DANH MC CC BNG

Bng 2.1. Mt gm, hng s in mi, tn hao tan, h s kp ca mu M01150 ........................................................................................................... 32

Bng 2.2. Kch thc ht trung bnh ca cc mu gm PZT-PZN-PMnN ...... 33

Bng 3.1. Kch thc ht trung bnh ca cc mu gm PZT-PZN-PMnN pha
tp x%kl CuO thiu kt ti 850oC. ........................................................ 41
Bng 4.1. Hng s in mi, tn hao in mi o ti nhit phng theo
nng CuO ............................................................................................ 42
Bng 4.2. Nhit Tm ca cc mu ti tn s 1kHz ........................................... 45
Bng 4.3. H s lin kt in c kp, h s phm cht Qm ca h gm PZTPZN-PMnN theo nng CuO ............................................................. 52
Bng 4.4. H s lin kt in c kt ca h gm PZT-PZN-PMnN theo nng
CuO...................................................................................................... 56
Bng 4.5. Cc h s p in ca h gm PZT- PZN- PMnN theo nng
CuO ........................................................................................................... 58

DANH MC CC HNH V, TH
Hnh 1.1. nh SEM th hin s hnh thnh lin kt gia 3 ht gn nhau ( c
dng hnh cu) trong thiu kt trng thi rn. ........................................ 5
Hnh 1.2. S gn kt hai ht ti bin tip xc........................................................ 6
Hnh 1.3. S tng din tch tip xc gia cc ht v s hnh thnh cc l xp
do s khuch tn b mt ca cc nguyn t: a) Trc khi thiu kt; b) Sau
khi thiu kt . ............................................................................................... 7

Hnh 1.4. Qu trnh khuch tn qua lp sn phm ca phn ng . .......................... 12

Hnh 1.5. S so snh vi cu trc hai m hnh (a) thiu kt trng thi rn (b)
thiu kt pha lng . .................................................................................... 14

Hnh 1.6. Cc giai on trong thiu kt pha lng . .................................................. 15

Hnh 1.7. S ph thuc mt gm PMNZT vo nhit thiu kt vi nng
CuO khc nhau .......................................................................................... 17

Hnh 1.8. S ph thuc ca mt gm PZT-PZN-PNN vo nng CuO thiu

kt cc nhit khc nhau. .................................................................... 18

Hnh 1.9. Mt ca gm PAN-PZT theo 0.0 < x 10.0%kl CuO thiu kt ti

900C so vi x = 0 thiu kt 1200C trong 1 gi ..................................... 19

Hnh 1.10. Gin nhiu x tia X ca gm PMNZT vi (a) 0,(b) 0.05 (c) 0.1 (d)
0.2 (e) 0.3 % nng CuO khc nhau thiu kt ti 1050C ................... 20

Hnh 1.11. Gin nhiu x tia X ca gm PZT-PZN-PNN + x% kl CuO thiu kt

9000C lu 2h [6]. ....................................................................................... 20

Hnh 1.12. nh SEM ca gm PMNZT tinh khit thiu kt ti (a) 950, (b) 1050,
(c) 1200C, v cc mu pha tp 0.1% kl CuO thiu kt ti (d) 950, (e)
1050, (f) 1200C lu trong 4 gi . ............................................................. 21

Hnh 1.13. nh SEM ca PZT-PZN-PNN + x% kl CuO gm thiu kt ti 900oC

lu trong 2 gi . ......................................................................................... 22

Hnh 1.14. H s p in (d33), h s lin kt in c (kP), v hng s in mi (r),

ca gm PMNZT tinh khit v pha tp CuO lu trong 4 gi nhit
thiu kt khc nhau. ................................................................................... 23

Hnh 1.15. Mt , hng s in mi (33T/0), h s lin kt in c (kp), h s

phm cht (Qm) v h s p in(d33) ca mu PZT-PZN-PNN + x% kl
CuO thiu kt ti 900oC lu trong 2h ....................................................... 24

Hnh 1.16. Dng ng tr ca gm 0.75PZT0.25PZNMn + xmol% CuO vi

0.0 x 3.0 thiu kt ti 850 oC lu trong 4 gi .................................... 25

Hnh 1.17. Dng ng tr ca gm 0.65PZT580.35PNN + x% mol CuO vi 0.0

x 4.0 thiu kt ti 900 oC lu trong 4 gi .......................................... 26

Hnh 2.1. Quy trnh cng ngh ch to gm p in. ......................................... 29

Hnh 2.2. Mt gm l mt hm ca nng CuO ca gm PZT-PZN-PMnN
thiu kt ti cc nhit khc nhau. ......................................................... 32

Hnh 2.3. nh SEM ca mu M4 thiu kt cc nhit (a) 8000C, (b) 8300C, (c)
8500C, (d) 8700C ....................................................................................... 33

Hnh 2.4. Gin nhiu x tia X ca (a) mu M0-1150 v (b) mu M4-850. ........ 34
Hnh 2.5. S ph thuc ca hng s in mi theo nng CuO ca gm thiu
kt ti cc

nhit khc nhau. ............................................................... 35

Hnh 2.6. S ph thuc ca tn hao in mi theo nng CuO ca gm thiu kt

ti cc nhit khc nhau. ........................................................................ 35

Hnh 2.7. S ph thuc ca hng s in mi theo nhit ca mu M4 thiu kt

ti cc nhit khc nhau.. ........................................................................ 36

Hnh 3.1. S ph thuc ca mt gm vo nng CuO . .................................. 37

Hnh 3.2. Gin nhiu x tia X ca cc mu gm PZT-PZN-PMnN pha tap
x%kl CuO. ................................................................................................ 38
Hnh 3.3. Ph tn sc theo nng lng EDS ca mu M4 thiu kt ti 850oC ...... 39
Hnh 3.4. S ph thuc ca hng s mng vo nng CuO. .......................... 39
Hnh 3.5. nh SEM ca cc mu .....................................................................40

Hnh 4.1. S ph thuc ca hng s in mi vo nng CuO ........................... 44

Hnh 4.2. S ph thuc ca hng s in mi v tn hao in mi theo nhit ti
tn s 1KHz ca cc mu. ......................................................................... 45

Hnh 4.3. S ph thuc ca nhit Tm ca h gm theo nng CuO ................ 46

Hnh 4.4. S ph thuc ca hng s in mi v tn hao in mi theo nhit
ca cc mu o ti cc tn s khc nhau. .................................................. 47

Hnh 4.5. Dng ng tr ca cc mu. ................................................................. 48

Hnh 4.6. S ph thuc ca in trng khng v phn cc d vo nng CuO ... 49
Hnh 4.7. Ph cng hng dao ng theo phng radian ca cc mu M0, M1,
M2, M3,M4, M5, M6 ............................................................................... 50
Hnh 4.8. Ph cng hng dao ng theo phng b dy ca cc mu M0, M1,
M2, M3,M4, M5, M6 ............................................................................... 54

Hnh 4.9. S ph thuc ca h s lin kt in c kp, kt v h s p in d31 theo

nng CuO ............................................................................................. 54

Hnh 4.10. S ph thuc ca h s phm cht c Qm v tn hao in mi tan theo

nng CuO ............................................................................................. 60