HIDROCACBON THM Cu 1: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 2. B. 4. C. 3. D. 5.

HCl (du) Br2 (1:1)/ Fe, t NaOH (du)/ p, t X Y Z Cu 2: Cho s chuyn ho sau: Toluen Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. m-metylphenol v o-metylphenol. B. benzyl bromua v o-bromtoluen. C. o-bromtoluen v p-bromtoluen. D. o-metylphenol v p-metylphenol. Cu 3: Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. stiren; clobenzen; isopren; but-1-en. B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. C. buta-1,3-ien; cumen; etilen; trans-but-2-en. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. Cu 4: Ngi ta iu ch anilin bng s sau
o o

Fe HCl 3 Benzen Nitrobenzen Anilin 0 H SO a c 2 4 t

HNO a c

Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 186,0 gam B. 111,6 gam C. 55,8 gam D. 93,0 gam Cu 5: Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s mol 1:1 (c mt bt st) l A. p-bromtoluen v m-bromtoluen. B. benzyl bromua. C. o-bromtoluen v p-bromtoluen. D. o-bromtoluen v m-bromtoluen. Cu 6: Cho cc pht biu sau: (a) Khi t chy hon ton mt hirocacbon X bt k, nu thu c s mol CO2 bng s mol H2O th X l anken. (b) Trong thnh phn hp cht hu c nht thit phi c cacbon. (c) Lin kt ho hc ch yu trong hp cht hu c l lin kt cng ho tr. (d) Nhng hp cht hu c khc nhau c cng phn t khi l ng phn ca nhau. (e) Phn ng hu c thng xy ra nhanh v khng theo mt hng nht nh. (g) Hp cht C9H14BrCl c vng benzen trong phn t. S pht biu ng l A. 3. B. 2. C. 5. D. 4. Cu 7: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. dung dch NaOH. C. nc brom D. giy qu tm. Cu 8: Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohexan, xiclopropan v xiclopentan. Trong cc cht trn, s cht phn ng c vi dung dch brom l A. 6. B. 4. C. 5. D. 3. Cu 9. Benzen khng tan trong nc v l do no sau y: A.Benzen l cht hu c, nc l cht v c nn khng tan vo nhau. B.Benzen c khi lng ring b hn nc C.Phn t benzen l phn t phn cc D.Phn t benzen l phn t khng phn cc, nc l dung mi c cc

Cu 10 ,Danh php IUPAC ankylbenzen c CTCT sau l : A. 1etyl3metylbenzen B.5etyl1metylbenzen C.2etyl4metylbenzen D.4metyl2etyl benzen Cu 11.Cho cc cht thm sau:

CH3 C2H5

1. , 2. , 3. , 4. ,5. , 6. a) Cc cht c nh hng th o- v p- l? b) Cc cht c nh hng th m- l? A. a) 1,2,3. b) 4,5,6. B. a) 1,2,4,6. b) 3,5. C. a) 1,3,5. b) 2,4,6. D. a) 3,4,5,6. b) 1,2. Cu 12. Cc cht no cho sau c th tham gia p/ th vi Cl2 (as) ? A.etin,butan,isopentan B.propan,toluen, xiclopentan C.xiclopropan,stiren,isobutan D.metan,benzen, xiclohexan Cu 13. Hirocacbon thm A c CTPT l C8H10. Bit khi nitro ha A ch thu c mt dn xut mononitro. A l: A. o-xilen. B. p-xilen. C. m-xilen D. etylbenzen Cu 14. Hin tng g xy ra khi cho bromlng vo ng nghim cha benzen, lc ri yn A.dd brom b mt mu. B.C kh thot ra C.Xut hin kt ta D.brom khng b mt mu Cu 15. Cho s sau: X X Y

Y
Cc nhm X, Y ph hp vi s trn l: A.X( - CH3), Y( - Cl) B.X( - CH3), Y( - NO2) C.X( - Cl), Y( - CH3) D.C A, B, C Cu 16. Chn cm t thch hp in vo khong trng .... trong cu sau: Su nguyn t C trong phn t benzen lin kt vi nhau to thnh ........ A.Mch thng B. Vng 6 cnh u, phng. C. vng 6 cnh, phng D. mch c nhnh. Cu 17. Benzen khng tan trong nc v l do no sau y: A.Benzen l cht hu c, nc l cht v c nn khng tan vo nhau. B.Benzen c khi lng ring b hn nc C.Phn t benzen l phn t phn cc D.Phn t benzen l phn t khng phn cc, nc l dung mi c cc Cu 18 .T benzen thu c p-bromnitrobenzen phi tin hnh ln lt cc p/ vi nhng tc nhn no sau? A. Br2 ( xt: Fe, t0) , HNO3(xt: H2SO4,t0) B. Br2 ( xt: Fe, t0) , HNO3 long C. Br2 ( As), HNO3 (xt: H2SO4,t0) D. HNO3(xt: H2SO4,t0) , Br2 ( xt: Fe, t0) Cu 19. Sn phm diclobenzen no ( nu sau y) c u tin to ra khi cho clobenzen tc dng vi clo c bt Fe un nng lm xc tc? A.o diclobenzen B.m diclobenzen C.p diclobenzen D.c A v C Cu 20. Hirocacbon thm A c CTPT l C8H10. Bit khi nitro ha A ch thu c mt dn xut mononitro. A l: A. o-xilen. B. p-xilen. C. m-xilen D. etylbenzen

Cu 21: Khi trn vng benzen c sn nhm th -X, th nhm th hai s u tin th vo v tr o- v p- . Vy -X l nhng nhm th no ? A. -CnH2n+1, -OH, -NH2. B. -OCH3, -NH2, -NO2. C. -CH3, -NH2, -COOH. D. -NO2, -COOH, -SO3H.

Cu 22: phn bit c cc cht Hex-1-in, Toluen, Benzen ta dng 1 thuc th duy nht l: A. dd AgNO3/NH3. Cu 23: Cho nng) thu c A. 67,6%. Cu 24: Tin hnh trng hp vi ml dung dch Br2 , stiren l A. 60%. B. dd Brom. C. dd KMnO4. D. dd HCl.

ml bezen (d , g ml) tc dng vi mt lng va brom lng (xc tc bt st, un ml brombenzen (d ,4 g ml). Hiu sut brom ha t l B. 73,49%. C. 85,3%. D. 65,35%

,4 gam stiren c hn hp X gm polistiren v stiren (d). Cho X tc dng , sau cho dung K d vo thy xut hin , gam iot. Hiu sut trng hp B. 75%. C. 80%. D. 83,33%.

Cu 25: t chy hon ton hirocacbon X cho CO2 v H2O theo t l mol 1,75 : 1 v th tch. Cho bay hi hon ton , 6 gam X thu c mt th tch hi ng bng th tch ca , 6 gam oxi trong cng iu kin. Nhn xt no sau y l ng i vi X ? A. X khng lm mt mu dung dch Br2 nhng lm mt mu dung dch KMnO4 un nng. B. X tc dng vi dung dch Br2 to kt ta trng. C. X c th trng hp thnh PS. D. X tan tt trong nc.