MC LC

Trang
Trang ph ba
Li cam oan
Li cm n
Mc lc
Danh mc cc k hiu v ch vit tt
Danh mc cc bng
Danh mc cc hnh v, th
M U .......................................................................................................... 1
CHNG 1: TNG QUAN L THUYT .................................................. 4
A. L thuyt v thiu kt ................................................................................... 4
1.1. Khi nim thiu kt .................................................................................... 4
1.2. Cc giai on ca qu trnh thiu kt ......................................................... 5
1.3. C ch di chuyn vt cht .......................................................................... 6
1.3.1. S di chuyn vt cht qua pha kh .................................................. 6
1.3.2. Khuch tn b mt........................................................................... 7
1.3.3. Khuch tn th tch ......................................................................... 7
1.3.4. Dng chy nht ............................................................................... 7
1.4. Kt tinh li trong qu trnh thiu kt ......................................................... 8
1.5. iu kin thiu kt ..................................................................................... 8
1.5.1. Tnh cht ca bt ban u ............................................................... 8
1.5.2. p lc p bt to hnh ..................................................................... 8
1.5.3. Nhit thiu kt ............................................................................ 8
1.5.4. Thi gian thiu kt .......................................................................... 8

1.5.5. co ngt ....................................................................................... 8

1.6. Phn loi thiu kt ...................................................................................... 9
1.6.1. Thiu kt pha rn............................................................................. 9
1.6.1.1. i cng v phn ng pha rn ........................................... 9
1.6.1.2. C ch ca phn ng pha rn ............................................. 10
1.6.2. Thiu kt pha lng......................................................................... 13
1.6.2.1. Lc dn ng ..................................................................... 14
1.6.2.2. Cc giai on thiu kt pha lng........................................ 15
B. nh hng ca CuO n cc tnh cht ca gm trn c s PZT ............... 17
1.1. nh hng ca nng CuO n mt gm ca h gm trn c s PZT
......................................................................................................................... 17
1.2. nh hng ca nng CuO n cu trc v vi cu trc ca gm trn c
s PZT ............................................................................................................. 19
1.2.1. nh hng ca nng CuO n cu trc ca gm trn c s PZT
....................................................................................................................... 19
1.2.2. nh hng ca nng CuO n vi cu trc ca gm trn c s
PZT ................................................................................................................ 20
1.3. nh hng ca nng CuO n tnh cht in mi, p in ca gm
trn c s PZT ................................................................................................. 23
1.4. nh hng ca nng CuO n tnh cht st in ca gm trn c s
PZT .................................................................................................................. 25
CHNG 2: CH TO MU .................................................................... 27
2.1. Cng ngh ch to mu ............................................................................ 27
2.2. nh hng ca CuO n nhit thiu kt............................................. 31
2.2.1. Kt qu kho st mt gm........................................................ 31

2.2.2. Kt qu phn tch cu trc ............................................................ 34

2.2.3. Kt qu kho st tnh cht in mi .............................................. 34
2.2.3.1. Hng s in mi nhit phng ................................... 34
2.2.3.2. S ph thuc ca hng s in mi theo nhit ............. 36
CHNG 3: NH HNG CA CuO N CU TRC, VI CU
TRC CA H GM PZT-PZN-PMnN ................................................... 37
3.1. nh hng ca CuO n mt gm ..................................................... 37
3.2. nh hng ca CuO n cu trc ca h gm ........................................ 38
3.3. nh hng ca CuO n vi cu trc ca gm ......................................... 39
CHNG 4: TNH CHT IN MI, ST IN, P IN CA H
GM PZT-PZN-PMnN + x%kl CuO ......................................................... 42
4.1. nh hng ca nng CuO n cc tnh cht in mi ca h gm.... 42
4.1.1. S ph thuc ca hng s in mi theo nng CuO nhit
phng ............................................................................................................... 42
4.1.2. S ph thuc ca hng s in mi theo nhit ........................ 44
4.1.3. S ph thuc nhit Tm ca h gm theo nng CuO ............ 45
4.1.4. S ph thuc ca hng s in mi theo tn s ............................ 46
4.2. Tnh cht st in ca h gm.................................................................. 48
4.3. nh hng ca nng CuO n tnh cht p in ca h gm ............ 50
KT LUN .................................................................................................... 61
DANH MC CC CNG TRNH CA TC GI .................................. 62
TI LIU THAM KHO ............................................................................ 63
PH LC