Nguyn Th Hoi 0979495156 ; 0973857103 FB : Thien Kiem

Bi tp anken
1- ng phn cu to
Cc anken c ng phn mch cacbon v ng phn vO v trY n .
2- ng phn hnh hc
Nu ha nhm th to nn mch chYnh nm vO cng phYa so v n g ng phn cis, nu
nm vO ha phYa so v n g ng phn trans.
V d 1: Vt cc ng phn hnh hc ca buten-2 (CH
3
- CH = CH - CH
3
)
H H H CH
3
C = C C = C
CH
3
CH
3
cis-buten-2 CH
3
H trans-buten -2
V d 2: Vt cc ng phn hnh hc ca penten-2 (CH
3
-CH= CH-CH
2
-CH
3
)
H H H C
2
H
5
C = C C = C
CH
3
C
2
H
5
cis-penten-2 CH
3
H trans-penten -2
II- Danh php
1- Tn thng:
Tn anken = Tn ankan tng ng, u an thnh u ilen
VY d: C
2
H
4
: eten
C
3
H
6
: propen
2- Tn quc t:
- Chn mch cacbon d nhEt cha n m mch chYnh.
- nh s th t cc nguyn t cacbon trong mch chYnh, bt u t u mch gn n hn.
- Tn Anken = V trY nhm th+Tn nhm th + Tn mch chYnh (tn quc t ca anken t ng
ng)+ v trY n .
VY d:
CH
3
-CH
2
- CH = CH
2
: buten-1
CH
3
-CH
2
= CH
2
- CH
3
: buten-2
CH
3
-CH- CH = CH
2
: 3-metybuten-1.
CH
3

C- Tnh cht ho hc
I- Phn ng cng
1- !h"n #ng c$ng hi%ro an&an
CH
2
= CH
2
+ H
2
CH
3
- CH
3

CH
3
- CH

= CH
2
+ H
2
CH
3
- CH
2
- CH
3
2- !h"n #ng c$ng 'r
2
, ()
2
Phn ng tn hnh theo 2 ga on:
CH
2
= CH
2
+ Br
2
Br - CH
2
- CH
2
- Br
CH
3
- CH

= CH
2
+ Br
2
CH
3
- CH - CH
2
Br Br
Phn ng m mEt mu da cam ca dung dch brom. Co cng phn ng tng t.
T*ng qu+t:
C
n
H
2n
+ Br
2
C
n
H
2n
Br
2
,- !h"n #ng c$ng a-it: .(), .'r, ./
CH
2
= CH
2
+ H-C CH
3
- CH
2
- C
ety corua
Phn ng cng axt tun theo qu tc Maccopnhcop:
Nhng g chng ta bit ngy hm nay s li thi vo ngy hm sau. Nu chng ta ngng hc th chng ta s ngng pht ti!n

N,
t
o

N,
t
o
Nguyn Th Hoi 0979495156 ; 0973857103 FB : Thien Kiem
CH
3
-CH-CH
3
(sn phEm chYnh)
CH
3
-CH = CH
2
+ H- Br Br
CH
3
-CH
2
-CH
2
-Br (sn phEm ph)
0- !h"n #ng c$ng n1c
CH
2
=CH
2
+ H-OH CH
3
-CH
2
-OH
Phn ng cng nc tun theo qu tc Maccopnhcop:
CH
3
-CH-CH
3
(sn phEm chYnh)
CH
3
-CH = CH
2
+ H-OH OH
CH
3
-CH
2
-CH
2
-OH (sn phEm ph)
II- Phn ng trng hp
Ou trnh cng hp n tp nhOu phn t nh (monome) to thnh phn t n (pome) c g
phn ng trng hp.
- Poeten (PE):
n CH
2
= CH
2
(- CH
2
- CH
2
-)
n

- Popropyen:
n CH
2
= CH (- CH
2
- CH -)
n
CH
3
CH
3
III- Phn ng ch!
C
n
H
2n
+
"
#n
O
2
n CO
2
+ n H
2
O
D- "i#$ ch%
1- !h2ng ph+p crac&inh
CH
3
-CH
2
- CH
3
CH
4
+ CH
2
= CH
2
CH
4
+ C
3
H
6

CH
3
-CH
2
- CH
2
- CH
3

C
2
H
6
+ C
2
H
4

2- !h2ng ph+p t+ch hi%ro 345hi%ro ho+6
CH
3
-CH
2
- CH
3
CH
3
- CH = CH
2
+ H
2
2- !h2ng ph+p t+ch n1c t7 r8u
CH
3
-CH
2
- OH CH
2
= CH
2
+ H
2
O
Phn ng tch nc tun rheo qu tc Zaxep: Nhm -OH b tch cng v nguyn t H nguyn t
cacbon bn cnh c bc cao hn.
CH
3
-CH=CH-CH
3
+ H
2
O (sn phEm chYnh)
CH
3
-CH- CH
2
- CH
3

OH CH
3
-CH
2
-CH=CH
2
+ H
2
O (sn phEm ph)
Dng 1: !i"# $%ng &h'n ( g)i #*n
Bi 1. $it %&ng ph'n v gi t(n an)*n c+ ,-.-/ ,0123 ,41563 ,715"
Bi +. $it %&ng ph'n v gi t(n h8p ch9t hu c: c+ ,-.-/ ,0123 ,41563 ,715"
,'u #/;n)*n l hi%o cacbon c+ /
a.cng th<c chung ,n1"n b.m=t li(n )t pi.
c.mt lin kt i,mch h, >.m=t li(n )t ba3m?ch h@
,'u 0/,1"A ,1B,1"B,1# c+ t(n gi thng thCng l /
a.butil*n -,-butilen c.DBbutil*n >.butB5B*n
,'u 4/,1#B,1A,1B,1# c+ t(n gi Ethay th E l /
Nhng g chng ta bit ngy hm nay s li thi vo ngy hm sau. Nu chng ta ngng hc th chng ta s ngng pht ti!n
H
+
H
+

H
+
Trng hp
xt ,
t
o

crackn

crackn
xt,
t
o
H2SO4 c
170
o
C
H2SO4 c
170
o
C
Nguyn Th Hoi 0979495156 ; 0973857103 FB : Thien Kiem
a.butil*n b.FBbutil*n c.DBbutil*n d.but-2-en
,'u7/ GH %&ng ph'n <ng vIi cng th<c ,012 l /
a.# b.4 c.6 >.J
,'u J/ an)*n ,012 c+ sH %&ng ph'n cKng ch<c l /
a.# b.4 c.7 >.J
,'u 2/ an)*n ,012 c+ sH %&ng ph'n c9u t?o cKng ch<c l /
a.3 b.0 c.7 >.J
,'u5"/ butB5B*n v cc butB"B*n l cc %&ng ph'n/
a.m?ch cacbon b.v t!" lin kt i, c.cisBtans. >.nh+m ch<c.
.'u 13 /0H107123: 1i%at h+a " an)*n chL t?o thnh " ancol MC8uN. 1ai an)*n %+ l
2, "Bm*tylpop*n v butB5B*n MhoOc but*nB5N. B, pop*n v butB"B*n MhoOc but*nB"N.
., *t*n v butB"B*n MhoOc but*nB"N. D, *t*n v butB5B*n MhoOc but*nB5N.
Bi 13/ Vt cng th<c c9u t?o cPa cc ch9t sau:
a/ 2,3-dmetypent-1- en :b/ 3-metypent-2-en ; c/

-buten :d) sobuten :e) metypropen

D&ng '( )on thnh ptp
B 4 : Hon thnh s phn ng sau :
a) C
2
H
4

C
2
H
6

C
2
H
4

,
"
1
4
,l

C
2
H
4

C
2
H
5
OH

C
2
H
4

PE
Eten gco
b) C
4
H
10

C
3
H
6

C
3
H
7
Br

C
3
H
7
OH

C
3
H
6

C
3
H
6
Br
2

| C
3
H
6
(OH)
2
D&ng *( Bi ton +,t ch! anken- T./ CTPT c0a anken
Qi 5/RHt chy m gam 5 hi>ocacbon S thu %C8c "370gam ,T
"
v 5632gam 1
"
T
aNSR ,-.- cPa S Mbit tL )hHi h:i cPa S so vIi 1"A0"N bN -Unh m
Qi "/ RHt chy hon ton 55"cm
#
5 hi>ocacbon ; M l ch9t )hU3 %)tcN &i >Vn sWn phXm lYn lC8t Zua bnh 5 %[ng
1
"
GT
0 %Oc
v bnh " ch<a NaT1 >C ngCi ta th9y )hHi lC8ng bnh 5 t\ng 6352g v )hHi lC8ng bnh " t\ng 6300gam.
SR ,-.- cPa ;
Qi #/ RHt chy ht 635mol 5 hi>ocacbon ; m?ch h@ thu %C8c ""g ,T
"
v ] gam 1
"
T
aN SR ,-.- cPa ; $it ,-,- v gi t(n cc %&ng ph'n m?ch h@ cPa ;
Qi 0/ RHt chy hon ton 5 hi>ocacbon S m?ch h@ c+ >S^)
"
_ 5" cYn 56362 lit T
"
@ %)tc thu %C8c 73J"lit ,T
"
M%)cN. SR ,-.- cPa S.
Qi 4/ RHt chy hon ton "3722litM%)cN m=t an)*n S v h9p th` ht sWn phXm chy Zua bnh %[ng nCIc vi tong
>C th9y )hHi lC8ng bnh t\ng th(m #53]"gam. SR ,-.- cPa S
Qi 7/ RHt chy hon ton 635mol an)*n ; cYn va %P J37gam T
"
. ,ho ton b= sWn phXm Zua bnh %[ng QaMT1N
"
th9y )hHi lC8ng bnh QaMT1N
"
t\ng 5630gam. SR ,-.-3 ,-,- cPa ;
D&ng 1( Bi ton 2nken 3 44 Bro/5
B6i 7( Cho 2,8 g 1 anken X tc dng va v 16 g Brom
b/ Tm CTPT ca A. Vt CTCT cPa t9t cW cc %&ng phn c9u t?o <ng vI CTPT tm %C8c.
B6i '( Cho 4,2 g 1 anken X tc dng va v 100m dd Brom1M.
a) Nu hn tng xy ra v vt ptpu Tm CTPT ca A
B 3/ 0,7 gam m=t anken A c th! m m9t mu 16,0 gam dung dach brom(trong CC
4
) c
n&ng %= 12,5%.
a/ Xc %anh cng th<c phn tb ch9t A
b/ Vt CTCT cPa t9t cW cc %&ng phn c9u t?o <ng vI CTPT tm %C8c.
Bi */ DVn t t 3,36 Yt hn h8p g&m eten v propen(%ktc)vo dung dach brom th9y dung
dach ba nh?t mu v khng c khY thot ra. khH C8ng dung dach sau phWn <ng t\ng 4,90
gam.
a/ Vt cc PTHH v gW thYch cc hcn tC8ng @ thY nghcm trn ?
b/ TYnh thnh phYn % vd th! tYch cPa m khY trong hen h8p ban %Yu ?
Bi 1/ DVn t t 5,04 Yt hn h8p g&m eten v propen(%ktc)vo dung dach brom th9y dung
dach ba nh?t mu v khng c khY thot ra. khH C8ng dung dach sau phWn <ng t\ng 7,35
gam.
a/ Vt cc PTHH v gW thYch cc hcn tC8ng @ thY nghcm trn ?
b/ TYnh thnh phYn % vd th! tYch cPa m khY trong hen h8p ban %Yu ?
B 6 : Cho 8,96 t metan v eten qua dd Brom d, thEy dd b nht mu v c 2,24 t
khY thot ra ktc
a) Vt ptp cho bt khY no thot ra. TYnh % kh ng m khY trong hn hp
B 6 : Cho 4,48 t (ktc) metan v eten qua dd Brom d, thEy bnh Brom tng 2,8 g
Nhng g chng ta bit ngy hm nay s li thi vo ngy hm sau. Nu chng ta ngng hc th chng ta s ngng pht ti!n
|
Nguyn Th Hoi 0979495156 ; 0973857103 FB : Thien Kiem
b) a) Vt ptpu TYnh % kh ng, % thO tYch m khY trong hn hp
Bi 89 Hro ho hon ton 1 mu oefn ht 448 m H
2
(ktc) thu c mt ankan
phn nhnh. Cng ng oefn kh td v brom to thnh 4,32 gam dn xuEt brom. X
CTCT v g tn oefn cho. Cc p xay ra hon ton
Bi 7:/ Mt hh khY gm 1 ankan v 1 anken c cng s nguyn t C trong phn t v
cng s mo va m mEt mu 80 g dd Brom. t chy hon ton hh trn to ra 13,44 t
CO
2
(ktc)
a. X CTCT ca ankan v anken cho b. Xc nh t kh ca hh so khng khY
.'u 7/0H1081B3: fVn 5372 lUt hn h8p )hU S g&m hai hi%ocacbon vo bnh %[ng >ung >ach bom M>CN. Gau )hi
phWn <ng gWy a hon ton3 c+ 0 gam bom %h phWn <ng v cin l?i 535" lUt )hU. Nu %Ht chy hon ton 5372 lUt S
th sinh a "32 lUt )hU ,T". ,ng th<c ph'n tb cPa hai hi%ocacbon l Mbit cc th! tUch )hU %du %o @ %)tcN
2, ,10 v ,"10. B, ,10 v ,#10. ., ,10 v ,#17. D, ,"17 v ,#17.
,'u##/ ;n)*n c+ nhidu tUnh ch9t )hc vIi an)an nhC / phWn <ng c=ng3tKng h8p3ogi h+a l >o tong ph'n tb an)*n
c+ ch<a/
a.li(n )t gichBma bdn. b.li(n )t pi MjN.
c.li(n )t pi MjN bdn . d..lin kt pi km bn .
,'u#0/ R! ph'n bict pop*n vIi popan 3ta >Kng /
a.>ung >ach bom b.>ung >ach thuHc tUm
c.>ung >ach bom tong ,,l0 d.c a,b,c.
,'u#4/ ,h9t tc >`ng vIi 1,l MhoOc 1Q31k31"GT0N t?o a " sWn phXm l/
a.*til*nb.butB"B*n c.isobutil*n d.propen.
,'u#7/ 1n h8p )hU pop*n v but*n tc >`ng vIi 1,l t?o a 0 sWn phXm 3cng th<c c9u t?o cPa but*n l/
a.,1"A ,1B,1"B,1# b.,1#B,1A,1B,1# c.,1A,1B ,1# >.,1" A ,B ,1#
,'u#J/ butB5B*n tc >`ng vIi 1Q t?o a sWn phXm chUnh l/
a.5Bclobut*n b.5Bclobut*n c.5Bclobutan d.2-clobutan
,'u#2/ -h*o Zui tlc macBcopBnhiBcop 3tong phWn <ng c=ng agit hoOc nCIc vo nHi %i cPa an)*n th phYn mang
%icn >C:ng c=ng vo /
a.cacbon bnc cao h:n b.cacbon bnc th9p h:n
c.cacbon mang ni i ,bc thp h!n>.cacbon mang nHi %i 3c+ Ut 1 h:n
,'u#]/ GWn phXm tKng h8p *til*n l /
a.poliM*til*nN b.polietilen c.poli*pil*n
.'u 14/0H108123: ,ho cc ch9t sau/ ,1
"
A,1B,1
"
B,1
"
B,1A,1
"
3 ,1
"
A,1B,1A,1B,1
"
B,1
#
3 ,1#B
,M,1#NA,1B,1#3 ,1"A,1B,1"B,1A,1". GH ch9t c+ %&ng ph'n hnh hc l/
2, #. B, ". ., 5. D, 0.
.'u +/0H1091B3: 1n h8p )hU S g&m 1" v m=t an)*n c+ )hW n\ng c=ng 1Q cho sWn phXm hu c: >uy nh9t. -L
)hHi cPa S so vIi 1" bong ]35. Run n+ng S c+ gc tc Ni3 sau )hi phWn <ng gWy a hon ton3 thu %C8c hn h8p
)hU p )hng lm m9t mu nCIc bomq tL )hHi cPa p so vIi 1" bong 5#. ,ng th<c c9u t?o cPa an)*n l
2, ,1"A,M,1#N". B, ,1"A,1". ., ,1"A,1B,1"B,1#. D, ,1#B,1A,1B,1#.
.'u +/.01093: 1n h8p )hU S g&m 1
"
v ,
"
1
0
c+ tL )hHi so vIi 1* l #3J4. fVn S Zua Ni nung n+ng3 thu %C8c
hn h8p )hU p c+ tL )hHi so vIi 1* l 4. 1icu su9t cPa phWn <ng hi%o ho l 2, "6r. B, "4r. ., 46r. D,
06r.
.'u 4/.01093: R! )hb hon ton "66 ml >ung >ach smnT
0
63"m t?o thnh ch9t ln mu n'u %*n cYn $ lUt )hU
,
"
1
0
M@ %)tcN. ti ta tHi thi!u cPa $ l 2, "3"06. B, "3722. ., 03026. D, 53#00.
.'u 8/.01093: ,ho cc ch9t/ giclobutan3 "Bm*tylpop*n3 butB5B*n3 ci"BbutB"B*n3 "Bm*tylbutB"B*n. fhy g&m cc
ch9t sau )hi phWn <ng vIi 1" M>C3 gc tc Ni3 t
o
N3 cho cKng m=t sWn phXm l/
2, giclobutan3 ci"BbutB"B*n v butB5B*n. B, butB5B*n3 "Bm*tylpop*n v ci"BbutB"B*n.
., giclobutan3 "Bm*tylbutB"B*n v butB5B*n. D, "Bm*tylpop*n3 ci"BbutB"B*n v giclobutan.
.'u 13/.01093: ,ho cc ch9t/ ,1
"
A,1u,1A,1
"
q ,1
#
u,1
"
u,1A,M,1
#
N
"
q ,1
#
u,1A,1u,1A,1
"
q
,1
#
u,1A,1
"
q ,1
#
u,1A,1u,TT1. GH ch9t c+ %&ng ph'n hnh hc l 2, 0. B, #. ., ".
D, 5.
.'u +/.01113: ,h9t no sau %'y c+ %&ng ph'n hnh hcv
;. ,1
"
A,1B,1A,1
"
Q. ,1
#
B,1A,1B,1A,1
"
,. ,1
#
B,1A,M,1
#
N
"
f. ,1
"
A,1B,1
"
B,1
#

.'u 6/0H107123: 1i%at h+a " an)*n chL t?o thnh " ancol MC8uN. 1ai an)*n %+ l
2, "Bm*tylpop*n v butB5B*n MhoOc but*nB5N. B, pop*n v butB"B*n MhoOc but*nB"N.
., *t*n v butB"B*n MhoOc but*nB"N. D, *t*n v butB5B*n MhoOc but*nB5N.
Nhng g chng ta bit ngy hm nay s li thi vo ngy hm sau. Nu chng ta ngng hc th chng ta s ngng pht ti!n
Nguyn Th Hoi 0979495156 ; 0973857103 FB : Thien Kiem
.'u 14/0H108123: ,ho cc ch9t sau/ ,1
"
A,1B,1
"
B,1
"
B,1A,1
"
3 ,1
"
A,1B,1A,1B,1
"
B,1
#
3 ,1#B
,M,1#NA,1B,1#3 ,1"A,1B,1"B,1A,1". GH ch9t c+ %&ng ph'n hnh hc l/ 2, #. B, ". ., 5.
D, 0.
.'u +/0H1091B3: 1n h8p )hU S g&m 1" v m=t an)*n c+ )hW n\ng c=ng 1Q cho sWn phXm hu c: >uy nh9t. -L
)hHi cPa S so vIi 1" bong ]35. Run n+ng S c+ gc tc Ni3 sau )hi phWn <ng gWy a hon ton3 thu %C8c hn h8p
)hU p )hng lm m9t mu nCIc bomq tL )hHi cPa p so vIi 1" bong 5#. ,ng th<c c9u t?o cPa an)*n l
2, ,1"A,M,1#N". B, ,1"A,1". ., ,1"A,1B,1"B,1#. D, ,1#B,1A,1B,1#.
Dng 1: 0%ng $4ng5$%ng &h'n567nh &h8&:
.'u 1: ;n)*n S c+ cng th<c c9u t?o/ ,1#w ,1"w ,M,1#NA,1w,1#. -(n cPa S l
2, isoh*gan. B, #Bm*tylp*ntB#B*n. ., #Bm*tylp*ntB"B*n. D, "B*tylbutB"B*n.
.'u +: GH %&ng ph'n cPa ,012 l
2, J. B, 0. ., 7. D, 4.
.'u 3: 18p ch9t ,4156 mch h c+ bao nhi(u #n$ %h&n c'u t(v
2, 0. B, 4. ., 7. D, 56.
.'u 4: 18p ch9t ,4156 c+ bao nhi(u #n$ %h&n ankenv
2, 0. B, 4. ., 7. D, J.
.'u 5: 18p ch9t ,4156 c+ bao nhi(u #n$ %h&n c'u t(v
2, 0. B, 4. ., 7. D, 56.
.'u 6: ,ho cc ch9t sau/ "Bm*tylbutB5B*n /13 q #3#B%im*tylbutB5B*n /+3q
#Bm*tylp*ntB5B*n /33 q #Bm*tylp*ntB"B*n/43q
Nhng ch9t no l %&ng ph'n cPa nhauv
2, M#N v M0N. B, M5N3M"N v M#N. ., M5N v M"N. D, M"N3M#N v M0N.
.'u 7: 18p ch9t no sau %'y c+ %&ng ph'n hnh hcv
2, "Bm*tylbutB"B*n. B. "BcloBbutB5B*n. ., "3#B %iclobutB"B*n. D. "3# w %im*tylp*ntB"B*n.
.'u 8: Nhng h8p ch9t no sau %'y c+ %&ng ph'n hnh hc McisBtansNv
,1#,1 A ,1" /93q ,1#,1 A ,1,l /993q ,1#,1 A ,M,1#N" /9993q
,"14w,M,1#NA,M,1#Nw,"14/9!3q ,"14w,M,1#NA,,lw,1#/!3,
2, MkN3 Mk$N3 M$N. B, MkkN3 Mk$N3 M$N. ., MkkkN3 Mk$N. D, MkkN3 kkk3 Mk$N3 M$N.
.'u 9: ,ho cc ch9t sau/ ,1" A,1w ,1"w ,1"w ,1A,1"q ,1"A,1w ,1A,1w ,1" w ,1#q
,1#w ,M,1#NA,1w ,1"q ,1"A,1w ,1"w ,1A,1"q ,1# w ,1" w ,1 A ,1 w ,1" w ,1#q
,1# w ,M,1#N A ,1 w ,1" w ,1#q ,1# w ,1" w ,M,1#N A ,M,"14N w ,1M,1#N"q ,1#B,1A,1B,1#.
GH ch9t c+ %&ng ph'n hnh hc l
2, 0. B, 5. ., ". D, #.
Dng +: :h;n <ng =>ng
.'u 10: xp >`ng Zui tlc maccopnhicop vo tCng h8p no sau %'yv
2, .hWn <ng c=ng cPa Q" vIi an)*n %Hi g<ng. ., .hWn <ng c=ng cPa 1S vo an)*n %Hi g<ng.
B, .hWn <ng tKng h8p cPa an)*n. D, .hWn <ng c=ng cPa 1S vo an)*n b9t %Hi g<ng.
.'u 11: shi cho butB5B*n tc >`ng vIi >ung >ach 1Q3 th*o Zui tlc maccopnhicop sWn phXm no sau %'y l sWn phXm chUnhv
2, ,1#B,1"B,1QB,1"Q ., ,1#B,1"B,1QB,1#
B, ,1"QB,1"B,1"B,1"Q D, ,1#B,1"B,1"B,1"Q
.'u 1+: ;n)*n ,012 c+ bao nhi(u %&ng ph'n )hi tc >`ng vIi >ung >ach 1,l chL cho m=t sWn phXm hu c: >uy nh9tv
2, ". B, 5. ., #. D, 0.
.'u 13: ,ho hn h8p t9t cW cc %&ng ph'n m?ch h@ cPa ,012 tc >`ng vIi 1"T M1y3toN thu %C8c tHi %a bao nhi(u sWn phXm
c=ngv
2, ". B, 0. ., 7. D, 4
.'u 14: ,+ bao nhi(u an)*n @ th! )hU M%)tN m )hi cho mi an)*n %+ tc >`ng vIi >ung >ach 1,l chL cho m=t sWn phXm hu
c: >uy nh9tv
2, ". B, 5. ., #. D, 0.
.'u 15: 1i%at h+a " an)*n chL t?o thnh " ancol MC8uN. 1ai an)*n %+ l
2, "Bm*tylpop*n v butB5B*n MhoOc but*nB5N. B, pop*n v butB"B*n MhoOc but*nB"N.
., *t*n v butB"B*n MhoOc but*nB"N. D, *t*n v butB5B*n MhoOc but*nB5N.
.'u 16: ;n)*n thUch h8p %! %idu ch ancol sau %'y M,1# ,1"N#,BT1 l
2, #B*tylp*ntB"B*n. B, #B*tylp*ntB#B*n. ., #B*tylp*ntB5B*n. D, #3#B %im*tylp*ntB5B*n.
.'u 17: 1i%at h+a hn h8p S g&m " an)*n thu %C8c chL thu %C8c " ancol. S g&m
2, ,1" A ,1" v ,1" A ,1 B ,1#. B, ,1" A ,1" v ,1# B ,1 A ,1 B ,1#.
., ,1# B ,1 A ,1 B ,1# v ,1" A ,1 B ,1" B ,1#. f. ; hoOc ,
.'u 18: GH cOp %&ng ph'n c9u t?o an)*n @ th! )hU M%)tN thoW mhn %idu )icn/ shi hi%at ho t?o thnh hn h8p g&m ba ancol
l
2, 7. B, #. ., 4. D, 0.
.'u 19: GH cOp %&ng ph'n an)*n @ th! )hU M%)tN thoW mhn %idu )icn/ shi hi%at ho t?o thnh hn h8p g&m ba ancol l
Nhng g chng ta bit ngy hm nay s li thi vo ngy hm sau. Nu chng ta ngng hc th chng ta s ngng pht ti!n
Nguyn Th Hoi 0979495156 ; 0973857103 FB : Thien Kiem
2, 7. B, J. ., 4. D, 2.
.'u +0: 18p ch9t S c+ ,-.- ,#173 S tc >`ng vIi >ung >ach 1Q thu %C8c m=t sWn phXm hu c: >uy nh9t. $ny S l
2, pop*n. B, popan. ., ispop*n. D,gicloopan.
.'u +1: 1ai ch9t S3p m?ch h@ c+ ,-.- ,#17 v ,012 v %du tc >`ng %C8c vIi nCIc bom. S3 p l
2, 1ai an)*n hoOc gicloan)an ving # c?nh. ., 1ai an)*n hoOc gicloan)an ving 0 c?nh.
B, 1ai an)*n hoOc hai an)an. D, 1ai an)*n %&ng %zng cPa nhau.
.'u ++: -Kng h8p *t*n3 sWn phXm thu %C8c c+ c9u t?o l
2, MB,1"A,1"BNn . B, MB,1"B,1"BNn . ., MB,1A,1BNn . D, MB,1#B,1#BNn .
.'u +3: Ridu ch *til*n tong phing thU nghicm t ,"14T13 M 1"GT0 %Oc3 5J6o,N thCng lVn cc ogit nhC GT"3 ,T".
,h9t >Kng %! lm s?ch *til*n l
2, >> bom >C. B, >> NaT1 >C. ., >> Na",T# >C. D, >> smnT0 lohng >C.
.'u +4: GWn phXm chUnh cPa s[ %*hi%at h+a "Bm*tylbutanB"Bol l ch9t no v
2, #Bm*tylbutB5B*n. B, "Bm*tylbutB5*n. ., #Bm*tylbutB"B*n. D, "Bm*tylbutB"B*n.
.'u +5: 18p ch9t "Bm*tylbutB"B*n l sWn phXm chUnh cPa phWn <ng tch t ch9t no tong cc ch9t sauv
2, "BbomB"Bm*tylbutan. B, "Bm*tylbutan B"B ol.
., #Bm*tylbutanB"B ol. D, -9t cW %du %ng.
.'u +6: Tgi ho *til*n bong >ung >ach smnT0 thu %C8c sWn phXm l
2, mnT"3 ,"10MT1N"3 sT1. ., s",T#3 1"T3 mnT".
B, ,"14T13 mnT"3 sT1. D, ,"10MT1N"3 s",T#3 mnT".
Dng 3: :h;n <ng =>ng B?om5H@/@: .A5B?5BH3
.'u +7: Qa hi%ocacbon S3 p3 { l %&ng %zng ) tip3 )hHi lC8ng ph'n tb cPa { bong " lYn )hHi lC8ng ph'n tb cPa S.
,c ch9t S3 p3 { thu=c >hy %&ng %zng
2, an)in. B, an)an. ., an)a%i*n. D, an)*n.
.'u +8: ,ho #3#7 lUt hn h8p *tan v *til*n M%)tcN %i chnm Zua Zua >ung >ach bom >C. Gau phWn <ng )hHi lC8ng bnh bom
t\ng th(m "32g. GH mol *tan v *til*n tong hn h8p lYn lC8t l
2, 6364 v 635. B, 635 v 6364. ., 635" v 636#. D, 636# v 635".
.'u +9: "32 gam an)*n ; lm m9t mu va %P >ung >ach ch<a 2g Q". 1i%at h+a ; chL thu %C8c m=t ancol >uy nh9t. ; c+
t(n l
2. *til*n. B. but B "B*n. ., h*gB "B*n. D, "3#B>im*tylbutB"B*n
.'u 30: 6364 mol hi%ocacbon S lm m9t mu va %P >ung >ach ch<a 2 gam bom cho a sWn phXm c+ hm lC8ng
bom %?t 7]347r. ,ng th<c ph'n tb cPa S l
2, ,#17 . B, ,012 . ., ,4156. D, ,412.
.'u 31: fVn t t 230g hn h8p S g&m butB5B*n v butB"B*n l=i chnm Zua bnh %[ng >ung >ach Q"3 )hi )t thc phWn <ng
th9y c+ m gam bom phWn <ng. m c+ gi ta l
2, 5"g. B, "0g. ., #7g. D, 02g.
.'u 3+: fVn #3#7 lUt M%)tcN hn h8p S g&m " an)*n l %&ng %zng ) tip vo bnh nCIc bom >C3 th9y )hHi lC8ng bnh t\ng
th(m J3Jg. -hnh phYn phYn r vd th! tUch cPa hai an)*n l
2, "4r v J4r. B, ##3##r v 7737Jr. ., 06r v 76|. D, #4r v 74r.
.'u 33: 1n h8p S g&m " an)*n l %&ng %zng li(n tip c+ th! tUch 0302 lUt M@ %)tcN. Nu cho hn h8p S %i Zua bnh %[ng
nCIc bom >C3 )hHi lC8ng bnh t\ng l(n ]32g. r th! tUch cPa m=t tong " an)*n l
2, 46r B, 06r ., J6r D, 26r.
.'u 34: fVn #3#7 lUt M%)tcN hn h8p S g&m " an)*n l %&ng %zng ) tip vo bnh nCIc bom >C3 th9y )hHi lC8ng bnh t\ng
th(m J3Jg. ,-.- cPa " an)*n l
2, ,"10 v ,#17. B, ,#17 v ,012. ., ,012 v ,4156. D, ,4156 v ,715".
.'u 35: m=t hn h8p S c+ th! tUch 553" lUt M%)tcN3 S g&m " an)*n %&ng %zng ) tip nhau. shi cho S Zua nCIc Q" >C th9y
)hHi lC8ng bnh Q" t\ng 5430g. Sc %anh ,-.- v sH mol mi an)*n tong hn h8p S.
2, 63" mol ,"10 v 63# mol ,#17 B, 63" mol ,#17 v 63" mol ,012
., 630 mol ,"10 v 635 mol ,#17 D, 63# mol ,"10 v 63" mol ,#17
.'u 36: m=t hn h8p S g&m an)an ; v an)*n Q3 ; c+ nhidu h:n Q m=t nguy(n tb cacbon3 ; v Q %du @ th! )hU @ %)tc.
shi cho 73J" lUt )hU S M%)tcN %i Zua nCIc Qom >C3 )hHi lC8ng bnh bom t\ng l(n "32gq th! tUch )hU cin l?i chL bong "^# th!
tUch hn h8p S ban %Yu. ,-.- cPa ;3 Q v )hHi lC8ng cPa hn h8p S l
2, ,0156 3 ,#17q 432g. B, ,#12 3 ,"10 q 432g.
., ,0156 3 ,#17 q 5"32g. D, ,#12 3 ,"10 q 5537g.
.'u 37: m=t hn h8p S g&m an)an ; v m=t an)*n Q c+ cKng sH nguy(n tb , v %du @ th! )hU @ %)tc. ,ho hn h8p S %i
Zua nCIc Q" >C th th! tUch )hU p cin l?i bong nba th! tUch S3 cin )hHi lC8ng p bong 54^"] )hHi lC8ng S. ,-.- ;3 Q v
thnh phYn r th*o th! tUch cPa hn h8p S l
2, 06r ,"17 v 76r ,"10 B, 46r ,#12 v 46r ,#17
., 46r ,0156 v 46r ,012 D, 46r ,"17 v 46r ,"10
.'u 38 : 1n h8p S g&m m*tan v 5 ol*}in. ,ho 5632 lUt hn h8p S Zua >ung >ach bom >C th9y c+ 5 ch9t )hU bay a3 %Ht
chy hon ton )hU ny thu %C8c 43400g ,T". -hnh phYn r vd th! tUch m*tan v ol*}in tong hn h8p S l
2, "7.5#r v J#.2Jr. B, #7.4r v 7#.4r. ., "6r v 26r. D, J#.]r v "7.5r.
.'u 39: ,ho 2]76ml M%)tcN an)*n S Zua >ung >ach bom >C. Gau phWn <ng th9y )hHi lC8ng bnh bom t\ng ""30g. Qit S c+
%&ng ph'n hnh hc. ,-,- cPa S l
Nhng g chng ta bit ngy hm nay s li thi vo ngy hm sau. Nu chng ta ngng hc th chng ta s ngng pht ti!n
Nguyn Th Hoi 0979495156 ; 0973857103 FB : Thien Kiem
2, ,1" A ,1 B ,1" B ,1#. B, ,1# B ,1 A ,1 B ,1#.
., ,1" A ,1 B ,1 B ,1" B ,1#. D, M,1#N" , A ,1".
.'u 40: 7, ,ho hi%ocacbon S phWn <ng vIi bom Mtong >ung >achN th*o tL lc mol 5 / 53 thu %C8c ch9t hu c: p Mch<a
J0362r Q vd )hHi lC8ngN. shi S phWn <ng vIi 1Q th thu %C8c hai sWn phXm hu c: )hc nhau. -(n gi cPa S l
2, butB5B*n. B, butB"B*n. ., .opil*n. D, Siclopopan.
-, 1i%ocacbon S c=ng 1,l th*o tL lc mol 5/5 t?o sWn phXm c+ hm lC8ng clo l 44360r. S c+ cng th<c ph'n tb l
.'u 41: 1n h8p S g&m m*tan v an)*n3 cho 437 lUt S Zua >ung >ach bom >C th9y )hHi lC8ng bnh bom t\ng J3"2g v c+
"3722 lUt )hU bay a M%)tcN. ,-.- cPa an)*n l
2, ,012 B, ,4156 ., ,#17 D, ,"10
.'u 4+: fVn #3#7 lUt M%)tcN hn h8p S g&m " an)*n l vo bnh nCIc bom >C3 th9y )hHi lC8ng bnh t\ng th(m
J3Jg. ,-.- cPa " an)*n l
2, ,"10 v ,012. B, ,#17 v ,012. ., ,012 v ,4156. D, ; hoOc Q.
.'u 43: ,ho 56 lUt hn h8p )hU M4037o,q 632670 atmN g&m " ol*}in l=i Zua bnh >ung >ach bom >C th9y )hHi lC8ng bnh
bom t\ng 5732g. ,-.- cPa " an)*n l MQit sH , tong cc an)*n )hng vC8t Zu 4N
2, ,"10 v ,4156. B, ,#17 v ,4156. ., ,012 v ,4156. D, ; hoOc Q.
Dng 4: :h;n <ng =>ng H+5TCnh HiDu EuF#
.'u 44: ,ho hn h8p S g&m *til*n v 1" c+ tL )hHi so vIi 1" bong 03"4. fVn S Zua b=t ni)*n nung n+ng Mhicu su9t phWn
<ng J4rN thu %C8c hn h8p p. -L )hHi cPa p so vIi 1" Mcc th! tUch %o @ cKng %idu )icnN l
2, 43"#. B, #3"4. ., 43#4. D, 56307.
.'u 45: ,ho 1" v 5 ol*}in c+ th! tUch bong nhau Zua Ni)*n %un n+ng ta %C8c hn h8p ;. Qit tL )hHi h:i cPa ; %Hi vIi 1"
l "#3". 1icu su9t phWn <ng hi%o ho l J4r. ,ng th<c ph'n tb ol*}in l
2, ,"10. B, ,#17. ., ,012. D, ,4156.
.'u 46: 1n h8p )hU S g&m 1" v m=t an)*n c+ )hW n\ng c=ng 1Q cho sWn phXm hu c: >uy nh9t. -L )hHi cPa S so vIi
1" bong ]35. Run n+ng S c+ gc tc Ni3 sau )hi phWn <ng gWy a hon ton3 thu %C8c hn h8p )hU p )hng lm m9t mu
nCIc bomq tL )hHi cPa p so vIi 1" bong 5#. ,ng th<c c9u t?o cPa an)*n l
2, ,1#B,1A,1B,1. B, ,1"A,1B,1"B,1#. ., ,1"A,M,1#N". D, ,1"A,1".
.'u 47: ,ho hn h8p S g&m an)*n v hi%o c+ tL )hHi so vIi h*li bong #3##. ,ho S %i Zua b=t ni)*n nung n+ng %n )hi
phWn <ng gWy a hon ton3 thu %C8c hn h8p p c+ tL )hHi so vIi h*li l 0. ,-.- cPa S l
2, ,"10. B, ,#17. ., ,012. D, ,4156.
.'u 48: 1n h8p )hU S g&m 1" v ,"10 c+ tL )hHi so vIi 1* l #3J4. fVn S Zua Ni nung n+ng3 thu %C8c hn h8p )hU p c+ tL
)hHi so vIi 1* l 4. 1icu su9t cPa phWn <ng hi%o ho l
2, "6r. B, "4r. ., 46r. D, 06r.
.'u 49: ,ho cc ch9t/ giclobutan3 "Bm*tylpop*n3 butB5B*n3 cisBbutB"B*n3 "Bm*tylbutB"B*n. fhy g&m cc ch9t sau )hi phWn
<ng vIi 1" M>C3 gc tc Ni3 t6N3 cho cKng m=t sWn phXm l
2, giclobutan3 cisBbutB"B*n v butB5B*n. B, butB5B*n3 "Bm*tylpop*n v cisBbutB"B*n.
., giclobutan3 "Bm*tylbutB"B*n v butB5B*n. D, "Bm*tylpop*n3 cis BbutB"B*n v giclobutan.
Dng 5: :h;n <ng =h8y
.'u 50: RHt chy hon ton a gam hn h8p *t*n3 pop*n3 butB"B*n cYn >Kng va %P b lUt ogi M@ %)tcN thu %C8c "30 mol ,T"
v "30 mol nCIc. ti ta cPa b l
2, ]"30 lUt. B, ]03" lUt. ., 26370 lUt. D, "03] lUt.
.'u 51: RHt chy hon ton $ lUt M%)tcN hn h8p S g&m ,103 ,"10 thu %C8c 6354 mol ,T" v 63" mol 1"T. ti ta cPa $ l
2, "3"0. B, #3#7. ., 0302. D, 5372.
.'u 5+: RHt chy hon ton 635 mol hm h8p g&m ,103 ,0156 v ,"10 thu %C8c 6350 mol ,T" v 63"#mol 1"T. GH mol cPa
an)an v an)*n tong hn h8p lYn lC8t l
2, 636] v 6365. B, 6365 v 636]. ., 6362 v 636". D, 636" v 6362
Nhng g chng ta bit ngy hm nay s li thi vo ngy hm sau. Nu chng ta ngng hc th chng ta s ngng pht ti!n