. 9,28. C. 14,88. D. 20,00. Cu 15: Trong t nhin clo c hai ng v c s khi l 35 v 37. Khi lng trung bnh nguyn t ca clo l 35,5. Vy % v khi lng ca 37Cl trong axit pecloric HClO4 l (Cho s khi 1H, 16O): A. 9,204 B. 9,25 C. 9,45 D. 9,404 Cu 16: Nhit si ca ancol etylic (I), anehit axetic (II), axit axetic (III) v axit propionic (IV) sp xp theo th t gim dn l: A. I > II > III > IV. B. IV > III > I > II. C. II > III > I > IV. D. IV > I > III > II. Cu 17: Xt ba nguyn t c cu hnh electron ln lt l: X: 1s22s22p63s1 ; Y: 1s22s22p63s2 ; Z: 1s22s22p63s23p1. Hiroxit ca X, Y, Z xp theo th t tng dn tnh baz l: A. XOH < Y(OH)2 < Z(OH)3 B. Z(OH)2 < Y(OH)3 < XOH C. Y(OH)2 < Z(OH)3 < XOH D. Z(OH)3 < Y(OH)2 < XOH Cu 18: Cho m gam hp cht hu c X c cng thc phn t l C3H6O2 tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Cng thc cu to ca X v gi tr ca m l: A. C2H5COOH v 8,88 gam. B. CH3COOCH3 v 6,66 gam. C. HCOOCH2CH3 v 8,88 gam. D. C2H5COOH v 6,66 gam. Cu 19: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l: 88

A. 19,455. B. 68,1. C. 17,025. D. 78,4 Cu 20: Hn hp X gm hai cht hu c n chc tc dng vi 500ml dung dch KOH 1M, thu c hai mui ca hai axit hu c v mt ancol. Cho lng ancol trn tc dng vi Na d th c 3,36 lt H2 (ktc). X gm : A. Hai este. B. Mt este mt ancol. C. Mt este v mt axit. D. Mt axit mt ancol. Cu 21: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O2 (iu kin chun). Dn sn phm chy qua bnh ng dung dch Ca(OH)2 d, sau phn ng hon ton thu c m gam kt ta. Gi tr ca m l: A. 10,0 B. 12,0 C. 15,0 D. 20,5 Cu 22: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 t nht l: A. KMnO4 B. KNO3 C. AgNO3 D. KClO3 Cu 23: C bao nhiu ng phn cu to, mch h c cng thc phn t C5H8 tc dng vi H2 d (xc tc thch hp) thu c sn phm isopentan ? A. 4. B. 2. C. 6. D. 3. Cu 24: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco, t nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l: A. 5 B. 4 C. 6 D. 7 Cu 25: Chn cu ng trong cc cu sau: A. Ancol a chc ha tan Cu(OH)2 to thnh dung dch mu xanh. B. Phng php chung iu ch ancol no, n chc bc 1 l cho an ken cng nc. C. un nng ancol metylic vi H2SO4 c 170oC thu c ete. D. Khi oxi ha ancol no, n chc th thu c anehit. Cu 26: Nung nng m gam hn hp gm Al v CuO trong iu kin khng c khng kh. Cho cht rn sau phn ng vo dung dch NaOH (d) thu c 672 ml kh H2 v cht rn X. Ho tan ht X trong dung dch HNO3 long (d) thy c 448 ml kh NO (cc phn ng xy ra hon ton v cc th tch kh o ktc). Gi tr m l: A. 2,94 B. 3,48 C. 34,80 D. 29,40 Cu 27: Mt hp cht X c khi lng phn t bng 103. Cho 51,50 gam X phn ng ht vi 500 ml dung dch NaOH 1,20M, thu c dung dch Y trong c mui ca aminaxit v ancol (c khi lng phn t ln hn khi lng phn t O2). C cn Y thu m gam cht rn. Gi tr m l: A. 52,50 B. 24,25 C. 26,25 D. 48,50 Cu 28: Cho Ba kim loi ln lt vo cc dung dch sau: NaHCO3, CuSO4, (NH4)2CO3, NaNO3, MgCl2. S dung dch to kt ta l: A. 5 B. 4 C. 2 D. 3 Cu 29: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin (3); p-metylanilin (4); metylamin (5); imetylamin (6). Th t tng dn lc baz ca cc cht l: A. (3) < (2) < (4) < (1) < (5) < (6) B. (2) > (3) > (4) > (1) > (5) > (6) C. (3) < (1) < (4) < (2) < (5) < (6) D. (2) < (3) < (4) < (1) < (5) < (6) Cu 30: Hp th hon ton 4,48 lt CO2 (ktc) vo 200ml dung dch cha Na2CO3 0,5M v NaOH 0,75M thu c dung dch X. Cho dung dch BaCl2 d vo dung dch X thu c kt ta c khi lng l: A. 29,55 gam. B. 19,7 gam. C. 9,85 gam. D. 39,4 gam. Cu 31: Cho cc cht sau: toluen, etilen, xiclopropan, stiren, vinylaxetilen, etanal, imetyl xeton, propilen. S cht lm mt mu dung dch KMnO4 nhit thng l: A. 4. B. 5. C. 7. D. 6. Cu 32: Hn hp X gm HCOOH v CH3COOH trn theo t l mol 1 : 1. Cho 10,6 gam hn hp X tc dng vi 11,5 gam C2H5OH (c H2SO4 c lm xc tc) thu c m gam este (hiu sut phn ng este ha t 80%). Gi tr ca m l: A. 16,2. B. 14,08. C. 17,6. D. 12,96. Cu 33: iu no sau y khng ng? A. Cht do l nhng vt liu b bin dng di tc dng ca nhit v p sut m vn gi nguyn bin dng khi thi tc dng. B. T visco, t axetat l t tng hp. C. Nilon-6,6 v t capron l poliamit D. T tm, bng, len l polime thin nhin. Cu 34: Tm nhn xt ng: A. Khi thay i bt k 1 trong 3 yu t: p sut, nhit hay nng ca mt h cn bng ho hc th h s chuyn dch sang mt trng thi cn bng mi. 89

B. Trong bnh kn tn ti cn bng 2NO2(nu) N2O4. Nu ngm bnh trn vo nc thy mu nu trong bnh nht dn. iu chng t chiu nghch ca phn ng l chiu thu nhit. C. Trong bnh kn, phn ng 2SO2 + O2 2SO3 trng thi cn bng. Thm SO2 vo , trng thi cn bng mi, ch c SO3 l c nng cao hn so vi trng thi cn bng c. D. Khi thm cht xc tc, hiu sut phn ng tng hp NH3: N2 + 3H2 NH3 s tng. Cu 35: Cho cc nhn xt sau: 1) Sc Ozon vo dung dch KI s thu c dung dch c kh nng lm h tinh bt ho xanh. 2) Hiro peoxit v hiro sunfua c th lm mt mu dung dch thuc tm trong mi trng H2SO4 long. 3) Sc hiro sunfua vo dung dch FeCl3 s thy xut hin vn c mu vng. 4) Dung dch H2S lu trong khng kh s c vn c mu vng. 5) Hiro peoxit l cht kh mnh v khng c tnh oxi ho Cc nhn xt ng l : A. 1, 3, 4. B. 1, 2, 4, 5. C. 1, 2, 3, 4. D. 2, 4, 5. Cu 36: Cho cc cht v ion sau: Cl-, Na, NH3, HCl, O2-, Fe2+, SO2, Cl2. Cc cht v ion ch th hin c tnh kh trong cc phn ng oxi ha kh l: A. Cl-, Na, O2B. Cl-, Na, O2-, NH3, Fe2+ 2D. Na, O2-, HCl, NH3, Fe2+ C. Na, O , NH3, HCl Cu 37: t chy 3,2 gam mt este E n chc, mch h c 3,584 lt CO2 (ktc) v 2,304 gam H2O. Nu cho 15 gam E tc dng vi 200 ml dung dch NaOH 1M, c cn dung dch sau phn ng thu c 14,3 gam cht rn khan. Vy cng thc ca ancol to nn este trn c th l: A. CH2=CH-OH B. CH3OH C. CH3CH2OH D. CH2=CH-CH2OH Cu 38: S nguyn t m nguyn t ca n ( trng thi c bn) c tng s electron trn cc phn lp s bng 7 l: A. 9. B. 3. C. 5. D. 1. Cu 39: Cho cc cht sau: axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l: A. 6 B. 7 C. 8 D. 5 Cu 40: Cho cc cht: FeCO3, Fe(NO3)2, Fe2(SO4)3, FeSO4, FeS, FeS2, CuS. S lng cht c th c kh thot ra khi cho vo dung dch HCl v un nng nh l: A. 7. B. 4. C. 5. D. 6. II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (Phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Chia 38,1 gam FeCl2 thnh 2 phn, phn 2 c khi lng gp 3 ln phn 1. em phn 1 phn ng ht vi dung dch KMnO4 d, trong mi trng H2SO4 long, d, thu ly kh thot ra. em ton b kh ny phn ng ht vi phn 2, c cn dung dch sau phn ng thu c m gam cht rn. Gi tr ca m l? A. 29,640. B. 28,575. C. 24,375. D. 33,900. Cu 42: Pht biu no sau y l ng ? A. Phn t cc amino axit ch c 1 nhm amino. B. Trong peptit mch h to ra t n phn t H2NRCOOH, s lin kt peptit l (n1) C. Dung dch cc amino axit u khng lm i mu qu tm. D. Phn t ipeptit mch h c 2 lin kt peptit. Cu 43: C cc dung dch ring r sau: AlCl3, NaCl, MgCl2, H2SO4. Ch dng thm mt dung dch no sau y nhn bit c 4 dung dch trn? A. NaOH. B. qu tm. C. AgNO3. D. BaCl2. Cu 44: Cho 35,48 gam hn hp X gm Cu v FeCO3 vo dung dch HNO3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton thu c NO; 0,03 mol kh CO2; dung dch Y v 21,44 gam kim loi. C cn dung dch Y thu c khi lng cht rn khan l: A. 38,82 g B. 36,24 g C. 36,42 g D. 38,28 g Cu 45: Khi phn tch thnh phn mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ancol ng vi cng thc phn t ca X l: A. 1 B. 2 C. 3 D. 4 Cu 46: Ha tan hon ton 80 gam hn hp X gm CuSO4, FeSO4 v Fe2(SO4)3 trong S chim 22,5% v khi lng trong nc c dung dch X. Thm NaOH d vo X, lc kt ta em nung trong khng kh n khi lng khng i thu c cht rn Y, thi CO d qua Y thu c hn hp rn Z. Bit cc phn ng xy ra hon ton. Khi lng ca Z l: A. 30 gam B. 40 gam C. 26 gam D. 36 gam

90

Cu 47: Cho m gam hn hp X gm hai ancol no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d AgNO3 trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. (Cc phn ng u xy ra hon ton). Gi tr ca m l: A. 7,4 B. 8,8 C. 9,2 D. 7,8 Cu 48: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l: A. 6 B. 4 C. 5 D. 3 Cu 49: hirat ha 2-metylbutan-2-ol thu c sn phm chnh l anken no sau y? A. 3-metyl but-1-en B. Pent-1-en C. 2-metyl but-1-en D. 2-metyl but-2-en Cu 50: Nung hn hp SO2, O2 c s mol bng nhau trong mt bnh kn c th tch khng i vi cht xc tc thch hp. Sau mt thi gian, a bnh v nht ban u thy p sut trong bnh gim 10% so vi p sut ban u. Hiu sut ca phn ng xy ra bng: A. 40% B. 50% C. 20% D. 75% B. Theo chng trnh Nng cao (t cu 51 n cu 60) Cu 51: Khi nung butan vi xc tc thch hp thu c hn hp T gm CH4, C3H6, C2H4, C2H6, C4H8, H2 v C4H10 d. t chy hon ton hn hp T thu c 8,96 lt CO2 (o ktc) v 9,0 gam H2O. Mt khc, hn hp T lm mt mu va ht 12 gam Br2 trong dung dch nc brom. Hiu sut phn ng nung butan l: A. 75%. B. 65%. C. 50%. D. 45%. Cu 52: A l hp cht hu c mch vng cha C, H, N trong N chim 15,054% theo khi lng. A tc dng vi HCl to ra mui c dng RNH3Cl. Cho 9,3g A tc dng ht vi nc brom d thu c a g kt ta. Gi tr ca a l: A. 30 gam B. 33 gam C. 44 gam D. 36 gam Cu 53: Cho 0,2 mol mt anehit n chc, mch h X phn ng va vi 300 ml dung dch cha AgNO3 2M trong NH3. Sau khi phn ng xy ra hon ton thu c 87,2 g kt ta. Cng thc phn t ca anehit l: B. C3H5CHO C. C4H3CHO D. C3H3CHO. A. C4H5CHO Cu 54: Trn 10,8g bt Al vi 34,8g bt Fe3O4 ri tin hnh phn ng nhit nhm trong iu kin khng c khng kh. Ho tan hon ton hn hp rn sau phn ng bng dung dch H2SO4 long (d) thu c 10,752 lt kh H2 (ktc). Hiu sut ca phn ng nhit nhm l: A. 70% B. 90% C. 80% D. 60% Cu 55: Th nh 6,85 gam Ba (c ct nh) vo 20 gam dung dch H2SO4 9,80%. Sau khi kt thc phn ng thu c dung dch X. Nng cht tan c trong dung dch X l: A. 23,22% B. 23,12% C. 22,16% D. 31,96% Cu 56: Cho dung dch NH3 d vo dung dch X cha hn hp MgCl2, ZnCl2, FeCl3, FeCl2 thu c kt ta Y. Nung kt ta Y trong khng kh ta c cht rn Z. Cho lung kh CO d i qua A nung nng (cc phn ng xy ra hon ton) thu c cht rn T. Trong T c cha: A. Fe2O3, MgO, ZnO B. Fe, Mg, Zn C. Fe, MgO D. Fe, MgO, ZnO Cu 57: Cho cc cht sau: phenol, kh sunfur, toluen, ancol benzylic, isopren, axit metacrylic, vinyl axetat, phenyl amin, axit benzoic. S cht phn ng c vi dung dch nc brom nhit thng l: A. 6. B. 5. C. 4. D. 3. Cu 58: Trong phng th nghim, kh hiro halogenua c iu ch t phn ng: NaXrn + H2SO4 c HX + NaHSO4 Phng php trn c dng iu ch hiro halogenua no? A. HBr B. HCl C. HCl v HBr D. HI Cu 59: Cho cc cht: ancol etylic, glixerol, glucoz, imetyl ete v axit fomic. S cht tc dng c vi Cu(OH)2 l: A. 4 B. 1 C. 3 D. 2 Cu 60: X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amoni axit no mch h, c mt nhm COOH v mt nhm NH2. t chy hon ton 0,1 mol X bng O2 va thu c sn phm gm CO2, H2O v N2 c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y tc dng hon ton vi NaOH (ly d 20% so vi lng cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn? A. 87,3 gam B. 9,99 gam C. 107,1 gam D. 94,5 gam
t0

1 2

A C

11 12

B A

21 22

C C

31 32 91

B D

41 42

D B

51 52

A B

3 4 5 6 7 8 9 10 2

B A A C B C D D

13 14 15 16 17 18 19 20

C D A B D D C C

23 24 25 26 27 28 29 30

D A C B A B A C

33 34 35 36 37 38 39 40

B B C A D B B B

43 44 45 46 47 48 49 50

A C D C D B D A

53 54 55 56 57 58 59 60

C C A C A B D D

I. Phn chung cho tt c cc th sinh: 40 cu Cu 1: Hp cht A c cng thc phn t C4H6Cl2O2. Cho 0,1 mol A tc dng va vi dung dch c cha 0,3 mol NaOH, thu c dung dch hn hp trong c hai cht hu c gm ancol etylic v cht hu c X, c cn dung dch sau phn ng thu c m gam cht rn khan. Khi lng m l: A. 9,6 gam B. 23,1 gam C. 11,4 gam D. 21,3 gam Cu 2: Nhn nh no sau y khng ng? A. Axeton khng lm mt mu dung dch KMnO4 iu kin thng. B. Cc xeton khi cho phn ng vi H2 u sinh ra ancol bc 2. C. Tr axetilen, cc ankin khi cng nc u cho sn phm chnh l xeton. D. Cc hp cht c cha nhm >C=O u phn ng vi dung dch Br2. Cu 3: Cho 70g hn hp phenol v cumen tc dung vi dung dch NaOH 16% va , sau phn ng thy tch ra hai lp cht lng phn cch, chit thy lp pha trn c th tch l 80 ml v c khi lng ring 0,86g/cm3. % theo khi lng ca cumen trong hn hp l: A. 26,86% B. 98,29% C. 73,14% D. 56,8% Cu 4: Cho 27,3 gam hn hp A gm hai este no, n chc tc dng va vi dung dch KOH, thu c 30,8 gam hn hp hai mui ca 2 axit k tip v 16,1 gam mt ancol. Khi lng ca este c khi lng phn t nh c trong hn hp A l A. 21 gam. B. 22 gam. C. 17,6 gam. D. 18,5 gam. Cu 5: Ch dng qu tm c th nhn bit c ti a bao nhiu dung dch trong cc dung dch sau: NaCl, NaHCO3, Na2CO3, NaHSO4, NaNO3, NaOH. A. 3 B. 2 C. 4 D. 6 Cu 6: Cho 13,62 gam trinitrotoluen (TNT) vo mt bnh ng bng thp c dung tch khng i 500ml (khng c khng kh) ri gy n. Sau phn ng nhit bnh l 18000C, p sut trong bnh l P atm, bit rng sn phm kh trong bnh sau n l hn hp CO, N2, H2. P c gi tr l: A. 224,38 B. 203,98 C. 152,98 D. 81,6 Cu 7: trung ho dung dch cha 0,9045 gam 1 axit hu c A cn 54,5 ml dung dch NaOH 0,2 M. Trong dung dch ancol B 94% (theo khi lng) t s mol ancol : nc l 86:14. Cng thc ca A v B l: A. C4H8(COOH)2, C2H5OH B. C6H4(COOH)2, CH3OH C. C4H8(COOH)2, CH3OH D. C6H4(COOH)2, C2H5OH. Cu 8: Cc cht kh sau: SO2, NO2, Cl2, N2O, H2S, CO2. Cc cht kh khi tc dng vi dung dch NaOH ( nhit thng) lun to ra 2 mui l: A. NO2, SO2 , CO2 B. CO2, Cl2, N2O C. SO2, CO2, H2S D. Cl2, NO2 Cu 9: Hp cht hu c X c cng thc phn t C6H10O2, cho 9,12 gam X tc dng vi dung dch NaOH va thu c dung dch Y, cho dung dch Y tc dng vi dung dch AgNO3 d trong NH3 un nng thu c 34,56 gam Ag. S ng phn cu to ca X l: A. 4. B. 5 C. 2. D. 3. Cu 10: Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3, Fe3O4 phn ng ht vi dung dch HNO3 long d thu c 1,344 lt kh NO sn phm kh duy nht ( ktc) v dung dch X. Dung dch X c th ho tan c ti a 11,2 gam Fe. S mol ca HNO3 c trong dung dch ban u l: A. 0,94 mol. B. 0,64 mol. C. 0,86 mol. D. 0,78 mol.

92

Cu 11: Cho cc cht v dung dch sau: toluen, stiren, etilen, xiclopropan, isopren, vinyl axetat, etyl acrylat, ivinyl oxalat, foocmon, axeton, dung dch glucoz, dung dch Fructoz, dung dch mantoz, dung dch saccaroz. S cht v dung dch c th lm mt mu dung dch Br2 l: A. 11. B. 10 C. 8 D. 9 Cu 12: Ha tan 14g hn hp Cu, Fe3O4 vo dung dch HCl, sau phn ng cn d 2,16g hn hp cht rn v dung dch X. Cho X tc dng vi AgNO3 d thu c bao nhiu gam kt ta: A. 45,92 B. 12,96 C. 58,88 D. 47,4 Cu 13: Ho tan ht m gam Al2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo X, thu c 2a gam kt ta. Mc khc, nu cho 400 ml dung dch NaOH 1M vo X, cng thu c a gam kt ta. Cc phn ng xy ra hon ton, gi tr ca m l: A. 18,81 B. 15,39 C. 20,52 D. 19,665 Cu 14: Cho cc phn ng: (1). O3 + dung dch KI (2). MnO2 + HCl c (3). KClO3 + HCl c
to t
o

(6). F2 + H2O

t
o

(7). H2S + dung dch Cl2 (8). HF + SiO2 (9). NH4Cl + NaNO2
to

to to

(4). NH4HCO3

(5). NH3(kh) + CuO (10). Cu2S + Cu2O S trng hp to ra n cht l: A. 5. B. 6. C. 7. D. 8. Cu 15: Ha tan 15,84 gam hn hp gm mt oxit kim loi kim v mt oxit kim loi kim th bng dung dch HCl d c dung dch X. C cn dung dch X, ly mui khan em in phn nng chy hon ton th thu c 6,048 lt kh (o ktc) anot v a (gam) hn hp kim loi catot. Gi tr ca a l: A. 7,2. B. 11,52. C. 3,33. D. 13,68. Cu 16: X l ipeptit Ala-Glu, Y l tripeptit Ala-Ala-Gly. un nng m (gam) hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:2 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 56,4 gam cht rn khan. Gi tr ca m l: A. 45,6 B. 40,27. C. 39,12. D. 38,68. Cu 17: C cc nhn xt sau: 1- Cht bo thuc loi cht este. 2- T nilon, t capron, t enang u iu ch bng phn ng trng ngng. 3- Vinyl axetat khng iu ch c trc tip t axit v ancol tng ng. 4- Nitro benzen phn ng vi HNO3 c (xc tc H2SO4 c) to thnh m-initrobenzen. 5- phenyl amoni clorua phn ng vi nc brom d to thnh (2,4,6-tribromphenyl) amoni clorua. Nhng cu ng l: A. 1, 3, 4. B. 2, 3, 4. C. Tt c. D. 1, 2, 4, 5. Cu 18: Mt loi phn Supephotphat kp c cha 72,68% mui canxi ihirophotphat cn li gm cc cht khng cha pht pho. dinh dng ca loi phn ln ny l: A. 60,68% B. 37,94% C. 30,34% D. 44,1% Cu 19: Pht biu no di y khng ng? A. Cht bo nh hn nc v khng tan trong nc B. M ng vt ch yu cu thnh t gc axit bo, no, tn ti trng thi rn C. Hiro ho du thc vt lng s to thnh cc m ng vt rn D. Nhc im ca cht git ra tng hp l gy nhim cho mi trng Cu 20: Cho cc cht sau: FeBr3, FeCl2, Fe3O4, AlBr3, MgI2, KBr, NaCl, CaF2, CaC2. Axit H2SO4 c nng c th oxi ha bao nhiu cht? A. 3 B. 6 C. 5 D. 7 Cu 21: Cho ankan X tc dng vi clo (as) thu c 26,5 gam hn hp cc dn xut clo (mono v iclo). Kh HCl bay ra c hp th hon ton bng nc sau trung ha bng dd NaOH thy tn ht 500 ml dd NaOH 1M. Xc nh CT ca X? A. C2H6 B. C4H10 C. C3H8 D. CH4 Cu 22: Cho cc cht: xiclobutan, metylxiclopropan, 1,2-imetylxiclopropan, -butilen, but-1-in, trans but-2-en, butaien, vinyl axetilen, isobutilen, anlen. C bao nhiu cht trong s cc cht trn khi tc dng vi hiro c th to ra butan. 93

A. 8 B. 9 C. 7 D. 6 Cu 23: Khi iu ch Na trong cng nghip ngi ta dng hn hp gm 2 phn NaCl v 3 phn CaCl2 v khi lng vi mc ch: A. To ra nhiu cht in ly hn B. Tng nng ion ClC. Gim nhit nng chy D. To ra hn hp c khi lng ring nh ni ln trn Na nng chy Cu 24: Cho cc phn ng:

CH2=CH2 + H2O C2H 5OH + HBr (bk)

toc

Cl 2 + KOH Mg(NO 3)2 Na 2O2 + H2O

toc

CH 3 -CH=CH2 + Br 2(dd) CH3 -CHO + H2

Fe3O4 + H2SO4 (loang)

Trong cc phn ng trn c bao nhiu phn ng l oxh-kh, bao nhiu phn ng ni phn t: A. 7 4 B. 6 4 C. 5 4 D. 6 2 Cu 25: Sb cha 2 ng v chnh 121Sb v 123 Sb, khi lng nguyn t trung bnh ca Sb l 121,75. % khi lng ca ng v 121 Sb trong Sb2O3 (MO=16) l: A. 52,2 B. 62,5 C. 26,1 D. 51,89 Cu 26: Cho H (Z=1), N (Z=7), O (Z=8). Trong phn t HNO3, tng s cp electron lp ngoi cng khng tham gia lin kt ca 5 nguyn t l: A. 8. B. 9. C. 7. D. 6. Cu 27: Mt loi cao su buna-N c phn trm khi lng ca nit l 19,72%. T l mt xch butaien v vinyl xianua l: A. 1 : 2 B. 2 : 1 C. 1 : 3 D. 3 : 1 Cu 28: Cho cc cn bng sau: (1) 2NH3(k) N2(k) + 3H2(k) H > 0 (2) 2SO2(k) + O2(k) 2SO3(k) H < 0(3) (4) H2(k) + I2(k) 2HI(k) H < 0 CaCO3(r) CaO(r) + CO2(k) H > 0 Trong cc cn bng trn cn bng no s chuyn dch theo chiu thun khi tng nhit v gim p sut: A. 1, 3. B. 2, 4. C. 1, 2, 3 ,4. D. 1, 4. Cu 29: Cho cc dung dung dch sau: (1): natri cacbonat; (2): st (III) clorrua; (3): axit sunfuaric long; (4): axit axetic; (5): natri phenolat; (6): phenyl amoni clorua; (7): imetyl amoni clorua. Dung dch metylamin tc dng c vi dung dch: A. 3, 4, 6, 7 B. 2, 3, 4, 6 C. 2, 3, 4, 5 D. 1, 2, 4, 5 Cu 30: Cho mt ipeptit Y c cng thc phn t C6H12N2O3. S ng phn peptit ca Y (ch cha gc -amino axit) mch h l: A. 5. B. 4. C. 7. D. 6. Cu 31: Cho dung dch mui X vo cc dung dch Na2CO3 ; dung dch Na2S u thy c kt ta v c kh bay ln. Vy X l : A. AlCl3 B. FeCl3 C. FeCl2 D. CuCl2. Cu 32: C cc pht biu sau y: (1) Amiloz c cu trc mch phn nhnh. (2) Mantoz b kh ha bi dd AgNO3 trong NH3. (3) Xenluloz c cu trc mch phn nhnh. (4) Saccaroz lm mt mu nc brom. (5) Fructoz c phn ng trng bc. (6) Glucoz tc dng c vi dung dch thuc tm. (7) Trong dung dch, glucoz tn ti ch yu dng mch vng v mt phn nh dng mch h. S pht biu ng l: A. 6. B. 4. C. 5. D. 3. Cu 33: Gi thit trong tinh th cc nguyn t st l nhng hnh cu chim 74% th tch tinh th, phn cn li l cc khe rng gia cc qu cu, cho nguyn t khi ca Fe l 55,85 200C khi lng ring ca Fe l 7,87g/cm3. Bn knh nguyn t gn ng ca Fe l: A. 1,28 A0. B. 1,41A0. C. 1,67 A0. D. 1,97 A0. Cu 34: Cho 7,8 gam hn hp X gm 2 ancol n chc, bc I qua CuO d, nung nng (phn ng hon ton) sau phn ng thy khi lng cht rn gim 3,2 gam. Cho hn hp sn phm tc dng vi AgNO3 d trong NH3, un nng thu c m gam Ag. Gi tr ca m l: A. 64,8 B. 43,2 C. 21,6 D. 86,4 94

Cu 35: Hn hp X gm NaBr v NaI. Cho hn hp X tan trong nc thu c dung dch Y. Nu cho brom d vo dung dch Y, sau phn ng hon ton, c cn thy khi lng mui khan thu c gim 7,05 gam. Nu sc kh clo d vo dung dch Y, phn ng hon ton, c cn dung dch thy khi lng mui khan gim 22,625 gam. Thnh phn % khi lng ca mt cht trong hn hp X l: A. 35,9% B. 47,8% C. 33,99% D. 64,3% Cu 36: Cho hi nc i qua than nung nng sau khi loi b hi nc d thu c 17,92 lt (ktc) hn hp kh X gm CO2, CO v H2. Hp th X vo dung dch Ba(OH)2 d thu c 35,46 gam kt ta v c V lt kh Y thot ra. Cho Y tc dng vi CuO d nung nng sau phn ng thy khi lng cht rn gim m gam. Gi tr ca m l: A. 12,8 gam B. 2,88 gam C. 9,92 gam D. 2,08 gam Cu 37: t chy hon ton mt hn hp X (glucoz, fructoz, metanal v etanoic) cn 3,36 lt O2 (iu kin chun). Dn sn phm chy qua bnh ng dung dch Ca(OH)2 d, sau phn ng hon ton thu c m gam kt ta. Gi tr ca m l A. 10,0 B. 12,0 C. 15,0 D. 20,5 Cu 38: C cc pht biu sau: (1) Lu hunh, photpho, C2H5OH u bc chy khi tip xc vi CrO3. (2) Ion Fe3+ c cu hnh electron vit gn l [Ar]3d5. (3) Bt nhm t bc chy khi tip xc vi kh clo. (4) Phn chua c cng thc l Na2SO4.Al2(SO4)3.24H2O. Cc pht biu ng l: A. (1), (2), (4) B. (1), (2). C. (1), (2), (3). D. (3), (4). Cu 39: in phn c mng ngn vi in cc tr 250 ml dung dch hn hp CuSO4 aM v NaCl 1,5M, vi cng dng in 5A trong 96,5 pht. Dung dch to thnh b gim so vi ban u l 17,15g. Gi tr ca a l A. 0,5 M. B. 0,4 M. C. 0,474M. D. 0,6M. Cu 40: Nung hn hp gm 11,2 gam Fe; 6,4 gam Cu v 19,5 gam Zn vi mt lng d lu hunh n khi phn ng hon ton. Sn phm ca phn ng tc dng vi dung dch HCl d thu c kh B. Th tch dung dch Pb(NO3)2 20% (d = 1,1 g/ml) ti thiu cn dng hp th ht kh B l A. 752,27 ml B. 902,73 ml C. 1053,18 ml D. 910,25 ml II. Phn ring( 10 cu) Th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II ) Phn I: Theo chng trnh Chun Cu 41: Cho cc cht sau: axetilen, axit oxalic, axit acrylic, fomanehit, phenyl fomat, vinyl axetilen, glucz, anehit axetic, metyl axetat, saccaroz, natri fomat, axeton. S cht c th tham gia phn ng trng gng l A. 6 B. 8 C. 7 D. 5 Cu 42: Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 50 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 19,04 lt kh CO2 ( ktc) v 14,76 gam H2O. % s mol ca axit linoleic trong m gam hn hp X l: A. 31,25% B. 30% C. 62,5% D. 60% Cu 43: Dy cc kim loi c cu trc mng tinh th lp phng tm khi l: A. Na, K, Ba B. Ca, Sr, Ba C. Mg, Ca, Ba D. Na, K, Mg Cu 44: Xt phn ng: CO(kh) + H2O (kh) CO2(kh) + H2(kh). Trong iu kin ng nhit, khi tng p sut ca h th tc phn ng nghch nh th no? A. Gim. B. Tng. C. C th tng hoc gim D. Khng i. Cu 45: Hin tng ln lt xy ra khi cho t t n d dung dch NaOH vo dung dch CrCl3, thm tip H2O2 d, ri cho dung dch BaCl2 vo l: A. To kt ta xanh lc ri tan, thnh dung dch da cam, sau c kt ta mu vng. B. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta da cam. C. To kt ta xanh lc ri tan, thnh dung dch mu vng, sau c kt ta mu vng. D. To kt ta trng ri tan, thnh dung dch mu xanh, sau c kt ta mu vng. Cu 46: Hn hp X gm hai anken c t khi so vi H2 bng 16,625. Ly hn hp Y cha 26,6 gam X v 2 gam H2. Cho Y vo bnh kn c dung tch V lt ( ktc) c cha Ni xc tc. Nung bnh mt thi gian sau a v 0 oC thy p sut trong bnh bng 7/9 at. Bit hiu sut phn ng hiro ho ca cc anken bng nhau v th tch ca bnh khng i. Hiu sut phn ng hiro ho l A. 40%. B. 50%. C. 75%. D. 77,77%. Cu 47: X c cng thc C4H14O3N2. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y gm 2 kh iu kin thng v u c kh nng lm xanh qu tm m. S CTCT ph hp ca X l: 95

A. 5 B. 3 C. 4 D. 2 Cu 48: C hai th nghim sau: Th nghim 1: Cho 6g ancol no h n chc X tc dng vi m gam Na, sau phn ng thu c 0,075 gam H2. Th nghim 2: Cho 6g ancol no h n chc X tc dng vi 2m gam Na, sau phn ng thu khng ti 0,1gam H2. X c cng thc l: A. CH3OH. B. C2H5OH. C. C3H7OH. D. C4H9OH. Cu 49: Ha tan m gam hh X gm CuCl2 v FeCl3 trong nc c dung dch Y. Chia Y thnh 2 phn bng nhau. Phn 1 : cho kh H2S d vo c 1,28g kt ta. Phn 2 : cho Na2S d vo c 3,04g kt ta. Gi tr ca m l : A. 14,6 g B. 8,4 g C. 10,2 g D. 9,2 g Cu 50: xc nh hm lng ca FeCO3 trong qung xierit, ngi ta lm nh sau: Cn 0,600 gam mu qung, ch ho n theo mt quy trnh hp l, thu c dd FeSO4 trong mi trng H2SO4 long. Chun dung dch thu c bng dung dch chun KMnO4 0,025M th dng va ht 25,2 ml dung dch chun. Thnh phn phn trm theo khi lng ca FeCO3 trong qung l: A. 12,18% B. 60,9% C. 24,26% D. 36,54% Phn II: Theo chng trnh nng cao Cu 51: Hn hp M gm mt peptit X v mt peptit Y (chng cu to t 1 loi aminoaxit, tng s nhm CONH trong 2 phn t l 5) vi t l s mol nX : nY = 1: 2. Khi thy phn hon ton m gam M thu c 12 gam glixin v 5,34 gam alanin. m c gi tr l : A. 14,46g B. 110,28g C. 16,548 D. 15,86g Cu 52: Cho s phn ng sau: Anehit no, mch h X1
+ H 2 / Ni ,t , p , xt H 2O X2 X3 t Cao su buna.
o o

2 X5 2 X3 Cao su buna. Anehit no mch h X4 2 Hy cho bit: khi cho X1 v X4 vi khi lng bng nhau tc dng hon ton vi dung dch AgNO3 trong NH3 un nng, cht no to ra lng Ag nhiu hn ? A. bng nhau. B. X1. C. X4. D. khng xc nh c. Cu 53: Cho dung dch CH3COONa 0,1M (Kb Ca CH3COO- l 5,71.10-10). Nng mol/l ca H+ trong dung dch bng: B. 1.32.10-9 mol/l C. 1,15.10-9 mol/l D. 2,25.10-10 mol/l A. 1,2.10-9 mol/l Cu 54: Cho dung dch AgNO3 vo dung dch X c kt ta to thnh, lc ly kt ta cho vo dung dch NH3 thy kt ta tan. Vy X A. ch c th l NaCl. B. ch c th l Na3PO4. C. l NaCl hay NaBr. D. l NaCl, NaBr hay NaI. Cu 55: X l mt hp cht mu lc thc t khng tan trong dung dch long axit v kim. Khi nu chy vi K2CO3 c mt khng kh th chuyn thnh cht Y c mu vng (d tan trong nc). Cho cht Y tc dng vi H2SO4 long to thnh cht Z c mu da cam. Cht Z tc dng vi HCl c thy to thnh cht kh mu vng lc. X, Y, Z ln lt l B. CrO, K2CrO4, K2Cr2O7. A. Cr2O3, K2CrO4, K2Cr2O7. C. CrO, K2Cr2O7, K2CrO4. D. CrO3, K2Cr2O7, K2CrO4. Cu 56: Ha tan 1,0 gam qung crom trong axit, oxi ha Cr3+ thnh Cr2O72-. Sau khi phn hy ht lng d cht oxi ha, pha long dd thnh 100 ml. Ly 20 ml dd ny cho vo 25 ml dd FeSO4 trong H2SO4. Chun lng d FeSO4 ht 7,50 ml dd chun K2Cr2O7 0,0150M. Bit rng 25 ml FeSO4 tng ng vi 35 ml dd chun K2Cr2O7. Thnh phn % ca crom trong qung l: A. 10,725% B. 13,65%. C. 35,1%. D. 26%. Cu 57: Hn hp X c C2H5OH, C2H5COOH, CH3CHO (trong C2H5OH chim 50% theo s mol). t chy m gam hn hp X thu c 2,88 gam H2O v 2,912 lt CO2 (ktc). Mt khc 9 gam hn hp X thc hin phn ng trng bc thy c p gam Ag kt ta. Gi tr ca p l A. 12,96. B. 4,32. C. 8,64. D. 5,4.

+ H / Ni ,t o

H O, H

t o , p , xt

A B D. D l: Cu 58: Cho s : Propilen A. CH3CH2CH2OH B. CH3CH2CH(OH)CN C. CH3C(OH)(CH3)CN D. CH3CH(OH)CH3. Cu 59: Ha tan hon ton hn hp gm mt kim loi ha tr 1 v oxit kim loi ha tr 2 vo nc d. Sau khi phn ng xong c 500 ml dd X ch cha mt cht tan duy nht v 4,48 lt kh H2. Tnh nng mol ca dung dch X: 96

+ H 2O, H +

+ CuO , t o

+ HCN

A. 0,2M B. 0,4 M C. 0,3M D. 0,25 M Cu 60: T khi ca mt hn hp kh ( gm 2 hidrocacbon mch h) so vi hidro l 17. iu kin tiu chun, trong bng ti, 400 ml hn hp tc dng va vi 71,4 cm3 dung dch brom 0,2 M. Sau phn ng th tch kh cn li l 240 cm3. Cng thc phn t ca 2 hidrocacbon l: A. C2H2 v C3H8 B. CH4 v C4H6 C. C2H6 v C3H6 D. C2H6 v C3H4

1 2 3 4 5 6 7 8 9 10

D D B D C B D D D C

11 12 13 14 15 16 17 18 19 20

B C A C B C A D C D

21 22 23 24 25 26 27 28 29 30

A C C D D C C A B A

31 32 33 34 35 36 37 38 39 40

A D A A B C C C B A

41 42 43 44 45 46 47 48 49 50

D B A B C B B D D B

51 52 53 54 55 56 57 58 59 60

A B B A A A A C B D

3 Cu 1: Cho 2.46 gam hn hp gm HCOOH, CH3COOH, C6H5OH, H2NCH2COOH tc dng va vi 40 ml dd NaOH 1M. Tng khi lng mui khan thu c sau khi p l A. 6.45 gam B. 8.42 gam C. 3.52 gam D. 3.34 gam Cu 2: Dy cc cht u lm mt mu dd thuc tm l A. Axeton, etilen, anehit axetic, cumen B. Etilen, axetilen, anehit fomic, toluen C. Benzen, but-1-en, axit fomic, p-xilen D. Xiclobutan, but-1-in, m-xilen, axit axetic Cu 3: Cho cc CTPT sau : C3H7Cl , C3H8O v C3H9N. Hy cho bit s sp xp no sau y theo chiu tng dn s lng ng phn ng vi cc CTPT ? A. C3H8O < C3H9N < C3H7Cl B. C3H7Cl < C3H8O < C3H9N C. C3H8O < C3H7Cl < C3H9N D. C3H7Cl < C3H9N < C3H8O Cu 4: Cht bo A c ch s axit l 7. x phng ho 10 kg A, ngi ta un nng n vi dd cha 1.420 kg NaOH. Sau khi p xy ra hon ton trung ho hn hp, cn dng 500ml dd HCl 1M. Khi lng x phng (kg) thu c l A. 10.3455 B. 10.3435 C. 10.3445 D. 10.3425 Cu 5: A l hn hp kh gm SO2 v CO2 c t khi hi so vi H2 l 27. Dn a mol hn hp kh A qua bnh ng 1 lt dd NaOH 1.5a M, sau p c cn dd thu c m gam mui. Biu thc lin h gia m v a l A. m=116a B. m=141a C. m=103.5a D. m=105a Cu 6: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3.75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca p hiro ho l A. 40% B. 50% C. 25% D. 20% Cu 7: Ru X, anehit Y, axit cacboxylic Z c cng s nguyn t H trong phn t, thuc cc dy ng ng no n chc mch h. t hon ton hn hp 3 cht ny (c s mol bng nhau) thu c t l mol CO2:H2O=11:12 . Vy CTPT ca X, Y, Z l: A. C4H10O, C5H10O, C5H10O2 B. C2H6O, C3H6O, C3H6O2 C. C3H8O, C4H8O, C4H8O2 D. CH4O, C2H4O, C2H4O2 Cu 8: Dy gm cc cht no sau y u c tnh lng tnh ? A. Al, NaHCO3, NaAlO2, ZnO, Be(OH)2 B. ZnCl2, AlCl3, NaAlO2, NaHCO3, H2NCH2COOH C. AlCl3, H2O, NaHCO3, Zn(OH)2, ZnO D. H2O, CH3COONH4, H2NCH2COOH, NaHCO3 Cu 9: t chy 1.6 gam mt este E n chc c 3.52 gam CO2 v 1.152 gam H2O. Nu cho 10 gam E tc dng vi 150ml dd NaOH 1M , c cn dd sau p thu c 16 gam cht rn khan . Vy cng thc ca axit to nn este trn c th l A. HOOC(CH2)3CH2OH B. HOOC-CH2-CH(OH)-CH3 C. CH2=C(CH3)-COOH D. CH2=CH-COOH Cu 10: Ha tan hon ton hn hp gm x mol Hg2S v 0,04 mol FeS2 bng dd HNO3 m c, un nng, ch thu cc mui sunfat kim loi c ha tr cao nht v c kh V lt NO2 thot ra(KTC). Tr s ca V l: A. 2,24 lt B. 8,96 lt C. 17,92 lt D. 20,16 lt Cu 11: Dy gm cc cht c th iu ch trc tip (bng mt p) to ra axit axetic l: 97

A. C2H4(OH)2, CH3OH, CH3CHO. B. CH3CHO, C2H5OH, C2H5COOCH3. C. CH3CHO, C6H12O6 (glucoz), CH3OH. D. CH3OH, C2H5OH, CH3CHO. Cu 12: Cho 3.2 gam Cu tc dng vi 100ml dd hn hp HNO3 0.8M v H2SO4 0.2M, sn phm kh duy nht l kh NO. S gam mui khan thu c l A. 8.84 B. 7.90 C. 5.64 D. 10.08 Cu 13: Ho tan ht m gam Al2(SO4)3 vo nc c dd A. Cho 300 ml dd NaOH 1M vo A, thu c a gam kt ta. Mc khc, nu cho 400 ml dd NaOH 1M vo A, cng thu c a gam kt ta. Gi tr ca m l A. 21.375. B. 42.75. C. 17.1. D. 22.8 Cu 14: t chy hon ton 4.872 gam mt Hirocacbon X, dn sn phm chy qua bnh ng dd nc vi trong. Sau p thu c 27.93 gam kt ta v thy khi lng dd gim 5.586 gam. CTPT ca X l A. C3H6 B. C4H8 C. CH4 D. C4H10 Cu 15: Ho tan 5.4 gam bt Al vo 150 ml dd A cha Fe(NO3)3 1M v Cu(NO3)2 1M. Kt thc p thu c m gam rn. Gi tr ca m l A. 10.95 B. 13.20 C. 15.20 D. 13.80 Cu 16: Thy phn 34.2 gam mantz vi hiu sut 50%. Sau tin hnh p trng bc vi dd thu c. Khi lng Ag kt ta l A. 10.8 gam B. 43.2 gam C. 32.4 gam D. 21.6 gam Cu 17: Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol), C6H6(benzen), CH3CHO. S cht trong dy p c vi nc brom l A. 8 B. 6 C. 7 D. 5 Cu 18: C 4 dd trong sut , mi dd ch cha mt cation v mt loi anion. Cc loi ion trong c 4 dd gm: Ca2+, Mg2+, Pb2+, Na+, SO42-, Cl-, CO32-, NO3-. l 4 dd g? A. BaCO3, MgSO4, NaCl, Pb(NO3)2 B. Mg(NO3)2, BaCl2, Na2CO3, PbSO4 D. BaCl2, MgSO4, Na2CO3, Pb(NO3)2 C. BaCl2, PbSO4, MgCl2, Na2CO3 Cu 19: Dy ch cha nhng amino axit c s nhm amino v s nhm cacboxyl bng nhau l A. Gly, Val, Tyr, Ala B. Gly, Ala, Glu, Tyr C. Gly, Val , Lys, Ala D. Gly, Ala, Glu, Lys Cu 20: Hy cho bit, p no sau y HCl ng vai tr l cht oxi ha? A. Fe + KNO3 + 4HCl FeCl3 + KCl + NO + 2H2O B. MnO2 + 4HCl MnCl2 + Cl2 + 2H2O C. Fe + 2HCl FeCl2 + H2 D. NaOH + HCl NaCl + H2O Cu 21: Cho 6.4 gam dd ru A c nng 71.875% tc dng vi lng d Na thu c 2.8 lt H2 iu kin chun. S nguyn t H c trong CTPT ru A l A. 6 B. 4 C. 8 D. 10 Cu 22: Cho hn hp kim loi Mg, Zn, Fe vo dd cha AgNO3 v Cu(NO3)2.. Sau khi p xy ra hon ton thu c dd X gm 3 mui v cht rn Y gm ba kim loi. Ba mui trong X l A. Mg(NO3)2, Zn(NO3)2, Fe(NO3)3 B. Mg(NO3)2, Zn(NO3)2, Fe(NO3)2 C. Mg(NO3)2, Fe(NO3)3, AgNO3 D. Mg(NO3)2, Zn(NO3)2, Cu(NO3)2 Cu 23: Sc V lt CO2 ( iu kin chun) vo 200 ml dd X gm Ba(OH)2 1M v NaOH 1M . Sau p thu c 19.7 gam kt ta, gi tr ca V l A. 2.24 v 11.2 B. 5.6 v 1.2 C. 2.24 v 4.48 D. 6.72 v 4.48 Cu 24: Tng s ht ca mt nguyn t X l 28. X l A. N B. F C. O D. Ne Cu 25: t chy hon ton mt hn hp A (glucz, anehit fomic, axit axetic) cn 2.24 lt O2 (iu kin chun). Dn sn phm chy qua bnh ng dd Ca(OH)2, thy khi lng bnh tng m gam. Gi tr ca m l A. 3.1 B. 6.2 C. 12.4 D. 4.4 Cu 26: Cho mt lung kh CO i qua ng s ng m gam Fe2O3 nung nng. Sau mt thi gian thu c 10.44 gam cht rn X gm Fe, FeO, Fe2O3 v Fe3O4. Ha tan ht X trong dd HNO3 c, nng thu c 4.368 lt NO2 (sn phm kh duy nht iu kin chun). Gi tr ca m l A. 24 B. 10.8 C. 12 D. 16 Cu 27: Cho cc cht sau : axetilen, axit fomic, fomanehit, phenyl fomat, glucz, anehit axetic, metyl axetat, mantz, natri fomat, axeton. S cht c th tham gia p trng gng l A. 5 B. 6 C. 7 D. 8 Cu 28: Bit Cu c s hiu nguyn t l 29. Cu hnh electron ca ion Cu+ l A. [Ar]3d9 B. [Ar]3d94s1 C. [Ar]3d10 D. [Ar]3d104s1 Cu 29: Cho 29.8 gam hn hp 2 amin n chc k tip tc dng ht vi dd HCl, lm kh dd thu c 51.7 gam mui khan. CTPT 2 amin l A. CH5N v C2H7N B. C2H7N v C3H9N C. C3H9N v C4H11N D. C3H7N v C4H9N Cu 30: Cho cc cht: amoniac (1); anilin (2); p-nitroanilin(3); p-metylanilin (4) ; metylamin (5) ; imetylamin (6) . Hy chn s sp xp cc cht trn theo th t lc baz tng dn . A. (3) < (1) < (4) <(2) < (5) < (6) B. (2) > (3) > (4) > (1) > (5) > (6) C. (2) < (3) < (4) < (1) < (5) < (6) D. (3) < (2) < (4) < (1) < (5) < (6) Cu 31: Cho phng trnh ho hc: 98

Al + HNO3 Al(NO3)3 + NO + N2O + H2O (Bit t l th tch N2O: NO = 1 : 3). Sau khi cn bng phng trnh ho hc trn vi h s cc cht l nhng s nguyn, ti gin th h s ca HNO3 l A. 64 B. 66 C. 60 D. 62 Cu 32: C 45.75 gam cao su buna-S p va ht vi 20 gam brom trong CCl4. T l mt xch butaien v stiren trong cao su buna-S l A. 1 : 3 B. 1 : 2 C. 2 : 3 D. 3 : 5 Cu 33: Khi nhit phn hon ton 100 gam mi cht sau: KClO3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht to ra lng O2 t nht l A. KNO3 B. KMnO4 C. AgNO3 D. KClO3 Cu 34: nhn bit ba l mt nhn: phenol, stiren, ancol benzylic, ngi ta dng mt thuc th duy nht l A. Na B. Dd NaOH C. Nc brom D. Ca(OH)2 Cu 35: Cho t t 150 ml dd HCl 1M vo 500 ml dd A gm Na2CO3 v NaHCO3 th thu c 1.008 lt kh (iu kin chun) v dd B. Cho dd B tc dng vi dd Ba(OH)2 d th thu c 29.55 gam kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dd A ln lt l: A. 0.21M v 0.18M B. 0.18M v 0.26M C. 0.2M v 0.4M D. 0.21M v 0.32M Cu 36: a mt hn hp kh N2 v H2 c t l 1: 3 vo thp tng hp, sau p thy th tch kh i ra gim 1/10 so vi ban u. Tnh thnh phn phn trm v th tch ca hn hp kh sau p. A. 22.22%, 66.67%, 11.11% B. 30%, 60%, 10% C. 20%, 60%, 20% D. 33.33%, 50%, 16.67% Cu 37: Cho cc kim loi: Cr, W , Fe , Cu , Cs . Sp xp theo chiu tng dn cng t tri sang phi l A. Cu < Cs < Fe < Cr < W B. Cs < Cu < Fe < W < Cr C. Cu < Cs < Fe < W < Cr D. Cs < Cu < Fe < Cr < W Cu 38: in phn 2 lt dd hn hp gm NaCl v CuSO4 n khi H2O b in phn hai cc th dng li, ti catt thu 1.28 gam kim loi v ant thu 0.336 lt kh ( iu kin chun). Coi th tch dd khng i th pH ca dd thu c bng A. 12 B. 2 C. 3 D. 13 Cu 39: H s ng trc cht b oxi ha bn tc cht p FexOy + CO FemOn + CO2 cn bng s nguyn t cc nguyn t l: A. nx my. B. m C. my nx. D. mx 2ny. Cu 40: Cho a mol bt km vo dd c ha tan b mol Fe(NO3)3. Tm iu kin lin h gia a v b sau khi kt thc p khng c kim loi. A. b > 3a B. a 2b C. b 2a D. b = 2a/3 Cu 41: Cho 13.8 gam axit A tc dng vi 16.8 gam KOH , c cn dd sau p thu c 26.46 gam cht rn. CTCT thu gn ca A l B. C3H6COOH C. C2H5COOH D. HCOOH A. CH3COOH Cu 42: Chn pht biu ng: A. Tnh oxi ha ca Ag+ > Cu2+ > Fe3+ > Ni2+ > Fe2+ B. Tnh oxi ha ca Ag+ > I2 > Fe3+ > Cu2+ > S2C. Tnh kh ca K > Mg > Zn > Ni > Fe > Hg D. Tnh kh ca K > Fe > Cu > I- > Fe2+ > Ag Cu 43: Cn ti thiu bao nhiu gam NaOH (m1) v Cl2 (m2) p hon ton vi 0.01 mol CrCl3. Gi tr ca m1 v m2 ln lt l A. 3.2 v 1.065 B. 3.2 v 0.5325 C. 6.4 v 0.5325 D. 6.4 v 1.065 Cu 44: Cho cc dd sau: Na2CO3, NaOH v CH3COONa c cng nng mol/l v c cc gi tr pH tng ng l pH1, pH2 v pH3. S sp xp no ng vi trnh t tng dn pH. A. pH3< pH2 < pH1 B. pH1 < pH3 < pH2 C. pH3 < pH1 < pH2 D. pH1 < pH2 < pH3 Cu 45: Ch dng mt thuc th phn bit cc kim loi sau: Mg, Zn, Fe, Ba? A. Dd H2SO4 long B. Nc C. Dd NaOH D. Dd HCl Cu 46: Ho tan 19.2 gam Cu vo 500 ml dd NaNO3 1M, sau thm vo 500ml dd HCl 2M . Kt thc p thu c dd X v kh NO duy nht, phi thm bao nhiu ml dd NaOH 1M vo X kt ta ht ion Cu2+ A. 120 B. 400 C. 600 D. 800 Cu 47: Cho Na d tc dng vi a gam dd CH3COOH. Kt thc p, thy khi lng H2 sinh ra l 0,45833a gam . Vy nng C% dd axit l A. 36% B. 10% C. 4.58% D. 25% Cu 48: Thy phn hon ton mt lng mantoz, sau cho ton b lng glucoz thu c ln men thnh ancol etylic th thu c 100 ml ancol 460. Khi lng ring ca ancol l 0,8gam/ml. Hp th ton b kh CO2 vo dd NaOH d thu c mui c khi lng l A. 84.8 gam B. 106 gam C. 212 gam D. 169.6 gam Cu 49: t chy hon ton 1 mol ancol no A cn 3.5 mol O2. CTPT ca A l A. C3H6O2 B. C3H8O3 C. C2H6O D. C2H6O2 Cu 50: Cho 0.1 mol cht X ( CH6O3N2) tc dng vi dd cha 0.2 mol NaOH un nng thu c cht kh lm xanh giy qu tm m v dd Y. C cn dd Y thu c m gam rn khan. Gi tr ca m l A. 8.5 B. 12.5 C. 15 D. 21.8 99

Cu 51: Ln men m gam glucz vi hiu sut 90%, lng CO2 sinh ra hp th ht vo nc vi trong thu c 15 gam kt ta v khi lng dd gim 5.1 gam. Gi tr m l A. 22.5 B. 45 C. 20.25 D. 30 Cu 52: Xt p thun nghch sau: SO2(k) + NO2(k) SO3(k) + NO(k). Cho 0.11(mol) SO2, 0.1(mol) NO2, 0.07(mol) SO3 vo bnh kn 1 lt. Khi t cn bng ha hc th cn li 0.02(mol) NO2. Vy hng s cn bng KC l A. 23 B. 20 C. 18 D. 0.05 Cu 53: Hirat ho 3.36 lt C2H2 ( iu kin chun) thu c hn hp A ( hiu sut p 60%) . Cho hn hp sn phm A tc dng vi dd Ag2O/NH3 d thu c m gam cht rn. Gi tr ca m l A. 33.84 B. 48.24 C. 14.4 D. 19.44 Cu 54: Cn bao nhiu a mol K2Cr2O7 v b mol HCl iu ch c 3.36 lit Cl2 iu kin chun. Gi tr a v b ln lt l: A. 0.05 v 0.7 B. 0.05 v 0.35 C. 0.1 v 0.7 D. 0.1 v 0.35 Cu 55: Hn hp A gm mu vi (cha 80% khi lng CaCO3) v mu qung Xierit (cha 65% khi lng FeCO3). Phn cn li trong vi v qung l cc tp cht tr. Ly 250 ml dd HCl 2,8M cho tc dng vi 38,2 gam hn hpA. P xy ra hon ton. Kt lun no di y ph hp? A. Khng d kin kt lun B. Cc mui Cacbonat p ht, do c HCl d C. P xy ra va D. Khng HCl p ht cc mui Cacbonat Cu 56: nhn bit cc kh: CO2, SO2, H2S, N2 cn dng cc dd: A. Nc brom v NaOH B. NaOH v Ca(OH)2 D. KMnO4 v NaOH C. Nc brom v Ca(OH)2 Cu 57: Cho 0.1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dd AgNO3 trong NH3, un nng thu c 32.4 gam Ag. Hai anehit trong X l A. CH3CHO v C3H5CHO. B. CH3CHO v C2H5CHO. C. HCHO v C2H5CHO. D. HCHO v CH3CHO. Cu 58: Cho 20 gam hn hp 3 amin no n chc l ng ng k tip c t l mol tng ng l 1: 10 : 5, tc dng va vi dd HCl thu c 31.68 gam hn hp mui. Tng s ng phn ca 3 amin trn l A. 7 B. 14 C. 28 D. 16 Cu 59: Dy gm cc kim loi u tc dng c vi dd FeCl3 l: A. Au, Cu, Al, Mg, Zn B. Fe, Zn, Cu, Al, Mg C. Cu, Ag, Au, Mg, Fe D. Fe, Mg, Cu, Ag, Al Cu 60: t chy hon ton 1 mol ancol no A cn 2.5 mol O2. CTPT ca A l A. C2H6O2 B. C3H8O3 C. C3H6O2 D. C2H6O 1 2 3 4 5 6 7 8 9 10 D B B D D B C D A C 11 12 13 14 15 16 17 18 19 20 D B A D D C B D A C 21 22 23 24 25 26 27 28 29 30 C B A B B C C C B D 31 32 33 34 35 36 37 38 39 40 B A C C A A B B C C 41 42 43 44 45 46 47 48 49 50 A D A C A D D A B B 51 52 53 54 55 56 57 58 59 60 A B A A B C D B B A

4 I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Pht biu no sau y ng? A. Trong mi trng kim, ipeptit mch h tc dng c vi Cu(OH)2 cho dung dch mu tm xanh B. Trong mt phn t tripeptit mch h c 3 lin kt peptit. C. Cc hp cht peptit bn trong mi trng baz v mi trng axit. D. axit glutamic HOOC-CH2-CH2-CH(NH2)-COOH c tnh lng tnh Cu 2: Trong t nhin, canxi sunfat tn ti di dng mui ngm nc (CaSO4.2H2O) c gi l A. thch cao sng. B. vi. C. thch cao nung. D. thch cao khan.

100

Cu 3: Este E c iu ch t axit n chc, mch h X v ancol n chc, mch h Y. t chy hon ton 4,8 gam E, thu c 5,376 lt CO2 v 3,456 gam H2O. Mt khc, khi cho 15 gam E tc dng vi 195 ml dung dch NaOH 1M, c cn dung dch sau phn ng thu c 14,1 gam cht rn khan. Cng thc cu to ca Y l B. CH3CH2CH2OH C. CH3CH2OH D. CHC-CH2OH A. CH2=CHCH2OH Cu 4: Hn hp X gm cc cht hu c mch h, n chc c cng cng thc phn t l C3H4O2. un nng nh 14,4 gam X vi dung dch KOH d n hon ton thu c dung dch Y (gi s khng c sn phm no thot ra khi dung dch sau phn ng). Trung ha baz cn d trong dung dch Y bng HNO3, thu c dung dch Z. Cho Z tc dng vi dung dch AgNO3 d trong NH3 thu c 43,2 gam kt ta. Hi cho 14,4 gam X tc dng Na d thu c ti a bao nhiu lit H2 ktc ? A. 2,24 lit B. 1,12 lit C. 3,36 lit D. 4,48 lit Cu 5: Cho 8,96 lit CO2 (ktc) sc vo dung dch cha 100 ml dung dch cha hn hp Ca(OH)2 2M v NaOH 1,5M thu c a gam kt ta v dung dch X. un nng k dung dch X thu c thm b gam kt ta. Gi tr b l: A. 5 gam B. 15 gam C. 20 gam D. 10 gam Cu 6: ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,15 mol Y, thu c tng khi lng CO2 v H2O bng 82,35 gam. t chy hon ton 0,1 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 40 B. 80 C. 60 D. 30 Cu 7: Tng s cc ht electron trong anion XY32- l 42. Trong X chim 40% v khi lng. Trong cc ht nhn ca X v Y u c s ht proton bng s ht ntron. V tr ca X, Y trong bng tun hon l? A. X th 16, chu k 3, nhm VIA; Y th 9; chu k 2, nhm VIIA B. X th 16, chu k 3, nhm VIA; Y th 8; chu k 2, nhm VIA C. X th 14, chu k 3, nhm IVA; Y th 8; chu k 2, nhm VIB D. X th 14, chu k 4, nhm VIIIB; Y th 9; chu k 2, nhm VIIA Cu 8: Hn hp X gm propin, propan v propilen c t khi so vi hiro l 21,2. t chy hon ton 15,9 gam X, sau hp th ton b sn phm vo bnh ng 1 lt dung dch Ba(OH)2 0,8M; thy khi lng bnh tng m gam v c a gam kt ta. Gi tr ca m v a ln lt l A. 42,4 gam v 157,6 gam B. 71,1 gam v 93,575 gam C. 42,4 gam v 63,04 gam D. 71,1 gam v 73,875 gam Cu 9: t chy hon ton 2,01 gam hn hp gm axit acrylic, vinyl axetat, metyl metacrylat. Ton b sn phm chy cho qua dung dch Ca(OH)2 d, sau phn ng thu c 9 gam kt ta v dung dch X. Vy khi lng dung dch X thay i so vi dung dch Ca(OH)2 ban u l: A. gim 3,87 gam B. tng 5,13 gam C. tng 3,96 gam D. gim 9 gam Cu 10: C hai hp cht hu c mch h X, Y l ng phn ca nhau, trong X l hp cht n chc, Y l hp cht a chc. Cng thc n gin ca chng l C2H4O. Bit X, Y tc dng vi Cu(OH)2 nhit thng. Vy X, Y l: A. X l axit n chc v Y l ancol n chc B. X l axit n chc, Y l ancol 3 chc. C. X l axit n chc; Y l anehit 2 chc. D. X l axit n chc, Y l ancol 2 chc. Cu 11: Cho cc nguyn t sau : X (Z=9) ; Y (Z=12) ; M (Z = 15) ; T (Z= 19). Hy cho bit s sp xp no ng vi chiu tng dn bn knh nguyn t ca cc nguyn t ? A. Y < T < X < M B. M < Y < X < T C. X < M < Y < T D. X < Y < M < T Cu 12: Cho cc dung dch: CH3COONa, (H2N)2CH-CH2-COOH, CH3NH2, C6H5OH, C6H5ONa, CH3COOH, C6H5NH2. Trong s cc dung dch trn, c bao nhiu dung dch lm i mu qu tm? A. 4 B. 3 C. 5 D. 6 Cu 13: Khi cho mt lng va dung dch long ca KMnO4 v H2SO4 vo mt lng H2O2, thu c 2,24 lt O2 (ktc). Khi lng ca H2O2 c trong dung dch ly v khi lng ca KMnO4 phn ng ln lt l A. 6,32 g v 2,04 g . B. 2,04 g v 3,16 g . C. 3,4g v 3,16 g. D. 3,4g v 6,32g. Cu 14: Cho 3,78 gam hn hp X gm CH2=CHCOOH, CH3COOH v CH2=CHCH2OH phn ng va vi dung dch cha 8 gam brom. Mt khc, trung ho 0,03 mol X cn dng va 20 ml dung dch NaOH 0,75M. Khi lng ca CH2=CHCOOH c trong 3,78 gam hn hp X l A. 2,16 gam B. 1,44 gam C. 1,08 gam D. 0,72 gam Cu 15: Cho 1 lit nc cng tm thi cha (Ca2+, Mg2+ v HCO3-). Bit t l mol ca 2 ion Ca2+ v Mg2+ tng ng l 2:1. Tng khi lng ca hai mui hidrocacbonat trong 1 lit nc trn l 14,1 gam. Tnh khi lng Ca(OH)2 cn thm vo 1 lit nc cng trn, nc thu c mt hon ton tnh cng? A. 17,76 gam B. 13,32 gam C. 6,66 gam D. 8,88 gam Cu 16: Cho phn ng sau: a CuFeS2 + b H2SO4 c Fe2(SO4)3 + d SO2 + e CuSO4 + f H2O Trong a, b, c, d, e l cc s nguyn dng, ti gin. Gi tr ca b, d trong phn ng trn sau khi cn bng tng ng l: A. 18 v 17 B. 18 v 13 C. 22 v 13 D. 22 v 17 Cu 17: Cho cc cht: (1) dung dch KOH (un nng); (2) H2/ xc tc Ni, to; (3) dung dch H2SO4 long (un nng); (4) dung dch Br2; (5) Cu(OH)2 nhit phng (6) Na 101

Hi Triolein nguyn cht c phn ng vi bao nhiu cht trong s cc cht trn ? A. 4 B. 5 C. 3 D. 2 Cu 18: Cho cc pht biu sau: (1) C th dng nc brom phn bit glucoz v fructoz. (2) Dung dch glucoz v dung dch saccaroz u c phn ng trng bc. (3) Dung dch saccaroz ho tan Cu(OH)2 nhit thng cho dung dch mu xanh lam. (4) Thu phn hon ton tinh bt thu c fructoz. S pht biu ng l: A. 3 B. 2 C. 4 D. 1 Cu 19: Nung hn hp X gm FeO, CuO, MgO v Al nhit cao, sau khi cc phn ng xy ra hon ton cho phn rn vo dd NaOH d thy c kh H2 bay ra v cht rn khng tan Y. Cho Y vo dd H2SO4 long, d. Cho bit c bao nhiu phn ng xy ra ? A. 5 B. 6 C. 7 D. 8 Cu 20: C bao nhiu ng phn l hp cht thm c cng CTPT: C8H10O tc dng c vi Na v tc dng c vi NaOH? A. 6 B. 8 C. 9 D. 7 Cu 21: Cho cc dung dch sau: H2SO4 (1); KHSO4 (2); KCl (3); CH3COOH (4); CH3NH2 (5) c cng nng 0,1M. Dy cc dung dch xp theo chiu tng dn gi tr pH l: A. (1), (2), (3), (4), (5). B. (1), (4), (3), (2), (5) C. (5), (3), (4), (2), (1) D. (1), (2), (4), (3), (5). Cu 22: Cho dung dch X cha 0,2 mol Al3+, 0,4 mol Mg2+, 0,4 mol NO3-, x mol Cl-, y mol Cu2+ - Nu cho dung dch X tc dng vi dung dch AgNO3 d th thu c 172,2 gam kt ta. - Nu cho 1,7 lit dung dch NaOH 1 M vo dung dch X th khi lng kt ta thu c l A. 25,3 gam B. 20,4 gam C. 40,8 gam D. 48,6 gam Cu 23: Cho hn hp Na, Al vo nc d thu c 4,48 lit H2 (ktc) v dung dch X ch cha 1 cht tan. Sc CO2 d vo dung dch X th thu c bao nhiu gam kt ta ? A. 15,6 gam B. 10,4 gam C. 7,8 gam D. 3,9 gam Cu 24: Cho cc cht rn sau: CuO, Fe3O4, BaCO3 v Al2O3. Ch dng mt thuc th no sau y c th nhn bit c tt c cc ha cht ? A. dd FeCl2 B. dd NaOH C. dd NH3 D. dd HCl. Cu 25: Hidrat ha 7,8 gam axetilen c xc tc HgSO4 800C, hiu sut phn ng ny l H %. Cho ton b hn hp thu c sau phn ng vo dung dch AgNO3 d trong NH3 th thu c 66,96 gam kt ta. Gi tr H l: A. 10,3% B. 70% C. 93% D. 7% Cu 26: Pht biu lin quan trng thi cn bng ha hc (CBHH) no di y l khng ng? A. Gi tr hng s cn bng ho hc ca mt phn ng khng thay i mi nhit . B. trng thi CBHH, cc phn ng thun v nghch vn xy ra vi tc bng nhau. C. S thay i yu t nhit , nng hoc p sut c th ph v trng thi CBHH v to ra s chuyn di cn bng. D. trng thi CBHH, nng cc cht tham gia phn ng v cc cht sn phm u khng i. Cu 27: Hn hp kh X gm 0,45 mol H2 v 0,15 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi H2 l 14,5. Nu cho ton b Y sc t t vo dung dch brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l A. 32. B. 48. C. 24. D. 16. Cu 28: Hn hp X gm CH3CH2COOH, HCOOH, C6H5COOH v HOOC-CH2-COOH. Khi cho m gam X tc dng vi NaHCO3 (d) th thu c 20,16 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 26,88 lt kh O2 (ktc), thu c 52,8 gam CO2 v y mol H2O. Gi tr ca y l A. 1,9 B. 2,1 C. 1,8. D. 1,6 Cu 29: Cho 3,78g Fe tc dng vi oxi thu c 4,26g hn hp A gm 4 cht rn. Ho tan ht A trong 500ml dd HNO3 x M thu c 0,84 lit NO (kc) v dd khng c NH4NO3. Tnh gi tr x? A. 0,12M B. 0,42M C. 0,21M D. 0,3M Cu 30: Cho cc phn ng ha hc sau: (I). C6H5CH(CH3)2
(1) +O2 (2) +H2 O;H 2SO4

(II). CH3CH2OH + CuO

t
o

(III). CH2=CH2 + O2

xt,t
o

(IV). CH3-C C-CH3 + H2O

o

HgSO4 ,t
o

(V). CH3-CH(OH)-CH3 + O2 (VII). CH3CHCl2 + NaOH

xt,t
o

(VI). CH CH + H2O

HgSO4 ,t to

(VIII). CH3COOCH=CH2 + KOH

102

C bao nhiu phn ng trn c th to ra anehit ?

A. 7

B. 4

C. 5

D. 3

Cu 31: Dy cc cht no sau y ch c lin kt cng ha tr trong phn t ? A. CaCl2, H2O, N2 B. K2O, SO2, H2S C. NH4Cl, CO2, H2S D. H2SO4, NH3, H2 Cu 32: Cho cc ha cht sau : (1) dung dch Fe2(SO4)3 ; (2) dung dch HCl v KNO3 ; (3) dung dch KNO3 v KOH ; (5) dung dch HCl ; (6) dung dch H2SO4 c, nng ; (7) Propan-1,2- iol; (8) dung dch HNO3 long. Hi c bao nhiu dung dch ha tan c Cu? A. 5 B. 4 C. 2 D. 3 Cu 33: Mt hn hp A (gm 0,1 mol Cu; 0,1 mol Ag; v 0,1 mol Fe2O3) em ha tan vo dung dch HCl d, sau phn ng thu c dung dch X v cht rn Y. Khi lng mui khan thu c khi c cn trong dung dch X v khi lng cht rn Y ln lt l: A. 32,5 gam v 17,2 gam B. 38, 9 gam v 10,8 gam C. 38,9 gam v 14,35 gam D. 32,5 gam v 10,8 gam Cu 34: Cho cc t sau: t axetat; t capron; t nitron; t visco; t nilon-6,6; t enang. Cc t thuc loi t tng hp l A. t capron; t nitron; t nilon-6,6; t enang. B. t capron; t visco; t nilon-6,6; t enang. C. t axetat; t capron; t nitron; t visco. D. t axetat; t capron; t nitron; t nilon-6,6. Cu 35: Cho s phn ng sau: X + H2SO4 (c, nng) Fe2(SO4)3 + SO2 + H2O. Trong s cc cht: Fe, FeCO3, FeO, Fe2O3, Fe3O4, Fe(OH)3, Fe(OH)2, FeS, FeS2 , Fe2(SO4)3 th s cht X tha mn s phn ng trn l: A. 7 B. 8 C. 5 D. 6 Cu 36: Hn hp X gm mt anehit v mt ankin c cng s nguyn t cacbon. t chy hon ton a (mol) hn hp X thu c 3a (mol) CO2 v 1,8a (mol) H2O. Cho 0,1 mol hn hp X tc dng c vi ti a 0,14 mol AgNO3 trong NH3 (iu kin thch hp). S mol ca anehit trong 0,1 mol hn hp X l A. 0,02. B. 0,08. C. 0,04. D. 0,03. Cu 37: Thc hin cc th nghim sau: (b) un nng NaCl tinh th vi H2SO4 (c). (a) Nung AgNO3 rn. (c) Sc kh SO2 vo dung dch NaHCO3. (d) Cho dung dch KHSO4 vo dd NaHCO3. (e) Cho CuS vo dung dch HCl (long). S th nghim sinh ra cht kh l A. 4. B. 2. C. 5. D. 3. Cu 38: Cho tng cht: C6H5NH2 (anilin), CH3-COOH v CH3-COOCH3 ln lt tc dng vi dung dch NaOH (t0) v vi dung dch HCl (t0). S phn ng xy ra l A. 6. B. 3. C. 5. D. 4. Cu 39: Cho 6,9 gam mt ancol, n chc phn ng vi CuO nung nng, thu c cht rn A v 9,3 gam hn hp X gm anehit, nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi lng d dung dch AgNO3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l A. 32,4 B. 64,8 C. 16,2 D. 24,3 Cu 40: Sau mt thi gian t in phn 200 ml dung dch CuSO4 (D = 1,25 g/ml) vi in cc tr, cng dng in 5A, nhn thy khi lng dung dch gim 8 gam. lm kt ta ht ion Cu2+ cn li trong dung dch sau in phn cn dng 100 ml dung dch H2S 0,5M. Nng phn trm ca dung dch CuSO4 ban u v gi tr ca t ln lt l A. 12% v 4012 giy B. 9,6% v 3860 giy C. 12% v 3860 giy D. 9,6% v 4396 giy II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Cho hn hp gm 2,7 gam Al v 8,4 gam Fe vo 200 ml dung dch cha Cu(NO3)2 1M v AgNO3 2M, sau khi cc phn ng xy ra hon ton thu c m gam kt ta. Gi tr m l: A. 34,4 gam B. 49,6 gam C. 54,4 gam D. 50,6 gam Cu 42: Cho bit c ti a bao nhiu cng thc cu to ancol no, mch h, bn v c 3 nguyn t cacbon trong phn t ? A. 6 B. 4 C. 5 D. 2 Cu 43: Trong cc cht: Fe3O4, HCl, FeSO4, Fe2(SO4)3, SO2. S cht c c tnh oxi ho v tnh kh l A. 4. B. 5. C. 2. D. 3. Cu 44: Cho dy cc kim loi kim: 11Na, 19K, 37Rb, 55Cs. Kim loi trong dy c nhit nng chy thp nht l A. Cs. B. Rb. C. Na. D. K. Cu 45: Cho Ankaien X thc hin phn ng cng vi Brom (t l mol 1:1) iu kin thch hp thu c sn phm c tn gi l 1,4-ibrom-2-metylbut-2-en. Tn gi ca ankaien X l A. 3-metylpenta-1,3-ien. B. 3-metylbuta-1,3-ien. C. 2-metylpenta-1,3-ien. D. 2-metylbuta-1,3-ien. Cu 46: Chia 7,8g hn hp gm C2H5OH v mt ancol cng dy ng ng thnh 2 phn bng nhau: 103

- Phn 1 cho tc dng vi Na d thu c 1,12 lt H2 (ktc). - Phn 2 cho tc dng vi 30 g CH3COOH, xc tc H2SO4 (). Bit hiu sut cc phn ng este u l 80%. Tng khi lng este thu c l: A. 10,2 gam. B. 8,8 gam. C. 8,1 gam. D. 6,48 gam. Cu 47: Ln men 360 gam glucoz trong iu kin thch hp (gi s ch c phn ng to thnh ancol etylic). Cho ton b lng kh CO2 sinh ra hp th ht vo dung dch NaOH, thu c 106 gam Na2CO3 v 168 gam NaHCO3. Hiu sut ca phn ng ln men glucz l A. 50% B. 62,5% C. 80% D. 75% Cu 48: Cho 0,15 mol - aminoaxit mch cacbon khng phn nhnh A phn ng va ht vi 150ml dung dch HCl 1M to 27,525gam mui. Mt khc, cho 44,1 gam A tc dng vi mt lng NaOH d to ra 57,3 gam mui khan. Cng thc cu to ca A l A. HOOC-CH2-CH(NH2)-COOH B. HOOC-CH2-CH2-CH(NH2)-COOH C. HOOC-CH2-CH2-CH2-CH(NH2)-COOH D. H2N- CH2-CH2-CH(NH2)-COOH Cu 49: Tin hnh 5 th nghim sau: - TN1: Nhng thanh st vo dung dch FeCl3. - TN2: Nhng thanh km vo dung dch CuSO4. - TN3: Cho thanh st tip xc vi thanh ng ri nhng vo dung dch HCl. - TN4: Nhng thanh nhm vo dung dch NaOH. - TN5: mt vt lm bng thp trong khng kh m. S trng hp xy ra n mn in ha l: A. 3 B. 2 C. 5 D. 4 Cu 50: Trong cu hnh electron ca nguyn t nguyn t X, tng s electron cc phn lp p l 7. S proton trong nguyn t Y t hn ca nguyn t X l 5. Vy tng s ht mang in c trong hp cht to bi nguyn t X v Y l: A. 50 B. 21 C. 100 D. 42 B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: un nng Butan - 2 - ol vi H2SO4 c 1700C, thu c cht hu c X. Cho X tc dng vi dung dch HBr c thu c cht hu c Y. un nng Y vi Mg trong ete khan thu c sn phm Z. (Trong X, Y, Z l cc sn phm chnh). Cng thc ca Z l B. CH3CH(MgBr)CH2CH3 A. CH3CH2CH2CH2OH C. CH3CH2CH2CH2MgBr D. CH3CH2CH(OH)CH3 Cu 52: Cho 39,5 gam hn hp X gm phenyl axetat v phenylamoni clorua tc dng va vi 400 ml dung dch NaOH 1M. Tnh khi lng mui khan thu c khi c cn dung dch sau phn ng ? A. 31,5 gam B. 38,4 gam C. 19,8 gam D. 50,1 gam Cu 53: Cho: E0(Cu2+/Cu)=0,34V; E0(Zn2+/Zn)=-0,76V. Kt lun no sau y khng ng? A. Cu2+ b Zn oxiho to thnh Cu. B. Cu2+ c tnh oxi ha mnh hn Zn2+. C. Phn ng xy ra trong pin l: Zn+Cu2+Zn2++Cu. D. Cu c tnh kh yu hn Zn. Cu 54: Cho 43,9 gam hn hp A gm Ni, Sn, Mg, Zn tc dng vi oxi d thu c 56,7 gam hn hp cc oxit. Mt khc cho 43,9 gam hh A tc dng dung dch H2SO4 long d c 13,44 lit kh H2 (ktc). Phn trm khi lng ca Sn trong hn hp l: A. 48,79% B. 27,11% C. 40,66% D. 54,21% Cu 55: Mt hn hp X gm sacaroz v mantoz. Thu phn hon ton hn hp X thu c glucoz v fructoz theo t l mol 4 : 1. Hi 17,1 gam hn hp X khi tc dng vi AgNO3 d trong NH3 th thu c ti a bao nhiu gam kt ta bc? A. 12,96 gam B. 4,32 gam C. 6,48 gam D. 10,8 gam Cu 56: Hai cht ng phn A, B (A c ly t ngun thin nhin) c cha 40,45%C, 7,86%H; 15,73% N v cn li l O. T khi hi ca cht lng so vi khng kh l 3,069. Khi phn ng vi NaOH, A cho mui C3H6O2NNa, cn B cho mui C2H4O2NNa. Nhn nh no di y l sai? A. A c tnh lng tnh nhng B ch c tnh baz B. A l alanin, B l metyl amino axetat. C. t0 thng A l cht lng, B l cht rn. D. A v B u tc dng vi HNO2 to kh N2. Cu 57: Hin tng xy ra khi cho dung dch KOH long vo dung dch K2Cr2O7 l: A. Khng c hin tng chuyn mu B. Xut hin kt ta trng C. Dung dch t mu vng chuyn sang mu da cam D. Dung dch t mu da cam chuyn sang mu vng Cu 58: X l hn hp gm cc kim loi: Al, Zn, Cu, Fe, Mg. Ha tan hon ton X trong dung dch HNO3 long d thu c dung dch A. Sc kh NH3 n d vo dung dch A thu c kt ta B. Nung B ngoi khng kh n khi lng khng i c cht rn C. Cho C vo ng s nung nng ri cho kh CO d i qua n phn ng hon ton c cht rn D. Cht rn D gm: 104

A. Al2O3, MgO, Zn, Fe B. Al2O3, MgO, Zn, Fe,Cu C. Al2O3, MgO, Fe D. MgO, Al, Zn, Fe, Cu Cu 59: Khi in phn dung dch CuSO4 vi anot bng Cu. Hin tng v qu trnh xy ra bn anot l: A. Khi lng anot gim, xy ra s kh Cu B. Khi lng anot khng thay i, xy ra s kh nc C. Khi lng anot gim, xy ra s oxi ha Cu D. Khi lng anot khng thay i, xy ra s oxi ha nc Cu 60: Cho s sau:
CH3OH / H 2SO4 H3O , t H 2SO4 c, t + HCN CH 3COCH 3 X Y Z (C4H 6O2 ) T.
+ 0 0

Cng thc cu to ca cht hu c T l A. CH2 = CHCOOCH3. C. CH3CH(OH)COOCH3.

B. CH3CH2COOCH3. D. CH2 = C(CH3)COOCH3.

1D 11C 21D 31D 41B 51B 5

2A 12C 22C 32B 42C 52A

3A 13D 23C 33B 43A 53A

4B 14B 24D 34A 44A 54D

5A 15D 25B 35D 45D 55C

6C 16A 26A 36A 46D 56C

7B 17A 27C 37A 47D 57D

8B 18B 28C 38D 48B 58C

9A 19B 29B 39B 49A 59C

10D 20C 30C 40B 50C 60D

I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1: Hn hp X gm 0,1 mol anlyl clorua; 0,3 mol benzyl bromua; 0,1 mol hexyl clorua; 0,15 mol phenyl bromua. un si X vi nc n khi phn ng xy ra hon ton, chit ly phn nc lc, ri cho tc dng vi dung dch AgNO3 d thu c m gam kt ta. Gi tr ca m l A. 57,4 B. 14,35 C. 70,75 D. 28,7 Cu 2: Cho 3,78 gam hn hp X gm CH2=CHCOOH, CH3COOH v CH2=CHCH2OH phn ng va vi dung dch cha 8 gam brom. Mt khc, trung ho 0,03 mol X cn dng va 20 ml dung dch NaOH 0,75M. Khi lng ca CH2=CHCOOH c trong 3,78 gam hn hp X l A. 0,72 gam B. 2,16 gam C. 1,08 gam D. 1,44 gam Cu 3: M l hn hp ca mt ancol no X v axit hu c n chc Y u mch h. t chy ht 0,4 mol hn hp M cn 30,24 lt O2 (ktc) va , thu c 52,8 gam CO2 v 19,8 gam H2O. Bit s nguyn t cacbon trong X v Y bng nhau. S mol ca Y ln hn s mol ca X. CTPT ca X, Y l A. C3H8O2 v C3H6O2 B. C3H8O2 v C3H2O2 C. C3H8O2 v C3H4O2 D. C4H8O2 v C4H4O2 Cu 4: Hn hp X gm axit HCOOH v CH3COOH c s mol bng nhau. Ly 5,3 g hn hp X cho tc dng vi 5,75 g C2H5OH (c H2SO4 c lm xc tc) thu c m (g) hn hp este (hiu sut cc phn ng este ha u bng 80%). Gi tr m l : A. 8,80 B. 8,10 C. 6,48 D. 7,04 Cu 5: Ho tan hon ton m gam bt Al vo 150 ml dung dch HCl 2M thu c dung dch X. Cho dung dch X tc dng vi 320 ml dung dch NaOH 1M thu c 4,68 gam kt ta. Tnh m? A. 2,7 gam B. 1,62 gam C. 2,16 gam D. 1,89 gam Cu 6: Oxi ha m gam ancol etylic mt thi gian thu c hn hp X. Chia X thnh 3 phn bng nhau: - Phn 1 tc dng va vi dung dch NaHCO3 thot ra 4,48 lt kh.- Phn 2 tc dng vi Na d thot ra 8,96 lt kh- Phn 3 tc dng vi dung dch AgNO3/NH3 d to thnh 21,6 gam Ag. Cc phn ng ca hn hp X xy ra hon ton. Th tch kh o ktc. Gi tr ca m v hiu sut phn ng oxi ha ancol etylic l A. 124,2 v 33,33% B. 82,8 v 50% C. 96,8 v 42,86% D. 96 v 60% Cu 7: Bit rng A tc dng vi dung dch NaOH, c cn dung dch sau phn ng thu c cht rn B v hn hp hi C. Chng ct C thu c D, D trng bc to sn phm E. E tc dng vi dung dch NaOH li thu c B. Cng thc cu to ca A l A. HCOOCH2CH=CH2 B. CH3COOCH=CH2 C. HCOOCH=CH-CH3 D. HCOOCH=CH2 105

Cu 8: Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng ca N trong X l 11,864%. C th iu ch ti a bao nhiu gam hn hp 3 kim loi t 14,61 gam X? A. 7,68 gam B. 3,36 gam C. 6,72 gam D. 10,56 gam Cu 9: Hn hp A gm 0,1 mol propenal v a mol kh hidro. Cho hn hp A qua ng s nung nng c cha Ni lm xc tc, thu c hn hp B gm propanal, propan-1-ol, propenal v 0,15 mol hidro. T khi hi ca hn hp B so vi metan bng 1,55. Gi tr ca a l A. 0,35 B. 0,3 C. 0,20 D. 0,25 Cu 10: Cho 2,7 gam Al tan hon ton trong dung dch HNO3 long, nng thu c kh 0,448 lt X duy nht (ktc). C cn dung dch thu c 22,7 gam cht rn khan. Vy cng thc ca kh X l: A. NO B. NO2 C. N2 D. N2O Cu 11: Cho a mol hp cht thm X phn ng va ht vi a lit dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na d thu c 22,4a lit H2 (ktc). Cng thc cu to thu gn ca X l A. HO-C6H4-COOH B. HO-CH2-C6H4OH C. CH3-C6H3(OH)2 D. HO-C6H4-COOCH3 Cu 12: Pht biu no sau y l sai? A. Na2CO3 l nguyn liu quan trng trong cng nghip sn xut thy tinh. B. nhit thng, tt c kim loi kim th u tc dng c vi nc. C. Nhm bn trong mi trng khng kh v nc l do c mng oxit Al2O3 bn vng bo v D. Theo chiu tng dn ca in tch ht nhn, nhit nng chy ca kim loi kim gim dn Cu 13: Cho phn ng: 2Al + 2H2O + 2OH- 2AlO-2 + 3H2. Cht oxi ha l: B. Al C. H2O D. H2O v OHA. OHCu 14: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm khi l: A. Mg, Ca, Ba B. Li , Na, Mg C. Na, K, Ba D. Na, K , Ca Cu 15: Ha tan 17 gam hn hp X gm K v Na vo nc c dung dch Y v 6,72 lt H2 (ktc). trung ha mt na dung dch Y cn dng dung dch hn hp H2SO4 v HCl (t l mol 1:2). Tng khi lng mui c to ra l: A. 42,05 gam B. 20,65 gam C. 21,025 gam D. 14,97 gam Cu 16: Trong s cc pht biu sau v anilin : (1) Anilin tan t trong nc nhng tan nhiu trong dung dch NaOH. (2) Anilin c tnh baz, dung dch anilin khng lm i mu qu tm. (3) Anilin dng sn xut phm nhum, dc phm, polime. (4) Anilin tham gia phn ng th brom vo nhn thm d hn benzen. Cc pht biu ng l A. (2), (3), (4) B. (1), (2), (3) C. (1), (2), (4) D. (1), (3), (4) Cu 17: t chy hon ton m gam hn hp gm anehit fomic, axit axetic, glucoz, glixerol thu c 29,12 lt CO2 (ktc) v 27 gam nc. Thnh phn phn trm khi lng ca glixerol trong hn hp ban u l: A. 23,4% B. 18,4% C. 43,8% D. 46,7% Cu 18: Cho hi nc i qua than nng , thu c 17,92 lt hn hp kh X (ktc) gm CO, CO2 v H2. Cho ton b X tc dng ht vi CuO (d) nung nng, thu c hn hp cht rn Y. Ha tan ton b Y bng dung dch HNO3 (long, d) c 8,96 lt NO (sn phm kh duy nht, ktc). Phn trm th tch kh CO trong X l: A. 28,57% B. 24,50% C. 14,28% D. 12,50% Cu 19: Cho 200 ml dung dch H3PO4 1M vo 250 ml dung dch hn hp NaOH 0,5M v KOH 1,5M. Sau khi phn ng hon ton thu c dung dch X. S gam mui c trong dung dch X l A. 36,6 gam B. 32,6 gam C. 40,2 gam D. 38,4 gam Cu 20: Ha tan ht 10,24 gam Cu bng 200 ml dung dch HNO3 3M c dung dch A. Thm 400 ml dung dch NaOH 1M vo dung dch A. Lc b kt ta, c cn dung dch ri nung cht rn n khi lng khng i thu c 26,44 gam cht rn. S mol HNO3 phn ng vi Cu l: A. 0,48 mol B. 0,58 mol C. 0,56 mol D. 0,4 mol Cu 21: Hn hp gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc, un nng c hn hp Y. Dn Y qua nc brom thy bnh nc brom tng 10,8 gam v thot ra 4,48 lit hn hp kh (ktc), c t khi so vi hidro l 8. Th tch kh O2 (ktc) va t chy hon ton hn hp Y l A. 33,6 lt B. 22,4 lit C. 26,88 lit D. 44,8 lit Cu 22: S iu ch PVC trong cng nghip hin nay l
2 A. C2H6 C2H5Cl C2H3Cl PVC

Cl

HCl

TH ,t , Pcao

1500 C HCl TH ,t , Pcao C2H2 C2H3Cl PVC Cl2 TH ,t , Pcao C. C2H4 C2H3Cl PVC Cl2 HCl TH ,t , Pcao D. C2H4 C2H4Cl2 C2H3Cl PVC
o

B. CH4

Cu 23: Trng hp no sau y thu c kt ta c khi lng ln nht ? A. Cho V(lt) dd HCl 2M vo V (lt) dd NaAlO2 1M B. Cho V(lt) dd AlCl3 1M vo V (lt) dd NaAlO2 1M C. Cho V(lt) dd NaOH 1M vo V (lt) dd AlCl3 1M 106

D. Cho V(lt) dd HCl 1M vo V (lt) dd NaAlO2 1M

Cu 24: Cho cc cn bng : H2(k) + I2(k) 2HI(k) (1) 2NO(k) + O2(k) 2NO2 (2) CO(k) +Cl2(k) COCl2(k) (3) N2 (k) + 3H2(k) 2NH3(k) (4) CaCO3 (r) CaO (r) + CO2(k) (5) Cc cn bng chuyn dch theo chiu thun khi tng p sut l: A. 1,2,3 B. 2,3,4 C. 1,3 D. 3,4,5 Cu 25: Cho hai mui X, Y tha mn iu kin sau: X + Y khng xy ra phn ng X + Cu khng xy ra phn ng Y + Cu khng xy ra phn ng X + Y + Cu xy ra phn ng X, Y l mui no di y? A. Fe(NO3)3 v NaHSO4. B. NaNO3 v NaHCO3. C. Mg(NO3)2 v KNO3. D. NaNO3 v NaHSO4. Cu 26: Tng s proton trong ht nhn nguyn t X v Y l 25. Y thuc nhm VIIA. iu kin thch hp n cht X tc dng vi Y. Kt lun no sau y ng? A. X l kim loi, Y l phi kim. B. trng thi c bn X c 2 electron c thn C. Cng thc oxit cao nht ca X l X2O D. Cng thc oxit cao nht ca Y l Y2O7 Cu 27: Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco, t nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l: A. 7 B. 4 C. 6 D. 5 Cu 28: Cho phng trnh ho hc: FeSO4 + KMnO4 + KHSO4 Fe2(SO4)3 + MnSO4 + K2SO4 + H2O. Tng h s ( s nguyn t, ti gin) ca cc cht c trong phng trnh phn ng l: A. 54 B. 52 C. 40 D. 48 Cu 29: Khi thu phn 1 peptit, ch thu c cc ipeptit Glu-His ; Asp-Glu ; Phe-Val v Val-Asp. Cu to peptit em thu phn l A. Phe-Val-Asp-Glu-His. B. His- Asp- Glu-Phe-Val-Asp-Glu. C. Asp-Glu-Phe-Val-Asp-Phe-Val-Asp. D. Glu-Phe-Val-Asp-Glu-His-Asp-Val-Asp. Cu 30: Pht biu no sau y khng ng? A. Trong mi phn t protit, cc aminoaxit c sp xp theo mt th t xc nh B. Phn t c hai nhm - CO-NH- c gi l ipeptit, ba nhm th c gi l tripeptit C. Cc peptit c t 10 n 50 n v amino axit cu thnh c gi l polipeptit D. Nhng hp cht hnh thnh bng cch ngng t hai hay nhiu -aminoaxit c gi l peptit Cu 31: Sc V lt CO2 (ktc) vo 200 ml dung dch X gm Ba(OH)2 1M v NaOH 1M. Sau phn ng thu c 19,7 gam kt ta, gi tr ln nht ca V l: A. 6,72 B. 8,96 C. 11,2 D. 13,44 Cu 32: Nhm cc cht u c kh nng tham gia phn ng trng gng l : A. Glucoz, axit fomic, anehit oxalic, mantoz. B. Glucoz, axit axetic, anehit oxalic, mantoz. C. Fructoz, axit fomic, anehit oxalic, saccaroz. D. Fructoz, axit fomic, formanehit, etylen glicol. Cu 33: Cho 1,82 gam hn hp bt X gm Cu v Ag (t l s mol tng ng 4 : 1) vo 30 ml dung dch gm H2SO4 0,5M v HNO3 2M, sau khi cc phn ng xy ra hon ton, thu c a mol kh NO (sn phm kh duy nht). Trn a mol NO trn vi 0,1 mol O2 thu c hn hp kh Y. Cho ton b Y tc dng vi H2O, thu c 150 ml dung dch c pH = z. Gi tr ca z l: A. 2 B. 3 C. 4 D. 1 Cu 34: Hp cht hu c A c cng thc phn t l C6H10O5. Khi A tc dng vi dung dch NaHCO3 v vi Na u thu c s mol kh bng s mol A phn ng. Mt khc, 0,1 mol A tc dng va vi 200ml dung dch KOH 1M. C cn dung dch sau phn ng thu c m gam mt mui khan duy nht. Cng thc ca A v gi tr ca m l A. HO-CH2CH2COOCH2CH2COOH; 25,6g B. HO-CH2CH2COOCH2CH2COOH; 23,8g C. HOOCCH2CHOHCH2CH2COOH; 23,8g D. HOOCCH2CHOHCH2CH2COOH; 25,6g Cu 35: Cho 400 ml dung dch E gm AlCl3 x mol/lt v Al2(SO4)3 y mol/lt tc dng vi 612 ml dung dch NaOH 1M, sau khi cc phn ng kt thc thu c 8,424 gam kt ta. Mt khc, khi cho 400 ml E tc dng vi dung dch BaCl2 (d) th thu c 33,552 gam kt ta. T l x : y l A. 3 : 4 B. 4 : 3 C. 3 : 2 D. 7 : 4

107

Cu 36: Hp th hon ton 2,24 lt CO2 ( ktc) vo 100 ml dung dch gm K2CO3 0,2M v KOH x mol/lit, sau khi cc phn ng xy ra hon ton thu c dung dch Y. Cho ton b Y tc dng vi dung dch BaCl2 d, thu c 11,82 gam kt ta. Gi tr ca x l: A. 1,4 B. 1,2 C. 1,0 D. 1,6 Cu 37: Cho s CH4 A1 A2 A3 A4 A5 CH4 C2H2 A6 A4 C2 H6O Bit A1, A4 u c kh nng phn ng c vi AgNO3 /NH3. A2, A5, A6 ln lt l : A. C4H4; CH3COONa; CH3COOC2H3. B. CH3COOH; C3H8; C2H4. C. CH3COONH4; CH3COONa; CH3CHO. D. C4H6; CH3COONa; CH3COOC2H3. Cu 38: Cho dy cc oxit sau: SO2, NO2, NO, SO3, P2O5, CO, N2O5, N2O. S oxit trong dy tc dng c vi H2O iu kin thng l: A. 5 B. 7 C. 8 D. 6 Cu 39: Thc hin cc th nghim vi hn hp gm Ag v Cu (hn hp X): (a) Cho X vo bnh cha mt lng d kh O3 ( iu kin thng) (b) Cho X vo mt lng d dung dch HNO3 (c) (c) Cho X vo mt lng d dung dch HCl (khng c mt O2) (d) Cho X vo mt lng d dung dch FeCl3 S th nghim m Cu b oxi ha cn Ag khng b oxi ha l: A. 1 B. 2 C. 3 D. 4 Cu 40: Thc hin cc th nghim sau: (a) Nung NH4NO3 rn. (b) un nng NaCl tinh th vi dung dch H2SO4 (c) (c) Sc kh Cl2 vo dung dch NaHCO3. (d) Sc kh CO2 vo dung dch Ca(OH)2 (d). (e)Sc kh SO2 vo dung dch KMnO4. (g) Cho dung dch KHSO4 vo dung dch NaHCO3. (h) Cho PbS vo dung dch HCl (long). (i) Cho Na2SO3 vo dung dch H2SO4 (d) , un nng. S th nghim sinh ra cht kh l: A. 2 B. 6 C. 5 D. 4 II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (phn A hoc B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: tch c CH3COOH t hn hp gm CH3COOH v C2H5OH ta dng ho cht no sau y? A. Na v dung dch HCl B. Ca(OH)2 v dung dch H2SO4 C. CuO (to) v AgNO3/NH3 d D. H2SO4 c Cu 42: Cho cn bng sau trong bnh kn: 2NO2 (k) N2O4 (k). (mu nu ) (khng mu) Bit khi h nhit ca bnh th mu nu nht dn. Phn ng thun c: A. H > 0, phn ng ta nhit B. H > 0, phn ng thu nhit C. H < 0, phn ng thu nhit D. H < 0, phn ng ta nhit Cu 43: C 4 cht X, Y, Z, T c cng thc phn t dng C2H2On (n 0) -X, Y, Z u tc dng c vi dung dch AgNO3/NH3 -Z, T tc dng c vi NaOH -X tc dng c vi nc Gi tr n ca X, Y, Z, T ln lt l A. 3,4,0,2 B. 4,0,3,2 C. 0,2,3,4 D. 2,0,3,4 Cu 44: Cho cc cht: Zn, Cl2, NaOH, NaCl, Cu, HCl, NH3, AgNO3. S cht tc dng c vi dung dch Fe(NO3)2 l A. 7 B. 6 C. 5 D. 4 Cu 45: Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO . Tn gi ca X l
3

A. metyl axetat. B. axit acrylic. C. phenol. D. anilin. Cu 46: Cho 11,6 gam mui FeCO3 tc dng vi dung dch HNO3 va , thu c hn hp kh cha CO2, NO v dung dch X. Cho dung dch H2SO4 d vo dung dch X c dung dch Y, dung dch Y ny ha tan c ti a m gam Cu, sinh ra sn phm kh NO duy nht. Gi tr ca m l: A. 32 gam B. 28,8 gam C. 3,2 gam D. 16 gam Cu 47: X v Y l kim loi trong s cc kim loi sau : Al, Fe, Ag, Cu, Na, Ca, Zn. - X tan trong dung dch HCl, dung dch HNO3 c ngui, dd NaOH m khng tan trong H2O. - Y khng tan trong dung dch NaOH, dung dch HCl, m tan trong dung dch AgNO3, dung dch HNO3 c ngui. X v Y ln lt l A. Al v Cu B. Na v Mg C. Ca v Ag D. Zn v Cu Cu 48: Mt hn hp X gm 2 amin k tip nhau trong dy ng ng amin no n chc. Ly 32,1 g hn hp cho vo 250 ml dung dch FeCl3(c d) thu c mt kt ta c khi lng bng khi lng hn hp trn. Loi b kt ta 108

ri thm t t dung dch AgNO3 vo n khi phn ng kt thc th phi dng 1,5 lit AgNO3 1M. Nng ban u ca FeCl3 l A. 1M B. 3M C. 2M D. 4M Cu 49: Mt hp cht thm c CTPT C7H8O. S ng phn tc dng c vi dung dch Br2 trong nc l: A. 4 B. 5 C. 6 D. 3 Cu 50: t chy hon ton m gam hn hp X gm 2 ancol A v B thuc cng dy ng ng thu c 6,72 lt CO2 v 7,65 gam nc. Mt khc khi cho m gam hn hp X tc dng vi Na d thu c 2,8 lt hiro. Bit t khi hi ca mi cht so vi hiro u nh hn 40, cc th tch kh o ktc. A v B c cng thc phn t ln lt l A. CH4O v C2H6O B. C2H6O v C3H8O C. C2H6O2 v C3H8O2 D. C3H8O2 v C4H10O2 B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho phn ng: Na2SO3 + KMnO4 + NaHSO4 Na2SO4 + MnSO4 + K2SO4 + H2O. Tng h s ca cc cht (l nhng s nguyn, ti gin) trong phng trnh phn ng l A. 47 B. 27 C. 31 D. 23 Cu 52: Hn hp A gm 0,1 mol anehit metacrylic v 0,3 mol kh hiro. Nung nng hn hp A mt thi gian, c mt cht xc tc Ni, thu c hn hp hi B gm hn hp cc ancol, cc anehit v hiro. T khi hi ca B so vi He bng 95/12. Hiu sut ca phn ng hiro ha anehit metacrylic l: A. 100% B. 70% C. 65% D. 80% Cu 53: Dn 4 gam hi ancol n chc qua CuO nung nng c 5,6 gam hn hp hi gm anhit, ru d v nc. Hiu sut oxi ha A t : A. 75 %. B. 85 % C. 80 % D. 90 % Cu 54: Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n mn in ho xy ra khi nhng hp kim Zn-Cu vo dung dch HCl c c im l: A. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi. B. Phn ng xy ra lun km theo s pht sinh dng in. C. u sinh ra Cu cc m. D. Phn ng cc dng u l s oxi ho Cl . Cu 55: Cho m gam hn hp X gm Cu v Fe3O4 tan va ht trong dung dch HCl 20%, thu c dung dch Y (ch cha 2 mui). Nng phn trm ca FeCl2 trong dung dch Y l A. 21,697% B. 20,535% C. 14,464% D. 23,256% Cu 56: Cho m gam Mg vo dung dch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c 3,36 gam cht rn. Gi tr ca m l A. 2,88. B. 2,16. C. 4,32. D. 5,04. Cu 57: Tc nhn ch yu gy ma axit l A. CO v CH4. B. CO v CO2. C. SO2 v NO2. D. CH4 v NH3. Cu 58: Cho mt ancol n chc X phn ng vi HBr c xc tc thu c cht hu c Y cha C, H, Br trong % khi lng Br trong Y l 69,56%. Bit MY < 260 vC. Cng thc phn t ca ancol X l: B. C4H7OH C. C5H9OH D. C5H11OH A. C5H7OH Cu 59: Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l A. 4. B. 5. C. 3. D. 6. Cu 60: Cho cc cht sau: axit glutamic; valin, lysin, alanin, trimetylamin, anilin. S cht lm qu tm chuyn mu hng, mu xanh, khng i mu ln lt l A. 2,1,3. B. 1, 2, 3. C. 3, 1, 2. D. 1, 1, 4.

1 2 3 4 5 6 7 8 9 10

C D C C C B B A B D

11 12 13 14 15 16 17 18 19 20

B B C C C A D D A C

21 22 23 24 25 26 27 28 29 30

A D B B D B D B A B

31 32 33 34 35 36 37 38 39 40 109

C A D A D A D A A C

41 42 43 44 45 46 47 48 49 50

B D C B C A D C A C

51 52 53 54 55 56 57 58 59 60

B D C A A A C C A B

 6 Cu 1. Cho 17,94 gam hn hp X gm Fe, Fe3O4 tc dng vi 320ml dung dch HNO3 a (mol/lt). Sau khi phn ng xy ra hon ton thu c 2,24 lt kh NO duy nht (ktc), dung dch B v 0,9 gam kim loi. Khi lng mui trong B v gi tr ca a l A). 48,60g v 2M B). 38,50g v 2,4M C). 65,34g v 1,6M D). 54,92g v 1,2M Cu 2. in phn dung dch hn hp cha 7,45 gam KCl v 28,2 gam Cu(NO3)2 ( in cc tr c mng ngn ) n khi khi lng dung dch gim 10,75 gam th ngt mch . Dung dch sau khi in phn cha nhng cht g sau y: B). KNO3 v Cu(NO3)2 cn d , HNO3. A). KNO3 va KOH C). KNO3 v Cu(NO3)2 cn d D). KNO3 v KCl d Cu 3. Hn hp X gm vinyl axetat, metyl acrylat v metyl axetat. t chy hon ton 3,32 gam X, thu c 3,36 lt CO2 (ktc). Phn trm s mol ca metyl axetat trong X l A). 27,92%. B). 25%. C). 75%. D). 72,08%. Cu 4. So snh bn knh nguyn t v ion sau: Mg ; O2- ; S ; P ; K+ ; Al3+. A). Mg > P > S > K+ > O2- > Al3+. B). K+ > Mg > P > Al3+ > S > O2-. 3+ + 2D). P > Al3+ > S > K+ > Mg > O2-. C). Al > S > K > Mg > O > P. Cu 5. Cho hh A gm 0,15 mol Mg v 0,35 mol Fe p vi V lt dd HNO3 1 M thu c dd B v hh C gm 0,05 mol N2O ; 0,1 mol NO v cn li 2,8 gam kim loi . Gi tr ca V l : A). 1,22 B). 1,1 C). 1,15 D). 0,9 Cu 6. Mt hp cht c cng thc MX. Tng s cc ht trong hp cht l 84, trong s ht mang in nhiu hn s ht khng mang in l 28. Nguyn t khi ca X ln hn ca M l 8. Tng s cc ht trong X2- nhiu hn trong M2+ l 16. Cng thc MX l: A). CaO B). MgO C). CaS D). MgS Cu 7. Ho tan hon ton 13,200 gam hn hp Na v K vo nc thu c dung dch X v 4,48 lt kh H2 (ktc). Cho 5,200 gam hn hp gm Mg v Fe tc dng ht vi dung dch HCl thu c dung dch Y cha m gam mui v 3,36 lt kh H2 (ktc). Cho X tc dng vi Y ( khng c oxi)n khi phn ng hon ton thu c x gam kt ta. Gi tr ca m v x l. A). 25,167 v 22,235 B). 10,525 v 12,000. C). 9,580 v 14,875. D). 15,850 v10,300. Cu 8. Hn hp X gm hai axit no. t chy hon ton 0,3mol X thu c 11,2lit kh CO2 (ktc). trung ho 0,3mol X cn 500ml dung dch NaOH 1M. Cng thc cu to ca hai axit l? A). CH3 - COOH v CH3 - CH2 - COOH B). H- COOH v CH3 - CH2 COOH C). CH3 - COOH v HOOC - CH2 COOH D). H- COOH v HOOC - COOH Cu 9. Ion R3+ c cu hnh electron phn lp ngoi cng l 3d5. V tr ca R trong bng tun hon l: A). Chu k 3 nhm VIIIB B). Chu k 4, nhm IIB C). Chu k 4, nhm VIIB D). Chu k 4 nhm VIIIB Cu 10. Cng thc ho hc ca supephotphat kp l: A). Ca(H2PO4)2 v CaSO4. B). Ca3(PO4)2. C). CaHPO4. D). Ca(H2PO4)2. Cu 11. Hn hp X gm Fe(NO3)2, Cu(NO3)2 v AgNO3. Thnh phn % khi lng ca nit trong X l 11,864%. C th iu ch c ti a bao nhiu gam hn hp ba kim loi t 14,16 gam X? A). 10,56 gam. B). 7,68 gam. C). 3,36 gam. D). 6,72 gam. Cu 12. C 4 dung dch ring bit: X (HCl), Y (CuCl2), Z (FeCl3), T (HCl c ln CuCl2). Nhng vo mi dung dch mt thanh st nguyn cht. S trng hp n mn in ho l A). 1 B). 3 C). 2. D). 0 Cu 13. Hn hp X gm 1 hirocacbon th kh v H2 c t khi so vi H2 bng 4,8. Cho X i qua Ni nung nng n khi phn ng xy ra hon ton thu c hn Y c t khi so vi CH4 bng 1. Cng thc phn t ca hirocacbon trong hn hp X l? A). C2H2. B). C3H4. C). C2H4. D). C3H6. Cu 14. Thu phn hon ton 1 mol pentapeptit A th thu c 3 mol glyxin; 1 mol alanin v 1mol valin. Khi thu phn khng hon ton A th trong hn hp sn phm thy c cc ipeptit Ala-Gly; Gly-Ala v tripeptit Gly-Gly-Val. Amino axit u N, amino axit u C pentapeptit A ln lt l A). Gly, Val. B). Ala, Val. C). Gly, Gly. D). Ala, Gly. Cu 15. C 4 cht ng vi 4 cng thc phn t C3H6O ; C3H6O2 ; C3H4O v C3H4O2 c k hiu ngu nhin l X, Y, Z, T. Thc hin cc phn ng nhn thy: X, Z cho phn ng trng gng; Y, T phn ng c vi NaOH; T phn ng vi H2 to thnh Y; Oxi ho Z thu c T. Cng thc cu to ng ca X, Y, Z, T ln lt l: A). X: C2H5CHO ; Y : C2H5COOH ; Z : CH2=CH-CHO; T : CH2=CH-COOH B). X: CH2=CH-COOH ; Y : C2H5CHO ; Z : C2H5COOH; T : CH2=CH-CHO C). X: C2H5COOH ; Y : C2H5CHO ; Z : CH2=CH-CHO; T : CH2=CH-COOH D). X: C2H5COOH ; Y : C2H5CHO ; Z : CH2=CH-COOH ; T : CH2=CH-CHO 110

Cu 16. Dn 2,24 lt hn hp kh X gm C2H2 v H2 (c t l th tch V(C2H2) ; V(H2) = 2 : 3 ) i qua Ni nung nng thu c hn hp Y, cho Y i qua dung dch Br2 d thu c 896ml hn hp kh Z bay ra khi bnh dung dch Br2. T khi ca Z i vi H2 bng 4,5. Bit cc kh u o ktc. Khi lng bnh Br2 tng thm l : A). 0,6 gam B). 0,8gam C). 1,6gam D). 0,4 gam Cu 17. Trong cc cht sau: (X1): 1,2 - iCloeten; (X2): buten-2; (X3): anehit acrylic; (X4): metylmetacrylat v (X5): axit oleic. Nhng cht no c ng phn hnh hc? Chn kt lun ng: B). (X2); (X3); (X5) C). (X1); (X2); (X3) D). (X1); (X2); (X5) A). (X1); (X3); (X5) Cu 18. Cho mt mu hp kim Na,Ba ,K tc dng vi nc (d) thu c dung dch X v 3,36 lt H2 ( ktc). Th tch dung dch axit H2SO4 2,5M cn dng trung ha dung dch X l A). 30 ml B). 60 ml C). 75 ml D). 150 ml Cu 19. Cho 0,4 mol hn hp X gm 2 ancol no, n chc, bc 1, l ng ng k tip un nng vi H2SO4 c 140oC thu c 7,704 gam hn hp 3 ete. Tham gia phn ng ete ho c 50% lng ancol c khi lng phn t nh v 40% lng ancol c khi lng phn t ln. Tn gi ca 2 ancol trong X l A). pentan-1-ol v butan-1-ol. B). propan-1-ol v butan-1-ol. C). etanol v propan-1-ol. D). metanol v etanol. Cu 20. Cho cc th nghim sau : 1) un si dung dch gm cc mui NaHCO3 v CaCl2; 2) Nh dung dch AlCl3 ti d vo dung dch NaOH; 3) Sc kh CO2 ti d vo dung dch NaAlO2; 4) Nh dung dch NH3 ti d vo dung dch AlCl3; 5) Sc kh CO2 ti d vo dung dch Ba(OH)2; 6) Nh dung dch KOH ti d vo dung dch MgSO4. Sau kh kt thc th nghim, s trng hp c kt ta l: A). 5. B). 6 C). 4 D). 3 Cu 21. Cho dy cc cht: natri axetat, phenylamoni clorua, natri phenolat, saccaroz, axit aminoaxetic, tristearin. S cht trong dy c phn ng khi cho tc dng vi dung dch HCl long, un nng l A). 5. B). 6. C). 3. D). 4. Cu 22. Cho X c CTPT C4H6O. Bit : - X phn ng Na theo t l mol 1 : 2 cho ra kh H2. - X phn ng C2H5OH , AgNO3/NH3 CTPT ca X l : A). CH2 = C = CH -CH2OH B). CH3- C C - CH2OH C). CH C - CH2 - O - CH3. D). CH C - CH2CH2OH Cu 23. Thc hin phn ng este ho gia axit axetic v hn hp gm 8,4 gam 3 ancol l ng ng ca ancol etylic. Sau phn ng thu c 16,8 gam 3 este. Ly sn phm ca phn ng este ho trn thc hin phn ng x phng ho vi dung dch NaOH 4 M th thu c m gam mui: (Gi s hiu sut phn ng este ho l 100%). Gi tr ca m l A). 10,0gam B). 16,4gam C). 8,0gam D). 20,0gam Cu 24. Thc hin phn ng nhit phn cc cht: CaCO3, NaHCO3, NH4NO2, NH4NO3, KMnO4, KClO3, Ca(ClO)2, Cu(NO3)2, AgNO3, Fe(OH)3. S phn ng oxi ho kh l: A). 10 B). 8 C). 7 D). 5 Cu 25. Cht hu c X mch h, tn ti dng trans c cng thc phn t C4H8O, X lm mt mu dung dch Br2 v tc dng vi Na gii phng kh H2. X ng vi cng thc phn t no sau y? A). CH2=CHCH2CH2OH. B). CH3CH2CH=CHOH. C). CH3CH=CHCH2OH. D). CH2=C(CH3)CH2OH Cu 26. Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2(anilin), C6H5OH (phenol), C6H6 (benzen), CH3CHO. S cht trong dy lm mt mu dung dch brom l A). 6 B). 5 C). 8 D). 7 Cu 27. Khi thu phn 0,1mol este A c to bi mt ancol a chc vi mt axit cacboxylic n chc cn dng va 12gam NaOH. Mt khc thu phn 6,35gam A cn dng 3gam NaOH v thu c 7,05gam mui. Cng thc ca A l: A). (HCOO)3C3H5. B). (CH3COO)2C2H4. D). (CH3COO)3C3H5. C). (C2H3COO)3C3H5. Cu 28. C 6 l mt nhn ng 6 cht lng sau: dung dch glucoz, dung dch HCOOH, dung dch CH3COOH, ancol etylic, glixerol, dung dch CH3CHO. Ch dng thm 2 thuc th no di y nhn bit c 6 l trn dung dch trn r nht ? A). Qi tm, Cu(OH)2. B). Cu(OH)2, Na2SO4. C). AgNO3 trong dung dch NH3, qu tm. D). AgNO3 trong dung dch NH3, Cu(OH)2. Cu 29. Mnh no sau y khng ng. A). Cc nguyn t kim loi kim th u tc dng vi nc gii phng H2. B). m in ca cc kiem loi kim gim dn t Li n Cs. C). Nng lng ion ha I1 ca kim loi kim gim dn t Li n Cs. D). Cc kim loi Na, K , Ba u tc dng vi dd HCl gii phng H2. Cu 30. Cho hn hp X gm (K, Al) nng 10,5 gam. Ha tan hon ton X trong nc c dung dch Y. Thm t t dung dch HCl 1M vo Y nhn thy khi thm c 100 ml th bt u c kt ta, v khi thm V ml na th thu c 3,9 gam kt ta trng keo. Gi tr ca V v phn trm khi lng K trong X l: A). 150 ml hoc 250 ml v 74,29 % B). 50 ml hoc 250 ml v 74,29 % C). 150 ml hoc 350 ml v 66,67 % D). 50 ml hoc 350 ml v 66,67 % Cu 31. Cho m gam hn hp gm bt ca hai kim loi X, Y vo dung dch CuSO4 (d). Kt thc phn ng thu c m gam cht rn. Hai kim loi X, Y c th l : A). Zn v Pb. B). Fe v Cu. C). Mg v Fe. D). Zn v Fe. 111

Cu 32. Mt loi nc cng c cha cc ion : Ca2+, Mg2+, Cl, HCO3; trong tng nng ca Cl v HCO3 l 0,016M. Hy cho bit cn ly bao nhiu ml dung dch Na2CO3 0,2 M bin 1 lt nc cng thnh nc mm (coi nh cc cht kt ta hon ton). A). 20 ml. B). 40 ml. C). 80 ml. D). 60 ml. Cu 33. Sc V lt CO2 (ktc) vo 200 ml dung dch X gm Ba(OH)2 1M v NaOH 1M. Sau phn ng thu c 19,7 gam kt ta, gi tr ln nht ca V l: A). 13,44 B). 11,2 C). 6,72 D). 8,96 Cu 34. Ho tan hon ton 33,8 gam hn hp gm FeCl2 v NaF (c cng s mol) vo mt lng nc d, thu c dung dch X. Cho dung dch AgNO3 d vo X, sau khi phn ng xy ra hon ton thu c m gam cht rn. Gi tr ca m l: A). 104,5 gam B). 79 gam C). 82,8 gam D). 57,4 gam Cu 35. Nc cng khng gy ra tc hi no di y ? A). Lm mt tnh ty ra ca x phng, lm h hi qun o. B). Lm hng cc dung dch pha ch. Lm thc phm lu chn v gim mi v thc phm. C). Gy hao tn nhin liu v khng an ton cho cc ni hi, lm tc cc ng ng dn nc. D). Gy ng c nc ung. Cu 36. Cho 3,2 gam Cu tc dng vi 100 ml dung dch hn hp HNO3 0,8M v H2SO4 0,2M, sn phm kh duy nht l kh NO. S gam mui khan thu c khi c cn dung dch sau phn ng l: A). 7,90 B). 5,64 C). 8,84 D). 10,08 Cu 37. t chy hon ton 29,6 gam hn hp X gm CH3COOH,CxHyCOOH,v (COOH)2 thu c 14,4 gam H2O v m gam CO2. Mt khc, 29,6 gam hn hp X phn ng hon ton vi NaHCO3 d thu c 11,2 lt (ktc) kh CO2.Tnh m: A). 48,4 gam B). 44 gam C). 52,8 gam D). 33 gam

X + H2O; Cu 38. Cho cc phn ng ha hc sau : 1) H2S + O2 (thiu)

2) NH3 + O2
,t xt Y + H2O;
o

3) PH3 + O2

Z + H2O
H 2O
+ Br2 ( dd )

Cc cht X, Y, Z ln lt l : D). SO2, N2, H3PO4.

A). S, NO, H3PO4.

B). SO2, N2, P2O5.

C). S, NO, P2O5.

Y CH3-C(CH3)Br-CHBr-CH3; Oxi ha Cu 39. Ancol X c cng thc C5H11OH. Bit : X X bi CuO un nng thu c sn phm khng c kh nng phn ng vi dung dch AgNO3/NH3. Tn gi ca X l: A). 3-metylbutan-2-ol. B). 3-metylbutan-1-ol. C). 2-metylbutan-2-ol. D). 2-metylbutan-3ol. Cu 40. Cht (Y) c cng thc phn t C3H9NO2, d phn ng vi axit v baz. Trn 1,365 gam (Y) vi 100ml dung dch NaOH 0,2M ri un nng nh, c kh thot ra lm xanh giy qu tm m v dung dch (A), c cn dung dch (A) thu c a gam cht rn. Gi tr ca a l: A). 1,43 gam B). 1,66 gam C). 2,30 gam D). 1, 25 gam Cu 41. Cho cc cht sau : benzyl axetat, vinyl axetat, triolein, phenyl axetat, metyl acrylat. S cht tc dng vi dung dch NaOH to ra ancol l A). 5. B). 2. C). 4 D). 3 Cu 42. Hn hp gm hai anhit n chc X v Y c chia thnh hai phn bng nhau: - Phn 1: un nng vi dd AgNO3/NH3 d th to ra 10,8 gam Ag. - Phn 2: oxi ha to thnh hai axit tng ng, sau cho hai axit ny phn ng vi 250 ml dung dch NaOH 0,26M c dung dch Z. trung ha lng NaOH d trong dung dch Z cn dng ng 100 ml dung dch HCl 0,25M. C cn dung dch Z ri em t chy cht rn thu c sau khi c cn, c 3,52 gam CO2 v 0,9 gam H2O. Cng thc phn t ca hai anhit X v Y l: A). HCHO v C2H3CHO B). HCHO v C2H5CHO. C). CH3CHO v C2H5CHO. D). HCHO v CH3CHO Cu 43. Cho m gam Fe vo dung dch cha ng thi H2SO4 v HNO3 thu c dung dch X v 4,48 lt NO(duy nht). Thm tip H2SO4 vo X th li thu c thm 1,792 lt kh NO duy nht na v dung dch Y. Dung dch Y ho tan va ht 8,32 gam Cu khng c kh bay ra (cc kh o ktc). Khi lng ca Fe cho vo l A). 11,2 g. B). 9,6 g. C). 16,8 g D). 16,24 g. Cu 44. Cho 2,16 gam bt Al vo dung dch cha hn hp CuCl2 0,12 mol v FeCl3 0,06 mol sau khi phn ng xy ra hon ton c cht rn A . Khi lng cht rn A l A). 1,12 g B). 7,68g C). 5,76g D). 5,28g Cu 45. Cho cn bng sau : N2 + 3H2 2NH3; = 92(kJ) . Pht biu no sau y ng ?
A). Khi gim nhit v thm xc tc, cn bng chuyn dch theo chiu ngch. B). Khi tng p sut v tng nhit , cn bng chuyn dch theo chiu ngch. C). Khi tng p sut v gim nhit , cn bng chuyn dch theo chiu thun. D). Khi tng nhit v thm N2, cn bng chuyn dch theo chiu thun. 112

Cu 46. Trong cc th nghim sau: (1) Cho H2S tc dng vi SO2; (2) Cho dung dch H2O2 tc dng vi dung dch KI; (3) Cho nc Gia-ven tc dng vi dung dch HCl; (4) Cho kh F2 qua nc nng; (5) Cho hi nc i qua than nng ; (6) t kim loi Mg trong kh CO2; (7) un dung dch gm axit fomic v axit sunfuric c. S th nghim to ra n cht l A). 5 B). 4 C). 7 D). 6. Cu 47. Dy cc cht u lm mt mu dung dch thuc tm l A). Xiclobutan, but-1-in, m-xilen, axit axetic B). Etilen, axetilen, anehit fomic, toluen C). Benzen, but-1-en, axit fomic, p-xilen D). Axeton, etilen, anehit axetic, cumen Cu 48. Mt cht hu c X c CTPT l C4H11NO2. Cho X tc dng hon ton vi 100ml dung dch NaOH 2M, sau phn ng thu c dung dch X v 2,24 lt kh Y (ktc). Nu trn lng kh Y ny vi 3,36 lt H2 (ktc) th c hn hp kh c t khi so vi H2 l 9,6. Hi khi c cn dung dch X th thu c bao nhiu gam cht rn khan? A). 12,2 gam B). 8,2 gam C). 8,6 gam D). 8,62 gam Cu 49. Cho cc polime sau: t nilon-6,6; poli(vinyl clorua); thy tinh plexiglas; teflon; nha novolac; t visco, t nitron, cao su buna. Trong , s polime c iu ch bng phn ng trng hp l: A). 6 B). 5 C). 7 D). 4 Cu 50. Mt ancol X bc 1 mch h (c th no hoc cha mt lin kt i) c CTPT l CxH10O. Ly 0,01 mol X v 0,02 mol CH3OH trn vi 0,1 mol Oxi ri t chy hon ton 2 ancol nhn thy sau phn ng c Oxi cn d. CTPT ca X l: B). C5H10O. C). C8H10O. D). C4H10O. A). C6H10O5.

1A 11D 21A 31D 41B

2B 12C 22D 32B 42A

3B 13B 23B 33B 43D

4A 14A 24C 34B 44B

5C 155 25C 35D 45C

6D 16B 26A 36A 46D

7D 17D 27C 37B 47B

8D 18B 28A 38C 48A

9D 19C 29A 39A 49B

10D 20A 30B 40A 50D

7 I. PHN CHUNG CHO TT C TH SINH (40 cu , t cu 1 n cu 40) 1/ Ho tan hon ton 7,020 gam hn hp CaCO v MgCO vo dung dch HCl d thy thot ra V lt kh ( ktc).
3 3

Dung dch thu c em c cn, c 7,845 gam mui khan. Gi tr ca V l a. 1,232 lt b. 1,344 lt c. 1,568 lt d. 1,680 lt 2/ Trn ln 100ml dung dch Ba(OH) 1M vi 100ml dung dch Al (SO ) 0,2M, khuy u cho phn ng xy ra
2 2 4 3

hon ton thu c x gam kt ta v dung dch A. Sc CO d vo A thu c y gam kt ta. Gi tr ca x v y tng
2

ng l a. 13,98 v 7,06. b. 23,3 v 7,06. c. 23,3 v 3,12. d. 13,98 v 3,12. 3/ Ho tan hon ton hn hp 0,12 mol FeS v a mol Cu S bng dung dch HNO va , thu c dung dch X (ch
2 2 3

cha 2 mui sunfat) v kh NO (sn phm kh duy nht). Gi tr ca a l a. 0,06 b. 0,12 c. 0,04 d. 0,075 4/ Cho 15,0 gam mt aminoaxit X c mt nhm amino v mt nhm cacboxyl tc dng vi dung dch NaOH thu c dung dch Y. C cn Y c 19,4 gam mui khan. X l b. H NC H COOH. a. H NCH COOH.
2 2 2 2 2 2 4 4 8

c.

H NC H COOH.
3 6

d.

H NC H COOH

5/ Ho tan 23,6 gam hn hp gm 2 axit cacboxylic vo nc thu c dung dch A. Chia A thnh hai phn bng nhau. Phn 1: Cho tc dng vi dung dch AgNO /NH d, thu c 21,6 gam Ag.
3 3

Phn 2: c trung ho hon ton bi 200ml dung dch NaOH 1M. Hai axit l a. axit fomic v axit acrylic. b. axit fomic v axit propionic. c. axit fomic v axit oxalic. d. axit axtic v axit fomic. 6/ Cho 6,72 gam Fe vo dung dch c 0,4 mol HNO (gi thit NO l sn phm kh duy nht). Sau khi phn ng
3

hon ton, phn dung dch c s gam mui tan l a. 29,04 b. 24,2 113

c. 25,32

d. 21,6

7/ un hn hp gm 0,3 mol Al v 0,3 mol S trong mi trng khng c khng kh. Hn hp thu c em ho tan bng dung dch HCl d thu c hn hp kh A (khng cn cht rn khng tan). Khi lng mol trung bnh ca hn hp A l a. 18,0 b. 23,3 c. 22,4 d. 25,5 8/ Nung hn hp A gm 0,15mol Cu v x mol Fe trong khng kh mt thi gian, thu c 63,2 gam hn hp B gm hai kim loi d v hn hp cc oxit ca chng. Ho tan ht lng hn hp B trn bng dung dch H SO c nng d
2 4

th thu c 0,3mol SO (sn phm kh duy nht). x c gi tr l

2

a. 0,7 mol. b. 0,6 mol. 9/ Cho cc ancol n chc sau: CH OH (1);

3 3 2

b. 0,4 mol. (CH ) C-OH (2); (CH ) C-CH -OH (3);

3 3 3 3 2 2 4

d. 0,5 mol.

(CH ) CH-OH (4). Nhng ancol khng b tch nc ni phn t khi un nng vi H SO c, 1700C to anken l a. (1) ; (2) v (3) 10/ Trong cng
+ C2H 4 ,xt

b. (1) v (3) nghip, iu

xt,t 0

ch

c. (1) v (4) Stiren ngi ta

thc

hin

d. (2) v (3) theo s

Benzen C6H5C2H5 Stiren . T 1,0 tn benzen cn ti thiu bao nhiu m3 (ktc) etilen v thu c bao nhiu kg Stiren. Bit hiu sut ca mi giai on phn ng u t 80% a. 229,6m3 etilen v 1606,6 kg Stiren. b. 229,6m3 etilen v 835,33 kg Stiren. d. 287,2m3 etilen v 853,33kg Stiren. c. 287,2m3 etilen v 1066,6 kg Stiren. 11/ Cho hn hp X gm hai kim loi kim tan ht trong 200ml dung dch cha BaCl 0,3M v Ba(HCO ) 0,8M thu
2 3 2

c 2,8 lt H ( ktc) v m gam kt ta. Gi tr ca m l

2

a. 43,34 b. 49,25 c. 31,52 d. 39,4 12/ Axit lactic (CH - CH(OH) - COOH) c th tc dng c vi tt c cc cht trong dy no sau y ?
3

a. Na, Na CO , K SO , CH COOH.
2 3 2 4 3

b. Na O, NaHCO , C H OH, HBr.

2 3 2 5

c. CH NH , HCl, CaSO .
3 2 4

d. CH OH, H , NaOH, Br .
3 2 2 2

13/ Cho hn hp X gm 2 axit hu c no. t chy hon ton a mol hn hp X thu c a mol H O. Mt khc, cho a mol hn hp X tc dng vi NaHCO thu c 1,4a mol CO . % khi lng ca axt c khi lng phn t nh hn
3 2

trong hn hp X l a. 27,3%.
3 2

b. 35,8%.
2 2

c. 25,4%.
KOH,etanol,t
0

d. 43,4%.
0

14/ Cho s sau: (CH ) CH-CH -CH Cl D

NaOH, H2O, t E.
0

HCl HCl KOH,etanol,t B C

Cc cht trn s l sn phm chnh. E c cng thc cu to l a. (CH ) CH - CH(OH)CH . b.(CH ) CH - CH CH OH.
3 2 3 2 3 3 2 2 2

c.

(CH ) C(OH) - CH - CH .
2 3 4

d.(CH ) C = CHCH
3 2 2 4

3.

15/ Cho cc cht sau:

KMnO , KCl, Al, dd H SO c, dd NaOH. C th iu ch trc tip c (nhiu nht) cc

kh no bng cch trn cc cht vi nhau hoc nhit phn cc cht a. O , Cl , H , SO , HCl. b. O , H , SO .
2 2 2 2 2 2 2 2

c. O , HCl, SO

d. Cl , H , SO , Cl O.
2 2 2 2 3

16/ Ho tan hon ton 2,16g Mg bng dung dch HNO d, thy thot ra 0,896 lt kh NO (ktc) v dung dch X. C cn dung dch X thu c lng mui khan l a. 6,52 gam. b.8,88 gam. c.13,32 gam. d. 13,92 gam. 17/ Cho cc nhn xt sau: 1) Sc Ozon vo dung dch KI s thu c dung dch c kh nng lm h tinh bt ho xanh. 2) Hiro peoxit v hiro sunfua c th lm mt mu dung dch thuc tm trong mi trng H SO long.
2 4

3) Sc hiro sunfua vo dung dch FeCl s thy xut hin vn c mu vng.

3

4) Dung dch H S lu trong khng kh s c vn c mu vng.

2

5) Hiro peoxit l cht kh mnh v khng c tnh oxi ho Cc nhn xt ng l a. 1, 2, 3, 4. b. 2, 4, 5. 18/ iu no sau y sai ? a. Cho propen hp nc (xc tc H+, t0) thu c 2 ancol. b. ng vi cng thc phn t C H c ba anken.
4 8

c. 1, 2, 4, 5.

d. 1, 3, 4.

114

c. d.

Tch mt phn t H t butan thu c 3 anken.

2

t chy bt k mt anken no cng thu c s mol CO bng s mol H O

2 2

19/ Dy no sau y ch gm cc cht c th trc tip iu ch anehit axetic ? a. ancol etylic; etilen; 1,1 -icloetan; axetilen. b. ancol etylic; axetilen; etyl axetat. c. ancol metylic; axit axetic; vinyl axetat. d. etilen; etan; axit fomic ; axetilen. 20/ un nng mui X thu c mui Y. Y tc dng vi dung dch HCl thu c mui X v mui Z. in phn dung dch mui Z thu c 2 kh v cht G. G tc dng vi CO c th thu c X hoc Y. t G trn ngn la xanh, ngn
2

la c mu vng. X, Y, Z, G tng ng l a. Na CO , NaHCO , NaCl, NaOH.

2 3 3 3

b. NaHCO , Na CO , NaCl, NaOH.

3 2 3

c. NaHCO , Na CO , NaOH, NaCl.

3 2 3 4

d. K CO , KOH, KHCO , KCl.

2 3 3

21/ Cho tht t t dung dch NaOH vo dung dch H PO ti d dung dch NaOH. Cc mui sinh ra trong th nghim trn ln lt theo th t a. Na PO , NaH PO , Na HPO .
3 4 2 2 4 2 4 4

b. Na PO , Na HPO , NaH PO .
3 4 2 4 2 4

c. NaH PO , Na HPO , Na PO .
2 4 4 3

d. NaH PO , Na PO , Na HPO .
2 4 3 4 2 4

22/ Nhn xt no sau y ng ? a. C th iu ch axetilen t vi, than qua 2 phn ng. b. Tecpen l nhng hirocacbon khng no c cng thc n gin nht l C H .
5 8

c. d.

Phn t C H c cu to thng.
2 2

Tecpen l sn phm trng hp isopren nn c cng thc chung (C H )

5

8 n

23/ Mt ankan to c dn xut monoclo trong hm lng clo l 38,38% khi lng. Ankan c s ng phn l a. 3 b. 4 c. 2 d. 1 24/ Cho t t 200 ml dung dch HCl vo 100ml dung dch cha Na CO , K CO , NaHCO 1M thu c 1,12 lt CO
2 3 2 3 3 2

(ktc) v dung dch X. Cho nc vi trong d vo dung dch X thu c 20 gam kt ta. Nng mol/l ca dung dch HCl l a. 1,25 M. b. 0,5 M. c. 0,75 M. d. 1,0 M. 25/ Phng trnh ho hc no sau y sai ? a. b. c. d. CH - CHBr - CH - CH
3 2 3

KOH, ancol, t CH3 - CH = CH - CH3 (sn phm chnh) + HBr

CH - CH MgBr + CO
3 2

CH CH COOMgBr.
3 2

CH CH - Br + Mg
3 2

etekhan

CH CH - Mg - Br.
3 2

Br - C H CH - Br + 2NaOH long, d
6 4 2

HOC H CH - OH + 2NaBr.
6 4 2

26/ phn bit cc dung dch khng mu: glyxin, etyl amin, axit acrylic. Cn dng 1 thuc th l c. Qu tm d. Dung dch HCl a. Dung dch NaOH b. Dung dch Na CO
2 3

27/ X l hp cht hu c c cng thc phn t C H O N. un X vi dung dch NaOH thu c mt cht c cng
5 11 2

thc phn t C H O NNa v cht hu c Y. Cho hi Y i qua CuO (t0) thu c cht hu c Z c kh nng cho phn
2 4 2

ng trng gng. X c cng thc cu to l a. CH (CH ) NO

3 2 4 2.

b. NH CH CH COOC H .
2 2 2 2 2 2 5

c. NH CH COOCH(CH )
2 2

3 2.

d. NH CH COO - CH CH CH .
2 2 3

28/ Cho s phn ng: a. CH - CH - COOH.

3 3 2

CH CHO
3

H3O , t HCN A

B. B l

b. CH - CH - CN.
3 3 2

c. CH - CH(OH) - COOH. 29/ in li ca CH COOH s tng khi

3

d. CH - CHO - CH

a. b. c. d.

Thm vo vi git dung dch HCl. Thm vo vi git dung dch Na2SO4. Thm vo mt lng nh tinh th CH COONa.
3

Pha long dung dch. 115

30/ Nhn xt no sau y sai ? a. Tnh axit ca cc axit halogenhiric tng dn theo th t HF, HCl, HBr, HI. b. Cho H SO c tc dng vi hn hp rn (NaI v MnO ) un nng, thu c I .
2 4 2 2

c. d.

Tnh kh ca cc hiro halogenua tng dn theo th t HF, HCl, HBr, HI. Cho H SO c tc dng vi NaI rn un nng, thu c hiro iotua.
2 4 2 4

31/ un nng hn hp 2 ancol n chc, mch h A, B vi H SO c 1400C thu c hn hp 3 ete. t chy 10,8 gam mt ete trong s 3 ete trn thu c 26,4 gam CO v 10,8 gam H O. A, B l
2 2

a. ancol metylic v ancol anlylic. b. ancol etylic v ancol vinylic. c ancol metylic v ancol etylic. d. ancol etylic v ancol anlylic. 32/ t chy hon ton 8,8 gam mt hp cht hu c A n chc (c C, H, O) thu c 8,96 lt CO (ktc) v 7,2
2

gam H O. A c th tc dng c vi Na CO to kh CO . S ng phn cu to cng chc ph hp vi A l

2 2 3 2

a. 2 b. 4 c. 3 d. 5 33/ Hn hp X gm hai cht hu c n chc tc dng vi 500ml dung dch KOH 1M, thu c hai mui ca hai axit hu c v mt ancol. Cho lng ancol trn tc dng vi Na d th c 3,36 lt H (ktc). X gm
2

a. Mt axit mt ancol. b. Mt este v mt axit. c. Mt este mt ancol. d. Hai este. 34/ Cho cc nhn xt sau: 1) Anehit l cht kh yu hn xeton. 2) Anehit no khng tham gia phn ng cng. 3) Cng thc phn t chung ca cc anehit no l C H O.
n 2n

4) Anehit khng phn ng vi nc. 5) Anehit khi phn ng vi phenol d (xc tc axit) un nng s thu c nha novolac. Nhn xt ng l a. 5. b. 1, 4. c. 2, 4, 5. d. 1, 2, 3. 35/ em oxi ho 2,76 gam ancol etylic bng CuO un nng, thu c hn hp A c cha anehit, axit, ancol d v nc. - Cho 1/2 hn hp A tc dng hon ton vi dung dch AgNO /NH d,t0 thu c 3,024 gam Ag.
3 3

- Cho 1/2 hn hp A trung ho va vi 10ml dung dch NaOH 1M. % khi lng ancol etylic b oxi ho l a. 80%. b. 95%. c. 75%. d. 40%. 36/ Cn trn dung dch A cha (HCl 0,1M v H SO 0,2M) vi dung dch B cha (NaOH 0,3M v KOH 0,2M) theo
2 4

t l th tch nh th no thu c dung dch c pH = 7 ? a. V / V = 1 : 2 b. V / V = 2 : 1

A B A B

c. V / V = 1 : 4
A

37/ Dy gm cc ion v nguyn t M u c cu hnh e l b. Na+, Ca2+, Cl-, O2-, Ar. a. K+, Ca2+, Cl-, S2-, Ar. c. K+, Mg2+, Br-, S2-, Ar. d. K+, Ca2+, F-, O2-, Ne. 38/ Ho tan hon ton 28,4 gam hn hp hai kim loi X (ho tr I) v Y (ho tr II) bng dung dch HCl d thu c dung dch Z v V lt kh ( ktc). C cn dung dch Z thu c 49,7 gam hn hp mui clorua khan. V bng a. 8,24 lt. b. 11,2 lt. c.6,72 lt. d.8,96 lt 39/ Sc kh hiro sunfua vo cc dung dch: FeCl , MgCl , NaCl, CuCl . C bao nhiu trng hp c cht rn to ra ? X+, Y2+, Z-, T22 2 2

B 1s22s22p63s23p6

d. V / V = 1 : 1
A B

a. 4 40/ Cho cc phn ng sau: a) FeS + H SO (c, nng)

2 4

b. 2

c. 1 b) MgO + HNO (c, nng)

3
0

d. 3

c) Fe + Fe (SO )
2

4 3

3 2 3

d) C H + H
2 2

Ni,t

e) CH CHO + [Ag(NH ) ]NO

3

f) CH COOCH + NaOH
3 3

t
0

g) glixerol + Cu(OH)

h) HCHO + Cu(OH)

t ,OH

S phn ng thuc loi phn ng oxi ho - kh l a. 6 b. 4 II. PHN RING [10 cu] Th sinh ch c lm mt trong hai phn (Phn A hoc B) 116

c. 7

d. 5

A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) 41/ Cho A l hp cht thm c cng thc phn t chnh l cng thc n gin nht. t chy hon ton 1,24 gam A ch thu c 1,568 lt CO (ktc) v 0,72 gam H O. Cho a mol A tc dng vi Na d thu c a mol kh H . Mt
2 2 2

khc, a mol A tc dng vi a mol NaOH. S cng thc cu to c th ph hp vi A l a. 4 b. 6 c. 3 d. 5 42/ X c cng thc phn t C H . X tc dng vi Clo (as) cho ti a 2 dn xut monoclo. X l
6 14

a. hexan. b.neohexan. c. 2, 3 - imetylbutan. d. isohexan. 43/ Dung dch X cha a mol NaAlO . Khi thm vo dung dch X b mol hoc 2b mol HCl th lng kt ta sinh ra
2

u nh nhau. T s a/b c gi tr a. 1,5 b. 1,25. c. 1 d. 1,75. 44/ Hn hp X cha K O, NH Cl, KHCO v BaCl c s mol bng nhau. Cho X vo nc d, un nng, dung dch
2 4 3 2

thu c cha cht tan l a. KCl BaCl

2

b. KCl, BaCl

c. KCl, KOH

d. KCl,

KHCO ,
3

45/ Thu phn cc hp cht sau trong mi trng kim 1. CH - CHCl 2. CH - COO - CH = CH - CH .
3 3 2 3 3

3. CH - COO - CH - CH = CH
3 2

4. CH - CH - CCl .
2 3

5. (CH - COO) CH
3 2

Nhng cht sau khi thy phn cho sn phm c phn ng trng bc l a. 1, 2, 4, 5 b. 1, 2, 4 c. 1, 3, 5 d. 1, 2, 5 46/ Ho tan hon ton 19,2 gam kim loi M trong dung dch HNO d thu c 8,96 lt (ktc) hn hp kh gm NO
3

v NO c t l th tch tng ng 3 : 1 (phn dung dch khng c mui amoni). Kim loi M l a. Fe b. Cu c. Al d. Mg 47/ M t hin tng no di y l khng chnh xc ? a. t chy mt mu lng trng trng thy xut hin mi kht nh mi tc chy. b. Nh vi git dung dch HNO c vo dung dch lng trng trng thy kt ta mu vng.
3

c.

Trn ln lng trng trng, dung dch NaOH v mt t CuSO thy xut hin mu c trng.
4

d. un nng dung dch lng trng trng thy hin tng ng t. 48/ Nhn nh no sau y ng ? a. C th phn bit glucoz v fructoz bng phn ng trng bc. b. Tinh bt c phn ng mu vi dung dch It. c. Glucoz v Fructoz c tnh cht ho hc ging nhau. d. Tinh bt v xenluloz u c to thnh t cc gc -glucoz. 49/ Cho phn ng A + 2B C + D vi tc phn ng V = k.[A].[B]2. Nu nhit khng i, nng mol cht A tng 2 ln, nng mol B tng 2 ln th tc phn ng tng a. 6 ln b. 8 ln c. 12 ln d. 4 ln 50/ Cho cc dung dch khng mu : K2S, KI, KNO , KCl ch dng mt thuc th no sau y nhn bit cc dung
3

dch trn ? a. dung dch AgNO

b. dung dch BaCl

c. qu tm

d. dung dch HCl

B. Theo chng trnh Nng cao (t cu 51 n cu 60) 51/ Ho tan hon ton 19,2 gam kim loi M trong dung dch HNO d thu c 14,336 lt kh (ktc) hn hp kh gm
3

NO v NO c t l mol tng ng 1 : 3 (dung dch khng c mui amoni). Kim loi M l

2

a. Mg b. Al c. Fe d. Cu 52/ Nhn nh sai l a. Phn t mantoz gm hai gc -glucoz ni vi nhau bi lin kt -1,6-glicozit. b. Tinh bt v xenluloz khng th hin tnh kh v trong phn t hu nh khng c nhm OH hemiaxetal t do. c. C th phn bit glucoz v fructoz bng v gic. d. Tinh bt c phn ng mu vi dung dch I v c cu trc vng xon.
2

53/ Ch dng mt thuc th no di y phn bit c ba cht lng: etanal, propan-2-on, pent-1-in. (1) dung dch Br ;(2) dung dch AgNO /NH ; (3) H /Ni, t0.
2 3 3 2

a. Thuc th (1). c. Thuc th (3).

b. Thuc th (2). d. Thuc th (1) hoc (2)

117

54/ Cho cc mui sau: Na CO , AlCl , C H ONa CH COOK, CH NH Cl, CuSO , NaHCO , NH NO , BaCl ,
2 3 3 6 5 , 3 3 3 4 3 4 3 2

K SO , C H ONa, NaAlO . S mui tham gia phn ng thu phn trong nc l

2 4 2 5 2

a. 12 b. 9 c. 10 d. 11 55/ Khi cho 0,02 mol hoc 0,04 mol CO hp th ht vo dung dch Ba(OH) th lng kt ta thu c u nh
2 2

nhau. S mol Ba(OH) c trong dung dch l

2

a. 0,03 b. 0,01 c. 0,02 d. 0,04 56/ A l mt cht hu c mch khng nhnh ch cha mt loi nhm chc, tc dng vi dung dch Na CO d thu
2 3

c mui A'. Nung A' vi vi ti xt th thu c kh metan. B l mt ancol mch h, a mol B tc dng vi Na d thu c a/2 mol H ; a mol B lm mt mu va dung dch c a mol Br . t a mol B thu c 3a mol CO . A tc
2 2 2

dng vi B thu c hp cht hu c X l a. CH COO-CH -CH=CH-OOCCH

3 2 2 3

b. CH -CH=CH-OOC-COO-CH=CH-CH
3 2

c. CH =CH-CH -OOCCH COO-CH=CH .

2 2 6 10

d.CH =CH-CH -OOCCH COO-CH -CH=CH .

2 2 2 2 2 3 3

57/ C bao nhiu cht c cng thc phn t C H c kh nng tc dng vi dung dch AgNO /NH cho kt ta mu vng ? a. 5 b. 6 c. 4 d. 3 58/ Cho cht v c X tc dng vi mt lng va dung dch KOH un nng, thu c kh X v dung dch X .
1 2

Kh X tc dng vi mt lng va CuO nung nng thu c kh X , H O, Cu. C cn dung dch X thu c cht
1 3 2 2

rn khan X (khng cha Clo). Nung X thy sinh ra kh X (M = 32u). Nhit phn X thu c kh X (M = 44u) v
4 4 5 6

H O. Cc cht X , X , X , X , X ln lt l
2 1 3 4 5 6

a. NH , NO, K CO , CO , O .
3 2 3 2 2

b.NH , NO, KNO , O , CO .

3 3 2 2

c. NH , N , KNO , O , CO .
3 2 3 2 2 8 10

d. NH , N , KNO , O , N O.
3 2 3 2 2

59/ S ng phn thm c cng thc phn t C H O, khng tc dng vi NaOH nhng tc dng vi Na l a. 4 b. 5 c. 2 60/ C th c bao nhiu tripeptit mch h sinh ra t hai aminoaxit: Alanin, Glyxin ? a. 6 b. 7 c. 5 d. 3 d. 8

1 d 21 c 41 c 8

2 d 22 c 42 c

3 a 23 c 43 b

4 a 24 d 44 a

5 a 25 d 45 d

6 c 26 c 46 b

7 b 27 d 47 c

8 a 28 c 48 b

9 b 29 d 49 b

10 d 30 d 50 a

11 a 31 a 51 a

12 b 32 a 52 a

13 d 33 b 53 b

14 c 34 a 54 c

15 a 35 a 55 a

16 d 36 d 56 d

17 a 37 a 57 c

18 b 38 c 58 d

19 a 39 c 59 b

20 b 40 d 60 d

Cu 1: X v Y l 2 nguyn t thuc nhm VII A ca bng tun hon cc nguyn t ha hc, chng tham gia cc p theo pthh: 5X2+ Y2 + 6H2O 10HX + 2HYO3 A. X l F, cn Y c th l Cl, Br,I B. X l I, cn Y c th l Cl, Br,F C. X l Br, cn Y c th l Cl, F ,I D. X l Cl, cn Y c th l Br,I Cu 2: s ng phn ca ankan C7H16 c cha nguyn t cacbon bc 3 trong phn t l: A. 4 cht B. 5 cht C. 6 cht D. 7 cht Cu 3: cht A (cha C,H,O) ,mch h c ngun gc t thc vt v rt thng gp trong i sng. Khi ly cng s mol A cho p ht vi Na2CO3 hoc vi Na th t l s mol CO2 v s mol H2O thu c tng ng l 3:4. Bit rng A c khi lng mol phn t l 192 gam v ch cha cc nhm chc p vi Na. Tn gi ca cht A l: A. axit lauric (trong qu da) B. axit tactaric (trong qu nho) C. axit malic trong qu to) D. axit xitric (trong qu chanh) Cu 4: Tin hnh in phn 100g dung dch Cu(NO3)2 vi in cc tr, cng dng in I = 5A trong thi gian 12 pht 52 giy th dng li. yn dung dch sau in phn n khi catot khng i, sau thm dung dch NaOH d v dung dch sau in phn thu c kt ta X. Lc ly kt ta X ri nung nng n khi lng khng i thu c 3,2g cht rn. Nng % ca dung dch Cu(NO3)2 ban u l? A. 7,52% B. 8,46% 118

C. 9,4% D. 11,28% Cu 5: Ha tan 2,16g hn hp 3 kim loi Na, Al, Fe vo nc (d), thu c 0,448 lt kh (ktc) v cht rn X. Tch lng cht rn X ri cho tc dng vi 60ml dung dch CuSO4 1M, sau phn ng thu c 3,2g kim loi v dung dch Y. Thn t t dung dch NaOH vo Y cho n khi kt ta t gi tr ln nht th dng li. Lc ly kt ta, nung trong khng kh n khi lng khng i, thu c cht rn c khi lng bng? A. 5,24g B. 3,64g C. 3,42g D. 2,62g Cu 6: cho 6,69g hh dng bt gm Al, v Fe vo 100ml dd CuSO4 0,75M, khuy k hh p xy ra hon ton thu c cht rn A. Ha tan hon ton A bng dd HNO3 1M thu c kh NO l sn phm kh duy nht. Th tch dd HNO3 cn dng: A.0,6 lt B.0,5 lt C. 0,4 lt D. 0,3 lt Cu 7: cho 10,32g hh X bao gm Cu, Ag tc dng va vi 160ml dd Y gm HNO3 1M v H2SO4 0,5M thu c kh NO duy nht v dd Z cha m gam cht tan. Gi tr cu m l: A.20,36 B.25,2 C.22,96 D.27,92 Cu 8: cho hh 2 anken ng ng k tip nhau tc dng vi nc (xt, t0) c hh X gm 3 ru. t chy ht 1,94g X ri hp th hon ton CO2 thu c vo 2 lt dd NaOH 0,15M c dd Y c nng ca NaOH l 0,05M. CTPT ca 2 anken l ( coi th tch ca dd thay i khng ng k) A.C2H4 v C3H6 B. C4H8 v C3H6 D. C5H10 v C6H12 C. C4H8 v C5H10 Cu 9: cho hh X gm 2 cht hu c c cng CTPT C2H7O2N tc dng va vi dd NaOH un nng, thu c dd Y v 4,48l kh Z(ktc) gm 2 kh ( u lm xanh qu tm m). T khi ca Z i vi H2 bng 12. C cn dd Y thu c mui khan c khi lng l: A. 14,3g B. 8,9g C. 16,5g D. 15g Cu 10: cho cc PTP sau : 2. H2O2 + 2KI I2 + KOH 1. H2O2 + KNO2 H2O + KNO3 3. H2O2 + Ag2O 2Ag + H2O +O2 4. 3H2O2 + 2KMnO4 2H2O + KOH +3O2 + 2MnO2 5. 5H2O2 + 2KMnO4 + 3H2SO4 8H2O + K2SO4 + 2MnSO4 + 5O2 Nhng p ng l: A. 2,3,5 B. 2,3,4,5 C. 1,2,4,5 D. 1,2,3,4,5 Cu 11: ha tan hon ton nhng lng bng nhau v s mol ca Fe2O3 v FeCO3 vo dd H2SO4 10% va thu c dd Y. Nng % ca Fe2(SO4)3 trong dd Y l: A. 13,294% B. 9,634% C. 9,533% D. 3,66% Cu 12 : cho cc cht sau: CH3CHCl2 , CH3COOCH=CH-CH3 ; CH3COOC(CH3)=CH2 ; CH3COO-CH2OOCCH3; CH3CH2CCl3; HCOOC2H5. Khi thy phn trong mi trng kim th s cht sau khi thy phn c sn phm tham gia p trng gng l: A. 2 cht B. 3 cht C. 4 cht D. 5 cht Cu 13: x phng ha hon ton 1kg cht bo c ch s axit bng 7, cn dng va dd c cha 3,2 mol NaOH. Khi lng x phng thu c sau p l: A. 1031,45 g B. 1103,15 g C. 1125,75 g D. 1021,35 g Cu 14: cho kh H2S t t n d vo dd hn hp gm FeCl3, AlCl3, NH4Cl, v CuCl2 thu c kt ta X gm : A. Fe2S3; Al2S3 v CuS B. FeS; Al2S3 v CuS C. S v CuS D. S; Al2S3 v CuS Cu 15: ha tan ht 11,6g FeCO3 bng dd HNO3 va , thu c hh kh (CO2; NO) v dd X. Thm dd HCl d vo dd X thu c dd Y. Hy cho bit dd Y c th ha tan ti a c bao nhiu gam bt Cu to ra sn phm kh duy nht l kh NO. A. 28,8g B. 16g C. 48g D. 32g Cu 16: nhn nh no di y khng ng: A. dd NaHCO3 c mi trng axit yu B. dd NaHCO3 c mi trng bazo yu C. NaHCO3 l cht lng tnh D. NaHCO3 rn b phn hy bi nhit Cu 17: cho 21,8g hh cht hu c X cha 1 loi nhm chc vo 1 lt dd NaOH 0,5M, thu c 24,6g mui v 0,1 mol ancol. Sau p phi dng 0,5 lt dd HCl trung ha ht NaOH d. Cht no di y c th tha mn tnh cht ca X: A. (HCOO)3C3H5 B. (HCOO)2C3H5(OOCCH3) C. (CH3COO)2C3H5OOCCH D. (CH3COO)3C3H5 119

Cu 18: hp cht X khng no, mch h c CTPT l: C5H8O2, khi tham gia p x phng ha thu c 1 andehit v 1 mui ca axit hu c. C bao nhiu CTCT ph hp vi X ( khng k ng phn cis, trans)? A. 2 cht B. 3 cht C. 4 cht D. 5 cht Cu 19: trong s cc cht phenol, anilin, glucozo, mantozo, axit acrilic, s lng cht p c vi dd nc Brom l: A.2 cht B. 3 cht C. 4 cht D. 5 cht Cu 20: cho cc PTP sau: 1. 5Cl2 + Br2 + 6H2O 10HCl + 2HBrO3 2. 2HI + 2FeCl3 2FeCl2 + I2 + 2HCl 3. 8HI + H2SO4 () 4I2 + H2S + 4H2O 4. 2HBr + H2SO4 () Br2 + SO2 + 2H2O 5. 2HCl + H2SO4 () Cl2 + SO2 + 2H2O 6. 4HBr + O2 2H2O + Br2 7. 2CaOCl2 + CO2 + H2O CaCO3 + CaCl2 +2H2O S p xy ra l: A. 7 p B. 6 p C. 5 p D. 4 p Cu 21: cho 200ml dd AlCl3 1M vo cc cha 350ml dd NaOH 2M. Sau p lc ly kt ta ri nung n khi lng khng i thu c cht rn c khi lng l: A. 5,1 g B. 7,8 g C. 10,2 g D. 15,6 g Cu 22: un nng m gam hh X gm C2H2, C2H4, v H2 vi xc tc Ni n p xy ra hon ton, thu c 8,96 lt hn hp kh Y (kc) c t khi so vi H2 bng 8. t chy hon ton cng lng hh X trn, sau cho sn phm chy hp th hon ton trong dd nc vi trong d th khi lng kt ta thu c l: A. 20 g B. 40 g C. 30 g D. 50 g Cu 23: dd A cha m gam NaOH v o0,3 mol NaAlO2. Cho t t dd cha 1 mol HCl vo dd A, thu c dd B v 15,6g kt ta. Sc CO2 vo dd B thy xut hin kt ta, gi tr ca m l: A. 24g B. 16g C.8g D.32g Cu 24: ha tan ht 9g hh gm Mg v Al vo dd H2SO4 long, d , thu c 9,408 lt kh ( ktc) v dd X. Thm dd Na2CO3 d vo dd X n p hon ton thu c m gam kt ta. Gi tr ca m l: A. 19,68g B. 20,16g C. 29,52g D. 34,42g Cu 25: cho 1 dd X c cha cc ion : Ba2+; Mg2+; Na+; Ca2+; H+, Cl-; trong cc dd cho di y, dd no c th dng loi b nhiu ion ra khi dd X: A. dd Na2SO4 B. dd Na2CO3 C. dd K2CO3 D. dd NaOH Cu 26: cho cc hp cht sau u c cha nhm th v tr para: CH3-C6H4-C2H5 (1); C2H5-C6H4-C2H5(2); C2H3C6H4-C2H5(3); C2H5-C6H4-C2H3(4); CH3-C6H4-C2H3(5). S cht khi un nng vi dd KMno4 thu c sn phm cha cacbon ch gm Kali axetat v Kali terephtalat l: A. 5 cht B. 4 cht C. 3 cht D. 2 cht Cu 27: bit rng c 1 mol cht X ( C7H6O3) p va vi dd cha 3 mol NaOH. Cho 2,76g X tc dng vi dd NaOH va , sau p, c cn dd ri nung nng cht rn cn li trong oxi d n p xy ra hon ton thu c cht rn c khi lng l: A. 0,84g B. 1,06g C. 3,18g D. 5,04g Cu 28: c 4 hp cht hu c c CTPT ln lt l : CH2O, CH2O2, C2H2O3, v C3H4O3. S cht va tc dng vi Na, va tc dng vi NaOH , va c p trng gng l: A.1 B.2 C.3 D.4 Cu 29: oxi ha 9,2 gam ru etylic bng oxi c xc tc, thu c 13,2g hh X gm andehit, axit, ru d v nc. Cho hh X tc dng vi Na d sinh ra 3,36 lt kh (ktc) H2. % khi lng ru b oxi ha: A. 25% B. 50% C. 75% D. 80% Cu 30: cho dd AgNO3 tc dng va vi dd NaF, NaCl, NaBr,NaI. S lng dd p to kt ta vi AgNO3 l: A. 1 B.2 C.3 D.4 Cu 31: cho 1 thanh st nng m gam vo cc ng dd CuSO4. Sau mt 1 thi gian ly thanh st ra thy khi lng thanh st nng (m+16) gam. Thm dd HCl d vo cc thy cn li a gam cht rn khng tan v c 6,72 lt kh(ktc) bay ra. Cc p xy ra hon ton. Gi tr ca a m m tng ng l: A.1,6g v.16,8g B. 6,4g v 16,8g C. 12,8g v 11,2g D.12,8g v 28g 120

Cu 32: ha tan ht hh rn gm CaC2, Al4C3, v Ca vo H2O d, thu c 3,36 lit (ktc) hh kh X c t khi so vi hidro l 10. Dn X qua Ni nung nng, thu c hh kh Y. Tip tc dn kh Y qua bnh ng nc Brom d th c 0,784 lt (ktc) hh kh Z (c t khi so vi He bng 6,5) i ra khi bnh. Khi lng bnh Brom tng ln l: A. 2,09g B. 3,45g C. 3,91g D. 2,545g Cu 33: Cho cc cht sau: C2H4; C2H2; C2H5OH; CH3COOCH=CH2; CH3COOCH2CH3; CH3CHCl2. S hp cht c th chuyn ha trc tip thnh CH3CHO iu kin thch hp l? A. 3 B. 4 C. 5 D. 6 Cu 34: vng khng b ha tan trong A. nc cng toan B. Hg C. dd NaCN D. dd HNO3 Cu 35: ha tan hon ton 0,1 mol FeS2 trong dd HNO3 c nng. Tnh th tch kh NO2 thot ra (ktc) v s mol HNO3 (ti thiu) tham gia p: A. 33,6 lt v 1,4 mol B. 33,6 lt v 1,5 mol C. 22,4lt v 1,5 mol D. 33,6 lt v 1,8 mol Cu 36: un nng m gam hh gm nhng lng bng nhau v s mol ca glucozo, fructozo, saccarozo v mantozo vi dd H2SO4 long, sau cho p vi lng d dd AgNO3/NH3 to ra 12,96g Ag. Gi tr ca m l: A. 10,44g B. 15,66g C. 21,6g D. 31,32g Cu 37: chia hh X gm Cu v Fe thnh 3 phn bng nhau. Phn 1: tc dng vi dd H2SO4 long , d to ra 4,48 lt kh H2(ktc) Phn 2: cho vo 200ml dd FeCl3 1M, sau p xy ra hon ton thy cn li 12 g cht khng tan. Phn 3: cho tc dng ht vi clo thu c m gam cht rn Gi tr ca m l: A. 28,4g B. 38,9g C. 40,4g D. 46g Cu 38: cho mi cht CH3I (X), HCl (Y), nc Br2(Z), NaNO2/HCl (T) tc dng vi anilin. Cht p c vi alinin l: A. Z B. Y v Z C. Y,Z v T D. X,Y,Z v T Cu 39: cho 1,74g hp cht X c CTPT C8H14O4 tc dng ht vi NaOH thu c 1,48g mui ca mt diaxit v hh 2 ancol. S lng hp cht c th tha mn tnh cht ca X A. 2 cht B. 4 cht C. 6 cht D. 8 cht Cu 40: Ha tan hon ton hn hp x mol FeS2 v y mol Cu2S bng dung dch HNO3 c, nng, thu c dung dch ch cha hai mui sunfat. T l x, y tng ng l? A. 1:1 B. 1:2 C. 2:1 D. 2:3 Cu 41: Nh git t t dung dch hn hp cha 0,105 mol Na2CO3 v 0,09 mol KHCO3 vo cc cha 100ml dung dch HCl 1,5M th th tch kh thot ra ktc l? A. 1,176 lt B. 1,68 lt C. 2,184 lt D. 2,688 lt Cu 42: Hn hp X gm phenol v anilin. Cho hn hp X tc dng va vi 50ml dung dch NAOH 1M thu c dung dch Y. Dung dch Y phn ng va vi 125ml dung dch HCl 1M. Thnh phn phn trm theo khi lng ca phenol c trong hn hp X l? A. 59,74% B. 28,79% C. 71,21% D. 40,26% Cu 43: Trong s cc hidrocacbon c t khi hi so vi H2 bng 20 th s cht c th lm mt mu dung dch KMnO4 l? A. 1 cht B. 2 cht C. 3 cht D. 4 cht Cu 44: Cho brom tc dng va vi dung dch CrCl3 trong mi trng kim thu c dung dch X c mu? A. nu B. vng C. xanh lc D. da cam Cu 45: Cho cc cp dung dch sau: (1) Na2CO3 v AlCl3; (2) NaNO3 v FeCl2; (3) HCl v Fe(NO3)2; (4) NaHCO3 v BaCl2; (5) NaHCO3 v NaHSO4 Khi trn cc dung dch trong cc cp vi nhau th cc cp c phn ng xy ra l? A. (1) (3) (4) B. (1) (4) (5) C. (1) (3) (5) D. (3) (2) (5) 121

Cu 46: Cho hp cht C12H10 (c cu to cn xng v khng lm mt mu dung dch KMnO4 khi n nng) tc dng vi HNO3, th s lng cc cht ng phn C12H9NO2 c th c to ra l? A. 4 cht B. 3 cht C. 2 cht D. 1 cht Cu 47: Cho anilin tc dng vi nc brom c kt ta A. Cho A tc dng vi HNO2 ban u 0oC 5oC, sau un nng nh c kt ta B. Vy B l? A. axit picric B. mui ca A vi HNO2 C. 2,4,6-tribromphenol D. anilin Cu 48: t 0,1 mol cht bo ngi ta thu c kh CO2 v H2O vi s mol CO2 ln hn s mol H2O l 0,6 mol. Hi cht bo c th cng hp ti a vi bao nhiu mol Br2? A. 2 mol B. 3 mol C. 4 mol D. 5 mol Cu 49: Hai hp cht X v Y l hai ancol, trong khi lng mol ca X nh hn ca Y. Khi t chy hon ton mi cht X, Y u to ra s mol CO2 t hn s mol H2O. t chy hon ton hn hp Z gm nhng lng bng nhau v s mol ca X v Y thu c t l s mol CO2 v H2O tng ng 2:3. S hp cht tha mn cc tnh cht ca Y l? A. 2 cht B. 4 cht C. 5 cht D. 6 cht Cu 50: Cho m gam hn hp X gm Cu, Fe, Al vo lng d axit H2SO4 long, thu c 8,96 lt kh (ktc) v cn li 0,5m gam cht rn khng tan. Mt khc nu cho m gam X vo lng d dung dch NaOH, thu c 6,72 lt kh (ktc). Gi s cc phn ng xy ra hon ton. Gi tr ca m l? A. 22,4g B. 22,0g C. 11,0g D. 5,4g

1 D 21 A 41 C

2 C 22 B 42 D

3 D 23 D 43 C

4 B 24 C 44 B

5 C 25 B 45 C

6 C 26 A 46 B

7 C 27 C 47 C

8 B 28 C 48 C

9 D 29 C 49 D

10 D 30 C 50 B

11 B 31 D

12 C 32 A

13 A 33 C

14 C 34 D

15 D 35 B

16 A 36 A

17 D 37 D

18 C 38 D

19 D 39 C

20 B 40 C

9 Cu 1: Sc 1,56g C2H2 vo dung dch cha HgSO4, H2SO4 trong nc 80oC thu c hn hp gm 2 cht kh (bit hiu sut phn ng t 80%). Tip tc cho hn hp kh thu c qua dung dch AgNO3/NH3 d thu c m gam kt ta. Gi tr ca m l? A. 13,248g B. 2,88g C. 12,96g D. 28,8g Cu 2: Cho cacbon (C) tc dng vi H2, Al, H2O, CuO, HNO3 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr cht kh? A. 5 B. 7 C. 6 D. 4 Cu 3: Hn hp X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,1 mol hn hp X ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng dung dch thay i: A. gim 10,4g B. tng 7,8g C. gim 7,8g D. tng 14,6g Cu 4: Ha tan hon ton hn hp X (gm x mol Fe, y mol Cu, z mol Fe2O3, v t mol Fe3O4) trong dung dch HCl khng thy c kh bay ra khi bnh, dung dch thu c ch cha 2 mui. Mi quan h gia s mol cc cht c trong hn hp X l? A. x+y = 2z+3t B. x+y = 2z+2t C. x+y = z+t D. x+y=2z+2t Cu 5: t chy hon ton 1 anhit X c nCO2 nH2O = nX. Cho 11,52g X phn ng vi lng d AgNO3 trong NH3 c 69,12g Ag. Cng thc ca X l? A. HCHO B. CH2(CHO)2 C. CH3CHO D. CH2=CH-CHO Cu 6: T m kg khoai c cha 25% tinh bt, bng phng php ln men ngi ta iu ch c 100 lt ru 60o. Gi tr ca m l? (Bit khi lng ring bit ca C2H5OH l 0,8g/ml hiu sut chung ca c qu trnh l 90%) A. 338,09kg B. 375,65kg C. 93,91kg D. 676,2kg Cu 7: Mt -aminoaxit c cng thc phn t l C2H5NO2, khi t chy 0,1 mol oligopeptit X to nn t -aminoaxit th thu c 12,6g nc. Vy X l? A. pentapeptit B. tripeptit 122

C. tetrapeptit D. ipeptit Cu 8: ha tan hon ton m gam hh gm Na, Na2O, NaOH v Na2CO3 trong dd axit H2SO4 40%(va ) thu c 8,96 lt hh kh c t khi so vi H2 bng 16,75 v dd Y c nng 51,449%. C cn Y thu c 170,4 gam mui. Gi tr ca m l: A. 37,2g B. 50,4g C. 50,6g D. 23,8g Cu 9: kh CO2 tc dng c vi: (1) nc Javen, (2) dd K2CO3; (3) nc brom; (4)dd NaHSO4; (5) dd KOH; (6) dd NaHCO3; (7) Mg nung nng A. 2,3,4,5 B. 1,2,5,6 C. 1,2,5,7 D. 2,4,5,7 Cu 10: Cho dy bin ha sau Xiclopropan X1 X2 X3 Khi cho 0,1 mol cht X3 tc dng vi AgNO3 d /NH3 thu c khi lng Ag l? A. 43,2g B. 21,6g C. 10,8g D. 32,4g Cu 11: cht hu c X c CTPT l C5H8O2. Cho X tc dng vi dd Br2 thu c cht hu c Y c cng thc l C5H8O2Br2. un nng Y trong NaOH d thu c glixeol; NaBr, v mui cacboxylat ca axit Z. Vy CTCT ca X l: B. H-COOCH(CH3)=CH=CH2 A. CH3-COOCH=CH-CH3 C. CH2=CH-COOCH2-CH3 D. CH3-COOCH2-CH=CH2 Cu 12: c cc nhn nh sau: 1.cu hnh electron ca ion X2+ l: 1s22s22p6 3s23p63d6. Trong bng tun hon cc nguyn t ha hc, nguyn t X thuc chu k 4, nhm VIIIB 2. cc ion v nguyn t : Ne, Na+, F- c im chung l c cng s electron. 3. bn knh ca cc vi ht sau c sp xp theo th t gim dn : Mg2+, Na+, F- Na, K 4. dy cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l: K, Mg,Si 5. tnh bazo ca cc hidroxit: NaOH, Al(OH)3, Mg(OH)2 gim dn Cho N (Z=7); F (Z=9); Ne (Z=10); Na (Z=11); Mg (Z=12); Al (Z=13); K (Z=19); Si (Z=14). S nhn nh ng l: A.5 B.4 C.3 D.2 Cu 13: cho hh X gm 2 -aminoaxit mch h no c 1 nhm COOH v 1 nhm NH2 ng ng k tip nhau c % khi lng oxi l 37,427%. Cho m gam X tc dng vi 800ml dd KOH 1M d. Sau p kt thc c cn dd thu c 90,7g cht rn khan. M c gi tr l: A. 58,14g B. 67,8g C. 68,4g D. 58,85g Cu 14:ha tan 32,53 g photpho halogenua vo nc thu c dd X. trung ha hon ton dd X cn dng 300ml dd KOH 2M. CT ca photpho halogenua l: A. PCl5 B. PBr5 D. PCl3 C. PBr3 Cu 15: cho cc cht : BaCl2; NaHSO3; NaHCO3; KHS; NH4Cl; AlCl3; CH3COONH4; Al2O3; Zn, ZnO. S cht lng tnh l: A. 6 B. 7 C. 5 D. 8 Cu 16: sc 13,44 lt kh CO2(ktc) vo 200ml dd X gm Ba(OH)2 1,5M, v NaOH 1M. Sau p thu c m1 gam kt ta v dd X. Cho dd X tc dng vi 200 ml dd BaCl2 1,2M v KOH 1,5M thu c m2 gam kt ta. Gi tr ca m2 l: A. 47,28g B. 59,1g C. 66,98g D. 39,4g Cu 17: xt p thun nghch sau: SO2 (k) + NO2 (k) SO3 (k) + NO (k) Cho 0,11 mol SO2, 0,1 mol NO2; 0,07 Mol SO3 vo bnh kn 1 lt. Khi t cn bng ha hc th cn lai02 mol NO2. Vy hng s cn bng Kc l: A.20 B.18 C.23 D. 0,05 Cu 18: cht no sau y khng tn ti cu to mng tinh th phn t: A. P trng, than ch B. I2, nc C. kim cng, P D. kim cng, P trng Cu 19: thc hin cc th nghim sau: 1. nung NH4NO3 rn 5. Sc kh SO2 vo dd KMnO4 2. un nng NaCl tinh th vi dd H2SO4 (c) 6. Cho dd KHSO4 vo dd NaHCO3 3. cho CaOCl2 vo dd HCl c 7. Cho ZnS vo dd HCl long 4. sc kh CO2 vo dd Ca(OH)2 d 8. Cho Na2CO3 vo dd Fe2(SO4)3 S th nghim xy ra l: A. 4 B.5 123

C.2 D.6 Cu 20: cho kim loi: Cr, W, Fe, Cu, Cs. Sp xp theo chiu tng dn cng t tri sang phi l: A. Cu < Cs<Fe<Cr<W B. Cu < Cs<Fe<W<Cr C. Cs < Cu<Fe<Cr<W D. Cs < Cu<Fe<W<Cr Cu 21: un nng formandehit vi phenol d c axit lm xc tc thu c polyme c cu trc: A. mch khng phn nhnh B. mng li khng gian C. mch phn nhnh D. khng xc nh Cu 22: t chy hon ton 29,16g hh X gm RCOOH, C2H3COOH, (COOH)2 thu c m gam H2O v 21,952 lt CO2 (ktc). Mt khc, 29,16g hh X p hon ton vi NaHCO3 d thu c 11,2 lt kh CO2 (ktc). Gi tr ca m l: A. 10,8g B. 12,6g C. 9g D. 8,1g Cu 23: cho t t 450ml dd HCl 1 vo 500ml dd X bao gm Na2CO3, NaHCO3 th thu c 5,6 lt kh (ktc) v dd Y. Cho dd Y tc dng vi dd Ba(OH)2 d th thu c 19,7g kt ta. Nng mol ca Na2CO3 v NaHCO3 trong dd X ln lt l: A. 0,2M v 0.5M B. 0,2M v 0,3M C. 0,3Mv0,4M D. 0,4M v 0,3M Cu 24: t chy hon ton m gam cht bo( cha triglixeric v stearic, axit panmitic v cc axit bo t do ) sau p thu c 13,44 lt CO2 (ktc) v 10,44g nc. X phng ha m gamX (H=90%) th thu c khi lng grixerol l: A. 1,656g B. 0,92g C. 2,484g D. 0,828g Cu 25: cho t t 300ml dd NaHCO3 0,1M, K2CO3 0,2M vo 100ml dd HCl 0,2M, NaHSO4 0,6M thu c V lt kh CO2 thot ra ktc v dd X. thm vo dd X 100ml dd KOH 0,6M; BaCl2 1,5M thu c m gam kt ta. gi tr ca V v m l: A. 0,448 lt v 25,8g B. 1,0752 lt v 24,224g C. 1,0752 lt v 23,436g D. 0,448 lt v 11,82g Cu 26: cho C7H16 tc dng vi clo c chiu sng theo t l mol 1:1 thu c hh gm 3 dn xut monoclo. S CTCT ca C7H16 c th c l: A. 5 B. 2 C. 4 D. 3 Cu 27: ha tan hon ton 31,25g hh X gm Mg, Al v Zn trong dd HNO3, sau p hon ton thu c dd Y v hh gm 0,1 mol N2O; 0,1 mol NO. C cn dd sau p thu c 157,05g hh mui. Vy s mol HNO3 b kh trong p l: A. 0,5 mol B. 0,3 mol C. 0,45 mol D. 0,4 mol Cu 28: cho cc dd sau c cng nng mol/lt : NH2CH2COOH (1); CH3COOH (2); CH3CH2NH2 (3); NH3 (4). Th t pH tng dn l: A. 2,1,4,3 B. 1,2,3,4 C. 1,2,4,3 D. 2,1,3,4 Cu 29: 1 mui X c cng thc l: C3H10O3N2. Ly 17,08g X cho p ht vi 200ml dd KOH 2M. C cn dd sau p thu c phn hi v cht rn. Trong phn hi c 1 cht hu c Y (bc 1) trong cht rn ch l cc cht v c. Khi lng ca phn rn l: A. 16,16g B. 28,7g C. 16,6g D. 11,8g Cu 30: M l tri este mch h to bi axit khng no n chc (c 1 lin kt C=C) v ru no ba chc. Bit trong M c % khi lng C l 56,69%. t hon ton 0,1 mol este M thu c bao nhiu mol CO2? A. 1 B. 1,1 C. 1,4 D. 1,2 Cu 31: nhn nh no sau y khng ng: A. tinh bt c 2 loi lin kt -[1,4]-giozit v -[1,6]-glicozit B. phn t mantozo do 2 gc -glucozo lin kt vi nhau qua nguyn t oxi , gc th nht C1, gc th 2 C4 (C1-OC4 ) C. phn t saccarozo do 2 gc -glucozo v -fructozo lin kt vi nhau qua nguyn t oxi, gc -glucozo C1, gc -fructozo C4 (C1-O-C4) D. xenlulozo c cc lin kt -[1,4]-glicozit Cu 32: cho cc polyme sau : PE (1), PVC (2), cao su buna (3), poli isopren(4), amilozo(5), amilopectin(6), xenlulozo(7), cao su lu ha (8), nha rezit(9). Cc polyme c cu trc phn t khng phn nhnh l: A.1,2,3,4,6,7 B. 1,3,4,5,8 C. 1,2,3,4,5,7 D. 1,2,4,6,8 Cu 33: X l 1 ancol c CTPT C3H8On , X c kh nng ha tan Cu(OH)2 nhit thng. S cht c th l X : A. 4 B. 3 C.2 D. 1

124

Cu 34: in phn vi in cc tr dd cha 0,3 mol AgNO3 vi cng dng in l 2,68A, trong thi gian t gi, thu c dd X (H=100%). Cho 22,4g bt Fe vo dd X thy thot ra kh NO( sn phm kh duy nht) v sau qu trnh p hon ton thu c 34,28g cht rn. Gi tr ca t l A. 1 gi B. 0,25 gi C. 1,2 gi D. 0,6 gi Cu 35: ha tan Fe3O4 trong lng d dd H2SO4 long d thu c dd X. Dd X tc dng c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al, H2S A. 7 B. 5 C. 6 D. 8 Cu 36: khi nhit phn hon ton m gam mi cht sau: KClO3 (xt MnO2), KMnO4, KNO3, AgNO3. Cht to ra lng oxi nhiu nht l: A. KNO3 B. AgNO3. C. KMnO4 D. : KClO3 (xt MnO2) Cu 37: gi s gang cng nh thp l hp kim ca Fe v cacbon v st ph liu ch gm Fe, cacbon v Fe2O3. Coi p xy ra trong l martanh l : Fe2O3 + 3C 2Fe + 3CO Khi lng st ph liu (cha 40% Fe2O3, 1%C) cn dng luyn vi 6 tn gang 5%C trong l luyn thp Martanh, nhm thu c loi thp 1%C l: A. 1,98 tn B. 1,82 tn C. 2,93 tn D. 2,73 tn Cu 38: cho dy cc cht sau: CrO3, Cr2O3, SiO2, Cr(OH)3, CrO, Zn(OH)2, NaHCO3, Al2O3. S cht trong dy tc dng vi dd NaOH c,nng l: A. 7 B. 6 C. 4 D. 5 Cu 39: cho dy cc cht sau: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin, vinyl clorua. S cc cht trong dy khi thy phn trong dd NaOH long d, un nng sinh ra ancol l: A. 3 B. 6 C. 4 D. 5 Cu 40: cho cc p: 1. Zn + HCl long 4. Cu + H2SO4c 2. Fe3O4 + H2SO4 long 5. Al +H2SO4 long 6. FeSO4 + KMnO4 + H2SO4 3. KClO3 + HCl c S p m H+ ca axit ng vai tr l cht oxi ha l: A. 6 B. 2 C. 5 D. 3 II.phn ring (10 cu) cho th sinh c chn lm 1 trong 2 phn ( phn I hoc phn II) Phn I: theo chng trnh chn ( t cu 41 n cu 50) Cu 41: ha tan hon ton m gam st trong dd HNO3 thy c 0,3 mol kh NO2 sn phm kh duy nht thot ra, nh tip dd HCl va vo li thy 0,02 mol kh NO duy nht thot ra. C cn dd sau p thu c cht rn c khi lng l: A. 24,27g B. 26,92g C. 19,5 D. 29,64g Cu 42: trong cc cht : propen (I), 2-metylbut-2-en (II), 3,4-dimetylhex-3-en (III), 3-clopro-1-en (IV) ; 1,2 dicloenten (V). Cht no c ng phn hnh hc: A. I,V B. III, V C. II, IV D. I,II,III, IV Cu 43: cc kh thi cng nghip v ca xe t, xe my... l ngyn nhn ch yu gy ra ma axit. Thnh phn ha hc ch yu trong cc kh thi trc tip gy ra ma axit l: A. SO2, CO, NO B. NO2, CO2, CO C. NO, NO2, SO2 D. SO2, CO, NO2 Cu 44: cho p 1. Ca(OH)2 + Cl2 4. H2S + SO2 2. NO2 +NaOH 5. KClO3 + S 3. PbS + O3 6. Fe2O3 + HCl S p oxi ha l: A. 2 B. 5 C. 4 D. 3 Cu 45: dy gm cc cht c th iu ch trc tip thnh axit axetic l: A. C2H5OH, CH3CHO, CH3COOCH3 B. C2H5OH, CH3CHO, HCOOCH3 C. C2H2, CH3CHO, HCOOCH3 D. C2H5OH, HCHO, CH3COOCH3 125

Cu 46: c cc dd sau: (vi dung mi l nc) CH3NH2 (1), anilin (2), amoniac(3), HOOC-CH(NH2)-COOH (4), H2N-CH(COOH)-NH2 (5), lysin (6), axit glutamic (7). Cc cht lm qu tm chuyn thnh mu xanh l: A. 1,2,3 B. 1,3,5,6 C. 1,2,3,5 D. 1,2,3,4,5 Cu 47: tch ring Ag ra khi hh Ag, Cu, Ni, Fe dng bt. Dd cn dng l ( vn gi nguyn khi lng ban u) B. dd H2SO4 long A. dd FeCl3 C. dd HNO3 c ngui D. dd HCl Cu 48: oxi ha hon ton 0,16mol hh gm ancol etylic v 1 ancol n chc X bng CuO nung nng (H=100%) thu c hh cht hu c Y. Cho hh Y p vi AgNO3 trong dd NH3 d thu c 51,84g Ag. Tn gi ca X l: A. propan-1-ol B. 2-metylpropan-2-ol C. propan-2-ol D. metanol Cu 49: cho lung kh H2 d qua hh cc oxit CuO, Fe2O3, K2O, MgO. Nung nng nhit cao. Sau p thu c hh rn cn li l: A. Cu,Fe,K2O,Mg B. Cu,Fe,K2O,MgO C. Cu,FeO,KOH,MgO D. Cu,Fe,KOH,MgO Cu 50: X l mt -aminoaxit no, cha 1 nhm COOH v 1 nhm NH2. T m gam X iu ch c m1 gam dipeptit. T 2m gam X iu ch c m2 gam tripeptit. t cht m1 gam dipeptit thu c 0,3mol nc. t chy m2 gam tripeptit thu c 0,55 mol H2O. Gi tr ca m l: A. 11,25g B. 13,35g C. 22,5g D. 26,7g

1 A 21 A 41 B

2 C 22 B 42 B

3 A 23 D 43 C

4 C 24 D 44 B

5 B 25 A 45 A

6 B 26 C 46 B

7 C 27 D 47 A

8 C 28 A 48 D

9 C 29 B 49 D

10 A 30 D 50 A

11 D 31 C

12 C 32 C

13 A 33 C

14 C 34 C

15 A 35 D

16 B 36 D

17 A 37 D

18 B 38 A

19 D 39 C

20 D 40 B

10 Cu 1: Nguyn t ca nguyn t X c electron mc nng lng cao nht l 4s. Nguyn t ca nguyn t Y c phn lp electron ngoi cng l 3p. Tng s electron phn lp ngoi cng ca X v Y l 7. Bit X v Y d dng phn ng vi nhau. Hp cht gia X v Y c dng: A.XY2 B. XY C.X3Y2 D.X2Y Cu 2: Tn l st trng km, nu khi tn b n mn in ha th trong qu trnh n mn: A. Km l cc dng v b oxy ha B. St l cc m v b oxy ha C. St l cc dng v ion H+ b oxy ha D. Km l cc m v b oxy ha Cu 3: cho phn ng : CH3-CCH + KMnO4 + KOH CH3COOH + MnO2 + K2CO3 + H2O Tng cc h s (nguyn ti a) ca cc cht trong phn ng l: A.28 B. 27 C. 21 D. 19 Cu 4: in phn dung dch 500ml dd hn hp CuSO4 v NaCl bng in cc tr vi cng dng in 10A n khi nc b in phn c 2 in cc th dng li mt thi gian l 5790 giy. Dung dch thu c sau in phn ha tan va 4g MgO. CM ca NaCl l? A.3,2M B.1,6M C.0,8M D.0,4M Cu 5: Trn 100ml dung dch CH3COOC2H5 1M vi 100ml dug dch NaOH 1M. Sau 15 pht nng CH3COOC2H5 cn li l 0,2M. Tc trung bnh ca phn ng trong 15 pht l? A.0,033mol/lt.pht. B.0,02mol/lt.pht C.0,01mol/lt.pht. D.0,0133mol/lt.pht Cu 6: C cc dung dch ring bit nh sau: C6H5-NH3Cl ; H2N-CH2-CH2-CH(NH2)-COOH ; ClH3N-CH2-COOH ; C6H5CH2NH2 ; HOOC-CH2-CH2-CH(NH2)-COOH ; H2N-CH2-COONa. S lng cc dung dch c pH > 7 l? A.2 B.5 C.4 D.3 Cu 7: Hn hp X c t khi so vi H2 l 28,7 gm C3H9N, C3H5N, C3H7N. Khi t chy hon ton 0,1 mol X, tng khi lng CO2 v H2O thu c l? 126

A.19,6g B.16,9g C.18,96g D.19,86g Cu 8: t chy hon ton 100 ml hn hp gm imetylamin v 2 hidrocacbon ng ng k tip thu c 140 ml CO2 v 250 ml hi nc (tt o cng k). Thnh phn % th tch ca cc cht trong hn hp theo tng phn t khi ln lt l? A. 60, 20, 20 B. 25, 25, 50 C. 30, 30, 40 D. 40, 30, 30 Cu 9: ng vi cng thc phn t C3H9O2N c bao nhiu cht va phn ng c vi dung dch NaOH va phn ng c vi dung dch HCl? A.4 B.3 C.2 D.5 Cu 10: Hp cht hu c C4H7O2Cl khi thy phn trong mi trng kim thu c cc sn phm trong c hai cht c kh nng phn ng trng Ag. Cng thc ng ca cht hu c trn l? A.HCOO-CHCL-CH2-CH3 B.HCOO-CH2-CHCl-CH3 C.CH3COO-CHCl-CH3 D.HCOO-CH2-CH2-CH2Cl Cu 11: Khi cho 1 mol andehit A mch h tc dng va vi a mol H2 thu c 1 mol ancol B. Cho 1 mol ancol B tc dng vi Na d thu c b mol H2. Bit a = 4b. A thuc dy ng ng no trong s cc ng ng sau: A.andehit 1 ni i C=C, n chc B.Andehit no, n chc C.Andehit no, hai chc D.andehit 1 ni i C=C, hai chc. Cu 12: Cho FeCl3, CuSO4, HNO3 long, HI, NaCl, Pb(NO3)2, AgNO3, H2SO4 c nng, KNO3. Thm bt Fe d ln lt vo cc dd trn th s trng hp to mui Fe(II) l: A.8 B.7 C.5 D.6 Cu 13: Cho hh X gm ancol etilic v ancol CnHm(OH)3 thnh 2 phn bng nhau: Phn 1 tc dng ht Na thu c 15,68 lt H2 kc. t chy hon ton phn 2 thu c 35,84 lt kh CO2 kc v 39,6 gam H2O. CTPT ca X l? B. C4H10O3 A. C3H8O3 C. C6H14O3 D. C5H12O3 Cu 14: X l hh ca N2 v H2 c t khi hi so vi H2 l 6,2. Nung nng X trong 1 bnh kn c xt thu c hh c d/H2 l 7,75. Hiu sut p tng hp NH3 l: A.25% B.40% C.50% D.75% Cu 15: Cho m gam hh X gm FeO, Fe2O3 v Fe3O4 tc dng va vi dd H2SO4 long d thu c dd B. C cn dd B thu c 55,2 gam mui khan. Nu cho B tc dng vi Clo d thu c 58,75 gam mui. Gi tr ca m? A.46,4 B.39,2 C.15,2 D.23,2 Cu 16: Ha tan hon ton 30 gam hn hp X gm Mg, Al, Zn trong dung dch HNO3 d thu c dung dch Y v hn hp kh gm 0,1 mol N2O v 0,1 mol NO. C cn dung dch sau phn ng thu c 127 gam mui khan. S mol HNO3 tham gia phn ng l? A.5 B.1,9 C.2,2 D.1,8 Cu 17: Hidrocacbon X c thnh phn khi lng l 92,30% cacbon v 7,70% hidro. t chy hon ton 0.01 mol X ri dn sn phm chy vo bnh ng dd NaOH d thy khi lng bnh NaOH tng 4,24 gam. Cng thc phn t ca X l? B.C8H10 C.C4H4 D.C8H8 A.C6H6 Cu 18: C bao nhiu hidrocacbon mch h trong phn t ch c mt lin kt bi khi tc dng vi H2 (Ni, to) thu c isopentan? A.3 B.4 C.2 D.1 Cu 19: Hidrat ha hon ton hn hp X cha C2H4 v C3H6 c t khi i vi H2 bng 18,2; thu c hn hp ancol. Trong t l s mol gia ru bc hai so vi bc mt l 2:3. % khi lng ca propan 1-ol- trong hn hp to thnh l? A.22,06% B.34,52% C.44,12% D.40,21% Cu 20: Cho s 3-metylbutan-1-olXY(sp chnh)ZT Cht T c tn thay th l? A.2-metylbutan-3-on B.metyl isopropyl xeton C.3-metylbutan-2-ol D.3-metyl butan-2-on Cu 21: Dy gm cc cht u tc dng c vi dd AgNO3/NH3: A.mantoz, but-1-in, etylen B.etylfomiat, axetylen, saccaroz C.benzadehit, but-2-in, axetylen D.axitfomic, vinylaxetylen, propin Cu 22: Cho cc cht: CaCO3, Fe(NO3)2, FeS, CuS, NaCl. V cc dd: HCl, H2SO4 long. Nu cho ln lt tng cht rn vo tng dd, th s phn ng xy ra l? A.4 B.5 C.6 D.7 Cu 23: Cho t t tng git 500ml dung dch cha Na2CO3 0,105M v KHCO3 0,18M vo 100ml dung dch HCl 1,5M, cho n khi kh ngng thot ra th thu c V lt CO2. Gi tr V l? A.2,184 B.1,008 C.1,176 D.1,68 127

Cu 24: Hn hp X gm Na, Ba, Na2O, BaO. Ha tan ht 107,9 gam hn hp X vo nc thu c 7,84 lt H2(ktc) v dung dch kim Y, trong c 28 gam NaOH. Hp th 17,92 lt kh SO2 (ktc) vo dung dch Y thu c m gam kt ta. Gi tr ca m l? A.130,2 gam B.173,6 gam C.108,5 gam D.21,7 gam Cu 25: Cho p tng hp NH3; 2NH3. H < 0 N2 + 3H2 Khi p t n cn bng th t khi hi ca hh kh torng bnh so vi H2 l d1. un nng bnh 1 thi gian t n trng thi cn bng mi th t khi hi ca hh kh trong bnh so vi H2 l d2. So snh d1 v d2 th: A. d1 < d2 B. d1 > d2 C. d1 = d2 D. d1 d2 Cu 26: Ha tan hon ton 0,5 mol hn hp gm Al v Al4C3 vo dung dch HCl (d), thu c a mol hn hp kh v dung dch X. Cho dd NH3 d vo dung dch X, lng kt ta thu c l 62,4 gam. Gi tr cu a l? A.0,55 B.0,60 C.0,50 D.0,90 Cu 27: Cho m gam hn hp X gm Fe v Fe3O4 tc dng vi 200 ml dung dch HNO3 3,2M, un nng v khuy u. Sau khi cc phn ng xy ra hon ton, thu c 2,24 lt kh NO (sn phm kh duy nht, ktc), dung dch Y v cn li 1,46 gam kim loi. Gi tr ca m l A. 17,04. B. 18,5 C. 19,2 D. 20,42 Cu 28: Ha tan hh gm Al, Fe, CuZn vo dd HCl d. Phn ng xong ly phn dung dch cho tc dng vi dd NH3 d c kt ta Y. Nung Y trong khng kh n khi lng khng c rn Z. Dn lung kh CO d qua Z thu c rn T. (cc phn ng hon ton) Rn T gm: A. Cu, Al2O3Fe B. Cu, Fe C. Al2O3, Fe D. Zn, Al2O3, Fe Cu 29: Cc tc nhn ha hc gy nhim mi trng nc: 1. Cc ion kim loi nng: Pb2+ , Hg2+ , Cd2+ , Ni2+ , Cu2+ 2. Cc anion: NO3-, PO43-, SO423. Thuc bo v thc vt, phn bn ha hc. A. 1,2 B. 1,3 C. 2,3 D. 1,2,3 Cu 30: phn bit 3 dung dch Na2CO3 (1); Na2CO3, NaHCO3 (2); NaHCO3 (3) c th dng cc dung dch: A. KOH, H2SO4. B. NH4Cl, H2SO4 C. NaCl, HCl D. BaCl2, H2SO4 Cu 31: Nung 4,46 gam hn hp X gm cc kim loi: Fe, Al, Zn, Mg trong oxi, sau mt thi gian thu c 5,42 gam hn hp Y. Ha tan hon ton Y vo dung dch HNO3 (d) th s mol HNO3 phn ng l 0,36 mol. Sau phn ng thu c V lt kh NO (sn phm kh duy nht ktc). Tnh V lt kh NO A. 0,12 B. 0,896 C. 1,344 D. 0,672 Cu 32: Cho a gam hh X gm Cu, Zn, Mg tan hon ton trong H2SO4 c nng thu c 7,84 lt SO2 ktc. Nu cho a gam hh X vo 400ml dung dch CuSO4 1M thu c bao nhiu gam cht rn A. 28 g B. 12,8 g C.22,4 g D. 25,6 g Cu 33:Th nghim no sau y khi hon thnh khng c kt ta: A. Dung dch AlCl3 d vo dung dch NaOH B. Cho Ba kim loi vo dung dch NH4HCO3. C. Cho dung dch Na[Al(OH)4] vo dung dch NH4Cl D. Cho HCl d vo dung dch Natri aluminat Cu 34: Trong phn t butadiene-1,3 c: A. 2 lin kt , 2 lin kt B. 2 lin kt , 7 lin kt C. 2 lin kt , 9 lin kt D. 4 lin kt , 7 lin kt Cu 35: Cho 100 ml dung dch hh CuSO4 1M v Al2(SO4)3 1,5 M tc dng vi dung dch NH3 d, lc ly kt ta em nung n khi lng khng i thu c cht rn c khi lng l: A. 23,3 g B. 30,6 g C. 15,3 g D. 8,0 g Cu 36: X phng ha hon ton 1 kg mt loi cht bo gm triolein v axit bo t do c ch s axit l 7 cn dng 3,125 mol KOH. Khi lng x phng thu c l: A. 1080,75 g B. 1083 g C. 733 g D. 896,75 g Cu 37: Cho cc nhit si: 100,70 C, 210 C, -230 C, 78,30 C. l nhit si tng ng ca: A. HCOOH, CH3OCH3, CH3CHO, C2H5OH B. C2H5OH, CH3OCH3, CH3CHO, HCOOH C. HCOOH, CH3CHO, CH3OCH3 , C2H5OH D. HCOOH, CH3CHO, C2H5OH, CH3OCH3 Cu 38: un nng dung dch cha 18 gam hh gm glucoz v fructoz vi lng dung dch AgNO3 / NH3 n phn ng hon ton thu c m gam Ag. Gi tr ca m: A. 21,6 g B. 10,8 g C. 43,2 g D. 5,4 g Cu 39: Cht hu c A l este ca amino axit cha mt chc NH2 v mt chc COOH hm lng Nit trong A l 15,73 %. X phng ha m gam cht A, hi alcon bay ra cho i qua CuO un nng c Andehit B. Cho B thc hin phn ng trng gng thy c 16,2 gam Ag kt ta. Gi tr ca M: A. 7,725g B. 6,675g C.5,625g D. 3,3375g Cu 40: Nhm cc vt liu c ch to t polyme trng ngng l: A. Cao su, nilon-6,6; t nitron B. Nilon-6,6; t lapsan, nilon-6 128

C. Nilon-6,6; t lapsan, PVC D. PVA, nilon-6, nilon-7 Cu 41: Cht X c CTPT C5H10. Khi hydro ha X thu c cht Y ln l 2-metyl butan. Cho X tc dng vi HCl thu c sn phm chnh l cht Z. Khi thy phn Z thu c Ancol bc 2 T. X l: A. pent-2-en B. 2-metylbut-1-en C. 3-metylbut-1-en D. 2-metylbut-2-en Cu 42: Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol axit no, hai chc, mch h. X phn ng ti a vi 2 mol HCl hoc 3 mol NaOH. t chy hon ton thu c N2, 10 mol CO2, x mol H2O. Gi tr ca x? A. 10 B. 9 C. 11 D. 12 Cu 43: Cho 20 ml cn tc dng vi Na d thu c 0,76 gam H2 (D C2H5OH= 0,8 g/ml). ru trong loi cn trn l: A. 69 o B. 46 o C. 76 o D. 92 o Cu 44: C bao nhiu hp cht thm c CTPT C8H10O tc dng Natri v oxi ha vi CuO to sn phm trng gng c. A. 4 B. 2 C. 3 D. 5 Cu 45: Trieste X c to thnh t glyxerol v 2 axit cacboxylic n chc mch h Trong phn t X, th t l m C: mO=7:8. Khi cho m gam X tc dng vi dung dch NaOH d th lng NaOH phn ng l 6g. Gi tr ca m l: A. 9,5 g B.29,5 g C. 4,6 g D. 16,5 g Cu 46: X phng ha hon ton 20,4 g cht hu c X n chc bng dd NaOH thu c mui Y v cht hu c Z. Nung Y vi NaOH rn cho kh R ln. Bit d R/ O2 = 0,5. Cho Z tc dng vi Na thu c 2,24 l H2 kc. Z tc dng vi CuO nng cho sn phm tham gia phn ng trng bc. Vy X l: A. Etyl axetat B. Isopropyl axetat C. Etyl propyonat D. Propyl axetat Cu 47: t chy a mol X l este ca glyxerol v 3 axit n chc thu c b mol CO2 v c mol H2O vi b-c = 4a. Hyro ha hon ton m gam X cn 6,72 l H2 ktc thu c 36,9g Y. Nu un m gam X vi dd NaOH va thu c bao nhiu gam mui khan? A. 40,5 g B. 39,7 g C. 42,6 g D. 41,4 g Cu 48: X l mt amino axit h no c mt nhm COOH v mt nhm NH2 t m gam X iu ch c 1 m1 gam ipeptit. T 2m gam X iu ch c m2 gam tripeptit. t chy hon ton m1 gam ipeptit thu c 0,3 mol nc. t chy hon ton m2 gam tripeptit thu c 0,55 mol nc. Gi tr ca m l: A. 11,25 B. 13,35 C. 2,5 D. 26,7 Cu 49: Hp cht thm X c cng thc cu to C8H8O2 khi phn ng vi dd NaOH thu c 2 mui. S ng phn cu to ca X l: A. 4 B. 3 C. 2 D. 5 Cu 50: Cho phng trnh ha hc sau y: a. Al4C3 + 12 H2O 4 Al(OH)3 + 3 CH4 b. Al + 3H2O + NaOH Na[Al(OH)4] + 3/2 H2 c. C2H2 + H2O CH3CHO d. C2H5Cl + H2O C2H5OH + HCl e. 2NaH + 2 H2O 2NaOH + H2 f. 2 F2 + 2 H2O 4 HF + O2 C bao nhiu phn ng ha hc trong s cc phn ng trn, trong H2O ng vai tr cht oxy ho A. 1 B. 2 C. 3 D. 4 1 A 21 D 41 C 2 D 22 C 42 A 3 A 23 A 43 B 4 C 24 A 44 A 5 B 25 B 45 A 6 D 26 D 46 D 7 D 27 B 47 A 8 A 28 C 48 A 9 A 29 B 49 A 10 A 30 D 50 B 11 A 31 C 12 B 32 C 13 A 33 D 14 C 34 C 15 D 35 C 16 B 36 A 17 D 37 C 18 B 38 A 19 A 39 D 20 D 40 B

11 Cu 1: trong cc loi t sau : t visco , t xenlulozo axetat, t nitron, t lapsan, nilong-6,6. s loi t c iu ch bng phng php trng ngng l: A. 1 B. 2 C. 3 D. 4 Cu 2: cho phn ng : FeS2 + H2SO4 ,nng Fe2(SO4)3 + SO2 + H2O Tng h s cn ban82ng nguyn ti gin ca cc cht tham gia l A. 20 B. 14 C. 18 D. 16 Cu 3: cho dung dch cha m gam hn hp gm nhng lng bng nhau v s mol ca mantozo v saccarozo tc dng vi lng d dung dch AgNO3/ NH3 thu c 21,6 gam Ag. Gi tr ca m l A.17,1 gam B. 34,2 gam C. 36,0 gam D.68,4 gam 129

Cu 4: trong cc cht : propen(1) ; 2 metyl-but-2en(II); 3,4- imetylhex-3-en(III); 3-cloprop-1-en(VI); 1,2 icloeten(V) . nhng cht c p hnh hc: A. I,V B. III,V C. II, IV D. I,II,III,VI Cu 5: pht biu ng l ; A. tripeptit l peptit trong phn t cha 3 lin kt peptit (-CO-NH-) v 2 gc amino axit B. cc peptit u tc dng vi Cu(OH)2 trong mi trng kim to phc cht mu tm C. phn t khi ca cc aminoaxit c 1 chc NH2 v 1 chc COOH lun lun l s chn D. im khc nhau gia protein vi cacbohidrat v lipit l phn t protein lun cha nit Cu 6: ba cht hu c c cng thc phn t ln lt l : (X) C2H6O2 , (Y) C2H2O2, v (Z) C2H2O4. trong phn t mi cht trn ch c cha 1 loi nhm chc . khi cho 3 cht tc dng vi Cu(OH)2 iu kin thch hp th cc cht c kh nng phn ng l : A. X v Y B. X v Z C. Y v Z D. X, Y v Z Cu 7: hp cht ion G to nn t cc ion n nguyn t M2+ v X2-. Tng s ht (notron, proton, v eclectron) trong phn t G l 84, trong s ht mang in nhiu hn khng mang in l 28 ht. s ht mang in ca ion X2- t hn s ht mang in ca ion M2+ l 20 ht . v tr ca M trong bng tun hon l A. 20, chu k 4, nhm II A B. 12, chu k 3, nhm II A C. 8, chu k 2, nhm VI A D. 26, chu k 4, nhm VIII B Cu 8: s ng phn ankahn C7H16 khi phn ng vi Cl2 to hh gm 3 p monocle A. 5 cht B. 4 cht C. 2 cht D. 3 cht Cu 9: cho hn hp gm 1,2 mol Mg v 1,2 mol Zn vo dung dch cha 2 mol Cu2+ v 1mol Ag+ n khi cc phn ng xy ra hon ton , thu c mt dung dch X . nh dd NaOH d vo dd X thu c a gam kt ta. gi tr ca a l: A. 72,4 B.69,6 C.79,4 D.89,2 Cu 10: cho hn hp X c C2H5OH, C2H5COOH, CH3CHO trong C2H5OH chim 50% theo s mol . t chy m gam hh X thu c 3,06gam H2O v 3.136 lt CO2(ktc) . mt khc 13,2gam hn hp X thc hin phn ng trng bc thy c a gam kt ta Ag . gi tr ca m l: A. 2,16 B 8,64 C.10,8 D. 9,72 Cu 11: cho s phn ng C2H2XY CH3COOH Trong cc cht : CH4, C2H4, CH3CHO, CH3COOCH=CH2 th s cht ph hp vi X theo s trn l A.4 B.3 C.2 D.1 Cu 12: cho cc phn ng sau (1) C6H5NH2 + HNO2 + HCl (2) C2H5NH2 + HNO2 (3) C6H5NH2 + HNO2 (4) H2NCH2COOH + HNO2 (5)CH3NH2 + HNO3 (6) C2H5NH2+ CH3Cl Cc phn ng to kh N2 l: A. 2,4,6 B.2,3,4 C.1,2,4,5 D.2,3,4,6 Cu 13: x phng ha hon ton 5g cht hu c X n chc bng dd NaOH thu c mui Y v cht hu c Z. cho Z tc dng vi dd AgNO3/NH3 d thu c 10,8 gam Ag. Nung Y vi NaOH rn cho kh R. bit d ( R/O2)=0,5, X l A.CH3CH2COOH=CH2 B. CH3COOHCH2=CH2 D. CH3COOH=CHCH3 C. CH3COOH=CHCH2CH3 Cu 14: t chy hon ton 7,2 gam mt axit cacboxylic X mch khng phn nhnh thu c 13,2 gam CO2 v 3,6 gam H2O. cng thc phn t ca X l : A. C3H4O2 B. C3H6O2 C. C3H4O2 hoc C6H8O4 D. C6H4O2 Cu 15: t chy hon ton mt este n chc , mch h X trong phn t c ti a 2 lin kt , thu c th tch kh O2 phn ng bng 9/8 th tch kh CO2(cc kh o cng iu kin). cho m gam X tc dng hon ton vi 200ml dung dch NaOH 0,75 M thu c dung dch Y. c cn Y thu c 11,04gan cht rn khan. Bit khi un Y vi dd AgNO3/NH3 c Ag xut hin . gi tri ca m l: A.10,56 B.8,6 C. 8,88 D.10,32 Cu 16: cho 1 cht X tc dng vi dd H2SO4 , nng d thy xut hin SO2 l sn phm kh duy nht . nu s mol H2SO4 p : s mol SO2= 4:1 th X c th l: A. Fe B. FeS C. Fe3O4 D. FeO Cu 17: dy cht no sau y ch gm cc cht ch c tnh oxi ha : A. Cl2, H2O2, HNO3, H2SO4. B. SO2, SO3,Br2, H2SO4 c. Fe(NO3)3, CuO, HCl, HNO3 D. O3, Fe2O3,H2SO4,O2 Cu 18: dung dch A gm NaOH x M, v Ba(OH)2 y M, ly 100ml dd A trn vi 400ml dd AlCl3 0,1M . mt khc , 100ml dd A tac dng vi dd Na2SO4 d thu c 2,32 gam kt ta. t l x:y l: A. 2:3 B.1:2 C. 2:1 D.1:1 Cu 19: cho 18,5 gam rn Fe,FeO,Fe2O3, v Fe3O4 vo cc ng 200ml dd HNO3 long . sau khi p xong c 2,24l(ktc) NO l sn phm kh duy nht v cn li l 1 cht rn nng 1,46gam l st . ch ra nng mol dd HNO3 A. 2M B. 1M C.3,2 D. 2,5M Cu 20: cho cc axit HF, HCl, HBr, HI, HNO3. s axit1 co th iu ch theo s : NaX(r) +H2SO4() NaHSO4+ HX ( X l gc axit). A. 2 B.4 C.3 D.5 130

Cu 21: C bao nhiu hp cht hu c mch h c M = 60vC, tc dng c Na hoc NaOH? A. 5 B. 4 C. 3 D. 2 Cu 22 : cho 0,02 mol Oleum H2SO4.nSO3 vo nc thnh 200ml dd . ly 10ml dd ny trung ha va vi 16ml dd NaOH 0,5M . gi tri ca n l A. 4 B.2 C. 3 D.1 Cu 23: cho 3 kim loi X,Y,Z bit E0(X2+/X) =-0,76V v E0(Y2+/Y) =-+0,34V Bit E0 ca pin X/Z= +0,63V th E0 ca pin Z/Y l: A.0,47V B.1,73V C.2,49V D. 0,21V Cu 24: cho hh 2 kim loi Mg v Zn vo dd cha 2 mui Fe2(SO4)3 v CuSO4 n p hon ton thu c cht rn A v dd B cha 3 cation kim loi . 3 cation kim loi l: A. Mg2+, Cu2+, Fe2+ B. Fe2+, Zn2+, Mg2+ 2+ 2+ 2+ C. Mg ,Zn , Cu D. Fe3+,Cu2+, Mg2+ cu 25: ha tan 58,4 gam hh mui khan AlCl3 v CrCl3 vo nc . them d dd NaOH sau tip tc cho them nc Clo ri li cho them d dd BaCl2, thu c 50,6g kt ta. thnh phn % khi lng AlCl3 l A. 45,72% B. 46,80% C. 47,50% D. 48% Cu 26: ha tan hon ton 16,32 gam hh bt X gm Fe, Cu, FexOy v CuO bng dd HNO3 long, d. Sau P thu c 2,688 lt NO ( kc) sn phm kh duy nht v dd cha 54,84gam hh mui nitrat. Nu cho 16,32gam X tc dng vi CO d th th tch CO cn dng (kc) l A. 2,688 lt B. 4,48 lt C. 3,36 lt D. 3,584 lt Cu 27: pht biu no sau y l khng ng A. phn ure c cng thc l ( NH2)2CO. B. B. phn hn hp cha nito, photpho,kali c gi chung l NPK C. Ch nn bn phn m amoni cho loi t t chua D. Amophot l hn hp ca 2 mui (NH4)2HPO4 v KNO3 Cu 28: X l hecxapeptit Ala-Gly-Ala-Val-Gly-Val. Y l tetrapeptit , Gly-Ala-Gly-Glu. Khi thy phn m gam X v Y trong mi trng axit thu c 4 loi aminoaxit trong c 30g glixin v 28,48 gam alanin . gi tri ca m l: A.87,4 B.73,4 C.77,6 D.83,2 Cu 29: ha tan m gam Al,Mg vo HCl d c 5,6 lt kh (kc) bay ra . cho m hh ny vo 200ml dd gm AgNO3 1M v Cu(NO3)2 0,8M. phn ng xong c bao nhiu gam kt ta. A. 43,2gam B.31,2 gam C.28gam D.24,8gam Cu 30:dung Co d kh hon ton m gam FexOy , dn ton b kh sinh ra vo 1 lt dd Ba(OH)2 0,1M thu c 0,05 mol kt ta. mt khc ha tan m gam FexOy bng dd HCl d ri c cn thu c 16,25 gam mui khan . gi tri ca m l A. 16 gam B.15,1 gam C.8 gam D.11,6 gam Cu 31; cho m gam hh X gm 2 mui cacbonat trung ha ca 2 kim loi ha tr II. Sau mt thi gian thu c 3,36 lt CO2(kc) v rn Y. choY tc dng ht vi dd HCl d, kh thot ra hp th hon ton vo dd Ca(OH)2 d , c 15gam kt ta. phn dd em c can thu c 32,5 g hh mui khan. Gi tri ca m l: A. 29,2gam B.35,8gam C.30,85gam D.27,55 gam Cu 32: hp th hon ton 2,24 lt CO2(kc) vo 100ml dd gm K2CO3 0,2M v KOH 0,4M , sau khi cc p xy ra hon ton thu c dd Y . cho ton b Y tc dng vi dd BaCl2 d thu c m gam kt ta. gi tr ca m l: A. 98,5 B.7,88 C.15,76 D.11,82 Cu 33: hh Z gm 1 ancol no n chc v 1 axit no n chc . t khi ca Z so vi H2 bng 21,25. dt chy hon ton 0,2 mol Z thu c 0,3 mol CO2 . cng thc ca ancol v axit ln l;t l : A. CH4O v C2H4O2 B. C2H6Ov C2H4O2 C. CH4O v C3H6O2 D. CH4O v C4H8O2 Cu 34: kh X to kt ta vi dd AgNO3 , lm mt mu dd KMnO4 , tc dng vi Clo , khng tn ti trong hh vi SO2, kh X l: B. H2S C. CO2 D. NH3 A. C2H2 Cu 35 : thc hin cc th nghim: (1) nung hh Fe +S ( r), (2) dd AgNO3 + dd Fe(NO3)2 , (3) Au + dd HNO3 c , nng ,(4) Fe + dd FeCl3, (5) nung hh Cu + Cu(NO3)2 rn , (6) nung CuO + H2, (7) Mg + dd NaHSO4 . s trng hp xy ra p oxi ha kim loai l: A.4 B. 5 C.3 D.2 Cu 36: trn 12 g hh bt Cu, Fe vi 8gam S thu c hh X . nung X trong bnh kn khng c khng kh , sau 1 thi gian thu c hh Y. ha tan ht Y trong dd HNO3 , nng, d thu c kh NO2 duy nht v dd gm 2 mui sunfat . % khi lng CU trong hh l A.61,36 % B.63,52% C.55,14% D.53,33% Cu 37: cho cc phn ng sau: a. H2S + FeSO4 b. Fe(NO3)2+ AgNO3 c. Cu + HCl+NaNO3 d.FeS2 + H2SO4 long e. CuS + H2SO4 long f. FeSO4 + Cu(NO3)2 131

g. Mg(HCO3)2 + NaHSO4 h.O3+KI+H2O s lng p xy ra l A.7 B.4 C.6 D.5 Cu 38: hn hp X gm 1 hidrocacbon mch h A ( c 2 lin kt trong phn t) v H2 c t khi so vi H2 l 4,8. un nng X vi xc tc NI p xy ra hon ton thu c hh Y c t khi so vi H2 l 8. cng tha ca A l: B. C4H6 C. C2H2 D. C5H8 A. C3H4 Cu 39: X c CTPT l C5H10 t X c s sau: Xancol A bc 2Y ancol B bc 3 . vi A,Y,B l cc sn phm chnh. vy CTCT ca X l : A. CH3-CH=CH-CH2-CH3 B. CH3-CH2-CH2-CH=CH2 C. CH3-C(CH3)=CH-CH3 D. CH3-CH(CH3)-CH=CH2 Cu 40: hidrocacbon E c cng thc nguyn l (CH)n vi n < 7 . E tc dng vi dd AgNO3/NH3 d, c kt ta F. khi lng phn t ca E v F khc nhau 214 vC. S CTCT ph hp ca E l : A.1 B.2 C.3 D.4 Cu 41: t chy hon ton m gam cht bo X ( cha triglyxerit ca axt stearic, axit panmitic v cc axit bo t do ). Sau p thu c 13,44 lt CO2 v 10,44 gam nc . x phng ha m gam X( H= 90%) th thu c khi lng glixerol l: A. 1,656 B.0,92 C.2,484 D.0,828 Cu 42: cho cc cht thm : CH3C6H4OH, C6H5CH2OH, C6H4(OH)2 ,C6H5OCH3, C6H5NH3Cl CH3C6H4NH2. s cht tc dng vi nc Brom l, A. 3 B.2 C.5 D.4 Cu 43: khi thy phn hon ton 0,1 mol triglixeric X bng dd NaOH thu c 0,1 mol mui Natri ca axit panmitic v 0,2 mol mui natri ca axit stearic . CTPT ca X l : A. C51H106O6 B. C55H102O6 C. C51H100O6 D. C55H106O6 Cu 44: un nng hp cht c vng thm Cl-CH2C6H4-Cl vi dd NaOH c d sn phm thu c c cht no? A.OH-CH2C6H4-Cl B. Cl-CH2C6H4-OH C. OH-CH2C6H4-ONa D. NaO-CH2C6H4-ONa Cu 45: un nng 1 ancol n chc A vi KBr v H2SO4 c , thu c hp cht B trong Br chim 58,4% . nu un B 1700C thu c 3 anken ng phn. Tn ca A l: A.pentan-2-ol B. 2-metyl butan-2-ol C.butan-2-ol D. 2-metyl propan-2-ol Cu 46: mt s hp cht hu c n chc c CTPT C4H8Oz c kh nng tham gia p trng gng. S CTCT c th c l : A. 2 B.4 C.3 D.5 Cu 47: X l 1 trieste ca glixerol vi axit n chc khng no Y ( c 1 lin kt C=C) mch h. t chy hon ton 0,1 mol X ri cho ton b sn phm chy hp th vo dd nc vi trong d thu c 120g kt ta . hi khi lng dd sau p thay i nh th no: A. gim 54,6g B.gim 67,2 g C. tng 67,2 g D. tng 49,2g Cu 48: X l aminoaxit cha 1 nhm amino v 2 nhom cacboxyl . cho X tc dng vi 150 ml dd HCl 2M thu8 c dd Y. ly ton b Y cho p va ht vi 250ml dd NaOH 2M, sau c cn thu c 35,25g rn khan. CTPT ca X l: A. C5H9O4N B.C4H7O4N C. C6H11O4N D.C7H13O4N Cu 49: dy gm cc cht no sau y ch c cu to bi cc gc: -glucozo? A.saccarozo v mantozo B.tinh bt v xenlulozo C. tinh bt v mantozo D. saccarozo v xenlulozo Cu 50: cho hh gm 0,44g CH3CHO v 8,7g 1 andehit X tc dng vi lng d dd AgNO3/NH3 thu c 66,96g Ag. CTCT ca X l: A. OHC-CHO B. CH3CH2CHO C. HCHO D.CH2=CHCHO

1 B 21 A 41 D

2 D 22 C 42 D

3 D 23 A 43 D

4 B 24 B 44 A

5 D 25 A 45 C

6 D 26 C 46 B

7 A 27 D 47 A

8 B 28 D 48 B

9 C 29 B 49 C

10 B 30 C 50 A

11 B 31 A

12 B 32 D

13 D 33 C

14 C 34 B

15 D 35 D

16 D 36 D

17 D 37 D

18 D 38 A

19 C 39 D

20 C 40 C

12 Cu 1: Anion XY32- c tng s ht mang in l 62. S ht mang in trong ht nhn ca Y nhiu hn s ht mang in trong ht nhn ca X l 2. Nhn nh no sau y l sai? 132

A.X, Y u l phi kim thuc chu k 2 B. Anion XY32- c tnh baz C.Trong phn t hp cht gia Na, X, Y va c lin kt ion va c lin kt cng ha tr. D. Anion XY32- c tnh kh Cu 2: Cho cc cht Fe, FeO, Fe3O4, Fe2O3, FeCO3, Fe(OH)3, FeS, FeS2, Fe(OH)2, FeSO3, FeSO4. Cho s phn ng sau: Fe2(SO4)3 + H2O X + H2SO4 c nng S cht X c th thc hin phn ng trn l? A.8 B.6 C.5 D.7 Cu 3: Tng s lin kt n trong phn t ankadien l? A. 3n-5 B. 2n-1 C. 2n-2 D.3n-3 Cu 4: khi kho st phn ng H2(k) + Br2(k) 2HBr(k) ti nhit T1, T2 (T1< T2), hng s cn bng theo nng c ch s tng ng K1, K2 (K2<K1) pht biu ng? A.phn ng nghch ta nhit, cn bng chuyn dch theo chiu thun khi tng nhit B. phn ng thun ta nhit, cn bng chuyn dch theo chiu nghch khi tng nhit C. phn ng nghch thu nhit, cn bng chuyn dch theo chiu thun khi tng nhit D. phn ng thun thu nhit, cn bng chuyn dch theo chiu nghch khi tng nhit Cu 5: in phn mt dung dch c ha tan 13,5g CuCl2 v 14,9g KCl (c mng ngn v in cc tr) trong thi gian 5790 giy vi cng dng in 5A. Dung dch sau in phn c trung ha va bi V lt dung dch H2SO4 1M. Gi tr ca V l? A. 0,15 B.0,05 C.0,2 D.0,1 Cu 6: Thy phn hon 1 loi triglixerit .Thu c axit stearit, axit oleic, axit linoleic. chuyn ha hon ton 221g A thnh cht bo rn cn dng va V lt H2 ktc. Gi tr V l? A.5.6 B.16,8 C.22,4 D. 20,2 Cu 7: t chy hon ton 8g hh 2 ankin X, Y (Mx<My) cht kh iu kin thng, thu c 26,4g CO2. Cho8g hh trn tc dng vi lng d dd AgNO3/NH3 thy khi lng kt ta vt qu 25g. Vy Y l? A. But-1-in B.but-2-in C.pent-1-in D.propin Cu 8: un nng 7.6g hh X gm C2H2, C2H4, v H2 tong bnh kn vi Ni, thu c hh kh Y. t chy hon ton hh Y, dn sn phm chy ln lt i qua bnh 1 ng H2SO4 c, bnh 2 ng Ca(OH)2 d. Thy khi lng bnh 1 tng 14,4g. Khi lng bnh 2 tng l? A.22g B.35,2g C.6g D.9,6g Cu 9: pH ca dung dch NH3 0,1M (Kb = 1,80.10-5) v NH4Cl 0,1M l? A. 10,25 B. 9,26 C. 9,86 D. 11,45 Cu 10: cho ancol 2 cht X tc dng vi lng d CuO un nng n phn ng xong thu c 9,36g mt cht hu c Y, ng thi thy khi lng cht rn gim 4,16g. Bit cht Y tc dng vi H2 d thu c cht Z ha tan c Cu(OH)2. CTCT ca Y? A. OHC-CHO B.OHC-CH2-CHO C.CH3-CO-CHO D.CH3-CO-CO-CH3 Cu 11: Cho 4 cht X, Y, Z, T c cng thc l C2H2On (n 0). X, Y, Z u tc dng vi dd AgNO3/NH3. Z, T tc dng c vi NaOH. Hidrat ha X c xc tc thu c hp cht cng chc vi Y. Vy X, Y, Z, T tng ng l? A.HOOC-COOH; CHCH; OHC-COOH; OHC-CHO B. OHC-CHO;CHCH; OHC-COOH; HOOC-COOH C. OHC-COOH ; HOOC-COOH; CHCH;OHC-CHO D. CHCH ; OHC-CHO; OHC-COOH; HOOC-COOH Cu 12: S ng phn mch h ng vi CTPT C3H6O: A.3 B.4 C.2 D.5 Cu 13: Khi cho andehit mch h X phn ng vi H2 d (Ni, to) th 0,125 mol X phn ng ht vi 0,25 mol H2 to cht Y. Ton b Y phn ng va vi 2,875g Na. Cht X c cng thc ng vi cng thc chung l? A. CnH2n-1CHO (n 2) B. CnH2n-3CHO (n 2) C. CnH2n (CHO)2 (n 0) D. CnH2n+1CHO (n 0) Cu 14: a. NaClO + CO2 + H2O NaHCO3 + HClO b. CO2 + 2Mg C + 2MgO c. 4Ag + O2 2Ag2O d. 4HF + SiO2 SiF4 + 2H2O e. Na2CO3 + SiO2 + H2O Na2SiO3 + H2O + CO2 g. Si + 2NaOH Na2SiO3 + H2 h. 8HI + H2SO4 c I2 + H2S + 4H2O i. AgNO3 + NaF AgF + NaNO3 s phn ng vit sai? 133

A. 1 B.2 C.3 D.4 Cu 15: dd A cha 4,82g hh NaF, NaCl, NaBr. Cho kh Cl2 va vo dd A ri c cn phn dd sau phn ng, thu c 3,93g hh mui halogenua khan B. Cho B vo nc ri phn ng vi AgNO3 d thu c 8,61g kt ta. % khi lng NaF trong A l? A.34,85 B.8,71 C.17,42 D.13,08 Cu 16: Dy no sau y gm cc cht ch c tnh oxi ha A.Cl2, H2O2, HNO3, H2SO4 B.SO2, SO3, Br2, H2SO4 C.Fe(NO3)3, CuO, HCl, HNO3 D.O3, Fe2O3, H2SO4, O2 Cu 17: Cho vo dd cha a mol NaAlO2 mt dd cha b mol hoc 3b mol HCl th lng kt ta sinh ra u bng nhau. T s a/b c gi tr l? A.1 B.1,25 C. 1,5 D.1,75 Cu 18: X, Y l 2 kim loi nhm IIA (Mx<My). Cho 4,9g hh kim loi X, Y tc dng vi lng d dd HCl thu c 4,48l H2 kc. Mt khc khi cho 2,16g X tc dng vi lng d dd HCl th lng HCl cn dng nhiu hn 0,36 mol. Hai kim loi X, Y l? A.Be v Ca B.Be v Mg C.Ca v Sr D.Mg v Ca Cu 19: phng trnh ion 2H+ + CO32- H2O + CO2 ca phn ng no sau y? A. CaCO3 + 2HNO3 Ca(NO3) + H2O + CO2 B. Ba(HCO3)2 + H2SO4 BaSO4 + H2O + CO2 C. NaHCO3 + HCl NaCl + H2O + CO2 D. K2CO3 + 2HCl 2KCl + H2O + CO2 Cu 20: cho cc cht sau: vinyl axetilen, mantozo, saccarozo, axit fomic, glucozo, natri fomat. S cht kh c Ag+ trong [Ag(NH3)2]OH l: A.4 B.3 C.2 D.5 Cu 21: Cht phn ng vi Cu(OH)2 to mu tm c trng l: A.Glixerol B.Tinh bt C.dd Amino axit D.dd Anbumin Cu 22: X l amino axit cha mt nhm amino v mt nhm cacboxyl, mch khng nhnh. Cho 0,1 mol X tc dng vi dd NaOH d to ra mui hu c Y. Ly ton b Y cho phn ng vi dd HCl thu c 24g mui. T X c th iu ch trc tip A. nilon-6 B.nilon-6,6 C.nilon-7 D.nilon-8 Cu 23: phn ng no iu ch axeton trong cng nghip A.(CH3COO)2Ca CH3COCH3 + CaCO3 B. CH3CHOHCH3 + CuO CH3COCH3 + Cu + H2O C. C6H5CH(CH3)2 C6H5OH + CH3COCH3 D. CH3CHCl2CH3 + 2KOH CH3COCH3 + 2KCl + 2H2O Cu 24: hidro ha hon ton m gam hh X gm 2 andehit no, n chc, mch h, k tip nhau trong dy ng ng (m+1) gam hn hp 2 ancol. t chy hon ton X thu c 30,8g CO2. Khi cho X tc dng vi dd AgNO3/NH3 d thu c lng Ag l? A.108g B.172,8g C.151,2g D.194,4g Cu 25: Cho m gam hh X gm axit acrilic v mt axit no n chc tc dng va 4,8g Br2 trong nc. Nu cho m gam hh X tc dng vi dd AgNO3/NH3 d th thu c 4,32g Ag. Gi tr ca m l? A. 1,9g B.1,64g C.3,08g D.2,62g Cu 26: S ng phn l hp cht thm c CTPT C8H10O tc dng vi dd NaOH l? A.9 B.6 C.7 D.8 Cu 27: Cho 14,6g hh X gm Na v Al vo nc d, sinh ra 11,2l kh kc. Khi lng ca Al trong hh l? A.5,4g hoc 8,85g B.8,85g C.8,1g D.5,4g hoc 8,1g Cu 28: Cho m gam bt Cu vo 200ml dd AgNO3 0,15M sao mt thi gian phn ng thu c 3,44g hh rn X v dd Y. Lc tch X ri thm 5,175g bt Pb vo Y, sau khi phn ng xy ra hon ton thu c 3,79g rn Z. Gi tr m l? A.2,56 B.1,28 C.1,92 D.1,6 Cu 29: Cho 26,8g hh bt X gm Al v Fe2O3, tin hnh phn ng nhit nhm cho n khi hon ton. Hn hp sn phm sau phn ng cho tc dng vi lng d dd HCl c 11,2 lt H2 kc. Khi lng ca Al trong X l? A.5,4g B.7,02g C.9,72g D.10,8g Cu 30: cho cc cht sau: C6H5OH(1), C6H5NH3Cl(2), CH2=CHCOOH(3), CH3CHO(4), HCOOCH3(5). Chn pht biu ng. A. Ch c (3) phn ng vi NaHCO3 B. Ch c (4) phn ng vi dd AgNO3/NH3 C. Cc cht p c vi ancol etylic (1), (3) D. Cc cht p c vi NaOH gm (1), (3), (5) Cu 31: X l penta peptit cu to t 1 amino axit A no, mch h c mt nhm COOH v m nhm NH2. Amino axit A c tng phn trm khi lng oxy v ni t l 61,33%. Khi thy phn khng hon ton m gam X trong mi trng axit thu c 28,35g tripeptit, 13,2g dipeptit v 11,25g A. Gi tr m l? 134

A.48,48g B.45,45g C.36,36g D.42,42g Cu 32: Ha tan 6,12g hh glucozo v saccarozo vo nc c dd A. Cho A p vi dd AgNO3/NH3 d c 3,24g Ag. Ly dd A un nng vi H2SO4 thu c dd B. Dung dch B lm mt mu a gam Br2. Cc p xy ra hon ton. Gi tr ca a l? A.2,4g B.5,6g C.4g D.9,6g Cu 33: Cho Fe tc dng hon ton vi S thu c hh rn X. Cho hh X tc dng vi dd HCl d thu c V lt kh duy nht kc. Cho hh X cn li tc dng vi dd HNO3 c nng d thu c 13V lt kh n l sn phm kh duy nht, kc. Thnh phn % khi lng Fe trong hh ban u l? A.52,21% B.52,12% C.25,21% D.51,22% Cu 34: Trong s cc dd NaOH, NaHCO3, NaHSO4, BaCl2 th s cp dd c th p vi nhau l? A.3 B.4 C.5 D.6 Cu 35: Mt hh gm ancol anlylic v mt ancol n chc X. t chy hon ton 7,5g hh cn dng 11,2 lt O2 kc. Cho ton b sn phm hp th vo dd Ca(OH)2 d thu c 35g kt ta. Cng thc ca X l? A.CH3OH B.C2H5OH C.C3H7OH D.C4H7OH Cu 36: phn bit cc cht rn Fe, FeS, Fe3O4 trong cc bnh mt nhn ta dng dung dch: A.HCl B. HNO3 long C.H2SO4 c nng D. CuCl2 Cu 37: dy gm cc kim loi m khi mi kim loi ghp vi in cc Cr th pin in ha xy ra qu trnh : CrCr3+ + 3e A.Mg, Zn B.Sn,Zn C.Mg,Fe D.Fe,Sn Cu 38: tch CO2 ra khi hn hp vi HCl v hi nc. Cho hh ln lt i qua cc bnh B.NaOH v H2SO4 C.H2SO4 v KOH D.NaHCO3 v P2O5 A.Na2CO3 v P2O5 Cu 39: cho 5,15g hh gm Zn v Cu vo 140ml dd AgNO3 1M. Sau khi p xong thu c 15,76g hh kim loi v dd B. Bit cho KOH d vo B c kt ta. % khi lng ca Zn trong hh l: A.63,1 B.38,76 C.61,3 D.37,86 Cu 40: cho 6 hp cht hu c : p-crezol, phenyl amoniclorua, axit metacrilic, anilin,vinyl axetat, axit amino axetic. S cht tc dng vi c hai ha cht l dd NaOH, v dd Br2 l: A.5 B.4 C.3 D.6 Cu 41: mt ancol n chc no A c %O l 50%. Oxi ha hon ton m gam A vi oxi xc tc thch hp thu c hh X gm andehit, axit, v nc. Cho X tc dng AgNO3/NH3. Thu c 0,32 mol Ag. Cho X tc dng Na d thu c 0,07 mol H2. Gi tr ca m l: A.5,52g B.3,2g C.7,4g D.6,4g Cu 42: cho cc dung dch c cng nng : Na2CO3(1), H2SO4(2),HCl(3),H2NCH2COOH(4). Gi tr pH ca cc dung dch c sp xp theo chiu tng t tri sang phi: A.3,2,4,1 B.4,1,2,3 C.1,2,3,4, D.2,3,4,1 Cu 43: c 5,92g hh X gm Fe v kim loi M(c ha tri kh06ng i) Chia X lm 2 phn bng nhau Phn 1 : ha tan ht trong dd HCl d, c 0,07 mol H2. Phn 2: ha tan ht trong dd HNO3 long d, c 0,06 mol NO ( sn phm kh duy nht) Kim loi M dng l A.Zn B.Al C.Mg D. Ca Cu 44: cho m gam hh X gm FeO, Fe2O3 , v Fe3O4 tc dng va vi dd H2SO4 long , d thu c dd B. C cn dd B thu c 55,2g mui khan. Nu cho B tc dng vi Clo thu c 58,75 gam mui. gi tr ca m l: A. 46,4 B. 39,2 C. 15,2 D.23,2 Cu 45: cho m gam bt Fe tc dng vi 175g dd AgNO3 34% sau phn ng thu c dd X ch cha 2 mui st v 4,5m gam cht rn. xc nh nng % ca Fe(NO3)2 trong dd X A. 9,81% B. 12,36% C.10,84% D.15,6% Cu 46: c cc nhn nh sau: a. cc nguyn t K (Z=19), Cr(Z=24),Cu(Z=29) u c s electron trong cc phn lp s l 7 b. cc ion v nguyn t : Ne, Na+, F- c im chung l c cng s electron c. khi t chy ancol no th ta c n(H2O) : n(CO2) >1 d. dy gm cc nguyn t c sp xp theo chiu gim dn bn knh nguyn t t tri sang phi l : K ,Mg, Si, N e. tnh bazo ca dy cc hidroxit: NaOH, Mg(OH)2, Al(OH)3 gim dn g. phn cc tang dn t HF, HCl, HI. Cho : N(Z=7), F(Z=9),Ne(z=10),Na(Z=11),Mg(Z=12), Al(Z=13), K(z=19), Si(Z=14). Nhn nh ng: A.3 B.5 C.4 D.2 Cu 47: kh nng phn ng th nguyn t Clo bng nhm OH ca cc cht c xp theo chiu tng dn t tri sang phi l. A.alyl clorua, phenyl clorua, propyl clorua B.anlyl clorua, propyl clorua, phenyl clorua C. phenyl clorua, anlyl clorua, propyl clorua D. phenyl clorua, propyl clorua, anlyl clorua Cu 48: cho este X n chc tc dng va vi NaOH thu c 12,8g hh Y gm mui v ancol. t chy hon toan Y thu c CO2 , H2O, 5,3g NaCO3. S CTCT ph hp vi X l 135

A. 2 B.4 C.3 D.6 Cu 49: hh X gm H2 , propen, propanal, ancol arylic. t chy hon ton 1 mol hh X thu c 40,32 lt CO2(kc). un X vi bt Ni , 1 thi gian thu c hh Y c d (Y/X)=1,25. Nu ly 0,1 mol Y th tc dng va vi V lt dd Br2 0,2M. gi tr ca V l: A.0,1 B.0,3 C.0,25 D.0,2 Cu 50: hh M gm 0,1 mol ancol X (no, n chc, mch h) v a mol hdrocacbon Y , vi s nguyn t cacbon trong X < s nguyn t cacbon trong Y. t chy hon ton M, thu c 8,96 lt kh CO2 (kc) v 7,2 g H2O. hidrocacbon Y v gi tr ca a l: A. C3H4 : 0,1 mol B C2H2: 0,1 mol C. C3H6: 0,05 mol D. C3H4: 0,05 mol 1 D 21 D 41 B 2 A 22 C 42 D 3 A 23 C 43 C 4 B 24 B 44 D 5 B 25 B 45 B 6 B 26 A 46 C 7 A 27 A 47 D 8 A 28 C 48 B 9 B 29 D 49 C 10 C 30 A 50 A 11 D 31 A 12 B 32 C 13 A 33 D 14 C 34 B 15 B 35 B 16 D 36 A 17 C 37 D 18 A 38 D 19 D 39 D 20 A 40 C

13 Cu 1: nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l ns2np3. Trong hp cht kh ca nguyn t X vi Hidro, X chim 82,35% khi lng. Thnh phn % ca X trong Oxit cao nht: A. 25,92 B.30,43 C.46,66 D.29,52 Cu 2: carotene trong qu c rt l 1 loi tecpen c CTPT C40H56. Khi hidro ha hon ton carotene thu c hidrocacbon no c CTPT C40H78. S lien kt v vng trong carotene ln lt l: A.12 v 1 B. 13 v 2 C.12 v 2 D.11 v 2 Cu 3: cho cn bng CO (k) + H2O (k) CO2 (k) + H2 (k). H<0 trong cc yu t: (1) tng nhit ; (2) gim p sut chung ca h;(3) them 1 lng hi nc,(4) thm 1 lng H2;(5) gim lng CO2,(6) dung cht xc tc. Cc yu t u lm cn bng chuyn dch theo chiu thun l: A.1,3,5 B.3,5 C.2,4,5 D.3,5,6 Cu 4: trong bnh kn cha hidrocacbon X v H2. Nung nng bnh ti p hon ton thu c hirdocacbon Y duy nht. cng nhit , p sut trong bnh nc khi nung gp 3 ln p sut trong bnh sau khi nung. t chy hon ton m gam Y thu c 3,36 lt CO2(kc) v 3,6g H2O. CTPT ca X l: A. C2H2 B.C2H4 C.C3H6 D. C3H4 Cu 5: cho isoprene tc dng vi HBr theo t l mol 1:1 th tng s ng phn cu to c th thu c l: A.4 B.7 C.5 D.6 Cu 6: cho 12,5g hh gm grixerol,v 1 ancol no n chc phn ng ht vi Na d thot ra 4,48 lit kh (kc). Cng lng hh trn ha tan c ti a 4,9 gam Cu(OH)2. Cong thc ca ancol l: A. C4H9OH B. CH3OH C. C3H7OH D. C2H5OH Cu 7: cho p Cu2S.FeS2 + HNO3 Cu (NO3)2 + H2SO4+ NO+H2O Tng cc h s nguyn t gim) ca cc cht tham gia trong pt l: A.45 B.52 C.50 D.49 Cu 8: pH ca dd NH3 0,1M (Kb= 1,80.10-5) v NH4Cl 0,1M l A.10,25 B. 9,26 C.9,86 D.11,45 Cu 9: cho cc trng hp sau: (1). O3 tc dng dd KI; (2) axit HF tc dng vi dd SiO2,(3) MnO2 tc dng vi dd HCl c, nung nng;(4) t H2S trong iu kin thiu khng kh;(5) KClO3 tc dng vi dd HCl c, nung nng;(6) n nng dd bo ha gm NH4Cl v NaNO2; (7) cho SO2 p vi Mg S trng hp to ra n cht l: A.5 B.6 C.4 D.3 Cu 10: cho hi nc qua than nng c hh kh A gm CO2, CO, H2. Ton b lng kh A kh va 48g Fe2O3 thnh Fe v thu c 10,8g nc. s mol CO2 trong hh kh A l: A.0,15 B. 0.3 C.0,2 D.0,25 Cu 11: mt bnh kn dung tch 1 lt cha 1,5mol H2 v 1 mol N2(c xc tc v nhit thch hp). trng thai cn bng c 0,2 mol NH3 to thnh . mun hiu sut t 25% cn phi thm bao mol N2 vo bnh na. A.1,5 B.2,25 C.0,83 D.1,71 Cu 12: t chy hon ton 10ml 1 este X cn 35ml O2 thu c th tch kh CO2 v hi H2O c t l tng ng l 4:3. Dn sn phm chy qua bnh ng P2O5 d, thy th tch gim 30ml. bit rng cc th tch c o cng iu kin. cng thc ca X l 136

A.C4H6O2 B. C4H6O4 C. C4H8O2 D. C8H6O4 Cu 13: Nhm cc vt liu c ch to t polymer trng ngng l: A. Teflon, nilon-6,6; t nitron. B. PVC, nilon-6, poly(phenol-fomandehit) C. Nilon-6,6; t lapsan, PVC C. Nilon-6,6; t lapsan, nilon-6 Cu 14: Cho 0,15 mol Lysin v 0,2 mol alanine vo 225 ml dung dch NaOH 2M, thu c dung dch X. Cho HCl d vo dung dch X. Sau cc phn ng xy ra hon ton, s mol HCl phn ng l: A. 0,80 B. 0,95 C. 0,70 D. 0,725 Cu 15: Cho cc cht sau: Vinyl axetilen, mantozo, saccarozo, axit fomic, glucozo, natri fomat. S cht kh c Ag+ trong [Ag(NH3)2]OH l: A. 4 B.3 C. 2 D. 5 Cu 16: Cho hn hp X gm Fe2O3, Al2O3 v Cu tc dng vi dung dch H2SO4 long d, thu c dd Y v phn khng tan Z. Cho Y tc dng vi dd Ba(OH)2 (long d) thu c kt ta: A. Fe(OH)2, Cu(OH)2 v BaSO4 B. Fe(OH)3, Cu(OH)2 v BaSO4 C. Fe(OH)3, BaSO4 D. Al(OH)3 , Fe(OH)3 Cu 17: Hp thu hon ton V lt ktc CO2 vo 100 ml dung dch NaOH a (mol/l) c dung dch A. Chia A lm 2 phn bng nhau: - Cho dung dch Ba(OH)2 vo phn (1) c 3,94 g kt ta. - Dung dch Ca(HCO3)2 d vo phn (2) c 3 g kt ta. Gi tr ca V v a tng ng l: A. 0,448 l v 1M B. 0,448 l v 1,2 M C. 0,896 l v 1M D. 0,896 l v 1,2 M Cu 18: Ha tan a gam CuSO4.5H2O vo nc thu c dung dch A. in phn dung dch A vi in cc tr: - Nu thi gian in phn l t giy th thu c kim loi ti catot v 0,007 mol kh ti anot - Nu thi gian in phn l t giy th thu c 0,024 mol kh hai in cc. Gi tr ca a l: A. 3,5 g B. 5 g C. 4,5 g D. 2,25 g Cu 19: Chia hn hp X gm Ba, Al v Fe thnh 2 phn bng nhau. - Cho phn (1) vo dung dch KOH d thu c 1,75 V1 lt kh H2 - Cho phn (2) vo mt lng d H2O thu c V1 lt kh H2 v m gam hn hp kim loi Y. Ha tan hon ton Y vo dung dch HCl d thu c 1,25 V1 lt kh H2 (cc th tch kh o cng k). Thnh phn % s mol ca Al trong hn hp X l: A. 57,14% B. 50% C. 66,67% D. 75% Cu 20: Dung dch X c cha: 0,07 mol Na+; 0,01 mol SO42-; 0,01 mol CO32- v x mol OH-. Dung dch Y c cha ClO4-, NO3- v y nh mol H+. Tng s mol ClO4-, NO3- l 0,08. Trn X v Y c 500 ml dung dch Z. Dung dch Z c pH (b qua s in ly ca H2O) l: A. 1 B. 2 C. 12 D. 1,22 Cu 21: Cho cc cht: CH3OH, C2H5OH, CH3CHO, C2H2, CH3COONa, CH3CN, CH2=CHCOOCH3. S cht iu ch c CH3COOH bng mt phn ng: A. 6 B. 5 C. 4 D. 3 Cu 22: t chy hon ton 0,1 mol este E cn va 0,35 mol O2. Sn phm chy cho qua bnh ng nc vi trong thy khi lng bnh tang 18,6 gam. Mt khc x phng ha m gam E bng dung dch NaOH va ri c cn c m1 gam mui khan. Bit m > m1. Vy E l este ca axit cacboxilic. A. Axit fomic B. Axit axetic C. Axit propionic D. Axit acrylic Cu 23: Cho axit salixylic (axit o-hydroxibenzoic) phn ng vi methanol, c xt thu c metylsalixylat dng lm thuc xoa bp gim au. phn ng hon ton vi 36,48 g metylsalixylat cn va V lt dung dch KOH 1M. Gi tr ca V l: A. 0,72 B. 0,48 C. 0,96 D. 0,24 Cu 24: Cho thy phn peptit trong mt axit H2N CH2 CO NH CH CO NH CH CO NH CH2 COOH CH2 - COOH CH2 C6H5 Thu c cc amino axit: A. H2N CH2 COOH; H2N CH(CH2 COOH) CO NH2 v H2N CH(CH2 C6H5) COOH B. H2N CH2 COOH; HOOC CH2 CH(NH2) COOH v C6H5 CH CH(NH2) COOH C. H2N CH2 COOH; H2N CH2 CH(NH2) COOH v C6H5 CH(NH2) COOH D. H2N CH2 COOH; HOOC CH(NH2) COOH v C6H5 CH(NH2) COOH 137

Cu 25: Dung dch nc ca cht A lm qu ng sang xanh, cn dung dch nc cht B khng lm i mu qu tm. Trn dung dch A vi dung dch B xut hin kt ta. A, B c th l: A. NaOH v K2SO4 B. K2CO3 v Ba(NO3)2 C. KOH v FeCl3 D. Ba(OH)2 v NaHSO4 Cu 26: C hai ng nghim, mt ng ng dung dch Na2SO4, mt ng ng dung dch Na2CO3. Ch dng mt ha cht trong s cc ha cht sau: dung dch HCl, dung dch BaCl2, dung dch NaHSO4, dung dch NaHSO3, dung dch AlCl3 th s ha cht c th phn bit hai dung dch trn l: A. 5 B. 2 C. 4 D. 3 Cu 27: Hn hp T gm 2 axit cacboxylic no, mch h. - Th nghim 1: t chy hon ton a mol hn hp T thu c a mol H2O - Th nghim 2: a mol hn hp T tc dng vi dung dch NaHCO3 d thu c 1,6 a mol CO2. Phn tram khi lng ca axit c phn t khi nh hn trong T l: A. 40,00 % B. 46,67% C. 31,76% D. 25,41% Cu 28: Cho m gam hn hp X gm Fe v FeS tc dng ht vi dung dch HCl d thu c V lt kh kc. Mt khc nu cho m gam hn hp X vo dung dch HNO3 d thu c dung dch Y ch cha 1 mui nitrat duy nht v 2V lt hn hp kh kc gm NO v SO2. Phn tram v khi lng ca Fe trong X l: A. 45,9% B. 54,1% C. 43,9% D. 52,1% Cu 29: Thc hin phn ng nhit nhm (khng c khng kh) m gam hn hp gm Al, Fe2O3 c hn hp B (H=100%). Ha tan B trong H2SO4 long d, thu c 2,24 lt kh kc. Nu ha tan B trong dung dch NaOH d th phn khng tan l 8,8 gam. Gi tr m bng: A. 19 g B. 13,9 g C. 8,42 g D. 15,64 g Cu 30: Cho 5 cp cht: a. Cu + dd FeCl3 b. H2S + dd CuSO4 c. Dd KI + dd FeCl3 d. Dd AgNO3 + dd FeCl3 e. Dd HCl + dd Fe(NO3)2 S cp cht phn ng c vi nhau: A. 5 B. 3 C. 4 D. 2 Cu 31: t chy V lt hi anehit X sinh V lt hi H2O. Mt khc, un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c 1 hn hp kh Y c th tch 2V lt (cc th tch kh o cng k nhit , p sut). X l cht no trong cc cht sau: A. CH2=CH-CHO B. CHC-CHO C. HCHO D. OHC-CHO Cu 32: Cho mt lng axit hu c A tc dng vi NaHCO3 va thu c dung dich A v s mol CO2 bay ra bng 2 s mol A. C cn dung dch sau phn ng ri t chy ht lng mui khan thu c H2O, 3,3 g CO2 v 2,65 g Na2CO3 CTCT thu gn ca A l: A. HOOC-CH2COOH B. HOOC-COOH C. CH3CH2COOH D. HOOC-(CH2)2COOH Cu 33: Mt amino axit X cha mt nhm NH2 v mt nhm COOH. Cho m gam X tc dng vi 300ml dung dch HCl 1M thu c dung dch Y. Dung dch Y phn ng va vi 500ml dung dch NaOH 1M v thu c dung dch Z. C cn dung dch Z thu c 39,75 gam mui khan. CTPT ca X l: A. C3H7O2N B. C2H5O2N D. C4H7O2N C. C4H9O2N Cu 34: Cho cht hu c X c CTPT C3H10O3N2 tc dng vi dung dch NaOH d, thu c cht hu c n chc Y lm xanh giy qu v cc cht v c. S ng phn cu to ca Y l: A. 3 B. 5 C. 6 D. 4 Cu 35: Mui X khi tc dng dung dch NaOH to kh Y lm xanh giy qu tm m, khi tc dng dung dch HCl to kh Z lm c nc vi trong nhng khng lm mt mu dung dch thuc tm. Mui X tc dng dung dch BaCl2 c kt ta. Mui X l: A. NH4HSO4 B. NH4HCO3 C. (NH4)2CO3 D. (NH4)2SO3 Cu 36: Cho cc cht: Al, NaHCO3, NH4NO3, Cr(OH)3, BaCl2, Na2HPO3, H2N-CH2-COOH, CH3COONH4, C2H5NH3Cl, ClNH3CH2COOH, CH3COOC2H5, CH2=CHCOONa, H2NCH2COONa. S cht lng tnh theo thuyt Bron-stet l? A. 4 B. 5 138

C. 6 D. 7 Cu 37: C 5 gi bt mu tng t nhau: (1) CuO, (2) FeO, (3) MnO2 , (4) Ag2O , (5) Fe + FeO. C th dng cht no trong cc dung dch di y phn bit cc cht trn: B. AgNO3 A. HNO3 c C. HCl c D, Ba(OH)2 Cu 38: cho hn hp bt Al, Zn,Cu tc dng vi dd AgNO3 , p xong thu c hn hp kim loi X v dd Y. cho dd NaOH d vo dd Y thu c kt ta Z. trong hn hp X gm: A.Cu, Zn,Ag B.Cu,Ag C.Zn, Ag D.Al, Cu, Ag Cu 39: s mol HCl v K2Cr2O7 cn iu ch c lng Clo va tc dng vi 1,12g Fe la: A.0,66 mol v 0,03 mol B. 0,14 mol v 0,01 mol C. 0,42 mol v 0,03 mol D. 0,16 mol v 0,01 mol Cu 40: ha tan hon ton 0,1 mol FeS2 trong dd HNO3 c nng. Tnh th tch kh NO2 thot ra (ktc) v s mol HNO3 ti thiu tham gia phn ng A. 33,6 v 0,03 mol B. 33,6 v 1,5 mol C. 22,4 v 1,5mol D. 33,6 v 1,8 mol Cu 41: cho 30,6g hh Mg, Al, Ag vo cc cha 900ml dd HCl 1M va .sau phn ng kt thc thm dn NaOH vo cc lng kt ta thu c l ln nht. lc ly kt ta v em nung nng nhit cao n khi lng khng i, thu c a gam cht rn. gi tri ca a l: A.37,8 B 45 C. 40,2 D.38,7 Cu 42: hn hp X gm ancol metylic v 1 ancol ng ng A. cho 4,6g X tc dng vi Na d thu c 1,12l kh H2(ktc). Mt khc oxi ha hon ton 4,6g hh X bng CuO nhit cao, d ri cho ton b sn phm thu c tc dng vi dd AgNO3 d/NH3 thu c 0,2 mol Ag. A l: A.etanol B. propan-2-ol C. propan-1-ol D.butan-2-ol Cu 43: cho ancol benzylic v p-crezol ln lt tc dng vi: Na, dd KOH, CH3COOH, nc Br2,s phn ng xy ra l: A. 4 B. 3 C. 5 D. 6 Cu 44: cho s : C2H2X axetandehit. Cht X c th l: 1. CH2=CHCl 2.CH3-CHCl2 3. CH2=CH2 4. CH3COOH=CH2 A. 1,2,4 B. 1,3,4 C. 2,3,4 D. 1,2,3,4 Cu 45: ha tan hn hp gm NaHCO3, NaCl, Na2SO4 vo nc ng dd X thm H2SO4 long vo dd X n khi khng thy kh thot ra na th dng li, lc ny trong dd cha mt lng mui vi khi lng bng 0,9 ln khi lng mui ban u. vy % khi lng ca NaHCO3 trong hh ban u l: A.84% B.28,96% C.64,62% D.80% Cu 46: hh X c C2H5OH, HCOOH, CH3CHO trong C2H5OH chim 50% theo s mol. t chy m gam hh X thu c 3,24g H2O v 3,136 lt CO2 (ktc). Cho m gam hh X thc hin p trng bc th thu c s mol Ag l: A. 0,06 B.0,24 C.0,08 D. 0,12 Cu 47: cho s sau: ( cc ch ci ch cc cht hu c) CH3ClXYZTM+N Bit N l hp cht thm. CTCT ca Z,M v N ln lt l : A. CH3COCH3, CH3COONa, C6H5ONa B. (CH3CO)2O, HCOONa, C6H5ONa D. (CH3CO)2O, CH3COONa, C6H5ONa C. (CH3CO)2O, CH3COONa, C6H5COONa Cu 48: Cho cc cht sau tc dng vi dung dch NaOH d. Ch ra phn ng vit sai: A. CH3COOC6H5 + 2 NaOH CH3COONa + C6H5ONa + H2O B. CH3 CCl2 CH3 + 2 NaOH CH3COCH3 + 2NaCl + H2O C. CH3 CCl3 + 3 NaOH CH3COOH + 3NaCl + H2O D. CH3 COOCH=CH2 + NaOH CH3COONa + CH3CHO Cu 49: Cht X tc dng vi Na v vi Cu(OH)2 trong mi trng kim khi un nng. Th tch ca 3,7 g hi cht X bng th tch ca 1,6 g kh O2 (cng k v nhit v p sut). Khi t chy hon ton 1 g X th th tch kh CO2 thu c cha n 0,7 lt (ktc). CTCT ca X: A. CH3-CO-CH2-OH B. O=CH-CH2-CH2-OH C. HOOC-CHO D. HOOC-CH2-CHO Cu 50: Khi X l cht hu c n chc. Nu cho 12,9 g X tc dng va vi 150 ml dung dch KOH 1M, kh cn dd sau phn ng thu c 21,3 g cht rn khan Y. Ch ra pht biu ng: A. X lm mt mu nc Brom 139

B. t 0,1 mol X thu c 0,5 mol CO2 C. X c iu ch trc tip t axit v ancol tng ng D. Trong Y c nhm chc OH

1 A 21 B 41 A

2 D 22 A 42 B

3 B 23 B 43 C

4 C 24 B 44 D

5 D 25 B 45 C

6 C 26 D 46 C

7 D 27 D 47 D

8 B 28 A 48 C

9 B 29 B 49 C

10 A 30 A 50 D

11 C 31 D

12 B 32 D

13 D 33 A

14 B 34 D

15 A 35 C

16 A 36 A

17 C 37 C

18 C 38 B

19 A 39 B

20 D 40 B

14 Cu 1: Cht hu c X c CTPT C2H2On, tc dng c vi dung dch AgNO3/NH3 . Gi tr ca n l: A. 0,2,3 B. 0,1,2 C. 2 D. 0,1,2,3 Cu 2: Ha tan hon ton rn X gm: FeCO3 v Fe3O4 trong HNO3 long thu c hn hp kh Y gm NO v CO2 c t khi so vi H2 l 18,5. Bit N+5 ch b kh thnh N+2. Phn tram khi lng FeCO3 trong X: A. 20% B. 40% C. 80% D. 83,33% Cu 3: Cho cc cht CH3CHO, C2H5OH, CH2=CHCOOH, H2, dung dch NaOH, Cu(OH)2/OH. S phn ng xy ra khi cho cc cht tc dng vi nhau tng i mt (k thch hp) A. 4 B. 5 C. 6 D. 7 Cu 4: Bit rng 1 mol X tc dng c vi 2 mol NaOH v khi tc dng vi Na d thu c 22,4 lt H2 (kc). Mt khc, t chy hon ton 0,1 mol cht hu c X l dn xut ca benzen, khi lng CO2 thu c nh hn 39,6 g. CTCT thu gn ca X l: A. HOC6H4COOCH3 B. HOOCCH2 C6H4COOH D. C2H5C6H3(OH)2 C. HOCH2C6H4COOH Cu 5: Cho cc p sau: cc p trong sn phm c to ra n cht l: 1. C6H5NH2 + HNO2 + HCl 2. C2H5NH2 + HNO2 3. C6H5NH2 + HNO2 4. H2NCH2COOH + HNO2 5. CH3NH2 + HNO3 6. C2H5NH2 + CH3I A. 2,4,6 B. 2,3,4 C. 1,2,4,5 D. 2,3,4,6 Cu 6: Cho mt s axit trong chu k 3: H2SO4, H3PO4 , H2SiO3 ,HClO4. Dy cc cht xp theo chiu tang dn tnh axit l: A. H3PO4 , H2SiO3 ,H2SO4,HClO4 B. H2SiO3 ,H3PO4 ,HClO4 ,H2SO4 C. H2SiO3 ,H3PO4 , H2SO4,HClO4 D. H3PO4 , H2SiO3 ,HClO4 ,H2SO4 Cu 7: Nguyn t ca nguyn t X c tng s e trong cc phn lp P l 7. Nguyn t ca nguyn t Y c tng s ht mang in nhiu hn s ht mang in ca X l 8. Hp cht ca X v Y c CT: A. X2Y3 B. X3Y C. X4Y3 D. XY3 Cu 8: Trong cng nghip iu ch kh than t, ngi ta thi hi nc qua than an nng . Phn ng ha hc xy ra nh sau: C(r) + H2O (k) CO (k) + H2 (k) H = 131kJ iu khng nh no sau y l ng: A. Tng p sut chung ca h lm cn bng khng thay i B. Tng nhit v tng p sut ca h lm cn bng chuyn sang chiu thun C. Tng nhit v tng p sut ca h lm cn bng chuyn sang chiu nghch D. Tng nhit v gim p sut ca h lm cn bng chuyn sang chiu thun Fe2(SO4)3 + K2SO4 + MnSO4 + Na2SO4 + H2O Cu 9: Cho pt ha hc: FeSO4 + KMnO4 + NaHSO4 Tng h s ca cc cht (l nhng s nguyn ti gin) trong pt p l: A. 46 B. 50 C. 52 D. 28 140

Cu 10: Cho ptp: 2A(k) + B(k) 2X(k) + 2Y(k). Ngi ta trn 4 cht, mi cht 1 mol vo bnh kn dung tch 2 lt (khng i). Khi cn bng lng cht X l 1,6 mol. Hng s cn bng ca phn ng ny l: A. 58,51 B. 33,44 C. 29,26 D. 40,96 Cu 11: Cho mt kim loi M vo dung dch CuSO4 d thu c cht rn X. Bit X tan ht trong dd H2SO4 long phn ng hon ton. Kim loi M c th l: A. Mg B. Na C. Ba D. Fe Cu 12: Cho cc cht dd BaCl2, dd Ba(OH)2, O2, nc Cl2, dd KMnO4, H2S, NaHSO3. S cht tc dng c vi SO2 l(xem iu kin c ). A.4 B.5 C.3 D.6 Cu 13: Cho hh gm 0,54g Al v 1,92g Cu vo 400ml dd cha hh gm H2SO4 0,5M; NaNO3 0,2M. Sau khi p xy ra hon ton, thu c dd X v kh NO (sn phm kh duy nht). Nu cho 360ml dd NaOH 1M vo dd X thu c a gam kt ta. Gi tr a l? A.4,5 B.2,94 C.3,72 D.4,11 Cu 14: Nung nng hon ton 27,3g hh NaNO3, Cu(NO3)2 thu c m gam cht rn v hh kh X. Dn X vo nc d th c 1,12 lt kh ktc khng b hp th (lng i ha tan khng ng k). Gi tr ca m l? A.17,8g B.16,5g C.19,5g D.14,9g Cu 15: trong qu trnh hot ng ca pin in ha Cr-Ni th nhn thy: A. Khi lng in cc Cr gim v nng ion Ni2+ trong dd tng. B. Khi lng in cc Ni tng v nng ion Ni2+ trong dd tng. C. Khi lng in cc Ni tng v nng ion Cr3+ trong dd tng. D. Khi lng in cc Ni tng v nng ion Cr3+ trong dd gim. Cu 16: - Th nghim 1: in phn dd CuSO4 vi anot bng ng (anot tan) - Th nghim 2: in phn dd CuSO4 vi anot bng graphit (in cc tr) Ch ra pht biu khng ng A.Trong th nghim 1 v 2: Nng Cu2+ gim nn mu xanh dd nht dn. B.Trong th nghim 1: ng t anot di chuyn v catot C.Trong th nghim 2: anot xy ra s oxi ha: 2H2O O2 + 4H+ + 4e D.Trong th nghim 1 v 2: th catot xy ra s kh: Cu2+ + 2e Cu Cu 17: Cho cc cp dd sau: 1. Na2CO3 v AlCl3 2. NaNO3 v FeCl2 3. HCl v Fe(NO3)2 4. NaHCO3 v BaCl2 5. NaHCO3 v NaHSO4 Khi trn cc dd trong cc cp cht vi nhau th cc cp cht c phn ng l: A. 1,3,4 B. 1,4,5 C. 1,3,5 D. 2,3,5 Cu 18: nung hon ton 25g qung l mt c hm lng CaCO3.MgCO3 trong qung l 92%. Hp th ton b kh sinh ra vo V lt dd Ba(OH)2 2M thu c kt ta l 19,7g. Gi tr ca V l? A. 75ml B. 300ml C. 100ml D. 125ml Cu 19: dd X cha a mol Ca(OH)2. Cho dd X hp th 0,06mol CO2 thu c 2b mol kt ta. Nhng nu dng 0,08 mol CO2 th thu c b mol kt ta. Gi tr ca a, b l? A. 0,01 v 0,03 B. 0,05 v 0,02 C. 0,01 v 0,02 D. 0,08 v 0,05 Cu 20: Ha tan hon ton m gam hh X gm Na2O v Al2O3 vo H2O thu c dd Y cha cc cht tan u c nng bng nhau. Cho dd cha 0,13 mol HCl vo Y, sau khi kt ta c tan mt phn cn li 3,12g kt ta. Gi tr ca m l? A. 5,65 B. 8,2 C. 8,75 D. 4,75 Cu 21: Ha tan 2,16g hh 3 kim loi Na, Al, Fe vo nc d thu c 0,448 lt kh (ktc) v cht rn X. Tch lng rn X ri cho tc dng vi 60 ml dd CuSO4 1M, sau khi p xy ra hon ton thu c 3,2g kim loi v dd Y. Thm t t dd NaOH vo dd Y n khi t gi tr ln nht th dng li. Lc ly kt ta, em nung nng trong khng kh n khi lng khng i, thu c cht rn c khi lng bng? A. 5,24g B. 3,64g C. 3,42g D. 2,62g 141

Cu 22: nung nng m gam hh X gm KClO3 v KMnO4 , sau 1 thi gian thu c rn Y v O2. Trong Y c 0,984g KCl chim 8,132% theo khi lng . trn lng O2 trn vi khng kh theo t l th tch l : Vo2:Vkk= 1:3 trong 1 bnh kn ta thu c hh kh Z. cho vo bnh 0,044 mol cacbon ri t chy ht cacbon , p xy ra hon ton , thu c hh kh T gm 3 kh O2, N2, CO2. Trong , CO2 chim 22,92% th tch . gi tr m (gam) l: A. 12,6 B.12,84 C.13,2 D.12,95 Cu 23: dn 11,2 lt(kc) hh kh X gm H2 v CO c t khi so vi H2 l 7,5 qua ng ng 12g rn Y, nung nng gm CuO, Fe2O3 c 10,2g rn Z. hh T gm kh v hi thot ra khi ng c t khi so vi H2 l bao nhiu? A. 9,3 B. 8,4 C 10,2 D. 9,75 Cu 24: pht biu no sau y l ng: A. photpho trng c cu trc mng tinh th nguyn t, photpho c cu trc polymer B. nitrophotka l hn hp ca NH4 H2PO4 v KNO3 C. kim cng c cu trc mng tinh th nguyn t, iot c cu trc mng tinh th phn t D. supephophat n cha hm lng P2O5 cao hn supephotphat kp Cu 25: cho 1 lung kh CO i qua ng s ng 0,04 mol hh X gm FeO v Fe2O3 t nng. Sau p c cht rn Y gm 4 cht, nng 4,784g v c 0,046 mol CO2 bay ra. Nu ha tan rn Y vo dd HNO3 d th thu c V lt NO duy nht(kc). Gi tr ca V l: A. 0,7616 B. 0,672 C.1,12 D.1,108 Cu 26: cho bt Cu d vo dd Fe(NO3)3 c dd X. cho AgNO3 d tc dng vi X, c dd Y. cho Fe tc dng vi Y, thu c hh kim loi Z. s PTP xy ra l: A.4 B.5 C.6 D.7 Cu 27: nhm cc vt liu c ch to t polymer trng hp l : A. cao su, polystyren, t enang B. PVA, thy tinh hu c, Teflon C. poly(ure-photmandehit), t lapsan, PVC D.t nitron, t lapsan, poly(phenon-photmandehit) Cu 28: 2 cht hu c X v Y u c CTPT l: C4H8O. cho X,Y tc dng vi H2 xt vi Ni, u to ra cng 1 sn phm duy nht c CT: C4H10O. X tc dng Na gii phng H2,Y khng tc dng vi Na, dd A gm AgNO3/NH3, dd Brom. CTCT ca X l: A. CH2=CHCHOHCH3 B. CH3CH=CHCH2OH C. . CH2=C(CH3)CH2OH D. CH2=CHCH2OCH3 Cu 29: cho cht hu c X c CTPT C3H10N2O2 tc dng vi dd NaOH d thu c mui Natri ca 1 cht hu c tp chc Y v cc cht v c. Khi lng phn t( theo dvC) ca Y l A. 69 B. 89 C.75 D.104 Cu 30: cho m gam hh X gm 2 cht hu c no n chc , mch h tc dng va vi dd cha 11,2 g NaOH, thu c mui ca 1 axit cacboxylic v 6,72 lt (ktc) 1 ancol. Nu t chy hon ton lng hh X trn thu c 51,4g hh gm CO2 v H2O. CT ca 2 hp cht hu c trong X l: A. CH3COOC2H5, C2H5OH B. HCOOC2H5, C2H5OH C. CH3COOC3H7, C3H7OH D. HCOOC2H5, HCOOH. Cu 31: thy phn este mch h E ( ch cha chc este) trong mi trng axit thu c hh ch gm axitcacboxylic a chc X v andehit n chc no Y. t chy hon ton E thu c nCO2-nH2O=nX. Vy este E c CT chung l: A.CnH2n-2O4 B. CnH2n-4O4 C. CnH2n-4O6 D. CnH2n-6O41 Cu 32: nung nng 4,8g bt S vi 6,5g Zn trong bnh kn khng c khng kh thu c hh rn X. ha tan X bng dd H2SO4 c, nng, d, thu c V lt SO2(kc) gi tr ca V la. A. 3,36 B. 8,96 C.12,32 D.14,56 Cu 33: hh X gm 3 amin n chc no l ng ng k tip nhau c xp theo th t khi lng mol phn t tng dn vi t l s mol tng ng 1:10:5. Cho 20g X tc dng vi dd HCl va . C cn dd thu c sau p thu c 31.68g hh mui. CT ca 3 amin l: A. CH3NH2, C2H5NH2, C3H7NH2 B. C2H5NH2, C3H7NH2, C4H9NH2 D. C4H9NH2, C5H11NH2, C6H13NH2 Cu 34: c 5 dd v cht lng sau: ddNH4HCO3,dd NaAlO2, dd C6H5ONa, C6H5NH2, HCOOH. C th dng 1 ha cht phn bit l : A.dd NaOH B.CO2 C. dd HCl D.Na 142

Cu 35: Hn hp A gm hai este n chc l X v Y l 2 este c chung gc axit. un nng m gam A vi 400 ml dung dch KOH 1M, kt thc phn ng thu c dung dch B v (m - 12,6) gam hn hp hi gm hai andehit no, n chc, ng ng k tip c t khi hi so vi H2 l 26,2. C cn dung dch B thu c (m + 6,68) gam cht rn. % khi lng ca X trong A? A. 54,66 B. 45,55 C. 36,44 D. 30,37 Cu 36: nung nng hon ton hh kh T gm but-1-en ,puta-1,3-dien v hidro c Ni xt, thu c 560ml hh kh V c t khi so vi H2 l 23,4. Nu t chy hon ton hh kh T ri hp th sn phm chy vo bnh ng dd Ca(OH)2 d, th thu c bao nhiu gam kt ta. A.10g B. 5g C.8g D.12g Cu 37: Oxi ha ancol etylic bi CuO, to vi hiu sut 80%. Thu c phn rn v dd X gm andehit, nc v ru d. Cho ton b X tc dng vi Na d thu c 4,48 lt H2 (ktc). X c khi lng l? A. 14,32 g B. 12,4 g C. 23,52 g D. 9,68 g Cu 38: chia 0,6mol hh 2 axit hu c no, thnh 2 phn bng nhau Phn 1: em t chy hon ton thu c 11,2l CO2(ktc) Phn 2: trung ha hon ton phn 2 cn 250ml dd NaOH 2M. CTCT ca 2 axit l: A. HCOOH, CH3COOH B. HCOOH, HOOC-COOH D. HCOOH, HOOC-CH2-COOH C. CH3COOH, HOOC-COOH Cu 39: cho m gam hh gm 1 axit cacboxylic n chc X v 1 este n chc Y tc dng hon ton vi 400ml dd NaOH 1M. c cn dd sau p thu c 1 ancol Z v 27,2g hh rn khan gm 2 cht c s moo bng nhau. Cho ton b ancol Z tc dng va vi Na thot ra 0,56l kh (kc) CTPT ca axit X l: A.C2H5COOH B.HCOOH C.CH2=CHCOOH D.CH3COOH Cu 40: t chy hon ton x mol axit cacboxylic E thu c y mol CO2 v z mol H2O ( vi y=z+x). cho x mol E tc dng vi NaHCO3 d thu c y/3 mol CO2. Tn ca E l: A. axit propanoic B. axit oxalic C.axit adipic D. axit metacrylic Cu 41: hh M gm 2 cht hu c X,Y k tip nhau trong cng dy ng ng, phn t ca chng ch c 1 loi nhm chc. t chy hon ton hh M , cho ton b sn phm chy (ch c CO2 v H2O) vo dd nc vi trong d, thy khi lng bnh tng 5,24g v to ra 7g cht kt ta. CTCT ca X, Y ln lt l A. C2H4(OH)2 , v HOCH2CH(OH)CH3 B. C2H4(OH)2 v HO[CH2]3OH C. HCOOH v CH3COOH D. CH3OH v C2H5OH Cu 42: t chy hon ton 2,24l (kc) hh X gm C2H4 v C4H4 th th tch kh CO2(kc) v khi lng hi H2O thu c ln lt l A. 5,6l v 2,7g B.8,96l v 3,6g C.3,36l v 3,6g D.6,72l v 3,6g Cu 43: hh X gm 2 -aminoaxit, h, no, c 1 nhm COOH v 1 nhm NH2 ng ng k tip c % khi lng O2 l 37,427%. Cho m gam X tc dng vi 800ml dd KOH 1M d, p xong c cn thu c 90,7g rn khan. Vy m c gi tr l: A. 58,14 B.67,8 C. 68,4 D.58,85 Cu 44: cho iso propen(2-metyl buta-1,3-dien) tc dng vi Brom theo t l mol 1:1 to ra ti a s ng phn cu to dn xut diBrom l A.2 B.3 C.4 D.1 Cu 45: Cho 0,25 mol hn hp X gm 2 andehit no n chc tc dng vi dung dch AgNO3 d/NH3 sinh ra 0,7 mol Ag. Mt khc khi t chy hon ton X thu c 24,2 gam CO2. Cng thc 2 andehit l? A. CH3CHO v C2H5CHO B. HCHO v CH3CHO C. HCHO v C3H7CHO D. HCHO v C2H5CHO Cu 46: hh X gm ancol metylic v 1 ru no n chc. cho 4.6g X tc dng vi Na d thu c 1,12l H2(kc). Mt khc oxi ha hon ton 4,6g X bng CuO, t0 ri cho ton b sn phm thu c tc dng vi dd Ag2O d/NH3 thu c 0,2 mol Ag . CTCT ca A l: A. C2H5OH B. CH3CHOHCH3 C.CH3CH2CH2OH D. CH3CH2CHOHCH3 Cu 47: cho cc dd c cng nng : Na2CO3(1), H2SO4(2), HCl(3), H2NCH2COOH(4), gi tri pH ca cc dd c sp xp theo chiu tng t tri sang phi l: A. 3,2,4,1 B. 4,1,2,3, C.1,2,3,4 D.2,3,4,1 Cu 48: cho cc cht sau : C6H5OH(1), C6H5NH3Cl(2), CH2=CHCOOH(3), CH3CHO(4), HCOOCH3(5) 143

Chn pht biu ng: A. ch c 3 p vi NaHCO3 B. ch c 4 p vi dd AgNO3/NH3 C.cc cht p c ancol etylic: 1,3 D. cc cht p c NaOH:1,3,5 Cu 49: X l tetrapeptit. Cho m gam X tc dng va vi 0,3 mol NaOH thu c 34,95g mui. Phn t khi ca X l? A. 324 B. 432 C. 234 D. 324 Cu 50: C bao nhiu amino axit v este ca amiono axit l ng phn cu to ca nhau c cng cng thc phn t l C4H9NO2? A. 6 B. 7 C. 8 D. 9 1 A 21 C 41 D 2 A 22 A 42 D 3 C 23 A 43 A 4 D 24 C 44 B 5 B 25 A 45 D 6 C 26 B 46 B 7 D 27 B 47 D 8 D 28 A 48 A 9 C 29 B 49 D 10 C 30 B 50 C 11 B 31 D 12 B 32 C 13 A 33 B 14 D 34 C 15 C 35 C 16 A 36 C 17 C 37 C 18 A 38 B 19 B 39 A 20 A 40 C

15 Cu 1: Ha tan m gam FeCl2 vo dung dch H2SO4 long d ri trn vi 40ml dung dch KMnO4 0,5 M thu c dd X vn cn mu tm v kh Y. mt mu tm ca X cn va 0,448 lt SO2. Cc phn ng xy ra hon ton. Gi tr ca m l: A. 2,54 B. 5,08 C. 3,81 D. 7,62 Cu 2: Cho dy chuyn ha: A B dd xanh lam A c th l nhng cht no trong dy sau y: A. Glucozo, saccarozo, mantozo B. Fructozo, saccarozo, xenlulozo C. Saccarozo, mantozo, tinh bt D. Glucozo, fructozo, mantozo Cu 3: cho dy cc cht : axetandehit axeton, axitfomic, glucozo, saccarozo, mantozo. S cc cht trong dy lm mt mu nc brom l? A. 3 B. 4 C. 5 D. 6 Cu 4: X phng ha hon ton 3,98 gam hn hp hai este bng dd NaOH thu c 4,1g mui ca mt axit cacboxylic v m gam hh 2 ancol l ng ng kt tip nhau. un nng hon ton m gam hh 2 ancol vi H2SO4 c, 140o thu c 0,45g H2O. Cng thc ca hai este l? A. HCOOCH3 v HCOOC2H5 B. C2H5COOCH3 v C2H5COOC2H5 C. CH3COOC2H5 v CH3COOC3H7 D. CH3COOCH3 v CH3COOC2H5 Cu 5: T cht no sau y iu ch c poli (vinyl ancol) bng 2 phn ng: A. CH2=CHCOOCH3 B. CH2=CH-COOCH2CH=CH2 C. CH2=CHCH2OH D. CH2=CHO-COCH3 Cu 6: Tng s electron trong 2 ion XY32- v XY42- ln lt l 42, 50. Ch ra pht biu khng ng A. X thuc chu k 3, nhm VIA B. X c tnh phi kim mnh hn Y C. X, Y u c cu hnh electron lp ngoi cng l ns2np4 D. Y c m in ln hn X Cu 7: Thc nghim cho thy tc ca phn ng ha hc A(k) + B(k) A B c tnh theo biu thc v= k[A].[B] vi k l hng s tc . Khi tng nng ca A v B gp 3 ln th tc p tng 81 ln. Tnh ? A. 2 B. 3 C. 4 D. 5 Cu 8: Cho cn bng: N2 + 3H2 2NH3 H<0. Ch ra pht biu sai? A. Gim th tch bnh cha, cn bng chuyn dch theo chiu thun B. Thm mt t bt Fe lm cht xc tc cn bng chuyn dch theo chiu thun C. Thm mt t H2SO4 cn bng chuyn dch theo chiu thun D. Tng nhit , cn bng chuyn dch theo chiu nghch Cu 9: Cho cc cp cht: nhng phn ng c cng phng trnh ion thu gn l; (1) Na2CO3 + BaCl2 144

(2) (NH4)2CO3 + Ba(OH)2 (3) Ba(HCO3)2 + K2CO3 (4) BaCl2 + MgCO3 (5) CO2 + Ba(OH)2 d (6) (NH4)2CO3 + BaCl2 A. 1, 2, 6 B. 1, 3, 5 C. 1, 3, 6 D. 1, 3, 4, 6 Cu 10: Dung dch ca nc cht A lm qu tm ng sang mu xanh, cn dd nc ca cht B khng lm qu tm i mu. Trn dd A v B xut hin kt ta. A v B l? A. NaOH, K2SO4 B. K2CO3, Ba(NO3)2 C. KOH, FeCl3 D. Ba(OH)2, NaHSO4 Cu 11: Nung nng hh dd X gm Al v mt oxit st trong iu kin khng c khng kh. Sau khi p xy ra hon ton thu c 14,85g hh cht rn Y. Cho Y tc dng vi dd V ml dd NaOH 2M thu c 1,68 lt H2 kc. Nu cho Y tc dng vi dd H2SO4 long d thu c 5,04 lt kh H2 kc. Cng thc ca oxit st v V? A. Fe2O3, 75ml B. Fe2O3, 50ml C. FeO, 75ml D. Fe3O4, 50ml Cu 12: Hn hp kh X gm 0,4 mol H2; 0,1 mol axetilen v 0,2 mol propen. Nung X mt thi gian vi xc tc Ni thu c hh kh Y c t khi so vi hidro l 14,75. Nu cho ton b Y sc t t vo dd brom (d) th c m gam brom tham gia p. Gi tr ca m l? A. 16 B. 8 C. 3,2 D. 32 Cu 13: Mt hh A cha H2 v mt anken c t khi so vi hidro bng 6,4. Dn A qua bt Ni nung nng thu c hh kh B khng lm mt mu dd brom v c t khi so vi hidro bng 8. Xc nh cng thc phn t ca anken. A. C2H4 B. C5H10 C. C3H6 D. C4H8 Cu 14: Ch ra pht biu khng ng: A. ng trng hp buta-1,3-d9ien vi acrilonitrin c xc tc Na c cao su buna-N. B. Cao su thin nhin l polime ca isoprene v mch phn t c cu hnh cis. C. Trng ngng hecxametylen iamin v axit terephtalic thu c nilon-6,6. D. t nilon-6,6; t capron, t enan thuc loi t poliamit. Cu 15: t chy hh X cha 3 rc no n chc mch h thu c 22,4 lt CO2 ktc v 28,8 gam H2O. Mt khc cho cng lng hh ru trn tc dng vi Na va thu c n gam cht rn. Gi tr ca m l? A. 38,6 B. 13,2 C. 38 D. 24,8 Cu 16: dung dch HCOOH 0,092% c D= 1g/ml. in li = 5%. pH ca dd l? A.3 B.4 C.5 D.2,78 Cu 17: Cho cc p xy ra trong dung dch I. AlCl3 + Na2CO3 II. Ba(HCO3)2 + H2SO4 III. BaCO3 + NaHSO4 IV. Ca(OH)2 + Ca(HCO3)2 V. Mg(HCO3)2 + H2SO4 VI. Ca(OH)2 + Na2CO3 S trng hp sau p va to kt ta va c kh bay ra? A.4 B.2 C.3 D.5 Cu 18: Cho cc p sau. S p m NH3 th hin tnh kh l? a. 2NH3 + 3Cl2 b. FeCl2 + 2NH3 + H2O c. NH3 +CO2 + H2O d. Cu(OH)2 + 4NH3 e. NH3 + CuO g. 2NH3 + 5/2O2 A.2 B.3 C.4 D.5 Cu 19: hon tan mt mu Zn trong dd HCl 25oC cn 243 pht. Cng mu Zn tan ht trong dd HCl nh trn 65oC cn 3 pht. ha tan ht mu Zn trong dd HCl c nng nh trn 45oC cn thi gian bao lu? A. 9 pht B. 81 pht C. 27 pht D. 18 pht Cu 20: C 1 s nhn nh v nhm, crom, st nh sau: a. C ba kim loi u b th ng ha vi HNO3 v H2SO4 c ngui. 145

b. c ba kim loi bn trong khng kh v nc do c lp oxit bo v c. tnh kh gim dn: Al, Fe, Cr d. t cc oxit ca chng, iu ch Al bng in phn nng chy, iu ch crom, st bng phng php nhit luyn e. c 3 kim loi tc dng vi Clo theo t l s mol. f. Al, Fe, Cr u l cc kim loi chuyn tip S nhn nh ng l? A.4 B.2 C.3 D.5 Cu 21: Mt loi vi cha 80% CaCO3 (v khi lng) phn cn li l tp cht tr. Nung nhit cao thu c cht rn c khi lng bng 73,6% khi lng trc khi nung. Hiu sut p phn hy CaCO3 v % CaO trong cht rn sau khi nung l? A. 62,5% v 35,9% B. 75% v 45,7% C. 62,5% v 37,5% D. 75% v 42% Cu 22: cho cc cht: phenol (1),anilin (2), toluen (3), metyl phenyl ete (4). Nhng cht tc dng vi nc Br2 l? A. (1), (2), (3) v (4) B. (3) v (4) C. (1), (2) v (4) D. (1) v (2) Cu 23: Khi nung butan vi xc tc thch hp thu c hh t gm CH4, C3H6, C2H4, C2H6, C4H8, H2 v C4H10 d. t chy hon ton hh T thu c 8,96 lt CO2(kc). Mt khc, hh T lm mt mu va ht 12g Br2 trong dd nc Brom. Hiu sut phn ng nung butan l? A. 45% B. 75% C. 50% D. 65% Cu 24: Cho m gam cht hu c A ch cha 1 loi chc tc dng vi 1 lt dd NaoH 0,5M thu c 16,4g mui v 0,1 mol ancol. Lng NaOH d c trung ha ht bng 0,5 lt HCl 0,6M. CT thu gn ca A. A. (CH3COO)3C3H5 B. C2H4(COOCH3)2 C. (C2H5COO)2C2H4 D. (CH3COO)2C2H4 Cu 25: t chy hon ton m gam hh gm HCHO, CH3COOH, C6H12O6, v glixerol thu c 29,12 lt CO2 kc v 27 gam H2O. Thnh phn % v khi lng ca glixerol trong hh: A. 43,8% B. 46,7% C. 35,1% D. 23,4% Cu 26: to lipit t grixerol phn ng vi 2 axit bo RCOOH, RCOOH, ta thu c hh cc Trieste . tnh s trieste ny? A.8 B.6 C.5 D.4 Cu 27: cho 1 lng Fe tan ht vo dd cha 0,1 mol HNO3 v 0,15 mol AgNO3 sau phn ng thu c dd X ch cha Fe(NO3)3, kh NO v cht rn Y. cho x gam bt Cu vo dd X thu c dd Z trong c khi lng Fe(NO3)3 l 7,986g. x c gi tri l: A.1,536g B.1,28g C.1,92g D.1,344g Cu 28: ha tan m gam hh Al,Ba vi s mol bng nhau vo nc c dd X.cho t t dd HCl 0,5M vo dd X n khi khi lng kt ta t gi tr ln nht thy dng ht 200ml. gi tr ca m l: A. 8,2g B. 16,4g C. 13,7g D. 9,55g Cu 29: khi trn cc hh : H2, O2(1); NO, O2(2); CO, N2(3); NH3, HCl(4); th cc hh c th tch gim ngay k thng l : A. 1,2 B. 3,4 C. 1,2,4 D. 2,4 Cu 30: phn bit cc cht rn : Fe, FeS, Fe3O4 trong cc l mt nhn, ta dng : A.HCl B.HNO3 D.CuCl2 C.H2SO4 Cu 31: cho Fe tc dng hon ton vi S, thu c hh rn X. cho hh X tc dng vi dd HCl d thu c 0,336l kh duy nht kc. Cho hh cn li tc dng vi dd HNO3 c nng d, thu c 4,368l kh nu duy nht kc. Thnh phn % khi lng Fe trong hh ban u. A.52,21% B. 52,12% C.25,21% D.51,22% Cu 32: trong cc dd sau: Ca(OH)2, BaCl2, Br2, H2S, KMnO4. S dd c th dng phn bit 2 kh: SO2, v CO2 l: A.1 B.2 C.3 D.4 Cu 33: Cho 3,45 gam Na vo V ml dd HCl 0,1M v H2SO4 0,05M thu c dd D c pH = 13. Gi tr ca V (Xem th tch dd khng thay i) A. 750 ml B. 375 ml C. 500 ml D. 200 ml Cu 34: cho dy cc cht : CrH3, Al2(SO4)3, Mg(OH)2, Zn(OH)2, NaHSO4, Ca(HCO3)2, CrO3 146

S cht trong dy c tnh cht lng tnh l: A. 5 B.2 C.3 D.4 Cu 35: cho 1,93g hh gm Fe, Al tc dng vi dd cha Cu2+ v 0,03 mol Ag+ . sau p thu c hh 2 kim loi c khi lng 6,44g. khi lng mi kim loi c trong hh u: A. 1,12g v 0,81g B. 1,39g v 0,54g C.0,85g v 1,08g D.0,56g v 1,37g Cu 36: in phn vi in cc tr dd cha 0,3mol AgNO3 vi I = 2,68A trong thi gian t gi thu c dd X(H= 100%). Cho 22,4 g bt Fe vo X thy thot ra kh NO sn phm kh duy nht v sau khi cc p xy ra hon ton thu c 34,28g cht rn. gi tr ca t l: A. 1 B. 0,25 C.1,2 D. 0,6 Cu 37: dn V lt kh Cl2 kc, vo dd cha 0,01 mol CrCl3 khi c mt KOH d. Tnh V lt kh Cl2 cn dng thu c mui Cromat nhiu nht A. 0,224 B. 0,672 C.0,448 D.0,336 Cu 38: X l dd AlCl3 , Y l dd NaOH 2M. thm 150 ml dd Y vo cc cha 100ml dd X, khy u ti p hon ton thu c 7,8g kt ta. thm tip 100ml dd Y , khuy u ti p hon ton li thu c 10,92g kt ta . nn mol/l ca dd X l: A. 1,6M B. 1,4M C. 2M D.1M Cu 39 : ha tan ht 9g hh gm Mg v Al vo dd H2SO4 long, d thu c 9,408l kh kc v dd X. thm vo dd X 1 lng d dd Na2CO3 n khi p xy ra hon ton thu c m gam kt ta. gi tr ca m l: A. 19,68g B. 20,16g C.29,52g D. 34,42g Cu 40: cho m gam Na vo 500ml dd HCl 0,1M v H2SO4 0,05M thu c dd D c pH = 13 . gi tr ca m l (xem th tch ca dd khng i) A. 3,45g B. 6,9g C.2,3g D.4,6g Cu 41: Pht biu ng l? A. Glucozo b kh bi AgNO3 trong dung dch NH3 (d) B. Benzen v cc ng ng ca n u lm mt mu dung dch thuc tm khi un nng C. Cho HNO2 vo dung dch alanin hoc dung dch etyl amin th u c si bt kh thot ra D. Lc bazo tng dn theo dy: C2H5ONa, NaOH, C6H5ONa, CH3COONa Cu 42: trong cc cht : CH3CH2CH2OH, C2H2, HCOOCH3, CH2=CHCl, CH4. S cht c th to andehit bng 1 p l: A. 2 B. 3 C. 4 D.5 Cu 43: un nng hh gm 1 ancol bc I v 1 ancol bc III no, n chc, vi H2SO4 c 1400C thu c 5,4g H2O v 26,4g hh 3 ete vi cc ete c s mol bng nhau. CTPT ca 2 ancol l: B. C2H6O; C4H10O A.C2H6O; C3H8O C. CH4O; C4H10O D. C3H8O; C4H10O Cu 44: kh 1,6g hh 2 andehit no bng kh H2 thu c hh 2 ancol. Dun nng 2 ancol ny vi H2SO4 c thu c hh 2 olefin l ng ng k tip. dt chy 2 olefin ny c 3,52g CO2. Bit cc p xy ra hon ton. CT ca 2 andehit l: A. HCHO; CH3CHO B. CH3CHO; C2H5CHO C. C2H5CHO; C3H7CHO D. CH3CHO; CH2(CHO)2 Cu 45: oxi ha 3,75g 1 andehit n chc X, bng oxi c xc tc thu c 5,35g hh Y gm axit,andehit d. t chy hon ton X ri cho sn phm chy hp th vo dd Ca(OH)2 d th khi lng kt ta thu c l A. 12,5g B. 17,05g C. 19,4g D. 25g Cu 46: t chy hon ton 29,16g hh X gm RCOOH, C2H3COOH, (COOH)2 thu c m gam H2O v 21,952g CO2 KC mt khc, 29,16g hh X p hon ton vi NaHCO3 d thu c 11,2l CO2 kc. Gi tr ca m l: A. 10,8 B.12,6 C.9 D.8,1 Cu 47: cho 5,28g este n chc, mch h p va vi 300ml dd AOH 0,2M. (A l kim loi kim) sau p hon ton, c cn dd thu c cht rn X ,t chy hon ton X thu c A2CO3 v 6,72l kc hh Y gm CO2, H2O. este l; A. CH3COOC2H5 B.C2H5COOCH3 C. C2H5COO C2H5 D. HCOOC3H7 Cu 48: cho hh kh X gm HCHO , v H2 i qua ng s ng bt NI un nng. Sau khi p xy ra hon ton thu c hh kh Y gm 2 cht hu c. t chy ht Y th thu c x mol CO2 v (x+0,3) mol H2O ( ktc).cho Y tc dng vi lng d AgNO3/NH3, sinh ra 21,6 gam Ag. Phn tram theo th tch ca H2 trong X l? A. 65,00% B. 46,15% 147

C. 35,00% D. 53,85% Cu 49: C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H2 xc tc Ni, to. A. 2 B. 3 C. 4 D.5 Cu 50: Hn hp kh X gm etylamin v hai hidrocacbon ng ng. t chy hon ton 120ml hh X bng mt lng oxi va , thu c Vml hh Y gm kh v hi nc. Nu cho Y i qua dd axit sunfuric c (d) th cn li 240ml kh (cc th tch kh v hi o cng iu kin). Gi tr ca V? A. 600 B. 360 C. 480 D. 550 1 A 21 B 41 C 2 C 22 C 42 C 3 B 23 B 43 C 4 D 24 D 44 B 5 D 25 B 45 A 6 B 26 B 46 B 7 B 27 D 47 B 8 B 28 A 48 B 9 C 29 D 49 B 10 B 30 A 50 A 11 C 31 D 12 A 32 C 13 D 33 C 14 C 34 C 15 C 35 A 16 A 36 C 17 C 37 D 18 B 38 A 19 C 39 C 20 C 40 A

16 Cu 1: t chy hon ton 1 este X thy th tch CO2, hi H2O v O2 phn ng c t l tng ng l 6:6:7 (cc th tch kh o cng k). Cho m gam X tc dng hon ton vi 400ml dd KOH 0,7M thu c dd Y. c cn Y thu c 25,76g cht rn khan. Gi tr ca m l: A. 21,12 B.13,32 C.17,76 D. 14,4 Cu 2: hh X gm 1 andehit v 1 ankin c cng s nguyn t cacbon. t chy hon ton a mol hh X thu c 3a mol CO2 v 1,8a mol H2O . vy 0,1 mol hh X tc dng c vi ti a bao nhiu gam Brom trong dd A. 35,2 B. 22,4 C. 16 D. 38,4 Cu 3: t chy hon ton m gam hh gm 4 cht : andehit fomit, axit axetit, 2-hidroxy propanoic v etilen glycol thu c 29,12l CO2 kc v 27g H2O. thnh phn phn tram khi lng ca etylen glycol trong hh l bao nhiu. A. 43,8% B. 28,38% C. 31,47% D. 23,40% Cu 4: 1 ancol n chc no A c % O l 50%. Oxi ha hon ton m gam A vi oxi xc tc thch hp thu c hh X gm andehit,axit, v H2O .cho X tc dng vi AgNO3/NH3 thu c 0,32mol Ag. Cho X tc dng Na d thu c 0,07 mol H2. Gi tr ca m l: A. 5,52g B. 6,4g C. 7,4g D.3,2g Cu 5: cho este X n chc no tc dng va vi NaOH thu c 12,8g hhY gm mui v ankan. t chy hon ton Y, thu c CO2, H2O 5,3g Na2CO3. S CTCT ph hp vi X l; A. 2 B. 4 C. 3 D. 6 Cu 6: polyme dng ch to thy tinh hu c c iu ch bng phn ng trng hp : A. CH2=CHCOOCH3 B. CH2=C(CH3)COOH C.CH2=C(CH3)COOCH3 D.CH3COOCH=CH2 Cu 7: cho cc p a. t Fe trong kh Clo b. cho hp kim Al-Cu vo dd HCl c. nhng thanh NI vo dd CuSO4 d. nhng thanh Cu vo dd (FeSO4 v H2SO4 long) e. hp kim Fe-C trong khng kh m g. nhng thanh Fe vo dd FeCl3 s trng hp xut hin n mn in ha l: A. 1 B.2 C.4 D.3 Cu 8: ch ra pht biu khng ng A. bin nhit tng dn t: NH3, PH3, ASH3. B. tnh axit gim gin t: HNO3, HPO3, HASO3 C. tnh axit tng dn t : HF, HCl, HBr, HI 148

D.tnh bazo gim dn t: KOH, NaOH, Mg(OH)2, Al(OH)3 Cu 9: ngi ta cho N2 v H2 v 1 bnh kn , th tch khng i v thc hin p tng hp ammoniac. Khi h t n cn bng ha hc, nng cc cht trong bnh nh sau: [N2]=2,5 M; [H2]=1,5M; [NH3]=2M. Vy nng ban u (CM) ca N2 v H2 ln lt l: A. 3.5M v 4,5M B. 3,5M v 2,5M C. 3,5M v 3,5M D. 2,5M v 4,5M Cu 10: cho tirosin (HOC6H4CH2CH(NH2)COOH) (X) phn ng vi cc cht sau, trng hp no pthh vit khng ng: A. X + 2NaOH NaOC6H4CH2CH(NH2)COONa + 2H2O B. X + 2HCl Cl-C6H4CH2CH(COOH)NH3Cl + H2O C. X + HNO2 HOC6H4CH2CH(OH)COOH + H2O + N2 D. X + C2H5OH HOC6H4CH2CH(NH2)COOC2H5 + H2O Cu 11: hh bt X gm BaCO3 , Fe(OH)2, Al(OH)3, CuO,MgCO3. Nung X trong khng kh n khi lng khng i c hh rn A1. Cho A1 vo nc d khuy u c dd B cha 2 cht tan v phn khng tan C1. Cho kh CO d qua bnh cha C1 nung nng c hn hp rn E (Cho cc phn ng xy ra hon ton). E cha ti a? A. 1 n cht v 2 hp cht B. 3 n cht C. 2 n cht v 2 hp cht D. 2 n cht v 1 hp cht. Cu 12: Ch dng Cu(OH)2 c th phn bit c tt c cc cht trong dd? A. saccarozo, glixerin, andehitaxetic, rc etylic B. glucozo, anbumin, glixerin, rc etylic C. glucozo, anbumin, glixerin, fructozo D. glucozo, glixerin, andehitaxetic, mantozo Cu 13: Cho cc phn ng sau: a. NH4Cl + NaNO2 b. Cu(NO3)2 c. (NH4)2CO3 d. CuO + NH3 e. H2NCH2COOH + HNO2 g. C6H5NH2 + HNO2 + HCl S phn ng to ra N2 l? A.2 B.3 C.1 D.4 Cu 14: Cho ancol (X) 2 chc mch tc dng vi lng d CO2 nung nng n phn ng hon ton thu c 9,36g 1 cht hu c Y, ng thi thy lng cht rn gim i 4,16g. Bit Y tc dng vi H2(Ni,to) c c cht Z ha tan c Cu(OH)2. CTCT ca Y l? B. CH3-CH(CHO)2 A. (CHO)2 C. CH3-CO-CHO D. CH2(CHO)2 Cu 15: Cho 6 hp cht hu c: p-crezol, phenyl amoniclorua, axit metacrilic, anilin, ninyl axetat, axit amino axetic. S cht tc dng c c hai ha cht l dd NaOH v dd Br2 l: A.3 B.4 C.5 D.6 Cu 16: X, Y l 2 ng phn c CTPT C4H9O2N. Khi phn ng vi NaOH, X to mui Natri ca alanine v cht hu c Z, cn Y to mui natri ca axit acrylic v kh T. Vy Z v T ln lt l? A. CH3OH, NH3 B. C2H5OH, CH3NH2 C. CH3OH, CH3NH2 D. C2H5OH, CH3NH2NH2 Cu 17: t chy hon ton este X mch h, cha mt loi chc thu c nCO2 nH2O = 2nX. Nu thy phn X trong mi trng axit thu c axit hu c Y v andehit no n chc Z. Vy pht biu ng l? A. axit hu c Y lm mt mu dd nc Brom B. este X c t nht 4 nguyn t cacbon trong phn t. C. andehit Z c nhit si thp nht trong dy ng ng. D. axit hu c Y khng phi n chc Cu 18: nhn bit cc kh: CO2, SO2, H2S, N2 cn dng cc dd: A. nc brom v dd Ca(OH)2 B. nc brom v dd NaOH C. KMnO4 v NaOH D. NaOH v Ca(OH)2 Cu 19: Phn ng no sau y khng dng iu ch trong phng th nghim? A. Cho FeS tc dng vi dd HCl to H2S B. Cho Na2SO3 tc dng vi dd H2SO4 to SO2 C. Cho NaNO3 rn tc dng vi dd H2SO4 c un nng to HNO3 D. in phn dd NaCl bo ha c mng ngn iu ch Clo Cu 20: tch CO2 ra khi hn hp vi HCl v hi nc. Cho hn hp ln lt i qua cc bnh: A. Na2CO3 v P2O5 B. NaOH v H2SO4 149

C. H2SO4 v KOH D. NaHCO3 v P2O5 Cu 21: Nguyn t ca nguyn t X to cation X2+. Trong cation X2+ c tng s ht p, n, e = 80 v t s ht electron so vi ht notron l 4/5. V tr ca X trong bng tun hon l? A. chu k 4, nhm IIA B. chu k 4, nhm VIA C. chu k 4, nhm VIIIB D. chu k 4, nhm IIB Cu 22: Dn lung kh CO qua ng s cha 7,2g Fe2O3 nung nng sau mt thi gian thu c 6,72g cht rn B. Ha tan hon ton B trong dd HNO3 d thu c 0,448 lt kh X l sn phm kh duy nht ktc. X l? A. N2O B. N2 C. NO2 D. NO Cu 23: A l hn hp cc mui Cu(NO3)2, Fe(NO3)2, Mg(NO3)2. Bit trong A th oxi chim 38,4% v khi lng. Cho dung dch KOH d vo dung dch cha 50g mui A. Lc kt ta thu c em nung trong chn khng n khi lng khng i thu c m gam oxit. Gi tr ca m l? A. 28,4 B. 18,2 C. 32,4 D. 17,6 Cu 24: Ha tan 6,4g bt Cu vo 100ml dd hn hp HCl 2M v Fe(NO3)3 0,2M to ra dung dch c khi lng mui bao nhiu? Bit sau phn ng c kh NO l sn phm kh duy nht. A. 13,66g B. 15,24g C. 14,28g D. 13,68g Cu 25: Ha tan mui cacbonnat ca kim loi X bng mt lng va dung dch H2SO4 9,8% thu c dung dch mui sunfat c nng 14,18%. Kim loi X l? A. Fe B. Zn C. Cu D. Mg Cu 26: Hon tan hon ton 74g hh gm FeO, Fe3O4, Fe2O3, bng dd H2SO4 long d sinh ra 178g mui sunfat. Nu cho 74g X tc dng vi CO d, to v dn sn phm kh qua dd Ca(OH)2 d th to khi lng kt ta l? A. 130g B. 150g C. 180g D. 240g Cu 27: Chia 7,8g hn hp ru etylic v mt ng ng ca n thnh hai phn bng nhau. Phn 1 tc dng vi Na (d) thu c 1,12 lt kh (ktc). Phn 2 tc dng vi 30g CH3COOH (c mt H2SO4 c). Tnh tng khi lng este thu c. Bit hiu sut phn ng este ha u l 80% A. 8,1g B. 8,8g C. 6,48g D. 7,48g Cu 28: C mt s pht biu: 1. Phenol v ancol benzylic u khng tc dng c vi HCl (c xt) 2. Phenol, anilin, ancol benzylic, benzyl amin u khng lm i mu giy qu tm 3. Andehit v xeton u cng c vi hidro xianua. 4. Trong cng nghip, phenol c sn xut t phenol 5. Kh nng phn ng th brom vng cng d dn theo th t: nitro benzen, benzene, toluene, phenol. 6. Cc cht: HCOOH, CH3COOH, H2CO3, C6H5OH, H2O, C2H5OH c lc axit gim dn t tri sang phi. S pht biu sai? A. 2, 4, 5, 6 B. 3, 4, 5, 6 C. 1, 2, 4, 6 D. 1, 4, 5, 6 Cu 29: X l hp cht tc dng vi Na2CO3 nhng khng to CO2. Khi cho X tc dng vi Na th s mol H2 sinh ra bng s mol X, khi cho X tc dng vi dd NaOH th s mol NaOH bng s mol X. X l cht no trong s cc cht di y? A. HOC6H4CH2COOH B. HOC6H4COOH C. HOC6H4OH D. HOCH2 C6H4OH Cu 30: Cho cng khi lng mi cht: CH3OH, CH3COOH, C2H4(OH)2, C3H5(OH)3 tc dng hon ton vi Na d. S mol H2 sinh ra ln nht t phn ng: B. CH3COOH A. CH3OH C. C2H4(OH)2 D. C3H5(OH)3 Cu 31: Cp cht no sau y khng th tham gia phn ng trng ngng? A. Phenol v fomandehit B. Buta-1,3-dien v stiren C. Axit adipic v hexametylen iamin D. Axit terephtalic v etylen glicol Cu 32: Nhng mt thanh kim loi M (ho tr 2) c khi lng 20 gam vo dd AgNO3 mt thi gian thy khi lng thanh M tng 15,1% so vi khi lng ban u. Nu ly lng M bng lng M tham gia phn ng trn tc dng ht vi dd HCl th thu c 0,448 lt kh H2 (ktc). Kim loi M l A. Ni. B. Pb. C. Zn. D. Mg. Cu 33: Cho cc cht: axetylen, vinyl axetylen, cumen, stiren, xyclohexan, xyclopropan v xyclopentan. Trong cc cht trn, s cht phn ng c vi dung dch Brom l: 150

A. 6 B. 5 C. 4 D. 3 Cu 34: Nhit phn hon ton hh X gm: CaCO3 v Na2CO3 thu c 29 g cht rn v V lt CO2. Hp th ht V lt CO2 vo 200 ml dd NaOH 2M to dd thu c c kh nng tc dng ti a 100 ml dd KOH 1M. Khi lng Na2CO3 trong X l: A. 15 g B. 4 g C. 12 g D. 10 g Cu 35: t chy hon ton hh X gm: FeS2 v Cu2S vi t l mol 1:1 thu c 3,36 lt SO2 (kc) v cht Y gm Fe2O3 v Cu2O. Hp th ht SO2 bng dd Brom va thu c dd Z c nng long. Cho ton b Y vo Z n p hon ton cn li m gam rn khng tan (bit Cu2O tc dng dd axit long to Cu2+ v Cu). Gi tr ca m l: A. 6,4 B. 3,2 C. 1,6 D. 0,8 Cu 36: Ha tan 20,8 g hh bt gm FeS, FeS2, S bng dd HNO3 c nng d thu c 53,76 lt NO2 (sn phm kh duy nht kc) vo dd X. Dd X tc dng vi dd NaOH d, lc ly ton b kt ta nung trong khng kh n khi lng khng i th khi lng cht rn thu c l: A. 9 g B. 8,2 g C. 10,7 g D. 16 g Cu 37: Nung nng 48,3 g hh gm Al v Fe3O4 trong k khng c khng kh. Sau khi p xy ra hon ton, thu c hh rn X. Cho X tc dng vi dd NaOH d thu c dd Y, cht rn Z v V lt kh H2 kc. Sc kh CO2 (d) vo dd Y, thu c 39 g kt ta. Gi tr ca V l: A. 3,36 B. 2,24 C. 4,48 D. 6,72 Cu 38: Nung 17,76 g hh M gm Al v Fe3O4 trong k khng c khng kh n p hon ton thu c cht rn M1. Ha tan M1 bng dung dch H2SO4 long d thu c 12,768 lt H2 kc. Tng s mol Al v Fe3O4 l A. 0,45 B. 0,4 C. 0,43 D. 0,5 Cu 39: Cho 11,6 g mui FeCO3 tc dng va vi dd HNO3, c hh kh CO2, NO v dd X. Khi thm dd HCl d vo dd X th thu c dd ha tan ti a bao nhiu gam bt ng kim loi, bit rng c kh NO duy nht bay ra. A. 14,4 g B. 3,2 g C. 28,8 g D. 32 g Cu 40: o chnh xc th tch ca dd chun trong chun th tch ta thng dng: A. Pipet B. Bnh nh mc C. Buret D. ng ong Cu 41: Trong nhng ng phn mch h ca C4H6 c bao nhiu cht khi cng Br2 theo t l 1:1 to thnh cp ng phn cis-trans A. 4 B. 3 C. 5 D. 6 Cu 42: 2,3 g hydrocacbon A tc dng vi lng d dd AgNO3 trong ammoniac to 7,65 g kt ta. A c th c bao nhiu CTCT. Bit MA < 135. A. 3 B. 4 C. 5 D. 6 Cu 43: Cho hydrocacbon khng no mch h X tc dng vi nc Brom d to ra hp cht Y cha 4 nguyn t Brom. Bit trong Y th % khi lng cacbon l 10%. t 0,1 mol X thu c s gam CO2. A. 17,6 g B. 22 g C. 13,2 g D. 8,8 g Cu 44: Cho cc hp cht: C6H6, CH3COONa, Al4C3, NaCN, CCl4, C12H22O11, CO, C2H7N, (NH2)2CO. S hp cht hu c l: A. 5 B. 6 C. 4 D. 7 Cu 45: Hp cht hu c X tc dng c Na v vi Cu(OH)2 trong mi trng kim khi un nng. Th tch ca 3,7 g hi cht X bng th tch ca 1,6 g kh O2 (cng k v nhit v p sut). Khi t chy hon ton 1 g X th th tch kh CO2 thu c vt qu 0,7 lt kc. CTCT ca X l: A. CH3-CO-CH2OH B. O=CH-CH2-CH2OH C. HOOC-CHO D. HCOOC2H5 Cu 46: C bao nhiu ng phn l hp cht thm c CTPT l C7H8O A. 3 B. 4 C. 5 D. 6 Cu 47: Hn hp A gm C3H4 v H2. Cho A i qua ng ng bt Ni nung nng thu c hh B ch gm 3 hydrocacbon c t khi so vi H2 21,5. T khi ca A so vi H2 l: A. 10,4 B. 9,2 C. 7,2 D. 8,6 151

Cu 48: Hn hp X gm axit fomic, metylfomat, etylaxetat, dimetyloxalat. Cho m gam X tc dng va vi dd cha 0,6 mol NaOH. Mt khc, t chy hon ton m g X cn 29,12 lt kh O2 kc, thu c 1,3 mol CO2 v y mol H2O. Gi tr ca y l: A. 1,3 B. 0,6 C. 1,2 D. 1,1 Cu 49: Hp cht hu c A c CTPT dng CxHyO2, trong oxy chim 29,09% v khi lng. Bit A tc dng vi NaOH theo t l 1:2 v tc dng vi Br2 trong dd theo t l 1:3. Tn gi ca A l: A. Ancol m-hydroxibenzylic B. m-hydroxibenzen C. p-dihydroxibenzen D. axit benzoic Cu 50: Cho 0,15 mol lysine v 0,2 mol alanine vo 225 ml dd NaOH 2M thu c dd X. Cho HCl d vo dd X. Sau khi cc p xy ra hon ton s mol HCl p l: A. 0,80 B. 0,95 C. 0,70 D. 0,725 1 C 21 C 41 A 2 A 22 D 42 B 3 C 23 A 43 C 4 D 24 C 44 A 5 B 25 A 45 B 6 C 26 A 46 C 7 D 27 C 47 D 8 A 28 B 48 C 9 A 29 D 49 B 10 B 30 D 50 B 11 D 31 B 12 B 32 C 13 B 33 B 14 C 34 A 15 A 35 C 16 C 36 D 17 A 37 A 18 A 38 C 19 D 39 D 20 D 40 C

17 Cu 1: Cho hn hp X gm 2 ancol, mch h thuc cng dy ng ng. t chy hon ton hh X thu c CO2 v H2O c t l mol tng ng l 3:4. Mt khc, cho 2,5 mol hh M tc dng vi Na (d), thu c nhiu hn 0,15 mol H2. Hai ancol l? A. C2H4(OH)2 v C3H6(OH)2 B. C2H5OH v C4H9OH C. C2H4(OH)2 v C4H8(OH)2 D. C2H5OH v C4H8(OH)2 Cu 2: C bao nhiu hp cht thm c CTPT C8H10O tc dng Na v b oxi ha vi CuO, to to sn phm trng gng c? A.4 B.2 C.3 D.5 Cu 3: Cho 0,05 mol cht hu c X tc dng hon ton vi dd Br2 d thu c cht Y th c 8 gam Br2 p. Cho cht Y tc dng vi KOH un nng trong nc nng thu c cht Z khng c kh nng ha tan Cu(OH)2. Cht X l? A. isobutilen B. xiclopropan C. propen D. propin Cu 4: Hp cht ion G to nn t cc ion n nguyn t M2+ v X2-. Tng s ht (no7tron, proton, electron) trong phn t G l 84, trong s ht mang in nhiu hn s ht khng mang in l 28 ht. S ht mang in ca ion X2t hn s ht mang in ca ion M2+ l 20 ht. V tr ca M trong bn tun hon l? A. 20, chu k 4, nhm IIA. B. 12, chu k 3, nhm IIA. C. 8, chu k 2, nhm VIA. D. 26, chu k 4, nhm VIIIB. Cu 5: Ch ra pht biu khng ng: A. Cc ion F-, Na+, Mg2+, Al3+ c bn knh tng dn. B. Mng tinh th n cht ca Li, Na, K, Ba u l kiu mng lp phng tm khi. C. Hn hp Al2O3 v criolit Na3AlF6 c nhit nng chy thp hn nhiu so vi Al2O3 D. Theo chiu tng dn ca in tch ht nhn, cc kim loi kim c nhit nng chy gim dn. Cu 6: Cho 100 ml dung dch hn hp CuSO4 1M v AlCl3 3M tc dng vi dung dch NH3 d, lc ly kt ta em nung n khi lng khng i thu c cht rn c khi lng l? A. 23,3gam B. 30,6gam C. 15,3gam D. 8,0gam Cu 7: Tin hnh in phn 100 gam dung dch Cu(NO3)2 vi in cc tr, cng dng in l 5A trong thi gian 12 pht 52 giy th dng li. yn dung dch sau in phn n khi catot khng i, sau thm dung dch NaOH d vo dung dch sau in phn thu c kt ta X. Lc ly kt ta X em nung trong khng kh n khi lng khng i thu c 3,2gam cht rn. Nng % ca dung dch Cu(NO3)2 ban u l? A. 7,52% B. 8,46% C. 9,4% D. 11,2% 152

Cu 8: Cho 0,1 mol X tc dng vi lng d AgNO3 trong dd NH3 un nng thu c 43,2gam Ag. Hidro ha X vi H2 d thu c Y, bit 0,1 mol Y phn ng va vi 4,6g Na. CT ca X l? A. HCHO B. O=CH=CHOH-CHO C. OHC-CHO D. HOCH2CHO Cu 9: Khi phn tch cht hu c A mch h cha C, H, O th c mC + mH = 3,5mO. Bit A c to ra khi tch nc t 2 phn t ancol n chc. Cng thc cu to ca 2 ancol? A. C2H5OH, CH2=CHCH2OH B. C2H5OH, CH2OH C. CH2=CHCH2OH, CH3OH D. CH3CH2CH2OH, CH3OH Cu 10: Cht khng th iu ch trc tip axitaxetic bng 1 phn ng? A. CH3OH B. C2H5OH C. CH3CN D. HCOOCH=CH2 Cu 11: Cho s phn ng sau: CH2=CHCH2CH3 X Y Cng thc cu to thu gn ca Y l? (Bit X, Y l sn phm chnh) B. CH3CH=CHCH3 A. CH3CH(OH)CH2CH3 C. CH2OHCH2CH2CH3 D. CH2=CH(CH3)2 Cu 12: Cho phng trnh phn ng: 2A(k) + B(k) 2X (k) + 2Y (k). Ngi ta trn 4 cht, mi cht 1 mol vo bnh kn dung tch 2 lt (khng i). Khi cn bng, lng cht X l 1,6 mol. Hng s cn bng ca p ny l? A. 29,26 B. 33,44 C. 58,51 D. 40,96 Cu 13: dn kh propilen vo dd KMnO4 to cht hu c c th ha tan c vi Cu(OH)2/OH- v c cht rn mu en to thnh. h s cn bng ti gin ca phng trnh l: A.b=20 B.b=28 C.b=18 D.b=16 Cu 14: X,Y l 2 kh khng mu , ln lt cho mi kh li t t qua nc Brom th X lm nc Brom nht dn , trong khi kh Y th lm nc Brom sm mu dn. vy X,Y c th ln lt l nhng kh no di y: A.H2S v HCl B.SO2 v HCl C. Cl2 v HCl D. SO2 v HI Cu 15: cho cc s p sau: X1 + X2 X4 + H2 X3 + X4 CaCO3 + NaOH X3 + X5 +X2 Fe(OH)3 + NaCl + CO2 Cc cht thch hp vi X3, X4, X5 ln lt l: A. Ca(OH)2, NaHCO3, FeCl3 B. Na2CO3, Ca(OH)2, FeCl2 C. Na2CO3, Ca(OH)2, FeCl3 D. Ca(OH)2, NaHCO3, FeCl2 Cu 16: hh A gm 3 cht hu c n chc c cng CTPT C3H8O tc dng vi CuO d c phn rn v hh B. cho hh B tc dng vi AgNO3/NH3 d to ra 21,6g Ag. Nu un nng A vi H2SO4 c 1400C th thu c 34,5g 4 ete v 4,5g H2O. thnh phn % khi lng ancol bc 2 trong A l: A. 15,38% B. 46,15% C. 30,77% D.61,54% Cu 17: mt hh M cha ancol A no,v axit hu c n chc B u mch h, c cng s nguyn t cacbon. t chy hon ton 0,4 mol hh M cn 1,35 mol O2 , thu c 1,2 mol CO2 v 1,1 mol H2O ( s mol ca A ln hn ca B).CTPT ca A v B ln lt l: A. C3H8O, C3H4O2 B. C3H8O3 , C3H6O2 C. C3H8O2 , C3H4O2 D. C3H8O, C3H2O2 Cu 18: thy phn hon ton a gam hh hai tripetit thu c 23,9g hhX gm cc amino axit ( cc amino axit ch c 1 nhm amino v 1 nhm cacboxyl trong phn t). nu cho 1/10 hh X tc dng vi dd HCl d, c cn dd, th lng mui khan thu c l 3,485g. tnh a? A.18,5g B.22,1g C.20,3g D.21,2g Cu 19: cho cc cht: tinh bt, xenlulozo, protein, mantozo,glucozo, glixerol, tri panmitin. S cht tham gia p th y phn l: A.3 B.4 C.6 D.5 Cu 20: cho cc p : 1.S + F3 2.SO2 +H2S 3.SO2 + O2 4.S + H2SO4(c, nng) 5. H2S + Cl2 d +H2O 6.SO2+ Br2+ H2O S p to ra sn phm m S mc oxi ha +6 l: A.2 B.3 C.4 D.5 Cu 21: cho 100ml dd AgNO3 0,6M vo 100ml dd hn hp NaF 0,1M; NaCl 0,2M; FeCl2 0,1M. khi lng rn thu c sau p: 153

A.6,82g B.5,74g C.7,01g D.8,9g Cu 22: cho 1 kim loi M vo dd Fe2(SO4)3 thu c cht rn X. bit rn X ch tan 1 phn trong dd H2SO4 long, p hon ton. Kim loi M c th l: A.Mg B.Na C.Ba D.Fe Cu 23: kh hon ton m gam hh CuO v MxOy bng CO d, t nng thu c rn X v hh kh Y. cho Y tc dng vi nc vi trong d thu c 3g kt ta. nu cho X tc dng dd HCl d c 0,268 lt kh bay ra kc v cn li 0,896 gam rn . cng thc MxOy A.Fe3O4 B.ZnO C.FeO D.Cr2O3 Cu 24: cho cc cp cht : nhng p c cng pt ion thu gn l: 1.Na2CO3 + BaCl2 2. (NH4)2CO3 + Ba(OH)2 3.Ba(HCO3)2 +K2CO3 4. BaCl2 + MgCO3 5.CO2 + Ba(OH)2 6. (NH4)2CO3 + BaCl2 A.1,3,6 B.1,2,6 C.1,3,5 D.1,3,4,6 Cu 25: Dung dch X cha a mol Ca(OH)2. Cho dung dch X hp th 0,06 mol CO2 c 2b mol kt ta, nhng nu dng 0,08 mol CO2 c b mol kt ta. Gi tr ca a,b l? A. 0,08 v 0,03 B. 0,05 v 0,02 C. 0,1 v 0,02 D. 0,08 v 0,02 Cu 26: Cho t t 150ml dd HCl 1M vo 500ml dd A gm Na2CO3 v NaHCO3 th thu c 1,008 lt kh (ktc) v dd B. Cho dd B tc dng vi dd Ba(OH)2 d th thu c 29,55g kt ta. Nng mol ca Na2CO3 va2 NaHCO3 trong dd A ln lt l? A. 0,18M v 0,26M B. 0,21M v 0,32M C. 0,21M v 0,18M D. 0,21M v 0,4M Cu 27: Dung dch A l dd NaOH. Ly 100ml dung dch A trn vi 400ml dd AlCl3 0,1M th lng kt ta sinh ra bng vi lng kt ta khi ly 500ml dd A trn vi 400ml dd AlCl3 0,1M. Gi tr CM dd NaOH l? A. 0,5 B. 0,4 C. 0,3 D. 0,2 Cu 28: Cho cc p: Nhng p th hin tnh kh ca hp cht st (II) l: I. FeCl2 + Cl2 II. FeO + CO III. FeS + HCl IV. Fe(OH)2 + HNO3 V. FeSO4 + H2SO4 + KMnO4 VI. FeSO4 + Mg A. I, II, IV B. I, IV, V C. II, III, VI D. I, III, V Cu 29: Cho m gam hn hp bt X gm ba kim loi Al, Cr, Sn c s mol bng nhau tc dng ht vi lng d O2 th cn 6,72 lt O2 ktc. Nu cho m gam X tc dng ht vi dd H2SO4 long, nng thu c V lt H2 kc. Gi tr ca V l? A. 10,572 lt B. 8,064 lt C. 9,408 lt D. 12,096 lt Cu 30: Cho hn hp Cu v Fe vo dd HNO3 long thud d X v cht rn Y. Cho Y tc dng vi HNO3 c ngui d v c kh bay ra v phn cn li khng Zn. Cho dd NaOH d vo dd X c kt ta T. Vy thnh phn ca Z v T l? A. Cu, Fe(OH)3 B. Fe, Fe(OH)2 C. Fe, Fe(OH)2 v Cu(OH)2 D. Cu, Fe(OH)2 Cu 31: Crackinh V lt butan thu c 35 lt hn hp X gm H2, C4H8, CH4, C3H6, C2H6, C2H4, C4H8. Cho X vo bnh ng dd Br2 d th cn li 20 lt hn hp (cc th tch o cng k nhit v p sut). Hiu sut ca qu trnh crackinh l? A. 57,14% B. 75% C. 80% D. 42,85% Cu 32: Cho cc dd ring bit sau: C6H5-NH3Cl; H2N-CH2-CH2-CH(NH2)-COOH; ClH3N-CH2-COOH; HOOC-CH2-CH2-CH(NH2)-COOH; H2N-CH2-COONa. S dung dch va tc dng vi NaOH v HCl l? A. 2 B. 3 C. 4 D. 5

154

Cu 33: Ch X tc dng c vi Na v Cu(OH)2 trong mi trng kim khi un nng. Th tch ca 3,7g hi cht X bng 1,6g O2 (cng k nhit v p sut). khi t chy hon ton 1g cht X th thu c 0,7 lt kh CO2 kc. Cng thc ca X l? A. CH3-CO-CH2OH B. O=CH-CH2-CH2OH C. HOOC-HCO D. HOOC-CH2-CHO. Cu 34: Ha tan hn hp cha 0,8 mol Al v 0,6 mol Mg vo dd HNO3 1M va n p hon ton thu c dd A v 6,72 lt hn hp kh N2 v N2O ktc. C cn dd A thu c 267,2g mui khan. Th tch HNO3 cn dng? A. 4 lt B. 4,2 lt C. 3,6 lt D. 4,4 lt Cu 35: Cho hn hp gm 0,54g Al v 1,92g Cu vo 400ml dd gm H2SO4 0,5M v NaNO3 0,2M. Sauk hi p hon ton thu c dd X v kh NO (sn phm kh duy nht). Nu cho 370 dd NaOH 1M vo dd X thu c a gam kt ta. Gi tr a? A. 4,5 B. 3,72 C. 2,94 D. 4,11 Cu 36: Cho dung dch X cha 0,1 mol FeCl2; 0,2 mol FeSO4; 0,1 mol CuSO4; 0,5 mol H2SO4. Tnh th tch dung dch KMnO4 0,8M cn dng oxi ha ht cc cht trong X l: A. 0,75 lt B. 0,125 lt C. 0,3 lt D. 0,03 lt Cu 37: Ha tan hon ton 12 gam hn hp X gm CuO, Fe2O3, MgO cn dng va 225ml dung dch HCl 2M. Mt khc, nu t nng 12 gam X trong kh CO d phn ng xy ra hon ton th thu c 10 gam cht rn Y. Phn trm khi lng MgO trong hn hp X bng: A. 66,67% B. 40,00% C. 50,00% D. 33,33% Cu 38: Mt hn hp X gm Hidrocacbon mch h A ( c hai lin kt trong phn t) v H2 c t khi so vi H2 bng 4,8. Nung nng X vi xc tc Ni phn ng xy ra hon ton ta thu c hn hp Y c t khi so vi H2 bng 8. Cng thc ca A? A. C3H4 B. C4H6 C. C2H2 D. C5H8 Cu 39: Kh X lm mt mu nc brom, mt mu dung dch KMnO4 nhng khng to kt ta khi tc dng vi dung dch nc vi trong d. Kh X l? A. propilen B. SO2 C. CO2 D. xiclopropan Cu 40: Cho 0,1 mol este A tc dng vi 1 lt dd NaOH 0,5M thu c 16,4 g mui v 0,1 mol ancol. Lng NaOH d c trung ha ht bng 0,5 lt dd HCl 0,6M. CT thu gn ca A? B. C2H4(COOCH3)2 A. (CH3COO)3C3H5 D. (CH3COO)2C2H4 C. (C2H5COO)2C2H4 Cu 41: Khi cho cng s mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th th tch CO2 sinh ra gp 2 ln th tch kh H2. Cht X l? A. Etylen glicol B. Axit oxalic C. Axit 3-hidroxipropanoic D. Ancol o-hidroxibenzylic Cu 42: t chy hon ton 0,1 mol mt amin no, mch h X cn 12,8g oxi va . Nu cho m gam X tc dng hon ton vi dd HCl d, thu c dung dch cha (m+16,79) gam mui. gi tr ca m l? A. 10,35 B. 17,02 C. 10,58 D. 13,8 Cu 43: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH v HCOOH v CH2=CH-CHO phn ng va vi dung dch cha 8 gam brom. Mt khc, nu cho X tc dng vi lng d AgNO3 trong dung dch NH3, sinh ra 4,32g Ag. Khi lng ca HCOOH trong X l? A. 0,46g B. 0,92g C. 0,23g D. 0,69g Cu 44: Cho a gam aminoaxit X c mt nhm amino v mt nhm cacboxyl tc dng vi dd cha 0,22 mol HCl c dd A. tc dng ht vi dd A cn va 140ml dd KOH 3M. Nu t chy hon ton a gam X thu c CO2, N2 v 19,8g H2O. Cng thc ca X l? A. H2NC3H6COOH B. H2NCH2COOH C. H2NC2H4COOH D. H2NC4H8COOH. Cu 45: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l? A. Anilin, metyl amin, ammoniac B. Amoniclorua, metyl amin, natri hidroxit C. Alanin, amoniac, natri hidroxit D. Natricacbonat, benzyl amin, natri axetat

155

Cu 46: Mt bnh kn cha V1 lt NH3 v V2 lt O2 (cng k). Nung bnh c xc tc NH3 chuyn ht thnh NO, sau NO chuyn ht thnh NO2. Lng NO2 v O2 cn li trong bnh hp thu va ht trong nc to thnh dd HNO3. T l V2/V1 l? A. 2 B. 1 C. 3 D. 3/2 Cu 47: Cho hn hp A gm 2 cht hu c X v Y (MX<MY) cha C, H, O tc dng va vi 40ml dd NaOH 1M thu c 1 mui v 1 ancol. un nng lng ancol trn vi H2SO4 c thu c 0,252 lt kh olefin kc vi hiu sut l 75%. t chy hon ton cng lng A trn thu c 5,5g CO2. Vy Y l? A. CH3COOC3H7 B. C2H5COOC2H5 C. C2H3COOC2H5 D. CH3COOC2H5 Cu 48: Cho 30,6 gam hn hp Mg, Zn, Ag vo cc cha 900ml dung dch HCl 1M va . Sau khi p kt thc thm dn NaOH vo cc lng kt ta thu c l ln nht. Lc ly kt ta v nung nhit cao n khi lng khng i, thu c a gam cht rn. Gi tr a l? A. 37,8 B. 45 C. 40,2 D. 38,7 Cu 49: A l ng phn ca alanine. un nng A vi dd NaOH to mui Natri ca axit cacboxilic B v kh C. Bit C lm xanh giy qu m, khi chy to sn phm khng lm c dd Ca(OH)2. Vy B, C ln lt l? A. Axit acrilic v amoniac B. Axit propionic v amoniac C. Axit acrylic v metyl amin D. Glyxin v ancol metylic Cu 50: Mt dung dch cacbohidrat c cc tnh cht: - Ha tan Cu(OH)2 cho phc ng mu xanh lam. Kh [Ag(NH)3]OH v Cu(OH)2 khi un nng. - B thy phn khi c mt xc tc axit hoc enzim. Dung dich l? A. Glucozo B. Saccarozo C. Fructozo D. Mantozo

1 C 21 A 41 B

2 A 22 C 42 D

3 B 23 A 43 A

4 A 24 A 44 D

5 A 25 B 45 D

6 C 26 C 46 A

7 B 27 C 47 A

8 C 28 B 48 A

9 C 29 C 49 A

10 D 30 B 50 D

11 B 31 B

12 A 32 A

13 D 33 B

14 D 34 B

15 C 35 B

16 D 36 B

17 D 37 D

18 C 38 A

19 D 39 A

20 C 40 D

18 Cu 1: cho hh 2 anken l ng ng k tip nhau tc dng vi H2O c xt to hh Z gm 3 ancol. t chy hon ton 1,06g hh Z sau hp th ton b sn phm chy vo 2 lt dd NaOH 0,1M thu c dd T trong c nng ca NaOH l 0,05M. CTCT ca 2 ancol l: A.C2H5OH v C4H9OH B. C2H5OH v C3H7OH C. C3H7OH v C4H9OH D. C4H9OH v C5H11OH Cu 2: mt ancol no mch h X c s nguyn t cacbon bng vi s nhm chc. t chy hon ton 0,2 mol 1 ancol X cn va 11,2 lt kh O2(kc). CTPT ca X: A.C4H10O4 B. CH4O C. C2H6O2 D. C3H8O3 Cu 3: hp cht thm X c CTPT C8H8O2 phn ng dd NaOH to 2 mui. s ng phn cu to ca X: A.4 B.3 C.2 D.5 Cu 4: thy phn a gam mantozo vi hiu sut 50% . sau tin hnh phn ng trang bc vi dd thu c 32,4g Ag. Gi tr ca a l: A.25,65g B.34,2g C.52,3g D.64,8g Cu 5: hn hp M gm 2 cht hu c X,Y cha C,H,O k tip nhau, phn t ca chng ch c 1 loi nhm chc. t chy hon ton hh M , cho ton b sn phm chy vo dd nc vi trong d. Thy khi lng bnh tng thm 5,24g v to ra 7g cht kt ta. cng thc cu to ca X, Y ln lt l: A.HCHO v CH3CHO B. C2H4(OH)2 v OH(CH2 )3OH C. HCOOH v CH3COOH D. CH3OH v C2H5HO 156

Cu 6: cho cc nguyn t : K(Z=19); N(Z=7); Si(Z=14); Mg(Z=12). Dy gm cc nguyn t c sp xp theo chiu tng dn m in t tri sang phi l: A.N,Si,Mg,K B. Mg,K,Si,N C. K,Mg,N, Si D. K,Mg,Si,N Cu 7: ion X2+ c cu hnh electron phn lp ngoi cng l 3d6. nguyn t Y c s electron bng s electrom ca X2+. Ch ra pht biu khng ng : A.X thuc chu k 4, nhm VIII B B.Y thuc chu k 4, nhm VI B C.X,Y u c 2 electron lp ngoi cng D. X,Y u l kim loi Cu 8: cho cn bng ha hc: H2 (k) + Cl2 (k) 2HCl. Vi Kc=0,8 v nng cn bng ca HCl l 0,2M. bit lc u s mol ca H2 ly gp 3 ln s mol ca Cl2. nng ca Cl2 v H2 lc ban u l: A.0,4M v 1,2M B. 0,3M v 0,9M C. 0,6M v 0,2M D. 0,2M v 0,6M Cu 9: cho cc p : s p t oxi ha kh l: a. O3 O2 + O b. Ca(OH)2 + Cl2 CaOCl2 + H2O c. KClO3 KCl+ 3/2 O2 d. 2KMnO4 K2MnO4 + MnO2 + O2 e. 4KClO3 KCl + 3 KClO4 g. 2H2S + SO2 3S + 2H2O A.3 B.2 C.1 D.4 Cu 10: dd A c cha Ba2+ (x mol) ; H+ (0,2 mol); Cl- (0,1 mol); v [NO3]- (0,4 mol). Cho t t dd K2CO3 1M vo A cho n khi lng kt ta ln nht thy tiu tn V lt dd K2CO3. gi tr ca V l: A.150ml B.400ml C.200ml D.250ml Cu 11: c 4 dd : KNO3 (X), C2H5OH (Y), HNO2 (Z), K2SO4(T), u c nng mol l 0,1M. dy cc cht xp theo chiu tng dn tinh dn in l: A.X,Y,Z,T B.Y,Z,X,T C.Z,Y,X,T D.Y,Z,T,X Cu 12: cho cc p : c bao nhiu p to c S : a. H2S + O2 (thiu) b. H2S + SO2 c. SO2 + Br2 + H2O d. SO2 + Mg A.4 B.3 C.2 D.1 Cu 13: ch ra cc p vit sai: A.SiO2 +4HF SiH4 + 2F2O B. NaClO + CO2 + H2O NaHCO3+ HClO C. PBr3 +3 H2O H3PO4 +3 HBr D. 2NH3 + 3Cl2 N2 + 6HCl Cu 14:sc 13,44l CO2 kc vo 200ml dd X gm Ba(OH)2 1,5M v NaOH 1M. sau p thu c m1 gam kt ta v dd X. cho X tc dng vi 200ml dd BaCl2 1,2M v KOH 1,5M thu c m2 gam kt ta , gi tr ca m2 l: A.47,28g B.59,1g C.66,98g D.39,4g Cu 15; cho cc cht v dd sau: ch ra cht hoc dd ha tan c vng ? 1. thy ngn; 2.dd NaCN; 3. ddHNO3; 4. dd hn hp HNO3 v HCl (t l 1:3) A.4 B.1,2 C.1,2,3,4 D.1,2,4 Cu 16: hh X gm 2,02 g hh kim loi Mg v Zn. Cho 2,02g Xvao2 2 lt dd HCl aM thot ra 0,896 lt kh. Mt khc nu cho 2,02g hh X vo 3 lt hh HCl aM thot ra 1,12l kh . gi tr ca a v s mol ca Mg trong hh X l : ( cc cht kh o kc) A.0,04M v 0,01mol B. 0,08M v 0,02mol C. 0,04M v 0,03mol D. 0,0333M v 0,03mol Cu 17: hh A gm 3 kim loi X,Y,Z c ha tr ln lt l 3,2,2 v c t l s mol ln lt l 1:2:3 . bit s mol ca X l x mol . ha tan hon ton A bng dd cha y mol HNO3(va ), sau p thu c dd khng cha NH4NO3 v V lt hh N2,N2O(kc). Y lin h theo x v V l: A.y = (13x+V/11,2) B. y = (13x+V/22,4) C. y = (10x+V/11,2) D. y = (10x+V/22,4) 157

Cu 18: t chy hon ton 100ml hh X gm dimetylami v 2 hidrocacbon ng ng k tip thu c 140ml CO2 v 250ml hi nc ( o cng k) . % th tch ca cc cht trong X theo tng M ln lt l: A.60,20,20 B.25,25,50 C.30,30,40 D.40,30,30 Cu 19: A l ng phn ca axit -aminpropionic . un nng A vi dd NaOH to ra mui natri ca axit cacboxilic B v kh C. bit C lm xanh giy qu m v B lm mt mu nc Brom. Vy B,C ln lt l: A.axit acrylic v ammoniac B.axit propyonic v ammoniac C.axit acrylic v metyl amin D.glyxin v ancol metylic Cu 20: x phng ha hon ton 3,98g hh 2 este no, n chc bng dd NaOH thu c 4,1g mui ca 1 axit cacboxylic v m gam hh hai ancol l ng ng k tip1 nhau. un nng hon ton m gam hh 2 ancol vi H2SO4 c, 1400C thu c 0,45g H2O. CT ca 2 este l : A.HCOOCH3 v HCOOC2H5. B. C2H5COOCH3 v C2H5COOC2H5 C. CH3COO C2H5 v CH3COOC3H7 D. CH3COOCH3 v CH3COOC2H5 Cu 21: khi thy phn hon ton a gam mt cht bo X thu c 1,84 gam glixerol, 6,04g natri lioleat (C17H31COONa) v m gam natri olaet ( C17H33COONa). Gi tr ca m, a ln lt l: A.12,16 ; 19,24 B.6,08 ; 19,24 C.12,16 ; 17,64 D. 6,08 ; 17,64 Cu 22: ha tan hon ton 12 g hh X gm CuO, Fe2O3, MgO cn dng va 225ml dd HCl 2M. mt khc nu t nng 12g X trong kh CO d p xy ra hon ton th thu c 10g cht rn Y. % khi lng MgO trong hh X bng: A.66,67% B.40% C.50% D.33,33% Cu 23: hh X gm Fe2O3 0,1 mol; Fe3O4 0,1 mol; FeO 0,2 mol; Fe 0,1 mol; cho X tc dng vi dd HNO3 long d ch sinh ra NO duy nht . s mol HNO3 cn dung l : A.2,6 B.2 C.2,3 D.2,4 Cu 24: cho thm 0,4 mol kh H2 vo hh X gm : 0,1 mol C2H2 v 0,2 mol C2H4. dc hh kh Y, cho Y qua Ni ,un nng thu hh kh Z ( gm ankan, anken, ankin, hidro). C t khi so vi H2 l 10, hh kh Z lm mt mu ti a m gam dd Br2 32%. Tnh m: A.60 B.100 C.75 D.125 **Cu 25: ha tan hon ton 14,52g hh X gm NaHCO3, KHCO3, MgCO3 trong dd HCl d thu c 3,36l CO2 kc. Khi lng mui KCl to thnh l: A.7,45g B.5,96g C.5,96g D.8,94g Cu 26: nung m gam hhX gm 2 mui cacbonat trung ha ca 2 kim loi ha tr II, sau 1 thi giam thu c 3,36l CO2 ktc v rn Y. cho Y tc dng ht vi dd HCl d , hki1 thot ra hp th ht vo dd Ca(OH)2 d thu c 15g kt ta. phn dd dem c cn thu c 32,5g hh mui khan. Gi tr ca m l. A.29,2g B.35,8g C.20,85g D.27,55g Cu 27: dd X cha 0,6mol NaHCO3 v 0,3 mol Na2CO. thm t t dd cha 0,8 mol HCl vo dd X c dd Y v V lt kh CO2 ktc. Thm vo dd Y nc vi trong d thy to thnh m gam kt ta. gi tr V v m tng ng l: A.11,2 lt v 90 gam B. 16,8 lt v 60 gam C. 11,2 lt v 40 gam D. 11,2 lt v 60 gam Cu 28: dn V lt H2 ktc qua ng nghim ng m gam hh Fe2O3 v CuO nung nng. Sau phn ng thu c 16,32g hh rn X. ha tan ht X trong HNO3 long, d thu c 2,688 lt NO kc. V dd chau71 54,84 g hh mui nitrat. Vy gi tr V v m ln lt l: A.3,316 lt v 19,2g B. 4,032 lt v 19,04g C. 3,316 lt v 19,04g D. 4,032 lt v 19,2g Cu 29: t chy hon ton 7,2g mt cacboxilic X thu c 13,2g CO2 v 3,6g H2O . bit X tc dng ht vi NaHCO3 th s mol CO2 sinh ra bng 2 ln s mol X. CTPT ca X l: A.C3H4O2 B.C3H6O2 C.C6H8O4 D.C9H12O4 Cu 30: 3 cht hu c mch h c CTPT l : (X) C2H6O2, (Y) C2H2O2, (Z) C2H2O4. trong phn t mi cht trn ch cha 1 loi nhm chc. khi cho 3 cht tc dng vi Cu(OH)2 iu kin thch hp th cc cht kh nng p l: A.X v Y B. X v Z C.Y v Z D.X,Y v Z 158

Cu 31: hh A gm 0,1 mol CH2=CHCHO v 0,3 mol H2. cho hh A qua ng s nung nng c cha Ni lm xc tc , thu c hh B gm 4 cht l : propanal, propan-1-ol, propenal v hidro. T khi hi ca hh B so vi Metan bng 1,55. s mol H2 trong hh B bng bao nhiu. A.0,1 B.0,2 C.0,15 D.0,05 Cu 32: in phn dd cha ng thi 2 cht tan l HCl 0,2M v KCl 0,1M in cc tr, mng ngn xp, thu c dd c pH = 12 (xem Vdd khng i). chng t: A. Ch c KCl b in phn B. Ch c HCl b in phn C. HCl v KCl b in phn ht D. HCl b in phn ht cn KCl in phn cha ht Cu 33: cht X bng 1 p to ra C2H5OH v t C2H5OH bng mt p to ra cht X. trong cc cht : C2H2, C2H4, C2H5COOCH3, CH3CHO, CH3COOC2H5, C2H5ONa, C2H5Cl. S cht X ph hp l: A.3 B.4 C.6 D.5 Cu 34: chia hh X gm Cu v Fe thnh 3 phn bng nhau. Phn 1 tc dng vi H2SO4 long d to ra 4,48 lt kh kc Phn 2 cho vo 200ml dd FeCl3 1M sau p xy ra hon ton thy cn li 12g cht rn khan khn tan Phn 3 tc dng ht vi clo th thu c m gam cht rn. Gi tr ca m l: A.28,4g B.38,9g C.40,4g D.46g Cu 35: cho hh bt gm FeO3, Al2O3,CuO v Cu tc dng hon ton vi dd H2SO4 loang4 du7, th thu c dd X v phn khng tan Y. cho X tc dng vi dd Ba(OH)2 long,d. Thu c kt ta Z. nung Z trong khng kh n khi lng khng i thu c rn T. ch ra pht biu ng. A.phn khng tan Y l Cu v CuO B.kt ta Z gm Fe(OH)2, CuO, Al2O3,BaSO4 C.rn T gm Fe2O3, CuO, Al2O3, BaSO4 D.rn T gm Fe2O3, BaSO4 Cu 36: ln men gim 0,5 lt dd ancol etylic 9,20 ( khi lng ring ca ancol etylic nguyn cht l 0,8g/ml) vi hiu sut l 80%, thu c hh X. trung ha hh X cn V ml dd NaOH 2M. gi tr ca V l A.0,5 B.0,16 C.0,32 D.0,6 Cu 37: hh M gm axit cacboxylic X, ancol Y( u n chc, s mol X gp 2 ln s mol Y) v este Z c to ra t X v Y. cho mt lng va vi dd cha 0,2 mol NaOH, to ra 16,4g mui v 8,05g ancol. Este Z l: A.etyl fomat B.metyl axetat C.etyl axetat D.metyl propionate Cu 38: khi nhit phn hon ton tng mui sau: KMnO4, NaNO3, Cu(NO3)2 , CaCO3,KClO3 (xt MnO2). C bao nhiu mui to ra s mol kh ln hn s mol mui tng ng. A.2 B.3 C.1 D.4 Cu 39: tng s ht proton,electron,notron, trong ion n nguyn t X3+ c 37 ht. ch ra pht biu ng. A.X c 3 electron c thn lp ngoi cng B.X thuc nhm II A C.c th iu ch X bng phng php nhit luyn D.dd XCln c pH<7 Cu 40:cho 2,88 gn Mg vo dd hn hp cha 0,06 mol Fe2(SO4)3, v 0,02 mol CuSO4 . sau khi p xy ra hon ton th thu c m gam cht rn. gi tr ca m l: A.2,24g B.4,32g C.4,48g D.3,52g Cu 41: Hn hp X gm Fe3O4 v CuO. Cho H2 d i qua 6,32g hn hp X nung nng n p hon ton thu c rn Y v 1,62 gam H2O. Cho Y tc dng ht vi dd HNO3 2M thu c 2,24 lt NO v NO2 kc. Th tch dd HNO3 2M ti thiu cn dng (ml) A. 130 B. 145 C. 80 D. 95 Cu 42: hh Z gm 0,15 mol CH4, 0,09 mol C2H2 v 0,2 mol H2. nung nng hh Z vi Ni thu c hh Y. cho Y qua Brom d thot rah h kh A c MA=16. tng khi lng dd Br2 l 0,82g. s mol ca C2H6 trong A l: A.0,05 B.0,1 C.0,06 D.0,08 Cu 43: t chy hon ton 0,1 mol cht hu c X l dn xut ca bezen, khi lng CO2 thu c l nh hn 35,2g. bit rng , 1 mol X ch tc dng c vi 1 mol NaOH. CTCT thu gn ca X l. A.C2H5C6H4OH B. OHC6H4CH2OH 159

C. OHCH2C6H4COOH D. C6H4(OH)2 Cu 44: mt ancol no,n chc A c %O l 50%. Oxi ha hon ton m gam A vi Oxi xt thch hp thu c hh X gm andehit,axit, v H2O. cho X tc dng AgNO3/NH3 thu c 0,32 mol Ag. Cho X tc dng vi Na d thu c 0,07 mol H2. gi tr ca m l: A.5,52g B.6,4g C.7,4g D.3,2g Cu 45: s ng phn tp chc ancol-andehit c cng CTPT C4H8O2. l A.3 B.4 C.5 D.6 Cu 46:cho dy cc cht sau: axetandehit, axeton, glucozo ,fructozo ,saccarozo ,mantozo. S cht trong dy lm mt mu nc Br2 A.3 B.4 C.5 D.6 Cu 47: cho 6,4g dd ancol A c nng 71,87% tc dng vi lng d Na thu c 2,8 lt H2 kc. S nguyn t H c trong cng thc phn t A l: A.4 B.6 C.8 D.10 Cu 48: ch ra pht biu khng ng: A.ng trng ho9p5 buta-1,3-dien vi acrilonitrin c xc tc Na c cao su buna_S B.cao su thin nhin l polime ca isoprene C.polime ch to thy tinh hu c (Plexiglas) iu ch bng p trng hp CH2=C(CH3)COOCH3 D.t nilon-6,6 l t poliamit Cu 49: Cho 13,0 gam bt Zn vo dung dch cha 0,1mol Fe(NO3)3, 0,1 mol Cu(NO3)2 v 0,1mol AgNO3 , khuy u cho phn ng hon ton. Tnh khi lng kt ta sau khi phn ng? A. 17,2 gam B. 14,0 gam C. 19,07 gam D. 16,4 gam Cu 50: cho 0,1 mol CH3COOH vo cc cha 30ml dd ROH 20% (d=1,2g/ml; R l kim loi nhm I A). c cn dd sau p thu c cht rn khan X. t chy hon ton rn X th cn li 9,54g cht rn Y v c m gam hh gm CO2 v hi nc bay ra. gi tr ca m l: A.7,54 B.8,26 C.9,3 D.10,02

1 D 21 C 41 A

2 C 22 D 42 C

3 A 23 A 43 B

4 B 24 C 44 D

5 D 25 D 45 C

6 D 26 A 46 B

7 C 27 C 47 C

8 D 28 D 48 A

9 B 29 C 49 A

10 D 30 D 50 B

11 B 31 C

12 B 32 D

13 A 33 D

14 B 34 D

15 D 35 B

16 C 36 C

17 A 37 C

18 A 38 A

19 A 39 D

20 D 40 D

19 Cu 1: X phng ha hon ton 0,1 mol 1 este n chc X cn va 50ml dd NaOH 4M, c cn dung dch thu c phn rn khan c khi lng 19,8g. CTCT thu gn ca X l? A. CH3COO-C6H4-CH3 B. HCOOCH2C6H5 C. C6H5COOCH3 D. CH3-COO-C6H5 Cu 2: t chy 1 lt hidrocacbon X cn 6 lt oxi to ra 4 lt CO2. Nu em trng hp tt c cc ng phn cu to mch h ca X th s loi polime thu c l? A. 2 B. 3 C. 4 D. 5 Cu 3: Nung m gam X cha 80% khi lng CaCO3 (phn cn li l tp cht tr) mt thi gian thu c cht rn Y cha 45,65% CaO. Hiu sut phn ng phn hy CaCO3 l: A. 50% B. 75% C. 80% D. 70% Cu 4: Cho cc cht: HBr, Na2CO3, HNO3, (CH3CO)2O, NaOH, H2. Hi phenol phn ng c vi bao nhiu cht k thch hp: A. 2 B. 3 C. 4 D. 5 160

Cu 5: Mt hn hp X gm 2 amin n chc k tip. Ly a gam X tc dng va vi 250ml dung dch FeCl3 0,8M thu c a gam kt ta. CT ca 2 amin: A. CH5N, C2H7N B. C2H7N, C3H9N C. C3H7N, C4H9N D. C3H9N, C4H11N Cu 6: Hidrat ha 13 gam C2H2 vi hiu sut 90% c hh A. Cho A p vi dd AgNO3/NH3 th c kt ta c khi lng? A. 98,3 B. 109,2 C. 97,2 D. 121,3 Cu 7: Dy gm cc hp cht m trong phn t ch gm lin kt cng ha tr? A. HBr, NH4Cl B. NH3, NaCl C. CCl4, HNO3 D. NH4Cl, NaClO Cu 8: Hai nguyn t X, Y ca cc nguyn t thuc 2 nhm A lin tip. Tng s ht mang in trong ht nhn ca X v Y bng 23. Bit trng thi c bn nguyn t X c 3 electron c thn lp ngoi cng v X, Y d dng phn ng vi nhau. Vy Y l nguyn t no? A. Cacbon B. Silic C. Oxi D. Lu hunh Cu 9: in phn 2 lt dung dch hn hp gm NaCl v CuSO4 n khi H2O b in phn hai cc th dng li, ti catot thu 1,28g kim loi v anot thu 0,336 lt kh ( ktc). Coi th tch dung dch khng i th pH ca dd thu c bng? A. 12 B. 13 C. 2 D. 3 Cu 10: Cho t t 300ml dd NaHCO3 0,1M v K2CO3 0,2M vo 100ml dd HCl 0,2M v NaHSO4 0,6M thu c V lt CO2 thot ra (ktc) v dd X. Thm vo dd X 100ml dd KOH 0,6M + BaCl2 1,5M thu c m gam kt ta. Gi tr ca V v m l? A. 0,448 lt v 25,8g B. 1,0752 lt v 24,224g C. 1,0752 lt v 23,436g D. 0,448 lt v 11,82g Cu 11: Thc hin p trong bnh kn c dung tch 500ml vi 1 mol N2, 4 mol H2 v mt t xc tc (c th tch khng ng k). Khi p t ti trng thi cn bng th p sut trong bnh bng 0,8 ln p sut ban u khi cha xy ra p cng nhit . Hng s cn bng ca p N2 + 3H2 2NH3 xy ra trong bnh l? A. 0,016 B. 0,032 C. 0,128 D. 0,80 Cu 12: Cc kh thi cng nghip v ca cc ng c t, xe myl nguyn nhn ch yu gy ma axit. Thnh phn ha hc ch yu trong cc kh thi gy ma axit l? A. SO2, CO, NO B. CO2, CO, NO C. SO2, NO, NO2 D. SO2, CO, NO2 Cu 13: Nh dung dch NH3 hay dung dch NaOH n d vo dung dch mui X u thy hin tng: lc u xut hin kt ta sau kt ta tan. Vy dd X l? A. CrCl3 B. ZnSO4 D. NiCl2 C. Al(NO3)3 Cu 14: Hn hp X gm 2 hidrocacbon mch h. Dn 3,36 lt (ktc) X vo bnh ng dd Brom d khng c kh bay ra khi bnh. Lng Brom phn ng l 40g. t chy hon ton lng X trn thu c 15,4g CO2. Hn hp X gm: A. C3H4 v C2H4 B. C3H6 v C2H2 C. C4H8 v C2H2 D. C2H4 v C4H6 Cu 15: Ln men 15g Glucozo vi hiu sut a% lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10g kt ta. Khi lng dd sau phn ng gim 3,4g so vi khi lng dd nc vi trong ban u. Gi tr ca hiu sut a%? A. 60% B. 90% C. 75% D. 80% Cu 16: Cho m gam hn hp X gm ancol Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn 1 tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4g CO2. Gi tr ca m l? A. 36,4g B. 45,2g C. 44,8g D. 40,2g Cu 17: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en, buta-1,3-ien. S cht sau khi p vi H2(d, xc tc Ni, to) cho cng mt sn phm l ankan khng nhnh. A. 3 B. 4 C. 5 D. 2 Cu 18: Cho cc cht: CH3OH, C2H5OH, CH3CHO, C2H2, CH3COONa, CH3CN. S cht to c CH3COOOH bng 1 p? A. 6 B. 5 C. 4 D. 3 161

Cu 19: Mt este n chc mch h c t l khi lng mC : mO = 3:2 v khi t chy ht A thu c V CO2:V H2O = 4:3. un nng A trong dd NaOH d thu c hn hp sn phm, trong c ru bc mt. S CTCT ph hp vi X l? A. 2 B. 1 C. 3 D. 4 Cu 20: X l mt loi phn bn ha hc. Ha tan X trong nc to dd Y. Bit Y tc dng c vi dd NaOH hoc dd HCl u c kh bay ra. Vy X l? A. amophot B. amoni nitrat C. amoni sunfat D. ure Cu 21: t chy hon ton hn hp X gm 0,02 mol FeS2 v 0,01 mol FeS ri cho kh thu c hp th ht vo dung dch KMnO4 va , thu c V lt dd c pH= 2. Gi tr ca V l? A. 2 B. 4 C. 6 D. 8 Cu 22: Cho 26,8g hn hp bt X gm: Al v Fe2O3, tin hnh phn ng nhit nhm cho ti khi hon ton. Hn hp sn phm sau p cho tc dng vi lng d dd HCl c 11,2 lt H2 ktc. Khi lng ca Al trong X l? A. 5,4g B. 7,02g C. 9,72g D. 10,8g Cu 23: Cho 20g hn hp kim loi M v Al vo dung dch hn hp H2SO4 v HCl (s mol HCl gp 3 ln s mol H2SO4) th thu c 11,2 lt kh H2 (ktc) v 3,4g kim loai d. Lc ly phn dd ri em c cn thu c m gam mui khan. Tnh m? A. 51,7g B. 75,1g C. 57,1g D. 71,5g Cu 24: Ha tan hon ton a gam FeS2 vo dd HNO3 c kh mu nu bay ra l sn phm kh duy nht v to ra dd X ch cha 3 loi ion (b qua s thy phn mui v s in li ca nc). Ly 1/10 X pha long thu c dd c pH=2. Gi tr ca a l? A. 1,6 B. 2,4 C. 16 D. 24 Cu 25: A l hn hp kh gm SO2 v CO2 v c t khi hi so vi H2 l 27. Dn a mol hn hp kh A qua bnh ng 1 lt dung dch NaOH 1,8a M, sau phn ng dung dch thu c cha m gam mui. Biu thc lin h gia m v a l? A. m=105a B. m= 103,5a C. m= 104,4a D. m= 111,6a Cu 26: Trong qu trnh in phn dung dch ZnSO4, in cc tr (1) v phn ng n mn in ha xy ra khi nhng hp kim Zn-Cu vo dd H2SO4 long (2) th: A. catot ca (1) v (2) u xy ra s kh Zn2+ + 2e Zn B. catot ca (1) xy ra s kh Zn2+ cn catot ca (2) xy ra s kh H+ C. anot ca (1) v (2) u xy ra s oxi ha: 2H2O O2 + 4H+ + 4e D. anot ca (1) xy ra s oxi ha H2O cn anot ca (2) xy ra s oxi ha Cu Cu 27: S ng phn cu to este mch h vi CTPT C4H6O2, c to ra t axit v ancol thch hp. A. 2 B. 3 C. 1 D. 4 Cu 28: un nng hn hp A gm 2 cht hu c n chc vi 200ml dd NaOH 1M th phn ng va thu c ancol X v 17,8g hn hp mui Y. Cho ton b lng ancol X phn ng vi Na d sinh ra 1,12 lt H2 ktc. CTCT ca 2 cht trong A l? A. HOOCCH3, CH3COOH B. C2H5COOC2H5, CH3COOC2H5 C. C2H5COOCH3, CH3COOCH3 D. CH3COOCH3, C2H5COOH Cu 29: Ba cht hu c X, Y, Z c cng CT C3H6O v c cc tnh cht: X, Z u phn ng vi nc brom. X, Y, Z u phn ng vi H2 nhng ch c X, Z to ra cng mt sn phm, cht Y ch tc dng vi brom ch c mt CH3COOH. Cc cht X, Y, Z ln lt l? A. C2H5CHO, CH2=CHOCH3, CH2=CHCH2OH B. (CH3)2CO, C2H5CHO, CH2=CHCH2OH C. C2H5CHO, (CH3)2CO, CH2=CHCH2OH D. CH2=CHCH2OH, (CH3)2CO, CH2=CHOCH3 Cu 30: Hai cht ha c X v Y l 2 ancol trong khi lng mol ca X nh hn ca Y. Khi t chy hon ton mi cht X v Y u to s mol CO2 t hn s mol H2O. t chy hon ton hn hp Z gm nhng lng bng nhau v s mol X v Y thu c t l s mol CO2 v H2O tng ng l 2:3. S hp cht tha mn tnh cht ca X v Y l? A. 5 B. 2 C. 6 D. 4 Cu 31: Hai axit hu c E, F. Hn hp gm 0,2 mol E v 0,2 mol F tc dng vi Na d sinh ra 0,5 mol H2. Hn hp gm 0,3 mol E v 0,1 mol F tc dng vi Na d sinh ra 0,45 mol H2 S nhm chc ca E v F ln lt l: A. 3 v 2 B. 2 v 3 162

C. 1 v 3 D. 2 v 2 Cu 32: cho s X + dd NaOH, t0 Y + Z Y + NaOH rn, t0 T + P T 15000C Q + H2 Q + H2O ,t0,xt Z Cc cht X v Z ln lt l: A. HCOOCH=CH2 v HCHO B. CH3CH2COOCH=CH2 v CH3CHO C. CH2=CHCOOCH3 v CH3CHO D. CH3COOCH=CH2 v CH3CHO Cu 33: mt -amino axit c CTPT l C2H5NO2. Khi t chy 0,1 mol oligopeptit X ta nn t -amino axit th thu c 12,6g H2O. Vy X l: A. pentapeptit B. tripeptit C. tetrapeptit D. hecxapeptit Cu 34: t caprom, t lapsan ln lt thuc loi : A. u l t poliamit B. t axetat, t polieste C. t poliamit, t nitron D. t poliamit v t polieste Cu 35: amino axit X cha a nhm COOH v b nhm NH2. Cho 1 mol X tc dng ht vi dd HCl thu c 169,5g mui khan. Cho 1 mol X tc dng ht vi NaOH thu c 177g mui. Gi tr ca a v b ln lt l: A. 1 , 1 B. 2 , 1 C. 3 , 2 D. 1 , 2 Cu 36: s ng phn cha vng benzen ca hp cht C7H9N l A. 3 cht B. 4 cht C. 5 cht D. 6 cht Cu 37: cho hh bt gm 1,12g Fe v 0,24g Mg tc dng vi 250ml dd CuSO4. P xong thu c phn rn c khi lng 1,88g. Vy CM ca dd CuSO4long dng l: A. 0,1M B. 0,06M C. 0,2M D. 0,09M Cu 38: c cc cht rn L: Fe(NO3)2, FeS, CuS, CaCO3, NaCl v cc dd HCl c, H2SO4 long. Nu cho ln lt mi cht rn vo tng dd axit th c bao nhiu p xy ra : A. 4 B. 5 C. 6 D. 7 Cu 39: ch ra pht biu khng ng: A. st ty l st trng km B. hh tecmit gm bt nhm v Fe2O3 dng hn ng ry C. Cr2O3 dng to mu lc cho thy tinh D. qung giu st l qung manhetit Cu 40: ha tan hon ton 21g hh 2 kim loi Al v 1 kim loi kim M vo nc d th c dd B v 11,2 lt kh H2 ktc. Cho t t dd HCl vo dd B th thu c kt ta ln nht l 15,6g. Kim loi M l: A. Na B. Li C. Cs D. K Cu 41: nung hh A gm x mol Fe v 0,15mol Cu trong khng kh mt thi gian, thu c 63,2g hh cht rn B. Ha tan ht hh B bng bng dd H2SO4 c nng d thu c 6,72 lt kh SO2 ktc. Gi tr ca x l A. 0,4 mol B. 0,5 mol C. 0,7 mol D. 0,6 mol Cu 42: c 4 l cha ha cht b mt nhn ng ring bit trong 4 dd khng mu sau: NH4Cl, KCl, BaCl2, K2CO3. C th s dng thuc th no sau y phn bit cc l dung dch trn ? A. qu tm B. H2SO4 C. NaOH D. HCl Cu 43: ha tan hon ton 0,02 mol FeS2v 0,03 mol FeS vo lng d dd H2SO4 c nng thu c dd X v kh SO2 sp kh duy nht. Hp th ht SO2 bng lng va dd KMnO4 to dd c pH=2. Th tch dd Y l: A. 11,4 lt B. 22,8 lt C. 5,7 lt D. 17,1 lt Cu 44: V1 lt hh HCl v H2SO4 c pH=2 vi V2 lt dd NaOH , Ba(OH)2 c pH=12 to thnh 2 lt dd c pH=3. Tnh gi tr V1, V2 bit th tch dd khng thay i sau khi pha trn: A. 0,2 v 1,8 B. 1,8 v 0,2 C. 1,5 v 0,5 D. 1,1 v 0,9 Cu 45: dng 1 lng dd H2SO4 nng 20%, un nng ha tan va a mol CuO. Sau p lm ngui dung dch n 1000C th khi lng tinh th CuSO4.5H2O tch ra khi dd l 30,7g. Bit rng tan ca dd CuSO4 1000C l 17,4g. Gi tr ca a l: A. 0,1 B. 0,12 C. 0,2 D. 0,25 163

Cu 46: Cho 0,84 gam bt Mg vo 100 ml dd hn hp Cu(NO3)2 0,15M v Fe(NO3)3 0,2M cho n khi phn ng hon ton thu c m gam cht rn. Gi tr ca m l? A. 2 B. 1,52 C. 1,7 D. 2,8 Cu 47: Cho s iu ch phenol: Ancol propylic propen Y phenol Cng thc ca cht Y trong s trn l? A. C6H6 B. C6H5CH(CH3)2 C. C6H5CH2CH2CH3 D. C6H5CH3 Cu 48: Khi t chy hon ton mt ancol mch h X thu c th tch CO2 = 0,75 ln th tch hi nc o cng iu kin. Bit X tc dng Cu(OH)2 to dd xanh lam. S cht tha mn tnh cht ca X l? A. 1 cht B. 2 cht C. 3 cht D. 4 cht Cu 49: Cht khng phn ng vi triolien: A. I2 B. H2 C. dd NaOH D. Na Cu 50: Trn 18 gam axit axetic vi 23 gam ancol etylic ri un nng mt thi gian. Sau khi ngui hn hp v tch ring este th c hn hp cht lng X. Cho ton b X tc dng ht vi Na d thu c 6,72 lt H2 (ktc). Vy s gam este to ra l? A. 8,8 gam B. 17,6 gam C. 26,4 gam D. 44 gam

1 D 21 B 41 C

2 B 22 D 42 A

3 B 23 C 43 B

4 D 24 D 44 D

5 A 25 D 45 C

6 B 26 B 46 B

7 C 27 A 47 B

8 C 28 D 48 B

9 C 29 C 49 D

10 A 30 C 50 B

11 B 31 B

12 C 32 D

13 B 33 C

14 B 34 D

15 B 35 B

16 A 36 C

17 B 37 A

18 B 38 C

19 A 39 A

20 D 40 D

20 Cu 1: Cho 2 hp cht hu c thm ng phn A, B l C6H5-CH2OH, p-CH3-C6H4-OH. Cho A, B ln lt tc dng vi Na, dd KOH, CH3COOH, dd Br2. S phn ng xy ra l? A. 4 B. 3 C. 6 D. 5 Cu 2: t chy hon ton 10 ml mt este X cn 45 ml O2 thu c th tch CO2 v hi H2O c t l tng ng l 4:3. Dn sn phm chy qua bnh ng P2O5 d thy th tch gim 30 ml. Bit rng cc th tch c o cng iu kin. Cng thc ca X l? A. C4H6O2 B. C4H6O4 C. C4H8O2 D. C8H6O4 Cu 3: X l hn hp gm 2 cht hu c c CTPT l C3H9O2N. Cho X tc dng va vi dd NaOH c dd Y v 4,48 lt ktc hn hp Z gm 2 kh lm xanh giy qu v thuc cng 1 dy ng ng. Bit dZ/H2 = 20,7 khi c cn. Vy trong Y khi lng ca mui (c M ln hn) l? A. 3,4 B. 6,8 C. 1,7 D. 4,1 Cu 4: Cho cc cht sau: C6H5NH2; C2H5OH; CH3COOH; C6H5ONa; C2H5ONa. S cp cht tc dng c vi nhau l? A. 2 B. 4 C. 3 D. 5 Cu 5: Cho 0,04 mol mt hn hp X gm CH2=CH-COOH; HCOOH v CH2=CH-CHO phn ng va vi dung dch cha 8 gam brom. Mt khc, nu cho X tc dng vi lng d AgNO3 trong dung dch NH3, sinh ra 4,32 gam Ag. Nu cho 0,08 mol X tc dng vi Na th thu c bao nhiu lt H2 kc. A. 0,672 B. 0,448 C. 0,56 D. 0,896 Cu 6: Dy gm cc cht no sau y c to ra t CH3CHO bng mt phn ng? A. C2H2; CH3COOH B. C2H2; C2H5OH C. C2H5OH; CH3COONH4 D. CH3COOH; HCOOCH=CH2 164

Cu 7: Tng s ht mang in trong ion XY32- l 82. S ht mang in trong ht nhn ca nguyn t X nhiu hn s ht mang in trong ht nhn ca Y l 8. V tr ca X, Y A. X: chu k 3, nhm VI A; Y: chu k 2, nhm VI A B. X: chu k 3, nhm VI A; Y: chu k 2, nhm II A C. X: chu k 3, nhm VI A; Y: chu k 2, nhm IV A D. X: chu k 2, nhm VI A; Y: chu k 2, nhm IV A Cu 8: Cho cc nguyn t X (Z=11); Y (Z=16); Z (Z=9); T (Z=8); V (Z=19). m in cc nguyn t tng dn theo th t: A. X, V, Y, T, Z B. V, X, Y, T, Z C. V, X, T, Y, Z D. X, V, T, Y, Z Cu 9: Cho phng trnh ion thu gn sau: aSn2+ + bMnO4- + cH+ Sn4+ + Mn2+ + H2O Tng cc h s (cc s nguyn ti gin) ca cc cht tham gia phn ng (a+b+c) l: A. 18 B. 21 C. 15 D. 23 Cu 10: Cho 0,1 mol mt este X mch h tc dng va vi 100 ml dd NaOH 2M thu c 6,2 gam mt ancol v hn hp hai mui ca hai axit cacboxilic no n chc. t chy hon ton hai mui thu c Na2CO3, H2O v 0,3 mol CO2. CTPT ca X: B. C7H12O4 A. C5H8O4 C. C6H10O4 D. C8H14O4 Cu 11: cho cc p sau: a. 2NaHCO3 + CaCl2 CaCO3 + 2NaCl + H2O + CO2 b. NaHSO4 + BaCl2 BaSO4 + NaCl + HCl c. Ca(OH)2 + 2NH4Cl CaCl2 + 2NH3 + 2H2O d. Ca(OH)2 + NaHCO3 NaOH + CaCO3 + H2O e. Cl2 + 2NaOH 2NaCl + 2NaClO + H2O s p xy ra nhit thng l: A. 1 B. 2 C. 3 D. 4 Cu 13: cho 300ml dd X cha Na+, NH4+, CO32-, SO42-. Chia hh thnh 3 phn bng nhau: Phn 1: cho tc dng dd BaCl2 d c 43g kt ta Phn 2: cho tc dng dd HCl d c 0,1 mol kh bay ra Phn 3: tc dng vi dd NaOH d, c 0,2 mol kh bay ra. Tng khi lng mui trong 300ml dd X l: A. 51,72g B. 25,86g C. 49,25g D. 71,4g Cu 14: cho cc p sau : s p to ra sn phm m lu hunh mc oxi ha +4 l: a. S + F2 e. S + HNO3 c,nng f. FeS2 + O2 b. O2 d + H2S c. S + H2SO4 c, nng d. H2S + Cl2 + H2O A. 2 B. 3 C. 4 D. 5 Cu 15: mt hh X gm Al v Zn c khi lng l 9,2g. Cho X vo 1 lt dd Y cha AgNO3 0,1M v Cu(NO3)2 0,2M. Sau khi p kt thc thu c cht rn Z ( Z khng tc dng vi dd HCl) v dd P gm 2 mui. Tnh % khi lng ca Al v Zn trong hh X A. 29,34% B. 31,18% C. 33,14% D. 32,18% Cu 16: ha tan hon ton m gam hh gm Na, Na2O, NaOH v Na2CO3 trong dd H2SO4 40%( va ) thu c 8,96 lt hh kh c t khi so vi H2 l 16,75 v dd Y c nng 51,449%. C cn Y thu c 170,4g mui. Gi tr ca m l: A. 37,2g B. 50,4g C. 50,6g D. 23,8g Cu 17: ha tan ht 10g hh cht rn X gm Ca v CaC2 vo H2O thu c 4,256 lt (ktc) hh kh Y. Dn kh Y qua bt Ni 1 thi gian, t0 thu c hh kh Z. Dn Z qua bnh ng nc brom d thy khi lng bnh tng m gam v thot ra hh kh T. t chy ht T thu c 3,08g CO2 v 1,62g H2O. Gi tr ca m l: A. 1,02 B. 1,76 C. 1,2 D. 1,51 Cu 18: dd A cha m gam NaOH v 0,3 mol NaAlO2. Cho t t dd cha 1 mol HCl vo dd A, thu c dd B v 15,6g kt ta. Sc kh CO2 vo dd B thy xut hin kt ta. Gi tr ca m l: A. 24g B. 16g C. 8g D. 32g Cu 19: thy phn hon ton a gam hh hai tripeti thu c 23,9g hh X gm cc amino axit( cc amino axit ch c 1 nhm amino v 1 nhm cacboxyl trong phn t). Nu cho 1/10 hh X tc dng vi dd HCl d, c cn cn thn dd, th lng mui khan thu c l 3,485g. Tnh a ? 165

A. 18,5g B. 22,1g C. 20,3g D. 21,2g Cu 20: cho cc este: Phenyl axetax, vinyl axetat, benyl acrilat,dimetyl oxalat, metyl metacrylat, anlyl fomat. S este c iu ch t axit v ancol tng ng; A. 4 B. 3 C. 5 D. 6 Cu 21: dy gm cc cht lng tnh l: A. Ca(HCO3)2, NaHS, (NH4)2CO3 B. Al, Al2O3, Al(OH)3 C. Al2O3, Al2(SO4)3, Zn(OH)2 D. Al(OH)3, Al2O3, NaHSO4 Cu 22: ha tan hon ton 12g hh X gm CuO, Fe2O3, MgO cn dng va 225ml dd HCl 2M. Mt khc, nu t nng 12g hh X trong kh Co d p xy ra hon ton th thu c 10g cht rn Y. % khi lng MgO trong hh X l: A. 66,67% B. 40% C. 50% D. 33,33% Cu 23: cho hh gm FeO, CuO, Fe3O4 c s mol ba cht u bng nhau tc dng ht vi dd HNO3 thu c hh kh gm 0,09 mol NO2, v 0,05 mol NO. S mol mi cht l: A. 0,12mol B. 0,24mol C. 0,21mol D. 0,36mol Cu 24: cho hh X gm phenol v anilin. Cho hh X tc dng va vi 50ml dd NaOH 1M thu c dd Y. Dd Y p va vi 125ml dd HCl 1M. Thnh phn % theo khi lng ca phenol trong hh l: A. 59,74% B. 28,79% C. 71,21% D. 40,26% Cu 25: trn 10,8g bt Al vi 27,84g bt Fe3O4 ri tin hnh p nhit nhm trong iu kin khng c khng kh. Ha tan hon ton hh rn sau p bng dd HCl long d thu c 11,424 lt kh H2 ktc. Hiu sut ca p nhit nhm l: A. 75% B. 90% C. 80% D. 60% Cu 26: t chy hon ton 0,1 mol A CxHyOz thu c 0,8 mol CO2. trung ha 0,2 mol A cn 0,2mol NaOH. Mt khc, 0,5 mol A tc dng vi Na d thu c 0,5 mol H2. Dn ton b sn phm chy sau khi t 0,1 mol A qua bnh ng dd NaOH c d th tng khi lng bnh NaOH l: A. 31,8g B. 45,2g C. 38g D. 39,8g Cu 27: kh hon ton hh hai andehit n chc cn dng 5,6 lt H2 ktc. Sn phm thu c cho tc dng vi Na d thu c 1,68 lt H2 ktc. Hai andehit cho l: A. hai andehit no B. 1 andehit khng no v 1 andehit no C. 2 andehit khng no D. 2 andehit n chc lin tip trong dy ng ng. Cu 28: c bao nhiu ng phn no mch h c CTPT C3H6O2 tc dng c vi Na: A. 1 B. 2 C. 3 D. 4 Cu 29: cho 0,1 mol X tc dng vi lng d AgNO3 trong dd NH3 un nng thu c 43,2g Ag. Hidro ha X vi H2 d thu c Y, bit 0,1 mol Y p va vi 4,6g Na. CT ca X l: A. HCHO B. O=CH-CHOH-CHO C. OHC-CHO D. HOCH2CHO Cu 30: M l este mch h cha 1 loi chc to bi axit 2 chc no v 1 ru n chc cha 1 lin kt i. t chy hon ton 0,1 mol este cn dng 1 mol O2. CTPT ca M la: A. C9H12O4 B. C10H14O4 C. C11H16O4 D. C8H10O4 Cu 31: cho cc cht : HCHO, CH4, C2H2, CH2Cl2, CH3Cl, C2H5COOCH3. C bao nhiu cht c th iu ch trc tip metanol iu kin thch hp? A. 3 B. 5 C. 4 D. 2 Cu 32: ha tan hon ton m gam hh X gm Na2O v Al2O3 vo H2O thu c dd Y ch cha cht tan duy nht. Cho dd cha 0,12 mol HCl vo Y thu c 3,12g kt ta. Gi tr ca m l: A. 4,92 B. 9,84 C. 7,38 D. 2,46 Cu 33: cho 29,8g hh bt gm Zn v Fe vo 600ml dd CuSO4 0,5M. Sau khi cc p xy ra hon ton thu c dd X v 30,4g hh kim loi. % v khi lng ca Fe trong hh ban u l: A. 37,58% B. 56,37% C. 64,42% D. 43,64% Cu 34: cho 15,28g hhA gm Cu v Fe vo 1,1 lt dd Fe2(SO4)3 0,2M. P xong thu c dd X v 1,92g cht rn B. Cho B vo dd H2SO4 long khng thy kh bay ra. Tnh % khi lng ca Fe A. 32,98% B. 67,02% C. 23,89% D. 76,2% 166

Cu 35: cho 8,1g Al vo dd X cha 0,15mol HCl v 0,3 mol CuSO4 sau 1 thi gian thu c 1,68 lt kh H2 ktc, dd Y v cht rn Z. Cho ton b Y tc dng vi dd NaOH d sinh ra 22,05g kt ta. Khi lng ca Z l: A. 7,5g B. 10,2g C. 7,05g D. 9,6g Cu 36: hh cht hu c X c CTPT l: C4H8O2 mch thng tha mn cc tnh cht sau: - X lm mt mu dd Br2 - 4,4g X tc dng vi Na d thu c 0,56 lt H2 ktc - oxi ha X bi CuO, t0 to ra sn phm Y l hp cht a chc. CTCT ca X l: A.CH3CH2COCHO B. CH2=CH-CH(OH)-CH2OH C. HO-(CH2)3-CH=O D. HO-CH2-CH(CH3)-CHO Cu 37: c bao nhiu ng phn mch h c CTPT l: C5H8 tc dng vi H2 d xc tc Ni,t0 thu c sn phm l isopentan: A. 3 B. 2 C. 4 D. 5 Cu 38: pht biu no ng: A. t nilong-6,6 c iu ch bng p trng ngng HOOC-(CH2)6-COOH v H2N-(CH2)-NH2 B. t lapsan c iu ch bng p trng hp acrilonitrin C. cao su thin nhin l polime ca buta-1,3-dien D. nilong-6 c iu ch bng p trng ngng axit- aminocapoic Cu 39: hh A cha H2 v 1 ankin c t khi so vi hidro bng 4,8. Dn A qua bt Ni nung nng n p xy ra hon ton thu c hh kh B c t khi so vi hidro l 8. Xc nh CTPT ca ankin A. C2H2 B. C4H6 D. C5H8 C. C3H4 Cu 40: kh X lm mt mu nc Brom, mt mu dd KMnO4 nhng khng to kt ta khi tc dng vi dd nc vi trong d. Kh X l: A. propilen B. SO2 C. CO2 D. xiclopropan Cu 41: t chy hon ton 1 lt hh kh gm buta-1,2-dien v hidrocacbon X sinh ra 3 lt kh CO2 v 3 lt hi H2O(cc th tch kh v hi o cng iu kin nhit , p sut). CTPT ca X la: A. C2H6 B. C2H4 C. C3H8 D. C3H6 Cu 42: cho hh X gm 2 ancol mch h thuc cng dy ng ng. t chy hon ton hh X, thu c CO2 v H2O c t l mol tng ng l 3:4. Mt khc, cho 0,25 mol hh M tc dng vi Na d, thu c nhiu hn 0,15mol H2. Hai ancol l: A. C2H4(OH)2 v C3H6(OH)2 B. C2H5OH v C4H9OH D. C2H5OH v C4H8(OH)2 C. C2H4(OH)2 v C4H8(OH)2 Cu 43: cho s C2H2 X axetandehit . cht X c th l: 1. CH2=CHCl 2. CH3-CHCl2 3. CH2=CH2 4. CH3COOCH=CH2 A. 1,2,4 B. 1,3,4 C. 2,3,4 D. 1,2,3,4 Cu 44: cho s Polime thin nhin X Y Z(mt loi ng) Y + T Y + H2 M (sobitol) T + H2 M Bit X c p mu vi iot. Ch ra pht biu ng: A. M l hp cht hu c a chc B. Y v T tham gia p trng gng C. Z, T u lm mt mu nc brom D. X ch c cu trc mch khng phn nhnh Cu 45: khi cho cng s mol mt hp cht hu c X ( cha C,H,O) p hon ton vi Na hoc vi NaHCO3 th th tch CO2 sinh ra gp 2 ln th tch H2. Cht X l: A. etylen glicol B. axit oxalic C. axit3-hidroxipropanic D. ancol o-hidroxibenzylic Cu 46: cho a gam aminoaxit X c 1 nhm amino v 1 nhm cacboxyl tc dng vi dd cha 0,22 mol HCl c dd A. tc dng vi dd A cn va 140ml dd KOH 3M. Nu t chy hon ton a gam X thu c H2O, N2 v 44g CO2. CT ca X l: A. H2NC3H6COOH B. H2NCH2COOH C. H2NC2H4COOH D. H2NC4H8COOH Cu 47: dy gm cc cht u lm qu tm m chuyn sang mu xanh l: 167

A. anilin, metylamin, anomiac B. amoniclorua, metylamin, natri hidroxit C. anilin, amoniac, natrihidroxit D. natricacbonat, benzyl amin, natriaxetat Cu 48: trong cc polime sau: poli( metyl metacrylat), polistiren, nilong-7, poli(etylen-terephtalat), nilong-6,6 , poli(vinyl axetat), poli (acrilonitrin). S polime l sn phm ca p trng hp l: A. 4 B. 5 C. 3 D. 2 Cu 49: cho m gam hh X gm Al, Fe, Zn, Mg ( trong Fe chim 25,866% v khi khi lng) tc dng vi dd HCl gii phng 12,32 lt H2 ktc. Nu cho m gam X tc dng vi Cl2 thu c m+42,6g hh mui. Gi tr ca m l: A. 32,6g B. 24,85g C. 26,45g D. 21,56g Cu 50: cho hh X gm 1 ancol A(a mol) v 2 ancol ng phn B,C (a mol). T khi hi ca X so vi hidro bng 23. Cho m gam X i qua ng s ng CuO d, nung nng. Sau khi cc p xy ra hon ton thu c hh Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2g. Cho Y tc dng hon ton vi lng d dd AgNO3/NH3 to ra 48,6g Ag. % khi lng ca ca ancol bc hai trongX l: A. 65,2% B. 16,3% C. 48,9% D. 83,7%

1 D 21 A 41 A

2 A 22 D 42 C

3 D 23 A 43 D

4 B 24 D 44 D

5 A 25 A 45 B

6 C 26 C 46 D

7 A 27 B 47 D

8 B 28 D 48 A

9 D 29 C 49 D

10 B 30 A 50 C

11 D 31 C

12 A 32 A

13 D 33 B

14 B 34 A

15 A 35 B

16 C 36 C

17 B 37 A

18 D 38 D

19 C 39 C

20 A 40 A

THI TUYN SINH I HC, CAO NG NM 2012 Mn thi : HA, khi A PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1 : Nguyn t R to c cation R+. Cu hnh electron phn lp ngoi cng ca R+ ( trng thi c bn) l 2p6. Tng s ht mang in trong nguyn t R l A. 11. B. 10. C. 22. D. 23. Cu 2: in phn 150 ml dung dch AgNO3 1M vi in cc tr trong t gi, cng dng in khng i 2,68A (hiu sut qu trnh in phn l 100%), thu c cht rn X, dung dch Y v kh Z. Cho 12,6 gam Fe vo Y, sau khi cc phn ng kt thc thu c 14,5 gam hn hp kim loi v kh NO (sn phm kh duy nht ca N+5). Gi tr ca t l A. 0.8. B. 0,3. C. 1,0. D. 1,2. Cu 3: Cho cc pht biu sau: (a) Cht bo c gi chung l triglixerit hay triaxylglixerol. (b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c. (c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch. (d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5. S pht biu ng l A. 3. B. 2. C. 4. D. 1. Cu 4: Cho dy cc cht: stiren, ancol benzylic, anilin, toluen, phenol (C6H5OH). S cht trong dy c kh nng lm mt mu nc brom l A. 4. B. 3. C. 5. D. 2. Cu 5: Cho cc phn ng sau : (a) H2S + SO2 (b) Na2S2O3 + dung dch H2SO4 (long) (c) SiO2 + Mg
t ti le mol 1:2
0

(d) Al2O3 + dung dch NaOH (g) SiO2 + dung dch HF 168

(e) Ag + O3 S phn ng to ra n cht l

A. 4. Cu 6: Cho s phn ng :
xuctac

B. 5.

C. 6.

D. 3.

(a) X + H2O Y (b) Y + AgNO3 + NH3 + H2O amoni gluconat + Ag + NH4NO3 (c) Y
xuctac E+Z anh sang (d) Z + H2O X+G chat diep luc

X, Y, Z ln lt l: A. Tinh bt, glucoz, etanol. B. Tinh bt, glucoz, cacbon ioxit. C. Xenluloz, saccaroz, cacbon ioxit. D. Xenluloz, fructoz, cacbon ioxit. Cu 7: Qung no sau y giu st nht? A. Pirit st. B. Hematit . C. Manhetit. D. Xierit. Cu 8: Hn hp X c khi lng 82,3 gam gm KClO3, Ca (ClO3)2, CaCl2 v KCl. Nhit phn hon ton X thu c 13,44 lt O2 (ktc), cht rn Y gm CaCl2 v KCl. Ton b Y tc dng va vi 0,3 lt dung dch K2CO3 1M thu c dung dch Z. Lng KCl trong Z nhiu gp 5 ln lng KCl trong X. Phn trm khi lng KCl trong X l A. 25,62%. B. 12,67%. C. 18,10%. D. 29,77%. Cu 9: Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip (MX < MY). t chy hon ton mt lng M cn dng 4,536 lt O2 (ktc) thu c H2O, N2 v 2,24 lt CO2 (ktc). Cht Y l A. etylmetylamin. B. butylamin. C. etylamin. D. propylamin. Cu 10: Dy cht no sau y u th hin tnh oxi ha khi phn ng vi SO2? A. H2S, O2, nc brom. B. O2, nc brom, dung dch KMnO4. C. Dung dch NaOH, O2, dung dch KMnO4. D. Dung dch BaCl2, CaO, nc brom. Cu 11: Trong ancol X, oxi chim 26,667% v khi lng. un nng X vi H2SO4 c thu c anken Y. Phn t khi ca Y l A. 56. B. 70. C. 28. D. 42. Cu 12: Cho 2,8 gam bt st vo 200 ml dung dch gm AgNO3 0,1M v Cu(NO3)2 0,5M; khi cc phn ng xy ra hon ton thu c m gam cht rn X. Gi tr ca m l A. 4,72. B. 4,08. C. 4,48. D. 3,20. Cu 13: Hirat ha 5,2 gam axetilen vi xc tc HgSO4 trong mi trng axit, un nng. Cho ton b cc cht hu c sau phn ng vo mt lng d dung dch AgNO3 trong NH3 thu c 44,16 gam kt ta. Hiu sut phn ng hirat ha axetilen l A. 80%. B. 70%. C. 92%. D. 60%. Cu 14: Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH2 trong phn t), trong t l mO : mN = 80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch HCl 1M. Mt khc, t chy hon ton 3,83 gam hn hp X cn 3,192 lt O2 (ktc). Dn ton b sn phm chy (CO2, H2O v N2) vo nc vi trong d th khi lng kt ta thu c l A. 20 gam. B. 13 gam. C. 10 gam. D. 15 gam. Cu 15: Cho cc cp oxi ha kh c sp xp theo chiu tng dn tnh oxi ha ca dng oxi ha nh sau: Fe2+/Fe, Cu2+/Cu, Fe3+/Fe2+. Pht biu no sau y l ng? A. Cu2+ oxi ha c Fe2+ thnh Fe3+. B. Fe3+ oxi ha c Cu thnh Cu2+. D. Fe2+ oxi ha c Cu thnh Cu2+. C. Cu kh c Fe3+ thnh Fe. Cu 16: t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO2 v 0,4 mol H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l A. 4,08. B. 6,12. C. 8,16. D. 2,04. Cu 17: Phn trm khi lng ca nguyn t R trong hp cht kh vi hiro (R c s oxi ha thp nht) v trong oxit cao nht tng ng l a% v b%, vi a : b = 11 : 4. Pht biu no sau y l ng? A. Oxit cao nht ca R iu kin thng l cht rn. B. Nguyn t R ( trng thi c bn) c 6 electron s. C. Trong bng tun hon cc nguyn t ha hc, R thuc chu k 3. D. Phn t oxit cao nht ca R khng c cc. Cu 18: Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m gam X phn ng ht vi dung dch NaHCO3 thu c 1,344 lt CO2 (ktc). t chy hon ton m gam X cn 2,016 lt O2 (ktc), thu c 4,84 gam CO2 v a gam H2O. Gi tr ca a l A. 1,62. B. 1,80. C. 3,60. D. 1,44. Cu 19: Hn hp X gm Fe3O4 v Al c t l mol tng ng 1 : 3. Thc hin phn ng nhit nhm X (khng c khng kh) n khi phn ng xy ra hon ton thu c hn hp gm A. Al2O3 v Fe. B. Al, Fe v Al2O3. C. Al, Fe, Fe3O4 v Al2O3. D. Al2O3, Fe v Fe3O4. Cu 20: Hp cht X c cng thc C8H14O4. T X thc hin cc phn ng (theo ng t l mol): (a) X + 2NaOH X1 + X2 + H2O (b) X1 + H2SO4 X3 + Na2SO4 169

(c) nX3 + nX4 nilon-6,6 + 2nH2O (d) 2X2 + X3 X5 + 2H2O Phn t khi ca X5 l A. 198. B. 202. C. 216. D. 174. Cu 21: Cho 500ml dung dch Ba (OH)2 0,1M vo V ml dung dch Al2(SO4)3 0,1M; sau khi cc phn ng kt thc thu c 12,045 gam kt ta. Gi tr ca V l A. 75. B. 150. C. 300. D. 200. Cu 22: Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5- l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l : A. (4), (1), (5), (2), (3). B. (3), (1), (5), (2), (4). C. (4), (2), (3), (1), (5). D. (4), (2), (5), (1), (3). Cu 23: Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c th c ca X l A. 6. B. 5. C. 7. D. 4. Cu 24: t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn phm chy hp th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 39,4 gam kt ta v khi lng phn dung dch gim bt 19,912 gam. Cng thc phn t ca X l B. CH4. C. C2H4. D. C4H10. A. C3H4. Cu 25: Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui (vi in cc tr) l: A. Ni, Cu, Ag. B. Li, Ag, Sn. C. Ca, Zn, Cu. D. Al, Fe, Cr. Cu 26: Cho cc pht biu sau v phenol (C6H5OH): (a) Phenol tan nhiu trong nc lnh. (b) Phenol c tnh axt nhng dung dch phenol trong nc khng lm i mu qu tm. (c) Phenol c dng sn xut phm nhum, cht dit nm mc. (d) Nguyn t H ca vng benzen trong phenol d b thay th hn nguyn t H trong benzen. (e) Cho nc brom vo dung dch phenol thy xut hin kt ta. S pht biu ng l A. 5. B. 2. C. 3. D. 4. Cu 27: Thc hin cc th nghim sau ( iu kin thng): (a) Cho ng kim loi vo dung dch st (III) clorua. (b) Sc kh hiro sunfua vo dung dch ng (II) sunfat. (c) Cho dung dch bc nitrat vo dung dch st (III) clorua. (d) Cho bt lu hunh vo thy ngn. S th nghim xy ra phn ng l A. 2. B. 1. C. 3. D. 4. Cu 28: X v Y l hai nguyn t thuc cng mt chu k, hai nhm A lin tip. S proton ca nguyn t Y nhiu hn s proton ca nguyn t X. Tng s ht proton trong nguyn t X v Y l 33. Nhn xt no sau y v X, Y l ng? A. m in ca X ln hn m in ca Y. B. n cht X l cht kh iu kin thng. C. Lp ngoi cng ca nguyn t Y ( trng thi c bn) c 5 electron. D. Phn lp ngoi cng ca nguyn t X ( trng thi c bn) c 4 electron. Cu 29: Cho dy cc hp cht thm: p-HO-CH2-C6H4-OH, p-HO-C6H4-COOC2H5, p-HO-C6H4COOH, p-HCOO-C6H4-OH, p-CH3O-C6H4-OH. C bao nhiu cht trong dy tha mn ng thi 2 iu kin sau? (a) Ch tc dng vi NaOH theo t l mol 1 : 1. (b) Tc dng c vi Na (d) to ra s mol H2 bng s mol cht phn ng. A. 3. B. 4. C. 1. D. 2. Cu 30: Cho hn hp K2CO3 v NaHCO3 (t l mol 1 : 1) vo bnh dung dch Ba(HCO3)2 thu c kt ta X v dung dch Y. Thm t t dung dch HCl 0,5M vo bnh n khi khng cn kh thot ra th ht 560 ml. Bit ton b Y phn ng va vi 200 ml dung dch NaOH 1M. Khi lng kt ta X l A. 3,94 gam. B. 7,88 gam. C. 11,28 gam. D. 9,85 gam. Cu 31: t chy hon ton 3 lt hn hp X gm 2 anken kt tip nhau trong dy ng ng cn va 10,5 lt O2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol bc mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l A. 46,43%. B. 31,58%. C. 10,88%. D. 7,89%. Cu 32: Ha tan hon ton 2,43 gam hn hp gm Mg v Zn vo mt lng va dung dch H2SO4 long, sau phn ng thu c 1,12 lt H2 (ktc) v dung dch X. Khi lng mui trong dung dch X l A. 5,83 gam. B. 7,33 gam. C. 4,83 gam. D. 7,23 gam. Cu 33: Cho dy cc cht: Al, Al(OH)3, Zn(OH)2, NaHCO3, Na2SO4. S cht trong dy va phn ng c vi dung dch HCl, va phn ng c vi dung dch NaOH l A. 2. B. 5. C. 3. D. 4.

170

Cu 34: Ha tan hon ton m gam hn hp gm Na2O v Al2O3 vo nc thu c dung dch X trong sut. Thm t t dung dch HCl 1M vo X, khi ht 100 ml th bt u xut hin kt ta; khi ht 300 ml hoc 700 ml th u thu c a gam kt ta. Gi tr ca a v m ln lt l A. 23,4 v 56,3. B. 23,4 v 35,9. C. 15,6 v 27,7. D. 15,6 v 55,4. Cu 35: Cho dy cc oxit: NO2, Cr2O3, SO2, CrO3, CO2, P2O5, Cl2O7, SiO2, CuO. C bao nhiu oxit trong dy tc dng c vi dung dch NaOH long? A. 6. B. 7. C. 8. D. 5. Cu 36: Xt phn ng phn hy N2O5 trong dung mi CCl4 450C : N2O5 N2O4 +

1 O2 2

Ban u nng ca N2O5 l 2,33M, sau 184 giy nng ca N2O5 l 2,08M. Tc trung bnh ca phn ng tnh theo N2O5 l A. 1,36.10-3 mol/(l.s). B. 6,80.10-4 mol/(l.s) -3 C. 6,80.10 mol/(l.s). D. 2,72.10-3 mol/(l.s). Cu 37: Loi t no sau y c iu ch bng phn ng trng hp? A. T visco. B. T nitron. C. T nilon-6,6. D. T xenluloz axetat. Cu 38: Mt loi phn kali c thnh phn chnh l KCl (cn li l cc tp cht khng cha kali) c sn xut t qung xinvinit c dinh dng 55%. Phn trm khi lng ca KCl trong loi phn kali l A. 95,51%. B. 87,18%. C. 65,75%. D. 88,52%. Cu 39: Cho cc pht biu sau: (a) t chy hon ton este no, n chc, mch h lun thu c s mol CO2 bng s mol H2O. (b) Trong hp cht hu c nht thit phi c cacbon v hiro. (c) Nhng hp cht hu c c thnh phn nguyn t ging nhau, thnh phn phn t hn km nhau mt hay nhiu nhm CH2 l ng ng ca nhau. (d) Dung dch glucoz b kh bi AgNO3 trong NH3 to ra Ag. (e) Saccaraz ch c cu to mch vng. S pht biu ng l A. 4. B. 5. C. 3. D. 2. Cu 40: Pht biu no sau y l ng? A. Mui phenylamoni clorua khng tan trong nc. B. Tt c cc peptit u c phn ng mu biure. C. H2N-CH2-CH2-CO-NH-CH2-COOH l mt ipeptit. D. iu kin thng, metylamin v imetylamin l nhng cht kh c mi khai. II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn ring (phn A hoc phn B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Ha hi 8,64 gam hn hp gm mt axit no, n chc, mch h X v mt axit no, a chc Y (c mch cacbon h, khng phn nhnh) thu c mt th tch hi bng th tch ca 2,8 gam N2 (o trong cng iu kin nhit , p sut). t chy hon ton 8,64 gam hn hp hai axit trn thu c 11,44 gam CO2. Phn trm khi lng ca X trong hn hp ban u l A. 72,22% B. 65,15% C. 27,78% D. 35,25% Cu 42: Cho 100 ml dung dch AgNO3 2a mol/l vo 100 ml dung dch Fe(NO3)2 a mol/l. Sau khi phn ng kt thc thu c 8,64 gam cht rn v dung dch X. Cho dung dch HCl d vo X thu c m gam kt ta. Gi tr ca m l A. 11,48 B. 14,35 C. 17,22 D. 22,96 Cu 43: t chy hon ton mt lng ancol X to ra 0,4 mol CO2 v 0,5 mol H2O. X tc dng vi Cu(OH)2 to ra dung dch mu xanh lam. Oxi ha X bng CuO to hp cht hu c a cht Y. Nhn xt no sau y ng vi X? A. X lm mt mu nc brom B. Trong X c hai nhm OH lin kt vi hai nguyn t cacbon bc hai. C. Trong X c ba nhm CH3. D. Hirat ha but-2-en thu c X. Cu 44: Cho cc phn ng sau: (a) FeS + 2HCl FeCl2 + H2S (b) Na2S + 2HCl 2NaCl + H2S (c) 2AlCl3 + 3Na2S + 6H2O 2Al(OH)3 + 3H2S + 6NaCl (d) KHSO4 + KHS K2SO4 + H2S (e) BaS + H2SO4 (long) BaSO4 + H2S S phn ng c phng trnh ion rt gn S2- + 2H+ H2S l A. 4 B. 3 C. 2 D. 1 Cu 45: Cho s chuyn ha sau: (a) C3H4O2 + NaOH X + Y 171

(b) X + H2SO4 (long) Z + T (c) Z + dung dch AgNO3/NH3 (d) E + Ag + NH4NO3 (d) Y + dung dch AgNO3/NH3 (d) F + Ag +NH4NO3 Cht E v cht F theo th t l A. (NH4)2CO3 v CH3COOH B. HCOONH4 v CH3COONH4 D. HCOONH4 v CH3CHO C. (NH4)2CO3 v CH3COONH4 Cu 46: Cho hn hp gm Fe v Mg vo dung dch AgNO3, khi cc phn ng xy ra hon ton thu c dung dch X (gm hai mui) v cht rn Y (gm hai kim loi). Hai mui trong X l: A. Mg(NO3)2 v Fe(NO3)2 B. Fe(NO3)2 v AgNO3 C. Fe(NO3)3 v Mg(NO3)2 D. AgNO3 v Mg(NO3)2 Cu 47: S amin bc mt c cng cng thc phn t C3H9N l A. 4 B. 3 C. 1 D. 2 Cu 48: Nhn xt no sau y khng ng? A. Crom l kim loi cng nht trong tt c cc kim loi B. Nhm v crom u b th ng ha bi HNO3 c, ngui. C. Nhm v crom u phn ng vi HCl theo cng t l s mol. D. Vt dng lm bng nhm v crom u bn trong khng kh v nc v c mng oxit bo v. Cu 49: Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng, thu c hn hp Y c t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ha l A. 70% B. 60% C. 50% D. 80% Cu 50: Dung dch cht no sau y lm qu tm chuyn thnh mu hng? A. axit -aminoglutaric B. Axit , -iaminocaproic C. Axit -aminopropionic D. Axit aminoaxetic. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Cho dy cc cht : cumen, stiren, isopren, xiclohexan, axetilen, benzen. S cht trong dy lm mt mu dung dch brom l A. 2 B. 3 C. 4 D. 5 Cu 52: Kh este no, n chc, mch h X bng LiAlH4, thu c ancol duy nht Y. t chy hon ton Y thu c 0,2 mol CO2 v 0,3 mol H2O. t chy hon ton 0,1 mol X thu c tng khi lng CO2 v H2O l A. 24,8 gam B. 28,4 gam C. 16,8 gam D. 18,6 gam Cu 53: C cc cht sau : keo dn ure-fomanehit; t lapsan; t nilon-6,6; protein; si bng; amoniaxetat; nha novolac. Trong cc cht trn, c bao nhiu cht m trong phn t ca chng c cha nhm NH-CO-? A. 5 B. 4 C. 3 D. 6 Cu 54: Cho cc pht biu sau v cacbohirat: (a) Tt c cc cacbohirat u c phn ng thy phn. (b) Thy phn hon ton tinh bt thu c glucoz. (c) Glucoz, fructoz v mantoz u c phn ng trng bc. (d) Glucoz lm mt mu nc brom. S pht biu ng l: A. 3 B. 4 C. 1 D. 2 Cu 55: Cho s chuyn ha : CH3Cl
H 3O KCN Y X t0
+

Cng thc cu to X, Y ln lt l: A. CH3NH2, CH3COOH B. CH3NH2, CH3COONH4 C. CH3CN, CH3COOH D. CH3CN, CH3CHO Cu 56: Cho 18,4 gam hn hp X gm Cu2S, CuS, FeS2 v FeS tc dng ht vi HNO3 (c nng d) thu c V lt kh ch c NO2 ( ktc, sn phm kh duy nht) v dung dch Y. Cho ton b Y vo mt lng d dung dch BaCl2, thu c 46,6 gam kt ta, cn khi cho ton b Y tc dng vi dung dch NH3 d thu c 10,7 gam kt ta. Gi tr ca V l A. 38,08 B. 11,2 C. 24,64 D. 16,8 Cu 57 : Dung dch X gm CH3COOH 0,03 M v CH3COONa 0,01 M. Bit 250C, Ka ca CH3COOH l 1,75.10-5, b qua s phn li ca nc. Gi tr pH ca dung dch X 250C l A. 6,28 B. 4,76 C. 4,28 D. 4,04 Cu 58: Cho cc pht biu sau (a) Kh CO2 gy ra hin tng hiu ng nh knh (b) Kh SO2 gy ra hin tng ma axit. (c) Khi c thi ra kh quyn, freon (ch yu l CFCl3 v CF2Cl2) ph hy tng ozon (d) Moocphin v cocain l cc cht ma ty S pht biu ng l A. 2 B. 4 C. 3 D. 1 Cu 59: Nhn xt no sau y khng ng A. SO3 v CrO3 u l oxit axit. 172

B. Al(OH) 3 v Cr(OH)3 u l hiroxit lng tnh v c tnh kh. C. BaSO4 v BaCrO4 hu nh khng tan trong nc. D. Fe(OH)2 v Cr(OH)2 u l baz v c tnh kh. Cu 60 : Cho
0 0 0 E pin ( Zn Cu ) = 1,10V ; EZn 2+ / Zn = 0,76V v E Ag + / Ag = +0,80V . Sut in ng chun ca pin

in ha Cu-Ag l A. 0,56 V 1 C 21 B 41 C 2 C 22 D 42 A 3 A 23 C 43 B 4 B 24 A 44 D 5 A 25 A 45 C 6 B 26 D 46 A

B. 0,34 V 7 C 27 D 47 D 8 C 28 D 48 C 9 C 29 C 49 C 10 B 30 B 50 D

C. 0,46 V 11 D 31 D 51 B 12 A 32 D 52 A 13 A 33 D 53 C 14 B 34 C 54 A 15 B 35 A 55 C

D. 1,14 V 16 A 36 A 56 A 17 D 37 B 57 C 18 D 38 B 58 B 19 A 39 D 59 B 20 B 40 D 60 C

THI TUYN SINH I HC, CAO NG NM 2012 Mn thi : HA, khi B I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1 : Pht biu no sau y l ng ? A. Tt c cc phn ng ca lu hunh vi kim loi u cn un nng. B. Trong cng nghip nhm c sn xut t qung olomit. C. Ca(OH)2 c dng lm mt tnh cng vnh cu ca nc. D. CrO3 tc dng vi nc to ra hn hp axit. Cu 2 : t 5,6 gam Fe trong khng kh, thu c hn hp cht rn X. Cho ton b X tc dng vi dung dch HNO3 long (d), thu c kh NO (sn phm kh duy nht) v dung dch cha m gam mui. Gi tr ca m l: A. 18,0. B. 22,4. C. 15,6 D. 24,2. Cu 3: Khi ni v kim loi kim, pht biu no sau y l sai? A. Cc kim loi kim c mu trng bc v c nh kim. B. Trong t nhin, cc kim loi kim ch tn ti dng hp cht. C. T Li n Cs kh nng phn ng vi nc gim dn. D. Kim loi kim c nhit nng chy v nhit si thp. Cu 4: t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O2, thu c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (My < Mz). Cc th tch kh u o iu kin tiu chun. T l a : b l A. 2 : 3 B. 4 : 3 C. 3 : 2 D. 3 : 5 Cu 5: Thy phn este X mch h c cng thc phn t C4H6O2, sn phm thu c c kh nng trng bc. S este X tha mn tnh cht trn l A. 4 B. 3 C. 6 D. 5 Cu 6: Th nghim no sau y chng t trong phn t glucoz c 5 nhm hiroxyl? A. Kh hon ton glucoz thnh hexan. B. Cho glucoz tc dng vi Cu(OH)2. C. Tin hnh phn ng to este ca glucoz vi anhirit axetic. D. Thc hin phn ng trng bc. Cu 7: Cho dy chuyn ha sau: CaC2

+H2O X

+H2
Pd/PbCO3,t
0

+H2OZ
H2SO4, t0

Tn gi ca X v Z ln lt l: A axetilen v ancol etylic. B. axetilen v etylen glicol. C. etan v etanal D. etilen v ancol etylic. Cu 8: in phn dung dch hn hp gm 0,1 mol FeCl3, 0,2 mol CuCl2 v 0,1 mol HCl (in cc tr). Khi catot bt u thot kh th anot thu c V lt kh (ktc). Bit hiu sut ca qu trnh in phn l 100%. Gi tr ca V l: A. 5,60. B. 11,20. C. 22,40. D. 4,48. Cu 9: Cc polime thuc loi t nhn to l A. t visco v t nilon-6,6 B. t tm v t vinilon. C. t nilon-6,6 v t capron D. t visco v t xenluloz axetat. 173

Cu 10: un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol tripeptit mch h Y vi 600 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch thu c 72,48 gam mui khan ca cc amino axit u c mt nhm -COOH v mt nhm -NH2 trong phn t. Gi tr ca M l A. 51,72 B. 54,30 C. 66,00 D. 44,48 Cu 11: Cho s chuyn ha Fe(NO3)3

t0

+CO d, t0

+FeCl3

+T 3)3 Fe(NO

Cc cht X v T ln lt l A. FeO v NaNO3 B. FeO v AgNO3 C. Fe2O3 v Cu(NO3)2 D. Fe2O3 v AgNO3 Cu 12: Cho cc th nghim sau: (a) t kh H2S trong O2 d (b) Nhit phn KClO3 (xc tc MnO2) (c) Dn kh F2 vo nc nng (d) t P trong O2 d (e) Kh NH3 chy trong O2 (g) Dn kh CO2 vo dung dch Na2SiO3 S th nghim to ra cht kh l A. 5 B. 4 C. 2 D. 3 Cu 13: Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m gam mui. Gi tr ca m l A. 44,65 B. 50,65 C. 22,35 D. 33,50 Cu 14: Pht biu no sau y l sai? A. Nguyn t kim loi thng c 1, 2 hoc 3 electron lp ngoi cng. B. Cc nhm A bao gm cc nguyn t s v nguyn t p. C. Trong mt chu k, bn knh nguyn t kim loi nh hn bn knh nguyn t phi kim. D. Cc kim loi thng c nh kim do cc electron t do phn x nh sng nhn thy c. Cu 15: Cho hn hp X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X thu c 6,72 lt kh CO2 (ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh H2 (ktc). Gi tr ca V l A. 3,36 B. 11,20 C. 5,60 D. 6,72 Cu 16: S trieste khi thy phn u thu c sn phm gm glixerol, axit CH3COOH v axit C2H5COOH l A. 9 B. 4 C. 6 D. 2 Cu 17: Pht biu no sau y l ng? A. Hn hp FeS v CuS tan c ht trong dung dch HCl d. B. Thi khng kh qua than nung , thu c kh than t. C. Phtpho d bc chy trong khng kh iu kin thng. D. Dung dch hn hp HCl v KNO3 ha tan c bt ng. Cu 18: t chy hn hp gm 1,92 gam Mg v 4,48 gam Fe vi hn hp kh X gm Clo v Oxi, sau phn ng ch thu c hn hp Y gm cc oxit v mui clorua (khng cn kh d) ha tan Y bng mt lng va 120 ml dung dch HCl 2M, thu c dung dch Z. Cho AgNO3 d vo dung dch Z, thu c 56,69 gam kt ta. Phn trm th tch ca Clo trong hn hp X l A. 51,72% B. 76,70% C. 53,85% D. 56,36% Cu 19: Oxi ha 0,08 mol mt ancol n chc, thu c hn hp X gm mt axit cacboxylic, mt anehit, ancol d v nc. Ngng t ton b X ri chia lm hai phn bng nhau. Phn mt cho tc dng ht vi Na d, thu c 0,504 lt kh H2 (ktc). Phn hai cho phn ng trng bc hon ton thu c 9,72 gam Ag. Phn trm khi lng ancol b oxi ha l A. 50,00% B. 62,50% C. 31,25% D. 40,00% Cu 20: Nguyn t Y l phi kim thuc chu k 3, c cng thc oxit cao nht l YO3. Nguyn tt Y to vi kim loi M hp cht c cng thc MY, trong M chim 63,64% v khi lng. Kim loi M l A. Zn B. Cu C. Mg D. Fe Cu 21: t chy hon ton 20 ml hi hp cht hu c X (ch gm C, H, O) cn va 110 ml kh O2 thu c 160 ml hn hp Y gm kh v hi. Dn Y qua dung dch H2SO4 c (d), cn li 80 ml kh Z. Bit cc th tch kh v hi o cng iu kin. Cng thc phn t ca X l A. C4H8O2 B. C4H10O C. C3H8O D. C4H8O Cu 22: Mt dung dch X gm 0,01 mol Na+; 0,02 mol Ca2+; 0,02 mol nc). Ion X v gi tr ca a l A.

HCO3 v a mol ion X (b qua s in li ca

D.

NO3 v 0,03

B.

Cl v 0,01

C.

CO32 v 0,03

OH v 0,03

Cu 23: Cho phn ng : N2(k) + 3H2(k) theo chiu thun l A. gim nhit v gim p sut. C. gim nhit v tng p sut.

2NH3 (k); H = -92 kJ. Hai bin php u lm cn bng chuyn dch B. tng nhit v tng p sut. D. tng nhit v gim p sut. 174

Cu 24: Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp X (xc tc Ni) mt thi gian, thu c hn hp Y c t khi so vi H2 bng 10. Dn hn hp Y qua dung dch Brom d, sau khi phn ng xy ra hon ton, khi lng brom tham gia phn ng l A. 0 gam B. 24 gam C. 8 gam D. 16 gam Cu 25: Sc 4,48 lt kh CO2 (ktc) vo 1 lt dung dch hn hp Ba(OH)2 0,12M v NaOH 0,06M. Sau khi cc phn ng xy ra hon ton thu c m gam kt ta. Gi tr ca m l A. 19,70 B. 23,64 C. 7,88 D. 13,79 Cu 26: Trng hp no sau y xy ra n mn in ha? A. Si dy bc nhng trong dung dch HNO3. B. t l st trong kh Cl2. C. Thanh nhm nhng trong dung dch H2SO4 long. D. Thanh km nhng trong dung dch CuSO4. Cu 27: Cho 29 gam hn hp gm Al, Cu v Ag tc dng va vi 950 ml dung dch HNO3 1,5M, thu c dung dch cha m gam mui v 5,6 lt hn hp kh X (ktc) gm NO v N2O. T khi ca X so vi H2 l 16,4. Gi tr ca m l A. 98,20 B. 97,20 C. 98,75 D. 91,00 Cu 28: t chy hon ton 50 ml hn hp kh X gm trimetylamin v 2 hirocacbon ng ng k tip bng mt lng oxi va , thu c 375 ml hn hp Y gm kh v hi. Dn ton b Y qua dung dch H2SO4 c (d). Th tch kh cn li l 175 ml. Cc th tch kh v hi o cng iu kin. Hai hirocacbon l A. C2H4 v C3H6 B. C3H6 v C4H8 C. C2H6 v C3H8 D. C3H8 v C4H10 Cu 29: Cho cc cht ring bit sau: FeSO4, AgNO3, Na2SO3, H2S, HI, Fe3O4, Fe2O3 tc dng vi dung dch H2SO4 c, nng. S trng hp xy ra phn ng oxi ha kh l A. 6 B. 3 C. 4 D. 5 Cu 30: Cho 0,42 gam hn hp bt Fe v Al vo 250 ml dung dch AgNO3 0,12M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v 3,333 gam cht rn. Khi lng Fe trong hn hp ban u l A. 0,168 gam B. 0,123 gam C. 0,177 gam D. 0,150 gam Cu 31: Cho 0,125 mol anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3 thu c 27 gam Ag. Mt khc, hiro ha hon ton 0,25 mol X cn va 0,5 mol H2. Dy ng ng ca X c cng thc chung l A. CnH2n(CHO)2(n 0) B. CnH2n-3CHO (n 2) C. CnH2n+1CHO (n 0) D. CnH2n-1CHO (n 2) Cu 32: Cho cc cht sau : FeCO3, Fe3O4, FeS, Fe(OH)2. Nu ha tan cng s mol mi cht vo dung dch H2SO4 c, nng (d) th cht to ra s mol kh ln nht l A. Fe3O4 B. Fe(OH)2 C. FeS D. FeCO3 Cu 33: un nng m gam hn hp X gm cc cht c cng mt loi nhm chc vi 600 ml dung dch NaOH 1,15M, thu c dung dch Y cha mui ca mt axit cacboxylic n chc v 15,4 gam hi Z gm cc ancol. Cho ton b Z tc dng vi Na d, thu c 5,04 lt kh H2 (ktc). C cn dung dch Y, nung nng cht rn thu c vi CaO cho n khi phn ng xy ra hon ton, thu c 7,2 gam mt cht kh. Gi tr ca m l A. 40,60 B. 22,60 C. 34,30 D. 34,51 Cu 34: Hn hp X gm hai axit cacboxylic n chc. t chy hon ton 0,1 mol X cn 0,24 mol O2 thu c CO2 v 0,2 mol H2O. Cng thc hai axit l A. HCOOH v C2H5COOH B. CH2=CHCOOH v CH2=C(CH3)COOH C. CH3COOH v C2H5COOH D. CH3COOH v CH2=CHCOOH Cu 35: t 16,2 gam hn hp X gm Al v Fe trong kh Cl2 thu c hn hp cht rn Y. Cho Y vo nc d, thu c dung dch Z v 2,4 gam kim loi. Dung dch Z tc dng c vi ti a 0,21 mol KMnO4 trong dung dch H2SO4 (khng to ra SO2). Phn trm khi lng ca Fe trong hn hp X l A. 72,91% B. 64,00% C. 66,67% D. 37,33% Cu 36: Ha tan hon ton 0,1 mol FeS2 trong 200 ml dung dch HNO3 4M, sn phm thu c gm dung dch X v mt cht kh thot ra. Dung dch X c th ha tan ti a m gam Cu. Bit trong cc qu trnh trn, sn phm kh duy nht ca N+5 u l NO. Gi tr ca m l A. 12,8 B. 6,4 C. 9,6 D. 3,2 Cu 37: Este X l hp cht thm c cng thc phn t l C9H10O2. Cho X tc dng vi dung dch NaOH, to ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l A. CH3COOCH2C6H5 B. HCOOC6H4C2H5 C. C6H5COOC2H5 D. C2H5COOC6H5 Cu 38: Alanin c cng thc l A. C6H5-NH2 B. CH3-CH(NH2)-COOH C. H2N-CH2-COOH D. H2N-CH2-CH2-COOH CaO, t0 2 CH4 + K2CO3 + Na2CO3 Cu 39: Cho phng trnh ha hc : 2X + 2NaOH Cht X l A. CH2(COOK)2 B. CH2(COONa)2 C. CH3COOK D. CH3COONa

175

Cu 40: Dn lung kh CO i qua hn hp gm CuO v Fe2O3 nung nng, sau mt thi gian thu c cht rn X v kh Y. Cho Y hp th hon ton vo dung dch Ba(OH)2 d, thu c 29,55 gam kt ta. Cht rn X phn ng vi dung dch HNO3 d thu c V lt kh NO (sn phm kh duy nht ktc). Gi tr ca V l A. 2,24 B. 4,48 V. 6,72 D. 3,36 II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn ca phn ring (phn A hoc phn B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Cho dy cc cht sau: toluen, phenyl fomat, fructoz, glyxylvalin (Gly-val), etylen glicol, triolein. S cht b thy phn trong mi trng axit l: A. 6 B. 3 C. 4 D. 5 Cu 42: Cho phng trnh ha hc (vi a, b, c, d l cc h s): aFeSO4 + bCl2 cFe2(SO4)3 + dFeCl3 T l a : c l A. 4 : 1 B. 3 : 2 C. 2 : 1 D. 3 :1 Cu 43: Cho m gam bt sc vo dung dch hn hp gm 0,15 mol CuSO4 v 0,2 mol HCl. Sau khi cc phn ng xy ra hon ton, thu c 0,725m gam hn hp kim loi. Gi tr ca m l A. 16,0 B. 18,0 C. 16,8 D.11,2 Cu 44: iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt axit nitric 94,5% (D=1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l A. 60 B. 24 C. 36 D. 40 Cu 45: C bao nhiu cht cha vng benzene c cng cng thc phn t C7H8O? A. 3 B. 5 C. 6 D. 4 Cu 46: t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c cng thc n gin nht khc nhau, thu c 2,2 gam CO2 v 0,9 gam H2O. Cc cht trong X l A. mt ankan v mt ankin B. hai ankaien C. hai anken. D. mt anken v mt ankin. Cu 47: Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng thc phn t C3H9O2N (sn phm duy nht). S cp cht X v Y tha mn iu kin trn l A. 3 B. 2 C. 4 D. 1 Cu 48: Pht biu no sau y l sai? A. Clo c dng dit trng nc trong h thng cung cp nc sch. B. Amoniac c dng iu ch nhin liu cho tn la. C. Lu hunh ioxit c dng lm cht chng thm nc. D. Ozon trong khng kh l nguyn nhn chnh gy ra s bin i kh hu. Cu 49: Pht biu no sau y l sai? A. Cr(OH)3 tan trong dung dch NaOH. B. Trong mi trng axit, Zn kh Cr3+ thnh Cr. C. Photpho bc chy khi tip xc vi CrO3. D. Trong mi trng kim, Br2 oxi ha CrO 2 thnh CrO 4 . Cu 50: Nung nng 46,6 gam hn hp gm Al v Cr2O3 (trong iu kin khng c khng kh) n khi phn ng xy ra hon ton. Chia hn hp thu c sau phn ng thnh hai phn bng nhau. Phn mt phn ng va vi 300 ml dung dch NaOH 1M (long). ha tan ht phn hai cn va dung dch cha a mol HCl. Gi tr ca a l A. 0,9 B. 1,3 C. 0,5 D. 1,5 B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Thy phn hn hp gm 0,01 mol saccaroz v 0,02 mol mantoz trong mi trng axit, vi hiu sut u l 60% theo mi cht, thu c dung dch X. Trung ha dung dch X, thu c dung dch Y, sau cho ton b Y tc dng vi lng d dung dch AgNO3 trong NH3, thu c m gam Ag. Gi tr ca m l A. 6,480 B. 9,504 C. 8,208 D. 7,776 Cu 52: Mt mu kh thi c sc vo dung dch CuSO4, thy xut hin kt ta mu en. Hin tng ny do cht no c trong kh thi gy ra? A. H2S B. NO2 C. SO2 D. CO2 Cu 53: Cho phenol (C6H5OH) ln lt tc dng vi (CH3CO)2O v cc dung dch: NaOH, HCl, Br2, HNO3, CH3COOH. S trng hp xy ra phn ng l A. 3 B. 4 C. 2 D. 1 Cu 54: Ha tan Au bng nc cng toan th sn phm kh l NO; ha tan Ag trong dung dch HNO3 c th sn phm kh l NO2. s mol NO2 bng s mol NO th t l s mol Ag v Au tng ng l A. 1 : 2 B. 3 : 1 C. 1 : 1 D. 1 : 3 Cu 55: Ngi ta iu ch H2 v O2 bng phng php in phn dung dch NaOH vi in cc tr, cng dng in 0,67 A trong thi gian 40 gi. Dung dch thu c sau in phn c khi lng 100 gam v nng NaOH l 6%. Nng dung dch NaOH trc in phn l (gi thit lng nc bay hi khng ng k) A. 5,08% B. 6,00% C. 5,50% D. 3,16% 176
2-

Cu 56: Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm chnh l A. 2-metybutan-2-ol B. 3-metybutan-2-ol C.3-metylbutan-1-ol D.2-metylbutan-3-ol Cu 57: Dung dch cht X khng lm i mu qu tm; dung dch cht Y lm qu tm ha xanh. Trn ln hai dung dch trn thu c kt ta. Hai cht X v Y tng ng l A. KNO3 v Na2CO3 B. Ba(NO3)2 v Na2CO3 D. Ba(NO3)2 v K2SO4 C. Na2SO4 v BaCl2 Cu 58: Trng hp no sau y to ra kim loi? A. t FeS2 trong oxi d. B. Nung hn hp qung apatit, x vn v than cc trong l ng. C. t Ag2S trong oxi d. D. Nung hn hp qung photphorit, ct v than cc trong l in. Cu 59: t chy hon ton m gam hn hp X gm hai ancol, thu c 13,44 lt kh CO2 (ktc) v 15,3 gam H2O. Mt khc, cho m gam X tc dng vi Na (d), thu c 4,48 lt kh H2 (ktc). Gi tr ca m l A. 12,9 B. 15,3 C. 12,3 D. 16,9 Cu 60: Cho cc cht : caprolactam (1), isopropylbenzen (2), acrilonitrin (3), glyxin (4), vinyl axetat (5). Cc cht c kh nng tham gia phn ng trng hp to polime l A. (1), (2) v (3) B. (1), (2) v (5) C. (1), (3) v (5) D. (3), (4) v (5) 1 D 21 D 41 B 2 D 22 A 42 D 3 C 23 C 43 A 4 B 24 B 44 D 5 A 25 A 45 B 6 C 26 D 46 A 7 A 27 A 47 C 8 A 28 B 48 D 9 D 29 C 49 B 10 A 30 C 50 B 11 D 31 D 51 B 12 B 32 C 52 A 13 A 33 A 53 B 14 C 34 D 54 C 15 A 35 C 55 C 16 B 36 A 56 A 17 D 37 D 57 B 18 C 38 B 58 C 19 B 39 A 59 B 20 D 40 A 60 C

THI TUYN SINH CAO NG NM 2012 Mn thi : HA, khi A v B I. PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) Cu 1 : Cho dy cc cht: N2, H2, NH3, NaCl, HCl, H2O. S cht trong dy m phn t ch cha lin kt cng ha tr khng cc l A. 2. B. 4. C. 3. D. 5. Cu 2 : Cho dy cc dung dch: axit axetic, phenylamoni clorua, natri axetat, metylamin, glyxin, phenol (C6H5OH). S dung dch trong dy tc dng c vi dung dch NaOH l A. 6. B. 3. C. 4. D. 5. Cu 3: Hn hp X gm Na, Al v Fe (vi t l s mol gia Na v Al tng ng l 2 : 1). Cho X tc dng vi H2O (d) thu c cht rn Y v V lt kh. Cho ton b Y tc dng vi dung dch H2SO4 long (d) thu c 0,25V lt kh. Bit cc kh o cng iu kin, cc phn ng u xy ra hon ton. T l s mol ca Fe v Al trong X tng ng l A. 1 : 2. B. 5 : 8. C. 5 : 16. D. 16 : 5. Cu 4: Nung hn hp bt gm Al v Fe2O3 (trong iu kin khng c oxi), thu c hn hp cht rn X. Chia X thnh 2 phn bng nhau: - Cho phn 1 vo dung dch HCl (d) thu c 7,84 lt kh H2 (ktc); - Cho phn 2 vo dung dch NaOH (d) thu c 3,36 lt kh H2 (ktc). Bit rng cc phn ng u xy ra hon ton. Phn trm khi lng ca Fe trong X l A. 42,32%. B. 46,47%. C. 66,39%. D. 33,61%. Cu 5: Cho m gam hn hp hoi X gm hai ancol (n chc, bc I, l ng ng k tip) phn ng vi CuO d, thu c hn hp hi Y gm nc v anehit. T khi hi ca Y so vi kh hiro bng 14,5. Cho ton b Y phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 97,2 gam Ag. Gi tr ca m l A. 14,0. B. 14,7. C. 10,1. D. 18,9. Cu 6: Kim loi no sau y iu ch c bng phng php thy luyn? A. Ca. B. K. C. Mg. D. Cu. Cu 7: Cho s phn ng: Este X (C4HnO2)
+ AgNO3 / NH 3 + NaOH + NaOH Y Z C2H3O2Na. t0 t0 t0

Cng thc cu to ca X tha mn s cho l A. CH2=CHCOOCH3. B. CH3COOCH2CH3. C. HCOOCH2CH2CH3. D. CH3COOCH=CH2. Cu 8: Cho 42,4 gam hn hp gm Cu v Fe3O4 (c t l s mol tng ng l 3 : 1) tc dng vi dung dch HCl d, sau khi cc phn ng xy ra hon ton cn li m gam cht rn. Gi tr ca m l 177

A. 12,8. B. 19,2. C. 9,6. D. 6,4. Cu 9: Pht biu no sau y l ng? A. Polietilen v poli (vinyl clorua) l sn phm ca phn ng trng ngng. B. T visco, t xenluloz axetat u thuc loi t tng hp. C. Si bng, t tm thuc loi polime thin nhin. D. T nilon-6,6 c iu ch t hexametyleniamin v axit axetic. Cu 10 : Ha tan hon ton 8,9 gam hn hp gm Mg v Zn bng lng va 500 ml dung dch HNO3 1M. Sau khi cc phn ng kt thc, thu c 1,008 lt kh N2O (ktc) duy nht v dung dch X cha m gam mui. Gi tr ca m l A. 34,10 B. 31,32 C. 34,32 D. 33,70 Cu 11: Trong phn t axit cacboxylic X c s nguyn t cacbon bng s nhm chc. t chy hon ton mt lng X thu c s mol CO2 bng s mol H2O. Tn gi ca X l A. axit axetic. B. axit oxalic. C. axit fomic. D. axit malonic Cu 12: Ha tan hon ton 1,1 gam hn hp gm mt kim loi kim X v mt kim loi kim th Y (Mx < My) trong dung dch HCl d, thu c 1,12 lt kh H2 (ktc). Kim loi X l A. K. B. Na. C. Rb. D. Li. Cu 13: Cho cc pht biu sau: (1) Fructoz v glucoz u c kh nng tham gia phn ng trng bc; (2) Saccaroz v tinh bt u khng b thy phn khi c axit H2SO4 (long) lm xc tc; (3) Tinh bt c to thnh trong cy xanh nh qu trnh quang hp; (4) Xenluloz v saccaroz u thuc loi disaccarit; Pht biu ng l A. (3) v (4). B. (1) v (3). C. (1) v (2). D. (2) v (4). Cu 14: Dung dch long (d) no sau y tc dng c vi kim loi st to thnh mui st(III)? A. HNO3. B. H2SO4. C. FeCl3. D. HCl. Cu 15: Nung mt lng butan trong bnh kn (c xc tc thch hp) thu c hn hp kh X gm ankan v anken. T khi ca X so vi kh hiro l 21,75. Phn trm th tch ca butan trong X l A. 33,33% B. 50,00% C. 66,67% D. 25,00% t0 Cu 16: Cho phn ng ha hc: Cl2 + KOH KCl + KClO3 + H2O T l gia s nguyn t clo ng vai tr cht oxi ha v s nguyn t clo ng vai tr cht kh trong phng trnh ha hc ca phn ng cho tng ng l A. 3 : 1. B. 1 : 3. C. 5 : 1. D. 1 : 5. Cu 17: t chy hon ton m gam hn hp X gm hai ancol n chc, cng dy ng ng, thu c 15,68 lt kh CO2 (ktc) v 17,1 gam nc. Mt khc, thc hin phn ng este ha m gam X vi 15,6 gam axit axetic, thu c a gam este. Bit hiu sut phn ng este ha ca hai ancol u bng 60%. Gi tr ca a l A. 15,48. B. 25,79. C. 24,80. D. 14,88. Cu 18: Dung dch E gm x mol Ca2+, y mol Ba2+, z mol

HCO-3

. Cho t t dung dch Ca(OH)2 nng a mol/l

vo dung dch E n khi thu c lng kt ta ln nht th va ht V lt dung dch Ca(OH)2. Biu thc lin h gia cc gi tr V, a, x, y l A.

V=

x+ y a

B.

V=

x + 2y a

C.

V = 2a ( x + y )

D.

V = a(2 x + y )

Cu 19: Pht biu no sau y l ng? A. Trong hp cht, tt c cc kim loi kim u c s oxi ha +1. B. Trong nhm 1A, tnh kh ca cc kim loi gim dn t Li n Cs. C. Tt c cc hiroxit ca kim loi nhm IIA u d tan trong nc. D. Tt c cc kim loi nhm IIA u c mng tinh th lp phng tm khi. Cu 20: Thnh phn chnh ca phn bn phc hp amophot l B. NH4NO3 v Ca(H2PO4)2. A. NH4H2PO4 v (NH4)2HPO4. C. NH4H2PO4 v Ca(H2PO4)2. D. Ca3(PO4)2 v (NH4)2HPO4. Cu 21: Cho dy cc ion : Fe2+, Ni2+, Cu2+, Sn2+. Trong cng iu kin, ion c tnh oxi ha mnh nht trong dy l A. Fe2+ B. Sn2+ C. Cu2+ D. Ni2+ Cu 22: Cho 20 gam hn hp gm hai amin no, n chc, mch h tc dng va vi V ml dung dch HCl 1M, thu c dung dch cha 31,68 gam hn hp mui. Gi tr ca V l A. 200. B. 100. C. 320. D. 50. Cu 23: Cho cc este : etyl fomat (1), vinyl axetat (2), triolein (3), metyl acrylat (4), phenyl axetat (5). Dy gm cc este u phn ng c vi dung dch NaOH (un nng) sinh ra ancol l A. (1), (2), (3). B. (1), (3), (4). C. (2), (3), (5). D. (3), (4), (5). Cu 24: Pht biu no sau y l sai? A. Tripeptit Gly-Ala-Gly c phn ng mu biure vi Cu(OH)2. B. Trong phn t ipeptit mch h c hai lin kt peptit. C. Protein n gin c to thnh t cc gc -amino axit. 178

D. Tt c cc peptit u c kh nng tham gia phn ng thy phn. Cu 25: Tin hnh in phn (vi in cc tr) V lt dung dch CuCl2 0,5M. Khi dng in phn thu c dung dch X v 1,68 lt kh Cl2 (ktc) duy nht anot. Ton b dung dch X tc dng va vi 12,6 gam Fe. Gi tr ca V l A. 0,60. B. 0,15. C. 0,45. D. 0,80. Cu 26: S ancol bc I l ng phn cu to ca nhau c cng thc phn t C5H12O l A. 4. B. 1 C. 8. D. 3 Cu 27: Tin hnh cc th nghim sau: (a) Cho l Fe vo dung dch gm CuSO4 v H2SO4 long; (b) t dy Fe trong bnh ng kh O2; (c) Cho l Cu vo dung dch gm Fe(NO3) v HNO3; (d) Cho l Zn vo dung dch HCl; S th nghim c xy ra n mn in ha l A. 3 B. 2 C. 1 D. 4 Cu 28: Cho dung dch cha m gam hn hp gjm phenol (C6H5OH) v axit axetic tc dng va vi nc brom, thu c dung dch X v 33,1 gam kt ta 2,4,6-tribromphenol. Trung ha hon ton X cn va 500 ml dung dch NaOH 1M. Gi tr ca m l A. 21,4 B. 24,8 C. 33,4 D. 39,4 Cu 29: Cho dy gm cc phn t v ion : Zn, S, FeO, SO2, Fe2+, Cu2+, HCl. Tng s phn t v ion trong dy va c tnh oxi ha, va c tnh kh l A. 7 B. 4 C. 6 D. 5 Cu 30: Tin hnh cc th nghim sau (1) Cho Zn vo dung dch AgNO3; (2) Cho Fe Vo dung dch Fe2(SO4)3; (3) Cho Na vo dung dch CuSO4; (4) Dn kh CO (d) qua bt CuO nng. Cc th nghim c to thnh kim loi l A. (3) v (4). B. (1) v (2). C. (2) v (3). D. (1) v (4). Cu 31: Pht biu no sau y l ng? A. Ancol etylic tc dng c vi dung dch NaOH. B. Axit bo l nhng axit cacboxylic a chc. C. Etylen glicol l ancol no, n chc, mch h. D. Este isoamyl axetat c mi chui chn. Cu 32: Ln men 90 kg glucoz thu c V lt ancol etylic (D = 0,8 g/ml) vi hiu sut ca qu trnh ln men l 80%. Gi tr ca V l A. 71,9 B. 46,0 C. 23,0 D. 57,5 Cu 33: Pht biu no sau y l sai? A. Cao su buna-N thuc loi cao su thin nhin. B. Lc baz ca aniline yu hn lc baz ca metylamin. C. Cht bo cn c gi l triglixerit hoc triaxylglixerol. D. Poli(metyl metacrylat) c dng ch to thy tinh hu c. Cu 34: Nguyn t ca nguyn t X c tng s ht proton, ntron, electron l 52. Trong ht nhn nguyn t X c s ht khng mang in nhiu hn s ht mang in l 1. V tr (chu k, nhm) ca X trong bng tun hon cc nguyn t ha hc l A.chu k 3, nhm VA. B. chu k 3, nhm VIIA. C. chu k 2, nhm VA. D. chu k 2, nhm VIIA. Cu 35: Cho Fe tc dng vi dung dch H2SO4 long to thnh kh X; nhit phn tinh th KNO3 to thnh kh Y; cho tinh th KMnO4 tc dng vi dung dch HCl c to thnh kh Z. Cc kh X, Y v Z ln lt l A. Cl2, O2 v H2S B. H2, O2 v Cl2. C. SO2, O2 v Cl2. D. H2, NO2 v Cl2. Cu 36: S nhm amino v s nhm cacboxyl c trong mt phn t axit glutamic tng ng l A. 1 v 1. B. 2 v 2. C. 2 v 1. D. 1 v 2. Cu 37: Hp th hon ton 0,336 lt kh CO2 (ktc) vo 200 ml dung dch gm NaOH 0,1M v KOH 0,1M thu c dung dch X. C cn ton b dung dch X thu c bao nhiu gam cht rn khan? A. 2,44 gam B. 2,22 gam C. 2,31 gam D. 2,58 gam. Cu 38: Cho cn bng ha hc : CaCO3 (rn) CaO (rn) + CO2(kh) Bit phn ng thun l phn ng thu nhit. Tc ng no sau y vo h cn bng cn bng cho chuyn dch theo chiu thun? A. Gim nhit . B. Tng p sut. C. Tng nng t kh CO2. D. Tng nhit . Cu 39: Cho dy cc cht: etan, etanol, etanal, axit etanoic. Cht c nhit si cao nht trong dy l A. etanal B. etan C. etanol. D. axit etanoic. 179

Cu 40: Thy phn hon ton m gam ipeptit Gly-Ala (mch h) bng dung dch KOH va , thu c dung dch X. C cn ton b dung dch X thu c 2,4 gam mui khan. Gi tr ca m l A. 1,22 B. 1,46 C. 1,36 D. 1,64 II. PHN RING (10 cu) Th sinh ch c lm mt trong hai phn ring (phn A hoc phn B) A. Theo chng trnh Chun (10 cu, t cu 41 n cu 50) Cu 41: Cng thc chung ca amin no, n chc, mch h l A. CnH2n-1N (n 2) B. CnH2n-5N (n 6) C. CnH2n+1N (n 2) D. CnH2n+3N (n 1) Cu 42: Cht no sau y va tc dng c vi dung dch NaOH, va tc dng c vi nc Br2? A. CH3CH2CH2OH B. CH3COOCH3 C. CH3CH2COOH. D. CH2=CHCOOH. Cu 43: Cho 1,42 gam P2O5 tc dng hon ton vi 50 ml dung dch KOH 1M, thu c dung dch X. C cn dung dch X thu c cht rn khan gm A. H3PO4 v KH2PO4. B. K3PO4 v KOH. D. K2HPO4 v K3PO4. C. KH2PO4 v K2HPO4. Cu 44: Ha tan hon ton 2,7 gam hn hp X gm Fe, Cr, Al bng dung dch HCl d, thu c 1,568 lt kh H2 (ktc). Mt khc, cho 2,7 gam X phn ng hon ton vi kh Cl2 d, thu c 9,09 gam mui. Khi lng Al trong 2,7 gam X l bao nhiu? A. 0,54 gam B. 0,81 gam C. 0,27 gam D. 1,08 gam Cu 45: Ha hi hon ton 4,4 gam mt este X mch h, thu c th tch hi bng th tch ca 1,6 gam kh oxi (o cng iu kin). Mt khc, thy phn hon ton 11 gam X bng dung dch NaOH d, thu c 10,25 gam mui. Cng thc ca X l B. CH3COOC2H5. C. C2H5COOC2H5. D. HCOOC3H7. A. C2H5COOCH3. Cu 46 : Cho dy cc cht : anehit axetic, axetilen, glucoz, axit axetic, metyl axetat. S cht trong dy c kh nng tham gia phn ng trng bc l A. 4 B. 5 C. 2 D. 3 Cu 47: t chy hon ton hn hp X gm hai ancol no, hai chc, mch h cn va V1 lt kh O2, thu c V2 lt kh CO2 v a mol H2O. Cc kh u o iu kin tiu chun. Biu thc lin h gia cc gi tr V1, V2, a l B. V1 = V2 +22,4a C. V1 = V2 - 22,4a D. V1 = 2V2 + 11,2a A. V1 = 2V2 - 11,2a Cu 48: Cho phn ng ha hc : Br2 + HCOOH 2HBr + CO2 Lc u nng ca HCOOH l 0,010 mol/l, sau 40 giy nng ca HCOOH l 0,008 mol/l. Tc trun g bnh ca phn ng trong khong thi gian sau 40 giy tnh theo HCOOH l B. 2,5.10-4 mol/(l.s) C. 2,0.10-4 mol/(l.s) D. 2,5.10-5 mol/(l.s) A. 5,0.10-5 mol/(l.s) Cu 49: loi b Al, Fe, CuO ra khi hn hp gm Ag, Al, Fe v CuO, c th dng lng d dung dch no sau y? A. Dung dch Fe(NO3)3. B. Dung dch NaOH. C. Dung dch HNO3. D. Dung dch HCl. Cu 50: Cho cc cht hu c : CH3CH(CH3)NH2 (X) v CH3CH(NH2)COOH (Y). Tn thay th ca X v Y ln lt l A. propan-2-amin v axit aminoetanoic B. propan-2-amin v axit 2-aminopropanoic C. propan-1-amin v axit 2-aminopropanoic D. propan-1-amin v axit aminoetanoic. B. Theo chng trnh Nng cao (10 cu, t cu 51 n cu 60) Cu 51: Pht biu no sau y l ng? A. nhit thng, cc amino axit u l nhng cht lng. B. Cc amino axit thin nhin hu ht l cc -amino axit. C. Amino axit thuc loi hp cht hu c tp chc. D. Axit glutamic l thnh phn chnh ca bt ngt. Cu 52: Cho cc pht biu: (1) Tt c cc anehit u c c tnh oxi ha v tnh kh; (2) Tt c cc axit cacboxylic u khng tham gia phn ng trng bc; (3) Phn ng thy phn este trong mi trng axit l phn ng thun nghch; (4) Tt c cc ancol no, a chc u ha tan c Cu(OH)2. Pht biu ng l A. (2) v (4) B. (3) v (4) C. (1) v (3) D. (1) v (2) Cu 53: Cho 14, 55 gam mui H2NCH2COONa tc dng hon ton vi dung dch HCl d, thu c dung dch X. C cn ton b dung dch X, thu c bao nhiu gam mui khan? A. 16,73 gam B. 25,50 gam C. 8,78 gam D. 20,03 gam Cu 54: Cho s phn ng:
+ Cl2 (d) t
0

Cr

+ KOH (c, d) +Cl2

Y 180

Bit Y l hp cht ca crom. Hai cht X v Y ln lt l A. CrCl2 v K2CrO4. B. CrCl3 v K2Cr2O7 C. CrCl3 v K2CrO4 D. CrCl2 v Cr(OH)3 Cu 55: t chy hon ton hn hp X gm hai hirocacbon k tip nhau trong dy ng ng, thu c 2,24 lt kh CO2 (ktc) v 3,24 gam H2O. Hai hirocacbon trong X l B. C2H4 v C3H6. C. CH4 v C2H6 D. C2H6 v C3H8 A. C2H2 v C3H4. Cu 56: Cho th in cc chun ca cc cp oxi ha - kh Ag+/Ag, Cu2+/Cu, Pb2+/Pb, Zn2+/Zn c gi tr ln lt l : +0,80V; +0,34V; -0,13V; -0,76V. Trong cc pin sau, pin no c sut in ng chun ln nht? A. Pin Pb-Cu. B. Pin Pb-Ag. C. Pin Zn-Cu D. Pin Zn-Ag. Cu 57: Bit 250C, hng s phn li baz ca NH3 l 1,74.10-5, b qua s phn li ca nc. Gi tr pH ca dung dch NH3 0,1M 250C l A. 11,12 B. 4,76 C. 13,00 D. 9,24 Cu 58: Oxi ha hon ton m gam kim loi X cn va 0,25m gam kh O2. X l kim loi no sau y? A. Al. B. Fe. C. Cu. D. Ca. Cu 59: Cho dy cc kim loi : Cu, Ni, Zn, Mg, Ba, Ag. S kim loi trong dy phn ng c vi dung dch FeCl3 l A. 3 B. 5 C. 6 D. 4 Cu 60: Cho cc phn ng sau
t X + 2NaOH 2Y + H2O (1) Y + HCl (long) Z + NaCl (2) Bit X l cht hu c c cng thc phn t C6H10O5. Khi cho 0,1 mol Z tc dng ht vi Na (d) th s mol H2 thu c l A. 0,20 B. 0,15 C. 0,10 D. 0,05
0

1 A 21 C 41 D

2 C 22 C 42 D

3 B 23 B 43 D

4 B 24 B 44 A

5 B 25 A 45 B

6 D 26 A 46 C

7 D 27 C 47 A

8 A 28 A 48 A

9 C 29 D 49 D

10 A 30 D 50 B

11 C 31 D 51 C

12 D 32 B 52 C

13 B 33 A 53 B

14 A 34 B 54 C

15 B 35 B 55 C

16 C 36 D 56 D

17 D 37 C 57 A

18 A 38 D 58 C

19 A 39 D 59 B

20 A 40 B 60 C

P N PHN 2 1 C 21 D 41 A 61 D 81 D 101 C 121 B 141 2 C 22 A 42 A 62 B 82 A 102 C 122 A 142 3 C 23 B 43 C 63 B 83 C 103 A 123 B 143 4 C 24 A 44 A 64 D 84 C 104 A 124 B 144 5 D 25 C 45 C 65 B 85 A 105 D 125 B 145 6 A 26 C 46 B 66 A 86 B 106 B 126 C 146 7 C 27 A 47 B 67 C 87 B 107 D 127 D 147 8 B 28 C 48 B 68 C 88 C 108 D 128 C 148 9 C 29 C 49 C 69 A 89 C 109 A 129 D 149 10 A 30 B 50 C 70 D 90 C 110 C 130 B 150 181 11 C 31 B 51 A 71 B 91 A 111 C 131 D 151 12 C 32 C 52 D 72 A 92 C 112 A 132 C 152 13 D 33 B 53 D 73 C 93 C 113 C 133 C 153 14 B 34 B 54 A 74 A 94 D 114 A 134 D 154 15 B 35 A 55 A 75 B 95 B 115 C 135 B 155 16 B 36 B 56 B 76 A 96 B 116 D 136 D 156 17 C 37 B 57 D 77 B 97 B 117 C 137 D 157 18 B 38 A 58 D 78 A 98 C 118 C 138 B 158 19 A 39 B 59 A 79 A 99 D 119 A 139 D 159 20 B 40 B 60 A 80 C 100 A 120 B 140 A 160

A 161 A 181 B 201 B 221 A 241 D 261 D 281 B 301 A 321 C 341 C 361 B 381 C 401 A 421 A 441 D 461 B 481 D 501 A 521 C 541

A 162 C 182 B 202 C 222 A 242 B 262 D 282 C 302 B 322 B 342 D 362 B 382 C 402 B 422 D 442 B 462 D 482 B 502 C 522 D 542

C 163 A 183 A 203 B 223 C 243 C 263 B 283 A 303 A 323 D 343 C 363 B 383 B 403 A 423 D 443 D 463 A 483 C 503 D 523 D 543

C 164 D 184 B 204 D 224 B 244 D 264 A 284 D 304 D 324 B 344 B 364 A 384 B 404 C 424 A 444 C 464 B 484 A 504 C 524 B 544

D 165 B 185 D 205 C 225 A 245 C 265 A 285 D 305 D 325 D 345 D 365 A 385 B 405 C 425 C 445 C 465 B 485 C 505 D 525 A 545

A 166 B 186 B 206 D 226 D 246 B 266 D 286 C 306 B 326 B 346 C 366 D 386 C 406 C 426 A 446 C 466 A 486 D 506 C 526 B 546

B 167 C 187 C 207 A 227 D 247 B 267 B 287 C 307 C 327 C 347 C 367 B 387 B 407 A 427 C 447 A 467 A 487 D 507 A 527 B 547

D 168 C 188 A 208 A 228 D 248 D 268 A 288 A 308 B 328 D 348 B 368 D 388 A 408 B 428 C 448 B 468 B 488 D 508 A 528 C 548

C 169 A 189 C 209 C 229 C 249 C 269 D 289 A 309 C 329 C 349 A 369 B 389 C 409 D 429 A 449 C 469 B 489 B 509 A 529 A 549

B 170 D 190 D 210 A 230 B 250 C 270 A 290 B 310 C 330 A 350 C 370 B 390 D 410 C 430 A 450 D 470 C 490 D 510 C 530 B 550 182

B 171 B 191 D 211 A 231 B 251 A 271 C 291 D 311 C 331 A 351 B 371 A 391 B 411 B 431 A 451 C 471 A 491 C 511 D 531 C 551

B 172 C 192 D 212 D 232 D 252 D 272 D 292 B 312 D 332 B 352 D 372 B 392 A 412 B 432 A 452 B 472 C 492 C 512 B 532 B 552

D 173 A 193 C 213 C 233 A 253 C 273 A 293 C 313 B 333 A 353 C 373 C 393 B 413 A 433 D 453 A 473 D 493 D 513 C 533 A 553

D 174 B 194 C 214 A 234 B 254 C 274 C 294 A 314 C 334 D 354 D 374 A 394 D 414 B 434 A 454 B 474 B 494 A 514 B 534 A 554

C 175 A 195 B 215 C 235 A 255 B 275 C 295 D 315 D 335 C 355 D 375 A 395 B 415 C 435 D 455 A 475 A 495 C 515 B 535 C 555

C 176 C 196 D 216 A 236 C 256 C 276 B 296 B 316 B 336 B 356 C 376 A 396 A 416 D 436 A 456 C 476 C 496 B 516 B 536 B 556

A 177 C 197 D 217 D 237 C 257 A 277 D 297 C 317 D 337 C 357 D 377 B 397 C 417 D 437 C 457 A 477 C 497 A 517 B 537 A 557

A 178 A 198 C 218 B 238 D 258 C 278 D 298 D 318 C 338 D 358 A 378 C 398 D 418 D 438 A 458 A 478 C 498 A 518 D 538 A 558

A 179 D 199 C 219 D 239 A 259 D 279 D 299 A 319 D 339 C 359 D 379 B 399 B 419 A 439 B 459 A 479 A 499 B 519 D 539 C 559

C 180 A 200 A 220 A 240 D 260 C 280 B 300 C 320 C 340 C 360 A 380 C 400 C 420 A 440 D 460 D 480 B 500 B 520 A 540 A 560

D 561 A 581 B 601 A 621 A 641 A 661 D 681 B 701 B 721 D 741 B 761 A 781 C 801 B

B 562 C 582 A 602 D 622 C 642 D 662 C 682 D 702 B 722 C 742 B 762 C 782 B 802 A

C 563 A 583 A 603 D 623 D 643 A 663 C 683 B 703 A 723 D 743 B 763 A 783 C 803 A

A 564 A 584 B 604 C 624 A 644 B 664 D 684 A 704 B 724 C 744 D 764 B 784 B 804 C

D 565 C 585 B 605 A 625 B 645 B 665 C 685 D 705 B 725 B 745 A 765 D 785 A 805 D

A 566 C 586 D 606 D 626 D 646 B 666 C 686 C 706 C 726 D 746 D 766 B 786 C 806 C

C 567 B 587 A 607 B 627 D 647 C 667 C 687 C 707 A 727 D 747 A 767 C 787 D 807 B

A 568 D 588 A 608 A 628 A 648 B 668 C 688 B 708 B 728 C 748 A 768 A 788 B 808 D

C 569 D 589 D 609 D 629 C 649 C 669 A 689 B 709 C 729 B 749 A 769 D 789 B 809 A

C 570 A 590 C 610 B 630 A 650 D 670 D 690 B 710 D 730 D 750 D 770 A 790 D

A 571 A 591 D 611 B 631 D 651 A 671 C 691 A 711 A 731 D 751 C 771 D 791 A

A 572 A 592 B 612 D 632 B 652 D 672 B 692 D 712 D 732 A 752 B 772 C 792 C

C 573 D 593 C 613 A 633 B 653 D 673 D 693 D 713 C 733 D 753 A 773 D 793 B

D 574 C 594 B 614 D 634 C 654 B 674 C 694 A 714 B 734 D 754 A 774 C 794 D

B 575 B 595 D 615 B 635 D 655 C 675 C 695 B 715 B 735 A 755 D 775 B 795 C

D 576 B 596 A 616 D 636 B 656 B 676 A 696 B 716 C 736 D 756 D 776 C 796 A

A 577 D 597 C 617 A 637 D 657 B 677 D 697 A 717 C 737 C 757 B 777 C 797 C

A 578 A 598 A 618 A 638 C 658 A 678 C 698 C 718 A 738 C 758 D 778 D 798 D

A 579 D 599 D 619 B 639 C 659 D 679 C 699 D 719 D 739 D 759 C 779 A 799 A

A 580 A 600 B 620 D 640 D 660 A 680 C 700 D 720 A 740 D 760 B 780 D 800 D

MC LC Phn 1: Mt s phng php gii ton A.Qui i hn hp nhiu cht thnh s lng cht t hn gim n s v phng trnh phn ng trong cc bi ton v c B. Qui i hn hp nhiu cht thnh s lng cht t hn gim n s v phng trnh phn ng trong cc bi ton hu c Phn 2: Gii thi i hc- cao ng t nm 2007 n 2011 theo tng chng ca cc lp 10, 11, 12 1.Nguyn t, bng tun hon cc nguyn t ha hc, lin kt ha hc 2.Phn ng oxi ha kh, tc phn ng v cn bng ha hc 3.S in li 4.Phi kim (cacbon, silic, nit, photpho, oxi, lu hunh, halogen)
183

5.i cng v kim loi 6.Kim loi kim, kim loi kim th, nhm, st, crom, ng. Ha hc v cc vn pht trin kinh t, x hi v mi trng 7.Tng hp ni dung cc kin thc ha v c thuc chng trnh ph thng 8.i cng ha hu c, hidrcacbon 9.Dn xut Halogen, ancol, phenol 10.Andehyt, xeton, axit cacboxylic 11.Este, lipit 12.Amin, amino axit v protein 13.Cacbohidrat 14.Polime v vt liu polime 15.Tng hp ni dung kin thc ha hu c thuc chng trnh ph thng Phn 3: Gii trn vn mt thi trong 90 pht 1 v p n 2 v p n 3 v p n 3 v p n 4 v p n 5 v p n 6 v p n 7 v p n 7 v p n 8 v p n 9 v p n 10 v p n 11 v p n 12 v p n 13 v p n 14 v p n 15 v p n 16 v p n 17 v p n 18 v p n 19 v p n 20 v p n thi H khi A ,B v C nm 2012- p n p n phn 2

184