S GIO DC V O TO H NI

TRNG THPT CHU VN AN

S 201

THI HC K I NM HC 2012- 2013

Mn Ha hc - Lp 12 Nng cao
(Dnh cho cc lp A, Toan, Tin)
Bui thi: sang ngay 22/12/2012
Thi gian lm bi: 90 pht, khng k thi gian giao .
thi gm 04 trang

Cho bit nguyn t khi (theo vC) cua cac nguyn t:

H = 1; O = 16; Cu = 64; Ag = 108; Fe = 56; Zn = 65; Mg = 24; Na = 23; Ca = 40;
K = 39; N = 14; Cl = 35,5; S = 32; Br = 80.
Cu 1: trung ho 15 gam mt loi cht bo c ch s axit bng 7, cn dng dung dch cha a gam
NaOH. Gi tr ca a l
A. 0,200.
B. 0,075.
C. 0,150.
D. 0,280.
Cu 2: Cho m gam hn hp bt Zn v Mg vo lng d dung dch FeSO4. Sau khi kt thc cc phn
ng, lc b phn dung dch thu c m gam bt rn. Phn trm theo khi lng ca Zn trong hn
hp bt ban u l
A. 12,67%.
B. 85,30%.
C. 90,59%.
D. 82,20%.
Cu 3: t chy hon ton 0,1 mol mt cht hu c X cn 4,48 lt O 2 ( ktc) thu c CO2 va H2O
vi s mol bng nhau. Bit rng X tc dng vi dung dch NaOH to ra 2 cht hu c. Cng thc cua
X l
A. CH3COOH.
B. HCOOC3H7.
C. HCOOCH3.
D. HCOOC2H5.
Cu 4: Khi thu phn hon ton 500 gam protein A th c 170 gam alanin. Nu phn t khi ca A
l 50.000 th s mt xch alanin trong phn t A l
A. 200.
B. 173.
C. 191.
D. 211.
Cu 5: Hp cht hu c X cha mt loi nhm chc, c cng thc phn t l C 6H10O4. Khi thy phn
X trong dung dich NaOH thu c mt mui va hai ancol c s nguyn t cacbon gp i nhau. X c
cng thc cu to la
A. HOOC - (CH2)4 COOH.
B. HOOC - CH2- CH2 - CH2 - COO - CH3.
C. CH3OOC - CH2 - COO - C2H5.
D. C2H5OOC - CH2 - CH2 COOCH3.
Cu 6: ng trng hp buta-1,3-ien v acrilonitrin (vinyl xianua) thu c mt loi cao su Buna-N
c cha 8,69% N v khi lng. T l s mt xch buta-1,3-ien v acrilonitrin ln lt l
A. 3 : 1.
B. 2 : 1.
C. 1 : 2.
D. 1 : 1.
Cu 7: Khi in phn NaCl nng chy (in cc tr), ti catt xy ra
A. s oxi ho ion Na+. B. s oxi ho ion Cl- C. s kh ion Cl-.
D. s kh ion Na+.
Cu 8: Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c
vi dung dch AgNO3?
A. Hg, Na, Ca.
B. Zn, Cu, Mg.
C. Fe, Ni, Sn.
D. Al, Fe, CuO.
Cu 9: Oxi ho 1 ancol n chc X bng CuO un nng c anehit Y. Oxi ho khng hon ton Y
bng O2 thu c axit Z. Cho Z tc dng vi X thu c m gam este. Thu phn m gam este ny
bng dung dch KOH va th thu c m 1 gam mui khan. Nu thu phn m gam este bng dung
dch Ca(OH)2 va th lng mui khan thu c l m 2 gam (bit m2 < m < m1). Cng thc ca Y
l
A. CH3CHO.
B. C2H5CHO.
C. C2H3CHO.
D. HCHO.
Cu 10: Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi
xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20 %)
A. 55 lt.
B. 81 lt.
C. 70 lt.
D. 49 lt.
Cu 11: Cho cc dung dch c cng nng : CH 3NH3Cl (1) ; C6H5NH3Cl (2); NH2-CH2-COOH (3).
Day cac dung dich c sp xp theo th t pH tng dn l
A. (3) < (1) < (2).
B. (2) < (3) < (1).
C. (1) < (2) < (3).
D. (2) < (1) < (3).
Cu 12: t 0,1 mol cht bo thu c s mol CO2 ln hn s mol H2O l 0,6 mol. Hi 1 mol cht
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bo c th cng hp ti a vi bao nhiu mol Br2?

A. 2 mol.
B. 3 mol.
C. 4 mol.
D. 5 mol.
Cu 13: Cho m gam hn hp X gm CuO, Fe2O3, FeO tac dung va u vi 100ml dung dich hn hp
H2SO4 1M va HCl 1M. Th tich khi NH 3 ti thiu iu kin tiu chun cn kh hoan toan m gam
hn hp X la
A. 1,12.
B. 2,24.
C. 4,48.
D. 6,72.
Cu 14: Dung dch no sau y lm qu tm i thnh mu xanh?
A. Dung dch alanin. B. Dung dch glyxin. C. Dung dch lysin.
D. Dung dch valin.
+
2+
Cu 15: Cho th in cc chun ca cc cp oxi ho kh Ag /Ag v Zn /Zn ln lt l +0,80V v
-0,76V. Sut in ng chun ca pin in ho Zn Ag bng
A. 0,84V.
B. 0,04V.
C. 1,56V.
D. 2,36V.
Cu 16: X phng ho hon ton 9,7 gam hn hp 2 este n chc X, Y cn ti thiu 100 ml dung
dch NaOH 1,5M. Sau phn ng, c cn dung dch thu c hn hp 2 ancol l ng ng k tip v
mt mui duy nht. Cng thc cu tao ca 2 este l
A. HCOOCH3 v HCOOC2H5.
B. CH3COOCH3 v CH3COOC2H5.
C. C2H5COOCH3 v C2H5COOC2H5
. D. C3H7COOCH3 v C3H7COOC2H5.
Cu 17: Trong cc dung dch sau: glucoz; 3-monoclopropan-1,2-iol (3MCPD); etylen glicol; KOH
long; Ala-Ala-Gly; amoniac; propan-1,3-iol. S dung dch ho tan c Cu(OH)2 l
A. 4.
B. 6.
C. 3.
D. 5.
Cu 18: Khi t chy hon ton mt este no, n chc th th tich hi nc sinh ra bng th tich khi
oxi phn ng cung iu kin. Tn gi ca este l
A. propyl axetat.
B. etyl axetat.
C. metyl axetat.
D. metyl fomat.
Cu 19: Nhng kim loi no sau y c th iu ch t oxit bng phng php nhit luyn?
A. Fe, Al, Cu.
B. Fe, Cu, Ni.
C. Ni, Cu, Ca.
D. Zn, Mg, Fe.
Cu 20: S miligam KOH cn trung ho lng axit beo t do v x phng ho triglixerit trong
mt gam cht bo gi l ch s x phng ho ca cht bo. Mt mu cht bo c ch s axit bng 7
cha 89% tristearin co chi s x phng ho l
A. 155.
B. 175.
C. 165.
D. 185.
Cu 21: Cho dy cc cht: C6H5NH2, H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2, C6H5OH
(phenol). S cht trong dy tc dng c vi dung dch HCl l
A. 5.
B. 2.
C. 3.
D. 4.
Cu 22: Kt lun no sau y la ng?
A. I2 c dng lm thuc th nhn ra xenluloz.
B. Qua trinh quang hp c giai oan tao ra glucoz.
C. Fructoz tham gia phn ng trng bac chng t fructoz c nhm CHO.
D. Trong qu trnh tiu ho, tinh bt b thu phn ch yu nh axit HCl c trong dch v d dy .
Cu 23: Cho 8,9 gam hn hp X gm 2 amino axit no, mch h tc dng vi dung dch HCl d c
a gam mui. Cng 8,9 gam X khi tc dng vi dung dch NaOH d th lng mui thu c l (a
1,45) gam. Hai amino axit co th l
A. NH2C2H4COOH v NH2C3H6COOH.
B. NH2CH2COOH v NH2C3H6COOH.
C. NH2C4H8COOH v NH2C3H6COOH.
D. NH2CH2COOH v NH2C2H4COOH.
Cu 24: Cho 0,03 mol Al v 0,05 mol Fe tc dng vi 100 ml dung dch X cha Cu(NO 3)2 v
AgNO3. Sau phn ng thu c dung dch Y v 8,12 gam cht rn Z gm 3 kim loi. Cho cht rn Z
tc dng vi dung dch HCl d thu c 0,672 lt H 2 (ktc). Cho bit cc phn ng xy ra hon ton.
Nng mol ca Cu(NO3)2 v AgNO3 trong dung dch X ln lt la
A. 0,5M v 0,3M.
B. 0,3M v 0,7M.
C. 0,4M v 0,2M.
D. 0,4M v 0,6M.
Cu 25: Hoa tan ht 50 gam hn hp X gm glucoz v saccaroz vo nc c dung dch Y. Dung
dch Y lm mt mu va 160 gam dung dch Br 2 20%. Phn trm v khi lng ca saccaroz
trong hn hp l
A. 25%.
B. 28%.
C. 40%.
D. 72%.
Cu 26: Mt vt bng hp kim Zn Cu bi n mon in hoa trong khng kh m. Qu trnh xy ra
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cc m l

A. 2H+ + 2e H2.
B. Zn Zn2+ +2e.

C. Cu Cu2+ + 2e.
D. 2H2O + 2e 2OH- + H2.
Cu 27: t chy hon ton a gam C 2H5OH thu c 0,2 mol CO 2. t chy hon ton b gam
CH3COOH thu c 0,3 mol CO 2. Cho a gam C2H5OH tc dng vi b gam CH 3COOH (xc tc
H2SO4 c) vi hiu sut phn ng l 50% th thu c m gam este. Gia tri cua m l
A. 8,8.
B. 6,6.
C. 6,8.
D. 4,4.
Cu 28: Tinh bt, xenluloz, saccaroz va mantoz u c kh nng tham gia phn ng
A. thy phn.
B. trng bac.
C. trng ngng.
D. tao phc vi Cu(OH)2.
Cu 29: un 34 gam phenyl axetat trong mt lng dung dch NaOH d, sau khi phn ng xay ra
hon ton thu c m gam mui. Gi tr ca m l
A. 29.
B. 44.
C. 20,5.
D. 49,5.
Cu 30: Ngm mt thanh st trong dung dich H2SO4 c, un nong. Sau khi phan ng hoa hoc xay ra
hoan toan, thu c 4,48 lit khi iu kin tiu chun va thy khi lng thanh st giam m gam. Gi
tr m l
A. 11,2.
B. 6,72.
C. 7,2.
D. 5,6.
Cu 31: Cho 21,9 gam mt amin n chc, bc 1 tc dng vi lng d dung dch FeCl 3, sau phn
ng thu c 10,7 gam kt ta. Phn trm khi lng cua N trong amin o l
A. 45,16%.
B. 19,72%.
C. 23,73%.
D. 19,18%.
Cu 32: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht
thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1
mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ho thc hin cng nhit )
A. 2,925.
B. 2,412.
C. 0,342.
D. 0,456.
Cu 33: Cho s chuyn ha sau: Tinh bt X Y Z metyl axetat.
(mi mi tn biu din mt phng trnh phn ng)
Cc cht Y, Z trong s trn ln lt l
A. C2H5OH, CH3COOH.
B. CH3COOH, CH3OH.
C. CH3COOH, C2H5OH.
D. C2H4, CH3COOH.
Cu 34: Phn ng no di y khng th hin tnh baz ca amin?
A. C6H5NH2 + HCl C6H5NH3Cl

B. CH3NH2 + H2O CH3NH + OH

3
3+
+
C. Fe + 3CH3NH2 + 3H2O Fe(OH)3 +
3CH3NH

3
D. CH3NH2 + HNO2 CH3OH + N2 + H2O

+CH3I
+HONO
+CuO
NH

Y
Z
Cu 35: Cho s phn ng:
3
(1 :1)
to
Bit Z c kh nng tham gia phn ng trng bac. Hai cht Y v Z ln lt l
A. CH3OH, HCHO.
B. C2H5OH, HCHO.
C. CH3OH, HCOOCH3.
D. C2H5OH, CH3CHO.
Cu 36: S ng phn amin c cng thc phn t C3H9N l
A. 4.
B. 3.
C. 2.
D. 5.
Cu 37: Khi trng ngng m gam axit -aminocaproic vi hiu sut 80% thu c polime, 2,88 gam
nc va amino axit con d. Gi tr ca m l
A. 20,96.
B. 23,02.
C. 18.08.
D. 26,2.
Cu 38: T hn hp glyxin (Gly) v alanin (Ala) c th to ra ti a bao nhiu loai ipeptit ?
A. 1 cht.
B. 2 cht.
C. 3 cht.
D. 4 cht.
Cu 39: Cho m gam anilin tc dng ht vi dung dch Br 2 thu c 9,9 gam kt ta. Gi tr m
dng l
A. 3,72.
B. 0,93.
C. 1,86.
D. 2,79.
Cu 40: Mt hp cht hu c X c cng thc C 3H9O2N. Cho X phn ng vi dung dch NaOH, un
nh thu c kh Z lm xanh qu tm m va mui Y. Nung Y vi NaOH rn (c CaO) thu c CH 4.
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Cng thc cu to thu gn ca X la

A. CH3COONH3CH3.
B. CH3CH2COONH4.
C. HCOONH3CH2CH3.
D. HCOONH2(CH3)2.
Cu 41: in phn (vi in cc tr) 200 ml dung dch CuSO4 nng x mol/l, sau mt thi gian thu
c dung dch Y vn cn mu xanh va khi lng gim 8 gam so vi dung dch ban u. Cho 16,8
gam bt st vo Y, sau khi cc phn ng xy ra hon ton thu c 12,4 gam kim loi. Gi tr ca x l
A. 2,25.
B. 3,25.
C. 1,25.
D. 1,50.
Cu 42: trung ha 20 gam dung dch ca mt amin n chc X nng 22,5% cn dng 100 ml
dung dch HCl 1M. Cng thc phn t ca X l
A. C2H7N.
B. CH5N.
C. C3H5N.
D. C3H7N.
Cu 43: Pht biu no sau y khng ng?
A. Khi glucoz dng mach vng th tt c cc nhm OH u to ete vi CH3OH.
B. dng mch h, glucoz c 5 nhm OH k nhau.
C. Trong dung dich, glucoz tn ti dng mch h v dng mch vng.
D. Glucoz tc dng c vi nc brom.
Cu 44: Pht biu nao sau y la ng?
A. Lc axit ca phenol yu hn ca ancol.
B. Cao su thin nhin la polime cua isopren co cu hinh cis.
C. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp.
D. Lc baz ca anilin mnh hn ca amoniac.
Cu 45: Cho dy chuyn ho: C 8H10O B - H 2O
polime.
(X)
C bao nhiu hp cht X cha vong benzen trong phn t thoa man s trn ?
A. 1.
B. 2.
C. 3.
D. 4.
Cu 46: Cho cc vt liu polime sau: nha PVC ; thu tinh hu c plexiglas ; t capron ; nha
bakelit ; cao su isopren ; t lapsan. S vt liu c iu ch t polime trng hp l
A. 3.
B. 4.
C. 2.
D. 5.
Cu 47: Trong s cc t sau: t tm, t visco, t nilon-6,6, t axetat, t capron, t lapsan. Nhng t
thuc loi t nhn to la
A. t visco v t axetat.
B. t nilon-6,6 v t capron.
C. t tm v t lapsan.
D. t visco v t nilon-6,6.
Cu 48: Pht biu nao sau y la ng?
A. Thy phn cht bo thu c etylen glicol.
B. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v
ancol.
C. Tt ca cac este c iu ch bng phn ng gia axit v ancol (xuc tac H2SO4 c).
D. Phn ng tng hp este t axit va ancol l phn ng thun nghch.
Cu 49: Cho cac cht : CH3COOCH=CH2 (I) ; HCOOCH2CH=CH2 (II).
Khi cho tng cht tac dung ht vi dung dich NaOH thi
A. chi san phm phan ng cua cht (II) tham gia phan ng trang bac.
B. sn phm cua 2 phan ng u tham gia phn ng trng bac.
C. sn phm cua 2 phan ng u khng tham gia phn ng trng bac.
D. chi san phm phan ng cua cht (I) tham gia phan ng trang bac.
Cu 50: Cho 50 ml dung dch glucoz tc dng vi mt lng d AgNO3 trong dung dch NH3 un nong
thu c 2,16 gam Ag. Nng mol/l ca dung dch glucoz dng l
A. 0,01M.
B. 0,02M.
C. 0,20M.
D. 0,10M.
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