BI TP HU C 1.

Dn 1,68 lt hn hp kh X gm CH4, C2H4 v H2 i qua mt bnh cha dung dch nc Br2, nhn thy dung dch b nht mu mt phn v khi lng dung dch tng thm 0,42 gam. a/ Xc nh % th tch cc kh trong hn hp X, bit rng 0,7 lt hn hp kh ny nng 0,4875 gam. b/ t chy hon ton 1,68 lt kh X ri hp th ton b sn phm to thnh bng 1 lt dung dch Ca(OH) 2 0,05M (khi lng ring l 1,025 g/ml). Tnh C% ca cc cht trong dung dch sau th nghim. Bit rng cc phn ng xy ra hon ton, cc th tch kh u o ktc. 2. a. Hn hp kh X gm mt hircacbon A mch h v H 2. t chy hon ton 8 gam X thu c 22 gam kh CO2. Mt khc 8 gam X tc dng va vi 250 ml dung dch Br2 1M. Xc nh CTPT ca A v tnh thnh phn % v th tch ca mi cht trong X. b. Hn hp kh Y gm mt hircacbon B mch h v H 2 c t khi so vi mtan bng 0,5. Nung nng hn hp Y c bt Ni lm xc tc n phn ng hon ton thu c hn hp kh Z c t khi so vi oxi bng 0,5. Xc nh CTPT ca B, Tnh thnh phn % theo th tch ca mi cht trong hn hp Y. c. t chy 1 lt hn hp gm 2 Hir cacbon th kh thu c 1,6 lt kh CO 2 v 1,4 lt hi nc. Cc th tch o cng iu kin nhit v p sut. Xc nh 2 cht v thnh phn % v s mol ca mi cht trong hn hp. 3. t chy hon ton 3,24 gam hn hp X gm 2 cht hu c (A) v (B) khc dy ng ng, trong (A) hn (B) mt nguyn t cacbon, ngi ta ch thu c H 2O v 9,24 gam CO2. Bit t khi hi ca X i vi H2 l dX/H2 = 13,5. Tm cng thc ca (A), (B) v tnh thnh phn % theo khi lng ca mi cht trong X. 4. t chy hon ton mt hir cacbon(X), thu c 6,72 lt CO 2 v 5,4g H2O. Bit 1 lt kh (X) nng 1,26g (th tch cc kh u o iu kin tiu chun). a/ Xc nh cng thc phn t ca hir cacbon(X). b/ Vit cc phng trnh iu ch poli etilen; ru etylic; axt axtic t (X) v ghi r iu kin. 5. t chy hon ton a gam hp cht hu c B (c to bi 2 loi nguyn t) ri hp th ht sn phm chy (gm CO2 v hi nc) bng cch dn hn hp ln lt i qua bnh 1 ng dung dch NaOH, bnh 2 ng dung dch H2SO4 c. Sau th nghim thy khi lng cc bnh 1 v 2 tng thm tng ng l 24,16g v 8,64g. Lng Oxi tiu tn ng bng lng Oxi to ra khi nhit phn hon ton 252,8g KMnO 4. a. Tnh a v xc nh cng thc phn t ca B. b. Khi cho B tc dng vi Clo ch to ra hn hp 2 dn xut ca B c cng khi lng mol bng 141g. Vit cng thc cu to ca B v ca cc dn xut Clo. 6. Mt hn hp gm 2 ankan c khi lng l 10,2 gam. t chy hon ton hn hp ankan ny cn dng 25,8 lt O2 (ktc). a/ Tm tng s mol ca 2 ankan. b/ Tm khi lng CO2 v H2O to thnh. c/ Tm cng thc phn t ca ankan bit rng phn t khi mi ankan khng qu 60. d/ Tnh khi lng ca mi ankan trong hn hp. 7. Cho 6,72 lt (ktc) hn hp kh A gm 2 hirocacbon mch h. Chia lm 2 phn bng nhau: Dn phn 1 qua dung dch Br2 d, khi lng dung dch tng a gam, lng Br2 phn ng ht 32 gam khng c kh thot ra khi dung dch. t chy phn 2 v cho sn phm chy qua bnh ng P2O5. Sau cho qua KOH rn. Sau th nghim bnh ng P2O5 tng b gam v bnh ng KOH tng 17,6 gam. a/ Tm cng thc phn t ca 2 hirocacbon. b/ Tnh % V cc kh trong A. c/ Tnh cc gi tr a, b. 8. Hn hp kh X gm mt ankan v mt anken. Cho 6,72 (l) hn hp X qua bnh nc brom d thy c 16(g) brm tham gia phn ng. Bit 11,2 (l) hn hp X nng 21,66(g). a, Tm cng thc phn t ca ankan v anken. b, t chy hon ton 6,72 (l) hn hp X v cho tt c sn phm chy hp th vo dung dch NaOH (d), sau thm BaCl2 d th thu c bao nhiu (g) cht kt ta? (Bit th tch cc kh u c o ktc) c, T anken trn hy vit phng trnh phn ng iu ch glyxrin (C3H5(OH)3).

9. t chy hon ton hn hp (A) gm 2 hircacbon (X), (Y) mch h, cng dy ng ng. Hp th ton b sn phm vo 4,5 lt dung dch Ca(OH)2 0,02M, thu c kt ta v khi lng dung dch tng 3,78 gam. Cho dung dch Ba(OH)2 d vo dung dch thu c, kt ta li tng thm, tng khi lng kt ta 2 ln l 18,85 gam. T khi hi ca hn hp (A) i vi Heli nh hn 10. Hy xc nh cng thc cu to ca (X), (Y). Bit rng s mol ca (X) bng 60% tng s mol ca (X), (Y) c trong hn hp (A). Cc phn ng xy ra hon ton. 10. Hn hp kh A gm C2H2 v H2 c khi lng 5,8 gam v c th tch l 11,2 lt ( ktc). Dn hn hp A qua ng ng Ni nung nng, thu c hn hp kh B. Cho B qua bnh ng dung dch Br 2 d, thu c hn hp kh thot ra X. t chy hon ton X ri cho ton b sn phm vo bnh cha dung dch Ca(OH)2 d thu c 24 gam kt ta v khi lng bnh tng ln 17,4 gam. a/ Xc nh th tch ca tng kh trong hn hp A ( ktc). b/ Tnh tng khi lng ca bnh ng dung dch brm. c/ Tnh thnh phn % v s mol cc kh trong hn hp B. 11. t chy hon ton mt lng cht hu c A cn 6,72 lt oxi (ktc). Cho ton b sn phm to thnh (ch gm CO2, H2O) vo mt lng nc vi trong, sau khi kt thc phn ng thu c 10 gam kt ta v 200 ml dung dch mui c nng 0,5M, khi lng dung dch mui ny nng hn khi lng nc vi trong em dng l 8,6 gam. Hy xc nh cng thc phn t hp cht hu c A. Bit 40 < M A < 74. 12. t chy hon ton V lit hn hp kh gm a gam hiro cacbon A v b gam hiro cacbon B (mch h). Ch thu c 35,2 gam CO2 v 16 gam H2O. Nu thm vo V lt X mt lng a/2 gam A c hn hp kh Y, t chy hon ton Y ch thu c 48,4 gam CO2 v 23,4 gam H2O. Xc nh cng thc phn t A, B. 13. Cho hn hp X gm Ca v CaC2 vo nc d c hn hp kh Y. Cho hn hp kh Y qua bnh cha Ni nung nng c hn hp kh Z gm 4 cht. Cho hn hp kh Z qua bnh ng dung dch Br 2 d, ri t chy hon ton hn hp kh thot ra khi bnh. Vit cc phng trnh ho hc xy ra trong cc th nghim trn. 14. t chy hon ton hn hp cha 2 hiro cacbon A, B. Sn phm thu c ln lt cho qua bnh (1) ng H2SO4 c, khi lng bnh tng 3,24 gam, bnh (2) ng dung dch Ca(OH) 2 d, to thnh 16 gam cht rn. Xc nh CTPT ca cc hiro cacbon. Bit rng s mol ca A, B c trong hn hp bng nhau v s mol CO 2 c to ra t phn ng chy ca A v B bng nhau. 15. Cho 2 hn hp kh A1 v A2 iu kin thng, mi hn hp gm H2 v mt hircacbon mch h bt k. Khi t chy 6 gam hn hp A1 to ra 17,6 gam CO2, mt khc 6 gam A1 lm mt mu c 32 gam brm trong dung dch. Hn hp A2(cha H2 d) C t khi hi i vi H2 l 3. Cho A2 qua ng ng Ni nung nng(gi thit hiu sut 100%), to ra hn hp B c t khi so vi H2 l 4,5. a. Tnh thnh phn % th tch cc kh trong A1 v A2. b. Tm cng thc phn t ca hai hircacbon trong A1 v A2. 16. Ngi ta t chy mt hidrcacbon no bng O2 d ri dn sn phm chy i ln lt qua H 2SO4 c ri n 350ml dung dch NaOH 2M thu c dung dch A. Khi thm BaCl 2 d vo dung dch A thy tc ra 39,4gam kt ta BaCO3 cn lng H2SO4 tng thm 10,8gam. Hi hir cc bon trn l cht no ?