PH LC

Ph lc 1: Gin nhiu x tia X ca cc mu thiu kt nhit 850oC

Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample M0

1300

d=2.874

1200

1100

1000

900

Lin (Cps)

800

700

600

500

100

d=1.355

d=1.437

d=2.036

d=1.822

200

d=2.346

d=4.070

300

d=1.661

400

0
20

30

40

50

60

70

2-Theta - Scale
File: Khanh Hue mau M0.raw - Type: 2Th/Th locked - Start: 20.000 - End: 70.010 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 12 s - 2-Theta: 20.000 - Theta: 10.000 - Chi: 0.0
00-022-0663 (I) - Lead Niobium Zinc Oxide - Pb(Nb0.66Zn0.33)O3 - Y: 53.75 % - d x by: 1. - WL: 1.5406 - Rhombo.H.axes - a 5.74190 - b 5.74190 - c 7.04710 - alpha 90.000 - beta 90.000 - gamma 120.000

Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample M1-850

1200

d=2.869

1100

1000

900

800

600

500

d=1.357

100

d=1.821

200

d=2.031

d=2.342

300

d=1.435

d=1.658

400

d=4.066

Lin (Cps)

700

0
20

30

40

50

60

2-Theta - Scale
File: Vuong Hue mau M1-850.raw - Type: 2Th/Th locked - Start: 20.000 - End: 70.010 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 11 s - 2-Theta: 20.000 - Theta: 10.000 - Chi
01-070-4060 (C) - Lead Zirconium Titanium Oxide - Pb(Zr0.52Ti0.48)O3 - Y: 48.60 % - d x by: 1. - WL: 1.5406 - Tetragonal - a 4.05500 - b 4.05500 - c 4.11000 - alpha 90.000 - beta 90.000 - gamma 90.000 -

70

Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample M2-850

d=2.871

700

600

Lin (Cps)

500

400

d=1.357

d=1.437

d=2.016

d=1.829
d=1.809

100

d=2.052

d=4.089
d=4.037

d=2.341

200

d=1.663
d=1.653

300

0
20

30

40

50

60

70

2-Theta - Scale
File: Vuong Hue mau M2-850.raw - Type: 2Th/Th locked - Start: 20.000 - End: 70.010 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 12 s - 2-Theta: 20.000 - Theta: 10.000 - Chi
01-070-4264 (C) - Lead Zirconium Titanium Oxide - Pb(Zr0.53Ti0.47)O3 - Y: 44.12 % - d x by: 1. - WL: 1.5406 - Tetragonal - a 4.03500 - b 4.03500 - c 4.13100 - alpha 90.000 - beta 90.000 - gamma 90.000 -

Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample M3-850

d=2.872

700

600

400

d=1.357

d=1.829
d=1.812

d=2.052

100

d=2.017

d=2.341

200

d=1.439

d=1.665
d=1.652

300

d=4.093

Lin (Cps)

500

0
20

30

40

50

60

2-Theta - Scale
File: Vuong Hue mau M3-850.raw - Type: Locked Coupled - Start: 20.000 - End: 70.010 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 5 s - 2-Theta: 20.000 - Theta: 10.000 - Ch
01-070-4264 (C) - Lead Zirconium Titanium Oxide - Pb(Zr0.53Ti0.47)O3 - Y: 36.84 % - d x by: 1. - WL: 1.5406 - Tetragonal - a 4.03500 - b 4.03500 - c 4.13100 - alpha 90.000 - beta 90.000 - gamma 90.000 -

70

Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample M4

d=2.878

500

Lin (Cps)

400

300

d=1.358

d=1.441

d=1.830

d=2.054

100

d=2.018

d=4.102

d=2.347

d=1.665

200

0
20

30

40

50

60

70

2-Theta - Scale
File: Vuong Hue mau M4(3).raw - Type: 2Th/Th locked - Start: 20.000 - End: 70.010 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 10 s - 2-Theta: 20.000 - Theta: 10.000 - Chi:
01-070-4264 (C) - Lead Zirconium Titanium Oxide - Pb(Zr0.53Ti0.47)O3 - Y: 28.95 % - d x by: 1. - WL: 1.5406 - Tetragonal - a 4.03500 - b 4.03500 - c 4.13100 - alpha 90.000 - beta 90.000 - gamma 90.000 -

Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample M5-850

800

d=2.875

700

600

400

d=1.358

d=1.439

d=1.830
d=1.810

d=2.016

d=2.620

d=3.181

100

d=2.054

d=2.342

200

d=1.665
d=1.652

300

d=4.098

Lin (Cps)

500

0
20

30

40

50

60

2-Theta - Scale
File: Vuong Hue mau M5-850.raw - Type: Locked Coupled - Start: 20.000 - End: 70.010 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 10 s - 2-Theta: 20.000 - Theta: 10.000 - C
01-070-4264 (C) - Lead Zirconium Titanium Oxide - Pb(Zr0.53Ti0.47)O3 - Y: 22.78 % - d x by: 1. - WL: 1.5406 - Tetragonal - a 4.03500 - b 4.03500 - c 4.13100 - alpha 90.000 - beta 90.000 - gamma 90.000 00-005-0543 (D) - Zirconium Oxide - ZrO2 - Y: 2.50 % - d x by: 1. - WL: 1.5406 - Monoclinic - a 5.17000 - b 5.26000 - c 5.30000 - alpha 90.000 - beta 80.170 - gamma 90.000 - Primitive - P21/c (14) - 4 - 142.

70

Faculty of Chemistry, HUS, VNU, D8 ADVANCE-Bruker - Sample M6-850

800

d=2.871

700

600

Lin (Cps)

500

400

d=1.357

d=1.827

d=2.051
d=2.019

d=2.622

100

d=3.176
d=3.094

d=4.091
d=4.029

200

d=1.436

d=2.342

d=1.664
d=1.651

300

0
20

30

40

50

60

70

2-Theta - Scale
File: Vuong Hue mau M6-850.raw - Type: Locked Coupled - Start: 20.000 - End: 70.010 - Step: 0.030 - Step time: 1. s - Temp.: 25 C (Room) - Time Started: 14 s - 2-Theta: 20.000 - Theta: 10.000 - C
01-070-4264 (C) - Lead Zirconium Titanium Oxide - Pb(Zr0.53Ti0.47)O3 - Y: 31.99 % - d x by: 1. - WL: 1.5406 - Tetragonal - a 4.03500 - b 4.03500 - c 4.13100 - alpha 90.000 - beta 90.000 - gamma 90.000 00-036-0420 (D) - Baddeleyite, syn - ZrO2 - Y: 2.02 % - d x by: 1. - WL: 1.5406 - Monoclinic - a 5.14630 - b 5.21350 - c 5.31100 - alpha 90.000 - beta 99.200 - gamma 90.000 - Primitive - P21/c (14) - 4 - 140.

Hnh P.1. Gin nhiu x tia X ca cc mu M0, M1, M2,

M3, M4, M5, M6 thiu kt nhit 850oC.
Ph lc 2: Dng ng tr ca cc mu thiu kt nhit 850oC
2

P (C/cm )

40
M1
M2
M3
M4
M5
M6

30
20
10
0

-20

-15

-10

-5

0
-10

10

15

20

E (kV /cm)

-20
-30
-40

Hnh P.2. Dng ng tr ca cc mu M0, M1, M2, M3,

M4, M5, M6 thiu kt nhit 850oC.